# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sgn4rh_p
_database_code_depnum_ccdc_archive 'CCDC 1865637'
_audit_update_record             
;
2018-09-03 deposited with the CCDC.
2018-11-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C59 H69 Cl2 N5 Rh2, 2(C H2 Cl2)'
_chemical_formula_sum            'C61 H73 Cl6 N5 Rh2'
_chemical_formula_weight         1294.76

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   26.8865(12)
_cell_length_b                   10.0794(4)
_cell_length_c                   23.4752(15)
_cell_angle_alpha                90
_cell_angle_beta                 110.681(6)
_cell_angle_gamma                90
_cell_volume                     5951.8(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3728
_cell_measurement_theta_min      3.0322
_cell_measurement_theta_max      29.0918

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.409
_exptl_crystal_size_mid          0.328
_exptl_crystal_size_min          0.127
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.445
_exptl_crystal_F_000             2664
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_absorpt_coefficient_mu    0.866
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.718
_exptl_absorpt_correction_T_max  0.896
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15414
_diffrn_reflns_av_unetI/netI     0.0485
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_theta_min         3.042
_diffrn_reflns_theta_max         29.156
_diffrn_reflns_theta_full        26.000
_diffrn_measured_fraction_theta_max 0.848
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.848
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.848
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             6812
_reflns_number_gt                4524
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2018/3 (Sheldrick, 2018)'
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0521P)²+7.7040P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6812
_refine_ls_number_parameters     338
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0820
_refine_ls_R_factor_gt           0.0448
_refine_ls_wR_factor_ref         0.1165
_refine_ls_wR_factor_gt          0.1010
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_restrained_S_all      0.992
_refine_ls_shift/su_max          0.036
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C40 C 0.1144(2) 0.2252(5) 0.4352(3) 0.091(2) Uani 1 1 d . . . . .
H40A H 0.124564 0.135937 0.428410 0.109 Uiso 1 1 calc R U . . .
H40B H 0.140349 0.285939 0.429852 0.109 Uiso 1 1 calc R U . . .
Cl3 Cl 0.11549(7) 0.23741(16) 0.50813(9) 0.1022(5) Uani 1 1 d . . . . .
Cl2 Cl 0.05195(8) 0.26092(16) 0.38100(10) 0.1137(6) Uani 1 1 d . . . . .
Rh1 Rh 0.09186(2) 0.75084(3) 0.42841(2) 0.03525(10) Uani 1 1 d . . . . .
Cl1 Cl 0.15496(4) 0.90385(10) 0.41644(5) 0.0595(3) Uani 1 1 d . . . . .
N3 N 0.000000 0.5886(4) 0.250000 0.0281(8) Uani 1 2 d S T P . .
N1 N 0.11706(10) 0.6151(3) 0.37622(12) 0.0312(6) Uani 1 1 d . . . . .
N2 N 0.11386(10) 0.4813(3) 0.29959(12) 0.0316(6) Uani 1 1 d . . . . .
C2 C 0.04350(12) 0.6581(3) 0.28137(14) 0.0292(7) Uani 1 1 d . . . . .
C21 C 0.13370(13) 0.3638(4) 0.21584(15) 0.0408(9) Uani 1 1 d . . . . .
C1 C 0.09096(12) 0.5835(3) 0.31883(14) 0.0291(7) Uani 1 1 d . . . . .
C5 C 0.15855(12) 0.4437(3) 0.34876(14) 0.0312(7) Uani 1 1 d . . . . .
C10 C 0.16039(12) 0.5293(3) 0.39590(15) 0.0313(7) Uani 1 1 d . . . . .
C11 C 0.02301(15) 0.6384(4) 0.41587(18) 0.0473(10) Uani 1 1 d . . . . .
H11 H 0.015012 0.574343 0.382418 0.057 Uiso 1 1 calc R U . . .
C3 C 0.04559(14) 0.7954(3) 0.28179(16) 0.0393(8) Uani 1 1 d . . . . .
H3 H 0.076981 0.839874 0.303005 0.047 Uiso 1 1 calc R U . . .
C6 C 0.19728(13) 0.3468(4) 0.35660(17) 0.0424(9) Uani 1 1 d . . . . .
H6 H 0.196628 0.289885 0.325173 0.051 Uiso 1 1 calc R U . . .
