# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_pt6clabs
_database_code_depnum_ccdc_archive 'CCDC 1824028'
_audit_update_record             
;
2018-02-14 deposited with the CCDC.
2018-08-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H40 Cl2 N4 O3 Pt'
_chemical_formula_weight         746.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.6316(14)
_cell_length_b                   5.6515(3)
_cell_length_c                   24.8995(14)
_cell_angle_alpha                90.00
_cell_angle_beta                 114.4690(10)
_cell_angle_gamma                90.00
_cell_volume                     3154.8(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6354
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      23.33

_exptl_crystal_description       prismatic
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.09
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1488
_exptl_absorpt_coefficient_mu    4.650
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2341
_exptl_absorpt_correction_T_max  0.6796
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22844
_diffrn_reflns_av_R_equivalents  0.0416
_diffrn_reflns_av_sigmaI/netI    0.0371
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         1.64
_diffrn_reflns_theta_max         25.00
_reflns_number_total             5570
_reflns_number_gt                4068
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0728P)²+5.1368P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5570
_refine_ls_number_parameters     343
_refine_ls_number_restraints     10
_refine_ls_R_factor_all          0.0627
_refine_ls_R_factor_gt           0.0410
_refine_ls_wR_factor_ref         0.1228
_refine_ls_wR_factor_gt          0.1072
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_restrained_S_all      0.994
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O3 O 0.2329(3) 0.4191(10) 0.3001(3) 0.0722(15) Uani 1 1 d . . .
H3A H 0.2580 0.5215 0.2997 0.108 Uiso 1 1 d R . .
H3B H 0.2061 0.4008 0.2653 0.108 Uiso 1 1 d R . .
C3 C 0.1821(3) 0.4772(11) 0.4264(3) 0.0445(16) Uani 1 1 d . . .
C4 C 0.1435(3) 0.6020(13) 0.4435(3) 0.0490(17) Uani 1 1 d . . .
H4 H 0.1364 0.5737 0.4768 0.059 Uiso 1 1 calc R . .
C5 C 0.1177(3) 0.7749(12) 0.4021(3) 0.0440(15) Uani 1 1 d . . .
C6 C 0.0750(3) 0.9646(12) 0.3940(3) 0.0492(17) Uani 1 1 d . . .
C7 C 0.0488(4) 1.0084(13) 0.4319(4) 0.063(2) Uani 1 1 d . . .
H7 H 0.0583 0.9177 0.4657 0.075 Uiso 1 1 calc R . .
C8 C 0.0078(4) 1.1914(16) 0.4186(4) 0.068(2) Uani 1 1 d . . .
H8 H -0.0118 1.2221 0.4428 0.082 Uiso 1 1 calc R . .
C9 C -0.0036(3) 1.3259(15) 0.3696(3) 0.062(2) Uani 1 1 d . . .
H9 H -0.0306 1.4502 0.3606 0.075 Uiso 1 1 calc R . .
C10 C 0.0247(3) 1.2783(13) 0.3339(3) 0.0561(19) Uani 1 1 d . . .
H10 H 0.0163 1.3719 0.3007 0.067 Uiso 1 1 calc R . .
C11 C 0.2201(3) 0.2756(12) 0.4545(3) 0.0448(16) Uani 1 1 d . . .
C12 C 0.2183(3) 0.1816(13) 0.5051(3) 0.0506(18) Uani 1 1 d . . .
H12 H 0.1932 0.2484 0.5203 0.061 Uiso 1 1 calc R . .
C13 C 0.2538(4) -0.0123(12) 0.5336(3) 0.0578(19) Uani 1 1 d . . .
C14 C 0.2907(3) -0.1125(14) 0.5108(3) 0.0556(18) Uani 1 1 d . . .
H14 H 0.3139 -0.2435 0.5288 0.067 Uiso 1 1 calc R . .
C15 C 0.2925(4) -0.0137(13) 0.4601(4) 0.060(2) Uani 1 1 d . . .
C16 C 0.2585(3) 0.1780(14) 0.4321(3) 0.0548(18) Uani 1 1 d . . .
H16 H 0.2611 0.2421 0.3988 0.066 Uiso 1 1 calc R . .
C17 C 0.2840(4) -0.2889(16) 0.6120(3) 0.074(2) Uani 1 1 d D . .
H17A H 0.3257 -0.2508 0.6235 0.089 Uiso 1 1 calc R . .
