# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1mb
_database_code_depnum_ccdc_archive 'CCDC 1842108'
_audit_update_record             
;
2018-06-20 deposited with the CCDC.
2018-07-20 downloaded from the CCDC.
;
_audit_creation_date             2018-06-19
_audit_creation_method           
;
Olex2 1.2-alpha
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H38 Ru2'
_chemical_formula_sum            'C30 H38 Ru2'
_chemical_formula_weight         600.74
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.6703(3)
_cell_length_b                   11.0228(3)
_cell_length_c                   13.1457(4)
_cell_angle_alpha                90
_cell_angle_beta                 91.186(3)
_cell_angle_gamma                90
_cell_volume                     1256.08(7)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    5981
_cell_measurement_temperature    123.00(10)
_cell_measurement_theta_max      75.4250
_cell_measurement_theta_min      3.3590
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    9.828
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.41817
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear red'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.588
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             612
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_av_unetI/netI     0.0304
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            2565
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         76.528
_diffrn_reflns_theta_min         5.237
_diffrn_ambient_temperature      123.00(10)
_diffrn_detector_area_resol_mean 10.3546
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -66.00  -23.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064   57.0000  -30.0000 43

#__ type_ start__ end____ width___ exp.time_
  2 omega  -22.00   25.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064   57.0000  -30.0000 47

#__ type_ start__ end____ width___ exp.time_
  3 omega -109.00  -15.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064  -57.0000 -180.0000 94

#__ type_ start__ end____ width___ exp.time_
  4 omega    4.00   39.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       41.2064 -125.0000   90.0000 35

#__ type_ start__ end____ width___ exp.time_
  5 omega   82.00  145.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  178.0000   60.0000 63

#__ type_ start__ end____ width___ exp.time_
  6 omega   30.00  109.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -94.0000  150.0000 79

#__ type_ start__ end____ width___ exp.time_
  7 omega   45.00   76.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000   30.0000 31

#__ type_ start__ end____ width___ exp.time_
  8 omega   42.00   77.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000   60.0000 35

#__ type_ start__ end____ width___ exp.time_
  9 omega   39.00   71.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  178.0000   60.0000 32

#__ type_ start__ end____ width___ exp.time_
 10 omega   43.00   69.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  -60.0000 26

#__ type_ start__ end____ width___ exp.time_
 11 omega   40.00   66.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  150.0000 26

#__ type_ start__ end____ width___ exp.time_
 12 omega   45.00   77.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000  -30.0000 32

#__ type_ start__ end____ width___ exp.time_
 13 omega   32.00  103.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000 -103.0000 -108.0000 71

#__ type_ start__ end____ width___ exp.time_
 14 omega   85.00  155.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   45.0000  -60.0000 70

#__ type_ start__ end____ width___ exp.time_
 15 omega   43.00   76.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000    0.0000 33

#__ type_ start__ end____ width___ exp.time_
 16 omega   38.00   67.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -45.0000 -150.0000 29

#__ type_ start__ end____ width___ exp.time_
 17 omega -115.00  -12.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064  -57.0000   90.0000 103

#__ type_ start__ end____ width___ exp.time_
 18 omega  -98.00   -2.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064  125.0000  120.0000 96

#__ type_ start__ end____ width___ exp.time_
 19 omega -115.00  -12.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064  -57.0000    0.0000 103

#__ type_ start__ end____ width___ exp.time_
 20 omega -115.00  -12.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -41.2064  -57.0000  -90.0000 103

#__ type_ start__ end____ width___ exp.time_
 21 omega   82.00  158.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   30.0000   90.0000 76

#__ type_ start__ end____ width___ exp.time_
 22 omega   82.00  158.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000   30.0000 -120.0000 76

#__ type_ start__ end____ width___ exp.time_
 23 omega   35.00   54.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      113.0000  -30.0000  120.0000 19
;
_diffrn_measurement_device_type  'SuperNova, Single source at ofset, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.1115593000
_diffrn_orient_matrix_UB_12      -0.0725713000
_diffrn_orient_matrix_UB_13      -0.0664706000
_diffrn_orient_matrix_UB_21      -0.0245343000
_diffrn_orient_matrix_UB_22      -0.1127861000
_diffrn_orient_matrix_UB_23      0.0669260000
_diffrn_orient_matrix_UB_31      -0.1361513000
_diffrn_orient_matrix_UB_32      -0.0392110000
_diffrn_orient_matrix_UB_33      -0.0696265000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2470
_reflns_number_total             2565
_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
'CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49)'
_computing_data_collection       
'CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49)'
_computing_data_reduction        
'CrysAlisPro, Agilent Technologies, Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET) (compiled Dec 3 2012,18:21:49)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         2.219
_refine_diff_density_min         -1.552
_refine_diff_density_rms         0.198
_refine_ls_extinction_coef       0.00080(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     147
_refine_ls_number_reflns         2565
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0572
_refine_ls_R_factor_gt           0.0548
_refine_ls_restrained_S_all      1.085
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0431P)²+20.5405P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1448
_refine_ls_wR_factor_ref         0.1457
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.874(7)
 0.126(7)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3.a Me refined with riding coordinates:
 C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C9(H9A,H9B,H9C), C8(H8A,H8B,H8C), C10(H10A,
 H10B,H10C)
3.b Aromatic/amide H refined with riding coordinates:
 C14(H14), C11(H11), C13(H13), C12(H12)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.70683(6) 0.63116(4) 0.93107(4) 0.0156(2) Uani 1 1 d . . . . .
C6 C 0.7135(9) 0.9189(6) 0.9966(5) 0.0225(14) Uani 1 1 d . . . . .
H6A H 0.607717 0.938404 1.009378 0.034 Uiso 1 1 calc R . . . .
H6B H 0.760766 0.885786 1.057178 0.034 Uiso 1 1 calc R . . . .
H6C H 0.767429 0.991103 0.977247 0.034 Uiso 1 1 calc R . . . .
C2 C 0.8576(7) 0.7752(6) 0.8709(5) 0.0168(13) Uani 1 1 d . . . . .
C7 C 1.0206(8) 0.8089(7) 0.9004(6) 0.0267(16) Uani 1 1 d . . . . .
H7A H 1.019626 0.864378 0.956713 0.040 Uiso 1 1 calc R . . . .
H7B H 1.076694 0.737162 0.919723 0.040 Uiso 1 1 calc R . . . .
H7C H 1.069397 0.846692 0.843707 0.040 Uiso 1 1 calc R . . . .
C1 C 0.7206(8) 0.8273(6) 0.9122(5) 0.0164(13) Uani 1 1 d . . . . .
C15 C 0.5092(9) 0.4592(6) 0.9585(5) 0.0233(15) Uani 1 1 d . . . . .
C9 C 0.5506(10) 0.6325(7) 0.7019(7) 0.0308(17) Uani 1 1 d . . . . .
H9A H 0.616224 0.583382 0.660832 0.046 Uiso 1 1 calc R . . . .
H9B H 0.477924 0.581602 0.735771 0.046 Uiso 1 1 calc R . . . .
H9C H 0.496140 0.689724 0.659484 0.046 Uiso 1 1 calc R . . . .
C3 C 0.8130(8) 0.6943(6) 0.7900(5) 0.0174(13) Uani 1 1 d . . . . .
C5 C 0.5906(8) 0.7812(6) 0.8544(5) 0.0172(13) Uani 1 1 d . . . . .
C4 C 0.6470(8) 0.6995(6) 0.7798(5) 0.0202(14) Uani 1 1 d . . . . .
C14 C 0.6643(10) 0.4321(6) 0.9280(6) 0.0265(16) Uani 1 1 d . . . . .
H14 H 0.678955 0.394267 0.865720 0.032 Uiso 1 1 calc R . . . .
C8 C 0.9194(10) 0.6232(7) 0.7252(6) 0.0285(17) Uani 1 1 d . . . . .
H8A H 0.860276 0.576256 0.676889 0.043 Uiso 1 1 calc R . . . .
H8B H 0.985870 0.677723 0.689728 0.043 Uiso 1 1 calc R . . . .
H8C H 0.980659 0.569923 0.767367 0.043 Uiso 1 1 calc R . . . .
C11 C 0.6257(9) 0.5917(7) 1.0875(6) 0.0260(16) Uani 1 1 d . . . . .
H11 H 0.615973 0.659514 1.129020 0.031 Uiso 1 1 calc R . . . .
C13 C 0.7949(10) 0.4612(6) 0.9895(7) 0.0288(17) Uani 1 1 d . . . . .
H13 H 0.890661 0.427741 0.975734 0.035 Uiso 1 1 calc R . . . .
C10 C 0.4232(8) 0.8138(7) 0.8677(6) 0.0279(16) Uani 1 1 d . . . . .
H10A H 0.414425 0.870400 0.922778 0.042 Uiso 1 1 calc R . . . .
H10B H 0.383022 0.849849 0.806178 0.042 Uiso 1 1 calc R . . . .
H10C H 0.365533 0.741820 0.882641 0.042 Uiso 1 1 calc R . . . .
C12 C 0.7778(10) 0.5417(7) 1.0721(6) 0.0275(16) Uani 1 1 d . . . . .
H12 H 0.860848 0.561701 1.114777 0.033 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C2 2.214(6) . ?
Ru1 C1 2.180(6) . ?
Ru1 C15 2.586(7) . ?
Ru1 C15 2.592(7) 3_667 ?
Ru1 C3 2.200(6) . ?
Ru1 C5 2.174(6) . ?
Ru1 C4 2.179(7) . ?
Ru1 C14 2.225(7) . ?
Ru1 C11 2.230(7) . ?
Ru1 C13 2.158(7) . ?
Ru1 C12 2.177(7) . ?
C6 C1 1.502(9) . ?
C2 C7 1.504(10) . ?
C2 C1 1.436(9) . ?
C2 C3 1.434(10) . ?
C1 C5 1.439(10) . ?
C15 C15 1.426(14) 3_667 ?
C15 C14 1.442(11) . ?
C15 C11 1.422(11) 3_667 ?
C9 C4 1.502(10) . ?
C3 C4 1.444(10) . ?
C3 C8 1.491(10) . ?
C5 C4 1.425(10) . ?
C5 C10 1.509(9) . ?
C14 C13 1.414(12) . ?
C11 C12 1.448(11) . ?
C13 C12 1.412(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Ru1 C15 156.2(2) . 3_667 ?
C2 Ru1 C15 166.9(2) . . ?
C2 Ru1 C14 143.1(3) . . ?
C2 Ru1 C11 132.0(3) . . ?
C1 Ru1 C2 38.1(2) . . ?
C1 Ru1 C15 141.4(2) . . ?
C1 Ru1 C15 119.1(2) . 3_667 ?
C1 Ru1 C3 64.2(2) . . ?
C1 Ru1 C14 170.2(3) . . ?
C1 Ru1 C11 108.5(3) . . ?
C15 Ru1 C15 32.0(3) . 3_667 ?
C3 Ru1 C2 37.9(3) . . ?
C3 Ru1 C15 129.8(2) . . ?
C3 Ru1 C15 156.0(3) . 3_667 ?
C3 Ru1 C14 111.6(3) . . ?
C3 Ru1 C11 169.8(3) . . ?
C5 Ru1 C2 63.9(2) . . ?
C5 Ru1 C1 38.6(3) . . ?
C5 Ru1 C15 102.6(2) . 3_667 ?
C5 Ru1 C15 108.7(2) . . ?
C5 Ru1 C3 64.3(3) . . ?
C5 Ru1 C4 38.2(3) . . ?
C5 Ru1 C14 131.8(3) . . ?
C5 Ru1 C11 115.1(3) . . ?
C5 Ru1 C12 149.3(3) . . ?
C4 Ru1 C2 63.7(3) . . ?
C4 Ru1 C1 64.3(3) . . ?
C4 Ru1 C15 103.6(3) . . ?
C4 Ru1 C15 118.9(3) . 3_667 ?
C4 Ru1 C3 38.5(3) . . ?
C4 Ru1 C14 106.8(3) . . ?
C4 Ru1 C11 146.7(3) . . ?
C14 Ru1 C15 60.7(2) . 3_667 ?
C14 Ru1 C15 33.8(3) . . ?
C14 Ru1 C11 76.7(3) . . ?
C11 Ru1 C15 60.4(3) . . ?
C11 Ru1 C15 33.2(3) . 3_667 ?
C13 Ru1 C2 122.9(3) . . ?
C13 Ru1 C1 151.8(3) . . ?
C13 Ru1 C15 73.8(3) . 3_667 ?
C13 Ru1 C15 62.9(3) . . ?
C13 Ru1 C3 115.1(3) . . ?
C13 Ru1 C5 169.3(3) . . ?
C13 Ru1 C4 134.5(3) . . ?
C13 Ru1 C14 37.6(3) . . ?
C13 Ru1 C11 67.6(3) . . ?
C13 Ru1 C12 38.0(3) . . ?
C12 Ru1 C2 118.1(3) . . ?
C12 Ru1 C1 122.1(3) . . ?
C12 Ru1 C15 74.1(3) . . ?
C12 Ru1 C15 62.9(3) . 3_667 ?
C12 Ru1 C3 138.2(3) . . ?
C12 Ru1 C4 172.5(3) . . ?
C12 Ru1 C14 67.2(3) . . ?
C12 Ru1 C11 38.3(3) . . ?
C7 C2 Ru1 130.0(5) . . ?
C1 C2 Ru1 69.7(4) . . ?
C1 C2 C7 125.7(6) . . ?
C3 C2 Ru1 70.5(3) . . ?
C3 C2 C7 125.6(6) . . ?
C3 C2 C1 108.5(6) . . ?
C6 C1 Ru1 125.4(5) . . ?
C2 C1 Ru1 72.2(4) . . ?
C2 C1 C6 126.5(6) . . ?
C2 C1 C5 107.7(6) . . ?
C5 C1 Ru1 70.5(4) . . ?
C5 C1 C6 125.7(6) . . ?
Ru1 C15 Ru1 148.0(3) . 3_667 ?
C15 C15 Ru1 74.3(6) 3_667 . ?
C15 C15 Ru1 73.8(6) 3_667 3_667 ?
C15 C15 C14 117.6(9) 3_667 . ?
C14 C15 Ru1 139.9(5) . 3_667 ?
C14 C15 Ru1 59.2(4) . . ?
C11 C15 Ru1 59.3(4) 3_667 3_667 ?
C11 C15 Ru1 140.5(5) 3_667 . ?
C11 C15 C15 118.1(9) 3_667 3_667 ?
C11 C15 C14 124.3(7) 3_667 . ?
C2 C3 Ru1 71.6(3) . . ?
C2 C3 C4 107.3(6) . . ?
C2 C3 C8 126.1(7) . . ?
C4 C3 Ru1 70.0(4) . . ?
C4 C3 C8 126.5(7) . . ?
C8 C3 Ru1 126.1(5) . . ?
C1 C5 Ru1 70.9(4) . . ?
C1 C5 C10 126.8(6) . . ?
C4 C5 Ru1 71.1(4) . . ?
C4 C5 C1 108.1(6) . . ?
C4 C5 C10 125.1(6) . . ?
C10 C5 Ru1 124.4(5) . . ?
C9 C4 Ru1 124.8(5) . . ?
C3 C4 Ru1 71.5(4) . . ?
C3 C4 C9 125.7(7) . . ?
C5 C4 Ru1 70.7(4) . . ?
C5 C4 C9 125.8(7) . . ?
C5 C4 C3 108.5(6) . . ?
C15 C14 Ru1 86.9(4) . . ?
C13 C14 Ru1 68.6(4) . . ?
C13 C14 C15 122.3(7) . . ?
C15 C11 Ru1 87.5(5) 3_667 . ?
C15 C11 C12 122.3(7) 3_667 . ?
C12 C11 Ru1 68.9(4) . . ?
C14 C13 Ru1 73.8(4) . . ?
C12 C13 Ru1 71.7(4) . . ?
C12 C13 C14 119.1(7) . . ?
C11 C12 Ru1 72.8(4) . . ?
C13 C12 Ru1 70.3(4) . . ?
C13 C12 C11 117.2(7) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.874(7)
2 0.126(7)

