# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_NH8RTMO
_database_code_depnum_ccdc_archive 'CCDC 1883323'
_audit_update_record             
;
2018-12-23 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C53 H40 Eu N3 O6'
_chemical_formula_weight         966.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.1559(4)
_cell_length_b                   22.4747(5)
_cell_length_c                   16.1361(6)
_cell_angle_alpha                90
_cell_angle_beta                 109.698(4)
_cell_angle_gamma                90
_cell_volume                     4491.8(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5774
_cell_measurement_theta_min      2.24
_cell_measurement_theta_max      26.52

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.430
_exptl_crystal_F_000             1960
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    1.450
_shelx_estimated_absorpt_T_min   0.760
_shelx_estimated_absorpt_T_max   0.869
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_correction_T_min  0.742
_exptl_absorpt_correction_T_max  1.0
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.43i (Rigaku Oxford Diffraction, 2015)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -12.00  94.00   1.00   70.00    --   26.84  57.00  90.00  106
  2  ω    -13.00  94.00   1.00   70.00    --   26.84  37.00-120.00  107
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0171575000
_diffrn_orient_matrix_UB_12      -0.0248537000
_diffrn_orient_matrix_UB_13      0.0282824000
_diffrn_orient_matrix_UB_21      -0.0527724000
_diffrn_orient_matrix_UB_22      -0.0029048000
_diffrn_orient_matrix_UB_23      0.0021324000
_diffrn_orient_matrix_UB_31      -0.0143198000
_diffrn_orient_matrix_UB_32      -0.0191471000
_diffrn_orient_matrix_UB_33      -0.0371551000

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14766
_diffrn_reflns_av_unetI/netI     0.0512
_diffrn_reflns_av_R_equivalents  0.0245
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         1.877
_diffrn_reflns_theta_max         28.290
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.871
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.871
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.871
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             9723
_reflns_number_gt                7354
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_computing_data_collection       'CrysAlisPro 1.171.38.43i (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.43i (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43i (Rigaku OD, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    
'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
_computing_publication_material  'SHELXL-2016/6 (Sheldrick, 2016)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0500P)²+0.0223P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_extinction_coef       0.00117(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         9723
_refine_ls_number_parameters     573
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0659
_refine_ls_R_factor_gt           0.0457
_refine_ls_wR_factor_ref         0.1158
_refine_ls_wR_factor_gt          0.1034
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_restrained_S_all      1.088
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4958(4) 0.5907(2) 1.0404(3) 0.0492(10) Uani 1 1 d . . . . .
C2 C 0.6171(4) 0.5887(2) 1.0807(3) 0.0496(10) Uani 1 1 d . . . . .
C3 C 0.6746(4) 0.6393(2) 1.0779(3) 0.0618(13) Uani 1 1 d . . . . .
H3 H 0.637916 0.673275 1.050882 0.074 Uiso 1 1 calc R U . . .
C4 C 0.7850(4) 0.6406(3) 1.1142(4) 0.0743(15) Uani 1 1 d . . . . .
H4 H 0.822384 0.675569 1.113234 0.089 Uiso 1 1 calc R U . . .
C5 C 0.8403(4) 0.5901(3) 1.1522(3) 0.0732(15) Uani 1 1 d . . . . .
H5 H 0.915199 0.590720 1.176336 0.088 Uiso 1 1 calc R U . . .
C6 C 0.7847(4) 0.5390(3) 1.1542(3) 0.0708(14) Uani 1 1 d . . . . .
H6 H 0.822207 0.504714 1.179225 0.085 Uiso 1 1 calc R U . . .
C7 C 0.6731(4) 0.5378(2) 1.1193(3) 0.0572(12) Uani 1 1 d . . . . .
H7 H 0.635820 0.503040 1.121671 0.069 Uiso 1 1 calc R U . . .
C8 C 0.4338(4) 0.5518(2) 1.0713(3) 0.0552(11) Uani 1 1 d . . . . .
H8 H 0.469796 0.525097 1.115451 0.066 Uiso 1 1 calc R U . . .
C9 C 0.3210(4) 0.5505(2) 1.0399(3) 0.0507(11) Uani 1 1 d . . . . .
C10 C 0.2633(4) 0.5059(2) 1.0767(3) 0.0554(12) Uani 1 1 d . . . . .
C11 C 0.3060(5) 0.4512(2) 1.1087(3) 0.0729(15) Uani 1 1 d . . . . .
H11 H 0.373006 0.440188 1.106184 0.087 Uiso 1 1 calc R U . . .
