# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1869846'
_audit_update_record             
;
2018-09-26 deposited with the CCDC.
2018-11-09 downloaded from the CCDC.
;
_audit_creation_date             2017-01-18
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.11.07 svn.r3352 for OlexSys, GUI svn.r5261)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C86 H72 Ag12 Cr2 F12 N6 O15 S6'
_chemical_formula_sum            'C86 H72 Ag12 Cr2 F12 N6 O15 S6'
_chemical_formula_weight         3248.29
_chemical_melting_point          ?
_chemical_oxdiff_formula         C1H1O1N1S1Cr1F1Ag1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.5753(3)
_cell_length_b                   16.3742(8)
_cell_length_c                   17.2297(9)
_cell_angle_alpha                66.079(5)
_cell_angle_beta                 72.957(4)
_cell_angle_gamma                82.717(3)
_cell_volume                     2607.4(2)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    2753
_cell_measurement_temperature    293
_cell_measurement_theta_max      21.7890
_cell_measurement_theta_min      3.3960
_shelx_estimated_absorpt_T_max   0.712
_shelx_estimated_absorpt_T_min   0.652
_exptl_absorpt_coefficient_mu    2.598
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.99097
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    2.069
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1566
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0477
_diffrn_reflns_av_unetI/netI     0.1035
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17105
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.027
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_min         2.895
_diffrn_ambient_temperature      293
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -23.00   25.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  -99.0000 -150.0000 48

#__ type_ start__ end____ width___ exp.time_
  2 omega  -11.00   26.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323 -101.0000   -4.0000 37

#__ type_ start__ end____ width___ exp.time_
  3 omega   45.00   89.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104   57.0000 -120.0000 44

#__ type_ start__ end____ width___ exp.time_
  4 omega    2.00   41.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  -37.0000  -30.0000 39

#__ type_ start__ end____ width___ exp.time_
  5 omega  -49.00   33.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  -57.0000   90.0000 82

#__ type_ start__ end____ width___ exp.time_
  6 omega   14.00   90.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104   37.0000 -150.0000 76

