# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_audit_block_doi                 10.5517/ccdc.csd.cc22j3nd
_database_code_depnum_ccdc_archive 'CCDC 1922113'
loop_
_audit_author_name
_audit_author_address
'Liu Wei'
;South China Agriculture University
China
;
_audit_update_record             
;
2019-06-10 deposited with the CCDC.	2019-09-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C20 H14 Ag N2 O2'
_chemical_formula_weight         422.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.2278(6)
_cell_length_b                   9.2785(8)
_cell_length_c                   11.2960(11)
_cell_angle_alpha                83.923(7)
_cell_angle_beta                 78.995(7)
_cell_angle_gamma                84.363(6)
_cell_volume                     839.05(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    6181
_cell_measurement_theta_min      5.060
_cell_measurement_theta_max      55.064

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            YELLOW
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.671
_exptl_crystal_F_000             422
_exptl_transmission_factor_min   0.737
_exptl_transmission_factor_max   0.798
_exptl_crystal_size_max          0.259
_exptl_crystal_size_mid          0.223
_exptl_crystal_size_min          0.186
_exptl_absorpt_coefficient_mu    1.216
_shelx_estimated_absorpt_T_min   0.744
_shelx_estimated_absorpt_T_max   0.805
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker AXS'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8811
_diffrn_reflns_av_unetI/netI     0.0622
_diffrn_reflns_av_R_equivalents  0.0935
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         1.844
_diffrn_reflns_theta_max         27.542
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.956
_diffrn_measured_fraction_theta_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.956
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.956
_diffrn_reflns_point_group_measured_fraction_full 0.974
_reflns_number_total             3701
_reflns_number_gt                3367
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0387P)²+1.0021P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3701
_refine_ls_number_parameters     226
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0377
_refine_ls_wR_factor_ref         0.0907
_refine_ls_wR_factor_gt          0.0874
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.04219(3) 0.08209(2) 0.10325(2) 0.01514(9) Uani 1 1 d . . . . .
O1 O 0.7888(3) 0.2248(2) 0.1205(2) 0.0203(5) Uani 1 1 d . . . . .
O2 O 0.8093(3) 0.1526(3) 0.3118(2) 0.0261(5) Uani 1 1 d . . . . .
N1 N 1.1680(3) 0.2008(3) -0.0684(2) 0.0138(5) Uani 1 1 d . . . . .
N2 N 1.8814(3) 0.1123(3) -0.2151(2) 0.0147(5) Uani 1 1 d . . . . .
C1 C 1.4214(4) 0.4282(3) -0.3913(2) 0.0124(6) Uani 1 1 d . . . . .
C2 C 1.5953(4) 0.4075(3) -0.4279(3) 0.0123(6) Uani 1 1 d . . . . .
C3 C 1.6698(4) 0.4794(3) -0.5362(3) 0.0129(6) Uani 1 1 d . . . . .
H3 H 1.7867 0.4647 -0.5613 0.015 Uiso 1 1 calc R U . . .
C4 C 1.3313(4) 0.3483(3) -0.2810(3) 0.0116(6) Uani 1 1 d . . . . .
C5 C 1.2057(4) 0.4192(3) -0.2012(3) 0.0167(6) Uani 1 1 d . . . . .
H5 H 1.1742 0.5195 -0.2177 0.020 Uiso 1 1 calc R U . . .
C6 C 1.1276(4) 0.3422(3) -0.0981(3) 0.0166(6) Uani 1 1 d . . . . .
H6 H 1.0410 0.3917 -0.0456 0.020 Uiso 1 1 calc R U . . .
C7 C 1.2854(4) 0.1318(3) -0.1466(3) 0.0147(6) Uani 1 1 d . . . . .
H7 H 1.3138 0.0314 -0.1277 0.018 Uiso 1 1 calc R U . . .
C8 C 1.3671(4) 0.1993(3) -0.2533(3) 0.0121(6) Uani 1 1 d . . . . .
H8 H 1.4468 0.1452 -0.3073 0.015 Uiso 1 1 calc R U . . .
C9 C 1.7026(4) 0.3117(3) -0.3548(3) 0.0127(6) Uani 1 1 d . . . . .
C10 C 1.6923(4) 0.3242(3) -0.2316(3) 0.0142(6) Uani 1 1 d . . . . .
H10 H 1.6250 0.4015 -0.1936 0.017 Uiso 1 1 calc R U . . .
C11 C 1.7819(4) 0.2219(3) -0.1653(3) 0.0148(6) Uani 1 1 d . . . . .
H11 H 1.7723 0.2299 -0.0810 0.018 Uiso 1 1 calc R U . . .
C12 C 1.8985(4) 0.1058(3) -0.3354(3) 0.0156(6) Uani 1 1 d . . . . .
H12 H 1.9735 0.0321 -0.3724 0.019 Uiso 1 1 calc R U . . .
C13 C 1.8112(4) 0.2022(3) -0.4074(3) 0.0150(6) Uani 1 1 d . . . . .
H13 H 1.8254 0.1935 -0.4919 0.018 Uiso 1 1 calc R U . . .
C14 C 0.7272(4) 0.1991(3) 0.2316(3) 0.0142(6) Uani 1 1 d . . . . .
C15 C 0.5399(4) 0.2207(3) 0.2671(3) 0.0156(6) Uani 1 1 d . . . . .
C16 C 0.4432(4) 0.2810(4) 0.1833(3) 0.0218(7) Uani 1 1 d . . . . .
H16 H 0.4948 0.3104 0.1029 0.026 Uiso 1 1 calc R U . . .
C17 C 0.2706(5) 0.2985(4) 0.2168(4) 0.0284(8) Uani 1 1 d . . . . .
H17 H 0.2048 0.3407 0.1596 0.034 Uiso 1 1 calc R U . . .
C18 C 0.1954(5) 0.2539(4) 0.3344(4) 0.0333(9) Uani 1 1 d . . . . .
H18 H 0.0779 0.2652 0.3574 0.040 Uiso 1 1 calc R U . . .
C19 C 0.2910(5) 0.1933(4) 0.4175(4) 0.0312(9) Uani 1 1 d . . . . .
H19 H 0.2394 0.1628 0.4976 0.037 Uiso 1 1 calc R U . . .
C20 C 0.4630(4) 0.1768(4) 0.3841(3) 0.0209(7) Uani 1 1 d . . . . .
H20 H 0.5284 0.1351 0.4417 0.025 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.201(3) 2_855 ?
Ag1 N1 2.247(2) . ?
Ag1 O1 2.344(2) . ?
Ag1 Ag1 3.1339(5) 2_755 ?
O1 C14 1.267(4) . ?
O2 C14 1.247(4) . ?
N1 C7 1.339(4) . ?
N1 C6 1.345(4) . ?
N2 C11 1.343(4) . ?
N2 C12 1.347(4) . ?
N2 Ag1 2.200(3) 2_855 ?
C1 C3 1.389(4) 2_864 ?
C1 C2 1.412(4) . ?
C1 C4 1.487(4) . ?
C2 C3 1.392(4) . ?
C2 C9 1.491(4) . ?
C3 C1 1.389(4) 2_864 ?
C3 H3 0.9500 . ?
C4 C5 1.396(4) . ?
C4 C8 1.399(4) . ?
C5 C6 1.381(4) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.383(4) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 C13 1.390(4) . ?
C9 C10 1.395(4) . ?
C10 C11 1.388(4) . ?
C10 H10 0.9500 . ?
C11 H11 0.9500 . ?
C12 C13 1.386(4) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C15 1.516(5) . ?
C15 C16 1.388(5) . ?
C15 C20 1.390(4) . ?
C16 C17 1.396(5) . ?
C16 H16 0.9500 . ?
