# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_agpypo_meta
_database_code_depnum_ccdc_archive 'CCDC 1883488'
_audit_update_record             
;
2018-12-06 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C10 H11 Ag N2 O6 P2'
_chemical_formula_sum            'C10 H11 Ag N2 O6 P2'
_chemical_formula_weight         425.02

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.3129(8)
_cell_length_b                   6.2896(6)
_cell_length_c                   12.7052(12)
_cell_angle_alpha                90
_cell_angle_beta                 93.007(4)
_cell_angle_gamma                90
_cell_volume                     663.37(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    4354
_cell_measurement_theta_min      2.8609
_cell_measurement_theta_max      27.5253

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.128
_exptl_crystal_F_000             420
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.386
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.112
_exptl_absorpt_coefficient_mu    1.790
_shelx_estimated_absorpt_T_min   0.545
_shelx_estimated_absorpt_T_max   0.825
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS V2014/5 (Bruker AXS Inc.)'
_exptl_absorpt_correction_T_min  0.58
_exptl_absorpt_correction_T_max  0.71
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Nonius KappaCCD with Bruker APEXII detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            7704
_diffrn_reflns_av_unetI/netI     0.0182
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.861
_diffrn_reflns_theta_max         27.489
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             1521
_reflns_number_gt                1415
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0259P)²+0.4690P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1521
_refine_ls_number_parameters     100
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0220
_refine_ls_R_factor_gt           0.0197
_refine_ls_wR_factor_ref         0.0511
_refine_ls_wR_factor_gt          0.0494
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.000000 0.000000 0.000000 0.02210(8) Uani 1 2 d S . P . .
P1 P 1.07017(5) 0.61257(7) 0.32471(3) 0.01152(11) Uani 1 1 d . . . . .
O1 O 1.22545(16) 0.49082(18) 0.32964(11) 0.0148(3) Uani 1 1 d . . . . .
O2 O 1.09427(16) 0.8590(2) 0.31623(10) 0.0160(3) Uani 1 1 d D . . . .
H2 H 1.149(3) 0.895(4) 0.2739(17) 0.019 Uiso 1 1 d D U . . .
O3 O 0.96190(16) 0.5786(2) 0.41580(10) 0.0186(3) Uani 1 1 d . . . . .
H3O H 1.000000 0.500000 0.500000 0.028 Uiso 1 2 d S U P . .
N1 N 0.91016(18) 0.2809(2) 0.06845(12) 0.0151(3) Uani 1 1 d . . . . .
C1 C 0.9902(2) 0.3511(3) 0.15674(14) 0.0136(3) Uani 1 1 d . . . . .
H1 H 1.076375 0.267214 0.186091 0.016 Uiso 1 1 calc R U . . .
C2 C 0.9535(2) 0.5385(3) 0.20674(14) 0.0117(3) Uani 1 1 d . . . . .
C3 C 0.8255(2) 0.6599(3) 0.16335(14) 0.0152(3) Uani 1 1 d . . . . .
H3 H 0.797168 0.790726 0.194888 0.018 Uiso 1 1 calc R U . . .
C4 C 0.7404(2) 0.5869(3) 0.07370(15) 0.0181(4) Uani 1 1 d . . . . .
H4 H 0.651649 0.665423 0.043877 0.022 Uiso 1 1 calc R U . . .
C5 C 0.7868(2) 0.3975(3) 0.02820(14) 0.0167(4) Uani 1 1 d . . . . .
H5 H 0.729011 0.348834 -0.033669 0.020 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.1219(15) . ?
Ag1 N1 2.1219(15) 3_755 ?
P1 O1 1.4993(13) . ?
P1 O3 1.5181(14) . ?
P1 O2 1.5670(14) . ?
P1 C2 1.8032(18) . ?
O2 H2 0.760(19) . ?
O3 H3O 1.2100 . ?
N1 C5 1.341(2) . ?
N1 C1 1.348(2) . ?
C1 C2 1.381(2) . ?
C1 H1 0.9500 . ?
C2 C3 1.399(2) . ?
C3 C4 1.387(2) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(3) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N1 180.0 . 3_755 ?
O1 P1 O3 116.09(8) . . ?
O1 P1 O2 113.27(7) . . ?
O3 P1 O2 105.95(8) . . ?
O1 P1 C2 109.10(8) . . ?
O3 P1 C2 106.42(8) . . ?
O2 P1 C2 105.27(8) . . ?
P1 O2 H2 115.4(19) . . ?
P1 O3 H3O 127.00 . . ?
C5 N1 C1 118.19(16) . . ?
C5 N1 Ag1 125.31(12) . . ?
C1 N1 Ag1 116.41(12) . . ?
N1 C1 C2 123.44(16) . . ?
N1 C1 H1 118.3 . . ?
C2 C1 H1 118.3 . . ?
