# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Eu-TPC
_database_code_depnum_ccdc_archive 'CCDC 1940497'
loop_
_audit_author_name
_audit_author_address
'Xiao-Dong Yang'
;Beijing Institute of Technology
China
;
_audit_update_record             
;
2019-07-15 deposited with the CCDC.	2019-10-01 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H47 Br Eu N5 O22'
_chemical_formula_sum            'C30 H47 Br Eu N5 O22'
_chemical_formula_weight         1061.59

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.5744(3)
_cell_length_b                   12.8702(6)
_cell_length_c                   18.8207(9)
_cell_angle_alpha                107.276(4)
_cell_angle_beta                 98.664(3)
_cell_angle_gamma                97.376(3)
_cell_volume                     2152.14(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    293
_cell_measurement_reflns_used    6650
_cell_measurement_theta_min      3.1252
_cell_measurement_theta_max      29.4562

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_F_000             1072
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_absorpt_coefficient_mu    2.471
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.87206
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.4170
_diffrn_reflns_number            20984
_diffrn_reflns_av_unetI/netI     0.0526
_diffrn_reflns_av_R_equivalents  0.0316
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.131
_diffrn_reflns_theta_max         29.522
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.849
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.849
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.849
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             10196
_reflns_number_gt                8409
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_structure_solution    'SHELXS-2016/6 (Sheldrick, 2016)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'DIAMOND. Version 3.0. Crystal Impact'
_computing_publication_material  'Windows Word 2010'
_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1005P)²+4.1709P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10196
_refine_ls_number_parameters     391
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0688
_refine_ls_R_factor_gt           0.0564
_refine_ls_wR_factor_ref         0.1673
_refine_ls_wR_factor_gt          0.1566
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.23418(2) 0.01062(2) -0.49746(2) 0.03010(10) Uani 1 1 d . . . . .
Br1 Br 1.4856(3) 0.1365(4) 0.1800(2) 0.297(2) Uani 1 1 d . . . . .
O1 O 0.4493(4) 0.0391(4) -0.4117(2) 0.0459(10) Uani 1 1 d . . . . .
O1W O 0.2970(6) -0.1732(5) -0.5117(4) 0.0730(16) Uani 1 1 d . . . . .
O2 O 0.6830(4) 0.0414(4) -0.3851(2) 0.0485(11) Uani 1 1 d . . . . .
O2W O 0.3921(5) 0.1801(4) -0.5004(3) 0.0605(13) Uani 1 1 d . . . . .
O3 O 0.8548(4) 0.0561(4) 0.4024(2) 0.0475(10) Uani 1 1 d . . . . .
O4 O 1.0946(4) 0.0983(4) 0.4324(2) 0.0488(11) Uani 1 1 d . . . . .
O5 O 0.7952(4) 0.8299(4) 0.3980(2) 0.0467(10) Uani 1 1 d . . . . .
O6 O 1.0301(5) 0.8804(4) 0.4286(2) 0.0511(11) Uani 1 1 d . . . . .
N1 N 0.5643(5) 0.1731(4) -0.1309(2) 0.0360(10) Uani 1 1 d . . . . .
N2 N 0.9907(5) 0.1354(4) 0.1779(3) 0.0406(11) Uani 1 1 d . . . . .
N3 N 0.9561(6) 0.5922(4) 0.1788(3) 0.0422(12) Uani 1 1 d . . . . .
C1 C 0.5643(5) 0.0552(5) -0.3675(3) 0.0307(10) Uani 1 1 d . . . . .
C2 C 0.5625(5) 0.0951(4) -0.2834(3) 0.0293(10) Uani 1 1 d . . . . .
C3 C 0.4384(6) 0.1146(5) -0.2578(3) 0.0404(13) Uani 1 1 d . . . . .
H3 H 0.350871 0.101918 -0.293105 0.048 Uiso 1 1 calc R U . . .
C4 C 0.6887(6) 0.1152(5) -0.2301(3) 0.0362(12) Uani 1 1 d . . . . .
H4 H 0.775675 0.100998 -0.246358 0.043 Uiso 1 1 calc R U . . .
C5 C 0.4405(6) 0.1526(6) -0.1811(3) 0.0432(14) Uani 1 1 d . . . . .
H5 H 0.354010 0.164423 -0.163553 0.052 Uiso 1 1 calc R U . . .
C6 C 0.6879(5) 0.1555(5) -0.1540(3) 0.0370(12) Uani 1 1 d . . . . .
