# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_20180983-fsj-1_0m
_database_code_depnum_ccdc_archive 'CCDC 1915232'
loop_
_audit_author_name
_audit_author_address
FL-cw
;SCUT
China
;
_audit_update_record             
;
2019-05-10 deposited with the CCDC.	2019-10-22 downloaded from the CCDC.
;
_audit_creation_date             2018-10-18
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C27 H43 F N O P Si'
_chemical_formula_sum            'C27 H43 F N O P Si'
_chemical_formula_weight         475.68
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.936(3)
_cell_length_b                   10.888(2)
_cell_length_c                   22.186(5)
_cell_angle_alpha                90
_cell_angle_beta                 95.814(6)
_cell_angle_gamma                90
_cell_volume                     2868.4(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9477
_cell_measurement_temperature    220
_cell_measurement_theta_max      70.06
_cell_measurement_theta_min      3.59
_shelx_estimated_absorpt_T_max   0.981
_shelx_estimated_absorpt_T_min   0.970
_exptl_absorpt_coefficient_mu    0.162
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.6591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.0896 before and 0.0745 after correction. The Ratio of minimum to maximum transmission is 0.8842. The λ/2 correction factor is 0.00150.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.102
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1032
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1142
_diffrn_reflns_av_unetI/netI     0.1418
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            15016
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.007
_diffrn_reflns_theta_max         25.007
_diffrn_reflns_theta_min         1.715
_diffrn_ambient_temperature      220.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2670
_reflns_number_total             5049
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.289
_refine_diff_density_min         -0.292
_refine_diff_density_rms         0.066
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.903
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     301
_refine_ls_number_reflns         5049
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1315
_refine_ls_R_factor_gt           0.0633
_refine_ls_restrained_S_all      0.903
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0483P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1297
_refine_ls_wR_factor_ref         0.1558
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C11(H11), C14(H14), C17(H17)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C4(H4), C6(H6)
2.c Idealised Me refined as rotating group:
 C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C15(H15A,H15B,H15C), C16(H16A,H16B,
 H16C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C22(H22A,
 H22B,H22C), C23(H23A,H23B,H23C), C25(H25A,H25B,H25C), C26(H26A,H26B,H26C),
 C27(H27A,H27B,H27C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.54708(8) 0.61870(8) 0.35069(4) 0.0284(3) Uani 1 1 d . . . . .
Si1 Si 0.90764(9) 0.29491(9) 0.37094(4) 0.0314(3) Uani 1 1 d . . . . .
F1 F 0.7656(2) 0.5420(2) 0.07413(9) 0.0640(7) Uani 1 1 d . . . . .
O1 O 0.6112(2) 0.5071(2) 0.36856(10) 0.0347(6) Uani 1 1 d . . . . .
N1 N 0.5420(2) 0.6426(3) 0.27383(12) 0.0321(8) Uani 1 1 d . . . . .
C1 C 0.4639(3) 0.7248(3) 0.24404(17) 0.0377(10) Uani 1 1 d . . . . .
H1 H 0.4082 0.7666 0.2630 0.045 Uiso 1 1 calc R . . . .
C2 C 0.4791(3) 0.7358(3) 0.18534(16) 0.0369(10) Uani 1 1 d . . . . .
H2 H 0.4359 0.7841 0.1566 0.044 Uiso 1 1 calc R . . . .
C3 C 0.5720(3) 0.6612(3) 0.17463(15) 0.0309(9) Uani 1 1 d . . . . .
C4 C 0.6228(3) 0.6424(3) 0.12191(16) 0.0409(10) Uani 1 1 d . . . . .
H4 H 0.5964 0.6818 0.0855 0.049 Uiso 1 1 calc R . . . .
C5 C 0.7125(4) 0.5644(4) 0.12493(16) 0.0388(10) Uani 1 1 d . . . . .
C6 C 0.7544(3) 0.5060(3) 0.17741(16) 0.0334(9) Uani 1 1 d . . . . .
H6 H 0.8173 0.4542 0.1768 0.040 Uiso 1 1 calc R . . . .