C25 C 0.20102(16) 0.3978(5) 0.17107(18) 0.0565(11) Uani 1 1 d . . . . .
C4 C 0.000000 0.8643(5) 0.250000 0.0448(13) Uani 1 2 d S T P . .
H4 H 0.000001 0.956561 0.249998 0.054 Uiso 1 2 calc R U P . .
C22 C 0.13836(15) 0.2250(4) 0.21155(17) 0.0486(10) Uani 1 1 d . . . . .
C12 C 0.06289(18) 0.5979(4) 0.46817(19) 0.0554(11) Uani 1 1 d . . . . .
H12 H 0.077538 0.510513 0.464683 0.066 Uiso 1 1 calc R U . . .
C9 C 0.20084(14) 0.5217(4) 0.45295(16) 0.0407(8) Uani 1 1 d . . . . .
H9 H 0.202128 0.579364 0.484373 0.049 Uiso 1 1 calc R U . . .
C20 C 0.09194(14) 0.4203(4) 0.23842(16) 0.0466(10) Uani 1 1 d . . . . .
H20A H 0.071634 0.486726 0.209685 0.056 Uiso 1 1 calc R U . . .
H20B H 0.067667 0.349895 0.239394 0.056 Uiso 1 1 calc R U . . .
C7 C 0.23665(14) 0.3394(4) 0.41323(18) 0.0485(10) Uani 1 1 d . . . . .
H7 H 0.262854 0.274892 0.420208 0.058 Uiso 1 1 calc R U . . .
C8 C 0.23846(14) 0.4254(4) 0.46030(17) 0.0466(9) Uani 1 1 d . . . . .
H8 H 0.265925 0.417208 0.497695 0.056 Uiso 1 1 calc R U . . .
C15 C 0.08015(18) 0.8607(4) 0.5000(2) 0.0588(12) Uani 1 1 d . . . . .
H15 H 0.108630 0.923851 0.520253 0.071 Uiso 1 1 calc R U . . .
C26 C 0.16504(15) 0.4492(4) 0.19647(16) 0.0463(9) Uani 1 1 d . . . . .
C36 C 0.1610(2) 0.5974(4) 0.2021(2) 0.0718(13) Uani 1 1 d . . . . .
H36A H 0.131318 0.617904 0.214267 0.108 Uiso 1 1 calc R U . . .
H36B H 0.156046 0.638312 0.163600 0.108 Uiso 1 1 calc R U . . .
H36C H 0.193091 0.630266 0.232175 0.108 Uiso 1 1 calc R U . . .
C23 C 0.17437(17) 0.1754(4) 0.18548(19) 0.0554(11) Uani 1 1 d . . . . .
C16 C 0.04472(17) 0.9038(4) 0.4452(2) 0.0561(11) Uani 1 1 d . . . . .
H16 H 0.052578 0.992386 0.433391 0.067 Uiso 1 1 calc R U . . .
C24 C 0.20427(17) 0.2622(5) 0.1647(2) 0.0584(11) Uani 1 1 d . . . . .
C13 C 0.0665(2) 0.6320(6) 0.5320(2) 0.0903(18) Uani 1 1 d . . . . .
H13A H 0.037739 0.588181 0.540412 0.108 Uiso 1 1 calc R U . . .
H13B H 0.099711 0.597531 0.560390 0.108 Uiso 1 1 calc R U . . .
C33 C 0.1777(2) 0.0250(5) 0.1769(3) 0.0916(18) Uani 1 1 d . . . . .
H33A H 0.158006 0.002215 0.135242 0.137 Uiso 1 1 calc R U . . .
H33B H 0.162875 -0.020746 0.203054 0.137 Uiso 1 1 calc R U . . .
H33C H 0.214171 -0.000512 0.186882 0.137 Uiso 1 1 calc R U . . .
C32 C 0.1058(2) 0.1314(5) 0.2343(2) 0.0772(14) Uani 1 1 d . . . . .
H32A H 0.072470 0.114308 0.202288 0.116 Uiso 1 1 calc R U . . .
H32B H 0.099380 0.170792 0.268309 0.116 Uiso 1 1 calc R U . . .
H32C H 0.124779 0.049575 0.246801 0.116 Uiso 1 1 calc R U . . .
C17 C -0.01317(18) 0.8666(5) 0.4190(3) 0.0801(15) Uani 1 1 d . . . . .