H6 H 0.774616 0.171060 -0.117638 0.044 Uiso 1 1 calc R U . . .
C7 C 0.5588(7) 0.2130(7) -0.0477(3) 0.0517(17) Uani 1 1 d . . . . .
H7A H 0.507513 0.151521 -0.034590 0.062 Uiso 1 1 calc R U . . .
H7B H 0.502602 0.273423 -0.038474 0.062 Uiso 1 1 calc R U . . .
C8 C 0.7045(6) 0.2543(5) 0.0041(3) 0.0401(13) Uani 1 1 d . . . . .
C9 C 0.7767(6) 0.1807(5) 0.0286(3) 0.0364(12) Uani 1 1 d . . . . .
C10 C 0.7124(9) 0.0593(6) 0.0026(5) 0.068(2) Uani 1 1 d . . . . .
H10A H 0.609380 0.050240 0.003002 0.102 Uiso 1 1 calc R U . . .
H10B H 0.759622 0.024274 0.036878 0.102 Uiso 1 1 calc R U . . .
H10C H 0.726492 0.024277 -0.049042 0.102 Uiso 1 1 calc R U . . .
C11 C 0.9093(6) 0.2202(4) 0.0785(3) 0.0328(11) Uani 1 1 d . . . . .
C12 C 0.9956(7) 0.1397(5) 0.1005(4) 0.0429(13) Uani 1 1 d . . . . .
H12A H 0.958399 0.064724 0.063524 0.051 Uiso 1 1 calc R U . . .
H12B H 1.096932 0.161059 0.097309 0.051 Uiso 1 1 calc R U . . .
C13 C 0.9687(6) 0.3329(5) 0.1039(3) 0.0366(12) Uani 1 1 d . . . . .
C14 C 1.1112(8) 0.3746(7) 0.1598(5) 0.066(2) Uani 1 1 d . . . . .
H14A H 1.148634 0.311777 0.169765 0.099 Uiso 1 1 calc R U . . .
H14B H 1.097229 0.425502 0.207443 0.099 Uiso 1 1 calc R U . . .
H14C H 1.179953 0.413437 0.138413 0.099 Uiso 1 1 calc R U . . .
C15 C 0.8979(7) 0.4062(5) 0.0776(3) 0.0379(12) Uani 1 1 d . . . . .
C16 C 0.9693(8) 0.5256(5) 0.1008(4) 0.0518(17) Uani 1 1 d . . . . .
H16A H 1.072441 0.529207 0.098687 0.062 Uiso 1 1 calc R U . . .
H16B H 0.926019 0.559152 0.063807 0.062 Uiso 1 1 calc R U . . .
C17 C 0.7654(7) 0.3673(5) 0.0267(3) 0.0422(13) Uani 1 1 d . . . . .
C18 C 0.6864(11) 0.4461(7) -0.0035(5) 0.075(2) Uani 1 1 d . . . . .
H18A H 0.753108 0.515243 0.005613 0.112 Uiso 1 1 calc R U . . .
H18B H 0.606696 0.461847 0.022722 0.112 Uiso 1 1 calc R U . . .
H18C H 0.648769 0.411642 -0.058097 0.112 Uiso 1 1 calc R U . . .
C19 C 1.1090(7) 0.1205(6) 0.2184(4) 0.0509(16) Uani 1 1 d . . . . .
H19 H 1.194512 0.117784 0.198553 0.061 Uiso 1 1 calc R U . . .
C20 C 0.8689(6) 0.1360(6) 0.2033(3) 0.0454(14) Uani 1 1 d . . . . .
H20 H 0.786823 0.148559 0.173992 0.055 Uiso 1 1 calc R U . . .
C21 C 1.1074(6) 0.1090(6) 0.2888(4) 0.0496(16) Uani 1 1 d . . . . .
H21 H 1.193121 0.103211 0.318966 0.060 Uiso 1 1 calc R U . . .
C22 C 0.8591(6) 0.1188(6) 0.2710(3) 0.0442(14) Uani 1 1 d . . . . .
H22 H 0.769655 0.115632 0.287055 0.053 Uiso 1 1 calc R U . . .
C23 C 0.9794(6) 0.1060(5) 0.3155(3) 0.0360(11) Uani 1 1 d . . . . .
C24 C 0.9750(6) 0.0857(5) 0.3901(3) 0.0360(11) Uani 1 1 d . . . . .
C25 C 1.0740(8) 0.6550(6) 0.2277(4) 0.0577(19) Uani 1 1 d . . . . .