C7 C 0.7055(3) 0.5220(3) 0.23206(15) 0.0270(8) Uani 1 1 d . . . . .
C8 C 0.6122(3) 0.6025(3) 0.22963(14) 0.0266(8) Uani 1 1 d . . . . .
C9 C 0.7603(3) 0.4537(3) 0.28249(16) 0.0287(9) Uani 1 1 d . . . . .
C10 C 0.8165(3) 0.3903(3) 0.31773(16) 0.0334(9) Uani 1 1 d . . . . .
C11 C 0.9935(3) 0.4007(3) 0.42474(16) 0.0408(10) Uani 1 1 d . . . . .
H11 H 0.9449 0.4225 0.4567 0.049 Uiso 1 1 calc R . . . .
C12 C 1.0269(4) 0.5220(4) 0.39675(19) 0.0541(12) Uani 1 1 d . . . . .
H12A H 1.0796 0.5060 0.3672 0.081 Uiso 1 1 calc GR . . . .
H12B H 1.0620 0.5752 0.4283 0.081 Uiso 1 1 calc GR . . . .
H12C H 0.9603 0.5618 0.3770 0.081 Uiso 1 1 calc GR . . . .
C13 C 1.0993(4) 0.3378(4) 0.4574(2) 0.0713(16) Uani 1 1 d . . . . .
H13A H 1.0774 0.2625 0.4764 0.107 Uiso 1 1 calc GR . . . .
H13B H 1.1349 0.3927 0.4881 0.107 Uiso 1 1 calc GR . . . .
H13C H 1.1520 0.3189 0.4281 0.107 Uiso 1 1 calc GR . . . .
C14 C 0.9964(3) 0.1989(3) 0.32361(16) 0.0369(10) Uani 1 1 d . . . . .
H14 H 1.0466 0.1480 0.3517 0.044 Uiso 1 1 calc R . . . .
C15 C 1.0707(4) 0.2741(4) 0.28587(19) 0.0572(13) Uani 1 1 d . . . . .
H15A H 1.0240 0.3266 0.2584 0.086 Uiso 1 1 calc GR . . . .
H15B H 1.1142 0.2194 0.2628 0.086 Uiso 1 1 calc GR . . . .
H15C H 1.1214 0.3244 0.3124 0.086 Uiso 1 1 calc GR . . . .
C16 C 0.9242(4) 0.1116(4) 0.2824(2) 0.0647(14) Uani 1 1 d . . . . .
H16A H 0.8813 0.0589 0.3068 0.097 Uiso 1 1 calc GR . . . .
H16B H 0.9723 0.0617 0.2596 0.097 Uiso 1 1 calc GR . . . .
H16C H 0.8729 0.1588 0.2547 0.097 Uiso 1 1 calc GR . . . .
C17 C 0.8144(3) 0.1930(4) 0.41227(17) 0.0443(11) Uani 1 1 d . . . . .
H17 H 0.7610 0.1544 0.3808 0.053 Uiso 1 1 calc R . . . .
C18 C 0.7420(4) 0.2639(4) 0.45446(18) 0.0584(13) Uani 1 1 d . . . . .
H18A H 0.7897 0.2947 0.4891 0.088 Uiso 1 1 calc GR . . . .
H18B H 0.6856 0.2093 0.4682 0.088 Uiso 1 1 calc GR . . . .
H18C H 0.7050 0.3322 0.4325 0.088 Uiso 1 1 calc GR . . . .
C19 C 0.8772(4) 0.0862(4) 0.4473(2) 0.0757(16) Uani 1 1 d . . . . .
H19A H 0.9238 0.0435 0.4207 0.114 Uiso 1 1 calc GR . . . .
H19B H 0.8228 0.0295 0.4613 0.114 Uiso 1 1 calc GR . . . .
H19C H 0.9243 0.1188 0.4818 0.114 Uiso 1 1 calc GR . . . .
C20 C 0.6153(4) 0.7521(4) 0.45333(17) 0.0575(13) Uani 1 1 d . . . . .
H20A H 0.5404 0.7735 0.4632 0.086 Uiso 1 1 calc GR . . . .