C12 C 0.2507(6) 0.4128(3) 1.1443(4) 0.095(2) Uani 1 1 d . . . . .
H12 H 0.281075 0.376365 1.166857 0.114 Uiso 1 1 calc R U . . .
C13 C 0.1511(6) 0.4280(3) 1.1467(4) 0.096(2) Uani 1 1 d . . . . .
H13 H 0.114571 0.402169 1.171821 0.116 Uiso 1 1 calc R U . . .
C14 C 0.1052(6) 0.4805(3) 1.1126(4) 0.100(2) Uani 1 1 d . . . . .
H14 H 0.036526 0.490203 1.112612 0.120 Uiso 1 1 calc R U . . .
C15 C 0.1615(5) 0.5197(3) 1.0776(4) 0.0808(17) Uani 1 1 d . . . . .
H15 H 0.130194 0.555853 1.054497 0.097 Uiso 1 1 calc R U . . .
C16 C 0.2545(4) 0.59760(18) 0.7175(3) 0.0487(10) Uani 1 1 d . . . . .
C17 C 0.3162(4) 0.5654(2) 0.6687(3) 0.0538(11) Uani 1 1 d . . . . .
C18 C 0.4242(4) 0.5534(2) 0.7128(3) 0.0706(14) Uani 1 1 d . . . . .
H18 H 0.455509 0.566794 0.770334 0.085 Uiso 1 1 calc R U . . .
C19 C 0.4866(5) 0.5226(3) 0.6743(4) 0.095(2) Uani 1 1 d . . . . .
H19 H 0.558809 0.514802 0.705656 0.114 Uiso 1 1 calc R U . . .
C20 C 0.4413(6) 0.5034(3) 0.5892(4) 0.111(2) Uani 1 1 d . . . . .
H20 H 0.482792 0.482779 0.562141 0.133 Uiso 1 1 calc R U . . .
C21 C 0.3356(6) 0.5146(3) 0.5445(4) 0.113(3) Uani 1 1 d . . . . .
H21 H 0.305219 0.501523 0.486636 0.136 Uiso 1 1 calc R U . . .
C22 C 0.2717(5) 0.5454(3) 0.5837(3) 0.092(2) Uani 1 1 d . . . . .
H22 H 0.199132 0.552307 0.552454 0.110 Uiso 1 1 calc R U . . .
C23 C 0.1438(4) 0.6076(2) 0.6802(3) 0.0528(11) Uani 1 1 d . . . . .
H23 H 0.110005 0.596562 0.621825 0.063 Uiso 1 1 calc R U . . .
C24 C 0.0805(4) 0.63304(18) 0.7245(3) 0.0469(10) Uani 1 1 d . . . . .
C25 C -0.0369(4) 0.6451(2) 0.6773(3) 0.0508(11) Uani 1 1 d . . . . .
C26 C -0.0898(5) 0.6854(2) 0.7135(3) 0.0669(14) Uani 1 1 d . . . . .
H26 H -0.052036 0.705054 0.765484 0.080 Uiso 1 1 calc R U . . .
C27 C -0.1995(6) 0.6967(3) 0.6721(5) 0.096(2) Uani 1 1 d . . . . .
H27 H -0.234386 0.724177 0.696271 0.116 Uiso 1 1 calc R U . . .
C28 C -0.2555(6) 0.6677(4) 0.5968(5) 0.121(3) Uani 1 1 d . . . . .
H28 H -0.329141 0.674393 0.570310 0.145 Uiso 1 1 calc R U . . .
C29 C -0.2041(5) 0.6293(4) 0.5607(4) 0.107(2) Uani 1 1 d . . . . .
H29 H -0.242863 0.610187 0.508461 0.129 Uiso 1 1 calc R U . . .
C30 C -0.0959(4) 0.6174(3) 0.5988(3) 0.0739(15) Uani 1 1 d . . . . .
H30 H -0.062252 0.590894 0.572184 0.089 Uiso 1 1 calc R U . . .
C31 C 0.2370(5) 0.8173(2) 0.8573(3) 0.0643(14) Uani 1 1 d . . . . .
C32 C 0.1606(5) 0.8659(2) 0.8586(3) 0.0709(15) Uani 1 1 d . . . . .
C33 C 0.0805(5) 0.8545(3) 0.8949(4) 0.0808(16) Uani 1 1 d . . . . .
H33 H 0.074847 0.816863 0.917020 0.097 Uiso 1 1 calc R U . . .