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_[1]pf6
_database_code_depnum_ccdc_archive 'CCDC 1842109'
_audit_update_record             
;
2018-06-20 deposited with the CCDC.
2018-07-20 downloaded from the CCDC.
;
_audit_creation_date             2018-06-19
_audit_creation_method           
;
Olex2 1.2-alpha
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H39 Ru2, C4 H8 O, F6 P'
_chemical_formula_sum            'C34 H47 F6 O P Ru2'
_chemical_formula_weight         818.82
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.2572(3)
_cell_length_b                   12.5519(3)
_cell_length_c                   12.7014(4)
_cell_angle_alpha                115.951(3)
_cell_angle_beta                 100.575(3)
_cell_angle_gamma                98.837(2)
_cell_volume                     1665.66(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    15838
_cell_measurement_temperature    123.0(6)
_cell_measurement_theta_max      66.6310
_cell_measurement_theta_min      3.7910
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    8.316
_exptl_absorpt_correction_T_max  0.641
_exptl_absorpt_correction_T_min  0.359
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.633
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             832
_exptl_crystal_size_max          0.2198
_exptl_crystal_size_mid          0.1267
_exptl_crystal_size_min          0.0755
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0305
_diffrn_reflns_av_unetI/netI     0.0241
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            24105
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        66.805
_diffrn_reflns_theta_max         66.805
_diffrn_reflns_theta_min         3.804
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Xcalibur, AtlasS2, Gemini ultra'
_diffrn_measurement_method       ?
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5473
_reflns_number_total             5844
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.673
_refine_diff_density_min         -0.417
_refine_diff_density_rms         0.059
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     448
_refine_ls_number_reflns         5844
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.0220
_refine_ls_R_factor_gt           0.0200
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0191P)²+1.1589P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0466
_refine_ls_wR_factor_ref         0.0476
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
F2A \\sim F6 \\sim F6A \\sim F1 \\sim F1A \\sim F5 \\sim F5A \\sim F2: within
2A with sigma of 0.04 and sigma for terminal atoms of 0.02
3. Others
 Sof(F6A)=Sof(F1A)=Sof(F5A)=Sof(F2A)=1-FVAR(1)
 Sof(F1)=Sof(F6)=Sof(F2)=Sof(F5)=FVAR(1)
4.a Ternary CH refined with riding coordinates:
 C14(H14), C12(H12), C13(H13), C11(H11)
4.b Secondary CH2 refined with riding coordinates:
 C34(H34A,H34B), C33(H33A,H33B), C31(H31A,H31B), C32(H32A,H32B)
4.c Aromatic/amide H refined with riding coordinates:
 C15(H15), C17(H17), C16(H16), C18(H18)
4.d Idealised Me refined as rotating group:
 C27(H27A,H27B,H27C), C28(H28A,H28B,H28C), C10(H10A,H10B,H10C), C9(H9A,H9B,
 H9C), C8(H8A,H8B,H8C), C29(H29A,H29B,H29C), C26(H26A,H26B,H26C), C6(H6A,H6B,
 H6C), C7(H7A,H7B,H7C), C30(H30A,H30B,H30C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru2 Ru 0.30747(2) 0.43503(2) 0.73547(2) 0.01402(5) Uani 1 1 d . . . . .
Ru1 Ru 0.28213(2) 0.05295(2) 0.36349(2) 0.01562(5) Uani 1 1 d . . . . .
O1 O 0.11967(16) 0.98693(17) 0.71339(18) 0.0393(4) Uani 1 1 d . . . . .
C19 C 0.26550(18) 0.22616(17) 0.60980(19) 0.0172(4) Uani 1 1 d . . . . .
C20 C 0.37101(18) 0.28342(17) 0.60235(19) 0.0165(4) Uani 1 1 d . . . . .
C5 C 0.19569(19) -0.06751(18) 0.16330(18) 0.0196(4) Uani 1 1 d . . . . .
C22 C 0.21329(18) 0.51925(18) 0.64237(19) 0.0180(4) Uani 1 1 d . . . . .
C21 C 0.16122(19) 0.51580(19) 0.7334(2) 0.0200(4) Uani 1 1 d . . . . .
C14 C 0.37800(19) 0.25045(18) 0.47787(19) 0.0190(4) Uani 1 1 d . . . . .
H14 H 0.454342 0.277969 0.467338 0.023 Uiso 1 1 calc R . . . .
C15 C 0.46083(18) 0.36414(18) 0.70993(19) 0.0192(4) Uani 1 1 d . . . . .
H15 H 0.530671 0.404142 0.705139 0.023 Uiso 1 1 calc R . . . .
C23 C 0.32995(18) 0.59147(18) 0.7027(2) 0.0186(4) Uani 1 1 d . . . . .
C17 C 0.3415(2) 0.32963(19) 0.8329(2) 0.0232(5) Uani 1 1 d . . . . .
H17 H 0.332042 0.344189 0.910186 0.028 Uiso 1 1 calc R . . . .
C3 C 0.37494(19) -0.07075(18) 0.25754(19) 0.0211(4) Uani 1 1 d . . . . .
C24 C 0.34990(19) 0.63464(18) 0.8309(2) 0.0205(4) Uani 1 1 d . . . . .
C12 C 0.1719(2) 0.17264(19) 0.3958(2) 0.0247(5) Uani 1 1 d . . . . .
H12 H 0.096693 0.151787 0.335246 0.030 Uiso 1 1 calc R . . . .
C4 C 0.31707(19) -0.02679(18) 0.18327(18) 0.0193(4) Uani 1 1 d . . . . .
C16 C 0.4463(2) 0.38504(19) 0.8244(2) 0.0226(5) Uani 1 1 d . . . . .
H16 H 0.507701 0.436878 0.896476 0.027 Uiso 1 1 calc R . . . .
C25 C 0.2451(2) 0.58757(19) 0.8498(2) 0.0215(4) Uani 1 1 d . . . . .
C13 C 0.2770(2) 0.23178(18) 0.3891(2) 0.0243(5) Uani 1 1 d . . . . .
H13 H 0.280153 0.254969 0.323527 0.029 Uiso 1 1 calc R . . . .
C1 C 0.1782(2) -0.13646(18) 0.22616(19) 0.0221(5) Uani 1 1 d . . . . .
C18 C 0.2501(2) 0.25195(18) 0.7250(2) 0.0218(5) Uani 1 1 d . . . . .
H18 H 0.178193 0.217179 0.730472 0.026 Uiso 1 1 calc R . . . .
C2 C 0.2885(2) -0.13979(18) 0.2837(2) 0.0235(5) Uani 1 1 d . . . . .
C11 C 0.18069(18) 0.14033(19) 0.4912(2) 0.0215(4) Uani 1 1 d . . . . .
H11 H 0.110999 0.086399 0.490301 0.026 Uiso 1 1 calc R . . . .
C27 C 0.1527(2) 0.4643(2) 0.5098(2) 0.0250(5) Uani 1 1 d . . . . .
H27A H 0.209055 0.449583 0.462819 0.038 Uiso 1 1 calc GR . . . .
H27B H 0.112521 0.520954 0.496409 0.038 Uiso 1 1 calc GR . . . .
H27C H 0.096917 0.386306 0.483146 0.038 Uiso 1 1 calc GR . . . .
C28 C 0.4146(2) 0.6212(2) 0.6413(2) 0.0278(5) Uani 1 1 d . . . . .
H28A H 0.492819 0.633477 0.688037 0.042 Uiso 1 1 calc GR . . . .
H28B H 0.408231 0.696397 0.637531 0.042 Uiso 1 1 calc GR . . . .
H28C H 0.398037 0.553168 0.558452 0.042 Uiso 1 1 calc GR . . . .
C10 C 0.1025(2) -0.0454(2) 0.0869(2) 0.0278(5) Uani 1 1 d . . . . .
H10A H 0.034940 -0.045032 0.117900 0.042 Uiso 1 1 calc GR . . . .
H10B H 0.081405 -0.110897 0.002035 0.042 Uiso 1 1 calc GR . . . .
H10C H 0.130236 0.034042 0.090693 0.042 Uiso 1 1 calc GR . . . .
C9 C 0.3733(2) 0.0432(2) 0.1286(2) 0.0264(5) Uani 1 1 d . . . . .
H9A H 0.327618 0.098028 0.120027 0.040 Uiso 1 1 calc GR . . . .
H9B H 0.378164 -0.014553 0.048209 0.040 Uiso 1 1 calc GR . . . .
H9C H 0.450934 0.092002 0.182040 0.040 Uiso 1 1 calc GR . . . .
C8 C 0.5023(2) -0.0578(2) 0.2919(2) 0.0300(5) Uani 1 1 d . . . . .
H8A H 0.544157 0.022039 0.304973 0.045 Uiso 1 1 calc GR . . . .
H8B H 0.521116 -0.123635 0.226098 0.045 Uiso 1 1 calc GR . . . .
H8C H 0.524539 -0.063312 0.367174 0.045 Uiso 1 1 calc GR . . . .
C29 C 0.4584(2) 0.7193(2) 0.9284(2) 0.0309(5) Uani 1 1 d . . . . .
H29A H 0.463713 0.706419 0.999738 0.046 Uiso 1 1 calc GR . . . .
H29B H 0.457710 0.804661 0.951947 0.046 Uiso 1 1 calc GR . . . .
H29C H 0.524830 0.702330 0.897489 0.046 Uiso 1 1 calc GR . . . .
C26 C 0.0380(2) 0.4555(2) 0.7112(2) 0.0302(5) Uani 1 1 d . . . . .
H26A H 0.011171 0.380895 0.631646 0.045 Uiso 1 1 calc GR . . . .
H26B H -0.008907 0.512188 0.711802 0.045 Uiso 1 1 calc GR . . . .
H26C H 0.031118 0.433794 0.775437 0.045 Uiso 1 1 calc GR . . . .
C6 C 0.0639(2) -0.1993(2) 0.2256(2) 0.0331(6) Uani 1 1 d . . . . .
H6A H 0.072726 -0.210464 0.298041 0.050 Uiso 1 1 calc GR . . . .
H6B H 0.033892 -0.279586 0.151986 0.050 Uiso 1 1 calc GR . . . .
H6C H 0.010056 -0.148872 0.226266 0.050 Uiso 1 1 calc GR . . . .
C7 C 0.3094(2) -0.2136(2) 0.3478(2) 0.0336(6) Uani 1 1 d . . . . .
H7A H 0.386370 -0.176858 0.405877 0.050 Uiso 1 1 calc GR . . . .
H7B H 0.303800 -0.298028 0.287754 0.050 Uiso 1 1 calc GR . . . .
H7C H 0.251591 -0.214285 0.391756 0.050 Uiso 1 1 calc GR . . . .
C34 C 0.1507(2) 0.9076(3) 0.6103(3) 0.0401(6) Uani 1 1 d . . . . .
H34A H 0.215546 0.953309 0.597221 0.048 Uiso 1 1 calc R . . . .
H34B H 0.084687 0.869498 0.535933 0.048 Uiso 1 1 calc R . . . .
C30 C 0.2242(2) 0.6156(2) 0.9705(2) 0.0339(6) Uani 1 1 d . . . . .
H30A H 0.168645 0.545050 0.961606 0.051 Uiso 1 1 calc GR . . . .
H30B H 0.193613 0.687809 0.999258 0.051 Uiso 1 1 calc GR . . . .
H30C H 0.296832 0.632399 1.029785 0.051 Uiso 1 1 calc GR . . . .
C33 C 0.1855(3) 0.8111(3) 0.6395(3) 0.0488(7) Uani 1 1 d . . . . .
H33A H 0.246827 0.782629 0.602362 0.059 Uiso 1 1 calc R . . . .
H33B H 0.118856 0.739529 0.609610 0.059 Uiso 1 1 calc R . . . .
C31 C 0.2025(3) 0.9993(3) 0.8154(3) 0.0474(7) Uani 1 1 d . . . . .
H31A H 0.171274 1.021901 0.886527 0.057 Uiso 1 1 calc R . . . .
H31B H 0.273184 1.064008 0.837952 0.057 Uiso 1 1 calc R . . . .
C32 C 0.2290(3) 0.8763(3) 0.7772(3) 0.0547(8) Uani 1 1 d . . . . .
H32A H 0.188447 0.830172 0.811374 0.066 Uiso 1 1 calc R . . . .
H32B H 0.312691 0.886577 0.804655 0.066 Uiso 1 1 calc R . . . .
P1 P 0.20836(5) 0.37286(5) 0.14131(5) 0.02279(12) Uani 1 1 d . . . . .
F3 F 0.30353(14) 0.44677(14) 0.10899(13) 0.0413(4) Uani 1 1 d . . . . .
F4 F 0.11596(15) 0.29973(16) 0.17541(17) 0.0550(5) Uani 1 1 d . . . . .
F1 F 0.2306(6) 0.4820(5) 0.2726(6) 0.0525(15) Uani 0.619(15) 1 d . U P A 1
F6 F 0.3084(6) 0.3258(9) 0.1893(9) 0.0640(19) Uani 0.619(15) 1 d . U P A 1
F2 F 0.1796(9) 0.2606(8) 0.0090(8) 0.071(3) Uani 0.619(15) 1 d . U P A 1
F5 F 0.1045(5) 0.4148(9) 0.0895(6) 0.0584(16) Uani 0.619(15) 1 d . U P A 1
F6A F 0.2791(12) 0.4644(12) 0.2833(8) 0.065(3) Uani 0.381(15) 1 d . U P A 2
F1A F 0.1460(10) 0.4717(10) 0.1390(13) 0.057(3) Uani 0.381(15) 1 d . U P A 2
F5A F 0.1565(13) 0.2865(13) 0.0013(12) 0.067(4) Uani 0.381(15) 1 d . U P A 2
F2A F 0.2771(12) 0.2770(10) 0.1444(12) 0.057(2) Uani 0.381(15) 1 d . U P A 2
H H 0.352(2) 0.054(2) 0.476(2) 0.030(7) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru2 C19 2.3038(19) . ?
Ru2 C20 2.2824(19) . ?
Ru2 C22 2.195(2) . ?
Ru2 C21 2.192(2) . ?
Ru2 C15 2.217(2) . ?
Ru2 C23 2.167(2) . ?
Ru2 C17 2.206(2) . ?
Ru2 C24 2.174(2) . ?
Ru2 C16 2.193(2) . ?
Ru2 C25 2.187(2) . ?
Ru2 C18 2.235(2) . ?
Ru1 C5 2.242(2) . ?
Ru1 C14 2.228(2) . ?
Ru1 C3 2.189(2) . ?
Ru1 C12 2.130(2) . ?
Ru1 C4 2.216(2) . ?
Ru1 C13 2.136(2) . ?
Ru1 C1 2.223(2) . ?
Ru1 C2 2.197(2) . ?
Ru1 C11 2.232(2) . ?
Ru1 H 1.52(3) . ?
O1 C34 1.417(3) . ?
O1 C31 1.423(4) . ?
C19 C20 1.420(3) . ?
C19 C18 1.410(3) . ?
C19 C11 1.473(3) . ?
C20 C14 1.472(3) . ?
C20 C15 1.414(3) . ?
C5 C4 1.433(3) . ?
C5 C1 1.429(3) . ?
C5 C10 1.500(3) . ?
C22 C21 1.433(3) . ?
C22 C23 1.430(3) . ?
C22 C27 1.493(3) . ?
C21 C25 1.430(3) . ?
C21 C26 1.496(3) . ?
C14 H14 1.0000 . ?
C14 C13 1.424(3) . ?
C15 H15 0.9500 . ?
C15 C16 1.411(3) . ?
C23 C24 1.431(3) . ?
C23 C28 1.502(3) . ?
C17 H17 0.9500 . ?
C17 C16 1.410(3) . ?
C17 C18 1.419(3) . ?
C3 C4 1.424(3) . ?
C3 C2 1.443(3) . ?
C3 C8 1.504(3) . ?
C24 C25 1.435(3) . ?
C24 C29 1.497(3) . ?
C12 H12 1.0000 . ?
C12 C13 1.420(3) . ?
C12 C11 1.428(3) . ?
C4 C9 1.501(3) . ?
C16 H16 0.9500 . ?
C25 C30 1.497(3) . ?
C13 H13 1.0000 . ?
C1 C2 1.430(3) . ?
C1 C6 1.496(3) . ?
C18 H18 0.9500 . ?
C2 C7 1.498(3) . ?
C11 H11 1.0000 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C34 C33 1.511(4) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C33 C32 1.512(5) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.511(4) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
P1 F3 1.6020(14) . ?
P1 F4 1.5879(16) . ?
P1 F1 1.565(5) . ?
P1 F6 1.578(7) . ?
P1 F2 1.578(7) . ?
P1 F5 1.591(4) . ?
P1 F6A 1.622(10) . ?
P1 F1A 1.562(7) . ?
P1 F5A 1.558(12) . ?
P1 F2A 1.580(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C20 Ru2 C19 36.07(7) . . ?
C22 Ru2 C19 110.12(8) . . ?
C22 Ru2 C20 110.66(7) . . ?
C22 Ru2 C15 130.52(8) . . ?
C22 Ru2 C17 159.98(8) . . ?
C22 Ru2 C18 128.63(8) . . ?
C21 Ru2 C19 115.64(8) . . ?
C21 Ru2 C20 138.56(8) . . ?
C21 Ru2 C22 38.13(8) . . ?
C21 Ru2 C15 168.63(8) . . ?
C21 Ru2 C17 124.00(8) . . ?
C21 Ru2 C16 152.96(8) . . ?
C21 Ru2 C18 109.09(8) . . ?
C15 Ru2 C19 65.76(7) . . ?
C15 Ru2 C20 36.59(8) . . ?
C15 Ru2 C18 78.84(8) . . ?
C23 Ru2 C19 133.29(8) . . ?
C23 Ru2 C20 110.36(7) . . ?
C23 Ru2 C22 38.27(8) . . ?
C23 Ru2 C21 64.09(8) . . ?