C17 C18 1.393(6) . ?
C17 H17 0.9500 . ?
C18 C19 1.378(6) . ?
C18 H18 0.9500 . ?
C19 C20 1.391(5) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N1 132.89(10) 2_855 . ?
N2 Ag1 O1 130.38(9) 2_855 . ?
N1 Ag1 O1 96.63(9) . . ?
N2 Ag1 Ag1 96.76(7) 2_855 2_755 ?
N1 Ag1 Ag1 75.76(7) . 2_755 ?
O1 Ag1 Ag1 92.04(6) . 2_755 ?
C14 O1 Ag1 102.1(2) . . ?
C7 N1 C6 117.2(2) . . ?
C7 N1 Ag1 120.82(19) . . ?
C6 N1 Ag1 121.9(2) . . ?
C11 N2 C12 117.8(3) . . ?
C11 N2 Ag1 121.25(19) . 2_855 ?
C12 N2 Ag1 118.8(2) . 2_855 ?
C3 C1 C2 119.0(3) 2_864 . ?
C3 C1 C4 118.8(3) 2_864 . ?
C2 C1 C4 122.2(3) . . ?
C3 C2 C1 118.9(3) . . ?
C3 C2 C9 118.6(3) . . ?
C1 C2 C9 122.4(2) . . ?
C1 C3 C2 122.1(3) 2_864 . ?
C1 C3 H3 118.9 2_864 . ?
C2 C3 H3 118.9 . . ?
C5 C4 C8 117.2(3) . . ?
C5 C4 C1 121.1(3) . . ?
C8 C4 C1 121.7(3) . . ?
C6 C5 C4 119.4(3) . . ?
C6 C5 H5 120.3 . . ?
C4 C5 H5 120.3 . . ?
N1 C6 C5 123.3(3) . . ?
N1 C6 H6 118.3 . . ?
C5 C6 H6 118.3 . . ?
N1 C7 C8 123.3(3) . . ?
N1 C7 H7 118.3 . . ?
C8 C7 H7 118.3 . . ?
C7 C8 C4 119.4(3) . . ?
C7 C8 H8 120.3 . . ?
C4 C8 H8 120.3 . . ?
C13 C9 C10 118.1(3) . . ?
C13 C9 C2 120.2(3) . . ?
C10 C9 C2 121.6(3) . . ?
C11 C10 C9 119.0(3) . . ?
C11 C10 H10 120.5 . . ?
C9 C10 H10 120.5 . . ?
N2 C11 C10 122.8(3) . . ?
N2 C11 H11 118.6 . . ?
C10 C11 H11 118.6 . . ?
N2 C12 C13 122.7(3) . . ?
N2 C12 H12 118.6 . . ?
C13 C12 H12 118.6 . . ?
C12 C13 C9 119.3(3) . . ?
C12 C13 H13 120.4 . . ?
C9 C13 H13 120.4 . . ?
O2 C14 O1 124.6(3) . . ?
O2 C14 C15 118.5(3) . . ?
O1 C14 C15 116.9(3) . . ?
C16 C15 C20 119.4(3) . . ?
C16 C15 C14 120.9(3) . . ?
C20 C15 C14 119.7(3) . . ?
C15 C16 C17 120.3(3) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 119.7(4) . . ?
C18 C17 H17 120.1 . . ?
C16 C17 H17 120.1 . . ?
C19 C18 C17 120.1(4) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C18 C19 C20 120.0(4) . . ?
C18 C19 H19 120.0 . . ?
C20 C19 H19 120.0 . . ?
C15 C20 C19 120.5(3) . . ?
C15 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C3 C1 C2 C3 -0.6(5) 2_864 . . . ?
C4 C1 C2 C3 176.1(3) . . . . ?
C3 C1 C2 C9 179.2(3) 2_864 . . . ?
C4 C1 C2 C9 -4.1(4) . . . . ?
C1 C2 C3 C1 0.6(5) . . . 2_864 ?
C9 C2 C3 C1 -179.2(3) . . . 2_864 ?
C3 C1 C4 C5 -46.4(4) 2_864 . . . ?
C2 C1 C4 C5 136.9(3) . . . . ?
C3 C1 C4 C8 132.9(3) 2_864 . . . ?
C2 C1 C4 C8 -43.8(4) . . . . ?
C8 C4 C5 C6 2.3(5) . . . . ?
C1 C4 C5 C6 -178.4(3) . . . . ?
C7 N1 C6 C5 -2.9(5) . . . . ?
Ag1 N1 C6 C5 178.2(2) . . . . ?
C4 C5 C6 N1 1.1(5) . . . . ?
C6 N1 C7 C8 1.2(5) . . . . ?
Ag1 N1 C7 C8 -179.8(2) . . . . ?
N1 C7 C8 C4 2.2(5) . . . . ?
C5 C4 C8 C7 -3.8(4) . . . . ?
C1 C4 C8 C7 176.9(3) . . . . ?
C3 C2 C9 C13 -53.5(4) . . . . ?
C1 C2 C9 C13 126.6(3) . . . . ?
C3 C2 C9 C10 129.5(3) . . . . ?
C1 C2 C9 C10 -50.4(4) . . . . ?
C13 C9 C10 C11 -4.1(4) . . . . ?
C2 C9 C10 C11 173.0(3) . . . . ?
C12 N2 C11 C10 2.5(4) . . . . ?
Ag1 N2 C11 C10 -160.6(2) 2_855 . . . ?
C9 C10 C11 N2 1.4(5) . . . . ?
C11 N2 C12 C13 -3.6(4) . . . . ?
Ag1 N2 C12 C13 159.9(2) 2_855 . . . ?
N2 C12 C13 C9 0.8(5) . . . . ?
C10 C9 C13 C12 3.1(4) . . . . ?
C2 C9 C13 C12 -174.0(3) . . . . ?
Ag1 O1 C14 O2 21.6(4) . . . . ?
Ag1 O1 C14 C15 -155.7(2) . . . . ?
O2 C14 C15 C16 175.8(3) . . . . ?
O1 C14 C15 C16 -6.7(4) . . . . ?
O2 C14 C15 C20 -5.7(4) . . . . ?
O1 C14 C15 C20 171.8(3) . . . . ?
C20 C15 C16 C17 0.6(5) . . . . ?
C14 C15 C16 C17 179.1(3) . . . . ?
C15 C16 C17 C18 -0.7(5) . . . . ?
C16 C17 C18 C19 0.3(6) . . . . ?
C17 C18 C19 C20 0.1(6) . . . . ?
C16 C15 C20 C19 -0.2(5) . . . . ?
C14 C15 C20 C19 -178.8(3) . . . . ?
C18 C19 C20 C15 -0.1(6) . . . . ?

_refine_diff_density_max         0.585
_refine_diff_density_min         -1.457
_refine_diff_density_rms         0.145

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_audit_block_doi                 10.5517/ccdc.csd.cc22j3qg
_database_code_depnum_ccdc_archive 'CCDC 1922115'
loop_
_audit_author_name
_audit_author_address
'Liu Wei'
;South China Agriculture University
China
;
_audit_update_record             
;
2019-06-10 deposited with the CCDC.	2019-09-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C129 H93 Ag6 N19 O14'
_chemical_formula_weight         2780.44

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.8004(6)
_cell_length_b                   17.5129(6)
_cell_length_c                   18.7660(8)
_cell_angle_alpha                67.675(4)
_cell_angle_beta                 76.215(4)
_cell_angle_gamma                68.734(4)
_cell_volume                     3883.2(3)
_cell_formula_units_Z            1
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    16148
_cell_measurement_theta_min      4.605
_cell_measurement_theta_max      52.568

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            'PALE YELLOW'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.189
_exptl_crystal_F_000             1394
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.140
_exptl_crystal_size_mid          0.109
_exptl_crystal_size_min          0.063
_exptl_absorpt_coefficient_mu    0.796
_shelx_estimated_absorpt_T_min   0.897
_shelx_estimated_absorpt_T_max   0.952
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker AXS'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            74961
_diffrn_reflns_av_unetI/netI     0.0897
_diffrn_reflns_av_R_equivalents  0.0935
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.181
_diffrn_reflns_theta_max         27.546
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.972
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             17432
_reflns_number_gt                11578
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0637P)²+17.2284P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17432
_refine_ls_number_parameters     799
_refine_ls_number_restraints     66
_refine_ls_R_factor_all          0.1123
_refine_ls_R_factor_gt           0.0688
_refine_ls_wR_factor_ref         0.1681
_refine_ls_wR_factor_gt          0.1516
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.95324(3) 0.65337(2) 0.75535(2) 0.02251(11) Uani 1 1 d . . . . .
