# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_LIFM-24(Pr)
_database_code_depnum_ccdc_archive 'CCDC 1819541'
_audit_update_record             
;
2018-01-26 deposited with the CCDC.
2018-03-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H64 N14 O26 Pr2'
_chemical_formula_sum            'C72 H64 N14 O26 Pr2'
_chemical_formula_weight         1823.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -2.4164 10.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           TRICLINIC
_symmetry_space_group_name_H-M   P-1
_space_group_name_Hall           '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.0807(3)
_cell_length_b                   11.0770(5)
_cell_length_c                   32.5012(13)
_cell_angle_alpha                91.153(4)
_cell_angle_beta                 94.764(3)
_cell_angle_gamma                91.904(3)
_cell_volume                     3613.7(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    2693
_cell_measurement_theta_min      3.2280
_cell_measurement_theta_max      62.1379

_exptl_crystal_description       PLATE
_exptl_crystal_colour            'LIGHT GREEN'
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.676
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1840
_exptl_absorpt_coefficient_mu    11.027
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_correction_T_min  0.306
_exptl_absorpt_correction_T_max  0.332
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            20664
_diffrn_reflns_av_R_equivalents  0.1153
_diffrn_reflns_av_sigmaI/netI    0.1221
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         2.73
_diffrn_reflns_theta_max         59.99
_reflns_number_total             10649
_reflns_number_gt                7364
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0120P)²+81.7947P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    GEOM
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10649
_refine_ls_number_parameters     977
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1126
_refine_ls_R_factor_gt           0.0640
_refine_ls_wR_factor_ref         0.1970
_refine_ls_wR_factor_gt          0.1556
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_restrained_S_all      1.076
_refine_ls_shift/su_max          0.041
_refine_ls_shift/su_mean         0.004

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pr1 Pr 0.65466(7) 0.60228(6) 0.37916(2) 0.0291(2) Uani 1 1 d . . .
Pr2 Pr 1.23090(7) 1.89817(6) 0.12322(2) 0.0303(2) Uani 1 1 d . . .
O4 O 1.3219(9) 1.8566(8) 0.0583(3) 0.037(2) Uiso 1 1 d . . .
O5 O 0.8142(9) 0.6271(8) 0.4396(3) 0.036(2) Uiso 1 1 d . . .
O7 O 1.0490(8) 1.7811(7) 0.1645(3) 0.032(2) Uani 1 1 d . . .
O8 O 0.6102(9) 0.4223(8) 0.3229(3) 0.039(2) Uani 1 1 d . . .
O9 O 1.2825(8) 1.6860(8) 0.1312(3) 0.037(2) Uani 1 1 d . . .
N10 N 0.6727(12) 0.3463(10) 0.4129(3) 0.038(3) Uani 1 1 d . . .
O11 O 1.2754(9) 1.9178(7) 0.2057(3) 0.034(2) Uani 1 1 d . . .
O12 O 0.5911(11) 0.5998(8) 0.2978(3) 0.048(3) Uani 1 1 d . . .
O13 O 0.7115(9) 0.8135(8) 0.3709(3) 0.035(2) Uani 1 1 d . . .
N14 N 0.5867(10) 0.4875(10) 0.2918(3) 0.029(2) Uani 1 1 d . . .
N15 N 1.3299(11) 2.0234(8) 0.2071(3) 0.028(2) Uani 1 1 d . . .
O16 O 1.3068(9) 2.0836(7) 0.1737(3) 0.033(2) Uani 1 1 d . . .
O17 O 1.3978(10) 2.0625(9) 0.2375(3) 0.046(2) Uani 1 1 d . . .
N19 N 0.9856(10) 1.8737(9) 0.1729(3) 0.031(3) Uani 1 1 d . . .
O20 O 0.7677(10) 0.3892(9) 0.3946(3) 0.046(2) Uani 1 1 d . . .
O22 O 0.8931(10) 1.8697(9) 0.1960(3) 0.050(3) Uani 1 1 d . . .
N23 N 0.3421(11) 0.9877(10) 0.4713(4) 0.039(3) Uani 1 1 d . . .
N24 N 1.2176(13) 2.1556(11) 0.0862(3) 0.041(3) Uani 1 1 d . . .
O25 O 0.4279(10) 0.7237(8) 0.3460(3) 0.043(2) Uani 1 1 d . . .
C26 C 0.8479(13) 0.7109(11) 0.6291(4) 0.030(3) Uiso 1 1 d . . .
O27 O 0.5785(9) 0.4138(8) 0.4197(3) 0.037(2) Uani 1 1 d . . .
N28 N 0.8634(10) 0.5898(9) 0.5642(3) 0.033(3) Uani 1 1 d . . .
O29 O 0.5309(9) 0.6892(8) 0.4340(3) 0.038(2) Uani 1 1 d . . .
O30 O 0.6739(15) 0.2407(9) 0.4238(3) 0.078(4) Uani 1 1 d . . .
N31 N 1.2710(10) 1.4242(9) 0.2178(3) 0.032(3) Uani 1 1 d . . .
O32 O 1.2099(15) 2.2607(10) 0.0786(4) 0.083(4) Uani 1 1 d . . .
C34 C 0.7199(14) 0.7357(10) 0.6377(4) 0.032(3) Uani 1 1 d . . .
H34 H 0.6507 0.6791 0.6314 0.039 Uiso 1 1 calc R . .
O35 O 1.1198(9) 2.0845(8) 0.0892(3) 0.039(2) Uani 1 1 d . . .
O37 O 1.0431(8) 1.8236(8) 0.0742(3) 0.034(2) Uani 1 1 d . . .
O38 O 0.5614(10) 0.4464(9) 0.2565(3) 0.043(2) Uani 1 1 d . . .
O39 O 1.0187(9) 1.9692(8) 0.1559(3) 0.043(2) Uani 1 1 d . . .
N40 N 1.2946(11) 1.9227(9) -0.0650(4) 0.038(3) Uani 1 1 d . . .
O41 O 1.3313(12) 2.1052(10) 0.0923(3) 0.059(3) Uani 1 1 d . . .
C42 C 1.2559(14) 1.8037(11) -0.1304(4) 0.033(3) Uani 1 1 d . . .
O43 O 0.2561(10) 0.6128(9) 0.3235(4) 0.054(3) Uani 1 1 d . . .
C45 C 0.9624(13) 0.6368(11) 0.5432(4) 0.035(3) Uani 1 1 d . . .
H45 H 1.0427 0.6605 0.5577 0.042 Uiso 1 1 calc R . .
N46 N 0.8600(12) 1.5172(9) 0.0245(4) 0.039(3) Uani 1 1 d . . .
C48 C 1.2895(13) 1.4777(11) 0.1483(4) 0.036(3) Uani 1 1 d . . .
H48 H 1.3016 1.4538 0.1213 0.043 Uiso 1 1 calc R . .
O49 O 0.4116(9) 0.5366(8) 0.3635(3) 0.040(2) Uiso 1 1 d . . .
C50 C 0.9247(14) 0.9040(13) 0.6559(4) 0.040(4) Uani 1 1 d . . .
H50 H 0.9935 0.9616 0.6614 0.049 Uiso 1 1 calc R . .
C51 C 0.4089(14) 0.7858(13) 0.4825(4) 0.042(4) Uani 1 1 d . . .
H51 H 0.4116 0.7192 0.4995 0.050 Uiso 1 1 calc R . .
C52 C 1.2785(12) 1.6049(11) 0.1585(4) 0.028(3) Uani 1 1 d . . .
C53 C 1.1102(11) 1.2965(11) 0.2519(4) 0.028(3) Uani 1 1 d . . .
C55 C 1.2834(14) 1.9261(11) -0.1105(4) 0.034(3) Uani 1 1 d . . .
H55A H 1.3656 1.9601 -0.1196 0.041 Uiso 1 1 calc R . .
H55B H 1.2121 1.9787 -0.1195 0.041 Uiso 1 1 calc R . .
C56 C 0.4695(13) 0.8934(11) 0.4227(4) 0.033(3) Uani 1 1 d . . .
H56 H 0.5121 0.8988 0.3984 0.040 Uiso 1 1 calc R . .
N57 N 0.3660(11) 0.6259(9) 0.3447(4) 0.037(3) Uani 1 1 d . . .
C58 C 0.9243(12) 1.1606(11) 0.2338(4) 0.031(3) Uani 1 1 d . . .
H58 H 0.8893 1.0910 0.2198 0.037 Uiso 1 1 calc R . .
C59 C 0.3445(14) 0.8847(13) 0.4939(5) 0.041(4) Uani 1 1 d . . .
H59 H 0.3002 0.8826 0.5179 0.049 Uiso 1 1 calc R . .
C60 C 1.2640(14) 1.5420(11) 0.2288(4) 0.037(3) Uani 1 1 d . . .