H20B H 0.6695 0.8101 0.4725 0.086 Uiso 1 1 calc GR . . . .
H20C H 0.6341 0.6699 0.4679 0.086 Uiso 1 1 calc GR . . . .
C21 C 0.6185(3) 0.7565(3) 0.38422(16) 0.0376(10) Uani 1 1 d . . . . .
C22 C 0.5727(4) 0.8804(3) 0.3594(2) 0.0570(13) Uani 1 1 d . . . . .
H22A H 0.5787 0.8844 0.3162 0.085 Uiso 1 1 calc GR . . . .
H22B H 0.6160 0.9466 0.3796 0.085 Uiso 1 1 calc GR . . . .
H22C H 0.4943 0.8884 0.3668 0.085 Uiso 1 1 calc GR . . . .
C23 C 0.7413(3) 0.7436(4) 0.37026(19) 0.0559(12) Uani 1 1 d . . . . .
H23A H 0.7709 0.6653 0.3853 0.084 Uiso 1 1 calc GR . . . .
H23B H 0.7858 0.8096 0.3898 0.084 Uiso 1 1 calc GR . . . .
H23C H 0.7447 0.7479 0.3268 0.084 Uiso 1 1 calc GR . . . .
C24 C 0.3983(3) 0.5982(3) 0.36662(16) 0.0338(9) Uani 1 1 d . . . . .
C25 C 0.3418(3) 0.5132(3) 0.31683(19) 0.0509(12) Uani 1 1 d . . . . .
H25A H 0.3306 0.5578 0.2788 0.076 Uiso 1 1 calc GR . . . .
H25B H 0.2696 0.4858 0.3282 0.076 Uiso 1 1 calc GR . . . .
H25C H 0.3897 0.4426 0.3121 0.076 Uiso 1 1 calc GR . . . .
C26 C 0.3252(3) 0.7121(3) 0.37303(18) 0.0500(11) Uani 1 1 d . . . . .
H26A H 0.3615 0.7655 0.4041 0.075 Uiso 1 1 calc GR . . . .
H26B H 0.2521 0.6872 0.3843 0.075 Uiso 1 1 calc GR . . . .
H26C H 0.3156 0.7558 0.3348 0.075 Uiso 1 1 calc GR . . . .
C27 C 0.4047(4) 0.5279(4) 0.42758(19) 0.0575(13) Uani 1 1 d . . . . .
H27A H 0.4494 0.4541 0.4248 0.086 Uiso 1 1 calc GR . . . .
H27B H 0.3293 0.5056 0.4363 0.086 Uiso 1 1 calc GR . . . .
H27C H 0.4393 0.5799 0.4597 0.086 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.469(2) . ?
P1 N1 1.720(3) . ?
P1 C21 1.845(4) . ?
P1 C24 1.858(4) . ?
Si1 C10 1.843(4) . ?
Si1 C11 1.885(4) . ?
Si1 C14 1.882(4) . ?
Si1 C17 1.875(4) . ?
F1 C5 1.370(4) . ?
N1 C1 1.407(4) . ?
N1 C8 1.422(4) . ?
C1 H1 0.9400 . ?
C1 C2 1.338(5) . ?
C2 H2 0.9400 . ?
C2 C3 1.414(5) . ?
C3 C4 1.386(5) . ?
C3 C8 1.418(4) . ?
C4 H4 0.9400 . ?
C4 C5 1.362(5) . ?
C5 C6 1.376(5) . ?
C6 H6 0.9400 . ?
C6 C7 1.409(5) . ?
C7 C8 1.414(5) . ?
C7 C9 1.443(5) . ?
C9 C10 1.197(4) . ?
C11 H11 0.9900 . ?
C11 C12 1.529(5) . ?
C11 C13 1.551(5) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 H13C 0.9700 . ?
C14 H14 0.9900 . ?
C14 C15 1.520(5) . ?
C14 C16 1.523(5) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 H16C 0.9700 . ?
C17 H17 0.9900 . ?
C17 C18 1.544(5) . ?
C17 C19 1.548(5) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 H18C 0.9700 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C20 C21 1.538(5) . ?