C34 C 0.0095(5) 0.8989(4) 0.8982(4) 0.099(2) Uani 1 1 d . . . . .
H34 H -0.043448 0.891149 0.923154 0.118 Uiso 1 1 calc R U . . .
C35 C 0.0164(7) 0.9543(4) 0.8650(5) 0.111(3) Uani 1 1 d . . . . .
H35 H -0.031443 0.984153 0.867577 0.134 Uiso 1 1 calc R U . . .
C36 C 0.0928(7) 0.9655(3) 0.8286(4) 0.104(2) Uani 1 1 d . . . . .
H36 H 0.096542 1.002927 0.805341 0.125 Uiso 1 1 calc R U . . .
C37 C 0.1660(6) 0.9218(3) 0.8253(3) 0.0841(17) Uani 1 1 d . . . . .
H37 H 0.218839 0.930379 0.800595 0.101 Uiso 1 1 calc R U . . .
C38 C 0.3398(5) 0.8295(2) 0.8540(3) 0.0688(15) Uani 1 1 d . . . . .
H38 H 0.360065 0.869200 0.854243 0.083 Uiso 1 1 calc R U . . .
C39 C 0.4135(4) 0.7863(2) 0.8504(3) 0.0613(13) Uani 1 1 d . . . . .
C40 C 0.5205(5) 0.8024(3) 0.8433(3) 0.0694(14) Uani 1 1 d . . . . .
C41 C 0.5392(6) 0.8553(3) 0.8066(4) 0.0897(19) Uani 1 1 d . . . . .
H41 H 0.484268 0.883343 0.786902 0.108 Uiso 1 1 calc R U . . .
C42 C 0.6397(8) 0.8667(4) 0.7993(5) 0.117(3) Uani 1 1 d . . . . .
H42 H 0.652460 0.902482 0.775582 0.140 Uiso 1 1 calc R U . . .
C43 C 0.7188(7) 0.8254(4) 0.8268(5) 0.118(3) Uani 1 1 d . . . . .
H43 H 0.785438 0.832917 0.820796 0.142 Uiso 1 1 calc R U . . .
C44 C 0.7031(6) 0.7733(4) 0.8628(4) 0.105(2) Uani 1 1 d . . . . .
H44 H 0.758592 0.745633 0.882333 0.126 Uiso 1 1 calc R U . . .
C45 C 0.6028(5) 0.7620(3) 0.8702(3) 0.0782(16) Uani 1 1 d . . . . .
H45 H 0.591284 0.725977 0.894096 0.094 Uiso 1 1 calc R U . . .
C46 C 0.4699(4) 0.7664(2) 1.0750(3) 0.0630(13) Uani 1 1 d . . . . .
H46 H 0.522740 0.766919 1.048547 0.076 Uiso 1 1 calc R U . . .
C47 C 0.4783(4) 0.7936(2) 1.1514(3) 0.0680(14) Uani 1 1 d . . . . .
H47 H 0.536557 0.815468 1.187267 0.082 Uiso 1 1 calc R U . . .
C48 C 0.3206(3) 0.74818(18) 1.0970(2) 0.0422(9) Uani 1 1 d . . . . .
C49 C 0.2128(4) 0.72536(19) 1.0827(2) 0.0455(10) Uani 1 1 d . . . . .
C50 C 0.1591(4) 0.7325(2) 1.1420(3) 0.0610(13) Uani 1 1 d . . . . .
H50 H 0.190641 0.752931 1.194559 0.073 Uiso 1 1 calc R U . . .
C51 C 0.0583(5) 0.7086(3) 1.1215(4) 0.0804(17) Uani 1 1 d . . . . .
H51 H 0.020831 0.711848 1.161014 0.096 Uiso 1 1 calc R U . . .
C52 C 0.0127(5) 0.6803(2) 1.0440(4) 0.0771(16) Uani 1 1 d . . . . .
H52 H -0.056996 0.665120 1.028670 0.093 Uiso 1 1 calc R U . . .
C53 C 0.0702(4) 0.6745(2) 0.9890(3) 0.0636(13) Uani 1 1 d . . . . .
H53 H 0.039009 0.654157 0.936287 0.076 Uiso 1 1 calc R U . . .
Eu1 Eu 0.28742(2) 0.67107(2) 0.90851(2) 0.04272(9) Uani 1 1 d . . . . .
N1 N 0.3724(3) 0.73794(17) 1.0417(2) 0.0506(9) Uani 1 1 d . . . . .
N2 N 0.3820(4) 0.78201(18) 1.1654(2) 0.0587(11) Uani 1 1 d . . . . .
