# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1867337'
_audit_update_record             
;
2018-09-12 deposited with the CCDC.
2018-11-16 downloaded from the CCDC.
;
#=======================================================================

# 5. CHEMICAL DATA

_chemical_name_systematic        
; ?
;
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac          ?
_chemical_formula_sum            'Al1 Eu14 Sb11'
_chemical_formula_weight         3493.7
_chemical_melting_point          ?
_chemical_compound_source        ?
_chemical_absolute_configuration .

#=======================================================================

# 6. CRYSTAL DATA

_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   'I 41/a c d'
_symmetry_space_group_name_Hall  '-I 4bd;-2c'
_symmetry_Int_Tables_number      142

loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y+1/2,z
3 -y+1/4,x+3/4,z+1/4
4 y+1/4,-x+1/4,z+3/4
5 -x+1/2,y,-z
6 x,-y,-z+1/2
7 y+3/4,x+1/4,-z+1/4
8 -y+1/4,-x+1/4,-z+1/4
9 -x,-y,-z
10 x,y+1/2,-z
11 y+3/4,-x+1/4,-z+3/4
12 -y+3/4,x+3/4,-z+1/4
13 x+1/2,-y,z
14 -x,y,z+1/2
15 -y+1/4,-x+3/4,z+3/4
16 y+3/4,x+3/4,z+3/4
17 x+1/2,y+1/2,z+1/2
18 -x+1/2,-y,z+1/2
19 -y+3/4,x+1/4,z+3/4
20 y+3/4,-x+3/4,z+1/4
21 -x,y+1/2,-z+1/2
22 x+1/2,-y+1/2,-z
23 y+1/4,x+3/4,-z+3/4
24 -y+3/4,-x+3/4,-z+3/4
25 -x+1/2,-y+1/2,-z+1/2
26 x+1/2,y,-z+1/2
27 y+1/4,-x+3/4,-z+1/4
28 -y+1/4,x+1/4,-z+3/4
29 x,-y+1/2,z+1/2
30 -x+1/2,y+1/2,z
31 -y+3/4,-x+1/4,z+1/4
32 y+1/4,x+1/4,z+1/4

_cell_length_a                   17.2649(4)
_cell_length_b                   17.2649(4)
_cell_length_c                   22.9224(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     6832.6(3)

loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
_twin_individual_twin_matrix_11
_twin_individual_twin_matrix_12
_twin_individual_twin_matrix_13
_twin_individual_twin_matrix_21
_twin_individual_twin_matrix_22
_twin_individual_twin_matrix_23
_twin_individual_twin_matrix_31
_twin_individual_twin_matrix_32
_twin_individual_twin_matrix_33
? ? ? ? ? ? ? ? ? ? ?

_cell_formula_units_Z            8

_cell_measurement_reflns_used    25497
_cell_measurement_theta_min      2.44
_cell_measurement_theta_max      32.20
_cell_measurement_temperature    293
_cell_special_details            
; ?
;

_exptl_crystal_density_diffrn    6.79
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             11648

_exptl_absorpt_coefficient_mu    33.8
_exptl_crystal_description       block
_exptl_crystal_size_max          0.035
_exptl_crystal_size_mid          0.030
_exptl_crystal_size_min          0.020
_exptl_crystal_size_rad          ?
_exptl_crystal_colour            silver
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   XArea
_exptl_absorpt_correction_T_min  0.019
_exptl_absorpt_correction_T_max  0.045
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
? ? ? ?

#=======================================================================

# 7. EXPERIMENTAL DATA

_exptl_special_details           ?

_diffrn_ambient_temperature      293
_diffrn_source                   ?
_diffrn_source_power             ?
_diffrn_source_voltage           ?
_diffrn_source_current           ?
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'IPDS Stoe'
_diffrn_detector                 ?
_diffrn_detector_area_resol_mean ?
_diffrn_measurement_method       '??integration method??'
_diffrn_measurement_specimen_support ?

_diffrn_reflns_number            57201
_diffrn_reflns_theta_min         2.36
_diffrn_reflns_theta_max         32.06
_diffrn_reflns_theta_full        32.06
_diffrn_measured_fraction_theta_max 1
_diffrn_measured_fraction_theta_full 1
_diffrn_reflns_av_R_equivalents  0.1598
_diffrn_reflns_av_unetI/netI     0.0487
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_reduction_process ?

_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?

_diffrn_radiation_probe          X-ray

#=======================================================================

# 8. REFINEMENT DATA

_refine_special_details          
; ?
;

_reflns_number_total             2971
_reflns_number_gt                1826
_reflns_threshold_expression     I>3σ(I)

_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_gt           0.0345
_refine_ls_wR_factor_gt          0.0571
_refine_ls_R_factor_all          0.0805
_refine_ls_wR_factor_ref         0.0695
_refine_ls_goodness_of_fit_ref   1.16
_refine_ls_goodness_of_fit_gt    1.22
_refine_ls_restrained_S_gt       ?
_refine_ls_restrained_S_all      ?
_refine_ls_number_reflns         2971
_refine_ls_number_parameters     62
_refine_ls_number_restraints     0
_refine_ls_number_constraints    0
_refine_ls_weighting_scheme      sigma
_refine_ls_weighting_details     w=1/(σ²(I)+0.0004I²)
_refine_ls_hydrogen_treatment    ?
_refine_ls_shift/su_max          0.0004
_refine_ls_shift/su_mean         0.0001
_refine_diff_density_max         2.74
_refine_diff_density_min         -2.94
_refine_ls_extinction_method     
'B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)'
_refine_ls_extinction_coef       40(20)
_refine_ls_abs_structure_details ?
_refine_ls_abs_structure_Flack   ?
_refine_ls_abs_structure_Rogers  ?

loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Al 0.0645 0.0514 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Eu -0.1578 3.6682 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Sb -0.5866 1.5461 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  ?
_computing_molecular_graphics    ?
_computing_publication_material  ?

loop_
_restr_distance_atom_site_label_1
_restr_distance_site_symmetry_1
_restr_distance_atom_site_label_2
_restr_distance_site_symmetry_2
_restr_distance_target
_restr_distance_target_weight_param
? ? ? ? ? ?

loop_
_restr_angle_atom_site_label_1
_restr_angle_site_symmetry_1
_restr_angle_atom_site_label_2
_restr_angle_site_symmetry_2
_restr_angle_atom_site_label_3
_restr_angle_site_symmetry_3
_restr_angle_target
_restr_angle_target_weight_param
? ? ? ? ? ? ? ?

loop_
_restr_torsion_atom_site_label_1
_restr_torsion_site_symmetry_1
_restr_torsion_atom_site_label_2
_restr_torsion_site_symmetry_2
_restr_torsion_atom_site_label_3
_restr_torsion_site_symmetry_3
_restr_torsion_atom_site_label_4
_restr_torsion_site_symmetry_4
_restr_torsion_angle_target
_restr_torsion_weight_param
? ? ? ? ? ? ? ? ? ?

loop_
_restr_equal_distance_atom_site_label_1
_restr_equal_distance_site_symmetry_1
_restr_equal_distance_atom_site_label_2
_restr_equal_distance_site_symmetry_2
_restr_equal_distance_class_class_id
_restr_equal_distance_class_target_weight_param
? ? ? ? ? ?

loop_
_restr_equal_angle_atom_site_label_1
_restr_equal_angle_site_symmetry_1
_restr_equal_angle_atom_site_label_2
_restr_equal_angle_site_symmetry_2
_restr_equal_angle_atom_site_label_3
_restr_equal_angle_site_symmetry_3
_restr_equal_angle_class_class_id
_restr_equal_angle_class_target_weight_param
? ? ? ? ? ? ? ?

loop_
_restr_equal_torsion_atom_site_label_1
_restr_equal_torsion_site_symmetry_1
_restr_equal_torsion_atom_site_label_2
_restr_equal_torsion_site_symmetry_2
_restr_equal_torsion_atom_site_label_3
_restr_equal_torsion_site_symmetry_3
_restr_equal_torsion_atom_site_label_4
_restr_equal_torsion_site_symmetry_4
_restr_equal_torsion_class_class_id
_restr_equal_torsion_class_target_weight_param
? ? ? ? ? ? ? ? ? ?


#=======================================================================

# 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_site_symmetry_multiplicity
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.04391(3) 0.07244(3) 0.17137(2) Uani 0.02156(13) 32 1 d . . .
Eu2 Eu 0.02100(3) 0.37660(4) 0.00263(3) Uani 0.02421(14) 32 1 d . . .
Eu3 Eu 0.35607(5) 0 0.25 Uani 0.02154(19) 16 1 d . . .
Eu4 Eu 0.34128(4) 0.06830(4) 0.09267(2) Uani 0.02518(15) 32 1 d . . .
Al Al 0 0.25 0.375 Uani 0.0209(12) 8 1 d . . .
Sb1 Sb 0.13305(4) 0.38305(4) 0.125 Uani 0.01998(18) 16 1 d . . .
Sb2 Sb 0.36509(5) 0.25319(4) 0.06209(3) Uani 0.02121(17) 32 1 d . . .
Sb3 Sb 0.13138(5) 0.02507(4) 0.04697(3) Uani 0.02097(17) 32 1 d . . .
Sb4 Sb 0 0.25 0.125 Uani 0.0237(3) 8 1 d . . .