C23 Ru2 C15 106.28(8) . . ?
C23 Ru2 C17 157.06(9) . . ?
C23 Ru2 C24 38.49(8) . . ?
C23 Ru2 C16 125.10(8) . . ?
C23 Ru2 C25 64.20(8) . . ?
C23 Ru2 C18 165.67(9) . . ?
C17 Ru2 C19 65.88(8) . . ?
C17 Ru2 C20 78.14(7) . . ?
C17 Ru2 C15 67.27(8) . . ?
C17 Ru2 C18 37.27(9) . . ?
C24 Ru2 C19 171.66(8) . . ?
C24 Ru2 C20 138.37(8) . . ?
C24 Ru2 C22 64.16(8) . . ?
C24 Ru2 C21 64.17(8) . . ?
C24 Ru2 C15 112.66(8) . . ?
C24 Ru2 C17 121.67(8) . . ?
C24 Ru2 C16 106.00(8) . . ?
C24 Ru2 C25 38.43(8) . . ?
C24 Ru2 C18 152.13(8) . . ?
C16 Ru2 C19 77.83(8) . . ?
C16 Ru2 C20 66.14(7) . . ?
C16 Ru2 C22 162.51(8) . . ?
C16 Ru2 C15 37.32(8) . . ?
C16 Ru2 C17 37.38(9) . . ?
C16 Ru2 C18 67.00(8) . . ?
C25 Ru2 C19 146.15(8) . . ?
C25 Ru2 C20 174.15(7) . . ?
C25 Ru2 C22 63.86(8) . . ?
C25 Ru2 C21 38.11(8) . . ?
C25 Ru2 C15 145.14(8) . . ?
C25 Ru2 C17 107.70(8) . . ?
C25 Ru2 C16 118.37(8) . . ?
C25 Ru2 C18 119.11(8) . . ?
C18 Ru2 C19 36.15(8) . . ?
C18 Ru2 C20 65.58(7) . . ?
C5 Ru1 H 143.1(10) . . ?
C14 Ru1 C5 133.84(8) . . ?
C14 Ru1 C11 73.47(7) . . ?
C14 Ru1 H 78.0(10) . . ?
C3 Ru1 C5 63.02(8) . . ?
C3 Ru1 C14 116.64(8) . . ?
C3 Ru1 C4 37.71(8) . . ?
C3 Ru1 C1 63.58(8) . . ?
C3 Ru1 C2 38.43(8) . . ?
C3 Ru1 C11 163.56(8) . . ?
C3 Ru1 H 87.7(10) . . ?
C12 Ru1 C5 96.74(8) . . ?
C12 Ru1 C14 67.08(8) . . ?
C12 Ru1 C3 156.07(9) . . ?
C12 Ru1 C4 118.37(8) . . ?
C12 Ru1 C13 38.90(9) . . ?
C12 Ru1 C1 108.84(8) . . ?
C12 Ru1 C2 144.98(9) . . ?
C12 Ru1 C11 38.13(9) . . ?
C12 Ru1 H 115.7(10) . . ?
C4 Ru1 C5 37.49(8) . . ?
C4 Ru1 C14 111.22(7) . . ?
C4 Ru1 C1 62.91(8) . . ?
C4 Ru1 C11 154.04(8) . . ?
C4 Ru1 H 124.2(10) . . ?
C13 Ru1 C5 102.74(8) . . ?
C13 Ru1 C14 38.02(9) . . ?
C13 Ru1 C3 129.01(8) . . ?
C13 Ru1 C4 100.18(8) . . ?
C13 Ru1 C1 134.02(9) . . ?
C13 Ru1 C2 163.21(8) . . ?
C13 Ru1 C11 67.15(8) . . ?
C13 Ru1 H 113.4(10) . . ?
C1 Ru1 C5 37.33(8) . . ?
C1 Ru1 C14 170.94(8) . . ?
C1 Ru1 C11 108.65(8) . . ?
C1 Ru1 H 110.9(10) . . ?
C2 Ru1 C5 62.79(8) . . ?
C2 Ru1 C14 147.66(8) . . ?
C2 Ru1 C4 63.26(8) . . ?
C2 Ru1 C1 37.75(9) . . ?
C2 Ru1 C11 126.55(8) . . ?
C2 Ru1 H 80.3(10) . . ?
C11 Ru1 C5 120.59(8) . . ?
C11 Ru1 H 81.7(10) . . ?
C34 O1 C31 104.7(2) . . ?
C20 C19 Ru2 71.14(11) . . ?
C20 C19 C11 114.83(18) . . ?
C18 C19 Ru2 69.26(11) . . ?
C18 C19 C20 119.67(19) . . ?
C18 C19 C11 125.49(19) . . ?
C11 C19 Ru2 133.40(14) . . ?
C19 C20 Ru2 72.78(11) . . ?
C19 C20 C14 115.28(18) . . ?
C14 C20 Ru2 131.63(14) . . ?
C15 C20 Ru2 69.19(11) . . ?
C15 C20 C19 120.09(19) . . ?
C15 C20 C14 124.62(19) . . ?
C4 C5 Ru1 70.26(11) . . ?
C4 C5 C10 126.3(2) . . ?
C1 C5 Ru1 70.60(12) . . ?
C1 C5 C4 108.06(19) . . ?
C1 C5 C10 125.6(2) . . ?
C10 C5 Ru1 126.14(14) . . ?
C21 C22 Ru2 70.85(12) . . ?
C21 C22 C27 125.4(2) . . ?
C23 C22 Ru2 69.83(11) . . ?
C23 C22 C21 107.78(19) . . ?
C23 C22 C27 126.69(19) . . ?
C27 C22 Ru2 128.09(14) . . ?
C22 C21 Ru2 71.02(11) . . ?
C22 C21 C26 125.7(2) . . ?
C25 C21 Ru2 70.74(12) . . ?
C25 C21 C22 108.09(19) . . ?
C25 C21 C26 126.1(2) . . ?
C26 C21 Ru2 127.35(15) . . ?
Ru1 C14 H14 118.0 . . ?
C20 C14 Ru1 105.63(13) . . ?
C20 C14 H14 118.0 . . ?
C13 C14 Ru1 67.48(11) . . ?
C13 C14 C20 118.20(19) . . ?
C13 C14 H14 118.0 . . ?
Ru2 C15 H15 127.2 . . ?
C20 C15 Ru2 74.22(11) . . ?
C20 C15 H15 120.1 . . ?
C16 C15 Ru2 70.42(12) . . ?
C16 C15 C20 119.7(2) . . ?
C16 C15 H15 120.1 . . ?
C22 C23 Ru2 71.89(11) . . ?
C22 C23 C24 108.39(18) . . ?
C22 C23 C28 125.3(2) . . ?
C24 C23 Ru2 71.02(11) . . ?
C24 C23 C28 126.2(2) . . ?
C28 C23 Ru2 125.09(14) . . ?
Ru2 C17 H17 128.7 . . ?
C16 C17 Ru2 70.82(12) . . ?
C16 C17 H17 120.2 . . ?
C16 C17 C18 119.55(19) . . ?
C18 C17 Ru2 72.48(12) . . ?
C18 C17 H17 120.2 . . ?
C4 C3 Ru1 72.18(11) . . ?
C4 C3 C2 107.65(19) . . ?
C4 C3 C8 125.9(2) . . ?
C2 C3 Ru1 71.09(11) . . ?
C2 C3 C8 126.2(2) . . ?
C8 C3 Ru1 126.65(15) . . ?
C23 C24 Ru2 70.49(11) . . ?
C23 C24 C25 107.64(19) . . ?
C23 C24 C29 126.1(2) . . ?
C25 C24 Ru2 71.26(11) . . ?
C25 C24 C29 126.1(2) . . ?
C29 C24 Ru2 126.22(15) . . ?
Ru1 C12 H12 121.9 . . ?
C13 C12 Ru1 70.76(12) . . ?
C13 C12 H12 121.9 . . ?
C13 C12 C11 116.1(2) . . ?
C11 C12 Ru1 74.81(12) . . ?
C11 C12 H12 121.9 . . ?
C5 C4 Ru1 72.25(11) . . ?
C5 C4 C9 125.8(2) . . ?
C3 C4 Ru1 70.11(11) . . ?
C3 C4 C5 108.35(18) . . ?
C3 C4 C9 125.7(2) . . ?
C9 C4 Ru1 126.37(14) . . ?
Ru2 C16 H16 128.5 . . ?
C15 C16 Ru2 72.26(12) . . ?
C15 C16 H16 119.7 . . ?
C17 C16 Ru2 71.80(12) . . ?
C17 C16 C15 120.6(2) . . ?
C17 C16 H16 119.7 . . ?
C21 C25 Ru2 71.14(11) . . ?
C21 C25 C24 108.09(18) . . ?
C21 C25 C30 125.7(2) . . ?
C24 C25 Ru2 70.31(11) . . ?
C24 C25 C30 126.1(2) . . ?
C30 C25 Ru2 127.38(15) . . ?
Ru1 C13 H13 122.1 . . ?
C14 C13 Ru1 74.50(12) . . ?
C14 C13 H13 122.1 . . ?
C12 C13 Ru1 70.34(12) . . ?
C12 C13 C14 115.78(19) . . ?
C12 C13 H13 122.1 . . ?
C5 C1 Ru1 72.07(11) . . ?
C5 C1 C2 107.96(19) . . ?
C5 C1 C6 125.5(2) . . ?
C2 C1 Ru1 70.13(12) . . ?
C2 C1 C6 126.4(2) . . ?
C6 C1 Ru1 125.83(15) . . ?
Ru2 C18 H18 127.3 . . ?
C19 C18 Ru2 74.59(11) . . ?
C19 C18 C17 120.3(2) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 Ru2 70.26(12) . . ?
C17 C18 H18 119.9 . . ?
C3 C2 Ru1 70.48(11) . . ?
C3 C2 C7 126.1(2) . . ?
C1 C2 Ru1 72.11(11) . . ?
C1 C2 C3 107.97(19) . . ?
C1 C2 C7 125.7(2) . . ?
C7 C2 Ru1 128.09(15) . . ?
Ru1 C11 H11 118.2 . . ?
C19 C11 Ru1 106.06(13) . . ?
C19 C11 H11 118.2 . . ?
C12 C11 Ru1 67.06(12) . . ?
C12 C11 C19 117.82(19) . . ?
C12 C11 H11 118.2 . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C21 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
C21 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
O1 C34 H34A 110.7 . . ?
O1 C34 H34B 110.7 . . ?
O1 C34 C33 105.2(2) . . ?
H34A C34 H34B 108.8 . . ?
C33 C34 H34A 110.7 . . ?
C33 C34 H34B 110.7 . . ?
C25 C30 H30A 109.5 . . ?
C25 C30 H30B 109.5 . . ?
C25 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C34 C33 H33A 111.0 . . ?
C34 C33 H33B 111.0 . . ?
C34 C33 C32 104.0(2) . . ?
H33A C33 H33B 109.0 . . ?
C32 C33 H33A 111.0 . . ?
C32 C33 H33B 111.0 . . ?
O1 C31 H31A 110.4 . . ?
O1 C31 H31B 110.4 . . ?
O1 C31 C32 106.6(2) . . ?
H31A C31 H31B 108.6 . . ?
C32 C31 H31A 110.4 . . ?
C32 C31 H31B 110.4 . . ?
C33 C32 H32A 110.9 . . ?
C33 C32 H32B 110.9 . . ?
C31 C32 C33 104.1(2) . . ?
C31 C32 H32A 110.9 . . ?
C31 C32 H32B 110.9 . . ?
H32A C32 H32B 109.0 . . ?
F3 P1 F6A 86.5(4) . . ?
F4 P1 F3 178.87(10) . . ?
F4 P1 F5 85.8(3) . . ?
F4 P1 F6A 92.7(4) . . ?
F1 P1 F3 93.3(2) . . ?
F1 P1 F4 86.1(2) . . ?
F1 P1 F6 90.7(3) . . ?
F1 P1 F2 177.2(4) . . ?
F1 P1 F5 91.0(3) . . ?
F6 P1 F3 86.1(3) . . ?
F6 P1 F4 92.9(3) . . ?
F6 P1 F5 177.7(3) . . ?
F2 P1 F3 89.2(4) . . ?
F2 P1 F4 91.4(4) . . ?
F2 P1 F6 90.7(4) . . ?
F2 P1 F5 87.4(4) . . ?
F5 P1 F3 95.2(3) . . ?
F1A P1 F3 82.2(3) . . ?
F1A P1 F4 98.6(3) . . ?
F1A P1 F6A 90.6(5) . . ?
F1A P1 F2A 177.2(5) . . ?
F5A P1 F3 87.1(6) . . ?
F5A P1 F4 93.7(6) . . ?
F5A P1 F6A 172.3(7) . . ?
F5A P1 F1A 92.7(6) . . ?
F5A P1 F2A 88.1(6) . . ?
F2A P1 F3 95.2(5) . . ?
F2A P1 F4 84.0(5) . . ?
F2A P1 F6A 88.3(5) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_[3]barf
_database_code_depnum_ccdc_archive 'CCDC 1842110'
_audit_update_record             
;
2018-05-08 deposited with the CCDC.
2018-07-20 downloaded from the CCDC.
;
_audit_creation_date             2018-05-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.04.26 svn.r3504 for OlexSys, GUI svn.r5492)
;
_shelxl_version_number           2014/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '4(C15 H19 Ru), 2(C32 H12 B F24)'
_chemical_formula_sum            'C124 H100 B2 F48 Ru4'
_chemical_formula_weight         2927.93
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.52733(11)
_cell_length_b                   23.1371(2)
_cell_length_c                   24.6760(3)
_cell_angle_alpha                87.0962(9)
_cell_angle_beta                 89.0569(9)
_cell_angle_gamma                87.5307(9)
_cell_volume                     5996.46(12)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    33142
_cell_measurement_temperature    123.1(2)
_cell_measurement_theta_max      66.5120
_cell_measurement_theta_min      3.8130
_shelx_estimated_absorpt_T_max   0.656
_shelx_estimated_absorpt_T_min   0.458
_exptl_absorpt_coefficient_mu    5.110
_exptl_absorpt_correction_T_max  0.909
_exptl_absorpt_correction_T_min  0.853
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.37b (Rigaku Oxford Diffraction, 2017)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'dark green'
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.622
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2924
_exptl_crystal_size_max          0.181
_exptl_crystal_size_mid          0.128
_exptl_crystal_size_min          0.09
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0348
_diffrn_reflns_av_unetI/netI     0.0347
_diffrn_reflns_Laue_measured_fraction_full 0.970
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            67882
_diffrn_reflns_point_group_measured_fraction_full 0.970
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         66.754
_diffrn_reflns_theta_min         3.829
_diffrn_ambient_temperature      123.1(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Xcalibur, AtlasS2, Gemini ultra'
_diffrn_measurement_method       ?
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                18178
_reflns_number_total             21058
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.735
_refine_diff_density_min         -0.851
_refine_diff_density_rms         0.076
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1623
_refine_ls_number_reflns         21058
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0439
_refine_ls_R_factor_gt           0.0358
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0411P)²+6.6568P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0846
_refine_ls_wR_factor_ref         0.0892
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C41(H41), C26(H26), C28(H28), C29(H29), C27(H27), C44(H44), C56(H56),
 C42(H42), C59(H59), C11(H11), C13(H13), C43(H43), C57(H57), C12(H12), C14(H14),
  C58(H58)
2.b Aromatic/amide H refined with riding coordinates:
 C68(H68), C112(H112), C116(H116), C94(H94), C78(H78), C98(H98), C72(H72),
 C110(H110), C104(H104), C70(H70), C114(H114), C66(H66), C62(H62), C74(H74),
 C80(H80), C64(H64), C108(H108), C106(H106), C84(H84), C100(H100), C102(H102),
 C82(H82), C76(H76), C96(H96)
2.c Idealised Me refined as rotating group:
 C39(H39A,H39B,H39C), C24(H24A,H24B,H24C), C21(H21A,H21B,H21C), C37(H37A,H37B,
 H37C), C52(H52A,H52B,H52C), C51(H51A,H51B,H51C), C36(H36A,H36B,H36C), C55(H55A,
 H55B,H55C), C23(H23A,H23B,H23C), C54(H54A,H54B,H54C), C40(H40A,H40B,H40C),
 C38(H38A,H38B,H38C), C25(H25A,H25B,H25C), C22(H22A,H22B,H22C), C53(H53A,H53B,
 H53C), C6(H6A,H6B,H6C), C10(H10A,H10B,H10C), C9(H9A,H9B,H9C), C7(H7A,H7B,H7C),
 C8(H8A,H8B,H8C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru2 Ru 0.17049(2) 0.44529(2) 0.03514(2) 0.01911(6) Uani 1 1 d . . . . .
Ru3 Ru 0.12195(2) 0.42767(2) 0.54477(2) 0.01992(6) Uani 1 1 d . . . . .
Ru4 Ru 0.10840(2) -0.04737(2) 0.43184(2) 0.02319(6) Uani 1 1 d . . . . .
Ru1 Ru 0.88988(2) 0.05046(2) 0.06533(2) 0.02390(6) Uani 1 1 d . . . . .
F40 F 0.78171(18) 0.92532(8) 0.31326(8) 0.0358(4) Uani 1 1 d . . . . .
F15 F -0.08120(16) 0.43304(8) 0.28553(9) 0.0356(4) Uani 1 1 d . . . . .
F11 F 0.6714(2) 0.45090(8) 0.35611(8) 0.0385(5) Uani 1 1 d . . . . .
F20 F 0.20712(17) 0.20360(9) 0.49933(8) 0.0390(5) Uani 1 1 d . . . . .
F5 F 0.21877(19) 0.08038(8) 0.18659(8) 0.0396(5) Uani 1 1 d . . . . .
F47 F 0.51323(18) 0.51270(7) 0.18897(8) 0.0350(4) Uani 1 1 d . . . . .
F48 F 0.3432(2) 0.54923(8) 0.15342(8) 0.0400(5) Uani 1 1 d . . . . .
F12 F 0.50006(18) 0.49077(8) 0.32341(9) 0.0373(5) Uani 1 1 d . . . . .
F46 F 0.3335(2) 0.50162(8) 0.23008(8) 0.0398(5) Uani 1 1 d . . . . .
F6 F 0.2300(2) 0.16552(8) 0.14898(8) 0.0378(5) Uani 1 1 d . . . . .
F35 F 0.79732(18) 0.78071(9) -0.00598(8) 0.0393(5) Uani 1 1 d . . . . .
F36 F 0.6512(2) 0.84601(8) -0.02323(8) 0.0424(5) Uani 1 1 d . . . . .
F10 F 0.67921(19) 0.50359(8) 0.28231(8) 0.0388(5) Uani 1 1 d . . . . .
