# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1872479'
loop_
_audit_author_name
_audit_author_address
'yang mei'
; Soochow University
China
;
_audit_update_record             
;
2019-01-21 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C58 H52 Ag4 N6 O12 P4'
_chemical_formula_sum            'C58 H52 Ag4 N6 O12 P4'
_chemical_formula_weight         1580.41

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.096(2)
_cell_length_b                   23.934(5)
_cell_length_c                   11.876(2)
_cell_angle_alpha                90
_cell_angle_beta                 108.96(3)
_cell_angle_gamma                90
_cell_volume                     2982.8(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    10733
_cell_measurement_theta_min      3.0572
_cell_measurement_theta_max      27.5165

_exptl_crystal_description       Block
_exptl_crystal_colour            Dark-cyan
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.760
_exptl_crystal_F_000             1572
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.468
_shelx_estimated_absorpt_T_min   0.758
_shelx_estimated_absorpt_T_max   0.758
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6697
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
'Jacobson, R. (1998) Private communication to Rigaku Company, Tokyo, Japan.'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       /w
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14194
_diffrn_reflns_av_unetI/netI     0.0681
_diffrn_reflns_av_R_equivalents  0.0384
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         3.132
_diffrn_reflns_theta_max         27.494
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             6791
_reflns_number_gt                4621
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_cell_refinement       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_reduction        'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_structure_solution    'SHELXS-2016/6 (Sheldrick, 2016)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0317P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6791
_refine_ls_number_parameters     379
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1005
_refine_ls_R_factor_gt           0.0570
_refine_ls_wR_factor_ref         0.0989
_refine_ls_wR_factor_gt          0.0866
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_restrained_S_all      1.092
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.69561(4) 0.57823(2) 0.39149(4) 0.05298(14) Uani 1 1 d . . . . .
Ag2 Ag 0.86917(4) 0.44472(2) 0.50885(4) 0.04963(13) Uani 1 1 d . . . . .
P1 P 0.56752(11) 0.65817(4) 0.34018(11) 0.0328(3) Uani 1 1 d . . . . .
P2 P 0.11263(11) 0.59651(4) 0.30599(10) 0.0308(3) Uani 1 1 d . . . . .
N2 N 0.9365(4) 0.58260(16) 0.6138(4) 0.0431(10) Uani 1 1 d . . . . .
O1 O 0.9077(3) 0.55818(13) 0.5157(3) 0.0500(9) Uani 1 1 d . . . . .
O2 O 1.0485(4) 0.59266(17) 0.6668(4) 0.0803(13) Uani 1 1 d . . . . .
O3 O 0.8507(4) 0.59826(17) 0.6523(4) 0.0701(11) Uani 1 1 d . . . . .
N3 N 0.6346(5) 0.45666(19) 0.2885(4) 0.0557(12) Uani 1 1 d . . . . .
O4 O 0.7259(3) 0.48789(13) 0.3523(3) 0.0479(8) Uani 1 1 d . . . . .
O5 O 0.6416(4) 0.40625(16) 0.3111(4) 0.0773(12) Uani 1 1 d . . . . .
O6 O 0.5449(4) 0.47813(19) 0.2094(4) 0.0843(13) Uani 1 1 d . . . . .
N1 N 0.3744(3) 0.59718(14) 0.3804(3) 0.0352(9) Uani 1 1 d . . . . .
C1 C 0.4361(4) 0.65066(16) 0.4063(4) 0.0326(10) Uani 1 1 d . . . . .
H1A H 0.471214 0.655458 0.492793 0.039 Uiso 1 1 calc R U . . .
H1B H 0.372846 0.680178 0.374804 0.039 Uiso 1 1 calc R U . . .
C2 C 0.2641(4) 0.59351(17) 0.2728(4) 0.0317(10) Uani 1 1 d . . . . .
H2A H 0.267944 0.558395 0.231627 0.038 Uiso 1 1 calc R U . . .
H2B H 0.266780 0.624343 0.219359 0.038 Uiso 1 1 calc R U . . .
C3 C 0.4359(4) 0.54886(16) 0.4394(4) 0.0282(9) Uani 1 1 d . . . . .
C4 C 0.5483(4) 0.55217(17) 0.5383(4) 0.0329(10) Uani 1 1 d . . . . .
H4 H 0.582255 0.587504 0.565679 0.040 Uiso 1 1 calc R U . . .
C5 C 0.3900(4) 0.49509(17) 0.4038(4) 0.0330(10) Uani 1 1 d . . . . .