C1 C2 C3 117.81(16) . . ?
C1 C2 P1 118.72(13) . . ?
C3 C2 P1 123.46(14) . . ?
C4 C3 C2 119.16(17) . . ?
C4 C3 H3 120.4 . . ?
C2 C3 H3 120.4 . . ?
C3 C4 C5 119.06(16) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 H4 120.5 . . ?
N1 C5 C4 122.32(16) . . ?
N1 C5 H5 118.8 . . ?
C4 C5 H5 118.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 -1.2(3) . . . . ?
Ag1 N1 C1 C2 175.61(14) . . . . ?
N1 C1 C2 C3 0.5(3) . . . . ?
N1 C1 C2 P1 179.74(14) . . . . ?
O1 P1 C2 C1 18.76(17) . . . . ?
O3 P1 C2 C1 -107.20(15) . . . . ?
O2 P1 C2 C1 140.63(15) . . . . ?
O1 P1 C2 C3 -162.07(15) . . . . ?
O3 P1 C2 C3 71.97(17) . . . . ?
O2 P1 C2 C3 -40.21(17) . . . . ?
C1 C2 C3 C4 0.7(3) . . . . ?
P1 C2 C3 C4 -178.43(14) . . . . ?
C2 C3 C4 C5 -1.3(3) . . . . ?
C1 N1 C5 C4 0.5(3) . . . . ?
Ag1 N1 C5 C4 -175.95(14) . . . . ?
C3 C4 C5 N1 0.7(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O2 H2 O1 0.760(19) 1.82(2) 2.5807(19) 177(3) 2_755 yes
C1 H1 O1 0.95 2.41 3.272(2) 150.7 2_745 yes

_refine_diff_density_max         0.477
_refine_diff_density_min         -0.450
_refine_diff_density_rms         0.074



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ag2pypo
_database_code_depnum_ccdc_archive 'CCDC 1883489'
_audit_update_record             
;
2018-12-06 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C15 H12 Ag7 N4 O12 P3'
_chemical_formula_sum            'C15 H12 Ag7 N4 O12 P3'
_chemical_formula_weight         1288.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   5.8965(2)
_cell_length_b                   31.1708(12)
_cell_length_c                   13.7850(5)
_cell_angle_alpha                90
_cell_angle_beta                 101.0070(10)
_cell_angle_gamma                90
_cell_volume                     2487.05(16)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9066
_cell_measurement_theta_min      2.4714
_cell_measurement_theta_max      28.1597
_cell_measurement_temperature    150.(2)

_exptl_crystal_description       plate
_exptl_crystal_colour            'translucent colourless'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.441
_exptl_crystal_F_000             2400
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.645
_exptl_crystal_size_mid          0.299
_exptl_crystal_size_min          0.104
_exptl_absorpt_coefficient_mu    5.661
_shelx_estimated_absorpt_T_min   0.121
_shelx_estimated_absorpt_T_max   0.591
_exptl_absorpt_correction_type   'Numerical Mu From Formula'
_exptl_absorpt_process_details   
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
;
_exptl_absorpt_correction_T_min  0.57
_exptl_absorpt_correction_T_max  0.87
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            113416
_diffrn_reflns_av_unetI/netI     0.0280
_diffrn_reflns_av_R_equivalents  0.0886
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.471
_diffrn_reflns_theta_max         28.313
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6183
_reflns_number_gt                5228
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0128P)²+5.6712P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6183
_refine_ls_number_parameters     375
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0388
_refine_ls_R_factor_gt           0.0258
_refine_ls_wR_factor_ref         0.0441
_refine_ls_wR_factor_gt          0.0414
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_restrained_S_all      1.077
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.66225(5) -0.03100(2) 0.92588(2) 0.01700(6) Uani 1 1 d . . . . .
Ag2 Ag 0.08309(5) -0.01288(2) 0.79541(2) 0.01572(6) Uani 1 1 d . . . . .
Ag3 Ag -0.37338(5) 0.03913(2) 0.75103(2) 0.01448(6) Uani 1 1 d . . . . .
Ag4 Ag 0.26572(4) 0.09183(2) 0.88606(2) 0.01391(6) Uani 1 1 d . . . . .
Ag5 Ag 0.24894(5) -0.00466(2) 0.48781(2) 0.01251(6) Uani 1 1 d . . . . .
Ag6 Ag -0.02518(5) 0.09400(2) 0.39438(2) 0.02013(7) Uani 1 1 d . . . . .
Ag7 Ag 0.52874(5) 0.11241(2) 0.53891(2) 0.01722(6) Uani 1 1 d . . . . .
C1 C 0.7583(6) 0.12400(11) 0.9793(2) 0.0107(7) Uani 1 1 d . . . . .
C2 C 0.5095(6) 0.18107(12) 0.9352(3) 0.0175(8) Uani 1 1 d . . . . .