F19 F 0.3639(2) 0.14290(8) 0.51467(8) 0.0408(5) Uani 1 1 d . . . . .
F28 F 1.08963(17) 0.57536(8) 0.21457(9) 0.0415(5) Uani 1 1 d . . . . .
F30 F 0.9060(2) 0.54800(8) 0.19581(10) 0.0441(5) Uani 1 1 d . . . . .
F21 F 0.3421(2) 0.21903(9) 0.56105(8) 0.0418(5) Uani 1 1 d . . . . .
F41 F 0.6314(2) 0.90568(9) 0.36953(8) 0.0436(5) Uani 1 1 d . . . . .
F27 F 1.0370(2) 0.83735(9) 0.20127(10) 0.0485(6) Uani 1 1 d . . . . .
F42 F 0.7712(2) 0.83950(8) 0.34913(8) 0.0382(5) Uani 1 1 d . . . . .
F34 F 0.6551(2) 0.76634(9) -0.06487(8) 0.0450(5) Uani 1 1 d . . . . .
F4 F 0.3686(2) 0.09852(9) 0.12979(8) 0.0464(5) Uani 1 1 d . . . . .
F8 F 0.7642(2) 0.37896(9) 0.13075(9) 0.0468(5) Uani 1 1 d . . . . .
F29 F 0.9407(2) 0.57354(9) 0.27564(8) 0.0538(6) Uani 1 1 d . . . . .
F39 F 0.3053(2) 0.97037(9) 0.23245(10) 0.0541(6) Uani 1 1 d . . . . .
F3 F 0.6948(2) 0.03498(9) 0.26646(10) 0.0526(6) Uani 1 1 d . . . . .
F31 F 0.2640(2) 0.67038(10) 0.00162(9) 0.0512(6) Uani 1 1 d . . . . .
F33 F 0.2001(2) 0.68189(11) 0.08260(8) 0.0495(6) Uani 1 1 d . . . . .
F9 F 0.6509(2) 0.30574(10) 0.12275(8) 0.0509(6) Uani 1 1 d . . . . .
F1 F 0.5910(2) 0.03346(9) 0.34087(10) 0.0516(6) Uani 1 1 d . . . . .
F37 F 0.4081(2) 0.97268(9) 0.15774(9) 0.0511(6) Uani 1 1 d . . . . .
F44 F 0.2522(3) 0.63404(10) 0.37567(9) 0.0627(7) Uani 1 1 d . . . . .
F13 F 0.1093(2) 0.45856(9) 0.29013(13) 0.0643(8) Uani 1 1 d . . . . .
F16 F -0.0351(2) 0.16807(10) 0.30116(12) 0.0635(7) Uani 1 1 d . . . . .
F7 F 0.8190(2) 0.29649(11) 0.16950(10) 0.0617(7) Uani 1 1 d . . . . .
F24 F 0.7936(2) 0.32264(12) 0.42178(9) 0.0577(7) Uani 1 1 d . . . . .
F32 F 0.1854(2) 0.75220(10) 0.02337(12) 0.0607(7) Uani 1 1 d . . . . .
F18 F -0.18023(19) 0.23117(10) 0.31953(14) 0.0685(8) Uani 1 1 d . . . . .
F26 F 1.0545(3) 0.81498(12) 0.11989(10) 0.0722(8) Uani 1 1 d . . . . .
F2 F 0.7379(2) 0.09363(9) 0.32716(13) 0.0644(8) Uani 1 1 d . . . . .
F25 F 1.18170(19) 0.77603(10) 0.17835(14) 0.0717(9) Uani 1 1 d . . . . .
F43 F 0.3799(3) 0.70151(11) 0.38292(10) 0.0658(7) Uani 1 1 d . . . . .
F14 F 0.0411(3) 0.42645(12) 0.21672(10) 0.0928(12) Uani 1 1 d . . . . .
F17 F -0.0565(3) 0.19575(13) 0.38042(11) 0.0767(9) Uani 1 1 d . . . . .
F45 F 0.2125(3) 0.71902(13) 0.33934(11) 0.0797(9) Uani 1 1 d . . . . .
F38 F 0.2629(2) 0.91192(9) 0.17153(13) 0.0683(8) Uani 1 1 d . . . . .
C68 C 0.5643(3) 0.30675(12) 0.23163(12) 0.0196(6) Uani 1 1 d . . . . .
H68 H 0.5574 0.2709 0.2150 0.024 Uiso 1 1 calc R . . . .
F22 F 0.7996(3) 0.26059(14) 0.48804(15) 0.0980(13) Uani 1 1 d . . . . .
C93 C 0.7484(3) 0.71847(12) 0.19053(11) 0.0180(6) Uani 1 1 d . . . . .
C112 C 0.4452(3) 0.70185(12) 0.27018(12) 0.0207(6) Uani 1 1 d . . . . .
H112 H 0.4526 0.7385 0.2852 0.025 Uiso 1 1 calc R . . . .
C67 C 0.4937(3) 0.31677(12) 0.27888(11) 0.0178(6) Uani 1 1 d . . . . .
C116 C 0.4949(3) 0.63552(12) 0.20236(11) 0.0186(6) Uani 1 1 d . . . . .
H116 H 0.5383 0.6254 0.1699 0.022 Uiso 1 1 calc R . . . .
F23 F 0.7110(3) 0.34318(15) 0.49642(13) 0.0925(11) Uani 1 1 d . . . . .
C94 C 0.8415(3) 0.75932(12) 0.17926(12) 0.0193(6) Uani 1 1 d . . . . .
H94 H 0.8147 0.7981 0.1696 0.023 Uiso 1 1 calc R . . . .
C78 C 0.1604(3) 0.24728(12) 0.31858(12) 0.0202(6) Uani 1 1 d . . . . .
H78 H 0.1867 0.2085 0.3286 0.024 Uiso 1 1 calc R . . . .
C34 C 0.1674(3) 0.35204(13) 0.49770(12) 0.0240(6) Uani 1 1 d . . . . .
C115 C 0.4181(3) 0.59504(12) 0.22865(12) 0.0196(6) Uani 1 1 d . . . . .
C73 C 0.2541(3) 0.28760(12) 0.30705(11) 0.0181(6) Uani 1 1 d . . . . .
C98 C 0.7958(3) 0.66243(12) 0.20484(11) 0.0177(6) Uani 1 1 d . . . . .
H98 H 0.7372 0.6331 0.2135 0.021 Uiso 1 1 calc R . . . .
C99 C 0.5503(3) 0.74058(11) 0.12364(11) 0.0174(6) Uani 1 1 d . . . . .
C113 C 0.3698(3) 0.66129(13) 0.29706(12) 0.0239(6) Uani 1 1 d . . . . .
C97 C 0.9254(3) 0.64788(12) 0.20689(11) 0.0199(6) Uani 1 1 d . . . . .
C72 C 0.5094(3) 0.37079(12) 0.30080(12) 0.0191(6) Uani 1 1 d . . . . .
H72 H 0.4612 0.3803 0.3322 0.023 Uiso 1 1 calc R . . . .
C71 C 0.5921(3) 0.41076(12) 0.27851(12) 0.0211(6) Uani 1 1 d . . . . .
C111 C 0.5105(2) 0.69055(12) 0.22187(11) 0.0170(6) Uani 1 1 d . . . . .
C110 C 0.6418(3) 0.81656(12) 0.25788(12) 0.0197(6) Uani 1 1 d . . . . .
H110 H 0.7065 0.7904 0.2720 0.024 Uiso 1 1 calc R . . . .
C104 C 0.6283(3) 0.76062(12) 0.08086(12) 0.0207(6) Uani 1 1 d . . . . .
H104 H 0.7103 0.7733 0.0887 0.025 Uiso 1 1 calc R . . . .
C79 C 0.4494(3) 0.26310(11) 0.37515(12) 0.0178(6) Uani 1 1 d . . . . .
C69 C 0.6446(3) 0.34766(13) 0.20809(12) 0.0222(6) Uani 1 1 d . . . . .
C70 C 0.6607(3) 0.39982(13) 0.23171(12) 0.0232(6) Uani 1 1 d . . . . .
H70 H 0.7172 0.4272 0.2162 0.028 Uiso 1 1 calc R . . . .
C118 C 0.9664(3) 0.58709(13) 0.22335(12) 0.0253(6) Uani 1 1 d . . . . .
C114 C 0.3544(3) 0.60731(13) 0.27631(12) 0.0231(6) Uani 1 1 d . . . . .
H114 H 0.3018 0.5798 0.2943 0.028 Uiso 1 1 calc R . . . .
C105 C 0.5726(3) 0.80094(12) 0.21285(12) 0.0187(6) Uani 1 1 d . . . . .
C18 C 0.1849(3) 0.36264(13) -0.00530(12) 0.0238(6) Uani 1 1 d . . . . .
C75 C 0.0784(3) 0.35828(13) 0.28877(12) 0.0221(6) Uani 1 1 d . . . . .
C66 C 0.3614(3) 0.19020(12) 0.23977(12) 0.0214(6) Uani 1 1 d . . . . .
H66 H 0.2978 0.2167 0.2252 0.026 Uiso 1 1 calc R . . . .
C20 C 0.3553(3) 0.39826(13) 0.04021(13) 0.0246(6) Uani 1 1 d . . . . .
C61 C 0.4307(3) 0.20570(12) 0.28441(12) 0.0182(6) Uani 1 1 d . . . . .
C95 C 0.9709(3) 0.74545(12) 0.18168(12) 0.0212(6) Uani 1 1 d . . . . .
C65 C 0.3825(3) 0.13728(12) 0.21607(12) 0.0220(6) Uani 1 1 d . . . . .
C62 C 0.5237(3) 0.16526(12) 0.30356(13) 0.0221(6) Uani 1 1 d . . . . .
H62 H 0.5727 0.1739 0.3339 0.026 Uiso 1 1 calc R . . . .
C74 C 0.2076(3) 0.34364(12) 0.29160(11) 0.0191(6) Uani 1 1 d . . . . .
H74 H 0.2666 0.3727 0.2827 0.023 Uiso 1 1 calc R . . . .
C81 C 0.4115(3) 0.23182(12) 0.46993(12) 0.0221(6) Uani 1 1 d . . . . .
C109 C 0.6190(3) 0.86869(12) 0.28224(12) 0.0219(6) Uani 1 1 d . . . . .
C80 C 0.3742(3) 0.23701(12) 0.41591(12) 0.0209(6) Uani 1 1 d . . . . .
H80 H 0.2951 0.2223 0.4065 0.025 Uiso 1 1 calc R . . . .
C64 C 0.4765(3) 0.09793(12) 0.23544(13) 0.0255(7) Uani 1 1 d . . . . .
H64 H 0.4923 0.0620 0.2190 0.031 Uiso 1 1 calc R . . . .
C108 C 0.5242(3) 0.90802(13) 0.26308(13) 0.0247(6) Uani 1 1 d . . . . .
H108 H 0.5074 0.9436 0.2799 0.030 Uiso 1 1 calc R . . . .
C106 C 0.4794(3) 0.84145(12) 0.19399(12) 0.0206(6) Uani 1 1 d . . . . .
H106 H 0.4311 0.8332 0.1634 0.025 Uiso 1 1 calc R . . . .
C107 C 0.4552(3) 0.89377(12) 0.21882(13) 0.0250(6) Uani 1 1 d . . . . .
C41 C 0.1147(3) 0.52324(12) 0.55176(12) 0.0233(6) Uani 1 1 d . . . . .
H41 H 0.1963 0.5438 0.5524 0.028 Uiso 1 1 calc R . . . .
C48 C 0.2329(3) 0.01166(14) 0.38531(13) 0.0292(7) Uani 1 1 d . . . . .
C26 C 0.0005(3) 0.48470(13) 0.07600(12) 0.0226(6) Uani 1 1 d . . . . .
H26 H -0.0469 0.4609 0.1039 0.027 Uiso 1 1 calc R . . . .
C16 C 0.2702(3) 0.37309(13) 0.07994(12) 0.0255(7) Uani 1 1 d . . . . .
C101 C 0.3907(3) 0.72597(12) 0.05510(12) 0.0221(6) Uani 1 1 d . . . . .
C84 C 0.5662(3) 0.28205(12) 0.39235(12) 0.0209(6) Uani 1 1 d . . . . .
H84 H 0.6228 0.2984 0.3660 0.025 Uiso 1 1 calc R . . . .
C100 C 0.4288(3) 0.72477(12) 0.10882(11) 0.0189(6) Uani 1 1 d . . . . .
H100 H 0.3705 0.7128 0.1365 0.023 Uiso 1 1 calc R . . . .
C45 C 0.0523(3) 0.51916(12) 0.50095(12) 0.0199(6) Uani 1 1 d . . . . .
C35 C 0.1523(3) 0.33416(13) 0.55380(13) 0.0254(7) Uani 1 1 d . . . . .
C63 C 0.5466(3) 0.11250(12) 0.27939(13) 0.0245(6) Uani 1 1 d . . . . .
C103 C 0.5893(3) 0.76264(12) 0.02722(12) 0.0229(6) Uani 1 1 d . . . . .
C30 C -0.0410(3) 0.48733(12) 0.02082(12) 0.0200(6) Uani 1 1 d . . . . .
C17 C 0.1647(3) 0.35178(13) 0.05158(13) 0.0259(7) Uani 1 1 d . . . . .
C19 C 0.3022(3) 0.39211(13) -0.01245(12) 0.0237(6) Uani 1 1 d . . . . .
C120 C 0.6995(3) 0.88445(13) 0.32808(13) 0.0265(7) Uani 1 1 d . . . . .
C88 C 0.6100(3) 0.46408(13) 0.30942(13) 0.0264(7) Uani 1 1 d . . . . .
C31 C 0.2485(3) 0.36074(14) 0.58403(13) 0.0268(7) Uani 1 1 d . . . . .
C124 C 0.4020(3) 0.53964(13) 0.20116(13) 0.0242(6) Uani 1 1 d . . . . .
C47 C 0.3087(3) -0.03385(14) 0.41182(13) 0.0283(7) Uani 1 1 d . . . . .
C83 C 0.6023(3) 0.27794(13) 0.44639(12) 0.0239(6) Uani 1 1 d . . . . .
C28 C 0.1912(3) 0.53698(13) 0.05031(13) 0.0249(6) Uani 1 1 d . . . . .
H28 H 0.2761 0.5508 0.0602 0.030 Uiso 1 1 calc R . . . .
C102 C 0.4712(3) 0.74453(13) 0.01349(12) 0.0236(6) Uani 1 1 d . . . . .
H102 H 0.4461 0.7448 -0.0233 0.028 Uiso 1 1 calc R . . . .
C29 C 0.1599(3) 0.53406(13) -0.00504(12) 0.0234(6) Uani 1 1 d . . . . .
H29 H 0.2244 0.5447 -0.0336 0.028 Uiso 1 1 calc R . . . .
C82 C 0.5243(3) 0.25333(13) 0.48612(12) 0.0246(6) Uani 1 1 d . . . . .
H82 H 0.5475 0.2513 0.5232 0.030 Uiso 1 1 calc R . . . .
C77 C 0.0311(3) 0.26152(13) 0.31602(13) 0.0241(6) Uani 1 1 d . . . . .
C86 C 0.3014(3) 0.12106(13) 0.17078(13) 0.0271(7) Uani 1 1 d . . . . .
C27 C 0.1109(3) 0.51215(13) 0.09131(12) 0.0259(7) Uani 1 1 d . . . . .
H27 H 0.1392 0.5088 0.1299 0.031 Uiso 1 1 calc R . . . .
C50 C 0.1751(3) -0.07530(14) 0.35270(13) 0.0283(7) Uani 1 1 d . . . . .
C44 C -0.0875(3) 0.44787(13) 0.54709(12) 0.0224(6) Uani 1 1 d . . . . .
H44 H -0.1477 0.4159 0.5446 0.027 Uiso 1 1 calc R . . . .
C56 C 0.0894(3) -0.07009(15) 0.52035(13) 0.0333(8) Uani 1 1 d . . . . .
H56 H 0.1668 -0.0833 0.5413 0.040 Uiso 1 1 calc R . . . .
C91 C 0.3313(3) 0.19988(14) 0.51084(13) 0.0289(7) Uani 1 1 d . . . . .
C76 C -0.0120(3) 0.31731(13) 0.30091(13) 0.0257(7) Uani 1 1 d . . . . .
H76 H -0.1003 0.3273 0.2989 0.031 Uiso 1 1 calc R . . . .
C33 C 0.2728(3) 0.38966(13) 0.49323(13) 0.0256(7) Uani 1 1 d . . . . .
C42 C 0.0687(3) 0.49600(13) 0.60036(12) 0.0243(6) Uani 1 1 d . . . . .
H42 H 0.1157 0.4987 0.6350 0.029 Uiso 1 1 calc R . . . .
C49 C 0.1492(3) -0.01388(14) 0.34961(13) 0.0291(7) Uani 1 1 d . . . . .
C96 C 1.0149(3) 0.68906(13) 0.19554(12) 0.0239(6) Uani 1 1 d . . . . .
H96 H 1.1033 0.6792 0.1972 0.029 Uiso 1 1 calc R . . . .
C59 C -0.0988(3) -0.03089(15) 0.44614(13) 0.0312(7) Uani 1 1 d . . . . .
H59 H -0.1532 -0.0165 0.4150 0.037 Uiso 1 1 calc R . . . .
C122 C 0.6727(3) 0.78825(14) -0.01658(13) 0.0302(7) Uani 1 1 d . . . . .
C5 C 0.8241(3) 0.07637(14) 0.14527(13) 0.0300(7) Uani 1 1 d . . . . .
C46 C 0.2729(3) -0.08780(14) 0.39171(13) 0.0276(7) Uani 1 1 d . . . . .
C11 C 0.9158(3) 0.07029(15) -0.02343(13) 0.0335(8) Uani 1 1 d . . . . .
H11 H 0.8405 0.0836 -0.0457 0.040 Uiso 1 1 calc R . . . .
C87 C 0.7191(3) 0.33275(14) 0.15832(14) 0.0326(7) Uani 1 1 d . . . . .
C13 C 1.0702(3) 0.09118(16) 0.04540(15) 0.0368(8) Uani 1 1 d . . . . .
H13 H 1.1048 0.1190 0.0705 0.044 Uiso 1 1 calc R . . . .
C32 C 0.3214(3) 0.39512(14) 0.54627(13) 0.0267(7) Uani 1 1 d . . . . .
C43 C -0.0335(3) 0.45822(13) 0.59798(12) 0.0245(6) Uani 1 1 d . . . . .
H43 H -0.0577 0.4341 0.6310 0.029 Uiso 1 1 calc R . . . .
C57 C 0.0259(4) -0.11056(15) 0.49040(15) 0.0374(8) Uani 1 1 d . . . . .
H57 H 0.0573 -0.1520 0.4912 0.045 Uiso 1 1 calc R . . . .
C85 C 0.6428(3) 0.06965(13) 0.30339(15) 0.0333(8) Uani 1 1 d . . . . .
C4 C 0.8388(4) 0.01455(15) 0.14541(15) 0.0386(9) Uani 1 1 d . . . . .
C89 C 0.0365(3) 0.41830(14) 0.26976(15) 0.0332(8) Uani 1 1 d . . . . .
C121 C 0.2611(3) 0.70770(14) 0.04097(13) 0.0283(7) Uani 1 1 d . . . . .
C3 C 0.7536(4) -0.00530(15) 0.10792(17) 0.0442(10) Uani 1 1 d . . . . .
C12 C 0.9793(4) 0.11097(15) 0.00614(14) 0.0362(8) Uani 1 1 d . . . . .
H12 H 0.9499 0.1527 0.0039 0.043 Uiso 1 1 calc R . . . .
C14 C 1.0970(3) 0.03153(15) 0.05417(14) 0.0322(7) Uani 1 1 d . . . . .
H14 H 1.1486 0.0175 0.0862 0.039 Uiso 1 1 calc R . . . .
C1 C 0.7307(3) 0.09463(14) 0.10613(13) 0.0303(7) Uani 1 1 d . . . . .
C117 C 1.0615(3) 0.79262(14) 0.17041(15) 0.0310(7) Uani 1 1 d . . . . .
C58 C -0.0687(3) -0.09049(16) 0.45305(15) 0.0373(8) Uani 1 1 d . . . . .
H58 H -0.1038 -0.1179 0.4276 0.045 Uiso 1 1 calc R . . . .
C123 C 0.3022(4) 0.67784(15) 0.34774(15) 0.0382(8) Uani 1 1 d . . . . .
C119 C 0.3576(3) 0.93630(13) 0.19513(15) 0.0326(8) Uani 1 1 d . . . . .
C60 C 0.0488(3) -0.01018(14) 0.51906(12) 0.0267(7) Uani 1 1 d . . . . .
C39 C 0.0922(3) 0.33406(15) 0.45095(14) 0.0347(8) Uani 1 1 d . . . . .
H39A H 0.0648 0.3684 0.4286 0.052 Uiso 1 1 calc GR . . . .
H39B H 0.0173 0.3139 0.4647 0.052 Uiso 1 1 calc GR . . . .