H5 H 0.314972 0.490905 0.338626 0.040 Uiso 1 1 calc R U . . .
C6 C 0.4800(4) 0.66583(18) 0.1833(4) 0.0360(11) Uani 1 1 d . . . . .
C7 C 0.3928(4) 0.7083(2) 0.1364(5) 0.0472(13) Uani 1 1 d . . . . .
H7 H 0.380910 0.736670 0.186541 0.057 Uiso 1 1 calc R U . . .
C8 C 0.3233(5) 0.7092(3) 0.0161(5) 0.0633(16) Uani 1 1 d . . . . .
H8 H 0.264788 0.738138 -0.015496 0.076 Uiso 1 1 calc R U . . .
C9 C 0.3404(7) 0.6672(3) -0.0572(6) 0.086(2) Uani 1 1 d . . . . .
H9 H 0.293623 0.667810 -0.138928 0.103 Uiso 1 1 calc R U . . .
C10 C 0.4236(6) 0.6254(3) -0.0127(6) 0.081(2) Uani 1 1 d . . . . .
H10 H 0.433297 0.596825 -0.063399 0.098 Uiso 1 1 calc R U . . .
C11 C 0.4946(5) 0.6241(2) 0.1065(5) 0.0562(14) Uani 1 1 d . . . . .
H11 H 0.553074 0.594947 0.136299 0.067 Uiso 1 1 calc R U . . .
C12 C 0.6334(4) 0.72535(17) 0.3991(4) 0.0345(10) Uani 1 1 d . . . . .
C13 C 0.6309(5) 0.77288(19) 0.3314(5) 0.0513(14) Uani 1 1 d . . . . .
H13 H 0.594842 0.771128 0.248055 0.062 Uiso 1 1 calc R U . . .
C14 C 0.6804(6) 0.8224(2) 0.3848(6) 0.0673(18) Uani 1 1 d . . . . .
H14 H 0.676635 0.854482 0.338017 0.081 Uiso 1 1 calc R U . . .
C15 C 0.7353(5) 0.8255(2) 0.5058(6) 0.0591(15) Uani 1 1 d . . . . .
H15 H 0.768613 0.859647 0.541693 0.071 Uiso 1 1 calc R U . . .
C16 C 0.7419(5) 0.7787(2) 0.5756(5) 0.0518(14) Uani 1 1 d . . . . .
H16 H 0.778984 0.780666 0.658774 0.062 Uiso 1 1 calc R U . . .
C17 C 0.6932(5) 0.72902(19) 0.5208(4) 0.0463(13) Uani 1 1 d . . . . .
H17 H 0.700824 0.696688 0.567569 0.056 Uiso 1 1 calc R U . . .
C18 C 0.0746(4) 0.67070(16) 0.3060(4) 0.0316(10) Uani 1 1 d . . . . .
C19 C 0.0163(4) 0.68938(18) 0.3867(4) 0.0418(12) Uani 1 1 d . . . . .
H19 H 0.001011 0.663969 0.440874 0.050 Uiso 1 1 calc R U . . .
C20 C -0.0194(5) 0.7445(2) 0.3887(5) 0.0523(14) Uani 1 1 d . . . . .
H20 H -0.059149 0.756289 0.443428 0.063 Uiso 1 1 calc R U . . .
C21 C 0.0031(5) 0.7821(2) 0.3109(5) 0.0554(15) Uani 1 1 d . . . . .
H21 H -0.019921 0.819810 0.312935 0.066 Uiso 1 1 calc R U . . .
C22 C 0.0595(5) 0.76445(19) 0.2298(5) 0.0512(14) Uani 1 1 d . . . . .
H22 H 0.074778 0.790228 0.176312 0.061 Uiso 1 1 calc R U . . .
C23 C 0.0939(4) 0.70928(17) 0.2262(4) 0.0404(11) Uani 1 1 d . . . . .
H23 H 0.130859 0.697676 0.169203 0.049 Uiso 1 1 calc R U . . .
C24 C -0.0049(4) 0.57014(16) 0.1709(4) 0.0335(10) Uani 1 1 d . . . . .
C25 C -0.1060(5) 0.53882(19) 0.1815(5) 0.0488(13) Uani 1 1 d . . . . .
H25 H -0.109963 0.529780 0.257255 0.059 Uiso 1 1 calc R U . . .
C26 C -0.2014(5) 0.5209(2) 0.0795(6) 0.0642(17) Uani 1 1 d . . . . .
H26 H -0.270871 0.500530 0.086946 0.077 Uiso 1 1 calc R U . . .
