# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1818852'
_audit_update_record             
;
2018-05-03 deposited with the CCDC.
2018-05-14 downloaded from the CCDC.
;
_audit_creation_date             2018-05-03
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.04.03 svn.r3497 for OlexSys, GUI svn.r5486)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C34 H22 Eu N4 O8, N O3'
_chemical_formula_sum            'C34 H22 Eu N5 O11'
_chemical_formula_weight         828.52
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.5851(11)
_cell_length_b                   11.3157(11)
_cell_length_c                   13.7776(10)
_cell_angle_alpha                92.788(7)
_cell_angle_beta                 101.970(8)
_cell_angle_gamma                92.107(8)
_cell_volume                     1610.6(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    2662
_cell_measurement_temperature    273(8)
_cell_measurement_theta_max      24.2280
_cell_measurement_theta_min      3.6030
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.019
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.86073
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.708
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             824
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0526
_diffrn_reflns_av_unetI/netI     0.0953
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11137
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         25.994
_diffrn_reflns_theta_min         3.363
_diffrn_ambient_temperature      273(8)
_diffrn_detector_area_resol_mean 16.0733
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -20.00   19.00   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -19.5055  -99.0000  150.0000 26

#__ type_ start__ end____ width___ exp.time_
  2 omega  -48.00   21.00   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -19.5055   38.0000 -180.0000 46

#__ type_ start__ end____ width___ exp.time_
  3 omega   49.00   76.00   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       22.7867  178.0000  -60.0000 18

#__ type_ start__ end____ width___ exp.time_
  4 omega   -1.00   93.50   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       22.7867   57.0000   90.0000 63

#__ type_ start__ end____ width___ exp.time_
  5 omega   -1.00   92.00   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       22.7867   57.0000    0.0000 62

#__ type_ start__ end____ width___ exp.time_
  6 omega  -48.00   46.50   1.5000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       22.7867  -57.0000 -150.0000 63
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0656391000
_diffrn_orient_matrix_UB_12      -0.0183634000
_diffrn_orient_matrix_UB_13      -0.0033812000
_diffrn_orient_matrix_UB_21      -0.0197882000
_diffrn_orient_matrix_UB_22      0.0529024000
_diffrn_orient_matrix_UB_23      -0.0230386000
_diffrn_orient_matrix_UB_31      -0.0016872000
_diffrn_orient_matrix_UB_32      -0.0284895000
_diffrn_orient_matrix_UB_33      -0.0472920000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.710
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5192
_reflns_number_total             6309
_reflns_odcompleteness_completeness 99.79
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         1.534
_refine_diff_density_min         -0.974
_refine_diff_density_rms         0.149
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         6309
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0645
_refine_ls_R_factor_gt           0.0491
_refine_ls_restrained_S_all      1.079
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0237P)²+0.4490P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0920
_refine_ls_wR_factor_ref         0.1030
_refine_special_details          SQUEEZE
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C4) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
3.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12), C14(H14),
 C15(H15), C16(H16), C20(H20), C21(H21), C22(H22), C24(H24), C25(H25), C26(H26),
  C27(H27), C29(H29), C31(H31), C32(H32), C33(H33)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.43109(3) 0.48487(3) 1.35274(2) 0.02010(10) Uani 1 1 d . . . . .
O1 O 0.2069(4) 0.5466(4) 1.2804(3) 0.0381(11) Uani 1 1 d . . . . .
O2 O 0.3609(4) 0.5839(4) 1.1990(3) 0.0330(11) Uani 1 1 d . . . . .
O3 O -0.3591(4) 0.5460(4) 0.4998(3) 0.0277(10) Uani 1 1 d . . . . .
O4 O -0.3560(4) 0.5646(4) 0.3421(3) 0.0297(10) Uani 1 1 d . . . . .
O5 O 0.3030(4) 0.3087(4) 1.2663(3) 0.0389(11) Uani 1 1 d . . . . .
O6 O 0.4782(4) 0.3565(4) 1.2115(3) 0.0328(10) Uani 1 1 d . . . . .
O7 O 0.4550(5) -0.3231(4) 0.5807(3) 0.0389(12) Uani 1 1 d . . . . .