Ag3 Ag 0.50501(4) -0.12660(3) 1.27642(2) 0.03369(13) Uani 1 1 d . . . . .
Ag1 Ag 1.02855(4) 0.80633(4) 0.25593(3) 0.0626(2) Uani 1 1 d . . . . .
N5 N 0.8807(3) 0.5404(3) 0.8196(3) 0.0250(10) Uani 1 1 d . . . . .
N9 N 0.4464(4) -0.1612(3) 1.4031(3) 0.0255(10) Uani 1 1 d . . . . .
N4 N 0.8709(4) 0.8663(3) 0.3191(3) 0.0338(11) Uani 1 1 d . . . . .
O1 O 0.6115(3) -0.2728(3) 1.3424(2) 0.0378(10) Uani 1 1 d . . . . .
N3 N 0.8281(4) 0.7486(3) 0.6757(3) 0.0323(11) Uani 1 1 d . . . . .
C33 C 0.7438(4) 0.2813(4) 0.9174(3) 0.0270(12) Uani 1 1 d . . . . .
H33 H 0.7341 0.3120 0.8644 0.032 Uiso 1 1 calc R U . . .
N6 N 0.9742(4) 0.3146(3) 1.1675(3) 0.0316(11) Uani 1 1 d . . . . .
N2 N 1.1074(3) 0.6068(3) 0.6744(2) 0.0231(9) Uani 1 1 d . . . . .
O2 O 0.6556(3) -0.3541(3) 1.4622(3) 0.0435(11) Uani 1 1 d . . . . .
C37 C 0.8124(4) 0.2624(4) 1.0311(3) 0.0266(12) Uani 1 1 d . . . . .
C28 C 0.8812(5) 0.3985(4) 0.8339(3) 0.0277(12) Uani 1 1 d . . . . .
H28 H 0.9008 0.3534 0.8120 0.033 Uiso 1 1 calc R U . . .
C40 C 0.8683(5) 0.2830(4) 1.0761(3) 0.0281(12) Uani 1 1 d . . . . .
C58 C 0.5977(4) -0.2920(4) 1.4152(3) 0.0302(13) Uani 1 1 d . . . . .
N1 N 1.1686(3) 0.7167(3) 0.3147(3) 0.0310(11) Uani 1 1 d . . . . .
C4 C 1.2443(4) 0.5889(4) 0.4166(3) 0.0278(12) Uani 1 1 d . . . . .
H4 H 1.2385 0.5356 0.4542 0.033 Uiso 1 1 calc R U . . .
C7 C 1.3994(4) 0.5269(3) 0.5385(3) 0.0199(10) Uani 1 1 d . . . . .
C3 C 1.3296(4) 0.6155(3) 0.4097(3) 0.0200(10) Uani 1 1 d . . . . .
C11 C 1.2969(4) 0.5552(3) 0.5838(3) 0.0192(10) Uani 1 1 d . . . . .
C36 C 0.7734(4) 0.1914(4) 1.0701(3) 0.0307(13) Uani 1 1 d . . . . .
H36 H 0.7849 0.1597 1.1227 0.037 Uiso 1 1 calc R U . . .
C34 C 0.7046(5) 0.2117(4) 0.9556(3) 0.0300(13) Uani 1 1 d . . . . .
C10 C 1.2437(4) 0.6420(3) 0.5732(3) 0.0240(11) Uani 1 1 d . . . . .
H10 H 1.2707 0.6854 0.5344 0.029 Uiso 1 1 calc R U . . .
C50 C 0.6523(4) 0.1882(3) 0.9096(3) 0.0269(12) Uani 1 1 d . . . . .
N7 N 0.5813(4) -0.0293(3) 1.1899(3) 0.0418(14) Uani 1 1 d . . . . .
C53 C 0.5017(4) -0.2354(3) 1.4507(3) 0.0257(12) Uani 1 1 d . . . . .
C20 C 0.5950(4) 0.9683(3) 0.4574(3) 0.0240(11) Uani 1 1 d . . . . .
C12 C 1.2523(4) 0.4947(3) 0.6412(3) 0.0225(11) Uani 1 1 d . . . . .
H12 H 1.2861 0.4345 0.6505 0.027 Uiso 1 1 calc R U . . .
C26 C 0.8358(5) 0.9513(4) 0.3115(3) 0.0338(13) Uani 1 1 d . . . . .
H26 H 0.8741 0.9882 0.2751 0.041 Uiso 1 1 calc R U . . .
C13 C 1.1596(4) 0.5226(3) 0.6842(3) 0.0273(12) Uani 1 1 d . . . . .
H13 H 1.1306 0.4804 0.7229 0.033 Uiso 1 1 calc R U . . .
C21 C 0.5125(4) 1.0359(4) 0.4206(3) 0.0284(12) Uani 1 1 d . . . . .
H21 H 0.5213 1.0610 0.3658 0.034 Uiso 1 1 calc R U . . .
N8 N 0.5650(4) 0.1513(3) 0.8113(3) 0.0314(11) Uani 1 1 d . . . . .
C32 C 0.7969(4) 0.3080(4) 0.9535(3) 0.0267(12) Uani 1 1 d . . . . .
C2 C 1.3325(4) 0.6955(4) 0.3535(3) 0.0259(12) Uani 1 1 d . . . . .
H2 H 1.3897 0.7166 0.3464 0.031 Uiso 1 1 calc R U . . .
C51 C 0.5691(4) 0.2502(4) 0.8689(3) 0.0285(12) Uani 1 1 d . . . . .
H51 H 0.5408 0.3063 0.8742 0.034 Uiso 1 1 calc R U . . .
C6 C 1.4165(4) 0.5591(3) 0.4576(3) 0.0192(10) Uani 1 1 d . . . . .
C29 C 0.8274(4) 0.3885(3) 0.9085(3) 0.0246(11) Uani 1 1 d . . . . .
C17 C 0.7661(4) 0.8788(3) 0.5722(3) 0.0286(13) Uani 1 1 d . . . . .
H17 H 0.7802 0.9281 0.5324 0.034 Uiso 1 1 calc R U . . .
C41 C 0.8241(5) 0.2887(4) 1.1494(3) 0.0382(15) Uani 1 1 d . . . . .
H41 H 0.7568 0.2815 1.1698 0.046 Uiso 1 1 calc R U . . .
C18 C 0.8419(4) 0.8196(4) 0.6193(3) 0.0337(14) Uani 1 1 d . . . . .
H18 H 0.9072 0.8300 0.6111 0.040 Uiso 1 1 calc R U . . .
C38 C 1.0173(5) 0.3092(4) 1.0968(3) 0.0324(13) Uani 1 1 d . . . . .
H38 H 1.0848 0.3161 1.0779 0.039 Uiso 1 1 calc R U . . .
