# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_NC_Ag6
_database_code_depnum_ccdc_archive 'CCDC 1966339'
loop_
_audit_author_name
_audit_author_address
yangjinsen
;zzu
China
;
_audit_update_record             
;
2019-11-18 deposited with the CCDC.	2020-01-14 downloaded from the CCDC.
;
_audit_creation_date             2019-01-15
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)
;
_shelxl_version_number           2013-2
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C35 H23 Ag3 F9 N O6 P2, C H Cl3'
_chemical_formula_sum            'C36 H24 Ag3 Cl3 F9 N O6 P2'
_chemical_formula_weight         1229.46
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.39040(10)
_cell_length_b                   26.0236(2)
_cell_length_c                   13.09980(10)
_cell_angle_alpha                90
_cell_angle_beta                 94.1310(10)
_cell_angle_gamma                90
_cell_volume                     4212.96(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    12541
_cell_measurement_temperature    200.00(10)
_cell_measurement_theta_max      72.2630
_cell_measurement_theta_min      3.3990
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    14.319
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.42309
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.27b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.938
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2392
_exptl_crystal_size_max          0.01
_exptl_crystal_size_mid          0.006
_exptl_crystal_size_min          0.005
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_unetI/netI     0.0379
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            24591
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.726
_diffrn_reflns_theta_min         3.397
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      200.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -43.00  24.00   0.50    0.50    --   45.50 -57.00-120.00  134
  2  ω     20.00 130.00   0.50    0.50    --   45.50  57.00  60.00  220
  3  ω     96.00 133.00   0.50    0.50    --   45.50  57.00 -90.00   74
  4  ω    -42.00  42.00   0.50    0.50    --   45.50 -38.00 150.00  168
  5  ω     14.00 135.00   0.50    1.46    --  100.10 -45.00 120.00  242
  6  ω     11.00  88.00   0.50    1.46    --  100.10   0.00-150.00  154
  7  ω     32.00 122.00   0.50    1.46    --  100.10 -61.00 120.00  180
  8  ω     11.00  36.00   0.50    1.46    --  100.10 -77.00 150.00   50
  9  ω    103.00 183.00   0.50    1.46    --  100.10   0.00-150.00  160
 10  ω     68.00 106.00   0.50    1.46    --  100.10 -77.00 150.00   76
 11  ω     11.00 132.00   0.50    1.46    --  100.10 -45.00 -60.00  242
 12  ω     71.00 152.00   0.50    1.46    --  100.10  61.00 -90.00  162
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0483249000
_diffrn_orient_matrix_UB_12      0.0527082000
_diffrn_orient_matrix_UB_13      -0.0311312000
_diffrn_orient_matrix_UB_21      -0.0162294000
_diffrn_orient_matrix_UB_22      0.0118838000
_diffrn_orient_matrix_UB_23      0.1130927000
_diffrn_orient_matrix_UB_31      0.1137951000
_diffrn_orient_matrix_UB_32      0.0241193000
_diffrn_orient_matrix_UB_33      0.0122225000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7309
_reflns_number_total             8179
_reflns_odcompleteness_completeness 99.96
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.612
_refine_diff_density_min         -1.379
_refine_diff_density_rms         0.100
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         8179
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0410
_refine_ls_R_factor_gt           0.0365
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0472P)²+7.5182P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0943
_refine_ls_wR_factor_ref         0.0970
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C13) \\sim Ueq, Uanis(C11) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
3. Others
 Fixed Sof: F1(0.5) F1B(0.5) F2(0.5) F2B(0.5) F3(0.5) F3B(0.5) F4(0.5)
 F4B(0.5) F5(0.5) F5B(0.5) F6(0.5) F6B(0.5)
4.a Ternary CH refined with riding coordinates:
 C36(H36)
4.b Aromatic/amide H refined with riding coordinates:
 C8(H8), C9(H9), C10(H10), C11(H11), C12(H12), C14(H14), C15(H15), C16(H16),
 C17(H17), C18(H18), C20(H20), C21(H21), C22(H22), C25(H25), C26(H26), C27(H27),
  C28(H28), C29(H29), C31(H31), C32(H32), C33(H33), C34(H34), C35(H35)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.37690(2) 0.61824(2) 0.40779(2) 0.03472(9) Uani 1 1 d . . . . .
