# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_se-10-new_a
_audit_block_doi                 10.5517/ccdc.csd.cc1nzms1
_database_code_depnum_ccdc_archive 'CCDC 1548784'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-05-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H32 Au N O P, F6 Sb'
_chemical_formula_sum            'C25 H32 Au F6 N O P Sb'
_chemical_formula_weight         826.20
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           33
_space_group_name_H-M_alt        'P n a 21'
_space_group_name_Hall           'P 2c -2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z+1/2'

_cell_length_a                   13.6337(9)
_cell_length_b                   26.2681(17)
_cell_length_c                   7.7160(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2763.3(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9908
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      28.78
_cell_measurement_theta_min      2.75
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    6.398
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.3047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1133 before and 0.0418 after correction.
The Ratio of minimum to maximum transmission is 0.4086.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.986
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1584
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0458
_diffrn_reflns_av_unetI/netI     0.0292
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            38897
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         28.809
_diffrn_reflns_theta_min         2.751
_diffrn_ambient_temperature      180.18
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.856
_reflns_Friedel_fraction_full    0.982
_reflns_Friedel_fraction_max     0.983
_reflns_number_gt                6936
_reflns_number_total             7155
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_refine_diff_density_max         0.955
_refine_diff_density_min         -1.998
_refine_diff_density_rms         0.113
_refine_ls_abs_structure_details 
;
 Flack x determined using 3071 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.008(5)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         7155
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0286
_refine_ls_R_factor_gt           0.0276
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0455P)²+3.3082P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0688
_refine_ls_wR_factor_ref         0.0695
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00B(H00B), C00D(H00D), C00E(H00E), C00H(H00H), C00K(H00K), C00L(H00L),
 C00N(H00N), C00P(H00P), C00S(H00S), C00T(H00T), C00V(H00V), C00X(H00X),
 C00Y(H00Y), C01K(H01K)
2.b Idealised Me refined as rotating group:
 C00J(H00A,H00C,H00F), C00O(H00G,H00I,H00J), C00R(H00M,H00O,H00Q), C00W(H00R,
 H00U,H00W), C018(H01A,H01B,H01C), C01B(H01D,H01E,H01F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.26515(2) 0.36926(2) 0.33880(4) 0.01361(6) Uani 1 1 d . . . . .
Sb02 Sb 0.17030(3) 0.60945(2) 0.56502(5) 0.01462(9) Uani 1 1 d . . . . .
P003 P 0.25105(10) 0.32066(6) 0.5744(2) 0.0117(3) Uani 1 1 d . . . . .
F004 F 0.2629(3) 0.60272(18) 0.3868(6) 0.0299(10) Uani 1 1 d . . . . .
F005 F 0.1817(3) 0.53982(14) 0.6121(6) 0.0257(8) Uani 1 1 d . . . . .
O006 O 0.2753(3) 0.41182(19) 0.1132(6) 0.0214(9) Uani 1 1 d . . . . .
F007 F 0.2716(3) 0.62291(18) 0.7234(7) 0.0287(10) Uani 1 1 d . . . . .
F008 F 0.0775(3) 0.61517(16) 0.7442(5) 0.0270(9) Uani 1 1 d . . . . .
F009 F 0.0687(3) 0.59600(19) 0.4087(5) 0.0324(10) Uani 1 1 d . . . . .
F00A F 0.1589(3) 0.67944(15) 0.5187(6) 0.0334(10) Uani 1 1 d . . . . .
C00B C 0.3637(4) 0.2918(2) 0.8584(8) 0.0179(11) Uani 1 1 d . . . . .
H00B H 0.3149 0.2664 0.8720 0.021 Uiso 1 1 calc R . . . .
N00C N 0.2192(4) 0.4541(2) 0.1069(7) 0.0185(10) Uani 1 1 d . . . . .
C00D C 0.3888(4) 0.4856(2) 0.4428(8) 0.0166(11) Uani 1 1 d . . . . .
H00D H 0.3484 0.5151 0.4458 0.020 Uiso 1 1 calc R . . . .
C00E C 0.3763(4) 0.4475(2) 0.5669(8) 0.0149(10) Uani 1 1 d . . . . .
H00E H 0.3280 0.4513 0.6548 0.018 Uiso 1 1 calc R . . . .
C00F C 0.1411(4) 0.3408(2) 0.7027(8) 0.0173(11) Uani 1 1 d . . . . .
C00G C 0.3558(4) 0.3270(2) 0.7222(7) 0.0135(10) Uani 1 1 d . . . . .
C00H C 0.4594(4) 0.4807(2) 0.3157(9) 0.0199(12) Uani 1 1 d . . . . .
H00H H 0.4680 0.5068 0.2320 0.024 Uiso 1 1 calc R . . . .
C00I C 0.4346(4) 0.4039(2) 0.5622(8) 0.0140(9) Uani 1 1 d . . . . .
C00J C 0.1498(4) 0.3988(2) 0.7269(9) 0.0190(12) Uani 1 1 d . . . . .
H00A H 0.2107 0.4066 0.7887 0.028 Uiso 1 1 calc GR . . . .
H00C H 0.0937 0.4112 0.7943 0.028 Uiso 1 1 calc GR . . . .
H00F H 0.1504 0.4154 0.6133 0.028 Uiso 1 1 calc GR . . . .
C00K C 0.1238(5) 0.4533(2) 0.1521(8) 0.0221(12) Uani 1 1 d . . . . .
H00K H 0.0955 0.4228 0.1958 0.026 Uiso 1 1 calc R . . . .
C00L C 0.5069(4) 0.3653(2) 0.8221(10) 0.0208(12) Uani 1 1 d . . . . .
H00L H 0.5563 0.3905 0.8107 0.025 Uiso 1 1 calc R . . . .
C00N C 0.5180(4) 0.4375(2) 0.3105(9) 0.0222(13) Uani 1 1 d . . . . .
H00N H 0.5664 0.4339 0.2228 0.027 Uiso 1 1 calc R . . . .
C00O C 0.0489(4) 0.3290(3) 0.5979(9) 0.0254(14) Uani 1 1 d . . . . .
H00G H 0.0545 0.3442 0.4824 0.038 Uiso 1 1 calc GR . . . .
H00I H -0.0086 0.3431 0.6572 0.038 Uiso 1 1 calc GR . . . .
H00J H 0.0415 0.2920 0.5868 0.038 Uiso 1 1 calc GR . . . .
C00P C 0.5058(4) 0.3995(2) 0.4335(9) 0.0199(12) Uani 1 1 d . . . . .
H00P H 0.5465 0.3702 0.4299 0.024 Uiso 1 1 calc R . . . .
C00Q C 0.4293(4) 0.3645(2) 0.7020(8) 0.0142(11) Uani 1 1 d . . . . .
C00R C 0.1821(5) 0.2506(2) 0.3307(10) 0.0253(13) Uani 1 1 d . . . . .
H00M H 0.1155 0.2623 0.3569 0.038 Uiso 1 1 calc GR . . . .
H00O H 0.1796 0.2154 0.2883 0.038 Uiso 1 1 calc GR . . . .
H00Q H 0.2111 0.2725 0.2417 0.038 Uiso 1 1 calc GR . . . .
C00S C 0.1088(7) 0.5404(3) 0.0705(11) 0.0358(16) Uani 1 1 d . . . . .
H00S H 0.0707 0.5705 0.0588 0.043 Uiso 1 1 calc R . . . .
C00T C 0.0671(6) 0.4965(3) 0.1352(9) 0.0308(15) Uani 1 1 d . . . . .
H00T H -0.0001 0.4960 0.1677 0.037 Uiso 1 1 calc R . . . .
C00V C 0.2060(7) 0.5403(3) 0.0232(9) 0.0308(16) Uani 1 1 d . . . . .
H00V H 0.2350 0.5704 -0.0222 0.037 Uiso 1 1 calc R . . . .
C00W C 0.1337(5) 0.3169(3) 0.8827(8) 0.0243(13) Uani 1 1 d . . . . .
H00R H 0.1282 0.2799 0.8716 0.036 Uiso 1 1 calc GR . . . .
H00U H 0.0756 0.3302 0.9422 0.036 Uiso 1 1 calc GR . . . .
H00W H 0.1925 0.3254 0.9498 0.036 Uiso 1 1 calc GR . . . .
C00X C 0.4422(5) 0.2937(2) 0.9743(8) 0.0222(13) Uani 1 1 d . . . . .
H00X H 0.4463 0.2696 1.0656 0.027 Uiso 1 1 calc R . . . .
C00Y C 0.5137(5) 0.3303(3) 0.9568(8) 0.0227(13) Uani 1 1 d . . . . .
H00Y H 0.5670 0.3317 1.0359 0.027 Uiso 1 1 calc R . . . .
C012 C 0.2452(5) 0.2529(2) 0.4966(9) 0.0176(12) Uani 1 1 d . . . . .
C018 C 0.2048(8) 0.2141(3) 0.6251(11) 0.0400(19) Uani 1 1 d . . . . .
H01A H 0.2390 0.2177 0.7362 0.060 Uiso 1 1 calc GR . . . .
H01B H 0.2149 0.1797 0.5798 0.060 Uiso 1 1 calc GR . . . .
H01C H 0.1345 0.2201 0.6421 0.060 Uiso 1 1 calc GR . . . .
C01B C 0.3502(5) 0.2387(3) 0.4500(12) 0.0352(18) Uani 1 1 d . . . . .
H01D H 0.3761 0.2633 0.3662 0.053 Uiso 1 1 calc GR . . . .
H01E H 0.3513 0.2045 0.3991 0.053 Uiso 1 1 calc GR . . . .
H01F H 0.3908 0.2391 0.5549 0.053 Uiso 1 1 calc GR . . . .
C01K C 0.2620(5) 0.4965(3) 0.0413(9) 0.0248(14) Uani 1 1 d . . . . .
H01K H 0.3292 0.4963 0.0084 0.030 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2296(15) . ?
Au01 O006 2.074(5) . ?
Sb02 F004 1.875(4) . ?
Sb02 F005 1.871(4) . ?
Sb02 F007 1.878(4) . ?
Sb02 F008 1.880(4) . ?
Sb02 F009 1.871(4) . ?
Sb02 F00A 1.879(4) . ?
P003 C00F 1.873(6) . ?
P003 C00G 1.835(6) . ?
P003 C012 1.881(7) . ?
O006 N00C 1.349(7) . ?
C00B H00B 0.9500 . ?
C00B C00G 1.404(8) . ?
C00B C00X 1.395(8) . ?
N00C C00K 1.346(8) . ?
N00C C01K 1.357(9) . ?
C00D H00D 0.9500 . ?
C00D C00E 1.395(8) . ?
C00D C00H 1.381(9) . ?
C00E H00E 0.9500 . ?
C00E C00I 1.396(7) . ?
C00F C00J 1.538(9) . ?
C00F C00O 1.527(8) . ?
C00F C00W 1.527(9) . ?
C00G C00Q 1.414(8) . ?
C00H H00H 0.9500 . ?
C00H C00N 1.388(8) . ?
C00I C00P 1.393(8) . ?
C00I C00Q 1.496(8) . ?
C00J H00A 0.9800 . ?
C00J H00C 0.9800 . ?
C00J H00F 0.9800 . ?
C00K H00K 0.9500 . ?
C00K C00T 1.380(9) . ?
C00L H00L 0.9500 . ?
C00L C00Q 1.405(8) . ?
C00L C00Y 1.390(9) . ?
C00N H00N 0.9500 . ?
C00N C00P 1.387(9) . ?
C00O H00G 0.9800 . ?
C00O H00I 0.9800 . ?
C00O H00J 0.9800 . ?
C00P H00P 0.9500 . ?
C00R H00M 0.9800 . ?
C00R H00O 0.9800 . ?
C00R H00Q 0.9800 . ?
C00R C012 1.543(8) . ?
C00S H00S 0.9500 . ?
C00S C00T 1.380(11) . ?
C00S C00V 1.374(13) . ?
C00T H00T 0.9500 . ?
C00V H00V 0.9500 . ?
C00V C01K 1.387(11) . ?
C00W H00R 0.9800 . ?
C00W H00U 0.9800 . ?
C00W H00W 0.9800 . ?
C00X H00X 0.9500 . ?
C00X C00Y 1.376(9) . ?
C00Y H00Y 0.9500 . ?
C012 C018 1.524(10) . ?
C012 C01B 1.523(9) . ?
C018 H01A 0.9800 . ?
C018 H01B 0.9800 . ?
C018 H01C 0.9800 . ?
C01B H01D 0.9800 . ?
C01B H01E 0.9800 . ?
C01B H01F 0.9800 . ?
C01K H01K 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O006 Au01 P003 177.38(15) . . ?
F004 Sb02 F007 90.0(2) . . ?
F004 Sb02 F008 179.2(2) . . ?
F004 Sb02 F00A 90.5(2) . . ?
F005 Sb02 F004 89.7(2) . . ?
F005 Sb02 F007 89.80(19) . . ?
F005 Sb02 F008 89.50(18) . . ?
F005 Sb02 F00A 179.8(2) . . ?
F007 Sb02 F008 90.1(2) . . ?
F007 Sb02 F00A 90.0(2) . . ?
F009 Sb02 F004 90.5(2) . . ?
F009 Sb02 F005 90.1(2) . . ?
F009 Sb02 F007 179.5(2) . . ?
F009 Sb02 F008 89.47(19) . . ?
F009 Sb02 F00A 90.0(2) . . ?
F00A Sb02 F008 90.35(19) . . ?
C00F P003 Au01 109.8(2) . . ?
C00F P003 C012 113.7(3) . . ?
C00G P003 Au01 112.8(2) . . ?
C00G P003 C00F 105.6(3) . . ?
C00G P003 C012 108.5(3) . . ?
C012 P003 Au01 106.6(2) . . ?
N00C O006 Au01 115.8(4) . . ?
C00G C00B H00B 119.5 . . ?
C00X C00B H00B 119.5 . . ?
C00X C00B C00G 121.1(5) . . ?
O006 N00C C01K 116.4(5) . . ?
C00K N00C O006 121.7(5) . . ?
C00K N00C C01K 121.7(6) . . ?
C00E C00D H00D 119.8 . . ?
C00H C00D H00D 119.8 . . ?
C00H C00D C00E 120.4(5) . . ?
C00D C00E H00E 120.0 . . ?
C00D C00E C00I 120.1(5) . . ?
C00I C00E H00E 120.0 . . ?
C00J C00F P003 106.4(4) . . ?
C00O C00F P003 108.7(4) . . ?
C00O C00F C00J 109.3(5) . . ?
C00O C00F C00W 110.1(5) . . ?
C00W C00F P003 114.7(4) . . ?
C00W C00F C00J 107.5(5) . . ?
C00B C00G P003 117.8(4) . . ?
C00B C00G C00Q 119.1(5) . . ?
C00Q C00G P003 123.2(4) . . ?
C00D C00H H00H 120.1 . . ?
C00D C00H C00N 119.9(5) . . ?
C00N C00H H00H 120.1 . . ?
C00E C00I C00Q 121.4(5) . . ?
C00P C00I C00E 118.9(5) . . ?
C00P C00I C00Q 119.4(5) . . ?
C00F C00J H00A 109.5 . . ?
C00F C00J H00C 109.5 . . ?
C00F C00J H00F 109.5 . . ?
H00A C00J H00C 109.5 . . ?
H00A C00J H00F 109.5 . . ?
H00C C00J H00F 109.5 . . ?
N00C C00K H00K 119.9 . . ?
N00C C00K C00T 120.2(6) . . ?
C00T C00K H00K 119.9 . . ?
C00Q C00L H00L 118.9 . . ?
C00Y C00L H00L 118.9 . . ?
C00Y C00L C00Q 122.3(6) . . ?
C00H C00N H00N 120.0 . . ?
C00P C00N C00H 120.0(6) . . ?
C00P C00N H00N 120.0 . . ?
C00F C00O H00G 109.5 . . ?
C00F C00O H00I 109.5 . . ?
C00F C00O H00J 109.5 . . ?
H00G C00O H00I 109.5 . . ?
H00G C00O H00J 109.5 . . ?
H00I C00O H00J 109.5 . . ?
C00I C00P H00P 119.6 . . ?
C00N C00P C00I 120.8(6) . . ?
C00N C00P H00P 119.6 . . ?
C00G C00Q C00I 126.5(5) . . ?
C00L C00Q C00G 118.1(5) . . ?
C00L C00Q C00I 115.4(5) . . ?
H00M C00R H00O 109.5 . . ?
H00M C00R H00Q 109.5 . . ?
H00O C00R H00Q 109.5 . . ?
C012 C00R H00M 109.5 . . ?
C012 C00R H00O 109.5 . . ?
C012 C00R H00Q 109.5 . . ?
C00T C00S H00S 120.3 . . ?
C00V C00S H00S 120.3 . . ?
C00V C00S C00T 119.5(7) . . ?
C00K C00T C00S 119.4(7) . . ?
C00K C00T H00T 120.3 . . ?
C00S C00T H00T 120.3 . . ?
C00S C00V H00V 119.8 . . ?
C00S C00V C01K 120.4(7) . . ?
C01K C00V H00V 119.8 . . ?
C00F C00W H00R 109.5 . . ?
C00F C00W H00U 109.5 . . ?
C00F C00W H00W 109.5 . . ?
H00R C00W H00U 109.5 . . ?
H00R C00W H00W 109.5 . . ?
H00U C00W H00W 109.5 . . ?
C00B C00X H00X 119.8 . . ?
C00Y C00X C00B 120.3(6) . . ?
C00Y C00X H00X 119.8 . . ?
C00L C00Y H00Y 120.4 . . ?
C00X C00Y C00L 119.2(5) . . ?
C00X C00Y H00Y 120.4 . . ?
C00R C012 P003 109.0(4) . . ?
C018 C012 P003 116.1(5) . . ?
C018 C012 C00R 108.2(6) . . ?
C01B C012 P003 105.5(5) . . ?
C01B C012 C00R 108.6(6) . . ?
C01B C012 C018 109.2(7) . . ?
C012 C018 H01A 109.5 . . ?
C012 C018 H01B 109.5 . . ?
C012 C018 H01C 109.5 . . ?
H01A C018 H01B 109.5 . . ?
H01A C018 H01C 109.5 . . ?
H01B C018 H01C 109.5 . . ?
C012 C01B H01D 109.5 . . ?
C012 C01B H01E 109.5 . . ?
C012 C01B H01F 109.5 . . ?
H01D C01B H01E 109.5 . . ?
H01D C01B H01F 109.5 . . ?
H01E C01B H01F 109.5 . . ?
N00C C01K C00V 118.8(7) . . ?
N00C C01K H01K 120.6 . . ?
C00V C01K H01K 120.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P003 C00F C00J -50.9(4) . . . . ?
Au01 P003 C00F C00O 66.7(5) . . . . ?
Au01 P003 C00F C00W -169.6(4) . . . . ?
Au01 P003 C00G C00B -168.8(4) . . . . ?
Au01 P003 C00G C00Q 9.4(6) . . . . ?
Au01 P003 C012 C00R -39.6(5) . . . . ?
Au01 P003 C012 C018 -162.0(5) . . . . ?
Au01 P003 C012 C01B 76.9(5) . . . . ?
Au01 O006 N00C C00K -47.3(7) . . . . ?
Au01 O006 N00C C01K 137.2(5) . . . . ?
P003 C00G C00Q C00I -0.2(9) . . . . ?
P003 C00G C00Q C00L -179.2(5) . . . . ?
O006 N00C C00K C00T -176.4(6) . . . . ?
O006 N00C C01K C00V 176.6(6) . . . . ?
C00B C00G C00Q C00I 178.1(6) . . . . ?
C00B C00G C00Q C00L -0.9(9) . . . . ?
C00B C00X C00Y C00L -0.3(10) . . . . ?
N00C C00K C00T C00S 0.4(10) . . . . ?
C00D C00E C00I C00P 0.8(8) . . . . ?
C00D C00E C00I C00Q 174.5(5) . . . . ?
C00D C00H C00N C00P -0.4(9) . . . . ?
C00E C00D C00H C00N 0.4(9) . . . . ?
C00E C00I C00P C00N -0.8(9) . . . . ?
C00E C00I C00Q C00G 77.8(8) . . . . ?
C00E C00I C00Q C00L -103.2(7) . . . . ?
C00F P003 C00G C00B 71.3(5) . . . . ?
C00F P003 C00G C00Q -110.5(5) . . . . ?
C00F P003 C012 C00R 81.5(5) . . . . ?
C00F P003 C012 C018 -40.9(6) . . . . ?
C00F P003 C012 C01B -162.0(5) . . . . ?
C00G P003 C00F C00J 71.0(5) . . . . ?
C00G P003 C00F C00O -171.5(4) . . . . ?
C00G P003 C00F C00W -47.7(5) . . . . ?
C00G P003 C012 C00R -161.3(4) . . . . ?
C00G P003 C012 C018 76.3(6) . . . . ?
C00G P003 C012 C01B -44.8(6) . . . . ?
C00G C00B C00X C00Y 0.0(10) . . . . ?
C00H C00D C00E C00I -0.7(8) . . . . ?
C00H C00N C00P C00I 0.5(10) . . . . ?
C00K N00C C01K C00V 1.0(10) . . . . ?
C00P C00I C00Q C00G -108.6(7) . . . . ?
C00P C00I C00Q C00L 70.4(7) . . . . ?
C00Q C00I C00P C00N -174.6(6) . . . . ?
C00Q C00L C00Y C00X -0.1(10) . . . . ?
C00S C00V C01K N00C -0.2(11) . . . . ?
C00T C00S C00V C01K -0.4(12) . . . . ?
C00V C00S C00T C00K 0.4(11) . . . . ?
C00X C00B C00G P003 178.9(5) . . . . ?
C00X C00B C00G C00Q 0.6(9) . . . . ?
C00Y C00L C00Q C00G 0.7(10) . . . . ?
C00Y C00L C00Q C00I -178.4(6) . . . . ?
C012 P003 C00F C00J -170.2(4) . . . . ?
C012 P003 C00F C00O -52.6(5) . . . . ?
C012 P003 C00F C00W 71.1(5) . . . . ?
C012 P003 C00G C00B -51.0(5) . . . . ?
C012 P003 C00G C00Q 127.3(5) . . . . ?
C01K N00C C00K C00T -1.1(10) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Dichloromethane, diethyl ether'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-101
_audit_block_doi                 10.5517/ccdc.csd.cc1nzmw4
_database_code_depnum_ccdc_archive 'CCDC 1548787'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-05-13
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H36 Au N O P, F6 Sb'
_chemical_formula_sum            'C30 H36 Au F6 N O P Sb'
_chemical_formula_weight         890.28
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.2962(8)
_cell_length_b                   20.4180(17)
_cell_length_c                   15.2295(12)
_cell_angle_alpha                90
_cell_angle_beta                 95.669(2)
_cell_angle_gamma                90
_cell_volume                     3186.0(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9972
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      33.82
_cell_measurement_theta_min      2.22
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.557
_exptl_absorpt_correction_T_max  0.7467
_exptl_absorpt_correction_T_min  0.3084
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1533 before and 0.0539 after correction.
The Ratio of minimum to maximum transmission is 0.4130.
The λ/2 correction factor is Not present.
;

_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.856
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1720
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_unetI/netI     0.0374
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            38007
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         33.825
_diffrn_reflns_theta_min         2.224
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10988
_reflns_number_total             12716
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'

_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_refine_diff_density_max         3.169
_refine_diff_density_min         -3.085
_refine_diff_density_rms         0.197
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     377
_refine_ls_number_reflns         12716
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0566
_refine_ls_R_factor_gt           0.0453
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0469P)²+15.8279P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1062
_refine_ls_wR_factor_ref         0.1122
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00F(H00F), C00H(H00H), C00K(H00K), C00L(H00L), C00N(H00N), C00P(H00P),
 C00Q(H00Q), C00R(H00R), C00S(H00S), C00T(H00T), C00U(H00U), C00V(H00V),
 C00Y(H00Y), C010(H010), C011(H011)
2.b Idealised Me refined as rotating group:
 C00W(H00A,H00B,H00C), C00X(H00D,H00E,H00G), C00Z(H00I,H00J,H00M), C012(H01A,
 H01B,H01C), C013(H01D,H01E,H01F), C014(H01G,H01H,H01I), C015(H01J,H01K,H01L)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.28173(2) 0.58920(2) 0.24949(2) 0.01924(4) Uani 1 1 d . . . . .
Sb02 Sb 0.50314(3) 0.31736(2) 0.14579(2) 0.02480(6) Uani 1 1 d . . . . .
P003 P 0.48393(9) 0.62699(5) 0.28490(6) 0.01556(16) Uani 1 1 d . . . . .
O004 O 0.0956(3) 0.55180(18) 0.2139(2) 0.0302(7) Uani 1 1 d . . . . .
F005 F 0.5242(4) 0.38524(18) 0.0664(2) 0.0461(8) Uani 1 1 d . . . . .
N006 N 0.0210(3) 0.57614(17) 0.1457(2) 0.0188(6) Uani 1 1 d . . . . .
F007 F 0.3769(4) 0.3687(2) 0.1941(3) 0.0554(11) Uani 1 1 d . . . . .
F008 F 0.3741(4) 0.28314(18) 0.0632(3) 0.0625(13) Uani 1 1 d . . . . .
F009 F 0.6260(4) 0.2667(2) 0.0953(3) 0.0648(13) Uani 1 1 d . . . . .
F00A F 0.6327(4) 0.3519(2) 0.2260(3) 0.0674(14) Uani 1 1 d . . . . .
C00B C 0.4382(4) 0.62262(18) 0.4675(3) 0.0189(6) Uani 1 1 d . . . . .
C00C C -0.1425(4) 0.5623(2) 0.0246(3) 0.0220(7) Uani 1 1 d . . . . .
C00D C 0.5224(4) 0.64025(19) 0.4034(3) 0.0186(6) Uani 1 1 d . . . . .
C00E C -0.0645(4) 0.53441(18) 0.0974(3) 0.0181(6) Uani 1 1 d . . . . .
C00F C 0.0243(4) 0.6414(2) 0.1290(3) 0.0284(9) Uani 1 1 d . . . . .
H00F H 0.0804 0.6688 0.1661 0.034 Uiso 1 1 calc R . . . .
F00G F 0.4761(7) 0.2506(2) 0.2249(4) 0.0892(18) Uani 1 1 d . . . . .
C00H C 0.6432(4) 0.6692(2) 0.4323(3) 0.0251(8) Uani 1 1 d . . . . .
H00H H 0.7009 0.6810 0.3900 0.030 Uiso 1 1 calc R . . . .
C00I C 0.3079(4) 0.5915(2) 0.4477(3) 0.0209(7) Uani 1 1 d . . . . .
C00J C 0.4935(4) 0.7089(2) 0.2299(3) 0.0232(7) Uani 1 1 d . . . . .
C00K C -0.2299(4) 0.5214(2) -0.0289(3) 0.0249(8) Uani 1 1 d . . . . .
H00K H -0.2810 0.5389 -0.0787 0.030 Uiso 1 1 calc R . . . .
C00L C 0.0604(5) 0.5341(3) 0.4167(3) 0.0351(11) Uani 1 1 d . . . . .
H00L H -0.0235 0.5148 0.4048 0.042 Uiso 1 1 calc R . . . .
C00M C 0.6053(4) 0.5650(2) 0.2535(3) 0.0223(7) Uani 1 1 d . . . . .
C00N C 0.1715(5) 0.4952(3) 0.4230(3) 0.0325(10) Uani 1 1 d . . . . .
H00N H 0.1634 0.4490 0.4162 0.039 Uiso 1 1 calc R . . . .
C00O C -0.0749(4) 0.4671(2) 0.1195(3) 0.0225(7) Uani 1 1 d . . . . .
C00P C 0.1955(5) 0.6298(2) 0.4434(4) 0.0321(9) Uani 1 1 d . . . . .
H00P H 0.2027 0.6758 0.4513 0.039 Uiso 1 1 calc R . . . .
C00Q C -0.1639(4) 0.4305(2) 0.0653(3) 0.0237(7) Uani 1 1 d . . . . .
H00Q H -0.1738 0.3854 0.0785 0.028 Uiso 1 1 calc R . . . .
C00R C -0.1348(5) 0.6297(2) 0.0055(4) 0.0302(9) Uani 1 1 d . . . . .
H00R H -0.1862 0.6477 -0.0439 0.036 Uiso 1 1 calc R . . . .
C00S C 0.2947(4) 0.5234(2) 0.4391(3) 0.0264(8) Uani 1 1 d . . . . .
H00S H 0.3702 0.4964 0.4444 0.032 Uiso 1 1 calc R . . . .
C00T C -0.2395(4) 0.4565(2) -0.0076(3) 0.0252(8) Uani 1 1 d . . . . .
H00T H -0.2981 0.4290 -0.0428 0.030 Uiso 1 1 calc R . . . .
C00U C 0.0728(5) 0.6013(3) 0.4277(4) 0.0371(11) Uani 1 1 d . . . . .
H00U H -0.0030 0.6280 0.4246 0.044 Uiso 1 1 calc R . . . .
C00V C -0.0533(5) 0.6691(2) 0.0582(4) 0.0332(10) Uani 1 1 d . . . . .
H00V H -0.0493 0.7148 0.0468 0.040 Uiso 1 1 calc R . . . .
C00W C 0.5749(6) 0.5463(3) 0.1566(3) 0.0382(12) Uani 1 1 d . . . . .
H00A H 0.4809 0.5391 0.1438 0.057 Uiso 1 1 calc GR . . . .
H00B H 0.6219 0.5060 0.1446 0.057 Uiso 1 1 calc GR . . . .
H00C H 0.6026 0.5817 0.1192 0.057 Uiso 1 1 calc GR . . . .
C00X C 0.4426(9) 0.7017(3) 0.1323(4) 0.057(2) Uani 1 1 d . . . . .
H00D H 0.4974 0.6704 0.1039 0.086 Uiso 1 1 calc GR . . . .
H00E H 0.4456 0.7443 0.1029 0.086 Uiso 1 1 calc GR . . . .
H00G H 0.3525 0.6857 0.1275 0.086 Uiso 1 1 calc GR . . . .
C00Y C 0.5978(5) 0.6635(2) 0.5837(3) 0.0307(9) Uani 1 1 d . . . . .
H00Y H 0.6234 0.6707 0.6445 0.037 Uiso 1 1 calc R . . . .
C00Z C 0.3980(8) 0.7532(3) 0.2728(5) 0.057(2) Uani 1 1 d . . . . .
H00I H 0.3136 0.7309 0.2728 0.085 Uiso 1 1 calc GR . . . .
H00J H 0.3865 0.7942 0.2396 0.085 Uiso 1 1 calc GR . . . .
H00M H 0.4327 0.7627 0.3337 0.085 Uiso 1 1 calc GR . . . .
C010 C 0.4775(5) 0.6353(2) 0.5567(3) 0.0260(8) Uani 1 1 d . . . . .
H010 H 0.4203 0.6245 0.5998 0.031 Uiso 1 1 calc R . . . .
C011 C 0.6799(5) 0.6808(2) 0.5208(3) 0.0321(10) Uani 1 1 d . . . . .
H011 H 0.7617 0.7007 0.5384 0.038 Uiso 1 1 calc R . . . .
C012 C -0.0020(6) 0.4325(2) 0.1963(4) 0.0359(11) Uani 1 1 d . . . . .
H01A H 0.0917 0.4334 0.1898 0.054 Uiso 1 1 calc GR . . . .
H01B H -0.0316 0.3869 0.1979 0.054 Uiso 1 1 calc GR . . . .
H01C H -0.0185 0.4545 0.2513 0.054 Uiso 1 1 calc GR . . . .
C013 C 0.6257(6) 0.7420(4) 0.2348(7) 0.081(3) Uani 1 1 d . . . . .
H01D H 0.6590 0.7483 0.2967 0.122 Uiso 1 1 calc GR . . . .
H01E H 0.6172 0.7846 0.2051 0.122 Uiso 1 1 calc GR . . . .
H01F H 0.6865 0.7145 0.2056 0.122 Uiso 1 1 calc GR . . . .
C014 C 0.5817(8) 0.5033(3) 0.3080(5) 0.056(2) Uani 1 1 d . . . . .
H01G H 0.6072 0.5121 0.3706 0.084 Uiso 1 1 calc GR . . . .
H01H H 0.6340 0.4671 0.2884 0.084 Uiso 1 1 calc GR . . . .
H01I H 0.4890 0.4916 0.2997 0.084 Uiso 1 1 calc GR . . . .
C015 C 0.7467(6) 0.5836(4) 0.2717(6) 0.065(3) Uani 1 1 d . . . . .
H01J H 0.7644 0.6226 0.2373 0.098 Uiso 1 1 calc GR . . . .
H01K H 0.8015 0.5473 0.2550 0.098 Uiso 1 1 calc GR . . . .
H01L H 0.7665 0.5930 0.3347 0.098 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2358(9) . ?
