# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1819929'
_audit_update_record             
;
2018-01-28 deposited with the CCDC.
2018-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C138 H132 Dy10 N32 O54 P4'
_chemical_formula_sum            'C138 H132 Dy10 N32 O54 P4'
_chemical_formula_weight         4851.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.731(5)
_cell_length_b                   14.057(3)
_cell_length_c                   25.496(5)
_cell_angle_alpha                90
_cell_angle_beta                 112.797(4)
_cell_angle_gamma                90
_cell_volume                     8171(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9955
_cell_measurement_theta_min      2.300
_cell_measurement_theta_max      27.625

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.972
_exptl_crystal_F_000             4672
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    4.643
_shelx_estimated_absorpt_T_min   0.543
_shelx_estimated_absorpt_T_max   0.801
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.520
_exptl_absorpt_correction_T_max  0.800
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'BRUKER D8'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            45959
_diffrn_reflns_av_unetI/netI     0.0695
_diffrn_reflns_av_R_equivalents  0.0594
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         2.236
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measured_fraction_theta_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_point_group_measured_fraction_full 0.988
_reflns_number_total             15879
_reflns_number_gt                11779
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+554.8861P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15879
_refine_ls_number_parameters     1080
_refine_ls_number_restraints     767
_refine_ls_R_factor_all          0.1300
_refine_ls_R_factor_gt           0.0935
_refine_ls_wR_factor_ref         0.2675
_refine_ls_wR_factor_gt          0.2373
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.095 0.028 0.345 167 27 ' '
2 0.095 -0.028 0.655 166 27 ' '
3 0.579 0.090 0.144 9 1 ' '
4 0.905 0.472 0.845 167 27 ' '
5 0.094 0.528 0.155 166 27 ' '
6 0.579 0.410 0.644 9 1 ' '
7 0.421 0.590 0.356 9 1 ' '
8 0.421 0.910 0.856 9 1 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.83069(4) 0.75783(6) 0.57128(4) 0.0265(2) Uani 1 1 d . . . . .
Dy2 Dy 0.74732(4) 0.75993(6) 0.41080(4) 0.0256(2) Uani 1 1 d . . . . .
Dy3 Dy 0.67838(4) 0.49778(6) 0.34364(4) 0.0281(2) Uani 1 1 d . . . . .
Dy4 Dy 0.59959(4) 0.46030(6) 0.45412(4) 0.0271(2) Uani 1 1 d . . . . .
Dy5 Dy 0.75578(4) 0.53073(6) 0.58837(4) 0.0269(2) Uani 1 1 d . . . . .
P1 P 0.6799(2) 0.6829(3) 0.5002(2) 0.0245(9) Uani 1 1 d . U . . .
P2 P 0.7996(2) 0.5637(3) 0.4736(2) 0.0253(10) Uani 1 1 d . . . . .
C1 C 0.8571(8) 0.9662(12) 0.6553(8) 0.039(3) Uani 1 1 d D U . . .
H1 H 0.8752 0.9257 0.6871 0.046 Uiso 1 1 calc R U . . .
C2 C 0.8588(9) 1.0610(10) 0.6627(8) 0.040(4) Uani 1 1 d D U . . .
H2 H 0.8778 1.0848 0.7003 0.048 Uiso 1 1 calc R U . . .
N13 N 0.8355(7) 1.1247(11) 0.6204(6) 0.040(3) Uani 1 1 d D U . . .
C4 C 0.8075(9) 1.0863(11) 0.5685(8) 0.041(4) Uani 1 1 d D U . . .
H4 H 0.7884 1.1269 0.5369 0.049 Uiso 1 1 calc R U . . .
C5 C 0.8060(9) 0.9910(10) 0.5605(8) 0.037(3) Uani 1 1 d D U . . .
C6 C 0.7735(7) 0.9433(11) 0.5033(8) 0.025(4) Uani 1 1 d . . . . .
C7 C 0.7044(11) 0.9931(18) 0.3658(10) 0.052(6) Uani 1 1 d . . . . .
H7 H 0.7030 1.0606 0.3649 0.063 Uiso 1 1 calc R U . . .
C8 C 0.6767(10) 0.9387(13) 0.3162(9) 0.034(4) Uani 1 1 d . . . . .
H8 H 0.6532 0.9694 0.2817 0.041 Uiso 1 1 calc R U . . .
C9 C 0.6517(9) 0.7068(13) 0.2788(8) 0.028(4) Uani 1 1 d . . . . .
C10 C 0.6196(8) 0.6458(11) 0.2282(7) 0.034(3) Uani 1 1 d D U . . .
C11 C 0.5948(8) 0.6804(14) 0.1746(6) 0.036(3) Uani 1 1 d D U . . .
H11 H 0.5971 0.7467 0.1686 0.044 Uiso 1 1 calc R U . . .
N14 N 0.5670(8) 0.6239(10) 0.1293(7) 0.041(3) Uani 1 1 d D U . . .
C13 C 0.5653(9) 0.5305(11) 0.1407(7) 0.037(3) Uani 1 1 d D U . . .
H13 H 0.5455 0.4876 0.1106 0.045 Uiso 1 1 calc R U . . .
C14 C 0.5912(8) 0.4975(13) 0.1944(6) 0.035(3) Uani 1 1 d D U . . .
H14 H 0.5907 0.4307 0.2000 0.042 Uiso 1 1 calc R U . . .
C15 C 0.9849(6) 0.7867(15) 0.6393(8) 0.038(3) Uani 1 1 d D U . . .
H15 H 0.9794 0.8433 0.6174 0.045 Uiso 1 1 calc R U . . .
C16 C 1.0386(8) 0.7647(14) 0.6781(8) 0.046(4) Uani 1 1 d D U . . .
H16 H 1.0701 0.8059 0.6811 0.055 Uiso 1 1 calc R U . . .
N15 N 1.0509(7) 0.6886(12) 0.7130(7) 0.043(3) Uani 1 1 d D U . . .
C18 C 1.0042(6) 0.6312(16) 0.7038(8) 0.040(4) Uani 1 1 d D U . . .
H18 H 1.0094 0.5760 0.7268 0.048 Uiso 1 1 calc R U . . .
C19 C 0.9504(8) 0.6490(13) 0.6634(7) 0.037(5) Uani 1 1 d D . . . .
C20 C 0.8983(9) 0.5874(15) 0.6493(9) 0.038(5) Uani 1 1 d . . . . .
C21 C 0.8532(10) 0.3857(19) 0.6943(10) 0.051(6) Uani 1 1 d . . . . .
H21 H 0.8877 0.3637 0.7243 0.062 Uiso 1 1 calc R U . . .
C22 C 0.7984(10) 0.3347(18) 0.6778(10) 0.050(6) Uani 1 1 d . . . . .
H22 H 0.7960 0.2757 0.6949 0.060 Uiso 1 1 calc R U . . .
C23 C 0.6659(10) 0.3426(17) 0.5729(9) 0.041(5) Uani 1 1 d . . . . .
C24 C 0.6122(8) 0.2878(12) 0.5498(6) 0.032(3) Uani 1 1 d D U . . .
C25 C 0.5947(7) 0.2268(12) 0.5815(8) 0.034(3) Uani 1 1 d D U . . .
H25 H 0.6169 0.2245 0.6214 0.041 Uiso 1 1 calc R U . . .
N16 N 0.5473(6) 0.1689(11) 0.5594(6) 0.036(3) Uani 1 1 d D U . . .
C27 C 0.5162(8) 0.1785(12) 0.5027(6) 0.029(3) Uani 1 1 d D U . . .
H27 H 0.4833 0.1383 0.4846 0.035 Uiso 1 1 calc R U . . .
C28 C 0.5305(6) 0.2436(9) 0.4710(7) 0.021(3) Uani 1 1 d D U . . .
H28 H 0.5065 0.2493 0.4317 0.025 Uiso 1 1 calc R U . . .
C29 C 0.6241(8) 0.7522(13) 0.5122(9) 0.030(3) Uani 1 1 d . U . . .
H29A H 0.5854 0.7354 0.4826 0.035 Uiso 1 1 calc R U . . .
H29B H 0.6236 0.7343 0.5495 0.035 Uiso 1 1 calc R U . . .
C30 C 0.6322(7) 0.8586(12) 0.5112(5) 0.028(3) Uani 1 1 d D U . . .
C31 C 0.6632(8) 0.9071(13) 0.5618(6) 0.034(3) Uani 1 1 d D U . . .
C32 C 0.6892(7) 0.8614(13) 0.6142(5) 0.032(3) Uani 1 1 d D U . . .
H32 H 0.6860 0.7942 0.6153 0.038 Uiso 1 1 calc R U . . .
C33 C 0.7197(9) 0.9092(12) 0.6648(7) 0.039(3) Uani 1 1 d D U . . .
H33 H 0.7379 0.8761 0.6997 0.046 Uiso 1 1 calc R U . . .
C34 C 0.7222(10) 1.0080(12) 0.6618(8) 0.044(4) Uani 1 1 d D U . . .
H34 H 0.7405 1.0423 0.6963 0.053 Uiso 1 1 calc R U . . .
C35 C 0.6997(8) 1.0593(13) 0.6113(6) 0.037(3) Uani 1 1 d D U . . .
H35 H 0.7041 1.1264 0.6108 0.044 Uiso 1 1 calc R U . . .
C36 C 0.6702(8) 1.0085(13) 0.5613(6) 0.034(3) Uani 1 1 d D U . . .
C37 C 0.6468(7) 1.0579(13) 0.5100(6) 0.033(3) Uani 1 1 d D U . . .
H37 H 0.6510 1.1250 0.5095 0.039 Uiso 1 1 calc R U . . .
C38 C 0.6171(8) 1.0090(13) 0.4594(6) 0.039(3) Uani 1 1 d D U . . .
C39 C 0.5954(8) 1.0599(14) 0.4084(6) 0.037(3) Uani 1 1 d D U . . .
H39 H 0.5995 1.1271 0.4091 0.045 Uiso 1 1 calc R U . . .
C40 C 0.5678(9) 1.0137(12) 0.3565(8) 0.042(4) Uani 1 1 d D U . . .
H40 H 0.5563 1.0482 0.3218 0.051 Uiso 1 1 calc R U . . .
C41 C 0.5572(9) 0.9162(12) 0.3559(8) 0.042(4) Uani 1 1 d D U . . .
H41 H 0.5359 0.8855 0.3208 0.051 Uiso 1 1 calc R U . . .
C42 C 0.5774(8) 0.8630(14) 0.4060(6) 0.037(3) Uani 1 1 d D U . . .
H42 H 0.5698 0.7966 0.4041 0.045 Uiso 1 1 calc R U . . .
C43 C 0.6085(8) 0.9050(13) 0.4588(5) 0.033(3) Uani 1 1 d D U . . .
C44 C 0.8637(7) 0.5091(13) 0.4668(8) 0.025(3) Uani 1 1 d . U . . .
H44A H 0.8561 0.4401 0.4601 0.030 Uiso 1 1 calc R U . . .
H44B H 0.8680 0.5359 0.4327 0.030 Uiso 1 1 calc R U . . .
C45 C 0.9210(7) 0.5218(11) 0.5169(7) 0.029(3) Uani 1 1 d D U . . .
C46 C 0.9383(7) 0.4530(11) 0.5601(8) 0.034(3) Uani 1 1 d D U . . .
C47 C 0.9035(8) 0.3784(12) 0.5661(9) 0.040(3) Uani 1 1 d D U . . .
H47 H 0.8639 0.3736 0.5399 0.048 Uiso 1 1 calc R U . . .
C48 C 0.9255(7) 0.3110(15) 0.6095(7) 0.042(3) Uani 1 1 d D U . . .
H48 H 0.9021 0.2580 0.6106 0.050 Uiso 1 1 calc R U . . .
C49 C 0.9820(8) 0.3215(15) 0.6515(9) 0.049(4) Uani 1 1 d D U . . .
H49 H 0.9957 0.2783 0.6826 0.058 Uiso 1 1 calc R U . . .
C50 C 1.0185(9) 0.3951(13) 0.6479(8) 0.042(3) Uani 1 1 d D U . . .
H50 H 1.0571 0.4003 0.6761 0.051 Uiso 1 1 calc R U . . .
C51 C 0.9988(7) 0.4613(12) 0.6035(8) 0.034(3) Uani 1 1 d D U . . .
C52 C 1.0348(8) 0.5370(11) 0.6018(8) 0.037(3) Uani 1 1 d D U . . .
H52 H 1.0728 0.5430 0.6310 0.044 Uiso 1 1 calc R U . . .
C53 C 1.0158(8) 0.6041(11) 0.5578(8) 0.036(3) Uani 1 1 d D U . . .
C54 C 1.0529(9) 0.6801(12) 0.5587(9) 0.043(4) Uani 1 1 d D U . . .
H54 H 1.0890 0.6880 0.5903 0.051 Uiso 1 1 calc R U . . .
C55 C 1.0368(8) 0.7445(15) 0.5134(8) 0.046(4) Uani 1 1 d D U . . .
H55 H 1.0637 0.7913 0.5113 0.056 Uiso 1 1 calc R U . . .
C56 C 0.9802(7) 0.7382(13) 0.4711(9) 0.043(4) Uani 1 1 d D U . . .
H56 H 0.9669 0.7845 0.4417 0.051 Uiso 1 1 calc R U . . .
C57 C 0.9432(8) 0.6637(11) 0.4723(8) 0.035(3) Uani 1 1 d D U . . .
H57 H 0.9058 0.6588 0.4420 0.042 Uiso 1 1 calc R U . . .
C58 C 0.9586(7) 0.5957(11) 0.5159(8) 0.033(3) Uani 1 1 d D U . . .
C59 C 0.8762(9) 0.8746(13) 0.4798(9) 0.033(4) Uani 1 1 d . . . . .
C60 C 0.9145(10) 0.9561(18) 0.4741(11) 0.051(6) Uani 1 1 d . . . . .
H60A H 0.9187 0.9509 0.4376 0.076 Uiso 1 1 calc R U . . .
H60B H 0.9532 0.9526 0.5052 0.076 Uiso 1 1 calc R U . . .
H60C H 0.8960 1.0170 0.4759 0.076 Uiso 1 1 calc R U . . .
C61 C 0.8157(10) 0.6968(18) 0.6919(10) 0.046(5) Uani 1 1 d . . . . .
C62 C 0.8332(12) 0.7153(19) 0.7537(10) 0.058(7) Uani 1 1 d . . . . .
H62A H 0.8207 0.6621 0.7712 0.087 Uiso 1 1 calc R U . . .
H62B H 0.8146 0.7741 0.7590 0.087 Uiso 1 1 calc R U . . .
H62C H 0.8759 0.7221 0.7718 0.087 Uiso 1 1 calc R U . . .
C63 C 0.5601(8) 0.6023(11) 0.3660(8) 0.025(4) Uani 1 1 d . . . . .
C64 C 0.5321(9) 0.6635(17) 0.3150(9) 0.042(5) Uani 1 1 d . . . . .
H64A H 0.5037 0.7061 0.3212 0.063 Uiso 1 1 calc R U . . .
H64B H 0.5118 0.6235 0.2817 0.063 Uiso 1 1 calc R U . . .
H64C H 0.5622 0.7014 0.3086 0.063 Uiso 1 1 calc R U . . .
C65 C 0.7150(9) 0.3521(14) 0.4289(8) 0.034(4) Uani 1 1 d . . . . .
C66 C 0.7337(11) 0.2727(15) 0.4705(9) 0.042(5) Uani 1 1 d . . . . .
H66A H 0.7706 0.2460 0.4713 0.064 Uiso 1 1 calc R U . . .
H66B H 0.7034 0.2232 0.4591 0.064 Uiso 1 1 calc R U . . .
H66C H 0.7393 0.2964 0.5084 0.064 Uiso 1 1 calc R U . . .
C67 C 0.6256(15) 0.2805(17) 0.2968(11) 0.071(8) Uani 1 1 d D U . . .
C68 C 0.6537(17) 0.2220(19) 0.2647(12) 0.081(8) Uani 1 1 d D U . . .
H68A H 0.6619 0.1580 0.2811 0.121 Uiso 1 1 calc R U . . .
H68B H 0.6904 0.2522 0.2676 0.121 Uiso 1 1 calc R U . . .
H68C H 0.6270 0.2179 0.2247 0.121 Uiso 1 1 calc R U . . .
C69 C 0.7923(10) 0.4816(17) 0.3062(9) 0.044(5) Uani 1 1 d . . . . .
C70 C 0.8090(11) 0.3811(17) 0.3003(11) 0.051(6) Uani 1 1 d . . . . .
H70A H 0.8515 0.3772 0.3109 0.077 Uiso 1 1 calc R U . . .
H70B H 0.7887 0.3604 0.2607 0.077 Uiso 1 1 calc R U . . .
H70C H 0.7976 0.3399 0.3253 0.077 Uiso 1 1 calc R U . . .
C71 C 0.5228(8) 0.5207(12) 0.5273(8) 0.026(4) Uani 1 1 d . . . . .
C72 C 0.4983(11) 0.384(2) 0.3213(11) 0.078(7) Uani 1 1 d D U . . .
H72A H 0.4653 0.3988 0.3322 0.117 Uiso 1 1 calc R U . . .
H72B H 0.4882 0.3294 0.2954 0.117 Uiso 1 1 calc R U . . .
H72C H 0.5067 0.4393 0.3021 0.117 Uiso 1 1 calc R U . . .
C73 C 0.6703(12) 0.555(2) 0.6729(8) 0.062(6) Uani 1 1 d D U . . .
H73A H 0.6751 0.4892 0.6864 0.093 Uiso 1 1 calc R U . . .
H73B H 0.6318 0.5788 0.6697 0.093 Uiso 1 1 calc R U . . .
H73C H 0.7012 0.5947 0.7000 0.093 Uiso 1 1 calc R U . . .
N1 N 0.8299(7) 0.9280(11) 0.6031(6) 0.036(3) Uani 1 1 d D U . . .
N2 N 0.7572(8) 1.0010(12) 0.4602(7) 0.037(4) Uani 1 1 d . . . . .
N3 N 0.7308(8) 0.9490(10) 0.4111(7) 0.034(4) Uani 1 1 d . . . . .
N4 N 0.6830(7) 0.8468(12) 0.3171(7) 0.030(3) Uani 1 1 d . . . . .
N5 N 0.6524(7) 0.7998(11) 0.2675(7) 0.033(4) Uani 1 1 d . . . . .
N6 N 0.6178(7) 0.5528(9) 0.2407(7) 0.034(3) Uani 1 1 d D U . . .
N7 N 0.9389(7) 0.7287(10) 0.6314(7) 0.035(3) Uani 1 1 d D U . . .
N8 N 0.9052(8) 0.5133(13) 0.6861(8) 0.039(4) Uani 1 1 d . . . . .
N9 N 0.8530(7) 0.4612(11) 0.6670(7) 0.033(4) Uani 1 1 d . . . . .
N10 N 0.7534(7) 0.3715(12) 0.6394(7) 0.037(4) Uani 1 1 d . . . . .
N11 N 0.7027(8) 0.3169(12) 0.6241(8) 0.040(4) Uani 1 1 d . . . . .
N12 N 0.5784(5) 0.3010(10) 0.4939(5) 0.026(3) Uani 1 1 d D U . . .
O1 O 0.7669(6) 0.8513(9) 0.5003(6) 0.033(3) Uani 1 1 d . . . . .
O2 O 0.6781(5) 0.6676(10) 0.3283(5) 0.029(3) Uani 1 1 d . . . . .
O3 O 0.8511(5) 0.6052(9) 0.6055(5) 0.028(3) Uani 1 1 d . . . . .
O4 O 0.6761(6) 0.4071(9) 0.5416(5) 0.028(3) Uani 1 1 d . . . . .
O5 O 0.7392(5) 0.6913(9) 0.5528(5) 0.024(2) Uani 1 1 d . U . . .
O6 O 0.6807(5) 0.7119(9) 0.4433(5) 0.022(2) Uani 1 1 d . U . . .
O7 O 0.6649(5) 0.5774(8) 0.5008(5) 0.025(2) Uani 1 1 d . U . . .
O8 O 0.8145(5) 0.6692(9) 0.4912(5) 0.026(3) Uani 1 1 d . . . . .
O9 O 0.7512(5) 0.5735(9) 0.4146(6) 0.029(3) Uani 1 1 d . . . . .
O10 O 0.7791(6) 0.5039(8) 0.5130(5) 0.030(3) Uani 1 1 d . . . . .
O11 O 0.8326(6) 0.7596(9) 0.6630(6) 0.032(3) Uani 1 1 d . . . . .
O12 O 0.7844(6) 0.6231(11) 0.6701(6) 0.039(3) Uani 1 1 d . . . . .
O13 O 0.8873(7) 0.8455(10) 0.5319(6) 0.038(3) Uani 1 1 d . . . . .
O14 O 0.8376(5) 0.8427(9) 0.4356(6) 0.029(3) Uani 1 1 d . . . . .
O15 O 0.7384(8) 0.4950(14) 0.2987(6) 0.057(5) Uani 1 1 d . . . . .
O16 O 0.8274(8) 0.5490(14) 0.3165(8) 0.062(5) Uani 1 1 d . . . . .
O17 O 0.7420(6) 0.3626(9) 0.3970(6) 0.036(3) Uani 1 1 d . . . . .
O18 O 0.6730(6) 0.4050(9) 0.4243(6) 0.035(3) Uani 1 1 d . . . . .
O19 O 0.5998(6) 0.5437(10) 0.3666(6) 0.036(3) Uani 1 1 d . . . . .
O20 O 0.5434(5) 0.6026(9) 0.4068(6) 0.030(3) Uani 1 1 d . . . . .
O21 O 0.6269(9) 0.3703(11) 0.2962(8) 0.062(5) Uani 1 1 d . . . . .
O22 O 0.6055(13) 0.2380(15) 0.3289(9) 0.091(8) Uani 1 1 d . . . . .
O23 O 0.5516(7) 0.3608(13) 0.3736(7) 0.054(4) Uani 1 1 d D U . . .
H23A H 0.5667 0.3062 0.3745 0.065 Uiso 1 1 d R U . . .
O24 O 0.4949(6) 0.4462(9) 0.4364(5) 0.030(3) Uani 1 1 d . . . . .
O25 O 0.5741(5) 0.5135(10) 0.5319(6) 0.031(3) Uani 1 1 d . . . . .
O26 O 0.6743(6) 0.5594(10) 0.6162(6) 0.040(3) Uani 1 1 d D U . . .
H26A H 0.6425 0.5742 0.5888 0.048 Uiso 1 1 d R U . . .
O1W O 0.7995(6) 0.7095(10) 0.3536(6) 0.036(3) Uani 1 1 d . . . . .
H1WB H 0.8291 0.7452 0.3600 0.054 Uiso 1 1 d R U . . .
H1WA H 0.8109 0.6524 0.3621 0.054 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O8 2.291(12) . ?
Dy1 O1 2.297(14) . ?
Dy1 O3 2.297(12) . ?
Dy1 O5 2.321(12) . ?
Dy1 O11 2.322(14) . ?
Dy1 O13 2.361(13) . ?
Dy1 N1 2.529(15) . ?
Dy1 N7 2.550(16) . ?
Dy2 O6 2.217(11) . ?
Dy2 O14 2.375(12) . ?
Dy2 O1W 2.398(13) . ?
Dy2 O8 2.439(12) . ?
Dy2 O1 2.498(14) . ?
Dy2 O2 2.499(13) . ?
Dy2 N4 2.604(16) . ?
Dy2 O9 2.623(13) . ?
Dy2 N3 2.689(15) . ?
Dy3 O15 2.200(17) . ?
Dy3 O21 2.259(16) . ?
Dy3 O9 2.264(13) . ?
Dy3 O19 2.328(13) . ?
Dy3 O2 2.418(13) . ?
Dy3 O18 2.481(13) . ?
Dy3 O17 2.505(14) . ?
Dy3 N6 2.584(16) . ?
Dy4 O7 2.290(13) . ?
Dy4 O18 2.356(13) . ?
Dy4 O23 2.385(16) . ?
Dy4 O4 2.418(12) . ?
Dy4 O25 2.421(13) . ?
Dy4 O24 2.457(13) . ?
Dy4 O20 2.467(13) . ?
Dy4 O19 2.523(14) . ?
Dy4 N12 2.594(13) . ?
Dy5 O10 2.242(12) . ?
Dy5 O12 2.321(14) . ?
Dy5 O5 2.408(12) . ?
Dy5 O26 2.416(14) . ?
Dy5 O3 2.459(13) . ?
Dy5 O4 2.550(13) . ?
Dy5 O7 2.566(12) . ?
Dy5 N10 2.602(16) . ?
Dy5 N9 2.649(15) . ?
P1 O6 1.515(12) . ?
P1 O7 1.531(13) . ?
P1 O5 1.563(13) . ?
P1 C29 1.808(17) . ?
P2 O9 1.523(13) . ?
P2 O10 1.537(12) . ?
P2 O8 1.551(13) . ?
P2 C44 1.830(17) . ?
C1 C2 1.345(10) . ?
C1 N1 1.347(10) . ?
C1 H1 0.9500 . ?
C2 N13 1.346(10) . ?
C2 H2 0.9500 . ?
N13 C4 1.347(10) . ?
C4 C5 1.353(10) . ?
C4 H4 0.9500 . ?
C5 N1 1.349(10) . ?
C5 C6 1.52(3) . ?
C6 N2 1.30(2) . ?
C6 O1 1.30(2) . ?
C7 N3 1.25(3) . ?
C7 C8 1.41(3) . ?
C7 H7 0.9500 . ?
C8 N4 1.30(2) . ?
C8 H8 0.9500 . ?
C9 O2 1.30(2) . ?
C9 N5 1.34(2) . ?
C9 C10 1.50(3) . ?
C10 N6 1.351(10) . ?
C10 C11 1.353(10) . ?
C11 N14 1.349(10) . ?
C11 H11 0.9500 . ?
N14 C13 1.348(10) . ?
C13 C14 1.348(10) . ?
C13 H13 0.9500 . ?
C14 N6 1.354(10) . ?
C14 H14 0.9500 . ?
C15 N7 1.349(11) . ?
C15 C16 1.350(11) . ?
C15 H15 0.9500 . ?
C16 N15 1.349(11) . ?
C16 H16 0.9500 . ?
N15 C18 1.353(11) . ?
C18 C19 1.353(11) . ?
C18 H18 0.9500 . ?
C19 N7 1.350(11) . ?
C19 C20 1.48(3) . ?
C20 O3 1.29(2) . ?
C20 N8 1.37(3) . ?
C21 N9 1.27(3) . ?
C21 C22 1.44(3) . ?
C21 H21 0.9500 . ?
C22 N10 1.27(3) . ?
C22 H22 0.9500 . ?
C23 O4 1.29(2) . ?
C23 N11 1.32(3) . ?
C23 C24 1.45(3) . ?
C24 N12 1.357(10) . ?
C24 C25 1.361(10) . ?
C25 N16 1.357(10) . ?
C25 H25 0.9500 . ?
N16 C27 1.355(10) . ?
C27 C28 1.356(10) . ?
C27 H27 0.9500 . ?
C28 N12 1.364(10) . ?
C28 H28 0.9500 . ?
C29 C30 1.51(2) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C43 1.393(9) . ?
C30 C31 1.397(9) . ?
C31 C32 1.393(9) . ?
C31 C36 1.44(3) . ?
C32 C33 1.389(9) . ?
C32 H32 0.9500 . ?
C33 C34 1.393(9) . ?
C33 H33 0.9500 . ?
C34 C35 1.391(9) . ?
C34 H34 0.9500 . ?
C35 C36 1.395(9) . ?
C35 H35 0.9500 . ?
C36 C37 1.394(9) . ?
C37 C38 1.393(9) . ?
C37 H37 0.9500 . ?
C38 C39 1.396(9) . ?
C38 C43 1.48(3) . ?
C39 C40 1.392(9) . ?
C39 H39 0.9500 . ?
C40 C41 1.394(9) . ?
C40 H40 0.9500 . ?
C41 C42 1.394(9) . ?
C41 H41 0.9500 . ?
C42 C43 1.398(9) . ?
C42 H42 0.9500 . ?
C44 C45 1.51(2) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.401(9) . ?
C45 C58 1.402(9) . ?
C46 C47 1.401(9) . ?
C46 C51 1.48(3) . ?
C47 C48 1.398(9) . ?
C47 H47 0.9500 . ?
C48 C49 1.400(9) . ?
C48 H48 0.9500 . ?
C49 C50 1.398(9) . ?
C49 H49 0.9500 . ?
C50 C51 1.399(9) . ?
C50 H50 0.9500 . ?
C51 C52 1.400(9) . ?
C52 C53 1.401(9) . ?
C52 H52 0.9500 . ?
C53 C54 1.402(9) . ?
C53 C58 1.41(3) . ?
C54 C55 1.400(9) . ?
C54 H54 0.9500 . ?
C55 C56 1.400(9) . ?
C55 H55 0.9500 . ?
C56 C57 1.398(9) . ?
C56 H56 0.9500 . ?
C57 C58 1.402(9) . ?
C57 H57 0.9500 . ?
C59 O14 1.25(2) . ?
C59 O13 1.31(2) . ?
C59 C60 1.53(3) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 O12 1.28(3) . ?
C61 O11 1.32(3) . ?
C61 C62 1.49(3) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 O20 1.26(2) . ?
C63 O19 1.28(2) . ?
C63 C64 1.49(3) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 O17 1.24(2) . ?
C65 O18 1.25(2) . ?
C65 C66 1.48(3) . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 O22 1.26(3) . ?
C67 O21 1.26(3) . ?
C67 C68 1.506(10) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 O16 1.24(3) . ?
C69 O15 1.29(3) . ?
C69 C70 1.50(3) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 O25 1.23(2) . ?
C71 O24 1.26(2) 3_666 ?
C71 C71 1.53(4) 3_666 ?
C72 O23 1.505(10) . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 O26 1.489(10) . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
N2 N3 1.38(2) . ?
N4 N5 1.37(2) . ?
N8 N9 1.40(2) . ?
N10 N11 1.39(2) . ?
O23 H23A 0.8499 . ?
O24 C71 1.26(2) 3_666 ?
O26 H26A 0.8499 . ?
O1W H1WB 0.8501 . ?
O1W H1WA 0.8501 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Dy1 O1 77.3(5) . . ?
O8 Dy1 O3 76.5(5) . . ?
O1 Dy1 O3 144.7(5) . . ?
O8 Dy1 O5 77.3(4) . . ?
O1 Dy1 O5 75.7(4) . . ?
O3 Dy1 O5 75.8(4) . . ?
O8 Dy1 O11 146.3(4) . . ?
O1 Dy1 O11 121.8(5) . . ?
O3 Dy1 O11 73.3(5) . . ?
O5 Dy1 O11 81.1(4) . . ?
O8 Dy1 O13 80.4(5) . . ?
O1 Dy1 O13 72.9(5) . . ?
O3 Dy1 O13 124.7(5) . . ?
O5 Dy1 O13 144.7(5) . . ?
O11 Dy1 O13 129.7(5) . . ?
O8 Dy1 N1 141.3(4) . . ?
O1 Dy1 N1 67.9(5) . . ?
O3 Dy1 N1 142.2(5) . . ?
O5 Dy1 N1 108.5(5) . . ?
O11 Dy1 N1 70.5(5) . . ?
O13 Dy1 N1 73.9(5) . . ?
O8 Dy1 N7 103.2(5) . . ?
O1 Dy1 N7 143.7(4) . . ?
O3 Dy1 N7 66.2(4) . . ?
O5 Dy1 N7 140.4(4) . . ?
O11 Dy1 N7 77.9(5) . . ?
O13 Dy1 N7 71.5(5) . . ?
N1 Dy1 N7 95.5(5) . . ?
O6 Dy2 O14 143.9(5) . . ?
O6 Dy2 O1W 142.2(5) . . ?
O14 Dy2 O1W 68.6(5) . . ?
O6 Dy2 O8 83.7(4) . . ?
O14 Dy2 O8 76.7(4) . . ?
O1W Dy2 O8 90.3(4) . . ?
O6 Dy2 O1 74.0(4) . . ?
O14 Dy2 O1 71.0(4) . . ?
O1W Dy2 O1 138.4(5) . . ?
O8 Dy2 O1 70.9(4) . . ?
O6 Dy2 O2 77.9(4) . . ?
O14 Dy2 O2 138.1(4) . . ?
O1W Dy2 O2 71.9(4) . . ?
O8 Dy2 O2 117.2(4) . . ?
O1 Dy2 O2 149.7(4) . . ?
O6 Dy2 N4 101.9(5) . . ?
O14 Dy2 N4 101.0(5) . . ?
O1W Dy2 N4 82.1(5) . . ?
O8 Dy2 N4 172.3(5) . . ?
O1 Dy2 N4 115.5(5) . . ?
O2 Dy2 N4 59.8(5) . . ?
O6 Dy2 O9 72.7(4) . . ?
O14 Dy2 O9 117.6(4) . . ?
O1W Dy2 O9 73.0(4) . . ?
O8 Dy2 O9 56.1(4) . . ?
O1 Dy2 O9 119.3(4) . . ?
O2 Dy2 O9 61.0(4) . . ?
N4 Dy2 O9 120.2(5) . . ?
O6 Dy2 N3 99.5(5) . . ?
O14 Dy2 N3 69.1(5) . . ?
O1W Dy2 N3 114.3(5) . . ?
O8 Dy2 N3 124.7(5) . . ?
O1 Dy2 N3 57.7(5) . . ?
O2 Dy2 N3 117.4(5) . . ?
N4 Dy2 N3 60.0(5) . . ?
O9 Dy2 N3 172.2(5) . . ?
O15 Dy3 O21 93.5(8) . . ?
O15 Dy3 O9 86.3(6) . . ?
O21 Dy3 O9 155.5(5) . . ?
O15 Dy3 O19 159.0(6) . . ?
O21 Dy3 O19 90.2(7) . . ?
O9 Dy3 O19 98.7(5) . . ?
O15 Dy3 O2 83.9(6) . . ?
O21 Dy3 O2 137.0(5) . . ?
O9 Dy3 O2 67.4(4) . . ?
O19 Dy3 O2 79.4(4) . . ?
O15 Dy3 O18 133.3(5) . . ?
O21 Dy3 O18 80.0(6) . . ?
O9 Dy3 O18 82.3(5) . . ?
O19 Dy3 O18 67.7(4) . . ?
O2 Dy3 O18 130.9(4) . . ?
O15 Dy3 O17 82.0(5) . . ?
O21 Dy3 O17 78.1(6) . . ?
O9 Dy3 O17 77.6(5) . . ?
O19 Dy3 O17 118.9(4) . . ?
O2 Dy3 O17 142.9(4) . . ?
O18 Dy3 O17 51.3(4) . . ?
O15 Dy3 N6 73.7(6) . . ?
O21 Dy3 N6 73.1(5) . . ?
O9 Dy3 N6 129.8(4) . . ?
O19 Dy3 N6 87.7(5) . . ?
O2 Dy3 N6 65.0(4) . . ?
O18 Dy3 N6 143.4(5) . . ?
O17 Dy3 N6 140.7(4) . . ?
O7 Dy4 O18 85.9(5) . . ?
O7 Dy4 O23 152.1(5) . . ?
O18 Dy4 O23 73.6(6) . . ?
O7 Dy4 O4 66.5(4) . . ?
O18 Dy4 O4 76.7(5) . . ?
O23 Dy4 O4 124.2(5) . . ?
O7 Dy4 O25 73.0(4) . . ?
O18 Dy4 O25 147.6(5) . . ?
O23 Dy4 O25 133.3(5) . . ?
O4 Dy4 O25 72.5(4) . . ?
O7 Dy4 O24 129.4(4) . . ?
O18 Dy4 O24 143.4(5) . . ?
O23 Dy4 O24 69.9(5) . . ?
O4 Dy4 O24 122.5(4) . . ?
O25 Dy4 O24 65.5(4) . . ?
O7 Dy4 O20 79.7(4) . . ?
O18 Dy4 O20 117.9(4) . . ?
O23 Dy4 O20 93.3(5) . . ?
O4 Dy4 O20 142.5(4) . . ?
O25 Dy4 O20 82.8(4) . . ?
O24 Dy4 O20 67.8(4) . . ?
O7 Dy4 O19 83.3(5) . . ?
O18 Dy4 O19 66.5(4) . . ?
O23 Dy4 O19 71.5(5) . . ?
O4 Dy4 O19 133.7(4) . . ?
O25 Dy4 O19 132.2(4) . . ?
O24 Dy4 O19 103.7(4) . . ?
O20 Dy4 O19 52.0(4) . . ?
O7 Dy4 N12 128.8(4) . . ?
O18 Dy4 N12 98.0(4) . . ?
O23 Dy4 N12 73.8(5) . . ?
O4 Dy4 N12 65.0(4) . . ?
O25 Dy4 N12 77.9(4) . . ?
O24 Dy4 N12 69.2(4) . . ?
O20 Dy4 N12 136.9(4) . . ?
O19 Dy4 N12 144.8(4) . . ?
O10 Dy5 O12 140.6(5) . . ?
O10 Dy5 O5 84.1(4) . . ?
O12 Dy5 O5 76.2(5) . . ?
O10 Dy5 O26 143.2(5) . . ?
O12 Dy5 O26 69.0(5) . . ?
O5 Dy5 O26 85.1(4) . . ?
O10 Dy5 O3 71.1(5) . . ?
O12 Dy5 O3 70.4(5) . . ?
O5 Dy5 O3 71.3(4) . . ?
O26 Dy5 O3 136.8(5) . . ?
O10 Dy5 O4 83.9(5) . . ?
O12 Dy5 O4 135.5(5) . . ?
O5 Dy5 O4 118.4(4) . . ?
O26 Dy5 O4 70.7(4) . . ?
O3 Dy5 O4 152.4(4) . . ?
O10 Dy5 O7 74.1(4) . . ?
O12 Dy5 O7 119.9(4) . . ?
O5 Dy5 O7 57.9(4) . . ?
O26 Dy5 O7 70.3(4) . . ?
O3 Dy5 O7 120.1(4) . . ?
O4 Dy5 O7 60.6(4) . . ?
O10 Dy5 N10 110.3(5) . . ?
O12 Dy5 N10 95.2(6) . . ?
O5 Dy5 N10 164.0(5) . . ?
O26 Dy5 N10 79.2(5) . . ?
O3 Dy5 N10 118.9(5) . . ?
O4 Dy5 N10 58.9(5) . . ?
O7 Dy5 N10 118.2(5) . . ?
O10 Dy5 N9 97.3(5) . . ?
O12 Dy5 N9 69.9(5) . . ?
O5 Dy5 N9 127.1(5) . . ?
O26 Dy5 N9 117.1(5) . . ?
O3 Dy5 N9 59.7(4) . . ?
O4 Dy5 N9 114.4(4) . . ?
O7 Dy5 N9 170.1(5) . . ?
N10 Dy5 N9 59.6(5) . . ?
O6 P1 O7 111.2(7) . . ?
O6 P1 O5 116.4(7) . . ?
O7 P1 O5 102.5(7) . . ?
O6 P1 C29 108.1(8) . . ?
O7 P1 C29 108.5(8) . . ?
O5 P1 C29 109.8(8) . . ?
O9 P2 O10 111.3(8) . . ?
O9 P2 O8 101.9(7) . . ?
O10 P2 O8 115.8(7) . . ?
O9 P2 C44 108.8(8) . . ?
O10 P2 C44 110.5(8) . . ?
O8 P2 C44 108.1(8) . . ?
C2 C1 N1 120.6(18) . . ?
C2 C1 H1 119.7 . . ?
N1 C1 H1 119.7 . . ?
C1 C2 N13 124.5(18) . . ?
C1 C2 H2 117.8 . . ?
N13 C2 H2 117.8 . . ?
C2 N13 C4 114.8(17) . . ?
N13 C4 C5 121.2(18) . . ?
N13 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
N1 C5 C4 123.4(17) . . ?
N1 C5 C6 112.7(13) . . ?
C4 C5 C6 123.7(14) . . ?
N2 C6 O1 125.4(19) . . ?
N2 C6 C5 114.3(15) . . ?
O1 C6 C5 120.1(16) . . ?
N3 C7 C8 117(2) . . ?
N3 C7 H7 121.3 . . ?
C8 C7 H7 121.3 . . ?
N4 C8 C7 121(2) . . ?
N4 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
O2 C9 N5 125.4(18) . . ?
O2 C9 C10 119.6(15) . . ?
N5 C9 C10 114.9(15) . . ?
N6 C10 C11 123.0(17) . . ?
N6 C10 C9 113.9(13) . . ?
C11 C10 C9 123.1(14) . . ?
N14 C11 C10 122.2(17) . . ?
N14 C11 H11 118.9 . . ?
C10 C11 H11 118.9 . . ?
C13 N14 C11 115.9(17) . . ?
C14 C13 N14 120.8(17) . . ?
C14 C13 H13 119.6 . . ?
N14 C13 H13 119.6 . . ?
C13 C14 N6 124.6(17) . . ?
C13 C14 H14 117.7 . . ?
N6 C14 H14 117.7 . . ?
N7 C15 C16 120.2(18) . . ?
N7 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
N15 C16 C15 124.8(19) . . ?
N15 C16 H16 117.6 . . ?
C15 C16 H16 117.6 . . ?
C16 N15 C18 113.6(18) . . ?
N15 C18 C19 122.8(19) . . ?
N15 C18 H18 118.6 . . ?
C19 C18 H18 118.6 . . ?
N7 C19 C18 121.9(19) . . ?
N7 C19 C20 112.3(15) . . ?
C18 C19 C20 125.7(16) . . ?
O3 C20 N8 125(2) . . ?
O3 C20 C19 120.6(18) . . ?
N8 C20 C19 114.5(18) . . ?
N9 C21 C22 117(2) . . ?
N9 C21 H21 121.6 . . ?
C22 C21 H21 121.6 . . ?
N10 C22 C21 118(2) . . ?
N10 C22 H22 121.1 . . ?
C21 C22 H22 121.1 . . ?
O4 C23 N11 125(2) . . ?
O4 C23 C24 119.3(17) . . ?
N11 C23 C24 115.3(17) . . ?
N12 C24 C25 120.2(15) . . ?
N12 C24 C23 116.6(13) . . ?
C25 C24 C23 123.1(14) . . ?
N16 C25 C24 123.6(16) . . ?
N16 C25 H25 118.2 . . ?
C24 C25 H25 118.2 . . ?
C27 N16 C25 115.2(15) . . ?
N16 C27 C28 122.1(15) . . ?
N16 C27 H27 118.9 . . ?
C28 C27 H27 118.9 . . ?
C27 C28 N12 121.9(14) . . ?
C27 C28 H28 119.1 . . ?
N12 C28 H28 119.1 . . ?
C30 C29 P1 114.5(13) . . ?
C30 C29 H29A 108.6 . . ?
P1 C29 H29A 108.6 . . ?
C30 C29 H29B 108.6 . . ?
P1 C29 H29B 108.6 . . ?
H29A C29 H29B 107.6 . . ?
C43 C30 C31 122.2(16) . . ?
C43 C30 C29 118.0(15) . . ?
C31 C30 C29 119.7(15) . . ?
C32 C31 C30 123.1(16) . . ?
C32 C31 C36 116.9(14) . . ?
C30 C31 C36 120.0(14) . . ?
C33 C32 C31 123.4(17) . . ?
C33 C32 H32 118.3 . . ?
C31 C32 H32 118.3 . . ?
C32 C33 C34 116.8(18) . . ?
C32 C33 H33 121.6 . . ?
C34 C33 H33 121.6 . . ?
C35 C34 C33 123.9(18) . . ?
C35 C34 H34 118.1 . . ?
C33 C34 H34 118.1 . . ?
C34 C35 C36 117.4(17) . . ?
C34 C35 H35 121.3 . . ?
C36 C35 H35 121.3 . . ?
C37 C36 C35 118.9(16) . . ?
C37 C36 C31 119.7(14) . . ?
C35 C36 C31 121.5(14) . . ?
C38 C37 C36 120.2(16) . . ?
C38 C37 H37 119.9 . . ?
C36 C37 H37 119.9 . . ?
C37 C38 C39 119.0(17) . . ?
C37 C38 C43 121.2(14) . . ?
C39 C38 C43 119.8(15) . . ?
C40 C39 C38 121.0(17) . . ?
C40 C39 H39 119.5 . . ?
C38 C39 H39 119.5 . . ?
C39 C40 C41 119.3(18) . . ?
C39 C40 H40 120.3 . . ?
C41 C40 H40 120.3 . . ?
C42 C41 C40 121.3(18) . . ?
C42 C41 H41 119.4 . . ?
C40 C41 H41 119.4 . . ?
C41 C42 C43 121.6(17) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
C30 C43 C42 126.6(17) . . ?
C30 C43 C38 116.7(14) . . ?
C42 C43 C38 116.8(14) . . ?
C45 C44 P2 115.7(12) . . ?
C45 C44 H44A 108.4 . . ?
P2 C44 H44A 108.4 . . ?
C45 C44 H44B 108.4 . . ?
P2 C44 H44B 108.4 . . ?
H44A C44 H44B 107.4 . . ?
C46 C45 C58 121.5(16) . . ?
C46 C45 C44 119.0(15) . . ?
C58 C45 C44 119.0(14) . . ?
C47 C46 C45 126.0(16) . . ?
C47 C46 C51 117.5(14) . . ?
C45 C46 C51 116.5(14) . . ?
C48 C47 C46 121.8(17) . . ?
C48 C47 H47 119.1 . . ?
C46 C47 H47 119.1 . . ?
C47 C48 C49 120.0(19) . . ?
C47 C48 H48 120.0 . . ?
C49 C48 H48 120.0 . . ?
C50 C49 C48 120.4(19) . . ?
C50 C49 H49 119.8 . . ?
C48 C49 H49 119.8 . . ?
C49 C50 C51 120.9(18) . . ?
C49 C50 H50 119.5 . . ?
C51 C50 H50 119.5 . . ?
C50 C51 C52 120.4(17) . . ?
C50 C51 C46 119.1(15) . . ?
C52 C51 C46 120.5(14) . . ?
C51 C52 C53 121.2(16) . . ?
C51 C52 H52 119.4 . . ?
C53 C52 H52 119.4 . . ?
C52 C53 C54 119.0(17) . . ?
C52 C53 C58 118.5(14) . . ?
C54 C53 C58 122.4(15) . . ?
C55 C54 C53 120.3(18) . . ?
C55 C54 H54 119.9 . . ?
C53 C54 H54 119.9 . . ?
C54 C55 C56 118.2(19) . . ?
C54 C55 H55 120.9 . . ?
C56 C55 H55 120.9 . . ?
C57 C56 C55 119.9(18) . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C56 C57 C58 123.3(17) . . ?
C56 C57 H57 118.4 . . ?
C58 C57 H57 118.4 . . ?
C45 C58 C57 122.8(16) . . ?
C45 C58 C53 121.8(14) . . ?
C57 C58 C53 115.3(14) . . ?
O14 C59 O13 126.2(18) . . ?
O14 C59 C60 118.0(19) . . ?
O13 C59 C60 115.8(18) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
O12 C61 O11 125(2) . . ?
O12 C61 C62 119(2) . . ?
O11 C61 C62 117(2) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O20 C63 O19 119.3(16) . . ?
O20 C63 C64 121.9(17) . . ?
O19 C63 C64 118.7(17) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O17 C65 O18 120.3(18) . . ?
O17 C65 C66 117.3(19) . . ?
O18 C65 C66 122.3(18) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
O22 C67 O21 120(2) . . ?
O22 C67 C68 118(2) . . ?
O21 C67 C68 121(2) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O16 C69 O15 121(2) . . ?
O16 C69 C70 123(2) . . ?
O15 C69 C70 116(2) . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
O25 C71 O24 126.8(18) . 3_666 ?
O25 C71 C71 115(2) . 3_666 ?
O24 C71 C71 118(2) 3_666 3_666 ?
O23 C72 H72A 109.5 . . ?
O23 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
O23 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
O26 C73 H73A 109.5 . . ?
O26 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
O26 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C1 N1 C5 115.4(16) . . ?
C1 N1 Dy1 129.1(11) . . ?
C5 N1 Dy1 114.7(10) . . ?
C6 N2 N3 108.8(16) . . ?
C7 N3 N2 118.1(18) . . ?
C7 N3 Dy2 120.9(15) . . ?
N2 N3 Dy2 120.6(12) . . ?
C8 N4 N5 116.4(16) . . ?
C8 N4 Dy2 120.6(13) . . ?
N5 N4 Dy2 123.0(11) . . ?
C9 N5 N4 108.7(15) . . ?
C10 N6 C14 113.4(16) . . ?
C10 N6 Dy3 118.1(10) . . ?
C14 N6 Dy3 127.6(11) . . ?
C15 N7 C19 116.4(17) . . ?
C15 N7 Dy1 128.3(12) . . ?
C19 N7 Dy1 115.0(10) . . ?
C20 N8 N9 107.9(17) . . ?
C21 N9 N8 116.2(17) . . ?
C21 N9 Dy5 122.2(15) . . ?
N8 N9 Dy5 121.0(11) . . ?
C22 N10 N11 114.6(18) . . ?
C22 N10 Dy5 123.4(15) . . ?
N11 N10 Dy5 121.9(12) . . ?
C23 N11 N10 109.0(16) . . ?
C24 N12 C28 116.6(13) . . ?
C24 N12 Dy4 113.2(9) . . ?
C28 N12 Dy4 128.1(9) . . ?
C6 O1 Dy1 119.3(12) . . ?
C6 O1 Dy2 122.7(12) . . ?
Dy1 O1 Dy2 104.8(5) . . ?
C9 O2 Dy3 123.0(12) . . ?
C9 O2 Dy2 121.4(12) . . ?
Dy3 O2 Dy2 114.8(5) . . ?
C20 O3 Dy1 120.1(13) . . ?
C20 O3 Dy5 123.7(13) . . ?
Dy1 O3 Dy5 106.0(4) . . ?
C23 O4 Dy4 121.0(13) . . ?
C23 O4 Dy5 119.3(12) . . ?
Dy4 O4 Dy5 114.0(5) . . ?
P1 O5 Dy1 136.2(7) . . ?
P1 O5 Dy5 102.6(6) . . ?
Dy1 O5 Dy5 106.9(4) . . ?
P1 O6 Dy2 136.6(7) . . ?
P1 O7 Dy4 144.7(8) . . ?
P1 O7 Dy5 97.0(6) . . ?
Dy4 O7 Dy5 118.2(5) . . ?
P2 O8 Dy1 135.8(7) . . ?
P2 O8 Dy2 104.4(6) . . ?
Dy1 O8 Dy2 106.9(5) . . ?
P2 O9 Dy3 145.5(8) . . ?
P2 O9 Dy2 97.5(6) . . ?
Dy3 O9 Dy2 115.7(5) . . ?
P2 O10 Dy5 136.6(7) . . ?
C61 O11 Dy1 132.0(13) . . ?
C61 O12 Dy5 139.8(15) . . ?
C59 O13 Dy1 131.8(13) . . ?
C59 O14 Dy2 136.8(13) . . ?
C69 O15 Dy3 142.7(15) . . ?
C65 O17 Dy3 93.6(12) . . ?
C65 O18 Dy4 152.2(12) . . ?
C65 O18 Dy3 94.7(11) . . ?
Dy4 O18 Dy3 112.9(5) . . ?
C63 O19 Dy3 152.7(12) . . ?
C63 O19 Dy4 92.6(11) . . ?
Dy3 O19 Dy4 112.4(5) . . ?
C63 O20 Dy4 95.6(11) . . ?
C67 O21 Dy3 143(2) . . ?
C72 O23 Dy4 127.5(17) . . ?
C72 O23 H23A 116.4 . . ?
Dy4 O23 H23A 116.1 . . ?
C71 O24 Dy4 118.5(12) 3_666 . ?
C71 O25 Dy4 122.1(12) . . ?
C73 O26 Dy5 131.0(14) . . ?
C73 O26 H26A 114.8 . . ?
Dy5 O26 H26A 114.2 . . ?
Dy2 O1W H1WB 109.6 . . ?
Dy2 O1W H1WA 109.1 . . ?
H1WB O1W H1WA 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 N13 -1(3) . . . . ?
C1 C2 N13 C4 2(3) . . . . ?
C2 N13 C4 C5 -3(3) . . . . ?
N13 C4 C5 N1 3(3) . . . . ?
N13 C4 C5 C6 178.0(18) . . . . ?
N1 C5 C6 N2 -170.8(17) . . . . ?
C4 C5 C6 N2 13(3) . . . . ?
N1 C5 C6 O1 6(2) . . . . ?
C4 C5 C6 O1 -170.1(19) . . . . ?
N3 C7 C8 N4 -6(4) . . . . ?
O2 C9 C10 N6 5(3) . . . . ?
N5 C9 C10 N6 -178.1(17) . . . . ?
O2 C9 C10 C11 -174.8(18) . . . . ?
N5 C9 C10 C11 2(3) . . . . ?
N6 C10 C11 N14 -1(3) . . . . ?
C9 C10 C11 N14 178.7(18) . . . . ?
C10 C11 N14 C13 0(3) . . . . ?
C11 N14 C13 C14 -1(3) . . . . ?
N14 C13 C14 N6 4(3) . . . . ?
N7 C15 C16 N15 -3(3) . . . . ?
C15 C16 N15 C18 3(3) . . . . ?
C16 N15 C18 C19 0(3) . . . . ?
N15 C18 C19 N7 -4(3) . . . . ?
N15 C18 C19 C20 177.0(19) . . . . ?
N7 C19 C20 O3 9(2) . . . . ?
C18 C19 C20 O3 -171.5(18) . . . . ?
N7 C19 C20 N8 -170.6(16) . . . . ?
C18 C19 C20 N8 9(3) . . . . ?
N9 C21 C22 N10 -4(4) . . . . ?
O4 C23 C24 N12 7(3) . . . . ?
N11 C23 C24 N12 -168.9(18) . . . . ?
O4 C23 C24 C25 -172.1(19) . . . . ?
N11 C23 C24 C25 12(3) . . . . ?
N12 C24 C25 N16 7(3) . . . . ?
C23 C24 C25 N16 -174(2) . . . . ?
C24 C25 N16 C27 -3(3) . . . . ?
C25 N16 C27 C28 -2(3) . . . . ?
N16 C27 C28 N12 2(3) . . . . ?
O6 P1 C29 C30 -57.7(15) . . . . ?
O7 P1 C29 C30 -178.4(12) . . . . ?
O5 P1 C29 C30 70.3(15) . . . . ?
P1 C29 C30 C43 87.3(19) . . . . ?
P1 C29 C30 C31 -92.3(19) . . . . ?
C43 C30 C31 C32 -177.4(18) . . . . ?
C29 C30 C31 C32 2(3) . . . . ?
C43 C30 C31 C36 1(3) . . . . ?
C29 C30 C31 C36 -178.9(16) . . . . ?
C30 C31 C32 C33 -179.5(18) . . . . ?
C36 C31 C32 C33 2(3) . . . . ?
C31 C32 C33 C34 2(3) . . . . ?
C32 C33 C34 C35 -4(3) . . . . ?
C33 C34 C35 C36 3(3) . . . . ?
C34 C35 C36 C37 179.6(19) . . . . ?
C34 C35 C36 C31 0(3) . . . . ?
C32 C31 C36 C37 178.0(17) . . . . ?
C30 C31 C36 C37 -1(3) . . . . ?
C32 C31 C36 C35 -3(3) . . . . ?
C30 C31 C36 C35 178.4(18) . . . . ?
C35 C36 C37 C38 180.0(18) . . . . ?
C31 C36 C37 C38 -1(3) . . . . ?
C36 C37 C38 C39 -178.3(18) . . . . ?
C36 C37 C38 C43 2(3) . . . . ?
C37 C38 C39 C40 177.1(19) . . . . ?
C43 C38 C39 C40 -3(3) . . . . ?
C38 C39 C40 C41 6(3) . . . . ?
C39 C40 C41 C42 -5(3) . . . . ?
C40 C41 C42 C43 1(3) . . . . ?
C31 C30 C43 C42 179.4(19) . . . . ?
C29 C30 C43 C42 0(3) . . . . ?
C31 C30 C43 C38 -1(3) . . . . ?
C29 C30 C43 C38 179.9(16) . . . . ?
C41 C42 C43 C30 -177.8(19) . . . . ?
C41 C42 C43 C38 2(3) . . . . ?
C37 C38 C43 C30 -1(3) . . . . ?
C39 C38 C43 C30 178.9(18) . . . . ?
C37 C38 C43 C42 179.0(18) . . . . ?
C39 C38 C43 C42 -1(3) . . . . ?
O9 P2 C44 C45 161.4(12) . . . . ?
O10 P2 C44 C45 -76.2(14) . . . . ?
O8 P2 C44 C45 51.5(14) . . . . ?
P2 C44 C45 C46 91.2(19) . . . . ?
P2 C44 C45 C58 -96.3(18) . . . . ?
C58 C45 C46 C47 178(2) . . . . ?
C44 C45 C46 C47 -10(3) . . . . ?
C58 C45 C46 C51 -1(3) . . . . ?
C44 C45 C46 C51 170.8(16) . . . . ?
C45 C46 C47 C48 178(2) . . . . ?
C51 C46 C47 C48 -3(3) . . . . ?
C46 C47 C48 C49 6(3) . . . . ?
C47 C48 C49 C50 -5(3) . . . . ?
C48 C49 C50 C51 2(3) . . . . ?
C49 C50 C51 C52 177(2) . . . . ?
C49 C50 C51 C46 0(3) . . . . ?
C47 C46 C51 C50 0(3) . . . . ?
C45 C46 C51 C50 179.5(18) . . . . ?
C47 C46 C51 C52 -176.6(19) . . . . ?
C45 C46 C51 C52 3(3) . . . . ?
C50 C51 C52 C53 -179.8(19) . . . . ?
C46 C51 C52 C53 -3(3) . . . . ?
C51 C52 C53 C54 178.3(19) . . . . ?
C51 C52 C53 C58 2(3) . . . . ?
C52 C53 C54 C55 176(2) . . . . ?
C58 C53 C54 C55 -8(3) . . . . ?
C53 C54 C55 C56 8(3) . . . . ?
C54 C55 C56 C57 -6(3) . . . . ?
C55 C56 C57 C58 4(3) . . . . ?
C46 C45 C58 C57 177.8(19) . . . . ?
C44 C45 C58 C57 6(3) . . . . ?
C46 C45 C58 C53 1(3) . . . . ?
C44 C45 C58 C53 -171.7(17) . . . . ?
C56 C57 C58 C45 179(2) . . . . ?
C56 C57 C58 C53 -3(3) . . . . ?
C52 C53 C58 C45 -1(3) . . . . ?
C54 C53 C58 C45 -176.9(19) . . . . ?
C52 C53 C58 C57 -178.2(18) . . . . ?
C54 C53 C58 C57 6(3) . . . . ?
C2 C1 N1 C5 1(3) . . . . ?
C2 C1 N1 Dy1 170.0(15) . . . . ?
C4 C5 N1 C1 -1(3) . . . . ?
C6 C5 N1 C1 -177.3(16) . . . . ?
C4 C5 N1 Dy1 -172.3(17) . . . . ?
C6 C5 N1 Dy1 12(2) . . . . ?
O1 C6 N2 N3 1(3) . . . . ?
C5 C6 N2 N3 177.4(15) . . . . ?
C8 C7 N3 N2 -179(2) . . . . ?
C8 C7 N3 Dy2 9(3) . . . . ?
C6 N2 N3 C7 170(2) . . . . ?
C6 N2 N3 Dy2 -18(2) . . . . ?
C7 C8 N4 N5 177(2) . . . . ?
C7 C8 N4 Dy2 0(3) . . . . ?
O2 C9 N5 N4 -3(3) . . . . ?
C10 C9 N5 N4 180.0(15) . . . . ?
C8 N4 N5 C9 -164.8(18) . . . . ?
Dy2 N4 N5 C9 13(2) . . . . ?
C11 C10 N6 C14 3(3) . . . . ?
C9 C10 N6 C14 -177.0(16) . . . . ?
C11 C10 N6 Dy3 172.7(15) . . . . ?
C9 C10 N6 Dy3 -7(2) . . . . ?
C13 C14 N6 C10 -4(3) . . . . ?
C13 C14 N6 Dy3 -172.9(15) . . . . ?
C16 C15 N7 C19 -1(3) . . . . ?
C16 C15 N7 Dy1 171.9(15) . . . . ?
C18 C19 N7 C15 4(3) . . . . ?
C20 C19 N7 C15 -176.6(16) . . . . ?
C18 C19 N7 Dy1 -169.7(15) . . . . ?
C20 C19 N7 Dy1 10(2) . . . . ?
O3 C20 N8 N9 1(3) . . . . ?
C19 C20 N8 N9 -179.2(16) . . . . ?
C22 C21 N9 N8 176(2) . . . . ?
C22 C21 N9 Dy5 4(3) . . . . ?
C20 N8 N9 C21 175(2) . . . . ?
C20 N8 N9 Dy5 -13(2) . . . . ?
C21 C22 N10 N11 178(2) . . . . ?
C21 C22 N10 Dy5 1(3) . . . . ?
O4 C23 N11 N10 1(3) . . . . ?
C24 C23 N11 N10 176.6(18) . . . . ?
C22 N10 N11 C23 -158(2) . . . . ?
Dy5 N10 N11 C23 18(2) . . . . ?
C25 C24 N12 C28 -7(3) . . . . ?
C23 C24 N12 C28 174.5(17) . . . . ?
C25 C24 N12 Dy4 158.3(15) . . . . ?
C23 C24 N12 Dy4 -21(2) . . . . ?
C27 C28 N12 C24 2(2) . . . . ?
C27 C28 N12 Dy4 -160.2(12) . . . . ?
N2 C6 O1 Dy1 153.2(15) . . . . ?
C5 C6 O1 Dy1 -23(2) . . . . ?
N2 C6 O1 Dy2 18(2) . . . . ?
C5 C6 O1 Dy2 -158.1(12) . . . . ?
N5 C9 O2 Dy3 -176.7(14) . . . . ?
C10 C9 O2 Dy3 0(2) . . . . ?
N5 C9 O2 Dy2 -8(2) . . . . ?
C10 C9 O2 Dy2 168.7(12) . . . . ?
N8 C20 O3 Dy1 153.6(15) . . . . ?
C19 C20 O3 Dy1 -26(2) . . . . ?
N8 C20 O3 Dy5 13(2) . . . . ?
C19 C20 O3 Dy5 -166.6(12) . . . . ?
N11 C23 O4 Dy4 -171.8(17) . . . . ?
C24 C23 O4 Dy4 13(3) . . . . ?
N11 C23 O4 Dy5 -20(3) . . . . ?
C24 C23 O4 Dy5 164.7(14) . . . . ?
O6 P1 O5 Dy1 10.6(13) . . . . ?
O7 P1 O5 Dy1 132.1(9) . . . . ?
C29 P1 O5 Dy1 -112.7(11) . . . . ?
O6 P1 O5 Dy5 -121.1(7) . . . . ?
O7 P1 O5 Dy5 0.4(7) . . . . ?
C29 P1 O5 Dy5 115.6(8) . . . . ?
O7 P1 O6 Dy2 -113.3(11) . . . . ?
O5 P1 O6 Dy2 3.5(13) . . . . ?
C29 P1 O6 Dy2 127.7(11) . . . . ?
O6 P1 O7 Dy4 -52.0(13) . . . . ?
O5 P1 O7 Dy4 -177.0(11) . . . . ?
C29 P1 O7 Dy4 66.8(14) . . . . ?
O6 P1 O7 Dy5 124.7(6) . . . . ?
O5 P1 O7 Dy5 -0.4(6) . . . . ?
C29 P1 O7 Dy5 -116.5(8) . . . . ?
O9 P2 O8 Dy1 135.0(10) . . . . ?
O10 P2 O8 Dy1 14.1(13) . . . . ?
C44 P2 O8 Dy1 -110.4(11) . . . . ?
O9 P2 O8 Dy2 0.9(8) . . . . ?
O10 P2 O8 Dy2 -120.1(7) . . . . ?
C44 P2 O8 Dy2 115.4(7) . . . . ?
O10 P2 O9 Dy3 -41.4(15) . . . . ?
O8 P2 O9 Dy3 -165.5(12) . . . . ?
C44 P2 O9 Dy3 80.5(15) . . . . ?
O10 P2 O9 Dy2 123.3(6) . . . . ?
O8 P2 O9 Dy2 -0.8(7) . . . . ?
C44 P2 O9 Dy2 -114.8(7) . . . . ?
O9 P2 O10 Dy5 -108.5(12) . . . . ?
O8 P2 O10 Dy5 7.2(15) . . . . ?
C44 P2 O10 Dy5 130.6(11) . . . . ?
O12 C61 O11 Dy1 -12(3) . . . . ?
C62 C61 O11 Dy1 169.6(16) . . . . ?
O11 C61 O12 Dy5 17(4) . . . . ?
C62 C61 O12 Dy5 -164.3(17) . . . . ?
O14 C59 O13 Dy1 -19(3) . . . . ?
C60 C59 O13 Dy1 160.5(15) . . . . ?
O13 C59 O14 Dy2 23(3) . . . . ?
C60 C59 O14 Dy2 -156.1(15) . . . . ?
O16 C69 O15 Dy3 -92(3) . . . . ?
C70 C69 O15 Dy3 89(3) . . . . ?
O18 C65 O17 Dy3 -1(2) . . . . ?
C66 C65 O17 Dy3 177.0(17) . . . . ?
O17 C65 O18 Dy4 -174.7(19) . . . . ?
C66 C65 O18 Dy4 8(4) . . . . ?
O17 C65 O18 Dy3 1(2) . . . . ?
C66 C65 O18 Dy3 -176.9(19) . . . . ?
O20 C63 O19 Dy3 -150(2) . . . . ?
C64 C63 O19 Dy3 34(4) . . . . ?
O20 C63 O19 Dy4 6.9(16) . . . . ?
C64 C63 O19 Dy4 -168.9(15) . . . . ?
O19 C63 O20 Dy4 -7.0(17) . . . . ?
C64 C63 O20 Dy4 168.6(16) . . . . ?
O22 C67 O21 Dy3 80(5) . . . . ?
C68 C67 O21 Dy3 -93(4) . . . . ?
O24 C71 O25 Dy4 -174.6(13) 3_666 . . . ?
C71 C71 O25 Dy4 9(2) 3_666 . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O16 0.85 2.00 2.64(3) 131.3 .
O26 H26A O25 0.85 1.95 2.65(2) 139.9 .
O23 H23A O22 0.85 2.01 2.69(3) 135.8 .
C72 H72A O24 0.98 2.56 3.09(4) 114.5 .
C66 H66C O4 0.98 2.57 3.30(3) 131.2 .
C62 H62B O1W 0.98 2.59 3.15(3) 116.6 4_576
C29 H29A O20 0.99 2.60 3.39(2) 136.7 .
C28 H28 N14 0.95 2.58 3.23(2) 125.8 2_645
C15 H15 O13 0.95 2.47 2.98(2) 113.7 .
C14 H14 O21 0.95 2.42 2.99(2) 118.7 .
C13 H13 N16 0.95 2.57 3.41(2) 148.4 4_565
C2 H2 N15 0.95 2.67 3.57(3) 159.9 2_756