H39C H 0.1451 0.3081 0.4289 0.052 Uiso 1 1 calc GR . . . .
C2 C 0.6871(3) 0.04391(18) 0.08269(16) 0.0423(9) Uani 1 1 d . . . . .
C90 C -0.0605(3) 0.21505(15) 0.32892(16) 0.0345(8) Uani 1 1 d . . . . .
C24 C 0.3628(3) 0.40971(15) -0.06564(14) 0.0359(8) Uani 1 1 d . . . . .
H24A H 0.4083 0.4453 -0.0619 0.054 Uiso 1 1 calc GR . . . .
H24B H 0.2970 0.4165 -0.0932 0.054 Uiso 1 1 calc GR . . . .
H24C H 0.4229 0.3788 -0.0767 0.054 Uiso 1 1 calc GR . . . .
C15 C 0.9533(3) 0.01009(14) -0.01984(12) 0.0266(7) Uani 1 1 d . . . . .
C92 C 0.7254(3) 0.30072(16) 0.46294(14) 0.0375(8) Uani 1 1 d . . . . .
C21 C 0.2929(4) 0.36612(17) 0.13965(14) 0.0418(9) Uani 1 1 d . . . . .
H21A H 0.2112 0.3650 0.1592 0.063 Uiso 1 1 calc GR . . . .
H21B H 0.3400 0.3989 0.1512 0.063 Uiso 1 1 calc GR . . . .
H21C H 0.3425 0.3300 0.1477 0.063 Uiso 1 1 calc GR . . . .
C37 C 0.4355(3) 0.42838(17) 0.55946(17) 0.0435(9) Uani 1 1 d . . . . .
H37A H 0.4315 0.4377 0.5978 0.065 Uiso 1 1 calc GR . . . .
H37B H 0.4363 0.4643 0.5367 0.065 Uiso 1 1 calc GR . . . .
H37C H 0.5132 0.4048 0.5525 0.065 Uiso 1 1 calc GR . . . .
C52 C 0.4100(3) -0.02591(18) 0.45234(16) 0.0414(9) Uani 1 1 d . . . . .
H52A H 0.3858 0.0072 0.4741 0.062 Uiso 1 1 calc GR . . . .
H52B H 0.4906 -0.0187 0.4333 0.062 Uiso 1 1 calc GR . . . .
H52C H 0.4199 -0.0610 0.4761 0.062 Uiso 1 1 calc GR . . . .
C51 C 0.3333(4) -0.14625(16) 0.40605(18) 0.0452(9) Uani 1 1 d . . . . .
H51A H 0.3673 -0.1466 0.4428 0.068 Uiso 1 1 calc GR . . . .
H51B H 0.4026 -0.1546 0.3802 0.068 Uiso 1 1 calc GR . . . .
H51C H 0.2696 -0.1757 0.4045 0.068 Uiso 1 1 calc GR . . . .
C36 C 0.2717(4) 0.35027(18) 0.64330(14) 0.0432(9) Uani 1 1 d . . . . .
H36A H 0.1908 0.3437 0.6624 0.065 Uiso 1 1 calc GR . . . .
H36B H 0.3106 0.3841 0.6574 0.065 Uiso 1 1 calc GR . . . .
H36C H 0.3291 0.3161 0.6491 0.065 Uiso 1 1 calc GR . . . .
C55 C 0.1165(4) -0.11885(18) 0.31888(16) 0.0441(9) Uani 1 1 d . . . . .
H55A H 0.1045 -0.1547 0.3409 0.066 Uiso 1 1 calc GR . . . .
H55B H 0.1728 -0.1271 0.2879 0.066 Uiso 1 1 calc GR . . . .
H55C H 0.0341 -0.1033 0.3057 0.066 Uiso 1 1 calc GR . . . .
C23 C 0.0993(3) 0.34743(15) -0.04972(15) 0.0374(8) Uani 1 1 d . . . . .
H23A H 0.1002 0.3778 -0.0789 0.056 Uiso 1 1 calc GR . . . .
H23B H 0.0125 0.3441 -0.0353 0.056 Uiso 1 1 calc GR . . . .
H23C H 0.1291 0.3104 -0.0641 0.056 Uiso 1 1 calc GR . . . .
B1 B 0.4059(3) 0.26889(13) 0.31098(13) 0.0176(6) Uani 1 1 d . . . . .
C54 C 0.0565(4) 0.01876(18) 0.31295(16) 0.0470(10) Uani 1 1 d . . . . .
H54A H -0.0120 -0.0065 0.3044 0.070 Uiso 1 1 calc GR . . . .
H54B H 0.1002 0.0315 0.2794 0.070 Uiso 1 1 calc GR . . . .
H54C H 0.0207 0.0526 0.3311 0.070 Uiso 1 1 calc GR . . . .
C40 C 0.0571(3) 0.29344(15) 0.57816(17) 0.0405(9) Uani 1 1 d . . . . .
H40A H -0.0174 0.2939 0.5548 0.061 Uiso 1 1 calc GR . . . .
H40B H 0.0309 0.3058 0.6142 0.061 Uiso 1 1 calc GR . . . .
H40C H 0.0957 0.2541 0.5813 0.061 Uiso 1 1 calc GR . . . .
C38 C 0.3247(4) 0.41599(16) 0.44103(15) 0.0397(8) Uani 1 1 d . . . . .
H38A H 0.3588 0.4537 0.4476 0.060 Uiso 1 1 calc GR . . . .
H38B H 0.2566 0.4211 0.4144 0.060 Uiso 1 1 calc GR . . . .
H38C H 0.3928 0.3904 0.4270 0.060 Uiso 1 1 calc GR . . . .
B2 B 0.5965(3) 0.73743(13) 0.18721(13) 0.0177(6) Uani 1 1 d . . . . .
C25 C 0.4816(3) 0.42241(16) 0.05119(16) 0.0390(8) Uani 1 1 d . . . . .
H25A H 0.4783 0.4401 0.0865 0.058 Uiso 1 1 calc GR . . . .
H25B H 0.5017 0.4518 0.0227 0.058 Uiso 1 1 calc GR . . . .
H25C H 0.5475 0.3911 0.0516 0.058 Uiso 1 1 calc GR . . . .
C22 C 0.0561(3) 0.32087(16) 0.07799(17) 0.0415(9) Uani 1 1 d . . . . .
H22A H -0.0190 0.3263 0.0550 0.062 Uiso 1 1 calc GR . . . .
H22B H 0.0371 0.3366 0.1135 0.062 Uiso 1 1 calc GR . . . .
H22C H 0.0790 0.2794 0.0827 0.062 Uiso 1 1 calc GR . . . .
C53 C 0.2419(4) 0.07554(15) 0.39292(18) 0.0461(10) Uani 1 1 d . . . . .
H53A H 0.1572 0.0946 0.3898 0.069 Uiso 1 1 calc GR . . . .
H53B H 0.2987 0.0923 0.3650 0.069 Uiso 1 1 calc GR . . . .
H53C H 0.2756 0.0813 0.4289 0.069 Uiso 1 1 calc GR . . . .
C6 C 0.6803(4) 0.15548(18) 0.09501(19) 0.0562(11) Uani 1 1 d . . . . .
H6A H 0.7485 0.1823 0.0992 0.084 Uiso 1 1 calc GR . . . .
H6B H 0.6109 0.1642 0.1207 0.084 Uiso 1 1 calc GR . . . .
H6C H 0.6483 0.1598 0.0579 0.084 Uiso 1 1 calc GR . . . .
C10 C 0.8888(4) 0.1150(2) 0.18222(17) 0.0522(11) Uani 1 1 d . . . . .
H10A H 0.9681 0.0957 0.1952 0.078 Uiso 1 1 calc GR . . . .
H10B H 0.8327 0.1231 0.2133 0.078 Uiso 1 1 calc GR . . . .
H10C H 0.9079 0.1514 0.1624 0.078 Uiso 1 1 calc GR . . . .
C9 C 0.9263(5) -0.0227(2) 0.18141(18) 0.0739(17) Uani 1 1 d . . . . .
H9A H 0.9545 -0.0574 0.1626 0.111 Uiso 1 1 calc GR . . . .
H9B H 0.8810 -0.0342 0.2150 0.111 Uiso 1 1 calc GR . . . .
H9C H 1.0003 -0.0009 0.1901 0.111 Uiso 1 1 calc GR . . . .
C7 C 0.5858(4) 0.0422(3) 0.0412(2) 0.0798(18) Uani 1 1 d . . . . .
H7A H 0.5821 0.0788 0.0194 0.120 Uiso 1 1 calc GR . . . .
H7B H 0.5036 0.0365 0.0594 0.120 Uiso 1 1 calc GR . . . .
H7C H 0.6054 0.0101 0.0176 0.120 Uiso 1 1 calc GR . . . .
C8 C 0.7353(5) -0.06803(19) 0.0968(3) 0.086(2) Uani 1 1 d . . . . .
H8A H 0.6944 -0.0703 0.0617 0.128 Uiso 1 1 calc GR . . . .
H8B H 0.6815 -0.0855 0.1255 0.128 Uiso 1 1 calc GR . . . .
H8C H 0.8182 -0.0890 0.0962 0.128 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru2 C18 2.200(3) . ?
Ru2 C20 2.190(3) . ?
Ru2 C26 2.223(3) . ?
Ru2 C16 2.194(3) . ?
Ru2 C30 2.415(3) . ?
Ru2 C30 2.420(3) 2_565 ?
Ru2 C17 2.184(3) . ?
Ru2 C19 2.182(3) . ?
Ru2 C28 2.193(3) . ?
Ru2 C29 2.234(3) . ?
Ru2 C27 2.194(3) . ?
Ru3 C34 2.181(3) . ?
Ru3 C41 2.225(3) . ?
Ru3 C45 2.418(3) . ?
Ru3 C45 2.426(3) 2_566 ?
Ru3 C35 2.174(3) . ?
Ru3 C31 2.196(3) . ?
Ru3 C44 2.235(3) . ?
Ru3 C33 2.200(3) . ?
Ru3 C42 2.194(3) . ?
Ru3 C32 2.200(3) . ?
Ru3 C43 2.197(3) . ?
Ru4 C48 2.202(3) . ?
Ru4 C47 2.190(3) . ?
Ru4 C50 2.183(3) . ?
Ru4 C56 2.228(3) . ?
Ru4 C49 2.178(3) . ?
Ru4 C59 2.223(3) . ?
Ru4 C46 2.180(3) . ?
Ru4 C57 2.198(3) . ?
Ru4 C58 2.195(3) . ?
Ru4 C60 2.421(3) . ?
Ru4 C60 2.426(3) 2_556 ?
Ru1 C5 2.184(3) . ?
Ru1 C11 2.230(3) . ?
Ru1 C13 2.193(3) . ?
Ru1 C4 2.173(3) . ?
Ru1 C3 2.191(3) . ?
Ru1 C12 2.200(3) . ?
Ru1 C14 2.221(3) . ?
Ru1 C1 2.184(3) . ?
Ru1 C2 2.181(3) . ?
Ru1 C15 2.418(3) 2_755 ?
Ru1 C15 2.415(3) . ?
F40 C120 1.342(4) . ?
F15 C89 1.328(4) . ?
F11 C88 1.346(4) . ?
F20 C91 1.341(4) . ?
F5 C86 1.348(4) . ?
F47 C124 1.339(4) . ?
F48 C124 1.344(4) . ?
F12 C88 1.337(4) . ?
F46 C124 1.333(4) . ?
F6 C86 1.343(4) . ?
F35 C122 1.344(4) . ?
F36 C122 1.348(4) . ?
F10 C88 1.339(4) . ?
F19 C91 1.347(4) . ?
F28 C118 1.330(4) . ?
F30 C118 1.346(4) . ?
F21 C91 1.345(4) . ?
F41 C120 1.341(4) . ?
F27 C117 1.330(4) . ?
F42 C120 1.345(4) . ?
F34 C122 1.337(4) . ?
F4 C86 1.340(4) . ?
F8 C87 1.339(4) . ?
F29 C118 1.339(4) . ?
F39 C119 1.339(4) . ?
F3 C85 1.339(4) . ?
F31 C121 1.331(4) . ?
F33 C121 1.332(4) . ?
F9 C87 1.338(4) . ?
F1 C85 1.341(4) . ?
F37 C119 1.336(4) . ?
F44 C123 1.320(4) . ?
F13 C89 1.353(4) . ?
F16 C90 1.329(4) . ?
F7 C87 1.341(4) . ?
F24 C92 1.327(4) . ?
F32 C121 1.334(4) . ?
F18 C90 1.319(4) . ?
F26 C117 1.327(4) . ?
F2 C85 1.325(4) . ?
F25 C117 1.321(4) . ?
F43 C123 1.354(5) . ?
F14 C89 1.313(4) . ?
F17 C90 1.326(5) . ?
F45 C123 1.323(5) . ?
F38 C119 1.324(4) . ?
C68 H68 0.9500 . ?
C68 C67 1.396(4) . ?
C68 C69 1.395(4) . ?
F22 C92 1.324(4) . ?
C93 C94 1.406(4) . ?
C93 C98 1.399(4) . ?
C93 B2 1.643(4) . ?
C112 H112 0.9500 . ?
C112 C113 1.391(4) . ?
C112 C111 1.397(4) . ?
C67 C72 1.404(4) . ?
C67 B1 1.638(4) . ?
C116 H116 0.9500 . ?
C116 C115 1.392(4) . ?
C116 C111 1.401(4) . ?
F23 C92 1.317(5) . ?
C94 H94 0.9500 . ?
C94 C95 1.388(4) . ?
C78 H78 0.9500 . ?
C78 C73 1.402(4) . ?
C78 C77 1.389(4) . ?
C34 C35 1.433(4) . ?
C34 C33 1.439(4) . ?
C34 C39 1.496(4) . ?
C115 C114 1.380(4) . ?
C115 C124 1.497(4) . ?
C73 C74 1.403(4) . ?
C73 B1 1.640(4) . ?
C98 H98 0.9500 . ?
C98 C97 1.392(4) . ?
C99 C104 1.399(4) . ?
C99 C100 1.405(4) . ?
C99 B2 1.647(4) . ?
C113 C114 1.390(4) . ?
C113 C123 1.488(4) . ?
C97 C118 1.492(4) . ?
C97 C96 1.384(4) . ?
C72 H72 0.9500 . ?
C72 C71 1.385(4) . ?
C71 C70 1.380(4) . ?
C71 C88 1.503(4) . ?
C111 B2 1.640(4) . ?
C110 H110 0.9500 . ?
C110 C105 1.410(4) . ?
C110 C109 1.385(4) . ?
C104 H104 0.9500 . ?
C104 C103 1.390(4) . ?
C79 C80 1.398(4) . ?
C79 C84 1.402(4) . ?
C79 B1 1.653(4) . ?
C69 C70 1.384(4) . ?
C69 C87 1.493(4) . ?
C70 H70 0.9500 . ?
C114 H114 0.9500 . ?
C105 C106 1.396(4) . ?
C105 B2 1.637(4) . ?
C18 C17 1.427(4) . ?
C18 C19 1.440(4) . ?
C18 C23 1.496(4) . ?
C75 C74 1.389(4) . ?
C75 C76 1.390(4) . ?
C75 C89 1.494(4) . ?
C66 H66 0.9500 . ?
C66 C61 1.401(4) . ?
C66 C65 1.391(4) . ?
C20 C16 1.436(4) . ?
C20 C19 1.439(4) . ?
C20 C25 1.498(4) . ?
C61 C62 1.396(4) . ?
C61 B1 1.642(4) . ?
C95 C96 1.393(4) . ?
C95 C117 1.493(4) . ?
C65 C64 1.389(4) . ?
C65 C86 1.490(4) . ?
C62 H62 0.9500 . ?
C62 C63 1.396(4) . ?
C74 H74 0.9500 . ?
C81 C80 1.394(4) . ?
C81 C82 1.380(4) . ?
C81 C91 1.492(4) . ?
C109 C108 1.394(4) . ?
C109 C120 1.494(4) . ?
C80 H80 0.9500 . ?
C64 H64 0.9500 . ?
C64 C63 1.385(4) . ?
C108 H108 0.9500 . ?
C108 C107 1.383(4) . ?
C106 H106 0.9500 . ?
C106 C107 1.396(4) . ?
C107 C119 1.496(4) . ?
C41 H41 1.0000 . ?
C41 C45 1.434(4) . ?
C41 C42 1.415(4) . ?
C48 C47 1.431(5) . ?
C48 C49 1.423(5) . ?
C48 C53 1.506(5) . ?
C26 H26 1.0000 . ?
C26 C30 1.434(4) . ?
C26 C27 1.414(4) . ?
C16 C17 1.440(4) . ?
C16 C21 1.496(4) . ?
C101 C100 1.390(4) . ?
C101 C102 1.384(4) . ?
C101 C121 1.498(4) . ?
C84 H84 0.9500 . ?
C84 C83 1.390(4) . ?
C100 H100 0.9500 . ?
C45 Ru3 2.426(3) 2_566 ?
C45 C45 1.446(6) 2_566 ?
C45 C44 1.429(4) 2_566 ?
C35 C31 1.444(4) . ?
C35 C40 1.503(5) . ?
C63 C85 1.494(4) . ?
C103 C102 1.382(4) . ?
C103 C122 1.496(4) . ?
C30 Ru2 2.420(3) 2_565 ?
C30 C30 1.448(6) 2_565 ?
C30 C29 1.433(4) 2_565 ?
C17 C22 1.498(4) . ?
C19 C24 1.495(4) . ?
C31 C32 1.430(5) . ?
C31 C36 1.493(5) . ?
C47 C46 1.434(4) . ?
C47 C52 1.497(5) . ?
C83 C82 1.385(4) . ?
C83 C92 1.490(4) . ?
C28 H28 1.0000 . ?
C28 C29 1.416(4) . ?
C28 C27 1.422(4) . ?
C102 H102 0.9500 . ?
C29 C30 1.433(4) 2_565 ?
C29 H29 1.0000 . ?
C82 H82 0.9500 . ?
C77 C76 1.384(4) . ?
C77 C90 1.494(4) . ?
C27 H27 1.0000 . ?
C50 C49 1.434(5) . ?
C50 C46 1.431(5) . ?
C50 C55 1.499(5) . ?
C44 C45 1.429(4) 2_566 ?
C44 H44 1.0000 . ?
C44 C43 1.423(4) . ?
C56 H56 1.0000 . ?
C56 C57 1.418(5) . ?
C56 C60 1.432(5) . ?
C76 H76 0.9500 . ?
C33 C32 1.427(4) . ?
C33 C38 1.502(4) . ?
C42 H42 1.0000 . ?
C42 C43 1.419(4) . ?
C49 C54 1.496(5) . ?
C96 H96 0.9500 . ?
C59 H59 1.0000 . ?
C59 C58 1.404(5) . ?
C59 C60 1.435(5) 2_556 ?
C5 C4 1.432(5) . ?
C5 C1 1.426(5) . ?
C5 C10 1.499(5) . ?
C46 C51 1.498(5) . ?
C11 H11 1.0000 . ?
C11 C12 1.416(5) . ?
C11 C15 1.430(5) . ?
C13 H13 1.0000 . ?
C13 C12 1.418(5) . ?
C13 C14 1.403(5) . ?
C32 C37 1.503(4) . ?
C43 H43 1.0000 . ?
C57 H57 1.0000 . ?
C57 C58 1.416(5) . ?
C4 C3 1.406(6) . ?
C4 C9 1.504(6) . ?
C3 C2 1.431(6) . ?
C3 C8 1.511(5) . ?
C12 H12 1.0000 . ?
C14 H14 1.0000 . ?
C14 C15 1.437(5) 2_755 ?
C1 C2 1.430(5) . ?
C1 C6 1.497(5) . ?
C58 H58 1.0000 . ?
C60 Ru4 2.426(3) 2_556 ?
C60 C59 1.435(5) 2_556 ?
C60 C60 1.452(6) 2_556 ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C2 C7 1.493(6) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C15 Ru1 2.418(3) 2_755 ?
C15 C14 1.437(5) 2_755 ?
C15 C15 1.446(6) 2_755 ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C18 Ru2 C26 127.55(11) . . ?
C18 Ru2 C30 107.93(10) . . ?
C18 Ru2 C30 107.65(10) . 2_565 ?
C18 Ru2 C29 126.75(11) . . ?
C20 Ru2 C18 64.21(11) . . ?
C20 Ru2 C26 149.80(11) . . ?
C20 Ru2 C16 38.23(12) . . ?
C20 Ru2 C30 172.06(11) . . ?
C20 Ru2 C30 144.01(11) . 2_565 ?
C20 Ru2 C28 110.27(11) . . ?
C20 Ru2 C29 118.87(11) . . ?
C20 Ru2 C27 122.68(11) . . ?
C26 Ru2 C30 64.34(10) . 2_565 ?
C26 Ru2 C30 35.73(10) . . ?
C26 Ru2 C29 78.44(11) . . ?
C16 Ru2 C18 63.99(11) . . ?
C16 Ru2 C26 116.37(11) . . ?
C16 Ru2 C30 170.52(11) . 2_565 ?
C16 Ru2 C30 140.87(11) . . ?
C16 Ru2 C29 152.88(12) . . ?
C30 Ru2 C30 34.85(13) . 2_565 ?
C17 Ru2 C18 38.00(11) . . ?
C17 Ru2 C20 64.15(11) . . ?
C17 Ru2 C26 106.71(11) . . ?
C17 Ru2 C16 38.39(12) . . ?
C17 Ru2 C30 132.21(11) . 2_565 ?
C17 Ru2 C30 110.70(11) . . ?
C17 Ru2 C28 159.03(12) . . ?