#__ type_ start__ end____ width___ exp.time_
  7 omega   32.00   96.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104 -178.0000   60.0000 64
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0152162000
_diffrn_orient_matrix_UB_12      0.0423642000
_diffrn_orient_matrix_UB_13      -0.0299142000
_diffrn_orient_matrix_UB_21      0.0122078000
_diffrn_orient_matrix_UB_22      -0.0173446000
_diffrn_orient_matrix_UB_23      -0.0331735000
_diffrn_orient_matrix_UB_31      -0.0673883000
_diffrn_orient_matrix_UB_32      -0.0122604000
_diffrn_orient_matrix_UB_33      0.0137111000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4711
_reflns_number_total             9217
_reflns_odcompleteness_completeness 86.23
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_refine_diff_density_max         1.459
_refine_diff_density_min         -0.955
_refine_diff_density_rms         0.117
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.945
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     797
_refine_ls_number_reflns         9217
_refine_ls_number_restraints     297
_refine_ls_R_factor_all          0.1410
_refine_ls_R_factor_gt           0.0594
_refine_ls_restrained_S_all      0.940
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0422P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1013
_refine_ls_wR_factor_ref         0.1236
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 F2B-C37B \\sim F3B-C37B \\sim F1A-C37A \\sim F1B-C37B \\sim F2A-C37A \\sim
F3A-C37A
 with sigma of 0.01
 C37A-C36A \\sim C37B-C36B
 with sigma of 0.01
 F4A-C35 \\sim F6B-C35 \\sim F5A-C35 \\sim F5B-C35 \\sim F6A-C35 \\sim F4B-C35
 with sigma of 0.01
 C18B-C17B \\sim C17B-C16B \\sim C21B-C16B \\sim C21B-C20B \\sim C20B-C19B
\\sim C19B-C18B
 with sigma of 0.01
 C13B-C12 \\sim C13A-C12
 with sigma of 0.01
 C22B-C13B \\sim C14B-C13B \\sim C15B-C14B \\sim C16B-C15B \\sim C21B-C16B
\\sim C22B-C21B
 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C14B) \\sim Ueq, Uanis(C13B) \\sim Ueq, Uanis(C13A) \\sim Ueq,
Uanis(C22A) \\sim Ueq, Uanis(C22B) \\sim Ueq, Uanis(C14A) \\sim Ueq,
Uanis(C15A) \\sim Ueq, Uanis(C20A) \\sim Ueq, Uanis(C21A) \\sim Ueq,
Uanis(C20B) \\sim Ueq, Uanis(C19A) \\sim Ueq, Uanis(C19B) \\sim Ueq,
Uanis(C18B) \\sim Ueq, Uanis(C18A) \\sim Ueq, Uanis(C17A) \\sim Ueq,
Uanis(C17B) \\sim Ueq, Uanis(C16A) \\sim Ueq, Uanis(C16B) \\sim Ueq,
Uanis(C15B) \\sim Ueq, Uanis(C21B) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(F4A) \\sim Ueq, Uanis(F6B) \\sim Ueq, Uanis(F5A) \\sim Ueq, Uanis(F5B)
\\sim Ueq, Uanis(F6A) \\sim Ueq, Uanis(F4B) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(C36A) \\sim Ueq, Uanis(C36B) \\sim Ueq, Uanis(C37B) \\sim Ueq, Uanis(F1B)
\\sim Ueq, Uanis(F2A) \\sim Ueq, Uanis(F2B) \\sim Ueq, Uanis(F3A) \\sim Ueq,
Uanis(F1A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C41) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4. Others
 Sof(C36B)=Sof(C37B)=Sof(F3B)=Sof(F2B)=Sof(F1B)=Sof(F4B)=Sof(F5B)=Sof(F6B)=1-
 FVAR(1)
 Sof(F1A)=Sof(F2A)=Sof(F3A)=Sof(C36A)=Sof(C37A)=Sof(F4A)=Sof(F5A)=Sof(F6A)=
 FVAR(1)
 Fixed Sof: H12A(0.5) H12B(0.5) H12C(0.5) H12D(0.5) C13A(0.5) C13B(0.5)
 C14A(0.5) H14A(0.5) C15A(0.5) C16A(0.5) H16A(0.5) C17A(0.5) H17A(0.5)
 C18A(0.5) H18A(0.5) C19A(0.5) H19A(0.5) C20A(0.5) C21A(0.5) H21A(0.5)
 C22A(0.5) H22A(0.5) C14B(0.5) H14B(0.5) C15B(0.5) H15B(0.5) C16B(0.5)
 C17B(0.5) H17B(0.5) C18B(0.5) H18B(0.5) C19B(0.5) H19B(0.5) C21B(0.5)
 C20B(0.5) H20B(0.5) C22B(0.5) H22B(0.5) O8(0.5)
5.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C12(H12A,H12B), C12(H12C,H12D), C23(H23A,H23B)
5.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C6(H6), C7(H7), C8(H8), C9(H9), C11(H11), C25(H25), C27(H27),
 C28(H28), C29(H29), C30(H30), C32(H32), C33(H33), C14A(H14A), C16A(H16A),
 C17A(H17A), C18A(H18A), C19A(H19A), C21A(H21A), C22A(H22A), C14B(H14B),
 C15B(H15B), C17B(H17B), C18B(H18B), C19B(H19B), C20B(H20B), C22B(H22B)
5.c Idealised Me refined as rotating group:
 C39(H39A,H39B,H39C), C41(H41A,H41B,H41C), C43(H43A,H43B,H43C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.31306(7) 0.67094(6) -0.03321(5) 0.0694(3) Uani 1 1 d . . . . .
Ag2 Ag 0.26711(7) 0.47420(6) 0.16056(5) 0.0651(2) Uani 1 1 d . . . . .
Ag3 Ag 0.58483(7) 0.69599(6) -0.24969(6) 0.0797(3) Uani 1 1 d . . . . .
Ag4 Ag 0.55871(7) 0.72030(7) -0.00490(7) 0.0876(3) Uani 1 1 d . . . . .
Ag5 Ag 0.31191(6) 0.47554(5) -0.01778(4) 0.0552(2) Uani 1 1 d . . . . .
Ag6 Ag 0.47756(9) 0.47685(8) -0.19166(6) 0.1008(4) Uani 1 1 d . . . . .
Cr1 Cr -0.01623(13) 0.56290(11) 0.06037(9) 0.0518(4) Uani 1 1 d . . . . .
S8 S 0.37110(18) 0.61008(16) -0.15020(14) 0.0472(6) Uani 1 1 d . . . . .
S9 S 0.30490(19) 0.34338(16) 0.11523(15) 0.0487(6) Uani 1 1 d . . . . .
S10 S 0.3675(2) 0.62115(17) 0.11400(16) 0.0562(7) Uani 1 1 d . . . . .
O1 O 0.0350(6) 0.5070(6) 0.1453(5) 0.105(3) Uani 1 1 d . . . . .
O2 O -0.1677(6) 0.5846(6) 0.0908(5) 0.111(3) Uani 1 1 d . . . . .
O3 O 0.0658(5) 0.6526(5) -0.0016(5) 0.077(2) Uani 1 1 d . . . . .
O4 O 0.2497(8) 0.8166(5) -0.0479(6) 0.100(3) Uani 1 1 d . . . . .
O5 O 0.4400(8) 0.8571(5) -0.0466(6) 0.104(3) Uani 1 1 d . . . . .
O6 O 0.1494(7) 0.4318(6) 0.3110(5) 0.107(3) Uani 1 1 d . . . . .
O7 O 0.2889(7) 0.3309(6) 0.3720(5) 0.107(3) Uani 1 1 d . . . . .
N1 N 0.7041(9) 0.7762(7) 0.0378(7) 0.099(3) Uani 1 1 d . . . . .
N2 N 0.3647(10) 0.4734(8) -0.2811(7) 0.099(4) Uani 1 1 d . . . . .
N3 N 0.5509(8) 0.8438(7) -0.2836(7) 0.086(3) Uani 1 1 d . . . . .
C1 C 0.1383(7) 0.2947(6) 0.1523(7) 0.065(3) Uani 1 1 d . . . . .
H1A H 0.073429 0.331637 0.176367 0.078 Uiso 1 1 calc R . . . .
H1B H 0.115145 0.292871 0.102571 0.078 Uiso 1 1 calc R . . . .
C2 C 0.1368(7) 0.2029(7) 0.2205(6) 0.051(3) Uani 1 1 d . . . . .
C3 C 0.1117(8) 0.1905(8) 0.3093(8) 0.068(3) Uani 1 1 d . . . . .
H3 H 0.092681 0.240442 0.323737 0.082 Uiso 1 1 calc R . . . .
C4 C 0.1138(8) 0.1087(10) 0.3753(7) 0.078(4) Uani 1 1 d . . . . .
H4 H 0.097303 0.103196 0.433239 0.093 Uiso 1 1 calc R . . . .
C5 C 0.1416(8) 0.0323(8) 0.3541(8) 0.064(3) Uani 1 1 d . . . . .
C6 C 0.1435(10) -0.0552(11) 0.4212(9) 0.100(5) Uani 1 1 d . . . . .
H6 H 0.127967 -0.062285 0.479567 0.120 Uiso 1 1 calc R . . . .
C7 C 0.1672(13) -0.1254(11) 0.4000(13) 0.115(6) Uani 1 1 d . . . . .
H7 H 0.169276 -0.181603 0.444326 0.138 Uiso 1 1 calc R . . . .
C8 C 0.1891(11) -0.1190(10) 0.3150(13) 0.109(5) Uani 1 1 d . . . . .
H8 H 0.203940 -0.169732 0.301873 0.130 Uiso 1 1 calc R . . . .
C9 C 0.1885(9) -0.0354(9) 0.2503(9) 0.086(4) Uani 1 1 d . . . . .
H9 H 0.204254 -0.030475 0.192529 0.103 Uiso 1 1 calc R . . . .
C10 C 0.1652(8) 0.0426(7) 0.2668(8) 0.059(3) Uani 1 1 d . . . . .
C11 C 0.1647(8) 0.1285(7) 0.2010(7) 0.060(3) Uani 1 1 d . . . . .
H11 H 0.183730 0.134855 0.142650 0.072 Uiso 1 1 calc R . . . .
C12 C 0.2647(9) 0.6812(7) 0.1806(7) 0.075(3) Uani 1 1 d D . . . .
H12A H 0.259647 0.743762 0.142921 0.090 Uiso 0.5 1 calc R . P A 1
H12B H 0.175814 0.657484 0.204238 0.090 Uiso 0.5 1 calc R . P A 1
H12C H 0.234550 0.737284 0.142110 0.090 Uiso 0.5 1 calc R . P B 2
H12D H 0.187485 0.645840 0.220171 0.090 Uiso 0.5 1 calc R . P B 2
C23 C 0.2290(7) 0.6472(6) -0.1994(6) 0.053(2) Uani 1 1 d . . . . .
H23A H 0.219678 0.607764 -0.226791 0.063 Uiso 1 1 calc R . . . .
H23B H 0.148171 0.644840 -0.153732 0.063 Uiso 1 1 calc R . . . .
C24 C 0.2514(8) 0.7412(7) -0.2672(6) 0.048(2) Uani 1 1 d . . . . .
C25 C 0.1996(8) 0.8124(7) -0.2469(6) 0.053(3) Uani 1 1 d . . . . .
H25 H 0.149430 0.803206 -0.189791 0.064 Uiso 1 1 calc R . . . .
C26 C 0.2210(8) 0.9017(7) -0.3120(8) 0.059(3) Uani 1 1 d . . . . .
C27 C 0.1635(9) 0.9749(8) -0.2932(9) 0.079(3) Uani 1 1 d . . . . .
H27 H 0.110970 0.965803 -0.236722 0.095 Uiso 1 1 calc R . . . .
C28 C 0.1820(12) 1.0596(9) -0.3553(12) 0.097(4) Uani 1 1 d . . . . .
H28 H 0.142887 1.107494 -0.340702 0.116 Uiso 1 1 calc R . . . .
C29 C 0.2588(16) 1.0748(11) -0.4400(11) 0.114(6) Uani 1 1 d . . . . .
H29 H 0.268538 1.132571 -0.482936 0.136 Uiso 1 1 calc R . . . .
C30 C 0.3201(13) 1.0049(10) -0.4605(9) 0.103(5) Uani 1 1 d . . . . .
H30 H 0.375575 1.015494 -0.516566 0.124 Uiso 1 1 calc R . . . .
C31 C 0.2993(10) 0.9152(9) -0.3961(7) 0.070(3) Uani 1 1 d . . . . .
C32 C 0.3520(11) 0.8406(9) -0.4158(7) 0.081(4) Uani 1 1 d . . . . .
H32 H 0.402589 0.848735 -0.472465 0.097 Uiso 1 1 calc R . . . .
C33 C 0.3302(9) 0.7579(8) -0.3535(7) 0.070(3) Uani 1 1 d . . . . .
H33 H 0.368492 0.709715 -0.367838 0.084 Uiso 1 1 calc R . . . .
C34 C 0.3243(12) 0.8654(8) -0.0471(7) 0.068(3) Uani 1 1 d . . . . .
C35 C 0.2577(12) 0.9535(10) -0.0422(7) 0.108(5) Uani 1 1 d D . . . .
C38 C 0.2799(13) 0.4650(9) -0.2999(7) 0.087(4) Uani 1 1 d . . . . .
C39 C 0.1635(12) 0.4495(12) -0.3235(8) 0.151(7) Uani 1 1 d . . . . .
H39A H 0.182210 0.470189 -0.386390 0.226 Uiso 1 1 calc GR . . . .
H39B H 0.088330 0.481380 -0.301990 0.226 Uiso 1 1 calc GR . . . .
H39C H 0.144699 0.386729 -0.297399 0.226 Uiso 1 1 calc GR . . . .
C40 C 0.7960(13) 0.7900(8) 0.0518(9) 0.091(4) Uani 1 1 d . . . . .
C41 C 0.9133(12) 0.8058(10) 0.0722(11) 0.150(6) Uani 1 1 d . U . . .
H41A H 0.962324 0.854678 0.023240 0.224 Uiso 1 1 calc GR . . . .
H41B H 0.968002 0.753062 0.083291 0.224 Uiso 1 1 calc GR . . . .
H41C H 0.886683 0.820199 0.123530 0.224 Uiso 1 1 calc GR . . . .
C42 C 0.5286(10) 0.9109(10) -0.2830(8) 0.070(3) Uani 1 1 d . . . . .
C43 C 0.5016(10) 1.0004(8) -0.2850(8) 0.096(4) Uani 1 1 d . . . . .
H43A H 0.575183 1.038053 -0.324621 0.144 Uiso 1 1 calc GR . . . .
H43B H 0.488009 0.999124 -0.226956 0.144 Uiso 1 1 calc GR . . . .
H43C H 0.423505 1.023352 -0.304796 0.144 Uiso 1 1 calc GR . . . .
C13A C 0.317(3) 0.674(2) 0.2549(17) 0.068(9) Uani 0.5 1 d D U P C 1
F1A F -0.025(3) 0.335(2) 0.460(2) 0.144(12) Uani 0.46(2) 1 d D U P D 1
F2A F 0.133(3) 0.306(2) 0.5280(14) 0.111(9) Uani 0.46(2) 1 d D U P D 1
F3A F 0.062(3) 0.4324(18) 0.472(2) 0.136(11) Uani 0.46(2) 1 d D U P D 1
C36A C 0.203(4) 0.389(3) 0.370(2) 0.056(12) Uani 0.46(2) 1 d D U P D 1
C37A C 0.089(3) 0.3577(16) 0.4599(18) 0.10(2) Uani 0.46(2) 1 d D . P D 1
F4A F 0.151(2) 0.942(3) 0.0246(17) 0.146(13) Uani 0.46(2) 1 d D U P D 1
F5A F 0.330(3) 0.993(2) -0.017(3) 0.173(12) Uani 0.46(2) 1 d D U P D 1
F6A F 0.242(3) 1.0124(16) -0.1182(11) 0.139(10) Uani 0.46(2) 1 d D U P D 1
C13B C 0.339(2) 0.6995(15) 0.2331(12) 0.048(8) Uani 0.5 1 d D U P C 2
C36B C 0.186(3) 0.368(2) 0.373(2) 0.059(10) Uani 0.54(2) 1 d D U P D 2
C37B C 0.101(3) 0.3632(14) 0.4675(18) 0.080(14) Uani 0.54(2) 1 d D U P D 2
F3B F -0.018(3) 0.393(3) 0.4664(14) 0.163(16) Uani 0.54(2) 1 d D . P D 2
F2B F 0.146(3) 0.4109(18) 0.4987(12) 0.143(8) Uani 0.54(2) 1 d D U P D 2
F1B F 0.085(3) 0.2786(15) 0.5186(18) 0.135(10) Uani 0.54(2) 1 d D U P D 2
F4B F 0.150(2) 0.9744(14) -0.0712(18) 0.137(8) Uani 0.54(2) 1 d D U P D 2
F5B F 0.3429(19) 1.0199(11) -0.079(2) 0.145(9) Uani 0.54(2) 1 d D U P D 2
F6B F 0.209(3) 0.945(2) 0.0405(10) 0.148(11) Uani 0.54(2) 1 d D U P D 2
C14A C 0.418(2) 0.7292(16) 0.2363(15) 0.059(6) Uani 0.5 1 d . U P C 1
H14A H 0.452842 0.771218 0.179895 0.071 Uiso 0.5 1 calc R . P C 1
C15A C 0.468(3) 0.718(2) 0.3081(17) 0.065(8) Uani 0.5 1 d . U P C 1
C16A C 0.573(3) 0.771(2) 0.2947(19) 0.095(9) Uani 0.5 1 d . U P C 1
H16A H 0.610805 0.815112 0.240091 0.114 Uiso 0.5 1 calc R . P C 1
C17A C 0.618(3) 0.753(3) 0.371(2) 0.088(11) Uani 0.5 1 d . U P C 1
H17A H 0.685457 0.787231 0.367105 0.105 Uiso 0.5 1 calc R . P C 1
C18A C 0.562(6) 0.688(4) 0.450(3) 0.12(2) Uani 0.5 1 d . U P C 1
H18A H 0.599444 0.678310 0.495472 0.143 Uiso 0.5 1 calc R . P C 1
C19A C 0.462(4) 0.636(3) 0.469(3) 0.107(11) Uani 0.5 1 d . U P C 1
H19A H 0.422126 0.596424 0.525260 0.129 Uiso 0.5 1 calc R . P C 1
C20A C 0.420(4) 0.648(3) 0.392(3) 0.087(11) Uani 0.5 1 d . U P C 1
C21A C 0.314(2) 0.5969(18) 0.4028(17) 0.096(8) Uani 0.5 1 d . U P C 1
H21A H 0.276261 0.553727 0.457851 0.115 Uiso 0.5 1 calc R . P C 1
C22A C 0.268(2) 0.6105(16) 0.3333(14) 0.070(6) Uani 0.5 1 d . U P C 1
H22A H 0.200907 0.574554 0.340493 0.084 Uiso 0.5 1 calc R . P C 1
C14B C 0.4247(19) 0.7715(14) 0.1905(15) 0.069(7) Uani 0.5 1 d D U P C 2
H14B H 0.428092 0.808041 0.132190 0.083 Uiso 0.5 1 calc R . P C 2
C15B C 0.5051(19) 0.7915(15) 0.2310(12) 0.079(6) Uani 0.5 1 d D U P C 2
H15B H 0.561737 0.840060 0.199640 0.095 Uiso 0.5 1 calc R . P C 2
C16B C 0.501(3) 0.7391(17) 0.3183(12) 0.063(9) Uani 0.5 1 d D U P C 2
C17B C 0.580(3) 0.762(2) 0.358(2) 0.084(12) Uani 0.5 1 d D U P C 2
H17B H 0.635099 0.811143 0.327691 0.101 Uiso 0.5 1 calc R . P C 2
C18B C 0.575(5) 0.707(2) 0.445(2) 0.083(15) Uani 0.5 1 d D U P C 2
H18B H 0.621295 0.723671 0.475109 0.100 Uiso 0.5 1 calc R . P C 2
C19B C 0.502(3) 0.629(2) 0.489(2) 0.114(14) Uani 0.5 1 d D U P C 2
H19B H 0.510479 0.588808 0.543867 0.136 Uiso 0.5 1 calc R . P C 2
C21B C 0.415(3) 0.6675(18) 0.3645(17) 0.053(9) Uani 0.5 1 d D U P C 2
C20B C 0.418(3) 0.611(2) 0.4497(18) 0.106(11) Uani 0.5 1 d D U P C 2
H20B H 0.363429 0.560982 0.480215 0.127 Uiso 0.5 1 calc R . P C 2
C22B C 0.339(2) 0.6484(18) 0.3200(13) 0.082(8) Uani 0.5 1 d D U P C 2
H22B H 0.285321 0.598385 0.350404 0.098 Uiso 0.5 1 calc R . P C 2
O8 O 0.0488(12) 0.4890(11) 0.0052(11) 0.084(5) Uani 0.5 1 d . . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag4 3.0388(11) . ?
Ag1 Ag5 3.1026(12) . ?
Ag1 S8 2.486(2) . ?
Ag1 S10 2.547(2) . ?
Ag1 O3 2.540(5) . ?
Ag1 O4 2.325(8) . ?
Ag2 Ag3 3.0674(11) 2_665 ?
Ag2 Ag5 2.9598(10) . ?
Ag2 Ag6 3.1568(12) 2_665 ?
Ag2 S9 2.513(3) . ?
Ag2 S10 2.479(3) . ?
Ag2 O1 2.512(6) . ?
Ag2 O6 2.371(7) . ?
Ag3 S8 2.570(2) . ?
Ag3 S9 2.706(2) 2_665 ?
Ag3 O7 2.318(7) 2_665 ?
Ag3 N3 2.255(11) . ?
Ag4 Ag5 3.2392(12) 2_665 ?
Ag4 S9 2.530(2) 2_665 ?
Ag4 S10 2.575(3) . ?
Ag4 O5 2.370(7) . ?
Ag4 N1 2.304(10) . ?
Ag5 Ag6 2.9876(11) . ?
Ag5 S8 2.426(2) . ?
Ag5 S9 2.421(2) . ?
Ag6 S8 2.590(3) . ?
Ag6 S10 2.435(2) 2_665 ?
Ag6 N2 2.229(9) . ?
Cr1 O1 1.589(6) . ?
Cr1 O2 1.575(6) . ?
Cr1 O3 1.599(7) . ?
Cr1 O8 1.789(14) 2_565 ?
Cr1 O8 1.783(14) . ?
S8 C23 1.856(7) . ?
S9 C1 1.852(8) . ?
S10 C12 1.838(9) . ?
O4 C34 1.198(12) . ?
O5 C34 1.217(12) . ?
O6 C36A 1.23(5) . ?
O6 C36B 1.27(4) . ?
O7 C36A 1.22(4) . ?
O7 C36B 1.18(4) . ?
N1 C40 1.137(12) . ?
N2 C38 1.079(13) . ?
N3 C42 1.099(14) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C2 1.483(12) . ?
C2 C3 1.406(13) . ?
C2 C11 1.367(12) . ?
C3 H3 0.9300 . ?
C3 C4 1.364(13) . ?
C4 H4 0.9300 . ?
C4 C5 1.413(14) . ?
C5 C6 1.432(15) . ?
C5 C10 1.391(14) . ?
C6 H6 0.9300 . ?
C6 C7 1.316(18) . ?
C7 H7 0.9300 . ?
C7 C8 1.376(19) . ?
C8 H8 0.9300 . ?
C8 C9 1.372(16) . ?
C9 H9 0.9300 . ?
C9 C10 1.395(14) . ?
C10 C11 1.405(13) . ?
C11 H11 0.9300 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
C12 H12D 0.9700 . ?
C12 C13A 1.493(15) . ?
C12 C13B 1.492(15) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 C24 1.503(12) . ?
C24 C25 1.357(12) . ?
C24 C33 1.409(12) . ?
C25 H25 0.9300 . ?
C25 C26 1.432(12) . ?
C26 C27 1.388(13) . ?
C26 C31 1.385(13) . ?
C27 H27 0.9300 . ?
C27 C28 1.360(15) . ?
C28 H28 0.9300 . ?
C28 C29 1.384(17) . ?
C29 H29 0.9300 . ?
C29 C30 1.364(18) . ?
C30 H30 0.9300 . ?
C30 C31 1.433(16) . ?
C31 C32 1.403(14) . ?
C32 H32 0.9300 . ?
C32 C33 1.340(14) . ?
C33 H33 0.9300 . ?
C34 C35 1.546(17) . ?
C35 F4A 1.321(10) . ?
C35 F5A 1.326(10) . ?
C35 F6A 1.316(10) . ?
C35 F4B 1.324(9) . ?
C35 F5B 1.322(9) . ?
C35 F6B 1.321(10) . ?
C38 C39 1.485(17) . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 C41 1.464(15) . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 C43 1.444(15) . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C13A C14A 1.37(3) . ?