O8 O 0.4184(4) -0.3125(3) 0.4147(3) 0.0280(10) Uani 1 1 d . . . . .
N1 N 0.1149(5) 0.6684(5) 0.8519(3) 0.0363(14) Uani 1 1 d . . . . .
N2 N 0.0853(5) 0.6700(5) 0.6918(3) 0.0303(12) Uani 1 1 d . . . . .
N3 N 0.4013(6) 0.1072(5) 0.8819(3) 0.0354(13) Uani 1 1 d . . . . .
N4 N 0.4028(6) 0.0751(4) 0.7269(3) 0.0333(13) Uani 1 1 d . . . . .
C1 C 0.2445(6) 0.5839(5) 1.2058(4) 0.0283(14) Uani 1 1 d . . . . .
C2 C 0.1480(6) 0.6286(6) 1.1211(4) 0.0306(15) Uani 1 1 d . . . . .
C3 C 0.0364(8) 0.6735(8) 1.1371(5) 0.066(3) Uani 1 1 d . . . . .
H3 H 0.016548 0.671710 1.199726 0.080 Uiso 1 1 calc R . . . .
C4 C -0.0484(9) 0.7222(8) 1.0599(6) 0.072(3) Uani 1 1 d . U . . .
H4 H -0.123397 0.755466 1.071356 0.086 Uiso 1 1 calc R . . . .
C5 C -0.0207(8) 0.7210(9) 0.9660(5) 0.073(3) Uani 1 1 d . . . . .
H5 H -0.076755 0.753403 0.913972 0.087 Uiso 1 1 calc R . . . .
C6 C 0.0894(6) 0.6719(6) 0.9504(4) 0.0364(17) Uani 1 1 d . . . . .
C7 C 0.1752(6) 0.6268(6) 1.0266(4) 0.0327(15) Uani 1 1 d . . . . .
H7 H 0.251127 0.595349 1.015217 0.039 Uiso 1 1 calc R . . . .
C8 C 0.2349(7) 0.6716(7) 0.8279(5) 0.046(2) Uani 1 1 d . . . . .
H8 H 0.314066 0.673487 0.872661 0.055 Uiso 1 1 calc R . . . .
C9 C 0.2175(6) 0.6715(7) 0.7284(5) 0.0406(18) Uani 1 1 d . . . . .
H9 H 0.281648 0.672320 0.691349 0.049 Uiso 1 1 calc R . . . .
C10 C 0.0253(6) 0.6690(6) 0.7687(4) 0.0317(15) Uani 1 1 d . . . . .
H10 H -0.063535 0.668713 0.764365 0.038 Uiso 1 1 calc R . . . .
C11 C 0.0205(6) 0.6709(6) 0.5903(4) 0.0294(15) Uani 1 1 d . . . . .
C12 C -0.1001(6) 0.6177(5) 0.5606(4) 0.0255(13) Uani 1 1 d . . . . .
H12 H -0.138717 0.578869 0.605656 0.031 Uiso 1 1 calc R . . . .
C13 C -0.1646(6) 0.6224(5) 0.4621(4) 0.0251(13) Uani 1 1 d . . . . .
C14 C -0.1049(7) 0.6779(6) 0.3947(4) 0.0397(17) Uani 1 1 d . . . . .
H14 H -0.147419 0.680243 0.328604 0.048 Uiso 1 1 calc R . . . .
C15 C 0.0183(7) 0.7300(8) 0.4264(5) 0.058(2) Uani 1 1 d . . . . .
H15 H 0.059409 0.765376 0.381006 0.069 Uiso 1 1 calc R . . . .
C16 C 0.0807(7) 0.7298(7) 0.5252(5) 0.049(2) Uani 1 1 d . . . . .
H16 H 0.161400 0.768362 0.547381 0.059 Uiso 1 1 calc R . . . .
C17 C -0.3007(6) 0.5739(5) 0.4318(4) 0.0208(12) Uani 1 1 d . . . . .
C18 C 0.3806(6) 0.2905(6) 1.2091(4) 0.0288(15) Uani 1 1 d . . . . .
C19 C 0.3528(6) 0.1861(6) 1.1356(4) 0.0289(14) Uani 1 1 d . . . . .
C20 C 0.2822(7) 0.0882(6) 1.1524(5) 0.0444(18) Uani 1 1 d . . . . .