H60 H 1.2567 1.5625 0.2564 0.044 Uiso 1 1 calc R . .
C62 C 0.6853(13) 0.9711(11) 0.2750(4) 0.032(3) Uiso 1 1 d . . .
H62 H 0.6793 0.9542 0.2467 0.039 Uiso 1 1 calc R . .
C65 C 1.3567(15) 1.7404(13) -0.1462(5) 0.041(4) Uani 1 1 d . . .
H65 H 1.4424 1.7751 -0.1445 0.050 Uiso 1 1 calc R . .
C66 C 0.7014(13) 1.1883(11) 0.2596(4) 0.032(3) Uani 1 1 d . . .
H66A H 0.6527 1.2561 0.2692 0.038 Uiso 1 1 calc R . .
H66B H 0.6605 1.1627 0.2326 0.038 Uiso 1 1 calc R . .
C67 C 0.8274(13) 0.6150(10) 0.4782(4) 0.028(3) Uani 1 1 d . . .
N68 N 0.6912(10) 1.0881(9) 0.2884(3) 0.032(3) Uani 1 1 d . . .
C69 C 1.4091(14) 1.8750(11) -0.0459(5) 0.037(3) Uani 1 1 d . . .
H69 H 1.4792 1.8567 -0.0616 0.045 Uiso 1 1 calc R . .
C70 C 1.0284(14) 1.3654(11) 0.2738(4) 0.037(3) Uani 1 1 d . . .
H70 H 1.0632 1.4360 0.2872 0.045 Uiso 1 1 calc R . .
C71 C 0.4061(14) 0.9888(12) 0.4363(4) 0.037(3) Uani 1 1 d . . .
H71 H 0.4061 1.0589 0.4210 0.044 Uiso 1 1 calc R . .
C72 C 1.2554(13) 1.3292(11) 0.2490(4) 0.032(3) Uani 1 1 d . . .
H72A H 1.2950 1.3584 0.2757 0.039 Uiso 1 1 calc R . .
H72B H 1.3018 1.2579 0.2413 0.039 Uiso 1 1 calc R . .
C73 C 0.8477(14) 1.6248(13) 0.0045(5) 0.042(4) Uani 1 1 d . . .
H73 H 0.7937 1.6286 -0.0200 0.051 Uiso 1 1 calc R . .
C75 C 0.7464(14) 0.5553(12) 0.5432(5) 0.042(4) Uani 1 1 d . . .
H75 H 0.6781 0.5230 0.5576 0.050 Uiso 1 1 calc R . .
C77 C 0.9911(14) 1.7260(12) 0.0587(4) 0.036(3) Uani 1 1 d . . .
C78 C 1.1284(13) 1.7507(12) -0.1336(4) 0.034(3) Uani 1 1 d . . .
H78 H 1.0581 1.7916 -0.1237 0.041 Uiso 1 1 calc R . .
C79 C 1.0569(13) 1.1916(11) 0.2316(4) 0.034(3) Uani 1 1 d . . .
H79 H 1.1103 1.1431 0.2166 0.041 Uiso 1 1 calc R . .
C80 C 0.7039(12) 1.1114(12) 0.3300(4) 0.033(3) Uani 1 1 d . . .
H80 H 0.7087 1.1913 0.3394 0.040 Uiso 1 1 calc R . .
C81 C 0.9149(16) 1.7265(12) 0.0208(5) 0.050(4) Uani 1 1 d . . .
H81 H 0.9097 1.7978 0.0062 0.060 Uiso 1 1 calc R . .
C82 C 0.8420(14) 1.2280(11) 0.2558(4) 0.032(3) Uani 1 1 d . . .
C83 C 1.2089(13) 1.5760(11) -0.1665(4) 0.031(3) Uani 1 1 d . . .
C84 C 0.7097(12) 1.0225(11) 0.3579(4) 0.029(3) Uani 1 1 d . . .
H84 H 0.7169 1.0421 0.3860 0.035 Uiso 1 1 calc R . .
C85 C 1.2020(14) 1.9314(11) -0.0007(4) 0.035(3) Uani 1 1 d . . .
H85 H 1.1306 1.9525 0.0140 0.042 Uiso 1 1 calc R . .
C86 C 0.4724(14) 0.7815(12) 0.4453(4) 0.036(3) Uani 1 1 d . . .
C87 C 1.2823(13) 1.3948(11) 0.1773(4) 0.032(3) Uani 1 1 d . . .
H87 H 1.2850 1.3137 0.1697 0.039 Uiso 1 1 calc R . .
C88 C 0.9529(14) 0.7947(12) 0.6390(4) 0.036(3) Uiso 1 1 d . . .
H88 H 1.0398 0.7767 0.6342 0.043 Uiso 1 1 calc R . .
C89 C 1.0050(15) 1.6121(11) 0.0771(4) 0.040(3) Uani 1 1 d . . .
H89 H 1.0603 1.6055 0.1012 0.048 Uiso 1 1 calc R . .
C90 C 1.3142(14) 1.8812(11) 0.0205(4) 0.034(3) Uani 1 1 d . . .
C91 C 0.8781(15) 0.5877(11) 0.6094(4) 0.038(3) Uani 1 1 d . . .
H91A H 0.9684 0.5668 0.6185 0.045 Uiso 1 1 calc R . .
H91B H 0.8180 0.5259 0.6188 0.045 Uiso 1 1 calc R . .
C92 C 0.8971(13) 1.3331(11) 0.2766(4) 0.031(3) Uani 1 1 d . . .
H92 H 0.8445 1.3804 0.2922 0.038 Uiso 1 1 calc R . .
C93 C 1.3340(13) 1.6268(12) -0.1645(4) 0.037(3) Uani 1 1 d . . .
H93 H 1.4031 1.5860 -0.1752 0.044 Uiso 1 1 calc R . .
C94 C 1.1956(13) 1.9498(12) -0.0420(4) 0.036(3) Uani 1 1 d . . .
H94 H 1.1194 1.9825 -0.0548 0.043 Uiso 1 1 calc R . .
C95 C 0.6878(14) 0.8788(12) 0.3013(5) 0.039(3) Uani 1 1 d . . .
H95 H 0.6780 0.8001 0.2907 0.047 Uiso 1 1 calc R . .
C96 C 0.7266(13) 0.5666(12) 0.5020(4) 0.035(3) Uani 1 1 d . . .
H96 H 0.6447 0.5421 0.4887 0.042 Uiso 1 1 calc R . .
C98 C 0.9492(12) 0.6507(11) 0.5023(4) 0.031(3) Uani 1 1 d . . .
H98 H 1.0199 0.6839 0.4892 0.037 Uiso 1 1 calc R . .
C100 C 0.7964(13) 0.9323(12) 0.6654(4) 0.038(4) Uani 1 1 d . . .
C102 C 1.2672(13) 1.6312(12) 0.2010(4) 0.035(3) Uani 1 1 d . . .
H102 H 1.2619 1.7112 0.2099 0.042 Uiso 1 1 calc R . .
C105 C 0.7048(14) 0.8977(11) 0.3446(4) 0.036(3) Uani 1 1 d . . .
C107 C 0.9400(14) 1.5140(12) 0.0603(4) 0.038(3) Uani 1 1 d . . .
H107 H 0.9495 1.4408 0.0736 0.045 Uiso 1 1 calc R . .
C110 C 0.6957(14) 0.8456(12) 0.6559(4) 0.038(3) Uani 1 1 d . . .
H110 H 0.6094 0.8618 0.6620 0.046 Uiso 1 1 calc R . .
C114 C 1.4202(14) 1.8547(13) -0.0051(5) 0.042(4) Uani 1 1 d . . .
H114 H 1.4980 1.8229 0.0069 0.051 Uiso 1 1 calc R . .
C121 C 1.1063(13) 1.6359(11) -0.1517(4) 0.036(3) Uani 1 1 d . . .
H121 H 1.0212 1.6001 -0.1537 0.043 Uiso 1 1 calc R . .
N3 N 0.8637(11) 1.1466(10) 0.6780(3) 0.035(3) Uani 1 1 d . . .
C15 C 1.5463(14) 1.8148(11) 0.1516(5) 0.037(3) Uani 1 1 d . . .
C1 C 0.7672(13) 1.0507(11) 0.6857(4) 0.035(3) Uani 1 1 d . . .
H1A H 0.6789 1.0745 0.6756 0.042 Uiso 1 1 calc R . .
H1B H 0.7673 1.0399 0.7153 0.042 Uiso 1 1 calc R . .
C2 C 1.5577(13) 1.7707(11) 0.1923(4) 0.035(3) Uani 1 1 d . . .
H2 H 1.5047 1.8020 0.2117 0.042 Uiso 1 1 calc R . .
