# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1909266'
loop_
_audit_author_name
_audit_author_address
'Celia Maya'
;University of Seville
Spain
;
_audit_update_record             
;
2019-04-10 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;

_vrf_PLAT213_5                   
;
PROBLEM: Atom X has ADP max/min Ratio .
RESPONSE: This value is due to unsolved disorder 
in t-Butyl groups.
;
_vrf_PLAT412_5                   
;
PROBLEM:  Short Intra XH3 .. XHn 
RESPONSE: This alert is due to close contacts between protons of
highly disorderd terminal methyl groups with high thermal parameters
;
_vrf_PLAT770_5                   
;
PROBLEM:  Suspect C-H Bond in CIF 
RESPONSE: False alert, these C and H atoms belong to different methyl
groups of disordered t-butyl. They do not form any bond.
;
_vrf_PLAT201_5                   
;
PROBLEM:  Isotropic non-H Atoms in Main Residue(s)
RESPONSE: C27 and C28 belong to a minor disorder modelling.
;
_vrf_PLAT220_5                   
;
PROBLEM:  Non-Solvent  Resd 1  C   Ueq(max)/Ueq(min) Range 
RESPONSE: This is logical in a structure where significant disorder 
of the numerous tBu groups is observed.
;
_vrf_PLAT242_5                   
;
PROBLEM:  Low    'MainMol' Ueq as Compared to Neighbors of 
RESPONSE: This is logical in a structure where significant disorder 
of the numerous tBu groups is observed.
;
_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C27 H56 Ag0.50 F3 N O2 P2 Pt S'
_chemical_formula_weight         826.75

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0015 0.0009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0056 0.0036 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0096 0.0061 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0667 0.0580 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.0826 0.0763 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -1.6473 0.7167 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -0.6812 5.7081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0030 0.0019 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.0486(7)
_cell_length_b                   12.1884(10)
_cell_length_c                   14.5657(11)
_cell_angle_alpha                86.336(4)
_cell_angle_beta                 65.642(2)
_cell_angle_gamma                60.390(2)
_cell_volume                     1667.5(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    5893
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      18.69