Au01 O004 2.085(3) . ?
Sb02 F005 1.866(3) . ?
Sb02 F007 1.876(3) . ?
Sb02 F008 1.872(4) . ?
Sb02 F009 1.859(3) . ?
Sb02 F00A 1.857(4) . ?
Sb02 F00G 1.858(4) . ?
P003 C00D 1.829(4) . ?
P003 C00J 1.879(4) . ?
P003 C00M 1.873(4) . ?
O004 N006 1.326(5) . ?
N006 C00E 1.383(5) . ?
N006 C00F 1.358(6) . ?
C00B C00D 1.414(5) . ?
C00B C00I 1.488(6) . ?
C00B C010 1.402(6) . ?
C00C C00E 1.421(6) . ?
C00C C00K 1.424(6) . ?
C00C C00R 1.412(6) . ?
C00D C00H 1.408(6) . ?
C00E C00O 1.422(5) . ?
C00F H00F 0.9500 . ?
C00F C00V 1.396(7) . ?
C00H H00H 0.9500 . ?
C00H C011 1.383(6) . ?
C00I C00P 1.393(6) . ?
C00I C00S 1.402(6) . ?
C00J C00X 1.533(7) . ?
C00J C00Z 1.529(8) . ?
C00J C013 1.515(7) . ?
C00K H00K 0.9500 . ?
C00K C00T 1.370(6) . ?
C00L H00L 0.9500 . ?
C00L C00N 1.388(8) . ?
C00L C00U 1.387(8) . ?
C00M C00W 1.527(6) . ?
C00M C014 1.541(7) . ?
C00M C015 1.504(7) . ?
C00N H00N 0.9500 . ?
C00N C00S 1.394(7) . ?
C00O C00Q 1.390(6) . ?
C00O C012 1.502(6) . ?
C00P H00P 0.9500 . ?
C00P C00U 1.389(8) . ?
C00Q H00Q 0.9500 . ?
C00Q C00T 1.397(6) . ?
C00R H00R 0.9500 . ?
C00R C00V 1.364(7) . ?
C00S H00S 0.9500 . ?
C00T H00T 0.9500 . ?
C00U H00U 0.9500 . ?
C00V H00V 0.9500 . ?
C00W H00A 0.9800 . ?
C00W H00B 0.9800 . ?
C00W H00C 0.9800 . ?
C00X H00D 0.9800 . ?
C00X H00E 0.9800 . ?
C00X H00G 0.9800 . ?
C00Y H00Y 0.9500 . ?
C00Y C010 1.390(7) . ?
C00Y C011 1.384(8) . ?
C00Z H00I 0.9800 . ?
C00Z H00J 0.9800 . ?
C00Z H00M 0.9800 . ?
C010 H010 0.9500 . ?
C011 H011 0.9500 . ?
C012 H01A 0.9800 . ?
C012 H01B 0.9800 . ?
C012 H01C 0.9800 . ?
C013 H01D 0.9800 . ?
C013 H01E 0.9800 . ?
C013 H01F 0.9800 . ?
C014 H01G 0.9800 . ?
C014 H01H 0.9800 . ?
C014 H01I 0.9800 . ?
C015 H01J 0.9800 . ?
C015 H01K 0.9800 . ?
C015 H01L 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O004 Au01 P003 178.20(11) . . ?
F005 Sb02 F007 88.18(17) . . ?
F005 Sb02 F008 87.80(19) . . ?
F008 Sb02 F007 89.9(2) . . ?
F009 Sb02 F005 91.0(2) . . ?
F009 Sb02 F007 178.62(17) . . ?
F009 Sb02 F008 88.9(2) . . ?
F00A Sb02 F005 91.3(2) . . ?
F00A Sb02 F007 90.6(2) . . ?
F00A Sb02 F008 178.9(2) . . ?
F00A Sb02 F009 90.54(19) . . ?
F00A Sb02 F00G 89.8(3) . . ?
F00G Sb02 F005 178.0(2) . . ?
F00G Sb02 F007 90.1(2) . . ?
F00G Sb02 F008 91.1(3) . . ?
F00G Sb02 F009 90.6(2) . . ?
C00D P003 Au01 113.24(13) . . ?
C00D P003 C00J 107.02(19) . . ?
C00D P003 C00M 105.49(18) . . ?
C00J P003 Au01 106.75(13) . . ?
C00M P003 Au01 109.52(14) . . ?
C00M P003 C00J 115.0(2) . . ?
N006 O004 Au01 120.9(2) . . ?
O004 N006 C00E 118.3(3) . . ?
O004 N006 C00F 119.5(3) . . ?
C00F N006 C00E 122.1(4) . . ?
C00D C00B C00I 124.8(4) . . ?
C010 C00B C00D 118.9(4) . . ?
C010 C00B C00I 116.3(4) . . ?
C00E C00C C00K 119.2(4) . . ?
C00R C00C C00E 120.8(4) . . ?
C00R C00C C00K 119.9(4) . . ?
C00B C00D P003 123.7(3) . . ?
C00H C00D P003 118.0(3) . . ?
C00H C00D C00B 118.3(4) . . ?
N006 C00E C00C 116.7(3) . . ?
N006 C00E C00O 121.9(4) . . ?
C00C C00E C00O 121.4(4) . . ?
N006 C00F H00F 119.4 . . ?
N006 C00F C00V 121.3(4) . . ?
C00V C00F H00F 119.4 . . ?
C00D C00H H00H 119.2 . . ?
C011 C00H C00D 121.7(4) . . ?
C011 C00H H00H 119.2 . . ?
C00P C00I C00B 119.9(4) . . ?
C00P C00I C00S 118.6(4) . . ?
C00S C00I C00B 121.3(4) . . ?
C00X C00J P003 108.6(3) . . ?
C00Z C00J P003 105.7(3) . . ?
C00Z C00J C00X 107.4(5) . . ?
C013 C00J P003 117.5(3) . . ?
C013 C00J C00X 108.0(6) . . ?
C013 C00J C00Z 109.2(6) . . ?
C00C C00K H00K 120.4 . . ?
C00T C00K C00C 119.2(4) . . ?
C00T C00K H00K 120.4 . . ?
C00N C00L H00L 120.3 . . ?
C00U C00L H00L 120.3 . . ?
C00U C00L C00N 119.5(5) . . ?
C00W C00M P003 109.8(3) . . ?
C00W C00M C014 106.7(5) . . ?
C014 C00M P003 105.7(3) . . ?
C015 C00M P003 116.2(3) . . ?
C015 C00M C00W 110.1(5) . . ?
C015 C00M C014 107.9(6) . . ?
C00L C00N H00N 119.8 . . ?
C00L C00N C00S 120.3(5) . . ?
C00S C00N H00N 119.8 . . ?
C00E C00O C012 126.6(4) . . ?
C00Q C00O C00E 116.1(4) . . ?
C00Q C00O C012 117.3(4) . . ?
C00I C00P H00P 119.7 . . ?
C00U C00P C00I 120.7(5) . . ?
C00U C00P H00P 119.7 . . ?
C00O C00Q H00Q 118.3 . . ?
C00O C00Q C00T 123.4(4) . . ?
C00T C00Q H00Q 118.3 . . ?
C00C C00R H00R 120.1 . . ?
C00V C00R C00C 119.8(4) . . ?
C00V C00R H00R 120.1 . . ?
C00I C00S H00S 119.8 . . ?
C00N C00S C00I 120.4(4) . . ?
C00N C00S H00S 119.8 . . ?
C00K C00T C00Q 120.5(4) . . ?
C00K C00T H00T 119.7 . . ?
C00Q C00T H00T 119.7 . . ?
C00L C00U C00P 120.5(5) . . ?
C00L C00U H00U 119.8 . . ?
C00P C00U H00U 119.8 . . ?
C00F C00V H00V 120.4 . . ?
C00R C00V C00F 119.2(4) . . ?
C00R C00V H00V 120.4 . . ?
C00M C00W H00A 109.5 . . ?
C00M C00W H00B 109.5 . . ?
C00M C00W H00C 109.5 . . ?
H00A C00W H00B 109.5 . . ?
H00A C00W H00C 109.5 . . ?
H00B C00W H00C 109.5 . . ?
C00J C00X H00D 109.5 . . ?
C00J C00X H00E 109.5 . . ?
C00J C00X H00G 109.5 . . ?
H00D C00X H00E 109.5 . . ?
H00D C00X H00G 109.5 . . ?
H00E C00X H00G 109.5 . . ?
C010 C00Y H00Y 120.4 . . ?
C011 C00Y H00Y 120.4 . . ?
C011 C00Y C010 119.2(4) . . ?
C00J C00Z H00I 109.5 . . ?
C00J C00Z H00J 109.5 . . ?
C00J C00Z H00M 109.5 . . ?
H00I C00Z H00J 109.5 . . ?
H00I C00Z H00M 109.5 . . ?
H00J C00Z H00M 109.5 . . ?
C00B C010 H010 119.1 . . ?
C00Y C010 C00B 121.7(4) . . ?
C00Y C010 H010 119.1 . . ?
C00H C011 C00Y 120.2(4) . . ?
C00H C011 H011 119.9 . . ?
C00Y C011 H011 119.9 . . ?
C00O C012 H01A 109.5 . . ?
C00O C012 H01B 109.5 . . ?
C00O C012 H01C 109.5 . . ?
H01A C012 H01B 109.5 . . ?
H01A C012 H01C 109.5 . . ?
H01B C012 H01C 109.5 . . ?
C00J C013 H01D 109.5 . . ?
C00J C013 H01E 109.5 . . ?
C00J C013 H01F 109.5 . . ?
H01D C013 H01E 109.5 . . ?
H01D C013 H01F 109.5 . . ?
H01E C013 H01F 109.5 . . ?
C00M C014 H01G 109.5 . . ?
C00M C014 H01H 109.5 . . ?
C00M C014 H01I 109.5 . . ?
H01G C014 H01H 109.5 . . ?
H01G C014 H01I 109.5 . . ?
H01H C014 H01I 109.5 . . ?
C00M C015 H01J 109.5 . . ?
C00M C015 H01K 109.5 . . ?
C00M C015 H01L 109.5 . . ?
H01J C015 H01K 109.5 . . ?
H01J C015 H01L 109.5 . . ?
H01K C015 H01L 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P003 C00D C00B 5.8(4) . . . . ?
Au01 P003 C00D C00H -174.8(3) . . . . ?
Au01 P003 C00J C00X -50.3(5) . . . . ?
Au01 P003 C00J C00Z 64.7(4) . . . . ?
Au01 P003 C00J C013 -173.2(6) . . . . ?
Au01 P003 C00M C00W 53.4(4) . . . . ?
Au01 P003 C00M C014 -61.4(4) . . . . ?
Au01 P003 C00M C015 179.0(5) . . . . ?
Au01 O004 N006 C00E 148.0(3) . . . . ?
Au01 O004 N006 C00F -36.3(5) . . . . ?
P003 C00D C00H C011 -179.9(4) . . . . ?
O004 N006 C00E C00C -179.8(4) . . . . ?
O004 N006 C00E C00O 0.6(6) . . . . ?
O004 N006 C00F C00V -179.6(4) . . . . ?
N006 C00E C00O C00Q -179.6(4) . . . . ?
N006 C00E C00O C012 1.9(7) . . . . ?
N006 C00F C00V C00R 0.7(8) . . . . ?
C00B C00D C00H C011 -0.4(6) . . . . ?
C00B C00I C00P C00U -178.0(5) . . . . ?
C00B C00I C00S C00N 178.2(4) . . . . ?
C00C C00E C00O C00Q 0.9(6) . . . . ?
C00C C00E C00O C012 -177.6(5) . . . . ?
C00C C00K C00T C00Q -0.4(7) . . . . ?
C00C C00R C00V C00F 1.8(8) . . . . ?
C00D P003 C00J C00X -171.9(4) . . . . ?
C00D P003 C00J C00Z -56.8(4) . . . . ?
C00D P003 C00J C013 65.2(6) . . . . ?
C00D P003 C00M C00W 175.6(4) . . . . ?
C00D P003 C00M C014 60.8(4) . . . . ?
C00D P003 C00M C015 -58.8(6) . . . . ?
C00D C00B C00I C00P -98.4(5) . . . . ?
C00D C00B C00I C00S 86.1(5) . . . . ?
C00D C00B C010 C00Y -1.4(6) . . . . ?
C00D C00H C011 C00Y 0.5(7) . . . . ?
C00E N006 C00F C00V -4.1(7) . . . . ?
C00E C00C C00K C00T 1.7(6) . . . . ?
C00E C00C C00R C00V -1.1(7) . . . . ?
C00E C00O C00Q C00T 0.5(6) . . . . ?
C00F N006 C00E C00C 4.7(6) . . . . ?
C00F N006 C00E C00O -174.9(4) . . . . ?
C00I C00B C00D P003 -0.3(5) . . . . ?
C00I C00B C00D C00H -179.8(4) . . . . ?
C00I C00B C010 C00Y 179.1(4) . . . . ?
C00I C00P C00U C00L 0.4(8) . . . . ?
C00J P003 C00D C00B 123.1(3) . . . . ?
C00J P003 C00D C00H -57.4(4) . . . . ?
C00J P003 C00M C00W -66.8(4) . . . . ?
C00J P003 C00M C014 178.5(4) . . . . ?
C00J P003 C00M C015 58.9(6) . . . . ?
C00K C00C C00E N006 178.4(4) . . . . ?
C00K C00C C00E C00O -2.0(6) . . . . ?
C00K C00C C00R C00V 178.4(5) . . . . ?
C00L C00N C00S C00I -1.1(7) . . . . ?
C00M P003 C00D C00B -114.0(3) . . . . ?
C00M P003 C00D C00H 65.5(4) . . . . ?
C00M P003 C00J C00X 71.3(5) . . . . ?
C00M P003 C00J C00Z -173.6(4) . . . . ?
C00M P003 C00J C013 -51.6(6) . . . . ?
C00N C00L C00U C00P 1.2(8) . . . . ?
C00O C00Q C00T C00K -0.7(7) . . . . ?
C00P C00I C00S C00N 2.7(7) . . . . ?
C00R C00C C00E N006 -2.1(6) . . . . ?
C00R C00C C00E C00O 177.5(4) . . . . ?
C00R C00C C00K C00T -177.8(4) . . . . ?
C00S C00I C00P C00U -2.4(7) . . . . ?
C00U C00L C00N C00S -0.9(8) . . . . ?
C010 C00B C00D P003 -179.7(3) . . . . ?
C010 C00B C00D C00H 0.8(6) . . . . ?
C010 C00B C00I C00P 81.0(5) . . . . ?
C010 C00B C00I C00S -94.4(5) . . . . ?
C010 C00Y C011 C00H -1.0(7) . . . . ?
C011 C00Y C010 C00B 1.5(7) . . . . ?
C012 C00O C00Q C00T 179.2(5) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-107-plate
_audit_block_doi                 10.5517/ccdc.csd.cc1nzmy6
_database_code_depnum_ccdc_archive 'CCDC 1548789'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-06-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H41 Au N3 O, F6 Sb'
_chemical_formula_sum            'C32 H41 Au F6 N3 O Sb'
_chemical_formula_weight         916.39
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.3868(9)
_cell_length_b                   16.4862(11)
_cell_length_c                   15.8416(10)
_cell_angle_alpha                90
_cell_angle_beta                 99.7790(10)
_cell_angle_gamma                90
_cell_volume                     3445.4(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    200
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      2.220
_cell_measurement_theta_min      25.242
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.098
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
 SADABS-2014/5 (Bruker,2016) was used for absorption correction.
 
82327 Corrected reflections written to file mo_HFJ_107plate_0m.hkl
 Estimated minimum and maximum transmission:  0.5598  0.7464
 The ratio of these values is more reliable than their absolute values!
 Additional spherical absorption correction applied with mu*r =  0.2000

;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.767
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   0.7464
_exptl_transmission_factor_min   0.5598
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_av_unetI/netI     0.0237
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            80949
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.661
_diffrn_reflns_theta_min         2.220
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10966
_reflns_number_total             12609
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_refine_diff_density_max         1.046
_refine_diff_density_min         -1.108
_refine_diff_density_rms         0.104
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         12609
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0300
_refine_ls_R_factor_gt           0.0215
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0161P)²+3.5787P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0431
_refine_ls_wR_factor_ref         0.0456
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Others
 Fixed Sof: H00S(0.5) H00A(0.5) C016(0.5) H01J(0.5) H01K(0.5) H01L(0.5)
 C017(0.5) H01M(0.5) H01N(0.5) H01O(0.5) C1(0.5) H1A(0.5) H1B(0.5) H1C(0.5)
 C7(0.5) H7A(0.5) H7B(0.5) H7C(0.5)
3.a Ternary CH refined with riding coordinates:
 C00S(H00S), C00S(H00A), C00T(H00T), C00V(H00V), C00W(H00W)
3.b Aromatic/amide H refined with riding coordinates:
 C00E(H00E), C00H(H00H), C00J(H00J), C00K(H00K), C00N(H00N), C00P(H00P),
 C00Q(H00Q), C00R(H00R), C00Z(H00Z), C011(H011), C012(H012), C015(H015), C2(H2)
3.c Idealised Me refined with riding coordinates:
 C1(H1A,H1B,H1C)
3.d Idealised Me refined as rotating group:
 C00X(H00B,H00C,H00D), C00Y(H00F,H00G,H00I), C010(H01A,H01B,H01C), C013(H01D,
 H01E,H01F), C014(H01G,H01H,H01I), C016(H01J,H01K,H01L), C017(H01M,H01N,H01O),
 C018(H01P,H01Q,H01R), C7(H7A,H7B,H7C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.59747(2) 0.33782(2) 0.14648(2) 0.01522(2) Uani 1 1 d . . . . .
Sb00 Sb 0.15629(2) 0.41005(2) 0.44159(2) 0.01896(3) Uani 1 1 d . . . . .
O003 O 0.46202(10) 0.30094(10) 0.07731(9) 0.0242(3) Uani 1 1 d . . . . .
F004 F 0.13280(10) 0.43446(9) 0.32372(8) 0.0331(3) Uani 1 1 d . . . . .
F005 F 0.17776(11) 0.38569(9) 0.55885(8) 0.0325(3) Uani 1 1 d . . . . .
F006 F 0.29062(11) 0.38443(12) 0.43619(11) 0.0503(4) Uani 1 1 d . . . . .
F007 F 0.12353(13) 0.30117(9) 0.41548(10) 0.0396(3) Uani 1 1 d . . . . .
F008 F 0.02021(10) 0.43032(10) 0.44493(9) 0.0371(3) Uani 1 1 d . . . . .
N009 N 0.72760(11) 0.42203(9) 0.28674(9) 0.0134(3) Uani 1 1 d . . . . .
F00A F 0.19001(14) 0.51776(9) 0.46797(10) 0.0468(4) Uani 1 1 d . . . . .
C00B C 0.72391(13) 0.37593(10) 0.21586(11) 0.0133(3) Uani 1 1 d . . . . .
N00C N 0.82165(11) 0.36639(10) 0.20631(10) 0.0150(3) Uani 1 1 d . . . . .
N00D N 0.37616(12) 0.31783(10) 0.10769(11) 0.0185(3) Uani 1 1 d . . . . .
C00E C 0.50772(15) 0.43584(13) 0.39995(13) 0.0232(4) Uani 1 1 d . . . . .
H00E H 0.4777 0.4070 0.4411 0.028 Uiso 1 1 calc R . . . .
C00F C 0.85411(14) 0.32599(11) 0.13463(12) 0.0168(3) Uani 1 1 d . . . . .
C00G C 0.63746(13) 0.45199(11) 0.31560(11) 0.0146(3) Uani 1 1 d . . . . .
C00H C 0.37547(16) 0.36058(13) 0.18051(13) 0.0226(4) Uani 1 1 d . . . . .
H00H H 0.4372 0.3807 0.2122 0.027 Uiso 1 1 calc R . . . .
C00I C 0.89438(15) 0.24760(13) 0.14642(12) 0.0211(4) Uani 1 1 d . . . . .
C00J C 0.82658(14) 0.44116(11) 0.32184(12) 0.0164(3) Uani 1 1 d . . . . .
H00J H 0.8485 0.4727 0.3717 0.020 Uiso 1 1 calc R . . . .
C00K C 0.91518(16) 0.25015(15) -0.00207(14) 0.0280(5) Uani 1 1 d . . . . .
H00K H 0.9361 0.2239 -0.0495 0.034 Uiso 1 1 calc R . . . .
C00L C 0.84325(15) 0.36769(13) 0.05661(13) 0.0217(4) Uani 1 1 d . . . . .
C00M C 0.59753(14) 0.40741(11) 0.37693(11) 0.0158(3) Uani 1 1 d . . . . .
C00N C 0.92478(16) 0.21056(14) 0.07562(14) 0.0272(4) Uani 1 1 d . . . . .
H00N H 0.9524 0.1574 0.0810 0.033 Uiso 1 1 calc R . . . .
C00O C 0.59381(15) 0.52308(12) 0.27791(12) 0.0199(4) Uani 1 1 d . . . . .
C00P C 0.28538(17) 0.37488(14) 0.20867(15) 0.0280(4) Uani 1 1 d . . . . .
H00P H 0.2848 0.4044 0.2601 0.034 Uiso 1 1 calc R . . . .
C00Q C 0.87545(17) 0.32768(14) -0.01166(14) 0.0270(4) Uani 1 1 d . . . . .
H00Q H 0.8700 0.3541 -0.0655 0.032 Uiso 1 1 calc R . . . .
C00R C 0.88571(14) 0.40613(12) 0.27126(12) 0.0177(3) Uani 1 1 d . . . . .
H00R H 0.9576 0.4083 0.2787 0.021 Uiso 1 1 calc R . . . .
C00S C 0.7994(2) 0.45306(14) 0.04631(14) 0.0318(5) Uani 1 1 d . . . . .
H00S H 0.7757 0.4682 0.1008 0.038 Uiso 0.5 1 calc R . P A -1
H00A H 0.7477 0.4547 0.0850 0.038 Uiso 0.5 1 calc R . P B 1
C00T C 0.90061(18) 0.20270(14) 0.23093(14) 0.0288(5) Uani 1 1 d . . . . .
H00T H 0.8955 0.2439 0.2763 0.035 Uiso 1 1 calc R . . . .
C00V C 0.64646(15) 0.32975(11) 0.41503(13) 0.0193(4) Uani 1 1 d . . . . .
H00V H 0.7174 0.3282 0.4031 0.023 Uiso 1 1 calc R . . . .
C00W C 0.63887(18) 0.57044(12) 0.21135(14) 0.0262(4) Uani 1 1 d . . . . .
H00W H 0.7037 0.5433 0.2041 0.031 Uiso 1 1 calc R . . . .
C00X C 0.5904(2) 0.25593(14) 0.37231(17) 0.0366(6) Uani 1 1 d . . . . .
H00B H 0.5208 0.2555 0.3840 0.055 Uiso 1 1 calc GR . . . .
H00C H 0.6253 0.2064 0.3952 0.055 Uiso 1 1 calc GR . . . .
H00D H 0.5890 0.2585 0.3103 0.055 Uiso 1 1 calc GR . . . .
C00Y C 0.8096(3) 0.14516(18) 0.22650(17) 0.0449(7) Uani 1 1 d . . . . .
H00F H 0.7465 0.1763 0.2127 0.067 Uiso 1 1 calc GR . . . .
H00G H 0.8121 0.1182 0.2820 0.067 Uiso 1 1 calc GR . . . .
H00I H 0.8121 0.1043 0.1820 0.067 Uiso 1 1 calc GR . . . .
C00Z C 0.19856(16) 0.30335(14) 0.08716(16) 0.0284(4) Uani 1 1 d . . . . .
H00Z H 0.1376 0.2837 0.0539 0.034 Uiso 1 1 calc R . . . .
C010 C 0.5683(2) 0.56889(14) 0.12438(15) 0.0327(5) Uani 1 1 d . . . . .
H01A H 0.5584 0.5127 0.1045 0.049 Uiso 1 1 calc GR . . . .
H01B H 0.5987 0.6004 0.0827 0.049 Uiso 1 1 calc GR . . . .
H01C H 0.5027 0.5926 0.1303 0.049 Uiso 1 1 calc GR . . . .
C011 C 0.28958(15) 0.28924(12) 0.06110(14) 0.0225(4) Uani 1 1 d . . . . .
H011 H 0.2917 0.2593 0.0102 0.027 Uiso 1 1 calc R . . . .
C012 C 0.50385(17) 0.54879(13) 0.30374(15) 0.0280(5) Uani 1 1 d . . . . .
H012 H 0.4713 0.5967 0.2797 0.034 Uiso 1 1 calc R . . . .
C013 C 0.65167(17) 0.32511(14) 0.51182(13) 0.0259(4) Uani 1 1 d . . . . .
H01D H 0.6868 0.3731 0.5387 0.039 Uiso 1 1 calc GR . . . .
H01E H 0.6887 0.2762 0.5339 0.039 Uiso 1 1 calc GR . . . .
H01F H 0.5828 0.3231 0.5251 0.039 Uiso 1 1 calc GR . . . .
C014 C 0.6641(2) 0.65767(14) 0.24092(17) 0.0367(6) Uani 1 1 d . . . . .
H01G H 0.6018 0.6857 0.2488 0.055 Uiso 1 1 calc GR . . . .
H01H H 0.6950 0.6862 0.1976 0.055 Uiso 1 1 calc GR . . . .
H01I H 0.7117 0.6569 0.2953 0.055 Uiso 1 1 calc GR . . . .
C015 C 0.19547(17) 0.34610(14) 0.16174(16) 0.0293(5) Uani 1 1 d . . . . .
H015 H 0.1328 0.3556 0.1805 0.035 Uiso 1 1 calc R . . . .
C016 C 0.7166(7) 0.4620(5) -0.0221(4) 0.0287(14) Uani 0.5 1 d . . P C -1
H01J H 0.7416 0.4610 -0.0767 0.043 Uiso 0.5 1 calc GR . P C -1
H01K H 0.6825 0.5137 -0.0161 0.043 Uiso 0.5 1 calc GR . P C -1
H01L H 0.6686 0.4173 -0.0205 0.043 Uiso 0.5 1 calc GR . P C -1
C017 C 0.8959(5) 0.5121(4) 0.0354(4) 0.0398(13) Uani 0.5 1 d . . P C -1
H01M H 0.9490 0.5067 0.0860 0.060 Uiso 0.5 1 calc GR . P C -1
H01N H 0.8730 0.5686 0.0298 0.060 Uiso 0.5 1 calc GR . P C -1
H01O H 0.9229 0.4961 -0.0158 0.060 Uiso 0.5 1 calc GR . P C -1
C018 C 1.0002(3) 0.1580(2) 0.2567(2) 0.0588(9) Uani 1 1 d . . . . .
H01P H 1.0058 0.1151 0.2149 0.088 Uiso 1 1 calc GR . . . .
H01Q H 1.0025 0.1338 0.3135 0.088 Uiso 1 1 calc GR . . . .
H01R H 1.0567 0.1961 0.2583 0.088 Uiso 1 1 calc GR . . . .
C2 C 0.46190(16) 0.50563(15) 0.36347(15) 0.0289(5) Uani 1 1 d . . . . .
H2 H 0.4007 0.5240 0.3798 0.035 Uiso 1 1 calc R . . . .
C1 C 0.8650(5) 0.5186(4) 0.0732(5) 0.0446(14) Uani 0.5 1 d . . P C 1
H1A H 0.9142 0.5023 0.1234 0.067 Uiso 0.5 1 calc R . P C 1
H1B H 0.8254 0.5648 0.0881 0.067 Uiso 0.5 1 calc R . P C 1
H1C H 0.9010 0.5341 0.0267 0.067 Uiso 0.5 1 calc R . P C 1
C7 C 0.7370(7) 0.4689(5) -0.0468(5) 0.0400(18) Uani 0.5 1 d . . P C 1
H7A H 0.7838 0.4724 -0.0880 0.060 Uiso 0.5 1 calc GR . P C 1
H7B H 0.6993 0.5198 -0.0471 0.060 Uiso 0.5 1 calc GR . P C 1
H7C H 0.6895 0.4241 -0.0629 0.060 Uiso 0.5 1 calc GR . P C 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 O003 2.0454(14) . ?
Au01 C00B 1.9585(17) . ?
Sb00 F004 1.8836(13) . ?
Sb00 F005 1.8744(13) . ?
Sb00 F006 1.8633(14) . ?
Sb00 F007 1.8773(14) . ?
Sb00 F008 1.8616(13) . ?
Sb00 F00A 1.8621(15) . ?
O003 N00D 1.348(2) . ?
N009 C00B 1.350(2) . ?
N009 C00G 1.448(2) . ?
N009 C00J 1.383(2) . ?
C00B N00C 1.352(2) . ?
N00C C00F 1.445(2) . ?
N00C C00R 1.387(2) . ?
N00D C00H 1.353(3) . ?
N00D C011 1.349(2) . ?
C00E H00E 0.9500 . ?
C00E C00M 1.395(3) . ?
C00E C2 1.383(3) . ?
C00F C00I 1.401(3) . ?
C00F C00L 1.400(3) . ?
C00G C00M 1.395(3) . ?
C00G C00O 1.398(3) . ?
C00H H00H 0.9500 . ?
C00H C00P 1.375(3) . ?
C00I C00N 1.397(3) . ?
C00I C00T 1.520(3) . ?
C00J H00J 0.9500 . ?
C00J C00R 1.348(3) . ?
C00K H00K 0.9500 . ?
C00K C00N 1.380(3) . ?
C00K C00Q 1.383(3) . ?
C00L C00Q 1.396(3) . ?
C00L C00S 1.523(3) . ?
C00M C00V 1.516(3) . ?
C00N H00N 0.9500 . ?
C00O C00W 1.517(3) . ?
C00O C012 1.402(3) . ?
C00P H00P 0.9500 . ?
C00P C015 1.387(3) . ?
C00Q H00Q 0.9500 . ?
C00R H00R 0.9500 . ?
C00S H00S 1.0000 . ?
C00S H00A 1.0000 . ?
C00S C016 1.420(9) . ?
C00S C017 1.649(6) . ?
C00S C1 1.412(6) . ?
C00S C7 1.589(9) . ?
C00T H00T 1.0000 . ?
C00T C00Y 1.536(4) . ?
C00T C018 1.518(4) . ?
C00V H00V 1.0000 . ?
C00V C00X 1.526(3) . ?
C00V C013 1.525(3) . ?
C00W H00W 1.0000 . ?
C00W C010 1.533(3) . ?
C00W C014 1.532(3) . ?
C00X H00B 0.9800 . ?
C00X H00C 0.9800 . ?
C00X H00D 0.9800 . ?
C00Y H00F 0.9800 . ?
C00Y H00G 0.9800 . ?
C00Y H00I 0.9800 . ?
C00Z H00Z 0.9500 . ?
C00Z C011 1.371(3) . ?
C00Z C015 1.382(3) . ?
C010 H01A 0.9800 . ?
C010 H01B 0.9800 . ?
C010 H01C 0.9800 . ?
C011 H011 0.9500 . ?
C012 H012 0.9500 . ?
C012 C2 1.377(3) . ?
C013 H01D 0.9800 . ?
C013 H01E 0.9800 . ?
C013 H01F 0.9800 . ?
C014 H01G 0.9800 . ?
C014 H01H 0.9800 . ?
C014 H01I 0.9800 . ?
C015 H015 0.9500 . ?
C016 H01J 0.9800 . ?
C016 H01K 0.9800 . ?
C016 H01L 0.9800 . ?
C016 C7 0.527(8) . ?
C017 H01M 0.9800 . ?
C017 H01N 0.9800 . ?
C017 H01O 0.9800 . ?
C017 C1 0.789(8) . ?
C018 H01P 0.9800 . ?
C018 H01Q 0.9800 . ?
C018 H01R 0.9800 . ?
C2 H2 0.9500 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C00B Au01 O003 177.51(6) . . ?
F005 Sb00 F004 179.23(6) . . ?
F005 Sb00 F007 90.24(6) . . ?
F006 Sb00 F004 90.16(7) . . ?
F006 Sb00 F005 90.58(7) . . ?
F006 Sb00 F007 87.95(8) . . ?
F007 Sb00 F004 89.57(7) . . ?
F008 Sb00 F004 89.45(6) . . ?
F008 Sb00 F005 89.80(6) . . ?
F008 Sb00 F006 177.06(8) . . ?
F008 Sb00 F007 89.13(7) . . ?
F008 Sb00 F00A 91.35(8) . . ?
F00A Sb00 F004 90.69(7) . . ?
F00A Sb00 F005 89.51(7) . . ?
F00A Sb00 F006 91.57(9) . . ?
F00A Sb00 F007 179.46(8) . . ?
N00D O003 Au01 118.64(11) . . ?
C00B N009 C00G 122.69(15) . . ?
C00B N009 C00J 111.10(15) . . ?