loop_
_jana_atom_site_ADP_C_label
_jana_atom_site_ADP_C_type_symbol
_jana_atom_site_ADP_C_111
_jana_atom_site_ADP_C_112
_jana_atom_site_ADP_C_113
_jana_atom_site_ADP_C_122
_jana_atom_site_ADP_C_123
_jana_atom_site_ADP_C_133
_jana_atom_site_ADP_C_222
_jana_atom_site_ADP_C_223
_jana_atom_site_ADP_C_233
_jana_atom_site_ADP_C_333
? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_D_label
_jana_atom_site_ADP_D_type_symbol
_jana_atom_site_ADP_D_1111
_jana_atom_site_ADP_D_1112
_jana_atom_site_ADP_D_1113
_jana_atom_site_ADP_D_1122
_jana_atom_site_ADP_D_1123
_jana_atom_site_ADP_D_1133
_jana_atom_site_ADP_D_1222
_jana_atom_site_ADP_D_1223
_jana_atom_site_ADP_D_1233
_jana_atom_site_ADP_D_1333
_jana_atom_site_ADP_D_2222
_jana_atom_site_ADP_D_2223
_jana_atom_site_ADP_D_2233
_jana_atom_site_ADP_D_2333
_jana_atom_site_ADP_D_3333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_E_label
_jana_atom_site_ADP_E_type_symbol
_jana_atom_site_ADP_E_11111
_jana_atom_site_ADP_E_11112
_jana_atom_site_ADP_E_11113
_jana_atom_site_ADP_E_11122
_jana_atom_site_ADP_E_11123
_jana_atom_site_ADP_E_11133
_jana_atom_site_ADP_E_11222
_jana_atom_site_ADP_E_11223
_jana_atom_site_ADP_E_11233
_jana_atom_site_ADP_E_11333
_jana_atom_site_ADP_E_12222
_jana_atom_site_ADP_E_12223
_jana_atom_site_ADP_E_12233
_jana_atom_site_ADP_E_12333
_jana_atom_site_ADP_E_13333
_jana_atom_site_ADP_E_22222
_jana_atom_site_ADP_E_22223
_jana_atom_site_ADP_E_22233
_jana_atom_site_ADP_E_22333
_jana_atom_site_ADP_E_23333
_jana_atom_site_ADP_E_33333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_F_label
_jana_atom_site_ADP_F_type_symbol
_jana_atom_site_ADP_F_111111
_jana_atom_site_ADP_F_111112
_jana_atom_site_ADP_F_111113
_jana_atom_site_ADP_F_111122
_jana_atom_site_ADP_F_111123
_jana_atom_site_ADP_F_111133
_jana_atom_site_ADP_F_111222
_jana_atom_site_ADP_F_111223
_jana_atom_site_ADP_F_111233
_jana_atom_site_ADP_F_111333
_jana_atom_site_ADP_F_112222
_jana_atom_site_ADP_F_112223
_jana_atom_site_ADP_F_112233
_jana_atom_site_ADP_F_112333
_jana_atom_site_ADP_F_113333
_jana_atom_site_ADP_F_122222
_jana_atom_site_ADP_F_122223
_jana_atom_site_ADP_F_122233
_jana_atom_site_ADP_F_122333
_jana_atom_site_ADP_F_123333
_jana_atom_site_ADP_F_133333
_jana_atom_site_ADP_F_222222
_jana_atom_site_ADP_F_222223
_jana_atom_site_ADP_F_222233
_jana_atom_site_ADP_F_222333
_jana_atom_site_ADP_F_223333
_jana_atom_site_ADP_F_233333
_jana_atom_site_ADP_F_333333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?