C13A C22A 1.33(3) . ?
F1A C37A 1.306(10) . ?
F2A C37A 1.308(10) . ?
F3A C37A 1.304(10) . ?
C36A C37A 1.586(19) . ?
C13B C14B 1.387(10) . ?
C13B C22B 1.388(10) . ?
C36B C37B 1.585(19) . ?
C37B F3B 1.303(10) . ?
C37B F2B 1.304(10) . ?
C37B F1B 1.306(10) . ?
C14A H14A 0.9300 . ?
C14A C15A 1.42(3) . ?
C15A C16A 1.40(4) . ?
C15A C20A 1.42(4) . ?
C16A H16A 0.9300 . ?
C16A C17A 1.44(4) . ?
C17A H17A 0.9300 . ?
C17A C18A 1.35(4) . ?
C18A H18A 0.9300 . ?
C18A C19A 1.33(5) . ?
C19A H19A 0.9300 . ?
C19A C20A 1.45(5) . ?
C20A C21A 1.40(4) . ?
C21A H21A 0.9300 . ?
C21A C22A 1.35(3) . ?
C22A H22A 0.9300 . ?
C14B H14B 0.9300 . ?
C14B C15B 1.386(10) . ?
C15B H15B 0.9300 . ?
C15B C16B 1.389(10) . ?
C16B C17B 1.390(10) . ?
C16B C21B 1.390(10) . ?
C17B H17B 0.9300 . ?
C17B C18B 1.387(10) . ?
C18B H18B 0.9300 . ?
C18B C19B 1.391(10) . ?
C19B H19B 0.9300 . ?
C19B C20B 1.390(10) . ?
C21B C20B 1.390(10) . ?
C21B C22B 1.393(10) . ?
C20B H20B 0.9300 . ?
C22B H22B 0.9300 . ?
O8 O8 1.09(2) 2_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4 Ag1 Ag5 114.35(3) . . ?
S8 Ag1 Ag4 111.46(5) . . ?
S8 Ag1 Ag5 49.98(6) . . ?
S8 Ag1 S10 133.07(8) . . ?
S8 Ag1 O3 93.89(16) . . ?
S10 Ag1 Ag4 54.02(6) . . ?
S10 Ag1 Ag5 92.17(7) . . ?
O3 Ag1 Ag4 154.63(16) . . ?
O3 Ag1 Ag5 80.85(16) . . ?
O3 Ag1 S10 107.73(17) . . ?
O4 Ag1 Ag4 82.8(2) . . ?
O4 Ag1 Ag5 162.7(2) . . ?
O4 Ag1 S8 127.3(2) . . ?
O4 Ag1 S10 97.1(2) . . ?
O4 Ag1 O3 82.4(3) . . ?
Ag3 Ag2 Ag6 69.59(3) 2_665 2_665 ?
Ag5 Ag2 Ag3 102.16(3) . 2_665 ?
Ag5 Ag2 Ag6 112.96(3) . 2_665 ?
S9 Ag2 Ag3 56.99(5) . 2_665 ?
S9 Ag2 Ag5 51.72(6) . . ?
S9 Ag2 Ag6 112.40(5) . 2_665 ?
S10 Ag2 Ag3 118.76(6) . 2_665 ?
S10 Ag2 Ag5 97.08(6) . . ?
S10 Ag2 Ag6 49.41(5) . 2_665 ?
S10 Ag2 S9 138.60(8) . . ?
S10 Ag2 O1 106.0(2) . . ?
O1 Ag2 Ag3 134.1(2) . 2_665 ?
O1 Ag2 Ag5 80.83(18) . . ?
O1 Ag2 Ag6 151.4(2) . 2_665 ?
O1 Ag2 S9 95.8(2) . . ?
O6 Ag2 Ag3 77.79(19) . 2_665 ?
O6 Ag2 Ag5 152.9(2) . . ?
O6 Ag2 Ag6 92.6(2) . 2_665 ?
O6 Ag2 S9 111.4(2) . . ?
O6 Ag2 S10 106.7(2) . . ?
O6 Ag2 O1 80.3(3) . . ?
S8 Ag3 Ag2 86.44(5) . 2_665 ?
S8 Ag3 S9 94.11(7) . 2_665 ?
S9 Ag3 Ag2 51.13(5) 2_665 2_665 ?
O7 Ag3 Ag2 79.77(19) 2_665 2_665 ?
O7 Ag3 S8 122.1(2) 2_665 . ?
O7 Ag3 S9 117.45(18) 2_665 2_665 ?
N3 Ag3 Ag2 147.9(2) . 2_665 ?
N3 Ag3 S8 110.2(2) . . ?
N3 Ag3 S9 99.1(3) . 2_665 ?
N3 Ag3 O7 110.8(4) . 2_665 ?
Ag1 Ag4 Ag5 91.31(3) . 2_665 ?
S9 Ag4 Ag1 87.85(5) 2_665 . ?
S9 Ag4 Ag5 47.69(5) 2_665 2_665 ?
S9 Ag4 S10 115.17(8) 2_665 . ?
S10 Ag4 Ag1 53.20(5) . . ?
S10 Ag4 Ag5 79.99(6) . 2_665 ?
O5 Ag4 Ag1 76.3(2) . . ?
O5 Ag4 Ag5 165.2(2) . 2_665 ?
O5 Ag4 S9 122.6(2) . 2_665 ?
O5 Ag4 S10 98.3(2) . . ?
N1 Ag4 Ag1 164.7(2) . . ?
N1 Ag4 Ag5 100.4(3) . 2_665 ?
N1 Ag4 S9 107.3(2) . 2_665 ?
N1 Ag4 S10 119.0(3) . . ?
N1 Ag4 O5 93.3(3) . . ?
Ag1 Ag5 Ag4 154.22(3) . 2_665 ?
Ag2 Ag5 Ag1 71.25(3) . . ?
Ag2 Ag5 Ag4 102.10(3) . 2_665 ?
Ag2 Ag5 Ag6 154.70(3) . . ?
Ag6 Ag5 Ag1 105.26(4) . . ?
Ag6 Ag5 Ag4 69.77(3) . 2_665 ?
S8 Ag5 Ag1 51.70(6) . . ?
S8 Ag5 Ag2 122.36(6) . . ?
S8 Ag5 Ag4 124.92(6) . 2_665 ?
S8 Ag5 Ag6 56.00(6) . . ?
S9 Ag5 Ag1 125.37(6) . . ?
S9 Ag5 Ag2 54.58(6) . . ?
S9 Ag5 Ag4 50.61(6) . 2_665 ?
S9 Ag5 Ag6 120.15(6) . . ?
S9 Ag5 S8 166.70(7) . . ?
Ag5 Ag6 Ag2 91.60(3) . 2_665 ?
S8 Ag6 Ag2 84.26(5) . 2_665 ?
S8 Ag6 Ag5 50.97(5) . . ?
S10 Ag6 Ag2 50.64(6) 2_665 2_665 ?
S10 Ag6 Ag5 87.51(6) 2_665 . ?
S10 Ag6 S8 119.32(8) 2_665 . ?
N2 Ag6 Ag2 151.0(3) . 2_665 ?
N2 Ag6 Ag5 115.1(3) . . ?
N2 Ag6 S8 103.3(3) . . ?
N2 Ag6 S10 136.4(3) . 2_665 ?
O1 Cr1 O3 112.3(4) . . ?
O1 Cr1 O8 121.7(6) . 2_565 ?
O1 Cr1 O8 96.0(5) . . ?
O2 Cr1 O1 108.7(4) . . ?
O2 Cr1 O3 110.8(4) . . ?
O2 Cr1 O8 124.6(5) . . ?
O2 Cr1 O8 91.1(5) . 2_565 ?
O3 Cr1 O8 110.1(6) . 2_565 ?
O3 Cr1 O8 103.6(6) . . ?
O8 Cr1 O8 35.5(6) . 2_565 ?
Ag1 S8 Ag3 100.49(9) . . ?
Ag1 S8 Ag6 144.95(9) . . ?
Ag3 S8 Ag6 87.02(7) . . ?
Ag5 S8 Ag1 78.32(7) . . ?
Ag5 S8 Ag3 136.31(8) . . ?
Ag5 S8 Ag6 73.03(7) . . ?
C23 S8 Ag1 102.5(3) . . ?
C23 S8 Ag3 113.4(3) . . ?
C23 S8 Ag5 109.4(3) . . ?
C23 S8 Ag6 105.7(3) . . ?
Ag2 S9 Ag3 71.88(6) . 2_665 ?
Ag2 S9 Ag4 146.13(10) . 2_665 ?
Ag4 S9 Ag3 111.19(7) 2_665 2_665 ?
Ag5 S9 Ag2 73.70(7) . . ?
Ag5 S9 Ag3 132.26(10) . 2_665 ?
Ag5 S9 Ag4 81.70(7) . 2_665 ?
C1 S9 Ag2 103.9(3) . . ?
C1 S9 Ag3 112.6(3) . 2_665 ?
C1 S9 Ag4 105.3(3) . 2_665 ?
C1 S9 Ag5 107.0(3) . . ?
Ag1 S10 Ag4 72.78(7) . . ?
Ag2 S10 Ag1 89.32(8) . . ?
Ag2 S10 Ag4 140.05(10) . . ?
Ag6 S10 Ag1 139.41(10) 2_665 . ?
Ag6 S10 Ag2 79.95(8) 2_665 . ?
Ag6 S10 Ag4 90.77(8) 2_665 . ?
C12 S10 Ag1 111.1(3) . . ?
C12 S10 Ag2 109.3(4) . . ?
C12 S10 Ag4 110.4(4) . . ?
C12 S10 Ag6 109.4(3) . 2_665 ?
Cr1 O1 Ag2 129.9(4) . . ?
Cr1 O3 Ag1 126.2(3) . . ?
C34 O4 Ag1 120.5(7) . . ?
C34 O5 Ag4 125.9(7) . . ?
C36A O6 Ag2 121.4(16) . . ?
C36B O6 Ag2 123.2(14) . . ?
C36A O7 Ag3 124.7(18) . 2_665 ?
C40 N1 Ag4 163.5(10) . . ?
C38 N2 Ag6 157.0(11) . . ?
C42 N3 Ag3 166.2(12) . . ?
S9 C1 H1A 109.7 . . ?
S9 C1 H1B 109.7 . . ?
H1A C1 H1B 108.2 . . ?
C2 C1 S9 109.9(5) . . ?
C2 C1 H1A 109.7 . . ?
C2 C1 H1B 109.7 . . ?
C3 C2 C1 119.6(10) . . ?
C11 C2 C1 123.1(9) . . ?
C11 C2 C3 117.3(10) . . ?
C2 C3 H3 118.5 . . ?
C4 C3 C2 123.1(11) . . ?
C4 C3 H3 118.5 . . ?
C3 C4 H4 120.6 . . ?
C3 C4 C5 118.9(11) . . ?
C5 C4 H4 120.6 . . ?
C4 C5 C6 120.9(13) . . ?
C10 C5 C4 119.2(11) . . ?
C10 C5 C6 119.8(12) . . ?
C5 C6 H6 120.1 . . ?
C7 C6 C5 119.8(16) . . ?
C7 C6 H6 120.1 . . ?
C6 C7 H7 118.7 . . ?
C6 C7 C8 122.6(18) . . ?
C8 C7 H7 118.7 . . ?
C7 C8 H8 121.1 . . ?
C9 C8 C7 117.9(15) . . ?
C9 C8 H8 121.1 . . ?
C8 C9 H9 118.4 . . ?
C8 C9 C10 123.2(13) . . ?
C10 C9 H9 118.4 . . ?
C5 C10 C9 116.6(11) . . ?
C5 C10 C11 119.7(10) . . ?
C9 C10 C11 123.7(12) . . ?
C2 C11 C10 121.8(10) . . ?
C2 C11 H11 119.1 . . ?
C10 C11 H11 119.1 . . ?
S10 C12 H12A 109.0 . . ?
S10 C12 H12B 109.0 . . ?
S10 C12 H12C 109.3 . . ?
S10 C12 H12D 109.3 . . ?
H12A C12 H12B 107.8 . . ?
H12C C12 H12D 108.0 . . ?
C13A C12 S10 113.1(14) . . ?
C13A C12 H12A 109.0 . . ?
C13A C12 H12B 109.0 . . ?
C13B C12 S10 111.6(12) . . ?
C13B C12 H12C 109.3 . . ?
C13B C12 H12D 109.3 . . ?
S8 C23 H23A 109.8 . . ?
S8 C23 H23B 109.8 . . ?
H23A C23 H23B 108.2 . . ?
C24 C23 S8 109.6(5) . . ?
C24 C23 H23A 109.8 . . ?
C24 C23 H23B 109.8 . . ?
C25 C24 C23 121.4(8) . . ?
C25 C24 C33 117.9(10) . . ?
C33 C24 C23 120.7(10) . . ?
C24 C25 H25 119.5 . . ?
C24 C25 C26 121.0(10) . . ?
C26 C25 H25 119.5 . . ?
C27 C26 C25 121.6(11) . . ?
C31 C26 C25 119.3(10) . . ?
C31 C26 C27 119.1(11) . . ?
C26 C27 H27 119.1 . . ?
C28 C27 C26 121.8(13) . . ?
C28 C27 H27 119.1 . . ?
C27 C28 H28 119.9 . . ?
C27 C28 C29 120.2(14) . . ?
C29 C28 H28 119.9 . . ?
C28 C29 H29 120.1 . . ?
C30 C29 C28 119.9(15) . . ?
C30 C29 H29 120.1 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.3(15) . . ?
C31 C30 H30 119.9 . . ?
C26 C31 C30 118.7(12) . . ?
C26 C31 C32 118.8(11) . . ?
C32 C31 C30 122.5(12) . . ?
C31 C32 H32 119.7 . . ?
C33 C32 C31 120.6(10) . . ?
C33 C32 H32 119.7 . . ?
C24 C33 H33 118.8 . . ?
C32 C33 C24 122.4(11) . . ?
C32 C33 H33 118.8 . . ?
O4 C34 O5 132.1(11) . . ?
O4 C34 C35 113.0(11) . . ?
O5 C34 C35 114.9(11) . . ?
F4A C35 C34 114(2) . . ?
F4A C35 F5A 97(2) . . ?
F5A C35 C34 111.0(17) . . ?
F6A C35 C34 113.5(13) . . ?
F6A C35 F4A 114(2) . . ?
F6A C35 F5A 106(2) . . ?
F4B C35 C34 113.2(12) . . ?
F5B C35 C34 112.0(13) . . ?
F5B C35 F4B 112.8(18) . . ?
F6B C35 C34 110.8(17) . . ?
F6B C35 F4B 101.6(18) . . ?
F6B C35 F5B 106(2) . . ?
N2 C38 C39 177.6(17) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
N1 C40 C41 178.5(17) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
N3 C42 C43 178.2(16) . . ?
C42 C43 H43A 109.5 . . ?
C42 C43 H43B 109.5 . . ?
C42 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C14A C13A C12 118(2) . . ?
C22A C13A C12 118(3) . . ?
C22A C13A C14A 124.1(18) . . ?
O6 C36A C37A 107(3) . . ?
O7 C36A O6 129(3) . . ?
O7 C36A C37A 111(3) . . ?
F1A C37A F2A 115(3) . . ?
F1A C37A C36A 119(3) . . ?
F2A C37A C36A 113(3) . . ?
F3A C37A F1A 103(3) . . ?
F3A C37A F2A 103(3) . . ?
F3A C37A C36A 101(3) . . ?
C14B C13B C12 117.8(15) . . ?
C14B C13B C22B 115.2(18) . . ?
C22B C13B C12 126.8(17) . . ?
O6 C36B C37B 112(3) . . ?
O7 C36B O6 129(2) . . ?
O7 C36B C37B 114(3) . . ?
F3B C37B C36B 111(2) . . ?
F3B C37B F2B 104(3) . . ?
F3B C37B F1B 104(2) . . ?
F2B C37B C36B 116(2) . . ?
F2B C37B F1B 115(3) . . ?
F1B C37B C36B 107(2) . . ?
C13A C14A H14A 121.9 . . ?
C13A C14A C15A 116(2) . . ?
C15A C14A H14A 121.9 . . ?
C14A C15A C20A 120(3) . . ?
C16A C15A C14A 120(3) . . ?
C16A C15A C20A 120(3) . . ?
C15A C16A H16A 122.3 . . ?
C15A C16A C17A 115(3) . . ?
C17A C16A H16A 122.3 . . ?
C16A C17A H17A 119.5 . . ?
C18A C17A C16A 121(4) . . ?
C18A C17A H17A 119.5 . . ?
C17A C18A H18A 116.2 . . ?
C19A C18A C17A 128(5) . . ?
C19A C18A H18A 116.2 . . ?
C18A C19A H19A 123.6 . . ?
C18A C19A C20A 113(4) . . ?
C20A C19A H19A 123.6 . . ?
C15A C20A C19A 123(3) . . ?
C21A C20A C15A 118(4) . . ?
C21A C20A C19A 118(4) . . ?
C20A C21A H21A 120.2 . . ?
C22A C21A C20A 120(3) . . ?
C22A C21A H21A 120.2 . . ?
C13A C22A C21A 122(2) . . ?
C13A C22A H22A 119.2 . . ?
C21A C22A H22A 119.2 . . ?
C13B C14B H14B 118.5 . . ?
C15B C14B C13B 122.9(19) . . ?
C15B C14B H14B 118.5 . . ?
C14B C15B H15B 120.0 . . ?
C14B C15B C16B 120(2) . . ?
C16B C15B H15B 120.0 . . ?
C15B C16B C17B 119(2) . . ?
C15B C16B C21B 119(2) . . ?
C17B C16B C21B 122(2) . . ?
C16B C17B H17B 121.2 . . ?
C18B C17B C16B 118(3) . . ?
C18B C17B H17B 121.2 . . ?
C17B C18B H18B 119.3 . . ?
C17B C18B C19B 121(3) . . ?
C19B C18B H18B 119.3 . . ?
C18B C19B H19B 120.2 . . ?
C20B C19B C18B 120(3) . . ?
C20B C19B H19B 120.2 . . ?
C16B C21B C22B 119(3) . . ?
C20B C21B C16B 119(2) . . ?
C20B C21B C22B 122(2) . . ?
C19B C20B C21B 120(3) . . ?
C19B C20B H20B 120.2 . . ?
C21B C20B H20B 120.2 . . ?
C13B C22B C21B 124(2) . . ?
C13B C22B H22B 118.0 . . ?
C21B C22B H22B 118.0 . . ?
Cr1 O8 Cr1 144.5(6) . 2_565 ?
O8 O8 Cr1 71.9(14) 2_565 2_565 ?
O8 O8 Cr1 72.5(14) 2_565 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S8 C23 C24 84.1(6) . . . . ?
Ag1 S10 C12 C13A -164.0(16) . . . . ?
Ag1 S10 C12 C13B -144.6(10) . . . . ?
Ag1 O4 C34 O5 6.7(19) . . . . ?
Ag1 O4 C34 C35 -170.5(6) . . . . ?
Ag2 S9 C1 C2 -116.4(7) . . . . ?
Ag2 S10 C12 C13A 99.0(16) . . . . ?
Ag2 S10 C12 C13B 118.4(10) . . . . ?
Ag2 O6 C36A O7 -34(5) . . . . ?
Ag2 O6 C36A C37A -169.7(14) . . . . ?
Ag2 O6 C36B O7 16(5) . . . . ?
Ag2 O6 C36B C37B 171.5(13) . . . . ?
Ag3 S8 C23 C24 -23.3(7) . . . . ?
Ag3 S9 C1 C2 -40.5(8) 2_665 . . . ?
Ag3 O7 C36A O6 14(5) 2_665 . . . ?
Ag3 O7 C36A C37A 148.6(17) 2_665 . . . ?
Ag3 O7 C36B O6 -36(5) 2_665 . . . ?
Ag3 O7 C36B C37B 168.6(15) 2_665 . . . ?
Ag4 S9 C1 C2 80.8(7) 2_665 . . . ?
Ag4 S10 C12 C13A -85.2(17) . . . . ?
Ag4 S10 C12 C13B -65.8(11) . . . . ?
Ag4 O5 C34 O4 -19(2) . . . . ?
Ag4 O5 C34 C35 157.8(7) . . . . ?
Ag5 S8 C23 C24 166.0(6) . . . . ?
Ag5 S9 C1 C2 166.7(6) . . . . ?
Ag6 S8 C23 C24 -116.9(6) . . . . ?
Ag6 S10 C12 C13A 13.2(17) 2_665 . . . ?
Ag6 S10 C12 C13B 32.6(11) 2_665 . . . ?
S8 C23 C24 C25 -95.7(8) . . . . ?
S8 C23 C24 C33 82.6(9) . . . . ?
S9 C1 C2 C3 86.1(8) . . . . ?
S9 C1 C2 C11 -90.9(9) . . . . ?
S10 C12 C13A C14A 80(3) . . . . ?
S10 C12 C13A C22A -95(3) . . . . ?
S10 C12 C13B C14B 80(2) . . . . ?
S10 C12 C13B C22B -96(2) . . . . ?
O1 Cr1 O3 Ag1 37.7(6) . . . . ?
O1 Cr1 O8 Cr1 139.7(18) . . . 2_565 ?
O1 Cr1 O8 O8 139.7(18) . . . 2_565 ?
O2 Cr1 O1 Ag2 -164.7(6) . . . . ?
O2 Cr1 O3 Ag1 159.5(4) . . . . ?
O2 Cr1 O8 Cr1 22(2) . . . 2_565 ?
O2 Cr1 O8 O8 22(2) . . . 2_565 ?
O3 Cr1 O1 Ag2 -41.8(7) . . . . ?
O3 Cr1 O8 Cr1 -105.6(18) . . . 2_565 ?
O3 Cr1 O8 O8 -105.6(18) . . . 2_565 ?
O4 C34 C35 F4A 54(2) . . . . ?
O4 C34 C35 F5A 162(2) . . . . ?
O4 C34 C35 F6A -79(2) . . . . ?
O4 C34 C35 F4B -23.0(19) . . . . ?
O4 C34 C35 F5B -151.9(19) . . . . ?
O4 C34 C35 F6B 90(2) . . . . ?
O5 C34 C35 F4A -123(2) . . . . ?
O5 C34 C35 F5A -16(2) . . . . ?
O5 C34 C35 F6A 104(2) . . . . ?
O5 C34 C35 F4B 159.2(16) . . . . ?
O5 C34 C35 F5B 30(2) . . . . ?
O5 C34 C35 F6B -87(2) . . . . ?
O6 C36A C37A F1A 37(4) . . . . ?
O6 C36A C37A F2A 176(3) . . . . ?
O6 C36A C37A F3A -75(3) . . . . ?
O6 C36B C37B F3B 30(4) . . . . ?
O6 C36B C37B F2B -88(3) . . . . ?
O6 C36B C37B F1B 143(3) . . . . ?
O7 C36A C37A F1A -107(4) . . . . ?
O7 C36A C37A F2A 32(4) . . . . ?
O7 C36A C37A F3A 141(4) . . . . ?
O7 C36B C37B F3B -170(3) . . . . ?
O7 C36B C37B F2B 71(4) . . . . ?
O7 C36B C37B F1B -58(4) . . . . ?
C1 C2 C3 C4 -177.3(7) . . . . ?
C1 C2 C11 C10 178.6(7) . . . . ?
C2 C3 C4 C5 -0.5(13) . . . . ?
C3 C2 C11 C10 1.5(12) . . . . ?
C3 C4 C5 C6 -179.3(8) . . . . ?
C3 C4 C5 C10 -0.4(13) . . . . ?
C4 C5 C6 C7 178.8(11) . . . . ?
C4 C5 C10 C9 -178.3(8) . . . . ?
C4 C5 C10 C11 1.7(13) . . . . ?
C5 C6 C7 C8 -1(2) . . . . ?
C5 C10 C11 C2 -2.3(13) . . . . ?
C6 C5 C10 C9 0.7(13) . . . . ?
C6 C5 C10 C11 -179.4(8) . . . . ?
C6 C7 C8 C9 1(2) . . . . ?
C7 C8 C9 C10 -0.8(18) . . . . ?
C8 C9 C10 C5 -0.2(15) . . . . ?
C8 C9 C10 C11 179.8(9) . . . . ?
C9 C10 C11 C2 177.6(8) . . . . ?
C10 C5 C6 C7 -0.2(15) . . . . ?
C11 C2 C3 C4 -0.1(12) . . . . ?
C12 C13A C14A C15A -178(2) . . . . ?
C12 C13A C22A C21A 177(2) . . . . ?
C12 C13B C14B C15B -175.8(19) . . . . ?
C12 C13B C22B C21B 178(2) . . . . ?
C23 C24 C25 C26 -179.7(6) . . . . ?
C23 C24 C33 C32 179.8(9) . . . . ?
C24 C25 C26 C27 176.9(8) . . . . ?
C24 C25 C26 C31 -2.1(12) . . . . ?
C25 C24 C33 C32 -1.9(14) . . . . ?
C25 C26 C27 C28 -179.0(8) . . . . ?
C25 C26 C31 C30 -179.9(8) . . . . ?
C25 C26 C31 C32 2.0(13) . . . . ?
C26 C27 C28 C29 0.6(16) . . . . ?
C26 C31 C32 C33 -1.9(16) . . . . ?
C27 C26 C31 C30 1.1(14) . . . . ?
C27 C26 C31 C32 -177.0(9) . . . . ?
C27 C28 C29 C30 -2(2) . . . . ?
C28 C29 C30 C31 4(2) . . . . ?
C29 C30 C31 C26 -2.9(17) . . . . ?
C29 C30 C31 C32 175.1(11) . . . . ?
C30 C31 C32 C33 -180.0(10) . . . . ?
C31 C26 C27 C28 0.0(14) . . . . ?
C31 C32 C33 C24 1.9(16) . . . . ?
C33 C24 C25 C26 1.9(12) . . . . ?
C13A C14A C15A C16A 179(3) . . . . ?
C13A C14A C15A C20A 5(4) . . . . ?
C13B C14B C15B C16B -1(4) . . . . ?
C14A C13A C22A C21A 2(4) . . . . ?
C14A C15A C16A C17A -178(3) . . . . ?
C14A C15A C20A C19A -177(3) . . . . ?
C14A C15A C20A C21A -6(5) . . . . ?
C15A C16A C17A C18A 1(5) . . . . ?
C15A C20A C21A C22A 5(5) . . . . ?
C16A C15A C20A C19A 9(5) . . . . ?
C16A C15A C20A C21A 180(3) . . . . ?
C16A C17A C18A C19A -3(8) . . . . ?
C17A C18A C19A C20A 7(8) . . . . ?
C18A C19A C20A C15A -10(6) . . . . ?
C18A C19A C20A C21A 180(4) . . . . ?
C19A C20A C21A C22A 176(3) . . . . ?
C20A C15A C16A C17A -4(4) . . . . ?
C20A C21A C22A C13A -3(4) . . . . ?
C22A C13A C14A C15A -3(4) . . . . ?
C14B C13B C22B C21B 2(4) . . . . ?
C14B C15B C16B C17B -179(3) . . . . ?
C14B C15B C16B C21B -1(4) . . . . ?
C15B C16B C17B C18B -179(3) . . . . ?
C15B C16B C21B C20B 175(2) . . . . ?
C15B C16B C21B C22B 3(4) . . . . ?
C16B C17B C18B C19B 6(6) . . . . ?
C16B C21B C20B C19B 3(4) . . . . ?
C16B C21B C22B C13B -4(4) . . . . ?
C17B C16B C21B C20B -7(4) . . . . ?
C17B C16B C21B C22B -179(3) . . . . ?
C17B C18B C19B C20B -10(6) . . . . ?
C18B C19B C20B C21B 5(5) . . . . ?
C21B C16B C17B C18B 3(5) . . . . ?
C20B C21B C22B C13B -175(2) . . . . ?
C22B C13B C14B C15B 0(4) . . . . ?
C22B C21B C20B C19B 175(3) . . . . ?
O8 Cr1 O1 Ag2 65.6(8) . . . . ?
O8 Cr1 O1 Ag2 91.8(8) 2_565 . . . ?
O8 Cr1 O3 Ag1 -101.3(5) 2_565 . . . ?
O8 Cr1 O3 Ag1 -64.7(6) . . . . ?
O8 Cr1 O8 Cr1 0.002(2) 2_565 . . 2_565 ?