H17B H 0.2742 -0.4261 0.5863 0.089 Uiso 1 1 calc R . .
C18 C 0.2728(4) -0.3418(15) 0.6663(4) 0.084(3) Uani 1 1 d D . .
H18A H 0.2859 -0.2079 0.6930 0.101 Uiso 1 1 calc R . .
H18B H 0.2303 -0.3609 0.6546 0.101 Uiso 1 1 calc R . .
C19 C 0.3047(5) -0.5628(18) 0.6988(5) 0.111(4) Uani 1 1 d D . .
H19A H 0.2934 -0.5921 0.7312 0.134 Uiso 1 1 calc R . .
H19B H 0.2911 -0.6963 0.6720 0.134 Uiso 1 1 calc R . .
C20 C 0.3722(5) -0.5508(19) 0.7233(5) 0.114(4) Uani 1 1 d D . .
H20A H 0.3862 -0.4142 0.7490 0.136 Uiso 1 1 calc R . .
H20B H 0.3841 -0.5308 0.6910 0.136 Uiso 1 1 calc R . .
C21 C 0.4012(7) -0.773(2) 0.7576(7) 0.150(6) Uani 1 1 d D . .
H21A H 0.3920 -0.7873 0.7917 0.180 Uiso 1 1 calc R . .
H21B H 0.3857 -0.9109 0.7329 0.180 Uiso 1 1 calc R . .
C22 C 0.4683(7) -0.758(4) 0.7774(10) 0.282(14) Uani 1 1 d D . .
H22A H 0.4772 -0.7461 0.7434 0.423 Uiso 1 1 calc R . .
H22B H 0.4866 -0.8980 0.7993 0.423 Uiso 1 1 calc R . .
H22C H 0.4834 -0.6214 0.8020 0.423 Uiso 1 1 calc R . .
C23 C 0.3308(5) -0.0694(19) 0.3876(5) 0.095(3) Uani 1 1 d D . .
H23A H 0.3419 0.0957 0.3885 0.114 Uiso 1 1 calc R . .
H23B H 0.2914 -0.0905 0.3560 0.114 Uiso 1 1 calc R . .
C24 C 0.3755(4) -0.2245(18) 0.3769(4) 0.092(3) Uani 1 1 d D . .
H24A H 0.3671 -0.3891 0.3815 0.110 Uiso 1 1 calc R . .
H24B H 0.3710 -0.2025 0.3366 0.110 Uiso 1 1 calc R . .
C25 C 0.4390(4) -0.170(2) 0.4185(4) 0.105(4) Uani 1 1 d D . .
H25A H 0.4442 -0.1994 0.4587 0.127 Uiso 1 1 calc R . .
H25B H 0.4470 -0.0033 0.4154 0.127 Uiso 1 1 calc R . .
C26 C 0.4833(4) -0.318(2) 0.4053(5) 0.114(4) Uani 1 1 d D . .
H26A H 0.4766 -0.4838 0.4103 0.137 Uiso 1 1 calc R . .
H26B H 0.4767 -0.2939 0.3644 0.137 Uiso 1 1 calc R . .
C27 C 0.5472(4) -0.255(3) 0.4449(6) 0.148(6) Uani 1 1 d D . .
H27A H 0.5537 -0.2754 0.4858 0.178 Uiso 1 1 calc R . .
H27B H 0.5544 -0.0906 0.4391 0.178 Uiso 1 1 calc R . .
C28 C 0.5907(6) -0.410(3) 0.4320(8) 0.165(6) Uani 1 1 d D . .
H28A H 0.5777 -0.4247 0.3901 0.248 Uiso 1 1 calc R . .
H28B H 0.5924 -0.5636 0.4490 0.248 Uiso 1 1 calc R . .
H28C H 0.6296 -0.3389 0.4488 0.248 Uiso 1 1 calc R . .
C29 C 0.1154(5) 0.312(2) 0.5878(5) 0.087(3) Uani 1 1 d . . .
C30 C 0.1417(5) 0.115(2) 0.6280(5) 0.106(3) Uani 1 1 d . . .
H30A H 0.1392 -0.0265 0.6056 0.158 Uiso 1 1 calc R . .
H30B H 0.1205 0.0916 0.6524 0.158 Uiso 1 1 calc R . .
H30C H 0.1828 0.1488 0.6524 0.158 Uiso 1 1 calc R . .
Cl1 Cl 0.16900(10) 0.9053(4) 0.24888(9) 0.0623(5) Uani 1 1 d . . .