Ag2 Ag 0.42430(3) 0.49810(2) 0.25665(2) 0.04007(9) Uani 1 1 d . . . . .
Ag3 Ag 0.48109(2) 0.35830(2) 0.41304(2) 0.03825(9) Uani 1 1 d . . . . .
P1 P 0.45640(8) 0.41722(3) 0.18123(7) 0.02979(19) Uani 1 1 d . . . . .
P2 P 0.72846(7) 0.33857(3) 0.47175(7) 0.02950(19) Uani 1 1 d . . . . .
F1 F 0.1248(11) 0.6282(6) 0.183(2) 0.126(6) Uani 0.5 1 d . . P A 1
F1B F 0.200(2) 0.6523(7) 0.2417(10) 0.134(8) Uani 0.5 1 d . . P A 2
F2 F 0.2696(15) 0.6669(4) 0.2209(13) 0.105(5) Uani 0.5 1 d . . P A 1
F2B F 0.2726(16) 0.6643(6) 0.1045(18) 0.132(9) Uani 0.5 1 d . . P A 2
F3 F 0.223(2) 0.6507(7) 0.0708(9) 0.127(9) Uani 0.5 1 d . . P A 1
F3B F 0.1282(13) 0.6262(6) 0.104(2) 0.134(6) Uani 0.5 1 d . . P A 2
F4 F 0.4422(16) 0.2070(6) 0.635(2) 0.217(14) Uani 0.5 1 d . . P B 1
F4B F 0.4229(14) 0.2373(6) 0.7373(11) 0.088(6) Uani 0.5 1 d . . P B 2
F5 F 0.390(2) 0.2509(9) 0.7514(14) 0.165(11) Uani 0.5 1 d . . P B 1
F5B F 0.4147(14) 0.2061(4) 0.5945(10) 0.100(5) Uani 0.5 1 d . . P B 2
F6 F 0.2876(12) 0.2411(7) 0.6228(11) 0.080(5) Uani 0.5 1 d . . P B 1
F6B F 0.2863(12) 0.2473(9) 0.6420(16) 0.125(8) Uani 0.5 1 d . . P B 2
F7 F 0.7298(3) 0.48663(18) 0.5030(3) 0.0980(14) Uani 1 1 d . . . . .
F8 F 0.7539(3) 0.54808(15) 0.4001(4) 0.1052(15) Uani 1 1 d . . . . .
F9 F 0.6623(3) 0.48488(14) 0.3515(3) 0.0783(10) Uani 1 1 d . . . . .
O1 O 0.5912(4) 0.55876(14) 0.5537(2) 0.0621(10) Uani 1 1 d . . . . .
O2 O 0.5101(2) 0.55181(11) 0.3968(2) 0.0409(6) Uani 1 1 d . . . . .
O3 O 0.3298(3) 0.57203(11) 0.2550(2) 0.0445(7) Uani 1 1 d . . . . .
O4 O 0.2727(4) 0.55203(15) 0.0952(3) 0.0716(12) Uani 1 1 d . . . . .
O5 O 0.4030(3) 0.30470(17) 0.5142(3) 0.0680(11) Uani 1 1 d . . . . .
O6 O 0.5064(3) 0.31879(12) 0.6590(2) 0.0520(8) Uani 1 1 d . . . . .
N1 N 0.6157(3) 0.37668(11) 0.3087(2) 0.0289(6) Uani 1 1 d . . . . .
C1 C 0.2236(5) 0.6319(2) 0.1577(4) 0.0579(13) Uani 1 1 d . . . . .
C2 C 0.2817(3) 0.58056(16) 0.1695(3) 0.0379(9) Uani 1 1 d . . . . .
C3 C 0.6829(4) 0.51493(17) 0.4315(3) 0.0426(9) Uani 1 1 d . . . . .
C4 C 0.5840(3) 0.54439(14) 0.4645(3) 0.0348(8) Uani 1 1 d . . . . .