_shelx_SHELXL_version_number     2016/6
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag30_sq
_database_code_depnum_ccdc_archive 'CCDC 1869848'
_audit_update_record             
;
2018-09-26 deposited with the CCDC.
2018-11-09 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT910_ag30_sq             
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min)          64 Note  
RESPONSE: The missing reflections at low resolution might be shielded
by the beamstop.
;
# end Validation Reply Form
_audit_creation_date             2016-12-05
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.11.07 svn.r3352 for OlexSys, GUI svn.r5261)
+manual edit
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C230 H198 Ag30 Cr2 F24 N4 O28 S18'
_chemical_formula_sum            'C230 H198 Ag30 Cr2 F24 N4 O28 S18'
_chemical_formula_weight         7839.09
_chemical_melting_point          ?
_chemical_oxdiff_formula         C1H1O1N1S1Ag1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   17.8479(4)
_cell_length_b                   21.0072(4)
_cell_length_c                   21.9628(4)
_cell_angle_alpha                62.618(2)
_cell_angle_beta                 83.842(2)
_cell_angle_gamma                65.100(2)
_cell_volume                     6594.1(3)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    20693
_cell_measurement_temperature    102.3(3)
_cell_measurement_theta_max      28.9260
_cell_measurement_theta_min      3.5220
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.465
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89857
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.974
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             3792
_exptl_crystal_size_max          0.2500
_exptl_crystal_size_mid          0.2100
_exptl_crystal_size_min          0.2000
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0459
_diffrn_reflns_av_unetI/netI     0.0686
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            61028
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         3.426
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      102.3(3)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.2312
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -23.00   23.40   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -      -15.1755  -99.0000  -90.0000 58

#__ type_ start__ end____ width___ exp.time_
  2 omega  -49.00  -18.60   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -77.0000   90.0000 38

#__ type_ start__ end____ width___ exp.time_
  3 omega   -5.00   28.60   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -57.0000 -120.0000 42

#__ type_ start__ end____ width___ exp.time_
  4 omega   19.80   47.00   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -19.0000   90.0000 34

#__ type_ start__ end____ width___ exp.time_
  5 omega  -49.00   33.40   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -57.0000  -30.0000 103

#__ type_ start__ end____ width___ exp.time_
  6 omega  -49.00  -21.80   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -57.0000 -120.0000 34

#__ type_ start__ end____ width___ exp.time_
  7 omega   18.00   45.20   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -77.0000   90.0000 34

#__ type_ start__ end____ width___ exp.time_
  8 omega  -43.00   -3.80   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -19.0000   90.0000 49

#__ type_ start__ end____ width___ exp.time_
  9 omega   -9.00   84.60   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661   77.0000 -150.0000 117