N3 N 0.1686(3) 0.69624(16) 1.0065(2) 0.0476(8) Uani 1 1 d . . . . .
O1 O 0.4570(2) 0.62904(14) 0.98111(18) 0.0548(8) Uani 1 1 d . . . . .
O2 O 0.2621(2) 0.58549(13) 0.98176(19) 0.0527(7) Uani 1 1 d . . . . .
O3 O 0.3101(3) 0.61521(16) 0.79293(19) 0.0693(10) Uani 1 1 d . . . . .
O4 O 0.1164(3) 0.64930(15) 0.80428(19) 0.0602(8) Uani 1 1 d . . . . .
O5 O 0.2024(3) 0.76492(15) 0.8602(2) 0.0632(8) Uani 1 1 d . . . . .
O6 O 0.3963(3) 0.73035(14) 0.8526(2) 0.0634(9) Uani 1 1 d . . . . .
H2 H 0.359(4) 0.787(2) 1.207(3) 0.066(16) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.260(5) . ?
C1 C8 1.398(6) . ?
C1 C2 1.507(6) . ?
C2 C3 1.376(6) . ?
C2 C7 1.389(6) . ?
C3 C4 1.371(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.375(7) . ?
C4 H4 0.9300 . ?
C5 C6 1.369(7) . ?
C5 H5 0.9300 . ?
C6 C7 1.383(7) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 C9 1.397(6) . ?
C8 H8 0.9300 . ?
C9 O2 1.268(5) . ?
C9 C10 1.496(6) . ?
C10 C11 1.376(7) . ?
C10 C15 1.380(7) . ?
C11 C12 1.373(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.367(9) . ?
C12 H12 0.9300 . ?
C13 C14 1.354(9) . ?
C13 H13 0.9300 . ?
C14 C15 1.387(7) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C16 O3 1.254(5) . ?
C16 C23 1.394(6) . ?
C16 C17 1.495(6) . ?
C17 C22 1.372(6) . ?
C17 C18 1.384(7) . ?
C18 C19 1.373(7) . ?
C18 H18 0.9300 . ?
C19 C20 1.369(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.357(9) . ?
C20 H20 0.9300 . ?
C21 C22 1.395(8) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.389(6) . ?
C23 H23 0.9300 . ?
C24 O4 1.267(5) . ?
C24 C25 1.498(6) . ?
C25 C26 1.386(6) . ?
C25 C30 1.390(6) . ?
C26 C27 1.393(8) . ?
C26 H26 0.9300 . ?
C27 C28 1.356(10) . ?
C27 H27 0.9300 . ?
C28 C29 1.346(9) . ?
C28 H28 0.9300 . ?
C29 C30 1.372(8) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 O5 1.268(6) . ?
C31 C38 1.399(8) . ?
C31 C32 1.490(7) . ?
C32 C37 1.379(7) . ?
C32 C33 1.391(8) . ?
C33 C34 1.381(8) . ?
C33 H33 0.9300 . ?
C34 C35 1.372(9) . ?
C34 H34 0.9300 . ?
C35 C36 1.347(10) . ?
C35 H35 0.9300 . ?
C36 C37 1.388(8) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C38 C39 1.388(7) . ?
C38 H38 0.9300 . ?
C39 O6 1.280(5) . ?
C39 C40 1.495(7) . ?
C40 C45 1.368(8) . ?
C40 C41 1.386(7) . ?
C41 C42 1.390(9) . ?
C41 H41 0.9300 . ?
C42 C43 1.353(11) . ?
C42 H42 0.9300 . ?
C43 C44 1.352(10) . ?
C43 H43 0.9300 . ?
C44 C45 1.388(8) . ?
C44 H44 0.9300 . ?
C45 H45 0.9300 . ?
C46 C47 1.347(6) . ?
C46 N1 1.370(5) . ?
C46 H46 0.9300 . ?
C47 N2 1.384(6) . ?
C47 H47 0.9300 . ?
C48 N1 1.314(5) . ?
C48 N2 1.359(5) . ?
C48 C49 1.451(6) . ?
C49 N3 1.340(5) . ?
C49 C50 1.377(5) . ?
C50 C51 1.364(7) . ?
C50 H50 0.9300 . ?
C51 C52 1.351(7) . ?
C51 H51 0.9300 . ?
C52 C53 1.353(7) . ?
C52 H52 0.9300 . ?
C53 N3 1.323(6) . ?
C53 H53 0.9300 . ?
Eu1 O2 2.339(3) . ?