C27 C -0.1955(6) 0.5322(2) -0.0301(6) 0.0666(18) Uani 1 1 d . . . . .
H27 H -0.260934 0.519944 -0.098072 0.080 Uiso 1 1 calc R U . . .
C28 C -0.0949(6) 0.5615(2) -0.0426(5) 0.0579(15) Uani 1 1 d . . . . .
H28 H -0.090546 0.568998 -0.118871 0.070 Uiso 1 1 calc R U . . .
C29 C 0.0007(5) 0.58016(19) 0.0575(4) 0.0450(12) Uani 1 1 d . . . . .
H29 H 0.070261 0.599873 0.048608 0.054 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O4 2.260(3) . ?
Ag1 P1 2.3430(12) . ?
Ag1 O1 2.385(3) . ?
Ag2 O4 2.265(3) . ?
Ag2 P2 2.3582(13) 3_666 ?
Ag2 O1 2.587(3) 3_766 ?
P1 C6 1.808(5) . ?
P1 C12 1.810(4) . ?
P1 C1 1.876(4) . ?
P2 C24 1.821(5) . ?
P2 C18 1.825(4) . ?
P2 C2 1.849(4) . ?
N2 O2 1.221(5) . ?
N2 O3 1.241(5) . ?
N2 O1 1.248(5) . ?
N3 O5 1.233(5) . ?
N3 O6 1.237(5) . ?
N3 O4 1.289(5) . ?
N1 C3 1.408(5) . ?
N1 C1 1.437(5) . ?
N1 C2 1.456(5) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C3 C5 1.398(5) . ?
C3 C4 1.410(6) . ?
C4 C5 1.384(5) 3_666 ?
C4 H4 0.9400 . ?
C5 H5 0.9400 . ?
C6 C7 1.390(6) . ?
C6 C11 1.397(6) . ?
C7 C8 1.386(7) . ?
C7 H7 0.9400 . ?
C8 C9 1.383(8) . ?
C8 H8 0.9400 . ?
C9 C10 1.347(9) . ?
C9 H9 0.9400 . ?
C10 C11 1.379(7) . ?
C10 H10 0.9400 . ?
C11 H11 0.9400 . ?
C12 C17 1.384(6) . ?
C12 C13 1.388(6) . ?
C13 C14 1.373(7) . ?
C13 H13 0.9400 . ?
C14 C15 1.368(7) . ?
C14 H14 0.9400 . ?
C15 C16 1.381(7) . ?
C15 H15 0.9400 . ?
C16 C17 1.378(6) . ?
C16 H16 0.9400 . ?
C17 H17 0.9400 . ?
C18 C23 1.389(6) . ?
C18 C19 1.392(6) . ?
C19 C20 1.381(6) . ?
C19 H19 0.9400 . ?
C20 C21 1.369(7) . ?
C20 H20 0.9400 . ?
C21 C22 1.374(7) . ?
C21 H21 0.9400 . ?
C22 C23 1.379(6) . ?
C22 H22 0.9400 . ?
C23 H23 0.9400 . ?
C24 C29 1.388(6) . ?
C24 C25 1.388(6) . ?
C25 C26 1.393(7) . ?
C25 H25 0.9400 . ?
C26 C27 1.352(7) . ?
C26 H26 0.9400 . ?
C27 C28 1.366(8) . ?
C27 H27 0.9400 . ?
C28 C29 1.385(6) . ?
C28 H28 0.9400 . ?
C29 H29 0.9400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Ag1 P1 147.79(9) . . ?
O4 Ag1 O1 75.64(12) . . ?
P1 Ag1 O1 135.92(9) . . ?
O4 Ag2 P2 141.33(9) . 3_666 ?
O4 Ag2 O1 111.22(12) . 3_766 ?
P2 Ag2 O1 107.40(9) 3_666 3_766 ?
C6 P1 C12 108.8(2) . . ?
C6 P1 C1 102.1(2) . . ?
C12 P1 C1 101.2(2) . . ?
C6 P1 Ag1 115.34(15) . . ?
C12 P1 Ag1 119.35(15) . . ?
C1 P1 Ag1 107.53(13) . . ?
C24 P2 C18 103.77(19) . . ?
C24 P2 C2 103.8(2) . . ?
C18 P2 C2 105.34(19) . . ?
C24 P2 Ag2 119.78(15) . 3_666 ?
C18 P2 Ag2 110.88(15) . 3_666 ?
C2 P2 Ag2 111.98(14) . 3_666 ?
O2 N2 O3 121.7(5) . . ?