#__ type_ start__ end____ width___ exp.time_
 10 omega  -13.00   56.60   0.8000    7.5000
omega____ theta____ kappa____ phi______ frames
    -       18.0661  -99.0000   90.0000 87
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0267072000
_diffrn_orient_matrix_UB_12      -0.0190030000
_diffrn_orient_matrix_UB_13      0.0058264000
_diffrn_orient_matrix_UB_21      -0.0292959000
_diffrn_orient_matrix_UB_22      0.0266938000
_diffrn_orient_matrix_UB_23      0.0113199000
_diffrn_orient_matrix_UB_31      -0.0192482000
_diffrn_orient_matrix_UB_32      0.0261489000
_diffrn_orient_matrix_UB_33      -0.0342946000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                19347
_reflns_number_total             25823
_reflns_odcompleteness_completeness 99.76
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         1.743
_refine_diff_density_min         -2.461
_refine_diff_density_rms         0.157
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1519
_refine_ls_number_reflns         25823
_refine_ls_number_restraints     57
_refine_ls_R_factor_all          0.0657
_refine_ls_R_factor_gt           0.0432
_refine_ls_restrained_S_all      1.020
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0397P)²+10.8827P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.1032
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N2-C110 \\sim N2-C104 \\sim N2-C115
 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C109) \\sim Ueq, Uanis(C108) \\sim Ueq, Uanis(C103) \\sim Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
Uanis(N2) \\sim Ueq, Uanis(C110) \\sim Ueq, Uanis(C115) \\sim Ueq: with sigma
of 0.005 and sigma for terminal atoms of 0.02
Uanis(F3) \\sim Ueq, Uanis(F2) \\sim Ueq, Uanis(F1) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
4.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C13(H13A,H13B), C19(H19A,H19B), C21(H21A,H21B), C30(H30A,H30B),
 C36(H36A,H36B), C45(H45A,H45B), C56(H56A,H56B), C58(H58A,H58B)
4.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C6(H6), C7(H7), C8(H8), C10(H10), C12(H12), C15(H15),
 C17(H17), C18(H18), C22(H22), C29(H29), C32(H32), C33(H33), C34(H34), C35(H35),
  C38(H38), C39(H39), C40(H40), C41(H41), C42(H42), C48(H48), C49(H49),
 C52(H52), C53(H53), C57(H57), C59(H59), C60(H60), C62(H62), C63(H63), C65(H65),
  C66(H66), C67(H67), C71(H71), C72(H72), C73(H73), C74(H74), C76(H76),
 C78(H78), C79(H79), C81(H81), C83(H83), C84(H84), C85(H85), C86(H86), C87(H87),
  C88(H88), C89(H89), C90(H90), C91(H91), C94(H94), C95(H95), C96(H96),
 C97(H97), C98(H98), C99(H99), C100(H100), C103(H103), C105(H105), C107(H107),
 C108(H108), C109(H109), C112(H112)
4.c Idealised Me refined as rotating group:
 C82(H82A,H82B,H82C), C92(H92A,H92B,H92C), C106(H10A,H10B,H10C), C110(H11A,
 H11B,H11C), C114(H11D,H11E,H11F), C115(H11G,H11H,H11I)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.47057(3) 0.87325(3) 0.07426(2) 0.01862(10) Uani 1 1 d . . . . .
Ag2 Ag 0.71096(3) 0.75931(3) 0.07504(2) 0.02225(11) Uani 1 1 d . . . . .
Ag3 Ag 0.51216(3) 0.84069(3) 0.21156(2) 0.02087(11) Uani 1 1 d . . . . .
Ag4 Ag 0.40703(3) 0.80346(3) 0.01457(2) 0.02119(11) Uani 1 1 d . . . . .
Ag5 Ag 0.28902(3) 0.93233(3) 0.04677(2) 0.02249(11) Uani 1 1 d . . . . .
Ag6 Ag 0.83152(3) 0.79748(3) -0.12413(2) 0.02273(11) Uani 1 1 d . . . . .
Ag7 Ag 0.59609(3) 0.70041(3) 0.16937(2) 0.02161(11) Uani 1 1 d . . . . .
Ag8 Ag 0.50406(3) 0.95677(3) -0.25444(2) 0.02105(11) Uani 1 1 d . . . . .
Ag9 Ag 0.63861(3) 0.72048(3) -0.02445(2) 0.02559(12) Uani 1 1 d . . . . .
Ag10 Ag 0.69036(3) 0.86357(3) -0.22986(2) 0.02210(11) Uani 1 1 d . . . . .
Ag11 Ag 0.63562(3) 0.93201(3) 0.10274(2) 0.02390(12) Uani 1 1 d . . . . .
Ag12 Ag 0.46904(3) 0.88447(3) -0.11457(2) 0.02296(11) Uani 1 1 d . . . . .
Ag13 Ag 0.39297(3) 0.97332(3) 0.23788(2) 0.02399(11) Uani 1 1 d . . . . .
Ag14 Ag 0.84083(3) 0.80233(3) 0.00594(2) 0.02477(12) Uani 1 1 d . . . . .
Ag15 Ag 0.22631(3) 1.04042(3) 0.11367(2) 0.02619(12) Uani 1 1 d . . . . .
Cr1 Cr 0.58634(8) 0.93385(7) -0.05272(6) 0.0338(3) Uani 1 1 d . . . . .
S1 S 0.78230(10) 0.71897(9) -0.01044(7) 0.0187(3) Uani 1 1 d . . . . .
S2 S 0.65996(10) 0.79339(9) 0.16717(7) 0.0175(3) Uani 1 1 d . . . . .
S3 S 0.54407(10) 0.70182(9) 0.07068(7) 0.0184(3) Uani 1 1 d . . . . .
S4 S 0.37354(10) 0.86937(9) 0.16138(7) 0.0181(3) Uani 1 1 d . . . . .
S5 S 0.34244(10) 0.94965(9) -0.07407(7) 0.0192(3) Uani 1 1 d . . . . .
S6 S 0.58713(10) 0.81221(9) -0.15748(8) 0.0196(3) Uani 1 1 d . . . . .
S7 S 0.54272(10) 0.90835(9) 0.27109(7) 0.0186(3) Uani 1 1 d . . . . .
S8 S 0.75568(10) 0.94152(9) -0.21318(8) 0.0195(3) Uani 1 1 d . . . . .
S9 S 0.17707(10) 1.07391(9) -0.00184(8) 0.0214(3) Uani 1 1 d . . . . .
O1 O 0.5654(3) 0.8641(2) 0.0026(2) 0.0240(10) Uani 1 1 d . . . . .
O2 O 0.6031(4) 0.9760(3) -0.0183(2) 0.0466(15) Uani 1 1 d . . . . .
O3 O 0.6622(4) 0.9003(3) -0.0870(3) 0.0509(15) Uani 1 1 d . . . . .
C1 C 0.8576(4) 0.7534(4) 0.1786(3) 0.0215(14) Uani 1 1 d . . . . .
H1 H 0.821789 0.804309 0.144602 0.026 Uiso 1 1 calc R . . . .
C2 C 0.0426(4) 0.9681(4) 0.1032(3) 0.0282(16) Uani 1 1 d . . . . .
H2 H 0.059236 0.937449 0.079074 0.034 Uiso 1 1 calc R . . . .
C3 C 0.2865(4) 1.0779(4) -0.3445(3) 0.0228(14) Uani 1 1 d . . . . .
C4 C 0.8237(4) 0.7103(3) 0.2352(3) 0.0182(13) Uani 1 1 d . . . . .
C5 C 0.8293(4) 0.5705(3) 0.1049(3) 0.0207(14) Uani 1 1 d . . . . .
C6 C 0.9408(4) 0.7236(4) 0.1713(3) 0.0228(14) Uani 1 1 d . . . . .
H6 H 0.961600 0.754113 0.132595 0.027 Uiso 1 1 calc R . . . .
C7 C 0.4239(4) 0.7870(3) -0.2355(3) 0.0253(15) Uani 1 1 d . . . . .
H7 H 0.440089 0.807281 -0.280705 0.030 Uiso 1 1 calc R . . . .
C8 C 0.8345(4) 0.5804(3) 0.1644(3) 0.0205(14) Uani 1 1 d . . . . .
H8 H 0.856367 0.615418 0.162232 0.025 Uiso 1 1 calc R . . . .
C9 C 0.8187(4) 0.9677(4) -0.2854(3) 0.0278(16) Uani 1 1 d . . . . .
H9A H 0.781543 1.011836 -0.327548 0.033 Uiso 1 1 calc R . . . .
H9B H 0.856162 0.985620 -0.274355 0.033 Uiso 1 1 calc R . . . .
C10 C 0.8080(4) 0.5396(4) 0.2241(3) 0.0243(15) Uani 1 1 d . . . . .
H10 H 0.809605 0.548266 0.262621 0.029 Uiso 1 1 calc R . . . .
C11 C 0.4784(4) 0.7569(3) -0.1801(3) 0.0194(13) Uani 1 1 d . . . . .
C12 C 0.7983(4) 0.5194(4) 0.1097(3) 0.0215(14) Uani 1 1 d . . . . .
H12 H 0.794303 0.513462 0.069960 0.026 Uiso 1 1 calc R . . . .
C13 C 0.5639(4) 0.7538(4) -0.1894(3) 0.0204(14) Uani 1 1 d . . . . .
H13A H 0.571404 0.773335 -0.239035 0.024 Uiso 1 1 calc R . . . .
H13B H 0.604763 0.697981 -0.164973 0.024 Uiso 1 1 calc R . . . .
C14 C 0.2373(4) 1.1278(4) -0.3135(3) 0.0221(14) Uani 1 1 d . . . . .
C15 C 0.3220(4) 0.9954(4) -0.3020(3) 0.0237(15) Uani 1 1 d . . . . .
H15 H 0.354386 0.961360 -0.321226 0.028 Uiso 1 1 calc R . . . .
C16 C 0.4708(4) 0.8598(4) 0.3959(3) 0.0211(14) Uani 1 1 d . . . . .
C17 C 0.4547(5) 0.7250(4) -0.1123(3) 0.0274(16) Uani 1 1 d . . . . .
H17 H 0.493089 0.703253 -0.073647 0.033 Uiso 1 1 calc R . . . .
C18 C 0.3788(5) 0.7253(4) -0.1021(4) 0.0369(18) Uani 1 1 d . . . . .
H18 H 0.364570 0.703657 -0.056342 0.044 Uiso 1 1 calc R . . . .
C19 C 0.8589(4) 0.6159(4) 0.0394(3) 0.0253(15) Uani 1 1 d . . . . .
H19A H 0.871623 0.588707 0.010337 0.030 Uiso 1 1 calc R . . . .
H19B H 0.911013 0.615960 0.050907 0.030 Uiso 1 1 calc R . . . .
C20 C 0.8692(4) 0.8987(4) -0.2988(3) 0.0241(15) Uani 1 1 d . . . . .
C21 C 0.3667(4) 0.7729(4) 0.2046(3) 0.0247(15) Uani 1 1 d . . . . .
H21A H 0.341467 0.766170 0.171266 0.030 Uiso 1 1 calc R . . . .
H21B H 0.423092 0.729430 0.222097 0.030 Uiso 1 1 calc R . . . .
C22 C 0.1999(5) 1.2096(4) -0.3568(3) 0.0314(17) Uani 1 1 d . . . . .
H22 H 0.167716 1.243724 -0.337530 0.038 Uiso 1 1 calc R . . . .
C23 C 0.2626(4) 1.0118(4) -0.2017(3) 0.0230(14) Uani 1 1 d . . . . .
C24 C 0.8918(5) 0.8256(4) -0.3636(3) 0.0307(16) Uani 1 1 d . . . . .
C25 C 0.3722(4) 0.9155(4) 0.4623(3) 0.0232(14) Uani 1 1 d . . . . .
C26 C 0.0485(4) 1.0388(4) 0.0744(4) 0.0287(16) Uani 1 1 d . . . . .
C27 C 0.3427(5) 0.7886(4) -0.2269(4) 0.0340(18) Uani 1 1 d . . . . .
C28 C 0.9629(4) 0.6046(4) 0.2789(3) 0.0260(15) Uani 1 1 d . . . . .
C29 C 0.8764(4) 0.6367(4) 0.2841(3) 0.0244(15) Uani 1 1 d . . . . .
H29 H 0.854346 0.606805 0.322122 0.029 Uiso 1 1 calc R . . . .
C30 C 0.2522(4) 0.9749(4) -0.1277(3) 0.0204(14) Uani 1 1 d . . . . .
H30A H 0.244953 0.926398 -0.115537 0.025 Uiso 1 1 calc R . . . .
H30B H 0.201553 1.011798 -0.118167 0.025 Uiso 1 1 calc R . . . .
C31 C 0.0122(4) 0.9395(4) 0.1684(4) 0.0291(16) Uani 1 1 d . . . . .
C32 C 0.8433(4) 0.8903(4) -0.3503(3) 0.0287(16) Uani 1 1 d . . . . .
H32 H 0.791840 0.928738 -0.377600 0.034 Uiso 1 1 calc R . . . .
C33 C 0.4473(4) 0.9034(4) 0.4315(3) 0.0245(15) Uani 1 1 d . . . . .
H33 H 0.482041 0.925681 0.435526 0.029 Uiso 1 1 calc R . . . .
C34 C 0.5263(5) 0.5564(4) 0.2275(3) 0.0297(17) Uani 1 1 d . . . . .
H34 H 0.584321 0.540481 0.234577 0.036 Uiso 1 1 calc R . . . .
C35 C 1.0184(5) 0.5290(4) 0.3289(4) 0.0391(19) Uani 1 1 d . . . . .
H35 H 0.997590 0.498637 0.367692 0.047 Uiso 1 1 calc R . . . .
C36 C 0.5377(4) 0.6063(3) 0.1024(3) 0.0217(14) Uani 1 1 d . . . . .
H36A H 0.511203 0.606670 0.064851 0.026 Uiso 1 1 calc R . . . .
H36B H 0.594582 0.563316 0.115489 0.026 Uiso 1 1 calc R . . . .
C37 C 0.3193(4) 0.8841(4) 0.4553(3) 0.0262(15) Uani 1 1 d . . . . .
C38 C 0.2291(4) 1.0921(4) -0.2423(3) 0.0227(14) Uani 1 1 d . . . . .
H38 H 0.199091 1.125172 -0.221621 0.027 Uiso 1 1 calc R . . . .
C39 C 0.7269(5) 0.3856(4) 0.2963(4) 0.0387(19) Uani 1 1 d . . . . .
H39 H 0.713458 0.353251 0.339080 0.046 Uiso 1 1 calc R . . . .
C40 C 0.9445(4) 0.8399(4) -0.2572(3) 0.0270(15) Uani 1 1 d . . . . .
H40 H 0.962280 0.844856 -0.220976 0.032 Uiso 1 1 calc R . . . .
C41 C 0.4171(4) 0.8290(4) 0.3887(3) 0.0236(15) Uani 1 1 d . . . . .
H41 H 0.432701 0.798888 0.364069 0.028 Uiso 1 1 calc R . . . .
C42 C 0.3440(5) 0.8418(4) 0.4164(3) 0.0294(16) Uani 1 1 d . . . . .
H42 H 0.308414 0.821920 0.409633 0.035 Uiso 1 1 calc R . . . .
C43 C 0.7781(4) 0.4848(4) 0.2301(3) 0.0261(15) Uani 1 1 d . . . . .
C44 C 0.2977(5) 0.7154(4) 0.3857(3) 0.0315(18) Uani 1 1 d . . . . .
C45 C 0.7327(4) 0.7433(4) 0.2449(3) 0.0243(15) Uani 1 1 d . . . . .
H45A H 0.722250 0.781191 0.263072 0.029 Uiso 1 1 calc R . . . .
H45B H 0.720245 0.699391 0.280334 0.029 Uiso 1 1 calc R . . . .
C46 C 0.3144(4) 0.7698(4) 0.2637(3) 0.0243(15) Uani 1 1 d . . . . .
C47 C 0.3906(5) 0.5689(4) 0.2715(4) 0.0304(17) Uani 1 1 d . . . . .
C48 C 0.3107(4) 0.9634(4) -0.2334(3) 0.0235(14) Uani 1 1 d . . . . .
H48 H 0.335510 0.907586 -0.206215 0.028 Uiso 1 1 calc R . . . .
C49 C 0.3478(5) 0.7179(4) 0.3300(3) 0.0267(16) Uani 1 1 d . . . . .
H49 H 0.405038 0.682719 0.339455 0.032 Uiso 1 1 calc R . . . .
C50 C 0.9952(4) 0.6488(4) 0.2202(3) 0.0274(16) Uani 1 1 d . . . . .
C51 C 0.4779(5) 0.5445(4) 0.2858(3) 0.0339(18) Uani 1 1 d . . . . .
C52 C 0.2934(5) 1.1132(4) -0.4157(3) 0.0313(17) Uani 1 1 d . . . . .
H52 H 0.325308 1.080703 -0.436476 0.038 Uiso 1 1 calc R . . . .
C53 C 0.4034(5) 0.6138(4) 0.1519(4) 0.0299(16) Uani 1 1 d . . . . .
H53 H 0.378382 0.638048 0.106107 0.036 Uiso 1 1 calc R . . . .
C54 C 0.4891(4) 0.5903(4) 0.1633(3) 0.0223(14) Uani 1 1 d . . . . .
C55 C 0.7719(4) 0.4754(3) 0.1705(3) 0.0230(14) Uani 1 1 d . . . . .
C56 C 0.5511(4) 0.8442(4) 0.3652(3) 0.0230(14) Uani 1 1 d . . . . .
H56A H 0.576685 0.788427 0.373970 0.028 Uiso 1 1 calc R . . . .
H56B H 0.588976 0.851142 0.388985 0.028 Uiso 1 1 calc R . . . .
C57 C 0.2082(5) 1.2420(4) -0.4262(3) 0.0367(19) Uani 1 1 d . . . . .
H57 H 0.182005 1.297644 -0.453994 0.044 Uiso 1 1 calc R . . . .
C58 C 0.0749(5) 1.0711(5) 0.0033(4) 0.039(2) Uani 1 1 d . . . . .
H58A H 0.032548 1.125481 -0.024500 0.047 Uiso 1 1 calc R . . . .
H58B H 0.075211 1.038744 -0.018360 0.047 Uiso 1 1 calc R . . . .
C59 C 0.7421(5) 0.4208(4) 0.1768(4) 0.0344(18) Uani 1 1 d . . . . .
H59 H 0.737659 0.414079 0.137623 0.041 Uiso 1 1 calc R . . . .
C60 C 0.2847(6) 0.8213(4) -0.2840(5) 0.051(2) Uani 1 1 d . . . . .
H60 H 0.299718 0.841695 -0.329581 0.061 Uiso 1 1 calc R . . . .
C61 C 0.3188(5) 0.7579(4) -0.1596(4) 0.0373(19) Uani 1 1 d . . . . .
C62 C 0.3427(6) 0.5550(4) 0.3294(4) 0.0400(19) Uani 1 1 d . . . . .
H62 H 0.285065 0.569511 0.322349 0.048 Uiso 1 1 calc R . . . .
C63 C 0.2549(5) 1.1936(4) -0.4558(3) 0.0328(17) Uani 1 1 d . . . . .
H63 H 0.260157 1.216154 -0.503773 0.039 Uiso 1 1 calc R . . . .
C64 C 0.9677(4) 0.7683(5) -0.3214(4) 0.0332(17) Uani 1 1 d . . . . .
C65 C 0.7194(5) 0.3772(4) 0.2375(4) 0.0388(19) Uani 1 1 d . . . . .
H65 H 0.698564 0.341281 0.240120 0.047 Uiso 1 1 calc R . . . .
C66 C 0.8685(5) 0.8165(5) -0.4176(4) 0.043(2) Uani 1 1 d . . . . .
H66 H 0.817783 0.854365 -0.446223 0.052 Uiso 1 1 calc R . . . .
C67 C 0.3560(5) 0.6027(4) 0.2045(4) 0.0380(19) Uani 1 1 d . . . . .
H67 H 0.298455 0.618109 0.195562 0.046 Uiso 1 1 calc R . . . .
O4 O 0.6342(3) 0.6203(2) 0.2846(2) 0.0260(10) Uani 1 1 d . . . . .
O5 O 0.5120(3) 0.9248(3) -0.3428(2) 0.0270(11) Uani 1 1 d . . . . .
O6 O 0.8213(3) 0.7343(3) -0.1933(2) 0.0300(11) Uani 1 1 d . . . . .
O7 O 0.9808(3) 0.7138(3) 0.0219(2) 0.0321(11) Uani 1 1 d . . . . .
O8 O 0.6521(3) 0.8769(3) -0.3344(2) 0.0299(11) Uani 1 1 d . . . . .
O9 O 0.9754(3) 0.7408(3) -0.0901(2) 0.0301(11) Uani 1 1 d . . . . .
O10 O 0.2150(3) 0.8548(3) 0.0620(2) 0.0332(12) Uani 1 1 d . . . . .
O11 O 0.5408(3) 0.7142(3) 0.3103(2) 0.0370(12) Uani 1 1 d . . . . .
O12 O 0.2949(3) 0.7780(3) 0.0141(2) 0.0339(12) Uani 1 1 d . . . . .
O13 O 0.6548(4) 0.5931(3) -0.0193(2) 0.0423(14) Uani 1 1 d . . . . .
F1 F 0.6789(4) 0.5245(3) 0.4177(2) 0.0770(19) Uani 1 1 d . U . . .
C68 C 0.5974(4) 0.6496(4) 0.3232(3) 0.0232(14) Uani 1 1 d . . . . .
C69 C 0.5833(4) 0.8899(4) -0.3556(3) 0.0228(14) Uani 1 1 d . . . . .
F2 F 0.6709(5) 0.6258(3) 0.4197(3) 0.093(2) Uani 1 1 d . U . . .
C70 C 0.2331(4) 0.8051(4) 0.0408(3) 0.0247(15) Uani 1 1 d . . . . .
C71 C 0.3477(5) 0.9570(4) 0.5022(3) 0.0300(17) Uani 1 1 d . . . . .
H71 H 0.382387 0.978338 0.507988 0.036 Uiso 1 1 calc R . . . .
C72 C 0.0059(5) 0.8664(4) 0.1982(4) 0.0406(19) Uani 1 1 d . . . . .
H72 H 0.023757 0.834625 0.175100 0.049 Uiso 1 1 calc R . . . .
C73 C 0.2445(5) 0.8954(5) 0.4872(4) 0.0390(19) Uani 1 1 d . . . . .
H73 H 0.208814 0.874724 0.482095 0.047 Uiso 1 1 calc R . . . .
C74 C 0.3317(5) 0.6620(4) 0.4551(4) 0.042(2) Uani 1 1 d . . . . .
H74 H 0.388472 0.625316 0.465234 0.050 Uiso 1 1 calc R . . . .
C75 C 0.1693(5) 0.7716(4) 0.0475(4) 0.0296(16) Uani 1 1 d . . . . .
C76 C 0.2750(5) 0.9670(4) 0.5324(3) 0.0338(17) Uani 1 1 d . . . . .
H76 H 0.259944 0.995406 0.558492 0.041 Uiso 1 1 calc R . . . .
C77 C 1.0080(4) 0.7035(4) -0.0287(4) 0.0245(15) Uani 1 1 d . . . . .
C78 C 1.0829(5) 0.6150(5) 0.2151(4) 0.0377(18) Uani 1 1 d . . . . .
H78 H 1.105735 0.643596 0.176772 0.045 Uiso 1 1 calc R . . . .
C79 C 1.0182(5) 0.7026(5) -0.3351(4) 0.047(2) Uani 1 1 d . . . . .
H79 H 1.068533 0.662793 -0.306701 0.057 Uiso 1 1 calc R . . . .
C80 C -0.0124(5) 0.9860(5) 0.2036(4) 0.0379(19) Uani 1 1 d . . . . .
N1 N 0.9149(5) 0.6193(4) -0.1840(4) 0.0534(19) Uani 1 1 d . . . . .
F3 F 0.5698(5) 0.5974(5) 0.4396(3) 0.127(3) Uani 1 1 d . U . . .
C81 C 0.2013(6) 0.7146(5) 0.4941(4) 0.048(2) Uani 1 1 d . . . . .
H81 H 0.168308 0.714277 0.531065 0.058 Uiso 1 1 calc R . . . .
C82 C 0.9631(5) 0.6075(4) -0.1271(4) 0.0385(19) Uani 1 1 d . . . . .
H82A H 0.937439 0.654289 -0.119371 0.058 Uiso 1 1 calc GR . . . .
H82B H 1.019993 0.599286 -0.138455 0.058 Uiso 1 1 calc GR . . . .
H82C H 0.964275 0.561098 -0.085154 0.058 Uiso 1 1 calc GR . . . .
C83 C 1.1013(6) 0.4993(5) 0.3220(4) 0.050(2) Uani 1 1 d . . . . .
H83 H 1.137571 0.448904 0.356397 0.061 Uiso 1 1 calc R . . . .
C84 C 1.1338(5) 0.5420(5) 0.2648(5) 0.047(2) Uani 1 1 d . . . . .
H84 H 1.191529 0.520173 0.260588 0.057 Uiso 1 1 calc R . . . .
C85 C 0.2230(5) 0.9359(5) 0.5254(4) 0.0398(19) Uani 1 1 d . . . . .
H85 H 0.173042 0.942591 0.546959 0.048 Uiso 1 1 calc R . . . .
C86 C 0.5134(6) 0.5107(4) 0.3523(4) 0.042(2) Uani 1 1 d . . . . .
H86 H 0.570908 0.495619 0.360930 0.051 Uiso 1 1 calc R . . . .
C87 C 0.1810(5) 0.8215(6) 0.3011(4) 0.053(2) Uani 1 1 d . . . . .
H87 H 0.124180 0.858061 0.289982 0.063 Uiso 1 1 calc R . . . .
C88 C 0.9921(5) 0.7763(5) -0.2678(4) 0.0384(18) Uani 1 1 d . . . . .
H88 H 1.042188 0.737242 -0.238738 0.046 Uiso 1 1 calc R . . . .
C89 C 0.2304(5) 0.8201(5) 0.2499(4) 0.045(2) Uani 1 1 d . . . . .
H89 H 0.206801 0.854552 0.203328 0.054 Uiso 1 1 calc R . . . .
C90 C -0.0044(5) 1.0569(5) 0.1742(5) 0.054(2) Uani 1 1 d . . . . .
H90 H -0.019742 1.087930 0.197863 0.065 Uiso 1 1 calc R . . . .
C91 C -0.0505(5) 0.8871(6) 0.2955(4) 0.052(2) Uani 1 1 d . . . . .
H91 H -0.071279 0.868955 0.338963 0.063 Uiso 1 1 calc R . . . .
C92 C 0.8024(5) 0.6905(5) -0.2747(4) 0.046(2) Uani 1 1 d . . . . .
H92A H 0.782232 0.649113 -0.257817 0.069 Uiso 1 1 calc GR . . . .
H92B H 0.841225 0.684641 -0.308854 0.069 Uiso 1 1 calc GR . . . .
H92C H 0.755254 0.742491 -0.296078 0.069 Uiso 1 1 calc GR . . . .
C93 C 0.6313(6) 0.5967(4) 0.4002(4) 0.044(2) Uani 1 1 d . . . . .
C94 C 0.3794(7) 0.5217(5) 0.3933(4) 0.048(2) Uani 1 1 d . . . . .
H94 H 0.346648 0.513225 0.430861 0.058 Uiso 1 1 calc R . . . .
C95 C -0.0261(5) 0.8412(5) 0.2605(4) 0.049(2) Uani 1 1 d . . . . .
H95 H -0.031596 0.792814 0.279735 0.059 Uiso 1 1 calc R . . . .
C96 C 0.9935(5) 0.6979(6) -0.3885(5) 0.058(3) Uani 1 1 d . . . . .
H96 H 1.028367 0.655731 -0.398375 0.070 Uiso 1 1 calc R . . . .
C97 C 0.2837(7) 0.6630(5) 0.5076(4) 0.055(3) Uani 1 1 d . . . . .
H97 H 0.307516 0.627502 0.554051 0.066 Uiso 1 1 calc R . . . .
C98 C 0.0255(5) 1.0825(5) 0.1114(5) 0.049(2) Uani 1 1 d . . . . .
H98 H 0.030645 1.131025 0.092511 0.058 Uiso 1 1 calc R . . . .
C99 C 0.1664(6) 0.7666(6) 0.4276(4) 0.051(2) Uani 1 1 d . . . . .
H99 H 0.109219 0.802059 0.418869 0.061 Uiso 1 1 calc R . . . .
C100 C 0.9193(6) 0.7525(5) -0.4290(4) 0.051(2) Uani 1 1 d . . . . .
H100 H 0.902721 0.746356 -0.464956 0.061 Uiso 1 1 calc R . . . .
C101 C 0.8470(6) 0.6830(5) -0.2139(4) 0.052(2) Uani 1 1 d . . . . .
C102 C 0.2139(5) 0.7682(5) 0.3720(4) 0.0355(18) Uani 1 1 d . . . . .
C103 C 0.2381(6) 0.7605(5) -0.1511(5) 0.054(2) Uani 1 1 d . U . . .
H103 H 0.221387 0.740373 -0.106125 0.065 Uiso 1 1 calc R . . . .
C104 C 0.6861(6) 0.5699(5) -0.0608(4) 0.056(3) Uani 1 1 d D . . . .
C105 C -0.0449(5) 0.9567(6) 0.2680(4) 0.054(2) Uani 1 1 d . . . . .
H105 H -0.063060 0.987247 0.292241 0.064 Uiso 1 1 calc R . . . .
C106 C 0.7552(6) 0.5889(5) -0.1016(4) 0.060(3) Uani 1 1 d . . . . .
H10A H 0.756178 0.634729 -0.100691 0.091 Uiso 1 1 calc GR . . . .
H10B H 0.744906 0.600912 -0.149495 0.091 Uiso 1 1 calc GR . . . .
H10C H 0.808753 0.543297 -0.080936 0.091 Uiso 1 1 calc GR . . . .
C107 C 0.4640(6) 0.4990(5) 0.4068(4) 0.049(2) Uani 1 1 d . . . . .
H107 H 0.487898 0.475699 0.452743 0.059 Uiso 1 1 calc R . . . .
N2 N 0.6618(6) 0.5238(5) -0.0756(4) 0.080(3) Uani 1 1 d D U . . .
C108 C 0.1843(6) 0.7919(5) -0.2072(6) 0.065(3) Uani 1 1 d . U . . .
H108 H 0.130773 0.792100 -0.200940 0.078 Uiso 1 1 calc R . . . .
C109 C 0.2063(6) 0.8235(5) -0.2731(6) 0.066(3) Uani 1 1 d . U . . .
H109 H 0.166793 0.847153 -0.311502 0.079 Uiso 1 1 calc R . . . .
C110 C 0.5996(8) 0.5037(6) -0.0342(7) 0.099(4) Uani 1 1 d D U . . .
H11A H 0.607125 0.499949 0.011030 0.149 Uiso 1 1 calc GR . . . .
H11B H 0.605002 0.452700 -0.028316 0.149 Uiso 1 1 calc GR . . . .