H25 H 1.165674 0.650353 0.214836 0.069 Uiso 1 1 calc R U . . .
C26 C 0.8274(7) 0.5972(6) 0.1966(4) 0.0505(16) Uani 1 1 d . . . . .
H26 H 0.745028 0.550740 0.161617 0.061 Uiso 1 1 calc R U . . .
C27 C 1.0635(7) 0.7262(6) 0.2964(4) 0.0542(17) Uani 1 1 d . . . . .
H27 H 1.148050 0.769380 0.331317 0.065 Uiso 1 1 calc R U . . .
C28 C 0.8101(7) 0.6676(5) 0.2641(4) 0.0480(15) Uani 1 1 d . . . . .
H28 H 0.717412 0.670172 0.275941 0.058 Uiso 1 1 calc R U . . .
C29 C 0.9323(6) 0.7353(5) 0.3149(3) 0.0366(12) Uani 1 1 d . . . . .
C30 C 0.9175(6) 0.8204(4) 0.3870(3) 0.0356(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.331(4) . ?
Eu1 O6 2.349(4) 1_444 ?
Eu1 O4 2.354(4) 1_454 ?
Eu1 O2 2.397(4) 2_654 ?
Eu1 O5 2.412(4) 2_665 ?
Eu1 O3 2.418(4) 2_655 ?
Eu1 O1W 2.463(6) . ?
Eu1 O2W 2.509(5) . ?
Eu1 C30 3.193(6) 2_665 ?
Eu1 Eu1 4.4421(5) 2_554 ?
O1 C1 1.229(6) . ?
O2 C1 1.251(6) . ?
O3 C24 1.243(7) . ?
O4 C24 1.254(6) . ?
O5 C30 1.234(7) . ?
O6 C30 1.243(7) . ?
N1 C6 1.343(7) . ?
N1 C5 1.342(7) . ?
N1 C7 1.508(7) . ?
N2 C20 1.325(8) . ?
N2 C19 1.334(8) . ?
N2 C12 1.482(8) . ?
N3 C26 1.330(8) . ?
N3 C25 1.336(8) . ?
N3 C16 1.498(7) . ?
C1 C2 1.516(7) . ?
C2 C3 1.373(7) . ?
C2 C4 1.391(7) . ?
C3 C5 1.376(7) . ?
C3 H3 0.9500 . ?
C4 C6 1.373(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.506(8) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.386(9) . ?
C8 C17 1.406(9) . ?
C9 C11 1.394(8) . ?
C9 C10 1.506(9) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C13 1.396(8) . ?
C11 C12 1.517(8) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C15 1.392(8) . ?
C13 C14 1.517(8) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C17 1.401(9) . ?
C15 C16 1.504(8) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.526(9) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C21 1.379(9) . ?
C19 H19 0.9500 . ?
C20 C22 1.371(8) . ?
C20 H20 0.9500 . ?
C21 C23 1.393(8) . ?
C21 H21 0.9500 . ?
C22 C23 1.377(8) . ?
C22 H22 0.9500 . ?
C23 C24 1.508(7) . ?
C25 C27 1.371(9) . ?
C25 H25 0.9500 . ?
C26 C28 1.369(8) . ?
C26 H26 0.9500 . ?
C27 C29 1.362(8) . ?
C27 H27 0.9500 . ?
C28 C29 1.396(8) . ?
C28 H28 0.9500 . ?
C29 C30 1.509(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O6 145.03(19) . 1_444 ?
O1 Eu1 O4 142.73(17) . 1_454 ?
O6 Eu1 O4 72.18(17) 1_444 1_454 ?
O1 Eu1 O2 100.15(13) . 2_654 ?
O6 Eu1 O2 81.93(15) 1_444 2_654 ?
O4 Eu1 O2 79.14(15) 1_454 2_654 ?
O1 Eu1 O5 80.14(15) . 2_665 ?
O6 Eu1 O5 119.24(15) 1_444 2_665 ?
O4 Eu1 O5 78.69(16) 1_454 2_665 ?
O2 Eu1 O5 142.12(17) 2_654 2_665 ?
O1 Eu1 O3 80.25(15) . 2_655 ?
O6 Eu1 O3 78.85(16) 1_444 2_655 ?
O4 Eu1 O3 121.35(14) 1_454 2_655 ?
O2 Eu1 O3 144.95(18) 2_654 2_655 ?
O5 Eu1 O3 72.83(16) 2_665 2_655 ?