#=======================================================================

# 10. MOLECULAR GEOMETRY


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Eu1 Eu1 . 8_555 3.8946(8) ?
Eu1 Eu3 . 26_455 3.9153(9) ?
Eu1 Eu4 . 8_555 3.7085(9) ?
Eu1 Sb1 . 2_555 3.3248(9) ?
Eu1 Sb2 . 3_545 3.4071(8) ?
Eu1 Sb2 . 8_555 3.3597(10) ?
Eu1 Sb3 . . 3.3287(9) ?
Eu1 Sb3 . 8_555 3.3059(10) ?
Eu1 Sb4 . . 3.3320(6) ?
Eu2 Eu3 . 27_555 3.9654(6) ?
Eu2 Eu4 . 22_455 3.9121(8) ?
Eu2 Al . 7_455 3.6698(6) ?
Eu2 Sb1 . . 3.4093(7) ?
Eu2 Sb2 . 5_555 3.2570(9) ?
Eu2 Sb2 . 22_455 3.8036(9) ?
Eu2 Sb3 . 2_555 3.2919(10) ?
Eu2 Sb3 . 10_555 3.3905(10) ?
Eu2 Sb4 . . 3.5746(6) ?
Eu3 Eu4 . . 3.8028(6) ?
Eu3 Eu4 . 6_555 3.8028(6) ?
Eu3 Sb1 . 25_555 3.5103(5) ?
Eu3 Sb1 . 12_545 3.5103(5) ?
Eu3 Sb2 . 12_545 3.4465(9) ?
Eu3 Sb2 . 31_555 3.4465(9) ?
Eu3 Sb3 . 3_545 3.2373(10) ?
Eu3 Sb3 . 8_555 3.2373(10) ?
Eu4 Sb1 . 12_545 3.3128(10) ?
Eu4 Sb2 . . 3.2940(10) ?
Eu4 Sb2 . 12_545 3.5537(9) ?
Eu4 Sb3 . . 3.8454(11) ?
Eu4 Sb3 . 5_555 3.3206(9) ?
Eu4 Sb3 . 8_555 3.3450(9) ?
Al Sb2 . 3_545 2.7400(7) ?
Al Sb2 . 20_455 2.7400(7) ?
Al Sb2 . 25_555 2.7400(7) ?
Al Sb2 . 26_455 2.7400(7) ?
Sb1 Sb4 . . 3.2486(8) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
Eu1 Eu1 Eu3 8_555 . 26_455 158.63(2) ?
Eu1 Eu1 Eu4 8_555 . 8_555 91.383(18) ?
Eu1 Eu1 Sb1 8_555 . 2_555 103.473(19) ?
Eu1 Eu1 Sb2 8_555 . 3_545 122.01(2) ?
Eu1 Eu1 Sb2 8_555 . 8_555 140.89(2) ?
Eu1 Eu1 Sb3 8_555 . . 53.784(17) ?
Eu1 Eu1 Sb3 8_555 . 8_555 54.326(17) ?
Eu1 Eu1 Sb4 8_555 . . 54.238(12) ?
Eu3 Eu1 Eu4 26_455 . 8_555 109.138(18) ?
Eu3 Eu1 Sb1 26_455 . 2_555 57.309(14) ?
Eu3 Eu1 Sb2 26_455 . 3_545 55.635(15) ?
Eu3 Eu1 Sb2 26_455 . 8_555 55.928(15) ?
Eu3 Eu1 Sb3 26_455 . . 133.76(2) ?
Eu3 Eu1 Sb3 26_455 . 8_555 139.38(2) ?
Eu3 Eu1 Sb4 26_455 . . 104.612(16) ?
Eu4 Eu1 Sb1 8_555 . 2_555 137.55(2) ?
Eu4 Eu1 Sb2 8_555 . 3_545 113.58(2) ?
Eu4 Eu1 Sb2 8_555 . 8_555 55.287(18) ?
Eu4 Eu1 Sb3 8_555 . . 56.452(18) ?
Eu4 Eu1 Sb3 8_555 . 8_555 66.20(2) ?
Eu4 Eu1 Sb4 8_555 . . 145.04(2) ?
Sb1 Eu1 Sb2 2_555 . 3_545 91.913(19) ?
Sb1 Eu1 Sb2 2_555 . 8_555 92.09(2) ?
Sb1 Eu1 Sb3 2_555 . . 101.53(2) ?
Sb1 Eu1 Sb3 2_555 . 8_555 152.02(3) ?
Sb1 Eu1 Sb4 2_555 . . 58.418(16) ?
Sb2 Eu1 Sb2 3_545 . 8_555 92.50(2) ?
Sb2 Eu1 Sb3 3_545 . . 166.50(3) ?
Sb2 Eu1 Sb3 3_545 . 8_555 88.03(2) ?
Sb2 Eu1 Sb4 3_545 . . 92.799(19) ?
Sb2 Eu1 Sb3 8_555 . . 88.27(2) ?
Sb2 Eu1 Sb3 8_555 . 8_555 115.88(3) ?
Sb2 Eu1 Sb4 8_555 . . 150.18(2) ?
Sb3 Eu1 Sb3 . . 8_555 79.54(2) ?
Sb3 Eu1 Sb4 . . . 93.208(19) ?
Sb3 Eu1 Sb4 8_555 . . 93.62(2) ?
Eu3 Eu2 Eu4 27_555 . 22_455 139.814(19) ?
Eu3 Eu2 Al 27_555 . 7_455 97.547(15) ?
Eu3 Eu2 Sb1 27_555 . . 56.241(13) ?
Eu3 Eu2 Sb2 27_555 . 5_555 55.974(19) ?
Eu3 Eu2 Sb2 27_555 . 22_455 138.08(2) ?
Eu3 Eu2 Sb3 27_555 . 2_555 139.70(2) ?
Eu3 Eu2 Sb3 27_555 . 10_555 51.498(19) ?
Eu3 Eu2 Sb4 27_555 . . 99.160(15) ?