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.647
_exptl_crystal_F_000             831
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.140
_exptl_absorpt_coefficient_mu    2.543
_shelx_estimated_absorpt_T_min   0.558
_shelx_estimated_absorpt_T_max   0.717
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6065
_exptl_absorpt_correction_T_max  0.7447
_exptl_absorpt_process_details   
; 
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical 
 X-ray Solutions, Madison, Wisconsin, USA. 
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.56086
_diffrn_radiation_type           AgK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            27272
_diffrn_reflns_av_unetI/netI     0.0653
_diffrn_reflns_av_R_equivalents  0.0575
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.541
_diffrn_reflns_theta_max         22.031
_diffrn_reflns_theta_full        19.665
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             8249
_reflns_number_gt                6611
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+0.5972P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8249
_refine_ls_number_parameters     480
_refine_ls_number_restraints     89
_refine_ls_R_factor_all          0.0623
_refine_ls_R_factor_gt           0.0454
_refine_ls_wR_factor_ref         0.1352
_refine_ls_wR_factor_gt          0.1190
_refine_ls_goodness_of_fit_ref   0.896
_refine_ls_restrained_S_all      0.904
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.500000 0.500000 0.500000 0.02633(15) Uani 1 2 d S . P A 1
P1A P 0.53199(18) 0.21201(14) 0.72382(12) 0.0256(3) Uani 0.689(17) 1 d D . P .
.
P1B P 0.53199(18) 0.21201(14) 0.72382(12) 0.0256(3) Uani 0.311(17) 1 d D . P B
2
C1A C 0.5103(14) 0.1401(10) 0.8450(8) 0.030(5) Uani 0.64(2) 1 d D . P B 1
C2A C 0.3604(18) 0.212(2) 0.9296(15) 0.17(2) Uani 0.64(2) 1 d D . P B 1
H2A1 H 0.297664 0.205355 0.909139 0.258 Uiso 0.64(2) 1 calc R U P B 1
H2A2 H 0.330925 0.301109 0.942665 0.258 Uiso 0.64(2) 1 calc R U P B 1
H2A3 H 0.357602 0.176745 0.990636 0.258 Uiso 0.64(2) 1 calc R U P B 1
C3A C 0.603(2) 0.1537(18) 0.8849(15) 0.086(8) Uani 0.64(2) 1 d D . P B 1
H3A1 H 0.599840 0.113549 0.944043 0.129 Uiso 0.64(2) 1 calc R U P B 1
H3A2 H 0.567448 0.242917 0.903116 0.129 Uiso 0.64(2) 1 calc R U P B 1
H3A3 H 0.698857 0.113073 0.832527 0.129 Uiso 0.64(2) 1 calc R U P B 1
C4A C 0.558(2) -0.0014(13) 0.8327(12) 0.077(7) Uani 0.64(2) 1 d D . P B 1
H4A1 H 0.532812 -0.025538 0.898985 0.116 Uiso 0.64(2) 1 calc R U P B 1
H4A2 H 0.659709 -0.051126 0.793141 0.116 Uiso 0.64(2) 1 calc R U P B 1
H4A3 H 0.513340 -0.016876 0.798276 0.116 Uiso 0.64(2) 1 calc R U P B 1
C1B C 0.495(2) 0.1457(19) 0.8478(13) 0.054(16) Uiso 0.36(2) 1 d D . P B 2
C2B C 0.462(3) 0.230(2) 0.940(2) 0.056(7) Uiso 0.36(2) 1 d D . P B 2
H2B1 H 0.386940 0.315310 0.947807 0.083 Uiso 0.36(2) 1 calc R U P B 2
H2B2 H 0.545583 0.230709 0.929699 0.083 Uiso 0.36(2) 1 calc R U P B 2
H2B3 H 0.433294 0.195197 1.000929 0.083 Uiso 0.36(2) 1 calc R U P B 2
C4B C 0.358(2) 0.145(2) 0.874(2) 0.052(7) Uiso 0.36(2) 1 d D . P B 2
H4B1 H 0.371553 0.094350 0.818604 0.078 Uiso 0.36(2) 1 calc R U P B 2
H4B2 H 0.281758 0.231700 0.884737 0.078 Uiso 0.36(2) 1 calc R U P B 2
H4B3 H 0.334866 0.110163 0.935254 0.078 Uiso 0.36(2) 1 calc R U P B 2
C3B C 0.610(2) 0.009(2) 0.8395(19) 0.040(6) Uiso 0.36(2) 1 d D . P B 2
H3B1 H 0.573627 -0.026362 0.897233 0.060 Uiso 0.36(2) 1 calc R U P B 2
H3B2 H 0.690173 0.009356 0.838661 0.060 Uiso 0.36(2) 1 calc R U P B 2
H3B3 H 0.639690 -0.042341 0.777514 0.060 Uiso 0.36(2) 1 calc R U P B 2
C5A C 0.7251(13) 0.1320(13) 0.6319(11) 0.105(10) Uani 0.689(17) 1 d D . P B .
C6A C 0.742(3) 0.169(2) 0.5287(13) 0.22(2) Uani 0.689(17) 1 d D . P . .
H6A1 H 0.650532 0.215361 0.528242 0.330 Uiso 0.689(17) 1 calc R U P B .
H6A2 H 0.802805 0.092881 0.477167 0.330 Uiso 0.689(17) 1 calc R U P . .
H6A3 H 0.783110 0.221829 0.514576 0.330 Uiso 0.689(17) 1 calc R U P . .
C7A C 0.791(2) 0.183(2) 0.672(2) 0.150(15) Uani 0.689(17) 1 d D . P . .
H7A1 H 0.877006 0.171343 0.617076 0.226 Uiso 0.689(17) 1 calc R U P B .
H7A2 H 0.811696 0.137656 0.724500 0.226 Uiso 0.689(17) 1 calc R U P . .
H7A3 H 0.725617 0.272715 0.699915 0.226 Uiso 0.689(17) 1 calc R U P . .
C8A C 0.8072(18) -0.0122(14) 0.6179(15) 0.25(3) Uani 0.689(17) 1 d D . P . .
H8A1 H 0.752(3) -0.030(5) 0.595(3) 0.368 Uiso 0.689(17) 1 d D U P . .
H8A2 H 0.813(10) -0.063(4) 0.670(3) 0.368 Uiso 0.689(17) 1 d D U P . .
H8A3 H 0.901(2) -0.063(18) 0.563(4) 0.368 Uiso 0.689(17) 1 d D U P . .
C9A C 0.4395(17) 0.1657(12) 0.6643(11) 0.070(6) Uani 0.639(18) 1 d D U P B 1
C10A C 0.510(2) 0.0229(15) 0.6247(12) 0.183(19) Uani 0.639(18) 1 d D U P B 1
H10A H 0.438(3) 0.040(10) 0.604(3) 0.274 Uiso 0.639(18) 1 d D U P B 1
H10B H 0.504(9) -0.016(5) 0.684(2) 0.274 Uiso 0.639(18) 1 d D U P B 1
H10C H 0.604(3) -0.01(2) 0.570(3) 0.274 Uiso 0.639(18) 1 d D U P B 1
C11A C 0.2830(18) 0.2142(19) 0.744(2) 0.158(17) Uani 0.639(18) 1 d D . P B 1
H11A H 0.250173 0.286631 0.791815 0.237 Uiso 0.639(18) 1 calc R U P B 1
H11B H 0.278959 0.146751 0.780770 0.237 Uiso 0.639(18) 1 calc R U P B 1
H11C H 0.223720 0.238907 0.709688 0.237 Uiso 0.639(18) 1 calc R U P B 1
C12A C 0.431(3) 0.242(2) 0.5765(17) 0.164(18) Uani 0.639(18) 1 d D . P B 1
H12A H 0.522640 0.229345 0.532489 0.246 Uiso 0.639(18) 1 calc R U P B 1
H12B H 0.364437 0.331621 0.604529 0.246 Uiso 0.639(18) 1 calc R U P B 1
H12C H 0.399106 0.212877 0.537944 0.246 Uiso 0.639(18) 1 calc R U P B 1
C5B C 0.7225(15) 0.1808(15) 0.6783(12) 0.023(5) Uiso 0.311(17) 1 d D . P B 2
C6B C 0.748(3) 0.265(2) 0.5972(17) 0.040(6) Uiso 0.311(17) 1 d D . P B 2
H6B1 H 0.847580 0.234925 0.561923 0.060 Uiso 0.311(17) 1 calc R U P B 2
H6B2 H 0.697257 0.352443 0.630587 0.060 Uiso 0.311(17) 1 calc R U P B 2
H6B3 H 0.714415 0.260144 0.549039 0.060 Uiso 0.311(17) 1 calc R U P B 2
C7B C 0.747(3) 0.219(2) 0.7654(16) 0.036(6) Uiso 0.311(17) 1 d D . P B 2
H7B1 H 0.833710 0.220657 0.735952 0.054 Uiso 0.311(17) 1 calc R U P B 2
H7B2 H 0.754157 0.157357 0.810467 0.054 Uiso 0.311(17) 1 calc R U P B 2
H7B3 H 0.669043 0.302311 0.803359 0.054 Uiso 0.311(17) 1 calc R U P B 2
C8B C 0.847(3) 0.041(2) 0.6286(17) 0.043(7) Uiso 0.311(17) 1 d D . P B 2
H8B1 H 0.853980 0.019230 0.563564 0.064 Uiso 0.311(17) 1 calc R U P B 2
H8B2 H 0.830471 -0.016621 0.672637 0.064 Uiso 0.311(17) 1 calc R U P B 2
H8B3 H 0.934457 0.034039 0.618872 0.064 Uiso 0.311(17) 1 calc R U P B 2
C9B C 0.5349(19) 0.1198(15) 0.6231(11) 0.037(5) Uiso 0.361(18) 1 d D . P B 2
C10B C 0.596(2) 0.148(2) 0.5208(17) 0.053(7) Uiso 0.361(18) 1 d D . P B 2
H10D H 0.696740 0.109723 0.497262 0.080 Uiso 0.361(18) 1 calc R U P B 2
H10E H 0.552951 0.238849 0.523976 0.080 Uiso 0.361(18) 1 calc R U P B 2
H10F H 0.579216 0.112855 0.474164 0.080 Uiso 0.361(18) 1 calc R U P B 2
C11B C 0.609(3) -0.021(2) 0.620(2) 0.071(9) Uiso 0.361(18) 1 d D . P B 2
H11D H 0.627704 -0.063827 0.557345 0.106 Uiso 0.361(18) 1 calc R U P B 2
H11E H 0.550725 -0.041855 0.677181 0.106 Uiso 0.361(18) 1 calc R U P B 2
H11F H 0.697644 -0.049661 0.622306 0.106 Uiso 0.361(18) 1 calc R U P B 2
C12B C 0.381(3) 0.171(2) 0.656(2) 0.052(7) Uiso 0.361(18) 1 d D . P B 2
H12D H 0.327871 0.260255 0.684226 0.078 Uiso 0.361(18) 1 calc R U P B 2
H12E H 0.349796 0.125428 0.707368 0.078 Uiso 0.361(18) 1 calc R U P B 2
H12F H 0.366791 0.158644 0.598380 0.078 Uiso 0.361(18) 1 calc R U P B 2
P2 P 0.25334(17) 0.64580(15) 0.84785(12) 0.0255(3) Uani 1 1 d D . . A 1
C13A C 0.0951(9) 0.7318(10) 0.8176(7) 0.074(3) Uani 1 1 d D . . A 1
C14A C 0.0160(12) 0.6650(18) 0.8376(11) 0.122(6) Uani 1 1 d . . . A 1
H14A H -0.008107 0.647876 0.906290 0.183 Uiso 1 1 calc R U . A 1
H14B H 0.073874 0.585614 0.790168 0.183 Uiso 1 1 calc R U . A 1
H14C H -0.069276 0.717900 0.829536 0.183 Uiso 1 1 calc R U . A 1
C15A C -0.010(2) 0.8719(18) 0.872(2) 0.28(2) Uani 1 1 d . . . A 1
H15A H -0.096447 0.903025 0.865601 0.419 Uiso 1 1 calc R U . A 1
H15B H 0.030815 0.923262 0.841932 0.419 Uiso 1 1 calc R U . A 1
H15C H -0.030886 0.877085 0.943490 0.419 Uiso 1 1 calc R U . A 1
C16A C 0.1468(19) 0.738(2) 0.7003(12) 0.177(11) Uani 1 1 d . . . A 1
H16A H 0.066854 0.776568 0.684569 0.266 Uiso 1 1 calc R U . A 1
H16B H 0.213966 0.652885 0.661201 0.266 Uiso 1 1 calc R U . A 1
H16C H 0.191167 0.788487 0.683351 0.266 Uiso 1 1 calc R U . A 1
C17A C 0.3524(11) 0.7351(9) 0.8171(7) 0.076(4) Uani 1 1 d D . . . .
C18A C 0.408(2) 0.745(2) 0.7034(10) 0.194(12) Uani 1 1 d D . . . .
H18A H 0.442779 0.802773 0.691962 0.290 Uiso 1 1 calc R U . . .
H18B H 0.332760 0.775745 0.683240 0.290 Uiso 1 1 calc R U . . .
H18C H 0.484114 0.661496 0.663595 0.290 Uiso 1 1 calc R U . . .
C19A C 0.4828(14) 0.6641(15) 0.8370(11) 0.120(6) Uani 1 1 d D . . . .
H19A H 0.526519 0.714629 0.826379 0.180 Uiso 1 1 calc R U . . .
H19B H 0.549092 0.583478 0.790813 0.180 Uiso 1 1 calc R U . . .
H19C H 0.455354 0.649267 0.906275 0.180 Uiso 1 1 calc R U . . .
C20A C 0.265(2) 0.8707(12) 0.8766(16) 0.252(17) Uani 1 1 d D . . C 4
H20A H 0.244333 0.867901 0.947527 0.379 Uiso 1 1 calc R U . C 4
H20B H 0.177507 0.916342 0.870229 0.379 Uiso 1 1 calc R U . C 4
H20C H 0.317273 0.913569 0.849835 0.379 Uiso 1 1 calc R U . C 4
C21 C 0.1792(8) 0.6508(7) 0.9923(5) 0.0372(16) Uani 1 1 d D . . . .
C22 C 0.081(2) 0.7795(12) 1.0586(8) 0.146(9) Uani 1 1 d . . . . .
H22A H 0.046658 0.769916 1.129074 0.220 Uiso 1 1 calc R U . . .
H22B H 0.002267 0.826946 1.041993 0.220 Uiso 1 1 calc R U . . .
H22C H 0.130648 0.824676 1.047405 0.220 Uiso 1 1 calc R U . . .
C23 C 0.0962(14) 0.5845(15) 1.0232(8) 0.092(4) Uani 1 1 d . . . . .
H23A H 0.086832 0.561605 1.089186 0.137 Uiso 1 1 calc R U . . .
H23B H 0.144798 0.508503 0.973749 0.137 Uiso 1 1 calc R U . . .
H23C H 0.003546 0.640928 1.026555 0.137 Uiso 1 1 calc R U . . .
C24 C 0.2956(13) 0.5849(14) 1.0236(8) 0.089(4) Uani 1 1 d . . . . .
H24A H 0.327441 0.641592 1.028675 0.133 Uiso 1 1 calc R U . . .
H24B H 0.373143 0.509653 0.973634 0.133 Uiso 1 1 calc R U . . .
H24C H 0.261802 0.560630 1.088939 0.133 Uiso 1 1 calc R U . . .
Pt1A Pt 0.40282(2) 0.43460(2) 0.75980(2) 0.02397(9) Uani 0.488(11) 1 d D . P A
1
H1A H 0.273(8) 0.4222(11) 0.827(4) 0.12(10) Uiso 0.488(11) 1 d D . P A 1
C25 C 0.5569(13) 0.4615(12) 0.6384(9) 0.024(3) Uiso 0.488(11) 1 d . . P A 1
C26 C 0.6471(15) 0.4768(13) 0.5676(11) 0.033(3) Uiso 0.488(11) 1 d . . P A 1
H26 H 0.714884 0.488311 0.514287 0.040 Uiso 0.488(11) 1 calc R U P A 1
Pt1B Pt 0.40282(2) 0.43460(2) 0.75980(2) 0.02397(9) Uani 0.512(11) 1 d D . P B
2
H1B H 0.448(13) 0.404(12) 0.859(8) 0.02(3) Uiso 0.512(11) 1 d D . P A 2
C27 C 0.3435(14) 0.4622(12) 0.6392(9) 0.028(3) Uani 0.512(11) 1 d . . P B 2
C28 C 0.3093(14) 0.4759(13) 0.5694(10) 0.034(3) Uani 0.512(11) 1 d . . P B 2
H28 H 0.283149 0.486447 0.516206 0.040 Uiso 0.512(11) 1 calc R U P A 2
F1A F 0.068(2) 0.232(2) 0.6383(16) 0.105(6) Uiso 0.411(5) 1 d . . P D 1
F2A F 0.049(3) 0.397(2) 0.6822(19) 0.098(7) Uiso 0.411(5) 1 d . . P D 1
F3A F -0.129(3) 0.401(2) 0.683(2) 0.103(8) Uiso 0.411(5) 1 d . . P D 1
F1B F -0.1971(14) 0.6180(13) 0.7748(8) 0.118(5) Uani 0.589(5) 1 d D . P D 2
F2B F 0.0016(13) 0.4656(13) 0.6976(11) 0.097(5) Uani 0.589(5) 1 d D . P D 2
F3B F -0.1661(16) 0.4656(14) 0.6979(11) 0.093(5) Uani 0.589(5) 1 d D . P D 2
N1A N 0.0737(11) 0.5005(12) 0.4996(11) 0.100(4) Uani 1 1 d . U . D 2
S1 S 0.0684(6) 0.3672(5) 0.4956(4) 0.0460(14) Uiso 0.411(5) 1 d . . P D 1
O3A O -0.0060(14) 0.3614(13) 0.4515(10) 0.037(3) Uiso 0.411(5) 1 d . . P D 1
O4A O 0.250(2) 0.2862(19) 0.3910(16) 0.070(5) Uiso 0.411(5) 1 d . . P D 1
S1B S -0.0938(4) 0.6078(3) 0.5790(3) 0.0477(10) Uani 0.589(5) 1 d . U P D 2
O3B O -0.1993(12) 0.6555(19) 0.5478(11) 0.097(6) Uani 0.589(5) 1 d . . P D 2
O4B O -0.0639(17) 0.7195(16) 0.587(2) 0.177(13) Uani 0.589(5) 1 d . . P D 2
C29A C 0.005(3) 0.358(2) 0.6334(19) 0.062(6) Uiso 0.411(5) 1 d . . P D 1
C29B C -0.1137(12) 0.5317(14) 0.6951(12) 0.061(4) Uani 0.589(5) 1 d D . P D 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C26 2.258(13) 2_666 ?
Ag1 C26 2.258(13) . ?
Ag1 C25 2.336(12) . ?
Ag1 C25 2.336(12) 2_666 ?
P1A C5A 1.874(11) . ?
P1A C9B 1.883(13) . ?
P1A C1A 1.897(8) . ?
P1A C1B 1.903(15) . ?
P1A C5B 1.940(13) . ?
P1A C9A 1.947(12) . ?
P1A Pt1B 2.3225(15) . ?
P1A Pt1A 2.3225(15) . ?
C1A C2A 1.512(15) . ?
C1A C4A 1.519(13) . ?
C1A C3A 1.527(14) . ?
C2A H2A1 0.9600 . ?
C2A H2A2 0.9600 . ?
C2A H2A3 0.9600 . ?
C3A H3A1 0.9600 . ?
C3A H3A2 0.9600 . ?
C3A H3A3 0.9600 . ?
C4A H4A1 0.9600 . ?
C4A H4A2 0.9600 . ?
C4A H4A3 0.9600 . ?
C1B C3B 1.524(19) . ?
C1B C2B 1.533(19) . ?
C1B C4B 1.53(2) . ?
C2B H2B1 0.9600 . ?
C2B H2B2 0.9600 . ?
C2B H2B3 0.9600 . ?
C4B H4B1 0.9600 . ?
C4B H4B2 0.9600 . ?
C4B H4B3 0.9600 . ?
C3B H3B1 0.9600 . ?
C3B H3B2 0.9600 . ?
C3B H3B3 0.9600 . ?
C5A C6A 1.503(15) . ?
C5A C7A 1.506(16) . ?
C5A C8A 1.507(15) . ?
C6A H6A1 0.9600 . ?
C6A H6A2 0.9600 . ?
C6A H6A3 0.9600 . ?
C7A H7A1 0.9600 . ?
C7A H7A2 0.9600 . ?
C7A H7A3 0.9600 . ?
C8A H8A1 0.9590(10) . ?
C8A H8A2 0.9590(10) . ?
C8A H8A3 0.9590(11) . ?
C9A C10A 1.533(15) . ?
C9A C12A 1.541(16) . ?
C9A C11A 1.561(17) . ?
C10A H10A 0.9590(10) . ?
C10A H10B 0.9590(10) . ?
C10A H10C 0.9590(12) . ?
C11A H11A 0.9600 . ?
C11A H11B 0.9600 . ?
C11A H11C 0.9600 . ?
C12A H12A 0.9600 . ?
C12A H12B 0.9600 . ?
C12A H12C 0.9600 . ?
C5B C6B 1.549(18) . ?
C5B C8B 1.554(19) . ?
C5B C7B 1.563(18) . ?
C6B H6B1 0.9600 . ?
C6B H6B2 0.9600 . ?
C6B H6B3 0.9600 . ?
C7B H7B1 0.9600 . ?
C7B H7B2 0.9600 . ?
C7B H7B3 0.9600 . ?
C8B H8A2 1.54(7) . ?
C8B H8A3 1.33(15) . ?
C8B H8B1 0.9600 . ?
C8B H8B2 0.9600 . ?
C8B H8B3 0.9600 . ?
C9B C10B 1.47(2) . ?
C9B C12B 1.49(2) . ?
C9B C11B 1.49(2) . ?
C10B H10D 0.9600 . ?
C10B H10E 0.9600 . ?
C10B H10F 0.9600 . ?
C11B H8A1 1.56(4) . ?
C11B H11D 0.9600 . ?
C11B H11E 0.9600 . ?
C11B H11F 0.9600 . ?
C12B H12D 0.9600 . ?
C12B H12E 0.9600 . ?
C12B H12F 0.9600 . ?
P2 C13A 1.894(8) . ?
P2 C17A 1.895(8) . ?
P2 C21 1.908(7) . ?
P2 Pt1A 2.3345(15) . ?
C13A C14A 1.470(19) . ?
C13A C15A 1.537(18) . ?
C13A C16A 1.570(17) . ?
C14A H14A 0.9600 . ?
C14A H14B 0.9600 . ?
C14A H14C 0.9600 . ?
C15A H15A 0.9600 . ?
C15A H15B 0.9600 . ?
C15A H15C 0.9600 . ?
C16A H16A 0.9600 . ?
C16A H16B 0.9600 . ?
C16A H16C 0.9600 . ?
C17A C19A 1.516(13) . ?
C17A C20A 1.517(12) . ?
C17A C18A 1.531(13) . ?
C18A H18A 0.9600 . ?
C18A H18B 0.9600 . ?
C18A H18C 0.9600 . ?
C19A H19A 0.9600 . ?
C19A H19B 0.9600 . ?
C19A H19C 0.9600 . ?
C20A H20A 0.9600 . ?
C20A H20B 0.9600 . ?
C20A H20C 0.9600 . ?
C21 C24 1.479(13) . ?
C21 C22 1.486(12) . ?
C21 C23 1.496(14) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
Pt1A C25 2.121(12) . ?
Pt1A H1A 1.54(9) . ?
C25 C26 1.238(19) . ?
C26 H26 0.9300 . ?
Pt1B C27 2.106(12) . ?
Pt1B H1B 1.71(8) . ?
C27 C28 1.219(17) . ?
C28 H28 0.9300 . ?
F1A C29A 1.34(3) . ?
F2A C29A 1.28(3) . ?
F3A C29A 1.29(3) . ?
F1B C29B 1.269(13) . ?
F2B C29B 1.230(13) . ?
F3B C29B 1.235(14) . ?
N1A S1B 1.661(13) 2_566 ?
N1A S1B 1.668(12) . ?
N1A O3B 1.69(2) 2_566 ?
N1A N1A 1.78(2) 2_566 ?
S1 O3A 1.329(13) . ?
S1 O4A 1.84(2) . ?
S1 C29A 1.85(3) . ?
S1B O3B 1.369(12) . ?
S1B O4B 1.592(15) . ?
S1B C29B 1.861(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C26 Ag1 C26 180.0 2_666 . ?
C26 Ag1 C25 148.8(5) 2_666 . ?
C26 Ag1 C25 31.2(5) . . ?
C26 Ag1 C25 31.2(5) 2_666 2_666 ?
C26 Ag1 C25 148.8(5) . 2_666 ?
C25 Ag1 C25 180.0 . 2_666 ?
C5A P1A C9B 80.3(8) . . ?
C5A P1A C1A 109.6(6) . . ?
C5A P1A C1B 113.9(7) . . ?
C9B P1A C1B 111.0(8) . . ?
C5A P1A C5B 27.5(7) . . ?
C9B P1A C5B 107.7(7) . . ?
C1B P1A C5B 104.5(8) . . ?
C5A P1A C9A 107.7(8) . . ?
C1A P1A C9A 104.4(6) . . ?
C5A P1A Pt1B 117.4(5) . . ?
C9B P1A Pt1B 121.8(5) . . ?
C1B P1A Pt1B 109.8(6) . . ?
C5B P1A Pt1B 100.1(5) . . ?
C5A P1A Pt1A 117.4(5) . . ?
C1A P1A Pt1A 111.8(3) . . ?
C9A P1A Pt1A 104.9(4) . . ?
C2A C1A C4A 108.1(10) . . ?
C2A C1A C3A 105.9(10) . . ?
C4A C1A C3A 106.3(9) . . ?
C2A C1A P1A 113.1(9) . . ?
C4A C1A P1A 116.2(8) . . ?
C3A C1A P1A 106.4(8) . . ?
C1A C2A H2A1 109.5 . . ?
C1A C2A H2A2 109.5 . . ?
H2A1 C2A H2A2 109.5 . . ?
C1A C2A H2A3 109.5 . . ?
H2A1 C2A H2A3 109.5 . . ?
H2A2 C2A H2A3 109.5 . . ?
C1A C3A H3A1 109.5 . . ?
C1A C3A H3A2 109.5 . . ?
H3A1 C3A H3A2 109.5 . . ?
C1A C3A H3A3 109.5 . . ?
H3A1 C3A H3A3 109.5 . . ?
H3A2 C3A H3A3 109.5 . . ?
C1A C4A H4A1 109.5 . . ?
C1A C4A H4A2 109.5 . . ?
H4A1 C4A H4A2 109.5 . . ?
C1A C4A H4A3 109.5 . . ?
H4A1 C4A H4A3 109.5 . . ?
H4A2 C4A H4A3 109.5 . . ?
C3B C1B C2B 108.7(12) . . ?
C3B C1B C4B 107.9(13) . . ?
C2B C1B C4B 105.4(12) . . ?
C3B C1B P1A 114.3(15) . . ?
C2B C1B P1A 114.7(15) . . ?
C4B C1B P1A 105.3(15) . . ?
C1B C2B H2B1 109.5 . . ?
C1B C2B H2B2 109.5 . . ?
H2B1 C2B H2B2 109.5 . . ?
C1B C2B H2B3 109.5 . . ?
H2B1 C2B H2B3 109.5 . . ?
H2B2 C2B H2B3 109.5 . . ?
C1B C4B H4B1 109.5 . . ?
C1B C4B H4B2 109.5 . . ?
H4B1 C4B H4B2 109.5 . . ?
C1B C4B H4B3 109.5 . . ?
H4B1 C4B H4B3 109.5 . . ?
H4B2 C4B H4B3 109.5 . . ?
C1B C3B H3B1 109.5 . . ?
C1B C3B H3B2 109.5 . . ?
H3B1 C3B H3B2 109.5 . . ?
C1B C3B H3B3 109.5 . . ?
H3B1 C3B H3B3 109.5 . . ?
H3B2 C3B H3B3 109.5 . . ?
C6A C5A C7A 107.6(12) . . ?
C6A C5A C8A 108.1(10) . . ?
C7A C5A C8A 108.4(11) . . ?
C6A C5A P1A 110.1(12) . . ?
C7A C5A P1A 106.9(12) . . ?
C8A C5A P1A 115.4(10) . . ?
C5A C6A H6A1 109.5 . . ?
C5A C6A H6A2 109.5 . . ?
H6A1 C6A H6A2 109.5 . . ?
C5A C6A H6A3 109.5 . . ?
H6A1 C6A H6A3 109.5 . . ?
H6A2 C6A H6A3 109.5 . . ?
C5A C7A H7A1 109.5 . . ?
C5A C7A H7A2 109.5 . . ?
H7A1 C7A H7A2 109.5 . . ?
C5A C7A H7A3 109.5 . . ?
H7A1 C7A H7A3 109.5 . . ?
H7A2 C7A H7A3 109.5 . . ?
C5A C8A H8A1 99(3) . . ?
C5A C8A H8A2 127(3) . . ?
H8A1 C8A H8A2 101(7) . . ?
C5A C8A H8A3 122(10) . . ?
H8A1 C8A H8A3 101(7) . . ?
H8A2 C8A H8A3 101(7) . . ?
C10A C9A C12A 109.9(10) . . ?
C10A C9A C11A 107.7(10) . . ?
C12A C9A C11A 106.3(11) . . ?
C10A C9A P1A 116.6(11) . . ?
C12A C9A P1A 106.3(10) . . ?
C11A C9A P1A 109.6(9) . . ?
C9A C10A H10A 91(6) . . ?
C9A C10A H10B 105(4) . . ?
H10A C10A H10B 115(5) . . ?
C9A C10A H10C 113(10) . . ?
H10A C10A H10C 115(5) . . ?
H10B C10A H10C 115(5) . . ?
C9A C11A H11A 109.5 . . ?
C9A C11A H11B 109.5 . . ?
H11A C11A H11B 109.5 . . ?
C9A C11A H11C 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
C9A C12A H12A 109.5 . . ?
C9A C12A H12B 109.5 . . ?
H12A C12A H12B 109.5 . . ?
C9A C12A H12C 109.5 . . ?
H12A C12A H12C 109.5 . . ?
H12B C12A H12C 109.5 . . ?
C6B C5B C8B 106.2(11) . . ?
C6B C5B C7B 105.4(11) . . ?
C8B C5B C7B 105.0(11) . . ?
C6B C5B P1A 109.2(12) . . ?
C8B C5B P1A 116.8(13) . . ?
C7B C5B P1A 113.4(12) . . ?
C5B C6B H6B1 109.5 . . ?
C5B C6B H6B2 109.5 . . ?
H6B1 C6B H6B2 109.5 . . ?
C5B C6B H6B3 109.5 . . ?
H6B1 C6B H6B3 109.5 . . ?
H6B2 C6B H6B3 109.5 . . ?
C5B C7B H7B1 109.5 . . ?
C5B C7B H7B2 109.5 . . ?
H7B1 C7B H7B2 109.5 . . ?
C5B C7B H7B3 109.5 . . ?
H7B1 C7B H7B3 109.5 . . ?
H7B2 C7B H7B3 109.5 . . ?
C5B C8B H8A2 115(3) . . ?
C5B C8B H8A3 146(3) . . ?
H8A2 C8B H8A3 62(8) . . ?
C5B C8B H8B1 109.5 . . ?
H8A2 C8B H8B1 90.9 . . ?
H8A3 C8B H8B1 40.9 . . ?
C5B C8B H8B2 109.5 . . ?
H8A2 C8B H8B2 18.9 . . ?
H8A3 C8B H8B2 76.8 . . ?
H8B1 C8B H8B2 109.5 . . ?
C5B C8B H8B3 109.5 . . ?
H8A2 C8B H8B3 120.9 . . ?
H8A3 C8B H8B3 99.0 . . ?
H8B1 C8B H8B3 109.5 . . ?
H8B2 C8B H8B3 109.5 . . ?
C10B C9B C12B 109.4(12) . . ?
C10B C9B C11B 109.5(12) . . ?
C12B C9B C11B 109.5(12) . . ?
C10B C9B P1A 111.9(14) . . ?
C12B C9B P1A 102.5(14) . . ?
C11B C9B P1A 113.8(16) . . ?
C9B C10B H10D 109.5 . . ?
C9B C10B H10E 109.5 . . ?
H10D C10B H10E 109.5 . . ?
C9B C10B H10F 109.5 . . ?
H10D C10B H10F 109.5 . . ?
H10E C10B H10F 109.5 . . ?
C9B C11B H8A1 92(2) . . ?
C9B C11B H11D 109.5 . . ?
H8A1 C11B H11D 103.8 . . ?
C9B C11B H11E 109.5 . . ?
H8A1 C11B H11E 130.2 . . ?
H11D C11B H11E 109.5 . . ?
C9B C11B H11F 109.5 . . ?
H8A1 C11B H11F 22.1 . . ?
H11D C11B H11F 109.5 . . ?
H11E C11B H11F 109.5 . . ?
C9B C12B H12D 109.5 . . ?
C9B C12B H12E 109.5 . . ?
H12D C12B H12E 109.5 . . ?
C9B C12B H12F 109.5 . . ?
H12D C12B H12F 109.5 . . ?
H12E C12B H12F 109.5 . . ?
C13A P2 C17A 110.8(5) . . ?
C13A P2 C21 106.6(4) . . ?
C17A P2 C21 106.7(4) . . ?
C13A P2 Pt1A 110.4(3) . . ?
C17A P2 Pt1A 111.3(3) . . ?
C21 P2 Pt1A 110.9(2) . . ?
C14A C13A C15A 108.5(15) . . ?
C14A C13A C16A 105.2(12) . . ?
C15A C13A C16A 105.1(15) . . ?
C14A C13A P2 113.1(8) . . ?
C15A C13A P2 114.4(10) . . ?
C16A C13A P2 109.8(8) . . ?
C13A C14A H14A 109.5 . . ?
C13A C14A H14B 109.5 . . ?
H14A C14A H14B 109.5 . . ?
C13A C14A H14C 109.5 . . ?
H14A C14A H14C 109.5 . . ?
H14B C14A H14C 109.5 . . ?
C13A C15A H15A 109.5 . . ?
C13A C15A H15B 109.5 . . ?
H15A C15A H15B 109.5 . . ?
C13A C15A H15C 109.5 . . ?
H15A C15A H15C 109.5 . . ?
H15B C15A H15C 109.5 . . ?
C13A C16A H16A 109.5 . . ?
C13A C16A H16B 109.5 . . ?
H16A C16A H16B 109.5 . . ?
C13A C16A H16C 109.5 . . ?
H16A C16A H16C 109.5 . . ?
H16B C16A H16C 109.5 . . ?
C19A C17A C20A 107.3(9) . . ?
C19A C17A C18A 105.5(9) . . ?
C20A C17A C18A 106.8(9) . . ?
C19A C17A P2 111.1(7) . . ?
C18A C17A P2 111.1(8) . . ?
C17A C18A H18A 109.5 . . ?
C17A C18A H18B 109.5 . . ?
H18A C18A H18B 109.5 . . ?
C17A C18A H18C 109.5 . . ?
H18A C18A H18C 109.5 . . ?
H18B C18A H18C 109.5 . . ?
C17A C19A H19A 109.5 . . ?
C17A C19A H19B 109.5 . . ?
H19A C19A H19B 109.5 . . ?
C17A C19A H19C 109.5 . . ?
H19A C19A H19C 109.5 . . ?
H19B C19A H19C 109.5 . . ?
C17A C20A H20A 109.5 . . ?
C17A C20A H20B 109.5 . . ?
H20A C20A H20B 109.5 . . ?
C17A C20A H20C 109.5 . . ?
H20A C20A H20C 109.5 . . ?
H20B C20A H20C 109.5 . . ?
C24 C21 C22 105.6(10) . . ?
C24 C21 C23 108.0(9) . . ?
C22 C21 C23 105.0(10) . . ?
C24 C21 P2 110.7(6) . . ?
C22 C21 P2 117.0(7) . . ?
C23 C21 P2 110.0(6) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C25 Pt1A P1A 96.4(3) . . ?
C25 Pt1A P2 97.7(3) . . ?
P1A Pt1A P2 162.16(6) . . ?
C25 Pt1A H1A 164.1(8) . . ?
P1A Pt1A H1A 86.1(3) . . ?
P2 Pt1A H1A 83.3(3) . . ?
C26 C25 Pt1A 179.8(16) . . ?
C26 C25 Ag1 70.9(8) . . ?
Pt1A C25 Ag1 109.1(5) . . ?
C25 C26 Ag1 77.9(8) . . ?
C25 C26 H26 180.0 . . ?
Ag1 C26 H26 102.1 . . ?
C27 Pt1B P1A 96.7(3) . . ?
C27 Pt1B H1B 176(4) . . ?
P1A Pt1B H1B 80(4) . . ?
C28 C27 Pt1B 178.8(11) . . ?
C27 C28 H28 180.0 . . ?
S1B N1A S1B 115.5(6) 2_566 . ?
S1B N1A O3B 48.3(5) 2_566 2_566 ?
S1B N1A O3B 147.3(9) . 2_566 ?
O3A S1 O4A 102.2(9) . . ?
O3A S1 C29A 115.7(10) . . ?
O4A S1 C29A 130.1(10) . . ?
O3B S1B O4B 106.8(11) . . ?
O3B S1B N1A 121.0(8) . . ?
O4B S1B N1A 95.3(8) . . ?
N1A S1B N1A 64.5(6) 2_566 . ?
O3B S1B C29B 119.2(8) . . ?
O4B S1B C29B 111.9(12) . . ?
N1A S1B C29B 99.6(6) 2_566 . ?
N1A S1B C29B 100.1(6) . . ?
F2A C29A F3A 112(3) . . ?
F2A C29A F1A 101(2) . . ?
F3A C29A F1A 105(2) . . ?
F2A C29A S1 116(2) . . ?
F3A C29A S1 115(2) . . ?
F1A C29A S1 106.0(18) . . ?
F2B C29B F3B 110.0(14) . . ?
F2B C29B F1B 108.2(13) . . ?
F3B C29B F1B 107.4(13) . . ?
F2B C29B S1B 110.7(11) . . ?
F3B C29B S1B 110.8(11) . . ?
F1B C29B S1B 109.6(12) . . ?