O1 O 1.4680(9) 1.9015(8) 0.1410(3) 0.042(2) Uiso 1 1 d . . .
N1 N 1.7250(11) 1.6386(9) 0.1763(3) 0.032(3) Uani 1 1 d . . .
C7 C 0.9717(11) 1.2686(11) 0.6306(4) 0.026(3) Uani 1 1 d . . .
H7 H 0.9772 1.2918 0.6035 0.032 Uiso 1 1 calc R . .
C10 C 1.0591(13) 1.3239(11) 0.6629(4) 0.031(3) Uiso 1 1 d . . .
C11 C 1.7202(14) 1.6784(11) 0.1373(4) 0.037(3) Uani 1 1 d . . .
H11 H 1.7770 1.6475 0.1189 0.044 Uiso 1 1 calc R . .
C12 C 0.8811(14) 1.1826(12) 0.6395(4) 0.039(3) Uani 1 1 d . . .
H12 H 0.8277 1.1462 0.6177 0.046 Uiso 1 1 calc R . .
C13 C 1.6440(12) 1.6841(11) 0.2035(4) 0.030(3) Uani 1 1 d . . .
H13 H 1.6478 1.6554 0.2303 0.036 Uiso 1 1 calc R . .
C16 C 1.0363(14) 1.2860(13) 0.7032(5) 0.040(3) Uiso 1 1 d . . .
H16 H 1.0873 1.3209 0.7258 0.048 Uiso 1 1 calc R . .
C18 C 1.6330(13) 1.7634(11) 0.1250(4) 0.033(3) Uani 1 1 d . . .
H18 H 1.6303 1.7888 0.0979 0.040 Uiso 1 1 calc R . .
O2 O 1.1439(9) 1.4067(9) 0.6559(3) 0.044(2) Uiso 1 1 d . . .
C3 C 0.1241(14) 1.0451(11) 0.4916(4) 0.035(3) Uani 1 1 d . . .
C4 C 0.0863(14) 1.0502(12) 0.5322(4) 0.038(3) Uani 1 1 d . . .
H4 H 0.1436 1.0845 0.5535 0.046 Uiso 1 1 calc R . .
C8 C 0.0380(14) 0.9968(12) 0.4601(4) 0.039(3) Uani 1 1 d . . .
H8 H 0.0634 0.9957 0.4332 0.047 Uiso 1 1 calc R . .
C5 C 0.9411(15) 1.1993(13) 0.7096(5) 0.042(4) Uani 1 1 d . . .
H5 H 0.9293 1.1761 0.7365 0.050 Uiso 1 1 calc R . .
C14 C 0.2637(15) 1.0908(13) 0.4843(6) 0.054(4) Uani 1 1 d . . .
H14A H 0.2593 1.1509 0.4629 0.064 Uiso 1 1 calc R . .
H14B H 0.3064 1.1283 0.5094 0.064 Uiso 1 1 calc R . .
C6 C 0.6267(13) 1.4542(11) 0.0045(4) 0.036(3) Uani 1 1 d . . .
C9 C 0.5591(13) 1.4567(13) -0.0342(4) 0.040(3) Uani 1 1 d . . .
H9 H 0.5984 1.4280 -0.0572 0.048 Uiso 1 1 calc R . .
C17 C 0.5682(14) 1.4974(13) 0.0386(5) 0.042(4) Uani 1 1 d . . .
H17 H 0.6141 1.4959 0.0646 0.050 Uiso 1 1 calc R . .
C19 C 0.7696(14) 1.4132(12) 0.0091(5) 0.044(4) Uani 1 1 d . . .
H19A H 0.7771 1.3477 0.0284 0.053 Uiso 1 1 calc R . .
H19B H 0.7951 1.3840 -0.0174 0.053 Uiso 1 1 calc R . .
C1A C 1.8228(14) 1.5454(12) 0.1893(5) 0.039(3) Uani 1 1 d . . .
H1AA H 1.8220 1.5339 0.2188 0.047 Uiso 1 1 calc R . .
H1AB H 1.9115 1.5741 0.1840 0.047 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pr1 O2 2.414(9) 2_776 ?
Pr1 O13 2.416(8) . ?
Pr1 O5 2.438(9) . ?
Pr1 O29 2.457(8) . ?
Pr1 O49 2.540(9) . ?
Pr1 O27 2.618(8) . ?
Pr1 O12 2.668(10) . ?
Pr1 O8 2.679(9) . ?
Pr1 O20 2.693(9) . ?
Pr1 O25 2.837(10) . ?
Pr2 O4 2.410(9) . ?
Pr2 O1 2.411(10) . ?
Pr2 O9 2.438(8) . ?
Pr2 O37 2.478(8) . ?
Pr2 O35 2.604(8) . ?
Pr2 O39 2.603(9) . ?
Pr2 O16 2.654(8) . ?
Pr2 O7 2.677(9) . ?
Pr2 O11 2.684(9) . ?
Pr2 O41 2.721(10) . ?
O4 C90 1.262(16) . ?
O5 C67 1.262(15) . ?
O7 N19 1.263(12) . ?
O8 N14 1.265(13) . ?
O9 C52 1.278(15) . ?
N10 O30 1.229(14) . ?
N10 O20 1.254(15) . ?
N10 O27 1.259(14) . ?
O11 N15 1.274(13) . ?
O12 N14 1.254(14) . ?
O13 C105 1.278(15) . ?
N14 O38 1.230(13) . ?
N15 O17 1.217(13) . ?
N15 O16 1.295(13) . ?
N19 O22 1.245(14) . ?
N19 O39 1.251(13) . ?
N23 C71 1.355(17) . ?
N23 C59 1.368(17) . ?
N23 C14 1.484(17) . ?
N24 O32 1.199(15) . ?
N24 O35 1.252(14) . ?
N24 O41 1.294(16) . ?
O25 N57 1.230(14) . ?
C26 C34 1.379(18) . ?
C26 C88 1.397(18) . ?
C26 C91 1.546(18) . ?
N28 C45 1.352(16) . ?
N28 C75 1.353(18) . ?
N28 C91 1.464(17) . ?
O29 C86 1.261(15) . ?
N31 C60 1.353(16) . ?
N31 C87 1.363(16) . ?
N31 C72 1.489(15) . ?
C34 C110 1.380(19) . ?
O37 C77 1.263(15) . ?
N40 C94 1.333(17) . ?
N40 C69 1.389(18) . ?
N40 C55 1.476(17) . ?
C42 C65 1.381(19) . ?
C42 C78 1.391(19) . ?
C42 C55 1.498(18) . ?
O43 N57 1.258(15) . ?
C45 C98 1.337(19) . ?
N46 C107 1.363(18) . ?
N46 C73 1.372(17) . ?
N46 C19 1.496(17) . ?
C48 C87 1.336(18) . ?
C48 C52 1.451(18) . ?
O49 N57 1.254(14) . ?
C50 C88 1.368(19) . ?
C50 C100 1.399(19) . ?
C51 C59 1.353(19) . ?
C51 C86 1.414(19) . ?
C52 C102 1.420(18) . ?
C53 C70 1.374(18) . ?
C53 C79 1.395(18) . ?
C53 C72 1.507(17) . ?
C56 C71 1.339(18) . ?
C56 C86 1.455(18) . ?
C58 C82 1.368(18) . ?
C58 C79 1.378(18) . ?
C60 C102 1.355(18) . ?
C62 C95 1.346(18) . ?
C62 N68 1.357(16) . ?
C65 C93 1.385(19) . ?
C66 N68 1.475(15) . ?
C66 C82 1.486(18) . ?
C67 C96 1.424(18) . ?
C67 C98 1.439(18) . ?
N68 C80 1.364(17) . ?
C69 C114 1.35(2) . ?
C70 C92 1.370(19) . ?
C73 C81 1.37(2) . ?
C75 C96 1.35(2) . ?
C77 C81 1.40(2) . ?
C77 C89 1.414(19) . ?
C78 C121 1.393(19) . ?
C80 C84 1.353(17) . ?
C82 C92 1.409(19) . ?
C83 C93 1.360(19) . ?
C83 C121 1.363(18) . ?
C83 C1A 1.533(18) 2_885 ?
C84 C105 1.439(18) . ?
C85 C94 1.360(19) . ?
C85 C90 1.411(19) . ?
C89 C107 1.333(19) . ?
C90 C114 1.440(18) . ?
C95 C105 1.41(2) . ?
C100 C110 1.39(2) . ?
C100 C1 1.505(19) . ?
N3 C12 1.343(17) . ?
N3 C5 1.349(19) . ?
N3 C1 1.457(16) . ?
C15 O1 1.297(15) . ?
C15 C2 1.42(2) . ?
C15 C18 1.404(18) . ?
C2 C13 1.351(18) . ?
N1 C11 1.346(17) . ?