H2 H 0.357697 0.191321 0.910624 0.021 Uiso 1 1 calc R U . . .
C3 C 0.6835(7) 0.21076(12) 0.9630(3) 0.0204(8) Uani 1 1 d . . . . .
H3 H 0.652887 0.240622 0.955651 0.024 Uiso 1 1 calc R U . . .
C4 C 0.9035(7) 0.19607(12) 1.0019(3) 0.0205(8) Uani 1 1 d . . . . .
H4 H 1.027644 0.215584 1.021261 0.025 Uiso 1 1 calc R U . . .
C5 C 0.9384(6) 0.15242(12) 1.0118(3) 0.0162(8) Uani 1 1 d . . . . .
H5 H 1.086512 0.141697 1.040971 0.019 Uiso 1 1 calc R U . . .
C6 C 0.6324(6) -0.11209(11) 0.7256(2) 0.0122(7) Uani 1 1 d . . . . .
C7 C 0.8573(8) -0.17231(13) 0.7168(3) 0.0275(10) Uani 1 1 d . . . . .
H7 H 0.981589 -0.185766 0.693829 0.033 Uiso 1 1 calc R U . . .
C8 C 0.7331(9) -0.19573(14) 0.7735(3) 0.0339(11) Uani 1 1 d . . . . .
H8 H 0.770268 -0.224950 0.788347 0.041 Uiso 1 1 calc R U . . .
C9 C 0.5550(8) -0.17642(14) 0.8082(3) 0.0311(11) Uani 1 1 d . U . . .
H9 H 0.468108 -0.192017 0.847740 0.037 Uiso 1 1 calc R U . . .
C10 C 0.5044(7) -0.13400(13) 0.7848(3) 0.0219(9) Uani 1 1 d . . . . .
H10 H 0.383450 -0.119899 0.808925 0.026 Uiso 1 1 calc R U . . .
C11 C 0.1316(6) 0.12942(11) 0.6643(2) 0.0106(7) Uani 1 1 d . . . . .
C12 C -0.0067(7) 0.15194(12) 0.7183(3) 0.0180(8) Uani 1 1 d . . . . .
H12 H -0.130940 0.137904 0.740078 0.022 Uiso 1 1 calc R U . . .
C13 C 0.0376(8) 0.19461(13) 0.7399(3) 0.0264(10) Uani 1 1 d . . . . .
H13 H -0.053988 0.210282 0.777324 0.032 Uiso 1 1 calc R U . . .
C14 C 0.2174(8) 0.21414(13) 0.7061(3) 0.0281(10) Uani 1 1 d . U . . .
H14 H 0.251841 0.243566 0.719533 0.034 Uiso 1 1 calc R U . . .
C15 C 0.3463(8) 0.19015(13) 0.6524(3) 0.0252(9) Uani 1 1 d . . . . .
H15 H 0.468654 0.203918 0.628599 0.030 Uiso 1 1 calc R U . . .
N1 N 0.5434(5) 0.13847(10) 0.9410(2) 0.0129(6) Uani 1 1 d . . . . .
N2 N 0.8087(5) -0.13109(10) 0.6930(2) 0.0180(7) Uani 1 1 d . . . . .
N3 N 0.7276(7) 0.19942(12) 0.4518(3) 0.0317(9) Uani 1 1 d . . . . .
N4 N 0.3080(5) 0.14818(10) 0.6319(2) 0.0168(7) Uani 1 1 d . . . . .
O1 O 0.4481(4) -0.03734(9) 0.76541(18) 0.0197(6) Uani 1 1 d . . . . .
O2 O -0.1711(4) 0.06460(8) 0.63349(17) 0.0139(5) Uani 1 1 d . . . . .
O3 O 0.2305(4) 0.05047(8) 0.73323(17) 0.0109(5) Uani 1 1 d . . . . .
O4 O 0.5892(4) 0.04263(8) 0.96656(18) 0.0138(5) Uani 1 1 d . . . . .
O5 O 0.9812(4) 0.05793(8) 1.07727(17) 0.0142(5) Uani 1 1 d . . . . .
O6 O -0.0709(4) 0.05956(8) 0.88954(18) 0.0131(5) Uani 1 1 d . . . . .
O7 O 0.1718(4) 0.06129(8) 0.54782(17) 0.0141(5) Uani 1 1 d . . . . .
O8 O 0.2330(4) 0.03461(8) 0.33441(17) 0.0139(5) Uani 1 1 d . . . . .
O9 O 0.3749(4) -0.06376(8) 0.58785(17) 0.0121(5) Uani 1 1 d . . . . .
O10 O 0.7562(7) 0.16097(10) 0.4528(3) 0.0501(10) Uani 1 1 d . . . . .
O11 O 0.7641(6) 0.22458(10) 0.3893(2) 0.0410(8) Uani 1 1 d . . . . .