H17A H -0.031150 0.904560 0.444495 0.096 Uiso 1 1 calc R U . . .
H17B H -0.028532 0.906132 0.378951 0.096 Uiso 1 1 calc R U . . .
C18 C -0.02368(18) 0.7226(5) 0.4137(3) 0.0770(16) Uani 1 1 d . . . . .
H18A H -0.052513 0.705702 0.375574 0.092 Uiso 1 1 calc R U . . .
H18B H -0.035564 0.695342 0.446415 0.092 Uiso 1 1 calc R U . . .
C35 C 0.2341(2) 0.4931(6) 0.1483(3) 0.0893(17) Uani 1 1 d . . . . .
H35A H 0.226690 0.582795 0.156544 0.134 Uiso 1 1 calc R U . . .
H35B H 0.271181 0.474728 0.168717 0.134 Uiso 1 1 calc R U . . .
H35C H 0.225137 0.481716 0.105188 0.134 Uiso 1 1 calc R U . . .
C34 C 0.2408(2) 0.2056(6) 0.1332(3) 0.101(2) Uani 1 1 d . . . . .
H34A H 0.258780 0.276912 0.121448 0.151 Uiso 1 1 calc R U . . .
H34B H 0.266548 0.147719 0.160829 0.151 Uiso 1 1 calc R U . . .
H34C H 0.220009 0.156579 0.097751 0.151 Uiso 1 1 calc R U . . .
C14 C 0.0639(3) 0.7752(5) 0.5427(2) 0.0876(18) Uani 1 1 d . . . . .
H14A H 0.086722 0.794953 0.584132 0.105 Uiso 1 1 calc R U . . .
H14B H 0.027783 0.797765 0.538847 0.105 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C40 Cl3 1.706(7) . ?
C40 Cl2 1.748(7) . ?
Rh1 C12 2.090(4) . ?
Rh1 C11 2.101(3) . ?
Rh1 N1 2.102(3) . ?
Rh1 C16 2.120(4) . ?
Rh1 C15 2.127(4) . ?
Rh1 Cl1 2.3817(10) . ?
N3 C2 1.339(4) . ?
N3 C2 1.339(4) 2 ?
N1 C1 1.320(4) . ?
N1 C10 1.392(4) . ?
N2 C1 1.357(4) . ?
N2 C5 1.393(4) . ?
N2 C20 1.480(4) . ?
C2 C3 1.385(5) . ?
C2 C1 1.474(4) . ?
C21 C26 1.389(5) . ?
C21 C22 1.411(5) . ?
C21 C20 1.512(5) . ?
C5 C10 1.390(4) . ?
C5 C6 1.391(5) . ?
C10 C9 1.398(4) . ?
C11 C12 1.376(6) . ?
C11 C18 1.501(6) . ?
C3 C4 1.377(4) . ?
C6 C7 1.378(5) . ?
C25 C24 1.381(6) . ?
C25 C26 1.403(5) . ?
C25 C35 1.529(6) . ?
C22 C23 1.407(5) . ?
C22 C32 1.507(6) . ?
C12 C13 1.507(6) . ?
C9 C8 1.368(5) . ?
C7 C8 1.392(5) . ?
C15 C16 1.373(6) . ?
C15 C14 1.499(6) . ?
C26 C36 1.507(6) . ?
C23 C24 1.388(6) . ?
C23 C33 1.537(6) . ?
C16 C17 1.505(6) . ?
C24 C34 1.532(6) . ?
C13 C14 1.471(7) . ?
C17 C18 1.475(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl3 C40 Cl2 112.8(3) . . ?
C12 Rh1 C11 38.34(16) . . ?
C12 Rh1 N1 91.60(14) . . ?
C11 Rh1 N1 90.95(12) . . ?
C12 Rh1 C16 96.41(17) . . ?
C11 Rh1 C16 82.14(16) . . ?
N1 Rh1 C16 156.79(15) . . ?
C12 Rh1 C15 81.27(17) . . ?
C11 Rh1 C15 91.29(15) . . ?
N1 Rh1 C15 165.35(16) . . ?
C16 Rh1 C15 37.73(16) . . ?
C12 Rh1 Cl1 157.47(13) . . ?
C11 Rh1 Cl1 164.15(12) . . ?