_refine_diff_density_max         1.652
_refine_diff_density_min         -1.589
_refine_diff_density_rms         0.184

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_7
_database_code_depnum_ccdc_archive 'CCDC 1909270'
loop_
_audit_author_name
_audit_author_address
'Celia Maya'
;University of Seville
Spain
;
_audit_update_record             
;
2019-04-10 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;

_vrf_PLAT029_7                   
; 
PROBLEM: diffrn_measured_fraction_theta_full value Low . . 
RESPONSE: The quality of this crystal was poor, however, it represents the 
 best possible data after multiple recrystallization attempts. 
;
_vrf_PLAT213_7                   
; 
PROBLEM: Atom C16             has ADP max/min Ratio .... 
RESPONSE: This value is due to unsolved disorder in t-Butyl groups. 
;
_vrf_PLAT242_7                   
; 
PROBLEM: Low    'MainMol' Ueq as Compared to Neighbors 
RESPONSE: This value is due to unsolved disorder in t-Butyl groups. 
;
_vrf_PLAT220_7                   
; 
PROBLEM: Non-Solvent  Resd 1  C   Ueq(max)/Ueq(min) Range 
RESPONSE: This value is due to unsolved disorder in t-Butyl groups. 
;


_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C39 H83 F9 N1.50 O6 P3 Pt1.50 S3'
_chemical_formula_weight         1321.79

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.5584(12)
_cell_length_b                   13.122(2)
_cell_length_c                   48.577(7)
_cell_angle_alpha                90
_cell_angle_beta                 92.538(9)
_cell_angle_gamma                90
_cell_volume                     5450.1(14)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    2519
_cell_measurement_theta_min      2.64
_cell_measurement_theta_max      24.75

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.611
_exptl_crystal_F_000             2666
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.14
_exptl_absorpt_coefficient_mu    4.126
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5335
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_process_details   
; 
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical 
 X-ray Solutions, Madison, Wisconsin, USA. 
;