C5 C 0.3896(4) 0.2473(2) 0.6476(4) 0.0565(12) Uani 1 1 d . . . . .
C6 C 0.4386(4) 0.29601(17) 0.6035(3) 0.0430(10) Uani 1 1 d . . . . .
C7 C 0.3753(3) 0.36563(16) 0.2285(3) 0.0354(8) Uani 1 1 d . . . . .
C8 C 0.2773(4) 0.37819(19) 0.2690(3) 0.0447(10) Uani 1 1 d . . . . .
H8 H 0.2574 0.4125 0.2742 0.054 Uiso 1 1 calc R . . . .
C9 C 0.2098(4) 0.3402(2) 0.3015(4) 0.0595(13) Uani 1 1 d . . . . .
H9 H 0.1436 0.3489 0.3259 0.071 Uiso 1 1 calc R . . . .
C10 C 0.2402(5) 0.2896(2) 0.2977(4) 0.0624(14) Uani 1 1 d . . . . .
H10 H 0.1950 0.2642 0.3206 0.075 Uiso 1 1 calc R . . . .
C11 C 0.3375(4) 0.27615(19) 0.2600(4) 0.0540(12) Uani 1 1 d . U . . .
H11 H 0.3582 0.2418 0.2588 0.065 Uiso 1 1 calc R . . . .
C12 C 0.4043(4) 0.31365(16) 0.2240(3) 0.0423(9) Uani 1 1 d . . . . .
H12 H 0.4687 0.3043 0.1967 0.051 Uiso 1 1 calc R . . . .
C13 C 0.4394(3) 0.41174(15) 0.0428(3) 0.0340(8) Uani 1 1 d . U . . .
C14 C 0.3906(3) 0.45144(16) -0.0129(3) 0.0367(8) Uani 1 1 d . . . . .
H14 H 0.3688 0.4809 0.0202 0.044 Uiso 1 1 calc R . . . .
C15 C 0.3740(4) 0.44737(19) -0.1186(3) 0.0468(10) Uani 1 1 d . . . . .
H15 H 0.3409 0.4742 -0.1558 0.056 Uiso 1 1 calc R . . . .
C16 C 0.4058(4) 0.40422(19) -0.1689(3) 0.0463(10) Uani 1 1 d . . . . .
H16 H 0.3940 0.4018 -0.2396 0.056 Uiso 1 1 calc R . . . .
C17 C 0.4558(5) 0.36431(19) -0.1134(4) 0.0522(12) Uani 1 1 d . . . . .
H17 H 0.4780 0.3350 -0.1468 0.063 Uiso 1 1 calc R . . . .
C18 C 0.4722(4) 0.36824(17) -0.0087(3) 0.0477(11) Uani 1 1 d . . . . .
H18 H 0.5057 0.3414 0.0283 0.057 Uiso 1 1 calc R . . . .
C19 C 0.5953(3) 0.39615(13) 0.2133(3) 0.0302(7) Uani 1 1 d . . . . .
C20 C 0.6786(4) 0.40462(15) 0.1493(3) 0.0372(9) Uani 1 1 d . . . . .
H20 H 0.6639 0.4179 0.0839 0.045 Uiso 1 1 calc R . . . .
C21 C 0.7831(4) 0.39305(17) 0.1844(3) 0.0427(9) Uani 1 1 d . . . . .
H21 H 0.8395 0.3984 0.1425 0.051 Uiso 1 1 calc R . . . .
C22 C 0.8044(3) 0.37349(15) 0.2819(3) 0.0376(9) Uani 1 1 d . . . . .
H22 H 0.8748 0.3659 0.3067 0.045 Uiso 1 1 calc R . . . .
C23 C 0.7181(3) 0.36552(13) 0.3419(3) 0.0299(7) Uani 1 1 d . . . . .
C24 C 0.6874(3) 0.27237(14) 0.4486(3) 0.0318(8) Uani 1 1 d . . . . .
C25 C 0.6672(5) 0.25106(17) 0.3529(3) 0.0511(11) Uani 1 1 d . . . . .