Eu4 Eu2 Al 22_455 . 7_455 67.748(13) ?
Eu4 Eu2 Sb1 22_455 . . 154.36(2) ?
Eu4 Eu2 Sb2 22_455 . 5_555 112.56(2) ?
Eu4 Eu2 Sb2 22_455 . 22_455 50.520(16) ?
Eu4 Eu2 Sb3 22_455 . 2_555 54.067(17) ?
Eu4 Eu2 Sb3 22_455 . 10_555 94.28(2) ?
Eu4 Eu2 Sb4 22_455 . . 120.426(17) ?
Al Eu2 Sb1 7_455 . . 137.01(2) ?
Al Eu2 Sb2 7_455 . 5_555 46.126(15) ?
Al Eu2 Sb2 7_455 . 22_455 42.969(12) ?
Al Eu2 Sb3 7_455 . 2_555 118.32(2) ?
Al Eu2 Sb3 7_455 . 10_555 103.800(18) ?
Al Eu2 Sb4 7_455 . . 104.557(16) ?
Sb1 Eu2 Sb2 . . 5_555 93.07(2) ?
Sb1 Eu2 Sb2 . . 22_455 137.87(2) ?
Sb1 Eu2 Sb3 . . 2_555 100.52(2) ?
Sb1 Eu2 Sb3 . . 10_555 86.12(2) ?
Sb1 Eu2 Sb4 . . . 55.379(15) ?
Sb2 Eu2 Sb2 5_555 . 22_455 82.20(2) ?
Sb2 Eu2 Sb3 5_555 . 2_555 163.85(3) ?
Sb2 Eu2 Sb3 5_555 . 10_555 90.14(2) ?
Sb2 Eu2 Sb4 5_555 . . 91.068(19) ?
Sb2 Eu2 Sb3 22_455 . 2_555 81.87(2) ?
Sb2 Eu2 Sb3 22_455 . 10_555 135.43(2) ?
Sb2 Eu2 Sb4 22_455 . . 82.763(16) ?
Sb3 Eu2 Sb3 2_555 . 10_555 99.37(2) ?
Sb3 Eu2 Sb4 2_555 . . 89.538(18) ?
Sb3 Eu2 Sb4 10_555 . . 141.49(2) ?
Eu1 Eu3 Eu1 26_555 . 13_555 68.153(18) ?
Eu1 Eu3 Eu2 26_555 . 12_545 105.246(18) ?
Eu1 Eu3 Eu2 26_555 . 31_555 67.173(14) ?
Eu1 Eu3 Eu4 26_555 . . 113.149(19) ?
Eu1 Eu3 Eu4 26_555 . 6_555 73.626(14) ?
Eu1 Eu3 Sb1 26_555 . 25_555 52.857(16) ?
Eu1 Eu3 Sb1 26_555 . 12_545 121.01(2) ?
Eu1 Eu3 Sb2 26_555 . 12_545 54.688(17) ?
Eu1 Eu3 Sb2 26_555 . 31_555 53.850(18) ?
Eu1 Eu3 Sb3 26_555 . 3_545 128.923(15) ?
Eu1 Eu3 Sb3 26_555 . 8_555 122.030(17) ?
Eu1 Eu3 Eu2 13_555 . 12_545 67.173(14) ?
Eu1 Eu3 Eu2 13_555 . 31_555 105.246(18) ?
Eu1 Eu3 Eu4 13_555 . . 73.626(14) ?
Eu1 Eu3 Eu4 13_555 . 6_555 113.149(19) ?
Eu1 Eu3 Sb1 13_555 . 25_555 121.01(2) ?
Eu1 Eu3 Sb1 13_555 . 12_545 52.857(16) ?
Eu1 Eu3 Sb2 13_555 . 12_545 53.850(18) ?
Eu1 Eu3 Sb2 13_555 . 31_555 54.688(17) ?
Eu1 Eu3 Sb3 13_555 . 3_545 122.030(17) ?
Eu1 Eu3 Sb3 13_555 . 8_555 128.923(15) ?
Eu2 Eu3 Eu2 12_545 . 31_555 171.35(3) ?
Eu2 Eu3 Eu4 12_545 . . 107.447(12) ?
Eu2 Eu3 Eu4 12_545 . 6_555 73.160(12) ?
Eu2 Eu3 Sb1 12_545 . 25_555 125.581(14) ?
Eu2 Eu3 Sb1 12_545 . 12_545 53.848(13) ?
Eu2 Eu3 Sb2 12_545 . 12_545 121.02(2) ?
Eu2 Eu3 Sb2 12_545 . 31_555 51.555(16) ?
Eu2 Eu3 Sb3 12_545 . 3_545 55.046(17) ?
Eu2 Eu3 Sb3 12_545 . 8_555 132.72(2) ?
Eu2 Eu3 Eu4 31_555 . . 73.160(12) ?
Eu2 Eu3 Eu4 31_555 . 6_555 107.447(12) ?
Eu2 Eu3 Sb1 31_555 . 25_555 53.848(13) ?
Eu2 Eu3 Sb1 31_555 . 12_545 125.581(14) ?
Eu2 Eu3 Sb2 31_555 . 12_545 51.555(16) ?
Eu2 Eu3 Sb2 31_555 . 31_555 121.02(2) ?
Eu2 Eu3 Sb3 31_555 . 3_545 132.72(2) ?
Eu2 Eu3 Sb3 31_555 . 8_555 55.046(17) ?
Eu4 Eu3 Eu4 . . 6_555 172.30(3) ?
Eu4 Eu3 Sb1 . . 25_555 126.821(14) ?
Eu4 Eu3 Sb1 . . 12_545 53.692(14) ?
Eu4 Eu3 Sb2 . . 12_545 58.463(15) ?
Eu4 Eu3 Sb2 . . 31_555 128.15(2) ?
Eu4 Eu3 Sb3 . . 3_545 117.69(2) ?
Eu4 Eu3 Sb3 . . 8_555 56.046(16) ?
Eu4 Eu3 Sb1 6_555 . 25_555 53.692(14) ?