H11C H 0.544342 0.544567 -0.057151 0.149 Uiso 1 1 calc GR . . . .
F4 F 1.0797(3) 0.5703(2) -0.0038(2) 0.0445(11) Uani 1 1 d . . . . .
F5 F 0.2056(3) 0.6925(2) 0.0794(2) 0.0468(12) Uani 1 1 d . . . . .
F6 F 0.5292(3) 0.8265(3) -0.3941(2) 0.0472(12) Uani 1 1 d . . . . .
F7 F 0.5629(3) 0.9156(3) -0.47066(19) 0.0508(13) Uani 1 1 d . . . . .
F8 F 0.1081(3) 0.7927(3) 0.0833(3) 0.0520(12) Uani 1 1 d . . . . .
F9 F 0.1353(3) 0.7934(3) -0.0129(2) 0.0657(16) Uani 1 1 d . . . . .
F10 F 0.6565(3) 0.8028(3) -0.4045(3) 0.0757(18) Uani 1 1 d . . . . .
O14 O 0.5115(3) 0.9913(3) -0.1086(2) 0.0455(14) Uani 1 1 d . . . . .
F11 F 1.1364(4) 0.6121(3) 0.0404(4) 0.105(3) Uani 1 1 d . . . . .
C111 C 0.5828(5) 0.8583(4) -0.4063(4) 0.0315(17) Uani 1 1 d . . . . .
F12 F 1.1364(4) 0.6452(3) -0.0663(4) 0.116(3) Uani 1 1 d . . . . .
C112 C 0.7529(4) 0.4388(4) 0.2928(3) 0.0303(16) Uani 1 1 d . . . . .
H112 H 0.754414 0.445782 0.332360 0.036 Uiso 1 1 calc R . . . .
C113 C 1.0909(5) 0.6337(4) -0.0151(5) 0.042(2) Uani 1 1 d . . . . .
C114 C 0.9475(6) 0.5564(5) -0.2064(5) 0.059(3) Uani 1 1 d . . . . .
H11D H 1.007141 0.540793 -0.210305 0.088 Uiso 1 1 calc GR . . . .
H11E H 0.918511 0.576495 -0.251307 0.088 Uiso 1 1 calc GR . . . .
H11F H 0.938300 0.510458 -0.172376 0.088 Uiso 1 1 calc GR . . . .
C115 C 0.6939(8) 0.5018(7) -0.1291(6) 0.108(5) Uani 1 1 d D U . . .
H11G H 0.680217 0.549458 -0.173522 0.162 Uiso 1 1 calc GR . . . .
H11H H 0.669151 0.468937 -0.131001 0.162 Uiso 1 1 calc GR . . . .
H11I H 0.754423 0.471866 -0.119420 0.162 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag3 2.8754(6) . ?
Ag1 Ag4 2.9396(6) . ?
Ag1 Ag5 2.9577(7) . ?
Ag1 Ag7 3.1215(7) . ?
Ag1 S4 2.4355(16) . ?
Ag1 O1 2.193(4) . ?
Ag1 O2 2.555(5) 2_675 ?
Ag2 Ag7 2.9821(7) . ?
Ag2 Ag9 3.1999(6) . ?
Ag2 Ag14 2.8706(7) . ?
Ag2 S1 2.4304(16) . ?
Ag2 S2 2.4132(15) . ?
Ag3 Ag7 3.2067(7) . ?
Ag3 Ag13 2.9747(7) . ?
Ag3 S2 2.6511(17) . ?
Ag3 S4 2.5333(16) . ?
Ag3 S7 2.5577(14) . ?
Ag3 O11 2.413(4) . ?
Ag4 Ag5 2.9843(7) . ?
Ag4 Ag12 2.9391(7) . ?
Ag4 S3 2.4267(17) . ?
Ag4 S5 2.5595(15) . ?
Ag4 O12 2.281(4) . ?
Ag5 Ag15 3.0237(7) . ?
Ag5 S4 2.5363(15) . ?
Ag5 S5 2.6355(16) . ?
Ag5 S9 2.5515(16) . ?
Ag5 O10 2.392(4) . ?
Ag6 Ag10 3.0019(7) . ?
Ag6 Ag14 2.9295(6) . ?
Ag6 Ag15 3.2283(7) 2_675 ?
Ag6 S1 2.5861(15) . ?
Ag6 S8 2.5472(16) . ?
Ag6 O6 2.496(4) . ?
Ag6 O9 2.364(5) . ?
Ag7 S2 2.6254(15) . ?
Ag7 S3 2.4313(15) . ?
Ag7 O4 2.277(4) . ?
Ag8 Ag10 3.0187(7) . ?
Ag8 Ag12 2.8686(7) . ?
Ag8 Ag13 2.9282(6) 2_675 ?
Ag8 S6 2.6254(16) . ?
Ag8 S7 2.4454(15) 2_675 ?
Ag8 O5 2.301(4) . ?
Ag9 Ag12 3.3434(7) . ?
Ag9 S1 2.6008(16) . ?
Ag9 S3 2.5324(16) . ?
Ag9 S6 2.6457(16) . ?
Ag9 O13 2.517(5) . ?
Ag10 Ag13 3.0321(7) 2_675 ?
Ag10 S6 2.5600(16) . ?
Ag10 S8 2.5348(15) . ?
Ag10 O6 2.556(5) . ?
Ag10 O8 2.324(4) . ?
Ag11 S2 2.4388(15) . ?
Ag11 S5 2.4611(15) 2_675 ?
Ag11 O2 2.424(5) . ?
Ag11 O14 2.462(6) 2_675 ?
Ag12 S5 2.4199(17) . ?
Ag12 S6 2.4146(17) . ?
Ag13 S7 2.4431(17) . ?
Ag13 S8 2.4398(17) 2_675 ?
Ag14 Ag15 2.9342(7) 2_675 ?
Ag14 S1 2.5472(15) . ?
Ag14 S9 2.4415(15) 2_675 ?
Ag14 O7 2.346(5) . ?
Ag15 S8 2.4577(15) 2_675 ?
Ag15 S9 2.4534(15) . ?
Cr1 O1 1.578(4) . ?
Cr1 O2 1.528(5) . ?
Cr1 O3 1.537(5) . ?
Cr1 O14 1.542(5) . ?
S1 C19 1.845(6) . ?
S2 C45 1.838(6) . ?
S3 C36 1.847(6) . ?
S4 C21 1.854(6) . ?
S5 C30 1.837(6) . ?
S6 C13 1.857(6) . ?
S7 C56 1.855(6) . ?
S8 C9 1.850(6) . ?
S9 C58 1.839(7) . ?
C1 H1 0.9500 . ?
C1 C4 1.412(8) . ?
C1 C6 1.371(9) . ?
C2 H2 0.9500 . ?
C2 C26 1.368(9) . ?
C2 C31 1.423(9) . ?
C3 C14 1.444(9) . ?
C3 C15 1.412(9) . ?
C3 C52 1.406(9) . ?
C4 C29 1.376(8) . ?
C4 C45 1.510(9) . ?
C5 C8 1.433(8) . ?
C5 C12 1.361(8) . ?
C5 C19 1.502(8) . ?
C6 H6 0.9500 . ?
C6 C50 1.398(9) . ?
C7 H7 0.9500 . ?
C7 C11 1.363(8) . ?
C7 C27 1.429(10) . ?
C8 H8 0.9500 . ?
C8 C10 1.360(9) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C20 1.495(9) . ?
C10 H10 0.9500 . ?
C10 C43 1.411(9) . ?
C11 C13 1.495(8) . ?
C11 C17 1.425(9) . ?
C12 H12 0.9500 . ?
C12 C55 1.400(8) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C22 1.403(9) . ?
C14 C38 1.412(8) . ?
C15 H15 0.9500 . ?
C15 C48 1.371(9) . ?
C16 C33 1.376(8) . ?
C16 C41 1.420(8) . ?
C16 C56 1.489(9) . ?
C17 H17 0.9500 . ?
C17 C18 1.347(10) . ?
C18 H18 0.9500 . ?
C18 C61 1.445(10) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 C32 1.375(9) . ?
C20 C40 1.413(9) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C46 1.508(9) . ?
C22 H22 0.9500 . ?
C22 C57 1.375(9) . ?
C23 C30 1.475(8) . ?
C23 C38 1.371(9) . ?
C23 C48 1.430(9) . ?
C24 C32 1.414(10) . ?
C24 C64 1.420(10) . ?
C24 C66 1.413(9) . ?
C25 C33 1.414(9) . ?
C25 C37 1.412(9) . ?
C25 C71 1.421(9) . ?
C26 C58 1.503(10) . ?
C26 C98 1.403(10) . ?
C27 C60 1.415(10) . ?
C27 C61 1.415(11) . ?
C28 C29 1.416(9) . ?
C28 C35 1.420(9) . ?
C28 C50 1.431(9) . ?
C29 H29 0.9500 . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C72 1.414(9) . ?
C31 C80 1.417(9) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C34 C51 1.448(10) . ?
C34 C54 1.349(9) . ?
C35 H35 0.9500 . ?
C35 C83 1.366(12) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C36 C54 1.496(9) . ?
C37 C42 1.415(9) . ?
C37 C73 1.420(10) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
C39 C65 1.409(10) . ?
C39 C112 1.350(9) . ?
C40 H40 0.9500 . ?
C40 C88 1.359(10) . ?
C41 H41 0.9500 . ?
C41 C42 1.353(9) . ?
C42 H42 0.9500 . ?
C43 C55 1.431(8) . ?
C43 C112 1.430(9) . ?
C44 C49 1.429(9) . ?
C44 C74 1.416(9) . ?
C44 C102 1.398(11) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 C49 1.356(9) . ?
C46 C89 1.389(10) . ?
C47 C51 1.439(11) . ?
C47 C62 1.439(10) . ?
C47 C67 1.385(10) . ?
C48 H48 0.9500 . ?
C49 H49 0.9500 . ?
C50 C78 1.437(10) . ?
C51 C86 1.380(10) . ?
C52 H52 0.9500 . ?
C52 C63 1.373(10) . ?
C53 H53 0.9500 . ?
C53 C54 1.406(9) . ?
C53 C67 1.346(10) . ?
C55 C59 1.403(9) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 H57 0.9500 . ?
C57 C63 1.388(10) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 H59 0.9500 . ?
C59 C65 1.361(9) . ?
C60 H60 0.9500 . ?
C60 C109 1.380(13) . ?
C61 C103 1.413(11) . ?
C62 H62 0.9500 . ?
C62 C94 1.340(10) . ?
C63 H63 0.9500 . ?
C64 C79 1.443(11) . ?
C64 C88 1.400(9) . ?
C65 H65 0.9500 . ?
C66 H66 0.9500 . ?
C66 C100 1.388(11) . ?
C67 H67 0.9500 . ?
O4 C68 1.245(7) . ?
O5 C69 1.250(8) . ?
O6 C101 1.249(10) . ?
O7 C77 1.238(8) . ?
O8 C69 1.234(8) . ?
O9 C77 1.259(8) . ?
O10 C70 1.242(7) . ?
O11 C68 1.223(8) . ?
O12 C70 1.234(8) . ?
O13 C104 1.205(10) . ?
F1 C93 1.272(9) . ?
C68 C93 1.545(9) . ?
C69 C111 1.541(9) . ?
F2 C93 1.316(9) . ?
C70 C75 1.537(9) . ?
C71 H71 0.9500 . ?
C71 C76 1.372(10) . ?
C72 H72 0.9500 . ?
C72 C95 1.379(11) . ?
C73 H73 0.9500 . ?
C73 C85 1.372(10) . ?
C74 H74 0.9500 . ?
C74 C97 1.364(11) . ?
C75 F5 1.338(8) . ?
C75 F8 1.317(8) . ?
C75 F9 1.311(8) . ?
C76 H76 0.9500 . ?
C76 C85 1.396(10) . ?
C77 C113 1.514(10) . ?
C78 H78 0.9500 . ?
C78 C84 1.366(11) . ?
C79 H79 0.9500 . ?
C79 C96 1.356(11) . ?
C80 C90 1.389(11) . ?
C80 C105 1.428(11) . ?
N1 C82 1.461(9) . ?
N1 C101 1.298(11) . ?
N1 C114 1.489(10) . ?
F3 C93 1.323(10) . ?
C81 H81 0.9500 . ?
C81 C97 1.372(12) . ?
C81 C99 1.366(11) . ?
C82 H82A 0.9800 . ?
C82 H82B 0.9800 . ?
C82 H82C 0.9800 . ?
C83 H83 0.9500 . ?
C83 C84 1.401(12) . ?
C84 H84 0.9500 . ?
C85 H85 0.9500 . ?
C86 H86 0.9500 . ?
C86 C107 1.398(11) . ?
C87 H87 0.9500 . ?
C87 C89 1.355(11) . ?
C87 C102 1.435(10) . ?
C88 H88 0.9500 . ?
C89 H89 0.9500 . ?
C90 H90 0.9500 . ?
C90 C98 1.369(12) . ?
C91 H91 0.9500 . ?
C91 C95 1.402(12) . ?
C91 C105 1.345(12) . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C92 C101 1.540(11) . ?
C94 H94 0.9500 . ?
C94 C107 1.399(12) . ?
C95 H95 0.9500 . ?
C96 H96 0.9500 . ?
C96 C100 1.377(12) . ?
C97 H97 0.9500 . ?
C98 H98 0.9500 . ?
C99 H99 0.9500 . ?
C99 C102 1.406(10) . ?
C100 H100 0.9500 . ?
C103 H103 0.9500 . ?
C103 C108 1.359(13) . ?
C104 C106 1.526(12) . ?
C104 N2 1.380(8) . ?
C105 H105 0.9500 . ?
C106 H10A 0.9800 . ?
C106 H10B 0.9800 . ?
C106 H10C 0.9800 . ?
C107 H107 0.9500 . ?
N2 C110 1.436(8) . ?
N2 C115 1.434(8) . ?
C108 H108 0.9500 . ?
C108 C109 1.378(14) . ?
C109 H109 0.9500 . ?
C110 H11A 0.9800 . ?
C110 H11B 0.9800 . ?
C110 H11C 0.9800 . ?
F4 C113 1.337(8) . ?
F6 C111 1.324(8) . ?
F7 C111 1.325(8) . ?
F10 C111 1.330(8) . ?
F11 C113 1.320(9) . ?
F12 C113 1.305(10) . ?
C112 H112 0.9500 . ?
C114 H11D 0.9800 . ?
C114 H11E 0.9800 . ?
C114 H11F 0.9800 . ?
C115 H11G 0.9800 . ?
C115 H11H 0.9800 . ?
C115 H11I 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag3 Ag1 Ag4 135.38(2) . . ?
Ag3 Ag1 Ag5 110.21(2) . . ?
Ag3 Ag1 Ag7 64.499(16) . . ?
Ag4 Ag1 Ag5 60.800(16) . . ?
Ag4 Ag1 Ag7 86.209(17) . . ?
Ag5 Ag1 Ag7 127.13(2) . . ?
S4 Ag1 Ag3 56.25(4) . . ?
S4 Ag1 Ag4 94.38(4) . . ?
S4 Ag1 Ag5 55.08(4) . . ?
S4 Ag1 Ag7 91.64(4) . . ?
S4 Ag1 O2 88.19(13) . 2_675 ?
O1 Ag1 Ag3 121.05(11) . . ?
O1 Ag1 Ag4 84.65(10) . . ?
O1 Ag1 Ag5 128.46(11) . . ?
O1 Ag1 Ag7 82.63(11) . . ?
O1 Ag1 S4 174.24(12) . . ?
O1 Ag1 O2 97.41(17) . 2_675 ?
O2 Ag1 Ag3 99.60(10) 2_675 . ?
O2 Ag1 Ag4 113.42(11) 2_675 . ?
O2 Ag1 Ag5 67.77(12) 2_675 . ?
O2 Ag1 Ag7 160.33(11) 2_675 . ?
Ag7 Ag2 Ag9 82.983(17) . . ?
Ag14 Ag2 Ag7 169.92(2) . . ?
Ag14 Ag2 Ag9 104.972(19) . . ?
S1 Ag2 Ag7 127.65(4) . . ?
S1 Ag2 Ag9 52.90(4) . . ?
S1 Ag2 Ag14 56.71(4) . . ?
S2 Ag2 Ag7 57.07(4) . . ?
S2 Ag2 Ag9 134.91(4) . . ?
S2 Ag2 Ag14 117.41(4) . . ?
S2 Ag2 S1 171.67(6) . . ?
Ag1 Ag3 Ag7 61.472(15) . . ?
Ag1 Ag3 Ag13 108.98(2) . . ?
Ag13 Ag3 Ag7 164.73(2) . . ?
S2 Ag3 Ag1 77.36(3) . . ?
S2 Ag3 Ag7 52.21(3) . . ?
S2 Ag3 Ag13 140.52(4) . . ?
S4 Ag3 Ag1 53.07(4) . . ?
S4 Ag3 Ag7 87.92(4) . . ?
S4 Ag3 Ag13 76.89(4) . . ?
S4 Ag3 S2 128.34(5) . . ?
S4 Ag3 S7 128.64(5) . . ?
S7 Ag3 Ag1 138.44(4) . . ?
S7 Ag3 Ag7 143.40(4) . . ?
S7 Ag3 Ag13 51.75(4) . . ?
S7 Ag3 S2 96.95(5) . . ?
O11 Ag3 Ag1 122.53(12) . . ?
O11 Ag3 Ag7 69.05(11) . . ?
O11 Ag3 Ag13 111.64(12) . . ?
O11 Ag3 S2 94.77(13) . . ?
O11 Ag3 S4 99.85(13) . . ?
O11 Ag3 S7 98.84(12) . . ?
Ag1 Ag4 Ag5 59.899(16) . . ?
Ag12 Ag4 Ag1 87.001(17) . . ?
Ag12 Ag4 Ag5 104.733(19) . . ?
S3 Ag4 Ag1 75.50(4) . . ?
S3 Ag4 Ag5 129.76(4) . . ?
S3 Ag4 Ag12 94.12(4) . . ?
S3 Ag4 S5 137.62(5) . . ?
S5 Ag4 Ag1 78.20(4) . . ?
S5 Ag4 Ag5 56.14(4) . . ?
S5 Ag4 Ag12 51.66(4) . . ?
O12 Ag4 Ag1 140.45(12) . . ?
O12 Ag4 Ag5 84.80(12) . . ?
O12 Ag4 Ag12 121.28(12) . . ?
O12 Ag4 S3 123.80(13) . . ?
O12 Ag4 S5 97.46(13) . . ?
Ag1 Ag5 Ag4 59.301(16) . . ?
Ag1 Ag5 Ag15 100.602(18) . . ?
Ag4 Ag5 Ag15 158.67(2) . . ?
S4 Ag5 Ag1 51.94(4) . . ?
S4 Ag5 Ag4 91.24(4) . . ?
S4 Ag5 Ag15 69.05(4) . . ?
S4 Ag5 S5 128.48(5) . . ?
S4 Ag5 S9 120.18(5) . . ?
S5 Ag5 Ag1 76.73(4) . . ?
S5 Ag5 Ag4 53.75(4) . . ?
S5 Ag5 Ag15 133.22(4) . . ?
S9 Ag5 Ag1 129.24(4) . . ?
S9 Ag5 Ag4 146.07(4) . . ?
S9 Ag5 Ag15 51.37(4) . . ?
S9 Ag5 S5 93.84(5) . . ?
O10 Ag5 Ag1 126.42(12) . . ?
O10 Ag5 Ag4 75.89(12) . . ?
O10 Ag5 Ag15 116.45(11) . . ?
O10 Ag5 S4 106.14(12) . . ?
O10 Ag5 S5 100.43(11) . . ?
O10 Ag5 S9 104.30(13) . . ?
Ag10 Ag6 Ag15 94.235(18) . 2_675 ?
Ag14 Ag6 Ag10 133.20(2) . . ?
Ag14 Ag6 Ag15 56.663(15) . 2_675 ?
S1 Ag6 Ag10 102.94(4) . . ?
S1 Ag6 Ag14 54.58(3) . . ?
S1 Ag6 Ag15 98.55(4) . 2_675 ?
S8 Ag6 Ag10 53.60(3) . . ?
S8 Ag6 Ag14 104.88(4) . . ?
S8 Ag6 Ag15 48.63(3) . 2_675 ?
S8 Ag6 S1 128.32(5) . . ?
O6 Ag6 Ag10 54.48(11) . . ?
O6 Ag6 Ag14 152.88(11) . . ?
O6 Ag6 Ag15 146.57(11) . 2_675 ?
O6 Ag6 S1 99.84(11) . . ?
O6 Ag6 S8 98.46(11) . . ?
O9 Ag6 Ag10 150.66(11) . . ?
O9 Ag6 Ag14 75.48(10) . . ?
O9 Ag6 Ag15 99.89(11) . 2_675 ?
O9 Ag6 S1 100.23(11) . . ?
O9 Ag6 S8 121.29(11) . . ?
O9 Ag6 O6 103.98(15) . . ?
Ag1 Ag7 Ag3 54.029(14) . . ?
Ag2 Ag7 Ag1 80.199(17) . . ?
Ag2 Ag7 Ag3 97.965(18) . . ?
S2 Ag7 Ag1 73.42(4) . . ?
S2 Ag7 Ag2 50.49(3) . . ?
S2 Ag7 Ag3 52.94(4) . . ?
S3 Ag7 Ag1 71.97(4) . . ?
S3 Ag7 Ag2 84.98(4) . . ?
S3 Ag7 Ag3 124.10(4) . . ?
S3 Ag7 S2 127.13(5) . . ?
O4 Ag7 Ag1 137.16(11) . . ?
O4 Ag7 Ag2 121.82(12) . . ?
O4 Ag7 Ag3 84.95(11) . . ?
O4 Ag7 S2 92.57(11) . . ?
O4 Ag7 S3 139.29(11) . . ?
Ag12 Ag8 Ag10 97.57(2) . . ?
Ag12 Ag8 Ag13 99.742(19) . 2_675 ?
Ag13 Ag8 Ag10 61.287(16) 2_675 . ?
S6 Ag8 Ag10 53.40(4) . . ?
S6 Ag8 Ag12 51.91(4) . . ?
S6 Ag8 Ag13 97.37(4) . 2_675 ?
S7 Ag8 Ag10 114.08(4) 2_675 . ?
S7 Ag8 Ag12 99.09(4) 2_675 . ?
S7 Ag8 Ag13 53.17(4) 2_675 2_675 ?
S7 Ag8 S6 137.70(5) 2_675 . ?
O5 Ag8 Ag10 85.23(12) . . ?
O5 Ag8 Ag12 131.33(11) . . ?
O5 Ag8 Ag13 122.94(12) . 2_675 ?
O5 Ag8 S6 96.71(12) . . ?
O5 Ag8 S7 124.09(12) . 2_675 ?
Ag2 Ag9 Ag12 105.468(18) . . ?
S1 Ag9 Ag2 48.19(3) . . ?
S1 Ag9 Ag12 123.88(4) . . ?
S1 Ag9 S6 104.67(5) . . ?
S3 Ag9 Ag2 78.91(4) . . ?
S3 Ag9 Ag12 83.08(4) . . ?
S3 Ag9 S1 123.55(5) . . ?
S3 Ag9 S6 124.82(5) . . ?
S6 Ag9 Ag2 126.59(4) . . ?
S6 Ag9 Ag12 45.74(4) . . ?
O13 Ag9 Ag2 132.91(12) . . ?
O13 Ag9 Ag12 118.15(13) . . ?
O13 Ag9 S1 111.24(14) . . ?
O13 Ag9 S3 89.08(13) . . ?
O13 Ag9 S6 97.65(11) . . ?
Ag6 Ag10 Ag8 139.27(2) . . ?
Ag6 Ag10 Ag13 96.656(18) . 2_675 ?
Ag8 Ag10 Ag13 57.886(15) . 2_675 ?
S6 Ag10 Ag6 102.91(4) . . ?
S6 Ag10 Ag8 55.41(4) . . ?
S6 Ag10 Ag13 96.25(4) . 2_675 ?
S8 Ag10 Ag6 53.99(4) . . ?
S8 Ag10 Ag8 108.87(4) . . ?
S8 Ag10 Ag13 51.04(4) . 2_675 ?
S8 Ag10 S6 127.95(5) . . ?
S8 Ag10 O6 97.22(10) . . ?
O6 Ag10 Ag6 52.63(9) . . ?
O6 Ag10 Ag8 152.04(10) . . ?
O6 Ag10 Ag13 147.55(10) . 2_675 ?
O6 Ag10 S6 100.54(11) . . ?
O8 Ag10 Ag6 145.80(12) . . ?
O8 Ag10 Ag8 74.92(12) . . ?
O8 Ag10 Ag13 106.85(12) . 2_675 ?
O8 Ag10 S6 98.90(12) . . ?
O8 Ag10 S8 126.54(12) . . ?
O8 Ag10 O6 97.78(15) . . ?
S2 Ag11 S5 156.27(5) . 2_675 ?
S2 Ag11 O14 105.95(13) . 2_675 ?
S5 Ag11 O14 87.41(13) 2_675 2_675 ?
O2 Ag11 S2 108.50(12) . . ?
O2 Ag11 S5 90.85(12) . 2_675 ?
O2 Ag11 O14 89.23(19) . 2_675 ?
Ag4 Ag12 Ag9 77.023(17) . . ?
Ag8 Ag12 Ag4 166.67(2) . . ?
Ag8 Ag12 Ag9 108.27(2) . . ?
S5 Ag12 Ag4 56.05(4) . . ?
S5 Ag12 Ag8 121.81(4) . . ?
S5 Ag12 Ag9 129.32(4) . . ?
S6 Ag12 Ag4 121.56(4) . . ?
S6 Ag12 Ag8 58.85(4) . . ?
S6 Ag12 Ag9 51.69(4) . . ?
S6 Ag12 S5 173.46(5) . . ?
Ag3 Ag13 Ag10 159.14(2) . 2_675 ?
Ag8 Ag13 Ag3 104.09(2) 2_675 . ?
Ag8 Ag13 Ag10 60.828(16) 2_675 2_675 ?
S7 Ag13 Ag3 55.29(4) . . ?
S7 Ag13 Ag8 53.24(4) . 2_675 ?
S7 Ag13 Ag10 113.69(4) . 2_675 ?
S8 Ag13 Ag3 137.37(4) 2_675 . ?
S8 Ag13 Ag8 114.65(4) 2_675 2_675 ?
S8 Ag13 Ag10 53.88(4) 2_675 2_675 ?
S8 Ag13 S7 167.21(5) 2_675 . ?
Ag2 Ag14 Ag6 103.03(2) . . ?
Ag2 Ag14 Ag15 111.65(2) . 2_675 ?
Ag6 Ag14 Ag15 66.812(17) . 2_675 ?
S1 Ag14 Ag2 52.90(4) . . ?
S1 Ag14 Ag6 55.83(4) . . ?
S1 Ag14 Ag15 107.50(4) . 2_675 ?
S9 Ag14 Ag2 109.50(4) 2_675 . ?
S9 Ag14 Ag6 118.70(4) 2_675 . ?
S9 Ag14 Ag15 53.36(4) 2_675 2_675 ?
S9 Ag14 S1 150.83(6) 2_675 . ?
O7 Ag14 Ag2 124.78(12) . . ?
O7 Ag14 Ag6 86.22(10) . . ?
O7 Ag14 Ag15 121.67(11) . 2_675 ?
O7 Ag14 S1 95.89(12) . . ?
O7 Ag14 S9 112.81(12) . 2_675 ?
Ag5 Ag15 Ag6 156.97(2) . 2_675 ?
Ag14 Ag15 Ag5 102.333(19) 2_675 . ?
Ag14 Ag15 Ag6 56.526(15) 2_675 2_675 ?
S8 Ag15 Ag5 146.11(4) 2_675 . ?
S8 Ag15 Ag6 51.06(4) 2_675 2_675 ?
S8 Ag15 Ag14 107.16(4) 2_675 2_675 ?
S9 Ag15 Ag5 54.33(4) . . ?
S9 Ag15 Ag6 108.29(4) . 2_675 ?
S9 Ag15 Ag14 52.98(4) . 2_675 ?
S9 Ag15 S8 159.14(6) . 2_675 ?
O2 Cr1 O1 109.9(2) . . ?
O2 Cr1 O3 110.9(3) . . ?
O2 Cr1 O14 110.7(3) . . ?
O3 Cr1 O1 109.1(3) . . ?
O3 Cr1 O14 108.2(3) . . ?
O14 Cr1 O1 108.0(3) . . ?
Ag2 S1 Ag6 129.65(6) . . ?
Ag2 S1 Ag9 78.91(5) . . ?
Ag2 S1 Ag14 70.39(4) . . ?
Ag6 S1 Ag9 114.73(6) . . ?
Ag14 S1 Ag6 69.59(4) . . ?
Ag14 S1 Ag9 138.83(7) . . ?
C19 S1 Ag2 105.4(2) . . ?
C19 S1 Ag6 113.5(2) . . ?
C19 S1 Ag9 109.2(2) . . ?
C19 S1 Ag14 105.0(2) . . ?
Ag2 S2 Ag3 134.54(6) . . ?
Ag2 S2 Ag7 72.44(4) . . ?
Ag2 S2 Ag11 96.41(5) . . ?
Ag7 S2 Ag3 74.85(4) . . ?
Ag11 S2 Ag3 87.71(5) . . ?
Ag11 S2 Ag7 138.49(6) . . ?
C45 S2 Ag2 117.0(2) . . ?
C45 S2 Ag3 103.4(2) . . ?
C45 S2 Ag7 110.1(2) . . ?
C45 S2 Ag11 110.5(2) . . ?
Ag4 S3 Ag7 117.08(6) . . ?
Ag4 S3 Ag9 104.62(6) . . ?
Ag7 S3 Ag9 111.32(6) . . ?
C36 S3 Ag4 106.2(2) . . ?
C36 S3 Ag7 106.6(2) . . ?
C36 S3 Ag9 111.0(2) . . ?
Ag1 S4 Ag3 70.69(4) . . ?
Ag1 S4 Ag5 72.98(4) . . ?
Ag3 S4 Ag5 141.39(7) . . ?
C21 S4 Ag1 111.5(2) . . ?
C21 S4 Ag3 104.4(2) . . ?
C21 S4 Ag5 100.6(2) . . ?
Ag4 S5 Ag5 70.11(4) . . ?
Ag11 S5 Ag4 136.77(6) 2_675 . ?
Ag11 S5 Ag5 96.11(5) 2_675 . ?
Ag12 S5 Ag4 72.29(5) . . ?
Ag12 S5 Ag5 136.18(7) . . ?
Ag12 S5 Ag11 96.07(6) . 2_675 ?
C30 S5 Ag4 112.27(19) . . ?
C30 S5 Ag5 104.9(2) . . ?
C30 S5 Ag11 110.9(2) . 2_675 ?
C30 S5 Ag12 109.6(2) . . ?
Ag8 S6 Ag9 146.09(6) . . ?
Ag10 S6 Ag8 71.19(4) . . ?
Ag10 S6 Ag9 114.68(6) . . ?
Ag12 S6 Ag8 69.24(4) . . ?
Ag12 S6 Ag9 82.57(5) . . ?
Ag12 S6 Ag10 125.84(6) . . ?
C13 S6 Ag8 101.3(2) . . ?
C13 S6 Ag9 106.9(2) . . ?
C13 S6 Ag10 110.1(2) . . ?
C13 S6 Ag12 112.7(2) . . ?
Ag8 S7 Ag3 136.96(6) 2_675 . ?
Ag13 S7 Ag3 72.96(4) . . ?
Ag13 S7 Ag8 73.60(5) . 2_675 ?
C56 S7 Ag3 106.3(2) . . ?
C56 S7 Ag8 106.9(2) . 2_675 ?
C56 S7 Ag13 102.7(2) . . ?
Ag10 S8 Ag6 72.41(4) . . ?
Ag13 S8 Ag6 129.31(7) 2_675 . ?
Ag13 S8 Ag10 75.08(5) 2_675 . ?
Ag13 S8 Ag15 94.57(6) 2_675 2_675 ?
Ag15 S8 Ag6 80.32(5) 2_675 . ?
Ag15 S8 Ag10 132.39(7) 2_675 . ?
C9 S8 Ag6 110.6(2) . . ?
C9 S8 Ag10 107.6(2) . . ?
C9 S8 Ag13 115.8(2) . 2_675 ?
C9 S8 Ag15 118.4(2) . 2_675 ?
Ag14 S9 Ag5 136.72(7) 2_675 . ?
Ag14 S9 Ag15 73.66(4) 2_675 . ?
Ag15 S9 Ag5 74.30(5) . . ?
C58 S9 Ag5 108.4(3) . . ?
C58 S9 Ag14 108.4(3) . 2_675 ?
C58 S9 Ag15 107.4(2) . . ?
Cr1 O1 Ag1 126.2(2) . . ?
Ag11 O2 Ag1 106.21(18) . 2_675 ?
Cr1 O2 Ag1 118.2(3) . 2_675 ?
Cr1 O2 Ag11 129.5(3) . . ?
C4 C1 H1 119.1 . . ?
C6 C1 H1 119.1 . . ?
C6 C1 C4 121.8(6) . . ?
C26 C2 H2 119.3 . . ?
C26 C2 C31 121.5(6) . . ?
C31 C2 H2 119.3 . . ?
C15 C3 C14 117.8(6) . . ?
C52 C3 C14 118.9(6) . . ?
C52 C3 C15 123.3(6) . . ?
C1 C4 C45 122.4(5) . . ?
C29 C4 C1 118.4(6) . . ?
C29 C4 C45 119.2(6) . . ?
C8 C5 C19 119.4(5) . . ?
C12 C5 C8 118.7(5) . . ?
C12 C5 C19 121.9(6) . . ?
C1 C6 H6 119.7 . . ?
C1 C6 C50 120.6(6) . . ?
C50 C6 H6 119.7 . . ?
C11 C7 H7 119.4 . . ?
C11 C7 C27 121.1(7) . . ?
C27 C7 H7 119.4 . . ?
C5 C8 H8 120.0 . . ?
C10 C8 C5 120.0(5) . . ?
C10 C8 H8 120.0 . . ?
S8 C9 H9A 109.4 . . ?
S8 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
C20 C9 S8 111.2(4) . . ?
C20 C9 H9A 109.4 . . ?
C20 C9 H9B 109.4 . . ?
C8 C10 H10 119.2 . . ?
C8 C10 C43 121.6(5) . . ?
C43 C10 H10 119.2 . . ?
C7 C11 C13 120.9(6) . . ?
C7 C11 C17 119.5(6) . . ?
C17 C11 C13 119.6(6) . . ?
C5 C12 H12 118.6 . . ?
C5 C12 C55 122.9(5) . . ?
C55 C12 H12 118.6 . . ?
S6 C13 H13A 108.6 . . ?
S6 C13 H13B 108.6 . . ?
C11 C13 S6 114.6(4) . . ?
C11 C13 H13A 108.6 . . ?
C11 C13 H13B 108.6 . . ?
H13A C13 H13B 107.6 . . ?
C22 C14 C3 117.3(6) . . ?
C22 C14 C38 124.0(6) . . ?
C38 C14 C3 118.7(6) . . ?
C3 C15 H15 119.3 . . ?
C48 C15 C3 121.3(6) . . ?
C48 C15 H15 119.3 . . ?
C33 C16 C41 118.9(6) . . ?
C33 C16 C56 121.5(6) . . ?
C41 C16 C56 119.5(5) . . ?
C11 C17 H17 119.4 . . ?
C18 C17 C11 121.1(6) . . ?
C18 C17 H17 119.4 . . ?
C17 C18 H18 119.5 . . ?
C17 C18 C61 121.0(7) . . ?
C61 C18 H18 119.5 . . ?
S1 C19 H19A 109.0 . . ?
S1 C19 H19B 109.0 . . ?
C5 C19 S1 113.0(5) . . ?
C5 C19 H19A 109.0 . . ?
C5 C19 H19B 109.0 . . ?
H19A C19 H19B 107.8 . . ?
C32 C20 C9 121.4(6) . . ?
C32 C20 C40 118.9(6) . . ?
C40 C20 C9 119.7(6) . . ?
S4 C21 H21A 109.8 . . ?
S4 C21 H21B 109.8 . . ?
H21A C21 H21B 108.2 . . ?
C46 C21 S4 109.4(4) . . ?
C46 C21 H21A 109.8 . . ?
C46 C21 H21B 109.8 . . ?
C14 C22 H22 118.9 . . ?
C57 C22 C14 122.1(7) . . ?