_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            11882
_diffrn_reflns_av_unetI/netI     0.0723
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       64
_diffrn_reflns_theta_min         1.608
_diffrn_reflns_theta_max         30.493
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.453
_diffrn_measured_fraction_theta_full 0.635
_diffrn_reflns_Laue_measured_fraction_max 0.453
_diffrn_reflns_Laue_measured_fraction_full 0.635
_diffrn_reflns_point_group_measured_fraction_max 0.453
_diffrn_reflns_point_group_measured_fraction_full 0.635
_reflns_number_total             7550
_reflns_number_gt                5509
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+0.3187P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7550
_refine_ls_number_parameters     621
_refine_ls_number_restraints     25
_refine_ls_R_factor_all          0.0857
_refine_ls_R_factor_gt           0.0567
_refine_ls_wR_factor_ref         0.1660
_refine_ls_wR_factor_gt          0.1431
_refine_ls_goodness_of_fit_ref   0.982
_refine_ls_restrained_S_all      1.015
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.31883(4) 0.48000(3) 0.66741(2) 0.02602(16) Uani 1 1 d D . . . .
P1 P 0.2113(3) 0.52448(18) 0.62446(6) 0.0236(6) Uani 1 1 d D . . . .
P2 P 0.4293(3) 0.43628(19) 0.71024(5) 0.0224(6) Uani 1 1 d D . . . .
C1 C 0.0846(12) 0.6404(8) 0.6304(2) 0.035(3) Uani 1 1 d . . . . .
C2 C 0.0469(14) 0.7044(9) 0.6055(3) 0.067(4) Uani 1 1 d . . . . .
H2A H -0.008053 0.663907 0.591742 0.101 Uiso 1 1 calc R U . . .
H2B H 0.142000 0.729645 0.598261 0.101 Uiso 1 1 calc R U . . .
H2C H -0.017583 0.760682 0.610516 0.101 Uiso 1 1 calc R U . . .
C3 C 0.1719(15) 0.7077(10) 0.6530(3) 0.080(5) Uani 1 1 d . . . . .
H3A H 0.280176 0.713717 0.648872 0.120 Uiso 1 1 calc R U . . .
H3B H 0.163472 0.676306 0.670708 0.120 Uiso 1 1 calc R U . . .
H3C H 0.125239 0.774231 0.653193 0.120 Uiso 1 1 calc R U . . .
C4 C -0.0672(13) 0.6092(9) 0.6442(2) 0.049(3) Uani 1 1 d . . . . .
H4A H -0.128462 0.668846 0.647570 0.073 Uiso 1 1 calc R U . . .
H4B H -0.041279 0.575714 0.661407 0.073 Uiso 1 1 calc R U . . .
H4C H -0.126300 0.563565 0.632340 0.073 Uiso 1 1 calc R U . . .
C5 C 0.3737(12) 0.5589(9) 0.6013(2) 0.041(3) Uani 1 1 d . . . . .
C6 C 0.4558(13) 0.6561(9) 0.6118(3) 0.061(4) Uani 1 1 d . . . . .
H6A H 0.552456 0.664462 0.602787 0.091 Uiso 1 1 calc R U . . .
H6B H 0.476737 0.650898 0.631359 0.091 Uiso 1 1 calc R U . . .
H6C H 0.389565 0.713869 0.607947 0.091 Uiso 1 1 calc R U . . .
C7 C 0.3208(13) 0.5755(11) 0.5708(2) 0.062(4) Uani 1 1 d . . . . .
H7A H 0.249490 0.631912 0.569444 0.094 Uiso 1 1 calc R U . . .
H7B H 0.269567 0.515122 0.563798 0.094 Uiso 1 1 calc R U . . .
H7C H 0.410354 0.589678 0.560227 0.094 Uiso 1 1 calc R U . . .
C8 C 0.4994(14) 0.4760(11) 0.6041(3) 0.077(5) Uani 1 1 d . . . . .
H8A H 0.470063 0.419320 0.592466 0.116 Uiso 1 1 calc R U . . .
H8B H 0.509317 0.453656 0.622900 0.116 Uiso 1 1 calc R U . . .
H8C H 0.597585 0.502992 0.598639 0.116 Uiso 1 1 calc R U . . .
C9 C 0.0829(14) 0.4191(8) 0.6091(2) 0.039(3) Uani 1 1 d . . . . .
C10 C -0.0270(14) 0.4548(10) 0.5851(3) 0.055(3) Uani 1 1 d . . . . .
H10A H 0.033164 0.487307 0.571335 0.082 Uiso 1 1 calc R U . . .
H10B H -0.101737 0.502226 0.591764 0.082 Uiso 1 1 calc R U . . .
H10C H -0.080936 0.397057 0.577062 0.082 Uiso 1 1 calc R U . . .
C11 C 0.1860(15) 0.3364(9) 0.5974(3) 0.070(4) Uani 1 1 d . . . . .
H11A H 0.262863 0.315325 0.611211 0.105 Uiso 1 1 calc R U . . .
H11B H 0.237560 0.362716 0.581726 0.105 Uiso 1 1 calc R U . . .
H11C H 0.122514 0.279043 0.591808 0.105 Uiso 1 1 calc R U . . .
C12 C -0.0088(13) 0.3691(8) 0.6315(2) 0.048(3) Uani 1 1 d . . . . .
H12A H -0.080068 0.320094 0.623303 0.071 Uiso 1 1 calc R U . . .
H12B H -0.066534 0.420150 0.640880 0.071 Uiso 1 1 calc R U . . .
H12C H 0.062130 0.335530 0.644355 0.071 Uiso 1 1 calc R U . . .
C13 C 0.5727(15) 0.5402(11) 0.7209(3) 0.058(4) Uani 1 1 d . . . . .
C14 C 0.7012(17) 0.5442(15) 0.7008(3) 0.136(9) Uani 1 1 d . . . . .
H14A H 0.763640 0.604042 0.704197 0.204 Uiso 1 1 calc R U . . .
H14B H 0.656339 0.546401 0.682328 0.204 Uiso 1 1 calc R U . . .
H14C H 0.765794 0.484670 0.702987 0.204 Uiso 1 1 calc R U . . .
C15 C 0.492(2) 0.6437(11) 0.7179(5) 0.161(10) Uani 1 1 d . . . . .
H15A H 0.422469 0.653008 0.732624 0.241 Uiso 1 1 calc R U . . .
H15B H 0.433439 0.646372 0.700545 0.241 Uiso 1 1 calc R U . . .
H15C H 0.569301 0.696743 0.718472 0.241 Uiso 1 1 calc R U . . .
C16 C 0.647(2) 0.5247(15) 0.7490(4) 0.178(13) Uani 1 1 d . . . . .
H16A H 0.643337 0.453713 0.753646 0.267 Uiso 1 1 calc R U . . .
H16B H 0.590490 0.563262 0.762134 0.267 Uiso 1 1 calc R U . . .
H16C H 0.753297 0.547276 0.749203 0.267 Uiso 1 1 calc R U . . .
C17 C 0.2700(13) 0.4232(10) 0.7357(2) 0.051(4) Uani 1 1 d . . . . .
C18 C 0.207(2) 0.5282(14) 0.7416(5) 0.192(15) Uani 1 1 d . . . . .
H18A H 0.156290 0.555523 0.725198 0.287 Uiso 1 1 calc R U . . .
H18B H 0.291231 0.572080 0.747637 0.287 Uiso 1 1 calc R U . . .
H18C H 0.132468 0.523561 0.755824 0.287 Uiso 1 1 calc R U . . .
C19 C 0.3334(15) 0.3706(13) 0.7632(3) 0.092(6) Uani 1 1 d . . . . .
H19A H 0.248070 0.358830 0.774978 0.138 Uiso 1 1 calc R U . . .
H19B H 0.409091 0.414170 0.772391 0.138 Uiso 1 1 calc R U . . .
H19C H 0.381453 0.306743 0.758921 0.138 Uiso 1 1 calc R U . . .
C20 C 0.1403(14) 0.3603(14) 0.7253(3) 0.109(7) Uani 1 1 d . . . . .
H20A H 0.061225 0.357942 0.738703 0.163 Uiso 1 1 calc R U . . .
H20B H 0.177150 0.292563 0.721908 0.163 Uiso 1 1 calc R U . . .
H20C H 0.097013 0.388960 0.708460 0.163 Uiso 1 1 calc R U . . .
C21 C 0.5390(18) 0.3147(10) 0.7061(3) 0.075(5) Uani 1 1 d D . . . .
C22 C 0.637(3) 0.3217(16) 0.6808(4) 0.206(14) Uani 1 1 d . . . . .
H22A H 0.698046 0.383008 0.681678 0.310 Uiso 1 1 calc R U . . .
H22B H 0.568940 0.322858 0.664513 0.310 Uiso 1 1 calc R U . . .
H22C H 0.704947 0.263763 0.680188 0.310 Uiso 1 1 calc R U . . .
C23 C 0.425(3) 0.2274(11) 0.7025(4) 0.187(12) Uani 1 1 d . . . . .
H23A H 0.379391 0.212896 0.719783 0.280 Uiso 1 1 calc R U . . .
H23B H 0.478893 0.168091 0.696305 0.280 Uiso 1 1 calc R U . . .
H23C H 0.343876 0.245651 0.689106 0.280 Uiso 1 1 calc R U . . .
C24 C 0.643(2) 0.2856(12) 0.7303(4) 0.223(14) Uani 1 1 d D . . . .
H24A H 0.721(4) 0.236(3) 0.7265(11) 0.334 Uiso 1 1 d D U . . .
H24B H 0.590(5) 0.257(4) 0.7454(6) 0.334 Uiso 1 1 d D U . . .
H24C H 0.702(5) 0.341(3) 0.7385(10) 0.334 Uiso 1 1 d D U . . .
Pt2 Pt 0.500000 1.000000 0.500000 0.02905(18) Uani 1 2 d DS . P . .
P3 P 0.4026(3) 0.9713(2) 0.45541(6) 0.0266(6) Uani 1 1 d D . . . .
C25 C 0.2263(13) 1.0582(10) 0.4479(2) 0.047(3) Uani 1 1 d . . . . .
C26 C 0.1286(14) 1.0278(10) 0.4222(3) 0.061(4) Uani 1 1 d . . . . .
H26A H 0.089360 0.959884 0.424428 0.091 Uiso 1 1 calc R U . . .
H26B H 0.192435 1.030110 0.406458 0.091 Uiso 1 1 calc R U . . .
H26C H 0.042551 1.074184 0.419564 0.091 Uiso 1 1 calc R U . . .
C27 C 0.1267(15) 1.0590(14) 0.4734(3) 0.102(7) Uani 1 1 d . . . . .
H27A H 0.047939 1.110892 0.471365 0.153 Uiso 1 1 calc R U . . .
H27B H 0.192347 1.072910 0.489526 0.153 Uiso 1 1 calc R U . . .
H27C H 0.077557 0.993811 0.475338 0.153 Uiso 1 1 calc R U . . .
C28 C 0.2853(16) 1.1683(9) 0.4441(3) 0.075(5) Uani 1 1 d . . . . .
H28A H 0.353475 1.170538 0.428965 0.113 Uiso 1 1 calc R U . . .
H28B H 0.341286 1.190091 0.460634 0.113 Uiso 1 1 calc R U . . .
H28C H 0.197659 1.212632 0.440400 0.113 Uiso 1 1 calc R U . . .
C29 C 0.5624(13) 1.0020(9) 0.4307(3) 0.044(3) Uani 1 1 d . . . . .
C30 C 0.5091(15) 1.0176(13) 0.4013(3) 0.095(6) Uani 1 1 d . . . . .
H30A H 0.596030 1.038880 0.390850 0.143 Uiso 1 1 calc R U . . .
H30B H 0.429372 1.069130 0.400239 0.143 Uiso 1 1 calc R U . . .
H30C H 0.467577 0.954933 0.393857 0.143 Uiso 1 1 calc R U . . .
C31 C 0.6906(14) 0.9188(11) 0.4336(3) 0.077(5) Uani 1 1 d . . . . .
H31A H 0.649292 0.855057 0.426895 0.116 Uiso 1 1 calc R U . . .
H31B H 0.723630 0.911855 0.452672 0.116 Uiso 1 1 calc R U . . .
H31C H 0.778370 0.938038 0.423122 0.116 Uiso 1 1 calc R U . . .
C32 C 0.6494(16) 1.1018(10) 0.4410(3) 0.086(5) Uani 1 1 d . . . . .
H32A H 0.729187 1.118981 0.428530 0.129 Uiso 1 1 calc R U . . .
H32B H 0.696250 1.090313 0.459061 0.129 Uiso 1 1 calc R U . . .
H32C H 0.575633 1.156725 0.441721 0.129 Uiso 1 1 calc R U . . .
C33 C 0.3421(18) 0.8344(9) 0.4532(4) 0.087(6) Uani 1 1 d . . . . .
C34 C 0.4685(19) 0.7665(10) 0.4669(4) 0.131(8) Uani 1 1 d . . . . .
H34A H 0.469042 0.775555 0.486539 0.197 Uiso 1 1 calc R U . . .
H34B H 0.568847 0.784988 0.460366 0.197 Uiso 1 1 calc R U . . .
H34C H 0.446904 0.696501 0.462487 0.197 Uiso 1 1 calc R U . . .
C35 C 0.319(2) 0.7968(11) 0.4216(4) 0.140(9) Uani 1 1 d . . . . .
H35A H 0.310130 0.723876 0.421156 0.210 Uiso 1 1 calc R U . . .
H35B H 0.408119 0.817258 0.411543 0.210 Uiso 1 1 calc R U . . .
H35C H 0.226282 0.826785 0.413369 0.210 Uiso 1 1 calc R U . . .
C36 C 0.191(2) 0.8148(14) 0.4671(4) 0.142(9) Uani 1 1 d . . . . .
H36A H 0.166308 0.743458 0.466082 0.213 Uiso 1 1 calc R U . . .
H36B H 0.108097 0.853123 0.457953 0.213 Uiso 1 1 calc R U . . .
H36C H 0.201545 0.835336 0.486030 0.213 Uiso 1 1 calc R U . . .
S1 S 0.9352(3) 1.08187(19) 0.66567(6) 0.0327(7) Uani 1 1 d D . . . .
O1 O 0.8450(9) 1.1016(6) 0.64088(16) 0.048(2) Uani 1 1 d . . . . .
O2 O 0.9708(8) 1.1639(5) 0.68403(16) 0.049(2) Uani 1 1 d . . . . .
S2 S 0.7888(3) 0.8924(2) 0.67208(6) 0.0302(6) Uani 1 1 d D . . . .
O3 O 0.7893(8) 0.8741(5) 0.64321(15) 0.0386(19) Uani 1 1 d . . . . .
O4 O 0.8183(9) 0.8095(5) 0.69039(16) 0.054(2) Uani 1 1 d . . . . .
N1 N 0.8820(9) 0.9870(5) 0.68316(18) 0.029(2) Uani 1 1 d D . . . .
C37 C 1.1315(16) 1.0433(10) 0.6547(3) 0.056(4) Uani 1 1 d . . . . .
F1 F 1.1158(9) 0.9668(6) 0.63717(19) 0.082(3) Uani 1 1 d . . . . .
F2 F 1.1944(8) 1.1192(5) 0.64182(16) 0.077(2) Uani 1 1 d . . . . .
F3 F 1.2172(8) 1.0144(6) 0.6754(2) 0.081(3) Uani 1 1 d . . . . .
C38 C 0.5881(13) 0.9257(9) 0.6787(3) 0.045(3) Uani 1 1 d . . . . .
F4 F 0.5450(8) 1.0116(5) 0.66469(16) 0.050(2) Uani 1 1 d . . . . .
F5 F 0.5641(8) 0.9435(6) 0.70467(15) 0.070(2) Uani 1 1 d . . . . .
F6 F 0.4914(8) 0.8548(5) 0.66958(16) 0.071(2) Uani 1 1 d . . . . .
S3 S 0.0784(4) 0.4050(3) 0.49548(8) 0.0785(14) Uani 1 1 d D U . . .
O5 O 0.0140(10) 0.3646(7) 0.47245(18) 0.073(3) Uani 1 1 d D . . . .
O6A O 0.055(2) 0.4062(15) 0.5216(2) 0.066(6) Uani 0.5 1 d D U P . .
O6B O 0.1322(18) 0.3075(10) 0.5135(3) 0.058(5) Uiso 0.5 1 d D . P . .
N2 N 0.028(2) 0.4842(15) 0.5157(3) 0.052(6) Uani 0.5 1 d D U P . .
C39 C 0.2686(16) 0.4488(14) 0.4870(3) 0.061(4) Uani 1 1 d . . . . .
F7 F 0.3381(17) 0.4984(17) 0.5061(3) 0.274(13) Uani 1 1 d . . . . .
F8 F 0.2774(11) 0.5035(9) 0.4678(3) 0.158(7) Uani 1 1 d . . . . .
F9 F 0.3581(10) 0.3800(8) 0.4838(4) 0.199(8) Uani 1 1 d . . . . .
H1 H 0.173(19) 0.550(16) 0.6834(9) 0.34(13) Uiso 1 1 d D . . . .
H2 H 0.58(4) 1.112(14) 0.491(3) 0.6(2) Uiso 1 1 d D . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.318(3) . ?
Pt1 P2 2.319(3) . ?
Pt1 H1 1.75(9) . ?
P1 C5 1.882(10) . ?
P1 C1 1.897(10) . ?
P1 C9 1.898(11) . ?
P2 C21 1.866(12) . ?
P2 C17 1.889(10) . ?
P2 C13 1.892(12) . ?
C1 C2 1.495(15) . ?
C1 C4 1.546(14) . ?
C1 C3 1.573(16) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 C8 1.532(16) . ?
C5 C6 1.534(15) . ?
C5 C7 1.544(15) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C12 1.517(13) . ?
C9 C11 1.525(15) . ?
C9 C10 1.540(16) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 C16 1.49(2) . ?
C13 C14 1.504(18) . ?
C13 C15 1.53(2) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C20 1.455(16) . ?
C17 C18 1.51(2) . ?
C17 C19 1.578(17) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 C24 1.49(2) . ?
C21 C23 1.51(2) . ?
C21 C22 1.52(2) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9590(11) . ?
C24 H24B 0.9590(12) . ?
C24 H24C 0.9590(12) . ?
Pt2 P3 2.317(3) 3_676 ?
Pt2 P3 2.317(3) . ?
Pt2 H2 1.69(10) . ?
P3 C33 1.871(12) . ?
P3 C29 1.903(11) . ?
P3 C25 1.913(11) . ?
C25 C26 1.524(17) . ?
C25 C27 1.536(15) . ?
C25 C28 1.543(17) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 C30 1.493(16) . ?
C29 C31 1.550(16) . ?
C29 C32 1.578(17) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 C36 1.51(2) . ?
C33 C34 1.532(18) . ?
C33 C35 1.61(2) . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
S1 O2 1.422(7) . ?
S1 O1 1.425(8) . ?
S1 N1 1.586(7) . ?
S1 C37 1.856(13) . ?
S2 O4 1.420(8) . ?
S2 O3 1.423(7) . ?
S2 N1 1.558(7) . ?
S2 C38 1.815(12) . ?
C37 F3 1.275(16) . ?
C37 F2 1.304(14) . ?
C37 F1 1.317(15) . ?
C38 F6 1.309(12) . ?
C38 F5 1.309(13) . ?
C38 F4 1.359(13) . ?
S3 O6A 1.294(11) . ?
S3 O5 1.335(8) . ?
S3 N2 1.508(15) . ?
S3 O6B 1.607(12) . ?
S3 N2 1.787(17) 3_566 ?
S3 C39 1.791(14) . ?
N2 N2 1.63(3) 3_566 ?
C39 F8 1.182(17) . ?
C39 F9 1.199(17) . ?
C39 F7 1.261(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 179.32(9) . . ?
P1 Pt1 H1 90.3(4) . . ?
P2 Pt1 H1 90.1(4) . . ?
C5 P1 C1 109.9(5) . . ?
C5 P1 C9 111.7(5) . . ?
C1 P1 C9 108.6(5) . . ?
C5 P1 Pt1 108.9(4) . . ?
C1 P1 Pt1 105.8(4) . . ?
C9 P1 Pt1 111.7(4) . . ?
C21 P2 C17 111.9(7) . . ?
C21 P2 C13 108.8(7) . . ?
C17 P2 C13 111.4(6) . . ?
C21 P2 Pt1 107.6(5) . . ?
C17 P2 Pt1 109.4(4) . . ?
C13 P2 Pt1 107.5(4) . . ?
C2 C1 C4 110.2(9) . . ?
C2 C1 C3 109.2(10) . . ?
C4 C1 C3 103.1(9) . . ?
C2 C1 P1 115.7(8) . . ?
C4 C1 P1 110.5(7) . . ?
C3 C1 P1 107.4(7) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C8 C5 C6 104.6(10) . . ?
C8 C5 C7 111.1(10) . . ?
C6 C5 C7 108.3(10) . . ?
C8 C5 P1 108.1(8) . . ?
C6 C5 P1 109.8(8) . . ?
C7 C5 P1 114.5(7) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C7 H7A 109.5 . . ?
C5 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C5 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C5 C8 H8A 109.5 . . ?
C5 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C5 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C12 C9 C11 106.6(9) . . ?
C12 C9 C10 110.9(10) . . ?
C11 C9 C10 106.1(9) . . ?
C12 C9 P1 110.0(7) . . ?
C11 C9 P1 109.3(8) . . ?
C10 C9 P1 113.6(7) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C16 C13 C14 107.8(13) . . ?
C16 C13 C15 112.4(15) . . ?
C14 C13 C15 104.3(13) . . ?
C16 C13 P2 113.3(9) . . ?
C14 C13 P2 109.4(10) . . ?
C15 C13 P2 109.2(10) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C20 C17 C18 108.0(14) . . ?
C20 C17 C19 105.9(11) . . ?
C18 C17 C19 110.4(13) . . ?
C20 C17 P2 112.7(9) . . ?
C18 C17 P2 108.5(9) . . ?
C19 C17 P2 111.3(8) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C24 C21 C23 104.9(14) . . ?
C24 C21 C22 108.8(15) . . ?
C23 C21 C22 109.1(16) . . ?
C24 C21 P2 114.9(10) . . ?
C23 C21 P2 109.6(12) . . ?
C22 C21 P2 109.4(11) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 115(3) . . ?
C21 C24 H24B 115(3) . . ?
H24A C24 H24B 104(4) . . ?
C21 C24 H24C 115(3) . . ?
H24A C24 H24C 104(4) . . ?
H24B C24 H24C 104(4) . . ?
P3 Pt2 P3 180.0 3_676 . ?
P3 Pt2 H2 88(3) 3_676 . ?
P3 Pt2 H2 92(3) . . ?
C33 P3 C29 111.8(7) . . ?
C33 P3 C25 110.3(6) . . ?
C29 P3 C25 109.6(5) . . ?
C33 P3 Pt2 107.3(5) . . ?
C29 P3 Pt2 108.5(4) . . ?
C25 P3 Pt2 109.2(4) . . ?
C26 C25 C27 111.0(11) . . ?
C26 C25 C28 108.5(10) . . ?
C27 C25 C28 106.6(12) . . ?
C26 C25 P3 113.5(9) . . ?
C27 C25 P3 108.2(8) . . ?
C28 C25 P3 108.7(8) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C25 C28 H28A 109.5 . . ?
C25 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C25 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 C31 111.7(11) . . ?
C30 C29 C32 108.1(12) . . ?
C31 C29 C32 103.4(11) . . ?
C30 C29 P3 115.8(8) . . ?
C31 C29 P3 108.6(9) . . ?
C32 C29 P3 108.4(8) . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C29 C31 H31A 109.5 . . ?
C29 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C29 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C36 C33 C34 108.0(14) . . ?
C36 C33 C35 107.6(12) . . ?
C34 C33 C35 106.8(15) . . ?
C36 C33 P3 112.3(13) . . ?
C34 C33 P3 110.1(9) . . ?
C35 C33 P3 111.8(11) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33 C36 H36A 109.5 . . ?
C33 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C33 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
O2 S1 O1 119.0(5) . . ?
O2 S1 N1 108.5(5) . . ?
O1 S1 N1 116.0(5) . . ?
O2 S1 C37 102.5(6) . . ?
O1 S1 C37 105.7(6) . . ?
N1 S1 C37 103.0(5) . . ?
O4 S2 O3 118.6(5) . . ?
O4 S2 N1 108.6(5) . . ?
O3 S2 N1 116.8(5) . . ?
O4 S2 C38 102.5(5) . . ?
O3 S2 C38 105.0(5) . . ?
N1 S2 C38 102.8(5) . . ?
S2 N1 S1 126.5(6) . . ?
F3 C37 F2 111.7(13) . . ?
F3 C37 F1 108.7(12) . . ?
F2 C37 F1 107.8(11) . . ?
F3 C37 S1 110.5(9) . . ?
F2 C37 S1 109.1(9) . . ?
F1 C37 S1 109.0(10) . . ?
F6 C38 F5 109.2(10) . . ?
F6 C38 F4 105.5(11) . . ?
F5 C38 F4 106.4(10) . . ?
F6 C38 S2 111.0(8) . . ?
F5 C38 S2 113.8(9) . . ?
F4 C38 S2 110.4(8) . . ?
O6A S3 O5 138.6(10) . . ?
O6A S3 N2 44.8(9) . . ?
O5 S3 N2 134.5(8) . . ?
O6A S3 O6B 61.8(9) . . ?
O5 S3 O6B 103.8(7) . . ?
N2 S3 O6B 106.1(8) . . ?
O6A S3 N2 101.0(11) . 3_566 ?
O5 S3 N2 83.2(7) . 3_566 ?
N2 S3 N2 58.8(10) . 3_566 ?
O6B S3 N2 160.7(9) . 3_566 ?
O6A S3 C39 113.8(10) . . ?
O5 S3 C39 106.3(6) . . ?
N2 S3 C39 102.6(10) . . ?
O6B S3 C39 98.0(9) . . ?
N2 S3 C39 97.1(10) 3_566 . ?
S3 N2 N2 69.2(10) . 3_566 ?
S3 N2 S3 121.2(10) . 3_566 ?
N2 N2 S3 52.1(9) 3_566 3_566 ?
F8 C39 F9 107.0(14) . . ?
F8 C39 F7 102.9(18) . . ?
F9 C39 F7 101.6(17) . . ?
F8 C39 S3 117.8(12) . . ?
F9 C39 S3 112.3(14) . . ?
F7 C39 S3 113.6(10) . . ?