C00J N009 C00G 126.01(15) . . ?
N009 C00B Au01 123.61(13) . . ?
N009 C00B N00C 105.03(15) . . ?
N00C C00B Au01 131.35(13) . . ?
C00B N00C C00F 124.57(15) . . ?
C00B N00C C00R 110.51(15) . . ?
C00R N00C C00F 124.75(15) . . ?
O003 N00D C00H 122.79(16) . . ?
O003 N00D C011 115.96(16) . . ?
C011 N00D C00H 121.25(17) . . ?
C00M C00E H00E 119.6 . . ?
C2 C00E H00E 119.6 . . ?
C2 C00E C00M 120.7(2) . . ?
C00I C00F N00C 118.73(17) . . ?
C00L C00F N00C 117.86(17) . . ?
C00L C00F C00I 123.42(17) . . ?
C00M C00G N009 118.59(16) . . ?
C00M C00G C00O 123.88(17) . . ?
C00O C00G N009 117.49(16) . . ?
N00D C00H H00H 120.0 . . ?
N00D C00H C00P 119.94(19) . . ?
C00P C00H H00H 120.0 . . ?
C00F C00I C00T 121.96(17) . . ?
C00N C00I C00F 117.02(19) . . ?
C00N C00I C00T 120.97(19) . . ?
N009 C00J H00J 126.8 . . ?
C00R C00J N009 106.40(16) . . ?
C00R C00J H00J 126.8 . . ?
C00N C00K H00K 119.6 . . ?
C00N C00K C00Q 120.73(19) . . ?
C00Q C00K H00K 119.6 . . ?
C00F C00L C00S 121.92(18) . . ?
C00Q C00L C00F 116.90(19) . . ?
C00Q C00L C00S 121.18(19) . . ?
C00E C00M C00V 120.86(17) . . ?
C00G C00M C00E 117.00(17) . . ?
C00G C00M C00V 122.10(16) . . ?
C00I C00N H00N 119.5 . . ?
C00K C00N C00I 120.9(2) . . ?
C00K C00N H00N 119.5 . . ?
C00G C00O C00W 122.81(18) . . ?
C00G C00O C012 116.52(19) . . ?
C012 C00O C00W 120.66(18) . . ?
C00H C00P H00P 120.1 . . ?
C00H C00P C015 119.8(2) . . ?
C015 C00P H00P 120.1 . . ?
C00K C00Q C00L 121.0(2) . . ?
C00K C00Q H00Q 119.5 . . ?
C00L C00Q H00Q 119.5 . . ?
N00C C00R H00R 126.5 . . ?
C00J C00R N00C 106.97(16) . . ?
C00J C00R H00R 126.5 . . ?
C00L C00S H00S 108.1 . . ?
C00L C00S H00A 104.7 . . ?
C00L C00S C017 105.2(3) . . ?
C00L C00S C7 112.5(4) . . ?
H00S C00S H00A 27.2 . . ?
C016 C00S C00L 114.5(4) . . ?
C016 C00S H00S 108.1 . . ?
C016 C00S H00A 86.1 . . ?
C016 C00S C017 112.5(4) . . ?
C016 C00S C7 19.1(4) . . ?
C017 C00S H00S 108.1 . . ?
C017 C00S H00A 133.1 . . ?
C1 C00S C00L 117.8(3) . . ?
C1 C00S H00S 79.7 . . ?
C1 C00S H00A 104.7 . . ?
C1 C00S C016 121.1(5) . . ?
C1 C00S C017 28.6(3) . . ?
C1 C00S C7 110.9(4) . . ?
C7 C00S H00S 124.5 . . ?
C7 C00S H00A 104.7 . . ?
C7 C00S C017 96.0(4) . . ?
C00I C00T H00T 107.6 . . ?
C00I C00T C00Y 109.64(18) . . ?
C00Y C00T H00T 107.6 . . ?
C018 C00T C00I 112.8(2) . . ?
C018 C00T H00T 107.6 . . ?
C018 C00T C00Y 111.5(2) . . ?
C00M C00V H00V 107.9 . . ?
C00M C00V C00X 110.49(17) . . ?
C00M C00V C013 112.68(16) . . ?
C00X C00V H00V 107.9 . . ?
C013 C00V H00V 107.9 . . ?
C013 C00V C00X 109.93(17) . . ?
C00O C00W H00W 107.7 . . ?
C00O C00W C010 111.04(19) . . ?
C00O C00W C014 111.33(19) . . ?
C010 C00W H00W 107.7 . . ?
C014 C00W H00W 107.7 . . ?
C014 C00W C010 111.15(17) . . ?
C00V C00X H00B 109.5 . . ?
C00V C00X H00C 109.5 . . ?
C00V C00X H00D 109.5 . . ?
H00B C00X H00C 109.5 . . ?
H00B C00X H00D 109.5 . . ?
H00C C00X H00D 109.5 . . ?
C00T C00Y H00F 109.5 . . ?
C00T C00Y H00G 109.5 . . ?
C00T C00Y H00I 109.5 . . ?
H00F C00Y H00G 109.5 . . ?
H00F C00Y H00I 109.5 . . ?
H00G C00Y H00I 109.5 . . ?
C011 C00Z H00Z 120.0 . . ?
C011 C00Z C015 120.1(2) . . ?
C015 C00Z H00Z 120.0 . . ?
C00W C010 H01A 109.5 . . ?
C00W C010 H01B 109.5 . . ?
C00W C010 H01C 109.5 . . ?
H01A C010 H01B 109.5 . . ?
H01A C010 H01C 109.5 . . ?
H01B C010 H01C 109.5 . . ?
N00D C011 C00Z 120.1(2) . . ?
N00D C011 H011 120.0 . . ?
C00Z C011 H011 120.0 . . ?
C00O C012 H012 119.5 . . ?
C2 C012 C00O 121.0(2) . . ?
C2 C012 H012 119.5 . . ?
C00V C013 H01D 109.5 . . ?
C00V C013 H01E 109.5 . . ?
C00V C013 H01F 109.5 . . ?
H01D C013 H01E 109.5 . . ?
H01D C013 H01F 109.5 . . ?
H01E C013 H01F 109.5 . . ?
C00W C014 H01G 109.5 . . ?
C00W C014 H01H 109.5 . . ?
C00W C014 H01I 109.5 . . ?
H01G C014 H01H 109.5 . . ?
H01G C014 H01I 109.5 . . ?
H01H C014 H01I 109.5 . . ?
C00P C015 H015 120.5 . . ?
C00Z C015 C00P 118.9(2) . . ?
C00Z C015 H015 120.5 . . ?
C00S C016 H01J 109.5 . . ?
C00S C016 H01K 109.5 . . ?
C00S C016 H01L 109.5 . . ?
H01J C016 H01K 109.5 . . ?
H01J C016 H01L 109.5 . . ?
H01K C016 H01L 109.5 . . ?
C7 C016 C00S 99(2) . . ?
C7 C016 H01J 17.8 . . ?
C7 C016 H01K 101.2 . . ?
C7 C016 H01L 127.2 . . ?
C00S C017 H01M 109.5 . . ?
C00S C017 H01N 109.5 . . ?
C00S C017 H01O 109.5 . . ?
H01M C017 H01N 109.5 . . ?
H01M C017 H01O 109.5 . . ?
H01N C017 H01O 109.5 . . ?
C1 C017 C00S 58.8(6) . . ?
C1 C017 H01M 78.1 . . ?
C1 C017 H01N 75.3 . . ?
C1 C017 H01O 168.1 . . ?
C00T C018 H01P 109.5 . . ?
C00T C018 H01Q 109.5 . . ?
C00T C018 H01R 109.5 . . ?
H01P C018 H01Q 109.5 . . ?
H01P C018 H01R 109.5 . . ?
H01Q C018 H01R 109.5 . . ?
C00E C2 H2 119.6 . . ?
C012 C2 C00E 120.87(19) . . ?
C012 C2 H2 119.6 . . ?
C00S C1 H1A 109.5 . . ?
C00S C1 H1B 109.5 . . ?
C00S C1 H1C 109.5 . . ?
C017 C1 C00S 92.7(7) . . ?
C017 C1 H1A 102.3 . . ?
C017 C1 H1B 131.4 . . ?
C017 C1 H1C 22.9 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C00S C7 H7A 109.5 . . ?
C00S C7 H7B 109.5 . . ?
C00S C7 H7C 109.5 . . ?
C016 C7 C00S 62.0(17) . . ?
C016 C7 H7A 168.3 . . ?
C016 C7 H7B 81.7 . . ?
C016 C7 H7C 68.6 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 O003 N00D C00H 2.3(2) . . . . ?
Au01 O003 N00D C011 -177.48(14) . . . . ?
Au01 C00B N00C C00F 3.4(3) . . . . ?
Au01 C00B N00C C00R 178.76(14) . . . . ?
O003 N00D C00H C00P -179.17(19) . . . . ?
O003 N00D C011 C00Z 179.88(19) . . . . ?
N009 C00B N00C C00F -175.11(16) . . . . ?
N009 C00B N00C C00R 0.3(2) . . . . ?
N009 C00G C00M C00E -176.76(16) . . . . ?
N009 C00G C00M C00V 1.0(3) . . . . ?
N009 C00G C00O C00W -2.1(3) . . . . ?
N009 C00G C00O C012 176.95(17) . . . . ?
N009 C00J C00R N00C 0.0(2) . . . . ?
C00B N009 C00G C00M 94.7(2) . . . . ?
C00B N009 C00G C00O -83.4(2) . . . . ?
C00B N009 C00J C00R 0.1(2) . . . . ?
C00B N00C C00F C00I -104.2(2) . . . . ?
C00B N00C C00F C00L 75.6(2) . . . . ?
C00B N00C C00R C00J -0.2(2) . . . . ?
N00C C00F C00I C00N 179.93(18) . . . . ?
N00C C00F C00I C00T 2.7(3) . . . . ?
N00C C00F C00L C00Q 179.76(18) . . . . ?
N00C C00F C00L C00S 0.4(3) . . . . ?
N00D C00H C00P C015 -0.7(3) . . . . ?
C00E C00M C00V C00X 77.3(2) . . . . ?
C00E C00M C00V C013 -46.1(2) . . . . ?
C00F N00C C00R C00J 175.17(17) . . . . ?
C00F C00I C00N C00K 0.0(3) . . . . ?
C00F C00I C00T C00Y 97.3(2) . . . . ?
C00F C00I C00T C018 -137.8(2) . . . . ?
C00F C00L C00Q C00K 0.6(3) . . . . ?
C00F C00L C00S C016 -126.2(3) . . . . ?
C00F C00L C00S C017 109.8(3) . . . . ?
C00F C00L C00S C1 82.1(4) . . . . ?
C00F C00L C00S C7 -147.0(4) . . . . ?
C00G N009 C00B Au01 -3.8(2) . . . . ?
C00G N009 C00B N00C 174.82(15) . . . . ?
C00G N009 C00J C00R -174.73(17) . . . . ?
C00G C00M C00V C00X -100.4(2) . . . . ?
C00G C00M C00V C013 136.21(18) . . . . ?
C00G C00O C00W C010 114.4(2) . . . . ?
C00G C00O C00W C014 -121.1(2) . . . . ?
C00G C00O C012 C2 0.2(3) . . . . ?
C00H N00D C011 C00Z 0.1(3) . . . . ?
C00H C00P C015 C00Z 0.0(4) . . . . ?
C00I C00F C00L C00Q -0.4(3) . . . . ?
C00I C00F C00L C00S -179.8(2) . . . . ?
C00J N009 C00B Au01 -178.88(12) . . . . ?
C00J N009 C00B N00C -0.2(2) . . . . ?
C00J N009 C00G C00M -91.0(2) . . . . ?
C00J N009 C00G C00O 90.9(2) . . . . ?
C00L C00F C00I C00N 0.1(3) . . . . ?
C00L C00F C00I C00T -177.16(19) . . . . ?
C00L C00S C016 C7 -88.5(19) . . . . ?
C00L C00S C017 C1 -120.7(8) . . . . ?
C00L C00S C1 C017 69.7(9) . . . . ?
C00L C00S C7 C016 99.9(19) . . . . ?
C00M C00E C2 C012 -0.1(3) . . . . ?
C00M C00G C00O C00W 179.98(18) . . . . ?
C00M C00G C00O C012 -1.0(3) . . . . ?
C00N C00I C00T C00Y -79.8(3) . . . . ?
C00N C00I C00T C018 45.1(3) . . . . ?
C00N C00K C00Q C00L -0.5(3) . . . . ?
C00O C00G C00M C00E 1.1(3) . . . . ?
C00O C00G C00M C00V 178.92(17) . . . . ?
C00O C012 C2 C00E 0.3(3) . . . . ?
C00Q C00K C00N C00I 0.2(3) . . . . ?
C00Q C00L C00S C016 54.5(4) . . . . ?
C00Q C00L C00S C017 -69.6(3) . . . . ?
C00Q C00L C00S C1 -97.3(4) . . . . ?
C00Q C00L C00S C7 33.7(4) . . . . ?
C00R N00C C00F C00I 81.0(2) . . . . ?
C00R N00C C00F C00L -99.1(2) . . . . ?
C00S C00L C00Q C00K -180.0(2) . . . . ?
C00T C00I C00N C00K 177.3(2) . . . . ?
C00W C00O C012 C2 179.3(2) . . . . ?
C011 N00D C00H C00P 0.6(3) . . . . ?
C011 C00Z C015 C00P 0.7(4) . . . . ?
C012 C00O C00W C010 -64.6(3) . . . . ?
C012 C00O C00W C014 59.8(3) . . . . ?
C015 C00Z C011 N00D -0.7(3) . . . . ?
C016 C00S C017 C1 114.0(9) . . . . ?
C016 C00S C1 C017 -80.1(9) . . . . ?
C017 C00S C016 C7 32(2) . . . . ?
C017 C00S C7 C016 -150.9(19) . . . . ?
C2 C00E C00M C00G -0.6(3) . . . . ?
C2 C00E C00M C00V -178.38(19) . . . . ?
C1 C00S C016 C7 62(2) . . . . ?
C1 C00S C7 C016 -125.8(18) . . . . ?
C7 C00S C017 C1 124.0(9) . . . . ?
C7 C00S C1 C017 -62.0(9) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-102-plate
_database_code_depnum_ccdc_archive 'CCDC 1548790'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-05-13
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H39 Au N2 O P, F6 Sb'
_chemical_formula_sum            'C30 H39 Au F6 N2 O P Sb'
_chemical_formula_weight         907.32
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.4424(7)
_cell_length_b                   24.5485(17)
_cell_length_c                   14.4931(10)
_cell_angle_alpha                90
_cell_angle_beta                 104.1800(10)
_cell_angle_gamma                90
_cell_volume                     3257.1(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9774
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.50
_cell_measurement_theta_min      2.56
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.438
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.4732
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0977 before and 0.0492 after correction.
The Ratio of minimum to maximum transmission is 0.6341.
The λ/2 correction factor is Not present.
;

_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1760
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_unetI/netI     0.0308
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            75553
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         32.654
_diffrn_reflns_theta_min         2.203
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10413
_reflns_number_total             11882
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_refine_diff_density_max         1.417
_refine_diff_density_min         -1.199
_refine_diff_density_rms         0.123
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     387
_refine_ls_number_reflns         11882
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0332
_refine_ls_R_factor_gt           0.0247
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0110P)²+4.2167P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0451
_refine_ls_wR_factor_ref         0.0472
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C00W(H00W)
2.b Aromatic/amide H refined with riding coordinates:
 C00F(H00F), C00I(H00I), C00K(H00K), C00L(H00L), C00S(H00S), C00T(H00T),
 C00U(H00U), C00V(H00V), C00X(H00X), C00Z(H00Z), C010(H010), C011(H011),
 C012(H012), C014(H014)
2.c Idealised Me refined as rotating group:
 C00N(H00A,H00B,H00C), C00O(H00D,H00E,H00G), C00P(H00H,H00J,H00M), C00R(H00N,
 H00O,H00P), C00Y(H00Q,H00R,H00Y), C013(H01A,H01B,H01C), C015(H01D,H01E,H01F),
 C016(H01G,H01H,H01I)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.57236(2) 0.64207(2) 0.68849(2) 0.01138(2) Uani 1 1 d . . . . .
Sb02 Sb 0.93208(2) 0.32477(2) 0.78768(2) 0.01739(3) Uani 1 1 d . . . . .
P003 P 0.68834(6) 0.57201(2) 0.77514(4) 0.01115(9) Uani 1 1 d . . . . .
F004 F 1.00826(18) 0.27079(7) 0.72224(12) 0.0359(4) Uani 1 1 d . . . . .
F005 F 1.10945(17) 0.36249(7) 0.81177(12) 0.0340(4) Uani 1 1 d . . . . .
F006 F 0.75355(17) 0.28769(7) 0.76416(15) 0.0419(4) Uani 1 1 d . . . . .
O007 O 0.49116(18) 0.79566(6) 0.55910(11) 0.0194(3) Uani 1 1 d . . . . .
F008 F 0.8667(2) 0.36314(8) 0.67375(12) 0.0471(5) Uani 1 1 d . . . . .
F009 F 0.85649(18) 0.37801(7) 0.85483(13) 0.0349(4) Uani 1 1 d . . . . .
F00A F 0.99929(19) 0.28564(7) 0.90112(11) 0.0357(4) Uani 1 1 d . . . . .
N00B N 0.4938(2) 0.70987(7) 0.60762(12) 0.0137(3) Uani 1 1 d . . . . .
N00C N 0.4122(2) 0.76506(8) 0.47332(13) 0.0176(4) Uani 1 1 d . . . . .
C00D C 0.4175(2) 0.52395(9) 0.78587(14) 0.0131(4) Uani 1 1 d . . . . .
C00E C 0.5231(2) 0.75959(9) 0.63060(15) 0.0162(4) Uani 1 1 d . . . . .
C00F C 0.3381(2) 0.48188(9) 0.81467(16) 0.0172(4) Uani 1 1 d . . . . .
H00F H 0.2347 0.4845 0.8009 0.021 Uiso 1 1 calc R . . . .
C00G C 0.5712(2) 0.52033(8) 0.80872(14) 0.0128(4) Uani 1 1 d . . . . .
C00H C 0.3317(2) 0.56946(9) 0.73040(15) 0.0145(4) Uani 1 1 d . . . . .
C00I C 0.2132(3) 0.65701(10) 0.72457(19) 0.0244(5) Uani 1 1 d . . . . .
H00I H 0.1894 0.6882 0.7564 0.029 Uiso 1 1 calc R . . . .
C00J C 0.7990(2) 0.60161(9) 0.88912(15) 0.0162(4) Uani 1 1 d . . . . .
C00K C 0.1655(3) 0.65311(10) 0.62656(19) 0.0240(5) Uani 1 1 d . . . . .
H00K H 0.1100 0.6818 0.5912 0.029 Uiso 1 1 calc R . . . .
C00L C 0.2957(2) 0.61539(9) 0.77644(16) 0.0192(4) Uani 1 1 d . . . . .
H00L H 0.3279 0.6183 0.8437 0.023 Uiso 1 1 calc R . . . .
C00M C 0.7976(2) 0.53634(9) 0.70054(15) 0.0159(4) Uani 1 1 d . . . . .
C00N C 0.5903(3) 0.78192(11) 0.72591(17) 0.0251(5) Uani 1 1 d . . . . .
H00A H 0.6909 0.7931 0.7288 0.038 Uiso 1 1 calc GR . . . .
H00B H 0.5905 0.7540 0.7742 0.038 Uiso 1 1 calc GR . . . .
H00C H 0.5340 0.8135 0.7380 0.038 Uiso 1 1 calc GR . . . .
C00O C 0.2576(3) 0.77799(10) 0.46640(17) 0.0235(5) Uani 1 1 d . . . . .
H00D H 0.2316 0.7665 0.5249 0.035 Uiso 1 1 calc GR . . . .
H00E H 0.1961 0.7587 0.4119 0.035 Uiso 1 1 calc GR . . . .
H00G H 0.2424 0.8173 0.4578 0.035 Uiso 1 1 calc GR . . . .
C00P C 0.8540(3) 0.57925(10) 0.64212(17) 0.0237(5) Uani 1 1 d . . . . .
H00H H 0.7711 0.5977 0.5997 0.036 Uiso 1 1 calc GR . . . .
H00J H 0.9138 0.5616 0.6042 0.036 Uiso 1 1 calc GR . . . .
H00M H 0.9134 0.6060 0.6850 0.036 Uiso 1 1 calc GR . . . .
C00Q C 0.5603(2) 0.68075(9) 0.46255(14) 0.0164(4) Uani 1 1 d . . . . .
C00R C 0.9117(3) 0.64155(10) 0.86725(17) 0.0231(5) Uani 1 1 d . . . . .
H00N H 0.9890 0.6211 0.8481 0.035 Uiso 1 1 calc GR . . . .
H00O H 0.9545 0.6631 0.9242 0.035 Uiso 1 1 calc GR . . . .
H00P H 0.8637 0.6660 0.8155 0.035 Uiso 1 1 calc GR . . . .
C00S C 0.1986(3) 0.60731(10) 0.58004(17) 0.0227(5) Uani 1 1 d . . . . .
H00S H 0.1645 0.6044 0.5129 0.027 Uiso 1 1 calc R . . . .
C00T C 0.5557(3) 0.43248(9) 0.88378(16) 0.0201(4) Uani 1 1 d . . . . .
H00T H 0.6030 0.4014 0.9164 0.024 Uiso 1 1 calc R . . . .
C00U C 0.2818(2) 0.56557(10) 0.63164(15) 0.0183(4) Uani 1 1 d . . . . .
H00U H 0.3047 0.5343 0.5995 0.022 Uiso 1 1 calc R . . . .
C00V C 0.4056(3) 0.43660(9) 0.86256(16) 0.0200(4) Uani 1 1 d . . . . .
H00V H 0.3489 0.4085 0.8808 0.024 Uiso 1 1 calc R . . . .
C00W C 0.4441(2) 0.70745(9) 0.50261(14) 0.0147(4) Uani 1 1 d . . . . .
H00W H 0.3520 0.6856 0.4842 0.018 Uiso 1 1 calc R . . . .
C00X C 0.6975(3) 0.70410(10) 0.47384(16) 0.0207(4) Uani 1 1 d . . . . .
H00X H 0.7184 0.7382 0.5052 0.025 Uiso 1 1 calc R . . . .
C00Y C 0.6895(3) 0.63413(10) 0.93110(16) 0.0212(5) Uani 1 1 d . . . . .
H00Q H 0.6463 0.6633 0.8870 0.032 Uiso 1 1 calc GR . . . .
H00R H 0.7406 0.6500 0.9923 0.032 Uiso 1 1 calc GR . . . .
H00Y H 0.6122 0.6097 0.9407 0.032 Uiso 1 1 calc GR . . . .
C00Z C 0.5305(3) 0.63099(10) 0.41744(17) 0.0228(5) Uani 1 1 d . . . . .
H00Z H 0.4366 0.6150 0.4096 0.027 Uiso 1 1 calc R . . . .
C010 C 0.6374(2) 0.47399(9) 0.85731(16) 0.0179(4) Uani 1 1 d . . . . .
H010 H 0.7408 0.4709 0.8725 0.022 Uiso 1 1 calc R . . . .
C011 C 0.8039(3) 0.67778(12) 0.43947(16) 0.0266(5) Uani 1 1 d . . . . .
H011 H 0.8976 0.6938 0.4469 0.032 Uiso 1 1 calc R . . . .
C012 C 0.7726(3) 0.62746(12) 0.39382(18) 0.0307(6) Uani 1 1 d . . . . .
H012 H 0.8450 0.6093 0.3699 0.037 Uiso 1 1 calc R . . . .
C013 C 0.6920(3) 0.49883(11) 0.63324(18) 0.0276(5) Uani 1 1 d . . . . .
H01A H 0.6580 0.4704 0.6700 0.041 Uiso 1 1 calc GR . . . .
H01B H 0.7419 0.4820 0.5886 0.041 Uiso 1 1 calc GR . . . .
H01C H 0.6083 0.5200 0.5978 0.041 Uiso 1 1 calc GR . . . .
C014 C 0.6369(3) 0.60423(11) 0.38352(17) 0.0289(6) Uani 1 1 d . . . . .
H014 H 0.6161 0.5698 0.3532 0.035 Uiso 1 1 calc R . . . .
C015 C 0.8754(3) 0.56035(10) 0.96411(17) 0.0242(5) Uani 1 1 d . . . . .
H01D H 0.8021 0.5377 0.9832 0.036 Uiso 1 1 calc GR . . . .
H01E H 0.9332 0.5798 1.0198 0.036 Uiso 1 1 calc GR . . . .
H01F H 0.9400 0.5372 0.9374 0.036 Uiso 1 1 calc GR . . . .
C016 C 0.9289(3) 0.50348(11) 0.75654(19) 0.0284(5) Uani 1 1 d . . . . .
H01G H 0.9988 0.5281 0.7974 0.043 Uiso 1 1 calc GR . . . .
H01H H 0.9761 0.4851 0.7120 0.043 Uiso 1 1 calc GR . . . .
H01I H 0.8955 0.4763 0.7960 0.043 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2496(5) . ?
Au01 N00B 2.0661(17) . ?
Sb02 F004 1.8728(15) . ?
Sb02 F005 1.8702(15) . ?
Sb02 F006 1.8722(15) . ?
Sb02 F008 1.8697(17) . ?
Sb02 F009 1.8721(15) . ?
Sb02 F00A 1.8755(15) . ?
P003 C00G 1.825(2) . ?
P003 C00J 1.872(2) . ?
P003 C00M 1.883(2) . ?
O007 N00C 1.487(2) . ?
O007 C00E 1.340(3) . ?
N00B C00E 1.277(3) . ?
N00B C00W 1.480(3) . ?
N00C C00O 1.473(3) . ?
N00C C00W 1.486(3) . ?
C00D C00F 1.398(3) . ?
C00D C00G 1.411(3) . ?
C00D C00H 1.494(3) . ?
C00E C00N 1.477(3) . ?
C00F H00F 0.9500 . ?
C00F C00V 1.381(3) . ?
C00G C010 1.402(3) . ?
C00H C00L 1.394(3) . ?
C00H C00U 1.396(3) . ?
C00I H00I 0.9500 . ?
C00I C00K 1.384(4) . ?
C00I C00L 1.389(3) . ?
C00J C00R 1.536(3) . ?
C00J C00Y 1.544(3) . ?
C00J C015 1.531(3) . ?
C00K H00K 0.9500 . ?
C00K C00S 1.386(4) . ?
C00L H00L 0.9500 . ?
C00M C00P 1.527(3) . ?
C00M C013 1.522(3) . ?
C00M C016 1.534(3) . ?
C00N H00A 0.9800 . ?
C00N H00B 0.9800 . ?
C00N H00C 0.9800 . ?
C00O H00D 0.9800 . ?
C00O H00E 0.9800 . ?
C00O H00G 0.9800 . ?
C00P H00H 0.9800 . ?
C00P H00J 0.9800 . ?
C00P H00M 0.9800 . ?
C00Q C00W 1.511(3) . ?
C00Q C00X 1.389(3) . ?
C00Q C00Z 1.382(3) . ?
C00R H00N 0.9800 . ?
C00R H00O 0.9800 . ?
C00R H00P 0.9800 . ?
C00S H00S 0.9500 . ?
C00S C00U 1.392(3) . ?
C00T H00T 0.9500 . ?
C00T C00V 1.379(3) . ?
C00T C010 1.388(3) . ?
C00U H00U 0.9500 . ?
C00V H00V 0.9500 . ?
C00W H00W 1.0000 . ?
C00X H00X 0.9500 . ?
C00X C011 1.386(3) . ?
C00Y H00Q 0.9800 . ?
C00Y H00R 0.9800 . ?
C00Y H00Y 0.9800 . ?
C00Z H00Z 0.9500 . ?
C00Z C014 1.387(3) . ?
C010 H010 0.9500 . ?
C011 H011 0.9500 . ?
C011 C012 1.398(4) . ?
C012 H012 0.9500 . ?
C012 C014 1.377(4) . ?
C013 H01A 0.9800 . ?
C013 H01B 0.9800 . ?
C013 H01C 0.9800 . ?
C014 H014 0.9500 . ?
C015 H01D 0.9800 . ?
C015 H01E 0.9800 . ?
C015 H01F 0.9800 . ?
C016 H01G 0.9800 . ?
C016 H01H 0.9800 . ?
C016 H01I 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N00B Au01 P003 172.16(5) . . ?
F004 Sb02 F00A 89.55(8) . . ?
F005 Sb02 F004 90.43(7) . . ?
F005 Sb02 F006 179.34(8) . . ?
F005 Sb02 F009 89.74(7) . . ?
F005 Sb02 F00A 89.70(8) . . ?
F006 Sb02 F004 90.23(8) . . ?
F006 Sb02 F00A 90.39(8) . . ?
F008 Sb02 F004 89.65(9) . . ?
F008 Sb02 F005 90.14(8) . . ?
F008 Sb02 F006 89.78(9) . . ?
F008 Sb02 F009 91.25(9) . . ?
F008 Sb02 F00A 179.18(9) . . ?
F009 Sb02 F004 179.08(8) . . ?
F009 Sb02 F006 89.61(8) . . ?
F009 Sb02 F00A 89.55(8) . . ?
C00G P003 Au01 115.86(7) . . ?
C00G P003 C00J 106.15(10) . . ?
C00G P003 C00M 106.42(10) . . ?
C00J P003 Au01 106.62(7) . . ?
C00J P003 C00M 114.93(10) . . ?
C00M P003 Au01 107.17(7) . . ?
C00E O007 N00C 106.53(16) . . ?
C00E N00B Au01 126.66(15) . . ?
C00E N00B C00W 107.48(17) . . ?
C00W N00B Au01 122.03(13) . . ?
C00O N00C O007 103.50(16) . . ?
C00O N00C C00W 110.63(18) . . ?
C00W N00C O007 102.53(15) . . ?
C00F C00D C00G 118.63(19) . . ?
C00F C00D C00H 116.97(19) . . ?
C00G C00D C00H 124.38(18) . . ?
O007 C00E C00N 116.2(2) . . ?
N00B C00E O007 115.87(19) . . ?
N00B C00E C00N 127.9(2) . . ?
C00D C00F H00F 119.0 . . ?
C00V C00F C00D 122.0(2) . . ?
C00V C00F H00F 119.0 . . ?
C00D C00G P003 123.33(15) . . ?
C010 C00G P003 118.25(16) . . ?
C010 C00G C00D 118.39(19) . . ?
C00L C00H C00D 120.72(19) . . ?
C00L C00H C00U 119.0(2) . . ?
C00U C00H C00D 120.19(19) . . ?
C00K C00I H00I 119.9 . . ?
C00K C00I C00L 120.2(2) . . ?
C00L C00I H00I 119.9 . . ?
C00R C00J P003 109.32(15) . . ?
C00R C00J C00Y 108.42(19) . . ?
C00Y C00J P003 105.42(15) . . ?
C015 C00J P003 115.71(16) . . ?
C015 C00J C00R 109.79(19) . . ?
C015 C00J C00Y 107.88(18) . . ?
C00I C00K H00K 120.0 . . ?
C00I C00K C00S 120.0(2) . . ?
C00S C00K H00K 120.0 . . ?
C00H C00L H00L 119.8 . . ?
C00I C00L C00H 120.4(2) . . ?
C00I C00L H00L 119.8 . . ?
C00P C00M P003 108.20(15) . . ?
C00P C00M C016 108.03(19) . . ?
C013 C00M P003 106.53(15) . . ?
C013 C00M C00P 108.95(19) . . ?
C013 C00M C016 109.8(2) . . ?
C016 C00M P003 115.21(16) . . ?
C00E C00N H00A 109.5 . . ?
C00E C00N H00B 109.5 . . ?
C00E C00N H00C 109.5 . . ?
H00A C00N H00B 109.5 . . ?
H00A C00N H00C 109.5 . . ?
H00B C00N H00C 109.5 . . ?
N00C C00O H00D 109.5 . . ?
N00C C00O H00E 109.5 . . ?
N00C C00O H00G 109.5 . . ?
H00D C00O H00E 109.5 . . ?
H00D C00O H00G 109.5 . . ?
H00E C00O H00G 109.5 . . ?
C00M C00P H00H 109.5 . . ?
C00M C00P H00J 109.5 . . ?
C00M C00P H00M 109.5 . . ?
H00H C00P H00J 109.5 . . ?
H00H C00P H00M 109.5 . . ?
H00J C00P H00M 109.5 . . ?
C00X C00Q C00W 121.3(2) . . ?
C00Z C00Q C00W 118.9(2) . . ?
C00Z C00Q C00X 119.8(2) . . ?
C00J C00R H00N 109.5 . . ?
C00J C00R H00O 109.5 . . ?
C00J C00R H00P 109.5 . . ?