O12A O 0.7366(10) 0.21816(17) 0.5370(4) 0.0439(19) Uani 0.633(8) 1 d . . P . .
O12B O 0.5036(18) 0.1996(3) 0.4649(7) 0.049(3) Uiso 0.367(8) 1 d . . P . .
P1 P 0.08713(15) 0.07208(3) 0.64254(6) 0.00851(17) Uani 1 1 d . . . . .
P2 P 0.81830(15) 0.06645(3) 0.98005(6) 0.00940(17) Uani 1 1 d . . . . .
P3 P 0.55212(15) -0.05777(3) 0.68432(6) 0.00959(17) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O5 2.272(2) 3_757 ?
Ag1 O4 2.317(2) 3_657 ?
Ag1 O1 2.337(3) . ?
Ag1 O4 2.421(2) . ?
Ag1 Ag4 3.1743(4) 3_657 ?
Ag1 Ag3 3.2309(4) 1_655 ?
Ag1 Ag2 3.3787(4) 1_655 ?
Ag2 O5 2.334(2) 3_657 ?
Ag2 O3 2.382(2) . ?
Ag2 O1 2.393(2) . ?
Ag2 O8 2.421(2) 3_556 ?
Ag2 Ag3 3.1015(4) . ?
Ag3 O2 2.327(2) . ?
Ag3 O3 2.328(2) 1_455 ?
Ag3 O6 2.436(2) . ?
Ag4 N1 2.212(3) . ?
Ag4 O6 2.234(2) . ?
Ag4 O3 2.445(2) . ?
Ag4 O4 2.532(2) . ?
Ag5 O7 2.294(2) . ?
Ag5 O9 2.336(2) . ?
Ag5 O8 2.430(2) . ?
Ag5 O2 2.491(2) 3_556 ?
Ag5 Ag5 2.9298(5) 3_656 ?
Ag5 Ag5 3.0320(5) 3_556 ?
Ag6 N2 2.237(3) 3_656 ?
Ag6 O9 2.323(2) 3_556 ?
Ag6 O7 2.434(2) . ?
Ag7 N4 2.284(3) . ?
Ag7 O9 2.461(2) 3_656 ?
Ag7 O10 2.471(3) . ?
Ag7 O2 2.485(2) 1_655 ?
C1 N1 1.354(4) . ?
C1 C5 1.390(5) . ?
C1 P2 1.828(4) . ?
C2 N1 1.343(5) . ?
C2 C3 1.381(5) . ?
C2 H2 0.9500 . ?
C3 C4 1.383(5) . ?
C3 H3 0.9500 . ?
C4 C5 1.379(5) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 N2 1.346(5) . ?
C6 C10 1.392(5) . ?
C6 P3 1.820(4) . ?
C7 N2 1.344(5) . ?
C7 C8 1.377(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.374(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.380(6) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 N4 1.342(4) . ?
C11 C12 1.394(5) . ?
C11 P1 1.823(4) . ?
C12 C13 1.377(6) . ?
C12 H12 0.9500 . ?
C13 C14 1.379(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.378(6) . ?
C14 H14 0.9500 . ?
C15 N4 1.349(5) . ?
C15 H15 0.9500 . ?
N3 O10 1.210(5) . ?
N3 O11 1.214(4) . ?
N3 O12A 1.303(6) . ?
N3 O12B 1.367(10) . ?
O1 P3 1.514(3) . ?
O2 P1 1.522(2) . ?
O3 P1 1.526(2) . ?
O4 P2 1.522(2) . ?
O5 P2 1.516(3) . ?
O6 P2 1.530(2) 1_455 ?
O7 P1 1.522(2) . ?
O8 P3 1.522(3) 3_656 ?
O9 P3 1.538(2) . ?
O12A O12B 1.640(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Ag1 O4 131.45(9) 3_757 3_657 ?
O5 Ag1 O1 106.59(9) 3_757 . ?
O4 Ag1 O1 107.25(9) 3_657 . ?
O5 Ag1 O4 124.13(9) 3_757 . ?
O4 Ag1 O4 80.56(9) 3_657 . ?
O1 Ag1 O4 102.22(9) . . ?
O5 Ag1 Ag4 79.33(6) 3_757 3_657 ?
O4 Ag1 Ag4 52.12(6) 3_657 3_657 ?
O1 Ag1 Ag4 133.35(7) . 3_657 ?
O4 Ag1 Ag4 112.28(6) . 3_657 ?
O5 Ag1 Ag3 99.46(6) 3_757 1_655 ?
O4 Ag1 Ag3 128.68(6) 3_657 1_655 ?
O1 Ag1 Ag3 53.46(7) . 1_655 ?
O4 Ag1 Ag3 62.76(6) . 1_655 ?