H25 H 0.6713 0.2714 0.2949 0.061 Uiso 1 1 calc R . . . .
C26 C 0.6409(6) 0.1997(2) 0.3426(4) 0.0710(17) Uani 1 1 d . . . . .
H26 H 0.6272 0.1857 0.2776 0.085 Uiso 1 1 calc R . . . .
C27 C 0.6347(5) 0.16910(19) 0.4272(4) 0.0630(14) Uani 1 1 d . . . . .
H27 H 0.6179 0.1344 0.4197 0.076 Uiso 1 1 calc R . . . .
C28 C 0.6533(5) 0.18968(19) 0.5217(4) 0.0606(13) Uani 1 1 d . . . . .
H28 H 0.6504 0.1688 0.5790 0.073 Uiso 1 1 calc R . . . .
C29 C 0.6768(4) 0.24187(17) 0.5343(3) 0.0473(10) Uani 1 1 d . . . . .
H29 H 0.6852 0.2561 0.5995 0.057 Uiso 1 1 calc R . . . .
C30 C 0.8732(3) 0.33521(16) 0.5046(3) 0.0364(8) Uani 1 1 d . . . . .
C31 C 0.9351(4) 0.29190(19) 0.4889(4) 0.0470(10) Uani 1 1 d . . . . .
H31 H 0.9024 0.2622 0.4621 0.056 Uiso 1 1 calc R . . . .
C32 C 1.0463(4) 0.2930(2) 0.5135(4) 0.0605(14) Uani 1 1 d . . . . .
H32 H 1.0877 0.2638 0.5037 0.073 Uiso 1 1 calc R . . . .
C33 C 1.0951(4) 0.3370(3) 0.5523(4) 0.0667(15) Uani 1 1 d . . . . .
H33 H 1.1696 0.3378 0.5672 0.080 Uiso 1 1 calc R . . . .
C34 C 1.0343(5) 0.3795(3) 0.5690(5) 0.0727(17) Uani 1 1 d . . . . .
H34 H 1.0674 0.4092 0.5954 0.087 Uiso 1 1 calc R . . . .
C35 C 0.9225(4) 0.3783(2) 0.5465(5) 0.0590(13) Uani 1 1 d . . . . .
H35 H 0.8810 0.4070 0.5600 0.071 Uiso 1 1 calc R . . . .
Cl1 Cl 0.0831(3) 0.49072(16) 0.2970(3) 0.200(2) Uani 1 1 d . . . . .
Cl2 Cl 0.05236(18) 0.43772(10) 0.1092(2) 0.1166(7) Uani 1 1 d . . . . .
Cl3 Cl -0.09026(18) 0.52084(9) 0.1597(3) 0.1371(11) Uani 1 1 d . . . . .
C36 C 0.0470(7) 0.4944(4) 0.1672(8) 0.124(4) Uani 1 1 d . . . . .
H36 H 0.0953 0.5186 0.1355 0.148 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag3 2.8952(4) 3_666 ?
Ag1 P2 2.3989(9) 3_666 ?
Ag1 O2 2.401(3) . ?
Ag1 O3 2.372(3) . ?
Ag1 O6 2.392(3) 3_666 ?
Ag2 P1 2.3709(9) . ?
Ag2 O2 2.484(3) . ?
Ag2 O3 2.252(3) . ?
Ag3 Ag1 2.8952(4) 3_666 ?
Ag3 O1 2.389(3) 3_666 ?
Ag3 O5 2.196(3) . ?
Ag3 N1 2.282(3) . ?
Ag3 C7 2.673(4) . ?
P1 C7 1.812(4) . ?
P1 C13 1.816(4) . ?
P1 C19 1.826(4) . ?
P2 Ag1 2.3989(9) 3_666 ?
P2 C23 1.835(4) . ?
P2 C24 1.816(4) . ?
P2 C30 1.816(4) . ?
F1 C1 1.296(13) . ?
F1B C1 1.275(12) . ?
F2 C1 1.329(12) . ?
F2B C1 1.274(15) . ?
F3 C1 1.238(12) . ?
F3B C1 1.343(13) . ?
F4 C5 1.253(16) . ?