N1 C13 1.355(16) . ?
N1 C1A 1.494(16) . ?
C7 C12 1.349(18) . ?
C7 C10 1.428(17) . ?
C10 O2 1.270(15) . ?
C10 C16 1.416(19) . ?
C11 C18 1.354(18) . ?
C16 C5 1.37(2) . ?
O2 Pr1 2.414(9) 2_776 ?
C3 C8 1.37(2) . ?
C3 C4 1.403(19) . ?
C3 C14 1.52(2) . ?
C4 C8 1.38(2) 2_576 ?
C8 C4 1.38(2) 2_576 ?
C6 C9 1.38(2) . ?
C6 C17 1.384(19) . ?
C6 C19 1.521(19) . ?
C9 C17 1.393(19) 2_685 ?
C17 C9 1.393(19) 2_685 ?
C1A C83 1.533(18) 2_885 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Pr1 O13 77.8(3) 2_776 . ?
O2 Pr1 O5 82.0(3) 2_776 . ?
O13 Pr1 O5 82.6(3) . . ?
O2 Pr1 O29 149.7(3) 2_776 . ?
O13 Pr1 O29 80.8(3) . . ?
O5 Pr1 O29 74.1(3) . . ?
O2 Pr1 O49 136.5(3) 2_776 . ?
O13 Pr1 O49 116.9(3) . . ?
O5 Pr1 O49 137.7(3) . . ?
O29 Pr1 O49 72.8(3) . . ?
O2 Pr1 O27 118.9(3) 2_776 . ?
O13 Pr1 O27 155.0(3) . . ?
O5 Pr1 O27 81.7(3) . . ?
O29 Pr1 O27 76.2(3) . . ?
O49 Pr1 O27 65.3(3) . . ?
O2 Pr1 O12 71.0(3) 2_776 . ?
O13 Pr1 O12 85.0(3) . . ?
O5 Pr1 O12 152.1(3) . . ?
O29 Pr1 O12 128.1(3) . . ?
O49 Pr1 O12 70.1(3) . . ?
O27 Pr1 O12 117.1(3) . . ?
O2 Pr1 O8 74.6(3) 2_776 . ?
O13 Pr1 O8 130.5(3) . . ?
O5 Pr1 O8 131.7(3) . . ?
O29 Pr1 O8 135.6(3) . . ?
O49 Pr1 O8 65.1(3) . . ?
O27 Pr1 O8 74.1(3) . . ?
O12 Pr1 O8 47.5(3) . . ?
O2 Pr1 O20 71.1(3) 2_776 . ?
O13 Pr1 O20 141.4(3) . . ?
O5 Pr1 O20 71.1(3) . . ?
O29 Pr1 O20 116.7(3) . . ?
O49 Pr1 O20 101.5(3) . . ?
O27 Pr1 O20 47.9(3) . . ?
O12 Pr1 O20 105.2(3) . . ?
O8 Pr1 O20 61.5(3) . . ?
O2 Pr1 O25 122.2(3) 2_776 . ?
O13 Pr1 O25 70.1(3) . . ?
O5 Pr1 O25 136.3(3) . . ?
O29 Pr1 O25 68.5(3) . . ?
O49 Pr1 O25 47.1(3) . . ?
O27 Pr1 O25 109.6(3) . . ?
O12 Pr1 O25 59.7(3) . . ?
O8 Pr1 O25 91.5(3) . . ?
O20 Pr1 O25 147.1(3) . . ?
O4 Pr2 O1 76.3(3) . . ?
O4 Pr2 O9 79.6(3) . . ?
O1 Pr2 O9 75.8(3) . . ?
O4 Pr2 O37 73.1(3) . . ?
O1 Pr2 O37 146.6(3) . . ?
O9 Pr2 O37 85.8(3) . . ?
O4 Pr2 O35 87.8(3) . . ?
O1 Pr2 O35 120.2(3) . . ?
O9 Pr2 O35 156.8(3) . . ?
O37 Pr2 O35 71.9(3) . . ?
O4 Pr2 O39 143.3(3) . . ?
O1 Pr2 O39 137.8(3) . . ?
O9 Pr2 O39 116.4(3) . . ?
O37 Pr2 O39 75.4(3) . . ?
O35 Pr2 O39 64.7(3) . . ?
O4 Pr2 O16 124.7(3) . . ?
O1 Pr2 O16 68.9(3) . . ?
O9 Pr2 O16 128.2(3) . . ?
O37 Pr2 O16 141.6(3) . . ?
O35 Pr2 O16 75.0(3) . . ?
O39 Pr2 O16 73.2(3) . . ?
O4 Pr2 O7 132.6(3) . . ?
O1 Pr2 O7 125.1(3) . . ?
O9 Pr2 O7 68.7(3) . . ?
O37 Pr2 O7 70.4(3) . . ?
O35 Pr2 O7 108.0(3) . . ?
O39 Pr2 O7 47.7(3) . . ?
O16 Pr2 O7 102.7(3) . . ?
O4 Pr2 O11 147.1(3) . . ?
O1 Pr2 O11 71.5(3) . . ?
O9 Pr2 O11 86.1(3) . . ?
O37 Pr2 O11 135.4(3) . . ?
O35 Pr2 O11 114.2(3) . . ?
O39 Pr2 O11 69.5(3) . . ?
O16 Pr2 O11 47.6(3) . . ?
O7 Pr2 O11 65.8(3) . . ?
O4 Pr2 O41 69.7(3) . . ?
O1 Pr2 O41 73.5(3) . . ?
O9 Pr2 O41 140.6(3) . . ?
O37 Pr2 O41 107.3(3) . . ?
O35 Pr2 O41 47.1(3) . . ?
O39 Pr2 O41 103.0(3) . . ?
O16 Pr2 O41 60.1(3) . . ?
O7 Pr2 O41 150.7(3) . . ?
O11 Pr2 O41 106.6(3) . . ?
C90 O4 Pr2 144.2(8) . . ?
C67 O5 Pr1 143.0(8) . . ?
N19 O7 Pr2 95.6(7) . . ?
N14 O8 Pr1 97.2(7) . . ?
C52 O9 Pr2 138.8(8) . . ?
O30 N10 O20 119.7(12) . . ?
O30 N10 O27 121.9(13) . . ?
O20 N10 O27 118.4(11) . . ?
N15 O11 Pr2 97.0(7) . . ?
N14 O12 Pr1 98.0(7) . . ?
C105 O13 Pr1 142.3(9) . . ?
O38 N14 O12 119.2(10) . . ?
O38 N14 O8 123.5(11) . . ?
O12 N14 O8 117.3(11) . . ?
O17 N15 O11 122.0(10) . . ?
O17 N15 O16 123.9(10) . . ?
O11 N15 O16 114.1(10) . . ?
N15 O16 Pr2 97.8(6) . . ?
O22 N19 O39 121.7(10) . . ?
O22 N19 O7 121.9(11) . . ?
O39 N19 O7 116.4(10) . . ?
N10 O20 Pr1 94.9(7) . . ?
C71 N23 C59 118.0(11) . . ?
C71 N23 C14 122.2(11) . . ?
C59 N23 C14 119.7(11) . . ?
O32 N24 O35 124.6(14) . . ?
O32 N24 O41 121.7(14) . . ?
O35 N24 O41 113.6(11) . . ?
N57 O25 Pr1 87.9(7) . . ?
C34 C26 C88 120.8(12) . . ?
C34 C26 C91 120.2(11) . . ?
C88 C26 C91 118.9(12) . . ?
N10 O27 Pr1 98.4(7) . . ?
C45 N28 C75 118.9(12) . . ?
C45 N28 C91 120.3(11) . . ?
C75 N28 C91 120.5(11) . . ?
C86 O29 Pr1 144.4(8) . . ?
C60 N31 C87 118.6(11) . . ?
C60 N31 C72 119.8(11) . . ?
C87 N31 C72 121.3(10) . . ?
C26 C34 C110 119.2(12) . . ?
N24 O35 Pr2 102.2(8) . . ?
C77 O37 Pr2 140.5(9) . . ?
N19 O39 Pr2 99.6(7) . . ?
C94 N40 C69 118.9(12) . . ?
C94 N40 C55 123.4(12) . . ?
C69 N40 C55 117.2(11) . . ?
N24 O41 Pr2 95.3(7) . . ?
C65 C42 C78 118.1(13) . . ?
C65 C42 C55 120.9(13) . . ?
C78 C42 C55 121.0(12) . . ?
C98 C45 N28 122.5(13) . . ?
C107 N46 C73 118.9(12) . . ?
C107 N46 C19 122.6(11) . . ?
C73 N46 C19 117.9(12) . . ?
C87 C48 C52 120.4(13) . . ?
N57 O49 Pr1 101.7(7) . . ?
C88 C50 C100 122.5(14) . . ?