O2 N2 O1 118.8(4) . . ?
O3 N2 O1 119.4(4) . . ?
N2 O1 Ag1 112.7(3) . . ?
N2 O1 Ag2 98.8(3) . 3_766 ?
Ag1 O1 Ag2 136.37(15) . 3_766 ?
O5 N3 O6 123.4(5) . . ?
O5 N3 O4 117.2(5) . . ?
O6 N3 O4 119.4(4) . . ?
N3 O4 Ag1 122.3(3) . . ?
N3 O4 Ag2 115.2(3) . . ?
Ag1 O4 Ag2 112.29(14) . . ?
C3 N1 C1 120.3(4) . . ?
C3 N1 C2 121.4(3) . . ?
C1 N1 C2 116.6(3) . . ?
N1 C1 P1 112.1(3) . . ?
N1 C1 H1A 109.2 . . ?
P1 C1 H1A 109.2 . . ?
N1 C1 H1B 109.2 . . ?
P1 C1 H1B 109.2 . . ?
H1A C1 H1B 107.9 . . ?
N1 C2 P2 111.9(3) . . ?
N1 C2 H2A 109.2 . . ?
P2 C2 H2A 109.2 . . ?
N1 C2 H2B 109.2 . . ?
P2 C2 H2B 109.2 . . ?
H2A C2 H2B 107.9 . . ?
C5 C3 N1 122.4(4) . . ?
C5 C3 C4 116.1(4) . . ?
N1 C3 C4 121.5(4) . . ?
C5 C4 C3 121.9(4) 3_666 . ?
C5 C4 H4 119.0 3_666 . ?
C3 C4 H4 119.0 . . ?
C4 C5 C3 122.0(4) 3_666 . ?
C4 C5 H5 119.0 3_666 . ?
C3 C5 H5 119.0 . . ?
C7 C6 C11 118.3(5) . . ?
C7 C6 P1 123.9(4) . . ?
C11 C6 P1 117.6(4) . . ?
C8 C7 C6 120.4(5) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C9 C8 C7 119.6(6) . . ?
C9 C8 H8 120.2 . . ?
C7 C8 H8 120.2 . . ?
C10 C9 C8 120.6(6) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C9 C10 C11 120.6(6) . . ?
C9 C10 H10 119.7 . . ?
C11 C10 H10 119.7 . . ?
C10 C11 C6 120.4(5) . . ?
C10 C11 H11 119.8 . . ?
C6 C11 H11 119.8 . . ?
C17 C12 C13 117.8(4) . . ?
C17 C12 P1 117.1(3) . . ?
C13 C12 P1 125.1(4) . . ?
C14 C13 C12 120.7(5) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C15 C14 C13 120.4(5) . . ?
C15 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C14 C15 C16 120.4(5) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C17 C16 C15 118.7(5) . . ?
C17 C16 H16 120.6 . . ?
C15 C16 H16 120.6 . . ?
C16 C17 C12 121.9(5) . . ?
C16 C17 H17 119.0 . . ?
C12 C17 H17 119.0 . . ?
C23 C18 C19 117.7(4) . . ?
C23 C18 P2 124.0(3) . . ?
C19 C18 P2 118.2(3) . . ?
C20 C19 C18 121.2(5) . . ?
C20 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
C21 C20 C19 120.1(5) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 119.6(5) . . ?
C20 C21 H21 120.2 . . ?
C22 C21 H21 120.2 . . ?
C21 C22 C23 120.7(5) . . ?
C21 C22 H22 119.7 . . ?
C23 C22 H22 119.7 . . ?
C22 C23 C18 120.6(5) . . ?
C22 C23 H23 119.7 . . ?
C18 C23 H23 119.7 . . ?
C29 C24 C25 118.3(4) . . ?
C29 C24 P2 123.4(3) . . ?
C25 C24 P2 118.4(4) . . ?
C24 C25 C26 119.7(5) . . ?
C24 C25 H25 120.2 . . ?
C26 C25 H25 120.2 . . ?
C27 C26 C25 121.0(5) . . ?
C27 C26 H26 119.5 . . ?
C25 C26 H26 119.5 . . ?
C26 C27 C28 120.3(5) . . ?
C26 C27 H27 119.9 . . ?
C28 C27 H27 119.9 . . ?
C27 C28 C29 119.8(5) . . ?
C27 C28 H28 120.1 . . ?
C29 C28 H28 120.1 . . ?
C28 C29 C24 120.9(5) . . ?
C28 C29 H29 119.5 . . ?