C17 Ru2 C29 163.67(12) . . ?
C17 Ru2 C27 126.03(12) . . ?
C19 Ru2 C18 38.36(11) . . ?
C19 Ru2 C20 38.43(11) . . ?
C19 Ru2 C26 165.52(11) . . ?
C19 Ru2 C16 64.08(11) . . ?
C19 Ru2 C30 112.65(11) . 2_565 ?
C19 Ru2 C30 134.50(11) . . ?
C19 Ru2 C17 63.99(11) . . ?
C19 Ru2 C28 125.46(11) . . ?
C19 Ru2 C29 107.54(11) . . ?
C19 Ru2 C27 157.09(12) . . ?
C28 Ru2 C18 160.46(12) . . ?
C28 Ru2 C26 67.27(11) . . ?
C28 Ru2 C16 124.47(12) . . ?
C28 Ru2 C30 64.91(10) . 2_565 ?
C28 Ru2 C30 76.72(11) . . ?
C28 Ru2 C29 37.28(11) . . ?
C28 Ru2 C27 37.83(12) . . ?
C29 Ru2 C30 35.59(10) . 2_565 ?
C29 Ru2 C30 64.24(10) . . ?
C27 Ru2 C18 161.41(12) . . ?
C27 Ru2 C26 37.34(11) . . ?
C27 Ru2 C16 109.58(11) . . ?
C27 Ru2 C30 65.12(10) . . ?
C27 Ru2 C30 76.89(11) . 2_565 ?
C27 Ru2 C29 67.40(11) . . ?
C34 Ru3 C41 149.91(12) . . ?
C34 Ru3 C45 106.50(11) . 2_566 ?
C34 Ru3 C45 121.09(11) . . ?
C34 Ru3 C31 64.30(11) . . ?
C34 Ru3 C44 111.09(11) . . ?
C34 Ru3 C33 38.34(11) . . ?
C34 Ru3 C42 172.76(12) . . ?
C34 Ru3 C32 63.95(11) . . ?
C34 Ru3 C43 137.35(11) . . ?
C41 Ru3 C45 63.98(10) . 2_566 ?
C41 Ru3 C45 35.68(10) . . ?
C41 Ru3 C44 78.35(11) . . ?
C45 Ru3 C45 34.73(13) . 2_566 ?
C35 Ru3 C34 38.42(12) . . ?
C35 Ru3 C41 167.72(12) . . ?
C35 Ru3 C45 156.56(11) . . ?
C35 Ru3 C45 127.17(11) . 2_566 ?
C35 Ru3 C31 38.58(12) . . ?
C35 Ru3 C44 107.98(11) . . ?
C35 Ru3 C33 64.02(11) . . ?
C35 Ru3 C42 134.57(12) . . ?
C35 Ru3 C32 63.99(12) . . ?
C35 Ru3 C43 111.27(11) . . ?
C31 Ru3 C41 129.82(12) . . ?
C31 Ru3 C45 165.32(11) . 2_566 ?
C31 Ru3 C45 159.62(11) . . ?
C31 Ru3 C44 134.61(11) . . ?
C31 Ru3 C33 63.68(12) . . ?
C31 Ru3 C32 37.96(12) . . ?
C31 Ru3 C43 113.43(11) . . ?
C44 Ru3 C45 35.42(10) . 2_566 ?
C44 Ru3 C45 64.25(10) . . ?
C33 Ru3 C41 117.70(11) . . ?
C33 Ru3 C45 117.04(11) . 2_566 ?
C33 Ru3 C45 107.28(11) . . ?
C33 Ru3 C44 141.64(12) . . ?
C33 Ru3 C32 37.84(12) . . ?
C42 Ru3 C41 37.33(11) . . ?
C42 Ru3 C45 76.57(11) . 2_566 ?
C42 Ru3 C45 65.17(10) . . ?
C42 Ru3 C31 111.26(11) . . ?
C42 Ru3 C44 67.46(11) . . ?
C42 Ru3 C33 146.23(12) . . ?
C42 Ru3 C32 116.57(11) . . ?
C42 Ru3 C43 37.70(11) . . ?
C32 Ru3 C41 109.24(11) . . ?
C32 Ru3 C45 123.70(11) . . ?
C32 Ru3 C45 150.47(11) . 2_566 ?
C32 Ru3 C44 171.82(11) . . ?
C43 Ru3 C41 67.08(11) . . ?
C43 Ru3 C45 76.72(11) . . ?
C43 Ru3 C45 64.67(10) . 2_566 ?
C43 Ru3 C44 37.44(11) . . ?
C43 Ru3 C33 175.20(11) . . ?
C43 Ru3 C32 141.97(12) . . ?
C48 Ru4 C56 132.21(13) . . ?
C48 Ru4 C59 124.87(13) . . ?
C48 Ru4 C60 108.55(11) . 2_556 ?
C48 Ru4 C60 111.45(11) . . ?
C47 Ru4 C48 38.03(12) . . ?
C47 Ru4 C56 109.02(13) . . ?
C47 Ru4 C59 161.70(13) . . ?
C47 Ru4 C57 129.01(14) . . ?
C47 Ru4 C58 161.20(13) . . ?
C47 Ru4 C60 111.64(11) . . ?
C47 Ru4 C60 131.65(11) . 2_556 ?
C50 Ru4 C48 63.67(12) . . ?
C50 Ru4 C47 63.87(12) . . ?
C50 Ru4 C56 146.65(13) . . ?
C50 Ru4 C59 119.23(12) . . ?
C50 Ru4 C57 119.52(13) . . ?
C50 Ru4 C58 108.46(12) . . ?
C50 Ru4 C60 146.28(11) . 2_556 ?
C50 Ru4 C60 174.95(11) . . ?
C56 Ru4 C60 64.18(11) . 2_556 ?
C56 Ru4 C60 35.56(12) . . ?
C49 Ru4 C48 37.92(12) . . ?
C49 Ru4 C47 63.85(12) . . ?
C49 Ru4 C50 38.39(12) . . ?
C49 Ru4 C56 170.03(13) . . ?
C49 Ru4 C59 106.48(12) . . ?
C49 Ru4 C46 64.27(12) . . ?
C49 Ru4 C57 152.52(13) . . ?
C49 Ru4 C58 121.92(13) . . ?
C49 Ru4 C60 138.39(12) . . ?
C49 Ru4 C60 114.53(11) . 2_556 ?
C59 Ru4 C56 78.29(13) . . ?
C59 Ru4 C60 64.22(11) . . ?
C59 Ru4 C60 35.60(11) . 2_556 ?
C46 Ru4 C48 63.91(12) . . ?
C46 Ru4 C47 38.31(12) . . ?
C46 Ru4 C50 38.30(12) . . ?
C46 Ru4 C56 115.09(13) . . ?
C46 Ru4 C59 154.03(12) . . ?
C46 Ru4 C57 109.26(13) . . ?
C46 Ru4 C58 124.97(13) . . ?
C46 Ru4 C60 139.38(12) . . ?
C46 Ru4 C60 169.91(11) . 2_556 ?
C57 Ru4 C48 165.91(14) . . ?
C57 Ru4 C56 37.35(13) . . ?
C57 Ru4 C59 66.95(13) . . ?
C57 Ru4 C60 76.49(12) . 2_556 ?
C57 Ru4 C60 64.85(12) . . ?
C58 Ru4 C48 156.49(14) . . ?
C58 Ru4 C56 67.17(13) . . ?
C58 Ru4 C59 37.05(13) . . ?
C58 Ru4 C57 37.59(14) . . ?
C58 Ru4 C60 64.69(12) . 2_556 ?
C58 Ru4 C60 76.53(12) . . ?
C60 Ru4 C60 34.85(14) . 2_556 ?
C5 Ru1 C11 150.27(13) . . ?
C5 Ru1 C13 108.91(13) . . ?
C5 Ru1 C3 63.45(13) . . ?
C5 Ru1 C12 122.31(13) . . ?
C5 Ru1 C14 117.29(12) . . ?
C5 Ru1 C1 38.12(12) . . ?
C5 Ru1 C15 143.04(12) . 2_755 ?
C5 Ru1 C15 172.90(12) . . ?
C11 Ru1 C15 64.19(11) . 2_755 ?
C11 Ru1 C15 35.57(12) . . ?
C13 Ru1 C11 67.26(13) . . ?
C13 Ru1 C12 37.66(14) . . ?
C13 Ru1 C14 37.08(14) . . ?
C13 Ru1 C15 64.87(12) . 2_755 ?
C13 Ru1 C15 76.65(12) . . ?
C4 Ru1 C5 38.37(13) . . ?
C4 Ru1 C11 166.45(14) . . ?
C4 Ru1 C13 124.28(15) . . ?
C4 Ru1 C3 37.60(15) . . ?
C4 Ru1 C12 156.27(14) . . ?
C4 Ru1 C14 106.61(14) . . ?
C4 Ru1 C1 64.07(13) . . ?
C4 Ru1 C2 63.77(15) . . ?
C4 Ru1 C15 112.35(12) . 2_755 ?
C4 Ru1 C15 134.87(12) . . ?
C3 Ru1 C11 129.46(15) . . ?
C3 Ru1 C13 159.25(16) . . ?
C3 Ru1 C12 163.02(16) . . ?
C3 Ru1 C14 126.70(14) . . ?
C3 Ru1 C15 108.63(12) . 2_755 ?
C3 Ru1 C15 109.79(12) . . ?
C12 Ru1 C11 37.28(13) . . ?
C12 Ru1 C14 66.97(13) . . ?
C12 Ru1 C15 76.49(12) . 2_755 ?
C12 Ru1 C15 64.78(12) . . ?
C14 Ru1 C11 78.38(13) . . ?
C14 Ru1 C15 35.78(11) . 2_755 ?
C14 Ru1 C15 64.33(11) . . ?
C1 Ru1 C11 117.39(13) . . ?
C1 Ru1 C13 123.33(13) . . ?
C1 Ru1 C3 63.82(13) . . ?
C1 Ru1 C12 109.79(13) . . ?
C1 Ru1 C14 151.08(13) . . ?
C1 Ru1 C15 142.41(12) . . ?
C1 Ru1 C15 171.80(12) . 2_755 ?
C2 Ru1 C5 63.77(13) . . ?
C2 Ru1 C11 108.33(14) . . ?
C2 Ru1 C13 158.52(15) . . ?
C2 Ru1 C3 38.21(16) . . ?
C2 Ru1 C12 126.95(16) . . ?
C2 Ru1 C14 164.32(15) . . ?
C2 Ru1 C1 38.26(13) . . ?
C2 Ru1 C15 112.64(12) . . ?
C2 Ru1 C15 133.74(12) . 2_755 ?
C15 Ru1 C15 34.81(14) . 2_755 ?
C67 C68 H68 118.9 . . ?
C69 C68 H68 118.9 . . ?
C69 C68 C67 122.1(3) . . ?
C94 C93 B2 120.8(2) . . ?
C98 C93 C94 115.0(2) . . ?
C98 C93 B2 124.2(2) . . ?
C113 C112 H112 118.8 . . ?
C113 C112 C111 122.3(3) . . ?
C111 C112 H112 118.8 . . ?
C68 C67 C72 115.2(3) . . ?
C68 C67 B1 124.5(2) . . ?
C72 C67 B1 120.1(2) . . ?
C115 C116 H116 118.7 . . ?
C115 C116 C111 122.6(3) . . ?
C111 C116 H116 118.7 . . ?
C93 C94 H94 118.5 . . ?
C95 C94 C93 122.9(3) . . ?
C95 C94 H94 118.5 . . ?
C73 C78 H78 118.5 . . ?
C77 C78 H78 118.5 . . ?
C77 C78 C73 123.0(3) . . ?
C35 C34 Ru3 70.54(16) . . ?
C35 C34 C33 107.7(3) . . ?
C35 C34 C39 127.4(3) . . ?
C33 C34 Ru3 71.54(16) . . ?
C33 C34 C39 124.9(3) . . ?
C39 C34 Ru3 125.0(2) . . ?
C116 C115 C124 117.0(3) . . ?
C114 C115 C116 120.9(3) . . ?
C114 C115 C124 122.0(3) . . ?
C78 C73 C74 114.9(3) . . ?
C78 C73 B1 121.3(2) . . ?
C74 C73 B1 123.8(2) . . ?
C93 C98 H98 118.7 . . ?
C97 C98 C93 122.6(3) . . ?
C97 C98 H98 118.7 . . ?
C104 C99 C100 115.4(3) . . ?
C104 C99 B2 122.3(3) . . ?
C100 C99 B2 122.3(2) . . ?
C112 C113 C123 118.3(3) . . ?
C114 C113 C112 121.1(3) . . ?
C114 C113 C123 120.6(3) . . ?
C98 C97 C118 118.6(3) . . ?
C96 C97 C98 121.1(3) . . ?
C96 C97 C118 120.3(3) . . ?
C67 C72 H72 118.6 . . ?
C71 C72 C67 122.8(3) . . ?
C71 C72 H72 118.6 . . ?
C72 C71 C88 117.1(3) . . ?
C70 C71 C72 120.8(3) . . ?
C70 C71 C88 121.9(3) . . ?
C112 C111 C116 115.4(2) . . ?
C112 C111 B2 124.5(2) . . ?
C116 C111 B2 120.1(2) . . ?
C105 C110 H110 118.8 . . ?
C109 C110 H110 118.8 . . ?
C109 C110 C105 122.3(3) . . ?
C99 C104 H104 119.0 . . ?
C103 C104 C99 122.1(3) . . ?
C103 C104 H104 119.0 . . ?
C80 C79 C84 115.1(3) . . ?
C80 C79 B1 122.3(2) . . ?
C84 C79 B1 122.5(2) . . ?
C68 C69 C87 118.6(3) . . ?
C70 C69 C68 121.1(3) . . ?
C70 C69 C87 120.3(3) . . ?
C71 C70 C69 117.9(3) . . ?
C71 C70 H70 121.0 . . ?
C69 C70 H70 121.0 . . ?
F28 C118 F30 105.2(2) . . ?
F28 C118 F29 107.9(3) . . ?
F28 C118 C97 113.4(3) . . ?
F30 C118 C97 112.4(2) . . ?
F29 C118 F30 104.8(3) . . ?
F29 C118 C97 112.6(2) . . ?
C115 C114 C113 117.7(3) . . ?
C115 C114 H114 121.1 . . ?
C113 C114 H114 121.1 . . ?
C110 C105 B2 121.0(2) . . ?
C106 C105 C110 115.9(3) . . ?
C106 C105 B2 123.0(3) . . ?
C17 C18 Ru2 70.41(17) . . ?
C17 C18 C19 107.6(3) . . ?
C17 C18 C23 126.6(3) . . ?
C19 C18 Ru2 70.16(16) . . ?
C19 C18 C23 125.8(3) . . ?
C23 C18 Ru2 124.0(2) . . ?
C74 C75 C76 121.1(3) . . ?
C74 C75 C89 119.2(3) . . ?
C76 C75 C89 119.7(3) . . ?
C61 C66 H66 118.9 . . ?
C65 C66 H66 118.9 . . ?
C65 C66 C61 122.2(3) . . ?
C16 C20 Ru2 71.04(16) . . ?
C16 C20 C19 107.7(3) . . ?
C16 C20 C25 126.2(3) . . ?
C19 C20 Ru2 70.50(16) . . ?
C19 C20 C25 125.9(3) . . ?
C25 C20 Ru2 127.5(2) . . ?
C66 C61 B1 121.3(2) . . ?
C62 C61 C66 116.2(3) . . ?
C62 C61 B1 122.4(3) . . ?
C94 C95 C96 120.6(3) . . ?
C94 C95 C117 118.4(3) . . ?
C96 C95 C117 121.0(3) . . ?
C66 C65 C86 120.4(3) . . ?
C64 C65 C66 120.6(3) . . ?
C64 C65 C86 119.0(3) . . ?
C61 C62 H62 119.1 . . ?
C63 C62 C61 121.8(3) . . ?
C63 C62 H62 119.1 . . ?
C73 C74 H74 118.8 . . ?
C75 C74 C73 122.5(3) . . ?
C75 C74 H74 118.8 . . ?
C80 C81 C91 119.6(3) . . ?
C82 C81 C80 121.4(3) . . ?
C82 C81 C91 119.0(3) . . ?
C110 C109 C108 120.6(3) . . ?
C110 C109 C120 120.2(3) . . ?
C108 C109 C120 119.1(3) . . ?
C79 C80 H80 118.9 . . ?
C81 C80 C79 122.2(3) . . ?
C81 C80 H80 118.9 . . ?
C65 C64 H64 120.9 . . ?
C63 C64 C65 118.2(3) . . ?
C63 C64 H64 120.9 . . ?
C109 C108 H108 120.9 . . ?
C107 C108 C109 118.1(3) . . ?
C107 C108 H108 120.9 . . ?
C105 C106 H106 119.0 . . ?
C105 C106 C107 121.9(3) . . ?
C107 C106 H106 119.0 . . ?
C108 C107 C106 121.1(3) . . ?
C108 C107 C119 119.7(3) . . ?
C106 C107 C119 119.2(3) . . ?
Ru3 C41 H41 119.0 . . ?
C45 C41 Ru3 79.55(17) . . ?
C45 C41 H41 119.0 . . ?
C42 C41 Ru3 70.16(17) . . ?
C42 C41 H41 119.0 . . ?
C42 C41 C45 122.0(3) . . ?
C47 C48 Ru4 70.53(17) . . ?
C47 C48 C53 126.1(3) . . ?
C49 C48 Ru4 70.13(17) . . ?
C49 C48 C47 108.1(3) . . ?
C49 C48 C53 125.9(3) . . ?
C53 C48 Ru4 125.9(2) . . ?
Ru2 C26 H26 119.1 . . ?
C30 C26 Ru2 79.43(16) . . ?
C30 C26 H26 119.1 . . ?
C27 C26 Ru2 70.19(16) . . ?
C27 C26 H26 119.1 . . ?
C27 C26 C30 121.6(3) . . ?
C20 C16 Ru2 70.73(17) . . ?
C20 C16 C17 107.8(3) . . ?
C20 C16 C21 125.7(3) . . ?
C17 C16 Ru2 70.43(17) . . ?
C17 C16 C21 126.3(3) . . ?
C21 C16 Ru2 128.0(2) . . ?
C100 C101 C121 120.7(3) . . ?
C102 C101 C100 120.8(3) . . ?
C102 C101 C121 118.5(3) . . ?
C79 C84 H84 118.7 . . ?
C83 C84 C79 122.7(3) . . ?
C83 C84 H84 118.7 . . ?
C99 C100 H100 118.8 . . ?
C101 C100 C99 122.4(3) . . ?
C101 C100 H100 118.8 . . ?
Ru3 C45 Ru3 145.27(13) . 2_566 ?
C41 C45 Ru3 64.77(15) . . ?
C41 C45 Ru3 134.9(2) . 2_566 ?
C41 C45 C45 118.1(3) . 2_566 ?
C45 C45 Ru3 72.9(2) 2_566 . ?
C45 C45 Ru3 72.4(2) 2_566 2_566 ?
C44 C45 Ru3 65.00(15) 2_566 2_566 ?
C44 C45 Ru3 135.7(2) 2_566 . ?
C44 C45 C41 122.8(3) 2_566 . ?
C44 C45 C45 119.2(3) 2_566 2_566 ?
C34 C35 Ru3 71.04(17) . . ?
C34 C35 C31 108.1(3) . . ?
C34 C35 C40 127.2(3) . . ?
C31 C35 Ru3 71.54(17) . . ?
C31 C35 C40 124.6(3) . . ?
C40 C35 Ru3 124.6(2) . . ?
C62 C63 C85 119.4(3) . . ?
C64 C63 C62 121.0(3) . . ?
C64 C63 C85 119.5(3) . . ?
C104 C103 C122 119.9(3) . . ?
C102 C103 C104 121.4(3) . . ?
C102 C103 C122 118.6(3) . . ?
Ru2 C30 Ru2 145.15(13) . 2_565 ?
C26 C30 Ru2 64.85(15) . . ?
C26 C30 Ru2 135.27(19) . 2_565 ?
C26 C30 C30 118.6(3) . 2_565 ?
C30 C30 Ru2 72.4(2) 2_565 2_565 ?
C30 C30 Ru2 72.8(2) 2_565 . ?
C29 C30 Ru2 65.10(16) 2_565 2_565 ?
C29 C30 Ru2 135.1(2) 2_565 . ?
C29 C30 C26 122.9(3) 2_565 . ?
C29 C30 C30 118.5(3) 2_565 2_565 ?
C18 C17 Ru2 71.60(17) . . ?
C18 C17 C16 108.6(3) . . ?
C18 C17 C22 126.4(3) . . ?
C16 C17 Ru2 71.18(17) . . ?
C16 C17 C22 124.9(3) . . ?
C22 C17 Ru2 125.4(2) . . ?
C18 C19 Ru2 71.48(16) . . ?
C18 C19 C24 125.8(3) . . ?
C20 C19 Ru2 71.08(16) . . ?
C20 C19 C18 108.3(3) . . ?
C20 C19 C24 125.8(3) . . ?
C24 C19 Ru2 126.3(2) . . ?
F40 C120 F42 105.5(3) . . ?
F40 C120 C109 112.6(2) . . ?
F41 C120 F40 105.5(2) . . ?
F41 C120 F42 106.3(3) . . ?
F41 C120 C109 113.0(3) . . ?
F42 C120 C109 113.2(2) . . ?
F11 C88 C71 111.1(2) . . ?
F12 C88 F11 105.9(3) . . ?
F12 C88 F10 107.0(2) . . ?
F12 C88 C71 113.0(2) . . ?
F10 C88 F11 105.8(2) . . ?
F10 C88 C71 113.5(3) . . ?
C35 C31 Ru3 69.88(17) . . ?
C35 C31 C36 125.4(3) . . ?
C32 C31 Ru3 71.17(17) . . ?
C32 C31 C35 107.5(3) . . ?
C32 C31 C36 126.9(3) . . ?
C36 C31 Ru3 127.5(2) . . ?
F47 C124 F48 105.0(3) . . ?
F47 C124 C115 112.7(2) . . ?
F48 C124 C115 111.3(2) . . ?
F46 C124 F47 107.2(2) . . ?
F46 C124 F48 106.4(2) . . ?
F46 C124 C115 113.7(3) . . ?