Eu4 Eu3 Sb1 6_555 . 12_545 126.821(14) ?
Eu4 Eu3 Sb2 6_555 . 12_545 128.15(2) ?
Eu4 Eu3 Sb2 6_555 . 31_555 58.463(15) ?
Eu4 Eu3 Sb3 6_555 . 3_545 56.046(16) ?
Eu4 Eu3 Sb3 6_555 . 8_555 117.69(2) ?
Sb1 Eu3 Sb1 25_555 . 12_545 173.86(3) ?
Sb1 Eu3 Sb2 25_555 . 12_545 88.149(18) ?
Sb1 Eu3 Sb2 25_555 . 31_555 87.526(19) ?
Sb1 Eu3 Sb3 25_555 . 3_545 97.460(19) ?
Sb1 Eu3 Sb3 25_555 . 8_555 86.849(19) ?
Sb1 Eu3 Sb2 12_545 . 12_545 87.526(19) ?
Sb1 Eu3 Sb2 12_545 . 31_555 88.149(18) ?
Sb1 Eu3 Sb3 12_545 . 3_545 86.849(19) ?
Sb1 Eu3 Sb3 12_545 . 8_555 97.460(19) ?
Sb2 Eu3 Sb2 12_545 . 31_555 90.34(3) ?
Sb2 Eu3 Sb3 12_545 . 3_545 174.375(17) ?
Sb2 Eu3 Sb3 12_545 . 8_555 89.486(18) ?
Sb2 Eu3 Sb3 31_555 . 3_545 89.486(18) ?
Sb2 Eu3 Sb3 31_555 . 8_555 174.375(17) ?
Sb3 Eu3 Sb3 3_545 . 8_555 91.24(3) ?
Eu1 Eu4 Eu2 8_555 . 22_555 113.582(19) ?
Eu1 Eu4 Eu3 8_555 . . 109.415(19) ?
Eu1 Eu4 Sb1 8_555 . 12_545 137.79(3) ?
Eu1 Eu4 Sb2 8_555 . . 56.975(19) ?
Eu1 Eu4 Sb2 8_555 . 12_545 118.91(2) ?
Eu1 Eu4 Sb3 8_555 . . 51.869(17) ?
Eu1 Eu4 Sb3 8_555 . 5_555 99.72(2) ?
Eu1 Eu4 Sb3 8_555 . 8_555 56.033(18) ?
Eu2 Eu4 Eu3 22_555 . . 123.48(2) ?
Eu2 Eu4 Sb1 22_555 . 12_545 104.69(2) ?
Eu2 Eu4 Sb2 22_555 . . 63.032(19) ?
Eu2 Eu4 Sb2 22_555 . 12_545 71.847(18) ?
Eu2 Eu4 Sb3 22_555 . . 129.98(2) ?
Eu2 Eu4 Sb3 22_555 . 5_555 53.389(19) ?
Eu2 Eu4 Sb3 22_555 . 8_555 146.66(2) ?
Eu3 Eu4 Sb1 . . 12_545 58.637(10) ?
Eu3 Eu4 Sb2 . . . 119.60(2) ?
Eu3 Eu4 Sb2 . . 12_545 55.750(17) ?
Eu3 Eu4 Sb3 . . . 105.16(2) ?
Eu3 Eu4 Sb3 . . 5_555 146.61(2) ?
Eu3 Eu4 Sb3 . . 8_555 53.395(18) ?
Sb1 Eu4 Sb2 12_545 . . 165.13(3) ?
Sb1 Eu4 Sb2 12_545 . 12_545 88.91(2) ?
Sb1 Eu4 Sb3 12_545 . . 89.98(2) ?
Sb1 Eu4 Sb3 12_545 . 5_555 88.834(19) ?
Sb1 Eu4 Sb3 12_545 . 8_555 99.32(2) ?
Sb2 Eu4 Sb2 . . 12_545 79.40(2) ?
Sb2 Eu4 Sb3 . . . 104.34(2) ?
Sb2 Eu4 Sb3 . . 5_555 89.71(2) ?
Sb2 Eu4 Sb3 . . 8_555 89.10(2) ?
Sb2 Eu4 Sb3 12_545 . . 157.45(2) ?
Sb2 Eu4 Sb3 12_545 . 5_555 122.40(3) ?
Sb2 Eu4 Sb3 12_545 . 8_555 86.00(2) ?
Sb3 Eu4 Sb3 . . 5_555 80.08(2) ?
Sb3 Eu4 Sb3 . . 8_555 71.97(2) ?
Sb3 Eu4 Sb3 5_555 . 8_555 150.78(3) ?
Eu2 Al Eu2 7_455 . 8_555 74.277(13) ?
Eu2 Al Eu2 7_455 . 29_555 129.457(13) ?
Eu2 Al Eu2 7_455 . 14_555 129.457(13) ?
Eu2 Al Sb2 7_455 . 3_545 71.119(17) ?
Eu2 Al Sb2 7_455 . 20_455 58.968(17) ?
Eu2 Al Sb2 7_455 . 25_555 85.138(17) ?
Eu2 Al Sb2 7_455 . 26_455 157.499(17) ?
Eu2 Al Eu2 8_555 . 29_555 129.457(13) ?
Eu2 Al Eu2 8_555 . 14_555 129.457(13) ?
Eu2 Al Sb2 8_555 . 3_545 58.968(17) ?
Eu2 Al Sb2 8_555 . 20_455 71.119(17) ?
Eu2 Al Sb2 8_555 . 25_555 157.499(17) ?
Eu2 Al Sb2 8_555 . 26_455 85.138(17) ?
Eu2 Al Eu2 29_555 . 14_555 74.277(13) ?
Eu2 Al Sb2 29_555 . 3_545 85.138(17) ?
Eu2 Al Sb2 29_555 . 20_455 157.499(17) ?
Eu2 Al Sb2 29_555 . 25_555 58.968(17) ?
Eu2 Al Sb2 29_555 . 26_455 71.119(17) ?
Eu2 Al Sb2 14_555 . 3_545 157.499(17) ?