Ag4 Ag1 Ag3 173.179(12) 3_657 1_655 ?
O5 Ag1 Ag2 43.55(6) 3_757 1_655 ?
O4 Ag1 Ag2 172.57(6) 3_657 1_655 ?
O1 Ag1 Ag2 80.17(6) . 1_655 ?
O4 Ag1 Ag2 98.41(6) . 1_655 ?
Ag4 Ag1 Ag2 122.496(11) 3_657 1_655 ?
Ag3 Ag1 Ag2 55.913(8) 1_655 1_655 ?
O5 Ag2 O3 153.12(8) 3_657 . ?
O5 Ag2 O1 102.65(9) 3_657 . ?
O3 Ag2 O1 78.46(9) . . ?
O5 Ag2 O8 100.06(8) 3_657 3_556 ?
O3 Ag2 O8 104.38(8) . 3_556 ?
O1 Ag2 O8 111.97(9) . 3_556 ?
O5 Ag2 Ag3 101.73(6) 3_657 . ?
O3 Ag2 Ag3 81.85(6) . . ?
O1 Ag2 Ag3 155.22(6) . . ?
O8 Ag2 Ag3 58.92(6) 3_556 . ?
O5 Ag2 Ag1 42.10(6) 3_657 1_455 ?
O3 Ag2 Ag1 133.29(6) . 1_455 ?
O1 Ag2 Ag1 144.60(7) . 1_455 ?
O8 Ag2 Ag1 78.85(6) 3_556 1_455 ?
Ag3 Ag2 Ag1 59.631(9) . 1_455 ?
O2 Ag3 O3 120.80(8) . 1_455 ?
O2 Ag3 O6 93.48(8) . . ?
O3 Ag3 O6 127.78(8) 1_455 . ?
O2 Ag3 Ag2 76.98(6) . . ?
O3 Ag3 Ag2 156.27(6) 1_455 . ?
O6 Ag3 Ag2 60.26(6) . . ?
O2 Ag3 Ag1 141.37(6) . 1_455 ?
O3 Ag3 Ag1 95.87(6) 1_455 1_455 ?
O6 Ag3 Ag1 70.03(6) . 1_455 ?
Ag2 Ag3 Ag1 64.454(9) . 1_455 ?
N1 Ag4 O6 153.01(10) . . ?
N1 Ag4 O3 125.25(9) . . ?
O6 Ag4 O3 81.46(8) . . ?
N1 Ag4 O4 78.57(9) . . ?
O6 Ag4 O4 108.41(8) . . ?
O3 Ag4 O4 89.50(8) . . ?
N1 Ag4 Ag1 97.94(8) . 3_657 ?
O6 Ag4 Ag1 72.20(6) . 3_657 ?
O3 Ag4 Ag1 111.40(6) . 3_657 ?
O4 Ag4 Ag1 46.23(5) . 3_657 ?
O7 Ag5 O9 123.81(8) . . ?
O7 Ag5 O8 83.40(8) . . ?
O9 Ag5 O8 150.03(8) . . ?
O7 Ag5 O2 152.95(8) . 3_556 ?
O9 Ag5 O2 78.57(8) . 3_556 ?
O8 Ag5 O2 79.76(8) . 3_556 ?
O7 Ag5 Ag5 97.78(6) . 3_656 ?
O9 Ag5 Ag5 79.05(6) . 3_656 ?
O8 Ag5 Ag5 85.42(6) . 3_656 ?
O2 Ag5 Ag5 101.78(6) 3_556 3_656 ?
O7 Ag5 Ag5 67.13(6) . 3_556 ?
O9 Ag5 Ag5 102.45(6) . 3_556 ?
O8 Ag5 Ag5 99.84(6) . 3_556 ?
O2 Ag5 Ag5 95.05(6) 3_556 3_556 ?
Ag5 Ag5 Ag5 163.03(2) 3_656 3_556 ?
N2 Ag6 O9 151.17(10) 3_656 3_556 ?
N2 Ag6 O7 117.23(10) 3_656 . ?
O9 Ag6 O7 91.40(8) 3_556 . ?
N4 Ag7 O9 158.89(10) . 3_656 ?
N4 Ag7 O10 112.97(11) . . ?
O9 Ag7 O10 79.41(9) 3_656 . ?
N4 Ag7 O2 115.06(10) . 1_655 ?
O9 Ag7 O2 76.41(8) 3_656 1_655 ?
O10 Ag7 O2 102.82(11) . 1_655 ?
N1 C1 C5 120.9(3) . . ?
N1 C1 P2 119.7(3) . . ?
C5 C1 P2 119.2(3) . . ?
N1 C2 C3 123.5(3) . . ?
N1 C2 H2 118.2 . . ?
C3 C2 H2 118.2 . . ?
C2 C3 C4 118.5(4) . . ?
C2 C3 H3 120.7 . . ?