C59 C51 C86 121.4(12) . . ?
O9 C52 C102 123.4(11) . . ?
O9 C52 C48 121.8(12) . . ?
C102 C52 C48 114.8(11) . . ?
C70 C53 C79 118.7(12) . . ?
C70 C53 C72 122.8(12) . . ?
C79 C53 C72 118.5(11) . . ?
N40 C55 C42 112.7(10) . . ?
C71 C56 C86 120.7(12) . . ?
O25 N57 O49 121.3(12) . . ?
O25 N57 O43 120.3(11) . . ?
O49 N57 O43 118.4(11) . . ?
C82 C58 C79 122.6(13) . . ?
C51 C59 N23 122.3(13) . . ?
N31 C60 C102 122.1(13) . . ?
C95 C62 N68 122.0(13) . . ?
C93 C65 C42 121.9(13) . . ?
N68 C66 C82 111.9(11) . . ?
O5 C67 C96 124.5(12) . . ?
O5 C67 C98 121.6(12) . . ?
C96 C67 C98 113.9(12) . . ?
C62 N68 C80 118.3(11) . . ?
C62 N68 C66 121.4(11) . . ?
C80 N68 C66 119.8(10) . . ?
C114 C69 N40 121.0(13) . . ?
C53 C70 C92 121.9(13) . . ?
C56 C71 N23 123.0(12) . . ?
N31 C72 C53 110.5(10) . . ?
C81 C73 N46 120.0(14) . . ?
C96 C75 N28 121.6(12) . . ?
O37 C77 C81 119.9(12) . . ?
O37 C77 C89 124.2(13) . . ?
C81 C77 C89 115.9(13) . . ?
C42 C78 C121 119.7(13) . . ?
C58 C79 C53 119.2(12) . . ?
C84 C80 N68 122.4(12) . . ?
C73 C81 C77 121.7(13) . . ?
C58 C82 C92 117.8(12) . . ?
C58 C82 C66 121.3(12) . . ?
C92 C82 C66 120.9(11) . . ?
C93 C83 C121 121.1(13) . . ?
C93 C83 C1A 120.5(12) . 2_885 ?
C121 C83 C1A 118.1(12) . 2_885 ?
C80 C84 C105 120.5(13) . . ?
C94 C85 C90 121.7(12) . . ?
O29 C86 C51 122.1(12) . . ?
O29 C86 C56 123.4(12) . . ?
C51 C86 C56 114.5(11) . . ?
C48 C87 N31 122.8(12) . . ?
C50 C88 C26 118.3(13) . . ?
C107 C89 C77 121.0(14) . . ?
O4 C90 C85 124.0(11) . . ?
O4 C90 C114 121.5(13) . . ?
C85 C90 C114 114.5(12) . . ?
N28 C91 C26 111.9(10) . . ?
C70 C92 C82 119.8(12) . . ?
C83 C93 C65 118.8(13) . . ?
N40 C94 C85 122.4(13) . . ?
C62 C95 C105 122.0(12) . . ?
C75 C96 C67 122.0(13) . . ?
C45 C98 C67 121.1(12) . . ?
C110 C100 C50 117.3(13) . . ?
C110 C100 C1 120.6(12) . . ?
C50 C100 C1 122.2(13) . . ?
C60 C102 C52 121.2(12) . . ?
O13 C105 C95 124.7(12) . . ?
O13 C105 C84 120.6(12) . . ?
C95 C105 C84 114.7(11) . . ?
C89 C107 N46 122.3(12) . . ?
C34 C110 C100 121.8(13) . . ?
C69 C114 C90 121.5(14) . . ?
C83 C121 C78 120.3(12) . . ?
C12 N3 C5 118.2(12) . . ?
C12 N3 C1 121.6(12) . . ?
C5 N3 C1 120.1(11) . . ?
O1 C15 C2 121.8(12) . . ?
O1 C15 C18 123.4(13) . . ?
C2 C15 C18 114.6(12) . . ?
N3 C1 C100 112.5(11) . . ?
C13 C2 C15 121.5(12) . . ?
C15 O1 Pr2 130.5(8) . . ?
C11 N1 C13 120.5(11) . . ?
C11 N1 C1A 119.2(11) . . ?
C13 N1 C1A 120.4(11) . . ?
C12 C7 C10 120.0(12) . . ?
O2 C10 C16 123.2(13) . . ?
O2 C10 C7 121.8(12) . . ?
C16 C10 C7 114.8(12) . . ?
N1 C11 C18 120.0(12) . . ?
N3 C12 C7 123.8(14) . . ?
C2 C13 N1 120.8(12) . . ?
C5 C16 C10 121.5(14) . . ?
C11 C18 C15 122.6(13) . . ?
C10 O2 Pr1 130.3(8) . 2_776 ?
C8 C3 C4 120.4(13) . . ?
C8 C3 C14 121.7(14) . . ?
C4 C3 C14 117.8(14) . . ?
C8 C4 C3 118.7(13) 2_576 . ?
C3 C8 C4 120.8(13) . 2_576 ?
N3 C5 C16 121.6(13) . . ?
N23 C14 C3 109.1(12) . . ?
C9 C6 C17 120.0(13) . . ?
C9 C6 C19 119.9(13) . . ?
C17 C6 C19 119.9(13) . . ?
C6 C9 C17 119.6(13) . 2_685 ?
C6 C17 C9 120.3(14) . 2_685 ?
N46 C19 C6 109.3(11) . . ?
N1 C1A C83 112.0(11) . 2_885 ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        59.99
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         1.814
_refine_diff_density_min         -2.461
_refine_diff_density_rms         0.193

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_LIFM-25(Eu)
_database_code_depnum_ccdc_archive 'CCDC 1819542'
_audit_update_record             
;
2018-01-26 deposited with the CCDC.
2018-03-02 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          'not measured'
_chemical_formula_moiety         'C45 H40 N8 O17 Eu'
_chemical_formula_sum            'C45 H40 N8 O17 Eu'
_chemical_formula_weight         1116.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -5.3236 12.2178 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   22.15090(10)
_cell_length_b                   16.03780(10)
_cell_length_c                   27.67280(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     9830.81(8)
_cell_formula_units_Z            8
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    2546
_cell_measurement_theta_min      3.1211
_cell_measurement_theta_max      63.8872

_exptl_crystal_description       Plate
_exptl_crystal_colour            Colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.509
_exptl_crystal_F_000             4520
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_absorpt_coefficient_mu    9.816
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_correction_T_min  0.361
_exptl_absorpt_correction_T_max  0.381
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            168253
_diffrn_reflns_av_unetI/netI     0.0244
_diffrn_reflns_av_R_equivalents  0.0766
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         3.194
_diffrn_reflns_theta_max         73.930
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             9968
_reflns_number_gt                8971
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0650P)²+41.3403P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9928
_refine_ls_number_parameters     697
_refine_ls_number_restraints     38
_refine_ls_R_factor_all          0.0588
_refine_ls_R_factor_gt           0.0530
_refine_ls_wR_factor_ref         0.1545
_refine_ls_wR_factor_gt          0.1507
_refine_ls_goodness_of_fit_ref   1.144
_refine_ls_restrained_S_all      1.146
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.25297(2) 0.56980(2) 0.26863(2) 0.02172(10) Uani 1 1 d . . . . .
O1 O 0.29919(18) 0.6920(2) 0.24208(12) 0.0318(8) Uani 1 1 d . . . . .
O2 O 0.69284(17) 0.6381(2) 0.17747(13) 0.0371(9) Uani 1 1 d . . . . .
O3 O 0.24471(16) 0.4432(2) 0.30705(14) 0.0308(8) Uani 1 1 d . . . . .
O4 O -0.21963(16) 0.5057(2) 0.30243(11) 0.0301(8) Uani 1 1 d . . . . .
O6 O 0.36185(16) 0.5267(2) 0.28286(13) 0.0343(8) Uani 1 1 d . . . . .
O7 O 0.31975(18) 0.5913(2) 0.34263(13) 0.0355(8) Uani 1 1 d . . . . .
O8 O 0.40876(19) 0.5338(3) 0.35163(16) 0.0518(11) Uani 1 1 d . . . . .
O9 O 0.17886(18) 0.6284(2) 0.20746(14) 0.0362(8) Uani 1 1 d . . . . .
O10 O 0.15294(16) 0.5121(2) 0.24121(13) 0.0331(8) Uani 1 1 d . . . . .
O11 O 0.1027(2) 0.5584(3) 0.17908(18) 0.0560(12) Uani 1 1 d . . . . .
O12 O 0.2988(3) 0.0645(3) 0.0413(2) 0.0722(17) Uani 1 1 d . . . . .
O13 O 0.2679(2) 0.1886(3) 0.02604(15) 0.0427(10) Uani 1 1 d . . . . .