N1 Rh1 Cl1 87.88(8) . . ?
C16 Rh1 Cl1 92.79(12) . . ?
C15 Rh1 Cl1 93.83(12) . . ?
C2 N3 C2 116.9(4) . 2 ?
C1 N1 C10 105.6(3) . . ?
C1 N1 Rh1 126.0(2) . . ?
C10 N1 Rh1 128.0(2) . . ?
C1 N2 C5 106.9(2) . . ?
C1 N2 C20 124.5(3) . . ?
C5 N2 C20 128.5(3) . . ?
N3 C2 C3 123.5(3) . . ?
N3 C2 C1 117.7(3) . . ?
C3 C2 C1 118.7(3) . . ?
C26 C21 C22 120.8(3) . . ?
C26 C21 C20 119.5(4) . . ?
C22 C21 C20 119.6(4) . . ?
N1 C1 N2 112.5(3) . . ?
N1 C1 C2 121.5(3) . . ?
N2 C1 C2 126.0(3) . . ?
C10 C5 C6 121.0(3) . . ?
C10 C5 N2 105.6(3) . . ?
C6 C5 N2 133.4(3) . . ?
C5 C10 N1 109.3(3) . . ?
C5 C10 C9 121.7(3) . . ?
N1 C10 C9 128.9(3) . . ?
C12 C11 C18 125.2(4) . . ?
C12 C11 Rh1 70.4(2) . . ?
C18 C11 Rh1 112.6(3) . . ?
C4 C3 C2 118.3(3) . . ?
C7 C6 C5 116.7(3) . . ?
C24 C25 C26 119.4(4) . . ?
C24 C25 C35 121.1(4) . . ?
C26 C25 C35 119.4(4) . . ?
C3 C4 C3 119.4(5) . 2 ?
C23 C22 C21 118.4(4) . . ?
C23 C22 C32 120.5(4) . . ?
C21 C22 C32 121.2(4) . . ?
C11 C12 C13 125.2(4) . . ?
C11 C12 Rh1 71.3(2) . . ?
C13 C12 Rh1 111.9(3) . . ?
C8 C9 C10 116.7(3) . . ?
N2 C20 C21 114.0(3) . . ?
C6 C7 C8 122.1(3) . . ?
C9 C8 C7 121.6(3) . . ?
C16 C15 C14 122.6(4) . . ?
C16 C15 Rh1 70.8(2) . . ?
C14 C15 Rh1 112.9(3) . . ?
C21 C26 C25 120.0(4) . . ?
C21 C26 C36 121.0(4) . . ?
C25 C26 C36 119.1(4) . . ?
C24 C23 C22 120.1(4) . . ?
C24 C23 C33 120.5(4) . . ?
C22 C23 C33 119.2(4) . . ?
C15 C16 C17 125.4(4) . . ?
C15 C16 Rh1 71.4(2) . . ?
C17 C16 Rh1 110.0(3) . . ?
C23 C24 C25 121.2(4) . . ?
C23 C24 C34 119.0(4) . . ?
C25 C24 C34 119.8(4) . . ?
C14 C13 C12 113.8(4) . . ?
C18 C17 C16 114.8(4) . . ?
C17 C18 C11 114.9(4) . . ?
C13 C14 C15 114.0(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N3 C2 C3 -1.2(2) 2 . . . ?
C2 N3 C2 C1 176.8(3) 2 . . . ?
C10 N1 C1 N2 0.8(4) . . . . ?
Rh1 N1 C1 N2 -172.34(19) . . . . ?
C10 N1 C1 C2 -177.1(3) . . . . ?
Rh1 N1 C1 C2 9.8(4) . . . . ?
C5 N2 C1 N1 0.0(4) . . . . ?
C20 N2 C1 N1 176.9(3) . . . . ?
C5 N2 C1 C2 177.8(3) . . . . ?
C20 N2 C1 C2 -5.4(5) . . . . ?
N3 C2 C1 N1 -130.6(3) . . . . ?
C3 C2 C1 N1 47.5(4) . . . . ?
N3 C2 C1 N2 51.8(4) . . . . ?
C3 C2 C1 N2 -130.1(3) . . . . ?
C1 N2 C5 C10 -0.8(3) . . . . ?
C20 N2 C5 C10 -177.5(3) . . . . ?