H00N C00R H00O 109.5 . . ?
H00N C00R H00P 109.5 . . ?
H00O C00R H00P 109.5 . . ?
C00K C00S H00S 120.0 . . ?
C00K C00S C00U 120.1(2) . . ?
C00U C00S H00S 120.0 . . ?
C00V C00T H00T 120.2 . . ?
C00V C00T C010 119.7(2) . . ?
C010 C00T H00T 120.2 . . ?
C00H C00U H00U 119.8 . . ?
C00S C00U C00H 120.3(2) . . ?
C00S C00U H00U 119.8 . . ?
C00F C00V H00V 120.2 . . ?
C00T C00V C00F 119.6(2) . . ?
C00T C00V H00V 120.2 . . ?
N00B C00W N00C 104.27(16) . . ?
N00B C00W C00Q 109.59(17) . . ?
N00B C00W H00W 109.4 . . ?
N00C C00W C00Q 114.73(17) . . ?
N00C C00W H00W 109.4 . . ?
C00Q C00W H00W 109.4 . . ?
C00Q C00X H00X 119.9 . . ?
C011 C00X C00Q 120.2(2) . . ?
C011 C00X H00X 119.9 . . ?
C00J C00Y H00Q 109.5 . . ?
C00J C00Y H00R 109.5 . . ?
C00J C00Y H00Y 109.5 . . ?
H00Q C00Y H00R 109.5 . . ?
H00Q C00Y H00Y 109.5 . . ?
H00R C00Y H00Y 109.5 . . ?
C00Q C00Z H00Z 119.8 . . ?
C00Q C00Z C014 120.3(2) . . ?
C014 C00Z H00Z 119.8 . . ?
C00G C010 H010 119.2 . . ?
C00T C010 C00G 121.7(2) . . ?
C00T C010 H010 119.2 . . ?
C00X C011 H011 120.2 . . ?
C00X C011 C012 119.6(2) . . ?
C012 C011 H011 120.2 . . ?
C011 C012 H012 120.0 . . ?
C014 C012 C011 120.0(2) . . ?
C014 C012 H012 120.0 . . ?
C00M C013 H01A 109.5 . . ?
C00M C013 H01B 109.5 . . ?
C00M C013 H01C 109.5 . . ?
H01A C013 H01B 109.5 . . ?
H01A C013 H01C 109.5 . . ?
H01B C013 H01C 109.5 . . ?
C00Z C014 H014 120.0 . . ?
C012 C014 C00Z 120.1(2) . . ?
C012 C014 H014 120.0 . . ?
C00J C015 H01D 109.5 . . ?
C00J C015 H01E 109.5 . . ?
C00J C015 H01F 109.5 . . ?
H01D C015 H01E 109.5 . . ?
H01D C015 H01F 109.5 . . ?
H01E C015 H01F 109.5 . . ?
C00M C016 H01G 109.5 . . ?
C00M C016 H01H 109.5 . . ?
C00M C016 H01I 109.5 . . ?
H01G C016 H01H 109.5 . . ?
H01G C016 H01I 109.5 . . ?
H01H C016 H01I 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P003 C00G C00D -2.3(2) . . . . ?
Au01 P003 C00G C010 175.85(15) . . . . ?
Au01 P003 C00J C00R -61.58(16) . . . . ?
Au01 P003 C00J C00Y 54.79(15) . . . . ?
Au01 P003 C00J C015 173.88(15) . . . . ?
Au01 P003 C00M C00P 35.30(17) . . . . ?
Au01 P003 C00M C013 -81.72(16) . . . . ?
Au01 P003 C00M C016 156.29(16) . . . . ?
Au01 N00B C00E O007 163.50(14) . . . . ?
Au01 N00B C00E C00N -15.3(3) . . . . ?
Au01 N00B C00W N00C -174.26(13) . . . . ?
Au01 N00B C00W C00Q -51.0(2) . . . . ?
P003 C00G C010 C00T -178.86(18) . . . . ?
O007 N00C C00W N00B 17.68(19) . . . . ?
O007 N00C C00W C00Q -102.19(19) . . . . ?
N00C O007 C00E N00B 6.6(3) . . . . ?
N00C O007 C00E C00N -174.49(19) . . . . ?
C00D C00F C00V C00T 0.6(3) . . . . ?
C00D C00G C010 C00T -0.6(3) . . . . ?
C00D C00H C00L C00I -178.6(2) . . . . ?
C00D C00H C00U C00S 178.3(2) . . . . ?
C00E O007 N00C C00O 99.90(19) . . . . ?
C00E O007 N00C C00W -15.2(2) . . . . ?
C00E N00B C00W N00C -14.9(2) . . . . ?
C00E N00B C00W C00Q 108.3(2) . . . . ?
C00F C00D C00G P003 179.67(16) . . . . ?
C00F C00D C00G C010 1.5(3) . . . . ?
C00F C00D C00H C00L 90.9(3) . . . . ?
C00F C00D C00H C00U -86.8(2) . . . . ?
C00G P003 C00J C00R 174.34(16) . . . . ?
C00G P003 C00J C00Y -69.30(16) . . . . ?
C00G P003 C00J C015 49.80(19) . . . . ?
C00G P003 C00M C00P 159.84(15) . . . . ?
C00G P003 C00M C013 42.83(18) . . . . ?
C00G P003 C00M C016 -79.16(19) . . . . ?
C00G C00D C00F C00V -1.5(3) . . . . ?
C00G C00D C00H C00L -90.6(3) . . . . ?
C00G C00D C00H C00U 91.7(3) . . . . ?
C00H C00D C00F C00V 177.1(2) . . . . ?
C00H C00D C00G P003 1.2(3) . . . . ?
C00H C00D C00G C010 -177.0(2) . . . . ?
C00I C00K C00S C00U -1.0(4) . . . . ?
C00J P003 C00G C00D 115.83(18) . . . . ?
C00J P003 C00G C010 -66.03(19) . . . . ?
C00J P003 C00M C00P -82.98(18) . . . . ?
C00J P003 C00M C013 160.01(16) . . . . ?
C00J P003 C00M C016 38.0(2) . . . . ?
C00K C00I C00L C00H 0.2(4) . . . . ?
C00K C00S C00U C00H 0.3(3) . . . . ?
C00L C00H C00U C00S 0.6(3) . . . . ?
C00L C00I C00K C00S 0.8(4) . . . . ?
C00M P003 C00G C00D -121.29(18) . . . . ?
C00M P003 C00G C010 56.85(19) . . . . ?
C00M P003 C00J C00R 57.01(19) . . . . ?
C00M P003 C00J C00Y 173.37(14) . . . . ?
C00M P003 C00J C015 -67.53(19) . . . . ?
C00O N00C C00W N00B -92.1(2) . . . . ?
C00O N00C C00W C00Q 147.98(19) . . . . ?
C00Q C00X C011 C012 -0.3(3) . . . . ?
C00Q C00Z C014 C012 -0.7(4) . . . . ?
C00U C00H C00L C00I -0.9(3) . . . . ?
C00V C00T C010 C00G -0.3(4) . . . . ?
C00W N00B C00E O007 5.4(3) . . . . ?
C00W N00B C00E C00N -173.3(2) . . . . ?
C00W C00Q C00X C011 177.6(2) . . . . ?
C00W C00Q C00Z C014 -177.2(2) . . . . ?
C00X C00Q C00W N00B -63.1(3) . . . . ?
C00X C00Q C00W N00C 53.8(3) . . . . ?
C00X C00Q C00Z C014 0.1(3) . . . . ?
C00X C011 C012 C014 -0.2(4) . . . . ?
C00Z C00Q C00W N00B 114.1(2) . . . . ?
C00Z C00Q C00W N00C -129.0(2) . . . . ?
C00Z C00Q C00X C011 0.4(3) . . . . ?
C010 C00T C00V C00F 0.4(3) . . . . ?
C011 C012 C014 C00Z 0.7(4) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-42
_audit_block_doi                 10.5517/ccdc.csd.cc1nzn09
_database_code_depnum_ccdc_archive 'CCDC 1548791'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2017-05-02
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5335)
;
# start Validation Reply Form
_vrf_PLAT971_hfj-42              
;
PROBLEM: Check Calcd Residual Density 0.65A From Sb02 4.98 eA-3
RESPONSE: Some unresolved disorder, minor twin component or 
Fourier truncation cause intense peaks close to the heavy atoms
of the structure.
;
_vrf_PLAT972_hfj-42              
;
PROBLEM: Check Calcd Residual Density 0.54A From Sb02 -4.12 eA-3 
RESPONSE: Some unresolved disorder, minor twin component or 
Fourier truncation cause intense peaks close to the heavy atoms
of the structure.
;
# Added Tuesday 02 May 2017 01:38 PM
# end Validation Reply Form
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H35 Au F3 N O P, F6 Sb'
_chemical_formula_sum            'C29 H35 Au F9 N O P Sb'
_chemical_formula_weight         934.26
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   22.3269(18)
_cell_length_b                   10.4404(8)
_cell_length_c                   27.953(2)
_cell_angle_alpha                90
_cell_angle_beta                 92.084(2)
_cell_angle_gamma                90
_cell_volume                     6511.6(9)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9785
_cell_measurement_temperature    101(2)
_cell_measurement_theta_max      33.139
_cell_measurement_theta_min      2.263
_shelx_estimated_absorpt_T_max   0.701
_shelx_estimated_absorpt_T_min   0.408
_exptl_absorpt_coefficient_mu    5.455
_exptl_absorpt_correction_T_max  0.7213
_exptl_absorpt_correction_T_min  0.3357
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1231 before and 0.0574 after correction. The Ratio of minimum to maximum transmission is 0.4654. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.906
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             3600
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_transmission_factor_max   1.0000
_exptl_transmission_factor_min   0.4654
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_unetI/netI     0.0375
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            37353
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.185
_diffrn_reflns_theta_min         2.284
_diffrn_ambient_temperature      100.73
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10885
_reflns_number_total             12367
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       'APEX3 (Bruker AXS, 2016)'
_computing_data_reduction        'SAINT v8.37A (Bruker, 2016)'
_computing_molecular_graphics    'Diamond v4 (Brandenburg, 2012)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2015b)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015a)'
_refine_diff_density_max         4.902
_refine_diff_density_min         -4.397
_refine_diff_density_rms         0.188
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     395
_refine_ls_number_reflns         12367
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0437
_refine_ls_R_factor_gt           0.0364
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0496P)²+37.4109P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0907
_refine_ls_wR_factor_ref         0.0946
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00I(H00I), C00J(H00J), C00N(H00N), C00O(H00O), C00P(H00P), C00Q(H00Q),
 C00R(H00R), C00U(H00U), C00V(H00V), C00W(H00W), C00X(H00X), C00Z(H00Z),
 C011(H011), C012(H012)
2.b Idealised Me refined as rotating group:
 C00Y(H00A,H00B,H00C), C010(H01A,H01B,H01C), C013(H01D,H01E,H01F), C014(H01G,
 H01H,H01I), C015(H01J,H01K,H01L), C016(H01M,H01N,H01O), C017(H01P,H01Q,H01R)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.65050(2) 0.71447(2) 0.40102(2) 0.01284(4) Uani 1 1 d . . . . .
Sb02 Sb 0.80636(2) 0.31014(2) 0.41208(2) 0.02321(6) Uani 1 1 d . . . . .
P003 P 0.65560(4) 0.73577(8) 0.32167(3) 0.01487(14) Uani 1 1 d . . . . .
F004 F 0.76523(16) 0.1557(3) 0.41110(11) 0.0470(7) Uani 1 1 d . . . . .
O005 O 0.65176(11) 0.6879(2) 0.47517(8) 0.0161(4) Uani 1 1 d . . . . .
F006 F 0.80531(18) 0.3089(3) 0.48002(10) 0.0492(8) Uani 1 1 d . . . . .
F007 F 0.73482(14) 0.4017(3) 0.41142(11) 0.0511(8) Uani 1 1 d . . . . .
F008 F 0.42641(16) 0.3339(5) 0.34633(11) 0.0683(12) Uani 1 1 d . . . . .
F009 F 0.80658(18) 0.3158(4) 0.34604(10) 0.0542(9) Uani 1 1 d . . . . .
N00A N 0.67489(12) 0.5759(3) 0.49026(9) 0.0155(5) Uani 1 1 d . . . . .
F00B F 0.87829(17) 0.2200(4) 0.41661(17) 0.0644(11) Uani 1 1 d . . . . .
F00C F 0.4073(2) 0.2138(5) 0.4034(2) 0.105(2) Uani 1 1 d . . . . .
F00D F 0.84894(17) 0.4646(3) 0.41511(14) 0.0630(10) Uani 1 1 d . . . . .
C00E C 0.61976(14) 0.8798(3) 0.29646(11) 0.0186(6) Uani 1 1 d . . . . .
C00F C 0.57842(14) 0.9545(3) 0.37618(11) 0.0171(5) Uani 1 1 d . . . . .
C00G C 0.59041(14) 0.9709(3) 0.32437(12) 0.0196(6) Uani 1 1 d . . . . .
C00H C 0.48117(15) 0.3716(4) 0.41797(12) 0.0211(6) Uani 1 1 d . . . . .
C00I C 0.64787(15) 0.4677(3) 0.48544(11) 0.0164(5) Uani 1 1 d . . . . .
H00I H 0.6683 0.3953 0.4986 0.020 Uiso 1 1 calc R . . . .
C00J C 0.61942(16) 0.9980(3) 0.41167(13) 0.0211(6) Uani 1 1 d . . . . .
H00J H 0.6552 1.0395 0.4028 0.025 Uiso 1 1 calc R . . . .
C00K C 0.58951(15) 0.4434(3) 0.46213(11) 0.0163(5) Uani 1 1 d . . . . .
F00L F 0.37805(15) 0.4012(5) 0.40407(18) 0.0948(19) Uani 1 1 d . . . . .
C00M C 0.42362(18) 0.3320(4) 0.39294(15) 0.0296(8) Uani 1 1 d . . . . .
C00N C 0.52466(18) 0.2790(3) 0.42842(14) 0.0240(7) Uani 1 1 d . . . . .
H00N H 0.5175 0.1918 0.4202 0.029 Uiso 1 1 calc R . . . .
C00O C 0.49115(15) 0.4993(3) 0.42961(11) 0.0195(6) Uani 1 1 d . . . . .
H00O H 0.4611 0.5615 0.4224 0.023 Uiso 1 1 calc R . . . .
C00P C 0.62486(16) 0.9038(4) 0.24732(12) 0.0250(7) Uani 1 1 d . . . . .
H00P H 0.6440 0.8421 0.2281 0.030 Uiso 1 1 calc R . . . .
C00Q C 0.57820(17) 0.3149(3) 0.45080(14) 0.0230(7) Uani 1 1 d . . . . .
H00Q H 0.6076 0.2518 0.4586 0.028 Uiso 1 1 calc R . . . .
C00R C 0.52492(15) 0.8982(3) 0.38983(13) 0.0210(6) Uani 1 1 d . . . . .
H00R H 0.4962 0.8711 0.3660 0.025 Uiso 1 1 calc R . . . .
C00S C 0.73753(15) 0.7524(4) 0.30961(12) 0.0212(6) Uani 1 1 d . . . . .
C00T C 0.61683(17) 0.5955(4) 0.29259(13) 0.0252(7) Uani 1 1 d . . . . .
C00U C 0.60278(17) 1.0151(5) 0.22596(14) 0.0306(9) Uani 1 1 d . . . . .
H00U H 0.6062 1.0286 0.1926 0.037 Uiso 1 1 calc R . . . .
C00V C 0.54529(15) 0.5359(3) 0.45181(11) 0.0169(5) Uani 1 1 d . . . . .
H00V H 0.5523 0.6231 0.4599 0.020 Uiso 1 1 calc R . . . .
C00W C 0.57561(19) 1.1063(5) 0.25404(16) 0.0347(9) Uani 1 1 d . . . . .
H00W H 0.5612 1.1839 0.2401 0.042 Uiso 1 1 calc R . . . .
C00X C 0.56955(19) 1.0841(4) 0.30250(15) 0.0306(8) Uani 1 1 d . . . . .
H00X H 0.5508 1.1471 0.3214 0.037 Uiso 1 1 calc R . . . .
C00Y C 0.55260(19) 0.5993(5) 0.30999(15) 0.0331(9) Uani 1 1 d . . . . .
H00A H 0.5534 0.5971 0.3451 0.050 Uiso 1 1 calc GR . . . .
H00B H 0.5303 0.5251 0.2973 0.050 Uiso 1 1 calc GR . . . .
H00C H 0.5330 0.6783 0.2987 0.050 Uiso 1 1 calc GR . . . .
C00Z C 0.55499(19) 0.9208(4) 0.47295(13) 0.0262(7) Uani 1 1 d . . . . .
H00Z H 0.5476 0.9071 0.5058 0.031 Uiso 1 1 calc R . . . .
C010 C 0.75496(18) 0.8885(4) 0.32433(19) 0.0344(9) Uani 1 1 d . . . . .
H01A H 0.7365 0.9496 0.3016 0.052 Uiso 1 1 calc GR . . . .
H01B H 0.7986 0.8975 0.3243 0.052 Uiso 1 1 calc GR . . . .
H01C H 0.7409 0.9060 0.3565 0.052 Uiso 1 1 calc GR . . . .
C011 C 0.60782(18) 0.9807(4) 0.45977(13) 0.0261(7) Uani 1 1 d . . . . .
H011 H 0.6359 1.0097 0.4837 0.031 Uiso 1 1 calc R . . . .
C012 C 0.51333(17) 0.8815(4) 0.43792(13) 0.0243(7) Uani 1 1 d . . . . .
H012 H 0.4768 0.8430 0.4468 0.029 Uiso 1 1 calc R . . . .
C013 C 0.77360(16) 0.6600(4) 0.34221(14) 0.0269(7) Uani 1 1 d . . . . .
H01D H 0.7644 0.6763 0.3757 0.040 Uiso 1 1 calc GR . . . .
H01E H 0.8165 0.6731 0.3379 0.040 Uiso 1 1 calc GR . . . .
H01F H 0.7629 0.5715 0.3339 0.040 Uiso 1 1 calc GR . . . .
C014 C 0.6482(2) 0.4725(4) 0.3103(2) 0.0434(12) Uani 1 1 d . . . . .
H01G H 0.6889 0.4695 0.2983 0.065 Uiso 1 1 calc GR . . . .
H01H H 0.6256 0.3978 0.2986 0.065 Uiso 1 1 calc GR . . . .
H01I H 0.6502 0.4717 0.3454 0.065 Uiso 1 1 calc GR . . . .
C015 C 0.7549(2) 0.7286(6) 0.25781(16) 0.0423(12) Uani 1 1 d . . . . .
H01J H 0.7426 0.6420 0.2481 0.063 Uiso 1 1 calc GR . . . .
H01K H 0.7984 0.7371 0.2555 0.063 Uiso 1 1 calc GR . . . .
H01L H 0.7348 0.7914 0.2367 0.063 Uiso 1 1 calc GR . . . .
C016 C 0.73460(17) 0.5864(4) 0.51372(14) 0.0258(7) Uani 1 1 d . . . . .
H01M H 0.7635 0.6145 0.4903 0.039 Uiso 1 1 calc GR . . . .
H01N H 0.7467 0.5027 0.5267 0.039 Uiso 1 1 calc GR . . . .
H01O H 0.7334 0.6489 0.5398 0.039 Uiso 1 1 calc GR . . . .
C017 C 0.6131(2) 0.5961(5) 0.23779(15) 0.0383(11) Uani 1 1 d . . . . .
H01P H 0.5879 0.6676 0.2266 0.057 Uiso 1 1 calc GR . . . .
H01Q H 0.5957 0.5152 0.2262 0.057 Uiso 1 1 calc GR . . . .
H01R H 0.6534 0.6059 0.2255 0.057 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2363(8) . ?
Au01 O005 2.090(2) . ?
Sb02 F004 1.855(3) . ?
Sb02 F006 1.900(3) . ?
Sb02 F007 1.861(3) . ?
Sb02 F009 1.847(3) . ?
Sb02 F00B 1.862(3) . ?
Sb02 F00D 1.872(3) . ?
P003 C00E 1.832(3) . ?
P003 C00S 1.880(3) . ?
P003 C00T 1.872(4) . ?
O005 N00A 1.340(3) . ?
F008 C00M 1.307(5) . ?
N00A C00I 1.286(4) . ?
N00A C016 1.468(4) . ?
F00C C00M 1.323(6) . ?
C00E C00G 1.407(5) . ?
C00E C00P 1.405(4) . ?
C00F C00G 1.492(5) . ?
C00F C00J 1.401(5) . ?
C00F C00R 1.397(5) . ?
C00G C00X 1.402(5) . ?
C00H C00M 1.498(5) . ?
C00H C00N 1.394(5) . ?
C00H C00O 1.389(5) . ?
C00I H00I 0.9500 . ?
C00I C00K 1.458(5) . ?
C00J H00J 0.9500 . ?
C00J C011 1.390(5) . ?
C00K C00Q 1.399(5) . ?
C00K C00V 1.404(4) . ?
F00L C00M 1.295(6) . ?
C00N H00N 0.9500 . ?
C00N C00Q 1.381(5) . ?
C00O H00O 0.9500 . ?
C00O C00V 1.392(5) . ?
C00P H00P 0.9500 . ?
C00P C00U 1.388(6) . ?
C00Q H00Q 0.9500 . ?
C00R H00R 0.9500 . ?
C00R C012 1.389(5) . ?
C00S C010 1.526(6) . ?
C00S C013 1.536(5) . ?
C00S C015 1.533(6) . ?
C00T C00Y 1.532(6) . ?
C00T C014 1.536(6) . ?
C00T C017 1.531(5) . ?
C00U H00U 0.9500 . ?
C00U C00W 1.388(7) . ?
C00V H00V 0.9500 . ?
C00W H00W 0.9500 . ?
C00W C00X 1.386(6) . ?
C00X H00X 0.9500 . ?
C00Y H00A 0.9800 . ?
C00Y H00B 0.9800 . ?
C00Y H00C 0.9800 . ?
C00Z H00Z 0.9500 . ?
C00Z C011 1.396(6) . ?
C00Z C012 1.388(6) . ?
C010 H01A 0.9800 . ?
C010 H01B 0.9800 . ?
C010 H01C 0.9800 . ?
C011 H011 0.9500 . ?
C012 H012 0.9500 . ?
C013 H01D 0.9800 . ?
C013 H01E 0.9800 . ?
C013 H01F 0.9800 . ?
C014 H01G 0.9800 . ?
C014 H01H 0.9800 . ?
C014 H01I 0.9800 . ?
C015 H01J 0.9800 . ?
C015 H01K 0.9800 . ?
C015 H01L 0.9800 . ?
C016 H01M 0.9800 . ?
C016 H01N 0.9800 . ?
C016 H01O 0.9800 . ?
C017 H01P 0.9800 . ?
C017 H01Q 0.9800 . ?
C017 H01R 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O005 Au01 P003 175.85(7) . . ?
F004 Sb02 F006 89.12(14) . . ?
F004 Sb02 F007 91.26(16) . . ?
F004 Sb02 F00B 89.25(17) . . ?
F004 Sb02 F00D 178.08(15) . . ?
F007 Sb02 F006 88.38(15) . . ?
F007 Sb02 F00B 176.65(18) . . ?
F007 Sb02 F00D 89.57(17) . . ?
F009 Sb02 F004 91.84(15) . . ?
F009 Sb02 F006 178.47(15) . . ?
F009 Sb02 F007 90.41(16) . . ?
F009 Sb02 F00B 92.88(19) . . ?
F009 Sb02 F00D 89.89(17) . . ?
F00B Sb02 F006 88.32(19) . . ?
F00B Sb02 F00D 89.83(18) . . ?
F00D Sb02 F006 89.17(16) . . ?
C00E P003 Au01 115.20(11) . . ?
C00E P003 C00S 105.63(16) . . ?
C00E P003 C00T 106.65(17) . . ?
C00S P003 Au01 105.79(11) . . ?
C00T P003 Au01 108.27(12) . . ?
C00T P003 C00S 115.60(18) . . ?
N00A O005 Au01 114.76(18) . . ?
O005 N00A C016 114.1(3) . . ?
C00I N00A O005 124.0(3) . . ?
C00I N00A C016 121.8(3) . . ?
C00G C00E P003 123.2(2) . . ?
C00P C00E P003 118.2(3) . . ?
C00P C00E C00G 118.5(3) . . ?
C00J C00F C00G 120.9(3) . . ?
C00R C00F C00G 119.9(3) . . ?
C00R C00F C00J 119.1(3) . . ?
C00E C00G C00F 124.3(3) . . ?
C00X C00G C00E 118.8(3) . . ?
C00X C00G C00F 116.9(3) . . ?
C00N C00H C00M 119.1(3) . . ?
C00O C00H C00M 120.1(3) . . ?
C00O C00H C00N 120.8(3) . . ?
N00A C00I H00I 116.3 . . ?
N00A C00I C00K 127.5(3) . . ?
C00K C00I H00I 116.3 . . ?
C00F C00J H00J 119.9 . . ?
C011 C00J C00F 120.2(3) . . ?
C011 C00J H00J 119.9 . . ?
C00Q C00K C00I 114.8(3) . . ?
C00Q C00K C00V 119.6(3) . . ?
C00V C00K C00I 125.6(3) . . ?
F008 C00M F00C 104.9(5) . . ?
F008 C00M C00H 113.0(3) . . ?
F00C C00M C00H 113.1(4) . . ?
F00L C00M F008 107.3(4) . . ?
F00L C00M F00C 104.0(5) . . ?
F00L C00M C00H 113.7(4) . . ?
C00H C00N H00N 120.3 . . ?
C00Q C00N C00H 119.4(3) . . ?
C00Q C00N H00N 120.3 . . ?
C00H C00O H00O 120.1 . . ?
C00H C00O C00V 119.8(3) . . ?
C00V C00O H00O 120.1 . . ?
C00E C00P H00P 119.0 . . ?
C00U C00P C00E 122.0(4) . . ?
C00U C00P H00P 119.0 . . ?
C00K C00Q H00Q 119.7 . . ?
C00N C00Q C00K 120.6(3) . . ?
C00N C00Q H00Q 119.7 . . ?
C00F C00R H00R 119.7 . . ?
C012 C00R C00F 120.6(3) . . ?
C012 C00R H00R 119.7 . . ?
C010 C00S P003 106.1(3) . . ?
C010 C00S C013 107.6(3) . . ?
C010 C00S C015 109.6(4) . . ?
C013 C00S P003 109.2(2) . . ?
C015 C00S P003 115.8(3) . . ?
C015 C00S C013 108.3(3) . . ?
C00Y C00T P003 105.4(3) . . ?
C00Y C00T C014 109.9(4) . . ?
C014 C00T P003 108.4(3) . . ?
C017 C00T P003 116.0(3) . . ?
C017 C00T C00Y 107.5(3) . . ?
C017 C00T C014 109.5(4) . . ?
C00P C00U H00U 120.4 . . ?
C00P C00U C00W 119.1(3) . . ?
C00W C00U H00U 120.4 . . ?
C00K C00V H00V 120.1 . . ?
C00O C00V C00K 119.7(3) . . ?
C00O C00V H00V 120.1 . . ?
C00U C00W H00W 120.1 . . ?
C00X C00W C00U 119.9(4) . . ?
C00X C00W H00W 120.1 . . ?
C00G C00X H00X 119.2 . . ?
C00W C00X C00G 121.6(4) . . ?
C00W C00X H00X 119.2 . . ?
C00T C00Y H00A 109.5 . . ?
C00T C00Y H00B 109.5 . . ?
C00T C00Y H00C 109.5 . . ?
H00A C00Y H00B 109.5 . . ?
H00A C00Y H00C 109.5 . . ?
H00B C00Y H00C 109.5 . . ?
C011 C00Z H00Z 120.1 . . ?
C012 C00Z H00Z 120.1 . . ?
C012 C00Z C011 119.8(3) . . ?
C00S C010 H01A 109.5 . . ?
C00S C010 H01B 109.5 . . ?
C00S C010 H01C 109.5 . . ?
H01A C010 H01B 109.5 . . ?
H01A C010 H01C 109.5 . . ?
H01B C010 H01C 109.5 . . ?
C00J C011 C00Z 120.1(3) . . ?
C00J C011 H011 119.9 . . ?
C00Z C011 H011 119.9 . . ?
C00R C012 H012 119.9 . . ?
C00Z C012 C00R 120.1(4) . . ?
C00Z C012 H012 119.9 . . ?
C00S C013 H01D 109.5 . . ?
C00S C013 H01E 109.5 . . ?
C00S C013 H01F 109.5 . . ?
H01D C013 H01E 109.5 . . ?
H01D C013 H01F 109.5 . . ?
H01E C013 H01F 109.5 . . ?
C00T C014 H01G 109.5 . . ?
C00T C014 H01H 109.5 . . ?
C00T C014 H01I 109.5 . . ?
H01G C014 H01H 109.5 . . ?
H01G C014 H01I 109.5 . . ?
H01H C014 H01I 109.5 . . ?
C00S C015 H01J 109.5 . . ?
C00S C015 H01K 109.5 . . ?
C00S C015 H01L 109.5 . . ?
H01J C015 H01K 109.5 . . ?
H01J C015 H01L 109.5 . . ?
H01K C015 H01L 109.5 . . ?
N00A C016 H01M 109.5 . . ?
N00A C016 H01N 109.5 . . ?
N00A C016 H01O 109.5 . . ?
H01M C016 H01N 109.5 . . ?
H01M C016 H01O 109.5 . . ?
H01N C016 H01O 109.5 . . ?
C00T C017 H01P 109.5 . . ?
C00T C017 H01Q 109.5 . . ?
C00T C017 H01R 109.5 . . ?
H01P C017 H01Q 109.5 . . ?
H01P C017 H01R 109.5 . . ?
H01Q C017 H01R 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-74
_audit_block_doi                 10.5517/ccdc.csd.cc1q0rs8
_database_code_depnum_ccdc_archive 'CCDC 1579660'
_audit_update_record             
;
2017-10-12 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2017-06-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.09.09 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H38 Au N O2 P, F6 Sb'
_chemical_formula_sum            'C33 H0.50 Au F5 N0.50 O0.50 P Sb'
_chemical_formula_weight         856.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7651(4)
_cell_length_b                   10.8864(4)
_cell_length_c                   14.9113(6)
_cell_angle_alpha                105.1310(10)
_cell_angle_beta                 107.5650(10)
_cell_angle_gamma                99.5190(10)
_cell_volume                     1550.64(10)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9267
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      33.41
_cell_measurement_theta_min      2.47
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.700
_exptl_absorpt_correction_T_max  0.5957
_exptl_absorpt_correction_T_min  0.3879
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0750 before and 0.0419 after correction.
The Ratio of minimum to maximum transmission is 0.6512.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.834
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       ?
_exptl_crystal_F_000             792
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_unetI/netI     0.0273
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            46663
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         33.433
_diffrn_reflns_theta_min         2.466
_diffrn_ambient_temperature      113.32
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10942
_reflns_number_total             12019
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_refine_diff_density_max         0.802
_refine_diff_density_min         -1.331
_refine_diff_density_rms         0.110
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     378
_refine_ls_number_reflns         12019
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0253
_refine_ls_R_factor_gt           0.0199
_refine_ls_restrained_S_all      1.060
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0123P)²+0.8797P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0392
_refine_ls_wR_factor_ref         0.0405
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00D(H00D), C00F(H00F), C00J(H00J), C00M(H00M), C00O(H00O), C00P(H00P),
 C00Q(H00Q), C00R(H00R), C00V(H00V), C00W(H00W), C00X(H00X), C00Y(H00Y),
 C010(H010), C014(H014)
2.b Idealised Me refined as rotating group:
 C00L(H00A,H00B,H00C), C00N(H00E,H00G,H00H), C00S(H00I,H00K,H00L), C00Z(H00N,
 H00S,H00T), C011(H01A,H01B,H01C), C012(H01D,H01E,H01F), C013(H01G,H01H,H01I),
 C015(H01J,H01K,H01L)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.62670(2) 0.69287(2) 0.71485(2) 0.01276(2) Uani 1 1 d . . . . .
Sb02 Sb 0.07379(2) 0.34138(2) 0.66806(2) 0.01759(3) Uani 1 1 d . . . . .
P003 P 0.68827(4) 0.68772(4) 0.87101(3) 0.01205(7) Uani 1 1 d . . . . .
O004 O 0.55625(12) 0.68747(14) 0.56687(9) 0.0185(2) Uani 1 1 d . . . . .
F005 F -0.02149(13) 0.40571(15) 0.57084(10) 0.0356(3) Uani 1 1 d . . . . .
F006 F 0.20780(12) 0.33514(14) 0.61322(9) 0.0296(3) Uani 1 1 d . . . . .
N007 N 0.42314(14) 0.67280(15) 0.52453(11) 0.0165(3) Uani 1 1 d . . . . .