C48 C47 Ru4 71.44(17) . . ?
C48 C47 C46 108.1(3) . . ?
C48 C47 C52 125.6(3) . . ?
C46 C47 Ru4 70.48(17) . . ?
C46 C47 C52 126.3(3) . . ?
C52 C47 Ru4 125.0(2) . . ?
C84 C83 C92 120.6(3) . . ?
C82 C83 C84 120.9(3) . . ?
C82 C83 C92 118.5(3) . . ?
Ru2 C28 H28 119.7 . . ?
C29 C28 Ru2 72.92(17) . . ?
C29 C28 H28 119.7 . . ?
C29 C28 C27 119.9(3) . . ?
C27 C28 Ru2 71.09(17) . . ?
C27 C28 H28 119.7 . . ?
C101 C102 H102 121.1 . . ?
C103 C102 C101 117.8(3) . . ?
C103 C102 H102 121.1 . . ?
Ru2 C29 H29 119.3 . . ?
C30 C29 Ru2 79.31(17) 2_565 . ?
C30 C29 H29 119.3 2_565 . ?
C28 C29 Ru2 69.80(17) . . ?
C28 C29 C30 121.3(3) . 2_565 ?
C28 C29 H29 119.3 . . ?
C81 C82 C83 117.7(3) . . ?
C81 C82 H82 121.2 . . ?
C83 C82 H82 121.2 . . ?
C78 C77 C90 118.5(3) . . ?
C76 C77 C78 120.7(3) . . ?
C76 C77 C90 120.7(3) . . ?
F5 C86 C65 112.4(2) . . ?
F6 C86 F5 105.5(3) . . ?
F6 C86 C65 113.7(2) . . ?
F4 C86 F5 105.1(2) . . ?
F4 C86 F6 106.4(3) . . ?
F4 C86 C65 113.0(3) . . ?
Ru2 C27 H27 120.1 . . ?
C26 C27 Ru2 72.46(16) . . ?
C26 C27 C28 119.2(3) . . ?
C26 C27 H27 120.1 . . ?
C28 C27 Ru2 71.07(17) . . ?
C28 C27 H27 120.1 . . ?
C49 C50 Ru4 70.59(18) . . ?
C49 C50 C55 126.5(3) . . ?
C46 C50 Ru4 70.72(17) . . ?
C46 C50 C49 108.0(3) . . ?
C46 C50 C55 125.5(3) . . ?
C55 C50 Ru4 127.0(2) . . ?
Ru3 C44 H44 119.6 . . ?
C45 C44 Ru3 79.58(16) 2_566 . ?
C45 C44 H44 119.6 2_566 . ?
C43 C44 Ru3 69.81(16) . . ?
C43 C44 C45 120.8(3) . 2_566 ?
C43 C44 H44 119.6 . . ?
Ru4 C56 H56 119.3 . . ?
C57 C56 Ru4 70.18(19) . . ?
C57 C56 H56 119.3 . . ?
C57 C56 C60 121.3(3) . . ?
C60 C56 Ru4 79.60(18) . . ?
C60 C56 H56 119.3 . . ?
F20 C91 F19 106.0(3) . . ?
F20 C91 F21 106.6(3) . . ?
F20 C91 C81 113.2(3) . . ?
F19 C91 C81 111.9(3) . . ?
F21 C91 F19 106.1(2) . . ?
F21 C91 C81 112.5(3) . . ?
C75 C76 H76 121.1 . . ?
C77 C76 C75 117.8(3) . . ?
C77 C76 H76 121.1 . . ?
C34 C33 Ru3 70.12(16) . . ?
C34 C33 C38 125.2(3) . . ?
C32 C33 Ru3 71.09(17) . . ?
C32 C33 C34 108.1(3) . . ?
C32 C33 C38 126.7(3) . . ?
C38 C33 Ru3 126.5(2) . . ?
Ru3 C42 H42 120.1 . . ?
C41 C42 Ru3 72.50(17) . . ?
C41 C42 H42 120.1 . . ?
C41 C42 C43 119.1(3) . . ?
C43 C42 Ru3 71.25(16) . . ?
C43 C42 H42 120.1 . . ?
C48 C49 Ru4 71.96(18) . . ?
C48 C49 C50 108.1(3) . . ?
C48 C49 C54 125.2(3) . . ?
C50 C49 Ru4 71.02(18) . . ?
C50 C49 C54 126.6(3) . . ?
C54 C49 Ru4 125.6(2) . . ?
C97 C96 C95 117.8(3) . . ?
C97 C96 H96 121.1 . . ?
C95 C96 H96 121.1 . . ?
Ru4 C59 H59 119.1 . . ?
C58 C59 Ru4 70.39(19) . . ?
C58 C59 H59 119.1 . . ?
C58 C59 C60 121.8(3) . 2_556 ?
C60 C59 Ru4 79.94(18) 2_556 . ?
C60 C59 H59 119.1 2_556 . ?
F35 C122 F36 105.4(3) . . ?
F35 C122 C103 113.1(3) . . ?
F36 C122 C103 111.5(3) . . ?
F34 C122 F35 106.7(3) . . ?
F34 C122 F36 106.7(3) . . ?
F34 C122 C103 112.9(3) . . ?
C4 C5 Ru1 70.41(18) . . ?
C4 C5 C10 126.2(3) . . ?
C1 C5 Ru1 70.94(18) . . ?
C1 C5 C4 107.9(3) . . ?
C1 C5 C10 125.7(3) . . ?
C10 C5 Ru1 127.3(2) . . ?
C47 C46 Ru4 71.21(17) . . ?
C47 C46 C51 126.1(3) . . ?
C50 C46 Ru4 70.98(17) . . ?
C50 C46 C47 107.7(3) . . ?
C50 C46 C51 126.1(3) . . ?
C51 C46 Ru4 126.5(2) . . ?
Ru1 C11 H11 119.4 . . ?
C12 C11 Ru1 70.23(19) . . ?
C12 C11 H11 119.4 . . ?
C12 C11 C15 121.2(3) . . ?
C15 C11 Ru1 79.32(19) . . ?
C15 C11 H11 119.4 . . ?
F8 C87 F7 106.8(3) . . ?
F8 C87 C69 113.4(3) . . ?
F9 C87 F8 105.6(3) . . ?
F9 C87 F7 105.0(3) . . ?
F9 C87 C69 112.9(3) . . ?
F7 C87 C69 112.3(3) . . ?
Ru1 C13 H13 119.8 . . ?
C12 C13 Ru1 71.46(19) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 Ru1 72.55(19) . . ?
C14 C13 H13 119.8 . . ?
C14 C13 C12 119.7(3) . . ?
C31 C32 Ru3 70.88(17) . . ?
C31 C32 C37 125.9(3) . . ?
C33 C32 Ru3 71.06(17) . . ?
C33 C32 C31 108.6(3) . . ?
C33 C32 C37 125.4(3) . . ?
C37 C32 Ru3 126.9(2) . . ?
Ru3 C43 H43 119.7 . . ?
C44 C43 Ru3 72.75(16) . . ?
C44 C43 H43 119.7 . . ?
C42 C43 Ru3 71.05(16) . . ?
C42 C43 C44 119.9(3) . . ?
C42 C43 H43 119.7 . . ?
Ru4 C57 H57 119.9 . . ?
C56 C57 Ru4 72.47(18) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 Ru4 71.09(19) . . ?
C58 C57 C56 119.5(3) . . ?
C58 C57 H57 119.9 . . ?
F3 C85 F1 104.6(3) . . ?
F3 C85 C63 112.4(3) . . ?
F1 C85 C63 112.0(3) . . ?
F2 C85 F3 106.8(3) . . ?
F2 C85 F1 106.6(3) . . ?
F2 C85 C63 113.8(3) . . ?
C5 C4 Ru1 71.22(18) . . ?
C5 C4 C9 125.6(4) . . ?
C3 C4 Ru1 71.9(2) . . ?
C3 C4 C5 108.3(3) . . ?
C3 C4 C9 126.0(4) . . ?
C9 C4 Ru1 124.7(3) . . ?
F15 C89 F13 104.6(3) . . ?
F15 C89 C75 113.3(3) . . ?
F13 C89 C75 111.8(3) . . ?
F14 C89 F15 106.9(3) . . ?
F14 C89 F13 106.7(3) . . ?
F14 C89 C75 113.0(3) . . ?
F31 C121 F33 105.8(3) . . ?
F31 C121 F32 105.7(3) . . ?
F31 C121 C101 112.7(3) . . ?
F33 C121 F32 106.3(3) . . ?
F33 C121 C101 113.2(3) . . ?
F32 C121 C101 112.5(3) . . ?
C4 C3 Ru1 70.5(2) . . ?
C4 C3 C2 108.3(3) . . ?
C4 C3 C8 125.5(4) . . ?
C2 C3 Ru1 70.5(2) . . ?
C2 C3 C8 126.2(4) . . ?
C8 C3 Ru1 125.1(3) . . ?
Ru1 C12 H12 119.8 . . ?
C11 C12 Ru1 72.49(19) . . ?
C11 C12 C13 119.6(3) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 Ru1 70.88(19) . . ?
C13 C12 H12 119.8 . . ?
Ru1 C14 H14 119.1 . . ?
C13 C14 Ru1 70.37(19) . . ?
C13 C14 H14 119.1 . . ?
C13 C14 C15 121.7(3) . 2_755 ?
C15 C14 Ru1 79.63(18) 2_755 . ?
C15 C14 H14 119.1 2_755 . ?
C5 C1 Ru1 70.94(18) . . ?
C5 C1 C2 107.6(3) . . ?
C5 C1 C6 125.9(3) . . ?
C2 C1 Ru1 70.76(18) . . ?
C2 C1 C6 126.3(4) . . ?
C6 C1 Ru1 127.4(3) . . ?
F27 C117 C95 112.0(3) . . ?
F26 C117 F27 104.6(3) . . ?
F26 C117 C95 112.6(3) . . ?
F25 C117 F27 106.7(3) . . ?
F25 C117 F26 106.7(3) . . ?
F25 C117 C95 113.6(3) . . ?
Ru4 C58 H58 119.8 . . ?
C59 C58 Ru4 72.57(18) . . ?
C59 C58 C57 119.8(3) . . ?
C59 C58 H58 119.8 . . ?
C57 C58 Ru4 71.32(19) . . ?
C57 C58 H58 119.8 . . ?
F44 C123 F43 104.9(3) . . ?
F44 C123 F45 108.6(3) . . ?
F44 C123 C113 114.1(3) . . ?
F43 C123 C113 112.4(3) . . ?
F45 C123 F43 102.9(3) . . ?
F45 C123 C113 113.1(3) . . ?
F39 C119 C107 112.2(3) . . ?
F37 C119 F39 105.0(3) . . ?
F37 C119 C107 111.9(3) . . ?
F38 C119 F39 106.8(3) . . ?
F38 C119 F37 106.6(3) . . ?
F38 C119 C107 113.8(3) . . ?
Ru4 C60 Ru4 145.15(14) . 2_556 ?
C56 C60 Ru4 64.84(17) . . ?
C56 C60 Ru4 135.2(2) . 2_556 ?
C56 C60 C59 123.4(3) . 2_556 ?
C56 C60 C60 118.5(4) . 2_556 ?
C59 C60 Ru4 64.46(17) 2_556 2_556 ?
C59 C60 Ru4 135.6(2) 2_556 . ?
C59 C60 C60 118.1(4) 2_556 2_556 ?
C60 C60 Ru4 72.4(2) 2_556 2_556 ?
C60 C60 Ru4 72.8(2) 2_556 . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C3 C2 Ru1 71.3(2) . . ?
C3 C2 C7 125.9(4) . . ?
C1 C2 Ru1 70.97(18) . . ?
C1 C2 C3 107.8(3) . . ?
C1 C2 C7 126.3(4) . . ?
C7 C2 Ru1 125.5(3) . . ?
F16 C90 C77 112.4(3) . . ?
F18 C90 F16 106.9(3) . . ?
F18 C90 F17 106.2(3) . . ?
F18 C90 C77 113.9(3) . . ?
F17 C90 F16 104.1(3) . . ?
F17 C90 C77 112.7(3) . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Ru1 C15 Ru1 145.18(14) . 2_755 ?
C11 C15 Ru1 65.11(17) . . ?
C11 C15 Ru1 135.1(2) . 2_755 ?
C11 C15 C14 123.1(3) . 2_755 ?
C11 C15 C15 118.7(4) . 2_755 ?
C14 C15 Ru1 64.59(17) 2_755 2_755 ?
C14 C15 Ru1 135.4(2) 2_755 . ?
C14 C15 C15 118.2(4) 2_755 2_755 ?
C15 C15 Ru1 72.5(2) 2_755 2_755 ?
C15 C15 Ru1 72.7(2) 2_755 . ?
F24 C92 C83 113.7(3) . . ?
F22 C92 F24 106.3(3) . . ?
F22 C92 C83 112.6(3) . . ?
F23 C92 F24 104.5(3) . . ?
F23 C92 F22 105.9(3) . . ?
F23 C92 C83 113.1(3) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C50 C55 H55A 109.5 . . ?
C50 C55 H55B 109.5 . . ?
C50 C55 H55C 109.5 . . ?
H55A C55 H55B 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C67 B1 C73 111.4(2) . . ?
C67 B1 C79 108.3(2) . . ?
C67 B1 C61 109.5(2) . . ?
C73 B1 C79 110.1(2) . . ?
C73 B1 C61 108.9(2) . . ?
C61 B1 C79 108.6(2) . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C93 B2 C99 110.1(2) . . ?
C111 B2 C93 110.9(2) . . ?
C111 B2 C99 108.5(2) . . ?
C105 B2 C93 109.1(2) . . ?
C105 B2 C99 109.7(2) . . ?
C105 B2 C111 108.6(2) . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru2 C18 C17 C16 -61.9(2) . . . . ?
Ru2 C18 C17 C22 120.9(3) . . . . ?
Ru2 C18 C19 C20 61.9(2) . . . . ?
Ru2 C18 C19 C24 -121.8(3) . . . . ?
Ru2 C20 C16 C17 61.0(2) . . . . ?
Ru2 C20 C16 C21 -123.5(3) . . . . ?
Ru2 C20 C19 C18 -62.2(2) . . . . ?
Ru2 C20 C19 C24 121.6(3) . . . . ?
Ru2 C26 C30 Ru2 -144.5(2) . . . 2_565 ?
Ru2 C26 C30 C30 -51.1(3) . . . 2_565 ?
Ru2 C26 C30 C29 128.9(3) . . . 2_565 ?
Ru2 C26 C27 C28 55.5(2) . . . . ?
Ru2 C16 C17 C18 62.2(2) . . . . ?
Ru2 C16 C17 C22 -120.5(3) . . . . ?
Ru2 C28 C29 C30 62.9(3) . . . 2_565 ?
Ru2 C28 C27 C26 -56.2(2) . . . . ?
Ru3 C34 C35 C31 -62.3(2) . . . . ?
Ru3 C34 C35 C40 119.6(3) . . . . ?
Ru3 C34 C33 C32 61.3(2) . . . . ?
Ru3 C34 C33 C38 -121.3(3) . . . . ?
Ru3 C41 C45 Ru3 144.4(2) . . . 2_566 ?
Ru3 C41 C45 C45 51.7(3) . . . 2_566 ?
Ru3 C41 C45 C44 -129.6(3) . . . 2_566 ?
Ru3 C41 C42 C43 -55.8(2) . . . . ?
Ru3 C35 C31 C32 -61.6(2) . . . . ?
Ru3 C35 C31 C36 122.4(3) . . . . ?
Ru3 C31 C32 C33 -61.4(2) . . . . ?
Ru3 C31 C32 C37 122.3(3) . . . . ?
Ru3 C44 C43 C42 55.2(2) . . . . ?
Ru3 C33 C32 C31 61.3(2) . . . . ?
Ru3 C33 C32 C37 -122.4(3) . . . . ?
Ru3 C42 C43 C44 -56.0(2) . . . . ?
Ru4 C48 C47 C46 61.3(2) . . . . ?
Ru4 C48 C47 C52 -120.2(3) . . . . ?
Ru4 C48 C49 C50 -62.2(2) . . . . ?
Ru4 C48 C49 C54 121.3(3) . . . . ?
Ru4 C47 C46 C50 62.0(2) . . . . ?
Ru4 C47 C46 C51 -121.9(3) . . . . ?
Ru4 C50 C49 C48 62.8(2) . . . . ?
Ru4 C50 C49 C54 -120.8(3) . . . . ?
Ru4 C50 C46 C47 -62.1(2) . . . . ?
Ru4 C50 C46 C51 121.8(3) . . . . ?
Ru4 C56 C57 C58 -55.3(3) . . . . ?
Ru4 C56 C60 Ru4 144.5(3) . . . 2_556 ?
Ru4 C56 C60 C59 -129.4(3) . . . 2_556 ?
Ru4 C56 C60 C60 51.1(3) . . . 2_556 ?
Ru4 C59 C58 C57 55.5(3) . . . . ?
Ru4 C57 C58 C59 -56.1(3) . . . . ?
Ru1 C5 C4 C3 -62.7(2) . . . . ?
Ru1 C5 C4 C9 119.8(4) . . . . ?
Ru1 C5 C1 C2 61.6(2) . . . . ?
Ru1 C5 C1 C6 -122.8(4) . . . . ?
Ru1 C11 C12 C13 54.9(3) . . . . ?
Ru1 C11 C15 Ru1 -144.7(3) . . . 2_755 ?
Ru1 C11 C15 C14 129.4(3) . . . 2_755 ?
Ru1 C11 C15 C15 -51.1(3) . . . 2_755 ?
Ru1 C13 C12 C11 -55.7(3) . . . . ?
Ru1 C13 C14 C15 63.6(3) . . . 2_755 ?
Ru1 C4 C3 C2 -60.7(2) . . . . ?
Ru1 C4 C3 C8 119.8(4) . . . . ?
Ru1 C3 C2 C1 -61.9(2) . . . . ?
Ru1 C3 C2 C7 120.7(4) . . . . ?
Ru1 C1 C2 C3 62.1(2) . . . . ?
Ru1 C1 C2 C7 -120.5(4) . . . . ?
C68 C67 C72 C71 -2.2(4) . . . . ?
C68 C67 B1 C73 -112.3(3) . . . . ?
C68 C67 B1 C79 126.4(3) . . . . ?
C68 C67 B1 C61 8.2(4) . . . . ?
C68 C69 C70 C71 -1.7(4) . . . . ?
C68 C69 C87 F8 162.5(3) . . . . ?
C68 C69 C87 F9 42.3(4) . . . . ?
C68 C69 C87 F7 -76.3(4) . . . . ?
C93 C94 C95 C96 0.2(4) . . . . ?
C93 C94 C95 C117 -178.3(3) . . . . ?
C93 C98 C97 C118 179.2(3) . . . . ?
C93 C98 C97 C96 1.1(4) . . . . ?
C112 C113 C114 C115 1.1(4) . . . . ?
C112 C113 C123 F44 -168.3(3) . . . . ?
C112 C113 C123 F43 -49.0(4) . . . . ?
C112 C113 C123 F45 66.9(4) . . . . ?
C112 C111 B2 C93 110.5(3) . . . . ?
C112 C111 B2 C99 -128.5(3) . . . . ?
C112 C111 B2 C105 -9.4(4) . . . . ?
C67 C68 C69 C70 1.9(4) . . . . ?
C67 C68 C69 C87 178.5(3) . . . . ?
C67 C72 C71 C70 2.4(4) . . . . ?
C67 C72 C71 C88 -173.6(3) . . . . ?
C116 C115 C114 C113 -0.1(4) . . . . ?
C116 C115 C124 F47 54.1(3) . . . . ?
C116 C115 C124 F48 -63.6(3) . . . . ?
C116 C115 C124 F46 176.3(3) . . . . ?
C116 C111 B2 C93 -72.0(3) . . . . ?
C116 C111 B2 C99 49.0(3) . . . . ?
C116 C111 B2 C105 168.1(2) . . . . ?
C94 C93 C98 C97 -1.1(4) . . . . ?
C94 C93 B2 C99 80.1(3) . . . . ?
C94 C93 B2 C111 -159.8(2) . . . . ?
C94 C93 B2 C105 -40.3(3) . . . . ?
C94 C95 C96 C97 -0.2(4) . . . . ?
C94 C95 C117 F27 53.5(4) . . . . ?
C94 C95 C117 F26 -64.1(4) . . . . ?
C94 C95 C117 F25 174.4(3) . . . . ?
C78 C73 C74 C75 1.0(4) . . . . ?
C78 C73 B1 C67 163.0(2) . . . . ?
C78 C73 B1 C79 -76.8(3) . . . . ?
C78 C73 B1 C61 42.1(3) . . . . ?
C78 C77 C76 C75 -0.3(5) . . . . ?
C78 C77 C90 F16 -51.1(4) . . . . ?
C78 C77 C90 F18 -172.8(3) . . . . ?
C78 C77 C90 F17 66.2(4) . . . . ?
C34 C35 C31 Ru3 62.0(2) . . . . ?
C34 C35 C31 C32 0.4(3) . . . . ?
C34 C35 C31 C36 -175.6(3) . . . . ?
C34 C33 C32 Ru3 -60.6(2) . . . . ?
C34 C33 C32 C31 0.6(3) . . . . ?
C34 C33 C32 C37 177.0(3) . . . . ?
C115 C116 C111 C112 0.9(4) . . . . ?
C115 C116 C111 B2 -176.8(3) . . . . ?
C73 C78 C77 C76 0.9(5) . . . . ?
C73 C78 C77 C90 179.7(3) . . . . ?
C98 C93 C94 C95 0.4(4) . . . . ?
C98 C93 B2 C99 -100.6(3) . . . . ?