H20 H 0.252679 0.085811 1.211323 0.053 Uiso 1 1 calc R . . . .
C21 C 0.2537(9) -0.0073(7) 1.0833(5) 0.058(2) Uani 1 1 d . . . . .
H21 H 0.207690 -0.074090 1.096584 0.070 Uiso 1 1 calc R . . . .
C22 C 0.2948(8) -0.0018(6) 0.9939(5) 0.052(2) Uani 1 1 d . . . . .
H22 H 0.275460 -0.064699 0.946398 0.063 Uiso 1 1 calc R . . . .
C23 C 0.3634(7) 0.0962(6) 0.9765(4) 0.0339(15) Uani 1 1 d . . . . .
C24 C 0.3955(6) 0.1903(6) 1.0459(4) 0.0329(15) Uani 1 1 d . . . . .
H24 H 0.444615 0.255456 1.033465 0.039 Uiso 1 1 calc R . . . .
C25 C 0.4715(9) 0.1994(7) 0.8538(5) 0.061(3) Uani 1 1 d . . . . .
H25 H 0.511711 0.263851 0.894455 0.073 Uiso 1 1 calc R . . . .
C26 C 0.4711(9) 0.1792(6) 0.7568(5) 0.056(2) Uani 1 1 d . . . . .
H26 H 0.510272 0.227345 0.717608 0.067 Uiso 1 1 calc R . . . .
C27 C 0.3607(7) 0.0323(6) 0.8026(4) 0.0360(16) Uani 1 1 d . . . . .
H27 H 0.311318 -0.037774 0.800900 0.043 Uiso 1 1 calc R . . . .
C28 C 0.3734(6) 0.0212(5) 0.6278(4) 0.0276(14) Uani 1 1 d . . . . .
C29 C 0.4095(6) -0.0910(5) 0.6118(4) 0.0264(14) Uani 1 1 d . . . . .
H29 H 0.451052 -0.132313 0.664965 0.032 Uiso 1 1 calc R . . . .
C30 C 0.3842(6) -0.1445(5) 0.5155(4) 0.0240(13) Uani 1 1 d . . . . .
C31 C 0.3202(6) -0.0817(6) 0.4376(4) 0.0317(15) Uani 1 1 d . . . . .
H31 H 0.301787 -0.116156 0.373242 0.038 Uiso 1 1 calc R . . . .
C32 C 0.2836(7) 0.0319(6) 0.4554(5) 0.0436(18) Uani 1 1 d . . . . .
H32 H 0.240752 0.073918 0.403083 0.052 Uiso 1 1 calc R . . . .
C33 C 0.3109(8) 0.0835(6) 0.5514(5) 0.0439(19) Uani 1 1 d . . . . .
H33 H 0.286752 0.160121 0.563550 0.053 Uiso 1 1 calc R . . . .
C34 C 0.4239(6) -0.2695(5) 0.5017(4) 0.0262(14) Uani 1 1 d . . . . .
O9 O 0.0828(10) -0.0768(7) 0.7747(7) 0.140(4) Uani 1 1 d . . . . .
O10 O 0.1187(8) 0.1074(7) 0.7599(6) 0.103(2) Uani 1 1 d . . . . .
O11 O -0.0748(8) 0.0390(10) 0.7427(6) 0.141(4) Uani 1 1 d . . . . .
N5 N 0.0416(9) 0.0199(10) 0.7573(6) 0.082(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.514(4) . ?
Eu1 O2 2.436(4) . ?
Eu1 O3 2.351(3) 2_567 ?
Eu1 O4 2.433(4) 1_656 ?
Eu1 O5 2.476(4) . ?
Eu1 O6 2.515(4) . ?
Eu1 O7 2.347(4) 2_657 ?
Eu1 O8 2.426(4) 1_566 ?
O1 C1 1.262(7) . ?
O2 C1 1.255(7) . ?
O3 C17 1.270(6) . ?
O4 C17 1.251(6) . ?
O5 C18 1.266(6) . ?
O6 C18 1.245(7) . ?
O7 C34 1.262(6) . ?
O8 C34 1.260(6) . ?
N1 C6 1.437(7) . ?
N1 C8 1.378(8) . ?