Eu1 O1 2.341(3) . ?
Eu1 O6 2.347(3) . ?
Eu1 O3 2.349(3) . ?
Eu1 O4 2.362(3) . ?
Eu1 O5 2.392(3) . ?
Eu1 N1 2.551(3) . ?
Eu1 N3 2.633(3) . ?
N2 H2 0.83(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C8 124.3(4) . . ?
O1 C1 C2 116.6(4) . . ?
C8 C1 C2 119.2(4) . . ?
C3 C2 C7 118.7(4) . . ?
C3 C2 C1 118.3(4) . . ?
C7 C2 C1 122.9(4) . . ?
C4 C3 C2 121.3(5) . . ?
C4 C3 H3 119.4 . . ?
C2 C3 H3 119.4 . . ?
C3 C4 C5 119.8(5) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C6 C5 C4 119.8(5) . . ?
C6 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C5 C6 C7 120.5(5) . . ?
C5 C6 H6 119.7 . . ?
C7 C6 H6 119.7 . . ?
C6 C7 C2 119.8(5) . . ?
C6 C7 H7 120.1 . . ?
C2 C7 H7 120.1 . . ?
C9 C8 C1 124.1(4) . . ?
C9 C8 H8 118.0 . . ?
C1 C8 H8 118.0 . . ?
O2 C9 C8 124.3(4) . . ?
O2 C9 C10 116.4(4) . . ?
C8 C9 C10 119.3(4) . . ?
C11 C10 C15 118.2(5) . . ?
C11 C10 C9 123.3(5) . . ?
C15 C10 C9 118.5(5) . . ?
C12 C11 C10 120.7(6) . . ?
C12 C11 H11 119.6 . . ?
C10 C11 H11 119.6 . . ?
C13 C12 C11 120.1(6) . . ?
C13 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C14 C13 C12 120.4(6) . . ?
C14 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C13 C14 C15 119.5(6) . . ?
C13 C14 H14 120.2 . . ?
C15 C14 H14 120.2 . . ?
C10 C15 C14 120.9(6) . . ?
C10 C15 H15 119.5 . . ?
C14 C15 H15 119.5 . . ?
O3 C16 C23 123.4(4) . . ?
O3 C16 C17 115.0(4) . . ?
C23 C16 C17 121.6(4) . . ?
C22 C17 C18 118.0(4) . . ?
C22 C17 C16 124.1(5) . . ?
C18 C17 C16 117.9(4) . . ?
C19 C18 C17 122.2(5) . . ?
C19 C18 H18 118.9 . . ?
C17 C18 H18 118.9 . . ?
C20 C19 C18 119.2(6) . . ?
C20 C19 H19 120.4 . . ?
C18 C19 H19 120.4 . . ?
C21 C20 C19 119.8(6) . . ?
C21 C20 H20 120.1 . . ?
C19 C20 H20 120.1 . . ?
C20 C21 C22 121.1(6) . . ?
C20 C21 H21 119.5 . . ?
C22 C21 H21 119.5 . . ?
C17 C22 C21 119.8(6) . . ?
C17 C22 H22 120.1 . . ?
C21 C22 H22 120.1 . . ?
C24 C23 C16 124.4(4) . . ?
C24 C23 H23 117.8 . . ?
C16 C23 H23 117.8 . . ?
O4 C24 C23 124.0(4) . . ?
O4 C24 C25 115.5(4) . . ?
C23 C24 C25 120.5(4) . . ?
C26 C25 C30 118.0(5) . . ?
C26 C25 C24 118.9(4) . . ?
C30 C25 C24 123.1(4) . . ?
C25 C26 C27 120.2(6) . . ?
C25 C26 H26 119.9 . . ?
C27 C26 H26 119.9 . . ?
C28 C27 C26 120.3(6) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C29 C28 C27 119.7(7) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C28 C29 C30 121.8(7) . . ?
C28 C29 H29 119.1 . . ?
C30 C29 H29 119.1 . . ?
C29 C30 C25 119.9(6) . . ?
C29 C30 H30 120.0 . . ?
C25 C30 H30 120.0 . . ?
O5 C31 C38 123.2(5) . . ?
O5 C31 C32 115.3(5) . . ?
C38 C31 C32 121.5(5) . . ?
C37 C32 C33 118.6(6) . . ?
C37 C32 C31 122.7(6) . . ?
C33 C32 C31 118.8(5) . . ?
C34 C33 C32 120.1(6) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C35 C34 C33 120.4(7) . . ?
C35 C34 H34 119.8 . . ?