C24 C29 H29 119.5 . . ?

_refine_diff_density_max         0.454
_refine_diff_density_min         -0.431
_refine_diff_density_rms         0.089



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 1874058'
loop_
_audit_author_name
_audit_author_address
yangmei
;Soochow University
China
;
_audit_update_record             
;
2018-10-18 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C58 H52 Ag4 N6 O12 P4, 2(C H2 Cl2)'
_chemical_formula_sum            'C60 H56 Ag4 Cl4 N6 O12 P4'
_chemical_formula_weight         1750.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   28.2415(8)
_cell_length_b                   13.1850(3)
_cell_length_c                   19.6699(5)
_cell_angle_alpha                90
_cell_angle_beta                 114.578(3)
_cell_angle_gamma                90
_cell_volume                     6660.7(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    6094
_cell_measurement_theta_min      3.2880
_cell_measurement_theta_max      77.1510
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.745
_exptl_crystal_F_000             3480
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.150
_exptl_absorpt_coefficient_mu    12.215
_shelx_estimated_absorpt_T_min   0.150
_shelx_estimated_absorpt_T_max   0.262
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.14173
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   'Enhance (Cu) X-ray Source'
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.4471
_diffrn_reflns_number            17036
_diffrn_reflns_av_unetI/netI     0.0568
_diffrn_reflns_av_R_equivalents  0.0582
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.442
_diffrn_reflns_theta_max         77.443
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7008
_reflns_number_gt                5721
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1597P)²+16.6144P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7008
_refine_ls_number_parameters     424
_refine_ls_number_restraints     63
_refine_ls_R_factor_all          0.0913
_refine_ls_R_factor_gt           0.0800
_refine_ls_wR_factor_ref         0.2333
_refine_ls_wR_factor_gt          0.2129
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.05268(2) 0.18978(4) 0.36008(3) 0.0456(2) Uani 1 1 d . . . . .
Ag2 Ag 0.05245(2) -0.01718(5) 0.21818(3) 0.0476(2) Uani 1 1 d . . . . .
P1 P 0.09249(5) 0.28462(10) 0.47079(8) 0.0266(3) Uani 1 1 d . . . . .
P2 P 0.11876(5) 0.12717(12) 0.72129(8) 0.0295(3) Uani 1 1 d . . . . .
N1 N 0.07759(18) 0.1490(4) 0.5678(3) 0.0273(9) Uani 1 1 d . . . . .
C1 C 0.06955(19) 0.2536(4) 0.5445(3) 0.0236(10) Uani 1 1 d . . . . .
H1A H 0.087920 0.296947 0.588059 0.028 Uiso 1 1 calc R U . . .
H1B H 0.032323 0.269164 0.525550 0.028 Uiso 1 1 calc R U . . .
C2 C 0.12553(19) 0.1237(4) 0.6315(3) 0.0275(11) Uani 1 1 d . . . . .
H2A H 0.152731 0.171657 0.633961 0.033 Uiso 1 1 calc R U . . .
H2B H 0.136647 0.055705 0.624279 0.033 Uiso 1 1 calc R U . . .
C3 C 0.03960(19) 0.0752(4) 0.5341(3) 0.0227(9) Uani 1 1 d . . . . .
C4 C 0.0454(2) -0.0251(4) 0.5600(3) 0.0274(11) Uani 1 1 d . . . . .
H4 H 0.076157 -0.043589 0.601087 0.033 Uiso 1 1 calc R U . . .
C5 C 0.0076(2) -0.0974(4) 0.5273(3) 0.0276(11) Uani 1 1 d . . . . .
H5 H 0.013387 -0.163739 0.546595 0.033 Uiso 1 1 calc R U . . .
C6 C 0.0871(2) 0.4230(5) 0.4655(3) 0.0306(11) Uani 1 1 d . . . . .
C7 C 0.1011(3) 0.4720(6) 0.4137(4) 0.0476(17) Uani 1 1 d . . . . .
H7 H 0.111712 0.434475 0.381839 0.057 Uiso 1 1 calc R U . . .
C8 C 0.0990(4) 0.5789(6) 0.4098(4) 0.057(2) Uani 1 1 d . . . . .
H8 H 0.108989 0.612581 0.375738 0.068 Uiso 1 1 calc R U . . .
C9 C 0.0826(3) 0.6346(5) 0.4548(5) 0.0513(19) Uani 1 1 d . . . . .
H9 H 0.080884 0.705690 0.451188 0.062 Uiso 1 1 calc R U . . .