F4B C5 1.245(12) . ?
F5 C5 1.36(2) . ?
F5B C5 1.328(11) . ?
F6 C5 1.291(13) . ?
F6B C5 1.276(16) . ?
F7 C3 1.296(5) . ?
F8 C3 1.319(6) . ?
F9 C3 1.317(5) . ?
O1 Ag3 2.389(3) 3_666 ?
O1 C4 1.224(5) . ?
O2 C4 1.244(5) . ?
O3 C2 1.249(5) . ?
O4 C2 1.223(5) . ?
O5 C6 1.240(6) . ?
O6 Ag1 2.392(3) 3_666 ?
O6 C6 1.224(6) . ?
N1 C19 1.355(5) . ?
N1 C23 1.344(5) . ?
C1 C2 1.521(6) . ?
C3 C4 1.535(6) . ?
C5 C6 1.536(6) . ?
C7 C8 1.399(6) . ?
C7 C12 1.402(6) . ?
C8 H8 0.9300 . ?
C8 C9 1.383(7) . ?
C9 H9 0.9300 . ?
C9 C10 1.372(8) . ?
C10 H10 0.9300 . ?
C10 C11 1.380(8) . ?
C11 H11 0.9300 . ?
C11 C12 1.385(6) . ?
C12 H12 0.9300 . ?
C13 C14 1.380(6) . ?
C13 C18 1.393(6) . ?
C14 H14 0.9300 . ?
C14 C15 1.389(6) . ?
C15 H15 0.9300 . ?
C15 C16 1.374(7) . ?
C16 H16 0.9300 . ?
C16 C17 1.387(7) . ?
C17 H17 0.9300 . ?
C17 C18 1.376(6) . ?
C18 H18 0.9300 . ?
C19 C20 1.393(6) . ?
C20 H20 0.9300 . ?
C20 C21 1.375(6) . ?
C21 H21 0.9300 . ?
C21 C22 1.383(6) . ?
C22 H22 0.9300 . ?
C22 C23 1.388(5) . ?
C24 C25 1.378(6) . ?
C24 C29 1.388(6) . ?
C25 H25 0.9300 . ?
C25 C26 1.381(7) . ?
C26 H26 0.9300 . ?
C26 C27 1.371(8) . ?
C27 H27 0.9300 . ?
C27 C28 1.353(8) . ?
C28 H28 0.9300 . ?
C28 C29 1.396(7) . ?
C29 H29 0.9300 . ?
C30 C31 1.387(6) . ?
C30 C35 1.373(7) . ?
C31 H31 0.9300 . ?
C31 C32 1.392(7) . ?
C32 H32 0.9300 . ?
C32 C33 1.375(9) . ?
C33 H33 0.9300 . ?
C33 C34 1.364(9) . ?
C34 H34 0.9300 . ?
C34 C35 1.396(7) . ?
C35 H35 0.9300 . ?
Cl1 C36 1.729(11) . ?
Cl2 C36 1.664(11) . ?
Cl3 C36 1.831(10) . ?
C36 H36 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Ag1 Ag3 72.28(2) 3_666 3_666 ?
P2 Ag1 O2 141.78(7) 3_666 . ?
O2 Ag1 Ag3 79.65(7) . 3_666 ?
O3 Ag1 Ag3 152.79(7) . 3_666 ?
O3 Ag1 P2 132.86(8) . 3_666 ?
O3 Ag1 O2 73.31(10) . . ?
O3 Ag1 O6 99.04(11) . 3_666 ?
O6 Ag1 Ag3 78.69(8) 3_666 3_666 ?
O6 Ag1 P2 106.94(8) 3_666 3_666 ?
O6 Ag1 O2 92.03(12) 3_666 . ?
P1 Ag2 O2 137.03(7) . . ?
O3 Ag2 P1 149.01(8) . . ?
O3 Ag2 O2 73.80(10) . . ?
O1 Ag3 Ag1 82.86(9) 3_666 3_666 ?
O1 Ag3 C7 86.25(12) 3_666 . ?
O5 Ag3 Ag1 85.02(10) . 3_666 ?