C33 C34 H34 119.8 . . ?
C36 C35 C34 119.8(7) . . ?
C36 C35 H35 120.1 . . ?
C34 C35 H35 120.1 . . ?
C35 C36 C37 121.0(7) . . ?
C35 C36 H36 119.5 . . ?
C37 C36 H36 119.5 . . ?
C32 C37 C36 120.1(7) . . ?
C32 C37 H37 120.0 . . ?
C36 C37 H37 120.0 . . ?
C39 C38 C31 124.2(5) . . ?
C39 C38 H38 117.9 . . ?
C31 C38 H38 117.9 . . ?
O6 C39 C38 123.6(5) . . ?
O6 C39 C40 114.9(5) . . ?
C38 C39 C40 121.5(5) . . ?
C45 C40 C41 118.1(6) . . ?
C45 C40 C39 118.6(5) . . ?
C41 C40 C39 123.2(6) . . ?
C40 C41 C42 120.3(7) . . ?
C40 C41 H41 119.8 . . ?
C42 C41 H41 119.8 . . ?
C43 C42 C41 119.6(8) . . ?
C43 C42 H42 120.2 . . ?
C41 C42 H42 120.2 . . ?
C44 C43 C42 121.5(8) . . ?
C44 C43 H43 119.2 . . ?
C42 C43 H43 119.2 . . ?
C43 C44 C45 118.9(8) . . ?
C43 C44 H44 120.6 . . ?
C45 C44 H44 120.6 . . ?
C40 C45 C44 121.6(6) . . ?
C40 C45 H45 119.2 . . ?
C44 C45 H45 119.2 . . ?
C47 C46 N1 110.4(4) . . ?
C47 C46 H46 124.8 . . ?
N1 C46 H46 124.8 . . ?
C46 C47 N2 105.5(4) . . ?
C46 C47 H47 127.3 . . ?
N2 C47 H47 127.3 . . ?
N1 C48 N2 110.3(4) . . ?
N1 C48 C49 122.2(4) . . ?
N2 C48 C49 127.5(4) . . ?
N3 C49 C50 121.9(4) . . ?
N3 C49 C48 114.6(3) . . ?
C50 C49 C48 123.5(4) . . ?
C51 C50 C49 118.1(5) . . ?
C51 C50 H50 121.0 . . ?
C49 C50 H50 121.0 . . ?
C52 C51 C50 120.1(5) . . ?
C52 C51 H51 119.9 . . ?
C50 C51 H51 119.9 . . ?
C51 C52 C53 118.8(5) . . ?
C51 C52 H52 120.6 . . ?
C53 C52 H52 120.6 . . ?
N3 C53 C52 123.2(5) . . ?
N3 C53 H53 118.4 . . ?
C52 C53 H53 118.4 . . ?
O2 Eu1 O1 71.91(10) . . ?
O2 Eu1 O6 150.45(11) . . ?
O1 Eu1 O6 79.59(11) . . ?
O2 Eu1 O3 92.27(12) . . ?
O1 Eu1 O3 80.03(11) . . ?
O6 Eu1 O3 74.99(12) . . ?
O2 Eu1 O4 85.75(11) . . ?
O1 Eu1 O4 142.30(12) . . ?
O6 Eu1 O4 113.70(12) . . ?
O3 Eu1 O4 70.70(11) . . ?
O2 Eu1 O5 139.39(11) . . ?
O1 Eu1 O5 141.35(11) . . ?
O6 Eu1 O5 69.70(11) . . ?
O3 Eu1 O5 112.53(12) . . ?
O4 Eu1 O5 73.86(12) . . ?
O2 Eu1 N1 98.94(11) . . ?
O1 Eu1 N1 75.10(11) . . ?
O6 Eu1 N1 80.70(11) . . ?
O3 Eu1 N1 147.85(11) . . ?
O4 Eu1 N1 139.80(11) . . ?
O5 Eu1 N1 77.23(12) . . ?
O2 Eu1 N3 70.05(11) . . ?
O1 Eu1 N3 116.41(10) . . ?
O6 Eu1 N3 132.18(11) . . ?
O3 Eu1 N3 148.42(11) . . ?
O4 Eu1 N3 81.75(10) . . ?
O5 Eu1 N3 72.49(11) . . ?
N1 Eu1 N3 63.11(11) . . ?
C48 N1 C46 106.5(3) . . ?
C48 N1 Eu1 119.7(3) . . ?
C46 N1 Eu1 133.8(3) . . ?