C98 C93 B2 C111 19.5(4) . . . . ?
C98 C93 B2 C105 139.0(3) . . . . ?
C98 C97 C118 F28 168.5(3) . . . . ?
C98 C97 C118 F30 49.4(4) . . . . ?
C98 C97 C118 F29 -68.6(4) . . . . ?
C98 C97 C96 C95 -0.4(4) . . . . ?
C99 C104 C103 C102 -0.3(4) . . . . ?
C99 C104 C103 C122 175.8(3) . . . . ?
C113 C112 C111 C116 0.0(4) . . . . ?
C113 C112 C111 B2 177.6(3) . . . . ?
C72 C67 B1 C73 72.6(3) . . . . ?
C72 C67 B1 C79 -48.7(3) . . . . ?
C72 C67 B1 C61 -166.9(2) . . . . ?
C72 C71 C70 C69 -0.4(4) . . . . ?
C72 C71 C88 F11 68.4(3) . . . . ?
C72 C71 C88 F12 -50.5(4) . . . . ?
C72 C71 C88 F10 -172.5(3) . . . . ?
C111 C112 C113 C114 -1.0(5) . . . . ?
C111 C112 C113 C123 -178.9(3) . . . . ?
C111 C116 C115 C114 -0.9(4) . . . . ?
C111 C116 C115 C124 175.5(3) . . . . ?
C110 C105 C106 C107 -1.0(4) . . . . ?
C110 C105 B2 C93 -36.4(3) . . . . ?
C110 C105 B2 C99 -157.1(2) . . . . ?
C110 C105 B2 C111 84.5(3) . . . . ?
C110 C109 C108 C107 -0.8(4) . . . . ?
C110 C109 C120 F40 105.8(3) . . . . ?
C110 C109 C120 F41 -134.7(3) . . . . ?
C110 C109 C120 F42 -13.7(4) . . . . ?
C104 C99 C100 C101 3.3(4) . . . . ?
C104 C99 B2 C93 -36.9(3) . . . . ?
C104 C99 B2 C111 -158.4(2) . . . . ?
C104 C99 B2 C105 83.2(3) . . . . ?
C104 C103 C102 C101 2.0(4) . . . . ?
C104 C103 C122 F35 31.6(4) . . . . ?
C104 C103 C122 F36 -87.0(3) . . . . ?
C104 C103 C122 F34 152.9(3) . . . . ?
C79 C84 C83 C82 1.5(5) . . . . ?
C79 C84 C83 C92 -177.7(3) . . . . ?
C69 C68 C67 C72 0.0(4) . . . . ?
C69 C68 C67 B1 -175.3(3) . . . . ?
C70 C71 C88 F11 -107.6(3) . . . . ?
C70 C71 C88 F12 133.5(3) . . . . ?
C70 C71 C88 F10 11.5(4) . . . . ?
C70 C69 C87 F8 -20.9(4) . . . . ?
C70 C69 C87 F9 -141.1(3) . . . . ?
C70 C69 C87 F7 100.3(3) . . . . ?
C118 C97 C96 C95 -178.4(3) . . . . ?
C114 C115 C124 F47 -129.6(3) . . . . ?
C114 C115 C124 F48 112.7(3) . . . . ?
C114 C115 C124 F46 -7.4(4) . . . . ?
C114 C113 C123 F44 13.8(5) . . . . ?
C114 C113 C123 F43 133.0(3) . . . . ?
C114 C113 C123 F45 -111.0(4) . . . . ?
C105 C110 C109 C108 0.6(4) . . . . ?
C105 C110 C109 C120 -176.9(3) . . . . ?
C105 C106 C107 C108 0.9(4) . . . . ?
C105 C106 C107 C119 177.5(3) . . . . ?
C66 C61 C62 C63 0.3(4) . . . . ?
C66 C61 B1 C67 -87.1(3) . . . . ?
C66 C61 B1 C73 35.0(3) . . . . ?
C66 C61 B1 C79 154.9(2) . . . . ?
C66 C65 C64 C63 1.1(4) . . . . ?
C66 C65 C86 F5 -106.3(3) . . . . ?
C66 C65 C86 F6 13.5(4) . . . . ?
C66 C65 C86 F4 134.9(3) . . . . ?
C20 C16 C17 Ru2 -61.2(2) . . . . ?
C20 C16 C17 C18 1.0(3) . . . . ?
C20 C16 C17 C22 178.2(3) . . . . ?
C61 C66 C65 C64 -1.4(4) . . . . ?
C61 C66 C65 C86 176.3(3) . . . . ?
C61 C62 C63 C64 -0.6(4) . . . . ?
C61 C62 C63 C85 -176.9(3) . . . . ?
C65 C66 C61 C62 0.7(4) . . . . ?
C65 C66 C61 B1 178.8(3) . . . . ?
C65 C64 C63 C62 -0.1(4) . . . . ?
C65 C64 C63 C85 176.2(3) . . . . ?
C62 C61 B1 C67 90.9(3) . . . . ?
C62 C61 B1 C73 -147.0(3) . . . . ?
C62 C61 B1 C79 -27.1(4) . . . . ?
C62 C63 C85 F3 -152.8(3) . . . . ?
C62 C63 C85 F1 89.7(4) . . . . ?
C62 C63 C85 F2 -31.3(4) . . . . ?
C74 C73 B1 C67 -16.2(4) . . . . ?
C74 C73 B1 C79 104.0(3) . . . . ?
C74 C73 B1 C61 -137.0(3) . . . . ?
C74 C75 C76 C77 0.2(4) . . . . ?
C74 C75 C89 F15 -158.6(3) . . . . ?
C74 C75 C89 F13 -40.7(4) . . . . ?
C74 C75 C89 F14 79.7(4) . . . . ?
C109 C110 C105 C106 0.3(4) . . . . ?
C109 C110 C105 B2 -176.5(3) . . . . ?
C109 C108 C107 C106 0.1(4) . . . . ?
C109 C108 C107 C119 -176.5(3) . . . . ?
C80 C79 C84 C83 -3.1(4) . . . . ?
C80 C79 B1 C67 164.1(2) . . . . ?
C80 C79 B1 C73 42.0(3) . . . . ?
C80 C79 B1 C61 -77.1(3) . . . . ?
C80 C81 C82 C83 -2.9(4) . . . . ?
C80 C81 C91 F20 -31.0(4) . . . . ?
C80 C81 C91 F19 88.7(3) . . . . ?
C80 C81 C91 F21 -151.9(3) . . . . ?
C64 C65 C86 F5 71.5(4) . . . . ?
C64 C65 C86 F6 -168.7(3) . . . . ?
C64 C65 C86 F4 -47.3(4) . . . . ?
C64 C63 C85 F3 30.8(4) . . . . ?
C64 C63 C85 F1 -86.6(4) . . . . ?
C64 C63 C85 F2 152.4(3) . . . . ?
C108 C109 C120 F40 -71.7(4) . . . . ?
C108 C109 C120 F41 47.8(4) . . . . ?
C108 C109 C120 F42 168.7(3) . . . . ?
C108 C107 C119 F39 -30.1(4) . . . . ?
C108 C107 C119 F37 87.6(4) . . . . ?
C108 C107 C119 F38 -151.5(3) . . . . ?
C106 C105 B2 C93 147.1(3) . . . . ?
C106 C105 B2 C99 26.4(4) . . . . ?
C106 C105 B2 C111 -92.0(3) . . . . ?
C106 C107 C119 F39 153.2(3) . . . . ?
C106 C107 C119 F37 -89.1(3) . . . . ?
C106 C107 C119 F38 31.8(4) . . . . ?
C41 C42 C43 Ru3 56.4(2) . . . . ?
C41 C42 C43 C44 0.4(4) . . . . ?
C48 C47 C46 Ru4 -61.9(2) . . . . ?
C48 C47 C46 C50 0.1(3) . . . . ?
C48 C47 C46 C51 176.2(3) . . . . ?
C16 C20 C19 Ru2 61.6(2) . . . . ?
C16 C20 C19 C18 -0.5(3) . . . . ?
C16 C20 C19 C24 -176.8(3) . . . . ?
C84 C79 C80 C81 1.8(4) . . . . ?
C84 C79 B1 C67 -18.3(3) . . . . ?
C84 C79 B1 C73 -140.4(3) . . . . ?
C84 C79 B1 C61 100.5(3) . . . . ?
C84 C83 C82 C81 1.6(4) . . . . ?
C84 C83 C92 F24 -1.7(5) . . . . ?
C84 C83 C92 F22 -122.6(4) . . . . ?
C84 C83 C92 F23 117.3(4) . . . . ?
C100 C99 C104 C103 -2.3(4) . . . . ?
C100 C99 B2 C93 144.9(3) . . . . ?
C100 C99 B2 C111 23.4(3) . . . . ?
C100 C99 B2 C105 -95.1(3) . . . . ?
C100 C101 C102 C103 -1.0(4) . . . . ?
C100 C101 C121 F31 -131.1(3) . . . . ?
C100 C101 C121 F33 -11.0(4) . . . . ?
C100 C101 C121 F32 109.6(3) . . . . ?
C45 C41 C42 Ru3 63.1(3) . . . . ?
C45 C41 C42 C43 7.3(4) . . . . ?
C45 C44 C43 Ru3 -63.7(2) 2_566 . . . ?
C45 C44 C43 C42 -8.5(4) 2_566 . . . ?
C35 C34 C33 Ru3 -61.6(2) . . . . ?
C35 C34 C33 C32 -0.4(3) . . . . ?
C35 C34 C33 C38 177.1(3) . . . . ?
C35 C31 C32 Ru3 60.7(2) . . . . ?
C35 C31 C32 C33 -0.7(3) . . . . ?
C35 C31 C32 C37 -177.0(3) . . . . ?
C30 C26 C27 Ru2 -63.2(2) . . . . ?
C30 C26 C27 C28 -7.7(4) . . . . ?
C17 C18 C19 Ru2 -60.8(2) . . . . ?
C17 C18 C19 C20 1.1(3) . . . . ?
C17 C18 C19 C24 177.4(3) . . . . ?
C19 C18 C17 Ru2 60.6(2) . . . . ?
C19 C18 C17 C16 -1.3(3) . . . . ?
C19 C18 C17 C22 -178.5(3) . . . . ?
C19 C20 C16 Ru2 -61.3(2) . . . . ?
C19 C20 C16 C17 -0.3(3) . . . . ?
C19 C20 C16 C21 175.2(3) . . . . ?
C120 C109 C108 C107 176.7(3) . . . . ?
C88 C71 C70 C69 175.5(3) . . . . ?
C124 C115 C114 C113 -176.3(3) . . . . ?
C47 C48 C49 Ru4 60.6(2) . . . . ?
C47 C48 C49 C50 -1.6(4) . . . . ?
C47 C48 C49 C54 -178.1(3) . . . . ?
C102 C101 C100 C99 -1.7(4) . . . . ?
C102 C101 C121 F31 49.5(4) . . . . ?
C102 C101 C121 F33 169.6(3) . . . . ?
C102 C101 C121 F32 -69.9(4) . . . . ?
C102 C103 C122 F35 -152.2(3) . . . . ?
C102 C103 C122 F36 89.2(4) . . . . ?
C102 C103 C122 F34 -30.9(4) . . . . ?
C29 C28 C27 Ru2 56.3(2) . . . . ?
C29 C28 C27 C26 0.1(4) . . . . ?
C82 C81 C80 C79 1.2(4) . . . . ?
C82 C81 C91 F20 152.0(3) . . . . ?
C82 C81 C91 F19 -88.3(4) . . . . ?
C82 C81 C91 F21 31.1(4) . . . . ?
C82 C83 C92 F24 179.1(3) . . . . ?
C82 C83 C92 F22 58.2(5) . . . . ?
C82 C83 C92 F23 -61.8(4) . . . . ?
C77 C78 C73 C74 -1.2(4) . . . . ?
C77 C78 C73 B1 179.6(3) . . . . ?
C86 C65 C64 C63 -176.7(3) . . . . ?
C27 C26 C30 Ru2 -85.8(4) . . . 2_565 ?
C27 C26 C30 Ru2 58.7(2) . . . . ?
C27 C26 C30 C30 7.6(5) . . . 2_565 ?
C27 C26 C30 C29 -172.4(3) . . . 2_565 ?
C27 C28 C29 Ru2 -55.4(2) . . . . ?
C27 C28 C29 C30 7.5(4) . . . 2_565 ?
C56 C57 C58 Ru4 56.0(3) . . . . ?
C56 C57 C58 C59 -0.1(5) . . . . ?
C91 C81 C80 C79 -175.8(3) . . . . ?
C91 C81 C82 C83 174.0(3) . . . . ?
C76 C75 C74 C73 -0.5(4) . . . . ?
C76 C75 C89 F15 24.3(4) . . . . ?
C76 C75 C89 F13 142.2(3) . . . . ?
C76 C75 C89 F14 -97.4(4) . . . . ?
C76 C77 C90 F16 127.7(3) . . . . ?
C76 C77 C90 F18 6.0(5) . . . . ?
C76 C77 C90 F17 -115.0(4) . . . . ?
C33 C34 C35 Ru3 62.3(2) . . . . ?
C33 C34 C35 C31 0.0(3) . . . . ?
C33 C34 C35 C40 -178.1(3) . . . . ?
C42 C41 C45 Ru3 85.8(4) . . . 2_566 ?
C42 C41 C45 Ru3 -58.5(2) . . . . ?
C42 C41 C45 C45 -6.8(5) . . . 2_566 ?
C42 C41 C45 C44 171.9(3) . . . 2_566 ?
C49 C48 C47 Ru4 -60.4(2) . . . . ?
C49 C48 C47 C46 0.9(4) . . . . ?
C49 C48 C47 C52 179.4(3) . . . . ?
C49 C50 C46 Ru4 61.1(2) . . . . ?
C49 C50 C46 C47 -1.1(3) . . . . ?
C49 C50 C46 C51 -177.2(3) . . . . ?
C96 C97 C118 F28 -13.4(4) . . . . ?
C96 C97 C118 F30 -132.5(3) . . . . ?
C96 C97 C118 F29 109.5(3) . . . . ?
C96 C95 C117 F27 -125.0(3) . . . . ?
C96 C95 C117 F26 117.4(3) . . . . ?
C96 C95 C117 F25 -4.1(5) . . . . ?
C122 C103 C102 C101 -174.1(3) . . . . ?
C5 C4 C3 Ru1 62.3(2) . . . . ?
C5 C4 C3 C2 1.6(4) . . . . ?
C5 C4 C3 C8 -177.9(3) . . . . ?
C5 C1 C2 Ru1 -61.7(2) . . . . ?
C5 C1 C2 C3 0.4(4) . . . . ?
C5 C1 C2 C7 177.7(4) . . . . ?
C46 C50 C49 Ru4 -61.2(2) . . . . ?
C46 C50 C49 C48 1.6(4) . . . . ?
C46 C50 C49 C54 178.1(3) . . . . ?
C87 C69 C70 C71 -178.2(3) . . . . ?
C57 C56 C60 Ru4 -59.0(3) . . . . ?
C57 C56 C60 Ru4 85.5(4) . . . 2_556 ?
C57 C56 C60 C59 171.6(3) . . . 2_556 ?
C57 C56 C60 C60 -7.9(5) . . . 2_556 ?
C4 C5 C1 Ru1 -61.0(2) . . . . ?
C4 C5 C1 C2 0.6(4) . . . . ?
C4 C5 C1 C6 176.1(3) . . . . ?
C4 C3 C2 Ru1 60.7(2) . . . . ?
C4 C3 C2 C1 -1.3(4) . . . . ?
C4 C3 C2 C7 -178.6(4) . . . . ?
C89 C75 C74 C73 -177.5(3) . . . . ?
C89 C75 C76 C77 177.1(3) . . . . ?
C121 C101 C100 C99 178.9(3) . . . . ?
C121 C101 C102 C103 178.4(3) . . . . ?
C12 C11 C15 Ru1 58.9(3) . . . . ?
C12 C11 C15 Ru1 -85.8(4) . . . 2_755 ?
C12 C11 C15 C14 -171.7(3) . . . 2_755 ?
C12 C11 C15 C15 7.8(5) . . . 2_755 ?
C12 C13 C14 Ru1 -55.8(3) . . . . ?
C12 C13 C14 C15 7.8(5) . . . 2_755 ?
C14 C13 C12 Ru1 56.3(3) . . . . ?
C14 C13 C12 C11 0.6(5) . . . . ?
C1 C5 C4 Ru1 61.3(2) . . . . ?
C1 C5 C4 C3 -1.4(4) . . . . ?
C1 C5 C4 C9 -178.9(3) . . . . ?
C117 C95 C96 C97 178.3(3) . . . . ?
C123 C113 C114 C115 178.9(3) . . . . ?
C60 C56 C57 Ru4 63.6(3) . . . . ?
C60 C56 C57 C58 8.3(5) . . . . ?
C60 C59 C58 Ru4 -64.0(3) 2_556 . . . ?
C60 C59 C58 C57 -8.4(5) 2_556 . . . ?
C39 C34 C35 Ru3 -119.8(3) . . . . ?
C39 C34 C35 C31 177.9(3) . . . . ?
C39 C34 C35 C40 -0.2(5) . . . . ?
C39 C34 C33 Ru3 120.3(3) . . . . ?
C39 C34 C33 C32 -178.4(3) . . . . ?
C39 C34 C33 C38 -0.9(5) . . . . ?
C90 C77 C76 C75 -179.2(3) . . . . ?
C15 C11 C12 Ru1 -63.4(3) . . . . ?
C15 C11 C12 C13 -8.5(5) . . . . ?
C92 C83 C82 C81 -179.2(3) . . . . ?
C21 C16 C17 Ru2 123.3(3) . . . . ?
C21 C16 C17 C18 -174.5(3) . . . . ?
C21 C16 C17 C22 2.8(5) . . . . ?
C52 C47 C46 Ru4 119.6(3) . . . . ?
C52 C47 C46 C50 -178.4(3) . . . . ?
C52 C47 C46 C51 -2.3(5) . . . . ?
C36 C31 C32 Ru3 -123.3(3) . . . . ?
C36 C31 C32 C33 175.3(3) . . . . ?
C36 C31 C32 C37 -1.0(5) . . . . ?
C55 C50 C49 Ru4 122.2(3) . . . . ?
C55 C50 C49 C48 -175.0(3) . . . . ?
C55 C50 C49 C54 1.5(5) . . . . ?
C55 C50 C46 Ru4 -122.3(3) . . . . ?
C55 C50 C46 C47 175.6(3) . . . . ?
C55 C50 C46 C51 -0.5(5) . . . . ?
C23 C18 C17 Ru2 -118.3(3) . . . . ?
C23 C18 C17 C16 179.8(3) . . . . ?
C23 C18 C17 C22 2.6(5) . . . . ?
C23 C18 C19 Ru2 118.2(3) . . . . ?
C23 C18 C19 C20 -179.9(3) . . . . ?
C23 C18 C19 C24 -3.7(5) . . . . ?
B1 C67 C72 C71 173.4(3) . . . . ?
B1 C73 C74 C75 -179.8(3) . . . . ?
B1 C79 C80 C81 179.6(3) . . . . ?
B1 C79 C84 C83 179.1(3) . . . . ?
B1 C61 C62 C63 -177.8(3) . . . . ?
C40 C35 C31 Ru3 -119.8(3) . . . . ?
C40 C35 C31 C32 178.6(3) . . . . ?
C40 C35 C31 C36 2.6(5) . . . . ?
C38 C33 C32 Ru3 121.9(3) . . . . ?
C38 C33 C32 C31 -176.8(3) . . . . ?
C38 C33 C32 C37 -0.4(5) . . . . ?
B2 C93 C94 C95 179.8(3) . . . . ?
B2 C93 C98 C97 179.6(3) . . . . ?
B2 C99 C104 C103 179.3(3) . . . . ?
B2 C99 C100 C101 -178.3(3) . . . . ?
B2 C105 C106 C107 175.7(3) . . . . ?
C25 C20 C16 Ru2 123.1(3) . . . . ?
C25 C20 C16 C17 -175.9(3) . . . . ?
C25 C20 C16 C21 -0.4(5) . . . . ?
C25 C20 C19 Ru2 -122.7(3) . . . . ?
C25 C20 C19 C18 175.1(3) . . . . ?
C25 C20 C19 C24 -1.1(5) . . . . ?
C53 C48 C47 Ru4 120.8(3) . . . . ?
C53 C48 C47 C46 -177.9(3) . . . . ?
C53 C48 C47 C52 0.5(5) . . . . ?
C53 C48 C49 Ru4 -120.5(3) . . . . ?
C53 C48 C49 C50 177.3(3) . . . . ?
C53 C48 C49 C54 0.8(5) . . . . ?
C6 C1 C2 Ru1 122.8(4) . . . . ?
C6 C1 C2 C3 -175.1(3) . . . . ?
C6 C1 C2 C7 2.2(6) . . . . ?
C10 C5 C4 Ru1 -122.4(3) . . . . ?
C10 C5 C4 C3 174.8(3) . . . . ?
C10 C5 C4 C9 -2.6(6) . . . . ?
C10 C5 C1 Ru1 122.7(3) . . . . ?
C10 C5 C1 C2 -175.7(3) . . . . ?
C10 C5 C1 C6 -0.1(6) . . . . ?
C9 C4 C3 Ru1 -120.2(4) . . . . ?
C9 C4 C3 C2 179.1(3) . . . . ?
C9 C4 C3 C8 -0.4(6) . . . . ?
C8 C3 C2 Ru1 -119.8(4) . . . . ?
C8 C3 C2 C1 178.3(3) . . . . ?
C8 C3 C2 C7 0.9(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