Eu2 Al Sb2 14_555 . 20_455 85.138(17) ?
Eu2 Al Sb2 14_555 . 25_555 71.119(17) ?
Eu2 Al Sb2 14_555 . 26_455 58.968(17) ?
Sb2 Al Sb2 3_545 . 20_455 116.49(2) ?
Sb2 Al Sb2 3_545 . 25_555 106.08(2) ?
Sb2 Al Sb2 3_545 . 26_455 106.08(2) ?
Sb2 Al Sb2 20_455 . 25_555 106.08(2) ?
Sb2 Al Sb2 20_455 . 26_455 106.08(2) ?
Sb2 Al Sb2 25_555 . 26_455 116.49(2) ?
Eu1 Sb1 Eu1 2_555 . 8_555 121.80(3) ?
Eu1 Sb1 Eu2 2_555 . . 75.47(2) ?
Eu1 Sb1 Eu2 2_555 . 7_455 80.684(18) ?
Eu1 Sb1 Eu3 2_555 . 25_555 69.835(19) ?
Eu1 Sb1 Eu3 2_555 . 27_555 140.999(19) ?
Eu1 Sb1 Eu4 2_555 . 27_555 141.69(2) ?
Eu1 Sb1 Eu4 2_555 . 30_555 88.35(2) ?
Eu1 Sb1 Sb4 2_555 . . 60.902(17) ?
Eu1 Sb1 Eu2 8_555 . . 80.684(18) ?
Eu1 Sb1 Eu2 8_555 . 7_455 75.47(2) ?
Eu1 Sb1 Eu3 8_555 . 25_555 140.999(19) ?
Eu1 Sb1 Eu3 8_555 . 27_555 69.835(19) ?
Eu1 Sb1 Eu4 8_555 . 27_555 88.35(2) ?
Eu1 Sb1 Eu4 8_555 . 30_555 141.69(2) ?
Eu1 Sb1 Sb4 8_555 . . 60.902(17) ?
Eu2 Sb1 Eu2 . . 7_455 129.79(3) ?
Eu2 Sb1 Eu3 . . 25_555 136.12(3) ?
Eu2 Sb1 Eu3 . . 27_555 69.912(10) ?
Eu2 Sb1 Eu4 . . 27_555 137.410(19) ?
Eu2 Sb1 Eu4 . . 30_555 85.606(19) ?
Eu2 Sb1 Sb4 . . . 64.893(16) ?
Eu2 Sb1 Eu3 7_455 . 25_555 69.912(10) ?
Eu2 Sb1 Eu3 7_455 . 27_555 136.12(3) ?
Eu2 Sb1 Eu4 7_455 . 27_555 85.606(19) ?
Eu2 Sb1 Eu4 7_455 . 30_555 137.410(19) ?
Eu2 Sb1 Sb4 7_455 . . 64.893(16) ?
Eu3 Sb1 Eu3 25_555 . 27_555 127.21(3) ?
Eu3 Sb1 Eu4 25_555 . 27_555 71.87(2) ?
Eu3 Sb1 Eu4 25_555 . 30_555 67.672(16) ?
Eu3 Sb1 Sb4 25_555 . . 116.396(17) ?
Eu3 Sb1 Eu4 27_555 . 27_555 67.672(16) ?
Eu3 Sb1 Eu4 27_555 . 30_555 71.87(2) ?
Eu3 Sb1 Sb4 27_555 . . 116.396(17) ?
Eu4 Sb1 Eu4 27_555 . 30_555 77.98(2) ?
Eu4 Sb1 Sb4 27_555 . . 141.01(3) ?
Eu4 Sb1 Sb4 30_555 . . 141.01(3) ?
Eu1 Sb2 Eu1 4_554 . 8_555 80.84(2) ?
Eu1 Sb2 Eu2 4_554 . 5_555 81.69(2) ?
Eu1 Sb2 Eu2 4_554 . 22_555 69.092(18) ?
Eu1 Sb2 Eu3 4_554 . 27_555 69.677(18) ?
Eu1 Sb2 Eu4 4_554 . . 86.75(2) ?
Eu1 Sb2 Eu4 4_554 . 27_555 135.46(3) ?
Eu1 Sb2 Al 4_554 . 19_554 132.63(3) ?
Eu1 Sb2 Eu2 8_555 . 5_555 142.34(3) ?
Eu1 Sb2 Eu2 8_555 . 22_555 125.69(2) ?
Eu1 Sb2 Eu3 8_555 . 27_555 70.222(19) ?
Eu1 Sb2 Eu4 8_555 . . 67.74(2) ?
Eu1 Sb2 Eu4 8_555 . 27_555 83.94(2) ?
Eu1 Sb2 Al 8_555 . 19_554 139.02(2) ?
Eu2 Sb2 Eu2 5_555 . 22_555 77.32(2) ?
Eu2 Sb2 Eu3 5_555 . 27_555 72.471(19) ?
Eu2 Sb2 Eu4 5_555 . . 143.73(3) ?
Eu2 Sb2 Eu4 5_555 . 27_555 85.57(2) ?
Eu2 Sb2 Al 5_555 . 19_554 74.91(2) ?
Eu2 Sb2 Eu3 22_555 . 27_555 131.48(2) ?
Eu2 Sb2 Eu4 22_555 . . 66.448(19) ?
Eu2 Sb2 Eu4 22_555 . 27_555 147.74(3) ?
Eu2 Sb2 Al 22_555 . 19_554 65.912(18) ?
Eu3 Sb2 Eu4 27_555 . . 134.36(3) ?
Eu3 Sb2 Eu4 27_555 . 27_555 65.787(18) ?
Eu3 Sb2 Al 27_555 . 19_554 136.19(3) ?
Eu4 Sb2 Eu4 . . 27_555 124.97(2) ?
Eu4 Sb2 Al . . 19_554 88.54(2) ?
Eu4 Sb2 Al 27_555 . 19_554 83.404(19) ?
Eu1 Sb3 Eu1 . . 8_555 71.89(2) ?
Eu1 Sb3 Eu2 . . 2_555 77.01(2) ?