C4 C3 H3 120.7 . . ?
C5 C4 C3 118.4(4) . . ?
C5 C4 H4 120.8 . . ?
C3 C4 H4 120.8 . . ?
C4 C5 C1 120.5(3) . . ?
C4 C5 H5 119.8 . . ?
C1 C5 H5 119.8 . . ?
N2 C6 C10 121.3(3) . . ?
N2 C6 P3 118.4(3) . . ?
C10 C6 P3 120.2(3) . . ?
N2 C7 C8 122.3(4) . . ?
N2 C7 H7 118.9 . . ?
C8 C7 H7 118.9 . . ?
C9 C8 C7 119.3(4) . . ?
C9 C8 H8 120.3 . . ?
C7 C8 H8 120.3 . . ?
C8 C9 C10 119.0(4) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
C9 C10 C6 119.3(4) . . ?
C9 C10 H10 120.3 . . ?
C6 C10 H10 120.3 . . ?
N4 C11 C12 121.9(3) . . ?
N4 C11 P1 118.0(3) . . ?
C12 C11 P1 120.1(3) . . ?
C13 C12 C11 119.7(4) . . ?
C13 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C12 C13 C14 118.6(4) . . ?
C12 C13 H13 120.7 . . ?
C14 C13 H13 120.7 . . ?
C15 C14 C13 118.7(4) . . ?
C15 C14 H14 120.6 . . ?
C13 C14 H14 120.6 . . ?
N4 C15 C14 123.5(4) . . ?
N4 C15 H15 118.3 . . ?
C14 C15 H15 118.3 . . ?
C2 N1 C1 118.0(3) . . ?
C2 N1 Ag4 122.5(2) . . ?
C1 N1 Ag4 119.4(2) . . ?
C7 N2 C6 118.8(3) . . ?
C7 N2 Ag6 120.6(3) . 3_656 ?
C6 N2 Ag6 120.6(2) . 3_656 ?
O10 N3 O11 127.2(4) . . ?
O10 N3 O12A 116.9(4) . . ?
O11 N3 O12A 111.6(4) . . ?
O10 N3 O12B 97.9(5) . . ?
O11 N3 O12B 113.4(5) . . ?
O12A N3 O12B 75.8(5) . . ?
C11 N4 C15 117.6(3) . . ?
C11 N4 Ag7 122.3(2) . . ?
C15 N4 Ag7 120.0(3) . . ?
P3 O1 Ag1 120.83(14) . . ?
P3 O1 Ag2 140.01(15) . . ?
Ag1 O1 Ag2 98.67(9) . . ?
P1 O2 Ag3 129.27(14) . . ?
P1 O2 Ag7 123.55(13) . 1_455 ?
Ag3 O2 Ag7 99.29(9) . 1_455 ?
P1 O2 Ag5 102.90(12) . 3_556 ?
Ag3 O2 Ag5 99.10(9) . 3_556 ?
Ag7 O2 Ag5 94.37(8) 1_455 3_556 ?
P1 O3 Ag3 122.76(13) . 1_655 ?
P1 O3 Ag2 118.53(13) . . ?
Ag3 O3 Ag2 105.30(9) 1_655 . ?
P1 O3 Ag4 114.58(13) . . ?
Ag3 O3 Ag4 94.06(8) 1_655 . ?
Ag2 O3 Ag4 95.96(8) . . ?
P2 O4 Ag1 131.29(14) . 3_657 ?
P2 O4 Ag1 107.32(12) . . ?
Ag1 O4 Ag1 99.43(9) 3_657 . ?
P2 O4 Ag4 109.57(12) . . ?
Ag1 O4 Ag4 81.65(7) 3_657 . ?
Ag1 O4 Ag4 128.70(10) . . ?
P2 O5 Ag1 118.72(13) . 3_757 ?
P2 O5 Ag2 127.12(14) . 3_657 ?
Ag1 O5 Ag2 94.36(9) 3_757 3_657 ?
P2 O6 Ag4 118.29(13) 1_455 . ?
P2 O6 Ag3 108.25(12) 1_455 . ?
Ag4 O6 Ag3 128.43(10) . . ?
P1 O7 Ag5 128.87(14) . . ?
P1 O7 Ag6 118.21(13) . . ?
Ag5 O7 Ag6 99.01(9) . . ?
P3 O8 Ag2 123.75(13) 3_656 3_556 ?
P3 O8 Ag5 119.43(13) 3_656 . ?
Ag2 O8 Ag5 113.49(9) 3_556 . ?
P3 O9 Ag6 115.37(13) . 3_556 ?
P3 O9 Ag5 120.12(13) . . ?
Ag6 O9 Ag5 101.17(9) 3_556 . ?
P3 O9 Ag7 118.56(13) . 3_656 ?
Ag6 O9 Ag7 98.90(9) 3_556 3_656 ?