Cl2 Cl 0.07356(9) 1.3163(3) 0.23258(8) 0.0616(5) Uani 1 1 d . . .
N1 N 0.1397(2) 0.7615(9) 0.3600(2) 0.0415(13) Uani 1 1 d . . .
N2 N 0.1782(2) 0.5815(10) 0.3758(2) 0.0442(13) Uani 1 1 d . . .
H2 H 0.1993 0.5209 0.3536 0.053 Uiso 1 1 d R . .
N3 N 0.0641(2) 1.1023(10) 0.3449(2) 0.0455(13) Uani 1 1 d . . .
N4 N 0.0975(6) 0.467(2) 0.5582(5) 0.124(4) Uani 1 1 d . . .
O1 O 0.2478(3) -0.0950(11) 0.5822(3) 0.0744(16) Uani 1 1 d . . .
O2 O 0.3300(3) -0.1321(12) 0.4410(3) 0.0842(19) Uani 1 1 d . . .
Pt1 Pt 0.111138(12) 1.01237(4) 0.297886(11) 0.04505(13) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O3 H3A 0.8500 . ?
O3 H3B 0.8501 . ?
C3 N2 1.358(9) . ?
C3 C4 1.385(9) . ?
C3 C11 1.455(9) . ?
C4 C5 1.371(9) . ?
C4 H4 0.9300 . ?
C5 N1 1.365(8) . ?
C5 C6 1.458(9) . ?
C6 N3 1.380(9) . ?
C6 C7 1.367(11) . ?
C7 C8 1.387(10) . ?
C7 H7 0.9300 . ?
C8 C9 1.364(11) . ?
C8 H8 0.9300 . ?
C9 C10 1.364(10) . ?
C9 H9 0.9300 . ?
C10 N3 1.337(9) . ?
C10 H10 0.9300 . ?
C11 C12 1.383(9) . ?
C11 C16 1.397(9) . ?
C12 C13 1.398(10) . ?
C12 H12 0.9300 . ?
C13 O1 1.361(9) . ?
C13 C14 1.375(10) . ?
C14 C15 1.398(11) . ?
C14 H14 0.9300 . ?
C15 O2 1.377(9) . ?
C15 C16 1.369(10) . ?
C16 H16 0.9300 . ?
C17 O1 1.413(9) . ?
C17 C18 1.518(5) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 C19 1.518(5) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.517(5) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C21 1.518(5) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.518(5) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 O2 1.384(11) . ?
C23 C24 1.516(5) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 C25 1.509(5) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.516(5) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 C27 1.513(5) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.516(5) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 N4 1.113(13) . ?
C29 C30 1.460(16) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
Cl1 Pt1 2.3081(19) . ?
Cl2 Pt1 2.2812(18) . ?
N1 N2 1.335(7) . ?
N1 Pt1 1.999(5) . ?
N2 H2 0.9635 . ?
N3 Pt1 2.023(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
H3A O3 H3B 109.5 . . ?
N2 C3 C4 105.7(6) . . ?
N2 C3 C11 124.8(6) . . ?
C4 C3 C11 129.5(7) . . ?
C5 C4 C3 107.2(6) . . ?
C5 C4 H4 126.4 . . ?
C3 C4 H4 126.4 . . ?
N1 C5 C4 109.3(6) . . ?
N1 C5 C6 115.4(6) . . ?
C4 C5 C6 135.3(6) . . ?
N3 C6 C7 122.4(7) . . ?
N3 C6 C5 113.6(6) . . ?
C7 C6 C5 124.0(7) . . ?
C6 C7 C8 118.5(7) . . ?
C6 C7 H7 120.8 . . ?
C8 C7 H7 120.8 . . ?
C9 C8 C7 119.1(7) . . ?
C9 C8 H8 120.4 . . ?
C7 C8 H8 120.4 . . ?
C10 C9 C8 120.2(7) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
N3 C10 C9 122.5(7) . . ?
N3 C10 H10 118.8 . . ?
C9 C10 H10 118.8 . . ?
C12 C11 C16 119.5(6) . . ?
C12 C11 C3 118.9(6) . . ?
C16 C11 C3 121.6(6) . . ?
C11 C12 C13 121.0(7) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
O1 C13 C14 123.9(7) . . ?
O1 C13 C12 116.4(7) . . ?
C14 C13 C12 119.6(7) . . ?
C13 C14 C15 118.7(7) . . ?