Eu1 Sb3 Eu2 . . 10_545 102.59(3) ?
Eu1 Sb3 Eu3 . . 4_554 138.05(3) ?
Eu1 Sb3 Eu4 . . . 98.42(2) ?
Eu1 Sb3 Eu4 . . 5_555 146.62(3) ?
Eu1 Sb3 Eu4 . . 8_555 67.515(19) ?
Eu1 Sb3 Eu2 8_555 . 2_555 76.88(2) ?
Eu1 Sb3 Eu2 8_555 . 10_545 157.50(3) ?
Eu1 Sb3 Eu3 8_555 . 4_554 125.56(3) ?
Eu1 Sb3 Eu4 8_555 . . 61.931(19) ?
Eu1 Sb3 Eu4 8_555 . 5_555 87.99(2) ?
Eu1 Sb3 Eu4 8_555 . 8_555 109.82(2) ?
Eu2 Sb3 Eu2 2_555 . 10_545 80.63(2) ?
Eu2 Sb3 Eu3 2_555 . 4_554 139.78(2) ?
Eu2 Sb3 Eu4 2_555 . . 137.50(3) ?
Eu2 Sb3 Eu4 2_555 . 5_555 72.54(2) ?
Eu2 Sb3 Eu4 2_555 . 8_555 138.66(3) ?
Eu2 Sb3 Eu3 10_545 . 4_554 73.46(2) ?
Eu2 Sb3 Eu4 10_545 . . 140.15(3) ?
Eu2 Sb3 Eu4 10_545 . 5_555 85.79(2) ?
Eu2 Sb3 Eu4 10_545 . 8_555 86.88(2) ?
Eu3 Sb3 Eu4 4_554 . . 68.295(19) ?
Eu3 Sb3 Eu4 4_554 . 5_555 75.324(19) ?
Eu3 Sb3 Eu4 4_554 . 8_555 70.560(19) ?
Eu4 Sb3 Eu4 . . 5_555 94.88(2) ?
Eu4 Sb3 Eu4 . . 8_555 70.47(2) ?
Eu4 Sb3 Eu4 5_555 . 8_555 145.80(3) ?
Eu1 Sb4 Eu1 . . 2_555 142.795(13) ?
Eu1 Sb4 Eu1 . . 7_455 121.360(14) ?
Eu1 Sb4 Eu1 . . 8_555 71.525(14) ?
Eu1 Sb4 Eu2 . . . 142.170(13) ?
Eu1 Sb4 Eu2 . . 2_555 73.191(13) ?
Eu1 Sb4 Eu2 . . 7_455 72.775(13) ?
Eu1 Sb4 Eu2 . . 8_555 78.198(13) ?
Eu1 Sb4 Sb1 . . . 119.320(16) ?
Eu1 Sb4 Sb1 . . 2_555 60.680(16) ?
Eu1 Sb4 Eu1 2_555 . 7_455 71.525(14) ?
Eu1 Sb4 Eu1 2_555 . 8_555 121.360(14) ?
Eu1 Sb4 Eu2 2_555 . . 73.191(13) ?
Eu1 Sb4 Eu2 2_555 . 2_555 142.170(13) ?
Eu1 Sb4 Eu2 2_555 . 7_455 78.198(13) ?
Eu1 Sb4 Eu2 2_555 . 8_555 72.775(13) ?
Eu1 Sb4 Sb1 2_555 . . 60.680(16) ?
Eu1 Sb4 Sb1 2_555 . 2_555 119.320(16) ?
Eu1 Sb4 Eu1 7_455 . 8_555 142.795(13) ?
Eu1 Sb4 Eu2 7_455 . . 72.775(13) ?
Eu1 Sb4 Eu2 7_455 . 2_555 78.198(13) ?
Eu1 Sb4 Eu2 7_455 . 7_455 142.170(13) ?
Eu1 Sb4 Eu2 7_455 . 8_555 73.191(13) ?
Eu1 Sb4 Sb1 7_455 . . 119.320(16) ?
Eu1 Sb4 Sb1 7_455 . 2_555 60.680(16) ?
Eu1 Sb4 Eu2 8_555 . . 78.198(13) ?
Eu1 Sb4 Eu2 8_555 . 2_555 72.775(13) ?
Eu1 Sb4 Eu2 8_555 . 7_455 73.191(13) ?
Eu1 Sb4 Eu2 8_555 . 8_555 142.170(13) ?
Eu1 Sb4 Sb1 8_555 . . 60.680(16) ?
Eu1 Sb4 Sb1 8_555 . 2_555 119.320(16) ?
Eu2 Sb4 Eu2 . . 2_555 76.608(14) ?
Eu2 Sb4 Eu2 . . 7_455 119.456(13) ?
Eu2 Sb4 Eu2 . . 8_555 137.719(13) ?
Eu2 Sb4 Sb1 . . . 59.728(11) ?
Eu2 Sb4 Sb1 . . 2_555 120.272(11) ?
Eu2 Sb4 Eu2 2_555 . 7_455 137.719(13) ?
Eu2 Sb4 Eu2 2_555 . 8_555 119.456(13) ?
Eu2 Sb4 Sb1 2_555 . . 120.272(11) ?
Eu2 Sb4 Sb1 2_555 . 2_555 59.728(11) ?
Eu2 Sb4 Eu2 7_455 . 8_555 76.608(14) ?
Eu2 Sb4 Sb1 7_455 . . 59.728(11) ?
Eu2 Sb4 Sb1 7_455 . 2_555 120.272(11) ?
Eu2 Sb4 Sb1 8_555 . . 120.272(11) ?
Eu2 Sb4 Sb1 8_555 . 2_555 59.728(11) ?
Sb1 Sb4 Sb1 . . 2_555 180.0(5) ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
? ? ? ? ? ? ? ? ? ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
? ? ? ? ? ? ? ? ? ? ?


#=======================================================================

# 11. STRUCTURE-FACTOR LIST