C54 C 0.4747(5) -0.2605(4) 1.5311(3) 0.0300(12) Uani 1 1 d . . . . .
H54 H 0.5162 -0.3129 1.5635 0.036 Uiso 1 1 calc R U . . .
C25 C 0.7478(4) 0.9864(3) 0.3539(3) 0.0286(12) Uani 1 1 d . . . . .
H25 H 0.7249 1.0467 0.3463 0.034 Uiso 1 1 calc R U . . .
C35 C 0.7187(4) 0.1660(4) 1.0345(3) 0.0274(12) Uani 1 1 d . . . . .
C30 C 0.8009(4) 0.4567(4) 0.9366(3) 0.0281(12) Uani 1 1 d . . . . .
H30 H 0.7637 0.4532 0.9867 0.034 Uiso 1 1 calc R U . . .
C9 C 1.1508(4) 0.6651(3) 0.6194(3) 0.0263(12) Uani 1 1 d . . . . .
H9 H 1.1160 0.7249 0.6119 0.032 Uiso 1 1 calc R U . . .
C44 C 0.7313(5) 0.0191(4) 1.1329(3) 0.0337(14) Uani 1 1 d . . . . .
H44 H 0.8042 0.0084 1.1316 0.040 Uiso 1 1 calc R U . . .
C27 C 0.9054(4) 0.4742(3) 0.7925(3) 0.0271(12) Uani 1 1 d . . . . .
H27 H 0.9417 0.4799 0.7418 0.033 Uiso 1 1 calc R U . . .
C52 C 0.5290(5) 0.2286(4) 0.8214(3) 0.0333(14) Uani 1 1 d . . . . .
H52 H 0.4725 0.2711 0.7941 0.040 Uiso 1 1 calc R U . . .
C15 C 0.6544(4) 0.7916(4) 0.6411(3) 0.0362(14) Uani 1 1 d . . . . .
H15 H 0.5896 0.7799 0.6506 0.043 Uiso 1 1 calc R U . . .
C5 C 1.1666(5) 0.6409(4) 0.3680(3) 0.0343(14) Uani 1 1 d . . . . .
H5 H 1.1088 0.6211 0.3733 0.041 Uiso 1 1 calc R U . . .
C16 C 0.6688(4) 0.8658(3) 0.5832(3) 0.0274(12) Uani 1 1 d . . . . .
C22 C 0.8160(5) 0.8153(4) 0.3699(3) 0.0334(13) Uani 1 1 d . . . . .
H22 H 0.8404 0.7546 0.3762 0.040 Uiso 1 1 d R U . . .
O4 O 0.2685(5) -0.1929(3) 1.6737(3) 0.0596(14) Uani 1 1 d . . . . .
C24 C 0.6911(4) 0.9330(3) 0.4087(3) 0.0255(12) Uani 1 1 d . . . . .
C19 C 0.5829(4) 0.9321(3) 0.5377(3) 0.0252(12) Uani 1 1 d . . . . .
C1 C 1.2513(4) 0.7428(4) 0.3086(3) 0.0326(14) Uani 1 1 d . . . . .
H1 H 1.2540 0.7970 0.2713 0.039 Uiso 1 1 calc R U . . .
C43 C 0.6835(5) -0.0413(4) 1.1843(3) 0.0381(15) Uani 1 1 d . . . . .
H43 H 0.7252 -0.0935 1.2168 0.046 Uiso 1 1 calc R U . . .
C49 C 0.6877(5) 0.1074(4) 0.9011(4) 0.0373(15) Uani 1 1 d . . . . .
H49 H 0.7422 0.0627 0.9290 0.045 Uiso 1 1 calc R U . . .
C8 C 1.4837(4) 0.4664(3) 0.5797(3) 0.0188(10) Uani 1 1 d . . . . .
H8 H 1.4718 0.4424 0.6345 0.023 Uiso 1 1 calc R U . . .
C45 C 0.6733(5) 0.0954(4) 1.0834(3) 0.0321(13) Uani 1 1 d . . . . .
C42 C 0.8787(5) 0.3049(4) 1.1926(3) 0.0352(14) Uani 1 1 d . . . . .
H42 H 0.8468 0.3093 1.2423 0.042 Uiso 1 1 calc R U . . .
C31 C 0.8292(5) 0.5299(4) 0.8908(3) 0.0300(13) Uani 1 1 d . . . . .
H31 H 0.8108 0.5759 0.9114 0.036 Uiso 1 1 calc R U . . .
C55 C 0.3876(5) -0.2090(4) 1.5632(3) 0.0341(14) Uani 1 1 d . . . . .
C39 C 0.9668(5) 0.2939(4) 1.0504(3) 0.0308(13) Uani 1 1 d . . . . .
H39 H 0.9999 0.2908 1.0006 0.037 Uiso 1 1 calc R U . . .
C57 C 0.3619(5) -0.1109(4) 1.4342(3) 0.0356(14) Uani 1 1 d . . . . .
H57 H 0.3225 -0.0580 1.4009 0.043 Uiso 1 1 calc R U . . .
C56 C 0.3302(5) -0.1336(4) 1.5131(3) 0.0337(13) Uani 1 1 d . . . . .
H56 H 0.2688 -0.0971 1.5330 0.040 Uiso 1 1 calc R U . . .
C23 C 0.7270(5) 0.8467(4) 0.4164(3) 0.0319(13) Uani 1 1 d . . . . .
H23 H 0.6912 0.8083 0.4534 0.038 Uiso 1 1 calc R U . . .
C14 C 0.7348(4) 0.7348(4) 0.6849(4) 0.0370(15) Uani 1 1 d . . . . .
H14 H 0.7241 0.6834 0.7233 0.044 Uiso 1 1 calc R U . . .
C47 C 0.5257(6) 0.0439(5) 1.1413(4) 0.060(2) Uani 1 1 d . . . . .
H47 H 0.4528 0.0530 1.1445 0.072 Uiso 1 1 calc R U . . .
C59 C 0.3561(6) -0.2329(5) 1.6506(4) 0.0501(18) Uani 1 1 d . . . . .
C48 C 0.6427(5) 0.0920(4) 0.8511(4) 0.0382(15) Uani 1 1 d . . . . .
H48 H 0.6686 0.0364 0.8451 0.046 Uiso 1 1 calc R U . . .
O3 O 0.4290(6) -0.2898(5) 1.6912(3) 0.111(3) Uani 1 1 d . U . . .
O5 O 1.0820(9) 0.9557(7) 0.2240(6) 0.063(2) Uani 0.5 1 d . U P . .
C68 C 0.8574(4) 0.5892(3) 0.4709(3) 0.0179(10) Uani 1 1 d . . . . .
H68A H 0.8857 0.5286 0.4764 0.021 Uiso 1 1 d R U . . .
H68B H 0.8948 0.6211 0.4263 0.021 Uiso 1 1 d R U . . .
H68C H 0.7854 0.6082 0.4618 0.021 Uiso 1 1 d R U . . .
O9 O 0.9587(7) 0.6224(7) 0.5347(5) 0.138(3) Uani 1 1 d . . . . .
H9A H 0.9613 0.6311 0.5751 0.208 Uiso 1 1 calc R U . . .
C67 C 0.8610(6) 0.6042(5) 0.5412(5) 0.060(2) Uani 1 1 d . . . . .
H67A H 0.8561 0.5547 0.5859 0.072 Uiso 1 1 d R U . . .
H67B H 0.8027 0.6532 0.5475 0.072 Uiso 1 1 d R U . . .
C46 C 0.5665(5) 0.1066(5) 1.0872(4) 0.052(2) Uani 1 1 d . . . . .