F008 F 0.16693(15) 0.51237(15) 0.75305(12) 0.0484(4) Uani 1 1 d . . . . .
O009 O 0.61585(14) 1.07478(15) 0.30216(11) 0.0272(3) Uani 1 1 d . . . . .
F00A F 0.16415(15) 0.27491(17) 0.76522(11) 0.0437(4) Uani 1 1 d . . . . .
F00B F -0.02225(17) 0.16991(15) 0.58294(12) 0.0512(4) Uani 1 1 d . . . . .
F00C F -0.06551(14) 0.3477(2) 0.71897(11) 0.0529(5) Uani 1 1 d . . . . .
C00D C 0.37314(17) 0.88377(17) 0.36862(13) 0.0176(3) Uani 1 1 d . . . . .
H00D H 0.2796 0.8693 0.3579 0.021 Uiso 1 1 calc R . . . .
C00E C 0.45050(17) 0.81876(17) 0.42520(12) 0.0151(3) Uani 1 1 d . . . . .
C00F C 0.37724(17) 0.73212(17) 0.46129(13) 0.0168(3) Uani 1 1 d . . . . .
H00F H 0.2817 0.7160 0.4352 0.020 Uiso 1 1 calc R . . . .
C00G C 0.63606(17) 0.50991(17) 0.86099(13) 0.0161(3) Uani 1 1 d . . . . .
C00H C 0.87055(16) 0.73635(16) 0.93920(12) 0.0132(3) Uani 1 1 d . . . . .
C00I C 0.96445(16) 0.76349(16) 0.89388(12) 0.0134(3) Uani 1 1 d . . . . .
C00J C 0.43045(18) 0.96781(18) 0.32862(14) 0.0195(3) Uani 1 1 d . . . . .
H00J H 0.3770 1.0114 0.2912 0.023 Uiso 1 1 calc R . . . .
C00K C 0.93367(16) 0.79255(17) 0.79817(12) 0.0138(3) Uani 1 1 d . . . . .
C00L C 0.33281(18) 0.5813(2) 0.54923(15) 0.0225(4) Uani 1 1 d . . . . .
H00A H 0.3498 0.4940 0.5320 0.034 Uiso 1 1 calc GR . . . .
H00B H 0.2386 0.5745 0.5114 0.034 Uiso 1 1 calc GR . . . .
H00C H 0.3498 0.6143 0.6207 0.034 Uiso 1 1 calc GR . . . .
C00M C 0.91857(17) 0.72646(17) 1.03512(13) 0.0161(3) Uani 1 1 d . . . . .
H00M H 0.8565 0.7108 1.0672 0.019 Uiso 1 1 calc R . . . .
C00N C 0.7259(2) 0.44333(18) 0.81289(14) 0.0202(3) Uani 1 1 d . . . . .
H00E H 0.7160 0.4602 0.7500 0.030 Uiso 1 1 calc GR . . . .
H00G H 0.6986 0.3480 0.7998 0.030 Uiso 1 1 calc GR . . . .
H00H H 0.8205 0.4792 0.8581 0.030 Uiso 1 1 calc GR . . . .
C00O C 0.93013(18) 0.70095(18) 0.71167(13) 0.0186(3) Uani 1 1 d . . . . .
H00O H 0.9369 0.6148 0.7109 0.022 Uiso 1 1 calc R . . . .
C00P C 0.58762(18) 0.83993(19) 0.43858(13) 0.0188(3) Uani 1 1 d . . . . .
H00P H 0.6414 0.7966 0.4761 0.023 Uiso 1 1 calc R . . . .
C00Q C 0.91382(18) 0.9538(2) 0.71356(15) 0.0217(4) Uani 1 1 d . . . . .
H00Q H 0.9090 1.0404 0.7144 0.026 Uiso 1 1 calc R . . . .
C00R C 0.91668(19) 0.7358(2) 0.62657(14) 0.0230(4) Uani 1 1 d . . . . .
H00R H 0.9126 0.6726 0.5674 0.028 Uiso 1 1 calc R . . . .
C00S C 0.4882(2) 0.4483(2) 0.79013(17) 0.0285(4) Uani 1 1 d . . . . .
H00I H 0.4290 0.4873 0.8208 0.043 Uiso 1 1 calc GR . . . .
H00K H 0.4652 0.3529 0.7772 0.043 Uiso 1 1 calc GR . . . .
H00L H 0.4763 0.4657 0.7272 0.043 Uiso 1 1 calc GR . . . .
C00T C 0.61078(17) 0.80151(17) 0.94128(13) 0.0163(3) Uani 1 1 d . . . . .
C00U C 0.56778(18) 0.98855(18) 0.34338(14) 0.0193(3) Uani 1 1 d . . . . .
C00V C 1.14472(18) 0.75905(19) 1.03696(14) 0.0210(4) Uani 1 1 d . . . . .
H00V H 1.2373 0.7644 1.0688 0.025 Uiso 1 1 calc R . . . .
C00W C 1.10001(18) 0.77139(18) 0.94324(14) 0.0191(3) Uani 1 1 d . . . . .
H00W H 1.1630 0.7856 0.9116 0.023 Uiso 1 1 calc R . . . .
C00X C 0.92545(18) 0.91932(18) 0.79848(14) 0.0179(3) Uani 1 1 d . . . . .
H00X H 0.9278 0.9823 0.8571 0.022 Uiso 1 1 calc R . . . .
C00Y C 1.05433(18) 0.73895(18) 1.08406(13) 0.0183(3) Uani 1 1 d . . . . .
H00Y H 1.0849 0.7337 1.1494 0.022 Uiso 1 1 calc R . . . .
C00Z C 0.6544(2) 0.8245(2) 1.05332(14) 0.0252(4) Uani 1 1 d . . . . .
H00N H 0.6349 0.7397 1.0644 0.038 Uiso 1 1 calc GR . . . .
H00S H 0.6047 0.8814 1.0819 0.038 Uiso 1 1 calc GR . . . .
H00T H 0.7516 0.8672 1.0855 0.038 Uiso 1 1 calc GR . . . .
C010 C 0.90922(18) 0.8616(2) 0.62731(14) 0.0229(4) Uani 1 1 d . . . . .
H010 H 0.9010 0.8850 0.5691 0.027 Uiso 1 1 calc R . . . .
C011 C 0.6551(2) 0.93337(19) 0.92622(17) 0.0278(4) Uani 1 1 d . . . . .
H01A H 0.7538 0.9604 0.9482 0.042 Uiso 1 1 calc GR . . . .
H01B H 0.6243 1.0006 0.9654 0.042 Uiso 1 1 calc GR . . . .
H01C H 0.6154 0.9235 0.8555 0.042 Uiso 1 1 calc GR . . . .
C012 C 0.6531(2) 0.4831(2) 0.95914(15) 0.0257(4) Uani 1 1 d . . . . .
H01D H 0.7494 0.5090 1.0005 0.038 Uiso 1 1 calc GR . . . .
H01E H 0.6157 0.3888 0.9452 0.038 Uiso 1 1 calc GR . . . .
H01F H 0.6053 0.5343 0.9946 0.038 Uiso 1 1 calc GR . . . .
C013 C 0.45620(19) 0.7509(2) 0.89310(16) 0.0263(4) Uani 1 1 d . . . . .
H01G H 0.4287 0.7285 0.8206 0.039 Uiso 1 1 calc GR . . . .
H01H H 0.4154 0.8196 0.9188 0.039 Uiso 1 1 calc GR . . . .
H01I H 0.4259 0.6721 0.9092 0.039 Uiso 1 1 calc GR . . . .
C014 C 0.64594(18) 0.92341(19) 0.39770(14) 0.0202(3) Uani 1 1 d . . . . .
H014 H 0.7389 0.9363 0.4066 0.024 Uiso 1 1 calc R . . . .
C015 C 0.7577(2) 1.1032(3) 0.31854(17) 0.0322(5) Uani 1 1 d . . . . .
H01J H 0.7798 1.1678 0.2868 0.048 Uiso 1 1 calc GR . . . .
H01K H 0.7799 1.0219 0.2897 0.048 Uiso 1 1 calc GR . . . .
H01L H 0.8100 1.1394 0.3903 0.048 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2390(4) . ?
Au01 O004 2.0869(12) . ?
Sb02 F005 1.8746(12) . ?
Sb02 F006 1.8628(11) . ?
Sb02 F008 1.8603(14) . ?
Sb02 F00A 1.8703(13) . ?
Sb02 F00B 1.8701(15) . ?
Sb02 F00C 1.8772(13) . ?
P003 C00G 1.8772(18) . ?
P003 C00H 1.8265(17) . ?
P003 C00T 1.8761(17) . ?
O004 N007 1.3428(18) . ?
N007 C00F 1.301(2) . ?
N007 C00L 1.470(2) . ?
O009 C00U 1.364(2) . ?
O009 C015 1.437(2) . ?
C00D H00D 0.9500 . ?
C00D C00E 1.410(2) . ?
C00D C00J 1.376(3) . ?
C00E C00F 1.441(3) . ?
C00E C00P 1.399(2) . ?
C00F H00F 0.9500 . ?
C00G C00N 1.534(2) . ?
C00G C00S 1.536(3) . ?
C00G C012 1.530(3) . ?
C00H C00I 1.408(2) . ?
C00H C00M 1.406(2) . ?
C00I C00K 1.494(2) . ?
C00I C00W 1.398(2) . ?
C00J H00J 0.9500 . ?
C00J C00U 1.397(3) . ?
C00K C00O 1.395(2) . ?
C00K C00X 1.396(2) . ?
C00L H00A 0.9800 . ?
C00L H00B 0.9800 . ?
C00L H00C 0.9800 . ?
C00M H00M 0.9500 . ?
C00M C00Y 1.388(2) . ?
C00N H00E 0.9800 . ?
C00N H00G 0.9800 . ?
C00N H00H 0.9800 . ?
C00O H00O 0.9500 . ?
C00O C00R 1.390(3) . ?
C00P H00P 0.9500 . ?
C00P C014 1.387(3) . ?
C00Q H00Q 0.9500 . ?
C00Q C00X 1.388(3) . ?
C00Q C010 1.391(3) . ?
C00R H00R 0.9500 . ?
C00R C010 1.383(3) . ?
C00S H00I 0.9800 . ?
C00S H00K 0.9800 . ?
C00S H00L 0.9800 . ?
C00T C00Z 1.531(3) . ?
C00T C011 1.531(3) . ?
C00T C013 1.535(3) . ?
C00U C014 1.397(3) . ?
C00V H00V 0.9500 . ?
C00V C00W 1.384(3) . ?
C00V C00Y 1.382(3) . ?
C00W H00W 0.9500 . ?
C00X H00X 0.9500 . ?
C00Y H00Y 0.9500 . ?
C00Z H00N 0.9800 . ?
C00Z H00S 0.9800 . ?
C00Z H00T 0.9800 . ?
C010 H010 0.9500 . ?
C011 H01A 0.9800 . ?
C011 H01B 0.9800 . ?
C011 H01C 0.9800 . ?
C012 H01D 0.9800 . ?
C012 H01E 0.9800 . ?
C012 H01F 0.9800 . ?
C013 H01G 0.9800 . ?
C013 H01H 0.9800 . ?
C013 H01I 0.9800 . ?
C014 H014 0.9500 . ?
C015 H01J 0.9800 . ?
C015 H01K 0.9800 . ?
C015 H01L 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O004 Au01 P003 175.83(4) . . ?
F005 Sb02 F00C 87.76(6) . . ?
F006 Sb02 F005 90.31(6) . . ?
F006 Sb02 F00A 91.12(6) . . ?
F006 Sb02 F00B 90.27(7) . . ?
F006 Sb02 F00C 177.94(6) . . ?
F008 Sb02 F005 90.96(7) . . ?
F008 Sb02 F006 90.55(7) . . ?
F008 Sb02 F00A 89.84(8) . . ?
F008 Sb02 F00B 179.13(8) . . ?
F008 Sb02 F00C 90.18(8) . . ?
F00A Sb02 F005 178.35(6) . . ?
F00A Sb02 F00C 90.80(7) . . ?
F00B Sb02 F005 88.74(7) . . ?
F00B Sb02 F00A 90.43(8) . . ?
F00B Sb02 F00C 88.99(8) . . ?
C00G P003 Au01 106.51(6) . . ?
C00H P003 Au01 114.71(6) . . ?
C00H P003 C00G 103.61(8) . . ?
C00H P003 C00T 108.42(8) . . ?
C00T P003 Au01 108.22(6) . . ?
C00T P003 C00G 115.56(8) . . ?
N007 O004 Au01 116.61(10) . . ?
O004 N007 C00L 116.58(14) . . ?
C00F N007 O004 121.22(15) . . ?
C00F N007 C00L 122.12(15) . . ?
C00U O009 C015 117.41(16) . . ?
C00E C00D H00D 119.3 . . ?
C00J C00D H00D 119.3 . . ?
C00J C00D C00E 121.35(16) . . ?
C00D C00E C00F 115.51(15) . . ?
C00P C00E C00D 118.31(16) . . ?
C00P C00E C00F 126.15(16) . . ?
N007 C00F C00E 129.28(16) . . ?
N007 C00F H00F 115.4 . . ?
C00E C00F H00F 115.4 . . ?
C00N C00G P003 104.89(12) . . ?
C00N C00G C00S 108.30(16) . . ?
C00S C00G P003 109.58(12) . . ?
C012 C00G P003 116.03(13) . . ?
C012 C00G C00N 108.81(15) . . ?
C012 C00G C00S 108.94(16) . . ?
C00I C00H P003 122.27(12) . . ?
C00M C00H P003 118.53(13) . . ?
C00M C00H C00I 118.45(15) . . ?
C00H C00I C00K 125.44(14) . . ?
C00W C00I C00H 118.81(16) . . ?
C00W C00I C00K 115.67(15) . . ?
C00D C00J H00J 120.2 . . ?
C00D C00J C00U 119.55(16) . . ?
C00U C00J H00J 120.2 . . ?
C00O C00K C00I 121.05(15) . . ?
C00O C00K C00X 119.30(16) . . ?
C00X C00K C00I 119.14(15) . . ?
N007 C00L H00A 109.5 . . ?
N007 C00L H00B 109.5 . . ?
N007 C00L H00C 109.5 . . ?
H00A C00L H00B 109.5 . . ?
H00A C00L H00C 109.5 . . ?
H00B C00L H00C 109.5 . . ?
C00H C00M H00M 119.2 . . ?
C00Y C00M C00H 121.66(16) . . ?
C00Y C00M H00M 119.2 . . ?
C00G C00N H00E 109.5 . . ?
C00G C00N H00G 109.5 . . ?
C00G C00N H00H 109.5 . . ?
H00E C00N H00G 109.5 . . ?
H00E C00N H00H 109.5 . . ?
H00G C00N H00H 109.5 . . ?
C00K C00O H00O 120.0 . . ?
C00R C00O C00K 119.98(17) . . ?
C00R C00O H00O 120.0 . . ?
C00E C00P H00P 119.6 . . ?
C014 C00P C00E 120.74(16) . . ?
C014 C00P H00P 119.6 . . ?
C00X C00Q H00Q 120.0 . . ?
C00X C00Q C010 120.07(18) . . ?
C010 C00Q H00Q 120.0 . . ?
C00O C00R H00R 119.7 . . ?
C010 C00R C00O 120.54(18) . . ?
C010 C00R H00R 119.7 . . ?
C00G C00S H00I 109.5 . . ?
C00G C00S H00K 109.5 . . ?
C00G C00S H00L 109.5 . . ?
H00I C00S H00K 109.5 . . ?
H00I C00S H00L 109.5 . . ?
H00K C00S H00L 109.5 . . ?
C00Z C00T P003 116.25(12) . . ?
C00Z C00T C011 108.47(16) . . ?
C00Z C00T C013 109.38(16) . . ?
C011 C00T P003 104.48(12) . . ?
C011 C00T C013 108.80(16) . . ?
C013 C00T P003 109.17(12) . . ?
O009 C00U C00J 115.32(16) . . ?
O009 C00U C014 124.55(17) . . ?
C00J C00U C014 120.12(17) . . ?
C00W C00V H00V 120.1 . . ?
C00Y C00V H00V 120.1 . . ?
C00Y C00V C00W 119.81(16) . . ?
C00I C00W H00W 119.2 . . ?
C00V C00W C00I 121.69(17) . . ?
C00V C00W H00W 119.2 . . ?
C00K C00X H00X 119.8 . . ?
C00Q C00X C00K 120.32(17) . . ?
C00Q C00X H00X 119.8 . . ?
C00M C00Y H00Y 120.3 . . ?
C00V C00Y C00M 119.46(16) . . ?
C00V C00Y H00Y 120.3 . . ?
C00T C00Z H00N 109.5 . . ?
C00T C00Z H00S 109.5 . . ?
C00T C00Z H00T 109.5 . . ?
H00N C00Z H00S 109.5 . . ?
H00N C00Z H00T 109.5 . . ?
H00S C00Z H00T 109.5 . . ?
C00Q C010 H010 120.1 . . ?
C00R C010 C00Q 119.77(17) . . ?
C00R C010 H010 120.1 . . ?
C00T C011 H01A 109.5 . . ?
C00T C011 H01B 109.5 . . ?
C00T C011 H01C 109.5 . . ?
H01A C011 H01B 109.5 . . ?
H01A C011 H01C 109.5 . . ?
H01B C011 H01C 109.5 . . ?
C00G C012 H01D 109.5 . . ?
C00G C012 H01E 109.5 . . ?
C00G C012 H01F 109.5 . . ?
H01D C012 H01E 109.5 . . ?
H01D C012 H01F 109.5 . . ?
H01E C012 H01F 109.5 . . ?
C00T C013 H01G 109.5 . . ?
C00T C013 H01H 109.5 . . ?
C00T C013 H01I 109.5 . . ?
H01G C013 H01H 109.5 . . ?
H01G C013 H01I 109.5 . . ?
H01H C013 H01I 109.5 . . ?
C00P C014 C00U 119.91(16) . . ?
C00P C014 H014 120.0 . . ?
C00U C014 H014 120.0 . . ?
O009 C015 H01J 109.5 . . ?
O009 C015 H01K 109.5 . . ?
O009 C015 H01L 109.5 . . ?
H01J C015 H01K 109.5 . . ?
H01J C015 H01L 109.5 . . ?
H01K C015 H01L 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P003 C00G C00N 66.74(12) . . . . ?
Au01 P003 C00G C00S -49.33(14) . . . . ?
Au01 P003 C00G C012 -173.19(12) . . . . ?
Au01 P003 C00H C00I -5.35(16) . . . . ?
Au01 P003 C00H C00M -175.26(11) . . . . ?
Au01 P003 C00T C00Z -173.03(13) . . . . ?
Au01 P003 C00T C011 -53.54(13) . . . . ?
Au01 P003 C00T C013 62.69(14) . . . . ?
Au01 O004 N007 C00F 143.84(14) . . . . ?
Au01 O004 N007 C00L -39.34(19) . . . . ?
P003 C00H C00I C00K 17.5(2) . . . . ?
P003 C00H C00I C00W -166.03(13) . . . . ?
P003 C00H C00M C00Y 168.43(14) . . . . ?
O004 N007 C00F C00E 0.0(3) . . . . ?
O009 C00U C014 C00P 178.44(18) . . . . ?
C00D C00E C00F N007 -170.52(18) . . . . ?
C00D C00E C00P C014 0.4(3) . . . . ?
C00D C00J C00U O009 -179.12(17) . . . . ?
C00D C00J C00U C014 0.5(3) . . . . ?
C00E C00D C00J C00U 0.6(3) . . . . ?
C00E C00P C014 C00U 0.7(3) . . . . ?
C00F C00E C00P C014 178.19(18) . . . . ?
C00G P003 C00H C00I 110.33(14) . . . . ?
C00G P003 C00H C00M -59.59(15) . . . . ?
C00G P003 C00T C00Z 67.70(16) . . . . ?
C00G P003 C00T C011 -172.81(13) . . . . ?
C00G P003 C00T C013 -56.58(15) . . . . ?
C00H P003 C00G C00N -54.62(13) . . . . ?
C00H P003 C00G C00S -170.69(14) . . . . ?
C00H P003 C00G C012 65.45(15) . . . . ?
C00H P003 C00T C00Z -48.04(16) . . . . ?
C00H P003 C00T C011 71.45(14) . . . . ?
C00H P003 C00T C013 -172.31(13) . . . . ?
C00H C00I C00K C00O -108.2(2) . . . . ?
C00H C00I C00K C00X 80.0(2) . . . . ?
C00H C00I C00W C00V -2.9(3) . . . . ?
C00H C00M C00Y C00V -1.3(3) . . . . ?
C00I C00H C00M C00Y -1.9(3) . . . . ?
C00I C00K C00O C00R -172.63(16) . . . . ?
C00I C00K C00X C00Q 171.95(16) . . . . ?
C00J C00D C00E C00F -179.09(17) . . . . ?
C00J C00D C00E C00P -1.1(3) . . . . ?
C00J C00U C014 C00P -1.2(3) . . . . ?
C00K C00I C00W C00V 173.87(17) . . . . ?
C00K C00O C00R C010 1.2(3) . . . . ?
C00L N007 C00F C00E -176.62(18) . . . . ?
C00M C00H C00I C00K -172.53(16) . . . . ?
C00M C00H C00I C00W 3.9(2) . . . . ?
C00O C00K C00X C00Q 0.0(3) . . . . ?
C00O C00R C010 C00Q -0.7(3) . . . . ?
C00P C00E C00F N007 11.6(3) . . . . ?
C00T P003 C00G C00N -173.05(11) . . . . ?
C00T P003 C00G C00S 70.88(15) . . . . ?
C00T P003 C00G C012 -52.98(16) . . . . ?
C00T P003 C00H C00I -126.41(14) . . . . ?
C00T P003 C00H C00M 63.68(15) . . . . ?
C00W C00I C00K C00O 75.3(2) . . . . ?
C00W C00I C00K C00X -96.51(19) . . . . ?
C00W C00V C00Y C00M 2.4(3) . . . . ?
C00X C00K C00O C00R -0.9(3) . . . . ?
C00X C00Q C010 C00R -0.2(3) . . . . ?
C00Y C00V C00W C00I -0.3(3) . . . . ?
C010 C00Q C00X C00K 0.5(3) . . . . ?
C015 O009 C00U C00J 177.69(18) . . . . ?
C015 O009 C00U C014 -2.0(3) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-102-block
_audit_block_doi                 10.5517/ccdc.csd.cc1ndq1t
_database_code_depnum_ccdc_archive 'CCDC 1531556'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1021/acs.orglett.7b00411 2017
_audit_update_record             
;
2017-02-07 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-05-13
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C28 H36 Au N O P, F6 Sb'
_chemical_formula_sum            'C28 H36 Au F6 N O P Sb'
_chemical_formula_weight         866.26
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   7.4853(6)
_cell_length_b                   29.414(2)
_cell_length_c                   13.8470(11)
_cell_angle_alpha                90
_cell_angle_beta                 101.159(2)
_cell_angle_gamma                90
_cell_volume                     2991.1(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9774
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.50
_cell_measurement_theta_min      2.56
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.916
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.4732
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0977 before and 0.0492 after correction.
The Ratio of minimum to maximum transmission is 0.6341.
The λ/2 correction factor is Not present.
;

_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.924
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1672
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.11
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0222
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            57377
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         31.538
_diffrn_reflns_theta_min         2.562
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9429
_reflns_number_total             9907
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_refine_diff_density_max         1.468
_refine_diff_density_min         -2.265
_refine_diff_density_rms         0.143
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     359
_refine_ls_number_reflns         9907
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0343
_refine_ls_R_factor_gt           0.0317
_refine_ls_restrained_S_all      1.065
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+22.1062P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0638
_refine_ls_wR_factor_ref         0.0647
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00F(H00F), C00I(H00I), C00J(H00J), C00K(H00K), C00L(H00L), C00M(H00M),
 C00N(H00N), C00S(H00S), C00T(H00T), C00U(H00U), C00V(H00V), C00Y(H00Z),
 C00Z(H00), C011(H011), C012(H012)
2.b Idealised Me refined as rotating group:
 C00D(H00A,H00B,H00C), C00H(H00D,H00E,H00G), C00R(H00H,H00O,H00P), C00W(H00Q,
 H00R,H00W), C00X(H00X,H00Y,H), C010(H01A,H01B,H01C), C013(H01D,H01E,H01F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.50750(2) 0.38129(2) 0.78124(2) 0.01132(3) Uani 1 1 d . . . . .
Sb02 Sb -0.12830(3) 0.13991(2) 0.70636(2) 0.01137(4) Uani 1 1 d . . . . .
P003 P 0.31168(11) 0.32817(3) 0.70862(6) 0.01077(14) Uani 1 1 d . . . . .
F004 F -0.1448(3) 0.10628(8) 0.58887(17) 0.0218(4) Uani 1 1 d . . . . .
F005 F -0.3826(3) 0.13755(9) 0.68940(19) 0.0239(5) Uani 1 1 d . . . . .
F006 F -0.1498(3) 0.19403(7) 0.63341(17) 0.0215(4) Uani 1 1 d . . . . .
O007 O 0.6839(3) 0.42932(8) 0.86103(18) 0.0148(5) Uani 1 1 d . . . . .
F008 F -0.1090(4) 0.08483(8) 0.77570(19) 0.0253(5) Uani 1 1 d . . . . .
F009 F 0.1258(3) 0.14226(10) 0.7150(2) 0.0289(5) Uani 1 1 d . . . . .
F00A F -0.1099(4) 0.17273(8) 0.82373(17) 0.0242(5) Uani 1 1 d . . . . .
N00B N 0.8071(4) 0.41578(9) 0.9393(2) 0.0119(5) Uani 1 1 d . . . . .
C00C C 0.1758(4) 0.34523(12) 0.5898(2) 0.0129(6) Uani 1 1 d . . . . .
C00D C 0.0067(5) 0.35572(13) 0.7759(3) 0.0215(7) Uani 1 1 d . . . . .
H00A H 0.0687 0.3852 0.7797 0.032 Uiso 1 1 calc GR . . . .
H00B H -0.0705 0.3545 0.8255 0.032 Uiso 1 1 calc GR . . . .
H00C H -0.0689 0.3519 0.7102 0.032 Uiso 1 1 calc GR . . . .
C00E C 0.2258(5) 0.38146(12) 0.5348(2) 0.0143(6) Uani 1 1 d . . . . .
C00F C 0.0205(5) 0.31968(13) 0.5506(3) 0.0166(6) Uani 1 1 d . . . . .
H00F H -0.0126 0.2949 0.5874 0.020 Uiso 1 1 calc R . . . .
C00G C 0.4372(5) 0.27628(12) 0.6812(3) 0.0165(6) Uani 1 1 d . . . . .
C00H C 0.7464(5) 0.38152(13) 1.0027(3) 0.0174(6) Uani 1 1 d . . . . .
H00D H 0.6324 0.3915 1.0208 0.026 Uiso 1 1 calc GR . . . .
H00E H 0.8397 0.3776 1.0623 0.026 Uiso 1 1 calc GR . . . .
H00G H 0.7265 0.3525 0.9673 0.026 Uiso 1 1 calc GR . . . .
C00I C 0.5428(5) 0.40562(13) 0.5273(3) 0.0197(7) Uani 1 1 d . . . . .
H00I H 0.5521 0.3801 0.4866 0.024 Uiso 1 1 calc R . . . .
C00J C 0.9694(4) 0.43298(11) 0.9589(2) 0.0119(5) Uani 1 1 d . . . . .
H00J H 1.0477 0.4217 1.0162 0.014 Uiso 1 1 calc R . . . .
C00K C 1.3240(5) 0.50268(13) 0.8746(3) 0.0200(7) Uani 1 1 d . . . . .
H00K H 1.4532 0.5040 0.8863 0.024 Uiso 1 1 calc R . . . .
C00L C 1.2372(5) 0.47049(12) 0.9228(3) 0.0161(6) Uani 1 1 d . . . . .
H00L H 1.3074 0.4504 0.9690 0.019 Uiso 1 1 calc R . . . .
C00M C 0.9436(5) 0.49805(12) 0.8376(3) 0.0144(6) Uani 1 1 d . . . . .
H00M H 0.8144 0.4965 0.8243 0.017 Uiso 1 1 calc R . . . .
C00N C 1.0319(5) 0.53071(12) 0.7916(3) 0.0181(7) Uani 1 1 d . . . . .
H00N H 0.9623 0.5518 0.7478 0.022 Uiso 1 1 calc R . . . .
C00O C 0.1496(5) 0.31727(12) 0.7952(3) 0.0158(6) Uani 1 1 d . . . . .
C00P C 1.0457(4) 0.46747(11) 0.9035(2) 0.0115(5) Uani 1 1 d . . . . .
C00Q C 0.3849(5) 0.41213(11) 0.5646(2) 0.0144(6) Uani 1 1 d . . . . .
C00R C 0.0552(5) 0.27078(13) 0.7857(3) 0.0199(7) Uani 1 1 d . . . . .
H00H H -0.0207 0.2678 0.7199 0.030 Uiso 1 1 calc GR . . . .
H00O H -0.0213 0.2681 0.8354 0.030 Uiso 1 1 calc GR . . . .
H00P H 0.1473 0.2467 0.7957 0.030 Uiso 1 1 calc GR . . . .
C00S C -0.0864(5) 0.32976(14) 0.4593(3) 0.0197(7) Uani 1 1 d . . . . .
H00S H -0.1935 0.3127 0.4353 0.024 Uiso 1 1 calc R . . . .
C00T C 0.1182(5) 0.39019(15) 0.4412(3) 0.0238(8) Uani 1 1 d . . . . .
H00T H 0.1522 0.4142 0.4026 0.029 Uiso 1 1 calc R . . . .
C00U C 1.2214(5) 0.53290(13) 0.8091(3) 0.0195(7) Uani 1 1 d . . . . .
H00U H 1.2804 0.5550 0.7763 0.023 Uiso 1 1 calc R . . . .
C00V C -0.0354(5) 0.36483(16) 0.4038(3) 0.0242(8) Uani 1 1 d . . . . .
H00V H -0.1052 0.3715 0.3405 0.029 Uiso 1 1 calc R . . . .
C00W C 0.5694(5) 0.29205(13) 0.6161(3) 0.0201(7) Uani 1 1 d . . . . .
H00Q H 0.5002 0.3036 0.5536 0.030 Uiso 1 1 calc GR . . . .
H00R H 0.6451 0.2664 0.6035 0.030 Uiso 1 1 calc GR . . . .
H00W H 0.6474 0.3163 0.6498 0.030 Uiso 1 1 calc GR . . . .
C00X C 0.2550(6) 0.32185(16) 0.9013(3) 0.0256(8) Uani 1 1 d . . . . .
H00X H 0.3513 0.2988 0.9138 0.038 Uiso 1 1 calc GR . . . .
H00Y H 0.1716 0.3175 0.9470 0.038 Uiso 1 1 calc GR . . . .
H H 0.3096 0.3522 0.9108 0.038 Uiso 1 1 calc GR . . . .
C00Y C 0.6717(6) 0.47430(15) 0.6059(3) 0.0270(9) Uani 1 1 d . . . . .
H00Z H 0.7691 0.4955 0.6194 0.032 Uiso 1 1 calc R . . . .
C00Z C 0.3720(6) 0.45065(13) 0.6227(3) 0.0210(7) Uani 1 1 d . . . . .
H00 H 0.2649 0.4557 0.6485 0.025 Uiso 1 1 calc R . . . .
C010 C 0.5453(5) 0.25726(14) 0.7788(3) 0.0244(8) Uani 1 1 d . . . . .
H01A H 0.6151 0.2818 0.8164 0.037 Uiso 1 1 calc GR . . . .
H01B H 0.6288 0.2336 0.7650 0.037 Uiso 1 1 calc GR . . . .
H01C H 0.4607 0.2443 0.8173 0.037 Uiso 1 1 calc GR . . . .
C011 C 0.6873(6) 0.43601(15) 0.5488(3) 0.0252(8) Uani 1 1 d . . . . .
H011 H 0.7960 0.4307 0.5248 0.030 Uiso 1 1 calc R . . . .
C012 C 0.5154(6) 0.48156(13) 0.6428(3) 0.0253(8) Uani 1 1 d . . . . .
H012 H 0.5057 0.5076 0.6820 0.030 Uiso 1 1 calc R . . . .
C013 C 0.3168(5) 0.23875(13) 0.6244(3) 0.0245(8) Uani 1 1 d . . . . .
H01D H 0.2265 0.2288 0.6626 0.037 Uiso 1 1 calc GR . . . .
H01E H 0.3931 0.2129 0.6137 0.037 Uiso 1 1 calc GR . . . .
H01F H 0.2543 0.2507 0.5607 0.037 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P003 2.2429(8) . ?
Au01 O007 2.096(2) . ?
Sb02 F004 1.888(2) . ?