O5 Ag3 O1 106.06(16) . 3_666 ?
O5 Ag3 N1 150.17(14) . . ?
O5 Ag3 C7 112.51(13) . . ?
N1 Ag3 Ag1 90.80(8) . 3_666 ?
N1 Ag3 O1 102.68(12) . 3_666 ?
N1 Ag3 C7 76.97(12) . . ?
C7 Ag3 Ag1 161.45(9) . 3_666 ?
C7 P1 Ag2 113.68(14) . . ?
C7 P1 C13 104.79(18) . . ?
C7 P1 C19 103.62(18) . . ?
C13 P1 Ag2 118.36(13) . . ?
C13 P1 C19 104.22(17) . . ?
C19 P1 Ag2 110.76(12) . . ?
C23 P2 Ag1 115.17(12) . 3_666 ?
C24 P2 Ag1 113.26(13) . 3_666 ?
C24 P2 C23 102.01(17) . . ?
C24 P2 C30 104.73(18) . . ?
C30 P2 Ag1 116.22(13) . 3_666 ?
C30 P2 C23 103.87(18) . . ?
C4 O1 Ag3 116.6(3) . 3_666 ?
Ag1 O2 Ag2 100.97(10) . . ?
C4 O2 Ag1 122.9(2) . . ?
C4 O2 Ag2 133.9(2) . . ?
Ag2 O3 Ag1 109.19(11) . . ?
C2 O3 Ag1 137.6(3) . . ?
C2 O3 Ag2 112.0(2) . . ?
C6 O5 Ag3 122.9(3) . . ?
C6 O6 Ag1 121.4(3) . 3_666 ?
C19 N1 Ag3 122.4(3) . . ?
C23 N1 Ag3 118.3(2) . . ?
C23 N1 C19 119.3(3) . . ?
F1 C1 F2 105.2(11) . . ?
F1 C1 C2 110.9(8) . . ?
F1B C1 F3B 104.6(12) . . ?
F1B C1 C2 114.5(7) . . ?
F2 C1 C2 111.1(6) . . ?
F2B C1 F1B 110.2(13) . . ?
F2B C1 F3B 102.8(11) . . ?
F2B C1 C2 113.4(9) . . ?
F3 C1 F1 108.9(12) . . ?
F3 C1 F2 106.1(12) . . ?
F3 C1 C2 114.2(8) . . ?
F3B C1 C2 110.3(7) . . ?
O3 C2 C1 116.0(4) . . ?
O4 C2 O3 128.0(4) . . ?
O4 C2 C1 115.9(4) . . ?
F7 C3 F8 108.8(5) . . ?
F7 C3 F9 106.8(4) . . ?
F7 C3 C4 113.9(4) . . ?
F8 C3 C4 109.0(4) . . ?
F9 C3 F8 103.7(4) . . ?
F9 C3 C4 114.1(4) . . ?
O1 C4 O2 129.3(4) . . ?
O1 C4 C3 114.7(4) . . ?
O2 C4 C3 116.0(4) . . ?
F4 C5 F5 103.2(16) . . ?
F4 C5 F6 111.8(15) . . ?
F4 C5 C6 114.6(8) . . ?
F4B C5 F5B 104.6(12) . . ?
F4B C5 F6B 108.5(13) . . ?
F4B C5 C6 114.5(8) . . ?
F5 C5 C6 110.2(10) . . ?
F5B C5 C6 110.8(7) . . ?
F6 C5 F5 101.1(13) . . ?
F6 C5 C6 114.5(8) . . ?
F6B C5 F5B 104.0(13) . . ?
F6B C5 C6 113.6(11) . . ?
O5 C6 C5 112.4(4) . . ?
O6 C6 O5 130.8(4) . . ?
O6 C6 C5 116.7(4) . . ?
P1 C7 Ag3 96.55(16) . . ?
C8 C7 Ag3 93.2(3) . . ?
C8 C7 P1 118.3(3) . . ?
C8 C7 C12 118.2(4) . . ?
C12 C7 Ag3 81.9(2) . . ?
C12 C7 P1 123.4(3) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 C7 120.7(5) . . ?