C10 C 0.0687(3) 0.5861(5) 0.5047(5) 0.0513(19) Uani 1 1 d . . . . .
H10 H 0.057770 0.624452 0.535762 0.062 Uiso 1 1 calc R U . . .
C11 C 0.0704(3) 0.4807(5) 0.5108(4) 0.0405(14) Uani 1 1 d . . . . .
H11 H 0.060361 0.448620 0.545449 0.049 Uiso 1 1 calc R U . . .
C12 C 0.1625(2) 0.2623(5) 0.5218(4) 0.0354(13) Uani 1 1 d . . . . .
C13 C 0.1842(3) 0.1751(6) 0.5069(6) 0.0511(19) Uani 1 1 d . . . . .
H13 H 0.164383 0.132713 0.466629 0.061 Uiso 1 1 calc R U . . .
C14 C 0.2363(4) 0.1518(8) 0.5532(8) 0.080(4) Uani 1 1 d . . . . .
H14 H 0.250943 0.092038 0.544218 0.096 Uiso 1 1 calc R U . . .
C15 C 0.2654(3) 0.2117(10) 0.6092(7) 0.078(3) Uani 1 1 d . . . . .
H15 H 0.300505 0.195249 0.638013 0.094 Uiso 1 1 calc R U . . .
C16 C 0.2446(3) 0.2973(8) 0.6251(6) 0.063(2) Uani 1 1 d . . . . .
H16 H 0.265214 0.338577 0.665612 0.075 Uiso 1 1 calc R U . . .
C17 C 0.1926(3) 0.3237(6) 0.5811(5) 0.0459(16) Uani 1 1 d . . . . .
H17 H 0.178279 0.382727 0.591884 0.055 Uiso 1 1 calc R U . . .
C18 C 0.1855(3) 0.1054(9) 0.7909(6) 0.0749(15) Uani 1 1 d . U . . .
C19 C 0.1919(4) 0.0892(10) 0.8635(6) 0.0805(15) Uani 1 1 d . U . . .
H19 H 0.163450 0.089718 0.876484 0.097 Uiso 1 1 calc R U . . .
C20 C 0.2440(4) 0.0715(10) 0.9182(7) 0.0853(16) Uani 1 1 d . U . . .
H20 H 0.249040 0.052002 0.966680 0.102 Uiso 1 1 calc R U . . .
C21 C 0.2834(4) 0.0814(10) 0.9034(6) 0.0845(16) Uani 1 1 d . U . . .
H21 H 0.316981 0.077192 0.942132 0.101 Uiso 1 1 calc R U . . .
C22 C 0.2775(4) 0.0979(10) 0.8320(6) 0.0807(15) Uani 1 1 d . U . . .
H22 H 0.306944 0.102228 0.821282 0.097 Uiso 1 1 calc R U . . .
C23 C 0.2281(3) 0.1084(9) 0.7753(6) 0.0765(15) Uani 1 1 d . U . . .
H23 H 0.223936 0.117540 0.725778 0.092 Uiso 1 1 calc R U . . .
C24 C 0.1082(2) 0.2618(5) 0.7291(3) 0.0345(12) Uani 1 1 d . . . . .
C25 C 0.0565(3) 0.2966(7) 0.7062(4) 0.0500(18) Uani 1 1 d . . . . .
H25 H 0.029100 0.249721 0.693897 0.060 Uiso 1 1 calc R U . . .
C26 C 0.0463(4) 0.3983(8) 0.7020(5) 0.064(3) Uani 1 1 d . . . . .
H26 H 0.011896 0.421016 0.687104 0.077 Uiso 1 1 calc R U . . .
C27 C 0.0865(5) 0.4685(7) 0.7196(6) 0.072(3) Uani 1 1 d . . . . .
H27 H 0.079172 0.538341 0.714784 0.086 Uiso 1 1 calc R U . . .
C28 C 0.1375(5) 0.4347(7) 0.7444(6) 0.066(2) Uani 1 1 d . . . . .
H28 H 0.164915 0.481869 0.759230 0.080 Uiso 1 1 calc R U . . .
C29 C 0.1483(3) 0.3309(6) 0.7475(5) 0.0497(17) Uani 1 1 d . . . . .
H29 H 0.182715 0.308340 0.762152 0.060 Uiso 1 1 calc R U . . .
N2 N 0.0648(2) -0.0491(4) 0.3864(3) 0.0353(11) Uani 1 1 d . . . . .
O1 O 0.03584(16) 0.0137(3) 0.3347(2) 0.0300(8) Uani 1 1 d . . . . .