_refine_diff_density_max         1.109
_refine_diff_density_min         -1.555
_refine_diff_density_rms         0.150

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_8
_database_code_depnum_ccdc_archive 'CCDC 1909267'
loop_
_audit_author_name
_audit_author_address
'Celia Maya'
;University of Seville
Spain
;
_audit_update_record             
;
2019-04-10 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;
_vrf_PLAT213_8                   
;
PROBLEM: Atom X has ADP max/min Ratio .
RESPONSE: This value is due to unsolved disorder 
in t-Butyl groups.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C26 H57 F6 N O5 P2 Pt S2'
_chemical_formula_weight         898.87

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0015 0.0009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0096 0.0061 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0667 0.0580 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.0826 0.0763 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -0.6812 5.7081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0030 0.0019 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0056 0.0036 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   17.3950(7)
_cell_length_b                   11.6828(4)
_cell_length_c                   18.9417(8)
_cell_angle_alpha                90
_cell_angle_beta                 107.260(2)
_cell_angle_gamma                90
_cell_volume                     3676.0(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9906
_cell_measurement_theta_min      2.20
_cell_measurement_theta_max      21.95

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_F_000             1816
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    2.214
_shelx_estimated_absorpt_T_min   0.718
_shelx_estimated_absorpt_T_max   0.879
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5948
_exptl_absorpt_correction_T_max  0.7447
_exptl_absorpt_process_details   
; 
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical 
 X-ray Solutions, Madison, Wisconsin, USA. 
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.56086
_diffrn_radiation_type           AgK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            31111
_diffrn_reflns_av_unetI/netI     0.0505
_diffrn_reflns_av_R_equivalents  0.0481
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.637
_diffrn_reflns_theta_max         22.013
_diffrn_reflns_theta_full        19.665
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             9156
_reflns_number_gt                7474
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+0.9779P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9156
_refine_ls_number_parameters     419
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0494
_refine_ls_R_factor_gt           0.0343
_refine_ls_wR_factor_ref         0.1127
_refine_ls_wR_factor_gt          0.0997
_refine_ls_goodness_of_fit_ref   0.810
_refine_ls_restrained_S_all      0.810
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.97821(2) 0.86352(2) 0.20886(2) 0.00996(7) Uani 1.000(2) 1 d . . . . .
S2 S 0.80376(7) 0.88718(10) 0.53688(7) 0.0163(2) Uani 1 1 d . . . . .
S1 S 0.94203(7) 0.83235(10) 0.49781(7) 0.0158(2) Uani 1 1 d . . . . .
P2 P 0.87723(7) 1.00051(9) 0.16758(7) 0.0140(3) Uani 1 1 d . . . . .
P1 P 1.07037(6) 0.71479(9) 0.21860(6) 0.0108(2) Uani 1 1 d . . . . .
C14 C 0.8013(4) 0.8850(6) 0.2592(5) 0.050(2) Uani 1 1 d . . . . .
H14A H 0.774742 0.888745 0.296908 0.075 Uiso 1 1 calc R U . . .
H14B H 0.853654 0.851633 0.279213 0.075 Uiso 1 1 calc R U . . .
H14C H 0.770021 0.838876 0.218898 0.075 Uiso 1 1 calc R U . . .
C13 C 0.8098(3) 1.0060(5) 0.2312(3) 0.0307(12) Uani 1 1 d . . . . .
C16 C 0.7263(3) 1.0606(6) 0.1987(4) 0.0407(15) Uani 1 1 d . . . . .
H16A H 0.695385 1.015785 0.157636 0.061 Uiso 1 1 calc R U . . .
H16B H 0.732411 1.136918 0.182334 0.061 Uiso 1 1 calc R U . . .
H16C H 0.699091 1.063301 0.235978 0.061 Uiso 1 1 calc R U . . .
N1 N 0.8480(2) 0.8273(3) 0.4852(2) 0.0166(8) Uani 1 1 d . . . . .
C26 C 0.7774(3) 1.0286(4) 0.4931(3) 0.0229(10) Uani 1 1 d . . . . .
F4 F 0.84257(17) 1.0883(3) 0.49538(18) 0.0279(7) Uani 1 1 d . . . . .
F6 F 0.73356(19) 1.0863(3) 0.52837(18) 0.0313(7) Uani 1 1 d . . . . .
F5 F 0.73324(18) 1.0172(3) 0.42260(17) 0.0304(7) Uani 1 1 d . . . . .
O4 O 0.7275(2) 0.8332(3) 0.5263(2) 0.0295(9) Uani 1 1 d . . . . .
O3 O 0.9867(2) 0.9107(3) 0.5528(2) 0.0240(8) Uani 1 1 d . . . . .
C25 C 0.9753(3) 0.6907(4) 0.5361(3) 0.0286(12) Uani 1 1 d . . . . .
F2 F 1.0547(2) 0.6817(3) 0.5492(2) 0.0486(10) Uani 1 1 d . . . . .
F3 F 0.9598(3) 0.6764(3) 0.5998(2) 0.0506(10) Uani 1 1 d . . . . .
C9 C 1.0405(3) 0.6201(4) 0.1319(3) 0.0166(9) Uani 1 1 d . . . . .
C11 C 1.1054(3) 0.5338(4) 0.1258(3) 0.0238(11) Uani 1 1 d . . . . .
H11A H 1.125318 0.492801 0.171509 0.036 Uiso 1 1 calc R U . . .
H11B H 1.148966 0.574159 0.115490 0.036 Uiso 1 1 calc R U . . .
H11C H 1.082358 0.480742 0.086489 0.036 Uiso 1 1 calc R U . . .
C10 C 0.9651(3) 0.5531(6) 0.1308(4) 0.0481(19) Uani 1 1 d . . . . .
H10A H 0.947506 0.509375 0.085966 0.072 Uiso 1 1 calc R U . . .
H10B H 0.923380 0.605321 0.133246 0.072 Uiso 1 1 calc R U . . .
H10C H 0.976903 0.502295 0.172500 0.072 Uiso 1 1 calc R U . . .
C12 C 1.0194(5) 0.6909(6) 0.0605(3) 0.060(3) Uani 1 1 d . . . . .
H12A H 1.034486 0.769304 0.072251 0.090 Uiso 1 1 calc R U . . .
H12B H 0.962530 0.686543 0.036458 0.090 Uiso 1 1 calc R U . . .
H12C H 1.047976 0.661325 0.028237 0.090 Uiso 1 1 calc R U . . .
C8 C 1.1863(3) 0.8820(5) 0.2806(4) 0.0426(18) Uani 1 1 d . . . . .
H8A H 1.191522 0.855539 0.329826 0.064 Uiso 1 1 calc R U . . .
H8B H 1.140931 0.932484 0.264767 0.064 Uiso 1 1 calc R U . . .
H8C H 1.234342 0.922242 0.280282 0.064 Uiso 1 1 calc R U . . .
C5 C 1.1739(3) 0.7787(4) 0.2277(3) 0.0260(12) Uani 1 1 d . . . . .
C7 C 1.1728(5) 0.8309(6) 0.1515(4) 0.0482(19) Uani 1 1 d . . . . .
H7A H 1.222237 0.871303 0.156622 0.072 Uiso 1 1 calc R U . . .
H7B H 1.128334 0.882918 0.135102 0.072 Uiso 1 1 calc R U . . .
H7C H 1.167205 0.770597 0.115888 0.072 Uiso 1 1 calc R U . . .
C1 C 1.0750(3) 0.6198(4) 0.3015(3) 0.0209(10) Uani 1 1 d . . . . .
C3 C 0.9898(4) 0.6075(5) 0.3085(4) 0.0328(13) Uani 1 1 d . . . . .
H3A H 0.957782 0.561752 0.268390 0.049 Uiso 1 1 calc R U . . .
H3B H 0.965899 0.681883 0.306784 0.049 Uiso 1 1 calc R U . . .
H3C H 0.992496 0.571195 0.354589 0.049 Uiso 1 1 calc R U . . .
C2 C 1.1166(4) 0.5052(4) 0.3033(3) 0.0371(15) Uani 1 1 d . . . . .
H2A H 1.121531 0.467984 0.349632 0.056 Uiso 1 1 calc R U . . .
H2B H 1.169200 0.517032 0.297915 0.056 Uiso 1 1 calc R U . . .
H2C H 1.085449 0.458078 0.263570 0.056 Uiso 1 1 calc R U . . .
C21 C 0.8123(4) 0.9634(5) 0.0701(3) 0.0375(16) Uani 1 1 d . . . . .
C24 C 0.7542(4) 1.0580(5) 0.0315(3) 0.0371(15) Uani 1 1 d . . . . .
H24A H 0.784297 1.122480 0.022676 0.056 Uiso 1 1 calc R U . . .
H24B H 0.722009 1.081030 0.062379 0.056 Uiso 1 1 calc R U . . .
H24C H 0.719804 1.029943 -0.014727 0.056 Uiso 1 1 calc R U . . .
C22 C 0.7621(5) 0.8555(5) 0.0771(5) 0.064(3) Uani 1 1 d . . . . .
H22A H 0.735073 0.826374 0.028655 0.096 Uiso 1 1 calc R U . . .
H22B H 0.722998 0.876026 0.101521 0.096 Uiso 1 1 calc R U . . .
H22C H 0.797336 0.797814 0.105268 0.096 Uiso 1 1 calc R U . . .
C23 C 0.8612(6) 0.9316(8) 0.0186(4) 0.080(3) Uani 1 1 d . . . . .
H23A H 0.825800 0.921674 -0.030619 0.120 Uiso 1 1 calc R U . . .
H23B H 0.889702 0.861558 0.035107 0.120 Uiso 1 1 calc R U . . .
H23C H 0.899011 0.991555 0.018820 0.120 Uiso 1 1 calc R U . . .
C17 C 0.9227(3) 1.1487(4) 0.1644(3) 0.0275(13) Uani 1 1 d . . . . .
C4 C 1.1249(4) 0.6844(5) 0.3735(3) 0.0399(16) Uani 1 1 d . . . . .
H4A H 1.120493 0.643982 0.416243 0.060 Uiso 1 1 calc R U . . .
H4B H 1.104273 0.760601 0.373434 0.060 Uiso 1 1 calc R U . . .
H4C H 1.180448 0.687962 0.374707 0.060 Uiso 1 1 calc R U . . .
C6 C 1.2449(3) 0.6974(5) 0.2514(5) 0.053(2) Uani 1 1 d . . . . .
H6A H 1.293334 0.737574 0.252427 0.079 Uiso 1 1 calc R U . . .
H6B H 1.236885 0.635134 0.216873 0.079 Uiso 1 1 calc R U . . .
H6C H 1.249283 0.668057 0.299744 0.079 Uiso 1 1 calc R U . . .
C18 C 0.9961(4) 1.1624(5) 0.2337(4) 0.0366(15) Uani 1 1 d . . . . .
H18A H 1.021865 1.234469 0.231536 0.055 Uiso 1 1 calc R U . . .
H18B H 1.033549 1.101321 0.235466 0.055 Uiso 1 1 calc R U . . .
H18C H 0.978599 1.160024 0.277207 0.055 Uiso 1 1 calc R U . . .
C19 C 0.8641(3) 1.2479(4) 0.1572(3) 0.0352(15) Uani 1 1 d . . . . .
H19A H 0.846258 1.251410 0.200513 0.053 Uiso 1 1 calc R U . . .
H19B H 0.818583 1.236644 0.114373 0.053 Uiso 1 1 calc R U . . .
H19C H 0.890529 1.318282 0.152233 0.053 Uiso 1 1 calc R U . . .
C15 C 0.8533(4) 1.0739(6) 0.3024(3) 0.0445(17) Uani 1 1 d . . . . .
H15A H 0.824781 1.063984 0.338319 0.067 Uiso 1 1 calc R U . . .
H15B H 0.854533 1.153664 0.290664 0.067 Uiso 1 1 calc R U . . .
H15C H 0.907301 1.045956 0.322219 0.067 Uiso 1 1 calc R U . . .
C20 C 0.9574(5) 1.1535(7) 0.0984(4) 0.054(2) Uani 1 1 d . . . . .
H20A H 0.914063 1.155903 0.053105 0.081 Uiso 1 1 calc R U . . .
H20B H 0.989686 1.086683 0.098785 0.081 Uiso 1 1 calc R U . . .
H20C H 0.990051 1.220758 0.102248 0.081 Uiso 1 1 calc R U . . .
O5 O 0.8511(2) 0.9134(3) 0.61142(18) 0.0211(7) Uani 1 1 d . . . . .
O2 O 0.9563(2) 0.8283(3) 0.4272(2) 0.0249(8) Uani 1 1 d . . . . .
F1 F 0.9411(2) 0.6069(3) 0.4911(2) 0.0386(9) Uani 1 1 d . . . . .
O1 O 1.0248(2) 0.9218(3) 0.3260(2) 0.0175(7) Uani 1 1 d . . . . .
H1 H 1.008(3) 0.906(4) 0.359(3) 0.005(12) Uiso 1 1 d . . . . .
H2 H 1.059(4) 0.949(7) 0.350(4) 0.05(2) Uiso 1 1 d . . . . .
H3P H 0.944(4) 0.817(6) 0.139(4) 0.06(2) Uiso 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 O1 2.231(4) . ?
Pt1 P2 2.3330(11) . ?
Pt1 P1 2.3340(11) . ?
S2 O4 1.427(4) . ?
S2 O5 1.441(3) . ?
S2 N1 1.578(4) . ?
S2 C26 1.844(5) . ?
S1 O3 1.430(3) . ?
S1 O2 1.431(4) . ?
S1 N1 1.582(4) . ?
S1 C25 1.830(5) . ?
P2 C21 1.907(5) . ?
P2 C17 1.911(5) . ?
P2 C13 1.916(6) . ?
P1 C1 1.904(5) . ?
P1 C5 1.909(5) . ?
P1 C9 1.919(5) . ?
C14 C13 1.532(8) . ?
C13 C16 1.538(7) . ?
C13 C15 1.554(9) . ?
C26 F4 1.322(6) . ?
C26 F6 1.335(6) . ?
C26 F5 1.335(6) . ?
C25 F1 1.318(7) . ?
C25 F3 1.323(7) . ?
C25 F2 1.333(6) . ?
C9 C10 1.522(8) . ?
C9 C12 1.535(8) . ?
C9 C11 1.543(6) . ?
C8 C5 1.542(7) . ?
C5 C6 1.516(8) . ?
C5 C7 1.563(9) . ?
C1 C2 1.517(7) . ?
C1 C3 1.533(8) . ?
C1 C4 1.576(8) . ?
C21 C23 1.518(11) . ?
C21 C24 1.529(7) . ?
C21 C22 1.560(10) . ?
C17 C19 1.523(7) . ?
C17 C20 1.542(10) . ?
C17 C18 1.544(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Pt1 P2 98.01(9) . . ?
O1 Pt1 P1 96.32(9) . . ?
P2 Pt1 P1 165.54(4) . . ?
O4 S2 O5 117.9(2) . . ?
O4 S2 N1 108.8(2) . . ?
O5 S2 N1 117.4(2) . . ?
O4 S2 C26 103.6(2) . . ?
O5 S2 C26 104.1(2) . . ?
N1 S2 C26 102.8(2) . . ?
O3 S1 O2 119.6(2) . . ?
O3 S1 N1 116.6(2) . . ?
O2 S1 N1 108.4(2) . . ?
O3 S1 C25 104.5(2) . . ?
O2 S1 C25 102.6(3) . . ?
N1 S1 C25 102.5(2) . . ?
C21 P2 C17 107.9(3) . . ?
C21 P2 C13 108.6(3) . . ?
C17 P2 C13 109.0(3) . . ?
C21 P2 Pt1 109.84(17) . . ?
C17 P2 Pt1 110.75(17) . . ?
C13 P2 Pt1 110.64(16) . . ?
C1 P1 C5 110.2(3) . . ?
C1 P1 C9 107.7(2) . . ?
C5 P1 C9 108.1(2) . . ?
C1 P1 Pt1 111.06(16) . . ?
C5 P1 Pt1 108.87(16) . . ?
C9 P1 Pt1 110.89(14) . . ?
C14 C13 C16 110.1(5) . . ?
C14 C13 C15 104.1(6) . . ?
C16 C13 C15 107.0(5) . . ?
C14 C13 P2 109.1(4) . . ?
C16 C13 P2 116.4(4) . . ?
C15 C13 P2 109.4(4) . . ?
S2 N1 S1 124.2(2) . . ?
F4 C26 F6 109.2(4) . . ?
F4 C26 F5 108.5(4) . . ?
F6 C26 F5 107.8(4) . . ?
F4 C26 S2 111.2(3) . . ?
F6 C26 S2 109.3(4) . . ?
F5 C26 S2 110.7(4) . . ?
F1 C25 F3 108.7(5) . . ?
F1 C25 F2 107.8(5) . . ?
F3 C25 F2 107.4(5) . . ?
F1 C25 S1 112.8(4) . . ?
F3 C25 S1 110.5(4) . . ?
F2 C25 S1 109.5(4) . . ?
C10 C9 C12 106.6(6) . . ?
C10 C9 C11 108.0(4) . . ?
C12 C9 C11 106.0(5) . . ?
C10 C9 P1 108.8(4) . . ?
C12 C9 P1 112.1(3) . . ?
C11 C9 P1 115.0(3) . . ?
C6 C5 C8 110.7(5) . . ?
C6 C5 C7 107.6(6) . . ?
C8 C5 C7 104.8(5) . . ?
C6 C5 P1 116.4(4) . . ?
C8 C5 P1 108.2(4) . . ?
C7 C5 P1 108.5(4) . . ?
C2 C1 C3 112.5(5) . . ?
C2 C1 C4 105.4(4) . . ?
C3 C1 C4 105.6(5) . . ?
C2 C1 P1 115.9(4) . . ?
C3 C1 P1 108.7(3) . . ?
C4 C1 P1 108.2(4) . . ?
C23 C21 C24 106.6(6) . . ?
C23 C21 C22 106.9(6) . . ?
C24 C21 C22 108.5(5) . . ?
C23 C21 P2 113.2(5) . . ?
C24 C21 P2 114.6(4) . . ?
C22 C21 P2 106.7(5) . . ?
C19 C17 C20 108.2(5) . . ?
C19 C17 C18 111.1(5) . . ?
C20 C17 C18 105.2(5) . . ?
C19 C17 P2 114.8(4) . . ?
C20 C17 P2 108.9(4) . . ?
C18 C17 P2 108.2(3) . . ?