O14 O 0.2039(2) 0.0914(3) 0.04353(15) 0.0443(10) Uani 1 1 d . . . . .
O15 O 0.2104(2) -0.0729(2) -0.00119(14) 0.0437(10) Uani 1 1 d . . . . .
O16 O 0.0889(2) -0.0284(3) -0.00490(17) 0.0577(12) Uani 1 1 d . . . . .
O5A O 0.0166(4) 0.0547(6) 0.0540(3) 0.044(2) Uani 0.5 1 d . . P A 1
N5A N 0.0166(3) 0.1010(5) 0.1982(2) 0.0369(15) Uani 0.5 1 d D . P A 1
C45A C 0.0706(3) 0.0953(5) 0.1731(3) 0.0355(17) Uani 0.5 1 d D . P A 1
H45A H 0.1078 0.1024 0.1897 0.043 Uiso 0.5 1 calc R U P A 1
C46A C 0.0708(4) 0.0795(5) 0.1241(3) 0.0293(18) Uani 0.5 1 d D . P A 1
H46A H 0.1081 0.0758 0.1073 0.035 Uiso 0.5 1 calc R U P A 1
C47A C 0.0164(5) 0.0690(5) 0.0989(3) 0.0365(15) Uani 0.5 1 d D . P A 1
C48A C -0.0381(4) 0.0748(6) 0.1249(4) 0.0409(15) Uani 0.5 1 d D . P A 1
H48A H -0.0755 0.0680 0.1086 0.049 Uiso 0.5 1 calc R U P A 1
C49A C -0.0375(3) 0.0904(6) 0.1739(3) 0.039(2) Uani 0.5 1 d D . P A 1
H49A H -0.0745 0.0939 0.1911 0.047 Uiso 0.5 1 calc R U P A 1
O5B O -0.0162(4) 0.5920(6) 0.4490(3) 0.044(2) Uani 0.5 1 d . . P B 2
N5B N -0.0023(3) 0.5338(5) 0.3055(2) 0.0369(15) Uani 0.5 1 d D . P B 2
C45B C -0.0582(3) 0.5356(5) 0.3276(3) 0.0355(17) Uani 0.5 1 d D . P B 2
H45B H -0.0934 0.5233 0.3093 0.043 Uiso 0.5 1 calc R U P B 2
C46B C -0.0634(4) 0.5552(5) 0.3760(3) 0.0293(18) Uani 0.5 1 d D . P B 2
H46B H -0.1021 0.5564 0.3907 0.035 Uiso 0.5 1 calc R U P B 2
C47B C -0.0119(5) 0.5734(5) 0.4036(3) 0.0365(15) Uani 0.5 1 d D . P B 2
C48B C 0.0447(4) 0.5716(6) 0.3805(4) 0.0409(15) Uani 0.5 1 d D . P B 2
H48B H 0.0802 0.5841 0.3984 0.049 Uiso 0.5 1 calc R U P B 2
C49B C 0.0491(3) 0.5518(6) 0.3322(3) 0.039(2) Uani 0.5 1 d D . P B 2
H49B H 0.0876 0.5506 0.3171 0.047 Uiso 0.5 1 calc R U P B 2
N1 N 0.33432(18) 0.8229(3) 0.11855(15) 0.0269(9) Uani 1 1 d . . . . .
N2 N 0.63757(19) 0.8197(3) 0.08467(17) 0.0329(10) Uani 1 1 d . . . . .
N3 N 0.15972(18) 0.3260(3) 0.41915(15) 0.0266(9) Uani 1 1 d . . . . .
N4 N -0.15023(17) 0.3002(3) 0.36890(14) 0.0250(8) Uani 1 1 d . . . . .
N6 N 0.3650(2) 0.5500(3) 0.32649(16) 0.0317(9) Uani 1 1 d . . . . .
N7 N 0.1436(2) 0.5667(3) 0.20816(17) 0.0349(10) Uani 1 1 d . . . . .
N8 N 0.2573(2) 0.1148(3) 0.03692(16) 0.0351(10) Uani 1 1 d . . . . .
C1 C 0.3092(2) 0.7331(3) 0.20312(17) 0.0276(10) Uani 1 1 d . . . . .
C2 C 0.2990(3) 0.7001(3) 0.15642(18) 0.0332(11) Uani 1 1 d . . . . .
H2 H 0.2830 0.6454 0.1531 0.040 Uiso 1 1 calc R U . . .
C3 C 0.3117(2) 0.7455(4) 0.1161(2) 0.0359(12) Uani 1 1 d . . . . .
H3 H 0.3044 0.7215 0.0853 0.043 Uiso 1 1 calc R U . . .
C4 C 0.3445(2) 0.8576(3) 0.16250(19) 0.0323(11) Uani 1 1 d . . . . .
H4 H 0.3602 0.9126 0.1643 0.039 Uiso 1 1 calc R U . . .
C5 C 0.3325(3) 0.8149(3) 0.20433(19) 0.0316(11) Uani 1 1 d . . . . .
H5 H 0.3399 0.8409 0.2346 0.038 Uiso 1 1 calc R U . . .
C6 C 0.3490(2) 0.8693(3) 0.07387(19) 0.0318(11) Uani 1 1 d . . . . .
H6A H 0.3332 0.9269 0.0764 0.038 Uiso 1 1 calc R U . . .
H6B H 0.3292 0.8420 0.0459 0.038 Uiso 1 1 calc R U . . .
C7 C 0.4164(2) 0.8720(3) 0.06571(17) 0.0263(10) Uani 1 1 d . . . . .
C8 C 0.4461(2) 0.9470(3) 0.0621(2) 0.0352(12) Uani 1 1 d . . . . .
H8 H 0.4237 0.9975 0.0633 0.042 Uiso 1 1 calc R U . . .
C9 C 0.5087(2) 0.9499(4) 0.0567(2) 0.0376(12) Uani 1 1 d . . . . .
H9 H 0.5287 1.0021 0.0544 0.045 Uiso 1 1 calc R U . . .
C10 C 0.5418(2) 0.8766(3) 0.05465(18) 0.0298(11) Uani 1 1 d . . . . .
C11 C 0.5115(2) 0.8013(3) 0.0567(2) 0.0341(11) Uani 1 1 d . . . . .
H11 H 0.5337 0.7508 0.0540 0.041 Uiso 1 1 calc R U . . .
C12 C 0.4497(2) 0.7983(3) 0.0626(2) 0.0330(11) Uani 1 1 d . . . . .
H12 H 0.4298 0.7460 0.0646 0.040 Uiso 1 1 calc R U . . .
C13 C 0.6100(2) 0.8808(4) 0.0509(2) 0.0436(15) Uani 1 1 d . . . . .
H13A H 0.6226 0.8680 0.0174 0.052 Uiso 1 1 calc R U . . .
H13B H 0.6240 0.9377 0.0589 0.052 Uiso 1 1 calc R U . . .
C14 C 0.6667(2) 0.7525(4) 0.06792(19) 0.0369(12) Uani 1 1 d . . . . .
H14 H 0.6739 0.7476 0.0342 0.044 Uiso 1 1 calc R U . . .
C15 C 0.6859(3) 0.6914(4) 0.0979(2) 0.0375(13) Uani 1 1 d . . . . .
H15 H 0.7062 0.6444 0.0848 0.045 Uiso 1 1 calc R U . . .
C16 C 0.6764(2) 0.6963(3) 0.14811(18) 0.0272(10) Uani 1 1 d . . . . .
C17 C 0.6465(2) 0.7684(3) 0.16453(19) 0.0343(11) Uani 1 1 d . . . . .
H17 H 0.6391 0.7757 0.1981 0.041 Uiso 1 1 calc R U . . .
C18 C 0.6282(3) 0.8273(3) 0.1327(2) 0.0366(12) Uani 1 1 d . . . . .
H18 H 0.6082 0.8755 0.1445 0.044 Uiso 1 1 calc R U . . .
C19 C 0.2183(2) 0.4059(3) 0.34249(17) 0.0256(10) Uani 1 1 d . . . . .
C20 C 0.2062(3) 0.4467(4) 0.3867(2) 0.0432(15) Uani 1 1 d . . . . .
H20 H 0.2185 0.5030 0.3910 0.052 Uiso 1 1 calc R U . . .
C21 C 0.1769(3) 0.4060(4) 0.4235(2) 0.0397(13) Uani 1 1 d . . . . .
H21 H 0.1686 0.4350 0.4526 0.048 Uiso 1 1 calc R U . . .
C22 C 0.1724(2) 0.2847(3) 0.37769(18) 0.0275(10) Uani 1 1 d . . . . .
H22 H 0.1608 0.2279 0.3749 0.033 Uiso 1 1 calc R U . . .
