# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_170314b_0m
_database_code_depnum_ccdc_archive 'CCDC 1843841'
_audit_update_record             
;
2018-05-17 deposited with the CCDC.
2018-08-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C19 H19 Cl4 Co2 N4 O'
_chemical_formula_weight         579.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.4062(12)
_cell_length_b                   18.658(3)
_cell_length_c                   14.430(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.338(2)
_cell_angle_gamma                90.00
_cell_volume                     2233.3(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4416
_cell_measurement_theta_min      2.61
_cell_measurement_theta_max      26.90

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    1.722
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1164
_exptl_absorpt_coefficient_mu    1.983
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.7552
_exptl_absorpt_correction_T_max  0.8263
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            19904
_diffrn_reflns_av_R_equivalents  0.1059
_diffrn_reflns_av_sigmaI/netI    0.0813
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.80
_diffrn_reflns_theta_max         28.00
_reflns_number_total             5352
_reflns_number_gt                3734
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0660P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5352
_refine_ls_number_parameters     271
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0688
_refine_ls_R_factor_gt           0.0448
_refine_ls_wR_factor_ref         0.1293
_refine_ls_wR_factor_gt          0.1124
_refine_ls_goodness_of_fit_ref   0.993
_refine_ls_restrained_S_all      0.993
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.50743(5) 0.16267(2) 0.24139(3) 0.01876(13) Uani 1 1 d . . .
Co2 Co 0.50241(6) 0.34833(3) 0.27414(4) 0.02909(15) Uani 1 1 d . . .
C1 C 0.5659(4) 0.01192(19) 0.2563(3) 0.0275(8) Uani 1 1 d . . .
H1A H 0.4943 -0.0281 0.2615 0.033 Uiso 1 1 calc R . .
H1B H 0.6605 -0.0062 0.2334 0.033 Uiso 1 1 calc R . .
C2 C 0.6147(4) 0.04518(18) 0.3499(3) 0.0235(7) Uani 1 1 d . . .
C3 C 0.6651(4) 0.0100(2) 0.4338(3) 0.0305(8) Uani 1 1 d . . .
H3 H 0.6669 -0.0398 0.4369 0.037 Uiso 1 1 calc R . .
C4 C 0.7123(5) 0.0508(2) 0.5125(3) 0.0378(10) Uani 1 1 d . . .
H4 H 0.7448 0.0283 0.5699 0.045 Uiso 1 1 calc R . .
C5 C 0.7127(5) 0.1245(2) 0.5083(3) 0.0383(10) Uani 1 1 d . . .
H5 H 0.7470 0.1517 0.5619 0.046 Uiso 1 1 calc R . .
C6 C 0.6618(4) 0.1571(2) 0.4239(3) 0.0270(8) Uani 1 1 d . . .
C7 C 0.6490(5) 0.2364(2) 0.4043(3) 0.0349(9) Uani 1 1 d . . .
H7A H 0.5967 0.2598 0.4513 0.042 Uiso 1 1 calc R . .
H7B H 0.7560 0.2567 0.4075 0.042 Uiso 1 1 calc R . .
C8 C 0.3001(4) 0.0528(2) 0.1696(3) 0.0320(9) Uani 1 1 d . . .
H8A H 0.2508 0.0749 0.1111 0.038 Uiso 1 1 calc R . .
H8B H 0.2792 0.0017 0.1655 0.038 Uiso 1 1 calc R . .
C9 C 0.2317(4) 0.0841(2) 0.2494(3) 0.0289(8) Uani 1 1 d . . .
C10 C 0.0976(5) 0.0572(2) 0.2817(3) 0.0417(11) Uani 1 1 d . . .
H10 H 0.0441 0.0171 0.2539 0.050 Uiso 1 1 calc R . .
C11 C 0.0445(5) 0.0913(3) 0.3564(3) 0.0463(12) Uani 1 1 d . . .
H11 H -0.0420 0.0724 0.3812 0.056 Uiso 1 1 calc R . .
C12 C 0.1179(5) 0.1522(3) 0.3936(3) 0.0450(11) Uani 1 1 d . . .
H12 H 0.0805 0.1765 0.4421 0.054 Uiso 1 1 calc R . .
C13 C 0.2532(5) 0.1774(2) 0.3560(3) 0.0349(9) Uani 1 1 d . . .