H46 H 0.5235 0.1564 1.0532 0.063 Uiso 1 1 calc R U . . .
O6 O 1.0716(11) 1.0809(7) 0.1591(9) 0.099(4) Uani 0.5 1 d . U P . .
C64 C 1.0379(8) 0.9862(6) 0.1009(5) 0.047(2) Uani 0.5 1 d G U P . .
N10 N 1.0240(8) 0.9051(5) 0.1244(4) 0.041(2) Uani 0.5 1 d G U P . .
C60 C 0.9973(8) 0.8790(5) 0.0723(5) 0.046(2) Uani 0.5 1 d G U P . .
H60 H 0.9878 0.8230 0.0886 0.056 Uiso 0.5 1 d R U P . .
C61 C 0.9846(9) 0.9341(6) -0.0033(5) 0.049(3) Uani 0.5 1 d G U P . .
H61 H 0.9661 0.9163 -0.0394 0.058 Uiso 0.5 1 d R U P . .
C62 C 0.9985(9) 1.0152(6) -0.0269(4) 0.047(3) Uani 0.5 1 d G U P . .
C63 C 1.0252(7) 1.0413(5) 0.0252(5) 0.041(4) Uani 0.5 1 d G . P . .
H63 H 1.0348 1.0973 0.0089 0.049 Uiso 0.5 1 d R U P . .
C66 C 1.0704(13) 1.0084(11) 0.1573(9) 0.062(3) Uani 0.5 1 d . U P . .
C65 C 0.9829(16) 1.0739(13) -0.1098(10) 0.053(3) Uani 0.5 1 d . U P . .
O7 O 0.9585(8) 1.0545(7) -0.1541(5) 0.058(2) Uani 0.5 1 d . U P . .
O8 O 1.0026(8) 1.1462(7) -0.1281(5) 0.061(3) Uani 0.5 1 d . U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 N6 2.265(4) 2_767 ?
Ag2 N3 2.290(4) . ?
Ag2 N5 2.328(4) . ?
Ag2 N2 2.375(4) . ?
Ag3 N9 2.240(4) . ?
Ag3 N7 2.244(5) . ?
Ag3 N8 2.331(5) 2_657 ?
Ag3 O1 2.445(4) . ?
Ag1 N1 2.217(4) . ?
Ag1 N4 2.303(5) . ?
Ag1 O8 2.312(9) 2_775 ?
Ag1 N10 2.416(6) . ?
Ag1 O7 2.497(10) 2_775 ?
N5 C31 1.335(7) . ?
N5 C27 1.341(7) . ?
N9 C53 1.338(7) . ?
N9 C57 1.341(7) . ?
N4 C22 1.334(8) . ?
N4 C26 1.349(8) . ?
O1 C58 1.262(7) . ?
N3 C18 1.333(7) . ?
N3 C14 1.355(7) . ?
C33 C34 1.386(7) . ?
C33 C32 1.392(7) . ?
N6 C42 1.339(7) . ?
N6 C38 1.343(7) . ?
N6 Ag2 2.265(4) 2_767 ?
N2 C13 1.346(7) . ?
N2 C9 1.347(7) . ?
O2 C58 1.255(7) . ?
C37 C32 1.395(7) . ?
C37 C36 1.406(7) . ?
C37 C40 1.477(7) . ?
C28 C27 1.373(7) . ?
C28 C29 1.398(7) . ?
C40 C39 1.387(8) . ?
C40 C41 1.390(8) . ?
C58 C53 1.519(8) . ?
N1 C5 1.331(8) . ?
N1 C1 1.342(7) . ?
C4 C3 1.377(7) . ?
C4 C5 1.392(8) . ?
C7 C6 1.398(7) . ?
C7 C8 1.409(7) . ?
C7 C11 1.486(7) . ?
C3 C2 1.406(7) . ?
C3 C6 1.483(7) . ?
C11 C10 1.385(7) . ?
C11 C12 1.396(7) . ?
C36 C35 1.388(8) . ?
C34 C35 1.412(7) . ?
C34 C50 1.489(7) . ?
C10 C9 1.385(7) . ?
C50 C49 1.378(8) . ?
C50 C51 1.402(8) . ?
N7 C43 1.332(8) . ?
N7 C47 1.340(8) . ?
C53 C54 1.398(8) . ?
C20 C19 1.389(8) . ?
C20 C21 1.397(7) . ?
C20 C24 1.495(8) . ?
C12 C13 1.372(7) . ?
C26 C25 1.362(8) . ?
C21 C19 1.402(8) 2_676 ?
N8 C48 1.330(8) . ?
N8 C52 1.334(8) . ?
N8 Ag3 2.331(5) 2_657 ?
C32 C29 1.496(7) . ?
C2 C1 1.377(7) . ?
C51 C52 1.375(8) . ?
C6 C8 1.385(7) 2_866 ?
C29 C30 1.381(8) . ?
C17 C18 1.381(7) . ?
C17 C16 1.397(7) . ?
C41 C42 1.388(8) . ?
C38 C39 1.384(8) . ?
C54 C55 1.379(8) . ?
C25 C24 1.400(8) . ?
C35 C45 1.480(7) . ?
C30 C31 1.378(7) . ?
C44 C43 1.383(8) . ?
C44 C45 1.387(8) . ?
C15 C14 1.382(8) . ?
C15 C16 1.385(8) . ?
C16 C19 1.488(7) . ?
C22 C23 1.391(8) . ?
O4 C59 1.227(9) . ?
C24 C23 1.369(8) . ?
C19 C21 1.402(8) 2_676 ?
C49 C48 1.388(8) . ?
C8 C6 1.385(7) 2_866 ?
C45 C46 1.402(8) . ?
C55 C56 1.381(8) . ?
C55 C59 1.525(9) . ?
C57 C56 1.383(8) . ?
C47 C46 1.372(8) . ?
C59 O3 1.284(9) . ?
O5 C66 1.247(17) . ?
O5 O7 1.631(15) 2_775 ?
C68 C67 1.456(9) . ?
O9 C67 1.462(10) . ?
O6 C66 1.29(2) . ?
C64 O7 0.983(11) 2_775 ?
C64 C65 1.13(3) 2_775 ?
C64 N10 1.3900 . ?
C64 C63 1.3900 . ?
C64 C66 1.463(19) . ?
C64 C62 1.597(14) 2_775 ?
C64 C61 1.847(16) 2_775 ?
N10 C65 0.360(19) 2_775 ?
N10 O8 1.061(15) 2_775 ?
N10 O7 1.166(15) 2_775 ?
N10 C60 1.3900 . ?
N10 C62 1.847(11) 2_775 ?
C60 O8 0.970(12) 2_775 ?
C60 C61 1.3900 . ?
C60 C65 1.40(3) 2_775 ?
C60 C62 1.736(14) 2_775 ?
C60 C63 1.847(16) 2_775 ?
C61 C63 0.472(18) 2_775 ?
C61 C62 1.326(17) 2_775 ?
C61 C62 1.3900 . ?
C61 C64 1.847(11) 2_775 ?
C62 C62 0.948(11) 2_775 ?
C62 C63 1.14(2) 2_775 ?
C62 C61 1.33(2) 2_775 ?
C62 C63 1.3900 . ?
C62 C65 1.520(16) . ?
C62 C64 1.597(16) 2_775 ?
C62 C60 1.736(18) 2_775 ?
C62 N10 1.847(11) 2_775 ?
C63 C61 0.472(15) 2_775 ?
C63 C62 1.138(16) 2_775 ?
C63 C60 1.847(15) 2_775 ?
C66 O7 1.33(2) 2_775 ?
C65 N10 0.36(2) 2_775 ?
C65 C64 1.13(3) 2_775 ?
C65 O7 1.16(2) . ?