C57 C22 H22 118.9 . . ?
C38 C23 C30 122.7(6) . . ?
C38 C23 C48 117.4(6) . . ?
C48 C23 C30 119.9(6) . . ?
C32 C24 C64 118.3(6) . . ?
C66 C24 C32 122.8(7) . . ?
C66 C24 C64 118.9(7) . . ?
C33 C25 C71 122.3(6) . . ?
C37 C25 C33 120.0(6) . . ?
C37 C25 C71 117.7(6) . . ?
C2 C26 C58 120.8(6) . . ?
C2 C26 C98 118.4(7) . . ?
C98 C26 C58 120.6(7) . . ?
C60 C27 C7 121.8(8) . . ?
C61 C27 C7 119.4(6) . . ?
C61 C27 C60 118.9(8) . . ?
C29 C28 C35 122.3(7) . . ?
C29 C28 C50 119.0(6) . . ?
C35 C28 C50 118.7(7) . . ?
C4 C29 C28 121.4(6) . . ?
C4 C29 H29 119.3 . . ?
C28 C29 H29 119.3 . . ?
S5 C30 H30A 109.4 . . ?
S5 C30 H30B 109.4 . . ?
C23 C30 S5 111.3(4) . . ?
C23 C30 H30A 109.4 . . ?
C23 C30 H30B 109.4 . . ?
H30A C30 H30B 108.0 . . ?
C72 C31 C2 121.6(7) . . ?
C72 C31 C80 119.9(7) . . ?
C80 C31 C2 118.5(6) . . ?
C20 C32 C24 121.3(7) . . ?
C20 C32 H32 119.4 . . ?
C24 C32 H32 119.4 . . ?
C16 C33 C25 120.7(6) . . ?
C16 C33 H33 119.6 . . ?
C25 C33 H33 119.6 . . ?
C51 C34 H34 120.0 . . ?
C54 C34 H34 120.0 . . ?
C54 C34 C51 120.0(7) . . ?
C28 C35 H35 119.6 . . ?
C83 C35 C28 120.9(8) . . ?
C83 C35 H35 119.6 . . ?
S3 C36 H36A 109.2 . . ?
S3 C36 H36B 109.2 . . ?
H36A C36 H36B 107.9 . . ?
C54 C36 S3 112.0(4) . . ?
C54 C36 H36A 109.2 . . ?
C54 C36 H36B 109.2 . . ?
C25 C37 C42 117.8(6) . . ?
C25 C37 C73 119.7(6) . . ?
C42 C37 C73 122.5(6) . . ?
C14 C38 H38 118.5 . . ?
C23 C38 C14 123.0(6) . . ?
C23 C38 H38 118.5 . . ?
C65 C39 H39 119.5 . . ?
C112 C39 H39 119.5 . . ?
C112 C39 C65 120.9(6) . . ?
C20 C40 H40 119.3 . . ?
C88 C40 C20 121.4(6) . . ?
C88 C40 H40 119.3 . . ?
C16 C41 H41 119.6 . . ?
C42 C41 C16 120.8(6) . . ?
C42 C41 H41 119.6 . . ?
C37 C42 H42 119.2 . . ?
C41 C42 C37 121.7(6) . . ?
C41 C42 H42 119.2 . . ?
C10 C43 C55 118.6(6) . . ?
C10 C43 C112 122.9(6) . . ?
C112 C43 C55 118.5(6) . . ?
C74 C44 C49 121.5(7) . . ?
C102 C44 C49 119.7(6) . . ?
C102 C44 C74 118.8(7) . . ?
S2 C45 H45A 108.4 . . ?
S2 C45 H45B 108.4 . . ?
C4 C45 S2 115.7(4) . . ?
C4 C45 H45A 108.4 . . ?
C4 C45 H45B 108.4 . . ?
H45A C45 H45B 107.4 . . ?
C49 C46 C21 121.2(7) . . ?
C49 C46 C89 119.5(6) . . ?
C89 C46 C21 119.3(6) . . ?
C51 C47 C62 117.3(7) . . ?
C67 C47 C51 120.4(7) . . ?
C67 C47 C62 122.4(7) . . ?
C15 C48 C23 121.7(6) . . ?
C15 C48 H48 119.1 . . ?
C23 C48 H48 119.1 . . ?
C44 C49 H49 119.6 . . ?
C46 C49 C44 120.8(7) . . ?
C46 C49 H49 119.6 . . ?
C6 C50 C28 118.7(6) . . ?
C6 C50 C78 122.8(7) . . ?
C28 C50 C78 118.4(6) . . ?
C47 C51 C34 117.0(6) . . ?
C86 C51 C34 121.9(8) . . ?
C86 C51 C47 121.1(7) . . ?
C3 C52 H52 119.3 . . ?
C63 C52 C3 121.4(7) . . ?
C63 C52 H52 119.3 . . ?
C54 C53 H53 119.3 . . ?
C67 C53 H53 119.3 . . ?
C67 C53 C54 121.4(7) . . ?
C34 C54 C36 120.4(6) . . ?
C34 C54 C53 120.8(7) . . ?
C53 C54 C36 118.7(6) . . ?
C12 C55 C43 118.1(5) . . ?
C12 C55 C59 123.5(6) . . ?
C59 C55 C43 118.3(6) . . ?
S7 C56 H56A 108.6 . . ?
S7 C56 H56B 108.6 . . ?
C16 C56 S7 114.8(4) . . ?
C16 C56 H56A 108.6 . . ?
C16 C56 H56B 108.6 . . ?
H56A C56 H56B 107.5 . . ?
C22 C57 H57 119.9 . . ?
C22 C57 C63 120.2(7) . . ?
C63 C57 H57 119.9 . . ?
S9 C58 H58A 108.3 . . ?
S9 C58 H58B 108.3 . . ?
C26 C58 S9 116.1(5) . . ?
C26 C58 H58A 108.3 . . ?
C26 C58 H58B 108.3 . . ?
H58A C58 H58B 107.4 . . ?
C55 C59 H59 119.1 . . ?
C65 C59 C55 121.8(6) . . ?
C65 C59 H59 119.1 . . ?
C27 C60 H60 120.2 . . ?
C109 C60 C27 119.6(9) . . ?
C109 C60 H60 120.2 . . ?
C27 C61 C18 117.9(7) . . ?
C103 C61 C18 122.8(8) . . ?
C103 C61 C27 119.3(8) . . ?
C47 C62 H62 120.0 . . ?
C94 C62 C47 120.0(8) . . ?
C94 C62 H62 120.0 . . ?
C52 C63 C57 120.1(6) . . ?
C52 C63 H63 119.9 . . ?
C57 C63 H63 119.9 . . ?
C24 C64 C79 118.7(7) . . ?
C88 C64 C24 119.8(7) . . ?
C88 C64 C79 121.5(7) . . ?
C39 C65 H65 120.1 . . ?
C59 C65 C39 119.8(6) . . ?
C59 C65 H65 120.1 . . ?
C24 C66 H66 119.8 . . ?
C100 C66 C24 120.4(8) . . ?
C100 C66 H66 119.8 . . ?
C47 C67 H67 119.8 . . ?
C53 C67 C47 120.4(8) . . ?
C53 C67 H67 119.8 . . ?
C68 O4 Ag7 116.1(4) . . ?
C69 O5 Ag8 116.6(4) . . ?
Ag6 O6 Ag10 72.90(11) . . ?
C101 O6 Ag6 154.8(6) . . ?
C101 O6 Ag10 132.2(5) . . ?
C77 O7 Ag14 115.6(4) . . ?
C69 O8 Ag10 127.5(4) . . ?
C77 O9 Ag6 125.0(4) . . ?
C70 O10 Ag5 125.9(4) . . ?
C68 O11 Ag3 129.1(4) . . ?
C70 O12 Ag4 119.7(4) . . ?
C104 O13 Ag9 125.3(5) . . ?
O4 C68 C93 114.5(6) . . ?
O11 C68 O4 131.1(6) . . ?
O11 C68 C93 114.4(6) . . ?
O5 C69 C111 112.8(6) . . ?
O8 C69 O5 131.0(6) . . ?
O8 C69 C111 116.2(6) . . ?
O10 C70 C75 116.3(6) . . ?
O12 C70 O10 130.2(6) . . ?
O12 C70 C75 113.5(6) . . ?
C25 C71 H71 119.3 . . ?
C76 C71 C25 121.3(6) . . ?
C76 C71 H71 119.3 . . ?
C31 C72 H72 119.9 . . ?
C95 C72 C31 120.3(8) . . ?
C95 C72 H72 119.9 . . ?
C37 C73 H73 119.5 . . ?
C85 C73 C37 121.0(7) . . ?
C85 C73 H73 119.5 . . ?
C44 C74 H74 119.7 . . ?
C97 C74 C44 120.5(8) . . ?
C97 C74 H74 119.7 . . ?
F5 C75 C70 110.6(6) . . ?
F8 C75 C70 113.9(5) . . ?
F8 C75 F5 106.3(6) . . ?
F9 C75 C70 111.8(6) . . ?
F9 C75 F5 106.9(6) . . ?
F9 C75 F8 106.9(6) . . ?
C71 C76 H76 119.6 . . ?
C71 C76 C85 120.9(6) . . ?
C85 C76 H76 119.6 . . ?
O7 C77 O9 129.5(6) . . ?
O7 C77 C113 116.2(6) . . ?
O9 C77 C113 114.2(6) . . ?
C50 C78 H78 119.7 . . ?
C84 C78 C50 120.6(8) . . ?
C84 C78 H78 119.7 . . ?
C64 C79 H79 120.2 . . ?
C96 C79 C64 119.7(8) . . ?
C96 C79 H79 120.2 . . ?
C31 C80 C105 117.1(7) . . ?
C90 C80 C31 119.1(7) . . ?
C90 C80 C105 123.8(7) . . ?
C82 N1 C114 117.3(7) . . ?
C101 N1 C82 120.5(7) . . ?
C101 N1 C114 122.2(7) . . ?
C97 C81 H81 119.8 . . ?
C99 C81 H81 119.8 . . ?
C99 C81 C97 120.4(8) . . ?
N1 C82 H82A 109.5 . . ?
N1 C82 H82B 109.5 . . ?
N1 C82 H82C 109.5 . . ?
H82A C82 H82B 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
C35 C83 H83 119.5 . . ?
C35 C83 C84 120.9(7) . . ?
C84 C83 H83 119.5 . . ?
C78 C84 C83 120.5(8) . . ?
C78 C84 H84 119.8 . . ?
C83 C84 H84 119.8 . . ?
C73 C85 C76 119.5(7) . . ?
C73 C85 H85 120.3 . . ?
C76 C85 H85 120.3 . . ?
C51 C86 H86 120.3 . . ?
C51 C86 C107 119.5(8) . . ?
C107 C86 H86 120.3 . . ?
C89 C87 H87 119.7 . . ?
C89 C87 C102 120.5(8) . . ?
C102 C87 H87 119.7 . . ?
C40 C88 C64 120.3(7) . . ?
C40 C88 H88 119.9 . . ?
C64 C88 H88 119.9 . . ?
C46 C89 H89 119.1 . . ?
C87 C89 C46 121.8(7) . . ?
C87 C89 H89 119.1 . . ?
C80 C90 H90 119.6 . . ?
C98 C90 C80 120.8(7) . . ?
C98 C90 H90 119.6 . . ?
C95 C91 H91 119.7 . . ?
C105 C91 H91 119.7 . . ?
C105 C91 C95 120.6(8) . . ?
H92A C92 H92B 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C101 C92 H92A 109.5 . . ?
C101 C92 H92B 109.5 . . ?
C101 C92 H92C 109.5 . . ?
F1 C93 C68 116.3(6) . . ?
F1 C93 F2 108.0(8) . . ?
F1 C93 F3 106.8(7) . . ?
F2 C93 C68 110.5(6) . . ?
F2 C93 F3 103.6(7) . . ?
F3 C93 C68 110.8(7) . . ?
C62 C94 H94 118.8 . . ?
C62 C94 C107 122.5(8) . . ?
C107 C94 H94 118.8 . . ?
C72 C95 C91 119.9(8) . . ?
C72 C95 H95 120.0 . . ?
C91 C95 H95 120.0 . . ?
C79 C96 H96 119.0 . . ?
C79 C96 C100 121.9(8) . . ?
C100 C96 H96 119.0 . . ?
C74 C97 C81 120.6(8) . . ?
C74 C97 H97 119.7 . . ?
C81 C97 H97 119.7 . . ?
C26 C98 H98 119.2 . . ?
C90 C98 C26 121.6(7) . . ?
C90 C98 H98 119.2 . . ?
C81 C99 H99 119.6 . . ?
C81 C99 C102 120.9(9) . . ?
C102 C99 H99 119.6 . . ?
C66 C100 H100 119.8 . . ?
C96 C100 C66 120.3(7) . . ?
C96 C100 H100 119.8 . . ?
O6 C101 N1 120.3(8) . . ?
O6 C101 C92 123.4(8) . . ?
N1 C101 C92 116.2(8) . . ?
C44 C102 C87 117.6(7) . . ?
C44 C102 C99 118.9(7) . . ?
C99 C102 C87 123.6(8) . . ?
C61 C103 H103 120.0 . . ?
C108 C103 C61 120.1(9) . . ?
C108 C103 H103 120.0 . . ?
O13 C104 C106 123.4(8) . . ?
O13 C104 N2 122.3(9) . . ?
N2 C104 C106 114.4(8) . . ?
C80 C105 H105 118.9 . . ?
C91 C105 C80 122.1(8) . . ?
C91 C105 H105 118.9 . . ?
C104 C106 H10A 109.5 . . ?
C104 C106 H10B 109.5 . . ?
C104 C106 H10C 109.5 . . ?
H10A C106 H10B 109.5 . . ?
H10A C106 H10C 109.5 . . ?
H10B C106 H10C 109.5 . . ?
C86 C107 C94 119.7(8) . . ?
C86 C107 H107 120.1 . . ?
C94 C107 H107 120.1 . . ?
C104 N2 C110 113.2(8) . . ?
C104 N2 C115 122.3(9) . . ?
C115 N2 C110 124.4(10) . . ?
C103 C108 H108 119.4 . . ?
C103 C108 C109 121.1(9) . . ?
C109 C108 H108 119.4 . . ?
C60 C109 H109 119.5 . . ?
C108 C109 C60 120.9(9) . . ?
C108 C109 H109 119.5 . . ?
N2 C110 H11A 109.5 . . ?
N2 C110 H11B 109.5 . . ?
N2 C110 H11C 109.5 . . ?
H11A C110 H11B 109.5 . . ?
H11A C110 H11C 109.5 . . ?
H11B C110 H11C 109.5 . . ?
Cr1 O14 Ag11 132.1(3) . 2_675 ?
F6 C111 C69 113.0(6) . . ?
F6 C111 F7 107.0(5) . . ?
F6 C111 F10 106.3(6) . . ?
F7 C111 C69 111.0(6) . . ?
F7 C111 F10 106.7(6) . . ?
F10 C111 C69 112.5(6) . . ?
C39 C112 C43 120.6(6) . . ?
C39 C112 H112 119.7 . . ?
C43 C112 H112 119.7 . . ?
F4 C113 C77 110.4(6) . . ?
F11 C113 C77 113.1(7) . . ?
F11 C113 F4 105.7(6) . . ?
F12 C113 C77 113.8(7) . . ?
F12 C113 F4 105.8(7) . . ?
F12 C113 F11 107.4(8) . . ?
N1 C114 H11D 109.5 . . ?
N1 C114 H11E 109.5 . . ?
N1 C114 H11F 109.5 . . ?
H11D C114 H11E 109.5 . . ?
H11D C114 H11F 109.5 . . ?
H11E C114 H11F 109.5 . . ?
N2 C115 H11G 109.5 . . ?
N2 C115 H11H 109.5 . . ?
N2 C115 H11I 109.5 . . ?
H11G C115 H11H 109.5 . . ?
H11G C115 H11I 109.5 . . ?
H11H C115 H11I 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S4 C21 C46 173.0(4) . . . . ?
Ag2 S1 C19 C5 33.5(5) . . . . ?
Ag2 S2 C45 C4 22.3(5) . . . . ?
Ag3 S2 C45 C4 -179.2(4) . . . . ?
Ag3 S4 C21 C46 98.5(4) . . . . ?
Ag3 S7 C56 C16 -86.8(4) . . . . ?
Ag3 O11 C68 O4 -34.2(11) . . . . ?
Ag3 O11 C68 C93 143.0(5) . . . . ?
Ag4 S3 C36 C54 -72.5(5) . . . . ?
Ag4 S5 C30 C23 -124.6(4) . . . . ?
Ag4 O12 C70 O10 10.6(10) . . . . ?
Ag4 O12 C70 C75 -170.1(4) . . . . ?
Ag5 S4 C21 C46 -111.2(4) . . . . ?
Ag5 S5 C30 C23 161.2(4) . . . . ?
Ag5 S9 C58 C26 70.2(6) . . . . ?
Ag5 O10 C70 O12 8.0(11) . . . . ?
Ag5 O10 C70 C75 -171.3(4) . . . . ?
Ag6 S1 C19 C5 -179.3(4) . . . . ?
Ag6 S8 C9 C20 32.8(5) . . . . ?
Ag6 O6 C101 N1 9.9(18) . . . . ?
Ag6 O6 C101 C92 -169.9(7) . . . . ?
Ag6 O9 C77 O7 -34.1(9) . . . . ?
Ag6 O9 C77 C113 142.9(5) . . . . ?
Ag7 S2 C45 C4 102.3(4) . . . . ?
Ag7 S3 C36 C54 53.0(5) . . . . ?
Ag7 O4 C68 O11 3.4(10) . . . . ?
Ag7 O4 C68 C93 -173.8(4) . . . . ?
Ag8 S6 C13 C11 -75.2(5) . . . . ?
Ag8 S7 C56 C16 65.4(4) 2_675 . . . ?
Ag8 O5 C69 O8 -9.7(9) . . . . ?
Ag8 O5 C69 C111 170.1(4) . . . . ?
Ag9 S1 C19 C5 -49.9(5) . . . . ?
Ag9 S3 C36 C54 174.4(4) . . . . ?
Ag9 S6 C13 C11 85.7(5) . . . . ?
Ag9 O13 C104 C106 30.3(11) . . . . ?
Ag9 O13 C104 N2 -149.4(6) . . . . ?
Ag10 S6 C13 C11 -149.1(4) . . . . ?
Ag10 S8 C9 C20 -44.5(5) . . . . ?
Ag10 O6 C101 N1 -176.5(5) . . . . ?
Ag10 O6 C101 C92 3.8(12) . . . . ?
Ag10 O8 C69 O5 27.8(10) . . . . ?
Ag10 O8 C69 C111 -152.0(4) . . . . ?
Ag11 S2 C45 C4 -86.6(5) . . . . ?
Ag11 S5 C30 C23 58.5(5) 2_675 . . . ?
Ag12 S5 C30 C23 -46.3(5) . . . . ?
Ag12 S6 C13 C11 -3.2(5) . . . . ?
Ag13 S7 C56 C16 -11.1(5) . . . . ?
Ag13 S8 C9 C20 -126.1(4) 2_675 . . . ?
Ag14 S1 C19 C5 106.8(4) . . . . ?
Ag14 S9 C58 C26 -86.7(6) 2_675 . . . ?
Ag14 O7 C77 O9 10.5(9) . . . . ?
Ag14 O7 C77 C113 -166.5(4) . . . . ?
Ag15 S8 C9 C20 122.7(4) 2_675 . . . ?
Ag15 S9 C58 C26 -8.6(6) . . . . ?
S3 C36 C54 C34 -85.3(7) . . . . ?
S3 C36 C54 C53 92.4(6) . . . . ?
S4 C21 C46 C49 -114.6(6) . . . . ?
S4 C21 C46 C89 66.5(7) . . . . ?
S8 C9 C20 C32 98.4(6) . . . . ?
S8 C9 C20 C40 -80.6(7) . . . . ?
O1 Cr1 O2 Ag1 -131.3(3) . . . 2_675 ?
O1 Cr1 O2 Ag11 17.3(5) . . . . ?
O1 Cr1 O14 Ag11 58.9(4) . . . 2_675 ?
O2 Cr1 O1 Ag1 52.8(4) . . . . ?
O2 Cr1 O14 Ag11 -61.4(4) . . . 2_675 ?
O3 Cr1 O1 Ag1 174.5(3) . . . . ?
O3 Cr1 O2 Ag1 108.0(3) . . . 2_675 ?
O3 Cr1 O2 Ag11 -103.4(4) . . . . ?
O3 Cr1 O14 Ag11 176.9(3) . . . 2_675 ?
C1 C4 C29 C28 0.8(8) . . . . ?
C1 C4 C45 S2 44.2(7) . . . . ?
C1 C6 C50 C28 -1.4(9) . . . . ?
C1 C6 C50 C78 -179.8(6) . . . . ?
C2 C26 C58 S9 -111.4(7) . . . . ?
C2 C26 C98 C90 -1.6(11) . . . . ?
C2 C31 C72 C95 -178.1(7) . . . . ?
C2 C31 C80 C90 -1.4(10) . . . . ?
C2 C31 C80 C105 178.3(7) . . . . ?
C3 C14 C22 C57 0.8(10) . . . . ?
C3 C14 C38 C23 -3.2(9) . . . . ?
C3 C15 C48 C23 0.0(10) . . . . ?
C3 C52 C63 C57 0.3(11) . . . . ?
C4 C1 C6 C50 0.1(9) . . . . ?
C5 C8 C10 C43 2.5(10) . . . . ?
C5 C12 C55 C43 0.0(10) . . . . ?
C5 C12 C55 C59 -178.0(7) . . . . ?
C6 C1 C4 C29 0.2(8) . . . . ?
C6 C1 C4 C45 178.3(5) . . . . ?
C6 C50 C78 C84 179.0(6) . . . . ?
C7 C11 C13 S6 118.5(5) . . . . ?
C7 C11 C17 C18 -1.1(10) . . . . ?
C7 C27 C60 C109 -178.2(7) . . . . ?
C7 C27 C61 C18 -0.6(10) . . . . ?
C7 C27 C61 C103 179.0(6) . . . . ?
C8 C5 C12 C55 -0.7(10) . . . . ?
C8 C5 C19 S1 -80.3(7) . . . . ?
C8 C10 C43 C55 -3.2(10) . . . . ?
C8 C10 C43 C112 177.5(6) . . . . ?
C9 C20 C32 C24 179.0(6) . . . . ?
C9 C20 C40 C88 -179.9(6) . . . . ?
C10 C43 C55 C12 1.9(9) . . . . ?
C10 C43 C55 C59 -179.9(6) . . . . ?
C10 C43 C112 C39 -178.2(7) . . . . ?
C11 C7 C27 C60 178.5(6) . . . . ?
C11 C7 C27 C61 -0.4(9) . . . . ?
C11 C17 C18 C61 0.0(10) . . . . ?
C12 C5 C8 C10 -0.5(9) . . . . ?
C12 C5 C19 S1 100.4(6) . . . . ?
C12 C55 C59 C65 178.0(7) . . . . ?
C13 C11 C17 C18 -178.5(6) . . . . ?
C14 C3 C15 C48 -0.4(9) . . . . ?
C14 C3 C52 C63 0.5(10) . . . . ?
C14 C22 C57 C63 -0.1(11) . . . . ?
C15 C3 C14 C22 -177.9(6) . . . . ?
C15 C3 C14 C38 1.8(9) . . . . ?
C15 C3 C52 C63 177.2(6) . . . . ?
C16 C41 C42 C37 -2.0(10) . . . . ?
C17 C11 C13 S6 -64.1(7) . . . . ?
C17 C18 C61 C27 0.8(10) . . . . ?
C17 C18 C61 C103 -178.8(7) . . . . ?
C18 C61 C103 C108 -180.0(7) . . . . ?
C19 C5 C8 C10 -179.9(6) . . . . ?
C19 C5 C12 C55 178.6(6) . . . . ?
C20 C40 C88 C64 0.8(11) . . . . ?
C21 C46 C49 C44 179.9(5) . . . . ?
C21 C46 C89 C87 -178.0(7) . . . . ?
C22 C14 C38 C23 176.5(6) . . . . ?
C22 C57 C63 C52 -0.5(11) . . . . ?
C24 C64 C79 C96 1.7(12) . . . . ?
C24 C64 C88 C40 -1.8(11) . . . . ?
C24 C66 C100 C96 -1.0(13) . . . . ?
C25 C37 C42 C41 2.3(10) . . . . ?
C25 C37 C73 C85 -0.6(11) . . . . ?
C25 C71 C76 C85 0.5(11) . . . . ?
C26 C2 C31 C72 179.8(6) . . . . ?
C26 C2 C31 C80 0.1(10) . . . . ?
C27 C7 C11 C13 178.7(6) . . . . ?
C27 C7 C11 C17 1.3(9) . . . . ?
C27 C60 C109 C108 -2.1(13) . . . . ?
C27 C61 C103 C108 0.4(11) . . . . ?
C28 C35 C83 C84 -1.0(11) . . . . ?
C28 C50 C78 C84 0.7(10) . . . . ?
C29 C4 C45 S2 -137.7(5) . . . . ?
C29 C28 C35 C83 179.3(6) . . . . ?
C29 C28 C50 C6 2.4(8) . . . . ?
C29 C28 C50 C78 -179.1(6) . . . . ?
C30 C23 C38 C14 -178.5(6) . . . . ?
C30 C23 C48 C15 -179.9(6) . . . . ?
C31 C2 C26 C58 -175.5(6) . . . . ?
C31 C2 C26 C98 1.4(10) . . . . ?
C31 C72 C95 C91 -1.6(12) . . . . ?
C31 C80 C90 C98 1.2(12) . . . . ?
C31 C80 C105 C91 1.4(12) . . . . ?
C32 C20 C40 C88 1.1(10) . . . . ?
C32 C24 C64 C79 -179.2(7) . . . . ?
C32 C24 C64 C88 0.9(10) . . . . ?
C32 C24 C66 C100 178.8(8) . . . . ?
C33 C16 C41 C42 -0.1(9) . . . . ?
C33 C16 C56 S7 -100.6(6) . . . . ?
C33 C25 C37 C42 -0.6(9) . . . . ?
C33 C25 C37 C73 179.0(6) . . . . ?
C33 C25 C71 C76 -179.0(6) . . . . ?
C34 C51 C86 C107 -178.6(6) . . . . ?
C35 C28 C29 C4 179.6(6) . . . . ?
C35 C28 C50 C6 -179.3(6) . . . . ?
C35 C28 C50 C78 -0.9(9) . . . . ?
C35 C83 C84 C78 0.7(12) . . . . ?
C37 C25 C33 C16 -1.4(9) . . . . ?
C37 C25 C71 C76 -0.5(10) . . . . ?
C37 C73 C85 C76 0.6(12) . . . . ?
C38 C14 C22 C57 -178.9(6) . . . . ?
C38 C23 C30 S5 -96.9(7) . . . . ?
C38 C23 C48 C15 -1.1(9) . . . . ?
C40 C20 C32 C24 -2.0(10) . . . . ?
C41 C16 C33 C25 1.8(9) . . . . ?
C41 C16 C56 S7 79.7(7) . . . . ?
C42 C37 C73 C85 179.0(7) . . . . ?
C43 C55 C59 C65 -0.1(11) . . . . ?
C44 C74 C97 C81 1.1(12) . . . . ?
C45 C4 C29 C28 -177.3(5) . . . . ?
C47 C51 C86 C107 1.0(10) . . . . ?
C47 C62 C94 C107 -0.2(11) . . . . ?
C48 C23 C30 S5 81.8(6) . . . . ?
C48 C23 C38 C14 2.8(9) . . . . ?
C49 C44 C74 C97 177.2(7) . . . . ?
C49 C44 C102 C87 2.1(10) . . . . ?
C49 C44 C102 C99 -178.0(6) . . . . ?
C49 C46 C89 C87 3.1(11) . . . . ?
C50 C28 C29 C4 -2.2(9) . . . . ?
C50 C28 C35 C83 1.0(10) . . . . ?
C50 C78 C84 C83 -0.6(11) . . . . ?
C51 C34 C54 C36 177.2(5) . . . . ?
C51 C34 C54 C53 -0.4(9) . . . . ?
C51 C47 C62 C94 1.0(9) . . . . ?
C51 C47 C67 C53 -0.7(10) . . . . ?
C51 C86 C107 C94 -0.2(11) . . . . ?
C52 C3 C14 C22 -0.9(9) . . . . ?
C52 C3 C14 C38 178.8(6) . . . . ?
C52 C3 C15 C48 -177.1(6) . . . . ?
C54 C34 C51 C47 1.0(9) . . . . ?
C54 C34 C51 C86 -179.4(6) . . . . ?
C54 C53 C67 C47 1.3(10) . . . . ?
C55 C43 C112 C39 2.6(10) . . . . ?
C55 C59 C65 C39 -1.0(12) . . . . ?
C56 C16 C33 C25 -177.9(5) . . . . ?
C56 C16 C41 C42 179.6(6) . . . . ?
C58 C26 C98 C90 175.3(7) . . . . ?
C60 C27 C61 C18 -179.5(6) . . . . ?
C60 C27 C61 C103 0.1(10) . . . . ?
C61 C27 C60 C109 0.8(11) . . . . ?
C61 C103 C108 C109 -1.8(13) . . . . ?
C62 C47 C51 C34 178.3(6) . . . . ?
C62 C47 C51 C86 -1.3(9) . . . . ?
C62 C47 C67 C53 -179.3(6) . . . . ?
C62 C94 C107 C86 -0.2(12) . . . . ?
C64 C24 C32 C20 1.0(10) . . . . ?
C64 C24 C66 C100 0.0(11) . . . . ?
C64 C79 C96 C100 -2.8(14) . . . . ?
C65 C39 C112 C43 -3.7(11) . . . . ?
C66 C24 C32 C20 -177.8(7) . . . . ?
C66 C24 C64 C79 -0.3(10) . . . . ?
C66 C24 C64 C88 179.8(7) . . . . ?
C67 C47 C51 C34 -0.4(9) . . . . ?
C67 C47 C51 C86 180.0(6) . . . . ?
C67 C47 C62 C94 179.6(7) . . . . ?
C67 C53 C54 C34 -0.7(9) . . . . ?
C67 C53 C54 C36 -178.4(6) . . . . ?
O4 C68 C93 F1 -14.8(11) . . . . ?
O4 C68 C93 F2 108.7(8) . . . . ?
O4 C68 C93 F3 -137.0(7) . . . . ?
O5 C69 C111 F6 -41.3(8) . . . . ?
O5 C69 C111 F7 78.9(7) . . . . ?
O5 C69 C111 F10 -161.6(6) . . . . ?
O7 C77 C113 F4 94.2(7) . . . . ?
O7 C77 C113 F11 -24.0(9) . . . . ?
O7 C77 C113 F12 -146.9(7) . . . . ?
O8 C69 C111 F6 138.5(6) . . . . ?
O8 C69 C111 F7 -101.3(7) . . . . ?
O8 C69 C111 F10 18.2(9) . . . . ?
O9 C77 C113 F4 -83.2(8) . . . . ?
O9 C77 C113 F11 158.6(7) . . . . ?
O9 C77 C113 F12 35.7(9) . . . . ?
O10 C70 C75 F5 -128.0(6) . . . . ?
O10 C70 C75 F8 -8.4(9) . . . . ?
O10 C70 C75 F9 113.0(7) . . . . ?
O11 C68 C93 F1 167.5(7) . . . . ?
O11 C68 C93 F2 -69.0(9) . . . . ?
O11 C68 C93 F3 45.3(9) . . . . ?
O12 C70 C75 F5 52.6(8) . . . . ?
O12 C70 C75 F8 172.2(6) . . . . ?
O12 C70 C75 F9 -66.4(8) . . . . ?
O13 C104 N2 C110 -3.1(13) . . . . ?
O13 C104 N2 C115 174.5(9) . . . . ?
C71 C25 C33 C16 177.0(6) . . . . ?
C71 C25 C37 C42 -179.2(6) . . . . ?
C71 C25 C37 C73 0.5(9) . . . . ?
C71 C76 C85 C73 -0.6(11) . . . . ?
C72 C31 C80 C90 178.9(7) . . . . ?
C72 C31 C80 C105 -1.4(10) . . . . ?
C73 C37 C42 C41 -177.3(7) . . . . ?
C74 C44 C49 C46 -179.4(6) . . . . ?
C74 C44 C102 C87 -179.9(7) . . . . ?
C74 C44 C102 C99 0.1(10) . . . . ?
C79 C64 C88 C40 178.3(7) . . . . ?
C79 C96 C100 C66 2.5(15) . . . . ?
C80 C31 C72 C95 1.6(11) . . . . ?
C80 C90 C98 C26 0.3(13) . . . . ?
C81 C99 C102 C44 0.3(11) . . . . ?
C81 C99 C102 C87 -179.7(8) . . . . ?
C82 N1 C101 O6 -1.4(13) . . . . ?
C82 N1 C101 C92 178.3(7) . . . . ?
C88 C64 C79 C96 -178.4(8) . . . . ?
C89 C46 C49 C44 -1.2(9) . . . . ?
C89 C87 C102 C44 -0.3(12) . . . . ?
C89 C87 C102 C99 179.8(8) . . . . ?
C90 C80 C105 C91 -178.9(8) . . . . ?
C95 C91 C105 C80 -1.5(13) . . . . ?
C97 C81 C99 C102 0.0(12) . . . . ?
C98 C26 C58 S9 71.8(8) . . . . ?
C99 C81 C97 C74 -0.7(13) . . . . ?
C102 C44 C49 C46 -1.4(9) . . . . ?
C102 C44 C74 C97 -0.8(10) . . . . ?
C102 C87 C89 C46 -2.4(13) . . . . ?
C103 C108 C109 C60 2.7(14) . . . . ?
C105 C80 C90 C98 -178.5(8) . . . . ?
C105 C91 C95 C72 1.6(13) . . . . ?
C106 C104 N2 C110 177.2(9) . . . . ?
C106 C104 N2 C115 -5.2(13) . . . . ?
O14 Cr1 O1 Ag1 -68.0(3) . . . . ?
O14 Cr1 O2 Ag1 -12.1(4) . . . 2_675 ?
O14 Cr1 O2 Ag11 136.5(4) . . . . ?
C112 C39 C65 C59 3.0(12) . . . . ?
C112 C43 C55 C12 -178.8(6) . . . . ?
C112 C43 C55 C59 -0.6(10) . . . . ?
C114 N1 C101 O6 179.5(8) . . . . ?
C114 N1 C101 C92 -0.8(12) . . . . ?