N1 C10 1.328(7) . ?
N2 C9 1.384(8) . ?
N2 C10 1.343(7) . ?
N2 C11 1.425(7) . ?
N3 C23 1.451(7) . ?
N3 C25 1.375(8) . ?
N3 C27 1.337(8) . ?
N4 C26 1.359(9) . ?
N4 C27 1.322(7) . ?
N4 C28 1.436(7) . ?
C1 C2 1.505(8) . ?
C2 C3 1.358(9) . ?
C2 C7 1.389(8) . ?
C3 C4 1.392(10) . ?
C4 C5 1.385(9) . ?
C5 C6 1.361(9) . ?
C6 C7 1.370(8) . ?
C8 C9 1.346(8) . ?
C11 C12 1.365(8) . ?
C11 C16 1.385(8) . ?
C12 C13 1.392(7) . ?
C13 C14 1.388(8) . ?
C13 C17 1.490(8) . ?
C14 C15 1.387(9) . ?
C15 C16 1.384(9) . ?
C18 C19 1.497(8) . ?
C19 C20 1.369(9) . ?
C19 C24 1.403(8) . ?
C20 C21 1.386(9) . ?
C21 C22 1.393(9) . ?
C22 C23 1.362(9) . ?
C23 C24 1.380(8) . ?
C25 C26 1.344(9) . ?
C28 C29 1.360(8) . ?
C28 C33 1.364(8) . ?
C29 C30 1.400(8) . ?
C30 C31 1.387(8) . ?
C30 C34 1.505(8) . ?
C31 C32 1.382(8) . ?
C32 C33 1.388(9) . ?
O9 N5 1.208(11) . ?
O10 N5 1.254(10) . ?
O11 N5 1.236(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O6 101.47(14) . . ?
O2 Eu1 O1 52.79(13) . . ?
O2 Eu1 O5 86.41(15) . . ?
O2 Eu1 O6 71.55(14) . . ?
O3 Eu1 O1 87.24(13) 2_567 . ?
O3 Eu1 O2 138.33(13) 2_567 . ?
O3 Eu1 O4 125.79(13) 2_567 1_656 ?
O3 Eu1 O5 92.00(14) 2_567 . ?
O3 Eu1 O6 136.20(15) 2_567 . ?
O3 Eu1 O8 79.09(13) 2_567 1_566 ?
O4 Eu1 O1 132.19(14) 1_656 . ?
O4 Eu1 O2 83.70(13) 1_656 . ?
O4 Eu1 O5 130.56(13) 1_656 . ?
O4 Eu1 O6 78.68(14) 1_656 . ?
O5 Eu1 O1 71.76(15) . . ?
O5 Eu1 O6 52.33(14) . . ?
O7 Eu1 O1 142.22(17) 2_657 . ?
O7 Eu1 O2 142.80(13) 2_657 . ?
O7 Eu1 O3 75.51(14) 2_657 2_567 ?
O7 Eu1 O4 83.99(16) 2_657 1_656 ?
O7 Eu1 O5 75.48(16) 2_657 . ?
O7 Eu1 O6 71.66(13) 2_657 . ?
O7 Eu1 O8 133.23(14) 2_657 1_566 ?
O8 Eu1 O1 73.34(15) 1_566 . ?
O8 Eu1 O2 78.39(13) 1_566 . ?
O8 Eu1 O4 79.94(14) 1_566 1_656 ?
O8 Eu1 O5 144.31(15) 1_566 . ?
O8 Eu1 O6 144.63(13) 1_566 . ?
C1 O1 Eu1 90.6(4) . . ?
C1 O2 Eu1 94.4(3) . . ?
Eu1 O3 Eu1 104.29(14) 2_567 1_454 ?
C17 O3 Eu1 168.3(4) . 2_567 ?
C17 O3 Eu1 87.1(3) . 1_454 ?
C17 O4 Eu1 101.2(3) . 1_454 ?
C18 O5 Eu1 93.3(4) . . ?
C18 O6 Eu1 92.0(3) . . ?
C34 O7 Eu1 142.3(4) . 2_657 ?
C34 O8 Eu1 130.8(4) . 1_544 ?
C8 N1 C6 126.2(5) . . ?
C10 N1 C6 125.0(5) . . ?