Ag5 O9 Ag7 99.05(8) . 3_656 ?
N3 O10 Ag7 121.7(3) . . ?
N3 O12A O12B 53.9(4) . . ?
N3 O12B O12A 50.4(4) . . ?
O2 P1 O7 112.51(14) . . ?
O2 P1 O3 112.89(13) . . ?
O7 P1 O3 112.60(14) . . ?
O2 P1 C11 105.90(15) . . ?
O7 P1 C11 107.29(15) . . ?
O3 P1 C11 104.96(15) . . ?
O5 P2 O4 114.88(14) . . ?
O5 P2 O6 113.52(14) . 1_655 ?
O4 P2 O6 109.83(14) . 1_655 ?
O5 P2 C1 105.44(15) . . ?
O4 P2 C1 108.16(15) . . ?
O6 P2 C1 104.22(15) 1_655 . ?
O1 P3 O8 113.16(15) . 3_656 ?
O1 P3 O9 112.66(14) . . ?
O8 P3 O9 111.16(13) 3_656 . ?
O1 P3 C6 106.14(16) . . ?
O8 P3 C6 108.61(15) 3_656 . ?
O9 P3 C6 104.52(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 C4 -2.1(6) . . . . ?
C2 C3 C4 C5 -0.5(6) . . . . ?
C3 C4 C5 C1 2.8(6) . . . . ?
N1 C1 C5 C4 -2.6(5) . . . . ?
P2 C1 C5 C4 172.8(3) . . . . ?
N2 C7 C8 C9 -0.9(7) . . . . ?
C7 C8 C9 C10 0.4(6) . . . . ?
C8 C9 C10 C6 0.9(6) . . . . ?
N2 C6 C10 C9 -1.9(6) . . . . ?
P3 C6 C10 C9 174.3(3) . . . . ?
N4 C11 C12 C13 -0.3(6) . . . . ?
P1 C11 C12 C13 175.8(3) . . . . ?
C11 C12 C13 C14 0.8(6) . . . . ?
C12 C13 C14 C15 -0.3(6) . . . . ?
C13 C14 C15 N4 -0.8(7) . . . . ?
C3 C2 N1 C1 2.3(5) . . . . ?
C3 C2 N1 Ag4 -175.6(3) . . . . ?
C5 C1 N1 C2 0.1(5) . . . . ?
P2 C1 N1 C2 -175.3(3) . . . . ?
C5 C1 N1 Ag4 178.0(3) . . . . ?
P2 C1 N1 Ag4 2.7(4) . . . . ?
C8 C7 N2 C6 0.0(6) . . . . ?
C8 C7 N2 Ag6 177.6(3) . . . 3_656 ?
C10 C6 N2 C7 1.4(5) . . . . ?
P3 C6 N2 C7 -174.8(3) . . . . ?
C10 C6 N2 Ag6 -176.3(3) . . . 3_656 ?
P3 C6 N2 Ag6 7.5(4) . . . 3_656 ?
C12 C11 N4 C15 -0.8(5) . . . . ?
P1 C11 N4 C15 -176.9(3) . . . . ?
C12 C11 N4 Ag7 -177.9(3) . . . . ?
P1 C11 N4 Ag7 6.0(4) . . . . ?
C14 C15 N4 C11 1.3(6) . . . . ?
C14 C15 N4 Ag7 178.5(3) . . . . ?
O11 N3 O10 Ag7 -153.1(4) . . . . ?
O12A N3 O10 Ag7 52.4(6) . . . . ?
O12B N3 O10 Ag7 -25.6(6) . . . . ?
O10 N3 O12A O12B -91.8(6) . . . . ?
O11 N3 O12A O12B 109.9(6) . . . . ?
O10 N3 O12B O12A 115.9(4) . . . . ?
O11 N3 O12B O12A -107.7(5) . . . . ?
Ag3 O2 P1 O7 143.56(16) . . . . ?
Ag7 O2 P1 O7 -74.04(19) 1_455 . . . ?
Ag5 O2 P1 O7 30.18(16) 3_556 . . . ?
Ag3 O2 P1 O3 14.8(2) . . . . ?
Ag7 O2 P1 O3 157.17(14) 1_455 . . . ?
Ag5 O2 P1 O3 -98.61(13) 3_556 . . . ?
Ag3 O2 P1 C11 -99.53(19) . . . . ?
Ag7 O2 P1 C11 42.87(19) 1_455 . . . ?
Ag5 O2 P1 C11 147.09(12) 3_556 . . . ?
Ag5 O7 P1 O2 -78.5(2) . . . . ?
Ag6 O7 P1 O2 52.80(18) . . . . ?
Ag5 O7 P1 O3 50.4(2) . . . . ?
Ag6 O7 P1 O3 -178.26(13) . . . . ?