_shelx_SHELXL_version_number     2016/6
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 1869847'
_audit_update_record             
;
2018-11-05 deposited with the CCDC.
2018-11-09 downloaded from the CCDC.
;
_audit_creation_date             2018-10-26
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C106 H108 Ag14 F24 N6 O22 S6'
_chemical_formula_sum            'C106 H108 Ag14 F24 N6 O22 S6'
_chemical_formula_weight         3976.52
_chemical_melting_point          ?
_chemical_oxdiff_formula         C1H1O1S1Ag1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.109(13)
_cell_length_b                   26.729(9)
_cell_length_c                   29.365(13)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     13429(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    6879
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.1460
_cell_measurement_theta_min      3.0670
_shelx_estimated_absorpt_T_max   0.722
_shelx_estimated_absorpt_T_min   0.670
_exptl_absorpt_coefficient_mu    2.180
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.58082
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.967
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7728
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0421
_diffrn_reflns_av_unetI/netI     0.0529
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            32173
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         3.019
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -15.00   18.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  -99.0000   90.0000 66

#__ type_ start__ end____ width___ exp.time_
  2 omega   23.00   54.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323   19.0000   60.0000 62

#__ type_ start__ end____ width___ exp.time_
  3 omega   -4.00   82.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104   19.0000 -150.0000 172
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0328726000
_diffrn_orient_matrix_UB_12      -0.0042993000
_diffrn_orient_matrix_UB_13      -0.0145504000
_diffrn_orient_matrix_UB_21      0.0214981000
_diffrn_orient_matrix_UB_22      -0.0096064000
_diffrn_orient_matrix_UB_23      0.0188104000
_diffrn_orient_matrix_UB_31      -0.0145822000
_diffrn_orient_matrix_UB_32      -0.0238971000
_diffrn_orient_matrix_UB_33      -0.0049442000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7614
_reflns_number_total             11813
_reflns_odcompleteness_completeness 99.56
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS-1997 (Sheldrick, 2008)'
_refine_diff_density_max         1.159
_refine_diff_density_min         -1.035
_refine_diff_density_rms         0.119
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     808
_refine_ls_number_reflns         11813
_refine_ls_number_restraints     204
_refine_ls_R_factor_all          0.1028
_refine_ls_R_factor_gt           0.0626
_refine_ls_restrained_S_all      1.128
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0761P)²+27.9625P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1533
_refine_ls_wR_factor_ref         0.1727
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N1-C43
 1.32 with sigma of 0.01
 C42-C43
 1.53 with sigma of 0.01
 N1-C45
 1.46 with sigma of 0.01
 C2-C3 = C3-C4 = C4-C9 = C9-C10 = C10-C11 = C11-C2
 1.38 with sigma of 0.01
 C4-C5 = C5-C6 = C6-C7 = C7-C8 = C8-C9 = C9-C4
 1.38 with sigma of 0.01
 C40-C41
 1.55 with sigma of 0.01
 C18-C20 = C20-C22 = C13-C15
 2.35 with sigma of 0.01
 C15-C16 = C16-C17 = C17-C18 = C18-C19 = C19-C20 = C20-C15
 1.38 with sigma of 0.01
 C13-C14 = C14-C15 = C15-C20 = C20-C21 = C21-C22 = C22-C13
 1.38 with sigma of 0.01
 C41-F7 \\sim C41-F8 \\sim C41-F9
 with sigma of 0.01
3. Rigid bond restraints
 F2, C35, C7, C8, C4, C9, F1, C35, F9, C41, C40, C41, C30, C31
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 Ag1, S1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.0005
 Ag5, S3
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.0005
 Ag4, S1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.0005
 C17, C18, C28, C29, C15, C20, C4, C5, C14, C15, C18, C19, C15, C16
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 F7, C41, C29, C30, F10, C37, C20, C21, C10, C11, C26, C27
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 O9, C43, C9, C10, C42, C43, N1, C45, C5, C6, C21, C22, C31, C32
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 O3, C36, O4
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 O5, C38, O6
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
Uanis(F8) \\sim Ueq, Uanis(F1) \\sim Ueq, Uanis(F2) \\sim Ueq, Uanis(F10) \\sim
Ueq, Uanis(F11) \\sim Ueq, Uanis(C37) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(F9)
\\sim Ueq, Uanis(C29) \\sim Ueq, Uanis(C41) \\sim Ueq, Uanis(F7) \\sim Ueq:
with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C17) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C15) \\sim Ueq, Uanis(C20)
\\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C19) \\sim Ueq, Uanis(C18) \\sim Ueq,
Uanis(C22) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
5.a Riding coordinates:
 C44(H44A,H44B,H44C), C45(H45A,H45B,H45C), C46(H46A,H46B,H46C)
5.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C12(H12A,H12B), C23(H23A,H23B)
5.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C10(H10), C11(H11), C14(H14),
 C16(H16), C17(H17), C18(H18), C19(H19), C21(H21), C22(H22), C25(H25), C27(H27),
  C28(H28), C29(H29), C30(H30), C32(H32), C33(H33)
5.d Idealised Me refined as rotating group:
 C42(H42A,H42B,H42C), C48(H48A,H48B,H48C), C49(H49A,H49B,H49C), C50(H50A,H50B,
 H50C), C52(H52A,H52B,H52C), C53(H53A,H53B,H53C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.32501(5) 0.53321(3) 0.09136(3) 0.0787(3) Uani 1 1 d . U . . .
Ag2 Ag 0.46682(4) 0.47197(3) 0.10288(2) 0.0627(2) Uani 1 1 d . . . . .
Ag3 Ag 0.48147(4) 0.41391(3) 0.01551(2) 0.0614(2) Uani 1 1 d . . . . .
Ag4 Ag 0.33515(5) 0.41665(3) -0.04529(3) 0.0723(2) Uani 1 1 d . U . . .
Ag5 Ag 0.52003(6) 0.38780(3) -0.09221(3) 0.0883(3) Uani 1 1 d . U . . .
Ag6 Ag 0.61391(4) 0.47646(3) 0.04119(3) 0.0645(2) Uani 1 1 d . . . . .
Ag7 Ag 0.76240(5) 0.51573(3) -0.01044(3) 0.0737(2) Uani 1 1 d . . . . .
C1 C 0.3186(6) 0.3856(3) 0.0782(3) 0.066(3) Uani 1 1 d . . . . .
H1A H 0.287567 0.366243 0.056924 0.079 Uiso 1 1 calc R . . . .
H1B H 0.362942 0.365278 0.087307 0.079 Uiso 1 1 calc R . . . .
C2 C 0.2698(6) 0.3974(3) 0.1196(4) 0.075(3) Uani 1 1 d D . . . .
C3 C 0.1896(7) 0.4024(4) 0.1212(4) 0.108(5) Uani 1 1 d D . . . .
H3 H 0.159778 0.399924 0.094796 0.130 Uiso 1 1 calc R . . . .
C4 C 0.1531(7) 0.4115(4) 0.1646(4) 0.094(3) Uani 1 1 d D U . . .
C5 C 0.0734(8) 0.4152(5) 0.1655(5) 0.120(4) Uani 1 1 d D U . . .
H5 H 0.042492 0.412864 0.139534 0.144 Uiso 1 1 calc R . . . .
C6 C 0.0431(9) 0.4228(5) 0.2083(4) 0.133(6) Uani 1 1 d D U . . .
H6 H -0.010929 0.426146 0.209810 0.160 Uiso 1 1 calc R . . . .
C7 C 0.0822(10) 0.4262(5) 0.2497(5) 0.136(6) Uani 1 1 d D U . . .
H7 H 0.055636 0.431311 0.276950 0.163 Uiso 1 1 calc R . . . .
C8 C 0.1627(10) 0.4215(5) 0.2484(5) 0.146(6) Uani 1 1 d D U . . .
H8 H 0.193199 0.423299 0.274511 0.176 Uiso 1 1 calc R . . . .
C9 C 0.1957(8) 0.4138(4) 0.2048(4) 0.101(3) Uani 1 1 d D U . . .
C10 C 0.2757(8) 0.4097(5) 0.2042(4) 0.119(4) Uani 1 1 d D U . . .
H10 H 0.305876 0.412030 0.230434 0.143 Uiso 1 1 calc R . . . .
C11 C 0.3079(8) 0.4020(4) 0.1616(4) 0.112(5) Uani 1 1 d D U . . .
H11 H 0.362074 0.399390 0.160771 0.134 Uiso 1 1 calc R . . . .
C12 C 0.6262(7) 0.5299(3) 0.1523(3) 0.075(3) Uani 1 1 d . . . . .
H12A H 0.589690 0.519141 0.175657 0.090 Uiso 1 1 calc R . . . .
H12B H 0.664838 0.503731 0.148373 0.090 Uiso 1 1 calc R . . . .
C13 C 0.6660(8) 0.5772(4) 0.1674(4) 0.094(4) Uani 1 1 d D . . . .
C14 C 0.6281(9) 0.6124(5) 0.1936(5) 0.147(6) Uani 1 1 d D U . . .
H14 H 0.578173 0.607516 0.205317 0.176 Uiso 1 1 calc R . . . .
C15 C 0.6721(9) 0.6568(4) 0.2013(5) 0.129(4) Uani 1 1 d D U . . .
C16 C 0.6338(11) 0.6948(6) 0.2237(6) 0.165(5) Uani 1 1 d D U . . .
H16 H 0.583301 0.690000 0.234553 0.198 Uiso 1 1 calc R . . . .
C17 C 0.6712(11) 0.7404(6) 0.2299(6) 0.165(5) Uani 1 1 d D U . . .
H17 H 0.645985 0.766371 0.244913 0.199 Uiso 1 1 calc R . . . .
C18 C 0.7456(10) 0.7467(5) 0.2136(6) 0.161(5) Uani 1 1 d D U . . .
H18 H 0.768561 0.777920 0.217444 0.193 Uiso 1 1 calc R . . . .
C19 C 0.7893(9) 0.7104(5) 0.1919(6) 0.149(5) Uani 1 1 d D U . . .
H19 H 0.841080 0.714725 0.183093 0.179 Uiso 1 1 calc R . . . .
C20 C 0.7461(9) 0.6659(4) 0.1846(5) 0.134(4) Uani 1 1 d D U . . .
C21 C 0.7837(8) 0.6300(5) 0.1600(6) 0.153(5) Uani 1 1 d D U . . .
H21 H 0.834742 0.634101 0.149866 0.183 Uiso 1 1 calc R . . . .
C22 C 0.7412(8) 0.5869(4) 0.1511(5) 0.130(5) Uani 1 1 d D U . . .
H22 H 0.764498 0.562647 0.132844 0.156 Uiso 1 1 calc R . . . .
C23 C 0.6735(9) 0.3697(5) -0.0040(4) 0.110(5) Uani 1 1 d . . . . .
H23A H 0.714820 0.384320 0.014266 0.131 Uiso 1 1 calc R . . . .
H23B H 0.642643 0.348280 0.015658 0.131 Uiso 1 1 calc R . . . .
C24 C 0.7083(7) 0.3395(4) -0.0396(3) 0.069(3) Uani 1 1 d . . . . .
C25 C 0.7769(8) 0.3485(4) -0.0615(4) 0.089(3) Uani 1 1 d . . . . .
H25 H 0.804036 0.377960 -0.055402 0.107 Uiso 1 1 calc R . . . .
C26 C 0.8091(8) 0.3126(4) -0.0946(4) 0.086(3) Uani 1 1 d . U . . .
C27 C 0.8800(11) 0.3211(6) -0.1139(6) 0.139(6) Uani 1 1 d . U . . .
H27 H 0.905540 0.351202 -0.108398 0.167 Uiso 1 1 calc R . . . .
C28 C 0.9134(10) 0.2872(8) -0.1404(6) 0.145(6) Uani 1 1 d . U . . .
H28 H 0.963878 0.291895 -0.151331 0.174 Uiso 1 1 calc R . . . .
C29 C 0.8719(14) 0.2453(8) -0.1515(6) 0.148(6) Uani 1 1 d . U . . .
H29 H 0.894554 0.223640 -0.172395 0.177 Uiso 1 1 calc R . . . .
C30 C 0.8017(11) 0.2324(5) -0.1350(6) 0.130(5) Uani 1 1 d . U . . .
H30 H 0.776076 0.203179 -0.143481 0.156 Uiso 1 1 calc R . . . .
C31 C 0.7678(8) 0.2696(5) -0.1015(5) 0.097(4) Uani 1 1 d . U . . .
C32 C 0.6986(9) 0.2600(5) -0.0811(7) 0.130(5) Uani 1 1 d . U . . .
H32 H 0.671346 0.230745 -0.087647 0.156 Uiso 1 1 calc R . . . .
C33 C 0.6693(8) 0.2944(5) -0.0505(6) 0.118(5) Uani 1 1 d . . . . .
H33 H 0.621768 0.287594 -0.036393 0.141 Uiso 1 1 calc R . . . .
C34 C 0.3877(7) 0.5250(4) 0.1898(3) 0.073(3) Uani 1 1 d . . . . .
C35 C 0.3787(11) 0.5345(6) 0.2408(5) 0.123(5) Uani 1 1 d . U . . .
C36 C 0.5487(6) 0.3688(4) 0.1135(3) 0.071(2) Uani 1 1 d . U . . .
C37 C 0.5930(9) 0.3292(5) 0.1384(5) 0.098(4) Uani 1 1 d . U . . .
C38 C 0.7925(8) 0.4479(4) 0.0740(5) 0.087(3) Uani 1 1 d . U . . .
C39 C 0.8452(9) 0.4206(6) 0.1066(6) 0.114(5) Uani 1 1 d . . . . .
C40 C 0.1616(8) 0.3854(6) -0.0217(5) 0.101(4) Uani 1 1 d D U . . .
C41 C 0.0990(8) 0.3443(5) -0.0245(5) 0.138(5) Uani 1 1 d D U . . .
C42 C 0.1436(10) 0.5501(5) 0.1616(5) 0.148(5) Uani 1 1 d D U . . .
H42A H 0.153596 0.585378 0.163809 0.222 Uiso 1 1 calc GR . . . .
H42B H 0.187312 0.531932 0.173681 0.222 Uiso 1 1 calc GR . . . .
H42C H 0.097441 0.541990 0.178636 0.222 Uiso 1 1 calc GR . . . .
C43 C 0.1316(8) 0.5359(5) 0.1118(5) 0.134(4) Uani 1 1 d D U . . .
C44 C -0.0075(9) 0.5477(6) 0.1336(6) 0.148(7) Uani 1 1 d . . . . .
H44A H -0.010308 0.522498 0.156802 0.222 Uiso 1 1 d R . . . .
H44B H -0.056688 0.549668 0.117982 0.222 Uiso 1 1 d R . . . .
H44C H 0.004062 0.579478 0.147312 0.222 Uiso 1 1 d R . . . .
C45 C 0.0494(8) 0.5199(6) 0.0553(5) 0.147(5) Uani 1 1 d D U . . .
H45A H 0.099924 0.518982 0.041165 0.220 Uiso 1 1 d R . . . .
H45B H 0.016734 0.543502 0.039595 0.220 Uiso 1 1 d R . . . .
H45C H 0.025964 0.487302 0.053895 0.220 Uiso 1 1 d R . . . .
C46 C 0.4412(8) 0.2725(4) 0.0217(4) 0.096(4) Uani 1 1 d . . . . .
H46A H 0.475022 0.245425 0.013258 0.143 Uiso 1 1 d R . . . .
H46B H 0.399761 0.260135 0.040598 0.143 Uiso 1 1 d R . . . .
H46C H 0.470602 0.297235 0.038138 0.143 Uiso 1 1 d R . . . .
C47 C 0.4067(6) 0.2968(4) -0.0219(4) 0.078(3) Uani 1 1 d . . . . .
C48 C 0.3432(10) 0.2188(4) -0.0395(5) 0.143(7) Uani 1 1 d . . . . .
H48A H 0.385459 0.202629 -0.023868 0.215 Uiso 1 1 calc GR . . . .
H48B H 0.333040 0.201737 -0.067648 0.215 Uiso 1 1 calc GR . . . .
H48C H 0.297215 0.218064 -0.020813 0.215 Uiso 1 1 calc GR . . . .
C49 C 0.3309(8) 0.2933(4) -0.0903(4) 0.104(4) Uani 1 1 d . . . . .
H49A H 0.371535 0.309708 -0.107164 0.156 Uiso 1 1 calc GR . . . .
H49B H 0.291800 0.317330 -0.081791 0.156 Uiso 1 1 calc GR . . . .
H49C H 0.307555 0.267762 -0.108810 0.156 Uiso 1 1 calc GR . . . .
C50 C 0.6231(10) 0.3249(5) -0.1826(5) 0.130(5) Uani 1 1 d . . . . .
H50A H 0.629985 0.356973 -0.168539 0.195 Uiso 1 1 calc GR . . . .
H50B H 0.605148 0.329276 -0.213317 0.195 Uiso 1 1 calc GR . . . .
H50C H 0.671987 0.307255 -0.182792 0.195 Uiso 1 1 calc GR . . . .
C51 C 0.5644(8) 0.2955(4) -0.1565(4) 0.095(4) Uani 1 1 d . . . . .
C52 C 0.5033(10) 0.2187(5) -0.1391(6) 0.147(6) Uani 1 1 d . . . . .
H52A H 0.468874 0.240197 -0.122364 0.220 Uiso 1 1 calc GR . . . .
H52B H 0.533507 0.198864 -0.118295 0.220 Uiso 1 1 calc GR . . . .
H52C H 0.473172 0.197051 -0.158440 0.220 Uiso 1 1 calc GR . . . .
C53 C 0.5975(12) 0.2239(5) -0.2045(5) 0.170(8) Uani 1 1 d . . . . .
H53A H 0.562164 0.218107 -0.229395 0.255 Uiso 1 1 calc GR . . . .
H53B H 0.618373 0.192521 -0.194250 0.255 Uiso 1 1 calc GR . . . .
H53C H 0.639435 0.245071 -0.214535 0.255 Uiso 1 1 calc GR . . . .
F1 F 0.4176(9) 0.5720(4) 0.2540(3) 0.213(5) Uani 1 1 d . U . . .
F2 F 0.3107(9) 0.5515(7) 0.2510(4) 0.252(6) Uani 1 1 d . U . . .
F3 F 0.3904(8) 0.5012(3) 0.2680(2) 0.180(5) Uani 1 1 d . . . . .
F4 F 0.9129(6) 0.4107(6) 0.0909(5) 0.249(9) Uani 1 1 d . . . . .
F5 F 0.8597(11) 0.4433(5) 0.1415(5) 0.285(11) Uani 1 1 d . . . . .
F6 F 0.8226(8) 0.3786(5) 0.1167(5) 0.225(6) Uani 1 1 d . . . . .
F7 F 0.0669(11) 0.3361(7) 0.0115(6) 0.285(8) Uani 1 1 d D U . . .
F8 F 0.0498(9) 0.3514(5) -0.0535(6) 0.272(7) Uani 1 1 d D U . . .
F9 F 0.1212(8) 0.3028(5) -0.0362(6) 0.243(6) Uani 1 1 d D U . . .
F10 F 0.6606(6) 0.3400(4) 0.1510(5) 0.223(6) Uani 1 1 d . U . . .
F11 F 0.5940(9) 0.2883(4) 0.1186(4) 0.232(6) Uani 1 1 d . U . . .
F12 F 0.5649(8) 0.3147(4) 0.1749(4) 0.216(6) Uani 1 1 d . . . . .
N1 N 0.0581(7) 0.5354(5) 0.1035(5) 0.158(5) Uani 1 1 d D U . . .
N2 N 0.3643(6) 0.2705(3) -0.0490(4) 0.095(3) Uani 1 1 d . . . . .
N3 N 0.5550(8) 0.2485(4) -0.1666(4) 0.118(4) Uani 1 1 d . . . . .
O1 O 0.3444(6) 0.5494(3) 0.1653(2) 0.101(3) Uani 1 1 d . . . . .
O2 O 0.4359(5) 0.4944(3) 0.1805(2) 0.095(2) Uani 1 1 d . . . . .
O3 O 0.5296(6) 0.4041(3) 0.1365(3) 0.125(4) Uani 1 1 d . U . . .
O4 O 0.5372(6) 0.3604(3) 0.0735(2) 0.101(3) Uani 1 1 d . U . . .
O5 O 0.7221(6) 0.4476(4) 0.0858(3) 0.134(3) Uani 1 1 d . U . . .
O6 O 0.8206(5) 0.4636(4) 0.0397(4) 0.130(4) Uani 1 1 d . U . . .
O7 O 0.2266(6) 0.3713(3) -0.0349(4) 0.128(3) Uani 1 1 d . . . . .
O8 O 0.1413(5) 0.4222(4) -0.0040(5) 0.166(6) Uani 1 1 d . . . . .
O9 O 0.1838(4) 0.5254(3) 0.0831(3) 0.091(2) Uani 1 1 d . U . . .
O10 O 0.4220(5) 0.3412(2) -0.0297(2) 0.081(2) Uani 1 1 d . . . . .
O11 O 0.5261(6) 0.3143(3) -0.1253(3) 0.115(3) Uani 1 1 d . . . . .
S1 S 0.35453(12) 0.44291(8) 0.04950(8) 0.0561(5) Uani 1 1 d . U . . .
S2 S 0.57283(15) 0.53971(8) 0.09789(7) 0.0590(6) Uani 1 1 d . . . . .
S3 S 0.61052(14) 0.42036(8) -0.02593(8) 0.0584(5) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 2.9462(19) . ?
Ag1 Ag7 3.0973(15) 5_665 ?
Ag1 O1 2.239(7) . ?
Ag1 O9 2.437(8) . ?
Ag1 S1 2.755(3) . ?
Ag1 S3 2.539(2) 5_665 ?
Ag2 Ag3 3.0088(14) . ?
Ag2 Ag6 3.1029(19) . ?
Ag2 O2 2.415(7) . ?
Ag2 O3 2.328(7) . ?
Ag2 S1 2.598(3) . ?
Ag2 S2 2.567(3) . ?
Ag3 Ag4 3.0758(19) . ?
Ag3 Ag5 3.3058(17) . ?
Ag3 Ag6 2.9151(17) . ?
Ag3 O4 2.419(7) . ?
Ag3 O10 2.565(6) . ?
Ag3 S1 2.513(3) . ?
Ag3 S3 2.527(3) . ?
Ag4 Ag6 2.9895(14) 5_665 ?
Ag4 Ag7 2.9548(14) 5_665 ?
Ag4 O7 2.239(9) . ?
Ag4 O10 2.546(7) . ?
Ag4 S1 2.890(3) . ?
Ag4 S2 2.495(3) 5_665 ?
Ag5 O11 2.194(7) . ?
Ag5 S2 2.511(3) 5_665 ?
Ag5 S3 2.635(3) . ?
Ag6 Ag7 3.1393(19) . ?
Ag6 O5 2.396(9) . ?
Ag6 S2 2.475(2) . ?
Ag6 S3 2.477(3) . ?
Ag7 O6 2.259(9) . ?
Ag7 O8 2.375(9) 5_665 ?
Ag7 O9 2.570(8) 5_665 ?
Ag7 S1 2.557(3) 5_665 ?
C1 C2 1.508(13) . ?
C1 S1 1.854(8) . ?
C2 C3 1.380(9) . ?
C2 C11 1.400(9) . ?
C3 C4 1.440(9) . ?
C4 C5 1.368(9) . ?
C4 C9 1.389(7) . ?
C5 C6 1.375(9) . ?
C6 C7 1.391(9) . ?
C7 C8 1.382(9) . ?
C8 C9 1.414(9) . ?
C9 C10 1.373(9) . ?
C10 C11 1.382(9) . ?
C12 C13 1.503(14) . ?
C12 S2 1.860(9) . ?
C13 C14 1.376(9) . ?
C13 C22 1.398(9) . ?
C14 C15 1.425(9) . ?
C15 C16 1.376(9) . ?
C15 C20 1.379(7) . ?
C16 C17 1.387(9) . ?
C17 C18 1.371(9) . ?
C18 C19 1.378(9) . ?
C19 C20 1.418(9) . ?
C20 C21 1.362(9) . ?
C21 C22 1.387(9) . ?
C23 C24 1.451(14) . ?
C23 S3 1.846(10) . ?
C24 C25 1.359(15) . ?
C24 C33 1.415(17) . ?
C25 C26 1.474(15) . ?
C26 C27 1.359(19) . ?
C26 C31 1.363(17) . ?
C27 C28 1.32(2) . ?
C28 C29 1.36(2) . ?
C29 C30 1.34(2) . ?
C30 C31 1.516(19) . ?
C31 C32 1.350(19) . ?
C32 C33 1.38(2) . ?
C34 C35 1.526(15) . ?
C34 O1 1.222(12) . ?
C34 O2 1.194(12) . ?
C35 F1 1.264(18) . ?
C35 F2 1.285(19) . ?
C35 F3 1.212(15) . ?
C36 C37 1.493(15) . ?
C36 O3 1.206(12) . ?
C36 O4 1.214(12) . ?
C37 F10 1.248(15) . ?
C37 F11 1.237(15) . ?
C37 F12 1.237(16) . ?
C38 C39 1.504(17) . ?
C38 O5 1.255(15) . ?
C38 O6 1.190(15) . ?
C39 F4 1.27(2) . ?
C39 F5 1.216(18) . ?
C39 F6 1.224(15) . ?
C40 C41 1.538(9) . ?
C40 O7 1.236(16) . ?
C40 O8 1.165(16) . ?
C41 F7 1.211(9) . ?
C41 F8 1.213(9) . ?
C41 F9 1.220(9) . ?
C42 C43 1.525(9) . ?
C43 N1 1.281(9) . ?
C43 O9 1.259(15) . ?
C44 N1 1.466(17) . ?
C45 N1 1.483(9) . ?
C46 C47 1.552(15) . ?
C47 N2 1.285(14) . ?
C47 O10 1.237(12) . ?
C48 N2 1.453(14) . ?
C49 N2 1.474(15) . ?
C50 C51 1.487(18) . ?
C51 N3 1.300(14) . ?
C51 O11 1.233(14) . ?
C52 N3 1.439(17) . ?
C53 N3 1.484(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag7 104.54(4) . 5_665 ?
O1 Ag1 Ag2 82.8(2) . . ?
O1 Ag1 Ag7 153.8(2) . 5_665 ?
O1 Ag1 O9 105.1(3) . . ?
O1 Ag1 S1 125.1(2) . . ?
O1 Ag1 S3 125.1(2) . 5_665 ?
O9 Ag1 Ag2 141.26(18) . . ?
O9 Ag1 Ag7 53.75(19) . 5_665 ?
O9 Ag1 S1 93.55(19) . . ?
O9 Ag1 S3 113.4(2) . 5_665 ?
S1 Ag1 Ag2 54.10(5) . . ?
S1 Ag1 Ag7 51.41(5) . 5_665 ?
S3 Ag1 Ag2 90.04(6) 5_665 . ?
S3 Ag1 Ag7 80.54(7) 5_665 5_665 ?
S3 Ag1 S1 90.63(7) 5_665 . ?
Ag1 Ag2 Ag3 104.91(3) . . ?
Ag1 Ag2 Ag6 125.41(4) . . ?
Ag3 Ag2 Ag6 56.95(3) . . ?
O2 Ag2 Ag1 77.9(2) . . ?
O2 Ag2 Ag3 162.0(2) . . ?
O2 Ag2 Ag6 135.9(2) . . ?
O2 Ag2 S1 118.8(2) . . ?
O2 Ag2 S2 91.9(2) . . ?
O3 Ag2 Ag1 149.5(3) . . ?
O3 Ag2 Ag3 85.5(2) . . ?
O3 Ag2 Ag6 84.5(3) . . ?
O3 Ag2 O2 83.9(3) . . ?
O3 Ag2 S1 111.4(3) . . ?
O3 Ag2 S2 104.4(3) . . ?
S1 Ag2 Ag1 59.20(6) . . ?
S1 Ag2 Ag3 52.63(6) . . ?
S1 Ag2 Ag6 105.01(7) . . ?
S2 Ag2 Ag1 100.57(8) . . ?
S2 Ag2 Ag3 104.85(6) . . ?
S2 Ag2 Ag6 50.68(6) . . ?
S2 Ag2 S1 134.34(7) . . ?
Ag2 Ag3 Ag4 114.51(4) . . ?
Ag2 Ag3 Ag5 160.29(3) . . ?
Ag4 Ag3 Ag5 67.17(4) . . ?
Ag6 Ag3 Ag2 63.15(3) . . ?
Ag6 Ag3 Ag4 140.28(4) . . ?
Ag6 Ag3 Ag5 102.33(4) . . ?
O4 Ag3 Ag2 74.82(18) . . ?
O4 Ag3 Ag4 138.0(2) . . ?
O4 Ag3 Ag5 118.00(19) . . ?
O4 Ag3 Ag6 81.4(2) . . ?
O4 Ag3 O10 94.2(2) . . ?
O4 Ag3 S1 104.1(2) . . ?
O4 Ag3 S3 92.0(2) . . ?
O10 Ag3 Ag2 143.08(17) . . ?
O10 Ag3 Ag4 52.72(16) . . ?
O10 Ag3 Ag5 54.80(16) . . ?
O10 Ag3 Ag6 151.29(18) . . ?
S1 Ag3 Ag2 55.27(6) . . ?
S1 Ag3 Ag4 61.30(7) . . ?
S1 Ag3 Ag5 128.14(6) . . ?
S1 Ag3 Ag6 113.09(7) . . ?
S1 Ag3 O10 95.54(19) . . ?
S1 Ag3 S3 157.73(7) . . ?
S3 Ag3 Ag2 116.63(6) . . ?
S3 Ag3 Ag4 115.46(8) . . ?
S3 Ag3 Ag5 51.63(6) . . ?
S3 Ag3 Ag6 53.58(7) . . ?
S3 Ag3 O10 98.56(18) . . ?
Ag6 Ag4 Ag3 76.23(3) 5_665 . ?
Ag7 Ag4 Ag3 98.78(5) 5_665 . ?
Ag7 Ag4 Ag6 63.75(4) 5_665 5_665 ?
O7 Ag4 Ag3 125.6(3) . . ?
O7 Ag4 Ag6 138.9(3) . 5_665 ?
O7 Ag4 Ag7 77.7(3) . 5_665 ?
O7 Ag4 O10 91.7(3) . . ?
O7 Ag4 S1 95.4(3) . . ?
O7 Ag4 S2 149.5(3) . 5_665 ?
O10 Ag4 Ag3 53.28(15) . . ?
O10 Ag4 Ag6 125.43(16) . 5_665 ?
O10 Ag4 Ag7 135.62(16) . 5_665 ?
O10 Ag4 S1 87.29(16) . . ?
S1 Ag4 Ag3 49.70(5) . . ?
S1 Ag4 Ag6 72.28(5) . 5_665 ?
S1 Ag4 Ag7 51.88(5) . 5_665 ?
S2 Ag4 Ag3 81.77(7) 5_665 . ?
S2 Ag4 Ag6 52.71(5) 5_665 5_665 ?
S2 Ag4 Ag7 114.41(6) 5_665 5_665 ?
S2 Ag4 O10 96.50(18) 5_665 . ?
S2 Ag4 S1 114.23(7) 5_665 . ?
O11 Ag5 Ag3 128.5(3) . . ?
O11 Ag5 S2 133.7(3) . 5_665 ?
O11 Ag5 S3 126.5(3) . . ?
S2 Ag5 Ag3 76.97(6) 5_665 . ?
S2 Ag5 S3 99.55(8) 5_665 . ?
S3 Ag5 Ag3 48.75(6) . . ?
Ag2 Ag6 Ag7 162.03(3) . . ?
Ag3 Ag6 Ag2 59.90(4) . . ?
Ag3 Ag6 Ag4 141.73(4) . 5_665 ?
Ag3 Ag6 Ag7 134.09(4) . . ?
Ag4 Ag6 Ag2 104.47(3) 5_665 . ?
Ag4 Ag6 Ag7 57.59(3) 5_665 . ?
O5 Ag6 Ag2 107.1(2) . . ?
O5 Ag6 Ag3 123.8(3) . . ?
O5 Ag6 Ag4 93.5(3) . 5_665 ?
O5 Ag6 Ag7 75.4(3) . . ?
O5 Ag6 S2 94.1(3) . . ?
O5 Ag6 S3 105.0(3) . . ?
S2 Ag6 Ag2 53.37(6) . . ?
S2 Ag6 Ag3 110.19(7) . . ?
S2 Ag6 Ag4 53.33(6) . 5_665 ?
S2 Ag6 Ag7 109.05(7) . . ?
S2 Ag6 S3 160.42(9) . . ?
S3 Ag6 Ag2 114.97(6) . . ?
S3 Ag6 Ag3 55.17(6) . . ?
S3 Ag6 Ag4 128.12(6) . 5_665 ?
S3 Ag6 Ag7 80.62(6) . . ?
Ag1 Ag7 Ag6 80.72(5) 5_665 . ?
Ag4 Ag7 Ag1 114.24(5) 5_665 5_665 ?
Ag4 Ag7 Ag6 58.66(4) 5_665 . ?
O6 Ag7 Ag1 116.9(3) . 5_665 ?
O6 Ag7 Ag4 105.4(3) . 5_665 ?
O6 Ag7 Ag6 80.5(3) . . ?
O6 Ag7 O8 90.5(4) . 5_665 ?
O6 Ag7 O9 96.9(4) . 5_665 ?
O6 Ag7 S1 154.7(3) . 5_665 ?
O8 Ag7 Ag1 140.0(4) 5_665 5_665 ?
O8 Ag7 Ag4 82.3(3) 5_665 5_665 ?
O8 Ag7 Ag6 135.1(3) 5_665 . ?
O8 Ag7 O9 101.4(4) 5_665 5_665 ?
O8 Ag7 S1 108.7(3) 5_665 5_665 ?
O9 Ag7 Ag1 49.87(18) 5_665 5_665 ?
O9 Ag7 Ag4 157.44(18) 5_665 5_665 ?
O9 Ag7 Ag6 123.22(17) 5_665 . ?
S1 Ag7 Ag1 57.37(6) 5_665 5_665 ?
S1 Ag7 Ag4 62.75(7) 5_665 5_665 ?
S1 Ag7 Ag6 74.22(7) 5_665 . ?
S1 Ag7 O9 95.31(19) 5_665 5_665 ?
C2 C1 S1 112.2(6) . . ?
C3 C2 C1 126.7(10) . . ?
C3 C2 C11 115.1(11) . . ?
C11 C2 C1 118.1(9) . . ?
C2 C3 C4 118.5(12) . . ?
C5 C4 C3 117.5(11) . . ?
C5 C4 C9 120.2(11) . . ?
C9 C4 C3 122.2(11) . . ?
C4 C5 C6 113.9(13) . . ?
C5 C6 C7 128.9(14) . . ?
C8 C7 C6 116.6(14) . . ?
C7 C8 C9 115.9(14) . . ?
C4 C9 C8 124.5(13) . . ?
C10 C9 C4 120.6(12) . . ?
C10 C9 C8 114.9(12) . . ?
C9 C10 C11 114.9(13) . . ?
C10 C11 C2 128.7(13) . . ?
C13 C12 S2 111.0(7) . . ?
C14 C13 C12 121.7(11) . . ?
C14 C13 C22 119.9(10) . . ?
C22 C13 C12 118.1(11) . . ?
C13 C14 C15 114.2(10) . . ?
C16 C15 C14 116.1(14) . . ?
C16 C15 C20 118.5(13) . . ?
C20 C15 C14 125.1(10) . . ?
C15 C16 C17 119.4(16) . . ?
C18 C17 C16 119.4(17) . . ?
C17 C18 C19 125.3(14) . . ?
C18 C19 C20 112.2(10) . . ?
C15 C20 C19 124.9(11) . . ?
C21 C20 C15 119.9(11) . . ?
C21 C20 C19 115.2(13) . . ?
C20 C21 C22 116.0(10) . . ?
C21 C22 C13 124.8(11) . . ?
C24 C23 S3 113.4(7) . . ?
C25 C24 C23 126.5(12) . . ?
C25 C24 C33 117.0(11) . . ?
C33 C24 C23 116.3(12) . . ?
C24 C25 C26 121.1(11) . . ?
C27 C26 C25 120.0(14) . . ?
C27 C26 C31 122.8(13) . . ?
C31 C26 C25 117.0(12) . . ?
C28 C27 C26 121.1(18) . . ?
C27 C28 C29 118.4(18) . . ?
C30 C29 C28 126.3(18) . . ?
C29 C30 C31 114.1(15) . . ?
C26 C31 C30 116.8(13) . . ?
C32 C31 C26 123.4(14) . . ?
C32 C31 C30 119.8(15) . . ?
C31 C32 C33 118.6(14) . . ?
C32 C33 C24 122.8(14) . . ?
O1 C34 C35 115.4(11) . . ?
O2 C34 C35 114.2(11) . . ?
O2 C34 O1 130.5(9) . . ?
F1 C35 C34 112.3(15) . . ?
F1 C35 F2 97.1(13) . . ?
F2 C35 C34 112.3(14) . . ?
F3 C35 C34 120.5(12) . . ?
F3 C35 F1 107.0(14) . . ?
F3 C35 F2 104.8(18) . . ?
O3 C36 C37 114.7(10) . . ?
O3 C36 O4 130.1(10) . . ?
O4 C36 C37 115.2(10) . . ?
F10 C37 C36 116.8(12) . . ?
F11 C37 C36 113.8(11) . . ?
F11 C37 F10 109.3(15) . . ?
F11 C37 F12 97.8(14) . . ?
F12 C37 C36 116.7(14) . . ?
F12 C37 F10 100.1(13) . . ?
O5 C38 C39 113.3(14) . . ?
O6 C38 C39 117.8(14) . . ?
O6 C38 O5 128.7(13) . . ?
F4 C39 C38 114.6(16) . . ?
F5 C39 C38 114.7(14) . . ?
F5 C39 F4 102.9(15) . . ?
F5 C39 F6 108.5(19) . . ?
F6 C39 C38 114.2(13) . . ?
F6 C39 F4 100.5(15) . . ?
O7 C40 C41 113.0(13) . . ?
O8 C40 C41 114.9(13) . . ?
O8 C40 O7 131.7(12) . . ?
F7 C41 C40 113.5(12) . . ?
F7 C41 F8 109.0(17) . . ?
F7 C41 F9 102.9(16) . . ?
F8 C41 C40 114.2(12) . . ?
F8 C41 F9 99.3(15) . . ?
F9 C41 C40 116.6(13) . . ?
N1 C43 C42 108.4(14) . . ?
O9 C43 C42 127.0(12) . . ?
O9 C43 N1 124.6(13) . . ?
N2 C47 C46 119.7(11) . . ?
O10 C47 C46 118.2(10) . . ?
O10 C47 N2 122.0(11) . . ?
N3 C51 C50 118.3(12) . . ?
O11 C51 C50 121.8(11) . . ?
O11 C51 N3 119.9(13) . . ?
C43 N1 C44 129.5(16) . . ?
C43 N1 C45 106.4(12) . . ?
C44 N1 C45 124.1(13) . . ?
C47 N2 C48 122.8(12) . . ?
C47 N2 C49 120.1(10) . . ?
C48 N2 C49 117.0(11) . . ?
C51 N3 C52 118.9(12) . . ?
C51 N3 C53 122.7(13) . . ?
C52 N3 C53 118.4(11) . . ?
C34 O1 Ag1 123.9(6) . . ?
C34 O2 Ag2 122.6(7) . . ?
C36 O3 Ag2 119.8(7) . . ?
C36 O4 Ag3 129.5(7) . . ?
C38 O5 Ag6 126.0(9) . . ?
C38 O6 Ag7 126.2(9) . . ?
C40 O7 Ag4 128.5(8) . . ?
C40 O8 Ag7 117.6(9) . 5_665 ?
Ag1 O9 Ag7 76.4(2) . 5_665 ?
C43 O9 Ag1 128.1(9) . . ?
C43 O9 Ag7 154.8(8) . 5_665 ?
Ag4 O10 Ag3 73.99(17) . . ?
C47 O10 Ag3 135.6(7) . . ?
C47 O10 Ag4 132.1(7) . . ?
C51 O11 Ag5 136.0(9) . . ?
Ag1 S1 Ag4 128.43(8) . . ?
Ag2 S1 Ag1 66.70(7) . . ?
Ag2 S1 Ag4 137.61(9) . . ?
Ag3 S1 Ag1 127.29(9) . . ?
Ag3 S1 Ag2 72.11(7) . . ?
Ag3 S1 Ag4 69.00(7) . . ?
Ag3 S1 Ag7 129.15(10) . 5_665 ?
Ag7 S1 Ag1 71.22(6) 5_665 . ?
Ag7 S1 Ag2 136.03(10) 5_665 . ?
Ag7 S1 Ag4 65.37(6) 5_665 . ?
C1 S1 Ag1 117.4(3) . . ?
C1 S1 Ag2 102.6(3) . . ?
C1 S1 Ag3 102.3(3) . . ?
C1 S1 Ag4 101.5(3) . . ?
C1 S1 Ag7 107.6(3) . 5_665 ?
Ag4 S2 Ag2 144.19(10) 5_665 . ?
Ag4 S2 Ag5 89.85(8) 5_665 5_665 ?
Ag5 S2 Ag2 95.80(10) 5_665 . ?
Ag6 S2 Ag2 75.94(7) . . ?
Ag6 S2 Ag4 73.96(7) . 5_665 ?
Ag6 S2 Ag5 131.46(10) . 5_665 ?
C12 S2 Ag2 101.4(3) . . ?
C12 S2 Ag4 106.8(4) . 5_665 ?
C12 S2 Ag5 118.4(3) . 5_665 ?
C12 S2 Ag6 110.0(4) . . ?
Ag1 S3 Ag5 81.82(8) 5_665 . ?
Ag3 S3 Ag1 141.01(9) . 5_665 ?
Ag3 S3 Ag5 79.62(9) . . ?
Ag6 S3 Ag1 107.22(9) . 5_665 ?
Ag6 S3 Ag3 71.25(6) . . ?
Ag6 S3 Ag5 143.27(10) . . ?
C23 S3 Ag1 111.6(4) . 5_665 ?
C23 S3 Ag3 107.0(5) . . ?
C23 S3 Ag5 111.0(5) . . ?
C23 S3 Ag6 98.8(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 177.1(9) . . . . ?
C1 C2 C11 C10 -176.1(11) . . . . ?
C2 C1 S1 Ag1 5.7(9) . . . . ?
C2 C1 S1 Ag2 75.8(8) . . . . ?
C2 C1 S1 Ag3 149.9(7) . . . . ?
C2 C1 S1 Ag4 -139.4(7) . . . . ?
C2 C1 S1 Ag7 -71.8(8) . . . 5_665 ?
C2 C3 C4 C5 -178.6(10) . . . . ?
C2 C3 C4 C9 -2.0(16) . . . . ?
C3 C2 C11 C10 1.4(17) . . . . ?
C3 C4 C5 C6 178.6(10) . . . . ?
C3 C4 C9 C8 -178.5(11) . . . . ?
C3 C4 C9 C10 3.0(18) . . . . ?
C4 C5 C6 C7 -1(2) . . . . ?
C4 C9 C10 C11 -1.7(18) . . . . ?
C5 C4 C9 C8 -1.9(19) . . . . ?
C5 C4 C9 C10 179.5(12) . . . . ?
C5 C6 C7 C8 0(2) . . . . ?
C6 C7 C8 C9 0(2) . . . . ?
C7 C8 C9 C4 1(2) . . . . ?
C7 C8 C9 C10 179.5(13) . . . . ?
C8 C9 C10 C11 179.6(11) . . . . ?
C9 C4 C5 C6 2.0(18) . . . . ?
C9 C10 C11 C2 -0.5(19) . . . . ?
C11 C2 C3 C4 -0.1(14) . . . . ?
C12 C13 C14 C15 -174.6(11) . . . . ?
C12 C13 C22 C21 176.5(13) . . . . ?
C13 C12 S2 Ag2 -154.5(8) . . . . ?
C13 C12 S2 Ag4 47.9(9) . . . 5_665 ?
C13 C12 S2 Ag5 -51.3(10) . . . 5_665 ?
C13 C12 S2 Ag6 126.5(8) . . . . ?
C13 C14 C15 C16 174.1(14) . . . . ?
C13 C14 C15 C20 0(2) . . . . ?
C14 C13 C22 C21 2(2) . . . . ?
C14 C15 C16 C17 -176.0(16) . . . . ?
C14 C15 C20 C19 179.2(15) . . . . ?
C14 C15 C20 C21 -3(3) . . . . ?
C15 C16 C17 C18 0(3) . . . . ?
C15 C20 C21 C22 4(2) . . . . ?
C16 C15 C20 C19 6(3) . . . . ?
C16 C15 C20 C21 -176.2(16) . . . . ?
C16 C17 C18 C19 -2(3) . . . . ?
C17 C18 C19 C20 5(3) . . . . ?
C18 C19 C20 C15 -7(2) . . . . ?
C18 C19 C20 C21 174.9(16) . . . . ?
C19 C20 C21 C22 -177.7(14) . . . . ?
C20 C15 C16 C17 -2(3) . . . . ?
C20 C21 C22 C13 -4(2) . . . . ?
C22 C13 C14 C15 0.2(19) . . . . ?
C23 C24 C25 C26 175.1(9) . . . . ?
C23 C24 C33 C32 -175.0(13) . . . . ?
C24 C23 S3 Ag1 -45.5(12) . . . 5_665 ?
C24 C23 S3 Ag3 129.0(10) . . . . ?
C24 C23 S3 Ag5 43.9(12) . . . . ?
C24 C23 S3 Ag6 -158.0(10) . . . . ?
C24 C25 C26 C27 -176.0(12) . . . . ?
C24 C25 C26 C31 -1.4(16) . . . . ?
C25 C24 C33 C32 1.1(19) . . . . ?
C25 C26 C27 C28 173.7(14) . . . . ?
C25 C26 C31 C30 -179.1(10) . . . . ?
C25 C26 C31 C32 3.0(18) . . . . ?
C26 C27 C28 C29 6(3) . . . . ?
C26 C31 C32 C33 -3(2) . . . . ?
C27 C26 C31 C30 -4.6(18) . . . . ?
C27 C26 C31 C32 177.5(14) . . . . ?
C27 C28 C29 C30 -6(3) . . . . ?
C28 C29 C30 C31 1(3) . . . . ?
C29 C30 C31 C26 4.5(19) . . . . ?
C29 C30 C31 C32 -177.5(15) . . . . ?
C30 C31 C32 C33 179.6(13) . . . . ?
C31 C26 C27 C28 -1(2) . . . . ?
C31 C32 C33 C24 0(2) . . . . ?
C33 C24 C25 C26 -0.6(15) . . . . ?
C35 C34 O1 Ag1 -166.6(10) . . . . ?
C35 C34 O2 Ag2 -178.6(10) . . . . ?
C37 C36 O3 Ag2 176.2(9) . . . . ?
C37 C36 O4 Ag3 -173.1(9) . . . . ?
C39 C38 O5 Ag6 -171.7(9) . . . . ?
C39 C38 O6 Ag7 -170.0(9) . . . . ?
C41 C40 O7 Ag4 172.9(9) . . . . ?
C41 C40 O8 Ag7 172.5(9) . . . 5_665 ?
C42 C43 N1 C44 2(2) . . . . ?
C42 C43 N1 C45 -178.3(11) . . . . ?
C42 C43 O9 Ag1 -8.6(18) . . . . ?
C42 C43 O9 Ag7 155.7(12) . . . 5_665 ?
C46 C47 N2 C48 3.3(17) . . . . ?
C46 C47 N2 C49 179.6(11) . . . . ?
C46 C47 O10 Ag3 -12.9(15) . . . . ?
C46 C47 O10 Ag4 -126.0(9) . . . . ?
C50 C51 N3 C52 174.8(14) . . . . ?
C50 C51 N3 C53 -3(2) . . . . ?
C50 C51 O11 Ag5 -1(2) . . . . ?
N1 C43 O9 Ag1 172.9(10) . . . . ?
N1 C43 O9 Ag7 -23(3) . . . 5_665 ?
N2 C47 O10 Ag3 168.0(8) . . . . ?
N2 C47 O10 Ag4 54.9(14) . . . . ?
N3 C51 O11 Ag5 177.2(9) . . . . ?
O1 C34 C35 F1 -84.1(18) . . . . ?
O1 C34 C35 F2 24(2) . . . . ?
O1 C34 C35 F3 148.3(17) . . . . ?
O1 C34 O2 Ag2 2.1(18) . . . . ?
O2 C34 C35 F1 96.5(16) . . . . ?
O2 C34 C35 F2 -155.3(16) . . . . ?
O2 C34 C35 F3 -31(2) . . . . ?
O2 C34 O1 Ag1 12.7(19) . . . . ?
O3 C36 C37 F10 -69.5(19) . . . . ?
O3 C36 C37 F11 161.7(15) . . . . ?
O3 C36 C37 F12 48.8(19) . . . . ?
O3 C36 O4 Ag3 7(2) . . . . ?
O4 C36 C37 F10 111.0(16) . . . . ?
O4 C36 C37 F11 -18(2) . . . . ?
O4 C36 C37 F12 -130.7(15) . . . . ?
O4 C36 O3 Ag2 -4.3(19) . . . . ?
O5 C38 C39 F4 165.1(16) . . . . ?
O5 C38 C39 F5 -76(2) . . . . ?
O5 C38 C39 F6 50(2) . . . . ?
O5 C38 O6 Ag7 16(2) . . . . ?
O6 C38 C39 F4 -10(2) . . . . ?
O6 C38 C39 F5 109(2) . . . . ?
O6 C38 C39 F6 -125.1(19) . . . . ?
O6 C38 O5 Ag6 3(2) . . . . ?
O7 C40 C41 F7 123.9(19) . . . . ?
O7 C40 C41 F8 -110.4(19) . . . . ?
O7 C40 C41 F9 5(2) . . . . ?
O7 C40 O8 Ag7 1(3) . . . 5_665 ?
O8 C40 C41 F7 -50(2) . . . . ?
O8 C40 C41 F8 76(2) . . . . ?
O8 C40 C41 F9 -168.9(18) . . . . ?
O8 C40 O7 Ag4 -15(3) . . . . ?
O9 C43 N1 C44 -178.8(13) . . . . ?
O9 C43 N1 C45 0.5(19) . . . . ?
O10 C47 N2 C48 -177.6(12) . . . . ?
O10 C47 N2 C49 -1.3(17) . . . . ?
O11 C51 N3 C52 -4(2) . . . . ?
O11 C51 N3 C53 178.3(14) . . . . ?
S1 C1 C2 C3 93.0(11) . . . . ?
S1 C1 C2 C11 -89.8(10) . . . . ?
S2 C12 C13 C14 87.5(12) . . . . ?
S2 C12 C13 C22 -87.3(12) . . . . ?
S3 C23 C24 C25 87.8(13) . . . . ?
S3 C23 C24 C33 -96.6(12) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