_refine_diff_density_max         3.096
_refine_diff_density_min         -3.023
_refine_diff_density_rms         0.329

_shelxl_version_number           2013-4



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I-UV
_database_code_depnum_ccdc_archive 'CCDC 1819930'
_audit_update_record             
;
2018-06-21 deposited with the CCDC.
2018-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C134 H124 Dy10 N32 O54 P4, 10(H2 O), 2(H2 O)'
_chemical_formula_sum            'C134 H148 Dy10 N32 O66 P4'
_chemical_formula_weight         5011.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.653(3)
_cell_length_b                   14.5645(19)
_cell_length_c                   26.067(3)
_cell_angle_alpha                90
_cell_angle_beta                 112.969(3)
_cell_angle_gamma                90
_cell_volume                     8617.4(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9852
_cell_measurement_theta_min      2.275
_cell_measurement_theta_max      27.381

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.931
_exptl_crystal_F_000             4848
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    4.410
_shelx_estimated_absorpt_T_min   0.351
_shelx_estimated_absorpt_T_max   0.719
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.320
_exptl_absorpt_correction_T_max  0.719
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            55815
_diffrn_reflns_av_unetI/netI     0.0866
_diffrn_reflns_av_R_equivalents  0.0821
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.019
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             16870
_reflns_number_gt                10326
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0457P)²+690.6492P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16870
_refine_ls_number_parameters     1159
_refine_ls_number_restraints     924
_refine_ls_R_factor_all          0.1733
_refine_ls_R_factor_gt           0.1021
_refine_ls_wR_factor_ref         0.2725
_refine_ls_wR_factor_gt          0.2161
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_restrained_S_all      0.986
_refine_ls_shift/su_max          0.025
_refine_ls_shift/su_mean         0.000

# start Validation Reply Form
_vrf_PLAT973_I-UV                
;
PROBLEM: Check Calcd Positive Resid. Density on Dy4 4.31 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT342_I-UV                
;
PROBLEM: Low Bond Precision on C-C Bonds ............... 0.03636 Ang.
RESPONSE: Moderate data quality in context with desolvation and there are 
disorder anthracene groups in the structure.
;
_vrf_PLAT430_I-UV                
;
PROBLEM: Short Inter D...A Contact O8W ..O17 2.77 Ang.
RESPONSE: O8W, O4W, O5W, O6W, O7W, O9W, O10W, O11W, O12W and O13W are disorder 
lattcie water molecules in the structure. The occupancies of all these water 
molecules are refined as 0.5. The hydrogen atoms can not be determined by 
Fourier Map and omitted.

;
_vrf_PLAT971_I-UV                
;
PROBLEM: Check Calcd Resid. Dens. 1.09A From Dy5 3.36 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT972_I-UV                
;
PROBLEM: Check Calcd Resid. Dens. 0.67A From Dy1 -2.53 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT975_I-UV                
;
PROBLEM: Check Calcd Resid. Dens. 1.05A From O1W 1.93 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
# end Validation Reply Form