Sb02 F005 1.874(2) . ?
Sb02 F006 1.875(2) . ?
Sb02 F008 1.875(2) . ?
Sb02 F009 1.884(2) . ?
Sb02 F00A 1.872(2) . ?
P003 C00C 1.830(3) . ?
P003 C00G 1.869(3) . ?
P003 C00O 1.891(3) . ?
O007 N00B 1.340(4) . ?
N00B C00H 1.466(4) . ?
N00B C00J 1.295(4) . ?
C00C C00E 1.402(5) . ?
C00C C00F 1.402(5) . ?
C00D H00A 0.9800 . ?
C00D H00B 0.9800 . ?
C00D H00C 0.9800 . ?
C00D C00O 1.544(5) . ?
C00E C00Q 1.487(5) . ?
C00E C00T 1.411(5) . ?
C00F H00F 0.9500 . ?
C00F C00S 1.391(5) . ?
C00G C00W 1.533(5) . ?
C00G C010 1.540(5) . ?
C00G C013 1.541(5) . ?
C00H H00D 0.9800 . ?
C00H H00E 0.9800 . ?
C00H H00G 0.9800 . ?
C00I H00I 0.9500 . ?
C00I C00Q 1.392(5) . ?
C00I C011 1.390(5) . ?
C00J H00J 0.9500 . ?
C00J C00P 1.453(4) . ?
C00K H00K 0.9500 . ?
C00K C00L 1.390(5) . ?
C00K C00U 1.390(5) . ?
C00L H00L 0.9500 . ?
C00L C00P 1.410(5) . ?
C00M H00M 0.9500 . ?
C00M C00N 1.388(5) . ?
C00M C00P 1.399(5) . ?
C00N H00N 0.9500 . ?
C00N C00U 1.394(5) . ?
C00O C00R 1.533(5) . ?
C00O C00X 1.533(5) . ?
C00Q C00Z 1.404(5) . ?
C00R H00H 0.9800 . ?
C00R H00O 0.9800 . ?
C00R H00P 0.9800 . ?
C00S H00S 0.9500 . ?
C00S C00V 1.384(6) . ?
C00T H00T 0.9500 . ?
C00T C00V 1.384(6) . ?
C00U H00U 0.9500 . ?
C00V H00V 0.9500 . ?
C00W H00Q 0.9800 . ?
C00W H00R 0.9800 . ?
C00W H00W 0.9800 . ?
C00X H00X 0.9800 . ?
C00X H00Y 0.9800 . ?
C00X H 0.9800 . ?
C00Y H00Z 0.9500 . ?
C00Y C011 1.393(6) . ?
C00Y C012 1.381(6) . ?
C00Z H00 0.9500 . ?
C00Z C012 1.393(6) . ?
C010 H01A 0.9800 . ?
C010 H01B 0.9800 . ?
C010 H01C 0.9800 . ?
C011 H011 0.9500 . ?
C012 H012 0.9500 . ?
C013 H01D 0.9800 . ?
C013 H01E 0.9800 . ?
C013 H01F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O007 Au01 P003 174.87(7) . . ?
F005 Sb02 F004 88.70(11) . . ?
F005 Sb02 F006 89.13(11) . . ?
F005 Sb02 F008 90.45(11) . . ?
F005 Sb02 F009 176.51(11) . . ?
F006 Sb02 F004 89.78(10) . . ?
F006 Sb02 F009 89.05(11) . . ?
F008 Sb02 F004 88.52(11) . . ?
F008 Sb02 F006 178.25(11) . . ?
F008 Sb02 F009 91.28(12) . . ?
F009 Sb02 F004 88.32(11) . . ?
F00A Sb02 F004 179.27(11) . . ?
F00A Sb02 F005 91.74(11) . . ?
F00A Sb02 F006 90.81(10) . . ?
F00A Sb02 F008 90.90(11) . . ?
F00A Sb02 F009 91.26(12) . . ?
C00C P003 Au01 114.43(11) . . ?
C00C P003 C00G 104.77(16) . . ?
C00C P003 C00O 107.68(16) . . ?
C00G P003 Au01 110.45(12) . . ?
C00G P003 C00O 113.56(16) . . ?
C00O P003 Au01 106.12(11) . . ?
N00B O007 Au01 119.38(19) . . ?
O007 N00B C00H 116.3(3) . . ?
C00J N00B O007 121.6(3) . . ?
C00J N00B C00H 122.0(3) . . ?
C00E C00C P003 122.4(3) . . ?
C00F C00C P003 118.4(3) . . ?
C00F C00C C00E 119.1(3) . . ?
H00A C00D H00B 109.5 . . ?
H00A C00D H00C 109.5 . . ?
H00B C00D H00C 109.5 . . ?
C00O C00D H00A 109.5 . . ?
C00O C00D H00B 109.5 . . ?
C00O C00D H00C 109.5 . . ?
C00C C00E C00Q 126.5(3) . . ?
C00C C00E C00T 118.2(3) . . ?
C00T C00E C00Q 115.4(3) . . ?
C00C C00F H00F 119.2 . . ?
C00S C00F C00C 121.7(3) . . ?
C00S C00F H00F 119.2 . . ?
C00W C00G P003 106.2(2) . . ?
C00W C00G C010 109.7(3) . . ?
C00W C00G C013 107.3(3) . . ?
C010 C00G P003 108.5(3) . . ?
C010 C00G C013 110.1(3) . . ?
C013 C00G P003 114.9(2) . . ?
N00B C00H H00D 109.5 . . ?
N00B C00H H00E 109.5 . . ?
N00B C00H H00G 109.5 . . ?
H00D C00H H00E 109.5 . . ?
H00D C00H H00G 109.5 . . ?
H00E C00H H00G 109.5 . . ?
C00Q C00I H00I 119.6 . . ?
C011 C00I H00I 119.6 . . ?
C011 C00I C00Q 120.9(4) . . ?
N00B C00J H00J 116.2 . . ?
N00B C00J C00P 127.6(3) . . ?
C00P C00J H00J 116.2 . . ?
C00L C00K H00K 120.1 . . ?
C00L C00K C00U 119.9(3) . . ?
C00U C00K H00K 120.1 . . ?
C00K C00L H00L 119.8 . . ?
C00K C00L C00P 120.3(3) . . ?
C00P C00L H00L 119.8 . . ?
C00N C00M H00M 120.1 . . ?
C00N C00M C00P 119.8(3) . . ?
C00P C00M H00M 120.1 . . ?
C00M C00N H00N 119.6 . . ?
C00M C00N C00U 120.7(3) . . ?
C00U C00N H00N 119.6 . . ?
C00D C00O P003 105.9(2) . . ?
C00R C00O P003 116.0(3) . . ?
C00R C00O C00D 110.3(3) . . ?
C00X C00O P003 108.5(2) . . ?
C00X C00O C00D 108.2(3) . . ?
C00X C00O C00R 107.7(3) . . ?
C00L C00P C00J 115.7(3) . . ?
C00M C00P C00J 124.9(3) . . ?
C00M C00P C00L 119.4(3) . . ?
C00I C00Q C00E 120.4(3) . . ?
C00I C00Q C00Z 118.8(3) . . ?
C00Z C00Q C00E 120.5(3) . . ?
C00O C00R H00H 109.5 . . ?
C00O C00R H00O 109.5 . . ?
C00O C00R H00P 109.5 . . ?
H00H C00R H00O 109.5 . . ?
H00H C00R H00P 109.5 . . ?
H00O C00R H00P 109.5 . . ?
C00F C00S H00S 120.3 . . ?
C00V C00S C00F 119.5(3) . . ?
C00V C00S H00S 120.3 . . ?
C00E C00T H00T 119.0 . . ?
C00V C00T C00E 122.0(4) . . ?
C00V C00T H00T 119.0 . . ?
C00K C00U C00N 120.0(3) . . ?
C00K C00U H00U 120.0 . . ?
C00N C00U H00U 120.0 . . ?
C00S C00V C00T 119.5(3) . . ?
C00S C00V H00V 120.2 . . ?
C00T C00V H00V 120.2 . . ?
C00G C00W H00Q 109.5 . . ?
C00G C00W H00R 109.5 . . ?
C00G C00W H00W 109.5 . . ?
H00Q C00W H00R 109.5 . . ?
H00Q C00W H00W 109.5 . . ?
H00R C00W H00W 109.5 . . ?
C00O C00X H00X 109.5 . . ?
C00O C00X H00Y 109.5 . . ?
C00O C00X H 109.5 . . ?
H00X C00X H00Y 109.5 . . ?
H00X C00X H 109.5 . . ?
H00Y C00X H 109.5 . . ?
C011 C00Y H00Z 119.9 . . ?
C012 C00Y H00Z 119.9 . . ?
C012 C00Y C011 120.3(4) . . ?
C00Q C00Z H00 119.8 . . ?
C012 C00Z C00Q 120.4(4) . . ?
C012 C00Z H00 119.8 . . ?
C00G C010 H01A 109.5 . . ?
C00G C010 H01B 109.5 . . ?
C00G C010 H01C 109.5 . . ?
H01A C010 H01B 109.5 . . ?
H01A C010 H01C 109.5 . . ?
H01B C010 H01C 109.5 . . ?
C00I C011 C00Y 119.6(4) . . ?
C00I C011 H011 120.2 . . ?
C00Y C011 H011 120.2 . . ?
C00Y C012 C00Z 120.0(4) . . ?
C00Y C012 H012 120.0 . . ?
C00Z C012 H012 120.0 . . ?
C00G C013 H01D 109.5 . . ?
C00G C013 H01E 109.5 . . ?
C00G C013 H01F 109.5 . . ?
H01D C013 H01E 109.5 . . ?
H01D C013 H01F 109.5 . . ?
H01E C013 H01F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P003 C00C C00E 18.6(3) . . . . ?
Au01 P003 C00C C00F -164.3(2) . . . . ?
Au01 P003 C00G C00W -57.4(3) . . . . ?
Au01 P003 C00G C010 60.4(3) . . . . ?
Au01 P003 C00G C013 -175.8(3) . . . . ?
Au01 P003 C00O C00D 81.4(2) . . . . ?
Au01 P003 C00O C00R -155.9(2) . . . . ?
Au01 P003 C00O C00X -34.6(3) . . . . ?
Au01 O007 N00B C00H -39.6(3) . . . . ?
Au01 O007 N00B C00J 142.2(3) . . . . ?
P003 C00C C00E C00Q -3.1(5) . . . . ?
P003 C00C C00E C00T 176.1(3) . . . . ?
P003 C00C C00F C00S -178.0(3) . . . . ?
O007 N00B C00J C00P -0.7(5) . . . . ?
N00B C00J C00P C00L -161.8(3) . . . . ?
N00B C00J C00P C00M 20.9(5) . . . . ?
C00C P003 C00G C00W 66.3(3) . . . . ?
C00C P003 C00G C010 -175.9(2) . . . . ?
C00C P003 C00G C013 -52.1(3) . . . . ?
C00C P003 C00O C00D -41.5(3) . . . . ?
C00C P003 C00O C00R 81.1(3) . . . . ?
C00C P003 C00O C00X -157.6(3) . . . . ?
C00C C00E C00Q C00I 100.9(4) . . . . ?
C00C C00E C00Q C00Z -85.4(5) . . . . ?
C00C C00E C00T C00V 1.4(6) . . . . ?
C00C C00F C00S C00V 2.3(6) . . . . ?
C00E C00C C00F C00S -0.9(5) . . . . ?
C00E C00Q C00Z C012 -174.0(3) . . . . ?
C00E C00T C00V C00S 0.1(6) . . . . ?
C00F C00C C00E C00Q 179.8(3) . . . . ?
C00F C00C C00E C00T -0.9(5) . . . . ?
C00F C00S C00V C00T -1.9(6) . . . . ?
C00G P003 C00C C00E -102.5(3) . . . . ?
C00G P003 C00C C00F 74.6(3) . . . . ?
C00G P003 C00O C00D -157.1(2) . . . . ?
C00G P003 C00O C00R -34.4(3) . . . . ?
C00G P003 C00O C00X 86.9(3) . . . . ?
C00H N00B C00J C00P -178.9(3) . . . . ?
C00I C00Q C00Z C012 -0.2(5) . . . . ?
C00K C00L C00P C00J -179.3(3) . . . . ?
C00K C00L C00P C00M -1.9(5) . . . . ?
C00L C00K C00U C00N -0.3(6) . . . . ?
C00M C00N C00U C00K -1.2(6) . . . . ?
C00N C00M C00P C00J 177.6(3) . . . . ?
C00N C00M C00P C00L 0.4(5) . . . . ?
C00O P003 C00C C00E 136.3(3) . . . . ?
C00O P003 C00C C00F -46.6(3) . . . . ?
C00O P003 C00G C00W -176.4(2) . . . . ?
C00O P003 C00G C010 -58.6(3) . . . . ?
C00O P003 C00G C013 65.1(3) . . . . ?
C00P C00M C00N C00U 1.2(5) . . . . ?
C00Q C00E C00T C00V -179.3(4) . . . . ?
C00Q C00I C011 C00Y -2.1(6) . . . . ?
C00Q C00Z C012 C00Y -0.3(6) . . . . ?
C00T C00E C00Q C00I -78.4(4) . . . . ?
C00T C00E C00Q C00Z 95.3(4) . . . . ?
C00U C00K C00L C00P 1.9(6) . . . . ?
C011 C00I C00Q C00E 175.2(3) . . . . ?
C011 C00I C00Q C00Z 1.4(6) . . . . ?
C011 C00Y C012 C00Z -0.3(6) . . . . ?
C012 C00Y C011 C00I 1.5(6) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-109
_audit_block_doi                 10.5517/ccdc.csd.cc1nzmx5
_database_code_depnum_ccdc_archive 'CCDC 1548788'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2016-06-06
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C26 H24 Au N O P), 2(F6 Sb)'
_chemical_formula_sum            'C52 H48 Au2 F12 N2 O2 P2 Sb2'
_chemical_formula_weight         1660.29
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.6968(8)
_cell_length_b                   13.6523(9)
_cell_length_c                   15.5684(10)
_cell_angle_alpha                85.8930(10)
_cell_angle_beta                 81.9230(10)
_cell_angle_gamma                82.6460(10)
_cell_volume                     2645.9(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9977
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      36.27
_cell_measurement_theta_min      2.30
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    6.683
_exptl_absorpt_correction_T_max  0.7471
_exptl_absorpt_correction_T_min  0.4241
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1117 before and 0.0512 after correction.
The Ratio of minimum to maximum transmission is 0.5677.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.084
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1576
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   1.0000
_exptl_transmission_factor_min   0.5677
_diffrn_reflns_av_R_equivalents  0.0406
_diffrn_reflns_av_unetI/netI     0.0414
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            93925
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         36.309
_diffrn_reflns_theta_min         2.233
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                20367
_reflns_number_total             25478
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX2 v2014.11-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT v8.34A (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Diamond v4.0.1 (Brandenburg, 2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_refine_diff_density_max         1.040
_refine_diff_density_min         -1.829
_refine_diff_density_rms         0.162
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     733
_refine_ls_number_reflns         25478
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0470
_refine_ls_R_factor_gt           0.0290
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0177P)²+0.7350P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0499
_refine_ls_wR_factor_ref         0.0539
_refine_special_details          
;
3 ISOR restraints were applied to the 2nd disordered SbF6 anion (8 % occupancy).
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(F8) \\sim Ueq, Uanis(F1) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(F3) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.001
3. Others
 Sof(F1)=Sof(F2)=Sof(F3)=Sof(F8)=Sof(F9)=Sof(F10)=Sof(Sb2)=1-FVAR(1)
 Sof(Sb03)=Sof(F00B)=Sof(F00C)=Sof(F00D)=Sof(F00H)=Sof(F00I)=Sof(F00L)=FVAR(1)
4.a Aromatic/amide H refined with riding coordinates:
 C00M(H00M), C00P(H00P), C00R(H00R), C00S(H00S), C00T(H00T), C00V(H00V),
 C00W(H00W), C00Y(H00Y), C00Z(H00Z), C010(H010), C012(H012), C013(H013),
 C014(H014), C015(H015), C016(H016), C017(H017), C019(H019), C01A(H01H),
 C01B(H01B), C01C(H01C), C01E(H01I), C01F(H01F), C01G(H01G), C01H(H01J),
 C01J(H01K), C01K(H01M), C01L(H01L), C01M(H01P), C01N(H01N), C01O(H01O),
 C01P(H01Q), C01Q(H01S), C01R(H01R), C01S(H01T), C01U(H01U), C01W(H01),
 C01X(H0AA), C01Y(H01Y), C01Z(H01Z), C020(H020), C021(H021), C022(H022)
4.b Idealised Me refined as rotating group:
 C01T(H01A,H01D,H01E), C01V(H01V,H01W,H01X)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.76392(2) 0.82374(2) 0.55784(2) 0.01266(2) Uani 1 1 d . . . . .
Au02 Au 0.23654(2) 0.17677(2) 0.92732(2) 0.01479(2) Uani 1 1 d . . . . .
Sb03 Sb 0.16525(12) 0.66027(10) 0.92428(8) 0.01479(11) Uani 0.917(4) 1 d . . P
A 1
Sb04 Sb 1.17205(2) 0.65022(2) 0.40712(2) 0.01541(3) Uani 1 1 d . . . . .
P005 P 0.34481(4) 0.24639(4) 0.99827(3) 0.01288(9) Uani 1 1 d . . . . .
P006 P 0.64849(4) 0.76409(4) 0.48654(3) 0.01209(9) Uani 1 1 d . . . . .
F007 F 1.17840(11) 0.64249(10) 0.52670(8) 0.0255(3) Uani 1 1 d . . . . .
F008 F 1.16309(13) 0.66268(11) 0.28740(8) 0.0332(3) Uani 1 1 d . . . . .
O009 O 0.86538(11) 0.88479(11) 0.62621(9) 0.0177(3) Uani 1 1 d . . . . .
O00A O 0.14113(12) 0.10668(11) 0.85921(10) 0.0210(3) Uani 1 1 d . . . . .
F00B F 0.09260(19) 0.67370(16) 0.82577(14) 0.0279(5) Uani 0.917(4) 1 d . . P A
1
F00C F 0.11911(18) 0.79408(14) 0.94369(14) 0.0319(5) Uani 0.917(4) 1 d . . P A
1
F00D F 0.04264(12) 0.62505(15) 0.99443(11) 0.0319(5) Uani 0.917(4) 1 d . . P A
1
F00E F 1.10909(14) 0.53313(11) 0.41568(10) 0.0420(4) Uani 1 1 d . . . . .
F00F F 1.03713(12) 0.72452(13) 0.42583(10) 0.0420(4) Uani 1 1 d . . . . .
N00G N 0.92065(12) 0.82454(13) 0.68064(10) 0.0150(3) Uani 1 1 d . . . . .
F00H F 0.23914(19) 0.6504(2) 1.02100(17) 0.0343(5) Uani 0.917(4) 1 d . . P A 1
F00I F 0.20799(18) 0.52768(11) 0.90122(11) 0.0308(4) Uani 0.917(4) 1 d . . P A
1
F00J F 1.23539(16) 0.76723(13) 0.39650(11) 0.0521(5) Uani 1 1 d . . . . .
N00K N 0.07921(13) 0.16195(13) 0.80699(11) 0.0167(3) Uani 1 1 d . . . . .
F00L F 0.2875(2) 0.6973(2) 0.85448(17) 0.0414(6) Uani 0.917(4) 1 d . . P A 1
C00M C 0.44014(16) 1.00940(15) 0.34882(13) 0.0176(4) Uani 1 1 d . . . . .
H00M H 0.3982 1.0598 0.3190 0.021 Uiso 1 1 calc R . . . .
C00N C 0.71597(15) 0.68335(14) 0.40352(12) 0.0140(3) Uani 1 1 d . . . . .
F00O F 1.30699(12) 0.57715(14) 0.38779(10) 0.0504(5) Uani 1 1 d . . . . .
C00P C 0.54258(16) 1.02310(16) 0.36270(14) 0.0195(4) Uani 1 1 d . . . . .
H00P H 0.5705 1.0833 0.3432 0.023 Uiso 1 1 calc R . . . .
C00Q C 0.56428(15) 0.86037(14) 0.43366(12) 0.0139(3) Uani 1 1 d . . . . .
C00R C 0.80652(16) 0.62086(16) 0.42223(14) 0.0190(4) Uani 1 1 d . . . . .
H00R H 0.8315 0.6226 0.4768 0.023 Uiso 1 1 calc R . . . .
C00S C 0.17928(16) 0.38022(16) 1.06746(13) 0.0190(4) Uani 1 1 d . . . . .
H00S H 0.1540 0.3791 1.0130 0.023 Uiso 1 1 calc R . . . .
C00T C 0.09370(16) 0.03587(17) 0.60588(13) 0.0196(4) Uani 1 1 d . . . . .
H00T H 0.0532 0.0894 0.5784 0.024 Uiso 1 1 calc R . . . .
C00U C 0.43870(15) 0.15755(14) 1.04867(12) 0.0142(3) Uani 1 1 d . . . . .
C00V C 0.86038(17) 0.55598(16) 0.36140(15) 0.0219(4) Uani 1 1 d . . . . .
H00V H 0.9221 0.5134 0.3743 0.026 Uiso 1 1 calc R . . . .
C00W C 0.82644(16) 1.02179(15) 0.76013(13) 0.0175(4) Uani 1 1 d . . . . .
H00W H 0.8132 1.0201 0.7017 0.021 Uiso 1 1 calc R . . . .
C00X C 0.27284(15) 0.32070(14) 1.08423(12) 0.0140(3) Uani 1 1 d . . . . .
C00Y C 0.57367(18) 0.02372(17) 1.13805(14) 0.0223(4) Uani 1 1 d . . . . .
H00Y H 0.6193 -0.0219 1.1692 0.027 Uiso 1 1 calc R . . . .
C00Z C 0.30826(16) 0.32080(16) 1.16498(13) 0.0187(4) Uani 1 1 d . . . . .
H00Z H 0.3713 0.2797 1.1769 0.022 Uiso 1 1 calc R . . . .
C010 C 0.67996(17) 0.68086(16) 0.32334(13) 0.0195(4) Uani 1 1 d . . . . .
H010 H 0.6185 0.7235 0.3101 0.023 Uiso 1 1 calc R . . . .
C011 C 0.42515(15) 0.32510(15) 0.92538(12) 0.0152(4) Uani 1 1 d . . . . .
C012 C 0.12294(17) 0.44122(16) 1.13069(14) 0.0216(4) Uani 1 1 d . . . . .
H012 H 0.0598 0.4825 1.1192 0.026 Uiso 1 1 calc R . . . .
C013 C 0.60967(17) 0.10943(17) 1.09910(14) 0.0224(4) Uani 1 1 d . . . . .
H013 H 0.6807 0.1221 1.1027 0.027 Uiso 1 1 calc R . . . .
C014 C 0.53803(16) 0.71726(15) 0.64661(13) 0.0160(4) Uani 1 1 d . . . . .
H014 H 0.5799 0.7608 0.6678 0.019 Uiso 1 1 calc R . . . .
C015 C 0.46031(16) 0.84777(16) 0.42052(14) 0.0201(4) Uani 1 1 d . . . . .
H015 H 0.4316 0.7880 0.4405 0.024 Uiso 1 1 calc R . . . .
C016 C 0.48583(17) 0.28249(16) 0.85184(14) 0.0205(4) Uani 1 1 d . . . . .
H016 H 0.4830 0.2150 0.8422 0.025 Uiso 1 1 calc R . . . .
C017 C 0.47023(18) 0.00427(16) 1.13153(14) 0.0221(4) Uani 1 1 d . . . . .
H017 H 0.4456 -0.0549 1.1581 0.026 Uiso 1 1 calc R . . . .
C018 C 0.55638(15) 0.69565(14) 0.55894(12) 0.0142(3) Uani 1 1 d . . . . .
C019 C 0.90484(16) 0.94513(16) 0.88517(13) 0.0177(4) Uani 1 1 d . . . . .
H019 H 0.9451 0.8908 0.9119 0.021 Uiso 1 1 calc R . . . .
C01A C 0.40329(16) 0.07026(15) 1.08676(13) 0.0172(4) Uani 1 1 d . . . . .
H01H H 0.3331 0.0561 1.0819 0.021 Uiso 1 1 calc R . . . .
C01B C 0.78853(17) 1.10474(16) 0.80686(14) 0.0205(4) Uani 1 1 d . . . . .
H01B H 0.7485 1.1595 0.7804 0.025 Uiso 1 1 calc R . . . .
C01C C 0.82393(17) 0.55349(16) 0.28198(14) 0.0207(4) Uani 1 1 d . . . . .
H01C H 0.8606 0.5090 0.2405 0.025 Uiso 1 1 calc R . . . .
C01D C 0.88448(15) 0.94040(15) 0.79935(12) 0.0144(3) Uani 1 1 d . . . . .
C01E C 0.15954(17) 0.44140(16) 1.21046(14) 0.0210(4) Uani 1 1 d . . . . .
H01I H 0.1214 0.4833 1.2534 0.025 Uiso 1 1 calc R . . . .
C01F C 0.80855(17) 1.10852(16) 0.89208(14) 0.0211(4) Uani 1 1 d . . . . .
H01F H 0.7826 1.1658 0.9234 0.025 Uiso 1 1 calc R . . . .
C01G C 0.39910(16) 0.92240(16) 0.37832(14) 0.0202(4) Uani 1 1 d . . . . .
H01G H 0.3284 0.9137 0.3696 0.024 Uiso 1 1 calc R . . . .
C01H C 0.54293(16) 0.17727(16) 1.05465(13) 0.0190(4) Uani 1 1 d . . . . .
H01J H 0.5677 0.2366 1.0285 0.023 Uiso 1 1 calc R . . . .
C01I C 0.11121(15) 0.04153(15) 0.69241(12) 0.0162(4) Uani 1 1 d . . . . .
C01J C 0.49096(18) 0.47970(16) 0.87844(14) 0.0230(4) Uani 1 1 d . . . . .
H01K H 0.4922 0.5478 0.8867 0.028 Uiso 1 1 calc R . . . .
C01K C 0.42766(16) 0.42396(15) 0.93835(13) 0.0182(4) Uani 1 1 d . . . . .
H01M H 0.3866 0.4535 0.9877 0.022 Uiso 1 1 calc R . . . .
C01L C 0.60443(15) 0.94861(15) 0.40518(13) 0.0167(4) Uani 1 1 d . . . . .
H01L H 0.6746 0.9582 0.4148 0.020 Uiso 1 1 calc R . . . .
C01M C 0.16748(16) -0.03970(16) 0.73325(14) 0.0191(4) Uani 1 1 d . . . . .
H01P H 0.1784 -0.0377 0.7922 0.023 Uiso 1 1 calc R . . . .
C01N C 0.86644(17) 1.02872(16) 0.93144(14) 0.0205(4) Uani 1 1 d . . . . .
H01N H 0.8798 1.0312 0.9897 0.025 Uiso 1 1 calc R . . . .
C01O C 0.73412(18) 0.61574(16) 0.26268(14) 0.0217(4) Uani 1 1 d . . . . .
H01O H 0.7096 0.6139 0.2080 0.026 Uiso 1 1 calc R . . . .
C01P C 0.13500(18) -0.04716(18) 0.56013(14) 0.0244(5) Uani 1 1 d . . . . .
H01Q H 0.1244 -0.0497 0.5012 0.029 Uiso 1 1 calc R . . . .
C01Q C 0.55216(17) 0.43695(17) 0.80687(14) 0.0230(4) Uani 1 1 d . . . . .
H01S H 0.5959 0.4754 0.7669 0.028 Uiso 1 1 calc R . . . .
C01R C 0.92997(15) 0.85001(15) 0.75737(12) 0.0157(4) Uani 1 1 d . . . . .
H01R H 0.9721 0.8035 0.7907 0.019 Uiso 1 1 calc R . . . .
C01S C 0.25115(17) 0.38118(17) 1.22818(14) 0.0220(4) Uani 1 1 d . . . . .
H01T H 0.2749 0.3811 1.2834 0.026 Uiso 1 1 calc R . . . .
C01T C 0.97480(16) 0.73160(16) 0.64533(14) 0.0203(4) Uani 1 1 d . . . . .
H01A H 0.9211 0.6894 0.6356 0.030 Uiso 1 1 calc GR . . . .
H01D H 1.0204 0.6974 0.6867 0.030 Uiso 1 1 calc GR . . . .
H01E H 1.0190 0.7460 0.5901 0.030 Uiso 1 1 calc GR . . . .
C01U C 0.45939(17) 0.67577(16) 0.70273(14) 0.0204(4) Uani 1 1 d . . . . .
H01U H 0.4473 0.6907 0.7622 0.024 Uiso 1 1 calc R . . . .
C01V C 0.02328(17) 0.25451(17) 0.84172(15) 0.0234(4) Uani 1 1 d . . . . .
H01V H -0.0170 0.2404 0.8988 0.035 Uiso 1 1 calc GR . . . .
H01W H -0.0262 0.2854 0.8020 0.035 Uiso 1 1 calc GR . . . .
H01X H 0.0757 0.2996 0.8476 0.035 Uiso 1 1 calc GR . . . .
C01W C 0.06490(15) 0.13240(16) 0.73290(13) 0.0170(4) Uani 1 1 d . . . . .
H01 H 0.0181 0.1757 0.7009 0.020 Uiso 1 1 calc R . . . .
C01X C 0.54954(17) 0.33796(17) 0.79352(14) 0.0229(4) Uani 1 1 d . . . . .
H0AA H 0.5914 0.3085 0.7445 0.027 Uiso 1 1 calc R . . . .
C01Y C 0.41676(16) 0.58897(15) 0.58550(14) 0.0205(4) Uani 1 1 d . . . . .
H01Y H 0.3754 0.5446 0.5649 0.025 Uiso 1 1 calc R . . . .
C01Z C 0.49579(16) 0.63023(15) 0.52889(13) 0.0179(4) Uani 1 1 d . . . . .
H01Z H 0.5086 0.6139 0.4697 0.022 Uiso 1 1 calc R . . . .
C020 C 0.20712(17) -0.12302(17) 0.68723(15) 0.0235(4) Uani 1 1 d . . . . .
H020 H 0.2450 -0.1781 0.7150 0.028 Uiso 1 1 calc R . . . .
C021 C 0.19178(18) -0.12652(18) 0.60080(16) 0.0263(5) Uani 1 1 d . . . . .
H021 H 0.2202 -0.1834 0.5696 0.032 Uiso 1 1 calc R . . . .
C022 C 0.39802(17) 0.61210(16) 0.67172(15) 0.0224(4) Uani 1 1 d . . . . .
H022 H 0.3430 0.5844 0.7099 0.027 Uiso 1 1 calc R . . . .
F1 F 0.0159(12) 0.6875(16) 0.9629(12) 0.027(5) Uani 0.083(4) 1 d . U P A -1
F2 F 0.1583(18) 0.8115(13) 0.9146(12) 0.021(4) Uani 0.083(4) 1 d . . P A -1
F3 F 0.1575(17) 0.5371(15) 0.9162(12) 0.023(4) Uani 0.083(4) 1 d . U P A -1
F8 F 0.1299(17) 0.6857(18) 0.8052(14) 0.017(4) Uani 0.083(4) 1 d . U P A -1
F9 F 0.1928(19) 0.6599(19) 1.0310(16) 0.022(5) Uani 0.083(4) 1 d . . P A -1
F10 F 0.3045(19) 0.665(2) 0.8836(14) 0.027(5) Uani 0.083(4) 1 d . . P A -1
Sb2 Sb 0.1624(14) 0.6750(10) 0.9161(9) 0.0150(12) Uani 0.083(4) 1 d . . P A -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 P006 2.2215(5) . ?
Au01 O009 2.0676(13) . ?
Au02 P005 2.2192(5) . ?
Au02 O00A 2.0761(14) . ?
Sb03 F00B 1.884(2) . ?
Sb03 F00C 1.878(2) . ?
Sb03 F00D 1.867(2) . ?
Sb03 F00H 1.871(3) . ?
Sb03 F00I 1.8674(19) . ?
Sb03 F00L 1.869(3) . ?
Sb03 F1 1.904(15) . ?
Sb03 F2 2.051(18) . ?
Sb03 F3 1.711(19) . ?
Sb03 F8 1.97(2) . ?
Sb03 F9 1.75(2) . ?
Sb03 F10 1.80(2) . ?
Sb04 F007 1.8695(12) . ?
Sb04 F008 1.8776(13) . ?
Sb04 F00E 1.8652(14) . ?
Sb04 F00F 1.8724(14) . ?
Sb04 F00J 1.8654(15) . ?
Sb04 F00O 1.8658(15) . ?
P005 C00U 1.8068(19) . ?
P005 C00X 1.8080(19) . ?
P005 C011 1.807(2) . ?
P006 C00N 1.8086(19) . ?
P006 C00Q 1.8115(19) . ?