C23 C 0.2009(2) 0.3215(3) 0.34002(18) 0.0279(10) Uani 1 1 d . . . . .
H23 H 0.2092 0.2901 0.3117 0.033 Uiso 1 1 calc R U . . .
C24 C 0.1245(2) 0.2841(4) 0.45747(18) 0.0318(11) Uani 1 1 d . . . . .
H24A H 0.1248 0.3190 0.4870 0.038 Uiso 1 1 calc R U . . .
H24B H 0.1436 0.2300 0.4654 0.038 Uiso 1 1 calc R U . . .
C25 C 0.0604(2) 0.2697(3) 0.44170(17) 0.0269(10) Uani 1 1 d . . . . .
C26 C 0.0411(2) 0.1917(3) 0.4278(2) 0.0350(12) Uani 1 1 d . . . . .
H26 H 0.0681 0.1459 0.4294 0.042 Uiso 1 1 calc R U . . .
C27 C -0.0176(2) 0.1794(3) 0.4115(2) 0.0347(12) Uani 1 1 d . . . . .
H27 H -0.0299 0.1253 0.4017 0.042 Uiso 1 1 calc R U . . .
C28 C -0.0583(2) 0.2451(3) 0.40950(17) 0.0253(9) Uani 1 1 d . . . . .
C29 C -0.0384(3) 0.3231(4) 0.4240(3) 0.0466(16) Uani 1 1 d . . . . .
H29 H -0.0657 0.3688 0.4233 0.056 Uiso 1 1 calc R U . . .
C30 C 0.0198(3) 0.3357(4) 0.4393(3) 0.0449(15) Uani 1 1 d . . . . .
H30 H 0.0325 0.3901 0.4485 0.054 Uiso 1 1 calc R U . . .
C31 C -0.1228(2) 0.2287(3) 0.39382(19) 0.0288(10) Uani 1 1 d . . . . .
H31A H -0.1234 0.1798 0.3720 0.035 Uiso 1 1 calc R U . . .
H31B H -0.1473 0.2149 0.4226 0.035 Uiso 1 1 calc R U . . .
C32 C -0.1424(2) 0.3108(3) 0.32104(18) 0.0277(10) Uani 1 1 d . . . . .
H32 H -0.1203 0.2704 0.3032 0.033 Uiso 1 1 calc R U . . .
C33 C -0.1656(2) 0.3784(3) 0.29759(17) 0.0286(10) Uani 1 1 d . . . . .
H33 H -0.1600 0.3840 0.2637 0.034 Uiso 1 1 calc R U . . .
C34 C -0.1978(2) 0.4400(3) 0.32311(17) 0.0246(10) Uani 1 1 d . . . . .
C35 C -0.2044(2) 0.4272(3) 0.37360(17) 0.0261(10) Uani 1 1 d . . . . .
H35 H -0.2253 0.4672 0.3926 0.031 Uiso 1 1 calc R U . . .
C36 C -0.1811(2) 0.3584(3) 0.39485(17) 0.0266(10) Uani 1 1 d . . . . .
H36 H -0.1864 0.3504 0.4286 0.032 Uiso 1 1 calc R U . . .
C37 C 0.0027(5) 0.4999(9) 0.2571(4) 0.042(3) Uani 0.5 1 d . . P . .
H37A H 0.0390 0.5234 0.2414 0.050 Uiso 0.5 1 calc R U P B 2
H37B H -0.0329 0.5173 0.2380 0.050 Uiso 0.5 1 calc R U P B 2
C38 C 0.0070(4) 0.4019(9) 0.2566(4) 0.037(3) Uani 0.5 1 d . . P B .
C39 C 0.0198(5) 0.3584(9) 0.2950(4) 0.042(3) Uani 0.5 1 d . . P . .
H39 H 0.0248 0.3854 0.3253 0.050 Uiso 0.5 1 calc R U P B .
C40 C 0.0268(7) 0.2648(11) 0.2913(4) 0.062(4) Uani 0.5 1 d . . P B .
H40 H 0.0423 0.2313 0.3168 0.074 Uiso 0.5 1 calc R U P . .
C41 C 0.0100(5) 0.2348(9) 0.2506(4) 0.044(3) Uani 0.5 1 d . . P . .
C42 C 0.0033(5) 0.2792(8) 0.2075(4) 0.044(3) Uani 0.5 1 d . . P B .
H42 H 0.0014 0.2524 0.1769 0.053 Uiso 0.5 1 calc R U P . .
C43 C -0.0005(5) 0.3664(8) 0.2125(4) 0.041(3) Uani 0.5 1 d . . P . .
H43 H -0.0083 0.4003 0.1850 0.049 Uiso 0.5 1 calc R U P B .
C44 C 0.0149(6) 0.1382(9) 0.2474(4) 0.049(3) Uani 0.5 1 d . . P A .
H44A H 0.0520 0.1210 0.2648 0.058 Uiso 0.5 1 calc R U P C 1
H44B H -0.0198 0.1139 0.2650 0.058 Uiso 0.5 1 calc R U P C 1
O17 O 0.1755(2) 0.0863(4) 0.45012(19) 0.0673(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.280(3) 6_556 ?
Eu1 O3 2.299(4) . ?
Eu1 O4 2.301(3) 6_656 ?
Eu1 O1 2.331(3) . ?
Eu1 O10 2.518(4) . ?
Eu1 O9 2.538(4) . ?
Eu1 O6 2.540(4) . ?
Eu1 O7 2.550(4) . ?
Eu1 N7 2.945(5) . ?
Eu1 N6 2.970(4) . ?
O1 C1 1.282(6) . ?
O2 C16 1.290(6) . ?
O2 Eu1 2.280(3) 6_656 ?
O3 C19 1.289(6) . ?
O4 C34 1.292(6) . ?
O4 Eu1 2.301(3) 6_556 ?
O6 N6 1.266(6) . ?
O7 N6 1.281(6) . ?
O8 N6 1.222(6) . ?
O9 N7 1.261(6) . ?
O10 N7 1.283(6) . ?
O11 N7 1.218(6) . ?
O12 N8 1.229(7) . ?
O13 N8 1.244(6) . ?
O14 N8 1.254(6) . ?
O5A C47A 1.263(12) . ?
N5A C49A 1.386(7) . ?
N5A C45A 1.386(7) . ?
N5A C44 1.487(14) . ?
C45A C46A 1.378(7) . ?
C46A C47A 1.403(8) . ?
C47A C48A 1.408(8) . ?
C48A C49A 1.378(8) . ?
O5B C47B 1.295(11) . ?
N5B C45B 1.381(7) . ?
N5B C49B 1.389(7) . ?
N5B C37 1.449(13) . ?
C45B C46B 1.382(7) . ?
C46B C47B 1.404(8) . ?
C47B C48B 1.407(8) . ?
C48B C49B 1.376(8) . ?
N1 C3 1.340(7) . ?
N1 C4 1.357(7) . ?
N1 C6 1.479(6) . ?
N2 C14 1.339(7) . ?
N2 C18 1.349(7) . ?
N2 C13 1.486(7) . ?
N3 C21 1.344(7) . ?
N3 C22 1.354(6) . ?
N3 C24 1.477(6) . ?
N4 C32 1.347(6) . ?
N4 C36 1.361(6) . ?
N4 C31 1.469(6) . ?
C1 C5 1.411(7) . ?
C1 C2 1.414(7) . ?
C2 C3 1.362(7) . ?
C4 C5 1.371(7) . ?
C6 C7 1.511(7) . ?
C7 C8 1.374(7) . ?
C7 C12 1.395(7) . ?
C8 C9 1.396(8) . ?
C9 C10 1.386(8) . ?
C10 C11 1.382(8) . ?
C10 C13 1.516(7) . ?
C11 C12 1.380(8) . ?
C14 C15 1.352(8) . ?
C15 C16 1.407(7) . ?
C16 C17 1.408(7) . ?
C17 C18 1.354(8) . ?
C19 C23 1.409(7) . ?
C19 C20 1.413(7) . ?
C20 C21 1.372(8) . ?
C22 C23 1.354(7) . ?
C24 C25 1.504(7) . ?
C25 C26 1.376(7) . ?
C25 C30 1.390(8) . ?
C26 C27 1.389(7) . ?
C27 C28 1.388(7) . ?
C28 C29 1.386(7) . ?
C28 C31 1.515(6) . ?
C29 C30 1.373(8) . ?
C32 C33 1.364(7) . ?
C33 C34 1.408(7) . ?
C34 C35 1.420(6) . ?
C35 C36 1.353(7) . ?
C37 C38 1.57(2) . ?
C38 C39 1.303(17) . ?
C38 C43 1.358(16) . ?
C39 C40 1.51(2) . ?
C40 C41 1.280(18) . ?
C41 C42 1.396(14) . ?
C41 C44 1.55(2) . ?