O2 O 0.0496(3) -0.1358(5) 0.3824(5) 0.079(2) Uani 1 1 d . . . . .
O3 O 0.1046(2) -0.0181(5) 0.4355(4) 0.0619(16) Uani 1 1 d . . . . .
N3 N 0.0734(6) 0.2396(10) 0.2208(5) 0.107(2) Uani 1 1 d . U . . .
O4 O 0.0436(3) 0.1763(4) 0.2314(3) 0.0532(13) Uani 1 1 d . . . . .
O5 O 0.1079(4) 0.2786(8) 0.2718(4) 0.108(2) Uani 1 1 d . U . . .
O6 O 0.0597(4) 0.2765(8) 0.1577(4) 0.108(2) Uani 1 1 d . U . . .
C30 C 0.1726(5) 0.1609(10) 0.0846(8) 0.091(4) Uani 0.5 1 d . . P A 1
H30A H 0.156094 0.227095 0.081651 0.109 Uiso 0.5 1 calc R U P A 1
H30B H 0.145793 0.113870 0.052389 0.109 Uiso 0.5 1 calc R U P A 1
Cl1 Cl 0.1956(4) 0.1189(6) 0.1734(4) 0.114(3) Uani 0.5 1 d . . P A 1
Cl2 Cl 0.2200(6) 0.1726(10) 0.0512(9) 0.168(5) Uani 0.5 1 d . . P A 1
C30A C 0.1726(5) 0.1609(10) 0.0846(8) 0.091(4) Uani 0.5 1 d . . P B 2
H30C H 0.144220 0.124038 0.045343 0.109 Uiso 0.5 1 calc R U P B 2
H30D H 0.179287 0.223179 0.062835 0.109 Uiso 0.5 1 calc R U P B 2
Cl1A Cl 0.1549(4) 0.1912(8) 0.1582(6) 0.129(4) Uani 0.5 1 d . . P B 2
Cl2A Cl 0.2274(5) 0.0875(9) 0.1190(6) 0.142(4) Uani 0.5 1 d . . P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.3523(14) . ?
Ag1 O1 2.381(4) . ?
Ag1 O4 2.442(6) . ?
Ag1 O4 2.567(6) 2 ?
Ag2 O1 2.304(4) 2 ?
Ag2 P2 2.3492(15) 6 ?
Ag2 O1 2.555(4) . ?
Ag2 O4 2.586(6) . ?
P1 C6 1.830(6) . ?
P1 C12 1.830(6) . ?
P1 C1 1.863(5) . ?
P2 C24 1.817(7) . ?
P2 C18 1.835(8) . ?
P2 C2 1.855(6) . ?
N1 C3 1.395(7) . ?
N1 C1 1.441(7) . ?
N1 C2 1.450(6) . ?
C3 C4 1.403(7) . ?
C3 C5 1.407(7) 5_556 ?
C4 C5 1.376(8) . ?
C6 C11 1.394(9) . ?
C6 C7 1.397(9) . ?
C7 C8 1.412(11) . ?
C8 C9 1.371(13) . ?
C9 C10 1.357(13) . ?
C10 C11 1.394(9) . ?
C12 C17 1.383(11) . ?
C12 C13 1.390(10) . ?
C13 C14 1.406(13) . ?
C14 C15 1.326(19) . ?
C15 C16 1.368(17) . ?
C16 C17 1.405(11) . ?
C18 C23 1.359(17) . ?
C18 C19 1.378(17) . ?
C19 C20 1.434(12) . ?
C20 C21 1.269(18) . ?
C21 C22 1.361(18) . ?
C22 C23 1.385(11) . ?
C24 C29 1.380(10) . ?
C24 C25 1.413(10) . ?
C25 C26 1.367(13) . ?
C26 C27 1.392(16) . ?
C27 C28 1.387(16) . ?
C28 C29 1.398(12) . ?
N2 O3 1.210(8) . ?
N2 O2 1.212(8) . ?
N2 O1 1.302(7) . ?
N3 O5 1.186(12) . ?
N3 O6 1.236(13) . ?
N3 O4 1.264(12) . ?
C30 Cl1 1.683(15) . ?
C30 Cl2 1.726(18) . ?
C30A Cl2A 1.707(18) . ?
C30A Cl1A 1.763(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 O1 133.60(11) . . ?
P1 Ag1 O4 143.32(14) . . ?
O1 Ag1 O4 77.61(17) . . ?
P1 Ag1 O4 130.14(13) . 2 ?
O1 Ag1 O4 74.00(16) . 2 ?