P006 C018 1.808(2) . ?
O009 N00G 1.344(2) . ?
O00A N00K 1.337(2) . ?
F00B F8 0.57(2) . ?
F00B Sb2 1.767(17) . ?
F00C F2 0.678(19) . ?
F00C Sb2 1.713(15) . ?
F00D F1 1.00(2) . ?
F00D Sb2 1.973(16) . ?
N00G C01R 1.293(2) . ?
N00G C01T 1.468(3) . ?
F00H F9 0.59(2) . ?
F00H Sb2 2.003(16) . ?
F00I F3 0.65(2) . ?
F00I Sb2 2.041(14) . ?
N00K C01V 1.468(3) . ?
N00K C01W 1.292(2) . ?
F00L F10 0.65(2) . ?
F00L Sb2 1.785(16) . ?
C00M H00M 0.9500 . ?
C00M C00P 1.386(3) . ?
C00M C01G 1.381(3) . ?
C00N C00R 1.394(3) . ?
C00N C010 1.392(3) . ?
C00P H00P 0.9500 . ?
C00P C01L 1.390(3) . ?
C00Q C015 1.398(3) . ?
C00Q C01L 1.387(3) . ?
C00R H00R 0.9500 . ?
C00R C00V 1.390(3) . ?
C00S H00S 0.9500 . ?
C00S C00X 1.396(3) . ?
C00S C012 1.393(3) . ?
C00T H00T 0.9500 . ?
C00T C01I 1.405(3) . ?
C00T C01P 1.388(3) . ?
C00U C01A 1.391(3) . ?
C00U C01H 1.401(3) . ?
C00V H00V 0.9500 . ?
C00V C01C 1.384(3) . ?
C00W H00W 0.9500 . ?
C00W C01B 1.387(3) . ?
C00W C01D 1.404(3) . ?
C00X C00Z 1.394(3) . ?
C00Y H00Y 0.9500 . ?
C00Y C013 1.380(3) . ?
C00Y C017 1.392(3) . ?
C00Z H00Z 0.9500 . ?
C00Z C01S 1.391(3) . ?
C010 H010 0.9500 . ?
C010 C01O 1.392(3) . ?
C011 C016 1.405(3) . ?
C011 C01K 1.384(3) . ?
C012 H012 0.9500 . ?
C012 C01E 1.386(3) . ?
C013 H013 0.9500 . ?
C013 C01H 1.388(3) . ?
C014 H014 0.9500 . ?
C014 C018 1.398(3) . ?
C014 C01U 1.382(3) . ?
C015 H015 0.9500 . ?
C015 C01G 1.385(3) . ?
C016 H016 0.9500 . ?
C016 C01X 1.380(3) . ?
C017 H017 0.9500 . ?
C017 C01A 1.379(3) . ?
C018 C01Z 1.395(3) . ?
C019 H019 0.9500 . ?
C019 C01D 1.404(3) . ?
C019 C01N 1.391(3) . ?
C01A H01H 0.9500 . ?
C01B H01B 0.9500 . ?
C01B C01F 1.391(3) . ?
C01C H01C 0.9500 . ?
C01C C01O 1.387(3) . ?
C01D C01R 1.453(3) . ?
C01E H01I 0.9500 . ?
C01E C01S 1.385(3) . ?
C01F H01F 0.9500 . ?
C01F C01N 1.389(3) . ?
C01G H01G 0.9500 . ?
C01H H01J 0.9500 . ?
C01I C01M 1.403(3) . ?
C01I C01W 1.450(3) . ?
C01J H01K 0.9500 . ?
C01J C01K 1.393(3) . ?
C01J C01Q 1.385(3) . ?
C01K H01M 0.9500 . ?
C01L H01L 0.9500 . ?
C01M H01P 0.9500 . ?
C01M C020 1.389(3) . ?
C01N H01N 0.9500 . ?
C01O H01O 0.9500 . ?
C01P H01Q 0.9500 . ?
C01P C021 1.387(3) . ?
C01Q H01S 0.9500 . ?
C01Q C01X 1.387(3) . ?
C01R H01R 0.9500 . ?
C01S H01T 0.9500 . ?
C01T H01A 0.9800 . ?
C01T H01D 0.9800 . ?
C01T H01E 0.9800 . ?
C01U H01U 0.9500 . ?
C01U C022 1.391(3) . ?
C01V H01V 0.9800 . ?
C01V H01W 0.9800 . ?
C01V H01X 0.9800 . ?
C01W H01 0.9500 . ?
C01X H0AA 0.9500 . ?
C01Y H01Y 0.9500 . ?
C01Y C01Z 1.388(3) . ?
C01Y C022 1.382(3) . ?
C01Z H01Z 0.9500 . ?
C020 H020 0.9500 . ?
C020 C021 1.392(3) . ?
C021 H021 0.9500 . ?
C022 H022 0.9500 . ?
F1 Sb2 1.89(2) . ?
F2 Sb2 1.86(2) . ?
F3 Sb2 1.89(2) . ?
F8 Sb2 1.82(3) . ?
F9 Sb2 1.87(3) . ?
F10 Sb2 1.79(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O009 Au01 P006 177.14(4) . . ?
O00A Au02 P005 177.34(4) . . ?
F00B Sb03 F1 72.1(6) . . ?
F00B Sb03 F2 86.2(6) . . ?
F00B Sb03 F8 16.8(6) . . ?
F00C Sb03 F00B 88.82(10) . . ?
F00C Sb03 F1 66.0(6) . . ?
F00C Sb03 F2 19.2(5) . . ?
F00C Sb03 F8 88.4(7) . . ?
F00D Sb03 F00B 90.75(11) . . ?
F00D Sb03 F00C 89.80(10) . . ?
F00D Sb03 F00H 90.50(11) . . ?
F00D Sb03 F00I 90.11(11) . . ?
F00D Sb03 F00L 179.21(13) . . ?
F00D Sb03 F1 30.7(7) . . ?
F00D Sb03 F2 108.9(6) . . ?
F00D Sb03 F8 107.6(6) . . ?
F00H Sb03 F00B 178.29(14) . . ?
F00H Sb03 F00C 90.01(12) . . ?
F00H Sb03 F1 108.6(5) . . ?
F00H Sb03 F2 92.3(6) . . ?
F00H Sb03 F8 161.8(6) . . ?
F00I Sb03 F00B 88.89(10) . . ?
F00I Sb03 F00C 177.71(12) . . ?
F00I Sb03 F00H 92.28(11) . . ?
F00I Sb03 F00L 90.67(12) . . ?
F00I Sb03 F1 113.1(6) . . ?
F00I Sb03 F2 160.4(6) . . ?
F00I Sb03 F8 89.5(7) . . ?
F00L Sb03 F00B 89.32(11) . . ?
F00L Sb03 F00C 89.42(12) . . ?
F00L Sb03 F00H 89.41(13) . . ?
F00L Sb03 F1 148.8(7) . . ?
F00L Sb03 F2 70.3(6) . . ?
F00L Sb03 F8 72.5(6) . . ?
F1 Sb03 F2 83.3(8) . . ?
F1 Sb03 F8 87.2(8) . . ?
F3 Sb03 F00B 83.0(6) . . ?
F3 Sb03 F00C 158.8(7) . . ?
F3 Sb03 F00D 70.8(7) . . ?
F3 Sb03 F00H 98.5(6) . . ?
F3 Sb03 F00I 20.3(7) . . ?
F3 Sb03 F00L 110.0(7) . . ?
F3 Sb03 F1 92.8(8) . . ?
F3 Sb03 F2 169.2(9) . . ?
F3 Sb03 F8 89.3(9) . . ?
F3 Sb03 F9 100.4(11) . . ?
F3 Sb03 F10 100.0(11) . . ?
F8 Sb03 F2 80.5(9) . . ?
F9 Sb03 F00B 162.3(8) . . ?
F9 Sb03 F00C 81.8(8) . . ?
F9 Sb03 F00D 74.3(9) . . ?
F9 Sb03 F00H 18.3(8) . . ?
F9 Sb03 F00I 100.4(8) . . ?
F9 Sb03 F00L 105.5(8) . . ?
F9 Sb03 F1 90.3(9) . . ?
F9 Sb03 F2 89.7(10) . . ?
F9 Sb03 F8 170.1(11) . . ?
F9 Sb03 F10 90.8(10) . . ?
F10 Sb03 F00B 105.9(7) . . ?
F10 Sb03 F00C 101.1(9) . . ?
F10 Sb03 F00D 160.1(8) . . ?
F10 Sb03 F00H 73.1(7) . . ?
F10 Sb03 F00I 79.6(9) . . ?
F10 Sb03 F00L 20.3(7) . . ?
F10 Sb03 F1 166.7(10) . . ?
F10 Sb03 F2 83.5(10) . . ?
F10 Sb03 F8 89.5(8) . . ?
F007 Sb04 F008 177.91(6) . . ?
F007 Sb04 F00F 89.69(6) . . ?
F00E Sb04 F007 91.23(6) . . ?
F00E Sb04 F008 90.02(6) . . ?
F00E Sb04 F00F 90.90(8) . . ?
F00E Sb04 F00J 179.02(7) . . ?
F00E Sb04 F00O 89.55(8) . . ?
F00F Sb04 F008 88.62(7) . . ?
F00J Sb04 F007 89.73(7) . . ?
F00J Sb04 F008 89.03(7) . . ?
F00J Sb04 F00F 89.30(8) . . ?
F00J Sb04 F00O 90.25(9) . . ?
F00O Sb04 F007 90.60(6) . . ?
F00O Sb04 F008 91.08(7) . . ?
F00O Sb04 F00F 179.46(8) . . ?
C00U P005 Au02 113.18(7) . . ?
C00U P005 C00X 106.15(9) . . ?
C00X P005 Au02 112.60(6) . . ?
C011 P005 Au02 110.90(6) . . ?
C011 P005 C00U 105.84(9) . . ?
C011 P005 C00X 107.75(9) . . ?
C00N P006 Au01 111.76(6) . . ?
C00N P006 C00Q 107.17(9) . . ?
C00Q P006 Au01 112.74(6) . . ?
C018 P006 Au01 111.62(6) . . ?
C018 P006 C00N 108.19(9) . . ?
C018 P006 C00Q 105.00(9) . . ?
N00G O009 Au01 118.03(11) . . ?
N00K O00A Au02 118.52(12) . . ?
F8 F00B Sb03 90(2) . . ?
F8 F00B Sb2 86(2) . . ?
Sb2 F00B Sb03 6.3(5) . . ?
F2 F00C Sb03 94.9(17) . . ?
F2 F00C Sb2 91.2(17) . . ?
Sb2 F00C Sb03 5.2(5) . . ?
Sb03 F00D Sb2 6.2(4) . . ?
F1 F00D Sb03 76.7(8) . . ?
F1 F00D Sb2 70.5(9) . . ?
O009 N00G C01T 115.74(15) . . ?
C01R N00G O009 121.60(17) . . ?
C01R N00G C01T 122.54(17) . . ?
Sb03 F00H Sb2 5.7(5) . . ?
F9 F00H Sb03 69(2) . . ?
F9 F00H Sb2 69(2) . . ?
Sb03 F00I Sb2 4.5(4) . . ?
F3 F00I Sb03 66.1(18) . . ?
F3 F00I Sb2 67.6(18) . . ?
O00A N00K C01V 115.78(16) . . ?
C01W N00K O00A 121.71(17) . . ?
C01W N00K C01V 122.39(18) . . ?
F10 F00L Sb03 74(2) . . ?
F10 F00L Sb2 80(2) . . ?
Sb2 F00L Sb03 6.8(4) . . ?
C00P C00M H00M 120.0 . . ?
C01G C00M H00M 120.0 . . ?
C01G C00M C00P 119.93(19) . . ?
C00R C00N P006 117.80(14) . . ?
C010 C00N P006 122.54(15) . . ?
C010 C00N C00R 119.66(18) . . ?
C00M C00P H00P 120.0 . . ?
C00M C00P C01L 119.93(19) . . ?
C01L C00P H00P 120.0 . . ?
C015 C00Q P006 121.68(16) . . ?
C01L C00Q P006 119.02(14) . . ?
C01L C00Q C015 119.30(18) . . ?
C00N C00R H00R 119.9 . . ?
C00V C00R C00N 120.24(19) . . ?
C00V C00R H00R 119.9 . . ?
C00X C00S H00S 120.0 . . ?
C012 C00S H00S 120.0 . . ?
C012 C00S C00X 119.98(19) . . ?
C01I C00T H00T 119.7 . . ?
C01P C00T H00T 119.7 . . ?
C01P C00T C01I 120.6(2) . . ?
C01A C00U P005 118.36(15) . . ?
C01A C00U C01H 119.87(18) . . ?
C01H C00U P005 121.66(15) . . ?
C00R C00V H00V 120.1 . . ?
C01C C00V C00R 119.9(2) . . ?
C01C C00V H00V 120.1 . . ?
C01B C00W H00W 120.1 . . ?
C01B C00W C01D 119.81(19) . . ?
C01D C00W H00W 120.1 . . ?
C00S C00X P005 117.88(15) . . ?
C00Z C00X P005 122.29(15) . . ?
C00Z C00X C00S 119.83(18) . . ?
C013 C00Y H00Y 120.1 . . ?
C013 C00Y C017 119.8(2) . . ?
C017 C00Y H00Y 120.1 . . ?
C00X C00Z H00Z 120.0 . . ?
C01S C00Z C00X 119.94(19) . . ?
C01S C00Z H00Z 120.0 . . ?
C00N C010 H010 120.1 . . ?
C01O C010 C00N 119.89(19) . . ?
C01O C010 H010 120.1 . . ?
C016 C011 P005 117.24(16) . . ?
C01K C011 P005 123.06(15) . . ?
C01K C011 C016 119.69(19) . . ?
C00S C012 H012 120.2 . . ?
C01E C012 C00S 119.6(2) . . ?
C01E C012 H012 120.2 . . ?
C00Y C013 H013 119.7 . . ?
C00Y C013 C01H 120.5(2) . . ?
C01H C013 H013 119.7 . . ?
C018 C014 H014 119.8 . . ?
C01U C014 H014 119.8 . . ?
C01U C014 C018 120.48(18) . . ?
C00Q C015 H015 120.0 . . ?
C01G C015 C00Q 120.0(2) . . ?
C01G C015 H015 120.0 . . ?
C011 C016 H016 119.8 . . ?
C01X C016 C011 120.5(2) . . ?
C01X C016 H016 119.8 . . ?
C00Y C017 H017 119.8 . . ?
C01A C017 C00Y 120.5(2) . . ?
C01A C017 H017 119.8 . . ?
C014 C018 P006 118.08(15) . . ?
C01Z C018 P006 122.28(15) . . ?
C01Z C018 C014 119.31(18) . . ?
C01D C019 H019 119.8 . . ?
C01N C019 H019 119.8 . . ?
C01N C019 C01D 120.50(19) . . ?
C00U C01A H01H 120.0 . . ?
C017 C01A C00U 119.91(19) . . ?
C017 C01A H01H 120.0 . . ?
C00W C01B H01B 119.7 . . ?
C00W C01B C01F 120.6(2) . . ?
C01F C01B H01B 119.7 . . ?
C00V C01C H01C 119.9 . . ?
C00V C01C C01O 120.29(19) . . ?
C01O C01C H01C 119.9 . . ?
C00W C01D C01R 125.33(18) . . ?
C019 C01D C00W 119.19(18) . . ?
C019 C01D C01R 115.45(17) . . ?
C012 C01E H01I 119.6 . . ?
C01S C01E C012 120.71(19) . . ?
C01S C01E H01I 119.6 . . ?
C01B C01F H01F 119.9 . . ?
C01N C01F C01B 120.15(19) . . ?
C01N C01F H01F 119.9 . . ?
C00M C01G C015 120.46(19) . . ?
C00M C01G H01G 119.8 . . ?
C015 C01G H01G 119.8 . . ?
C00U C01H H01J 120.3 . . ?
C013 C01H C00U 119.4(2) . . ?
C013 C01H H01J 120.3 . . ?
C00T C01I C01W 115.44(18) . . ?
C01M C01I C00T 119.04(19) . . ?
C01M C01I C01W 125.48(18) . . ?
C01K C01J H01K 119.6 . . ?
C01Q C01J H01K 119.6 . . ?
C01Q C01J C01K 120.7(2) . . ?
C011 C01K C01J 119.38(19) . . ?
C011 C01K H01M 120.3 . . ?
C01J C01K H01M 120.3 . . ?
C00P C01L H01L 119.8 . . ?
C00Q C01L C00P 120.38(18) . . ?
C00Q C01L H01L 119.8 . . ?
C01I C01M H01P 120.1 . . ?
C020 C01M C01I 119.8(2) . . ?
C020 C01M H01P 120.1 . . ?
C019 C01N H01N 120.1 . . ?
C01F C01N C019 119.75(19) . . ?
C01F C01N H01N 120.1 . . ?
C010 C01O H01O 120.0 . . ?
C01C C01O C010 120.08(19) . . ?
C01C C01O H01O 120.0 . . ?
C00T C01P H01Q 120.1 . . ?
C021 C01P C00T 119.8(2) . . ?
C021 C01P H01Q 120.1 . . ?
C01J C01Q H01S 120.0 . . ?
C01J C01Q C01X 120.0(2) . . ?
C01X C01Q H01S 120.0 . . ?
N00G C01R C01D 128.53(18) . . ?
N00G C01R H01R 115.7 . . ?
C01D C01R H01R 115.7 . . ?
C00Z C01S H01T 120.1 . . ?
C01E C01S C00Z 119.87(19) . . ?
C01E C01S H01T 120.1 . . ?
N00G C01T H01A 109.5 . . ?
N00G C01T H01D 109.5 . . ?
N00G C01T H01E 109.5 . . ?
H01A C01T H01D 109.5 . . ?
H01A C01T H01E 109.5 . . ?
H01D C01T H01E 109.5 . . ?
C014 C01U H01U 120.1 . . ?
C014 C01U C022 119.7(2) . . ?
C022 C01U H01U 120.1 . . ?
N00K C01V H01V 109.5 . . ?
N00K C01V H01W 109.5 . . ?
N00K C01V H01X 109.5 . . ?
H01V C01V H01W 109.5 . . ?
H01V C01V H01X 109.5 . . ?
H01W C01V H01X 109.5 . . ?
N00K C01W C01I 128.27(19) . . ?
N00K C01W H01 115.9 . . ?
C01I C01W H01 115.9 . . ?
C016 C01X C01Q 119.7(2) . . ?
C016 C01X H0AA 120.2 . . ?
C01Q C01X H0AA 120.2 . . ?
C01Z C01Y H01Y 119.8 . . ?
C022 C01Y H01Y 119.8 . . ?
C022 C01Y C01Z 120.30(19) . . ?
C018 C01Z H01Z 120.0 . . ?
C01Y C01Z C018 119.94(19) . . ?
C01Y C01Z H01Z 120.0 . . ?
C01M C020 H020 119.7 . . ?
C01M C020 C021 120.5(2) . . ?
C021 C020 H020 119.7 . . ?
C01P C021 C020 120.1(2) . . ?
C01P C021 H021 119.9 . . ?
C020 C021 H021 119.9 . . ?
C01U C022 H022 119.9 . . ?
C01Y C022 C01U 120.2(2) . . ?
C01Y C022 H022 119.9 . . ?
F00D F1 Sb03 72.6(10) . . ?
F00D F1 Sb2 79.6(10) . . ?
Sb2 F1 Sb03 7.0(4) . . ?
F00C F2 Sb03 65.8(15) . . ?
F00C F2 Sb2 67.3(16) . . ?
Sb2 F2 Sb03 3.7(5) . . ?
Sb03 F3 Sb2 4.6(5) . . ?
F00I F3 Sb03 93.5(19) . . ?
F00I F3 Sb2 93.9(19) . . ?
F00B F8 Sb03 74(2) . . ?
F00B F8 Sb2 75(2) . . ?
Sb2 F8 Sb03 5.6(5) . . ?
Sb03 F9 Sb2 6.1(5) . . ?
F00H F9 Sb03 93(3) . . ?
F00H F9 Sb2 94(3) . . ?
F00L F10 Sb03 86(2) . . ?
F00L F10 Sb2 79(2) . . ?
Sb2 F10 Sb03 7.4(4) . . ?
F00B Sb2 F00D 90.9(8) . . ?
F00B Sb2 F00H 169.7(9) . . ?
F00B Sb2 F00I 86.9(7) . . ?
F00B Sb2 F00L 95.9(7) . . ?
F00B Sb2 F1 75.0(9) . . ?
F00B Sb2 F2 96.0(9) . . ?
F00B Sb2 F3 81.3(9) . . ?
F00B Sb2 F8 18.2(7) . . ?
F00B Sb2 F9 160.0(13) . . ?
F00B Sb2 F10 111.3(11) . . ?
F00C Sb2 F00B 98.3(7) . . ?
F00C Sb2 F00D 91.4(7) . . ?
F00C Sb2 F00H 90.7(8) . . ?
F00C Sb2 F00I 171.9(8) . . ?
F00C Sb2 F00L 97.8(8) . . ?
F00C Sb2 F1 69.5(8) . . ?
F00C Sb2 F2 21.4(6) . . ?
F00C Sb2 F3 156.3(12) . . ?
F00C Sb2 F8 98.5(10) . . ?
F00C Sb2 F9 82.8(10) . . ?
F00C Sb2 F10 108.2(13) . . ?
F00D Sb2 F00H 83.8(5) . . ?
F00D Sb2 F00I 82.3(6) . . ?
F00H Sb2 F00I 83.6(5) . . ?
F00L Sb2 F00D 167.6(8) . . ?
F00L Sb2 F00H 87.8(8) . . ?
F00L Sb2 F00I 87.7(6) . . ?
F00L Sb2 F1 162.6(9) . . ?
F00L Sb2 F2 76.8(9) . . ?
F00L Sb2 F3 105.8(9) . . ?
F00L Sb2 F8 77.9(8) . . ?
F00L Sb2 F9 103.7(12) . . ?
F00L Sb2 F10 20.9(8) . . ?
F1 Sb2 F00D 29.8(7) . . ?
F1 Sb2 F00H 103.8(9) . . ?
F1 Sb2 F00I 106.3(10) . . ?
F1 Sb2 F3 87.8(11) . . ?
F2 Sb2 F00D 112.8(10) . . ?
F2 Sb2 F00H 94.3(10) . . ?
F2 Sb2 F00I 164.5(12) . . ?
F2 Sb2 F1 89.2(11) . . ?
F2 Sb2 F3 176.3(14) . . ?
F2 Sb2 F9 92.1(13) . . ?
F3 Sb2 F00D 65.0(8) . . ?
F3 Sb2 F00H 88.4(7) . . ?
F3 Sb2 F00I 18.5(6) . . ?
F8 Sb2 F00D 109.0(12) . . ?
F8 Sb2 F00H 163.9(12) . . ?
F8 Sb2 F00I 88.4(10) . . ?
F8 Sb2 F1 91.9(11) . . ?
F8 Sb2 F2 89.7(11) . . ?
F8 Sb2 F3 88.4(12) . . ?
F8 Sb2 F9 177.8(15) . . ?
F9 Sb2 F00D 69.1(9) . . ?
F9 Sb2 F00H 17.0(7) . . ?
F9 Sb2 F00I 90.2(9) . . ?
F9 Sb2 F1 86.9(11) . . ?
F9 Sb2 F3 89.7(11) . . ?
F10 Sb2 F00D 147.0(12) . . ?
F10 Sb2 F00H 70.1(9) . . ?
F10 Sb2 F00I 75.2(11) . . ?
F10 Sb2 F1 173.7(13) . . ?
F10 Sb2 F2 89.6(13) . . ?
F10 Sb2 F3 93.7(12) . . ?
F10 Sb2 F8 94.3(11) . . ?
F10 Sb2 F9 86.9(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 P006 C00N C00R 38.26(18) . . . . ?
Au01 P006 C00N C010 -142.62(16) . . . . ?
Au01 P006 C00Q C015 -150.23(15) . . . . ?
Au01 P006 C00Q C01L 30.08(17) . . . . ?
Au01 P006 C018 C014 23.79(17) . . . . ?
Au01 P006 C018 C01Z -162.83(14) . . . . ?
Au01 O009 N00G C01R -136.48(16) . . . . ?
Au01 O009 N00G C01T 47.24(19) . . . . ?
Au02 P005 C00U C01A -38.78(17) . . . . ?
Au02 P005 C00U C01H 145.11(15) . . . . ?
Au02 P005 C00X C00S -41.44(17) . . . . ?
Au02 P005 C00X C00Z 139.19(15) . . . . ?
Au02 P005 C011 C016 -54.57(17) . . . . ?
Au02 P005 C011 C01K 124.38(15) . . . . ?
Au02 O00A N00K C01V -42.3(2) . . . . ?
Au02 O00A N00K C01W 141.68(16) . . . . ?
Sb03 F00B F8 Sb2 -5.4(5) . . . . ?
Sb03 F00B Sb2 F00C -148(6) . . . . ?
Sb03 F00B Sb2 F00D -56(5) . . . . ?
Sb03 F00B Sb2 F00H 2.8(6) . . . . ?
Sb03 F00B Sb2 F00I 26(5) . . . . ?
Sb03 F00B Sb2 F00L 113(5) . . . . ?
Sb03 F00B Sb2 F1 -82(5) . . . . ?
Sb03 F00B Sb2 F2 -169(6) . . . . ?
Sb03 F00B Sb2 F3 8(5) . . . . ?
Sb03 F00B Sb2 F8 120(6) . . . . ?
Sb03 F00B Sb2 F9 -56(5) . . . . ?
Sb03 F00B Sb2 F10 99(5) . . . . ?
Sb03 F00C F2 Sb2 3.7(6) . . . . ?
Sb03 F00C Sb2 F00B 140(8) . . . . ?
Sb03 F00C Sb2 F00D 49(7) . . . . ?
Sb03 F00C Sb2 F00H -35(7) . . . . ?
Sb03 F00C Sb2 F00L -123(8) . . . . ?
Sb03 F00C Sb2 F1 69(7) . . . . ?
Sb03 F00C Sb2 F2 -135(8) . . . . ?
Sb03 F00C Sb2 F3 52(6) . . . . ?
Sb03 F00C Sb2 F8 158(8) . . . . ?
Sb03 F00C Sb2 F9 -20(7) . . . . ?
Sb03 F00C Sb2 F10 -105(8) . . . . ?
Sb03 F00D F1 Sb2 -0.2(6) . . . . ?
Sb03 F00H F9 Sb2 -6.1(5) . . . . ?
Sb03 F00I F3 Sb2 4.6(5) . . . . ?
Sb03 F00L F10 Sb2 -2.2(7) . . . . ?
Sb03 F00L Sb2 F00B -121(6) . . . . ?
Sb03 F00L Sb2 F00C 140(6) . . . . ?
Sb03 F00L Sb2 F00D 2.3(5) . . . . ?
Sb03 F00L Sb2 F00H 49(5) . . . . ?
Sb03 F00L Sb2 F00I -34(5) . . . . ?
Sb03 F00L Sb2 F1 -178(9) . . . . ?
Sb03 F00L Sb2 F2 144(6) . . . . ?
Sb03 F00L Sb2 F3 -38(5) . . . . ?
Sb03 F00L Sb2 F8 -123(6) . . . . ?
Sb03 F00L Sb2 F9 55(5) . . . . ?
Sb03 F00L Sb2 F10 18(6) . . . . ?
Sb03 F1 Sb2 F00B 118(5) . . . . ?
Sb03 F1 Sb2 F00C -137(5) . . . . ?
Sb03 F1 Sb2 F00D -2(5) . . . . ?
Sb03 F1 Sb2 F00H -51(4) . . . . ?
Sb03 F1 Sb2 F00I 36(4) . . . . ?
Sb03 F1 Sb2 F00L 178(9) . . . . ?
Sb03 F1 Sb2 F2 -145(5) . . . . ?
Sb03 F1 Sb2 F3 37(4) . . . . ?
Sb03 F1 Sb2 F8 125(5) . . . . ?
Sb03 F1 Sb2 F9 -53(5) . . . . ?
Sb03 F2 Sb2 F00B 163(9) . . . . ?
Sb03 F2 Sb2 F00C 65(9) . . . . ?
Sb03 F2 Sb2 F00D 69(8) . . . . ?
Sb03 F2 Sb2 F00H -16(8) . . . . ?
Sb03 F2 Sb2 F00I -97(11) . . . . ?
Sb03 F2 Sb2 F00L -102(9) . . . . ?
Sb03 F2 Sb2 F1 88(9) . . . . ?
Sb03 F2 Sb2 F8 -180(100) . . . . ?
Sb03 F2 Sb2 F9 1(8) . . . . ?
Sb03 F2 Sb2 F10 -86(9) . . . . ?
Sb03 F3 Sb2 F00B -168(7) . . . . ?
Sb03 F3 Sb2 F00C -77(6) . . . . ?
Sb03 F3 Sb2 F00D -72(7) . . . . ?
Sb03 F3 Sb2 F00H 11(6) . . . . ?
Sb03 F3 Sb2 F00I 86(7) . . . . ?
Sb03 F3 Sb2 F00L 99(7) . . . . ?
Sb03 F3 Sb2 F1 -92(7) . . . . ?
Sb03 F3 Sb2 F8 176(7) . . . . ?
Sb03 F3 Sb2 F9 -5(6) . . . . ?
Sb03 F3 Sb2 F10 81(7) . . . . ?
Sb03 F8 Sb2 F00B -70(6) . . . . ?
Sb03 F8 Sb2 F00C -160(7) . . . . ?
Sb03 F8 Sb2 F00D -66(6) . . . . ?
Sb03 F8 Sb2 F00H 75(6) . . . . ?
Sb03 F8 Sb2 F00I 15(5) . . . . ?
Sb03 F8 Sb2 F00L 103(6) . . . . ?
Sb03 F8 Sb2 F1 -91(6) . . . . ?
Sb03 F8 Sb2 F2 180(100) . . . . ?
Sb03 F8 Sb2 F3 -3(5) . . . . ?
Sb03 F8 Sb2 F10 90(6) . . . . ?
Sb03 F9 Sb2 F00B 67(6) . . . . ?
Sb03 F9 Sb2 F00C 162(6) . . . . ?
Sb03 F9 Sb2 F00D 67(5) . . . . ?
Sb03 F9 Sb2 F00H -81(6) . . . . ?
Sb03 F9 Sb2 F00I -14(5) . . . . ?
Sb03 F9 Sb2 F00L -102(5) . . . . ?
Sb03 F9 Sb2 F1 92(5) . . . . ?
Sb03 F9 Sb2 F2 -179(6) . . . . ?
Sb03 F9 Sb2 F3 4(5) . . . . ?
Sb03 F9 Sb2 F10 -90(5) . . . . ?
Sb03 F10 Sb2 F00B -118(5) . . . . ?
Sb03 F10 Sb2 F00C 135(5) . . . . ?
Sb03 F10 Sb2 F00D 11(3) . . . . ?
Sb03 F10 Sb2 F00H 51(4) . . . . ?
Sb03 F10 Sb2 F00I -38(4) . . . . ?
Sb03 F10 Sb2 F00L -163(5) . . . . ?
Sb03 F10 Sb2 F2 145(5) . . . . ?
Sb03 F10 Sb2 F3 -36(4) . . . . ?
Sb03 F10 Sb2 F8 -125(5) . . . . ?
Sb03 F10 Sb2 F9 53(4) . . . . ?
P005 C00U C01A C017 -175.07(16) . . . . ?
P005 C00U C01H C013 175.70(16) . . . . ?
P005 C00X C00Z C01S 178.48(17) . . . . ?
P005 C011 C016 C01X -179.65(16) . . . . ?
P005 C011 C01K C01J -179.31(16) . . . . ?
P006 C00N C00R C00V 178.83(17) . . . . ?
P006 C00N C010 C01O -178.75(17) . . . . ?
P006 C00Q C015 C01G -178.76(16) . . . . ?
P006 C00Q C01L C00P 178.62(16) . . . . ?
P006 C018 C01Z C01Y -171.98(15) . . . . ?
O009 N00G C01R C01D 1.7(3) . . . . ?
O00A N00K C01W C01I -1.6(3) . . . . ?
F00B Sb03 F00C F2 -81.9(19) . . . . ?
F00B Sb03 F00C Sb2 -37(7) . . . . ?
F00B Sb03 F00D F1 -51.2(9) . . . . ?
F00B Sb03 F00D Sb2 -53(5) . . . . ?
F00B Sb03 F00I F3 -72.7(18) . . . . ?
F00B Sb03 F00I Sb2 35(7) . . . . ?
F00B Sb03 F00L F10 -145(3) . . . . ?
F00B Sb03 F00L Sb2 53(5) . . . . ?
F00B Sb03 F3 F00I 106.0(17) . . . . ?
F00B Sb03 F3 Sb2 12(7) . . . . ?
F00B Sb03 F9 F00H -174.7(5) . . . . ?