H13 H 0.3048 0.2190 0.3802 0.042 Uiso 1 1 calc R . .
C14 C 0.5509(5) 0.0679(2) 0.0997(3) 0.0340(9) Uani 1 1 d . . .
H14A H 0.4732 0.0867 0.0484 0.041 Uiso 1 1 calc R . .
H14B H 0.5798 0.0197 0.0835 0.041 Uiso 1 1 calc R . .
C15 C 0.6994(4) 0.1150(2) 0.1155(3) 0.0286(8) Uani 1 1 d . . .
C16 C 0.8211(5) 0.1108(2) 0.0659(3) 0.0395(10) Uani 1 1 d . . .
H16 H 0.8216 0.0747 0.0215 0.047 Uiso 1 1 calc R . .
C17 C 0.9470(6) 0.1605(2) 0.0808(3) 0.0457(11) Uani 1 1 d . . .
H17 H 1.0314 0.1585 0.0465 0.055 Uiso 1 1 calc R . .
C18 C 0.9422(5) 0.2131(2) 0.1485(3) 0.0388(10) Uani 1 1 d . . .
H18 H 1.0242 0.2469 0.1605 0.047 Uiso 1 1 calc R . .
C19 C 0.8157(4) 0.2146(2) 0.1973(3) 0.0315(8) Uani 1 1 d . . .
H19 H 0.8124 0.2501 0.2421 0.038 Uiso 1 1 calc R . .
Cl1 Cl 0.37239(11) 0.21971(5) 0.11797(6) 0.0312(2) Uani 1 1 d . . .
Cl2 Cl 0.60562(15) 0.38900(6) 0.15076(8) 0.0491(3) Uani 1 1 d . . .
Cl3 Cl 0.63630(17) 0.41721(6) 0.39663(8) 0.0530(3) Uani 1 1 d . . .
Cl4 Cl 0.23432(14) 0.36521(6) 0.26874(10) 0.0543(3) Uani 1 1 d . . .
N1 N 0.4803(3) 0.06669(15) 0.1868(2) 0.0235(6) Uani 1 1 d . . .
N2 N 0.6140(3) 0.11704(15) 0.3485(2) 0.0213(6) Uani 1 1 d . . .
N3 N 0.3077(3) 0.14310(15) 0.2877(2) 0.0233(6) Uani 1 1 d . . .
N4 N 0.6962(3) 0.16607(15) 0.1823(2) 0.0236(6) Uani 1 1 d . . .
O1 O 0.5579(3) 0.24826(12) 0.31314(17) 0.0250(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N2 1.861(3) . ?
Co1 O1 1.913(2) . ?
Co1 N4 1.920(3) . ?
Co1 N3 1.940(3) . ?
Co1 N1 1.955(3) . ?
Co1 Cl1 2.2220(10) . ?
Co2 O1 1.984(2) . ?
Co2 Cl2 2.2361(12) . ?
Co2 Cl4 2.2643(12) . ?
Co2 Cl3 2.3231(12) . ?
C1 C2 1.483(5) . ?
C1 N1 1.527(5) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 N2 1.341(4) . ?
C2 C3 1.382(5) . ?
C3 C4 1.371(6) . ?
C3 H3 0.9300 . ?
C4 C5 1.376(6) . ?
C4 H4 0.9300 . ?
C5 C6 1.367(5) . ?
C5 H5 0.9300 . ?
C6 N2 1.328(4) . ?
C6 C7 1.506(5) . ?
C7 O1 1.428(4) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.486(5) . ?
C8 N1 1.518(5) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 N3 1.347(5) . ?
C9 C10 1.382(5) . ?
C10 C11 1.387(7) . ?
C10 H10 0.9300 . ?
C11 C12 1.361(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.417(5) . ?
C12 H12 0.9300 . ?
C13 N3 1.318(5) . ?
C13 H13 0.9300 . ?
C14 N1 1.475(5) . ?
C14 C15 1.513(5) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.342(5) . ?
C15 N4 1.359(5) . ?
C16 C17 1.398(6) . ?
C16 H16 0.9300 . ?
C17 C18 1.389(6) . ?
C17 H17 0.9300 . ?
C18 C19 1.368(5) . ?
C18 H18 0.9300 . ?
C19 N4 1.344(5) . ?
C19 H19 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Co1 O1 84.14(11) . . ?