C65 O8 1.29(2) . ?
C65 C60 1.40(3) 2_775 ?
O7 C64 0.983(11) 2_775 ?
O7 N10 1.17(2) 2_775 ?
O7 C66 1.33(2) 2_775 ?
O7 O5 1.631(15) 2_775 ?
O7 Ag1 2.497(10) 2_775 ?
O8 C60 0.970(15) 2_775 ?
O8 N10 1.06(2) 2_775 ?
O8 Ag1 2.312(9) 2_775 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 Ag2 N3 126.10(18) 2_767 . ?
N6 Ag2 N5 114.41(16) 2_767 . ?
N3 Ag2 N5 100.72(16) . . ?
N6 Ag2 N2 98.43(16) 2_767 . ?
N3 Ag2 N2 107.12(16) . . ?
N5 Ag2 N2 109.39(15) . . ?
N9 Ag3 N7 136.63(18) . . ?
N9 Ag3 N8 122.10(16) . 2_657 ?
N7 Ag3 N8 97.46(17) . 2_657 ?
N9 Ag3 O1 71.58(15) . . ?
N7 Ag3 O1 120.36(17) . . ?
N8 Ag3 O1 101.64(16) 2_657 . ?
N1 Ag1 N4 124.13(17) . . ?
N1 Ag1 O8 131.4(3) . 2_775 ?
N4 Ag1 O8 104.3(3) . 2_775 ?
N1 Ag1 N10 127.5(3) . . ?
N4 Ag1 N10 103.6(3) . . ?
O8 Ag1 N10 25.8(4) 2_775 . ?
N1 Ag1 O7 118.6(3) . 2_775 ?
N4 Ag1 O7 95.7(3) . 2_775 ?
O8 Ag1 O7 53.0(4) 2_775 2_775 ?
N10 Ag1 O7 27.4(3) . 2_775 ?
C31 N5 C27 116.2(4) . . ?
C31 N5 Ag2 122.1(3) . . ?
C27 N5 Ag2 120.6(3) . . ?
C53 N9 C57 118.3(5) . . ?
C53 N9 Ag3 117.6(4) . . ?
C57 N9 Ag3 124.1(4) . . ?
C22 N4 C26 118.1(5) . . ?
C22 N4 Ag1 119.8(4) . . ?
C26 N4 Ag1 121.8(4) . . ?
C58 O1 Ag3 113.0(4) . . ?
C18 N3 C14 116.8(5) . . ?
C18 N3 Ag2 122.8(4) . . ?
C14 N3 Ag2 120.4(3) . . ?
C34 C33 C32 122.8(5) . . ?
C42 N6 C38 117.6(5) . . ?
C42 N6 Ag2 117.4(4) . 2_767 ?
C38 N6 Ag2 124.9(4) . 2_767 ?
C13 N2 C9 116.8(5) . . ?
C13 N2 Ag2 122.8(3) . . ?
C9 N2 Ag2 120.2(3) . . ?
C32 C37 C36 118.7(5) . . ?
C32 C37 C40 124.5(5) . . ?
C36 C37 C40 116.9(5) . . ?
C27 C28 C29 119.3(5) . . ?
C39 C40 C41 116.8(5) . . ?
C39 C40 C37 123.2(5) . . ?
C41 C40 C37 119.9(5) . . ?
O2 C58 O1 126.4(6) . . ?
O2 C58 C53 116.0(5) . . ?
O1 C58 C53 117.7(5) . . ?
C5 N1 C1 116.7(5) . . ?
C5 N1 Ag1 121.0(4) . . ?
C1 N1 Ag1 121.2(4) . . ?
C3 C4 C5 119.4(5) . . ?
C6 C7 C8 118.8(4) . . ?
C6 C7 C11 123.1(4) . . ?
C8 C7 C11 118.0(4) . . ?
C4 C3 C2 117.3(5) . . ?
C4 C3 C6 120.6(4) . . ?
C2 C3 C6 122.1(4) . . ?
C10 C11 C12 117.3(5) . . ?
C10 C11 C7 121.7(4) . . ?
C12 C11 C7 121.0(4) . . ?
C35 C36 C37 122.4(5) . . ?
C33 C34 C35 118.7(5) . . ?
C33 C34 C50 117.4(5) . . ?
C35 C34 C50 123.8(5) . . ?
C11 C10 C9 119.6(5) . . ?
C49 C50 C51 117.6(5) . . ?
C49 C50 C34 121.8(5) . . ?
C51 C50 C34 120.4(5) . . ?
C43 N7 C47 116.8(5) . . ?
C43 N7 Ag3 121.9(4) . . ?
C47 N7 Ag3 121.3(4) . . ?
N9 C53 C54 121.9(5) . . ?
N9 C53 C58 118.2(5) . . ?
C54 C53 C58 119.9(5) . . ?
C19 C20 C21 119.3(5) . . ?
C19 C20 C24 121.9(4) . . ?
C21 C20 C24 118.7(5) . . ?
C13 C12 C11 119.7(5) . . ?
N4 C26 C25 122.6(5) . . ?
N2 C13 C12 123.5(5) . . ?
C20 C21 C19 121.9(5) . 2_676 ?
C48 N8 C52 117.3(5) . . ?
C48 N8 Ag3 123.0(4) . 2_657 ?
C52 N8 Ag3 119.7(4) . 2_657 ?
C33 C32 C37 118.8(5) . . ?
C33 C32 C29 117.9(5) . . ?
C37 C32 C29 123.1(5) . . ?
C1 C2 C3 119.1(5) . . ?
C52 C51 C50 118.9(5) . . ?
C8 C6 C7 119.3(4) 2_866 . ?
C8 C6 C3 118.5(4) 2_866 . ?
C7 C6 C3 122.0(4) . . ?
C30 C29 C28 117.4(5) . . ?
C30 C29 C32 122.3(5) . . ?
C28 C29 C32 120.2(5) . . ?
C18 C17 C16 119.7(5) . . ?
C42 C41 C40 119.7(5) . . ?
N3 C18 C17 123.4(5) . . ?
N6 C38 C39 122.4(5) . . ?
C55 C54 C53 119.9(5) . . ?
C26 C25 C24 119.7(5) . . ?
C36 C35 C34 118.5(5) . . ?
C36 C35 C45 117.4(5) . . ?
C34 C35 C45 124.0(5) . . ?
C31 C30 C29 119.1(5) . . ?
N2 C9 C10 123.1(5) . . ?
C43 C44 C45 120.3(5) . . ?
N5 C27 C28 123.7(5) . . ?
N8 C52 C51 123.6(6) . . ?
C14 C15 C16 119.6(5) . . ?
N1 C5 C4 123.7(5) . . ?
C15 C16 C17 117.2(5) . . ?
C15 C16 C19 122.0(5) . . ?
C17 C16 C19 120.8(5) . . ?
N4 C22 C23 122.0(5) . . ?
C23 C24 C25 117.5(5) . . ?
C23 C24 C20 120.8(5) . . ?
C25 C24 C20 121.6(5) . . ?
C20 C19 C21 118.9(5) . 2_676 ?
C20 C19 C16 123.6(5) . . ?
C21 C19 C16 117.3(5) 2_676 . ?
N1 C1 C2 123.8(5) . . ?
N7 C43 C44 122.7(5) . . ?
C50 C49 C48 119.2(6) . . ?
C6 C8 C7 121.8(4) 2_866 . ?
C44 C45 C46 117.0(5) . . ?
C44 C45 C35 121.8(5) . . ?
C46 C45 C35 120.8(5) . . ?
N6 C42 C41 123.0(5) . . ?
N5 C31 C30 124.3(5) . . ?
C54 C55 C56 117.5(5) . . ?