C10 N1 C8 108.7(5) . . ?
C9 N2 C11 126.9(5) . . ?
C10 N2 C9 108.7(5) . . ?
C10 N2 C11 124.4(5) . . ?
C25 N3 C23 127.5(6) . . ?
C27 N3 C23 124.2(6) . . ?
C27 N3 C25 108.0(5) . . ?
C26 N4 C28 126.3(5) . . ?
C27 N4 C26 109.5(5) . . ?
C27 N4 C28 124.2(6) . . ?
O1 C1 Eu1 62.9(3) . . ?
O1 C1 C2 119.8(6) . . ?
O2 C1 Eu1 59.3(3) . . ?
O2 C1 O1 122.0(5) . . ?
O2 C1 C2 118.2(5) . . ?
C2 C1 Eu1 174.9(4) . . ?
C3 C2 C1 120.3(5) . . ?
C3 C2 C7 120.1(6) . . ?
C7 C2 C1 119.6(5) . . ?
C2 C3 C4 120.0(6) . . ?
C5 C4 C3 119.8(7) . . ?
C6 C5 C4 119.3(6) . . ?
C5 C6 N1 118.6(5) . . ?
C5 C6 C7 121.3(6) . . ?
C7 C6 N1 120.1(5) . . ?
C6 C7 C2 119.5(6) . . ?
C9 C8 N1 107.9(6) . . ?
C8 C9 N2 106.5(5) . . ?
N1 C10 N2 108.2(5) . . ?
C12 C11 N2 119.5(5) . . ?
C12 C11 C16 121.8(6) . . ?
C16 C11 N2 118.6(6) . . ?
C11 C12 C13 119.2(5) . . ?
C12 C13 C17 119.2(5) . . ?
C14 C13 C12 120.0(6) . . ?
C14 C13 C17 120.7(5) . . ?
C15 C14 C13 119.6(6) . . ?
C16 C15 C14 120.5(6) . . ?
C15 C16 C11 118.7(7) . . ?
O3 C17 Eu1 67.4(3) . 1_454 ?
O3 C17 C13 118.0(5) . . ?
O4 C17 Eu1 54.2(3) . 1_454 ?
O4 C17 O3 121.5(5) . . ?
O4 C17 C13 120.4(5) . . ?
C13 C17 Eu1 174.5(4) . 1_454 ?
O5 C18 Eu1 60.3(3) . . ?
O5 C18 C19 118.4(6) . . ?
O6 C18 Eu1 62.1(3) . . ?
O6 C18 O5 122.4(6) . . ?
O6 C18 C19 119.2(5) . . ?
C19 C18 Eu1 178.4(4) . . ?
C20 C19 C18 121.3(5) . . ?
C20 C19 C24 119.1(6) . . ?
C24 C19 C18 119.5(6) . . ?
C19 C20 C21 121.4(6) . . ?
C20 C21 C22 119.1(7) . . ?
C23 C22 C21 119.5(6) . . ?
C22 C23 N3 120.8(6) . . ?
C22 C23 C24 121.8(6) . . ?
C24 C23 N3 117.4(6) . . ?
C23 C24 C19 119.0(6) . . ?
C26 C25 N3 107.4(7) . . ?
C25 C26 N4 107.0(6) . . ?
N4 C27 N3 108.1(6) . . ?
C29 C28 N4 119.3(5) . . ?
C29 C28 C33 121.2(5) . . ?
C33 C28 N4 119.5(5) . . ?
C28 C29 C30 120.3(5) . . ?
C29 C30 C34 118.4(5) . . ?
C31 C30 C29 118.7(5) . . ?
C31 C30 C34 122.9(5) . . ?
C32 C31 C30 120.1(6) . . ?
C31 C32 C33 120.0(6) . . ?
C28 C33 C32 119.6(6) . . ?
O7 C34 C30 115.0(5) . . ?
O8 C34 O7 126.2(5) . . ?
O8 C34 C30 118.7(5) . . ?
O9 N5 O10 119.9(10) . . ?
O9 N5 O11 122.8(11) . . ?
O11 N5 O10 117.1(11) . . ?

_platon_squeeze_details          TITL
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.500 19 2 ' '
2 0.500 0.500 1.000 67 15 ' '

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