C42 C43 1.408(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O3 94.31(14) 6_556 . ?
O2 Eu1 O4 158.13(13) 6_556 6_656 ?
O3 Eu1 O4 91.23(13) . 6_656 ?
O2 Eu1 O1 93.37(14) 6_556 . ?
O3 Eu1 O1 157.46(13) . . ?
O4 Eu1 O1 89.47(13) 6_656 . ?
O2 Eu1 O10 81.93(13) 6_556 . ?
O3 Eu1 O10 75.22(12) . . ?
O4 Eu1 O10 79.07(12) 6_656 . ?
O1 Eu1 O10 126.91(12) . . ?
O2 Eu1 O9 83.14(14) 6_556 . ?
O3 Eu1 O9 125.72(13) . . ?
O4 Eu1 O9 76.48(13) 6_656 . ?
O1 Eu1 O9 76.25(13) . . ?
O10 Eu1 O9 50.65(12) . . ?
O2 Eu1 O6 125.73(13) 6_556 . ?
O3 Eu1 O6 76.33(13) . . ?
O4 Eu1 O6 76.13(12) 6_656 . ?
O1 Eu1 O6 81.99(13) . . ?
O10 Eu1 O6 141.48(12) . . ?
O9 Eu1 O6 144.92(12) . . ?
O2 Eu1 O7 75.43(13) 6_556 . ?
O3 Eu1 O7 78.13(13) . . ?
O4 Eu1 O7 126.43(12) 6_656 . ?
O1 Eu1 O7 83.36(12) . . ?
O10 Eu1 O7 143.35(12) . . ?
O9 Eu1 O7 149.39(12) . . ?
O6 Eu1 O7 50.31(12) . . ?
O2 Eu1 N7 84.21(13) 6_556 . ?
O3 Eu1 N7 100.52(13) . . ?
O4 Eu1 N7 73.98(13) 6_656 . ?
O1 Eu1 N7 101.32(13) . . ?
O10 Eu1 N7 25.67(12) . . ?
O9 Eu1 N7 25.21(12) . . ?
O6 Eu1 N7 149.87(12) . . ?
O7 Eu1 N7 159.38(13) . . ?
O2 Eu1 N6 100.75(13) 6_556 . ?
O3 Eu1 N6 73.90(13) . . ?
O4 Eu1 N6 101.11(13) 6_656 . ?
O1 Eu1 N6 83.86(13) . . ?
O10 Eu1 N6 149.12(12) . . ?
O9 Eu1 N6 159.95(12) . . ?
O6 Eu1 N6 25.04(12) . . ?
O7 Eu1 N6 25.41(12) . . ?
N7 Eu1 N6 172.69(12) . . ?
C1 O1 Eu1 140.6(3) . . ?
C16 O2 Eu1 157.6(3) . 6_656 ?
C19 O3 Eu1 142.9(3) . . ?
C34 O4 Eu1 147.3(3) . 6_556 ?
N6 O6 Eu1 96.8(3) . . ?
N6 O7 Eu1 95.9(3) . . ?
N7 O9 Eu1 95.8(3) . . ?
N7 O10 Eu1 96.1(3) . . ?
C49A N5A C45A 119.6(5) . . ?
C49A N5A C44 118.2(7) . . ?
C45A N5A C44 120.5(7) . . ?
C46A C45A N5A 120.5(5) . . ?
C45A C46A C47A 120.6(5) . . ?
O5A C47A C46A 120.5(9) . . ?
O5A C47A C48A 121.3(9) . . ?
C46A C47A C48A 118.2(5) . . ?
C49A C48A C47A 120.5(5) . . ?
C48A C49A N5A 120.5(5) . . ?
C45B N5B C49B 119.7(5) . . ?
C45B N5B C37 119.0(7) . . ?
C49B N5B C37 120.5(7) . . ?
N5B C45B C46B 120.5(5) . . ?
C45B C46B C47B 120.5(5) . . ?
O5B C47B C46B 121.0(9) . . ?
O5B C47B C48B 120.7(9) . . ?
C46B C47B C48B 118.2(5) . . ?
C49B C48B C47B 120.5(5) . . ?
C48B C49B N5B 120.5(5) . . ?
C3 N1 C4 119.2(4) . . ?
C3 N1 C6 120.4(4) . . ?
C4 N1 C6 120.4(4) . . ?
C14 N2 C18 119.2(4) . . ?
C14 N2 C13 120.7(5) . . ?
C18 N2 C13 119.8(5) . . ?
C21 N3 C22 118.9(4) . . ?
C21 N3 C24 121.3(4) . . ?
C22 N3 C24 119.7(4) . . ?
C32 N4 C36 119.8(4) . . ?
C32 N4 C31 120.5(4) . . ?
C36 N4 C31 119.7(4) . . ?
O8 N6 O6 121.6(5) . . ?
O8 N6 O7 122.2(5) . . ?
O6 N6 O7 116.3(4) . . ?
O8 N6 Eu1 173.2(4) . . ?
O6 N6 Eu1 58.1(2) . . ?
O7 N6 Eu1 58.6(2) . . ?
O11 N7 O9 122.4(5) . . ?
O11 N7 O10 121.1(5) . . ?
O9 N7 O10 116.5(4) . . ?
O11 N7 Eu1 171.2(4) . . ?
O9 N7 Eu1 59.0(2) . . ?
O10 N7 Eu1 58.2(2) . . ?
O12 N8 O13 120.4(5) . . ?
O12 N8 O14 119.7(5) . . ?
O13 N8 O14 119.8(5) . . ?
O1 C1 C5 121.4(5) . . ?
O1 C1 C2 123.3(5) . . ?
C5 C1 C2 115.3(5) . . ?
C3 C2 C1 121.1(5) . . ?
N1 C3 C2 122.1(5) . . ?
N1 C4 C5 121.3(5) . . ?
C4 C5 C1 121.1(5) . . ?
N1 C6 C7 110.9(4) . . ?
C8 C7 C12 119.0(5) . . ?
C8 C7 C6 120.6(5) . . ?
C12 C7 C6 120.5(5) . . ?
C7 C8 C9 120.8(5) . . ?
C10 C9 C8 120.1(5) . . ?
C11 C10 C9 118.9(5) . . ?
C11 C10 C13 121.6(5) . . ?
C9 C10 C13 119.5(5) . . ?
C12 C11 C10 121.1(5) . . ?
C11 C12 C7 120.1(5) . . ?
N2 C13 C10 109.7(4) . . ?
N2 C14 C15 121.5(5) . . ?
C14 C15 C16 121.3(5) . . ?
O2 C16 C15 122.6(5) . . ?
O2 C16 C17 121.6(5) . . ?
C15 C16 C17 115.8(5) . . ?
C18 C17 C16 120.2(5) . . ?
N2 C18 C17 122.1(5) . . ?
O3 C19 C23 122.2(5) . . ?
O3 C19 C20 122.0(5) . . ?
C23 C19 C20 115.8(5) . . ?
C21 C20 C19 120.7(5) . . ?
N3 C21 C20 121.5(5) . . ?
N3 C22 C23 122.4(4) . . ?
C22 C23 C19 120.6(5) . . ?
N3 C24 C25 111.1(4) . . ?
C26 C25 C30 118.6(5) . . ?
C26 C25 C24 120.9(5) . . ?
C30 C25 C24 120.5(5) . . ?
C25 C26 C27 120.7(5) . . ?
C28 C27 C26 120.9(5) . . ?
C29 C28 C27 117.8(5) . . ?
C29 C28 C31 122.6(5) . . ?
C27 C28 C31 119.6(4) . . ?
C30 C29 C28 121.4(5) . . ?
C29 C30 C25 120.6(5) . . ?
N4 C31 C28 113.0(4) . . ?
N4 C32 C33 121.4(5) . . ?
C32 C33 C34 120.6(4) . . ?
O4 C34 C33 122.6(4) . . ?
O4 C34 C35 121.0(4) . . ?
C33 C34 C35 116.3(4) . . ?
C36 C35 C34 120.5(4) . . ?
C35 C36 N4 121.4(4) . . ?
N5B C37 C38 112.8(9) . . ?
C39 C38 C43 122.4(14) . . ?
C39 C38 C37 122.7(10) . . ?
C43 C38 C37 114.8(11) . . ?
C38 C39 C40 119.8(11) . . ?
C41 C40 C39 113.8(14) . . ?
C40 C41 C42 126.1(15) . . ?
C40 C41 C44 113.8(12) . . ?
C42 C41 C44 117.9(12) . . ?
C41 C42 C43 115.5(12) . . ?
C38 C43 C42 119.8(11) . . ?
N5A C44 C41 116.9(9) . . ?

_refine_diff_density_max         2.258
_refine_diff_density_min         -0.816
_refine_diff_density_rms         0.121