C13 C14 H14 120.6 . . ?
C15 C14 H14 120.6 . . ?
O2 C15 C16 124.4(7) . . ?
O2 C15 C14 113.2(7) . . ?
C16 C15 C14 122.3(7) . . ?
C15 C16 C11 118.8(7) . . ?
C15 C16 H16 120.6 . . ?
C11 C16 H16 120.6 . . ?
O1 C17 C18 108.3(6) . . ?
O1 C17 H17A 110.0 . . ?
C18 C17 H17A 110.0 . . ?
O1 C17 H17B 110.0 . . ?
C18 C17 H17B 110.0 . . ?
H17A C17 H17B 108.4 . . ?
C19 C18 C17 113.1(7) . . ?
C19 C18 H18A 109.0 . . ?
C17 C18 H18A 109.0 . . ?
C19 C18 H18B 109.0 . . ?
C17 C18 H18B 109.0 . . ?
H18A C18 H18B 107.8 . . ?
C20 C19 C18 114.6(8) . . ?
C20 C19 H19A 108.6 . . ?
C18 C19 H19A 108.6 . . ?
C20 C19 H19B 108.6 . . ?
C18 C19 H19B 108.6 . . ?
H19A C19 H19B 107.6 . . ?
C19 C20 C21 111.8(9) . . ?
C19 C20 H20A 109.3 . . ?
C21 C20 H20A 109.3 . . ?
C19 C20 H20B 109.3 . . ?
C21 C20 H20B 109.3 . . ?
H20A C20 H20B 107.9 . . ?
C22 C21 C20 109.5(13) . . ?
C22 C21 H21A 109.8 . . ?
C20 C21 H21A 109.8 . . ?
C22 C21 H21B 109.8 . . ?
C20 C21 H21B 109.8 . . ?
H21A C21 H21B 108.2 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
O2 C23 C24 108.7(8) . . ?
O2 C23 H23A 109.9 . . ?
C24 C23 H23A 109.9 . . ?
O2 C23 H23B 109.9 . . ?
C24 C23 H23B 109.9 . . ?
H23A C23 H23B 108.3 . . ?
C25 C24 C23 112.5(8) . . ?
C25 C24 H24A 109.1 . . ?
C23 C24 H24A 109.1 . . ?
C25 C24 H24B 109.1 . . ?
C23 C24 H24B 109.1 . . ?
H24A C24 H24B 107.8 . . ?
C24 C25 C26 111.8(7) . . ?
C24 C25 H25A 109.3 . . ?
C26 C25 H25A 109.3 . . ?
C24 C25 H25B 109.3 . . ?
C26 C25 H25B 109.3 . . ?
H25A C25 H25B 107.9 . . ?
C27 C26 C25 112.1(8) . . ?
C27 C26 H26A 109.2 . . ?
C25 C26 H26A 109.2 . . ?
C27 C26 H26B 109.2 . . ?
C25 C26 H26B 109.2 . . ?
H26A C26 H26B 107.9 . . ?
C26 C27 C28 111.3(10) . . ?
C26 C27 H27A 109.4 . . ?
C28 C27 H27A 109.4 . . ?
C26 C27 H27B 109.4 . . ?
C28 C27 H27B 109.4 . . ?
H27A C27 H27B 108.0 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N4 C29 C30 177.1(15) . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N2 N1 C5 106.0(5) . . ?
N2 N1 Pt1 138.4(4) . . ?
C5 N1 Pt1 115.5(4) . . ?
N1 N2 C3 111.9(5) . . ?
N1 N2 H2 126.1 . . ?
C3 N2 H2 121.9 . . ?
C10 N3 C6 117.3(6) . . ?
C10 N3 Pt1 127.6(5) . . ?
C6 N3 Pt1 115.1(5) . . ?
C13 O1 C17 117.2(6) . . ?
C15 O2 C23 119.0(6) . . ?
N1 Pt1 N3 80.4(2) . . ?
N1 Pt1 Cl2 173.89(15) . . ?
N3 Pt1 Cl2 93.59(18) . . ?
N1 Pt1 Cl1 97.31(15) . . ?
N3 Pt1 Cl1 176.99(16) . . ?
Cl2 Pt1 Cl1 88.72(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C3 C4 C5 0.4(8) . . . . ?
C11 C3 C4 C5 -179.5(7) . . . . ?
C3 C4 C5 N1 -0.4(8) . . . . ?
C3 C4 C5 C6 -178.9(8) . . . . ?