Ag5 O7 P1 C11 165.38(17) . . . . ?
Ag6 O7 P1 C11 -63.28(18) . . . . ?
Ag3 O3 P1 O2 163.49(14) 1_655 . . . ?
Ag2 O3 P1 O2 28.51(19) . . . . ?
Ag4 O3 P1 O2 -83.74(16) . . . . ?
Ag3 O3 P1 O7 34.7(2) 1_655 . . . ?
Ag2 O3 P1 O7 -100.24(16) . . . . ?
Ag4 O3 P1 O7 147.51(13) . . . . ?
Ag3 O3 P1 C11 -81.64(18) 1_655 . . . ?
Ag2 O3 P1 C11 143.38(15) . . . . ?
Ag4 O3 P1 C11 31.13(17) . . . . ?
N4 C11 P1 O2 -150.3(3) . . . . ?
C12 C11 P1 O2 33.4(3) . . . . ?
N4 C11 P1 O7 -29.9(3) . . . . ?
C12 C11 P1 O7 153.8(3) . . . . ?
N4 C11 P1 O3 90.0(3) . . . . ?
C12 C11 P1 O3 -86.2(3) . . . . ?
Ag1 O5 P2 O4 121.74(15) 3_757 . . . ?
Ag2 O5 P2 O4 0.2(2) 3_657 . . . ?
Ag1 O5 P2 O6 -5.8(2) 3_757 . . 1_655 ?
Ag2 O5 P2 O6 -127.37(16) 3_657 . . 1_655 ?
Ag1 O5 P2 C1 -119.28(16) 3_757 . . . ?
Ag2 O5 P2 C1 119.17(18) 3_657 . . . ?
Ag1 O4 P2 O5 43.3(2) 3_657 . . . ?
Ag1 O4 P2 O5 -76.83(16) . . . . ?
Ag4 O4 P2 O5 139.48(13) . . . . ?
Ag1 O4 P2 O6 172.74(16) 3_657 . . 1_655 ?
Ag1 O4 P2 O6 52.58(16) . . . 1_655 ?
Ag4 O4 P2 O6 -91.11(15) . . . 1_655 ?
Ag1 O4 P2 C1 -74.1(2) 3_657 . . . ?
Ag1 O4 P2 C1 165.73(13) . . . . ?
Ag4 O4 P2 C1 22.03(17) . . . . ?
N1 C1 P2 O5 -142.0(3) . . . . ?
C5 C1 P2 O5 42.6(3) . . . . ?
N1 C1 P2 O4 -18.6(3) . . . . ?
C5 C1 P2 O4 165.9(3) . . . . ?
N1 C1 P2 O6 98.2(3) . . . 1_655 ?
C5 C1 P2 O6 -77.2(3) . . . 1_655 ?
Ag1 O1 P3 O8 -59.7(2) . . . 3_656 ?
Ag2 O1 P3 O8 130.3(2) . . . 3_656 ?
Ag1 O1 P3 O9 173.11(14) . . . . ?
Ag2 O1 P3 O9 3.1(3) . . . . ?
Ag1 O1 P3 C6 59.3(2) . . . . ?
Ag2 O1 P3 C6 -110.7(3) . . . . ?
Ag6 O9 P3 O1 -47.32(19) 3_556 . . . ?
Ag5 O9 P3 O1 74.21(18) . . . . ?
Ag7 O9 P3 O1 -164.27(14) 3_656 . . . ?
Ag6 O9 P3 O8 -175.53(13) 3_556 . . 3_656 ?
Ag5 O9 P3 O8 -54.00(18) . . . 3_656 ?
Ag7 O9 P3 O8 67.52(17) 3_656 . . 3_656 ?
Ag6 O9 P3 C6 67.48(17) 3_556 . . . ?
Ag5 O9 P3 C6 -170.99(15) . . . . ?
Ag7 O9 P3 C6 -49.47(18) 3_656 . . . ?
N2 C6 P3 O1 -152.1(3) . . . . ?
C10 C6 P3 O1 31.6(3) . . . . ?
N2 C6 P3 O8 -30.2(3) . . . 3_656 ?
C10 C6 P3 O8 153.5(3) . . . 3_656 ?
N2 C6 P3 O9 88.6(3) . . . . ?
C10 C6 P3 O9 -87.7(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C3 H3 O11 0.95 2.54 3.202(5) 126.6 4_566 yes
C7 H7 O11 0.95 2.38 3.321(6) 168.8 3_756 yes
C14 H14 O11 0.95 2.53 3.137(5) 121.8 4_566 yes
C15 H15 O12A 0.95 2.25 3.160(7) 160.9 . yes
C15 H15 O12B 0.95 2.31 2.924(11) 121.8 . yes

_refine_diff_density_max         0.958
_refine_diff_density_min         -0.887
_refine_diff_density_rms         0.163