_refine_diff_density_max         2.019
_refine_diff_density_min         -1.274
_refine_diff_density_rms         0.149

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1909268'
loop_
_audit_author_name
_audit_author_address
'Celia Maya'
;University of Seville
Spain
;
_audit_update_record             
;
2019-04-10 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;

_vrf_PLAT213_3                   
;
PROBLEM: Atom X has ADP max/min Ratio .
RESPONSE: This value is due to unsolved disorder 
in CF3 and SO3 groups of triflate anion.
;
_vrf_PLAT220_3                   
;
PROBLEM: Non-Solvent  Resd 1  F   Ueq(max)/Ueq(min) 
RESPONSE: This value is due to unsolved disorder 
in CF3 and SO3 groups of triflate anion.
;
_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C50 H108 Ag2 F6 O6 P4 Pt2 S2'
_chemical_formula_weight         1713.28

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0015 0.0009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0056 0.0036 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0096 0.0061 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0667 0.0580 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.0826 0.0763 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -1.6473 0.7167 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -0.6812 5.7081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.4375(6)
_cell_length_b                   16.5694(9)
_cell_length_c                   17.6644(9)
_cell_angle_alpha                90
_cell_angle_beta                 102.020(2)
_cell_angle_gamma                90
_cell_volume                     3274.2(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9877
_cell_measurement_theta_min      2.48
_cell_measurement_theta_max      22.10

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.738
_exptl_crystal_F_000             1704
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_exptl_absorpt_coefficient_mu    2.742
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6093
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_process_details   
; 
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical 
 X-ray Solutions, Madison, Wisconsin, USA. 
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.56086
_diffrn_radiation_type           AgK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            83347
_diffrn_reflns_av_unetI/netI     0.0601
_diffrn_reflns_av_R_equivalents  0.0690
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.733
_diffrn_reflns_theta_max         26.341
_diffrn_reflns_theta_full        19.665
_diffrn_measured_fraction_theta_max 0.964
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.964
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.964
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             13080
_reflns_number_gt                9470
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+0.3311P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         13080
_refine_ls_number_parameters     374
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0777
_refine_ls_R_factor_gt           0.0478
_refine_ls_wR_factor_ref         0.1487
_refine_ls_wR_factor_gt          0.1263
_refine_ls_goodness_of_fit_ref   0.948
_refine_ls_restrained_S_all      0.952
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.19120(2) 0.42620(2) 0.24248(2) 0.01769(6) Uani 1 1 d . . . . .
Ag1 Ag 0.32444(8) 0.47425(11) 0.37287(3) 0.0341(3) Uani 0.911(6) 1 d . . P A 1
Ag1B Ag 0.3416(8) 0.4440(8) 0.3760(4) 0.0360(18) Uiso 0.089(6) 1 d . . P A 2
S1 S 0.43281(13) 0.61721(9) 0.49442(8) 0.0370(3) Uani 1 1 d D . . . .
P1 P 0.04642(10) 0.38218(7) 0.30559(7) 0.0211(2) Uani 1 1 d . . . . .
P2 P 0.33169(10) 0.46035(7) 0.17153(6) 0.0180(2) Uani 1 1 d . . . . .
F1 F 0.260(2) 0.7148(12) 0.4563(7) 0.207(9) Uani 0.729(18) 1 d . . P B 1
F2 F 0.409(2) 0.7653(4) 0.5140(11) 0.170(8) Uani 0.729(18) 1 d . . P B 1
F3 F 0.3104(7) 0.7039(5) 0.5789(5) 0.056(2) Uani 0.729(18) 1 d . . P B 1
F1B F 0.2177(10) 0.6868(7) 0.4765(6) 0.022(3) Uiso 0.271(18) 1 d D . P B 2
F2B F 0.3628(13) 0.7775(9) 0.5014(9) 0.035(4) Uiso 0.271(18) 1 d D . P B 2
F3B F 0.3337(16) 0.6908(10) 0.5908(8) 0.028(4) Uiso 0.271(18) 1 d D . P B 2
O1 O 0.3549(7) 0.5529(4) 0.4807(5) 0.052(2) Uani 0.733(17) 1 d . . P A 1
O2 O 0.4809(11) 0.6423(5) 0.4277(6) 0.106(5) Uani 0.733(17) 1 d . . P A 1
O3 O 0.5181(10) 0.6095(10) 0.5666(6) 0.096(5) Uani 0.733(17) 1 d . . P A 1
O1B O 0.364(2) 0.5580(17) 0.5246(16) 0.096(11) Uiso 0.267(17) 1 d D . P A 2
O2B O 0.420(2) 0.6154(19) 0.4181(11) 0.087(9) Uiso 0.267(17) 1 d D . P A 2
O3B O 0.5349(15) 0.6341(10) 0.5418(9) 0.026(4) Uiso 0.267(17) 1 d D . P A 2
C1 C -0.0413(4) 0.4705(3) 0.3337(3) 0.0275(9) Uani 1 1 d . . . . .
C2 C 0.0442(6) 0.5358(3) 0.3746(4) 0.0399(13) Uani 1 1 d . . . . .
H2A H 0.096903 0.552174 0.341643 0.060 Uiso 1 1 calc R U . . .
H2B H 0.090385 0.514546 0.422086 0.060 Uiso 1 1 calc R U . . .
H2C H -0.001070 0.581461 0.385631 0.060 Uiso 1 1 calc R U . . .
C3 C -0.1333(6) 0.4512(4) 0.3853(4) 0.0450(15) Uani 1 1 d . . . . .
H3A H -0.183165 0.497406 0.387135 0.068 Uiso 1 1 calc R U . . .
H3B H -0.091244 0.438027 0.436745 0.068 Uiso 1 1 calc R U . . .
H3C H -0.181905 0.406177 0.363799 0.068 Uiso 1 1 calc R U . . .
C4 C -0.1115(6) 0.5123(4) 0.2611(4) 0.0441(14) Uani 1 1 d . . . . .
H4A H -0.145661 0.561456 0.275476 0.066 Uiso 1 1 calc R U . . .
H4B H -0.174089 0.477315 0.235271 0.066 Uiso 1 1 calc R U . . .
H4C H -0.058637 0.524485 0.226910 0.066 Uiso 1 1 calc R U . . .
C5 C 0.1029(5) 0.3167(3) 0.3957(3) 0.0343(12) Uani 1 1 d . . . . .
C6 C 0.2058(6) 0.2658(4) 0.3817(4) 0.0523(17) Uani 1 1 d . . . . .
H6A H 0.244581 0.240612 0.429301 0.078 Uiso 1 1 calc R U . . .
H6B H 0.262071 0.299401 0.363011 0.078 Uiso 1 1 calc R U . . .
H6C H 0.176334 0.224986 0.343984 0.078 Uiso 1 1 calc R U . . .
C7 C 0.1535(6) 0.3706(5) 0.4674(3) 0.0509(17) Uani 1 1 d . . . . .
H7A H 0.199370 0.337865 0.507816 0.076 Uiso 1 1 calc R U . . .
H7B H 0.088548 0.395252 0.485601 0.076 Uiso 1 1 calc R U . . .
H7C H 0.203779 0.411769 0.453069 0.076 Uiso 1 1 calc R U . . .
C8 C 0.0067(6) 0.2657(4) 0.4207(4) 0.0451(15) Uani 1 1 d . . . . .
H8A H -0.019537 0.224432 0.382819 0.068 Uiso 1 1 calc R U . . .
H8B H -0.059748 0.299441 0.425116 0.068 Uiso 1 1 calc R U . . .
H8C H 0.038895 0.241171 0.469820 0.068 Uiso 1 1 calc R U . . .
C9 C -0.0589(5) 0.3166(3) 0.2326(3) 0.0349(11) Uani 1 1 d . . . . .
C10 C -0.0814(6) 0.3584(4) 0.1543(3) 0.0495(17) Uani 1 1 d . . . . .
H10A H -0.007429 0.363149 0.137077 0.074 Uiso 1 1 calc R U . . .
H10B H -0.113809 0.411164 0.158914 0.074 Uiso 1 1 calc R U . . .
H10C H -0.137024 0.327212 0.117588 0.074 Uiso 1 1 calc R U . . .
C11 C 0.0021(7) 0.2369(4) 0.2248(5) 0.0568(18) Uani 1 1 d . . . . .
H11A H -0.052707 0.201494 0.192026 0.085 Uiso 1 1 calc R U . . .
H11B H 0.027228 0.212811 0.274922 0.085 Uiso 1 1 calc R U . . .
H11C H 0.070576 0.245969 0.202312 0.085 Uiso 1 1 calc R U . . .
C12 C -0.1846(5) 0.2999(5) 0.2519(4) 0.0476(16) Uani 1 1 d . . . . .
H12A H -0.227475 0.261918 0.215373 0.071 Uiso 1 1 calc R U . . .
H12B H -0.228848 0.349471 0.248816 0.071 Uiso 1 1 calc R U . . .
H12C H -0.174310 0.278200 0.303222 0.071 Uiso 1 1 calc R U . . .
C13 C 0.4363(5) 0.5476(3) 0.2098(3) 0.0324(11) Uani 1 1 d . . . . .
C14 C 0.5028(7) 0.5855(4) 0.1508(5) 0.0524(18) Uani 1 1 d . . . . .
H14A H 0.551564 0.629370 0.174791 0.079 Uiso 1 1 calc R U . . .
H14B H 0.445623 0.605141 0.107043 0.079 Uiso 1 1 calc R U . . .
H14C H 0.552410 0.545371 0.134069 0.079 Uiso 1 1 calc R U . . .
C15 C 0.5321(5) 0.5210(4) 0.2792(4) 0.0446(15) Uani 1 1 d . . . . .
H15A H 0.582124 0.480772 0.263003 0.067 Uiso 1 1 calc R U . . .
H15B H 0.494377 0.498753 0.318280 0.067 Uiso 1 1 calc R U . . .
H15C H 0.579813 0.566645 0.299917 0.067 Uiso 1 1 calc R U . . .
C16 C 0.3608(6) 0.6140(3) 0.2379(4) 0.0507(18) Uani 1 1 d . . . . .
H16A H 0.307297 0.589806 0.266582 0.076 Uiso 1 1 calc R U . . .
H16B H 0.315515 0.642341 0.194065 0.076 Uiso 1 1 calc R U . . .
H16C H 0.412732 0.651167 0.270554 0.076 Uiso 1 1 calc R U . . .
C17 C 0.4241(5) 0.3669(3) 0.1639(3) 0.0296(10) Uani 1 1 d . . . . .
C18 C 0.3435(7) 0.3023(4) 0.1160(4) 0.0524(17) Uani 1 1 d . . . . .
H18A H 0.324489 0.318364 0.062580 0.079 Uiso 1 1 calc R U . . .
H18B H 0.271123 0.296853 0.134926 0.079 Uiso 1 1 calc R U . . .
H18C H 0.384868 0.251546 0.120580 0.079 Uiso 1 1 calc R U . . .
C19 C 0.5345(5) 0.3793(4) 0.1292(3) 0.0407(14) Uani 1 1 d . . . . .
H19A H 0.590684 0.413264 0.162777 0.061 Uiso 1 1 calc R U . . .
H19B H 0.511443 0.404455 0.079363 0.061 Uiso 1 1 calc R U . . .
H19C H 0.570893 0.328024 0.123694 0.061 Uiso 1 1 calc R U . . .
C20 C 0.4645(6) 0.3314(4) 0.2457(3) 0.0437(15) Uani 1 1 d . . . . .
H20A H 0.514237 0.285106 0.243624 0.066 Uiso 1 1 calc R U . . .
H20B H 0.395587 0.315545 0.265239 0.066 Uiso 1 1 calc R U . . .
H20C H 0.508802 0.371290 0.279347 0.066 Uiso 1 1 calc R U . . .
C21 C 0.2481(5) 0.4901(4) 0.0697(3) 0.0367(13) Uani 1 1 d . . . . .
C22 C 0.1990(6) 0.5764(4) 0.0718(5) 0.063(2) Uani 1 1 d . . . . .
H22A H 0.264165 0.614067 0.080436 0.094 Uiso 1 1 calc R U . . .
H22B H 0.156201 0.580651 0.112982 0.094 Uiso 1 1 calc R U . . .
H22C H 0.146064 0.588160 0.023381 0.094 Uiso 1 1 calc R U . . .
C23 C 0.1373(6) 0.4366(5) 0.0473(4) 0.056(2) Uani 1 1 d . . . . .
H23A H 0.098540 0.447392 -0.005368 0.084 Uiso 1 1 calc R U . . .
H23B H 0.083148 0.447833 0.080766 0.084 Uiso 1 1 calc R U . . .
H23C H 0.160712 0.380844 0.052303 0.084 Uiso 1 1 calc R U . . .
C24 C 0.3206(6) 0.4830(5) 0.0055(3) 0.0531(18) Uani 1 1 d . . . . .
H24A H 0.345039 0.427977 0.001686 0.080 Uiso 1 1 calc R U . . .
H24B H 0.389946 0.516944 0.017891 0.080 Uiso 1 1 calc R U . . .
H24C H 0.271852 0.499634 -0.042969 0.080 Uiso 1 1 calc R U . . .
C25 C 0.3404(7) 0.7004(4) 0.5136(3) 0.0531(18) Uani 1 1 d D . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.2991(11) . ?
Pt1 P2 2.3047(11) . ?
Pt1 Ag1 2.6076(5) . ?
Pt1 Ag1B 2.631(7) . ?
Ag1 O1 2.274(6) . ?
Ag1 O3 2.347(10) 3_666 ?
Ag1B O3B 2.22(2) 3_666 ?
S1 O3B 1.317(16) . ?
S1 O2B 1.325(18) . ?
S1 O1 1.378(6) . ?
S1 O1B 1.426(19) . ?
S1 O3 1.441(8) . ?
S1 O2 1.461(7) . ?
S1 C25 1.810(7) . ?
P1 C1 1.898(5) . ?
P1 C9 1.909(5) . ?
P1 C5 1.923(5) . ?
P2 C17 1.895(5) . ?
P2 C13 1.909(5) . ?
P2 C21 1.917(5) . ?
F1 C25 1.238(12) . ?
F2 C25 1.328(15) . ?
F3 C25 1.273(10) . ?
F1B C25 1.438(12) . ?
F2B C25 1.331(13) . ?
F3B C25 1.392(14) . ?
C1 C4 1.531(8) . ?
C1 C2 1.534(8) . ?
C1 C3 1.562(7) . ?
C5 C6 1.509(8) . ?
C5 C8 1.523(7) . ?
C5 C7 1.560(9) . ?
C9 C11 1.513(9) . ?
C9 C10 1.520(8) . ?
C9 C12 1.569(8) . ?
C13 C15 1.529(9) . ?
C13 C16 1.543(7) . ?
C13 C14 1.544(8) . ?
C17 C19 1.528(8) . ?
C17 C20 1.540(7) . ?
C17 C18 1.546(8) . ?
C21 C23 1.530(9) . ?
C21 C22 1.539(9) . ?
C21 C24 1.542(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 174.69(4) . . ?
P1 Pt1 Ag1 90.92(3) . . ?
P2 Pt1 Ag1 93.44(3) . . ?
P1 Pt1 Ag1B 90.20(16) . . ?
P2 Pt1 Ag1B 93.45(17) . . ?
O1 Ag1 O3 89.4(3) . 3_666 ?
O1 Ag1 Pt1 150.9(2) . . ?
O3 Ag1 Pt1 118.3(2) 3_666 . ?
O3B Ag1B Pt1 136.8(7) 3_666 . ?
O3B S1 O2B 123.3(11) . . ?
O3B S1 O1B 113.1(10) . . ?
O2B S1 O1B 114.2(10) . . ?
O1 S1 O3 112.4(8) . . ?
O1 S1 O2 114.6(4) . . ?
O3 S1 O2 116.1(8) . . ?
O3B S1 C25 101.2(9) . . ?
O2B S1 C25 105.1(13) . . ?
O1 S1 C25 103.9(4) . . ?
O1B S1 C25 93.8(14) . . ?
O3 S1 C25 102.5(4) . . ?
O2 S1 C25 105.5(5) . . ?
C1 P1 C9 108.8(2) . . ?
C1 P1 C5 108.9(2) . . ?
C9 P1 C5 107.1(2) . . ?
C1 P1 Pt1 110.84(14) . . ?
C9 P1 Pt1 105.67(18) . . ?
C5 P1 Pt1 115.36(17) . . ?
C17 P2 C13 109.0(2) . . ?
C17 P2 C21 108.6(2) . . ?
C13 P2 C21 106.9(3) . . ?
C17 P2 Pt1 107.49(17) . . ?
C13 P2 Pt1 116.75(16) . . ?
C21 P2 Pt1 107.78(16) . . ?
S1 O1 Ag1 124.8(4) . . ?
S1 O3 Ag1 140.3(6) . 3_666 ?
S1 O3B Ag1B 130.6(11) . 3_666 ?
C4 C1 C2 104.3(4) . . ?
C4 C1 C3 106.4(5) . . ?
C2 C1 C3 108.1(5) . . ?
C4 C1 P1 110.1(4) . . ?
C2 C1 P1 110.3(4) . . ?
C3 C1 P1 116.9(4) . . ?
C6 C5 C8 111.9(5) . . ?
C6 C5 C7 106.4(5) . . ?
C8 C5 C7 104.5(5) . . ?
C6 C5 P1 108.6(4) . . ?
C8 C5 P1 114.5(4) . . ?
C7 C5 P1 110.7(4) . . ?
C11 C9 C10 107.9(6) . . ?
C11 C9 C12 109.1(5) . . ?
C10 C9 C12 106.8(5) . . ?
C11 C9 P1 108.7(4) . . ?
C10 C9 P1 108.6(4) . . ?
C12 C9 P1 115.6(4) . . ?
C15 C13 C16 107.6(5) . . ?
C15 C13 C14 106.7(5) . . ?
C16 C13 C14 108.3(5) . . ?
C15 C13 P2 110.9(4) . . ?
C16 C13 P2 107.6(4) . . ?
C14 C13 P2 115.4(4) . . ?
C19 C17 C20 108.4(5) . . ?
C19 C17 C18 108.8(5) . . ?
C20 C17 C18 106.1(5) . . ?
C19 C17 P2 116.0(4) . . ?
C20 C17 P2 108.0(3) . . ?
C18 C17 P2 109.1(4) . . ?
C23 C21 C22 104.9(5) . . ?
C23 C21 C24 108.0(5) . . ?
C22 C21 C24 110.1(5) . . ?
C23 C21 P2 108.6(4) . . ?
C22 C21 P2 109.2(5) . . ?
C24 C21 P2 115.5(4) . . ?
F1 C25 F3 116.0(13) . . ?
F1 C25 F2 100.5(12) . . ?
F3 C25 F2 103.1(8) . . ?
F2B C25 F3B 108.7(9) . . ?
F2B C25 F1B 106.2(8) . . ?
F3B C25 F1B 100.4(8) . . ?
F1 C25 S1 110.9(7) . . ?
F3 C25 S1 118.9(5) . . ?
F2 C25 S1 104.7(8) . . ?
F2B C25 S1 124.2(9) . . ?
F3B C25 S1 104.5(9) . . ?
F1B C25 S1 110.4(6) . . ?