C1 N2 C5 C6 -179.8(4) . . . . ?
C20 N2 C5 C6 3.5(6) . . . . ?
C6 C5 C10 N1 -179.6(3) . . . . ?
N2 C5 C10 N1 1.3(4) . . . . ?
C6 C5 C10 C9 -0.2(5) . . . . ?
N2 C5 C10 C9 -179.3(3) . . . . ?
C1 N1 C10 C5 -1.3(4) . . . . ?
Rh1 N1 C10 C5 171.6(2) . . . . ?
C1 N1 C10 C9 179.4(3) . . . . ?
Rh1 N1 C10 C9 -7.7(5) . . . . ?
N3 C2 C3 C4 2.4(5) . . . . ?
C1 C2 C3 C4 -175.6(3) . . . . ?
C10 C5 C6 C7 0.8(5) . . . . ?
N2 C5 C6 C7 179.7(4) . . . . ?
C2 C3 C4 C3 -1.1(2) . . . 2 ?
C26 C21 C22 C23 -1.9(5) . . . . ?
C20 C21 C22 C23 174.6(3) . . . . ?
C26 C21 C22 C32 178.0(4) . . . . ?
C20 C21 C22 C32 -5.5(6) . . . . ?
C18 C11 C12 C13 -0.4(7) . . . . ?
Rh1 C11 C12 C13 104.0(4) . . . . ?
C18 C11 C12 Rh1 -104.4(4) . . . . ?
C5 C10 C9 C8 -0.3(5) . . . . ?
N1 C10 C9 C8 178.9(3) . . . . ?
C1 N2 C20 C21 150.1(3) . . . . ?
C5 N2 C20 C21 -33.7(5) . . . . ?
C26 C21 C20 N2 -74.0(4) . . . . ?
C22 C21 C20 N2 109.5(4) . . . . ?
C5 C6 C7 C8 -1.0(6) . . . . ?
C10 C9 C8 C7 0.2(6) . . . . ?
C6 C7 C8 C9 0.5(6) . . . . ?
C22 C21 C26 C25 1.4(5) . . . . ?
C20 C21 C26 C25 -175.1(3) . . . . ?
C22 C21 C26 C36 -178.7(4) . . . . ?
C20 C21 C26 C36 4.8(5) . . . . ?
C24 C25 C26 C21 1.1(6) . . . . ?
C35 C25 C26 C21 178.2(4) . . . . ?
C24 C25 C26 C36 -178.8(4) . . . . ?
C35 C25 C26 C36 -1.6(6) . . . . ?
C21 C22 C23 C24 0.0(6) . . . . ?
C32 C22 C23 C24 -179.9(4) . . . . ?
C21 C22 C23 C33 -176.4(4) . . . . ?
C32 C22 C23 C33 3.7(6) . . . . ?
C14 C15 C16 C17 -3.6(7) . . . . ?
Rh1 C15 C16 C17 101.8(4) . . . . ?
C14 C15 C16 Rh1 -105.4(4) . . . . ?
C22 C23 C24 C25 2.5(7) . . . . ?
C33 C23 C24 C25 178.8(4) . . . . ?
C22 C23 C24 C34 -176.6(4) . . . . ?
C33 C23 C24 C34 -0.3(7) . . . . ?
C26 C25 C24 C23 -3.0(7) . . . . ?
C35 C25 C24 C23 179.9(4) . . . . ?
C26 C25 C24 C34 176.1(4) . . . . ?
C35 C25 C24 C34 -1.1(7) . . . . ?
C11 C12 C13 C14 -53.9(7) . . . . ?
Rh1 C12 C13 C14 28.0(6) . . . . ?
C15 C16 C17 C18 -54.9(7) . . . . ?
Rh1 C16 C17 C18 26.1(6) . . . . ?
C16 C17 C18 C11 -18.5(7) . . . . ?
C12 C11 C18 C17 82.9(6) . . . . ?
Rh1 C11 C18 C17 1.5(6) . . . . ?
C12 C13 C14 C15 -23.6(7) . . . . ?
C16 C15 C14 C13 89.3(6) . . . . ?
Rh1 C15 C14 C13 8.1(6) . . . . ?

_refine_diff_density_max         0.581
_refine_diff_density_min         -0.581
_refine_diff_density_rms         0.073