C9 C8 H8 119.6 . . ?
C8 C9 H9 119.9 . . ?
C10 C9 C8 120.1(5) . . ?
C10 C9 H9 119.9 . . ?
C9 C10 H10 119.8 . . ?
C9 C10 C11 120.4(5) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.2(5) . . ?
C12 C11 H11 119.9 . . ?
C7 C12 H12 119.8 . . ?
C11 C12 C7 120.3(4) . . ?
C11 C12 H12 119.8 . . ?
C14 C13 P1 119.0(3) . . ?
C14 C13 C18 119.0(4) . . ?
C18 C13 P1 122.0(3) . . ?
C13 C14 H14 120.1 . . ?
C13 C14 C15 119.9(4) . . ?
C15 C14 H14 120.1 . . ?
C14 C15 H15 119.6 . . ?
C16 C15 C14 120.9(4) . . ?
C16 C15 H15 119.6 . . ?
C15 C16 H16 120.2 . . ?
C15 C16 C17 119.6(4) . . ?
C17 C16 H16 120.2 . . ?
C16 C17 H17 120.2 . . ?
C18 C17 C16 119.6(4) . . ?
C18 C17 H17 120.2 . . ?
C13 C18 H18 119.5 . . ?
C17 C18 C13 121.1(4) . . ?
C17 C18 H18 119.5 . . ?
N1 C19 P1 115.7(3) . . ?
N1 C19 C20 121.1(4) . . ?
C20 C19 P1 122.8(3) . . ?
C19 C20 H20 120.5 . . ?
C21 C20 C19 119.0(4) . . ?
C21 C20 H20 120.5 . . ?
C20 C21 H21 119.9 . . ?
C20 C21 C22 120.1(4) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 H22 120.8 . . ?
C21 C22 C23 118.3(4) . . ?
C23 C22 H22 120.8 . . ?
N1 C23 P2 112.6(3) . . ?
N1 C23 C22 122.2(3) . . ?
C22 C23 P2 125.2(3) . . ?
C25 C24 P2 124.3(3) . . ?
C25 C24 C29 118.9(4) . . ?
C29 C24 P2 116.7(3) . . ?
C24 C25 H25 119.8 . . ?
C24 C25 C26 120.3(4) . . ?
C26 C25 H25 119.8 . . ?
C25 C26 H26 119.7 . . ?
C27 C26 C25 120.6(5) . . ?
C27 C26 H26 119.7 . . ?
C26 C27 H27 120.2 . . ?
C28 C27 C26 119.6(5) . . ?
C28 C27 H27 120.2 . . ?
C27 C28 H28 119.6 . . ?
C27 C28 C29 120.9(5) . . ?
C29 C28 H28 119.6 . . ?
C24 C29 C28 119.5(4) . . ?
C24 C29 H29 120.3 . . ?
C28 C29 H29 120.3 . . ?
C31 C30 P2 123.5(3) . . ?
C35 C30 P2 117.3(3) . . ?
C35 C30 C31 119.3(4) . . ?
C30 C31 H31 120.1 . . ?
C30 C31 C32 119.8(5) . . ?
C32 C31 H31 120.1 . . ?
C31 C32 H32 119.9 . . ?
C33 C32 C31 120.3(5) . . ?
C33 C32 H32 119.9 . . ?
C32 C33 H33 120.0 . . ?
C34 C33 C32 120.0(5) . . ?
C34 C33 H33 120.0 . . ?
C33 C34 H34 120.0 . . ?
C33 C34 C35 120.0(6) . . ?
C35 C34 H34 120.0 . . ?
C30 C35 C34 120.5(5) . . ?
C30 C35 H35 119.7 . . ?
C34 C35 H35 119.7 . . ?
Cl1 C36 Cl3 104.3(6) . . ?
Cl1 C36 H36 109.3 . . ?
Cl2 C36 Cl1 112.5(6) . . ?
Cl2 C36 Cl3 112.1(4) . . ?
Cl2 C36 H36 109.3 . . ?
Cl3 C36 H36 109.3 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.914
_oxdiff_exptl_absorpt_empirical_full_min 0.716