O1 Eu1 O1W 73.42(18) . . ?
O6 Eu1 O1W 73.60(18) 1_444 . ?
O4 Eu1 O1W 139.15(18) 1_454 . ?
O2 Eu1 O1W 74.6(2) 2_654 . ?
O5 Eu1 O1W 138.81(19) 2_665 . ?
O3 Eu1 O1W 72.00(19) 2_655 . ?
O1 Eu1 O2W 72.23(17) . . ?
O6 Eu1 O2W 139.54(17) 1_444 . ?
O4 Eu1 O2W 71.92(16) 1_454 . ?
O2 Eu1 O2W 73.57(17) 2_654 . ?
O5 Eu1 O2W 70.53(17) 2_665 . ?
O3 Eu1 O2W 137.08(17) 2_655 . ?
O1W Eu1 O2W 127.27(18) . . ?
O1 Eu1 C30 96.99(14) . 2_665 ?
O6 Eu1 C30 99.42(15) 1_444 2_665 ?
O4 Eu1 C30 70.42(15) 1_454 2_665 ?
O2 Eu1 C30 147.28(16) 2_654 2_665 ?
O5 Eu1 C30 19.83(14) 2_665 2_665 ?
O3 Eu1 C30 65.51(15) 2_655 2_665 ?
O1W Eu1 C30 137.47(18) . 2_665 ?
O2W Eu1 C30 85.58(16) . 2_665 ?
O1 Eu1 Eu1 140.11(10) . 2_554 ?
O6 Eu1 Eu1 46.45(11) 1_444 2_554 ?
O4 Eu1 Eu1 58.74(11) 1_454 2_554 ?
O2 Eu1 Eu1 119.22(9) 2_654 2_554 ?
O5 Eu1 Eu1 72.82(10) 2_665 2_554 ?
O3 Eu1 Eu1 64.20(10) 2_655 2_554 ?
O1W Eu1 Eu1 109.36(13) . 2_554 ?
O2W Eu1 Eu1 122.70(12) . 2_554 ?
C30 Eu1 Eu1 53.02(10) 2_665 2_554 ?
C1 O1 Eu1 178.5(4) . . ?
C1 O2 Eu1 134.6(3) . 2_654 ?
C24 O3 Eu1 135.8(4) . 2_655 ?
C24 O4 Eu1 142.8(4) . 1_656 ?
C30 O5 Eu1 118.7(4) . 2_665 ?
C30 O6 Eu1 173.3(5) . 1_666 ?
C6 N1 C5 121.2(4) . . ?
C6 N1 C7 121.2(4) . . ?
C5 N1 C7 117.5(4) . . ?
C20 N2 C19 121.0(5) . . ?
C20 N2 C12 120.8(5) . . ?
C19 N2 C12 117.9(5) . . ?
C26 N3 C25 120.2(5) . . ?
C26 N3 C16 120.3(5) . . ?
C25 N3 C16 119.1(5) . . ?
O1 C1 O2 126.3(5) . . ?
O1 C1 C2 117.1(4) . . ?
O2 C1 C2 116.6(4) . . ?
C3 C2 C4 118.4(4) . . ?
C3 C2 C1 121.4(4) . . ?
C4 C2 C1 120.2(4) . . ?
C2 C3 C5 120.1(5) . . ?
C2 C3 H3 119.9 . . ?
C5 C3 H3 119.9 . . ?
C6 C4 C2 120.1(5) . . ?
C6 C4 H4 120.0 . . ?
C2 C4 H4 120.0 . . ?
N1 C5 C3 120.3(5) . . ?
N1 C5 H5 119.9 . . ?
C3 C5 H5 119.9 . . ?
N1 C6 C4 120.0(5) . . ?
N1 C6 H6 120.0 . . ?
C4 C6 H6 120.0 . . ?
N1 C7 C8 113.9(5) . . ?
N1 C7 H7A 108.8 . . ?
C8 C7 H7A 108.8 . . ?
N1 C7 H7B 108.8 . . ?
C8 C7 H7B 108.8 . . ?
H7A C7 H7B 107.7 . . ?
C9 C8 C17 120.9(5) . . ?
C9 C8 C7 119.7(6) . . ?
C17 C8 C7 119.4(6) . . ?
C8 C9 C11 119.3(5) . . ?
C8 C9 C10 120.6(6) . . ?
C11 C9 C10 120.0(6) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 C13 120.5(5) . . ?