C48 N2 C47 107.5(4) . . ?
C48 N2 H2 117(4) . . ?
C47 N2 H2 135(4) . . ?
C53 N3 C49 117.9(4) . . ?
C53 N3 Eu1 121.9(3) . . ?
C49 N3 Eu1 119.6(3) . . ?
C1 O1 Eu1 136.8(3) . . ?
C9 O2 Eu1 136.8(3) . . ?
C16 O3 Eu1 138.6(3) . . ?
C24 O4 Eu1 136.3(3) . . ?
C31 O5 Eu1 134.1(3) . . ?
C39 O6 Eu1 134.8(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 24.5(6) . . . . ?
C8 C1 C2 C3 -154.2(4) . . . . ?
O1 C1 C2 C7 -154.5(4) . . . . ?
C8 C1 C2 C7 26.8(6) . . . . ?
C7 C2 C3 C4 -1.7(7) . . . . ?
C1 C2 C3 C4 179.3(5) . . . . ?
C2 C3 C4 C5 1.9(8) . . . . ?
C3 C4 C5 C6 -0.6(9) . . . . ?
C4 C5 C6 C7 -0.8(8) . . . . ?
C5 C6 C7 C2 0.9(7) . . . . ?
C3 C2 C7 C6 0.2(7) . . . . ?
C1 C2 C7 C6 179.3(4) . . . . ?
O1 C1 C8 C9 0.2(7) . . . . ?
C2 C1 C8 C9 178.9(4) . . . . ?
C1 C8 C9 O2 -2.2(7) . . . . ?
C1 C8 C9 C10 178.7(4) . . . . ?
O2 C9 C10 C11 151.4(4) . . . . ?
C8 C9 C10 C11 -29.4(7) . . . . ?
O2 C9 C10 C15 -27.7(6) . . . . ?
C8 C9 C10 C15 151.5(5) . . . . ?
C15 C10 C11 C12 -3.0(8) . . . . ?
C9 C10 C11 C12 177.9(5) . . . . ?
C10 C11 C12 C13 1.4(9) . . . . ?
C11 C12 C13 C14 1.2(10) . . . . ?
C12 C13 C14 C15 -2.0(10) . . . . ?
C11 C10 C15 C14 2.2(8) . . . . ?
C9 C10 C15 C14 -178.7(5) . . . . ?
C13 C14 C15 C10 0.3(10) . . . . ?
O3 C16 C17 C22 -176.4(5) . . . . ?
C23 C16 C17 C22 2.7(8) . . . . ?
O3 C16 C17 C18 5.6(6) . . . . ?
C23 C16 C17 C18 -175.4(5) . . . . ?
C22 C17 C18 C19 -0.1(9) . . . . ?
C16 C17 C18 C19 178.1(5) . . . . ?
C17 C18 C19 C20 0.7(10) . . . . ?
C18 C19 C20 C21 -0.6(12) . . . . ?
C19 C20 C21 C22 -0.1(12) . . . . ?
C18 C17 C22 C21 -0.6(9) . . . . ?
C16 C17 C22 C21 -178.7(6) . . . . ?
C20 C21 C22 C17 0.7(12) . . . . ?
O3 C16 C23 C24 -6.3(7) . . . . ?
C17 C16 C23 C24 174.7(4) . . . . ?
C16 C23 C24 O4 -0.9(7) . . . . ?
C16 C23 C24 C25 176.6(4) . . . . ?
O4 C24 C25 C26 16.8(6) . . . . ?
C23 C24 C25 C26 -161.0(4) . . . . ?
O4 C24 C25 C30 -162.9(4) . . . . ?
C23 C24 C25 C30 19.4(7) . . . . ?
C30 C25 C26 C27 1.0(7) . . . . ?
C24 C25 C26 C27 -178.7(5) . . . . ?
C25 C26 C27 C28 0.8(10) . . . . ?
C26 C27 C28 C29 -1.9(12) . . . . ?
C27 C28 C29 C30 1.3(12) . . . . ?
C28 C29 C30 C25 0.6(11) . . . . ?
C26 C25 C30 C29 -1.6(8) . . . . ?
C24 C25 C30 C29 178.0(5) . . . . ?
O5 C31 C32 C37 -156.2(5) . . . . ?
C38 C31 C32 C37 24.3(8) . . . . ?
O5 C31 C32 C33 24.0(7) . . . . ?
C38 C31 C32 C33 -155.5(5) . . . . ?
C37 C32 C33 C34 -0.8(8) . . . . ?
C31 C32 C33 C34 179.0(5) . . . . ?