N2 Co1 N4 93.59(12) . . ?
O1 Co1 N4 94.94(12) . . ?
N2 Co1 N3 87.40(12) . . ?
O1 Co1 N3 95.68(11) . . ?
N4 Co1 N3 169.38(13) . . ?
N2 Co1 N1 85.65(12) . . ?
O1 Co1 N1 169.71(11) . . ?
N4 Co1 N1 84.38(12) . . ?
N3 Co1 N1 85.16(12) . . ?
N2 Co1 Cl1 177.17(9) . . ?
O1 Co1 Cl1 94.22(8) . . ?
N4 Co1 Cl1 88.84(9) . . ?
N3 Co1 Cl1 90.47(9) . . ?
N1 Co1 Cl1 96.03(9) . . ?
O1 Co2 Cl2 116.20(8) . . ?
O1 Co2 Cl4 109.12(8) . . ?
Cl2 Co2 Cl4 115.98(5) . . ?
O1 Co2 Cl3 104.02(8) . . ?
Cl2 Co2 Cl3 102.44(5) . . ?
Cl4 Co2 Cl3 107.81(5) . . ?
C2 C1 N1 110.4(3) . . ?
C2 C1 H1A 109.6 . . ?
N1 C1 H1A 109.6 . . ?
C2 C1 H1B 109.6 . . ?
N1 C1 H1B 109.6 . . ?
H1A C1 H1B 108.1 . . ?
N2 C2 C3 119.3(3) . . ?
N2 C2 C1 113.8(3) . . ?
C3 C2 C1 126.9(3) . . ?
C4 C3 C2 117.9(4) . . ?
C4 C3 H3 121.1 . . ?
C2 C3 H3 121.1 . . ?
C3 C4 C5 121.4(4) . . ?
C3 C4 H4 119.3 . . ?
C5 C4 H4 119.3 . . ?
C6 C5 C4 118.7(4) . . ?
C6 C5 H5 120.6 . . ?
C4 C5 H5 120.6 . . ?
N2 C6 C5 119.3(4) . . ?
N2 C6 C7 113.3(3) . . ?
C5 C6 C7 127.3(4) . . ?
O1 C7 C6 109.7(3) . . ?
O1 C7 H7A 109.7 . . ?
C6 C7 H7A 109.7 . . ?
O1 C7 H7B 109.7 . . ?
C6 C7 H7B 109.7 . . ?
H7A C7 H7B 108.2 . . ?
C9 C8 N1 107.9(3) . . ?
C9 C8 H8A 110.1 . . ?
N1 C8 H8A 110.1 . . ?
C9 C8 H8B 110.1 . . ?
N1 C8 H8B 110.1 . . ?
H8A C8 H8B 108.4 . . ?
N3 C9 C10 121.1(4) . . ?
N3 C9 C8 114.9(3) . . ?
C10 C9 C8 123.9(4) . . ?
C9 C10 C11 118.6(4) . . ?
C9 C10 H10 120.7 . . ?
C11 C10 H10 120.7 . . ?
C12 C11 C10 120.5(4) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C11 C12 C13 117.8(4) . . ?
C11 C12 H12 121.1 . . ?
C13 C12 H12 121.1 . . ?
N3 C13 C12 121.6(4) . . ?
N3 C13 H13 119.2 . . ?
C12 C13 H13 119.2 . . ?
N1 C14 C15 108.5(3) . . ?
N1 C14 H14A 110.0 . . ?
C15 C14 H14A 110.0 . . ?
N1 C14 H14B 110.0 . . ?
C15 C14 H14B 110.0 . . ?
H14A C14 H14B 108.4 . . ?
C16 C15 N4 121.6(4) . . ?
C16 C15 C14 124.6(4) . . ?
N4 C15 C14 113.8(3) . . ?
C15 C16 C17 120.2(4) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 118.0(4) . . ?
C18 C17 H17 121.0 . . ?
C16 C17 H17 121.0 . . ?
C19 C18 C17 119.4(4) . . ?
C19 C18 H18 120.3 . . ?
C17 C18 H18 120.3 . . ?
N4 C19 C18 121.8(4) . . ?
N4 C19 H19 119.1 . . ?
C18 C19 H19 119.1 . . ?
C14 N1 C8 113.1(3) . . ?
C14 N1 C1 111.0(3) . . ?