F00B Sb03 F9 Sb2 -76(6) . . . . ?
F00B Sb03 F10 F00L 36(3) . . . . ?
F00B Sb03 F10 Sb2 53(5) . . . . ?
F00B F8 Sb2 F00C -91(3) . . . . ?
F00B F8 Sb2 F00D 4(3) . . . . ?
F00B F8 Sb2 F00H 145(3) . . . . ?
F00B F8 Sb2 F00I 85(2) . . . . ?
F00B F8 Sb2 F00L 173(3) . . . . ?
F00B F8 Sb2 F1 -21(3) . . . . ?
F00B F8 Sb2 F2 -110(3) . . . . ?
F00B F8 Sb2 F3 66(3) . . . . ?
F00B F8 Sb2 F10 160(3) . . . . ?
F00C Sb03 F00B F8 88(3) . . . . ?
F00C Sb03 F00B Sb2 29(5) . . . . ?
F00C Sb03 F00D F1 37.6(9) . . . . ?
F00C Sb03 F00D Sb2 35(5) . . . . ?
F00C Sb03 F00H F9 63(3) . . . . ?
F00C Sb03 F00H Sb2 -29(5) . . . . ?
F00C Sb03 F00L F10 126(3) . . . . ?
F00C Sb03 F00L Sb2 -36(5) . . . . ?
F00C Sb03 F3 F00I 174.0(4) . . . . ?
F00C Sb03 F3 Sb2 80(7) . . . . ?
F00C Sb03 F9 F00H -116(3) . . . . ?
F00C Sb03 F9 Sb2 -17(5) . . . . ?
F00C Sb03 F10 F00L -56(3) . . . . ?
F00C Sb03 F10 Sb2 -39(5) . . . . ?
F00C F2 Sb2 F00B 97.6(19) . . . . ?
F00C F2 Sb2 F00D 4(2) . . . . ?
F00C F2 Sb2 F00H -81.0(19) . . . . ?
F00C F2 Sb2 F00I -162(4) . . . . ?
F00C F2 Sb2 F00L -168(2) . . . . ?
F00C F2 Sb2 F1 22.8(19) . . . . ?
F00C F2 Sb2 F8 115(2) . . . . ?
F00C F2 Sb2 F9 -64(2) . . . . ?
F00C F2 Sb2 F10 -151(2) . . . . ?
F00D Sb03 F00B F8 178(3) . . . . ?
F00D Sb03 F00B Sb2 119(5) . . . . ?
F00D Sb03 F00C F2 -172.6(19) . . . . ?
F00D Sb03 F00C Sb2 -128(7) . . . . ?
F00D Sb03 F00H F9 -27(3) . . . . ?
F00D Sb03 F00H Sb2 -119(5) . . . . ?
F00D Sb03 F00I F3 18.1(18) . . . . ?
F00D Sb03 F00I Sb2 126(7) . . . . ?
F00D Sb03 F3 F00I -160.8(19) . . . . ?
F00D Sb03 F3 Sb2 105(7) . . . . ?
F00D Sb03 F9 F00H 152(3) . . . . ?
F00D Sb03 F9 Sb2 -109(5) . . . . ?
F00D Sb03 F10 F00L -178.0(4) . . . . ?
F00D Sb03 F10 Sb2 -161(6) . . . . ?
F00D F1 Sb2 F00B 120.1(10) . . . . ?
F00D F1 Sb2 F00C -134.8(11) . . . . ?
F00D F1 Sb2 F00H -49.3(10) . . . . ?
F00D F1 Sb2 F00I 38.0(11) . . . . ?
F00D F1 Sb2 F00L -180(4) . . . . ?
F00D F1 Sb2 F2 -143.5(12) . . . . ?
F00D F1 Sb2 F3 38.5(11) . . . . ?
F00D F1 Sb2 F8 126.8(13) . . . . ?
F00D F1 Sb2 F9 -51.3(12) . . . . ?
F00H Sb03 F00C F2 96.9(19) . . . . ?
F00H Sb03 F00C Sb2 142(7) . . . . ?
F00H Sb03 F00D F1 127.6(10) . . . . ?
F00H Sb03 F00D Sb2 125(5) . . . . ?
F00H Sb03 F00I F3 108.6(18) . . . . ?
F00H Sb03 F00I Sb2 -143(7) . . . . ?
F00H Sb03 F00L F10 36(3) . . . . ?
F00H Sb03 F00L Sb2 -126(5) . . . . ?
F00H Sb03 F3 F00I -73.3(17) . . . . ?
F00H Sb03 F3 Sb2 -168(7) . . . . ?
F00H Sb03 F9 Sb2 99(6) . . . . ?
F00H Sb03 F10 F00L -142(3) . . . . ?
F00H Sb03 F10 Sb2 -125(5) . . . . ?
F00H F9 Sb2 F00B 148(3) . . . . ?
F00H F9 Sb2 F00C -117(3) . . . . ?
F00H F9 Sb2 F00D 149(3) . . . . ?
F00H F9 Sb2 F00I 67(3) . . . . ?
F00H F9 Sb2 F00L -21(3) . . . . ?
F00H F9 Sb2 F1 173(3) . . . . ?
F00H F9 Sb2 F2 -98(3) . . . . ?
F00H F9 Sb2 F3 85(3) . . . . ?
F00H F9 Sb2 F10 -8(3) . . . . ?
F00I Sb03 F00B F8 -92(3) . . . . ?
F00I Sb03 F00B Sb2 -151(5) . . . . ?
F00I Sb03 F00D F1 -140.1(9) . . . . ?
F00I Sb03 F00D Sb2 -142(5) . . . . ?
F00I Sb03 F00H F9 -117(3) . . . . ?
F00I Sb03 F00H Sb2 151(5) . . . . ?
F00I Sb03 F00L F10 -56(3) . . . . ?
F00I Sb03 F00L Sb2 142(5) . . . . ?
F00I Sb03 F3 Sb2 -94(7) . . . . ?
F00I Sb03 F9 F00H 65(3) . . . . ?
F00I Sb03 F9 Sb2 164(5) . . . . ?
F00I Sb03 F10 F00L 122(3) . . . . ?
F00I Sb03 F10 Sb2 139(5) . . . . ?
F00I F3 Sb2 F00B 106.5(18) . . . . ?
F00I F3 Sb2 F00C -163(3) . . . . ?
F00I F3 Sb2 F00D -158.4(19) . . . . ?
F00I F3 Sb2 F00H -74.5(17) . . . . ?
F00I F3 Sb2 F00L 13(2) . . . . ?
F00I F3 Sb2 F1 -178.4(18) . . . . ?
F00I F3 Sb2 F8 89.7(19) . . . . ?
F00I F3 Sb2 F9 -91.5(19) . . . . ?
F00I F3 Sb2 F10 -4.6(19) . . . . ?
F00L Sb03 F00B F8 -1(3) . . . . ?
F00L Sb03 F00B Sb2 -61(5) . . . . ?
F00L Sb03 F00C F2 7.4(19) . . . . ?
F00L Sb03 F00C Sb2 52(7) . . . . ?
F00L Sb03 F00H F9 152(3) . . . . ?
F00L Sb03 F00H Sb2 60(5) . . . . ?
F00L Sb03 F00I F3 -162.0(18) . . . . ?
F00L Sb03 F00I Sb2 -54(7) . . . . ?
F00L Sb03 F3 F00I 19.2(19) . . . . ?
F00L Sb03 F3 Sb2 -75(7) . . . . ?
F00L Sb03 F9 F00H -29(3) . . . . ?
F00L Sb03 F9 Sb2 70(5) . . . . ?
F00L Sb03 F10 Sb2 17(5) . . . . ?
F00L F10 Sb2 F00B 45(3) . . . . ?
F00L F10 Sb2 F00C -62(3) . . . . ?
F00L F10 Sb2 F00D 174(2) . . . . ?
F00L F10 Sb2 F00H -146(3) . . . . ?
F00L F10 Sb2 F00I 125(3) . . . . ?
F00L F10 Sb2 F2 -52(2) . . . . ?
F00L F10 Sb2 F3 127(3) . . . . ?
F00L F10 Sb2 F8 38(3) . . . . ?
F00L F10 Sb2 F9 -144(3) . . . . ?
C00M C00P C01L C00Q 0.1(3) . . . . ?
C00N P006 C00Q C015 86.39(18) . . . . ?
C00N P006 C00Q C01L -93.30(17) . . . . ?
C00N P006 C018 C014 147.15(15) . . . . ?
C00N P006 C018 C01Z -39.47(18) . . . . ?
C00N C00R C00V C01C 0.0(3) . . . . ?
C00N C010 C01O C01C -0.1(3) . . . . ?
C00P C00M C01G C015 -1.1(3) . . . . ?
C00Q P006 C00N C00R 162.24(16) . . . . ?
C00Q P006 C00N C010 -18.6(2) . . . . ?
C00Q P006 C018 C014 -98.66(16) . . . . ?
C00Q P006 C018 C01Z 74.72(17) . . . . ?
C00Q C015 C01G C00M 0.2(3) . . . . ?
C00R C00N C010 C01O 0.4(3) . . . . ?
C00R C00V C01C C01O 0.3(3) . . . . ?
C00S C00X C00Z C01S -0.9(3) . . . . ?
C00S C012 C01E C01S -0.4(3) . . . . ?
C00T C01I C01M C020 1.6(3) . . . . ?
C00T C01I C01W N00K -170.9(2) . . . . ?
C00T C01P C021 C020 0.1(3) . . . . ?
C00U P005 C00X C00S -165.81(16) . . . . ?
C00U P005 C00X C00Z 14.82(19) . . . . ?
C00U P005 C011 C016 68.55(17) . . . . ?
C00U P005 C011 C01K -112.50(17) . . . . ?
C00V C01C C01O C010 -0.2(3) . . . . ?
C00W C01B C01F C01N -0.3(3) . . . . ?
C00W C01D C01R N00G -4.9(3) . . . . ?
C00X P005 C00U C01A 85.22(17) . . . . ?
C00X P005 C00U C01H -90.89(18) . . . . ?
C00X P005 C011 C016 -178.22(15) . . . . ?
C00X P005 C011 C01K 0.73(19) . . . . ?
C00X C00S C012 C01E -0.8(3) . . . . ?
C00X C00Z C01S C01E -0.3(3) . . . . ?
C00Y C013 C01H C00U -0.8(3) . . . . ?
C00Y C017 C01A C00U -0.8(3) . . . . ?
C010 C00N C00R C00V -0.3(3) . . . . ?
C011 P005 C00U C01A -160.44(15) . . . . ?
C011 P005 C00U C01H 23.45(19) . . . . ?
C011 P005 C00X C00S 81.17(17) . . . . ?
C011 P005 C00X C00Z -98.20(18) . . . . ?
C011 C016 C01X C01Q -1.1(3) . . . . ?
C012 C00S C00X P005 -177.91(17) . . . . ?
C012 C00S C00X C00Z 1.5(3) . . . . ?
C012 C01E C01S C00Z 1.0(3) . . . . ?
C013 C00Y C017 C01A -0.3(3) . . . . ?
C014 C018 C01Z C01Y 1.3(3) . . . . ?
C014 C01U C022 C01Y 1.1(3) . . . . ?
C015 C00Q C01L C00P -1.1(3) . . . . ?
C016 C011 C01K C01J -0.4(3) . . . . ?
C017 C00Y C013 C01H 1.1(3) . . . . ?
C018 P006 C00N C00R -85.02(17) . . . . ?
C018 P006 C00N C010 94.11(18) . . . . ?
C018 P006 C00Q C015 -28.51(19) . . . . ?
C018 P006 C00Q C01L 151.80(16) . . . . ?
C018 C014 C01U C022 0.0(3) . . . . ?
C019 C01D C01R N00G 177.2(2) . . . . ?
C01A C00U C01H C013 -0.3(3) . . . . ?
C01B C00W C01D C019 -1.1(3) . . . . ?
C01B C00W C01D C01R -178.94(19) . . . . ?
C01B C01F C01N C019 0.3(3) . . . . ?
C01D C00W C01B C01F 0.7(3) . . . . ?
C01D C019 C01N C01F -0.7(3) . . . . ?
C01G C00M C00P C01L 0.9(3) . . . . ?
C01H C00U C01A C017 1.1(3) . . . . ?
C01I C00T C01P C021 1.7(3) . . . . ?
C01I C01M C020 C021 0.2(3) . . . . ?
C01J C01Q C01X C016 0.0(3) . . . . ?
C01K C011 C016 C01X 1.4(3) . . . . ?
C01K C01J C01Q C01X 1.0(3) . . . . ?
C01L C00Q C015 C01G 0.9(3) . . . . ?
C01M C01I C01W N00K 11.2(3) . . . . ?
C01M C020 C021 C01P -1.1(3) . . . . ?
C01N C019 C01D C00W 1.1(3) . . . . ?
C01N C019 C01D C01R 179.15(19) . . . . ?
C01P C00T C01I C01M -2.6(3) . . . . ?
C01P C00T C01I C01W 179.41(19) . . . . ?
C01Q C01J C01K C011 -0.8(3) . . . . ?
C01T N00G C01R C01D 177.70(19) . . . . ?
C01U C014 C018 P006 172.40(16) . . . . ?
C01U C014 C018 C01Z -1.2(3) . . . . ?
C01V N00K C01W C01I -177.4(2) . . . . ?
C01W C01I C01M C020 179.42(19) . . . . ?
C01Z C01Y C022 C01U -1.0(3) . . . . ?
C022 C01Y C01Z C018 -0.2(3) . . . . ?
F1 Sb03 F00B F8 153(3) . . . . ?
F1 Sb03 F00B Sb2 94(5) . . . . ?
F1 Sb03 F00C F2 -153(2) . . . . ?
F1 Sb03 F00C Sb2 -108(7) . . . . ?
F1 Sb03 F00D Sb2 -2(5) . . . . ?
F1 Sb03 F00H F9 -2(3) . . . . ?
F1 Sb03 F00H Sb2 -94(5) . . . . ?
F1 Sb03 F00I F3 -2.7(19) . . . . ?
F1 Sb03 F00I Sb2 105(7) . . . . ?
F1 Sb03 F00L F10 162(3) . . . . ?
F1 Sb03 F00L Sb2 1(5) . . . . ?
F1 Sb03 F3 F00I 177.5(18) . . . . ?
F1 Sb03 F3 Sb2 83(7) . . . . ?
F1 Sb03 F9 F00H 178(3) . . . . ?
F1 Sb03 F9 Sb2 -82(5) . . . . ?
F1 Sb03 F10 F00L -43(5) . . . . ?
F1 Sb03 F10 Sb2 -26(6) . . . . ?
F2 Sb03 F00B F8 69(3) . . . . ?
F2 Sb03 F00B Sb2 10(5) . . . . ?
F2 Sb03 F00C Sb2 45(8) . . . . ?
F2 Sb03 F00D F1 35.0(11) . . . . ?
F2 Sb03 F00D Sb2 33(5) . . . . ?
F2 Sb03 F00H F9 82(3) . . . . ?
F2 Sb03 F00H Sb2 -10(5) . . . . ?
F2 Sb03 F00I F3 -148(3) . . . . ?
F2 Sb03 F00I Sb2 -40(7) . . . . ?
F2 Sb03 F00L F10 128(3) . . . . ?
F2 Sb03 F00L Sb2 -33(5) . . . . ?
F2 Sb03 F3 F00I 109(4) . . . . ?
F2 Sb03 F3 Sb2 15(7) . . . . ?
F2 Sb03 F9 F00H -98(3) . . . . ?
F2 Sb03 F9 Sb2 1(5) . . . . ?
F2 Sb03 F10 F00L -48(2) . . . . ?
F2 Sb03 F10 Sb2 -31(5) . . . . ?
F2 F00C Sb2 F00B -85(2) . . . . ?
F2 F00C Sb2 F00D -176(2) . . . . ?
F2 F00C Sb2 F00H 100(2) . . . . ?
F2 F00C Sb2 F00L 12(2) . . . . ?
F2 F00C Sb2 F1 -156(2) . . . . ?
F2 F00C Sb2 F3 -172(3) . . . . ?
F2 F00C Sb2 F8 -67(2) . . . . ?
F2 F00C Sb2 F9 115(2) . . . . ?
F2 F00C Sb2 F10 31(2) . . . . ?
F3 Sb03 F00B F8 -111(3) . . . . ?
F3 Sb03 F00B Sb2 -171(5) . . . . ?
F3 Sb03 F00C F2 -149(3) . . . . ?
F3 Sb03 F00C Sb2 -104(8) . . . . ?
F3 Sb03 F00D F1 -133.6(12) . . . . ?
F3 Sb03 F00D Sb2 -136(5) . . . . ?
F3 Sb03 F00H F9 -98(3) . . . . ?
F3 Sb03 F00H Sb2 170(5) . . . . ?
F3 Sb03 F00I Sb2 108(7) . . . . ?
F3 Sb03 F00L F10 -63(3) . . . . ?
F3 Sb03 F00L Sb2 135(5) . . . . ?
F3 Sb03 F9 F00H 86(3) . . . . ?
F3 Sb03 F9 Sb2 -175(5) . . . . ?
F3 Sb03 F10 F00L 122(2) . . . . ?
F3 Sb03 F10 Sb2 139(5) . . . . ?
F8 Sb03 F00B Sb2 -60(6) . . . . ?
F8 Sb03 F00C F2 -65(2) . . . . ?
F8 Sb03 F00C Sb2 -20(7) . . . . ?
F8 Sb03 F00D F1 -50.7(12) . . . . ?
F8 Sb03 F00D Sb2 -53(5) . . . . ?
F8 Sb03 F00H F9 148(4) . . . . ?
F8 Sb03 F00H Sb2 56(5) . . . . ?
F8 Sb03 F00I F3 -89.5(19) . . . . ?
F8 Sb03 F00I Sb2 19(7) . . . . ?
F8 Sb03 F00L F10 -146(3) . . . . ?
F8 Sb03 F00L Sb2 53(5) . . . . ?
F8 Sb03 F3 F00I 90.3(18) . . . . ?
F8 Sb03 F3 Sb2 -4(7) . . . . ?
F8 Sb03 F10 F00L 32(3) . . . . ?
F8 Sb03 F10 Sb2 49(5) . . . . ?
F8 F00B Sb2 F00C 92(3) . . . . ?
F8 F00B Sb2 F00D -177(3) . . . . ?
F8 F00B Sb2 F00H -118(6) . . . . ?
F8 F00B Sb2 F00I -94(3) . . . . ?
F8 F00B Sb2 F00L -7(3) . . . . ?
F8 F00B Sb2 F1 158(3) . . . . ?
F8 F00B Sb2 F2 70(3) . . . . ?
F8 F00B Sb2 F3 -112(3) . . . . ?
F8 F00B Sb2 F9 -176(4) . . . . ?
F8 F00B Sb2 F10 -21(3) . . . . ?
F9 Sb03 F00B F8 146(4) . . . . ?
F9 Sb03 F00B Sb2 87(6) . . . . ?
F9 Sb03 F00C F2 113(2) . . . . ?
F9 Sb03 F00C Sb2 158(7) . . . . ?
F9 Sb03 F00D F1 119.1(13) . . . . ?
F9 Sb03 F00D Sb2 117(5) . . . . ?
F9 Sb03 F00H Sb2 -92(6) . . . . ?
F9 Sb03 F00I F3 92(2) . . . . ?
F9 Sb03 F00I Sb2 -160(7) . . . . ?
F9 Sb03 F00L F10 44(3) . . . . ?
F9 Sb03 F00L Sb2 -117(5) . . . . ?
F9 Sb03 F3 F00I -91.7(19) . . . . ?
F9 Sb03 F3 Sb2 174(7) . . . . ?
F9 Sb03 F10 F00L -138(3) . . . . ?
F9 Sb03 F10 Sb2 -121(5) . . . . ?
F10 Sb03 F00B F8 -13(3) . . . . ?
F10 Sb03 F00B Sb2 -72(5) . . . . ?
F10 Sb03 F00C F2 24(2) . . . . ?
F10 Sb03 F00C Sb2 69(7) . . . . ?
F10 Sb03 F00D F1 161(3) . . . . ?
F10 Sb03 F00D Sb2 159(6) . . . . ?
F10 Sb03 F00H F9 165(3) . . . . ?
F10 Sb03 F00H Sb2 73(5) . . . . ?
F10 Sb03 F00I F3 -179.0(19) . . . . ?
F10 Sb03 F00I Sb2 -71(7) . . . . ?
F10 Sb03 F00L Sb2 -161(6) . . . . ?
F10 Sb03 F3 F00I 1.0(19) . . . . ?
F10 Sb03 F3 Sb2 -93(7) . . . . ?
F10 Sb03 F9 F00H -15(3) . . . . ?
F10 Sb03 F9 Sb2 84(5) . . . . ?
F10 F00L Sb2 F00B -139(3) . . . . ?
F10 F00L Sb2 F00C 122(3) . . . . ?
F10 F00L Sb2 F00D -16(6) . . . . ?
F10 F00L Sb2 F00H 31(3) . . . . ?
F10 F00L Sb2 F00I -52(3) . . . . ?
F10 F00L Sb2 F1 164(5) . . . . ?
F10 F00L Sb2 F2 126(3) . . . . ?
F10 F00L Sb2 F3 -56(3) . . . . ?
F10 F00L Sb2 F8 -141(3) . . . . ?
F10 F00L Sb2 F9 37(3) . . . . ?
Sb2 F00B F8 Sb03 5.4(5) . . . . ?
Sb2 F00C F2 Sb03 -3.7(6) . . . . ?
Sb2 F00D F1 Sb03 0.2(6) . . . . ?
Sb2 F00H F9 Sb03 6.1(5) . . . . ?
Sb2 F00I F3 Sb03 -4.6(5) . . . . ?
Sb2 F00L F10 Sb03 2.2(7) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_hfj-103
_audit_block_doi                 10.5517/ccdc.csd.cc1nznbm
_database_code_depnum_ccdc_archive 'CCDC 1548801'
_audit_update_record             
;
2017-05-09 deposited with the CCDC.
2018-11-19 downloaded from the CCDC.
;
_audit_creation_date             2017-02-01
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.01.04 svn.r3372 for OlexSys, GUI svn.r5292)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C10 H12 Au Cl3 N2 O'
_chemical_formula_sum            'C10 H12 Au Cl3 N2 O'
_chemical_formula_weight         479.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.7725(9)
_cell_length_b                   7.7140(8)
_cell_length_c                   18.4793(18)
_cell_angle_alpha                90
_cell_angle_beta                 102.713(2)
_cell_angle_gamma                90
_cell_volume                     1358.9(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9928
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      33.21
_cell_measurement_theta_min      2.63
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    11.400
_exptl_absorpt_correction_T_max  0.7465
_exptl_absorpt_correction_T_min  0.3455
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1296 before and 0.0483 after correction. The Ratio of minimum to maximum transmission is 0.4628. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.344
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_unetI/netI     0.0232
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            23752
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         33.211
_diffrn_reflns_theta_min         2.747
_diffrn_ambient_temperature      100.02
_diffrn_detector                 'Bruker PHOTON100 area detector'
_diffrn_detector_area_resol_mean 10.4167
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture, CMOS detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4849
_reflns_number_total             5179
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'APEX3 (Bruker AXS, 2016)'
_computing_data_collection       'APEX3 (Bruker AXS, 2016)'
_computing_data_reduction        'APEX3 (Bruker AXS, 2016)'
_computing_molecular_graphics    'Diamond v4 (Brandenburg, 2012)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2015b)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015a)'
_refine_diff_density_max         0.902
_refine_diff_density_min         -1.935
_refine_diff_density_rms         0.168
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.178
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     156
_refine_ls_number_reflns         5179
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0229
_refine_ls_R_factor_gt           0.0203
_refine_ls_restrained_S_all      1.178
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0160P)²+1.7489P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0453
_refine_ls_wR_factor_ref         0.0459
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C00A(H00A)
2.b Aromatic/amide H refined with riding coordinates:
 C009(H009), C00B(H00B), C00C(H00C), C00E(H00E), C00H(H00K)
2.c Idealised Me refined as rotating group:
 C00F(H00D,H00F,H00G), C00G(H00H,H00I,H00J)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au01 Au 0.64877(2) 0.57273(2) 0.44436(2) 0.00900(3) Uani 1 1 d . . . . .
Cl02 Cl 0.86038(6) 0.66700(8) 0.51012(3) 0.01530(10) Uani 1 1 d . . . . .
Cl03 Cl 0.43767(6) 0.48070(8) 0.37568(3) 0.01811(11) Uani 1 1 d . . . . .
Cl04 Cl 0.55288(6) 0.83059(8) 0.46300(3) 0.01740(11) Uani 1 1 d . . . . .
N005 N 0.7352(2) 0.3428(3) 0.42518(11) 0.0117(3) Uani 1 1 d . . . . .
O006 O 0.8441(2) 0.0918(2) 0.44217(10) 0.0158(3) Uani 1 1 d . . . . .
C007 C 0.7613(3) 0.4054(3) 0.29618(12) 0.0116(4) Uani 1 1 d . . . . .
N008 N 0.8289(2) 0.1335(3) 0.36232(11) 0.0146(4) Uani 1 1 d . . . . .
C009 C 0.8924(3) 0.4859(3) 0.31239(13) 0.0151(4) Uani 1 1 d . . . . .
H009 H 0.9568 0.4615 0.3578 0.018 Uiso 1 1 calc R . . . .
C00A C 0.7231(2) 0.2755(3) 0.34892(12) 0.0117(4) Uani 1 1 d . . . . .
H00A H 0.6270 0.2279 0.3289 0.014 Uiso 1 1 calc R . . . .
C00B C 0.9288(3) 0.6018(3) 0.26218(15) 0.0190(5) Uani 1 1 d . . . . .
H00B H 1.0183 0.6559 0.2731 0.023 Uiso 1 1 calc R . . . .
C00C C 0.8341(3) 0.6384(3) 0.19599(14) 0.0218(5) Uani 1 1 d . . . . .
H00C H 0.8589 0.7179 0.1618 0.026 Uiso 1 1 calc R . . . .
C00D C 0.7975(2) 0.2285(3) 0.47231(13) 0.0116(4) Uani 1 1 d . . . . .
C00E C 0.6671(3) 0.4427(3) 0.22956(13) 0.0159(4) Uani 1 1 d . . . . .
H00E H 0.5778 0.3882 0.2181 0.019 Uiso 1 1 calc R . . . .
C00F C 0.7766(3) -0.0243(3) 0.32219(16) 0.0227(5) Uani 1 1 d . . . . .
H00D H 0.8462 -0.1169 0.3357 0.034 Uiso 1 1 calc GR . . . .
H00F H 0.7597 -0.0027 0.2687 0.034 Uiso 1 1 calc GR . . . .
H00G H 0.6887 -0.0594 0.3353 0.034 Uiso 1 1 calc GR . . . .
C00G C 0.8245(3) 0.2312(4) 0.55413(13) 0.0166(4) Uani 1 1 d . . . . .
H00H H 0.7581 0.3101 0.5699 0.025 Uiso 1 1 calc GR . . . .
H00I H 0.9205 0.2711 0.5743 0.025 Uiso 1 1 calc GR . . . .
H00J H 0.8127 0.1142 0.5725 0.025 Uiso 1 1 calc GR . . . .
C00H C 0.7044(3) 0.5599(3) 0.17990(14) 0.0211(5) Uani 1 1 d . . . . .
H00K H 0.6400 0.5858 0.1347 0.025 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au01 Cl02 2.2751(6) . ?
Au01 Cl03 2.2843(6) . ?
Au01 Cl04 2.2573(6) . ?
Au01 N005 2.0289(19) . ?
N005 C00A 1.482(3) . ?
N005 C00D 1.293(3) . ?
O006 N008 1.485(3) . ?
O006 C00D 1.320(3) . ?
C007 C009 1.396(3) . ?
C007 C00A 1.501(3) . ?
C007 C00E 1.395(3) . ?
N008 C00A 1.490(3) . ?
N008 C00F 1.458(3) . ?
C009 H009 0.9500 . ?
C009 C00B 1.390(3) . ?
C00A H00A 1.0000 . ?
C00B H00B 0.9500 . ?
C00B C00C 1.391(4) . ?
C00C H00C 0.9500 . ?
C00C C00H 1.377(4) . ?
C00D C00G 1.477(3) . ?
C00E H00E 0.9500 . ?
C00E C00H 1.393(4) . ?
C00F H00D 0.9800 . ?
C00F H00F 0.9800 . ?
C00F H00G 0.9800 . ?
C00G H00H 0.9800 . ?
C00G H00I 0.9800 . ?
C00G H00J 0.9800 . ?
C00H H00K 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl02 Au01 Cl03 178.56(2) . . ?
Cl04 Au01 Cl02 89.76(2) . . ?
Cl04 Au01 Cl03 90.24(2) . . ?
N005 Au01 Cl02 90.49(6) . . ?
N005 Au01 Cl03 89.47(6) . . ?
N005 Au01 Cl04 178.65(6) . . ?
C00A N005 Au01 121.55(14) . . ?
C00D N005 Au01 129.09(16) . . ?
C00D N005 C00A 109.20(19) . . ?
C00D O006 N008 106.13(17) . . ?
C009 C007 C00A 120.4(2) . . ?
C00E C007 C009 119.6(2) . . ?
C00E C007 C00A 120.0(2) . . ?
O006 N008 C00A 103.79(17) . . ?
C00F N008 O006 105.76(19) . . ?
C00F N008 C00A 112.1(2) . . ?
C007 C009 H009 120.0 . . ?
C00B C009 C007 120.1(2) . . ?
C00B C009 H009 120.0 . . ?
N005 C00A C007 113.86(18) . . ?
N005 C00A N008 101.10(17) . . ?
N005 C00A H00A 110.6 . . ?
C007 C00A H00A 110.6 . . ?
N008 C00A C007 109.63(19) . . ?
N008 C00A H00A 110.6 . . ?
C009 C00B H00B 120.0 . . ?
C009 C00B C00C 119.9(3) . . ?
C00C C00B H00B 120.0 . . ?
C00B C00C H00C 119.9 . . ?
C00H C00C C00B 120.3(2) . . ?
C00H C00C H00C 119.9 . . ?
N005 C00D O006 114.6(2) . . ?
N005 C00D C00G 129.2(2) . . ?
O006 C00D C00G 116.3(2) . . ?
C007 C00E H00E 120.1 . . ?
C00H C00E C007 119.9(2) . . ?
C00H C00E H00E 120.1 . . ?
N008 C00F H00D 109.5 . . ?
N008 C00F H00F 109.5 . . ?
N008 C00F H00G 109.5 . . ?
H00D C00F H00F 109.5 . . ?
H00D C00F H00G 109.5 . . ?
H00F C00F H00G 109.5 . . ?
C00D C00G H00H 109.5 . . ?
C00D C00G H00I 109.5 . . ?
C00D C00G H00J 109.5 . . ?
H00H C00G H00I 109.5 . . ?
H00H C00G H00J 109.5 . . ?
H00I C00G H00J 109.5 . . ?
C00C C00H C00E 120.3(2) . . ?
C00C C00H H00K 119.8 . . ?
C00E C00H H00K 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au01 N005 C00A C007 49.2(2) . . . . ?
Au01 N005 C00A N008 166.67(14) . . . . ?
Au01 N005 C00D O006 -179.31(15) . . . . ?
Au01 N005 C00D C00G 0.0(4) . . . . ?
O006 N008 C00A N005 21.9(2) . . . . ?
O006 N008 C00A C007 142.38(18) . . . . ?
C007 C009 C00B C00C 0.5(4) . . . . ?
C007 C00E C00H C00C 0.4(4) . . . . ?
N008 O006 C00D N005 9.7(3) . . . . ?
N008 O006 C00D C00G -169.7(2) . . . . ?
C009 C007 C00A N005 56.0(3) . . . . ?
C009 C007 C00A N008 -56.4(3) . . . . ?
C009 C007 C00E C00H -0.1(4) . . . . ?
C009 C00B C00C C00H -0.2(4) . . . . ?
C00A N005 C00D O006 5.4(3) . . . . ?
C00A N005 C00D C00G -175.3(2) . . . . ?
C00A C007 C009 C00B 177.9(2) . . . . ?
C00A C007 C00E C00H -178.3(2) . . . . ?
C00B C00C C00H C00E -0.3(4) . . . . ?
C00D N005 C00A C007 -135.1(2) . . . . ?
C00D N005 C00A N008 -17.6(2) . . . . ?
C00D O006 N008 C00A -20.2(2) . . . . ?
C00D O006 N008 C00F -138.4(2) . . . . ?
C00E C007 C009 C00B -0.3(4) . . . . ?
C00E C007 C00A N005 -125.8(2) . . . . ?
C00E C007 C00A N008 121.7(2) . . . . ?
C00F N008 C00A N005 135.6(2) . . . . ?
C00F N008 C00A C007 -103.9(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