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.16352(5) 0.72786(9) 0.41924(5) 0.0615(3) Uani 1 1 d . U . . .
Dy2 Dy 0.24630(5) 0.72285(8) 0.58257(5) 0.0502(3) Uani 1 1 d . U . . .
Dy3 Dy 0.31545(5) 0.46943(7) 0.64402(4) 0.0436(3) Uani 1 1 d . . . . .
Dy4 Dy 0.39927(4) 0.45145(6) 0.54130(3) 0.0368(2) Uani 1 1 d . . . . .
Dy5 Dy 0.24443(5) 0.51038(9) 0.40632(4) 0.0513(3) Uani 1 1 d . . . . .
P1 P 0.3158(2) 0.6624(4) 0.4927(2) 0.0443(12) Uani 1 1 d . U . . .
P2 P 0.1959(2) 0.5419(4) 0.5154(2) 0.0435(11) Uani 1 1 d . U . . .
C1 C 0.1415(12) 0.9332(18) 0.3431(13) 0.095(6) Uani 1 1 d D U . . .
H1 H 0.1217 0.8964 0.3111 0.115 Uiso 1 1 calc R U . . .
C2 C 0.1447(13) 1.0255(15) 0.3389(14) 0.101(6) Uani 1 1 d D U . . .
H2 H 0.1274 1.0512 0.3026 0.122 Uiso 1 1 calc R U . . .
C4 C 0.1947(13) 1.0443(18) 0.4324(13) 0.101(6) Uani 1 1 d D U . . .
H4 H 0.2136 1.0814 0.4644 0.121 Uiso 1 1 calc R U . . .
C5 C 0.1929(13) 0.9520(16) 0.4382(13) 0.096(6) Uani 1 1 d D U . . .
C6 C 0.2217(8) 0.9026(17) 0.4934(12) 0.060(7) Uani 1 1 d . . . . .
C7 C 0.2884(13) 0.9449(19) 0.6316(13) 0.085(5) Uani 1 1 d . U . . .
H7 H 0.2882 1.0100 0.6336 0.102 Uiso 1 1 calc R U . . .
C8 C 0.3153(12) 0.8884(18) 0.6807(13) 0.078(4) Uani 1 1 d . U . . .
H8 H 0.3380 0.9152 0.7157 0.094 Uiso 1 1 calc R U . . .
C9 C 0.3376(11) 0.6659(17) 0.7125(11) 0.063(4) Uani 1 1 d . U . . .
C10 C 0.3747(9) 0.6041(12) 0.7616(8) 0.053(6) Uani 1 1 d D . . . .
C11 C 0.4050(10) 0.6367(18) 0.8134(7) 0.073(8) Uani 1 1 d D . . . .
H11 H 0.4060 0.7009 0.8201 0.088 Uiso 1 1 calc R U . . .
C13 C 0.4350(9) 0.4905(15) 0.8421(8) 0.065(7) Uani 1 1 d D . . . .
H13 H 0.4580 0.4483 0.8698 0.078 Uiso 1 1 calc R U . . .
C14 C 0.4042(9) 0.4602(15) 0.7900(7) 0.076(9) Uani 1 1 d D . . . .
H14 H 0.4018 0.3958 0.7836 0.091 Uiso 1 1 calc R U . . .
C15 C 0.0087(8) 0.749(2) 0.3399(13) 0.105(12) Uani 1 1 d D . . . .
H15 H 0.0127 0.8065 0.3581 0.126 Uiso 1 1 calc R U . . .
C16 C -0.0443(10) 0.7226(19) 0.3029(11) 0.082(9) Uani 1 1 d D . . . .
H16 H -0.0770 0.7620 0.2969 0.098 Uiso 1 1 calc R U . . .
C18 C -0.0067(9) 0.589(2) 0.2861(11) 0.089(6) Uani 1 1 d D U . . .
H18 H -0.0105 0.5323 0.2673 0.107 Uiso 1 1 calc R U . . .
C19 C 0.0458(11) 0.6149(19) 0.3244(10) 0.083(6) Uani 1 1 d D U . . .
C20 C 0.1015(9) 0.5577(18) 0.3423(10) 0.057(6) Uani 1 1 d . . . . .
C21 C 0.1472(13) 0.355(2) 0.3102(12) 0.093(6) Uani 1 1 d . U . . .
H21 H 0.1124 0.3309 0.2824 0.112 Uiso 1 1 calc R U . . .
C22 C 0.2007(12) 0.306(2) 0.3303(11) 0.092(5) Uani 1 1 d . U . . .
H22 H 0.2023 0.2442 0.3188 0.110 Uiso 1 1 calc R U . . .
C23 C 0.3370(11) 0.3278(16) 0.4297(8) 0.057(6) Uani 1 1 d . . . . .
C24 C 0.3924(10) 0.2742(15) 0.4547(7) 0.056(6) Uani 1 1 d D . . . .
C25 C 0.4114(9) 0.2081(14) 0.4292(10) 0.061(6) Uani 1 1 d D . . . .
H25 H 0.3898 0.1988 0.3905 0.073 Uiso 1 1 calc R U . . .
C27 C 0.4902(11) 0.1721(14) 0.5094(8) 0.063(7) Uani 1 1 d D . . . .
H27 H 0.5236 0.1358 0.5301 0.075 Uiso 1 1 calc R U . . .
C28 C 0.4736(7) 0.2416(10) 0.5342(7) 0.037(4) Uani 1 1 d D . . . .
H28 H 0.4973 0.2545 0.5721 0.044 Uiso 1 1 calc R U . . .
C29 C 0.3733(10) 0.7295(16) 0.4810(10) 0.056(3) Uani 1 1 d . U . . .
H29A H 0.4121 0.7158 0.5108 0.067 Uiso 1 1 calc R U . . .
H29B H 0.3748 0.7114 0.4450 0.067 Uiso 1 1 calc R U . . .
C30 C 0.3608(10) 0.8330(17) 0.4804(8) 0.068(4) Uani 1 1 d D U . . .
C31 C 0.3327(10) 0.8751(14) 0.4286(9) 0.074(4) Uani 1 1 d D U . . .
C32 C 0.3084(10) 0.8273(18) 0.3784(8) 0.072(4) Uani 1 1 d D U . . .
H32 H 0.3121 0.7623 0.3805 0.087 Uiso 1 1 calc R U . . .
C33 C 0.2793(11) 0.8646(16) 0.3254(10) 0.083(5) Uani 1 1 d D U . . .
H33 H 0.2631 0.8276 0.2930 0.099 Uiso 1 1 calc R U . . .
C34 C 0.2756(12) 0.9602(16) 0.3235(12) 0.086(5) Uani 1 1 d D U . . .
H34 H 0.2570 0.9895 0.2883 0.103 Uiso 1 1 calc R U . . .
C35 C 0.2983(12) 1.014(2) 0.3713(10) 0.092(5) Uani 1 1 d D U . . .
H35 H 0.2962 1.0792 0.3691 0.110 Uiso 1 1 calc R U . . .
C36 C 0.3244(12) 0.9700(14) 0.4227(10) 0.085(4) Uani 1 1 d D U . . .
C37 C 0.3441(12) 1.023(2) 0.4712(9) 0.089(5) Uani 1 1 d D U . . .
H37 H 0.3364 1.0867 0.4689 0.106 Uiso 1 1 calc R U . . .
C38 C 0.3748(13) 0.9828(14) 0.5232(10) 0.092(5) Uani 1 1 d D U . . .
C39 C 0.3960(14) 1.031(2) 0.5733(11) 0.100(5) Uani 1 1 d D U . . .
H39 H 0.3949 1.0963 0.5705 0.120 Uiso 1 1 calc R U . . .
C40 C 0.4185(14) 0.9952(17) 0.6271(13) 0.102(6) Uani 1 1 d D U . . .
H40 H 0.4259 1.0316 0.6594 0.123 Uiso 1 1 calc R U . . .
C41 C 0.4291(14) 0.9010(17) 0.6292(13) 0.100(6) Uani 1 1 d D U . . .
H41 H 0.4482 0.8719 0.6643 0.120 Uiso 1 1 calc R U . . .
C42 C 0.4122(12) 0.849(2) 0.5806(10) 0.090(5) Uani 1 1 d D U . . .
H42 H 0.4215 0.7853 0.5832 0.109 Uiso 1 1 calc R U . . .
C43 C 0.3818(12) 0.8876(14) 0.5282(10) 0.081(4) Uani 1 1 d D U . . .
C44 C 0.1301(10) 0.4871(18) 0.5213(9) 0.058(4) Uani 1 1 d . U . . .
H44A H 0.1399 0.4224 0.5328 0.069 Uiso 1 1 calc R U . . .
H44B H 0.1221 0.5185 0.5513 0.069 Uiso 1 1 calc R U . . .
C45 C 0.0760(11) 0.4883(16) 0.4706(10) 0.074(4) Uani 1 1 d D U . . .
C46 C 0.0620(11) 0.4171(19) 0.4316(10) 0.093(5) Uani 1 1 d D U . . .
C47 C 0.1006(14) 0.344(2) 0.4359(13) 0.104(6) Uani 1 1 d D U . . .
H47 H 0.1369 0.3415 0.4673 0.125 Uiso 1 1 calc R U . . .
C48 C 0.0873(14) 0.276(2) 0.3953(12) 0.115(6) Uani 1 1 d D U . . .
H48 H 0.1152 0.2306 0.3958 0.137 Uiso 1 1 calc R U . . .
C49 C 0.0305(13) 0.278(3) 0.3540(14) 0.120(6) Uani 1 1 d D U . . .
H49 H 0.0196 0.2278 0.3288 0.145 Uiso 1 1 calc R U . . .
C50 C -0.0123(16) 0.346(2) 0.3452(14) 0.118(6) Uani 1 1 d D U . . .
H50 H -0.0494 0.3468 0.3147 0.142 Uiso 1 1 calc R U . . .
C51 C 0.0069(11) 0.412(2) 0.3873(11) 0.104(5) Uani 1 1 d D U . . .
C52 C -0.0334(14) 0.4824(19) 0.3820(13) 0.104(5) Uani 1 1 d D U . . .
H52 H -0.0708 0.4806 0.3519 0.125 Uiso 1 1 calc R U . . .
C53 C -0.0204(10) 0.555(2) 0.4196(11) 0.096(5) Uani 1 1 d D U . . .
C54 C -0.0633(13) 0.6230(19) 0.4103(13) 0.098(5) Uani 1 1 d D U . . .
H54 H -0.1000 0.6212 0.3794 0.118 Uiso 1 1 calc R U . . .
C55 C -0.0485(12) 0.693(2) 0.4496(11) 0.098(5) Uani 1 1 d D U . . .
H55 H -0.0765 0.7409 0.4442 0.118 Uiso 1 1 calc R U . . .
C56 C 0.0044(10) 0.699(2) 0.4963(12) 0.092(5) Uani 1 1 d D U . . .
H56 H 0.0117 0.7472 0.5230 0.111 Uiso 1 1 calc R U . . .
C57 C 0.0458(12) 0.6309(18) 0.5013(12) 0.086(5) Uani 1 1 d D U . . .
H57 H 0.0831 0.6341 0.5315 0.103 Uiso 1 1 calc R U . . .
C58 C 0.0348(9) 0.5579(18) 0.4638(10) 0.084(4) Uani 1 1 d D U . . .
C61 C 0.1858(15) 0.676(3) 0.3059(13) 0.099(5) Uani 1 1 d . U . . .
C62 C 0.1702(15) 0.693(3) 0.2437(12) 0.115(8) Uani 1 1 d . U . . .
H62A H 0.2055 0.6844 0.2356 0.172 Uiso 1 1 calc R U . . .
H62B H 0.1552 0.7551 0.2339 0.172 Uiso 1 1 calc R U . . .
H62C H 0.1400 0.6485 0.2218 0.172 Uiso 1 1 calc R U . . .
C63 C 0.4289(11) 0.5907(15) 0.6242(8) 0.050(5) Uani 1 1 d . . . . .
C64 C 0.4542(9) 0.6532(17) 0.6739(9) 0.053(6) Uani 1 1 d . . . . .
H64A H 0.4892 0.6840 0.6733 0.079 Uiso 1 1 calc R U . . .
H64B H 0.4650 0.6169 0.7082 0.079 Uiso 1 1 calc R U . . .
H64C H 0.4247 0.6992 0.6727 0.079 Uiso 1 1 calc R U . . .
C65 C 0.2786(8) 0.3352(15) 0.5550(8) 0.042(5) Uani 1 1 d . . . . .
C66 C 0.2662(13) 0.2542(17) 0.5165(11) 0.069(8) Uani 1 1 d . . . . .
H66A H 0.2487 0.2754 0.4778 0.104 Uiso 1 1 calc R U . . .
H66B H 0.2388 0.2125 0.5237 0.104 Uiso 1 1 calc R U . . .
H66C H 0.3031 0.2217 0.5228 0.104 Uiso 1 1 calc R U . . .
C67 C 0.4335(11) 0.3333(15) 0.6627(9) 0.053(3) Uani 1 1 d . U . . .
C68 C 0.4744(12) 0.2663(19) 0.6999(10) 0.069(6) Uani 1 1 d . U . . .
H68A H 0.4767 0.2124 0.6784 0.103 Uiso 1 1 calc R U . . .
H68B H 0.4602 0.2475 0.7286 0.103 Uiso 1 1 calc R U . . .
H68C H 0.5135 0.2941 0.7177 0.103 Uiso 1 1 calc R U . . .
C69 C 0.2439(13) 0.409(2) 0.7006(10) 0.072(8) Uani 1 1 d . . . . .
C70 C 0.2017(13) 0.366(2) 0.7224(11) 0.088(10) Uani 1 1 d . . . . .
H70A H 0.1627 0.3937 0.7042 0.132 Uiso 1 1 calc R U . . .
H70B H 0.2160 0.3752 0.7627 0.132 Uiso 1 1 calc R U . . .
H70C H 0.1989 0.2996 0.7145 0.132 Uiso 1 1 calc R U . . .
C71 C 0.5238(8) 0.4850(12) 0.5284(7) 0.035(4) Uani 1 1 d . . . . .
C77 C 0.1388(12) 0.8456(18) 0.5929(9) 0.112(4) Uani 1 1 d D U . . .
C78 C 0.0886(15) 0.912(3) 0.5701(12) 0.121(6) Uani 1 1 d D U . . .
H78A H 0.1015 0.9728 0.5860 0.181 Uiso 1 1 calc R U . . .
H78B H 0.0561 0.8912 0.5801 0.181 Uiso 1 1 calc R U . . .
H78C H 0.0752 0.9147 0.5295 0.181 Uiso 1 1 calc R U . . .
N1 N 0.1674(10) 0.8948(17) 0.3943(10) 0.094(6) Uani 1 1 d D U . . .
N2 N 0.2407(11) 0.9560(16) 0.5365(12) 0.089(6) Uani 1 1 d . U . . .
N3 N 0.2644(10) 0.9014(15) 0.5846(11) 0.086(5) Uani 1 1 d . U . . .
N4 N 0.3077(9) 0.8022(14) 0.6756(10) 0.073(4) Uani 1 1 d . U . . .
N5 N 0.3375(9) 0.7516(14) 0.7248(9) 0.069(4) Uani 1 1 d . U . . .
N6 N 0.3766(7) 0.5163(10) 0.7465(6) 0.046(4) Uani 1 1 d D . . . .
N7 N 0.0561(9) 0.6951(16) 0.3516(9) 0.082(6) Uani 1 1 d D U . . .
N8 N 0.0941(10) 0.484(2) 0.3115(9) 0.092(6) Uani 1 1 d . U . . .
N9 N 0.1478(10) 0.439(2) 0.3324(9) 0.089(5) Uani 1 1 d . U . . .
N10 N 0.2484(10) 0.3468(18) 0.3652(9) 0.081(5) Uani 1 1 d . U . . .
N11 N 0.2995(10) 0.2939(18) 0.3811(9) 0.079(5) Uani 1 1 d . U . . .
N12 N 0.4252(7) 0.2942(11) 0.5086(6) 0.054(5) Uani 1 1 d D . . . .
N13 N 0.1701(11) 1.0846(18) 0.3817(10) 0.104(6) Uani 1 1 d D U . . .
N14 N 0.4338(10) 0.5793(15) 0.8557(9) 0.074(6) Uani 1 1 d D . . . .
N15 N -0.0538(11) 0.6440(18) 0.2741(10) 0.096(6) Uani 1 1 d D U . . .
N16 N 0.4589(9) 0.1545(14) 0.4550(7) 0.073(6) Uani 1 1 d D . . . .
O1 O 0.2210(8) 0.8144(11) 0.4929(8) 0.067(5) Uani 1 1 d . . . . .
O2 O 0.3152(6) 0.6305(10) 0.6633(6) 0.048(4) Uani 1 1 d . . . . .
O3 O 0.1465(6) 0.5801(12) 0.3850(6) 0.058(4) Uani 1 1 d . . . . .
O4 O 0.3263(6) 0.3954(9) 0.4540(5) 0.043(3) Uani 1 1 d . . . . .
O5 O 0.2550(6) 0.6689(11) 0.4391(6) 0.051(4) Uani 1 1 d . . . . .
O6 O 0.3137(5) 0.6898(9) 0.5475(5) 0.036(3) Uani 1 1 d . . . . .
O7 O 0.3315(6) 0.5606(9) 0.4941(5) 0.044(3) Uani 1 1 d . . . . .
O8 O 0.1785(6) 0.6429(10) 0.4983(5) 0.045(2) Uani 1 1 d . U . . .
O9 O 0.2454(6) 0.5499(10) 0.5743(5) 0.045(2) Uani 1 1 d . U . . .
O10 O 0.2174(6) 0.4837(9) 0.4759(5) 0.042(2) Uani 1 1 d . U . . .
O11 O 0.1684(8) 0.7339(17) 0.3330(8) 0.091(5) Uani 1 1 d . U . . .
O12 O 0.2151(9) 0.6010(17) 0.3239(7) 0.093(5) Uani 1 1 d . U . . .
O14 O 0.1581(9) 0.7999(16) 0.5630(10) 0.102(4) Uani 1 1 d D U . . .
O15 O 0.2911(9) 0.3640(14) 0.7069(7) 0.073(5) Uani 1 1 d . . . . .
O16 O 0.2326(8) 0.4808(16) 0.6745(7) 0.076(6) Uani 1 1 d . . . . .
O17 O 0.2522(6) 0.3458(11) 0.5887(6) 0.051(4) Uani 1 1 d . . . . .
O18 O 0.3213(7) 0.3904(10) 0.5624(5) 0.049(4) Uani 1 1 d . . . . .
O19 O 0.3901(6) 0.5334(9) 0.6210(6) 0.046(3) Uani 1 1 d . . . . .
O20 O 0.4497(7) 0.5933(10) 0.5866(6) 0.048(4) Uani 1 1 d . . . . .
O21 O 0.3912(7) 0.3612(10) 0.6755(6) 0.054(3) Uani 1 1 d . U . . .
O22 O 0.4435(7) 0.3623(10) 0.6220(5) 0.049(3) Uani 1 1 d . U . . .
O24 O 0.5041(6) 0.4468(9) 0.5619(5) 0.042(3) Uani 1 1 d . . . . .
O25 O 0.5741(6) 0.4988(11) 0.5352(5) 0.046(3) Uani 1 1 d . . . . .
O26 O 0.1675(12) 0.834(2) 0.6441(11) 0.141(6) Uani 1 1 d D U . . .
O1W O 0.1944(8) 0.6573(15) 0.6364(8) 0.086(6) Uani 1 1 d . . . . .
H1WB H 0.1629 0.6875 0.6300 0.129 Uiso 1 1 d R U . . .
H1WA H 0.1859 0.6017 0.6267 0.129 Uiso 1 1 d R U . . .
O2W O 0.3242(7) 0.5346(13) 0.3800(6) 0.066(5) Uani 1 1 d . . . . .
H2WA H 0.3397 0.4831 0.3782 0.099 Uiso 1 1 d R U . . .
H2WB H 0.3118 0.5603 0.3482 0.099 Uiso 1 1 d R U . . .
O3W O 0.0992(7) 0.8050(14) 0.4519(9) 0.087(6) Uani 1 1 d . U . . .
H3WB H 0.0892 0.7696 0.4726 0.130 Uiso 1 1 d R U . . .
H3WA H 0.1173 0.8512 0.4706 0.130 Uiso 1 1 d R U . . .
O4W O 0.2451(14) 0.481(3) 0.2442(10) 0.067(10) Uani 0.5 1 d . . P A 1
O5W O 0.146(2) 0.377(2) 0.1821(19) 0.096(14) Uani 0.5 1 d . . P B 1
O6W O 0.0505(19) 0.471(4) 0.1843(15) 0.108(16) Uani 0.5 1 d . . P C 1
O7W O 0.322(2) 0.177(3) 0.6638(19) 0.099(13) Uani 0.5 1 d . U P D 1
O8W O 0.2003(14) 0.196(2) 0.6168(13) 0.056(8) Uani 0.5 1 d . U P E 1
O9W O 0.154(2) 0.099(4) 0.531(2) 0.118(16) Uani 0.5 1 d . U P F 1
O10W O 0.050(2) 0.986(4) 0.412(2) 0.126(18) Uani 0.5 1 d . U P G 1
O11W O 0.357(2) 0.101(4) 0.765(2) 0.123(17) Uani 0.5 1 d . U P H 1
O12W O 0.3410(15) 0.244(2) 0.7938(13) 0.067(9) Uani 0.5 1 d . U P I 1
O13W O 0.5575(14) 0.480(2) 0.6843(13) 0.064(8) Uani 0.5 1 d . U P J 1
O14W O 0.3660(12) 0.6446(18) 0.3244(11) 0.126(9) Uani 1 1 d . U . . .
H14A H 0.3568 0.6775 0.2953 0.189 Uiso 1 1 d R U . . .
H14B H 0.4032 0.6466 0.3426 0.189 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.272(19) . ?
Dy1 O5 2.276(15) . ?
Dy1 O11 2.298(19) . ?
Dy1 O3 2.304(17) . ?
Dy1 O8 2.307(14) . ?
Dy1 O3W 2.357(18) . ?
Dy1 N1 2.53(2) . ?
Dy1 N7 2.59(2) . ?
Dy2 O6 2.237(11) . ?
Dy2 O14 2.32(2) . ?
Dy2 O1W 2.432(19) . ?
Dy2 O8 2.471(13) . ?
Dy2 O2 2.516(14) . ?
Dy2 O9 2.527(14) . ?
Dy2 O1 2.548(18) . ?
Dy2 N4 2.58(2) . ?
Dy2 N3 2.64(2) . ?
Dy3 O9 2.282(14) . ?
Dy3 O21 2.335(15) . ?
Dy3 O19 2.339(14) . ?
Dy3 O2 2.400(14) . ?
Dy3 O17 2.449(14) . ?
Dy3 O16 2.468(18) . ?
Dy3 O18 2.472(13) . ?
Dy3 O15 2.485(16) . ?
Dy3 N6 2.594(16) . ?
Dy4 O7 2.287(15) . ?
Dy4 O22 2.347(13) . ?
Dy4 O18 2.370(14) . ?
Dy4 O4 2.426(12) . ?
Dy4 O24 2.426(14) . ?
Dy4 O25 2.441(13) 3_666 ?
Dy4 O20 2.462(14) . ?
Dy4 O19 2.483(13) . ?
Dy4 N12 2.610(16) . ?
Dy5 O10 2.197(12) . ?
Dy5 O2W 2.349(15) . ?
Dy5 O12 2.380(18) . ?
Dy5 O5 2.440(16) . ?
Dy5 O3 2.474(15) . ?
Dy5 O4 2.543(14) . ?
Dy5 O7 2.559(14) . ?
Dy5 N9 2.63(2) . ?
Dy5 N10 2.63(2) . ?
P1 O6 1.506(12) . ?
P1 O7 1.528(15) . ?
P1 O5 1.604(15) . ?
P1 C29 1.84(2) . ?
P2 O9 1.549(14) . ?
P2 O8 1.549(15) . ?
P2 O10 1.577(14) . ?
P2 C44 1.87(2) . ?
C1 C2 1.354(14) . ?
C1 N1 1.356(14) . ?
C1 H1 0.9500 . ?
C2 N13 1.353(14) . ?
C2 H2 0.9500 . ?
C4 N13 1.355(14) . ?
C4 C5 1.356(14) . ?
C4 H4 0.9500 . ?
C5 N1 1.355(14) . ?
C5 C6 1.51(4) . ?
C6 O1 1.29(3) . ?
C6 N2 1.29(3) . ?
C7 N3 1.30(3) . ?
C7 C8 1.45(4) . ?
C7 H7 0.9500 . ?
C8 N4 1.27(3) . ?
C8 H8 0.9500 . ?
C9 N5 1.29(3) . ?
C9 O2 1.29(2) . ?
C9 C10 1.54(3) . ?
C10 N6 1.344(11) . ?
C10 C11 1.350(11) . ?
C11 N14 1.343(11) . ?
C11 H11 0.9500 . ?
C13 N14 1.344(11) . ?
C13 C14 1.345(11) . ?
C13 H13 0.9500 . ?
C14 N6 1.348(11) . ?
C14 H14 0.9500 . ?
C15 N7 1.340(13) . ?
C15 C16 1.342(13) . ?
C15 H15 0.9500 . ?
C16 N15 1.340(13) . ?
C16 H16 0.9500 . ?
C18 N15 1.340(13) . ?
C18 C19 1.342(13) . ?
C18 H18 0.9500 . ?
C19 N7 1.340(13) . ?
C19 C20 1.52(3) . ?
C20 O3 1.27(3) . ?
C20 N8 1.31(3) . ?
C21 N9 1.34(4) . ?
C21 C22 1.41(4) . ?
C21 H21 0.9500 . ?
C22 N10 1.32(3) . ?
C22 H22 0.9500 . ?
C23 O4 1.25(2) . ?
C23 N11 1.34(3) . ?
C23 C24 1.49(3) . ?
C24 N12 1.350(11) . ?
C24 C25 1.353(11) . ?
C25 N16 1.348(11) . ?
C25 H25 0.9500 . ?
C27 C28 1.347(11) . ?
C27 N16 1.348(11) . ?
C27 H27 0.9500 . ?
C28 N12 1.353(11) . ?
C28 H28 0.9500 . ?
C29 C30 1.54(3) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C43 1.396(9) . ?
C30 C31 1.396(9) . ?
C31 C32 1.395(9) . ?
C31 C36 1.396(9) . ?
C32 C33 1.394(9) . ?
C32 H32 0.9500 . ?
C33 C34 1.394(9) . ?
C33 H33 0.9500 . ?
C34 C35 1.395(9) . ?
C34 H34 0.9500 . ?
C35 C36 1.396(9) . ?
C35 H35 0.9500 . ?
C36 C37 1.394(9) . ?
C37 C38 1.393(9) . ?
C37 H37 0.9500 . ?
C38 C39 1.395(9) . ?
C38 C43 1.397(9) . ?
C39 C40 1.393(9) . ?
C39 H39 0.9500 . ?
C40 C41 1.395(9) . ?
C40 H40 0.9500 . ?
C41 C42 1.393(9) . ?
C41 H41 0.9500 . ?
C42 C43 1.395(9) . ?
C42 H42 0.9500 . ?
C44 C45 1.47(3) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C58 1.397(9) . ?
C45 C46 1.398(9) . ?
C46 C47 1.398(9) . ?
C46 C51 1.400(9) . ?
C47 C48 1.396(9) . ?
C47 H47 0.9500 . ?
C48 C49 1.395(9) . ?
C48 H48 0.9500 . ?
C49 C50 1.395(9) . ?
C49 H49 0.9500 . ?
C50 C51 1.397(9) . ?
C50 H50 0.9500 . ?
C51 C52 1.396(9) . ?
C52 C53 1.395(9) . ?
C52 H52 0.9500 . ?
C53 C54 1.395(9) . ?
C53 C58 1.398(9) . ?
C54 C55 1.393(9) . ?
C54 H54 0.9500 . ?
C55 C56 1.395(9) . ?
C55 H55 0.9500 . ?
C56 C57 1.397(9) . ?
C56 H56 0.9500 . ?
C57 C58 1.397(9) . ?
C57 H57 0.9500 . ?
C61 O11 1.28(4) . ?
C61 O12 1.29(4) . ?
C61 C62 1.53(4) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 O19 1.25(3) . ?
C63 O20 1.27(2) . ?
C63 C64 1.51(3) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 O18 1.28(2) . ?
C65 O17 1.29(2) . ?
C65 C66 1.50(3) . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 O22 1.25(2) . ?
C67 O21 1.28(3) . ?
C67 C68 1.46(3) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 O16 1.22(4) . ?
C69 O15 1.29(3) . ?
C69 C70 1.50(4) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 O25 1.20(2) . ?
C71 O24 1.28(2) . ?
C71 C71 1.55(4) 3_666 ?
C77 O14 1.25(2) . ?
C77 O26 1.26(2) . ?
C77 C78 1.497(10) . ?
C78 H78A 0.9800 . ?
C78 H78B 0.9800 . ?
C78 H78C 0.9800 . ?
N2 N3 1.41(3) . ?
N4 N5 1.41(3) . ?
N8 N9 1.38(3) . ?
N10 N11 1.39(3) . ?
O25 Dy4 2.441(13) 3_666 ?
O1W H1WB 0.8510 . ?
O1W H1WA 0.8500 . ?
O2W H2WA 0.8502 . ?
O2W H2WB 0.8498 . ?
O3W H3WB 0.8499 . ?
O3W H3WA 0.8500 . ?
O14W H14A 0.8498 . ?
O14W H14B 0.8511 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O5 77.4(6) . . ?
O1 Dy1 O11 123.5(7) . . ?
O5 Dy1 O11 79.1(6) . . ?
O1 Dy1 O3 143.6(6) . . ?
O5 Dy1 O3 75.5(5) . . ?
O11 Dy1 O3 74.2(7) . . ?
O1 Dy1 O8 73.3(5) . . ?
O5 Dy1 O8 78.2(5) . . ?
O11 Dy1 O8 147.4(7) . . ?
O3 Dy1 O8 77.7(5) . . ?
O1 Dy1 O3W 73.5(7) . . ?
O5 Dy1 O3W 147.6(6) . . ?
O11 Dy1 O3W 129.4(7) . . ?
O3 Dy1 O3W 122.6(6) . . ?
O8 Dy1 O3W 80.2(6) . . ?
O1 Dy1 N1 67.0(7) . . ?
O5 Dy1 N1 106.7(6) . . ?
O11 Dy1 N1 72.0(9) . . ?
O3 Dy1 N1 144.9(7) . . ?
O8 Dy1 N1 137.4(7) . . ?
O3W Dy1 N1 74.5(7) . . ?
O1 Dy1 N7 144.4(7) . . ?
O5 Dy1 N7 138.1(6) . . ?
O11 Dy1 N7 76.8(7) . . ?
O3 Dy1 N7 65.2(6) . . ?
O8 Dy1 N7 105.9(6) . . ?
O3W Dy1 N7 71.3(7) . . ?
N1 Dy1 N7 97.7(7) . . ?
O6 Dy2 O14 142.7(7) . . ?
O6 Dy2 O1W 142.4(6) . . ?
O14 Dy2 O1W 70.0(8) . . ?
O6 Dy2 O8 83.6(4) . . ?
O14 Dy2 O8 77.4(7) . . ?
O1W Dy2 O8 90.2(6) . . ?
O6 Dy2 O2 81.9(5) . . ?
O14 Dy2 O2 135.3(7) . . ?
O1W Dy2 O2 69.1(6) . . ?
O8 Dy2 O2 119.5(5) . . ?
O6 Dy2 O9 74.6(4) . . ?
O14 Dy2 O9 119.1(7) . . ?
O1W Dy2 O9 70.7(6) . . ?
O8 Dy2 O9 58.3(5) . . ?
O2 Dy2 O9 61.3(4) . . ?
O6 Dy2 O1 72.1(5) . . ?
O14 Dy2 O1 70.9(7) . . ?
O1W Dy2 O1 137.7(6) . . ?
O8 Dy2 O1 66.0(5) . . ?
O2 Dy2 O1 152.9(5) . . ?
O9 Dy2 O1 116.9(5) . . ?
O6 Dy2 N4 102.9(6) . . ?
O14 Dy2 N4 98.4(7) . . ?
O1W Dy2 N4 83.2(7) . . ?
O8 Dy2 N4 173.1(6) . . ?
O2 Dy2 N4 59.7(6) . . ?
O9 Dy2 N4 120.6(6) . . ?
O1 Dy2 N4 118.2(7) . . ?
O6 Dy2 N3 94.2(7) . . ?
O14 Dy2 N3 70.4(8) . . ?
O1W Dy2 N3 119.9(8) . . ?
O8 Dy2 N3 122.2(6) . . ?
O2 Dy2 N3 117.2(6) . . ?
O9 Dy2 N3 168.8(7) . . ?
O1 Dy2 N3 58.7(7) . . ?
N4 Dy2 N3 60.4(8) . . ?
O9 Dy3 O21 151.6(5) . . ?
O9 Dy3 O19 91.0(5) . . ?
O21 Dy3 O19 75.9(5) . . ?
O9 Dy3 O2 66.5(5) . . ?
O21 Dy3 O2 130.8(5) . . ?
O19 Dy3 O2 74.4(5) . . ?
O9 Dy3 O17 78.4(5) . . ?
O21 Dy3 O17 87.0(5) . . ?
O19 Dy3 O17 121.7(4) . . ?
O2 Dy3 O17 142.1(5) . . ?
O9 Dy3 O16 76.0(5) . . ?
O21 Dy3 O16 125.5(6) . . ?
O19 Dy3 O16 152.6(6) . . ?
O2 Dy3 O16 78.3(6) . . ?
O17 Dy3 O16 79.8(6) . . ?
O9 Dy3 O18 80.4(5) . . ?
O21 Dy3 O18 71.4(5) . . ?
O19 Dy3 O18 69.5(5) . . ?
O2 Dy3 O18 129.9(5) . . ?
O17 Dy3 O18 52.3(4) . . ?
O16 Dy3 O18 129.9(5) . . ?
O9 Dy3 O15 122.7(6) . . ?
O21 Dy3 O15 73.6(6) . . ?
O19 Dy3 O15 146.3(6) . . ?
O2 Dy3 O15 116.5(6) . . ?
O17 Dy3 O15 70.8(5) . . ?
O16 Dy3 O15 52.1(7) . . ?
O18 Dy3 O15 112.9(6) . . ?
O9 Dy3 N6 129.8(5) . . ?
O21 Dy3 N6 75.7(5) . . ?
O19 Dy3 N6 87.7(5) . . ?
O2 Dy3 N6 64.9(4) . . ?
O17 Dy3 N6 141.3(5) . . ?
O16 Dy3 N6 82.7(5) . . ?
O18 Dy3 N6 143.4(5) . . ?
O15 Dy3 N6 71.1(5) . . ?
O7 Dy4 O22 148.6(4) . . ?
O7 Dy4 O18 84.1(5) . . ?
O22 Dy4 O18 73.7(5) . . ?
O7 Dy4 O4 67.1(5) . . ?
O22 Dy4 O4 124.8(5) . . ?
O18 Dy4 O4 73.8(5) . . ?
O7 Dy4 O24 129.0(4) . . ?
O22 Dy4 O24 72.8(5) . . ?
O18 Dy4 O24 146.0(5) . . ?
O4 Dy4 O24 122.2(4) . . ?
O7 Dy4 O25 74.1(5) . 3_666 ?
O22 Dy4 O25 135.9(5) . 3_666 ?
O18 Dy4 O25 143.3(5) . 3_666 ?
O4 Dy4 O25 70.7(4) . 3_666 ?
O24 Dy4 O25 65.6(4) . 3_666 ?
O7 Dy4 O20 78.5(5) . . ?
O22 Dy4 O20 93.6(5) . . ?
O18 Dy4 O20 120.5(5) . . ?
O4 Dy4 O20 141.5(5) . . ?
O24 Dy4 O20 67.8(5) . . ?
O25 Dy4 O20 84.0(5) 3_666 . ?
O7 Dy4 O19 80.2(5) . . ?
O22 Dy4 O19 71.2(5) . . ?
O18 Dy4 O19 68.8(5) . . ?
O4 Dy4 O19 132.1(5) . . ?
O24 Dy4 O19 105.4(5) . . ?
O25 Dy4 O19 133.1(5) 3_666 . ?
O20 Dy4 O19 52.4(4) . . ?
O7 Dy4 N12 130.9(4) . . ?
O22 Dy4 N12 73.8(5) . . ?
O18 Dy4 N12 94.1(5) . . ?
O4 Dy4 N12 65.5(5) . . ?
O24 Dy4 N12 70.8(5) . . ?
O25 Dy4 N12 79.3(5) 3_666 . ?
O20 Dy4 N12 138.7(5) . . ?
O19 Dy4 N12 144.1(5) . . ?
O10 Dy5 O2W 145.7(5) . . ?
O10 Dy5 O12 139.5(6) . . ?
O2W Dy5 O12 69.4(6) . . ?
O10 Dy5 O5 84.5(5) . . ?
O2W Dy5 O5 88.5(6) . . ?
O12 Dy5 O5 75.2(7) . . ?
O10 Dy5 O3 71.0(5) . . ?
O2W Dy5 O3 136.7(6) . . ?
O12 Dy5 O3 69.2(6) . . ?
O5 Dy5 O3 69.6(5) . . ?
O10 Dy5 O4 85.3(5) . . ?
O2W Dy5 O4 69.2(5) . . ?
O12 Dy5 O4 135.2(6) . . ?
O5 Dy5 O4 119.7(4) . . ?
O3 Dy5 O4 154.0(5) . . ?
O10 Dy5 O7 74.4(4) . . ?
O2W Dy5 O7 73.3(5) . . ?
O12 Dy5 O7 120.1(7) . . ?
O5 Dy5 O7 58.6(5) . . ?
O3 Dy5 O7 119.2(5) . . ?
O4 Dy5 O7 61.5(4) . . ?
O10 Dy5 N9 93.2(7) . . ?
O2W Dy5 N9 118.0(7) . . ?
O12 Dy5 N9 71.9(9) . . ?
O5 Dy5 N9 125.1(7) . . ?
O3 Dy5 N9 58.1(7) . . ?
O4 Dy5 N9 114.7(7) . . ?
O7 Dy5 N9 167.0(7) . . ?
O10 Dy5 N10 104.3(7) . . ?
O2W Dy5 N10 81.3(7) . . ?
O12 Dy5 N10 100.4(8) . . ?
O5 Dy5 N10 169.7(6) . . ?
O3 Dy5 N10 118.0(6) . . ?
O4 Dy5 N10 56.9(5) . . ?
O7 Dy5 N10 118.1(6) . . ?
N9 Dy5 N10 60.6(7) . . ?
O6 P1 O7 109.7(8) . . ?
O6 P1 O5 116.4(8) . . ?
O7 P1 O5 102.8(8) . . ?
O6 P1 C29 109.3(10) . . ?
O7 P1 C29 108.3(9) . . ?
O5 P1 C29 110.0(9) . . ?
O9 P2 O8 103.6(8) . . ?
O9 P2 O10 110.6(8) . . ?
O8 P2 O10 116.6(8) . . ?
O9 P2 C44 108.9(9) . . ?
O8 P2 C44 106.2(10) . . ?
O10 P2 C44 110.4(10) . . ?
C2 C1 N1 118(3) . . ?
C2 C1 H1 121.0 . . ?
N1 C1 H1 121.0 . . ?
N13 C2 C1 126(3) . . ?
N13 C2 H2 117.0 . . ?
C1 C2 H2 117.0 . . ?
N13 C4 C5 121(3) . . ?
N13 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
N1 C5 C4 123(3) . . ?
N1 C5 C6 114(2) . . ?
C4 C5 C6 124(2) . . ?
O1 C6 N2 128(3) . . ?
O1 C6 C5 118(2) . . ?
N2 C6 C5 115(2) . . ?
N3 C7 C8 116(3) . . ?
N3 C7 H7 122.0 . . ?
C8 C7 H7 122.0 . . ?
N4 C8 C7 118(3) . . ?
N4 C8 H8 120.9 . . ?
C7 C8 H8 120.9 . . ?
N5 C9 O2 126(3) . . ?
N5 C9 C10 115(2) . . ?
O2 C9 C10 118.6(18) . . ?
N6 C10 C11 124(2) . . ?
N6 C10 C9 113.0(15) . . ?
C11 C10 C9 122.9(17) . . ?
N14 C11 C10 121(2) . . ?
N14 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
N14 C13 C14 121(2) . . ?
N14 C13 H13 119.3 . . ?
C14 C13 H13 119.3 . . ?
C13 C14 N6 123.4(19) . . ?
C13 C14 H14 118.3 . . ?
N6 C14 H14 118.3 . . ?
N7 C15 C16 121(3) . . ?
N7 C15 H15 119.5 . . ?
C16 C15 H15 119.5 . . ?
N15 C16 C15 124(3) . . ?
N15 C16 H16 118.2 . . ?
C15 C16 H16 118.2 . . ?
N15 C18 C19 120(3) . . ?
N15 C18 H18 119.8 . . ?
C19 C18 H18 119.8 . . ?
N7 C19 C18 124(3) . . ?
N7 C19 C20 110.8(19) . . ?
C18 C19 C20 125(2) . . ?
O3 C20 N8 128(2) . . ?
O3 C20 C19 120(2) . . ?
N8 C20 C19 112(2) . . ?
N9 C21 C22 117(3) . . ?
N9 C21 H21 121.6 . . ?
C22 C21 H21 121.6 . . ?
N10 C22 C21 118(3) . . ?
N10 C22 H22 120.8 . . ?
C21 C22 H22 120.8 . . ?
O4 C23 N11 124(2) . . ?
O4 C23 C24 122.0(18) . . ?
N11 C23 C24 113.5(19) . . ?
N12 C24 C25 118.8(19) . . ?
N12 C24 C23 114.7(15) . . ?
C25 C24 C23 126.4(16) . . ?
N16 C25 C24 125(2) . . ?
N16 C25 H25 117.7 . . ?
C24 C25 H25 117.7 . . ?
C28 C27 N16 119(2) . . ?
C28 C27 H27 120.3 . . ?
N16 C27 H27 120.3 . . ?
C27 C28 N12 124.2(18) . . ?
C27 C28 H28 117.9 . . ?
N12 C28 H28 117.9 . . ?
C30 C29 P1 111.0(15) . . ?
C30 C29 H29A 109.4 . . ?
P1 C29 H29A 109.4 . . ?
C30 C29 H29B 109.4 . . ?
P1 C29 H29B 109.4 . . ?
H29A C29 H29B 108.0 . . ?
C43 C30 C31 119(2) . . ?
C43 C30 C29 123.2(19) . . ?
C31 C30 C29 118(2) . . ?
C32 C31 C36 114(2) . . ?
C32 C31 C30 123.9(19) . . ?
C36 C31 C30 122(2) . . ?
C33 C32 C31 127(2) . . ?
C33 C32 H32 116.5 . . ?
C31 C32 H32 116.5 . . ?
C32 C33 C34 115(3) . . ?
C32 C33 H33 122.4 . . ?
C34 C33 H33 122.4 . . ?
C33 C34 C35 122(3) . . ?
C33 C34 H34 118.9 . . ?
C35 C34 H34 118.9 . . ?
C34 C35 C36 118(3) . . ?
C34 C35 H35 120.9 . . ?
C36 C35 H35 120.9 . . ?
C37 C36 C35 119(2) . . ?
C37 C36 C31 117(2) . . ?
C35 C36 C31 124(2) . . ?
C38 C37 C36 121(3) . . ?
C38 C37 H37 119.4 . . ?
C36 C37 H37 119.4 . . ?
C37 C38 C39 124(2) . . ?
C37 C38 C43 120(2) . . ?
C39 C38 C43 115(2) . . ?
C40 C39 C38 128(3) . . ?
C40 C39 H39 116.2 . . ?
C38 C39 H39 116.2 . . ?
C39 C40 C41 114(3) . . ?
C39 C40 H40 123.1 . . ?
C41 C40 H40 123.1 . . ?
C42 C41 C40 121(3) . . ?
C42 C41 H41 119.5 . . ?
C40 C41 H41 119.5 . . ?
C41 C42 C43 122(3) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
C42 C43 C30 121(2) . . ?
C42 C43 C38 120(2) . . ?
C30 C43 C38 119(2) . . ?
C45 C44 P2 115.8(16) . . ?
C45 C44 H44A 108.3 . . ?
P2 C44 H44A 108.3 . . ?
C45 C44 H44B 108.3 . . ?
P2 C44 H44B 108.3 . . ?
H44A C44 H44B 107.4 . . ?
C58 C45 C46 119(2) . . ?
C58 C45 C44 119(2) . . ?
C46 C45 C44 122(2) . . ?
C45 C46 C47 122(2) . . ?
C45 C46 C51 122(2) . . ?
C47 C46 C51 116(2) . . ?
C48 C47 C46 122(3) . . ?
C48 C47 H47 119.0 . . ?
C46 C47 H47 119.0 . . ?
C49 C48 C47 116(3) . . ?
C49 C48 H48 122.1 . . ?
C47 C48 H48 122.1 . . ?
C48 C49 C50 128(4) . . ?
C48 C49 H49 116.2 . . ?
C50 C49 H49 116.2 . . ?
C49 C50 C51 111(3) . . ?
C49 C50 H50 124.5 . . ?
C51 C50 H50 124.5 . . ?
C52 C51 C50 115(2) . . ?
C52 C51 C46 118(3) . . ?
C50 C51 C46 127(3) . . ?
C53 C52 C51 122(3) . . ?
C53 C52 H52 119.0 . . ?
C51 C52 H52 119.0 . . ?
C54 C53 C52 118(2) . . ?
C54 C53 C58 124(3) . . ?
C52 C53 C58 119(3) . . ?
C55 C54 C53 115(3) . . ?
C55 C54 H54 122.3 . . ?
C53 C54 H54 122.3 . . ?
C54 C55 C56 125(3) . . ?
C54 C55 H55 117.4 . . ?
C56 C55 H55 117.4 . . ?
C55 C56 C57 116(3) . . ?
C55 C56 H56 122.1 . . ?
C57 C56 H56 122.1 . . ?
C56 C57 C58 123(3) . . ?
C56 C57 H57 118.6 . . ?
C58 C57 H57 118.6 . . ?
C45 C58 C57 122(2) . . ?
C45 C58 C53 121(2) . . ?
C57 C58 C53 117(2) . . ?
O11 C61 O12 128(3) . . ?
O11 C61 C62 119(3) . . ?
O12 C61 C62 113(3) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O19 C63 O20 119.9(19) . . ?
O19 C63 C64 120.6(19) . . ?
O20 C63 C64 119(2) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O18 C65 O17 115.2(19) . . ?
O18 C65 C66 122.5(18) . . ?
O17 C65 C66 121.6(18) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
O22 C67 O21 124(2) . . ?
O22 C67 C68 118(2) . . ?
O21 C67 C68 117.4(19) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O16 C69 O15 120(2) . . ?
O16 C69 C70 122(3) . . ?
O15 C69 C70 118(3) . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
O25 C71 O24 128.2(17) . . ?
O25 C71 C71 117(2) . 3_666 ?
O24 C71 C71 115(2) . 3_666 ?
O14 C77 O26 113(3) . . ?
O14 C77 C78 123.6(16) . . ?
O26 C77 C78 123.1(16) . . ?
C77 C78 H78A 109.5 . . ?
C77 C78 H78B 109.5 . . ?
H78A C78 H78B 109.5 . . ?
C77 C78 H78C 109.5 . . ?
H78A C78 H78C 109.5 . . ?
H78B C78 H78C 109.5 . . ?
C5 N1 C1 118(3) . . ?
C5 N1 Dy1 115.2(16) . . ?
C1 N1 Dy1 126.8(19) . . ?
C6 N2 N3 109(2) . . ?
C7 N3 N2 116(2) . . ?
C7 N3 Dy2 121(2) . . ?
N2 N3 Dy2 122.2(16) . . ?
C8 N4 N5 115(2) . . ?
C8 N4 Dy2 123(2) . . ?
N5 N4 Dy2 121.8(14) . . ?
C9 N5 N4 109(2) . . ?
C10 N6 C14 113.2(18) . . ?
C10 N6 Dy3 118.6(11) . . ?
C14 N6 Dy3 127.3(12) . . ?
C19 N7 C15 115(3) . . ?
C19 N7 Dy1 117.0(15) . . ?
C15 N7 Dy1 128.1(18) . . ?
C20 N8 N9 105.3(19) . . ?
C21 N9 N8 114(2) . . ?
C21 N9 Dy5 122.0(19) . . ?
N8 N9 Dy5 123.8(18) . . ?
C22 N10 N11 114(2) . . ?
C22 N10 Dy5 122(2) . . ?
N11 N10 Dy5 123.6(15) . . ?
C23 N11 N10 107(2) . . ?
C24 N12 C28 116.5(16) . . ?
C24 N12 Dy4 113.9(11) . . ?
C28 N12 Dy4 128.0(11) . . ?
C2 N13 C4 115(3) . . ?
C11 N14 C13 116(2) . . ?
C16 N15 C18 116(3) . . ?
C25 N16 C27 116(2) . . ?
C6 O1 Dy1 124.4(17) . . ?
C6 O1 Dy2 121.1(17) . . ?
Dy1 O1 Dy2 109.5(7) . . ?
C9 O2 Dy3 124.3(15) . . ?
C9 O2 Dy2 120.4(14) . . ?
Dy3 O2 Dy2 113.8(5) . . ?
C20 O3 Dy1 123.0(16) . . ?
C20 O3 Dy5 122.2(15) . . ?
Dy1 O3 Dy5 106.4(6) . . ?
C23 O4 Dy4 120.9(15) . . ?
C23 O4 Dy5 123.7(14) . . ?
Dy4 O4 Dy5 113.2(5) . . ?
P1 O5 Dy1 136.6(9) . . ?
P1 O5 Dy5 100.6(7) . . ?
Dy1 O5 Dy5 108.5(6) . . ?
P1 O6 Dy2 138.7(8) . . ?
P1 O7 Dy4 144.4(8) . . ?
P1 O7 Dy5 98.0(7) . . ?
Dy4 O7 Dy5 117.6(5) . . ?
P2 O8 Dy1 134.2(8) . . ?
P2 O8 Dy2 100.2(7) . . ?
Dy1 O8 Dy2 111.0(5) . . ?
P2 O9 Dy3 144.0(9) . . ?
P2 O9 Dy2 97.9(7) . . ?
Dy3 O9 Dy2 117.7(5) . . ?
P2 O10 Dy5 137.0(8) . . ?
C61 O11 Dy1 132(2) . . ?
C61 O12 Dy5 137(2) . . ?
C77 O14 Dy2 132.2(19) . . ?
C69 O15 Dy3 92.4(16) . . ?
C69 O16 Dy3 94.9(18) . . ?
C65 O17 Dy3 96.6(12) . . ?
C65 O18 Dy4 153.6(13) . . ?
C65 O18 Dy3 95.9(12) . . ?
Dy4 O18 Dy3 110.5(5) . . ?
C63 O19 Dy3 155.3(14) . . ?
C63 O19 Dy4 93.4(12) . . ?
Dy3 O19 Dy4 111.2(5) . . ?
C63 O20 Dy4 93.7(13) . . ?
C67 O21 Dy3 138.2(13) . . ?
C67 O22 Dy4 140.3(14) . . ?
C71 O24 Dy4 119.5(12) . . ?
C71 O25 Dy4 121.4(12) . 3_666 ?
Dy2 O1W H1WB 109.3 . . ?
Dy2 O1W H1WA 109.0 . . ?
H1WB O1W H1WA 109.4 . . ?
Dy5 O2W H2WA 109.2 . . ?
Dy5 O2W H2WB 109.0 . . ?
H2WA O2W H2WB 109.5 . . ?
Dy1 O3W H3WB 110.1 . . ?
Dy1 O3W H3WA 107.9 . . ?
H3WB O3W H3WA 109.5 . . ?
H14A O14W H14B 109.4 . . ?