C54 C55 C59 121.8(5) . . ?
C56 C55 C59 120.8(6) . . ?
C38 C39 C40 120.5(5) . . ?
N9 C57 C56 122.2(5) . . ?
C55 C56 C57 120.2(6) . . ?
C24 C23 C22 120.0(5) . . ?
N3 C14 C15 123.2(5) . . ?
N7 C47 C46 124.7(6) . . ?
O4 C59 O3 127.9(7) . . ?
O4 C59 C55 117.6(6) . . ?
O3 C59 C55 114.3(7) . . ?
N8 C48 C49 123.3(6) . . ?
C66 O5 O7 52.8(9) . 2_775 ?
C68 C67 O9 109.0(7) . . ?
C47 C46 C45 118.3(6) . . ?
O7 C64 C65 66.2(11) 2_775 2_775 ?
O7 C64 N10 55.7(9) 2_775 . ?
C65 C64 N10 11.5(10) 2_775 . ?
O7 C64 C63 174.6(9) 2_775 . ?
C65 C64 C63 109.2(10) 2_775 . ?
N10 C64 C63 120.0 . . ?
O7 C64 C66 62.0(10) 2_775 . ?
C65 C64 C66 128.3(13) 2_775 . ?
N10 C64 C66 117.5(8) . . ?
C63 C64 C66 122.5(8) . . ?
O7 C64 C62 131.2(11) 2_775 2_775 ?
C65 C64 C62 65.1(11) 2_775 2_775 ?
N10 C64 C62 76.0(5) . 2_775 ?
C63 C64 C62 44.1(5) . 2_775 ?
C66 C64 C62 166.5(10) . 2_775 ?
O7 C64 C61 173.7(12) 2_775 2_775 ?
C65 C64 C61 112.0(12) 2_775 2_775 ?
N10 C64 C61 122.9(6) . 2_775 ?
C63 C64 C61 4.2(7) . 2_775 ?
C66 C64 C61 119.6(9) . 2_775 ?
C62 C64 C61 46.9(4) 2_775 2_775 ?
C65 N10 O8 123(4) 2_775 2_775 ?
C65 N10 O7 81(4) 2_775 2_775 ?
O8 N10 O7 150.3(9) 2_775 2_775 ?
C65 N10 C64 39(4) 2_775 . ?
O8 N10 C64 161.6(7) 2_775 . ?
O7 N10 C64 44.2(6) 2_775 . ?
C65 N10 C60 83(4) 2_775 . ?
O8 N10 C60 44.1(6) 2_775 . ?
O7 N10 C60 163.9(6) 2_775 . ?
C64 N10 C60 120.0 . . ?
C65 N10 C62 22(4) 2_775 2_775 ?
O8 N10 C62 105.9(8) 2_775 2_775 ?
O7 N10 C62 101.0(7) 2_775 2_775 ?
C64 N10 C62 57.0(5) . 2_775 ?
C60 N10 C62 63.0(5) . 2_775 ?
C65 N10 Ag1 154(4) 2_775 . ?
O8 N10 Ag1 71.6(6) 2_775 . ?
O7 N10 Ag1 80.2(6) 2_775 . ?
C64 N10 Ag1 124.3(5) . . ?
C60 N10 Ag1 115.5(5) . . ?
C62 N10 Ag1 172.4(7) 2_775 . ?
O8 C60 N10 49.6(9) 2_775 . ?
O8 C60 C61 165.7(9) 2_775 . ?
N10 C60 C61 120.0 . . ?
O8 C60 C65 63.3(10) 2_775 2_775 ?
N10 C60 C65 14.9(8) . 2_775 ?
C61 C60 C65 105.5(8) . 2_775 ?
O8 C60 C62 119.3(11) 2_775 2_775 ?
N10 C60 C62 71.4(5) . 2_775 ?
C61 C60 C62 48.7(5) . 2_775 ?
C65 C60 C62 56.8(8) 2_775 2_775 ?
O8 C60 C63 161.5(12) 2_775 2_775 ?
N10 C60 C63 117.0(6) . 2_775 ?
C61 C60 C63 4.2(7) . 2_775 ?
C65 C60 C63 102.3(10) 2_775 2_775 ?
C62 C60 C63 45.5(4) 2_775 2_775 ?
C63 C61 C62 88(2) 2_775 2_775 ?
C63 C61 C62 49(2) 2_775 . ?
C62 C61 C62 40.8(5) 2_775 . ?
C63 C61 C60 163(3) 2_775 . ?
C62 C61 C60 79.4(5) 2_775 . ?
C62 C61 C60 120.0 . . ?
C63 C61 C64 13(2) 2_775 2_775 ?
C62 C61 C64 97.3(8) 2_775 2_775 ?
C62 C61 C64 57.0(6) . 2_775 ?
C60 C61 C64 175.8(6) . 2_775 ?
C62 C62 C63 83.1(12) 2_775 2_775 ?
C62 C62 C61 73.2(12) 2_775 2_775 ?
C63 C62 C61 155.4(12) 2_775 2_775 ?
C62 C62 C61 66.0(10) 2_775 . ?
C63 C62 C61 18.2(7) 2_775 . ?
C61 C62 C61 139.2(6) 2_775 . ?
C62 C62 C63 54.3(10) 2_775 . ?
C63 C62 C63 137.4(7) 2_775 . ?
C61 C62 C63 19.8(6) 2_775 . ?
C61 C62 C63 120.0 . . ?
C62 C62 C65 172.4(18) 2_775 . ?
C63 C62 C65 100.7(10) 2_775 . ?
C61 C62 C65 102.1(10) 2_775 . ?
C61 C62 C65 118.4(11) . . ?
C63 C62 C65 121.6(11) . . ?
C62 C62 C64 140.8(15) 2_775 2_775 ?
C63 C62 C64 58.2(6) 2_775 2_775 ?
C61 C62 C64 143.8(9) 2_775 2_775 ?
C61 C62 C64 76.0(5) . 2_775 ?
C63 C62 C64 163.6(5) . 2_775 ?
C65 C62 C64 42.5(10) . 2_775 ?
C62 C62 C60 124.9(18) 2_775 2_775 ?
C63 C62 C60 149.9(12) 2_775 2_775 ?
C61 C62 C60 51.9(7) 2_775 2_775 ?
C61 C62 C60 168.2(10) . 2_775 ?
C63 C62 C60 71.4(10) . 2_775 ?
C65 C62 C60 50.2(10) . 2_775 ?
C64 C62 C60 92.4(8) 2_775 2_775 ?
C62 C62 N10 168(2) 2_775 2_775 ?
C63 C62 N10 105.1(11) 2_775 2_775 ?
C61 C62 N10 97.3(9) 2_775 2_775 ?
C61 C62 N10 123.0(12) . 2_775 ?
C63 C62 N10 117.0(12) . 2_775 ?
C65 C62 N10 5.2(9) . 2_775 ?
C64 C62 N10 46.9(8) 2_775 2_775 ?
C60 C62 N10 45.5(3) 2_775 2_775 ?
C61 C63 C62 113(3) 2_775 2_775 ?
C61 C63 C62 72(3) 2_775 . ?
C62 C63 C62 42.6(6) 2_775 . ?
C61 C63 C64 163(3) 2_775 . ?
C62 C63 C64 77.7(6) 2_775 . ?
C62 C63 C64 120.0 . . ?
C61 C63 C60 12.5(19) 2_775 2_775 ?
C62 C63 C60 105.1(13) 2_775 2_775 ?
C62 C63 C60 63.0(10) . 2_775 ?
C64 C63 C60 175.8(11) . 2_775 ?
O5 C66 O6 106.7(15) . . ?
O5 C66 O7 78.6(12) . 2_775 ?