C32 C33 C34 C35 0.7(9) . . . . ?
C33 C34 C35 C36 0.2(11) . . . . ?
C34 C35 C36 C37 -1.0(11) . . . . ?
C33 C32 C37 C36 0.1(8) . . . . ?
C31 C32 C37 C36 -179.7(5) . . . . ?
C35 C36 C37 C32 0.8(10) . . . . ?
O5 C31 C38 C39 2.4(8) . . . . ?
C32 C31 C38 C39 -178.2(5) . . . . ?
C31 C38 C39 O6 -2.4(8) . . . . ?
C31 C38 C39 C40 177.5(5) . . . . ?
O6 C39 C40 C45 -22.7(7) . . . . ?
C38 C39 C40 C45 157.4(5) . . . . ?
O6 C39 C40 C41 154.0(5) . . . . ?
C38 C39 C40 C41 -25.9(8) . . . . ?
C45 C40 C41 C42 -1.0(9) . . . . ?
C39 C40 C41 C42 -177.8(5) . . . . ?
C40 C41 C42 C43 1.1(11) . . . . ?
C41 C42 C43 C44 -1.1(12) . . . . ?
C42 C43 C44 C45 1.1(11) . . . . ?
C41 C40 C45 C44 1.0(8) . . . . ?
C39 C40 C45 C44 177.9(5) . . . . ?
C43 C44 C45 C40 -1.0(9) . . . . ?
N1 C46 C47 N2 -0.7(6) . . . . ?
N1 C48 C49 N3 -3.7(6) . . . . ?
N2 C48 C49 N3 176.0(4) . . . . ?
N1 C48 C49 C50 176.1(4) . . . . ?
N2 C48 C49 C50 -4.2(7) . . . . ?
N3 C49 C50 C51 0.3(7) . . . . ?
C48 C49 C50 C51 -179.5(5) . . . . ?
C49 C50 C51 C52 -1.6(9) . . . . ?
C50 C51 C52 C53 2.2(9) . . . . ?
C51 C52 C53 N3 -1.4(9) . . . . ?
N2 C48 N1 C46 -0.5(5) . . . . ?
C49 C48 N1 C46 179.3(4) . . . . ?
N2 C48 N1 Eu1 176.7(3) . . . . ?
C49 C48 N1 Eu1 -3.5(5) . . . . ?
C47 C46 N1 C48 0.7(6) . . . . ?
C47 C46 N1 Eu1 -175.9(3) . . . . ?
N1 C48 N2 C47 0.1(5) . . . . ?
C49 C48 N2 C47 -179.7(4) . . . . ?
C46 C47 N2 C48 0.4(6) . . . . ?
C52 C53 N3 C49 0.1(7) . . . . ?
C52 C53 N3 Eu1 171.3(4) . . . . ?
C50 C49 N3 C53 0.5(7) . . . . ?
C48 C49 N3 C53 -179.7(4) . . . . ?
C50 C49 N3 Eu1 -170.9(3) . . . . ?
C48 C49 N3 Eu1 8.9(5) . . . . ?
C8 C1 O1 Eu1 12.6(7) . . . . ?
C2 C1 O1 Eu1 -166.0(3) . . . . ?
C8 C9 O2 Eu1 -8.6(7) . . . . ?
C10 C9 O2 Eu1 170.6(3) . . . . ?
C23 C16 O3 Eu1 -3.3(8) . . . . ?
C17 C16 O3 Eu1 175.8(3) . . . . ?
C23 C24 O4 Eu1 18.3(7) . . . . ?
C25 C24 O4 Eu1 -159.4(3) . . . . ?
C38 C31 O5 Eu1 24.4(7) . . . . ?
C32 C31 O5 Eu1 -155.1(3) . . . . ?
C38 C39 O6 Eu1 -25.2(7) . . . . ?
C40 C39 O6 Eu1 154.9(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C50 H50 O5 0.93 2.66 3.372(5) 134.4 4_576
C53 H53 O4 0.93 2.65 3.286(6) 125.7 .
N2 H2 O6 0.83(4) 2.27(4) 2.976(5) 144(4) 4_576
C50 H50 O5 0.93 2.66 3.372(5) 134.4 4_576
C53 H53 O4 0.93 2.65 3.286(6) 125.7 .
N2 H2 O6 0.83(4) 2.27(4) 2.976(5) 144(4) 4_576

_refine_diff_density_max         0.623
_refine_diff_density_min         -2.075
_refine_diff_density_rms         0.085