_refine_diff_density_max         3.819
_refine_diff_density_min         -2.614
_refine_diff_density_rms         0.308

_shelxl_version_number           2013-2

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I-A-Ar-cool
_database_code_depnum_ccdc_archive 'CCDC 1819933'
_audit_update_record             
;
2018-06-21 deposited with the CCDC.
2018-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C134 H124 Dy10 N32 O54 P4, 10(H2 O), 2(H2 O)'
_chemical_formula_sum            'C134 H148 Dy10 N32 O66 P4'
_chemical_formula_weight         5011.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.6145(16)
_cell_length_b                   14.5657(11)
_cell_length_c                   26.0805(18)
_cell_angle_alpha                90
_cell_angle_beta                 112.968(2)
_cell_angle_gamma                90
_cell_volume                     8609.3(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9932
_cell_measurement_theta_min      2.613
_cell_measurement_theta_max      27.534

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.933
_exptl_crystal_F_000             4848
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    4.415
_shelx_estimated_absorpt_T_min   0.271
_shelx_estimated_absorpt_T_max   0.472
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.260
_exptl_absorpt_correction_T_max  0.472
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            61489
_diffrn_reflns_av_unetI/netI     0.0713
_diffrn_reflns_av_R_equivalents  0.0693
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.019
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             16888
_reflns_number_gt                11895
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0457P)²+390.6493P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16888
_refine_ls_number_parameters     1159
_refine_ls_number_restraints     884
_refine_ls_R_factor_all          0.1247
_refine_ls_R_factor_gt           0.0832
_refine_ls_wR_factor_ref         0.2017
_refine_ls_wR_factor_gt          0.1761
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.16342(3) 0.72738(6) 0.41909(4) 0.0476(2) Uani 1 1 d . U . . .
Dy2 Dy 0.24624(3) 0.72241(5) 0.58239(3) 0.03662(19) Uani 1 1 d . U . . .
Dy3 Dy 0.31547(3) 0.46926(5) 0.64387(3) 0.02977(17) Uani 1 1 d . . . . .
Dy4 Dy 0.39918(3) 0.45128(4) 0.54122(3) 0.02405(16) Uani 1 1 d . . . . .
Dy5 Dy 0.24452(3) 0.51048(6) 0.40623(3) 0.0371(2) Uani 1 1 d . . . . .
P1 P 0.31596(16) 0.6616(3) 0.49284(17) 0.0316(8) Uani 1 1 d . U . . .
P2 P 0.19585(17) 0.5412(3) 0.51517(16) 0.0314(8) Uani 1 1 d . U . . .
C1 C 0.1441(9) 0.9345(13) 0.3448(10) 0.082(5) Uani 1 1 d D U . . .
H1 H 0.1267 0.8971 0.3127 0.098 Uiso 1 1 calc R U . . .
C2 C 0.1437(10) 1.0261(11) 0.3387(10) 0.088(5) Uani 1 1 d D U . . .
H2 H 0.1233 1.0513 0.3026 0.105 Uiso 1 1 calc R U . . .
C4 C 0.1943(9) 1.0423(12) 0.4313(10) 0.083(5) Uani 1 1 d D U . . .
H4 H 0.2126 1.0797 0.4633 0.100 Uiso 1 1 calc R U . . .
C5 C 0.1931(9) 0.9510(11) 0.4385(10) 0.079(5) Uani 1 1 d D U . . .
C6 C 0.2210(7) 0.9013(13) 0.4925(10) 0.057(5) Uani 1 1 d . . . . .
C7 C 0.2886(9) 0.9445(14) 0.6319(10) 0.079(5) Uani 1 1 d . U . . .
H7 H 0.2892 1.0097 0.6342 0.095 Uiso 1 1 calc R U . . .
C8 C 0.3144(9) 0.8884(14) 0.6806(10) 0.076(5) Uani 1 1 d . U . . .
H8 H 0.3355 0.9154 0.7160 0.091 Uiso 1 1 calc R U . . .
C9 C 0.3395(7) 0.6665(11) 0.7127(7) 0.038(4) Uani 1 1 d . . . . .
C10 C 0.3742(6) 0.6039(9) 0.7606(5) 0.037(4) Uani 1 1 d D . . . .
C11 C 0.4039(7) 0.6346(12) 0.8130(5) 0.051(5) Uani 1 1 d D . . . .
H11 H 0.4039 0.6985 0.8205 0.061 Uiso 1 1 calc R U . . .
C13 C 0.4338(7) 0.4883(11) 0.8412(6) 0.049(5) Uani 1 1 d D . . . .
H13 H 0.4542 0.4447 0.8691 0.059 Uiso 1 1 calc R U . . .
C14 C 0.4054(7) 0.4606(11) 0.7880(5) 0.048(4) Uani 1 1 d D . . . .
H14 H 0.4066 0.3970 0.7804 0.057 Uiso 1 1 calc R U . . .
C15 C 0.0076(6) 0.7468(16) 0.3401(10) 0.081(7) Uani 1 1 d D . . . .
H15 H 0.0111 0.8037 0.3589 0.097 Uiso 1 1 calc R U . . .
C16 C -0.0458(7) 0.7221(13) 0.3025(8) 0.076(7) Uani 1 1 d D . . . .
H16 H -0.0782 0.7623 0.2959 0.091 Uiso 1 1 calc R U . . .
C18 C -0.0065(6) 0.5911(16) 0.2860(8) 0.072(4) Uani 1 1 d D U . . .
H18 H -0.0098 0.5350 0.2664 0.087 Uiso 1 1 calc R U . . .
C19 C 0.0465(7) 0.6150(13) 0.3245(7) 0.064(4) Uani 1 1 d D U . . .
C20 C 0.0999(7) 0.5565(14) 0.3411(8) 0.051(5) Uani 1 1 d . . . . .
C21 C 0.1475(9) 0.3576(18) 0.3098(9) 0.080(4) Uani 1 1 d . U . . .
H21 H 0.1127 0.3349 0.2811 0.096 Uiso 1 1 calc R U . . .
C22 C 0.2007(9) 0.3046(18) 0.3298(9) 0.077(4) Uani 1 1 d . U . . .
H22 H 0.2015 0.2425 0.3189 0.093 Uiso 1 1 calc R U . . .
C23 C 0.3373(8) 0.3251(12) 0.4297(7) 0.043(4) Uani 1 1 d . . . . .
C24 C 0.3928(7) 0.2734(10) 0.4550(5) 0.044(4) Uani 1 1 d D . . . .
C25 C 0.4114(6) 0.2068(10) 0.4297(7) 0.048(4) Uani 1 1 d D . . . .
H25 H 0.3894 0.1963 0.3912 0.058 Uiso 1 1 calc R U . . .
C27 C 0.4895(7) 0.1735(10) 0.5099(6) 0.047(4) Uani 1 1 d D . . . .
H27 H 0.5226 0.1371 0.5313 0.057 Uiso 1 1 calc R U . . .
C28 C 0.4729(6) 0.2440(8) 0.5337(6) 0.032(3) Uani 1 1 d D . . . .
H28 H 0.4971 0.2583 0.5712 0.038 Uiso 1 1 calc R U . . .
C29 C 0.3721(7) 0.7291(11) 0.4813(8) 0.041(3) Uani 1 1 d . U . . .
H29A H 0.4109 0.7153 0.5112 0.049 Uiso 1 1 calc R U . . .
H29B H 0.3738 0.7102 0.4455 0.049 Uiso 1 1 calc R U . . .
C30 C 0.3616(7) 0.8321(11) 0.4799(6) 0.054(3) Uani 1 1 d D U . . .
C31 C 0.3325(7) 0.8744(10) 0.4280(7) 0.062(3) Uani 1 1 d D U . . .
C32 C 0.3082(7) 0.8255(14) 0.3779(7) 0.065(4) Uani 1 1 d D U . . .
H32 H 0.3112 0.7605 0.3796 0.077 Uiso 1 1 calc R U . . .
C33 C 0.2798(9) 0.8660(12) 0.3254(8) 0.076(4) Uani 1 1 d D U . . .
H33 H 0.2632 0.8300 0.2926 0.091 Uiso 1 1 calc R U . . .
C34 C 0.2770(9) 0.9620(12) 0.3237(10) 0.078(4) Uani 1 1 d D U . . .
H34 H 0.2597 0.9921 0.2887 0.094 Uiso 1 1 calc R U . . .
C35 C 0.2990(9) 1.0145(15) 0.3724(7) 0.080(4) Uani 1 1 d D U . . .
H35 H 0.2955 1.0795 0.3707 0.096 Uiso 1 1 calc R U . . .
C36 C 0.3263(8) 0.9702(10) 0.4239(7) 0.071(3) Uani 1 1 d D U . . .
C37 C 0.3461(8) 1.0228(14) 0.4728(7) 0.076(4) Uani 1 1 d D U . . .
H37 H 0.3405 1.0874 0.4705 0.091 Uiso 1 1 calc R U . . .
C38 C 0.3742(8) 0.9812(10) 0.5249(7) 0.074(4) Uani 1 1 d D U . . .
C39 C 0.3945(10) 1.0322(15) 0.5744(8) 0.087(5) Uani 1 1 d D U . . .
H39 H 0.3912 1.0971 0.5713 0.104 Uiso 1 1 calc R U . . .
C40 C 0.4192(10) 0.9949(12) 0.6279(10) 0.093(5) Uani 1 1 d D U . . .
H40 H 0.4284 1.0309 0.6606 0.112 Uiso 1 1 calc R U . . .
C41 C 0.4295(10) 0.9001(12) 0.6296(10) 0.087(5) Uani 1 1 d D U . . .
H41 H 0.4492 0.8713 0.6647 0.104 Uiso 1 1 calc R U . . .
C42 C 0.4116(8) 0.8462(14) 0.5814(7) 0.072(4) Uani 1 1 d D U . . .
H42 H 0.4190 0.7820 0.5845 0.087 Uiso 1 1 calc R U . . .
C43 C 0.3829(8) 0.8857(9) 0.5285(7) 0.063(3) Uani 1 1 d D U . . .
C44 C 0.1319(7) 0.4850(12) 0.5215(7) 0.042(3) Uani 1 1 d . U . . .
H44A H 0.1422 0.4200 0.5318 0.051 Uiso 1 1 calc R U . . .
H44B H 0.1247 0.5144 0.5524 0.051 Uiso 1 1 calc R U . . .
C45 C 0.0758(7) 0.4875(11) 0.4707(7) 0.055(3) Uani 1 1 d D U . . .
C46 C 0.0614(8) 0.4170(13) 0.4315(7) 0.074(4) Uani 1 1 d D U . . .
C47 C 0.1008(10) 0.3461(14) 0.4350(10) 0.084(4) Uani 1 1 d D U . . .
H47 H 0.1386 0.3458 0.4646 0.101 Uiso 1 1 calc R U . . .
C48 C 0.0855(10) 0.2756(17) 0.3958(9) 0.099(5) Uani 1 1 d D U . . .
H48 H 0.1119 0.2265 0.3986 0.118 Uiso 1 1 calc R U . . .
C49 C 0.0301(10) 0.2795(19) 0.3524(11) 0.108(5) Uani 1 1 d D U . . .
H49 H 0.0206 0.2331 0.3247 0.129 Uiso 1 1 calc R U . . .
C50 C -0.0123(12) 0.3463(16) 0.3465(11) 0.106(5) Uani 1 1 d D U . . .
H50 H -0.0505 0.3455 0.3173 0.127 Uiso 1 1 calc R U . . .
C51 C 0.0061(8) 0.4143(14) 0.3873(8) 0.087(4) Uani 1 1 d D U . . .
C52 C -0.0342(10) 0.4846(13) 0.3822(10) 0.087(4) Uani 1 1 d D U . . .
H52 H -0.0717 0.4831 0.3521 0.105 Uiso 1 1 calc R U . . .
C53 C -0.0207(7) 0.5568(14) 0.4200(7) 0.078(4) Uani 1 1 d D U . . .
C54 C -0.0627(9) 0.6251(14) 0.4127(10) 0.085(4) Uani 1 1 d D U . . .
H54 H -0.0997 0.6228 0.3820 0.102 Uiso 1 1 calc R U . . .
C55 C -0.0499(8) 0.6967(17) 0.4508(8) 0.087(4) Uani 1 1 d D U . . .
H55 H -0.0776 0.7447 0.4458 0.104 Uiso 1 1 calc R U . . .
C56 C 0.0039(7) 0.6976(15) 0.4965(9) 0.080(4) Uani 1 1 d D U . . .
H56 H 0.0121 0.7438 0.5242 0.096 Uiso 1 1 calc R U . . .
C57 C 0.0458(8) 0.6301(12) 0.5012(8) 0.067(4) Uani 1 1 d D U . . .
H57 H 0.0832 0.6336 0.5313 0.081 Uiso 1 1 calc R U . . .
C58 C 0.0349(6) 0.5577(12) 0.4635(7) 0.064(3) Uani 1 1 d D U . . .
C61 C 0.1852(10) 0.673(2) 0.3045(9) 0.081(4) Uani 1 1 d . U . . .
C62 C 0.1705(12) 0.693(2) 0.2438(9) 0.106(7) Uani 1 1 d . U . . .
H62A H 0.2026 0.6714 0.2336 0.159 Uiso 1 1 calc R U . . .
H62B H 0.1655 0.7594 0.2375 0.159 Uiso 1 1 calc R U . . .
H62C H 0.1338 0.6616 0.2209 0.159 Uiso 1 1 calc R U . . .
C63 C 0.4295(6) 0.5908(9) 0.6236(6) 0.028(3) Uani 1 1 d . . . . .
C64 C 0.4541(7) 0.6523(13) 0.6740(7) 0.046(4) Uani 1 1 d . . . . .
H64A H 0.4888 0.6848 0.6737 0.069 Uiso 1 1 calc R U . . .
H64B H 0.4654 0.6151 0.7079 0.069 Uiso 1 1 calc R U . . .
H64C H 0.4240 0.6970 0.6732 0.069 Uiso 1 1 calc R U . . .
C65 C 0.2801(7) 0.3353(11) 0.5562(6) 0.034(3) Uani 1 1 d . . . . .
C66 C 0.2649(9) 0.2581(12) 0.5155(8) 0.054(5) Uani 1 1 d . . . . .
H66A H 0.2489 0.2827 0.4775 0.081 Uiso 1 1 calc R U . . .
H66B H 0.2354 0.2186 0.5210 0.081 Uiso 1 1 calc R U . . .
H66C H 0.3005 0.2221 0.5213 0.081 Uiso 1 1 calc R U . . .
C67 C 0.4328(8) 0.3357(11) 0.6620(7) 0.041(3) Uani 1 1 d . U . . .
C68 C 0.4743(9) 0.2653(14) 0.6992(8) 0.062(5) Uani 1 1 d . U . . .
H68A H 0.4675 0.2060 0.6800 0.093 Uiso 1 1 calc R U . . .
H68B H 0.4672 0.2593 0.7335 0.093 Uiso 1 1 calc R U . . .
H68C H 0.5151 0.2847 0.7084 0.093 Uiso 1 1 calc R U . . .
C69 C 0.2447(8) 0.4086(14) 0.6997(7) 0.047(4) Uani 1 1 d . . . . .
C70 C 0.2016(9) 0.3662(17) 0.7229(8) 0.070(7) Uani 1 1 d . . . . .
H70A H 0.1724 0.4123 0.7223 0.105 Uiso 1 1 calc R U . . .
H70B H 0.2235 0.3457 0.7613 0.105 Uiso 1 1 calc R U . . .
H70C H 0.1815 0.3136 0.6998 0.105 Uiso 1 1 calc R U . . .
C71 C 0.5238(6) 0.4849(9) 0.5288(6) 0.026(3) Uani 1 1 d . . . . .
C77 C 0.1397(9) 0.8461(15) 0.5924(7) 0.101(4) Uani 1 1 d D U . . .
C78 C 0.0915(12) 0.9157(19) 0.5700(10) 0.114(5) Uani 1 1 d D U . . .
H78A H 0.1076 0.9771 0.5825 0.171 Uiso 1 1 calc R U . . .
H78B H 0.0606 0.9021 0.5837 0.171 Uiso 1 1 calc R U . . .
H78C H 0.0749 0.9135 0.5293 0.171 Uiso 1 1 calc R U . . .
N1 N 0.1684(7) 0.8941(12) 0.3950(7) 0.078(4) Uani 1 1 d D U . . .
N2 N 0.2403(7) 0.9548(11) 0.5366(9) 0.072(4) Uani 1 1 d . U . . .
N3 N 0.2644(7) 0.9024(10) 0.5848(8) 0.070(4) Uani 1 1 d . U . . .
N4 N 0.3087(7) 0.8040(11) 0.6757(8) 0.065(4) Uani 1 1 d . U . . .
N5 N 0.3379(7) 0.7508(11) 0.7245(7) 0.061(5) Uani 1 1 d . . . . .
N6 N 0.3754(5) 0.5161(8) 0.7451(5) 0.039(3) Uani 1 1 d D . . . .
N7 N 0.0560(6) 0.6948(11) 0.3523(7) 0.065(4) Uani 1 1 d D U . . .
N8 N 0.0956(7) 0.4837(15) 0.3112(7) 0.072(4) Uani 1 1 d . U . . .
N9 N 0.1483(7) 0.4375(14) 0.3320(7) 0.072(4) Uani 1 1 d . U . . .
N10 N 0.2484(7) 0.3465(13) 0.3639(6) 0.065(4) Uani 1 1 d . U . . .
N11 N 0.2988(6) 0.2934(12) 0.3816(6) 0.061(4) Uani 1 1 d . U . . .
N12 N 0.4247(5) 0.2958(8) 0.5084(4) 0.034(3) Uani 1 1 d D . . . .
N13 N 0.1708(8) 1.0834(13) 0.3814(8) 0.088(5) Uani 1 1 d D U . . .
N14 N 0.4335(6) 0.5772(10) 0.8549(6) 0.054(4) Uani 1 1 d D . . . .
N15 N -0.0551(7) 0.6429(13) 0.2740(7) 0.077(4) Uani 1 1 d D U . . .
N16 N 0.4591(6) 0.1546(10) 0.4558(5) 0.052(4) Uani 1 1 d D . . . .
O1 O 0.2218(5) 0.8159(8) 0.4938(6) 0.051(3) Uani 1 1 d . . . . .
O2 O 0.3149(4) 0.6307(8) 0.6637(4) 0.040(3) Uani 1 1 d . . . . .
O3 O 0.1462(5) 0.5800(9) 0.3853(5) 0.048(3) Uani 1 1 d . . . . .
O4 O 0.3270(4) 0.3939(7) 0.4548(4) 0.028(2) Uani 1 1 d . . . . .
O5 O 0.2563(4) 0.6686(7) 0.4398(4) 0.037(3) Uani 1 1 d . . . . .
O6 O 0.3135(4) 0.6930(7) 0.5466(4) 0.032(2) Uani 1 1 d . . . . .
O7 O 0.3311(4) 0.5601(7) 0.4931(4) 0.032(2) Uani 1 1 d . . . . .
O8 O 0.1787(4) 0.6422(7) 0.4978(4) 0.036(2) Uani 1 1 d . . . . .
O9 O 0.2453(4) 0.5489(7) 0.5738(4) 0.033(2) Uani 1 1 d . . . . .
O10 O 0.2149(5) 0.4840(7) 0.4751(4) 0.035(2) Uani 1 1 d . . . . .
O11 O 0.1675(6) 0.7303(12) 0.3316(6) 0.077(4) Uani 1 1 d . U . . .
O12 O 0.2152(6) 0.6016(12) 0.3238(5) 0.073(4) Uani 1 1 d . U . . .
O14 O 0.1584(7) 0.8008(11) 0.5630(7) 0.086(3) Uani 1 1 d D U . . .
O15 O 0.2912(6) 0.3626(9) 0.7063(5) 0.053(3) Uani 1 1 d . . . . .
O16 O 0.2327(5) 0.4811(10) 0.6744(5) 0.055(3) Uani 1 1 d . . . . .
O17 O 0.2520(5) 0.3456(8) 0.5877(5) 0.042(3) Uani 1 1 d . . . . .
O18 O 0.3210(4) 0.3905(7) 0.5618(4) 0.033(2) Uani 1 1 d . . . . .
O19 O 0.3903(4) 0.5340(6) 0.6218(4) 0.029(2) Uani 1 1 d . . . . .
O20 O 0.4499(5) 0.5934(7) 0.5869(4) 0.036(2) Uani 1 1 d . . . . .
O21 O 0.3914(5) 0.3612(8) 0.6750(4) 0.043(2) Uani 1 1 d . U . . .
O22 O 0.4441(5) 0.3628(7) 0.6215(4) 0.037(2) Uani 1 1 d . U . . .
O24 O 0.5049(4) 0.4468(7) 0.5617(4) 0.030(2) Uani 1 1 d . . . . .
O25 O 0.5749(4) 0.4986(8) 0.5350(4) 0.036(2) Uani 1 1 d . . . . .
O26 O 0.1679(10) 0.8336(16) 0.6428(9) 0.140(5) Uani 1 1 d D U . . .
O1W O 0.1940(6) 0.6568(10) 0.6358(6) 0.065(4) Uani 1 1 d . . . . .
H1WB H 0.1624 0.6869 0.6294 0.098 Uiso 1 1 d R U . . .
H1WA H 0.1854 0.6012 0.6260 0.098 Uiso 1 1 d R U . . .
O2W O 0.3238(5) 0.5348(9) 0.3792(4) 0.051(3) Uani 1 1 d . . . . .
H2WA H 0.3392 0.4834 0.3774 0.077 Uiso 1 1 d R U . . .
H2WB H 0.3113 0.5605 0.3474 0.077 Uiso 1 1 d R U . . .
O3W O 0.0993(5) 0.8069(10) 0.4522(7) 0.078(5) Uani 1 1 d . U . . .
H3WB H 0.0893 0.7715 0.4729 0.117 Uiso 1 1 d R U . . .
H3WA H 0.1175 0.8531 0.4709 0.117 Uiso 1 1 d R U . . .
O4W O 0.2446(10) 0.4830(18) 0.2449(8) 0.049(6) Uani 0.5 1 d . . P A 1
O5W O 0.1441(16) 0.3745(18) 0.1816(15) 0.086(11) Uani 0.5 1 d . . P B 1
O6W O 0.0514(13) 0.466(2) 0.1854(10) 0.065(8) Uani 0.5 1 d . . P C 1
O7W O 0.3211(14) 0.179(2) 0.6622(13) 0.079(9) Uani 0.5 1 d . U P D 1
O8W O 0.2011(10) 0.1988(15) 0.6197(10) 0.042(5) Uani 0.5 1 d . U P E 1
O9W O 0.1569(15) 0.099(2) 0.5303(15) 0.087(10) Uani 0.5 1 d . U P F 1
O10W O 0.0489(17) 0.981(3) 0.4103(16) 0.104(12) Uani 0.5 1 d . U P G 1
O11W O 0.3598(15) 0.097(2) 0.7640(14) 0.086(10) Uani 0.5 1 d . U P H 1
O12W O 0.3417(11) 0.2482(19) 0.7944(10) 0.056(6) Uani 0.5 1 d . U P I 1
O13W O 0.5586(10) 0.4729(16) 0.6857(9) 0.046(6) Uani 0.5 1 d . U P J 1
O14W O 0.3650(8) 0.6461(12) 0.3256(8) 0.100(6) Uani 1 1 d . U . . .
H14A H 0.3558 0.6790 0.2965 0.150 Uiso 1 1 d R U . . .
H14B H 0.4022 0.6481 0.3437 0.150 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O3 2.296(13) . ?
Dy1 O5 2.300(10) . ?
Dy1 O8 2.301(10) . ?
Dy1 O1 2.310(13) . ?
Dy1 O11 2.323(15) . ?
Dy1 O3W 2.375(13) . ?
Dy1 N1 2.523(17) . ?
Dy1 N7 2.580(15) . ?
Dy2 O6 2.236(9) . ?
Dy2 O14 2.320(14) . ?
Dy2 O1W 2.430(13) . ?
Dy2 O8 2.477(10) . ?
Dy2 O2 2.518(11) . ?
Dy2 O9 2.537(10) . ?
Dy2 O1 2.543(12) . ?
Dy2 N4 2.603(17) . ?
Dy2 N3 2.656(15) . ?
Dy3 O9 2.280(10) . ?
Dy3 O21 2.333(11) . ?
Dy3 O19 2.333(10) . ?
Dy3 O2 2.410(11) . ?
Dy3 O17 2.458(11) . ?
Dy3 O16 2.466(12) . ?
Dy3 O18 2.479(10) . ?
Dy3 O15 2.487(12) . ?
Dy3 N6 2.563(12) . ?
Dy4 O7 2.292(10) . ?
Dy4 O22 2.337(10) . ?
Dy4 O18 2.363(10) . ?
Dy4 O4 2.410(9) . ?
Dy4 O25 2.425(10) 3_666 ?
Dy4 O24 2.446(9) . ?
Dy4 O20 2.470(11) . ?
Dy4 O19 2.504(9) . ?
Dy4 N12 2.583(11) . ?
Dy5 O10 2.219(10) . ?
Dy5 O2W 2.346(11) . ?
Dy5 O12 2.386(13) . ?
Dy5 O5 2.440(11) . ?
Dy5 O3 2.480(11) . ?
Dy5 O7 2.536(10) . ?
Dy5 O4 2.570(10) . ?
Dy5 N9 2.629(15) . ?
Dy5 N10 2.649(17) . ?
P1 O6 1.498(11) . ?
P1 O7 1.524(11) . ?
P1 O5 1.580(10) . ?
P1 C29 1.814(14) . ?
P2 O9 1.543(10) . ?
P2 O10 1.546(10) . ?
P2 O8 1.549(11) . ?
P2 C44 1.837(14) . ?
C1 C2 1.343(11) . ?
C1 N1 1.344(11) . ?
C1 H1 0.9500 . ?
C2 N13 1.343(11) . ?
C2 H2 0.9500 . ?
C4 N13 1.343(11) . ?
C4 C5 1.345(11) . ?
C4 H4 0.9500 . ?
C5 N1 1.344(11) . ?
C5 C6 1.49(3) . ?
C6 O1 1.25(2) . ?
C6 N2 1.32(3) . ?
C7 N3 1.29(3) . ?
C7 C8 1.43(3) . ?
C7 H7 0.9500 . ?
C8 N4 1.24(2) . ?
C8 H8 0.9500 . ?
C9 N5 1.27(2) . ?
C9 O2 1.290(18) . ?
C9 C10 1.51(2) . ?
C10 N6 1.344(9) . ?
C10 C11 1.352(9) . ?
C11 N14 1.343(9) . ?
C11 H11 0.9500 . ?
C13 N14 1.344(9) . ?
C13 C14 1.348(9) . ?
C13 H13 0.9500 . ?
C14 N6 1.345(9) . ?
C14 H14 0.9500 . ?
C15 N7 1.342(10) . ?
C15 C16 1.346(10) . ?
C15 H15 0.9500 . ?
C16 N15 1.343(10) . ?
C16 H16 0.9500 . ?
C18 N15 1.343(10) . ?
C18 C19 1.346(10) . ?
C18 H18 0.9500 . ?
C19 N7 1.342(10) . ?
C19 C20 1.48(2) . ?
C20 N8 1.30(3) . ?
C20 O3 1.31(2) . ?
C21 N9 1.30(3) . ?
C21 C22 1.43(3) . ?
C21 H21 0.9500 . ?
C22 N10 1.31(2) . ?
C22 H22 0.9500 . ?
C23 O4 1.276(18) . ?
C23 N11 1.32(2) . ?
C23 C24 1.47(2) . ?
C24 N12 1.345(9) . ?
C24 C25 1.348(9) . ?
C25 N16 1.341(9) . ?
C25 H25 0.9500 . ?
C27 N16 1.341(9) . ?
C27 C28 1.344(9) . ?
C27 H27 0.9500 . ?
C28 N12 1.342(9) . ?
C28 H28 0.9500 . ?
C29 C30 1.52(2) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.403(8) . ?
C30 C43 1.403(8) . ?
C31 C32 1.402(8) . ?
C31 C36 1.405(8) . ?
C32 C33 1.400(8) . ?
C32 H32 0.9500 . ?
C33 C34 1.400(8) . ?
C33 H33 0.9500 . ?
C34 C35 1.399(8) . ?
C34 H34 0.9500 . ?
C35 C36 1.402(8) . ?
C35 H35 0.9500 . ?
C36 C37 1.401(8) . ?
C37 C38 1.400(8) . ?
C37 H37 0.9500 . ?
C38 C39 1.401(8) . ?
C38 C43 1.405(8) . ?
C39 C40 1.398(8) . ?
C39 H39 0.9500 . ?
C40 C41 1.402(8) . ?
C40 H40 0.9500 . ?
C41 C42 1.400(8) . ?
C41 H41 0.9500 . ?
C42 C43 1.404(8) . ?
C42 H42 0.9500 . ?
C44 C45 1.49(2) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.395(8) . ?
C45 C58 1.395(8) . ?
C46 C47 1.395(8) . ?
C46 C51 1.400(8) . ?
C47 C48 1.393(8) . ?
C47 H47 0.9500 . ?
C48 C49 1.392(8) . ?
C48 H48 0.9500 . ?
C49 C50 1.391(8) . ?
C49 H49 0.9500 . ?
C50 C51 1.394(8) . ?
C50 H50 0.9500 . ?
C51 C52 1.394(8) . ?
C52 C53 1.392(8) . ?
C52 H52 0.9500 . ?
C53 C54 1.392(8) . ?
C53 C58 1.396(8) . ?
C54 C55 1.389(8) . ?
C54 H54 0.9500 . ?
C55 C56 1.393(8) . ?
C55 H55 0.9500 . ?
C56 C57 1.393(8) . ?
C56 H56 0.9500 . ?
C57 C58 1.394(8) . ?
C57 H57 0.9500 . ?
C61 O12 1.26(3) . ?
C61 O11 1.28(3) . ?
C61 C62 1.51(3) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 O20 1.241(17) . ?
C63 O19 1.258(17) . ?
C63 C64 1.51(2) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 O18 1.251(17) . ?
C65 O17 1.273(17) . ?
C65 C66 1.49(2) . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 O21 1.251(19) . ?
C67 O22 1.254(18) . ?
C67 C68 1.51(2) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 O16 1.22(2) . ?
C69 O15 1.28(2) . ?
C69 C70 1.54(2) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C71 O25 1.220(16) . ?
C71 O24 1.254(17) . ?
C71 C71 1.57(3) 3_666 ?
C77 O14 1.228(17) . ?
C77 O26 1.238(17) . ?
C77 C78 1.495(10) . ?
C78 H78A 0.9800 . ?
C78 H78B 0.9800 . ?
C78 H78C 0.9800 . ?
N2 N3 1.39(2) . ?
N4 N5 1.42(2) . ?
N8 N9 1.37(2) . ?
N10 N11 1.38(2) . ?
O25 Dy4 2.425(10) 3_666 ?
O1W H1WB 0.8500 . ?
O1W H1WA 0.8501 . ?
O2W H2WA 0.8500 . ?
O2W H2WB 0.8502 . ?
O3W H3WB 0.8499 . ?
O3W H3WA 0.8499 . ?
O14W H14A 0.8501 . ?
O14W H14B 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Dy1 O5 76.1(4) . . ?
O3 Dy1 O8 77.3(4) . . ?
O5 Dy1 O8 77.8(3) . . ?
O3 Dy1 O1 143.7(4) . . ?
O5 Dy1 O1 77.0(4) . . ?
O8 Dy1 O1 73.6(4) . . ?
O3 Dy1 O11 73.3(5) . . ?
O5 Dy1 O11 79.5(4) . . ?
O8 Dy1 O11 146.3(5) . . ?
O1 Dy1 O11 124.6(5) . . ?
O3 Dy1 O3W 123.1(5) . . ?
O5 Dy1 O3W 146.8(5) . . ?
O8 Dy1 O3W 80.7(4) . . ?
O1 Dy1 O3W 72.8(5) . . ?
O11 Dy1 O3W 129.6(5) . . ?
O3 Dy1 N1 145.5(5) . . ?
O5 Dy1 N1 106.0(4) . . ?
O8 Dy1 N1 137.2(5) . . ?
O1 Dy1 N1 66.3(5) . . ?
O11 Dy1 N1 73.3(6) . . ?
O3W Dy1 N1 74.0(5) . . ?
O3 Dy1 N7 65.3(4) . . ?
O5 Dy1 N7 138.9(5) . . ?
O8 Dy1 N7 105.7(4) . . ?
O1 Dy1 N7 143.9(5) . . ?
O11 Dy1 N7 76.4(5) . . ?
O3W Dy1 N7 71.5(5) . . ?
N1 Dy1 N7 98.4(5) . . ?
O6 Dy2 O14 141.5(5) . . ?
O6 Dy2 O1W 143.8(4) . . ?
O14 Dy2 O1W 70.2(5) . . ?
O6 Dy2 O8 83.5(3) . . ?
O14 Dy2 O8 78.1(5) . . ?
O1W Dy2 O8 90.2(4) . . ?
O6 Dy2 O2 83.5(4) . . ?
O14 Dy2 O2 135.0(5) . . ?
O1W Dy2 O2 68.9(4) . . ?
O8 Dy2 O2 119.8(3) . . ?
O6 Dy2 O9 75.8(3) . . ?
O14 Dy2 O9 119.7(5) . . ?
O1W Dy2 O9 70.7(4) . . ?
O8 Dy2 O9 58.1(3) . . ?
O2 Dy2 O9 61.7(3) . . ?
O6 Dy2 O1 71.0(4) . . ?
O14 Dy2 O1 70.7(5) . . ?
O1W Dy2 O1 137.8(4) . . ?
O8 Dy2 O1 66.7(4) . . ?
O2 Dy2 O1 153.1(4) . . ?
O9 Dy2 O1 117.5(4) . . ?
O6 Dy2 N4 102.4(5) . . ?
O14 Dy2 N4 98.0(5) . . ?
O1W Dy2 N4 84.0(5) . . ?
O8 Dy2 N4 173.8(5) . . ?
O2 Dy2 N4 59.8(4) . . ?
O9 Dy2 N4 121.3(4) . . ?
O1 Dy2 N4 116.7(5) . . ?
O6 Dy2 N3 93.1(5) . . ?
O14 Dy2 N3 69.7(6) . . ?
O1W Dy2 N3 119.8(6) . . ?
O8 Dy2 N3 122.3(5) . . ?
O2 Dy2 N3 116.9(4) . . ?
O9 Dy2 N3 168.8(5) . . ?
O1 Dy2 N3 58.1(5) . . ?
N4 Dy2 N3 59.7(6) . . ?
O9 Dy3 O21 151.0(3) . . ?
O9 Dy3 O19 91.2(3) . . ?
O21 Dy3 O19 75.9(4) . . ?
O9 Dy3 O2 67.0(4) . . ?
O21 Dy3 O2 130.9(4) . . ?
O19 Dy3 O2 74.3(3) . . ?
O9 Dy3 O17 77.8(4) . . ?
O21 Dy3 O17 87.1(4) . . ?
O19 Dy3 O17 121.9(3) . . ?
O2 Dy3 O17 142.0(4) . . ?
O9 Dy3 O16 76.2(4) . . ?
O21 Dy3 O16 125.8(4) . . ?
O19 Dy3 O16 152.0(4) . . ?
O2 Dy3 O16 77.7(4) . . ?
O17 Dy3 O16 80.2(4) . . ?
O9 Dy3 O18 79.8(3) . . ?
O21 Dy3 O18 71.5(4) . . ?
O19 Dy3 O18 70.1(3) . . ?
O2 Dy3 O18 130.1(3) . . ?
O17 Dy3 O18 51.9(3) . . ?
O16 Dy3 O18 129.9(4) . . ?
O9 Dy3 O15 122.8(4) . . ?
O21 Dy3 O15 73.5(4) . . ?
O19 Dy3 O15 146.0(4) . . ?
O2 Dy3 O15 116.5(4) . . ?
O17 Dy3 O15 70.9(4) . . ?
O16 Dy3 O15 52.5(4) . . ?
O18 Dy3 O15 112.7(4) . . ?
O9 Dy3 N6 129.9(3) . . ?
O21 Dy3 N6 76.1(4) . . ?
O19 Dy3 N6 87.4(4) . . ?
O2 Dy3 N6 64.4(4) . . ?
O17 Dy3 N6 141.7(4) . . ?
O16 Dy3 N6 82.2(4) . . ?
O18 Dy3 N6 144.0(4) . . ?
O15 Dy3 N6 71.3(4) . . ?
O7 Dy4 O22 149.4(3) . . ?
O7 Dy4 O18 84.1(3) . . ?
O22 Dy4 O18 74.5(4) . . ?
O7 Dy4 O4 67.3(3) . . ?
O22 Dy4 O4 124.4(4) . . ?
O18 Dy4 O4 73.4(3) . . ?
O7 Dy4 O25 73.3(3) . 3_666 ?
O22 Dy4 O25 135.8(3) . 3_666 ?
O18 Dy4 O25 142.8(3) . 3_666 ?
O4 Dy4 O25 70.8(3) . 3_666 ?
O7 Dy4 O24 128.8(3) . . ?
O22 Dy4 O24 72.5(3) . . ?
O18 Dy4 O24 146.3(3) . . ?
O4 Dy4 O24 121.9(3) . . ?
O25 Dy4 O24 65.8(3) 3_666 . ?
O7 Dy4 O20 78.9(3) . . ?
O22 Dy4 O20 93.2(4) . . ?
O18 Dy4 O20 120.5(3) . . ?
O4 Dy4 O20 142.3(3) . . ?
O25 Dy4 O20 84.2(3) 3_666 . ?
O24 Dy4 O20 67.8(3) . . ?
O7 Dy4 O19 80.9(3) . . ?
O22 Dy4 O19 71.3(3) . . ?
O18 Dy4 O19 69.2(3) . . ?
O4 Dy4 O19 132.7(3) . . ?
O25 Dy4 O19 132.8(3) 3_666 . ?
O24 Dy4 O19 105.3(3) . . ?
O20 Dy4 O19 52.1(3) . . ?
O7 Dy4 N12 130.2(3) . . ?
O22 Dy4 N12 73.9(3) . . ?
O18 Dy4 N12 94.1(4) . . ?
O4 Dy4 N12 64.6(3) . . ?
O25 Dy4 N12 79.4(4) 3_666 . ?
O24 Dy4 N12 70.9(3) . . ?
O20 Dy4 N12 138.8(3) . . ?
O19 Dy4 N12 144.3(3) . . ?
O10 Dy5 O2W 147.5(4) . . ?
O10 Dy5 O12 138.3(4) . . ?
O2W Dy5 O12 68.9(4) . . ?
O10 Dy5 O5 84.5(3) . . ?
O2W Dy5 O5 88.2(4) . . ?
O12 Dy5 O5 75.5(5) . . ?
O10 Dy5 O3 69.4(4) . . ?
O2W Dy5 O3 136.6(4) . . ?
O12 Dy5 O3 69.4(4) . . ?
O5 Dy5 O3 70.3(4) . . ?
O10 Dy5 O7 75.7(3) . . ?
O2W Dy5 O7 73.6(3) . . ?
O12 Dy5 O7 120.0(4) . . ?
O5 Dy5 O7 58.0(3) . . ?
O3 Dy5 O7 119.2(4) . . ?
O10 Dy5 O4 86.1(3) . . ?
O2W Dy5 O4 70.0(4) . . ?
O12 Dy5 O4 135.6(4) . . ?
O5 Dy5 O4 119.1(3) . . ?
O3 Dy5 O4 153.4(3) . . ?
O7 Dy5 O4 61.4(3) . . ?
O10 Dy5 N9 92.3(5) . . ?
O2W Dy5 N9 117.1(5) . . ?
O12 Dy5 N9 72.1(6) . . ?
O5 Dy5 N9 126.3(5) . . ?
O3 Dy5 N9 58.8(5) . . ?
O7 Dy5 N9 167.1(5) . . ?
O4 Dy5 N9 114.1(5) . . ?
O10 Dy5 N10 104.9(5) . . ?
O2W Dy5 N10 80.9(5) . . ?
O12 Dy5 N10 100.0(6) . . ?
O5 Dy5 N10 169.1(4) . . ?
O3 Dy5 N10 117.9(4) . . ?
O7 Dy5 N10 118.4(4) . . ?
O4 Dy5 N10 57.3(4) . . ?
N9 Dy5 N10 59.8(5) . . ?
O6 P1 O7 113.0(6) . . ?
O6 P1 O5 115.9(6) . . ?
O7 P1 O5 102.0(6) . . ?
O6 P1 C29 107.6(7) . . ?
O7 P1 C29 109.0(7) . . ?
O5 P1 C29 109.1(7) . . ?
O9 P2 O10 112.2(6) . . ?
O9 P2 O8 103.9(6) . . ?
O10 P2 O8 115.7(6) . . ?
O9 P2 C44 108.4(7) . . ?
O10 P2 C44 108.5(7) . . ?
O8 P2 C44 107.7(7) . . ?
C2 C1 N1 122(2) . . ?
C2 C1 H1 119.0 . . ?
N1 C1 H1 119.0 . . ?
N13 C2 C1 123(2) . . ?
N13 C2 H2 118.6 . . ?
C1 C2 H2 118.6 . . ?
N13 C4 C5 123(2) . . ?
N13 C4 H4 118.3 . . ?
C5 C4 H4 118.3 . . ?
N1 C5 C4 121(2) . . ?
N1 C5 C6 112.8(15) . . ?
C4 C5 C6 125.8(19) . . ?
O1 C6 N2 125(2) . . ?
O1 C6 C5 121(2) . . ?
N2 C6 C5 114.5(16) . . ?
N3 C7 C8 116.9(18) . . ?
N3 C7 H7 121.6 . . ?
C8 C7 H7 121.6 . . ?
N4 C8 C7 119(2) . . ?
N4 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
N5 C9 O2 125.7(17) . . ?
N5 C9 C10 116.3(14) . . ?
O2 C9 C10 118.0(13) . . ?
N6 C10 C11 123.6(14) . . ?
N6 C10 C9 113.4(11) . . ?
C11 C10 C9 123.0(12) . . ?
N14 C11 C10 121.6(15) . . ?
N14 C11 H11 119.2 . . ?
C10 C11 H11 119.2 . . ?
N14 C13 C14 120.6(15) . . ?
N14 C13 H13 119.7 . . ?
C14 C13 H13 119.7 . . ?
N6 C14 C13 124.9(15) . . ?
N6 C14 H14 117.6 . . ?
C13 C14 H14 117.6 . . ?
N7 C15 C16 123.1(19) . . ?
N7 C15 H15 118.5 . . ?
C16 C15 H15 118.5 . . ?
N15 C16 C15 122.7(19) . . ?
N15 C16 H16 118.6 . . ?
C15 C16 H16 118.6 . . ?
N15 C18 C19 122.9(19) . . ?
N15 C18 H18 118.5 . . ?
C19 C18 H18 118.5 . . ?
N7 C19 C18 122.8(18) . . ?
N7 C19 C20 113.1(14) . . ?
C18 C19 C20 124.1(17) . . ?
N8 C20 O3 125.7(16) . . ?
N8 C20 C19 116.0(16) . . ?
O3 C20 C19 118.3(18) . . ?
N9 C21 C22 118.0(18) . . ?
N9 C21 H21 121.0 . . ?
C22 C21 H21 121.0 . . ?
N10 C22 C21 116(2) . . ?
N10 C22 H22 121.8 . . ?
C21 C22 H22 121.8 . . ?
O4 C23 N11 123.2(17) . . ?
O4 C23 C24 120.4(14) . . ?
N11 C23 C24 116.2(14) . . ?
N12 C24 C25 120.6(14) . . ?
N12 C24 C23 113.8(11) . . ?
C25 C24 C23 125.5(12) . . ?
N16 C25 C24 123.9(14) . . ?
N16 C25 H25 118.1 . . ?
C24 C25 H25 118.1 . . ?
N16 C27 C28 119.8(14) . . ?
N16 C27 H27 120.1 . . ?
C28 C27 H27 120.1 . . ?
N12 C28 C27 124.9(13) . . ?
N12 C28 H28 117.5 . . ?
C27 C28 H28 117.5 . . ?
C30 C29 P1 113.9(11) . . ?
C30 C29 H29A 108.8 . . ?
P1 C29 H29A 108.8 . . ?
C30 C29 H29B 108.8 . . ?
P1 C29 H29B 108.8 . . ?
H29A C29 H29B 107.7 . . ?
C31 C30 C43 119.8(15) . . ?
C31 C30 C29 118.3(14) . . ?
C43 C30 C29 121.9(13) . . ?
C32 C31 C30 123.3(14) . . ?
C32 C31 C36 116.0(15) . . ?
C30 C31 C36 120.6(15) . . ?
C33 C32 C31 124.5(18) . . ?
C33 C32 H32 117.8 . . ?
C31 C32 H32 117.8 . . ?
C34 C33 C32 117(2) . . ?
C34 C33 H33 121.6 . . ?
C32 C33 H33 121.6 . . ?
C35 C34 C33 121(2) . . ?
C35 C34 H34 119.3 . . ?
C33 C34 H34 119.3 . . ?
C34 C35 C36 119(2) . . ?
C34 C35 H35 120.4 . . ?
C36 C35 H35 120.4 . . ?
C37 C36 C35 119.1(16) . . ?
C37 C36 C31 119.0(16) . . ?
C35 C36 C31 121.9(17) . . ?
C38 C37 C36 120.8(18) . . ?
C38 C37 H37 119.6 . . ?
C36 C37 H37 119.6 . . ?
C37 C38 C39 121.9(16) . . ?
C37 C38 C43 119.9(17) . . ?
C39 C38 C43 118.2(17) . . ?
C40 C39 C38 125(2) . . ?
C40 C39 H39 117.5 . . ?
C38 C39 H39 117.5 . . ?
C39 C40 C41 115(2) . . ?
C39 C40 H40 122.7 . . ?
C41 C40 H40 122.7 . . ?
C42 C41 C40 122(2) . . ?
C42 C41 H41 118.9 . . ?
C40 C41 H41 118.9 . . ?
C41 C42 C43 121.0(19) . . ?
C41 C42 H42 119.5 . . ?
C43 C42 H42 119.5 . . ?
C30 C43 C42 121.7(14) . . ?
C30 C43 C38 119.8(15) . . ?
C42 C43 C38 118.4(16) . . ?
C45 C44 P2 116.0(11) . . ?
C45 C44 H44A 108.3 . . ?
P2 C44 H44A 108.3 . . ?
C45 C44 H44B 108.3 . . ?
P2 C44 H44B 108.3 . . ?
H44A C44 H44B 107.4 . . ?
C46 C45 C58 118.5(16) . . ?
C46 C45 C44 121.0(15) . . ?
C58 C45 C44 120.4(14) . . ?
C45 C46 C47 121.7(15) . . ?
C45 C46 C51 120.8(17) . . ?
C47 C46 C51 117.6(17) . . ?
C48 C47 C46 121(2) . . ?
C48 C47 H47 119.5 . . ?
C46 C47 H47 119.5 . . ?
C49 C48 C47 118(2) . . ?
C49 C48 H48 121.1 . . ?
C47 C48 H48 121.1 . . ?
C50 C49 C48 125(3) . . ?
C50 C49 H49 117.5 . . ?
C48 C49 H49 117.5 . . ?
C49 C50 C51 114(2) . . ?
C49 C50 H50 123.0 . . ?
C51 C50 H50 123.0 . . ?
C50 C51 C52 116.2(18) . . ?
C50 C51 C46 125(2) . . ?
C52 C51 C46 119.0(19) . . ?
C53 C52 C51 122(2) . . ?
C53 C52 H52 119.2 . . ?
C51 C52 H52 119.2 . . ?
C52 C53 C54 118.9(17) . . ?
C52 C53 C58 118.0(18) . . ?
C54 C53 C58 123.0(18) . . ?
C55 C54 C53 119(2) . . ?
C55 C54 H54 120.4 . . ?
C53 C54 H54 120.4 . . ?
C54 C55 C56 120(2) . . ?
C54 C55 H55 120.2 . . ?
C56 C55 H55 120.2 . . ?
C57 C56 C55 119(2) . . ?
C57 C56 H56 120.3 . . ?
C55 C56 H56 120.3 . . ?
C56 C57 C58 122.7(19) . . ?
C56 C57 H57 118.7 . . ?
C58 C57 H57 118.7 . . ?
C57 C58 C45 122.0(14) . . ?
C57 C58 C53 115.9(16) . . ?
C45 C58 C53 122.0(16) . . ?
O12 C61 O11 126(2) . . ?
O12 C61 C62 117(3) . . ?
O11 C61 C62 117(2) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O20 C63 O19 121.7(12) . . ?
O20 C63 C64 120.5(13) . . ?
O19 C63 C64 117.6(13) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O18 C65 O17 117.6(15) . . ?
O18 C65 C66 122.4(13) . . ?
O17 C65 C66 120.0(14) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
O21 C67 O22 127.3(15) . . ?
O21 C67 C68 116.5(14) . . ?
O22 C67 C68 116.2(15) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O16 C69 O15 122.8(16) . . ?
O16 C69 C70 120.1(19) . . ?
O15 C69 C70 117.0(18) . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
O25 C71 O24 128.3(13) . . ?
O25 C71 C71 115.4(16) . 3_666 ?
O24 C71 C71 116.2(14) . 3_666 ?
O14 C77 O26 113(2) . . ?
O14 C77 C78 123.6(13) . . ?
O26 C77 C78 122.9(13) . . ?
C77 C78 H78A 109.5 . . ?
C77 C78 H78B 109.5 . . ?
H78A C78 H78B 109.5 . . ?
C77 C78 H78C 109.5 . . ?
H78A C78 H78C 109.5 . . ?
H78B C78 H78C 109.5 . . ?
C1 N1 C5 115.8(19) . . ?
C1 N1 Dy1 128.1(14) . . ?
C5 N1 Dy1 115.7(11) . . ?
C6 N2 N3 110.3(15) . . ?
C7 N3 N2 118.3(17) . . ?
C7 N3 Dy2 120.1(15) . . ?
N2 N3 Dy2 120.8(12) . . ?
C8 N4 N5 116.8(18) . . ?
C8 N4 Dy2 123.5(16) . . ?
N5 N4 Dy2 119.7(11) . . ?
C9 N5 N4 111.2(15) . . ?
C10 N6 C14 113.0(13) . . ?
C10 N6 Dy3 119.4(8) . . ?
C14 N6 Dy3 127.3(9) . . ?
C15 N7 C19 114.2(17) . . ?
C15 N7 Dy1 129.7(13) . . ?
C19 N7 Dy1 116.1(10) . . ?
C20 N8 N9 108.6(15) . . ?
C21 N9 N8 114.6(16) . . ?
C21 N9 Dy5 122.9(13) . . ?
N8 N9 Dy5 122.4(13) . . ?
C22 N10 N11 114.6(18) . . ?
C22 N10 Dy5 122.2(14) . . ?
N11 N10 Dy5 122.6(10) . . ?
C23 N11 N10 109.9(14) . . ?
C28 N12 C24 114.7(12) . . ?
C28 N12 Dy4 127.8(8) . . ?
C24 N12 Dy4 116.0(8) . . ?
C4 N13 C2 114(2) . . ?
C11 N14 C13 116.2(14) . . ?
C18 N15 C16 114.2(18) . . ?
C27 N16 C25 115.8(13) . . ?
C6 O1 Dy1 122.4(13) . . ?
C6 O1 Dy2 123.8(14) . . ?
Dy1 O1 Dy2 108.4(4) . . ?
C9 O2 Dy3 124.6(10) . . ?
C9 O2 Dy2 121.4(10) . . ?
Dy3 O2 Dy2 113.2(4) . . ?
C20 O3 Dy1 123.3(12) . . ?
C20 O3 Dy5 121.7(11) . . ?
Dy1 O3 Dy5 106.2(4) . . ?
C23 O4 Dy4 122.1(10) . . ?
C23 O4 Dy5 122.9(10) . . ?
Dy4 O4 Dy5 112.6(4) . . ?
P1 O5 Dy1 136.7(6) . . ?
P1 O5 Dy5 101.1(5) . . ?
Dy1 O5 Dy5 107.4(4) . . ?
P1 O6 Dy2 139.1(6) . . ?
P1 O7 Dy4 143.0(6) . . ?
P1 O7 Dy5 98.9(5) . . ?
Dy4 O7 Dy5 118.1(4) . . ?
P2 O8 Dy1 134.7(6) . . ?
P2 O8 Dy2 100.1(5) . . ?
Dy1 O8 Dy2 111.1(4) . . ?
P2 O9 Dy3 144.6(6) . . ?
P2 O9 Dy2 97.8(5) . . ?
Dy3 O9 Dy2 117.3(4) . . ?
P2 O10 Dy5 137.4(6) . . ?
C61 O11 Dy1 133.3(15) . . ?
C61 O12 Dy5 138.0(15) . . ?
C77 O14 Dy2 132.2(15) . . ?
C69 O15 Dy3 90.9(10) . . ?
C69 O16 Dy3 93.4(11) . . ?
C65 O17 Dy3 95.3(9) . . ?
C65 O18 Dy4 154.6(10) . . ?
C65 O18 Dy3 94.9(9) . . ?
Dy4 O18 Dy3 110.3(4) . . ?
C63 O19 Dy3 157.6(9) . . ?
C63 O19 Dy4 91.8(8) . . ?
Dy3 O19 Dy4 110.4(4) . . ?
C63 O20 Dy4 93.8(8) . . ?
C67 O21 Dy3 137.1(10) . . ?
C67 O22 Dy4 138.1(10) . . ?
C71 O24 Dy4 119.1(8) . . ?
C71 O25 Dy4 121.8(9) . 3_666 ?
Dy2 O1W H1WB 109.3 . . ?
Dy2 O1W H1WA 109.1 . . ?
H1WB O1W H1WA 109.5 . . ?
Dy5 O2W H2WA 109.1 . . ?
Dy5 O2W H2WB 109.5 . . ?
H2WA O2W H2WB 109.5 . . ?
Dy1 O3W H3WB 109.5 . . ?
Dy1 O3W H3WA 108.7 . . ?
H3WB O3W H3WA 109.5 . . ?
H14A O14W H14B 109.5 . . ?