C8 N1 C1 110.1(3) . . ?
C14 N1 Co1 107.0(2) . . ?
C8 N1 Co1 105.7(2) . . ?
C1 N1 Co1 109.7(2) . . ?
C6 N2 C2 123.3(3) . . ?
C6 N2 Co1 117.6(2) . . ?
C2 N2 Co1 118.1(2) . . ?
C13 N3 C9 120.3(3) . . ?
C13 N3 Co1 126.3(3) . . ?
C9 N3 Co1 113.1(2) . . ?
C19 N4 C15 119.1(3) . . ?
C19 N4 Co1 126.9(3) . . ?
C15 N4 Co1 113.9(2) . . ?
C7 O1 Co1 114.1(2) . . ?
C7 O1 Co2 118.3(2) . . ?
Co1 O1 Co2 127.65(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 N2 -16.7(4) . . . . ?
N1 C1 C2 C3 166.2(3) . . . . ?
N2 C2 C3 C4 0.0(5) . . . . ?
C1 C2 C3 C4 177.1(4) . . . . ?
C2 C3 C4 C5 -1.2(6) . . . . ?
C3 C4 C5 C6 1.3(7) . . . . ?
C4 C5 C6 N2 -0.2(6) . . . . ?
C4 C5 C6 C7 178.5(4) . . . . ?
N2 C6 C7 O1 11.7(5) . . . . ?
C5 C6 C7 O1 -167.0(4) . . . . ?
N1 C8 C9 N3 32.0(4) . . . . ?
N1 C8 C9 C10 -149.8(3) . . . . ?
N3 C9 C10 C11 -1.6(6) . . . . ?
C8 C9 C10 C11 -179.6(4) . . . . ?
C9 C10 C11 C12 3.5(6) . . . . ?
C10 C11 C12 C13 -2.5(7) . . . . ?
C11 C12 C13 N3 -0.4(6) . . . . ?
N1 C14 C15 C16 157.3(4) . . . . ?
N1 C14 C15 N4 -26.2(4) . . . . ?
N4 C15 C16 C17 -1.4(6) . . . . ?
C14 C15 C16 C17 174.9(4) . . . . ?
C15 C16 C17 C18 0.6(6) . . . . ?
C16 C17 C18 C19 -0.3(6) . . . . ?
C17 C18 C19 N4 0.6(6) . . . . ?
C15 C14 N1 C8 152.9(3) . . . . ?
C15 C14 N1 C1 -82.7(3) . . . . ?
C15 C14 N1 Co1 37.0(3) . . . . ?
C9 C8 N1 C14 -154.9(3) . . . . ?
C9 C8 N1 C1 80.2(4) . . . . ?
C9 C8 N1 Co1 -38.2(3) . . . . ?
C2 C1 N1 C14 129.3(3) . . . . ?
C2 C1 N1 C8 -104.6(3) . . . . ?
C2 C1 N1 Co1 11.3(3) . . . . ?
N2 Co1 N1 C14 -123.8(2) . . . . ?
O1 Co1 N1 C14 -116.5(6) . . . . ?
N4 Co1 N1 C14 -29.8(2) . . . . ?
N3 Co1 N1 C14 148.4(2) . . . . ?
Cl1 Co1 N1 C14 58.5(2) . . . . ?
N2 Co1 N1 C8 115.4(2) . . . . ?
O1 Co1 N1 C8 122.7(6) . . . . ?
N4 Co1 N1 C8 -150.6(2) . . . . ?
N3 Co1 N1 C8 27.6(2) . . . . ?
Cl1 Co1 N1 C8 -62.3(2) . . . . ?
N2 Co1 N1 C1 -3.3(2) . . . . ?
O1 Co1 N1 C1 4.0(8) . . . . ?
N4 Co1 N1 C1 90.7(2) . . . . ?
N3 Co1 N1 C1 -91.1(2) . . . . ?
Cl1 Co1 N1 C1 178.9(2) . . . . ?
C5 C6 N2 C2 -1.0(5) . . . . ?
C7 C6 N2 C2 -179.8(3) . . . . ?
C5 C6 N2 Co1 167.8(3) . . . . ?
C7 C6 N2 Co1 -11.0(4) . . . . ?
C3 C2 N2 C6 1.1(5) . . . . ?
C1 C2 N2 C6 -176.3(3) . . . . ?