O4 Ag1 O4 69.2(2) . 2 ?
O1 Ag2 P2 145.32(11) 2 6 ?
O1 Ag2 O1 78.96(15) 2 . ?
P2 Ag2 O1 121.12(10) 6 . ?
O1 Ag2 O4 74.88(18) 2 . ?
P2 Ag2 O4 135.68(15) 6 . ?
O1 Ag2 O4 72.02(16) . . ?
C6 P1 C12 103.7(3) . . ?
C6 P1 C1 102.4(3) . . ?
C12 P1 C1 100.6(3) . . ?
C6 P1 Ag1 118.76(19) . . ?
C12 P1 Ag1 114.4(2) . . ?
C1 P1 Ag1 114.63(17) . . ?
C24 P2 C18 104.1(4) . . ?
C24 P2 C2 100.9(3) . . ?
C18 P2 C2 103.1(4) . . ?
C24 P2 Ag2 116.6(2) . 6_556 ?
C18 P2 Ag2 118.9(4) . 6_556 ?
C2 P2 Ag2 110.92(18) . 6_556 ?
C3 N1 C1 121.8(4) . . ?
C3 N1 C2 120.5(5) . . ?
C1 N1 C2 117.5(4) . . ?
N1 C1 P1 113.5(4) . . ?
N1 C2 P2 112.8(4) . . ?
N1 C3 C4 122.3(5) . . ?
N1 C3 C5 122.0(5) . 5_556 ?
C4 C3 C5 115.7(5) . 5_556 ?
C5 C4 C3 122.2(5) . . ?
C4 C5 C3 122.1(5) . 5_556 ?
C11 C6 C7 119.2(6) . . ?
C11 C6 P1 123.4(5) . . ?
C7 C6 P1 117.4(5) . . ?
C6 C7 C8 118.9(8) . . ?
C9 C8 C7 121.2(7) . . ?
C10 C9 C8 119.4(7) . . ?
C9 C10 C11 121.5(8) . . ?
C6 C11 C10 119.8(7) . . ?
C17 C12 C13 119.5(7) . . ?
C17 C12 P1 120.9(5) . . ?
C13 C12 P1 119.1(6) . . ?
C12 C13 C14 118.6(9) . . ?
C15 C14 C13 121.9(9) . . ?
C14 C15 C16 120.3(8) . . ?
C15 C16 C17 120.2(9) . . ?
C12 C17 C16 119.5(8) . . ?
C23 C18 C19 119.4(8) . . ?
C23 C18 P2 123.9(8) . . ?
C19 C18 P2 116.6(9) . . ?
C18 C19 C20 117.0(12) . . ?
C21 C20 C19 122.3(12) . . ?
C20 C21 C22 120.8(9) . . ?
C21 C22 C23 119.7(12) . . ?
C18 C23 C22 120.4(12) . . ?
C29 C24 C25 119.7(7) . . ?
C29 C24 P2 121.4(6) . . ?
C25 C24 P2 118.4(6) . . ?
C26 C25 C24 120.1(9) . . ?
C25 C26 C27 120.5(8) . . ?
C28 C27 C26 119.6(8) . . ?
C27 C28 C29 120.4(9) . . ?
C24 C29 C28 119.7(8) . . ?
O3 N2 O2 123.7(6) . . ?
O3 N2 O1 118.9(6) . . ?
O2 N2 O1 117.4(6) . . ?
N2 O1 Ag2 116.7(4) . 2 ?
N2 O1 Ag1 116.7(4) . . ?
Ag2 O1 Ag1 110.57(16) 2 . ?
N2 O1 Ag2 108.0(3) . . ?
Ag2 O1 Ag2 97.77(15) 2 . ?
Ag1 O1 Ag2 104.40(16) . . ?
O5 N3 O6 118.9(10) . . ?
O5 N3 O4 121.0(9) . . ?
O6 N3 O4 118.3(10) . . ?
N3 O4 Ag1 109.5(6) . . ?
N3 O4 Ag1 115.0(7) . 2 ?
Ag1 O4 Ag1 110.2(3) . 2 ?
N3 O4 Ag2 122.4(9) . . ?
Ag1 O4 Ag2 101.7(2) . . ?
Ag1 O4 Ag2 96.69(19) 2 . ?
Cl1 C30 Cl2 113.5(11) . . ?
Cl2A C30A Cl1A 108.9(9) . . ?

_refine_diff_density_max         2.806
_refine_diff_density_min         -1.514
_refine_diff_density_rms         0.234