_refine_diff_density_max         4.864
_refine_diff_density_min         -3.649
_refine_diff_density_rms         0.278

# start Validation Reply Form
_vrf_PLAT971_I-A-Ar-cool         
;
PROBLEM: Check Calcd Resid. Dens. 0.97A From Dy1 5.01 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT972_I-A-Ar-cool         
;
PROBLEM: Check Calcd Resid. Dens. 0.83A From Dy1 -3.55 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT973_I-A-Ar-cool         
;
PROBLEM: Check Calcd Positive Resid. Density on Dy4 2.40 eA-3
RESPONSE: These large residual are considered to be due largely to 
the effects of  the Dy metal itself and possibly contributed to 
by poor crystal quality or other effects.
;
_vrf_PLAT342_1                   
;
PROBLEM: Low Bond Precision on C-C Bonds ............... 0.02595 Ang.
RESPONSE: Moderate data quality in context with desolvation and there are 
disorder anthracene groups in the structure.
;
_vrf_PLAT430_1                   
;
PROBLEM: Short Inter D...A Contact O8W .. O17 .. 2.77 Ang.
RESPONSE: O8W, O4W, O5W, O6W, O7W, O9W, O10W, O11W, O12W and O13W are disorder 
lattcie water molecules in the structure. The occupancies of all these water 
molecules are refined as 0.5. The hydrogen atoms can not be determined by 
Fourier Map and omitted.
;
# end Validation Reply Form


_shelxl_version_number           2013-2

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I-A-N2
_database_code_depnum_ccdc_archive 'CCDC 1819931'
_audit_update_record             
;
2018-01-28 deposited with the CCDC.
2018-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C134 H116 Dy10 N32 O50 P4'
_chemical_formula_sum            'C134 H112 Dy10 N32 O50 P4'
_chemical_formula_weight         4719.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   25.525(6)
_cell_length_b                   14.312(4)
_cell_length_c                   25.318(6)
_cell_angle_alpha                90
_cell_angle_beta                 111.413(5)
_cell_angle_gamma                90
_cell_volume                     8610(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    373(2)
_cell_measurement_reflns_used    9972
_cell_measurement_theta_min      2.228
_cell_measurement_theta_max      26.334

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.820
_exptl_crystal_F_000             4520
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    4.402
_shelx_estimated_absorpt_T_min   0.352
_shelx_estimated_absorpt_T_max   0.473
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.330
_exptl_absorpt_correction_T_max  0.473
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      373(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'BRUKER D8'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            52072
_diffrn_reflns_av_unetI/netI     0.1743
_diffrn_reflns_av_R_equivalents  0.1488
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.012
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.994
_reflns_number_total             16839
_reflns_number_gt                7819
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+1003.6620P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16839
_refine_ls_number_parameters     1042
_refine_ls_number_restraints     940
_refine_ls_R_factor_all          0.2614
_refine_ls_R_factor_gt           0.1482
_refine_ls_wR_factor_ref         0.3499
_refine_ls_wR_factor_gt          0.2886
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

# start Validation Reply Form
_vrf_PLAT602_I-A-N2              
;
PROBLEM: VERY LARGE Solvent Accessible VOID(S) in Structure ! Info
RESPONSE: The data was collected at 373K under N2. Hence, the void is
almost empty.
;