C9 C11 C12 119.9(5) . . ?
C13 C11 C12 119.4(5) . . ?
N2 C12 C11 113.6(5) . . ?
N2 C12 H12A 108.8 . . ?
C11 C12 H12A 108.8 . . ?
N2 C12 H12B 108.8 . . ?
C11 C12 H12B 108.8 . . ?
H12A C12 H12B 107.7 . . ?
C15 C13 C11 120.0(5) . . ?
C15 C13 C14 120.3(6) . . ?
C11 C13 C14 119.7(6) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 C17 120.0(5) . . ?
C13 C15 C16 119.2(6) . . ?
C17 C15 C16 120.7(6) . . ?
N3 C16 C15 113.5(5) . . ?
N3 C16 H16A 108.9 . . ?
C15 C16 H16A 108.9 . . ?
N3 C16 H16B 108.9 . . ?
C15 C16 H16B 108.9 . . ?
H16A C16 H16B 107.7 . . ?
C15 C17 C8 119.1(5) . . ?
C15 C17 C18 120.9(6) . . ?
C8 C17 C18 119.9(6) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N2 C19 C21 120.2(6) . . ?
N2 C19 H19 119.9 . . ?
C21 C19 H19 119.9 . . ?
N2 C20 C22 121.2(5) . . ?
N2 C20 H20 119.4 . . ?
C22 C20 H20 119.4 . . ?
C19 C21 C23 119.7(5) . . ?
C19 C21 H21 120.2 . . ?
C23 C21 H21 120.2 . . ?
C20 C22 C23 119.7(5) . . ?
C20 C22 H22 120.2 . . ?
C23 C22 H22 120.2 . . ?
C22 C23 C21 118.1(5) . . ?
C22 C23 C24 122.1(5) . . ?
C21 C23 C24 119.8(5) . . ?
O3 C24 O4 127.0(5) . . ?
O3 C24 C23 117.1(5) . . ?
O4 C24 C23 115.8(5) . . ?
N3 C25 C27 120.5(6) . . ?
N3 C25 H25 119.8 . . ?
C27 C25 H25 119.8 . . ?
N3 C26 C28 121.9(6) . . ?
N3 C26 H26 119.1 . . ?
C28 C26 H26 119.1 . . ?
C29 C27 C25 120.2(6) . . ?
C29 C27 H27 119.9 . . ?
C25 C27 H27 119.9 . . ?
C26 C28 C29 118.3(6) . . ?
C26 C28 H28 120.9 . . ?
C29 C28 H28 120.9 . . ?
C27 C29 C28 118.8(5) . . ?
C27 C29 C30 121.0(5) . . ?
C28 C29 C30 120.1(5) . . ?
O5 C30 O6 124.9(5) . . ?
O5 C30 C29 118.1(5) . . ?
O6 C30 C29 116.9(5) . . ?
O5 C30 Eu1 41.5(3) . 2_665 ?
O6 C30 Eu1 83.7(3) . 2_665 ?
C29 C30 Eu1 157.2(4) . 2_665 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O2 C1 O1 3.5(10) 2_654 . . . ?
Eu1 O2 C1 C2 -176.9(4) 2_654 . . . ?
O1 C1 C2 C3 -1.4(9) . . . . ?
O2 C1 C2 C3 178.9(6) . . . . ?
O1 C1 C2 C4 -179.9(6) . . . . ?
O2 C1 C2 C4 0.4(8) . . . . ?
C4 C2 C3 C5 -0.3(9) . . . . ?
C1 C2 C3 C5 -178.9(6) . . . . ?
C3 C2 C4 C6 -1.2(9) . . . . ?
C1 C2 C4 C6 177.4(5) . . . . ?
C6 N1 C5 C3 -1.0(10) . . . . ?
C7 N1 C5 C3 -179.2(6) . . . . ?
C2 C3 C5 N1 1.5(10) . . . . ?
C5 N1 C6 C4 -0.5(10) . . . . ?
C7 N1 C6 C4 177.5(6) . . . . ?
C2 C4 C6 N1 1.6(9) . . . . ?
C6 N1 C7 C8 12.9(9) . . . . ?
C5 N1 C7 C8 -169.0(6) . . . . ?
N1 C7 C8 C9 -87.9(7) . . . . ?
N1 C7 C8 C17 92.0(7) . . . . ?
C17 C8 C9 C11 2.2(8) . . . . ?
C7 C8 C9 C11 -177.9(5) . . . . ?