C21 C22 1.537(5) . ?
C21 C23 1.534(5) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C22 H22C 0.9700 . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
C24 C25 1.543(5) . ?
C24 C26 1.532(5) . ?
C24 C27 1.549(5) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C25 H25C 0.9700 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C26 H26C 0.9700 . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 H27C 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 N1 110.99(14) . . ?
O1 P1 C21 110.91(15) . . ?
O1 P1 C24 109.33(15) . . ?
N1 P1 C21 104.19(16) . . ?
N1 P1 C24 105.55(15) . . ?
C21 P1 C24 115.63(17) . . ?
C10 Si1 C11 107.99(16) . . ?
C10 Si1 C14 106.55(16) . . ?
C10 Si1 C17 107.80(17) . . ?
C14 Si1 C11 113.09(18) . . ?
C17 Si1 C11 111.32(18) . . ?
C17 Si1 C14 109.83(17) . . ?
C1 N1 P1 121.2(2) . . ?
C1 N1 C8 106.3(3) . . ?
C8 N1 P1 132.3(2) . . ?
N1 C1 H1 124.3 . . ?
C2 C1 N1 111.5(3) . . ?
C2 C1 H1 124.3 . . ?
C1 C2 H2 126.3 . . ?
C1 C2 C3 107.3(3) . . ?
C3 C2 H2 126.3 . . ?
C2 C3 C8 108.5(3) . . ?
C4 C3 C2 130.1(3) . . ?
C4 C3 C8 121.4(3) . . ?
C3 C4 H4 121.3 . . ?
C5 C4 C3 117.4(3) . . ?
C5 C4 H4 121.3 . . ?
F1 C5 C6 117.1(4) . . ?
C4 C5 F1 119.8(3) . . ?
C4 C5 C6 123.1(3) . . ?
C5 C6 H6 119.2 . . ?
C5 C6 C7 121.6(3) . . ?
C7 C6 H6 119.2 . . ?
C6 C7 C8 115.9(3) . . ?
C6 C7 C9 114.2(3) . . ?
C8 C7 C9 129.9(3) . . ?
C3 C8 N1 106.4(3) . . ?
C7 C8 N1 133.0(3) . . ?
C7 C8 C3 120.6(3) . . ?
C10 C9 C7 169.6(4) . . ?
C9 C10 Si1 177.9(3) . . ?
Si1 C11 H11 106.2 . . ?
C12 C11 Si1 114.7(3) . . ?
C12 C11 H11 106.2 . . ?
C12 C11 C13 109.8(4) . . ?
C13 C11 Si1 113.0(3) . . ?
C13 C11 H11 106.2 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C11 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
C11 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si1 C14 H14 107.4 . . ?
C15 C14 Si1 113.6(3) . . ?
C15 C14 H14 107.4 . . ?
C15 C14 C16 109.4(3) . . ?
C16 C14 Si1 111.4(3) . . ?
C16 C14 H14 107.4 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si1 C17 H17 106.2 . . ?
C18 C17 Si1 113.4(3) . . ?
C18 C17 H17 106.2 . . ?
C18 C17 C19 110.1(3) . . ?
C19 C17 Si1 114.1(3) . . ?
C19 C17 H17 106.2 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C21 C20 H20A 109.5 . . ?
C21 C20 H20B 109.5 . . ?
C21 C20 H20C 109.5 . . ?
C20 C21 P1 108.6(3) . . ?
C22 C21 P1 115.9(3) . . ?
C22 C21 C20 109.9(3) . . ?
C23 C21 P1 104.8(3) . . ?
C23 C21 C20 108.6(3) . . ?
C23 C21 C22 108.7(3) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C24 P1 107.0(3) . . ?
C25 C24 C27 107.9(3) . . ?
C26 C24 P1 119.0(3) . . ?
C26 C24 C25 109.9(3) . . ?
C26 C24 C27 107.3(3) . . ?
C27 C24 P1 105.2(3) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C24 C27 H27A 109.5 . . ?
C24 C27 H27B 109.5 . . ?
C24 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