# end Validation Reply Form


loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.67629(7) 0.74055(13) 0.41595(7) 0.0620(5) Uani 1 1 d . . . . .
Dy2 Dy 0.75208(7) 0.74056(12) 0.57908(7) 0.0576(5) Uani 1 1 d . . . . .
Dy3 Dy 0.82461(8) 0.49980(12) 0.64370(7) 0.0584(5) Uani 1 1 d . . . . .
Dy4 Dy 0.89929(7) 0.45417(11) 0.53676(6) 0.0506(4) Uani 1 1 d . . . . .
Dy5 Dy 0.75353(7) 0.51993(12) 0.40092(7) 0.0585(5) Uani 1 1 d . U . . .
P1 P 0.8215(3) 0.6749(6) 0.4870(3) 0.048(2) Uani 1 1 d . . . . .
P2 P 0.7055(4) 0.5507(7) 0.5132(4) 0.064(3) Uani 1 1 d . . . . .
C1 C 0.6478(19) 0.948(3) 0.3333(17) 0.099(7) Uani 1 1 d D U . . .
H1 H 0.6333 0.9088 0.3019 0.119 Uiso 1 1 calc R U . . .
C2 C 0.6445(19) 1.041(2) 0.3272(19) 0.103(7) Uani 1 1 d D U . . .
H2 H 0.6238 1.0654 0.2917 0.123 Uiso 1 1 calc R U . . .
C4 C 0.6950(19) 1.060(3) 0.4204(17) 0.100(7) Uani 1 1 d D U . . .
H4 H 0.7114 1.0992 0.4515 0.120 Uiso 1 1 calc R U . . .
C5 C 0.6991(19) 0.968(2) 0.4298(19) 0.098(7) Uani 1 1 d D U . . .
C6 C 0.7270(15) 0.922(4) 0.4866(15) 0.081(14) Uani 1 1 d . . . . .
C7 C 0.7795(18) 0.972(2) 0.6252(17) 0.080(12) Uani 1 1 d . . . . .
H7 H 0.7717 1.0355 0.6271 0.097 Uiso 1 1 calc R U . . .
C8 C 0.807(3) 0.921(3) 0.673(2) 0.12(2) Uani 1 1 d . . . . .
H8 H 0.8281 0.9515 0.7061 0.140 Uiso 1 1 calc R U . . .
C9 C 0.8454(15) 0.701(3) 0.7100(15) 0.060(9) Uani 1 1 d . . . . .
C10 C 0.8798(16) 0.6420(19) 0.7582(12) 0.068(6) Uani 1 1 d D U . . .
C11 C 0.9065(14) 0.676(2) 0.8116(10) 0.071(6) Uani 1 1 d D U . . .
H11 H 0.9044 0.7393 0.8177 0.085 Uiso 1 1 calc R U . . .
C13 C 0.9339(15) 0.528(2) 0.8439(13) 0.076(6) Uani 1 1 d D U . . .
H13 H 0.9520 0.4874 0.8735 0.091 Uiso 1 1 calc R U . . .
C14 C 0.9076(14) 0.491(2) 0.7916(10) 0.072(6) Uani 1 1 d D U . . .
H14 H 0.9089 0.4266 0.7858 0.086 Uiso 1 1 calc R U . . .
C15 C 0.5289(11) 0.765(2) 0.3446(16) 0.104(8) Uani 1 1 d D U . . .
H15 H 0.5347 0.8208 0.3644 0.125 Uiso 1 1 calc R U . . .
C16 C 0.4770(11) 0.744(2) 0.3059(17) 0.108(8) Uani 1 1 d D U . . .
H16 H 0.4476 0.7864 0.2986 0.129 Uiso 1 1 calc R U . . .
C18 C 0.5122(12) 0.602(2) 0.2850(16) 0.106(8) Uani 1 1 d D U . . .
H18 H 0.5070 0.5483 0.2630 0.127 Uiso 1 1 calc R U . . .
C19 C 0.5639(11) 0.622(2) 0.3242(17) 0.100(8) Uani 1 1 d D U . . .
C20 C 0.616(2) 0.566(3) 0.3389(19) 0.086(14) Uani 1 1 d . . . . .
C21 C 0.663(2) 0.377(3) 0.2947(18) 0.114(9) Uani 1 1 d D U . . .
H21 H 0.6317 0.3533 0.2656 0.137 Uiso 1 1 calc R U . . .
C22 C 0.7156(18) 0.331(3) 0.3114(17) 0.113(9) Uani 1 1 d D U . . .
H22 H 0.7180 0.2763 0.2923 0.136 Uiso 1 1 calc R U . . .
C23 C 0.8395(17) 0.336(2) 0.4212(14) 0.069(8) Uani 1 1 d . U . . .
C24 C 0.8929(14) 0.277(2) 0.4471(11) 0.063(5) Uani 1 1 d D U . . .
C25 C 0.9085(12) 0.215(2) 0.4154(15) 0.069(5) Uani 1 1 d D U . . .
H25 H 0.8863 0.2059 0.3774 0.082 Uiso 1 1 calc R U . . .
C27 C 0.9836(14) 0.170(2) 0.4959(11) 0.064(5) Uani 1 1 d D U . . .
H27 H 1.0119 0.1284 0.5150 0.076 Uiso 1 1 calc R U . . .
C28 C 0.9681(10) 0.2388(17) 0.5240(13) 0.051(5) Uani 1 1 d D U . . .
H28 H 0.9922 0.2509 0.5610 0.061 Uiso 1 1 calc R U . . .
C29 C 0.8751(15) 0.751(2) 0.4757(15) 0.065(6) Uani 1 1 d . U . . .
H29A H 0.9112 0.7387 0.5056 0.077 Uiso 1 1 calc R U . . .
H29B H 0.8785 0.7337 0.4400 0.077 Uiso 1 1 calc R U . . .
C30 C 0.8633(14) 0.8532(15) 0.4746(8) 0.068(5) Uani 1 1 d D U . . .
C31 C 0.8349(14) 0.8999(14) 0.4235(8) 0.067(5) Uani 1 1 d D U . . .
C32 C 0.8118(14) 0.8488(16) 0.3731(9) 0.068(5) Uani 1 1 d D U . . .
H32 H 0.8137 0.7839 0.3729 0.082 Uiso 1 1 calc R U . . .
C33 C 0.7859(15) 0.8996(16) 0.3231(10) 0.075(6) Uani 1 1 d D U . . .
H33 H 0.7712 0.8672 0.2890 0.090 Uiso 1 1 calc R U . . .
C34 C 0.7810(15) 0.9971(16) 0.3221(10) 0.077(6) Uani 1 1 d D U . . .
H34 H 0.7638 1.0294 0.2883 0.092 Uiso 1 1 calc R U . . .
C35 C 0.8029(15) 1.0437(16) 0.3741(9) 0.077(6) Uani 1 1 d D U . . .
H35 H 0.7995 1.1084 0.3745 0.093 Uiso 1 1 calc R U . . .
C36 C 0.8298(15) 0.9972(14) 0.4256(8) 0.072(5) Uani 1 1 d D U . . .
C37 C 0.8498(15) 1.0470(15) 0.4767(8) 0.077(5) Uani 1 1 d D U . . .
H37 H 0.8447 1.1113 0.4775 0.093 Uiso 1 1 calc R U . . .
C38 C 0.8776(16) 0.9968(15) 0.5265(8) 0.078(5) Uani 1 1 d D U . . .
C39 C 0.8961(16) 1.0492(16) 0.5768(10) 0.082(6) Uani 1 1 d D U . . .
H39 H 0.8917 1.1138 0.5760 0.099 Uiso 1 1 calc R U . . .
C40 C 0.9212(16) 1.0018(17) 0.6281(11) 0.084(6) Uani 1 1 d D U . . .
H40 H 0.9309 1.0349 0.6620 0.101 Uiso 1 1 calc R U . . .
C41 C 0.9322(16) 0.9058(17) 0.6299(11) 0.083(6) Uani 1 1 d D U . . .
H41 H 0.9514 0.8758 0.6641 0.099 Uiso 1 1 calc R U . . .
C42 C 0.9135(15) 0.8561(17) 0.5787(9) 0.079(6) Uani 1 1 d D U . . .
H42 H 0.9208 0.7924 0.5792 0.094 Uiso 1 1 calc R U . . .
C43 C 0.8840(15) 0.8997(15) 0.5268(8) 0.075(5) Uani 1 1 d D U . . .
C44 C 0.6435(18) 0.497(3) 0.522(2) 0.102(8) Uani 1 1 d . U . . .
H44A H 0.6522 0.4321 0.5313 0.122 Uiso 1 1 d R U . . .
H44B H 0.6423 0.5187 0.5582 0.122 Uiso 1 1 d R U . . .
C45 C 0.5904(13) 0.501(2) 0.4771(15) 0.103(6) Uani 1 1 d D U . . .
C46 C 0.5729(14) 0.438(2) 0.4321(16) 0.113(6) Uani 1 1 d D U . . .
C47 C 0.6076(14) 0.363(3) 0.4318(18) 0.118(7) Uani 1 1 d D U . . .
H47 H 0.6421 0.3582 0.4616 0.141 Uiso 1 1 calc R U . . .
C48 C 0.5945(16) 0.293(3) 0.3901(18) 0.126(8) Uani 1 1 d D U . . .
H48 H 0.6197 0.2465 0.3898 0.151 Uiso 1 1 calc R U . . .
C49 C 0.5404(16) 0.299(3) 0.3488(18) 0.128(8) Uani 1 1 d D U . . .
H49 H 0.5296 0.2534 0.3210 0.154 Uiso 1 1 calc R U . . .
C50 C 0.5012(15) 0.369(3) 0.3460(17) 0.127(7) Uani 1 1 d D U . . .
H50 H 0.4655 0.3708 0.3178 0.152 Uiso 1 1 calc R U . . .
C51 C 0.5198(14) 0.436(3) 0.3888(16) 0.120(6) Uani 1 1 d D U . . .
C52 C 0.4837(14) 0.508(3) 0.3920(16) 0.118(7) Uani 1 1 d D U . . .
H52 H 0.4479 0.5092 0.3640 0.141 Uiso 1 1 calc R U . . .
C53 C 0.4969(14) 0.577(3) 0.4336(16) 0.112(6) Uani 1 1 d D U . . .
C54 C 0.4600(14) 0.647(3) 0.4370(17) 0.114(7) Uani 1 1 d D U . . .
H54 H 0.4250 0.6538 0.4082 0.137 Uiso 1 1 calc R U . . .
C55 C 0.4764(15) 0.707(3) 0.4839(17) 0.117(7) Uani 1 1 d D U . . .
H55 H 0.4509 0.7497 0.4879 0.140 Uiso 1 1 calc R U . . .
C56 C 0.5307(15) 0.702(3) 0.5247(16) 0.114(7) Uani 1 1 d D U . . .
H56 H 0.5416 0.7419 0.5557 0.137 Uiso 1 1 calc R U . . .
C57 C 0.5685(14) 0.636(3) 0.5187(16) 0.110(7) Uani 1 1 d D U . . .
H57 H 0.6058 0.6366 0.5435 0.132 Uiso 1 1 calc R U . . .
C58 C 0.5504(14) 0.569(2) 0.4757(15) 0.107(6) Uani 1 1 d D U . . .
C59 C 0.6286(16) 0.849(2) 0.509(2) 0.074(12) Uani 1 1 d . . . . .
C60 C 0.587(2) 0.918(3) 0.516(2) 0.13(2) Uani 1 1 d . . . . .
H60A H 0.5934 0.9250 0.5560 0.193 Uiso 1 1 calc R U . . .
H60B H 0.5492 0.8946 0.4970 0.193 Uiso 1 1 calc R U . . .
H60C H 0.5909 0.9769 0.5006 0.193 Uiso 1 1 calc R U . . .
C61 C 0.696(2) 0.677(3) 0.3002(17) 0.084(10) Uani 1 1 d . U . . .
C62 C 0.674(2) 0.685(3) 0.2321(16) 0.097(11) Uani 1 1 d . U . . .
H62A H 0.7002 0.6550 0.2186 0.145 Uiso 1 1 calc R U . . .
H62B H 0.6698 0.7492 0.2210 0.145 Uiso 1 1 calc R U . . .
H62C H 0.6380 0.6540 0.2160 0.145 Uiso 1 1 calc R U . . .
C63 C 0.9405(13) 0.600(3) 0.6183(13) 0.054(7) Uani 1 1 d . U . . .
C64 C 0.9700(15) 0.652(3) 0.6723(14) 0.074(9) Uani 1 1 d . U . . .
H64A H 0.9919 0.7019 0.6653 0.111 Uiso 1 1 calc R U . . .
H64B H 0.9944 0.6101 0.6999 0.111 Uiso 1 1 calc R U . . .
H64C H 0.9428 0.6777 0.6862 0.111 Uiso 1 1 calc R U . . .
C65 C 0.7918(18) 0.347(3) 0.5679(16) 0.070(9) Uani 1 1 d . U . . .
C66 C 0.7740(17) 0.262(3) 0.5285(15) 0.082(10) Uani 1 1 d . U . . .
H66A H 0.7490 0.2814 0.4916 0.123 Uiso 1 1 calc R U . . .
H66B H 0.7552 0.2177 0.5439 0.123 Uiso 1 1 calc R U . . .
H66C H 0.8068 0.2332 0.5253 0.123 Uiso 1 1 calc R U . . .
C67 C 0.9237(19) 0.347(3) 0.6630(15) 0.082(10) Uani 1 1 d . U . . .
C68 C 0.9624(19) 0.277(3) 0.7040(16) 0.098(12) Uani 1 1 d . U . . .
H68A H 1.0008 0.2910 0.7095 0.147 Uiso 1 1 calc R U . . .
H68B H 0.9535 0.2148 0.6886 0.147 Uiso 1 1 calc R U . . .
H68C H 0.9573 0.2799 0.7397 0.147 Uiso 1 1 calc R U . . .
C69 C 0.7169(14) 0.597(3) 0.6655(11) 0.062(10) Uani 1 1 d . . . . .
C70 C 0.6680(17) 0.566(3) 0.6842(15) 0.093(15) Uani 1 1 d . . . . .
H70A H 0.6681 0.6038 0.7156 0.139 Uiso 1 1 calc R U . . .
H70B H 0.6730 0.5017 0.6955 0.139 Uiso 1 1 calc R U . . .
H70C H 0.6328 0.5736 0.6531 0.139 Uiso 1 1 calc R U . . .
C71 C 1.0223(13) 0.476(2) 0.5284(12) 0.052(6) Uani 1 1 d . U . . .
N1 N 0.6726(16) 0.912(2) 0.3855(14) 0.098(7) Uani 1 1 d D U . . .
N2 N 0.7415(14) 0.983(2) 0.5292(14) 0.078(9) Uani 1 1 d . . . . .
N3 N 0.7649(17) 0.928(2) 0.5769(13) 0.090(12) Uani 1 1 d . . . . .
N4 N 0.8043(15) 0.832(2) 0.6716(12) 0.080(10) Uani 1 1 d . . . . .
N5 N 0.8387(18) 0.786(2) 0.7209(13) 0.093(12) Uani 1 1 d . . . . .
N6 N 0.8793(12) 0.5488(17) 0.7481(11) 0.067(5) Uani 1 1 d D U . . .
N7 N 0.5722(10) 0.703(2) 0.3542(14) 0.100(7) Uani 1 1 d D U . . .
N8 N 0.6108(12) 0.503(3) 0.3029(15) 0.105(14) Uani 1 1 d D . . . .
N9 N 0.6600(14) 0.453(2) 0.3218(15) 0.112(10) Uani 1 1 d D U . . .
N10 N 0.7610(13) 0.360(2) 0.3522(14) 0.106(9) Uani 1 1 d D U . . .
N11 N 0.8099(13) 0.3086(18) 0.3720(12) 0.072(7) Uani 1 1 d D U . . .
N12 N 0.9208(10) 0.2914(17) 0.5033(10) 0.058(5) Uani 1 1 d D U . . .
N13 N 0.6693(16) 1.101(3) 0.3698(14) 0.102(7) Uani 1 1 d D U . . .
N14 N 0.9361(13) 0.6209(18) 0.8564(12) 0.074(6) Uani 1 1 d D U . . .
N15 N 0.4682(10) 0.660(2) 0.2782(14) 0.107(7) Uani 1 1 d D U . . .
N16 N 0.9565(11) 0.165(2) 0.4392(11) 0.072(5) Uani 1 1 d D U . . .
O1 O 0.7343(9) 0.8331(17) 0.4853(10) 0.063(6) Uani 1 1 d . . . . .
O2 O 0.8313(10) 0.6624(17) 0.6611(10) 0.067(7) Uani 1 1 d . . . . .
O3 O 0.6588(10) 0.5933(18) 0.3824(9) 0.066(7) Uani 1 1 d . . . . .
O4 O 0.8299(10) 0.3975(16) 0.4499(7) 0.058(6) Uani 1 1 d . . . . .
O5 O 0.7632(8) 0.6811(13) 0.4352(8) 0.046(5) Uani 1 1 d . . . . .
O6 O 0.8172(7) 0.7009(16) 0.5423(8) 0.050(6) Uani 1 1 d . . . . .
O7 O 0.8371(8) 0.5705(13) 0.4891(7) 0.043(5) Uani 1 1 d . . . . .
O8 O 0.6891(8) 0.6547(15) 0.4947(8) 0.050(5) Uani 1 1 d . . . . .
O9 O 0.7554(9) 0.5620(17) 0.5718(9) 0.065(6) Uani 1 1 d . . . . .
O10 O 0.7255(12) 0.4977(14) 0.4719(8) 0.075(8) Uani 1 1 d . . . . .
O11 O 0.6802(10) 0.7424(17) 0.3273(10) 0.068(6) Uani 1 1 d . U . . .
O12 O 0.7284(11) 0.6069(18) 0.3187(9) 0.073(7) Uani 1 1 d . U . . .
O13 O 0.6182(10) 0.8171(19) 0.4555(11) 0.070(7) Uani 1 1 d . . . . .
O14 O 0.6671(11) 0.8109(19) 0.5513(11) 0.079(8) Uani 1 1 d . . . . .
O15 O 0.7579(13) 0.5298(18) 0.6804(10) 0.084(8) Uani 1 1 d . . . . .
O16 O 0.7106(13) 0.671(2) 0.6380(11) 0.092(9) Uani 1 1 d . . . . .
O17 O 0.7699(10) 0.3629(19) 0.6064(10) 0.079(8) Uani 1 1 d . . . . .
O18 O 0.8250(10) 0.4082(17) 0.5630(9) 0.063(6) Uani 1 1 d . . . . .
O19 O 0.8966(10) 0.5468(15) 0.6174(9) 0.065(6) Uani 1 1 d . U . . .
O20 O 0.9515(9) 0.6010(15) 0.5763(10) 0.055(6) Uani 1 1 d . . . . .
O21 O 0.8919(11) 0.3873(18) 0.6816(9) 0.071(7) Uani 1 1 d . U . . .
O22 O 0.9346(12) 0.361(2) 0.6200(10) 0.086(9) Uani 1 1 d . U . . .
O24 O 0.9993(9) 0.4366(16) 0.5605(9) 0.059(5) Uani 1 1 d . U . . .
O25 O 0.9290(7) 0.5040(16) 0.4617(9) 0.054(6) Uani 1 1 d . . . . .
O1W O 0.8345(10) 0.5454(18) 0.3728(13) 0.089(8) Uani 1 1 d . U . . .
H1WB H 0.8235 0.5728 0.3408 0.133 Uiso 1 1 d R U . . .
H1WA H 0.8585 0.5796 0.3974 0.133 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O3 2.25(3) . ?
Dy1 O5 2.26(2) . ?
Dy1 O8 2.262(19) . ?
Dy1 O1 2.27(3) . ?
Dy1 O11 2.28(2) . ?
Dy1 O13 2.34(3) . ?
Dy1 N1 2.56(3) . ?
Dy1 N7 2.60(2) . ?
Dy2 O6 2.253(18) . ?
Dy2 O14 2.26(3) . ?
Dy2 O16 2.34(3) . ?
Dy2 O8 2.48(2) . ?
Dy2 O9 2.57(2) . ?
Dy2 O2 2.57(3) . ?
Dy2 N4 2.59(3) . ?
Dy2 O1 2.61(2) . ?
Dy2 N3 2.71(4) . ?
Dy3 O9 2.21(2) . ?
Dy3 O15 2.26(3) . ?
Dy3 O19 2.27(2) . ?
Dy3 O21 2.29(3) . ?
Dy3 O2 2.36(2) . ?
Dy3 O17 2.39(2) . ?
Dy3 O18 2.43(2) . ?
Dy3 N6 2.59(3) . ?
Dy4 O7 2.31(2) . ?
Dy4 O18 2.32(2) . ?
Dy4 O22 2.38(2) . ?
Dy4 O25 2.40(2) . ?
Dy4 O4 2.41(2) . ?
Dy4 O24 2.41(2) . ?
Dy4 O19 2.46(2) . ?
Dy4 O20 2.49(2) . ?
Dy4 N12 2.61(2) . ?
Dy5 O10 2.19(2) . ?
Dy5 O12 2.31(2) . ?
Dy5 O1W 2.45(3) . ?
Dy5 O5 2.445(19) . ?
Dy5 O3 2.52(2) . ?
Dy5 O7 2.565(18) . ?
Dy5 O4 2.58(2) . ?
Dy5 N10 2.64(3) . ?
Dy5 N9 2.67(3) . ?
P1 O6 1.491(19) . ?
P1 O7 1.54(2) . ?
P1 O5 1.587(19) . ?
P1 C29 1.85(3) . ?
P2 O10 1.52(2) . ?
P2 O8 1.57(2) . ?
P2 O9 1.57(2) . ?
P2 C44 1.84(4) . ?
C1 N1 1.342(17) . ?
C1 C2 1.343(17) . ?
C1 H1 0.9300 . ?
C2 N13 1.342(17) . ?
C2 H2 0.9300 . ?
C4 N13 1.341(17) . ?
C4 C5 1.342(17) . ?
C4 H4 0.9300 . ?
C5 N1 1.342(17) . ?
C5 C6 1.50(5) . ?
C6 O1 1.29(5) . ?
C6 N2 1.33(5) . ?
C7 N3 1.30(4) . ?
C7 C8 1.36(6) . ?
C7 H7 0.9300 . ?
C8 N4 1.28(5) . ?
C8 H8 0.9300 . ?
C9 N5 1.27(4) . ?
C9 O2 1.28(4) . ?
C9 C10 1.48(5) . ?
C10 N6 1.358(15) . ?
C10 C11 1.359(15) . ?
C11 N14 1.358(14) . ?
C11 H11 0.9300 . ?
C13 C14 1.358(15) . ?
C13 N14 1.359(15) . ?
C13 H13 0.9300 . ?
C14 N6 1.361(14) . ?
C14 H14 0.9300 . ?
C15 C16 1.362(15) . ?
C15 N7 1.362(15) . ?
C15 H15 0.9300 . ?
C16 N15 1.362(15) . ?
C16 H16 0.9300 . ?
C18 N15 1.360(15) . ?
C18 C19 1.362(15) . ?
C18 H18 0.9300 . ?
C19 N7 1.361(15) . ?
C19 C20 1.48(5) . ?
C20 N8 1.25(5) . ?
C20 O3 1.30(5) . ?
C21 N9 1.31(3) . ?
C21 C22 1.41(6) . ?
C21 H21 0.9300 . ?
C22 N10 1.31(3) . ?
C22 H22 0.9300 . ?
C23 O4 1.23(4) . ?
C23 N11 1.26(4) . ?
C23 C24 1.53(5) . ?
C24 N12 1.353(14) . ?
C24 C25 1.354(14) . ?
C25 N16 1.351(14) . ?
C25 H25 0.9300 . ?
C27 C28 1.350(14) . ?
C27 N16 1.350(14) . ?
C27 H27 0.9300 . ?
C28 N12 1.355(14) . ?
C28 H28 0.9300 . ?
C29 C30 1.49(4) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 C43 1.400(9) . ?
C30 C31 1.401(9) . ?
C31 C32 1.400(9) . ?
C31 C36 1.401(9) . ?
C32 C33 1.399(9) . ?
C32 H32 0.9300 . ?
C33 C34 1.400(9) . ?
C33 H33 0.9300 . ?
C34 C35 1.397(9) . ?
C34 H34 0.9300 . ?
C35 C36 1.401(9) . ?
C35 H35 0.9300 . ?
C36 C37 1.399(9) . ?
C37 C38 1.399(9) . ?
C37 H37 0.9300 . ?
C38 C43 1.399(9) . ?
C38 C39 1.403(9) . ?
C39 C40 1.397(9) . ?
C39 H39 0.9300 . ?
C40 C41 1.400(9) . ?
C40 H40 0.9300 . ?
C41 C42 1.400(9) . ?
C41 H41 0.9300 . ?
C42 C43 1.400(9) . ?
C42 H42 0.9300 . ?
C44 C45 1.42(5) . ?
C44 H44A 0.9699 . ?
C44 H44B 0.9703 . ?
C45 C46 1.396(11) . ?
C45 C58 1.397(11) . ?
C46 C51 1.397(11) . ?
C46 C47 1.397(11) . ?
C47 C48 1.398(11) . ?
C47 H47 0.9300 . ?
C48 C49 1.397(11) . ?
C48 H48 0.9300 . ?
C49 C50 1.396(11) . ?
C49 H49 0.9300 . ?
C50 C51 1.397(11) . ?
C50 H50 0.9300 . ?
C51 C52 1.398(11) . ?
C52 C53 1.397(11) . ?
C52 H52 0.9300 . ?
C53 C58 1.396(11) . ?
C53 C54 1.397(10) . ?
C54 C55 1.396(11) . ?
C54 H54 0.9300 . ?
C55 C56 1.396(11) . ?
C55 H55 0.9300 . ?
C56 C57 1.396(11) . ?
C56 H56 0.9300 . ?
C57 C58 1.398(11) . ?
C57 H57 0.9300 . ?
C59 O14 1.28(5) . ?
C59 O13 1.37(5) . ?
C59 C60 1.51(5) . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
C61 O12 1.28(5) . ?
C61 O11 1.30(5) . ?
C61 C62 1.61(5) . ?
C62 H62A 0.9600 . ?
C62 H62B 0.9600 . ?
C62 H62C 0.9600 . ?
C63 O20 1.19(3) . ?
C63 O19 1.35(4) . ?
C63 C64 1.49(5) . ?
C64 H64A 0.9600 . ?
C64 H64B 0.9600 . ?
C64 H64C 0.9600 . ?
C65 O18 1.25(4) . ?
C65 O17 1.31(4) . ?
C65 C66 1.54(5) . ?
C66 H66A 0.9600 . ?
C66 H66B 0.9600 . ?
C66 H66C 0.9600 . ?
C67 O21 1.22(4) . ?
C67 O22 1.23(5) . ?
C67 C68 1.52(5) . ?
C68 H68A 0.9600 . ?
C68 H68B 0.9600 . ?
C68 H68C 0.9600 . ?
C69 O16 1.24(5) . ?
C69 O15 1.37(4) . ?
C69 C70 1.55(5) . ?
C70 H70A 0.9600 . ?
C70 H70B 0.9600 . ?
C70 H70C 0.9600 . ?
C71 O25 1.21(4) 3_766 ?
C71 O24 1.29(4) . ?
C71 C71 1.62(6) 3_766 ?
N2 N3 1.38(4) . ?
N4 N5 1.40(4) . ?
N8 N9 1.373(14) . ?
N10 N11 1.374(10) . ?
O25 C71 1.21(4) 3_766 ?
O1W H1WB 0.8499 . ?
O1W H1WA 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Dy1 O5 76.9(8) . . ?
O3 Dy1 O8 76.6(8) . . ?
O5 Dy1 O8 77.9(7) . . ?
O3 Dy1 O1 145.3(8) . . ?
O5 Dy1 O1 74.9(7) . . ?
O8 Dy1 O1 78.0(8) . . ?
O3 Dy1 O11 73.4(8) . . ?
O5 Dy1 O11 79.9(7) . . ?
O8 Dy1 O11 146.0(8) . . ?
O1 Dy1 O11 120.3(9) . . ?
O3 Dy1 O13 121.9(9) . . ?
O5 Dy1 O13 144.1(8) . . ?
O8 Dy1 O13 77.7(8) . . ?
O1 Dy1 O13 74.5(9) . . ?
O11 Dy1 O13 132.6(8) . . ?
O3 Dy1 N1 143.2(9) . . ?
O5 Dy1 N1 110.6(10) . . ?
O8 Dy1 N1 139.7(10) . . ?
O1 Dy1 N1 67.4(9) . . ?
O11 Dy1 N1 72.7(10) . . ?
O13 Dy1 N1 73.8(10) . . ?
O3 Dy1 N7 64.1(9) . . ?
O5 Dy1 N7 139.6(8) . . ?
O8 Dy1 N7 101.9(10) . . ?
O1 Dy1 N7 145.2(9) . . ?
O11 Dy1 N7 79.2(10) . . ?
O13 Dy1 N7 71.6(10) . . ?
N1 Dy1 N7 95.6(11) . . ?
O6 Dy2 O14 138.8(9) . . ?
O6 Dy2 O16 136.7(10) . . ?
O14 Dy2 O16 77.4(11) . . ?
O6 Dy2 O8 82.1(6) . . ?
O14 Dy2 O8 72.9(8) . . ?
O16 Dy2 O8 92.1(8) . . ?
O6 Dy2 O9 70.7(8) . . ?
O14 Dy2 O9 118.4(9) . . ?
O16 Dy2 O9 69.9(9) . . ?
O8 Dy2 O9 58.2(7) . . ?
O6 Dy2 O2 75.1(7) . . ?
O14 Dy2 O2 146.1(9) . . ?
O16 Dy2 O2 72.8(9) . . ?
O8 Dy2 O2 123.5(7) . . ?
O9 Dy2 O2 65.6(7) . . ?
O6 Dy2 N4 106.7(9) . . ?
O14 Dy2 N4 100.1(10) . . ?
O16 Dy2 N4 80.8(11) . . ?
O8 Dy2 N4 171.1(9) . . ?
O9 Dy2 N4 123.2(9) . . ?
O2 Dy2 N4 59.6(9) . . ?
O6 Dy2 O1 70.2(7) . . ?
O14 Dy2 O1 70.3(8) . . ?
O16 Dy2 O1 145.7(9) . . ?
O8 Dy2 O1 68.0(7) . . ?
O9 Dy2 O1 116.0(8) . . ?
O2 Dy2 O1 141.4(7) . . ?
N4 Dy2 O1 115.5(9) . . ?
O6 Dy2 N3 97.4(10) . . ?
O14 Dy2 N3 70.2(11) . . ?
O16 Dy2 N3 121.4(10) . . ?
O8 Dy2 N3 121.3(9) . . ?
O9 Dy2 N3 168.1(9) . . ?
O2 Dy2 N3 112.5(10) . . ?
N4 Dy2 N3 59.5(10) . . ?
O1 Dy2 N3 57.3(8) . . ?
O9 Dy3 O15 76.5(9) . . ?
O9 Dy3 O19 97.3(8) . . ?
O15 Dy3 O19 151.1(8) . . ?
O9 Dy3 O21 151.5(8) . . ?
O15 Dy3 O21 121.6(9) . . ?
O19 Dy3 O21 76.6(8) . . ?
O9 Dy3 O2 74.8(8) . . ?
O15 Dy3 O2 75.5(8) . . ?
O19 Dy3 O2 75.6(8) . . ?
O21 Dy3 O2 128.4(9) . . ?
O9 Dy3 O17 80.1(9) . . ?
O15 Dy3 O17 84.2(10) . . ?
O19 Dy3 O17 123.1(9) . . ?
O21 Dy3 O17 80.2(9) . . ?
O2 Dy3 O17 150.8(9) . . ?
O9 Dy3 O18 76.8(8) . . ?
O15 Dy3 O18 133.1(9) . . ?
O19 Dy3 O18 70.3(8) . . ?
O21 Dy3 O18 75.0(8) . . ?
O2 Dy3 O18 131.7(8) . . ?
O17 Dy3 O18 53.7(9) . . ?
O9 Dy3 N6 134.6(8) . . ?
O15 Dy3 N6 74.7(9) . . ?
O19 Dy3 N6 91.5(9) . . ?
O21 Dy3 N6 73.8(8) . . ?
O2 Dy3 N6 64.4(8) . . ?
O17 Dy3 N6 130.0(8) . . ?
O18 Dy3 N6 146.8(8) . . ?
O7 Dy4 O18 82.9(7) . . ?
O7 Dy4 O22 146.4(8) . . ?
O18 Dy4 O22 70.8(9) . . ?
O7 Dy4 O25 74.2(6) . . ?
O18 Dy4 O25 147.0(7) . . ?
O22 Dy4 O25 137.9(8) . . ?
O7 Dy4 O4 68.2(7) . . ?
O18 Dy4 O4 76.1(8) . . ?
O22 Dy4 O4 122.3(9) . . ?
O25 Dy4 O4 73.5(7) . . ?
O7 Dy4 O24 131.9(7) . . ?
O18 Dy4 O24 143.1(8) . . ?
O22 Dy4 O24 72.3(9) . . ?
O25 Dy4 O24 67.4(7) . . ?
O4 Dy4 O24 123.5(7) . . ?
O7 Dy4 O19 79.8(7) . . ?
O18 Dy4 O19 69.0(8) . . ?
O22 Dy4 O19 71.6(8) . . ?
O25 Dy4 O19 127.7(8) . . ?
O4 Dy4 O19 135.0(8) . . ?
O24 Dy4 O19 101.4(8) . . ?
O7 Dy4 O20 76.5(7) . . ?
O18 Dy4 O20 119.8(8) . . ?
O22 Dy4 O20 98.3(9) . . ?
O25 Dy4 O20 77.9(7) . . ?
O4 Dy4 O20 139.3(7) . . ?
O24 Dy4 O20 68.1(7) . . ?
O19 Dy4 O20 52.0(7) . . ?
O7 Dy4 N12 131.3(6) . . ?
O18 Dy4 N12 97.5(8) . . ?
O22 Dy4 N12 74.3(8) . . ?
O25 Dy4 N12 80.9(8) . . ?
O4 Dy4 N12 64.8(7) . . ?
O24 Dy4 N12 70.0(7) . . ?
O19 Dy4 N12 145.7(7) . . ?
O20 Dy4 N12 137.6(7) . . ?
O10 Dy5 O12 138.9(9) . . ?
O10 Dy5 O1W 145.7(10) . . ?
O12 Dy5 O1W 69.1(9) . . ?
O10 Dy5 O5 82.3(7) . . ?
O12 Dy5 O5 76.7(7) . . ?
O1W Dy5 O5 88.7(8) . . ?
O10 Dy5 O3 68.5(8) . . ?
O12 Dy5 O3 71.1(8) . . ?
O1W Dy5 O3 137.7(8) . . ?
O5 Dy5 O3 68.8(7) . . ?
O10 Dy5 O7 75.2(8) . . ?
O12 Dy5 O7 120.1(8) . . ?
O1W Dy5 O7 71.9(8) . . ?
O5 Dy5 O7 58.7(6) . . ?
O3 Dy5 O7 118.8(7) . . ?
O10 Dy5 O4 85.6(8) . . ?
O12 Dy5 O4 135.5(8) . . ?
O1W Dy5 O4 70.8(8) . . ?
O5 Dy5 O4 120.7(6) . . ?
O3 Dy5 O4 151.5(7) . . ?
O7 Dy5 O4 62.0(7) . . ?
O10 Dy5 N10 111.0(11) . . ?
O12 Dy5 N10 95.2(10) . . ?
O1W Dy5 N10 77.3(11) . . ?
O5 Dy5 N10 165.7(10) . . ?
O3 Dy5 N10 120.2(9) . . ?
O7 Dy5 N10 118.2(7) . . ?
O4 Dy5 N10 57.6(7) . . ?
O10 Dy5 N9 95.3(12) . . ?
O12 Dy5 N9 68.8(11) . . ?
O1W Dy5 N9 117.0(11) . . ?
O5 Dy5 N9 123.5(8) . . ?
O3 Dy5 N9 58.4(9) . . ?
O7 Dy5 N9 170.1(10) . . ?
O4 Dy5 N9 115.3(9) . . ?
N10 Dy5 N9 62.3(10) . . ?
O6 P1 O7 108.4(12) . . ?
O6 P1 O5 113.1(12) . . ?
O7 P1 O5 103.6(11) . . ?
O6 P1 C29 108.2(14) . . ?
O7 P1 C29 112.2(14) . . ?
O5 P1 C29 111.3(14) . . ?
O10 P2 O8 112.7(12) . . ?
O10 P2 O9 109.8(15) . . ?
O8 P2 O9 102.7(13) . . ?
O10 P2 C44 113(2) . . ?
O8 P2 C44 106.3(19) . . ?
O9 P2 C44 111.2(18) . . ?
N1 C1 C2 119(4) . . ?
N1 C1 H1 120.7 . . ?
C2 C1 H1 120.7 . . ?
N13 C2 C1 124(4) . . ?
N13 C2 H2 118.2 . . ?
C1 C2 H2 118.2 . . ?
N13 C4 C5 125(4) . . ?
N13 C4 H4 117.4 . . ?
C5 C4 H4 117.4 . . ?
N1 C5 C4 117(4) . . ?
N1 C5 C6 118(3) . . ?
C4 C5 C6 125(4) . . ?
O1 C6 N2 132(4) . . ?
O1 C6 C5 115(3) . . ?
N2 C6 C5 113(4) . . ?
N3 C7 C8 116(4) . . ?
N3 C7 H7 121.8 . . ?
C8 C7 H7 121.8 . . ?
N4 C8 C7 121(4) . . ?
N4 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
N5 C9 O2 128(4) . . ?
N5 C9 C10 117(3) . . ?
O2 C9 C10 115(3) . . ?
N6 C10 C11 120(3) . . ?
N6 C10 C9 116(2) . . ?
C11 C10 C9 123(2) . . ?
N14 C11 C10 123(3) . . ?
N14 C11 H11 118.3 . . ?
C10 C11 H11 118.3 . . ?
C14 C13 N14 125(3) . . ?
C14 C13 H13 117.3 . . ?
N14 C13 H13 117.3 . . ?
C13 C14 N6 118(3) . . ?
C13 C14 H14 120.9 . . ?
N6 C14 H14 120.9 . . ?
C16 C15 N7 120.1(4) . . ?
C16 C15 H15 120.0 . . ?
N7 C15 H15 120.0 . . ?
C15 C16 N15 119.8(5) . . ?
C15 C16 H16 120.1 . . ?
N15 C16 H16 120.1 . . ?
N15 C18 C19 119.9(5) . . ?
N15 C18 H18 120.1 . . ?
C19 C18 H18 120.1 . . ?
N7 C19 C18 120.1(5) . . ?
N7 C19 C20 113(3) . . ?
C18 C19 C20 127(3) . . ?
N8 C20 O3 132(4) . . ?
N8 C20 C19 111(4) . . ?
O3 C20 C19 117(3) . . ?
N9 C21 C22 118(4) . . ?
N9 C21 H21 121.2 . . ?
C22 C21 H21 121.2 . . ?
N10 C22 C21 124(4) . . ?
N10 C22 H22 118.0 . . ?
C21 C22 H22 118.0 . . ?
O4 C23 N11 129(4) . . ?
O4 C23 C24 119(3) . . ?
N11 C23 C24 112(3) . . ?
N12 C24 C25 124(3) . . ?
N12 C24 C23 114(2) . . ?
C25 C24 C23 121(2) . . ?
N16 C25 C24 120(3) . . ?
N16 C25 H25 120.1 . . ?
C24 C25 H25 120.1 . . ?
C28 C27 N16 118(3) . . ?
C28 C27 H27 121.1 . . ?
N16 C27 H27 121.1 . . ?
C27 C28 N12 126(3) . . ?
C27 C28 H28 117.0 . . ?
N12 C28 H28 117.0 . . ?
C30 C29 P1 115(3) . . ?
C30 C29 H29A 108.5 . . ?
P1 C29 H29A 108.5 . . ?
C30 C29 H29B 108.5 . . ?
P1 C29 H29B 108.5 . . ?
H29A C29 H29B 107.5 . . ?
C43 C30 C31 122.3(18) . . ?
C43 C30 C29 116(2) . . ?
C31 C30 C29 121(2) . . ?
C32 C31 C30 119.7(18) . . ?
C32 C31 C36 123(2) . . ?
C30 C31 C36 117.5(18) . . ?
C33 C32 C31 117(2) . . ?
C33 C32 H32 121.5 . . ?
C31 C32 H32 121.5 . . ?
C32 C33 C34 123(2) . . ?
C32 C33 H33 118.5 . . ?
C34 C33 H33 118.5 . . ?
C35 C34 C33 117(2) . . ?
C35 C34 H34 121.4 . . ?
C33 C34 H34 121.4 . . ?
C34 C35 C36 123(2) . . ?
C34 C35 H35 118.6 . . ?
C36 C35 H35 118.6 . . ?
C37 C36 C31 122.4(18) . . ?
C37 C36 C35 120.5(18) . . ?
C31 C36 C35 117(2) . . ?
C38 C37 C36 117.7(18) . . ?
C38 C37 H37 121.2 . . ?
C36 C37 H37 121.2 . . ?
C37 C38 C43 122.4(18) . . ?
C37 C38 C39 115.8(19) . . ?
C43 C38 C39 122(2) . . ?
C40 C39 C38 118(2) . . ?
C40 C39 H39 120.9 . . ?
C38 C39 H39 120.9 . . ?
C39 C40 C41 122(2) . . ?
C39 C40 H40 119.2 . . ?
C41 C40 H40 119.2 . . ?
C40 C41 C42 118(2) . . ?
C40 C41 H41 120.9 . . ?
C42 C41 H41 120.9 . . ?
C41 C42 C43 122(2) . . ?
C41 C42 H42 119.1 . . ?
C43 C42 H42 119.1 . . ?
C38 C43 C42 118(2) . . ?
C38 C43 C30 117.6(18) . . ?
C42 C43 C30 124.2(19) . . ?
C45 C44 P2 120(3) . . ?
C45 C44 H44A 107.2 . . ?
P2 C44 H44A 107.1 . . ?
C45 C44 H44B 113.3 . . ?
P2 C44 H44B 108.1 . . ?
H44A C44 H44B 99.5 . . ?
C46 C45 C58 115(3) . . ?
C46 C45 C44 124(3) . . ?
C58 C45 C44 121(3) . . ?
C45 C46 C51 125(3) . . ?
C45 C46 C47 119(3) . . ?
C51 C46 C47 115(3) . . ?
C46 C47 C48 125(3) . . ?
C46 C47 H47 117.4 . . ?
C48 C47 H47 117.4 . . ?
C49 C48 C47 115(3) . . ?
C49 C48 H48 122.7 . . ?
C47 C48 H48 122.7 . . ?
C50 C49 C48 125(3) . . ?
C50 C49 H49 117.3 . . ?
C48 C49 H49 117.3 . . ?
C49 C50 C51 115(3) . . ?
C49 C50 H50 122.6 . . ?
C51 C50 H50 122.6 . . ?
C46 C51 C50 125(3) . . ?
C46 C51 C52 115(3) . . ?
C50 C51 C52 120(3) . . ?
C53 C52 C51 125(3) . . ?
C53 C52 H52 117.3 . . ?
C51 C52 H52 117.3 . . ?
C58 C53 C54 120(3) . . ?
C58 C53 C52 114(3) . . ?
C54 C53 C52 125(3) . . ?
C55 C54 C53 119(3) . . ?
C55 C54 H54 120.3 . . ?
C53 C54 H54 120.3 . . ?
C54 C55 C56 120(3) . . ?
C54 C55 H55 119.8 . . ?
C56 C55 H55 119.8 . . ?
C57 C56 C55 119(3) . . ?
C57 C56 H56 120.3 . . ?
C55 C56 H56 120.3 . . ?
C56 C57 C58 120(3) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 H57 119.9 . . ?
C53 C58 C45 125(3) . . ?
C53 C58 C57 119(3) . . ?
C45 C58 C57 115(3) . . ?
O14 C59 O13 120(3) . . ?
O14 C59 C60 123(5) . . ?
O13 C59 C60 117(4) . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
O12 C61 O11 131(4) . . ?
O12 C61 C62 112(4) . . ?
O11 C61 C62 117(4) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O20 C63 O19 117(3) . . ?
O20 C63 C64 127(3) . . ?
O19 C63 C64 116(3) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O18 C65 O17 117(3) . . ?
O18 C65 C66 123(3) . . ?
O17 C65 C66 121(4) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
O21 C67 O22 131(4) . . ?
O21 C67 C68 114(4) . . ?
O22 C67 C68 114(4) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
O16 C69 O15 133(3) . . ?
O16 C69 C70 118(4) . . ?
O15 C69 C70 109(4) . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
O25 C71 O24 130(3) 3_766 . ?
O25 C71 C71 115(4) 3_766 3_766 ?
O24 C71 C71 114(4) . 3_766 ?
C5 N1 C1 121(4) . . ?
C5 N1 Dy1 111(2) . . ?
C1 N1 Dy1 128(3) . . ?
C6 N2 N3 104(3) . . ?
C7 N3 N2 115(3) . . ?
C7 N3 Dy2 117(3) . . ?
N2 N3 Dy2 125(2) . . ?
C8 N4 N5 116(4) . . ?
C8 N4 Dy2 122(3) . . ?
N5 N4 Dy2 122(2) . . ?
C9 N5 N4 110(3) . . ?
C10 N6 C14 119(3) . . ?
C10 N6 Dy3 115.0(17) . . ?
C14 N6 Dy3 126.1(19) . . ?
C19 N7 C15 119.8(5) . . ?
C19 N7 Dy1 115.3(15) . . ?
C15 N7 Dy1 124.2(15) . . ?
C20 N8 N9 106(3) . . ?
C21 N9 N8 118(3) . . ?
C21 N9 Dy5 119(3) . . ?
N8 N9 Dy5 122(2) . . ?
C22 N10 N11 123(4) . . ?
C22 N10 Dy5 117(3) . . ?
N11 N10 Dy5 120.1(18) . . ?
C23 N11 N10 110(3) . . ?
C24 N12 C28 112(3) . . ?
C24 N12 Dy4 112.6(17) . . ?
C28 N12 Dy4 129.4(17) . . ?
C4 N13 C2 114(4) . . ?
C11 N14 C13 114(3) . . ?
C18 N15 C16 120.0(6) . . ?
C27 N16 C25 118(3) . . ?
C6 O1 Dy1 123(2) . . ?
C6 O1 Dy2 117(2) . . ?
Dy1 O1 Dy2 104.8(9) . . ?
C9 O2 Dy3 126(2) . . ?
C9 O2 Dy2 117(2) . . ?
Dy3 O2 Dy2 107.2(8) . . ?
C20 O3 Dy1 126(3) . . ?
C20 O3 Dy5 119(3) . . ?
Dy1 O3 Dy5 106.0(9) . . ?
C23 O4 Dy4 123(2) . . ?
C23 O4 Dy5 119(2) . . ?
Dy4 O4 Dy5 112.7(8) . . ?
P1 O5 Dy1 138.7(12) . . ?
P1 O5 Dy5 100.6(9) . . ?
Dy1 O5 Dy5 108.4(7) . . ?
P1 O6 Dy2 140.3(11) . . ?
P1 O7 Dy4 146.6(11) . . ?
P1 O7 Dy5 97.0(10) . . ?
Dy4 O7 Dy5 116.4(7) . . ?
P2 O8 Dy1 135.6(13) . . ?
P2 O8 Dy2 101.2(10) . . ?
Dy1 O8 Dy2 109.2(8) . . ?
P2 O9 Dy3 149.9(15) . . ?
P2 O9 Dy2 97.7(12) . . ?
Dy3 O9 Dy2 112.3(9) . . ?
P2 O10 Dy5 141.7(13) . . ?
C61 O11 Dy1 130(2) . . ?
C61 O12 Dy5 133(3) . . ?
C59 O13 Dy1 131(2) . . ?
C59 O14 Dy2 144(3) . . ?
C69 O15 Dy3 129(2) . . ?
C69 O16 Dy2 136(3) . . ?
C65 O17 Dy3 95(2) . . ?
C65 O18 Dy4 151(2) . . ?
C65 O18 Dy3 95(2) . . ?
Dy4 O18 Dy3 110.0(10) . . ?
C63 O19 Dy3 157(2) . . ?
C63 O19 Dy4 92.6(19) . . ?
Dy3 O19 Dy4 110.8(9) . . ?
C63 O20 Dy4 95(2) . . ?
C67 O21 Dy3 132(2) . . ?
C67 O22 Dy4 138(3) . . ?
C71 O24 Dy4 118.7(19) . . ?
C71 O25 Dy4 120(2) 3_766 . ?
Dy5 O1W H1WB 109.0 . . ?
Dy5 O1W H1WA 109.3 . . ?
H1WB O1W H1WA 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 N13 7(8) . . . . ?
N13 C4 C5 N1 -4(8) . . . . ?
N13 C4 C5 C6 -179(4) . . . . ?
N1 C5 C6 O1 16(6) . . . . ?
C4 C5 C6 O1 -169(5) . . . . ?
N1 C5 C6 N2 -167(4) . . . . ?
C4 C5 C6 N2 8(7) . . . . ?
N3 C7 C8 N4 -19(8) . . . . ?
N5 C9 C10 N6 170(4) . . . . ?
O2 C9 C10 N6 -18(5) . . . . ?
N5 C9 C10 C11 -4(6) . . . . ?
O2 C9 C10 C11 169(4) . . . . ?
N6 C10 C11 N14 4(6) . . . . ?
C9 C10 C11 N14 177(3) . . . . ?
N14 C13 C14 N6 -2(6) . . . . ?
N7 C15 C16 N15 2(8) . . . . ?
N15 C18 C19 N7 -4(8) . . . . ?
N15 C18 C19 C20 178(5) . . . . ?
N7 C19 C20 N8 -165(4) . . . . ?
C18 C19 C20 N8 14(7) . . . . ?
N7 C19 C20 O3 9(6) . . . . ?
C18 C19 C20 O3 -172(5) . . . . ?
N9 C21 C22 N10 0(9) . . . . ?
O4 C23 C24 N12 9(5) . . . . ?
N11 C23 C24 N12 -168(3) . . . . ?
O4 C23 C24 C25 -173(4) . . . . ?
N11 C23 C24 C25 10(5) . . . . ?
N12 C24 C25 N16 -4(6) . . . . ?
C23 C24 C25 N16 179(3) . . . . ?
N16 C27 C28 N12 14(5) . . . . ?
O6 P1 C29 C30 -59(3) . . . . ?
O7 P1 C29 C30 -179(2) . . . . ?
O5 P1 C29 C30 66(3) . . . . ?
P1 C29 C30 C43 89(4) . . . . ?
P1 C29 C30 C31 -93(4) . . . . ?
C43 C30 C31 C32 -176(4) . . . . ?
C29 C30 C31 C32 7(6) . . . . ?
C43 C30 C31 C36 3(6) . . . . ?
C29 C30 C31 C36 -174(3) . . . . ?
C30 C31 C32 C33 -178(3) . . . . ?
C36 C31 C32 C33 4(6) . . . . ?
C31 C32 C33 C34 -2(6) . . . . ?
C32 C33 C34 C35 -1(6) . . . . ?
C33 C34 C35 C36 1(6) . . . . ?
C32 C31 C36 C37 176(4) . . . . ?
C30 C31 C36 C37 -3(6) . . . . ?
C32 C31 C36 C35 -3(6) . . . . ?
C30 C31 C36 C35 178(3) . . . . ?
C34 C35 C36 C37 -178(4) . . . . ?
C34 C35 C36 C31 1(6) . . . . ?
C31 C36 C37 C38 3(6) . . . . ?
C35 C36 C37 C38 -178(4) . . . . ?
C36 C37 C38 C43 -2(6) . . . . ?
C36 C37 C38 C39 -179(4) . . . . ?
C37 C38 C39 C40 176(4) . . . . ?
C43 C38 C39 C40 0(7) . . . . ?
C38 C39 C40 C41 5(7) . . . . ?
C39 C40 C41 C42 -5(7) . . . . ?
C40 C41 C42 C43 -1(7) . . . . ?
C37 C38 C43 C42 179(4) . . . . ?
C39 C38 C43 C42 -5(7) . . . . ?
C37 C38 C43 C30 3(6) . . . . ?
C39 C38 C43 C30 179(4) . . . . ?
C41 C42 C43 C38 5(6) . . . . ?
C41 C42 C43 C30 -179(4) . . . . ?
C31 C30 C43 C38 -3(6) . . . . ?
C29 C30 C43 C38 175(3) . . . . ?
C31 C30 C43 C42 -179(4) . . . . ?
C29 C30 C43 C42 -1(6) . . . . ?
O10 P2 C44 C45 -70(4) . . . . ?
O8 P2 C44 C45 54(4) . . . . ?
O9 P2 C44 C45 165(3) . . . . ?
P2 C44 C45 C46 84(6) . . . . ?
P2 C44 C45 C58 -98(5) . . . . ?
C58 C45 C46 C51 -2(8) . . . . ?
C44 C45 C46 C51 176(5) . . . . ?
C58 C45 C46 C47 -175(4) . . . . ?
C44 C45 C46 C47 4(8) . . . . ?
C45 C46 C47 C48 178(5) . . . . ?
C51 C46 C47 C48 5(8) . . . . ?
C46 C47 C48 C49 -5(8) . . . . ?
C47 C48 C49 C50 2(9) . . . . ?
C48 C49 C50 C51 0(9) . . . . ?
C45 C46 C51 C50 -176(5) . . . . ?
C47 C46 C51 C50 -3(8) . . . . ?
C45 C46 C51 C52 2(8) . . . . ?
C47 C46 C51 C52 175(5) . . . . ?
C49 C50 C51 C46 0(9) . . . . ?
C49 C50 C51 C52 -177(5) . . . . ?
C46 C51 C52 C53 0(8) . . . . ?
C50 C51 C52 C53 178(5) . . . . ?
C51 C52 C53 C58 -3(8) . . . . ?
C51 C52 C53 C54 -179(5) . . . . ?
C58 C53 C54 C55 -2(8) . . . . ?
C52 C53 C54 C55 174(5) . . . . ?
C53 C54 C55 C56 5(8) . . . . ?
C54 C55 C56 C57 -1(7) . . . . ?
C55 C56 C57 C58 -7(7) . . . . ?
C54 C53 C58 C45 179(4) . . . . ?
C52 C53 C58 C45 3(7) . . . . ?
C54 C53 C58 C57 -5(7) . . . . ?
C52 C53 C58 C57 178(4) . . . . ?
C46 C45 C58 C53 -1(7) . . . . ?
C44 C45 C58 C53 -179(4) . . . . ?
C46 C45 C58 C57 -177(4) . . . . ?
C44 C45 C58 C57 5(7) . . . . ?
C56 C57 C58 C53 10(7) . . . . ?
C56 C57 C58 C45 -174(4) . . . . ?
C4 C5 N1 C1 6(7) . . . . ?
C6 C5 N1 C1 -179(4) . . . . ?
C4 C5 N1 Dy1 -173(4) . . . . ?
C6 C5 N1 Dy1 2(5) . . . . ?
C2 C1 N1 C5 -8(7) . . . . ?
C2 C1 N1 Dy1 172(3) . . . . ?
O1 C6 N2 N3 -4(6) . . . . ?
C5 C6 N2 N3 179(3) . . . . ?
C8 C7 N3 N2 -175(4) . . . . ?
C8 C7 N3 Dy2 24(6) . . . . ?
C6 N2 N3 C7 -176(4) . . . . ?
C6 N2 N3 Dy2 -16(4) . . . . ?
C7 C8 N4 N5 174(4) . . . . ?
C7 C8 N4 Dy2 4(7) . . . . ?
O2 C9 N5 N4 10(6) . . . . ?
C10 C9 N5 N4 -178(3) . . . . ?
C8 N4 N5 C9 -161(4) . . . . ?
Dy2 N4 N5 C9 9(5) . . . . ?
C11 C10 N6 C14 -2(6) . . . . ?
C9 C10 N6 C14 -176(3) . . . . ?
C11 C10 N6 Dy3 179(3) . . . . ?
C9 C10 N6 Dy3 5(4) . . . . ?
C13 C14 N6 C10 2(6) . . . . ?
C13 C14 N6 Dy3 -180(3) . . . . ?
C18 C19 N7 C15 -1(8) . . . . ?
C20 C19 N7 C15 178(4) . . . . ?
C18 C19 N7 Dy1 -172(4) . . . . ?
C20 C19 N7 Dy1 7(5) . . . . ?
C16 C15 N7 C19 2(7) . . . . ?
C16 C15 N7 Dy1 172(3) . . . . ?
O3 C20 N8 N9 9(7) . . . . ?
C19 C20 N8 N9 -178(4) . . . . ?
C22 C21 N9 N8 174(5) . . . . ?
C22 C21 N9 Dy5 4(7) . . . . ?
C20 N8 N9 C21 172(5) . . . . ?
C20 N8 N9 Dy5 -17(5) . . . . ?
C21 C22 N10 N11 172(5) . . . . ?
C21 C22 N10 Dy5 -4(7) . . . . ?
O4 C23 N11 N10 0(6) . . . . ?
C24 C23 N11 N10 176(3) . . . . ?
C22 N10 N11 C23 -158(5) . . . . ?
Dy5 N10 N11 C23 17(4) . . . . ?
C25 C24 N12 C28 3(5) . . . . ?
C23 C24 N12 C28 -179(3) . . . . ?
C25 C24 N12 Dy4 158(3) . . . . ?
C23 C24 N12 Dy4 -24(4) . . . . ?
C27 C28 N12 C24 -8(5) . . . . ?
C27 C28 N12 Dy4 -159(3) . . . . ?
C5 C4 N13 C2 3(8) . . . . ?
C1 C2 N13 C4 -4(8) . . . . ?
C10 C11 N14 C13 -4(6) . . . . ?
C14 C13 N14 C11 3(6) . . . . ?
C19 C18 N15 C16 7(8) . . . . ?
C15 C16 N15 C18 -6(8) . . . . ?
C28 C27 N16 C25 -14(5) . . . . ?
C24 C25 N16 C27 9(5) . . . . ?
N2 C6 O1 Dy1 154(4) . . . . ?
C5 C6 O1 Dy1 -29(5) . . . . ?
N2 C6 O1 Dy2 22(6) . . . . ?
C5 C6 O1 Dy2 -161(3) . . . . ?
N5 C9 O2 Dy3 -164(3) . . . . ?
C10 C9 O2 Dy3 24(4) . . . . ?
N5 C9 O2 Dy2 -24(5) . . . . ?
C10 C9 O2 Dy2 165(2) . . . . ?
N8 C20 O3 Dy1 147(5) . . . . ?
C19 C20 O3 Dy1 -26(5) . . . . ?
N8 C20 O3 Dy5 4(6) . . . . ?
C19 C20 O3 Dy5 -169(3) . . . . ?
N11 C23 O4 Dy4 -170(3) . . . . ?
C24 C23 O4 Dy4 14(5) . . . . ?
N11 C23 O4 Dy5 -17(6) . . . . ?
C24 C23 O4 Dy5 166(2) . . . . ?
O6 P1 O5 Dy1 13(2) . . . . ?
O7 P1 O5 Dy1 130.7(15) . . . . ?
C29 P1 O5 Dy1 -108.6(19) . . . . ?
O6 P1 O5 Dy5 -120.9(12) . . . . ?
O7 P1 O5 Dy5 -3.7(11) . . . . ?
C29 P1 O5 Dy5 117.0(14) . . . . ?
O7 P1 O6 Dy2 -110(2) . . . . ?
O5 P1 O6 Dy2 4(3) . . . . ?
C29 P1 O6 Dy2 128(2) . . . . ?
O6 P1 O7 Dy4 -55(2) . . . . ?
O5 P1 O7 Dy4 -175.0(18) . . . . ?
C29 P1 O7 Dy4 65(2) . . . . ?
O6 P1 O7 Dy5 123.9(9) . . . . ?
O5 P1 O7 Dy5 3.5(11) . . . . ?
C29 P1 O7 Dy5 -116.6(13) . . . . ?
O10 P2 O8 Dy1 10(2) . . . . ?
O9 P2 O8 Dy1 128.5(17) . . . . ?
C44 P2 O8 Dy1 -115(2) . . . . ?
O10 P2 O8 Dy2 -122.7(14) . . . . ?
O9 P2 O8 Dy2 -4.6(13) . . . . ?
C44 P2 O8 Dy2 112.4(17) . . . . ?
O10 P2 O9 Dy3 -51(3) . . . . ?
O8 P2 O9 Dy3 -171(3) . . . . ?
C44 P2 O9 Dy3 75(3) . . . . ?
O10 P2 O9 Dy2 124.5(11) . . . . ?
O8 P2 O9 Dy2 4.4(12) . . . . ?
C44 P2 O9 Dy2 -109.0(19) . . . . ?
O8 P2 O10 Dy5 14(3) . . . . ?
O9 P2 O10 Dy5 -100(3) . . . . ?
C44 P2 O10 Dy5 135(3) . . . . ?
O12 C61 O11 Dy1 -23(7) . . . . ?
C62 C61 O11 Dy1 158(3) . . . . ?
O11 C61 O12 Dy5 25(7) . . . . ?
C62 C61 O12 Dy5 -157(3) . . . . ?
O14 C59 O13 Dy1 -26(5) . . . . ?
C60 C59 O13 Dy1 164(3) . . . . ?
O13 C59 O14 Dy2 33(6) . . . . ?
C60 C59 O14 Dy2 -157(3) . . . . ?
O16 C69 O15 Dy3 -18(6) . . . . ?
C70 C69 O15 Dy3 157(2) . . . . ?
O15 C69 O16 Dy2 12(6) . . . . ?
C70 C69 O16 Dy2 -162(3) . . . . ?
O18 C65 O17 Dy3 -6(4) . . . . ?
C66 C65 O17 Dy3 178(3) . . . . ?
O17 C65 O18 Dy4 156(3) . . . . ?
C66 C65 O18 Dy4 -28(8) . . . . ?
O17 C65 O18 Dy3 6(4) . . . . ?
C66 C65 O18 Dy3 -178(3) . . . . ?
O20 C63 O19 Dy3 -156(4) . . . . ?
C64 C63 O19 Dy3 24(7) . . . . ?
O20 C63 O19 Dy4 19(3) . . . . ?
C64 C63 O19 Dy4 -161(3) . . . . ?
O19 C63 O20 Dy4 -19(3) . . . . ?
C64 C63 O20 Dy4 161(3) . . . . ?
O22 C67 O21 Dy3 10(8) . . . . ?
C68 C67 O21 Dy3 179(3) . . . . ?
O21 C67 O22 Dy4 -10(8) . . . . ?
C68 C67 O22 Dy4 -179(3) . . . . ?
O25 C71 O24 Dy4 160(3) 3_766 . . . ?
C71 C71 O24 Dy4 -6(4) 3_766 . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O25 0.85 2.22 2.70(3) 115.6 .
C29 H29A O20 0.97 2.61 3.36(4) 134.0 .
C15 H15 O13 0.93 2.51 3.00(4) 113.2 .
C14 H14 O21 0.93 2.58 3.05(4) 112.0 .
C29 H29A O20 0.97 2.61 3.36(4) 134.0 .
C15 H15 O13 0.93 2.51 3.00(4) 113.2 .
C14 H14 O21 0.93 2.58 3.05(4) 112.0 .
C14 H14 O21 0.93 2.58 3.05(4) 112.0 .
C15 H15 O13 0.93 2.51 3.00(4) 113.2 .
C29 H29A O20 0.97 2.61 3.36(4) 134.0 .
C14 H14 O21 0.93 2.58 3.05(4) 112.0 .
C15 H15 O13 0.93 2.51 3.00(4) 113.2 .
C29 H29A O20 0.97 2.61 3.36(4) 134.0 .