C17 C8 C9 C10 -178.5(6) . . . . ?
C7 C8 C9 C10 1.4(8) . . . . ?
C8 C9 C11 C13 0.4(8) . . . . ?
C10 C9 C11 C13 -179.0(6) . . . . ?
C8 C9 C11 C12 -174.7(5) . . . . ?
C10 C9 C11 C12 5.9(8) . . . . ?
C20 N2 C12 C11 41.7(8) . . . . ?
C19 N2 C12 C11 -144.4(6) . . . . ?
C9 C11 C12 N2 -104.2(6) . . . . ?
C13 C11 C12 N2 80.6(7) . . . . ?
C9 C11 C13 C15 -2.2(8) . . . . ?
C12 C11 C13 C15 173.0(5) . . . . ?
C9 C11 C13 C14 178.3(6) . . . . ?
C12 C11 C13 C14 -6.5(8) . . . . ?
C11 C13 C15 C17 1.4(8) . . . . ?
C14 C13 C15 C17 -179.1(6) . . . . ?
C11 C13 C15 C16 -175.2(5) . . . . ?
C14 C13 C15 C16 4.3(8) . . . . ?
C26 N3 C16 C15 -56.4(9) . . . . ?
C25 N3 C16 C15 130.2(7) . . . . ?
C13 C15 C16 N3 -79.8(7) . . . . ?
C17 C15 C16 N3 103.7(7) . . . . ?
C13 C15 C17 C8 1.1(8) . . . . ?
C16 C15 C17 C8 177.6(5) . . . . ?
C13 C15 C17 C18 -179.5(6) . . . . ?
C16 C15 C17 C18 -3.0(9) . . . . ?
C9 C8 C17 C15 -2.9(8) . . . . ?
C7 C8 C17 C15 177.2(5) . . . . ?
C9 C8 C17 C18 177.7(6) . . . . ?
C7 C8 C17 C18 -2.3(8) . . . . ?
C20 N2 C19 C21 -2.1(11) . . . . ?
C12 N2 C19 C21 -176.0(6) . . . . ?
C19 N2 C20 C22 -1.6(11) . . . . ?
C12 N2 C20 C22 172.1(6) . . . . ?
N2 C19 C21 C23 4.1(11) . . . . ?
N2 C20 C22 C23 3.3(11) . . . . ?
C20 C22 C23 C21 -1.3(10) . . . . ?
C20 C22 C23 C24 -179.3(6) . . . . ?
C19 C21 C23 C22 -2.3(10) . . . . ?
C19 C21 C23 C24 175.8(6) . . . . ?
Eu1 O3 C24 O4 -7.1(10) 2_655 . . . ?
Eu1 O3 C24 C23 171.2(4) 2_655 . . . ?
Eu1 O4 C24 O3 50.0(10) 1_656 . . . ?
Eu1 O4 C24 C23 -128.3(5) 1_656 . . . ?
C22 C23 C24 O3 15.8(9) . . . . ?
C21 C23 C24 O3 -162.3(6) . . . . ?
C22 C23 C24 O4 -165.7(6) . . . . ?
C21 C23 C24 O4 16.2(9) . . . . ?
C26 N3 C25 C27 -0.7(11) . . . . ?
C16 N3 C25 C27 172.7(7) . . . . ?
C25 N3 C26 C28 1.4(11) . . . . ?
C16 N3 C26 C28 -172.0(6) . . . . ?
N3 C25 C27 C29 -1.4(12) . . . . ?
N3 C26 C28 C29 0.0(11) . . . . ?
C25 C27 C29 C28 2.7(11) . . . . ?
C25 C27 C29 C30 -174.4(7) . . . . ?
C26 C28 C29 C27 -2.0(10) . . . . ?
C26 C28 C29 C30 175.1(6) . . . . ?
Eu1 O5 C30 O6 8.5(8) 2_665 . . . ?
Eu1 O5 C30 C29 -166.9(4) 2_665 . . . ?
C27 C29 C30 O5 175.0(6) . . . . ?
C28 C29 C30 O5 -2.1(9) . . . . ?
C27 C29 C30 O6 -0.7(9) . . . . ?
C28 C29 C30 O6 -177.8(6) . . . . ?
C27 C29 C30 Eu1 152.2(8) . . . 2_665 ?
C28 C29 C30 Eu1 -24.9(13) . . . 2_665 ?

_refine_diff_density_max         3.994
_refine_diff_density_min         -2.886
_refine_diff_density_rms         0.145