C3 C2 N2 Co1 -167.7(3) . . . . ?
C1 C2 N2 Co1 14.9(4) . . . . ?
O1 Co1 N2 C6 5.4(3) . . . . ?
N4 Co1 N2 C6 100.0(3) . . . . ?
N3 Co1 N2 C6 -90.6(3) . . . . ?
N1 Co1 N2 C6 -175.9(3) . . . . ?
Cl1 Co1 N2 C6 -49(2) . . . . ?
O1 Co1 N2 C2 174.8(3) . . . . ?
N4 Co1 N2 C2 -90.5(3) . . . . ?
N3 Co1 N2 C2 78.9(3) . . . . ?
N1 Co1 N2 C2 -6.5(2) . . . . ?
Cl1 Co1 N2 C2 120.0(18) . . . . ?
C12 C13 N3 C9 2.3(6) . . . . ?
C12 C13 N3 Co1 -170.6(3) . . . . ?
C10 C9 N3 C13 -1.3(5) . . . . ?
C8 C9 N3 C13 176.9(3) . . . . ?
C10 C9 N3 Co1 172.5(3) . . . . ?
C8 C9 N3 Co1 -9.3(4) . . . . ?
N2 Co1 N3 C13 76.1(3) . . . . ?
O1 Co1 N3 C13 -7.8(3) . . . . ?
N4 Co1 N3 C13 171.7(6) . . . . ?
N1 Co1 N3 C13 161.9(3) . . . . ?
Cl1 Co1 N3 C13 -102.1(3) . . . . ?
N2 Co1 N3 C9 -97.3(3) . . . . ?
O1 Co1 N3 C9 178.8(2) . . . . ?
N4 Co1 N3 C9 -1.7(8) . . . . ?
N1 Co1 N3 C9 -11.5(3) . . . . ?
Cl1 Co1 N3 C9 84.6(2) . . . . ?
C18 C19 N4 C15 -1.3(5) . . . . ?
C18 C19 N4 Co1 -177.7(3) . . . . ?
C16 C15 N4 C19 1.7(5) . . . . ?
C14 C15 N4 C19 -174.9(3) . . . . ?
C16 C15 N4 Co1 178.5(3) . . . . ?
C14 C15 N4 Co1 1.9(4) . . . . ?
N2 Co1 N4 C19 -82.1(3) . . . . ?
O1 Co1 N4 C19 2.3(3) . . . . ?
N3 Co1 N4 C19 -177.2(6) . . . . ?
N1 Co1 N4 C19 -167.4(3) . . . . ?
Cl1 Co1 N4 C19 96.5(3) . . . . ?
N2 Co1 N4 C15 101.4(3) . . . . ?
O1 Co1 N4 C15 -174.2(3) . . . . ?
N3 Co1 N4 C15 6.3(8) . . . . ?
N1 Co1 N4 C15 16.1(3) . . . . ?
Cl1 Co1 N4 C15 -80.0(2) . . . . ?
C6 C7 O1 Co1 -7.5(4) . . . . ?
C6 C7 O1 Co2 173.7(2) . . . . ?
N2 Co1 O1 C7 1.8(3) . . . . ?
N4 Co1 O1 C7 -91.3(3) . . . . ?
N3 Co1 O1 C7 88.6(3) . . . . ?
N1 Co1 O1 C7 -5.5(8) . . . . ?
Cl1 Co1 O1 C7 179.5(2) . . . . ?
N2 Co1 O1 Co2 -179.53(18) . . . . ?
N4 Co1 O1 Co2 87.35(17) . . . . ?
N3 Co1 O1 Co2 -92.74(17) . . . . ?
N1 Co1 O1 Co2 173.1(5) . . . . ?
Cl1 Co1 O1 Co2 -1.85(16) . . . . ?
Cl2 Co2 O1 C7 116.9(3) . . . . ?
Cl4 Co2 O1 C7 -109.7(3) . . . . ?
Cl3 Co2 O1 C7 5.2(3) . . . . ?
Cl2 Co2 O1 Co1 -61.69(18) . . . . ?
Cl4 Co2 O1 Co1 71.72(17) . . . . ?
Cl3 Co2 O1 Co1 -173.43(14) . . . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        28.00
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.419
_refine_diff_density_min         -0.675
_refine_diff_density_rms         0.154