_refine_diff_density_max         3.431
_refine_diff_density_min         -1.896
_refine_diff_density_rms         0.302

_shelxl_version_number           2013-4

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_II
_database_code_depnum_ccdc_archive 'CCDC 1819932'
_audit_update_record             
;
2018-01-28 deposited with the CCDC.
2018-07-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C68 H63 Dy5 N16 O26 P2, C70 H67 Dy5 N16 O26 P2, 2(C H Cl3)'
_chemical_formula_sum            'C140 H132 Cl6 Dy10 N32 O52 P4'
_chemical_formula_weight         5056.35

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      trigonal
_space_group_IT_number           155
_space_group_name_H-M_alt        'R 3 2 :H'
_space_group_name_Hall           'R 3 2"'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'

_cell_length_a                   26.7135(7)
_cell_length_b                   26.7135(7)
_cell_length_c                   71.325(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     44079(3)
_cell_formula_units_Z            9
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    9927
_cell_measurement_theta_min      2.346
_cell_measurement_theta_max      27.583

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.714
_exptl_crystal_F_000             21906
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.300
_exptl_absorpt_coefficient_mu    3.955
_shelx_estimated_absorpt_T_min   0.301
_shelx_estimated_absorpt_T_max   0.383
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.300
_exptl_absorpt_correction_T_max  0.383
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'bruker D8'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            127761
_diffrn_reflns_av_unetI/netI     0.0272
_diffrn_reflns_av_R_equivalents  0.0371
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_l_min       -92
_diffrn_reflns_limit_l_max       71
_diffrn_reflns_theta_min         2.184
_diffrn_reflns_theta_max         27.593
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             22630
_reflns_number_gt                20204
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.881
_reflns_Friedel_fraction_max     0.997
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2000)'
_computing_cell_refinement       SMART
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL

_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0390P)²+2996.8516P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.510(19)
_chemical_absolute_configuration unk
_refine_ls_number_reflns         22630
_refine_ls_number_parameters     1127
_refine_ls_number_restraints     721
_refine_ls_R_factor_all          0.0755
_refine_ls_R_factor_gt           0.0617
_refine_ls_wR_factor_ref         0.1459
_refine_ls_wR_factor_gt          0.1319
_refine_ls_goodness_of_fit_ref   0.987
_refine_ls_restrained_S_all      0.980
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.000

# SQUEEZE RESULTS (Version = 120716)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.000 2177 643 ' '
2 0.000 0.000 0.207 9 0 ' '
3 0.000 0.000 0.275 147 40 ' '
4 0.667 0.333 0.333 2155 641 ' '
5 0.000 0.000 0.500 490 120 ' '
6 0.333 -0.333 0.667 2156 641 ' '
7 0.000 0.000 0.725 147 37 ' '
8 0.000 0.000 0.793 9 0 ' '
9 0.515 0.041 0.091 13 2 ' '
10 0.292 0.140 0.758 12 2 ' '
11 0.860 0.152 0.758 11 2 ' '
12 0.375 0.181 0.576 12 2 ' '
13 0.667 0.333 0.833 489 120 ' '
14 0.818 0.193 0.576 12 2 ' '
15 0.667 0.333 0.608 143 40 ' '
16 0.667 0.333 0.058 142 37 ' '
17 0.140 0.292 0.242 12 2 ' '
18 0.667 0.333 0.126 7 0 ' '
19 0.667 0.333 0.540 7 0 ' '
20 0.181 0.375 0.424 11 2 ' '
21 0.959 0.473 0.091 13 2 ' '
22 0.526 0.485 0.091 13 2 ' '
23 0.333 0.667 0.167 490 120 ' '
24 0.041 0.515 0.909 13 2 ' '
25 0.485 0.526 0.909 13 2 ' '
26 0.333 0.667 0.942 142 40 ' '
27 0.333 0.667 0.392 143 37 ' '
28 0.807 0.625 0.576 12 2 ' '
29 0.333 0.667 0.460 7 0 ' '
30 0.333 0.667 0.874 7 0 ' '
31 0.848 0.708 0.758 12 2 ' '
32 0.625 0.807 0.424 11 2 ' '
33 0.193 0.818 0.424 12 2 ' '
34 0.708 0.848 0.242 12 2 ' '
35 0.152 0.860 0.242 11 1 ' '
36 0.473 0.959 0.909 13 2 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?


loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy -0.03734(3) 0.38535(3) 0.81087(2) 0.02576(14) Uani 1 1 d D . . . .
Dy2 Dy 0.13539(3) 0.44930(3) 0.82394(2) 0.02546(14) Uani 1 1 d . . . . .
Dy3 Dy 0.17651(3) 0.3333 0.8333 0.02582(19) Uani 1 2 d S T P . .
Dy4 Dy 1.08824(4) 0.36543(4) 0.68762(2) 0.04285(19) Uani 1 1 d . . . . .
Dy5 Dy 0.91942(4) 0.25048(3) 0.70496(2) 0.03734(18) Uani 1 1 d . . . . .
Dy6 Dy 0.81832(5) 0.15166(5) 0.6667 0.0430(3) Uani 1 2 d S T P . .
P1 P 0.05618(14) 0.32276(15) 0.80760(5) 0.0227(7) Uani 1 1 d . . . . .
P2 P 0.97426(18) 0.22911(19) 0.66901(6) 0.0339(8) Uani 1 1 d . . . . .
C1 C 0.0553(7) 0.3071(7) 0.7829(2) 0.033(3) Uani 1 1 d . U . . .
H1A H 0.0158 0.2935 0.7781 0.040 Uiso 1 1 calc R U . . .
H1B H 0.0815 0.3438 0.7763 0.040 Uiso 1 1 calc R U . . .
C2 C 0.0723(5) 0.2637(6) 0.7774(2) 0.038(3) Uani 1 1 d D U . . .
C3 C 0.1297(6) 0.2818(6) 0.7722(2) 0.044(3) Uani 1 1 d D U . . .
C4 C 0.1723(6) 0.3405(8) 0.7712(3) 0.057(4) Uani 1 1 d D U . . .
H4 H 0.1626 0.3685 0.7752 0.068 Uiso 1 1 calc R U . . .
C5 C 0.2286(7) 0.3597(10) 0.7646(3) 0.071(5) Uani 1 1 d D U . . .
H5 H 0.2552 0.3998 0.7632 0.085 Uiso 1 1 calc R U . . .
C6 C 0.2445(9) 0.3184(8) 0.7602(3) 0.072(5) Uani 1 1 d D U . . .
H6 H 0.2830 0.3307 0.7563 0.086 Uiso 1 1 calc R U . . .
C7 C 0.2043(7) 0.2592(9) 0.7614(3) 0.062(4) Uani 1 1 d D U . . .
H7 H 0.2152 0.2312 0.7586 0.074 Uiso 1 1 calc R U . . .
C8 C 0.1473(6) 0.2422(7) 0.7668(3) 0.053(3) Uani 1 1 d D U . . .
C9 C 0.1061(7) 0.1830(7) 0.7669(3) 0.057(4) Uani 1 1 d D U . . .
H9 H 0.1168 0.1558 0.7628 0.069 Uiso 1 1 calc R U . . .
C10 C 0.0494(7) 0.1638(6) 0.7729(3) 0.055(4) Uani 1 1 d D U . . .
C11 C 0.0103(7) 0.1041(7) 0.7731(3) 0.060(4) Uani 1 1 d D U . . .
H11 H 0.0222 0.0775 0.7694 0.072 Uiso 1 1 calc R U . . .
C12 C -0.0466(8) 0.0845(8) 0.7788(4) 0.068(4) Uani 1 1 d D U . . .
H12 H -0.0734 0.0442 0.7793 0.081 Uiso 1 1 calc R U . . .
C13 C -0.0644(9) 0.1240(6) 0.7839(3) 0.061(4) Uani 1 1 d D U . . .
H13 H -0.1034 0.1103 0.7874 0.073 Uiso 1 1 calc R U . . .
C14 C -0.0249(6) 0.1834(6) 0.7837(3) 0.046(4) Uani 1 1 d D U . . .
H14 H -0.0370 0.2099 0.7873 0.055 Uiso 1 1 calc R U . . .
C15 C 0.0327(6) 0.2040(5) 0.7782(3) 0.043(3) Uani 1 1 d D U . . .
C16 C -0.0848(7) 0.4867(8) 0.8112(4) 0.058(6) Uani 1 1 d . . . . .
H16 H -0.1218 0.4537 0.8094 0.069 Uiso 1 1 calc R U . . .
C17 C -0.0789(10) 0.5423(9) 0.8110(4) 0.059(6) Uani 1 1 d . . . . .
H17 H -0.1126 0.5454 0.8095 0.070 Uiso 1 1 calc R U . . .
C18 C 0.0172(7) 0.5834(7) 0.8157(3) 0.046(5) Uani 1 1 d . . . . .
H18 H 0.0543 0.6165 0.8173 0.056 Uiso 1 1 calc R U . . .
C19 C 0.0104(8) 0.5285(8) 0.8162(3) 0.042(4) Uani 1 1 d . . . . .
C20 C 0.0622(7) 0.5204(6) 0.82006(19) 0.028(3) Uani 1 1 d . . . . .
C21 C 0.1988(7) 0.5948(7) 0.8342(3) 0.041(4) Uani 1 1 d . . . . .
H21 H 0.2062 0.6334 0.8336 0.049 Uiso 1 1 calc R U . . .
C22 C 0.2423(8) 0.5818(7) 0.8414(3) 0.042(4) Uani 1 1 d . . . . .
H22 H 0.2791 0.6114 0.8457 0.051 Uiso 1 1 calc R U . . .
C23 C 0.2475(5) 0.4612(6) 0.8490(2) 0.029(3) Uani 1 1 d . U . . .
C24 C 0.2880(6) 0.4413(6) 0.8552(2) 0.029(3) Uani 1 1 d . U . . .
C25 C 0.3423(7) 0.4772(8) 0.8626(3) 0.046(5) Uani 1 1 d . . . . .
H25 H 0.3548 0.5170 0.8644 0.055 Uiso 1 1 calc R U . . .
C26 C 0.3574(8) 0.4009(8) 0.8645(3) 0.050(5) Uani 1 1 d . . . . .
H26 H 0.3809 0.3849 0.8679 0.060 Uiso 1 1 calc R U . . .
C27 C 0.3039(8) 0.3646(8) 0.8567(3) 0.044(4) Uani 1 1 d . . . . .
H27 H 0.2921 0.3252 0.8544 0.052 Uiso 1 1 calc R U . . .
C28 C -0.0285(8) 0.4339(13) 0.7752(3) 0.078(7) Uani 1 1 d D U . . .
C29 C -0.0210(12) 0.4640(11) 0.7557(3) 0.065(6) Uani 1 1 d . U . . .
H29A H 0.0041 0.4561 0.7477 0.078 Uiso 1 1 calc R U . . .
H29B H -0.0035 0.5058 0.7575 0.078 Uiso 1 1 calc R U . . .
H29C H -0.0589 0.4488 0.7497 0.078 Uiso 1 1 calc R U . . .
C30 C -0.0300(6) 0.4041(6) 0.8595(2) 0.030(3) Uani 1 1 d . . . . .
C31 C -0.0063(8) 0.4686(6) 0.8620(2) 0.040(4) Uani 1 1 d . . . . .
H31A H -0.0323 0.4796 0.8560 0.048 Uiso 1 1 calc R U . . .
H31B H 0.0321 0.4900 0.8563 0.048 Uiso 1 1 calc R U . . .
H31C H -0.0034 0.4777 0.8754 0.048 Uiso 1 1 calc R U . . .
C32 C 0.2526(6) 0.4476(7) 0.8051(2) 0.033(3) Uani 1 1 d . U . . .
C33 C 0.3075(7) 0.4830(9) 0.7942(3) 0.052(5) Uani 1 1 d . U . . .
H33A H 0.3000 0.5018 0.7837 0.063 Uiso 1 1 calc R U . . .
H33B H 0.3215 0.4577 0.7895 0.063 Uiso 1 1 calc R U . . .
H33C H 0.3369 0.5125 0.8025 0.063 Uiso 1 1 calc R U . . .
C34 C 1.0115(8) 0.1881(7) 0.6711(2) 0.040(4) Uani 1 1 d . . . . .
H34A H 1.0507 0.2107 0.6656 0.048 Uiso 1 1 calc R U . . .
H34B H 1.0158 0.1816 0.6845 0.048 Uiso 1 1 calc R U . . .
C35 C 0.9780(9) 0.1281(8) 0.6608(2) 0.058(6) Uani 1 1 d D . . . .
C36 C 0.9885(8) 0.1243(7) 0.6417(2) 0.058(4) Uani 1 1 d D U . . .
C37 C 1.0273(9) 0.1712(8) 0.6306(2) 0.055(4) Uani 1 1 d D U . . .
H37 H 1.0467 0.2083 0.6362 0.066 Uiso 1 1 calc R U . . .
C38 C 1.0394(11) 0.1670(10) 0.6118(3) 0.068(4) Uani 1 1 d D U . . .
H38 H 1.0680 0.1995 0.6051 0.082 Uiso 1 1 calc R U . . .
C39 C 1.0077(10) 0.1129(9) 0.6032(4) 0.078(5) Uani 1 1 d D U . . .
H39 H 1.0131 0.1089 0.5902 0.093 Uiso 1 1 calc R U . . .
C40 C 0.9680(10) 0.0645(10) 0.6134(3) 0.070(5) Uani 1 1 d D U . . .
H40 H 0.9465 0.0280 0.6074 0.084 Uiso 1 1 calc R U . . .
C41 C 0.9605(9) 0.0708(7) 0.6325(3) 0.067(5) Uani 1 1 d D U . . .
C42 C 0.9230(11) 0.0229(10) 0.6432(4) 0.091(10) Uani 1 1 d D . . . .
H42 H 0.9035 -0.0137 0.6372 0.109 Uiso 1 1 calc R U . . .
C43 C 0.9121(13) 0.0254(9) 0.6622(4) 0.122(8) Uani 1 1 d D U . . .
C44 C 0.8744(15) -0.0251(11) 0.6720(5) 0.127(8) Uani 1 1 d D U . . .
H44 H 0.8546 -0.0613 0.6658 0.152 Uiso 1 1 calc R U . . .
C45 C 0.8668(16) -0.0207(11) 0.6912(5) 0.129(8) Uani 1 1 d D U . . .
H45 H 0.8425 -0.0547 0.6981 0.154 Uiso 1 1 calc R U . . .
C46 C 0.8938(15) 0.0326(9) 0.7005(5) 0.129(8) Uani 1 1 d D U . . .
H46 H 0.8856 0.0354 0.7133 0.155 Uiso 1 1 calc R U . . .
C47 C 0.9333(15) 0.0817(12) 0.6905(4) 0.124(8) Uani 1 1 d D U . . .
H47 H 0.9554 0.1173 0.6969 0.149 Uiso 1 1 calc R U . . .
C48 C 0.9405(12) 0.0790(8) 0.6712(4) 0.116(8) Uani 1 1 d D U . . .
C49 C 1.1793(8) 0.4611(9) 0.7230(3) 0.062(5) Uani 1 1 d D U . . .
H49 H 1.2073 0.4727 0.7133 0.075 Uiso 1 1 calc R U . . .
C50 C 1.1980(10) 0.4857(11) 0.7401(2) 0.068(5) Uani 1 1 d D U . . .
H50 H 1.2375 0.5139 0.7418 0.081 Uiso 1 1 calc R U . . .
C51 C 1.1067(8) 0.4304(7) 0.7502(2) 0.048(4) Uani 1 1 d D U . . .
H51 H 1.0790 0.4182 0.7600 0.057 Uiso 1 1 calc R U . . .
C52 C 1.0870(9) 0.4052(8) 0.73324(19) 0.050(4) Uani 1 1 d D U . . .
C53 C 1.0271(8) 0.3582(7) 0.7293(2) 0.035(3) Uani 1 1 d . . . . .
C54 C 0.8968(8) 0.2921(9) 0.7484(3) 0.053(5) Uani 1 1 d . . . . .
H54 H 0.9059 0.3095 0.7604 0.063 Uiso 1 1 calc R U . . .
C55 C 0.8362(9) 0.2539(8) 0.7426(2) 0.046(4) Uani 1 1 d . . . . .
H55 H 0.8044 0.2447 0.7507 0.056 Uiso 1 1 calc R U . . .
C56 C 0.7723(7) 0.1832(8) 0.7032(2) 0.035(3) Uani 1 1 d . . . . .
C57 C 0.7151(8) 0.1446(10) 0.6950(3) 0.059(4) Uani 1 1 d D U . . .
C58 C 0.6635(6) 0.1303(10) 0.7028(3) 0.065(5) Uani 1 1 d D U . . .
H58 H 0.6638 0.1473 0.7145 0.078 Uiso 1 1 calc R U . . .
C59 C 0.6166(9) 0.0738(12) 0.6783(3) 0.079(6) Uani 1 1 d D U . . .
H59 H 0.5818 0.0488 0.6718 0.094 Uiso 1 1 calc R U . . .
C60 C 0.6665(7) 0.0864(11) 0.6696(4) 0.072(5) Uani 1 1 d D U . . .
H60 H 0.6661 0.0693 0.6579 0.086 Uiso 1 1 calc R U . . .
C61 C 1.1511(11) 0.3207(13) 0.7057(3) 0.063(6) Uani 1 1 d . . . . .
C62 C 1.1784(14) 0.2881(13) 0.7134(4) 0.092(10) Uani 1 1 d . . . . .
H62A H 1.1954 0.2771 0.7032 0.110 Uiso 1 1 calc R U . . .
H62B H 1.1490 0.2532 0.7198 0.110 Uiso 1 1 calc R U . . .
H62C H 1.2087 0.3125 0.7224 0.110 Uiso 1 1 calc R U . . .
C63 C 1.1056(8) 0.3435(9) 0.6496(3) 0.045(4) Uani 1 1 d . . . . .
C64 C 1.1172(10) 0.3329(11) 0.6300(3) 0.057(5) Uani 1 1 d . . . . .
H64A H 1.1359 0.3695 0.6231 0.068 Uiso 1 1 calc R U . . .
H64B H 1.0806 0.3060 0.6238 0.068 Uiso 1 1 calc R U . . .
H64C H 1.1426 0.3163 0.6301 0.068 Uiso 1 1 calc R U . . .
C65 C 0.8263(11) 0.1085(9) 0.7099(3) 0.058(5) Uani 1 1 d . . . . .
C66 C 0.7966(12) 0.0636(10) 0.7258(3) 0.071(7) Uani 1 1 d . . . . .
H66A H 0.8254 0.0572 0.7321 0.085 Uiso 1 1 calc R U . . .
H66B H 0.7664 0.0271 0.7204 0.085 Uiso 1 1 calc R U . . .
H66C H 0.7792 0.0781 0.7348 0.085 Uiso 1 1 calc R U . . .
C68 C 0.9851(19) 0.1979(17) 0.7347(5) 0.123(13) Uani 1 1 d . . . . .
H68A H 0.9630 0.2063 0.7439 0.148 Uiso 1 1 calc R U . . .
H68B H 1.0249 0.2137 0.7391 0.148 Uiso 1 1 calc R U . . .
H68C H 0.9671 0.1560 0.7331 0.148 Uiso 1 1 calc R U . . .
C69 C 0.6904(8) 0.1220(8) 0.7531(4) 0.116(8) Uani 1 1 d D U . . .
H69 H 0.7122 0.1412 0.7414 0.139 Uiso 1 1 calc R U . . .
Cl1 Cl 0.6529(6) 0.1563(6) 0.76050(18) 0.150(4) Uani 1 1 d D U . . .
Cl2 Cl 0.6416(5) 0.0497(5) 0.7482(3) 0.168(6) Uani 1 1 d D U . . .
Cl3 Cl 0.7392(5) 0.1254(8) 0.7699(2) 0.234(10) Uani 1 1 d D U . . .
N1 N -0.0405(6) 0.4800(6) 0.8139(2) 0.035(3) Uani 1 1 d . . . . .
N2 N -0.0293(7) 0.5895(7) 0.8129(3) 0.059(5) Uani 1 1 d . . . . .
N3 N 0.1103(6) 0.5678(5) 0.8237(2) 0.032(3) Uani 1 1 d . . . . .
N4 N 0.1518(5) 0.5537(5) 0.82884(19) 0.028(3) Uani 1 1 d . . . . .
N5 N 0.2285(5) 0.5299(5) 0.8418(2) 0.037(3) Uani 1 1 d . . . . .
N6 N 0.2691(6) 0.5173(6) 0.8481(2) 0.036(3) Uani 1 1 d . U . . .
N7 N 0.2689(5) 0.3847(5) 0.85238(19) 0.029(3) Uani 1 1 d . . . . .
N8 N 0.3782(6) 0.4574(7) 0.8676(3) 0.053(4) Uani 1 1 d . . . . .
N9 N 1.1241(7) 0.4214(7) 0.7187(2) 0.059(4) Uani 1 1 d D U . . .
N10 N 1.1613(7) 0.4707(7) 0.7548(2) 0.062(4) Uani 1 1 d D U . . .
N11 N 0.9926(7) 0.3433(7) 0.7428(2) 0.043(3) Uani 1 1 d . . . . .
N12 N 0.9363(7) 0.3011(7) 0.7368(2) 0.046(4) Uani 1 1 d . . . . .
N13 N 0.8300(6) 0.2342(7) 0.7261(2) 0.044(3) Uani 1 1 d . . . . .
N14 N 0.7736(8) 0.1978(7) 0.7205(2) 0.052(4) Uani 1 1 d . . . . .
N15 N 0.7172(7) 0.1239(8) 0.6780(2) 0.060(4) Uani 1 1 d D U . . .
N16 N 0.6115(7) 0.0934(10) 0.6951(3) 0.077(5) Uani 1 1 d D U . . .
O1 O 0.0384(5) 0.3690(4) 0.80966(15) 0.030(2) Uani 1 1 d . . . . .
O2 O 0.1195(4) 0.3545(4) 0.81444(14) 0.0249(19) Uani 1 1 d . . . . .
O3 O 0.0170(4) 0.2667(4) 0.81771(14) 0.026(2) Uani 1 1 d . . . . .
O4 O 0.1963(4) 0.4227(4) 0.84381(14) 0.0238(19) Uani 1 1 d . . . . .
O5 O 0.0520(4) 0.4683(4) 0.82079(15) 0.028(2) Uani 1 1 d . . . . .
O6 O -0.0774(9) 0.4038(8) 0.7819(3) 0.081(5) Uani 1 1 d D U . . .
O7 O 0.0144(8) 0.4393(7) 0.78342(19) 0.070(4) Uani 1 1 d D U . . .
O8 O -0.0415(4) 0.3827(4) 0.84324(13) 0.0240(18) Uani 1 1 d . . . . .
O9 O -0.0412(5) 0.3719(4) 0.87366(15) 0.036(2) Uani 1 1 d . . . . .
O10 O 0.2180(5) 0.4671(5) 0.80660(15) 0.034(2) Uani 1 1 d . U . . .
O11 O 0.2447(5) 0.3996(5) 0.81258(15) 0.036(2) Uani 1 1 d . U . . .
O12 O 1.0050(5) 0.2807(6) 0.68222(15) 0.038(3) Uani 1 1 d . . . . .
O13 O 0.9131(5) 0.1941(5) 0.67785(16) 0.039(3) Uani 1 1 d . . . . .
O15 O 1.1187(6) 0.3215(6) 0.66296(17) 0.045(3) Uani 1 1 d . . . . .
O16 O 1.0830(6) 0.3740(6) 0.65302(19) 0.049(3) Uani 1 1 d . . . . .
O17 O 1.0970(7) 0.2968(7) 0.7071(2) 0.060(4) Uani 1 1 d . . . . .
O18 O 1.1794(8) 0.3685(8) 0.6978(2) 0.069(4) Uani 1 1 d . . . . .
O19 O 0.8680(6) 0.1558(5) 0.7154(2) 0.050(3) Uani 1 1 d . . . . .
O20 O 0.8034(6) 0.0947(6) 0.6935(2) 0.057(4) Uani 1 1 d . . . . .
O27 O 1.1618(8) 0.4589(7) 0.6785(2) 0.073(5) Uani 1 1 d D U . . .
O22 O 0.9853(7) 0.2230(6) 0.7178(2) 0.056(4) Uani 1 1 d . . . . .
H22A H 1.0169 0.2307 0.7099 0.084 Uiso 1 1 calc R U . . .
O23 O 0.8162(5) 0.2025(5) 0.69239(16) 0.042(3) Uani 1 1 d . . . . .
O24 O 1.0173(6) 0.3404(5) 0.71201(16) 0.042(3) Uani 1 1 d . . . . .
O1W O 0.1314(5) 0.4801(5) 0.79308(15) 0.038(3) Uani 1 1 d . . . . .
H1WA H 0.1216 0.5058 0.7936 0.057 Uiso 1 1 d R U . . .
H1WB H 0.1645 0.4941 0.7880 0.057 Uiso 1 1 d R U . . .
O14 O 0.9759(5) 0.2456(5) 0.64845(16) 0.038(3) Uani 1 1 d . . . . .
O25 O -0.1339(9) 0.3596(9) 0.8135(3) 0.040(4) Uani 0.5 1 d D U P . .
O26 O -0.1532(9) 0.3088(13) 0.8426(3) 0.067(6) Uani 0.5 1 d D U P . .
C70 C -0.1633(12) 0.3210(10) 0.8258(3) 0.063(5) Uani 0.5 1 d D U P . .
C71 C -0.2236(14) 0.2801(18) 0.8194(6) 0.074(9) Uani 0.5 1 d D U P . .
H71A H -0.2294 0.2912 0.8069 0.111 Uiso 0.5 1 calc R U P . .
H71B H -0.2512 0.2816 0.8282 0.111 Uiso 0.5 1 calc R U P . .
H71C H -0.2298 0.2407 0.8191 0.111 Uiso 0.5 1 calc R U P . .
C72 C 1.1631(11) 0.4964(11) 0.6667 0.089(8) Uani 1 2 d DS TU P . .
C73 C 1.2199(12) 0.5532(12) 0.6667 0.130(16) Uani 1 2 d DS TU P . .
H73A H 1.2181 0.5794 0.6574 0.195 Uiso 0.5 1 calc R U P . .
H73B H 1.2514 0.5461 0.6634 0.195 Uiso 0.5 1 calc R U P . .
H73C H 1.2268 0.5707 0.6792 0.195 Uiso 0.5 1 calc R U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.276(10) . ?
Dy1 O8 2.311(9) . ?
Dy1 O25 2.32(2) . ?
Dy1 O26 2.36(3) 17_556 ?
Dy1 O5 2.412(11) . ?
Dy1 O7 2.414(16) . ?
Dy1 O9 2.454(10) 17_556 ?
Dy1 O6 2.486(18) . ?
Dy1 O8 2.513(10) 17_556 ?
Dy1 N1 2.579(13) . ?
Dy1 C30 2.853(14) 17_556 ?
Dy2 O3 2.238(9) 17_556 ?
Dy2 O10 2.361(11) . ?
Dy2 O1W 2.371(11) . ?
Dy2 O2 2.445(10) . ?
Dy2 O4 2.513(9) . ?
Dy2 O5 2.531(9) . ?
Dy2 O1 2.606(11) . ?
Dy2 N4 2.622(11) . ?
Dy2 N5 2.662(14) . ?
Dy3 O4 2.297(10) . ?
Dy3 O4 2.297(10) 17_556 ?
Dy3 O2 2.305(10) 17_556 ?
Dy3 O2 2.305(10) . ?
Dy3 O11 2.329(10) . ?
Dy3 O11 2.329(10) 17_556 ?
Dy3 N7 2.537(12) . ?
Dy3 N7 2.537(12) 17_556 ?
Dy3 Dy2 3.8280(9) 17_556 ?
Dy4 O12 2.277(13) . ?
Dy4 O16 2.337(13) 10_546 ?
Dy4 O27 2.369(15) . ?
Dy4 O17 2.406(15) . ?
Dy4 O24 2.409(13) . ?
Dy4 O15 2.467(12) . ?
Dy4 O16 2.489(14) . ?
Dy4 O18 2.504(17) . ?
Dy4 N9 2.578(16) . ?
Dy4 Dy4 3.9596(17) 10_546 ?
Dy5 O14 2.203(11) 10_546 ?
Dy5 O19 2.316(13) . ?
Dy5 O22 2.402(13) . ?
Dy5 O13 2.404(11) . ?
Dy5 O23 2.553(13) . ?
Dy5 O24 2.565(13) . ?
Dy5 N12 2.568(16) . ?
Dy5 O12 2.580(12) . ?
Dy5 N13 2.670(15) . ?
Dy6 O23 2.300(12) 10_546 ?
Dy6 O23 2.301(12) . ?
Dy6 O13 2.337(12) . ?
Dy6 O13 2.337(12) 10_546 ?
Dy6 O20 2.350(15) 10_546 ?
Dy6 O20 2.350(15) . ?
Dy6 N15 2.547(17) 10_546 ?
Dy6 N15 2.547(17) . ?
Dy6 Dy5 3.8197(12) 10_546 ?
P1 O3 1.514(9) . ?
P1 O1 1.536(10) . ?
P1 O2 1.545(10) . ?
P1 C1 1.811(15) . ?
P2 O14 1.525(12) . ?
P2 O12 1.527(13) . ?
P2 O13 1.554(13) . ?
P2 C34 1.818(17) . ?
C1 C2 1.49(2) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C15 1.407(10) . ?
C2 C3 1.408(10) . ?
C3 C4 1.406(10) . ?
C3 C8 1.407(10) . ?
C4 C5 1.403(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.403(11) . ?
C5 H5 0.9500 . ?
C6 C7 1.401(11) . ?
C6 H6 0.9500 . ?
C7 C8 1.410(10) . ?
C7 H7 0.9500 . ?
C8 C9 1.403(10) . ?
C9 C10 1.402(10) . ?
C9 H9 0.9500 . ?
C10 C11 1.403(10) . ?
C10 C15 1.407(10) . ?
C11 C12 1.399(10) . ?
C11 H11 0.9500 . ?
C12 C13 1.402(10) . ?
C12 H12 0.9500 . ?
C13 C14 1.399(10) . ?
C13 H13 0.9500 . ?
C14 C15 1.405(10) . ?
C14 H14 0.9500 . ?
C16 N1 1.30(2) . ?
C16 C17 1.41(3) . ?
C16 H16 0.9500 . ?
C17 N2 1.30(3) . ?
C17 H17 0.9500 . ?
C18 N2 1.34(2) . ?
C18 C19 1.38(2) . ?
C18 H18 0.9500 . ?
C19 N1 1.34(2) . ?
C19 C20 1.53(2) . ?
C20 O5 1.279(17) . ?
C20 N3 1.30(2) . ?
C21 N4 1.24(2) . ?
C21 C22 1.46(2) . ?
C21 H21 0.9500 . ?
C22 N5 1.244(19) . ?
C22 H22 0.9500 . ?
C23 O4 1.287(16) . ?
C23 N6 1.311(19) . ?
C23 C24 1.49(2) . ?
C24 N7 1.347(19) . ?
C24 C25 1.38(2) . ?
C25 N8 1.35(2) . ?
C25 H25 0.9500 . ?
C26 N8 1.34(2) . ?
C26 C27 1.38(3) . ?
C26 H26 0.9500 . ?
C27 N7 1.32(2) . ?
C27 H27 0.9500 . ?
C28 O7 1.230(12) . ?
C28 O6 1.240(16) . ?
C28 C29 1.57(3) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 O8 1.260(17) . ?
C30 O9 1.261(18) . ?
C30 C31 1.52(2) . ?
C30 Dy1 2.853(14) 17_556 ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 O10 1.272(19) . ?
C32 O11 1.30(2) . ?
C32 C33 1.503(19) . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 C35 1.57(3) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C48 1.399(11) . ?
C35 C36 1.402(10) . ?
C36 C41 1.404(10) . ?
C36 C37 1.407(11) . ?
C37 C38 1.398(11) . ?
C37 H37 0.9500 . ?
C38 C39 1.398(11) . ?
C38 H38 0.9500 . ?
C39 C40 1.396(11) . ?
C39 H39 0.9500 . ?
C40 C41 1.401(11) . ?
C40 H40 0.9500 . ?
C41 C42 1.392(11) . ?
C42 C43 1.397(11) . ?
C42 H42 0.9500 . ?
C43 C48 1.395(9) . ?
C43 C44 1.400(11) . ?
C44 C45 1.397(11) . ?
C44 H44 0.9500 . ?
C45 C46 1.399(11) . ?
C45 H45 0.9500 . ?
C46 C47 1.398(11) . ?
C46 H46 0.9500 . ?
C47 C48 1.398(11) . ?
C47 H47 0.9500 . ?
C49 N9 1.354(12) . ?
C49 C50 1.356(12) . ?
C49 H49 0.9500 . ?
C50 N10 1.351(12) . ?
C50 H50 0.9500 . ?
C51 N10 1.350(12) . ?
C51 C52 1.360(12) . ?
C51 H51 0.9500 . ?
C52 N9 1.346(12) . ?
C52 C53 1.48(3) . ?
C53 N11 1.25(2) . ?
C53 O24 1.298(18) . ?
C54 N12 1.26(2) . ?
C54 C55 1.48(3) . ?
C54 H54 0.9500 . ?
C55 N13 1.27(2) . ?
C55 H55 0.9500 . ?
C56 O23 1.277(19) . ?
C56 N14 1.29(2) . ?
C56 C57 1.47(3) . ?
C57 N15 1.345(12) . ?
C57 C58 1.352(12) . ?
C58 N16 1.352(13) . ?
C58 H58 0.9500 . ?
C59 N16 1.346(13) . ?
C59 C60 1.350(13) . ?
C59 H59 0.9500 . ?
C60 N15 1.355(13) . ?
C60 H60 0.9500 . ?
C61 O18 1.25(3) . ?
C61 O17 1.26(3) . ?
C61 C62 1.49(3) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 O15 1.26(2) . ?
C63 O16 1.26(2) . ?
C63 C64 1.49(2) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 O19 1.26(3) . ?
C65 O20 1.29(3) . ?
C65 C66 1.55(3) . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C68 O22 1.38(3) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 Cl3 1.739(15) . ?
C69 Cl2 1.741(15) . ?
C69 Cl1 1.744(15) . ?
C69 H69 1.0000 . ?
N3 N4 1.386(17) . ?
N5 N6 1.363(18) . ?
N11 N12 1.42(2) . ?
N13 N14 1.38(2) . ?
O3 Dy2 2.238(9) 17_556 ?
O8 Dy1 2.513(10) 17_556 ?
O9 Dy1 2.454(10) 17_556 ?
O16 Dy4 2.337(13) 10_546 ?
O27 C72 1.297(12) . ?
O22 H22A 0.9500 . ?
O1W H1WA 0.8504 . ?
O1W H1WB 0.8499 . ?
O14 Dy5 2.203(11) 10_546 ?
O25 O26 0.78(3) 17_556 ?
O25 C70 1.283(13) . ?
O26 O25 0.78(3) 17_556 ?
O26 C70 0.96(4) 17_556 ?
O26 C70 1.304(17) . ?
O26 O26 1.74(4) 17_556 ?
O26 Dy1 2.36(3) 17_556 ?
C70 O26 0.96(4) 17_556 ?
C70 C70 1.22(5) 17_556 ?
C70 C71 1.496(14) . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 O27 1.297(12) 10_546 ?
C72 C73 1.52(3) . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O8 93.8(4) . . ?
O1 Dy1 O25 155.4(6) . . ?
O8 Dy1 O25 83.3(6) . . ?
O1 Dy1 O26 146.5(5) . 17_556 ?
O8 Dy1 O26 64.3(6) . 17_556 ?
O25 Dy1 O26 19.0(8) . 17_556 ?
O1 Dy1 O5 67.7(3) . . ?
O8 Dy1 O5 75.2(4) . . ?
O25 Dy1 O5 133.7(6) . . ?
O26 Dy1 O5 124.2(8) 17_556 . ?
O1 Dy1 O7 77.6(5) . . ?
O8 Dy1 O7 146.4(5) . . ?
O25 Dy1 O7 117.5(7) . . ?
O26 Dy1 O7 134.6(5) 17_556 . ?
O5 Dy1 O7 71.4(5) . . ?
O1 Dy1 O9 78.9(4) . 17_556 ?
O8 Dy1 O9 119.8(4) . 17_556 ?
O25 Dy1 O9 81.5(7) . 17_556 ?
O26 Dy1 O9 90.3(8) 17_556 17_556 ?
O5 Dy1 O9 144.6(4) . 17_556 ?
O7 Dy1 O9 90.7(5) . 17_556 ?
O1 Dy1 O6 121.3(6) . . ?
O8 Dy1 O6 144.8(5) . . ?
O25 Dy1 O6 66.4(8) . . ?
O26 Dy1 O6 85.0(7) 17_556 . ?
O5 Dy1 O6 112.8(5) . . ?
O7 Dy1 O6 51.9(6) . . ?
O9 Dy1 O6 74.5(5) 17_556 . ?
O1 Dy1 O8 83.6(3) . 17_556 ?
O8 Dy1 O8 67.6(4) . 17_556 ?
O25 Dy1 O8 72.7(6) . 17_556 ?
O26 Dy1 O8 65.2(6) 17_556 17_556 ?
O5 Dy1 O8 130.9(3) . 17_556 ?
O7 Dy1 O8 141.2(4) . 17_556 ?
O9 Dy1 O8 52.3(3) 17_556 17_556 ?
O6 Dy1 O8 116.1(5) . 17_556 ?
O1 Dy1 N1 131.2(4) . . ?
O8 Dy1 N1 85.4(4) . . ?
O25 Dy1 N1 73.0(6) . . ?
O26 Dy1 N1 74.7(7) 17_556 . ?
O5 Dy1 N1 65.0(4) . . ?
O7 Dy1 N1 76.9(5) . . ?
O9 Dy1 N1 141.7(4) 17_556 . ?
O6 Dy1 N1 69.4(5) . . ?
O8 Dy1 N1 138.3(4) 17_556 . ?
O1 Dy1 C30 81.4(4) . 17_556 ?
O8 Dy1 C30 93.8(4) . 17_556 ?
O25 Dy1 C30 74.6(6) . 17_556 ?
O26 Dy1 C30 75.7(8) 17_556 17_556 ?
O5 Dy1 C30 146.0(4) . 17_556 ?
O7 Dy1 C30 116.4(5) . 17_556 ?
O9 Dy1 C30 26.1(4) 17_556 17_556 ?
O6 Dy1 C30 94.8(5) . 17_556 ?
O8 Dy1 C30 26.2(4) 17_556 17_556 ?
N1 Dy1 C30 147.4(4) . 17_556 ?
O3 Dy2 O10 140.9(4) 17_556 . ?
O3 Dy2 O1W 145.3(4) 17_556 . ?
O10 Dy2 O1W 69.1(4) . . ?
O3 Dy2 O2 82.8(3) 17_556 . ?
O10 Dy2 O2 74.0(4) . . ?
O1W Dy2 O2 95.0(4) . . ?
O3 Dy2 O4 71.4(3) 17_556 . ?
O10 Dy2 O4 71.4(3) . . ?
O1W Dy2 O4 140.3(4) . . ?
O2 Dy2 O4 70.4(3) . . ?
O3 Dy2 O5 80.9(4) 17_556 . ?
O10 Dy2 O5 137.8(3) . . ?
O1W Dy2 O5 69.6(4) . . ?
O2 Dy2 O5 118.0(3) . . ?
O4 Dy2 O5 150.0(3) . . ?
O3 Dy2 O1 76.1(4) 17_556 . ?
O10 Dy2 O1 113.9(4) . . ?
O1W Dy2 O1 74.0(4) . . ?
O2 Dy2 O1 56.8(3) . . ?
O4 Dy2 O1 120.3(3) . . ?
O5 Dy2 O1 61.2(3) . . ?
O3 Dy2 N4 104.2(4) 17_556 . ?
O10 Dy2 N4 102.3(4) . . ?
O1W Dy2 N4 76.5(4) . . ?
O2 Dy2 N4 171.6(4) . . ?
O4 Dy2 N4 116.0(3) . . ?
O5 Dy2 N4 59.6(4) . . ?
O1 Dy2 N4 119.8(3) . . ?
O3 Dy2 N5 98.5(4) 17_556 . ?
O10 Dy2 N5 71.7(4) . . ?
O1W Dy2 N5 110.4(4) . . ?
O2 Dy2 N5 125.3(4) . . ?
O4 Dy2 N5 58.9(3) . . ?
O5 Dy2 N5 116.1(4) . . ?
O1 Dy2 N5 174.2(4) . . ?
N4 Dy2 N5 58.9(4) . . ?
O4 Dy3 O4 146.3(5) . 17_556 ?
O4 Dy3 O2 77.0(3) . 17_556 ?
O4 Dy3 O2 76.8(3) 17_556 17_556 ?
O4 Dy3 O2 76.8(3) . . ?
O4 Dy3 O2 77.0(3) 17_556 . ?
O2 Dy3 O2 76.9(5) 17_556 . ?
O4 Dy3 O11 74.3(4) . . ?
O4 Dy3 O11 120.2(4) 17_556 . ?
O2 Dy3 O11 145.8(4) 17_556 . ?
O2 Dy3 O11 78.7(4) . . ?
O4 Dy3 O11 120.2(4) . 17_556 ?
O4 Dy3 O11 74.4(4) 17_556 17_556 ?
O2 Dy3 O11 78.6(4) 17_556 17_556 ?
O2 Dy3 O11 145.8(4) . 17_556 ?
O11 Dy3 O11 132.6(6) . 17_556 ?
O4 Dy3 N7 66.9(4) . . ?
O4 Dy3 N7 143.1(4) 17_556 . ?
O2 Dy3 N7 109.7(4) 17_556 . ?
O2 Dy3 N7 139.8(4) . . ?
O11 Dy3 N7 75.5(4) . . ?
O11 Dy3 N7 71.7(4) 17_556 . ?
O4 Dy3 N7 143.1(4) . 17_556 ?
O4 Dy3 N7 66.9(4) 17_556 17_556 ?
O2 Dy3 N7 139.8(4) 17_556 17_556 ?
O2 Dy3 N7 109.7(4) . 17_556 ?
O11 Dy3 N7 71.7(4) . 17_556 ?
O11 Dy3 N7 75.5(4) 17_556 17_556 ?
N7 Dy3 N7 90.7(6) . 17_556 ?
O4 Dy3 Dy2 112.0(2) . 17_556 ?
O4 Dy3 Dy2 39.3(2) 17_556 17_556 ?
O2 Dy3 Dy2 37.5(2) 17_556 17_556 ?
O2 Dy3 Dy2 73.1(2) . 17_556 ?
O11 Dy3 Dy2 148.3(3) . 17_556 ?
O11 Dy3 Dy2 72.9(3) 17_556 17_556 ?
N7 Dy3 Dy2 136.1(3) . 17_556 ?
N7 Dy3 Dy2 104.6(3) 17_556 17_556 ?
O12 Dy4 O16 89.8(4) . 10_546 ?
O12 Dy4 O27 152.2(5) . . ?
O16 Dy4 O27 74.4(6) 10_546 . ?
O12 Dy4 O17 76.1(5) . . ?
O16 Dy4 O17 149.4(5) 10_546 . ?
O27 Dy4 O17 128.1(6) . . ?
O12 Dy4 O24 66.7(4) . . ?
O16 Dy4 O24 75.0(4) 10_546 . ?
O27 Dy4 O24 127.9(5) . . ?
O17 Dy4 O24 74.6(5) . . ?
O12 Dy4 O15 78.3(4) . . ?
O16 Dy4 O15 121.5(4) 10_546 . ?
O27 Dy4 O15 90.5(5) . . ?
O17 Dy4 O15 82.5(5) . . ?
O24 Dy4 O15 141.6(4) . . ?
O12 Dy4 O16 81.5(4) . . ?
O16 Dy4 O16 69.7(5) 10_546 . ?
O27 Dy4 O16 71.7(5) . . ?
O17 Dy4 O16 132.5(5) . . ?
O24 Dy4 O16 132.0(4) . . ?
O15 Dy4 O16 52.0(4) . . ?
O12 Dy4 O18 122.2(5) . . ?
O16 Dy4 O18 148.1(6) 10_546 . ?
O27 Dy4 O18 76.4(6) . . ?
O17 Dy4 O18 52.6(6) . . ?
O24 Dy4 O18 114.6(5) . . ?
O15 Dy4 O18 71.1(5) . . ?
O16 Dy4 O18 112.6(5) . . ?
O12 Dy4 N9 128.1(4) . . ?
O16 Dy4 N9 90.3(6) 10_546 . ?
O27 Dy4 N9 75.7(5) . . ?
O17 Dy4 N9 78.1(6) . . ?
O24 Dy4 N9 63.4(4) . . ?
O15 Dy4 N9 140.7(5) . . ?
O16 Dy4 N9 145.2(5) . . ?
O18 Dy4 N9 70.0(6) . . ?
O12 Dy4 Dy4 83.2(3) . 10_546 ?
O16 Dy4 Dy4 36.1(3) 10_546 10_546 ?
O27 Dy4 Dy4 70.4(4) . 10_546 ?
O17 Dy4 Dy4 157.7(4) . 10_546 ?
O24 Dy4 Dy4 104.8(3) . 10_546 ?
O15 Dy4 Dy4 85.4(3) . 10_546 ?
O16 Dy4 Dy4 33.6(3) . 10_546 ?
O18 Dy4 Dy4 138.9(4) . 10_546 ?
N9 Dy4 Dy4 122.1(4) . 10_546 ?
O14 Dy5 O19 140.6(5) 10_546 . ?
O14 Dy5 O22 143.5(5) 10_546 . ?
O19 Dy5 O22 70.6(5) . . ?
O14 Dy5 O13 85.4(4) 10_546 . ?
O19 Dy5 O13 75.9(5) . . ?
O22 Dy5 O13 87.0(5) . . ?
O14 Dy5 O23 70.9(4) 10_546 . ?
O19 Dy5 O23 70.3(5) . . ?
O22 Dy5 O23 138.9(5) . . ?
O13 Dy5 O23 71.5(4) . . ?
O14 Dy5 O24 82.6(4) 10_546 . ?
O19 Dy5 O24 136.9(4) . . ?
O22 Dy5 O24 69.7(4) . . ?
O13 Dy5 O24 117.7(4) . . ?
O23 Dy5 O24 151.4(4) . . ?
O14 Dy5 N12 104.8(5) 10_546 . ?
O19 Dy5 N12 98.2(5) . . ?
O22 Dy5 N12 81.9(5) . . ?
O13 Dy5 N12 168.7(5) . . ?
O23 Dy5 N12 115.9(4) . . ?
O24 Dy5 N12 60.3(4) . . ?
O14 Dy5 O12 75.4(4) 10_546 . ?
O19 Dy5 O12 119.5(5) . . ?
O22 Dy5 O12 70.5(4) . . ?
O13 Dy5 O12 57.6(4) . . ?
O23 Dy5 O12 120.1(4) . . ?
O24 Dy5 O12 60.1(4) . . ?
N12 Dy5 O12 119.8(4) . . ?
O14 Dy5 N13 95.4(5) 10_546 . ?
O19 Dy5 N13 69.3(5) . . ?
O22 Dy5 N13 117.8(5) . . ?
O13 Dy5 N13 125.1(5) . . ?
O23 Dy5 N13 57.5(4) . . ?
O24 Dy5 N13 116.8(4) . . ?
N12 Dy5 N13 59.6(5) . . ?
O12 Dy5 N13 170.4(4) . . ?
O23 Dy6 O23 147.1(6) 10_546 . ?
O23 Dy6 O13 77.0(4) 10_546 . ?
O23 Dy6 O13 77.4(4) . . ?
O23 Dy6 O13 77.4(4) 10_546 10_546 ?
O23 Dy6 O13 77.0(4) . 10_546 ?
O13 Dy6 O13 76.7(6) . 10_546 ?
O23 Dy6 O20 71.8(5) 10_546 10_546 ?
O23 Dy6 O20 122.9(5) . 10_546 ?
O13 Dy6 O20 144.4(5) . 10_546 ?
O13 Dy6 O20 80.1(5) 10_546 10_546 ?
O23 Dy6 O20 122.9(5) 10_546 . ?
O23 Dy6 O20 71.8(5) . . ?
O13 Dy6 O20 80.1(5) . . ?
O13 Dy6 O20 144.4(5) 10_546 . ?
O20 Dy6 O20 131.8(8) 10_546 . ?
O23 Dy6 N15 65.4(4) 10_546 10_546 ?
O23 Dy6 N15 143.0(4) . 10_546 ?
O13 Dy6 N15 107.0(6) . 10_546 ?
O13 Dy6 N15 140.1(4) 10_546 10_546 ?
O20 Dy6 N15 75.0(6) 10_546 10_546 ?
O20 Dy6 N15 72.9(5) . 10_546 ?
O23 Dy6 N15 143.0(4) 10_546 . ?
O23 Dy6 N15 65.4(4) . . ?
O13 Dy6 N15 140.1(4) . . ?
O13 Dy6 N15 107.0(6) 10_546 . ?
O20 Dy6 N15 72.9(5) 10_546 . ?
O20 Dy6 N15 75.0(6) . . ?
N15 Dy6 N15 95.0(8) 10_546 . ?
O23 Dy6 Dy5 40.5(3) 10_546 10_546 ?
O23 Dy6 Dy5 111.4(3) . 10_546 ?
O13 Dy6 Dy5 72.7(3) . 10_546 ?
O13 Dy6 Dy5 36.9(3) 10_546 10_546 ?
O20 Dy6 Dy5 72.5(4) 10_546 10_546 ?
O20 Dy6 Dy5 150.8(4) . 10_546 ?
N15 Dy6 Dy5 104.8(3) 10_546 10_546 ?
N15 Dy6 Dy5 133.6(5) . 10_546 ?
O3 P1 O1 114.3(6) . . ?
O3 P1 O2 114.8(6) . . ?
O1 P1 O2 102.8(6) . . ?
O3 P1 C1 108.2(7) . . ?
O1 P1 C1 107.8(7) . . ?
O2 P1 C1 108.6(6) . . ?
O14 P2 O12 114.0(7) . . ?
O14 P2 O13 115.7(7) . . ?
O12 P2 O13 102.8(6) . . ?
O14 P2 C34 107.9(7) . . ?
O12 P2 C34 106.6(7) . . ?
O13 P2 C34 109.4(8) . . ?
C2 C1 P1 117.4(12) . . ?
C2 C1 H1A 107.9 . . ?
P1 C1 H1A 107.9 . . ?
C2 C1 H1B 107.9 . . ?
P1 C1 H1B 107.9 . . ?
H1A C1 H1B 107.2 . . ?
C15 C2 C3 118.2(13) . . ?
C15 C2 C1 121.4(12) . . ?
C3 C2 C1 120.3(12) . . ?
C4 C3 C8 115.9(13) . . ?
C4 C3 C2 122.1(13) . . ?
C8 C3 C2 122.0(13) . . ?
C5 C4 C3 123.1(17) . . ?
C5 C4 H4 118.5 . . ?
C3 C4 H4 118.5 . . ?
C6 C5 C4 119(2) . . ?
C6 C5 H5 120.7 . . ?
C4 C5 H5 120.7 . . ?
C7 C6 C5 121(2) . . ?
C7 C6 H6 119.7 . . ?
C5 C6 H6 119.7 . . ?
C6 C7 C8 118.4(18) . . ?
C6 C7 H7 120.8 . . ?
C8 C7 H7 120.8 . . ?
C9 C8 C3 118.6(14) . . ?
C9 C8 C7 118.4(14) . . ?
C3 C8 C7 123.1(15) . . ?
C10 C9 C8 120.5(15) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C9 C10 C11 118.3(14) . . ?
C9 C10 C15 120.0(14) . . ?
C11 C10 C15 121.6(14) . . ?
C12 C11 C10 118.7(17) . . ?
C12 C11 H11 120.6 . . ?
C10 C11 H11 120.6 . . ?
C11 C12 C13 120.5(18) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C14 C13 C12 120.2(18) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C13 C14 C15 120.3(16) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C14 C15 C2 120.8(12) . . ?
C14 C15 C10 118.6(13) . . ?
C2 C15 C10 120.6(13) . . ?
N1 C16 C17 121.2(17) . . ?
N1 C16 H16 119.4 . . ?
C17 C16 H16 119.4 . . ?
N2 C17 C16 123(2) . . ?
N2 C17 H17 118.7 . . ?
C16 C17 H17 118.7 . . ?
N2 C18 C19 119.5(15) . . ?
N2 C18 H18 120.3 . . ?
C19 C18 H18 120.3 . . ?
N1 C19 C18 123.6(17) . . ?
N1 C19 C20 115.9(16) . . ?
C18 C19 C20 120.4(15) . . ?
O5 C20 N3 128.2(14) . . ?
O5 C20 C19 116.5(14) . . ?
N3 C20 C19 115.0(13) . . ?
N4 C21 C22 118.1(14) . . ?
N4 C21 H21 121.0 . . ?
C22 C21 H21 121.0 . . ?
N5 C22 C21 116.3(16) . . ?
N5 C22 H22 121.9 . . ?
C21 C22 H22 121.9 . . ?
O4 C23 N6 125.9(14) . . ?
O4 C23 C24 118.0(13) . . ?
N6 C23 C24 115.9(12) . . ?
N7 C24 C25 120.8(14) . . ?
N7 C24 C23 114.9(13) . . ?
C25 C24 C23 124.3(14) . . ?
N8 C25 C24 122.2(16) . . ?
N8 C25 H25 118.9 . . ?
C24 C25 H25 118.9 . . ?
N8 C26 C27 123.8(17) . . ?
N8 C26 H26 118.1 . . ?
C27 C26 H26 118.1 . . ?
N7 C27 C26 120.1(17) . . ?
N7 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
O7 C28 O6 121(3) . . ?
O7 C28 C29 119(2) . . ?
O6 C28 C29 119.9(19) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
O8 C30 O9 120.5(13) . . ?
O8 C30 C31 119.4(14) . . ?
O9 C30 C31 119.9(13) . . ?
O8 C30 Dy1 61.7(7) . 17_556 ?
O9 C30 Dy1 59.0(7) . 17_556 ?
C31 C30 Dy1 172.3(11) . 17_556 ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
O10 C32 O11 125.0(13) . . ?
O10 C32 C33 117.8(16) . . ?
O11 C32 C33 117.1(15) . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C35 C34 P2 111.9(12) . . ?
C35 C34 H34A 109.2 . . ?
P2 C34 H34A 109.2 . . ?
C35 C34 H34B 109.2 . . ?
P2 C34 H34B 109.2 . . ?
H34A C34 H34B 107.9 . . ?
C48 C35 C36 121.2(19) . . ?
C48 C35 C34 119.1(16) . . ?
C36 C35 C34 119.6(16) . . ?
C35 C36 C41 120.4(16) . . ?
C35 C36 C37 124.7(16) . . ?
C41 C36 C37 114.9(16) . . ?
C38 C37 C36 124.7(19) . . ?
C38 C37 H37 117.6 . . ?
C36 C37 H37 117.6 . . ?
C39 C38 C37 117(2) . . ?
C39 C38 H38 121.4 . . ?
C37 C38 H38 121.4 . . ?
C40 C39 C38 121(2) . . ?
C40 C39 H39 119.5 . . ?
C38 C39 H39 119.5 . . ?
C39 C40 C41 119(2) . . ?
C39 C40 H40 120.5 . . ?
C41 C40 H40 120.5 . . ?
C42 C41 C40 120.3(19) . . ?
C42 C41 C36 116.8(17) . . ?
C40 C41 C36 122.9(18) . . ?
C41 C42 C43 124(2) . . ?
C41 C42 H42 118.0 . . ?
C43 C42 H42 118.0 . . ?
C48 C43 C42 118(2) . . ?
C48 C43 C44 121(2) . . ?
C42 C43 C44 120(2) . . ?
C45 C44 C43 118(3) . . ?
C45 C44 H44 120.9 . . ?
C43 C44 H44 120.9 . . ?
C44 C45 C46 122(3) . . ?
C44 C45 H45 119.2 . . ?
C46 C45 H45 119.2 . . ?
C47 C46 C45 119(3) . . ?
C47 C46 H46 120.7 . . ?
C45 C46 H46 120.7 . . ?
C46 C47 C48 121(3) . . ?
C46 C47 H47 119.6 . . ?
C48 C47 H47 119.6 . . ?
C43 C48 C47 119(2) . . ?
C43 C48 C35 119(2) . . ?
C47 C48 C35 122(2) . . ?
N9 C49 C50 125.2(19) . . ?
N9 C49 H49 117.4 . . ?
C50 C49 H49 117.4 . . ?
N10 C50 C49 121(2) . . ?
N10 C50 H50 119.4 . . ?
C49 C50 H50 119.4 . . ?
N10 C51 C52 127.4(18) . . ?
N10 C51 H51 116.3 . . ?
C52 C51 H51 116.3 . . ?
N9 C52 C51 119.0(17) . . ?
N9 C52 C53 115.7(13) . . ?
C51 C52 C53 125.2(15) . . ?
N11 C53 O24 129.1(16) . . ?
N11 C53 C52 115.6(14) . . ?
O24 C53 C52 115.2(14) . . ?
N12 C54 C55 118.2(19) . . ?
N12 C54 H54 120.9 . . ?
C55 C54 H54 120.9 . . ?
N13 C55 C54 114.7(19) . . ?
N13 C55 H55 122.7 . . ?
C54 C55 H55 122.7 . . ?
O23 C56 N14 125.1(17) . . ?
O23 C56 C57 117.7(14) . . ?
N14 C56 C57 117.1(15) . . ?
N15 C57 C58 120.1(18) . . ?
N15 C57 C56 113.9(14) . . ?
C58 C57 C56 126.0(15) . . ?
C57 C58 N16 125(2) . . ?
C57 C58 H58 117.6 . . ?
N16 C58 H58 117.6 . . ?
N16 C59 C60 126(2) . . ?
N16 C59 H59 116.9 . . ?
C60 C59 H59 116.9 . . ?
C59 C60 N15 119(2) . . ?
C59 C60 H60 120.6 . . ?
N15 C60 H60 120.6 . . ?
O18 C61 O17 121(2) . . ?
O18 C61 C62 123(3) . . ?
O17 C61 C62 117(3) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O15 C63 O16 119.8(17) . . ?
O15 C63 C64 119.3(17) . . ?
O16 C63 C64 121.0(16) . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O19 C65 O20 128.9(19) . . ?
O19 C65 C66 114(2) . . ?
O20 C65 C66 117(2) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
O22 C68 H68A 109.5 . . ?
O22 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
O22 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
Cl3 C69 Cl2 108.9(15) . . ?
Cl3 C69 Cl1 112.1(16) . . ?
Cl2 C69 Cl1 109.6(13) . . ?
Cl3 C69 H69 108.7 . . ?
Cl2 C69 H69 108.7 . . ?
Cl1 C69 H69 108.7 . . ?
C16 N1 C19 116.0(15) . . ?
C16 N1 Dy1 127.0(12) . . ?
C19 N1 Dy1 116.4(11) . . ?
C17 N2 C18 117.0(16) . . ?
C20 N3 N4 109.0(11) . . ?
C21 N4 N3 115.7(12) . . ?
C21 N4 Dy2 122.5(10) . . ?
N3 N4 Dy2 121.5(8) . . ?
C22 N5 N6 116.9(14) . . ?
C22 N5 Dy2 121.9(12) . . ?
N6 N5 Dy2 119.8(9) . . ?
C23 N6 N5 110.3(12) . . ?
C27 N7 C24 118.2(14) . . ?
C27 N7 Dy3 126.6(11) . . ?
C24 N7 Dy3 114.0(9) . . ?
C26 N8 C25 115.0(15) . . ?
C52 N9 C49 114.6(17) . . ?
C52 N9 Dy4 118.3(11) . . ?
C49 N9 Dy4 126.4(12) . . ?
C51 N10 C50 112.5(17) . . ?
C53 N11 N12 110.0(14) . . ?
C54 N12 N11 114.1(17) . . ?
C54 N12 Dy5 124.5(14) . . ?
N11 N12 Dy5 121.3(11) . . ?
C55 N13 N14 115.5(16) . . ?
C55 N13 Dy5 122.4(14) . . ?
N14 N13 Dy5 121.6(11) . . ?
C56 N14 N13 110.1(16) . . ?
C57 N15 C60 117.9(18) . . ?
C57 N15 Dy6 114.9(11) . . ?
C60 N15 Dy6 126.8(13) . . ?
C59 N16 C58 112.1(19) . . ?
P1 O1 Dy1 145.1(6) . . ?
P1 O1 Dy2 96.9(5) . . ?
Dy1 O1 Dy2 116.1(4) . . ?
P1 O2 Dy3 136.6(6) . . ?
P1 O2 Dy2 103.4(5) . . ?
Dy3 O2 Dy2 107.4(4) . . ?
P1 O3 Dy2 138.8(6) . 17_556 ?
C23 O4 Dy3 121.6(9) . . ?
C23 O4 Dy2 120.9(9) . . ?
Dy3 O4 Dy2 105.4(4) . . ?
C20 O5 Dy1 124.2(9) . . ?
C20 O5 Dy2 119.5(9) . . ?
Dy1 O5 Dy2 114.0(4) . . ?
C28 O6 Dy1 91.8(16) . . ?
C28 O7 Dy1 95.5(16) . . ?
C30 O8 Dy1 155.3(10) . . ?
C30 O8 Dy1 92.1(8) . 17_556 ?
Dy1 O8 Dy1 112.3(4) . 17_556 ?
C30 O9 Dy1 94.9(9) . 17_556 ?
C32 O10 Dy2 139.4(10) . . ?
C32 O11 Dy3 133.5(9) . . ?
P2 O12 Dy4 144.9(7) . . ?
P2 O12 Dy5 96.5(6) . . ?
Dy4 O12 Dy5 118.5(5) . . ?
P2 O13 Dy6 135.4(7) . . ?
P2 O13 Dy5 103.0(6) . . ?
Dy6 O13 Dy5 107.3(5) . . ?
C63 O15 Dy4 94.6(11) . . ?
C63 O16 Dy4 155.3(13) . 10_546 ?
C63 O16 Dy4 93.6(11) . . ?
Dy4 O16 Dy4 110.2(5) 10_546 . ?
C61 O17 Dy4 95.3(15) . . ?
C61 O18 Dy4 91.0(14) . . ?
C65 O19 Dy5 137.6(14) . . ?
C65 O20 Dy6 130.7(13) . . ?
C72 O27 Dy4 132.9(18) . . ?
C68 O22 Dy5 131(2) . . ?
C68 O22 H22A 114.5 . . ?
Dy5 O22 H22A 114.5 . . ?
C56 O23 Dy6 122.1(11) . . ?
C56 O23 Dy5 122.4(10) . . ?
Dy6 O23 Dy5 103.7(5) . . ?
C53 O24 Dy4 126.6(11) . . ?
C53 O24 Dy5 117.0(11) . . ?
Dy4 O24 Dy5 114.2(4) . . ?
Dy2 O1W H1WA 109.2 . . ?
Dy2 O1W H1WB 109.3 . . ?
H1WA O1W H1WB 109.5 . . ?
P2 O14 Dy5 136.9(7) . 10_546 ?
O26 O25 C70 49(3) 17_556 . ?
O26 O25 Dy1 83(3) 17_556 . ?
C70 O25 Dy1 115.7(17) . . ?
O25 O26 C70 94(4) 17_556 17_556 ?
O25 O26 C70 147(4) 17_556 . ?
C70 O26 C70 63(3) 17_556 . ?
O25 O26 O26 141(5) 17_556 17_556 ?
C70 O26 O26 47.6(18) 17_556 17_556 ?
C70 O26 O26 33.2(16) . 17_556 ?
O25 O26 Dy1 77(3) 17_556 17_556 ?
C70 O26 Dy1 133(3) 17_556 17_556 ?
C70 O26 Dy1 135.7(14) . 17_556 ?
O26 O26 Dy1 118.5(4) 17_556 17_556 ?
O26 C70 C70 72(3) 17_556 17_556 ?
O26 C70 O25 37.1(19) 17_556 . ?
C70 C70 O25 106(3) 17_556 . ?
O26 C70 O26 99(3) 17_556 . ?
C70 C70 O26 44.9(19) 17_556 . ?
O25 C70 O26 135(3) . . ?
O26 C70 C71 147.1(19) 17_556 . ?
C70 C70 C71 124.5(19) 17_556 . ?
O25 C70 C71 112.3(16) . . ?
O26 C70 C71 112.3(15) . . ?
C70 C71 H71A 109.5 . . ?
C70 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C70 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
O27 C72 O27 133(3) 10_546 . ?
O27 C72 C73 113.6(15) 10_546 . ?
O27 C72 C73 113.6(15) . . ?
C72 C73 H73A 109.5 . . ?
C72 C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
C72 C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 P1 C1 C2 -57.0(13) . . . . ?
O1 P1 C1 C2 178.9(10) . . . . ?
O2 P1 C1 C2 68.2(12) . . . . ?
P1 C1 C2 C15 82.1(19) . . . . ?
P1 C1 C2 C3 -94.5(18) . . . . ?
C15 C2 C3 C4 -179.2(18) . . . . ?
C1 C2 C3 C4 -2(3) . . . . ?
C15 C2 C3 C8 4(3) . . . . ?
C1 C2 C3 C8 -179.7(17) . . . . ?
C8 C3 C4 C5 3(3) . . . . ?
C2 C3 C4 C5 -175(2) . . . . ?
C3 C4 C5 C6 -5(3) . . . . ?
C4 C5 C6 C7 3(4) . . . . ?
C5 C6 C7 C8 1(4) . . . . ?
C4 C3 C8 C9 -178(2) . . . . ?
C2 C3 C8 C9 0(3) . . . . ?
C4 C3 C8 C7 2(3) . . . . ?
C2 C3 C8 C7 179.4(19) . . . . ?
C6 C7 C8 C9 176(2) . . . . ?
C6 C7 C8 C3 -4(3) . . . . ?
C3 C8 C9 C10 -3(3) . . . . ?
C7 C8 C9 C10 178(2) . . . . ?
C8 C9 C10 C11 -178(2) . . . . ?
C8 C9 C10 C15 2(3) . . . . ?
C9 C10 C11 C12 -179(2) . . . . ?
C15 C10 C11 C12 0(4) . . . . ?
C10 C11 C12 C13 1(4) . . . . ?
C11 C12 C13 C14 -2(4) . . . . ?
C12 C13 C14 C15 1(3) . . . . ?
C13 C14 C15 C2 178(2) . . . . ?
C13 C14 C15 C10 0(3) . . . . ?
C3 C2 C15 C14 178.7(17) . . . . ?
C1 C2 C15 C14 2(3) . . . . ?
C3 C2 C15 C10 -4(3) . . . . ?
C1 C2 C15 C10 179.4(18) . . . . ?
C9 C10 C15 C14 178(2) . . . . ?
C11 C10 C15 C14 -1(3) . . . . ?
C9 C10 C15 C2 1(3) . . . . ?
C11 C10 C15 C2 -178(2) . . . . ?
N1 C16 C17 N2 2(4) . . . . ?
N2 C18 C19 N1 0(3) . . . . ?
N2 C18 C19 C20 -177.9(19) . . . . ?
N1 C19 C20 O5 0(2) . . . . ?
C18 C19 C20 O5 178.1(17) . . . . ?
N1 C19 C20 N3 -174.5(15) . . . . ?
C18 C19 C20 N3 4(2) . . . . ?
N4 C21 C22 N5 0(3) . . . . ?
O4 C23 C24 N7 8(2) . . . . ?
N6 C23 C24 N7 -167.3(15) . . . . ?
O4 C23 C24 C25 -174.0(16) . . . . ?
N6 C23 C24 C25 10(3) . . . . ?
N7 C24 C25 N8 -1(3) . . . . ?
C23 C24 C25 N8 -178.1(18) . . . . ?
N8 C26 C27 N7 -2(3) . . . . ?
O14 P2 C34 C35 -66.8(13) . . . . ?
O12 P2 C34 C35 170.3(11) . . . . ?
O13 P2 C34 C35 59.9(13) . . . . ?
P2 C34 C35 C48 -95(2) . . . . ?
P2 C34 C35 C36 87.9(19) . . . . ?
C48 C35 C36 C41 1(3) . . . . ?
C34 C35 C36 C41 177.6(18) . . . . ?
C48 C35 C36 C37 -177(2) . . . . ?
C34 C35 C36 C37 -1(3) . . . . ?
C35 C36 C37 C38 177(2) . . . . ?
C41 C36 C37 C38 -1(3) . . . . ?
C36 C37 C38 C39 4(3) . . . . ?
C37 C38 C39 C40 -4(4) . . . . ?
C38 C39 C40 C41 0(4) . . . . ?
C39 C40 C41 C42 -178(2) . . . . ?
C39 C40 C41 C36 4(4) . . . . ?
C35 C36 C41 C42 0(3) . . . . ?
C37 C36 C41 C42 178(2) . . . . ?
C35 C36 C41 C40 178(2) . . . . ?
C37 C36 C41 C40 -3(3) . . . . ?
C40 C41 C42 C43 -179(3) . . . . ?
C36 C41 C42 C43 0(4) . . . . ?
C41 C42 C43 C48 0(5) . . . . ?
C41 C42 C43 C44 -179(3) . . . . ?
C48 C43 C44 C45 -2(5) . . . . ?
C42 C43 C44 C45 178(3) . . . . ?
C43 C44 C45 C46 3(6) . . . . ?
C44 C45 C46 C47 -6(6) . . . . ?
C45 C46 C47 C48 7(5) . . . . ?
C42 C43 C48 C47 -176(3) . . . . ?
C44 C43 C48 C47 3(5) . . . . ?
C42 C43 C48 C35 1(4) . . . . ?
C44 C43 C48 C35 180(3) . . . . ?
C46 C47 C48 C43 -7(5) . . . . ?
C46 C47 C48 C35 177(3) . . . . ?
C36 C35 C48 C43 -1(4) . . . . ?
C34 C35 C48 C43 -178(2) . . . . ?
C36 C35 C48 C47 175(3) . . . . ?
C34 C35 C48 C47 -2(4) . . . . ?
N9 C49 C50 N10 1(4) . . . . ?
N10 C51 C52 N9 -1(3) . . . . ?
N10 C51 C52 C53 175.8(19) . . . . ?
N9 C52 C53 N11 -179.7(18) . . . . ?
C51 C52 C53 N11 3(3) . . . . ?
N9 C52 C53 O24 -3(3) . . . . ?
C51 C52 C53 O24 179.7(18) . . . . ?
N12 C54 C55 N13 -1(3) . . . . ?
O23 C56 C57 N15 14(3) . . . . ?
N14 C56 C57 N15 -170(2) . . . . ?
O23 C56 C57 C58 -164(2) . . . . ?
N14 C56 C57 C58 11(4) . . . . ?
N15 C57 C58 N16 3(4) . . . . ?
C56 C57 C58 N16 -178(2) . . . . ?
N16 C59 C60 N15 -3(5) . . . . ?
C17 C16 N1 C19 -1(3) . . . . ?
C17 C16 N1 Dy1 -171.7(17) . . . . ?
C18 C19 N1 C16 0(3) . . . . ?
C20 C19 N1 C16 177.9(18) . . . . ?
C18 C19 N1 Dy1 171.6(16) . . . . ?
C20 C19 N1 Dy1 -10.3(19) . . . . ?
C16 C17 N2 C18 -2(4) . . . . ?
C19 C18 N2 C17 1(4) . . . . ?
O5 C20 N3 N4 0(2) . . . . ?
C19 C20 N3 N4 173.9(13) . . . . ?
C22 C21 N4 N3 174.3(16) . . . . ?
C22 C21 N4 Dy2 -12(2) . . . . ?
C20 N3 N4 C21 -174.5(15) . . . . ?
C20 N3 N4 Dy2 11.8(17) . . . . ?
C21 C22 N5 N6 178.8(16) . . . . ?
C21 C22 N5 Dy2 12(2) . . . . ?
O4 C23 N6 N5 3(2) . . . . ?
C24 C23 N6 N5 178.1(14) . . . . ?
C22 N5 N6 C23 175.5(18) . . . . ?
Dy2 N5 N6 C23 -17.8(18) . . . . ?
C26 C27 N7 C24 3(3) . . . . ?
C26 C27 N7 Dy3 169.4(15) . . . . ?
C25 C24 N7 C27 -1(2) . . . . ?
C23 C24 N7 C27 176.6(15) . . . . ?
C25 C24 N7 Dy3 -169.6(14) . . . . ?
C23 C24 N7 Dy3 8.2(17) . . . . ?
C27 C26 N8 C25 1(3) . . . . ?
C24 C25 N8 C26 1(3) . . . . ?
C51 C52 N9 C49 2(3) . . . . ?
C53 C52 N9 C49 -175.2(19) . . . . ?
C51 C52 N9 Dy4 173.5(14) . . . . ?
C53 C52 N9 Dy4 -4(2) . . . . ?
C50 C49 N9 C52 -2(4) . . . . ?
C50 C49 N9 Dy4 -173(2) . . . . ?
C52 C51 N10 C50 0(3) . . . . ?
C49 C50 N10 C51 0(4) . . . . ?
O24 C53 N11 N12 0(3) . . . . ?
C52 C53 N11 N12 176.1(15) . . . . ?
C55 C54 N12 N11 173.3(16) . . . . ?
C55 C54 N12 Dy5 -6(3) . . . . ?
C53 N11 N12 C54 -166.5(18) . . . . ?
C53 N11 N12 Dy5 12.4(19) . . . . ?
C54 C55 N13 N14 179.3(16) . . . . ?
C54 C55 N13 Dy5 7(2) . . . . ?
O23 C56 N14 N13 -4(3) . . . . ?
C57 C56 N14 N13 -179.7(17) . . . . ?
C55 N13 N14 C56 176.2(17) . . . . ?
Dy5 N13 N14 C56 -11(2) . . . . ?
C58 C57 N15 C60 -3(4) . . . . ?
C56 C57 N15 C60 178(2) . . . . ?
C58 C57 N15 Dy6 -177(2) . . . . ?
C56 C57 N15 Dy6 4(3) . . . . ?
C59 C60 N15 C57 3(4) . . . . ?
C59 C60 N15 Dy6 176(2) . . . . ?
C60 C59 N16 C58 2(5) . . . . ?
C57 C58 N16 C59 -2(4) . . . . ?
O3 P1 O1 Dy1 -38.8(13) . . . . ?
O2 P1 O1 Dy1 -163.8(10) . . . . ?
C1 P1 O1 Dy1 81.6(12) . . . . ?
O3 P1 O1 Dy2 122.8(5) . . . . ?
O2 P1 O1 Dy2 -2.2(6) . . . . ?
C1 P1 O1 Dy2 -116.8(6) . . . . ?
O3 P1 O2 Dy3 12.0(11) . . . . ?
O1 P1 O2 Dy3 136.7(8) . . . . ?
C1 P1 O2 Dy3 -109.2(9) . . . . ?
O3 P1 O2 Dy2 -122.3(6) . . . . ?
O1 P1 O2 Dy2 2.4(6) . . . . ?
C1 P1 O2 Dy2 116.5(6) . . . . ?
O1 P1 O3 Dy2 -109.4(10) . . . 17_556 ?
O2 P1 O3 Dy2 9.0(12) . . . 17_556 ?
C1 P1 O3 Dy2 130.5(10) . . . 17_556 ?
N6 C23 O4 Dy3 151.7(14) . . . . ?
C24 C23 O4 Dy3 -23.5(18) . . . . ?
N6 C23 O4 Dy2 15(2) . . . . ?
C24 C23 O4 Dy2 -160.6(10) . . . . ?
N3 C20 O5 Dy1 -174.3(12) . . . . ?
C19 C20 O5 Dy1 12.0(18) . . . . ?
N3 C20 O5 Dy2 -12(2) . . . . ?
C19 C20 O5 Dy2 174.0(10) . . . . ?
O7 C28 O6 Dy1 4(3) . . . . ?
C29 C28 O6 Dy1 -178(2) . . . . ?
O6 C28 O7 Dy1 -5(3) . . . . ?
C29 C28 O7 Dy1 177(2) . . . . ?
O9 C30 O8 Dy1 -167.1(15) . . . . ?
C31 C30 O8 Dy1 17(3) . . . . ?
Dy1 C30 O8 Dy1 -172(2) 17_556 . . . ?
O9 C30 O8 Dy1 4.6(15) . . . 17_556 ?
C31 C30 O8 Dy1 -171.3(13) . . . 17_556 ?
O8 C30 O9 Dy1 -4.7(15) . . . 17_556 ?
C31 C30 O9 Dy1 171.1(13) . . . 17_556 ?
O11 C32 O10 Dy2 11(3) . . . . ?
C33 C32 O10 Dy2 -167.5(12) . . . . ?
O10 C32 O11 Dy3 -7(3) . . . . ?
C33 C32 O11 Dy3 171.6(12) . . . . ?
O14 P2 O12 Dy4 -50.8(13) . . . . ?
O13 P2 O12 Dy4 -176.9(11) . . . . ?
C34 P2 O12 Dy4 68.1(13) . . . . ?
O14 P2 O12 Dy5 126.7(6) . . . . ?
O13 P2 O12 Dy5 0.6(6) . . . . ?
C34 P2 O12 Dy5 -114.4(7) . . . . ?
O14 P2 O13 Dy6 6.4(12) . . . . ?
O12 P2 O13 Dy6 131.4(9) . . . . ?
C34 P2 O13 Dy6 -115.6(10) . . . . ?
O14 P2 O13 Dy5 -125.6(6) . . . . ?
O12 P2 O13 Dy5 -0.6(7) . . . . ?
C34 P2 O13 Dy5 112.4(7) . . . . ?
O16 C63 O15 Dy4 -2(2) . . . . ?
C64 C63 O15 Dy4 177.7(18) . . . . ?
O15 C63 O16 Dy4 -163(2) . . . 10_546 ?
C64 C63 O16 Dy4 17(4) . . . 10_546 ?
O15 C63 O16 Dy4 2(2) . . . . ?
C64 C63 O16 Dy4 -177.8(18) . . . . ?
O18 C61 O17 Dy4 7(2) . . . . ?
C62 C61 O17 Dy4 -170.7(18) . . . . ?
O17 C61 O18 Dy4 -7(2) . . . . ?
C62 C61 O18 Dy4 171(2) . . . . ?
O20 C65 O19 Dy5 15(4) . . . . ?
C66 C65 O19 Dy5 -159.6(16) . . . . ?
O19 C65 O20 Dy6 -9(4) . . . . ?
C66 C65 O20 Dy6 165.7(16) . . . . ?
N14 C56 O23 Dy6 155.5(15) . . . . ?
C57 C56 O23 Dy6 -29(2) . . . . ?
N14 C56 O23 Dy5 19(2) . . . . ?
C57 C56 O23 Dy5 -165.8(14) . . . . ?
N11 C53 O24 Dy4 -174.1(15) . . . . ?
C52 C53 O24 Dy4 10(2) . . . . ?
N11 C53 O24 Dy5 -12(2) . . . . ?
C52 C53 O24 Dy5 171.9(12) . . . . ?
O12 P2 O14 Dy5 -100.1(11) . . . 10_546 ?
O13 P2 O14 Dy5 18.9(13) . . . 10_546 ?
C34 P2 O14 Dy5 141.7(10) . . . 10_546 ?
Dy1 O25 C70 O26 54(3) . . . 17_556 ?
O26 O25 C70 C70 25(3) 17_556 . . 17_556 ?
Dy1 O25 C70 C70 78.5(13) . . . 17_556 ?
O26 O25 C70 O26 -16(3) 17_556 . . . ?
Dy1 O25 C70 O26 38(2) . . . . ?
O26 O25 C70 C71 164(3) 17_556 . . . ?
Dy1 O25 C70 C71 -142(2) . . . . ?
O25 O26 C70 O26 104(8) 17_556 . . 17_556 ?
C70 O26 C70 O26 53(3) 17_556 . . 17_556 ?
Dy1 O26 C70 O26 -71(2) 17_556 . . 17_556 ?
O25 O26 C70 C70 51(6) 17_556 . . 17_556 ?
O26 O26 C70 C70 -53(3) 17_556 . . 17_556 ?
Dy1 O26 C70 C70 -125(3) 17_556 . . 17_556 ?
O25 O26 C70 O25 114(6) 17_556 . . . ?
C70 O26 C70 O25 63(2) 17_556 . . . ?
O26 O26 C70 O25 10(2) 17_556 . . . ?
Dy1 O26 C70 O25 -62(3) 17_556 . . . ?
O25 O26 C70 C71 -66(6) 17_556 . . . ?
C70 O26 C70 C71 -117(2) 17_556 . . . ?
O26 O26 C70 C71 -170(2) 17_556 . . . ?
Dy1 O26 C70 C71 118(3) 17_556 . . . ?
Dy4 O27 C72 O27 -4.4(10) . . . 10_546 ?
Dy4 O27 C72 C73 175.6(10) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WB N10 0.85 2.44 2.89(2) 113.9 1_455
O22 H22A O17 0.95 1.99 2.74(2) 134.2 .
C69 H69 N14 1.00 2.17 3.15(4) 166.6 .
C54 H54 O9 0.95 2.42 3.24(2) 144.3 17_656
C34 H34A O15 0.99 2.59 3.32(2) 130.6 .
C27 H27 N2 0.95 2.58 3.21(2) 123.6 18_546
C26 H26 N2 0.95 2.65 3.25(2) 121.6 18_546
C26 H26 Cl3 0.95 2.78 3.50(2) 133.9 16_546
C21 H21 N6 0.95 2.49 3.34(2) 149.1 3_565
C16 H16 O25 0.95 2.39 2.97(3) 119.4 .

_refine_diff_density_max         4.537
_refine_diff_density_min         -2.281
_refine_diff_density_rms         0.230

_shelxl_version_number           2013-4