N1 C5 C6 N3 -0.6(9) . . . . ?
C4 C5 C6 N3 177.7(7) . . . . ?
N1 C5 C6 C7 -179.0(7) . . . . ?
C4 C5 C6 C7 -0.7(13) . . . . ?
N3 C6 C7 C8 3.1(12) . . . . ?
C5 C6 C7 C8 -178.6(7) . . . . ?
C6 C7 C8 C9 -2.2(12) . . . . ?
C7 C8 C9 C10 0.8(13) . . . . ?
C8 C9 C10 N3 -0.2(12) . . . . ?
N2 C3 C11 C12 -177.9(6) . . . . ?
C4 C3 C11 C12 2.0(11) . . . . ?
N2 C3 C11 C16 3.1(11) . . . . ?
C4 C3 C11 C16 -177.1(7) . . . . ?
C16 C11 C12 C13 -1.1(11) . . . . ?
C3 C11 C12 C13 179.9(6) . . . . ?
C11 C12 C13 O1 -178.5(7) . . . . ?
C11 C12 C13 C14 -0.6(11) . . . . ?
O1 C13 C14 C15 179.1(8) . . . . ?
C12 C13 C14 C15 1.3(12) . . . . ?
C13 C14 C15 O2 -178.8(7) . . . . ?
C13 C14 C15 C16 -0.5(12) . . . . ?
O2 C15 C16 C11 177.0(8) . . . . ?
C14 C15 C16 C11 -1.1(12) . . . . ?
C12 C11 C16 C15 1.9(11) . . . . ?
C3 C11 C16 C15 -179.1(7) . . . . ?
O1 C17 C18 C19 174.3(9) . . . . ?
C17 C18 C19 C20 62.4(14) . . . . ?
C18 C19 C20 C21 177.3(11) . . . . ?
C19 C20 C21 C22 176.2(16) . . . . ?
O2 C23 C24 C25 -69.4(12) . . . . ?
C23 C24 C25 C26 -177.2(10) . . . . ?
C24 C25 C26 C27 177.2(11) . . . . ?
C25 C26 C27 C28 178.5(13) . . . . ?
C4 C5 N1 N2 0.3(7) . . . . ?
C6 C5 N1 N2 179.0(6) . . . . ?
C4 C5 N1 Pt1 -176.4(5) . . . . ?
C6 C5 N1 Pt1 2.3(7) . . . . ?
C5 N1 N2 C3 0.0(7) . . . . ?
Pt1 N1 N2 C3 175.5(5) . . . . ?
C4 C3 N2 N1 -0.3(8) . . . . ?
C11 C3 N2 N1 179.6(6) . . . . ?
C9 C10 N3 C6 1.0(10) . . . . ?
C9 C10 N3 Pt1 -178.5(6) . . . . ?
C7 C6 N3 C10 -2.5(10) . . . . ?
C5 C6 N3 C10 179.1(6) . . . . ?
C7 C6 N3 Pt1 177.1(6) . . . . ?
C5 C6 N3 Pt1 -1.3(7) . . . . ?
C14 C13 O1 C17 3.0(12) . . . . ?
C12 C13 O1 C17 -179.1(7) . . . . ?
C18 C17 O1 C13 176.7(8) . . . . ?
C16 C15 O2 C23 -5.6(13) . . . . ?
C14 C15 O2 C23 172.7(9) . . . . ?
C24 C23 O2 C15 179.9(8) . . . . ?
N2 N1 Pt1 N3 -177.6(7) . . . . ?
C5 N1 Pt1 N3 -2.4(5) . . . . ?
N2 N1 Pt1 Cl2 -170.2(11) . . . . ?
C5 N1 Pt1 Cl2 5.0(18) . . . . ?
N2 N1 Pt1 Cl1 0.5(6) . . . . ?
C5 N1 Pt1 Cl1 175.7(4) . . . . ?
C10 N3 Pt1 N1 -178.5(6) . . . . ?
C6 N3 Pt1 N1 2.0(5) . . . . ?
C10 N3 Pt1 Cl2 2.3(6) . . . . ?
C6 N3 Pt1 Cl2 -177.2(4) . . . . ?
C10 N3 Pt1 Cl1 142(3) . . . . ?
C6 N3 Pt1 Cl1 -37(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O3 0.96 1.93 2.884(8) 172.1 .

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.762
_refine_diff_density_min         -0.867
_refine_diff_density_rms         0.117

#====END