_refine_diff_density_max         1.658
_refine_diff_density_min         -4.535
_refine_diff_density_rms         0.235

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1909269'
loop_
_audit_author_name
_audit_author_address
'Celia Maya'
;University of Seville
Spain
;
_audit_update_record             
;
2019-04-10 deposited with the CCDC.	2019-05-17 downloaded from the CCDC.
;


_vrf_PLAT213_2                   
;
PROBLEM: Atom C18A  has ADP max/min Ratio ....
RESPONSE: This value is due to unsolved disorder in t-Butyl groups.
;
_vrf_PLAT230_2                   
;
PROBLEM: Hirshfeld Test Diff for...
RESPONSE: This value is due to unsolved disorder in t-Butyl groups.
;
_vrf_PLAT412_2                   
;
PROBLEM: Short Intra XH3 .. XHn
RESPONSE: This value is due to unsolved disorder in t-Butyl groups.
;
_vrf_PLAT242_2                   
;
PROBLEM: SLow    'MainMol' Ueq as Compared to Neighbors
RESPONSE: This value is due to unsolved disorder in t-Butyl groups.
;
_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C26 H54 Ag F6 N O4 P2 Pt S2'
_chemical_formula_weight         987.72

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   21.294(2)
_cell_length_b                   15.9689(16)
_cell_length_c                   21.9021(19)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7447.6(12)
_cell_formula_units_Z            8
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9187
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      27.96

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.762
_exptl_crystal_F_000             3920
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.17
_exptl_absorpt_coefficient_mu    4.537
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5312
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_process_details   
; 
 SADABS, Bruker (2006). APEX 2. Version 2.1. Bruker Analytical 
 X-ray Solutions, Madison, Wisconsin, USA. 
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            243721
_diffrn_reflns_av_unetI/netI     0.0188
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         1.845
_diffrn_reflns_theta_max         30.576
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             11422
_reflns_number_gt                8493
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²+0.8342P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11422
_refine_ls_number_parameters     466
_refine_ls_number_restraints     39
_refine_ls_R_factor_all          0.0680
_refine_ls_R_factor_gt           0.0460
_refine_ls_wR_factor_ref         0.1741
_refine_ls_wR_factor_gt          0.1580
_refine_ls_goodness_of_fit_ref   1.265
_refine_ls_restrained_S_all      1.268
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.73872(2) 0.61694(2) 0.47787(2) 0.03518(9) Uani 1 1 d . . . A 1
Ag1 Ag 0.83130(3) 0.63164(4) 0.39717(2) 0.0777(2) Uani 1 1 d . . . A 1
P1 P 0.65837(6) 0.61636(8) 0.40666(7) 0.0396(3) Uani 1 1 d . . . A 1
P2 P 0.80377(8) 0.59881(9) 0.56181(6) 0.0448(3) Uani 1 1 d D . . A 1
C1 C 0.6527(3) 0.5078(4) 0.3701(3) 0.0585(14) Uani 1 1 d . . . A 1
C2 C 0.6105(4) 0.5040(4) 0.3129(3) 0.074(2) Uani 1 1 d . . . A 1
H2A H 0.628414 0.537971 0.281180 0.111 Uiso 1 1 calc R U . A 1
H2B H 0.569383 0.524549 0.322817 0.111 Uiso 1 1 calc R U . A 1
H2C H 0.607448 0.447108 0.299036 0.111 Uiso 1 1 calc R U . A 1
C3 C 0.6278(5) 0.4446(4) 0.4206(4) 0.092(3) Uani 1 1 d . . . A 1
H3A H 0.628941 0.388529 0.404731 0.139 Uiso 1 1 calc R U . A 1
H3B H 0.585488 0.458853 0.431366 0.139 Uiso 1 1 calc R U . A 1
H3C H 0.654096 0.448080 0.456110 0.139 Uiso 1 1 calc R U . A 1
C4 C 0.7178(3) 0.4796(5) 0.3529(3) 0.076(2) Uani 1 1 d . . . A 1
H4A H 0.716543 0.421921 0.340501 0.114 Uiso 1 1 calc R U . A 1
H4B H 0.745199 0.485507 0.387380 0.114 Uiso 1 1 calc R U . A 1
H4C H 0.733051 0.513259 0.319747 0.114 Uiso 1 1 calc R U . A 1
C5 C 0.5817(3) 0.6368(6) 0.4492(4) 0.087(3) Uani 1 1 d . . . A 1
C6 C 0.5789(4) 0.5946(8) 0.5074(4) 0.113(4) Uani 1 1 d . . . A 1
H6A H 0.537277 0.599244 0.523833 0.169 Uiso 1 1 calc R U . A 1
H6B H 0.608334 0.619893 0.534972 0.169 Uiso 1 1 calc R U . A 1
H6C H 0.589285 0.536553 0.501986 0.169 Uiso 1 1 calc R U . A 1
C7 C 0.5213(3) 0.6115(6) 0.4128(5) 0.105(3) Uani 1 1 d . . . A 1
H7A H 0.524040 0.553661 0.401228 0.158 Uiso 1 1 calc R U . A 1
H7B H 0.517964 0.645599 0.376836 0.158 Uiso 1 1 calc R U . A 1
H7C H 0.484987 0.619844 0.438013 0.158 Uiso 1 1 calc R U . A 1
C8 C 0.5849(5) 0.7382(8) 0.4630(7) 0.189(8) Uani 1 1 d . . . A 1
H8A H 0.555125 0.752355 0.494179 0.284 Uiso 1 1 calc R U . A 1
H8B H 0.575166 0.768531 0.426323 0.284 Uiso 1 1 calc R U . A 1
H8C H 0.626436 0.752798 0.476393 0.284 Uiso 1 1 calc R U . A 1
C9 C 0.6654(5) 0.6983(5) 0.3432(5) 0.118(4) Uani 1 1 d . . . A 1
C10 C 0.6021(5) 0.7211(5) 0.3131(5) 0.119(4) Uani 1 1 d . . . A 1
H10A H 0.584066 0.768368 0.333781 0.179 Uiso 1 1 calc R U . A 1
H10B H 0.574001 0.674260 0.315908 0.179 Uiso 1 1 calc R U . A 1
H10C H 0.608851 0.734897 0.270956 0.179 Uiso 1 1 calc R U . A 1
C11 C 0.7151(4) 0.6597(8) 0.2934(4) 0.120(4) Uani 1 1 d . . . A 1
H11A H 0.703982 0.602699 0.284444 0.180 Uiso 1 1 calc R U . A 1
H11B H 0.756786 0.661425 0.310022 0.180 Uiso 1 1 calc R U . A 1
H11C H 0.713617 0.692195 0.256559 0.180 Uiso 1 1 calc R U . A 1
C12 C 0.6923(5) 0.7806(5) 0.3691(5) 0.108(3) Uani 1 1 d . . . A 1
H12A H 0.693879 0.822004 0.337409 0.162 Uiso 1 1 calc R U . A 1
H12B H 0.733859 0.770780 0.384498 0.162 Uiso 1 1 calc R U . A 1
H12C H 0.665859 0.800140 0.401650 0.162 Uiso 1 1 calc R U . A 1
S1 S 0.94393(11) 0.54063(14) 0.31873(10) 0.0895(7) Uani 1 1 d . . . A 1
S2 S 0.92482(9) 0.71082(13) 0.29572(9) 0.0764(5) Uani 1 1 d . . . A 1
F1 F 0.9138(4) 0.5321(6) 0.2047(3) 0.194(4) Uani 1 1 d . . . A 1
F2 F 0.9208(5) 0.4144(5) 0.2458(5) 0.228(5) Uani 1 1 d . . . A 1
F3 F 0.8427(3) 0.4917(6) 0.2638(4) 0.197(4) Uani 1 1 d . . . A 1
F4 F 0.9687(4) 0.7649(5) 0.3986(3) 0.158(3) Uani 1 1 d . . . A 1
F5 F 0.9986(4) 0.8344(5) 0.3241(4) 0.173(3) Uani 1 1 d . . . A 1
F6 F 1.0381(3) 0.7164(5) 0.3384(4) 0.156(3) Uani 1 1 d . . . A 1
O1 O 1.0074(3) 0.5497(4) 0.2992(3) 0.112(2) Uani 1 1 d . . . A 1
O2 O 0.9288(4) 0.4867(4) 0.3680(3) 0.141(3) Uani 1 1 d . . . A 1
O3 O 0.9512(3) 0.6988(4) 0.2370(2) 0.113(2) Uani 1 1 d . . . A 1
O4 O 0.8724(3) 0.7650(4) 0.3040(4) 0.118(2) Uani 1 1 d . . . A 1
N1 N 0.9085(3) 0.6260(3) 0.3302(2) 0.0578(13) Uani 1 1 d . . . A 1
C25 C 0.9010(5) 0.5010(15) 0.2565(5) 0.209(10) Uani 1 1 d . . . A 1
C26 C 0.9871(5) 0.7586(7) 0.3449(5) 0.105(3) Uani 1 1 d . . . A 1
C13A C 0.7728(5) 0.6602(7) 0.6329(4) 0.070(4) Uani 0.574(10) 1 d D . P A 1
C14A C 0.7015(5) 0.6548(9) 0.6311(5) 0.064(3) Uani 0.574(10) 1 d D . P A 1
H14A H 0.688608 0.598449 0.639623 0.096 Uiso 0.574(10) 1 calc R U P A 1
H14B H 0.686896 0.670784 0.591260 0.096 Uiso 0.574(10) 1 calc R U P A 1
H14C H 0.684079 0.691897 0.661108 0.096 Uiso 0.574(10) 1 calc R U P A 1
C15A C 0.7868(8) 0.7537(7) 0.6297(6) 0.092(5) Uani 0.574(10) 1 d D . P A 1
H15A H 0.776495 0.779327 0.668085 0.137 Uiso 0.574(10) 1 calc R U P A 1
H15B H 0.762192 0.778663 0.597874 0.137 Uiso 0.574(10) 1 calc R U P A 1
H15C H 0.830624 0.761888 0.621265 0.137 Uiso 0.574(10) 1 calc R U P A 1
C16A C 0.7929(8) 0.6308(10) 0.6948(5) 0.083(5) Uani 0.574(10) 1 d D . P A 1
H16A H 0.768094 0.658205 0.725484 0.125 Uiso 0.574(10) 1 calc R U P A 1
H16B H 0.836434 0.644106 0.700927 0.125 Uiso 0.574(10) 1 calc R U P A 1
H16C H 0.787126 0.571338 0.697744 0.125 Uiso 0.574(10) 1 calc R U P A 1
C13B C 0.7425(7) 0.6036(8) 0.6253(7) 0.053(4) Uiso 0.426(10) 1 d D . P A 2
C14B C 0.7003(9) 0.6874(9) 0.6157(9) 0.060(5) Uiso 0.426(10) 1 d D . P A 2
H14D H 0.703001 0.705119 0.573902 0.090 Uiso 0.426(10) 1 calc R U P A 2
H14E H 0.715687 0.731048 0.641826 0.090 Uiso 0.426(10) 1 calc R U P A 2
H14F H 0.657355 0.675385 0.625707 0.090 Uiso 0.426(10) 1 calc R U P A 2
C15B C 0.7701(11) 0.6094(12) 0.6930(10) 0.071(7) Uiso 0.426(10) 1 d D . P A 2
H15D H 0.737792 0.628185 0.720345 0.107 Uiso 0.426(10) 1 calc R U P A 2
H15E H 0.804451 0.648332 0.693749 0.107 Uiso 0.426(10) 1 calc R U P A 2
H15F H 0.784649 0.555198 0.705648 0.107 Uiso 0.426(10) 1 calc R U P A 2
C16B C 0.6966(8) 0.5255(10) 0.6233(8) 0.075(5) Uiso 0.426(10) 1 d D . P A 2
H16D H 0.716684 0.478094 0.641870 0.113 Uiso 0.426(10) 1 calc R U P A 2
H16E H 0.686416 0.512574 0.581660 0.113 Uiso 0.426(10) 1 calc R U P A 2
H16F H 0.658771 0.538529 0.645242 0.113 Uiso 0.426(10) 1 calc R U P A 2
C17A C 0.8068(5) 0.4847(6) 0.5827(4) 0.071(4) Uani 0.595(12) 1 d D . P A 1
C18A C 0.8605(9) 0.4617(16) 0.6263(8) 0.147(13) Uani 0.595(12) 1 d D . P A 1
H18A H 0.869530 0.403024 0.622708 0.220 Uiso 0.595(12) 1 calc R U P A 1
H18B H 0.848267 0.474161 0.667494 0.220 Uiso 0.595(12) 1 calc R U P A 1
H18C H 0.897199 0.493518 0.615910 0.220 Uiso 0.595(12) 1 calc R U P A 1
C19A C 0.7423(7) 0.4606(9) 0.6113(6) 0.090(5) Uani 0.595(12) 1 d D . P A 1
H19A H 0.745018 0.405527 0.628700 0.135 Uiso 0.595(12) 1 calc R U P A 1
H19B H 0.710560 0.461161 0.580167 0.135 Uiso 0.595(12) 1 calc R U P A 1
H19C H 0.731583 0.500149 0.642596 0.135 Uiso 0.595(12) 1 calc R U P A 1
C20A C 0.8131(8) 0.4352(8) 0.5230(5) 0.076(5) Uani 0.595(12) 1 d D . P A 1
H20A H 0.856548 0.432198 0.511573 0.114 Uiso 0.595(12) 1 calc R U P A 1
H20B H 0.789736 0.462774 0.491402 0.114 Uiso 0.595(12) 1 calc R U P A 1
H20C H 0.796952 0.379628 0.528804 0.114 Uiso 0.595(12) 1 calc R U P A 1
C17B C 0.8330(6) 0.4866(9) 0.5576(6) 0.050(4) Uiso 0.405(12) 1 d D . P A 2
C18B C 0.8939(8) 0.4856(11) 0.5146(7) 0.068(5) Uiso 0.405(12) 1 d D . P A 2
H18D H 0.900438 0.430057 0.499198 0.102 Uiso 0.405(12) 1 calc R U P A 2
H18E H 0.929900 0.502805 0.537791 0.102 Uiso 0.405(12) 1 calc R U P A 2
H18F H 0.887730 0.523513 0.481097 0.102 Uiso 0.405(12) 1 calc R U P A 2
C20B C 0.7804(9) 0.4248(16) 0.5291(9) 0.073(7) Uiso 0.405(12) 1 d D . P A 2
H20D H 0.764630 0.448229 0.491787 0.109 Uiso 0.405(12) 1 calc R U P A 2
H20E H 0.746523 0.418456 0.557681 0.109 Uiso 0.405(12) 1 calc R U P A 2
H20F H 0.798843 0.371105 0.521023 0.109 Uiso 0.405(12) 1 calc R U P A 2
C19B C 0.8536(9) 0.4497(19) 0.6238(9) 0.062(6) Uiso 0.405(12) 1 d D . P A 2
H19D H 0.876325 0.398309 0.618294 0.094 Uiso 0.405(12) 1 calc R U P A 2
H19E H 0.816848 0.439364 0.648016 0.094 Uiso 0.405(12) 1 calc R U P A 2
H19F H 0.879957 0.489656 0.644274 0.094 Uiso 0.405(12) 1 calc R U P A 2
C21A C 0.8902(5) 0.6373(7) 0.5566(4) 0.073(3) Uani 0.659(12) 1 d D . P A 1
C22A C 0.9272(9) 0.6466(11) 0.6136(6) 0.112(7) Uani 0.659(12) 1 d D . P A 1
H22A H 0.968886 0.665241 0.603763 0.167 Uiso 0.659(12) 1 calc R U P A 1
H22B H 0.929467 0.593544 0.634126 0.167 Uiso 0.659(12) 1 calc R U P A 1
H22C H 0.907307 0.686850 0.639690 0.167 Uiso 0.659(12) 1 calc R U P A 1
C24A C 0.8941(7) 0.7162(9) 0.5208(6) 0.100(6) Uani 0.659(12) 1 d D . P A 1
H24A H 0.886523 0.763077 0.547265 0.150 Uiso 0.659(12) 1 calc R U P A 1
H24B H 0.863097 0.715433 0.488974 0.150 Uiso 0.659(12) 1 calc R U P A 1
H24C H 0.935151 0.721164 0.503059 0.150 Uiso 0.659(12) 1 calc R U P A 1
C23A C 0.9254(7) 0.5757(11) 0.5159(6) 0.108(6) Uani 0.659(12) 1 d D . P A 1
H23A H 0.960576 0.603381 0.497370 0.162 Uiso 0.659(12) 1 calc R U P A 1
H23B H 0.897683 0.555450 0.484600 0.162 Uiso 0.659(12) 1 calc R U P A 1
H23C H 0.939987 0.529499 0.540040 0.162 Uiso 0.659(12) 1 calc R U P A 1
C21B C 0.8660(7) 0.6703(8) 0.5734(6) 0.037(3) Uiso 0.341(12) 1 d D . P A 2
C22B C 0.8378(8) 0.7604(10) 0.5886(7) 0.055(5) Uiso 0.341(12) 1 d D . P A 2
H22D H 0.869074 0.802410 0.580937 0.083 Uiso 0.341(12) 1 calc R U P A 2
H22E H 0.825532 0.762379 0.630730 0.083 Uiso 0.341(12) 1 calc R U P A 2
H22F H 0.801861 0.770565 0.563217 0.083 Uiso 0.341(12) 1 calc R U P A 2
C23B C 0.9041(15) 0.6724(17) 0.5105(10) 0.084(10) Uiso 0.341(12) 1 d D . P A 2
H23D H 0.875382 0.666104 0.477048 0.127 Uiso 0.341(12) 1 calc R U P A 2
H23E H 0.934042 0.627523 0.509902 0.127 Uiso 0.341(12) 1 calc R U P A 2
H23F H 0.925690 0.724971 0.506861 0.127 Uiso 0.341(12) 1 calc R U P A 2
C24B C 0.9145(13) 0.6443(16) 0.6267(10) 0.060(6) Uiso 0.341(12) 1 d D . P A 2
H24D H 0.955325 0.634835 0.609377 0.090 Uiso 0.341(12) 1 calc R U P A 2
H24E H 0.900143 0.593957 0.646209 0.090 Uiso 0.341(12) 1 calc R U P A 2
H24F H 0.916989 0.688515 0.656305 0.090 Uiso 0.341(12) 1 calc R U P A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.3153(14) . ?
Pt1 P2 2.3199(14) . ?
Pt1 Ag1 2.6580(6) . ?
Ag1 N1 2.205(5) . ?
P1 C5 1.908(7) . ?
P1 C1 1.913(6) . ?
P1 C9 1.916(8) . ?
P2 C17A 1.879(10) . ?
P2 C21A 1.944(11) . ?
P2 C13A 1.955(10) . ?
C1 C4 1.505(9) . ?
C1 C2 1.543(8) . ?
C1 C3 1.589(10) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 C6 1.442(16) . ?
C5 C7 1.565(11) . ?
C5 C8 1.649(13) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C12 1.541(12) . ?
C9 C10 1.543(11) . ?
C9 C11 1.640(16) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
S1 O2 1.417(6) . ?
S1 O1 1.426(6) . ?
S1 N1 1.578(5) . ?
S1 C25 1.760(16) . ?
S2 O3 1.416(6) . ?
S2 O4 1.424(7) . ?
S2 N1 1.590(5) . ?
S2 C26 1.871(10) . ?
F1 C25 1.268(13) . ?
F2 C25 1.46(2) . ?
F3 C25 1.259(12) . ?
F4 C26 1.244(11) . ?
F5 C26 1.316(11) . ?
F6 C26 1.288(12) . ?
C13A C16A 1.497(12) . ?
C13A C14A 1.520(13) . ?
C13A C15A 1.524(13) . ?
C14A H14A 0.9600 . ?
C14A H14B 0.9600 . ?
C14A H14C 0.9600 . ?
C15A H15A 0.9600 . ?
C15A H15B 0.9600 . ?
C15A H15C 0.9600 . ?
C16A H16A 0.9600 . ?
C16A H16B 0.9600 . ?
C16A H16C 0.9600 . ?
C13B C16B 1.585(16) . ?
C13B C15B 1.599(17) . ?
C13B C14B 1.625(16) . ?
C14B H14D 0.9600 . ?
C14B H14E 0.9600 . ?
C14B H14F 0.9600 . ?
C15B H15D 0.9600 . ?
C15B H15E 0.9600 . ?
C15B H15F 0.9600 . ?
C16B H16D 0.9600 . ?
C16B H16E 0.9600 . ?
C16B H16F 0.9600 . ?
C17A C18A 1.533(14) . ?
C17A C20A 1.534(12) . ?
C17A C19A 1.557(13) . ?
C18A H18A 0.9600 . ?
C18A H18B 0.9600 . ?
C18A H18C 0.9600 . ?
C19A H19A 0.9600 . ?
C19A H19B 0.9600 . ?
C19A H19C 0.9600 . ?
C20A H20A 0.9600 . ?
C20A H20B 0.9600 . ?
C20A H20C 0.9600 . ?
C17B C18B 1.603(17) . ?
C17B C20B 1.617(18) . ?
C17B C19B 1.626(18) . ?
C18B H18D 0.9600 . ?
C18B H18E 0.9600 . ?
C18B H18F 0.9600 . ?
C20B H20D 0.9600 . ?
C20B H20E 0.9600 . ?
C20B H20F 0.9600 . ?
C19B H19D 0.9600 . ?
C19B H19E 0.9600 . ?
C19B H19F 0.9600 . ?
C21A C22A 1.484(12) . ?
C21A C24A 1.486(13) . ?
C21A C23A 1.524(13) . ?
C22A H22A 0.9600 . ?
C22A H22B 0.9600 . ?
C22A H22C 0.9600 . ?
C24A H24A 0.9600 . ?
C24A H24B 0.9600 . ?
C24A H24C 0.9600 . ?
C23A H23A 0.9600 . ?
C23A H23B 0.9600 . ?
C23A H23C 0.9600 . ?
C21B C22B 1.593(17) . ?
C21B C23B 1.599(19) . ?
C21B C24B 1.613(19) . ?
C22B H22D 0.9600 . ?
C22B H22E 0.9600 . ?
C22B H22F 0.9600 . ?
C23B H23D 0.9600 . ?
C23B H23E 0.9600 . ?
C23B H23F 0.9600 . ?
C24B H24D 0.9600 . ?
C24B H24E 0.9600 . ?
C24B H24F 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 167.05(5) . . ?
P1 Pt1 Ag1 95.77(4) . . ?
P2 Pt1 Ag1 95.46(4) . . ?
N1 Ag1 Pt1 172.57(13) . . ?
C5 P1 C1 107.8(3) . . ?
C5 P1 C9 107.7(5) . . ?
C1 P1 C9 108.7(4) . . ?
C5 P1 Pt1 107.6(3) . . ?
C1 P1 Pt1 109.4(2) . . ?
C9 P1 Pt1 115.4(2) . . ?
C17A P2 C21A 106.8(5) . . ?
C17A P2 C13A 107.6(5) . . ?
C21A P2 C13A 102.0(5) . . ?
C17A P2 Pt1 109.5(3) . . ?
C21A P2 Pt1 118.6(3) . . ?
C13A P2 Pt1 111.5(3) . . ?
C4 C1 C2 108.7(5) . . ?
C4 C1 C3 106.9(6) . . ?
C2 C1 C3 110.2(6) . . ?
C4 C1 P1 108.6(5) . . ?
C2 C1 P1 114.4(4) . . ?
C3 C1 P1 107.8(4) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C6 C5 C7 107.2(8) . . ?
C6 C5 C8 107.4(8) . . ?
C7 C5 C8 112.4(8) . . ?
C6 C5 P1 112.7(6) . . ?
C7 C5 P1 114.2(5) . . ?
C8 C5 P1 102.8(7) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C7 H7A 109.5 . . ?
C5 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C5 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C5 C8 H8A 109.5 . . ?
C5 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C5 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C12 C9 C10 106.3(8) . . ?
C12 C9 C11 109.0(8) . . ?
C10 C9 C11 111.6(9) . . ?
C12 C9 P1 110.1(7) . . ?
C10 C9 P1 113.7(7) . . ?
C11 C9 P1 106.0(6) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
O2 S1 O1 120.4(5) . . ?
O2 S1 N1 107.2(3) . . ?
O1 S1 N1 114.4(4) . . ?
O2 S1 C25 104.6(7) . . ?
O1 S1 C25 107.3(4) . . ?
N1 S1 C25 100.7(7) . . ?
O3 S2 O4 120.6(4) . . ?
O3 S2 N1 113.8(4) . . ?
O4 S2 N1 106.6(3) . . ?
O3 S2 C26 107.3(5) . . ?
O4 S2 C26 103.5(5) . . ?
N1 S2 C26 103.3(4) . . ?
S1 N1 S2 123.8(3) . . ?
S1 N1 Ag1 119.9(3) . . ?
S2 N1 Ag1 116.4(3) . . ?
F3 C25 F1 111.9(12) . . ?
F3 C25 F2 101.1(17) . . ?
F1 C25 F2 99.5(11) . . ?
F3 C25 S1 117.1(8) . . ?
F1 C25 S1 116.1(14) . . ?
F2 C25 S1 108.3(9) . . ?
F4 C26 F6 114.3(10) . . ?
F4 C26 F5 108.1(11) . . ?
F6 C26 F5 106.7(8) . . ?
F4 C26 S2 110.8(7) . . ?
F6 C26 S2 108.7(8) . . ?
F5 C26 S2 108.0(7) . . ?
C16A C13A C14A 107.0(9) . . ?
C16A C13A C15A 107.0(9) . . ?
C14A C13A C15A 104.4(9) . . ?
C16A C13A P2 117.9(9) . . ?
C14A C13A P2 106.7(7) . . ?
C15A C13A P2 112.9(8) . . ?
C13A C14A H14A 109.5 . . ?
C13A C14A H14B 109.5 . . ?
H14A C14A H14B 109.5 . . ?
C13A C14A H14C 109.5 . . ?
H14A C14A H14C 109.5 . . ?
H14B C14A H14C 109.5 . . ?
C13A C15A H15A 109.5 . . ?
C13A C15A H15B 109.5 . . ?
H15A C15A H15B 109.5 . . ?
C13A C15A H15C 109.5 . . ?
H15A C15A H15C 109.5 . . ?
H15B C15A H15C 109.5 . . ?
C13A C16A H16A 109.5 . . ?
C13A C16A H16B 109.5 . . ?
H16A C16A H16B 109.5 . . ?
C13A C16A H16C 109.5 . . ?
H16A C16A H16C 109.5 . . ?
H16B C16A H16C 109.5 . . ?
C16B C13B C15B 107.3(10) . . ?
C16B C13B C14B 107.6(10) . . ?
C15B C13B C14B 105.9(11) . . ?
C13B C14B H14D 109.5 . . ?
C13B C14B H14E 109.5 . . ?
H14D C14B H14E 109.5 . . ?
C13B C14B H14F 109.5 . . ?
H14D C14B H14F 109.5 . . ?
H14E C14B H14F 109.5 . . ?
C13B C15B H15D 109.5 . . ?
C13B C15B H15E 109.5 . . ?
H15D C15B H15E 109.5 . . ?
C13B C15B H15F 109.5 . . ?
H15D C15B H15F 109.5 . . ?
H15E C15B H15F 109.5 . . ?
C13B C16B H16D 109.5 . . ?
C13B C16B H16E 109.5 . . ?
H16D C16B H16E 109.5 . . ?
C13B C16B H16F 109.5 . . ?
H16D C16B H16F 109.5 . . ?
H16E C16B H16F 109.5 . . ?
C18A C17A C20A 109.9(10) . . ?
C18A C17A C19A 110.4(10) . . ?
C20A C17A C19A 107.0(9) . . ?
C18A C17A P2 114.2(11) . . ?
C20A C17A P2 107.1(7) . . ?
C19A C17A P2 107.9(8) . . ?
C17A C18A H18A 109.5 . . ?
C17A C18A H18B 109.5 . . ?
H18A C18A H18B 109.5 . . ?
C17A C18A H18C 109.5 . . ?
H18A C18A H18C 109.5 . . ?
H18B C18A H18C 109.5 . . ?
C17A C19A H19A 109.5 . . ?
C17A C19A H19B 109.5 . . ?
H19A C19A H19B 109.5 . . ?
C17A C19A H19C 109.5 . . ?
H19A C19A H19C 109.5 . . ?
H19B C19A H19C 109.5 . . ?
C17A C20A H20A 109.5 . . ?
C17A C20A H20B 109.5 . . ?
H20A C20A H20B 109.5 . . ?
C17A C20A H20C 109.5 . . ?
H20A C20A H20C 109.5 . . ?
H20B C20A H20C 109.5 . . ?
C18B C17B C20B 109.1(11) . . ?
C18B C17B C19B 107.5(10) . . ?
C20B C17B C19B 108.1(11) . . ?
C17B C18B H18D 109.5 . . ?
C17B C18B H18E 109.5 . . ?
H18D C18B H18E 109.5 . . ?
C17B C18B H18F 109.5 . . ?
H18D C18B H18F 109.5 . . ?
H18E C18B H18F 109.5 . . ?
C17B C20B H20D 109.5 . . ?
C17B C20B H20E 109.5 . . ?
H20D C20B H20E 109.5 . . ?
C17B C20B H20F 109.5 . . ?
H20D C20B H20F 109.5 . . ?
H20E C20B H20F 109.5 . . ?
C17B C19B H19D 109.5 . . ?
C17B C19B H19E 109.5 . . ?
H19D C19B H19E 109.5 . . ?
C17B C19B H19F 109.5 . . ?
H19D C19B H19F 109.5 . . ?
H19E C19B H19F 109.5 . . ?
C22A C21A C24A 109.3(9) . . ?
C22A C21A C23A 107.2(10) . . ?
C24A C21A C23A 102.3(9) . . ?
C22A C21A P2 119.0(10) . . ?
C24A C21A P2 110.6(8) . . ?
C23A C21A P2 107.2(8) . . ?
C21A C22A H22A 109.5 . . ?
C21A C22A H22B 109.5 . . ?
H22A C22A H22B 109.5 . . ?
C21A C22A H22C 109.5 . . ?
H22A C22A H22C 109.5 . . ?
H22B C22A H22C 109.5 . . ?
C21A C24A H24A 109.5 . . ?
C21A C24A H24B 109.5 . . ?
H24A C24A H24B 109.5 . . ?
C21A C24A H24C 109.5 . . ?
H24A C24A H24C 109.5 . . ?
H24B C24A H24C 109.5 . . ?
C21A C23A H23A 109.5 . . ?
C21A C23A H23B 109.5 . . ?
H23A C23A H23B 109.5 . . ?
C21A C23A H23C 109.5 . . ?
H23A C23A H23C 109.5 . . ?
H23B C23A H23C 109.5 . . ?
C22B C21B C23B 110.6(11) . . ?
C22B C21B C24B 108.9(11) . . ?
C23B C21B C24B 107.7(12) . . ?
C21B C22B H22D 109.5 . . ?
C21B C22B H22E 109.5 . . ?
H22D C22B H22E 109.5 . . ?
C21B C22B H22F 109.5 . . ?
H22D C22B H22F 109.5 . . ?
H22E C22B H22F 109.5 . . ?
C21B C23B H23D 109.5 . . ?
C21B C23B H23E 109.5 . . ?
H23D C23B H23E 109.5 . . ?
C21B C23B H23F 109.5 . . ?
H23D C23B H23F 109.5 . . ?
H23E C23B H23F 109.5 . . ?
C21B C24B H24D 109.5 . . ?
C21B C24B H24E 109.5 . . ?
H24D C24B H24E 109.5 . . ?
C21B C24B H24F 109.5 . . ?
H24D C24B H24F 109.5 . . ?
H24E C24B H24F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 S1 N1 S2 164.5(6) . . . . ?
O1 S1 N1 S2 28.3(6) . . . . ?
C25 S1 N1 S2 -86.4(6) . . . . ?
O2 S1 N1 Ag1 -15.8(6) . . . . ?
O1 S1 N1 Ag1 -151.9(4) . . . . ?
C25 S1 N1 Ag1 93.4(6) . . . . ?
O3 S2 N1 S1 27.5(6) . . . . ?
O4 S2 N1 S1 162.8(5) . . . . ?
C26 S2 N1 S1 -88.4(6) . . . . ?
O3 S2 N1 Ag1 -152.3(4) . . . . ?
O4 S2 N1 Ag1 -16.9(5) . . . . ?
C26 S2 N1 Ag1 91.8(5) . . . . ?
O2 S1 C25 F3 53.9(18) . . . . ?
O1 S1 C25 F3 -177.1(15) . . . . ?
N1 S1 C25 F3 -57.2(17) . . . . ?
O2 S1 C25 F1 -170.3(12) . . . . ?
O1 S1 C25 F1 -41.3(15) . . . . ?
N1 S1 C25 F1 78.6(13) . . . . ?
O2 S1 C25 F2 -59.5(8) . . . . ?
O1 S1 C25 F2 69.4(10) . . . . ?
N1 S1 C25 F2 -170.6(8) . . . . ?
O3 S2 C26 F4 -174.8(8) . . . . ?
O4 S2 C26 F4 56.7(9) . . . . ?
N1 S2 C26 F4 -54.3(9) . . . . ?
O3 S2 C26 F6 -48.4(8) . . . . ?
O4 S2 C26 F6 -176.9(7) . . . . ?
N1 S2 C26 F6 72.1(7) . . . . ?
O3 S2 C26 F5 67.0(9) . . . . ?
O4 S2 C26 F5 -61.5(9) . . . . ?
N1 S2 C26 F5 -172.6(8) . . . . ?
C21A P2 C17A C18A 35.5(10) . . . . ?
C13A P2 C17A C18A -73.4(10) . . . . ?
Pt1 P2 C17A C18A 165.1(9) . . . . ?
C21A P2 C17A C20A -86.5(9) . . . . ?
C13A P2 C17A C20A 164.6(9) . . . . ?
Pt1 P2 C17A C20A 43.1(9) . . . . ?
C21A P2 C17A C19A 158.6(7) . . . . ?
C13A P2 C17A C19A 49.7(8) . . . . ?
Pt1 P2 C17A C19A -71.8(7) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C24A^a H24C^a F4^a 0.96 2.50 3.208(14) 130.9 . yes

_refine_diff_density_max         1.275
_refine_diff_density_min         -2.502
_refine_diff_density_rms         0.130