O6 C66 O7 164.3(16) . 2_775 ?
O5 C66 C64 119.5(15) . . ?
O6 C66 C64 132.3(13) . . ?
O7 C66 C64 40.9(7) 2_775 . ?
N10 C65 C64 130(5) 2_775 2_775 ?
N10 C65 O7 82(4) 2_775 . ?
C64 C65 O7 50.7(12) 2_775 . ?
N10 C65 O8 44(4) 2_775 . ?
C64 C65 O8 173.1(18) 2_775 . ?
O7 C65 O8 122.5(15) . . ?
N10 C65 C60 82(4) 2_775 2_775 ?
C64 C65 C60 144.4(16) 2_775 2_775 ?
O7 C65 C60 163.4(17) . 2_775 ?
O8 C65 C60 42.1(9) . 2_775 ?
N10 C65 C62 152(5) 2_775 . ?
C64 C65 C62 72.4(12) 2_775 . ?
O7 C65 C62 123.0(18) . . ?
O8 C65 C62 114.4(15) . . ?
C60 C65 C62 73.0(9) 2_775 . ?
C64 O7 C65 63.0(12) 2_775 . ?
C64 O7 N10 80.1(9) 2_775 2_775 ?
C65 O7 N10 17.8(10) . 2_775 ?
C64 O7 C66 77.0(11) 2_775 2_775 ?
C65 O7 C66 140.0(14) . 2_775 ?
N10 O7 C66 156.2(12) 2_775 2_775 ?
C64 O7 O5 125.4(12) 2_775 2_775 ?
C65 O7 O5 170.6(14) . 2_775 ?
N10 O7 O5 152.8(10) 2_775 2_775 ?
C66 O7 O5 48.5(8) 2_775 2_775 ?
C64 O7 Ag1 152.5(11) 2_775 2_775 ?
C65 O7 Ag1 89.5(12) . 2_775 ?
N10 O7 Ag1 72.5(6) 2_775 2_775 ?
C66 O7 Ag1 130.4(9) 2_775 2_775 ?
O5 O7 Ag1 81.9(5) 2_775 2_775 ?
C60 O8 N10 86.3(11) 2_775 2_775 ?
C60 O8 C65 74.6(13) 2_775 . ?
N10 O8 C65 13.5(9) 2_775 . ?
C60 O8 Ag1 167.0(15) 2_775 2_775 ?
N10 O8 Ag1 82.6(8) 2_775 2_775 ?
C65 O8 Ag1 95.0(10) . 2_775 ?

_refine_diff_density_max         1.557
_refine_diff_density_min         -1.902
_refine_diff_density_rms         0.122



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_audit_block_doi                 10.5517/ccdc.csd.cc22j3pf
_database_code_depnum_ccdc_archive 'CCDC 1922114'
loop_
_audit_author_name
_audit_author_address
'Liu Wei'
;South China Agriculture University
China
;
_audit_update_record             
;
2019-06-10 deposited with the CCDC.	2019-09-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H34 Ag2 N4 O8'
_chemical_formula_weight         866.41

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_H-M_alt        'C c'
_space_group_name_Hall           'C -2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'

_cell_length_a                   18.1253(7)
_cell_length_b                   19.3124(10)
_cell_length_c                   10.4700(4)
_cell_angle_alpha                90
_cell_angle_beta                 112.6240(10)
_cell_angle_gamma                90
_cell_volume                     3382.9(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    13067
_cell_measurement_theta_min      5.96
_cell_measurement_theta_max      54.83

_exptl_crystal_description       block
_exptl_crystal_colour            YELLOW
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.701
_exptl_crystal_F_000             1744
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.084
_exptl_crystal_size_mid          0.072
_exptl_crystal_size_min          0.053
_exptl_absorpt_coefficient_mu    1.217
_shelx_estimated_absorpt_T_min   0.905
_shelx_estimated_absorpt_T_max   0.938
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  RAXIS-RAPID
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14657
_diffrn_reflns_av_unetI/netI     0.0577
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.982
_diffrn_reflns_theta_max         27.417
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             7211
_reflns_number_gt                6198
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.997
_reflns_Friedel_fraction_max     0.995
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0439P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.41(4)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         7211
_refine_ls_number_parameters     452
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0478
_refine_ls_R_factor_gt           0.0386
_refine_ls_wR_factor_ref         0.0907
_refine_ls_wR_factor_gt          0.0848
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.05620(2) -0.11159(2) 1.38594(4) 0.02774(15) Uani 1 1 d . . . . .
Ag2 Ag 0.75529(3) 0.11687(3) 0.90602(4) 0.02965(16) Uani 1 1 d . . . . .
N1 N 0.1641(4) -0.0717(3) 1.3439(7) 0.0277(14) Uani 1 1 d . . . . .
N2 N 0.6608(4) 0.0787(3) 0.9789(7) 0.0267(14) Uani 1 1 d . . . . .
N3 N 0.5170(4) 0.2796(3) 1.3263(7) 0.0244(13) Uani 1 1 d . . . . .
N4 N 0.2955(4) -0.2704(3) 0.9818(7) 0.0254(13) Uani 1 1 d . . . . .
O1 O 0.7884(3) 0.0938(2) 0.7271(5) 0.0303(10) Uani 1 1 d . . . . .
O2 O 0.7244(3) 0.1856(3) 0.6037(5) 0.0373(12) Uani 1 1 d . . . . .
O3 O 0.9267(3) -0.0725(2) 0.5229(5) 0.0304(10) Uani 1 1 d . . . . .
O4 O 0.9902(3) -0.0163(2) 0.4070(5) 0.0318(11) Uani 1 1 d . . . . .
O5 O 1.0721(3) 0.1044(2) 0.4271(5) 0.0341(12) Uani 1 1 d . . . . .
H5B H 1.0466 0.0668 0.4212 0.041 Uiso 1 1 d R U . . .
C1 C 0.1572(5) -0.0160(4) 1.2645(9) 0.0315(18) Uani 1 1 d . . . . .
H1A H 0.1116 0.0128 1.2447 0.038 Uiso 1 1 calc R U . . .
C2 C 0.2131(4) 0.0023(4) 1.2090(9) 0.0291(16) Uani 1 1 d . . . . .
H2A H 0.2053 0.0423 1.1527 0.035 Uiso 1 1 calc R U . . .
C3 C 0.2805(4) -0.0391(3) 1.2372(8) 0.0227(15) Uani 1 1 d . . . . .
C4 C 0.2880(4) -0.0977(4) 1.3197(9) 0.0272(16) Uani 1 1 d . . . . .
H4A H 0.3323 -0.1280 1.3394 0.033 Uiso 1 1 calc R U . . .
C5 C 0.2296(5) -0.1111(4) 1.3726(11) 0.030(2) Uani 1 1 d . . . . .
H5A H 0.2365 -0.1499 1.4317 0.036 Uiso 1 1 calc R U . . .
C6 C 0.5903(5) 0.1134(4) 0.9351(11) 0.029(2) Uani 1 1 d . . . . .
H6A H 0.5815 0.1492 0.8687 0.035 Uiso 1 1 calc R U . . .
C7 C 0.5308(5) 0.0990(4) 0.9827(9) 0.0301(18) Uani 1 1 d . . . . .
H7A H 0.4828 0.1253 0.9499 0.036 Uiso 1 1 calc R U . . .
C8 C 0.5403(4) 0.0466(3) 1.0776(8) 0.0235(15) Uani 1 1 d . . . . .
C9 C 0.6127(4) 0.0102(4) 1.1231(8) 0.0304(17) Uani 1 1 d . . . . .
H9A H 0.6220 -0.0266 1.1876 0.037 Uiso 1 1 calc R U . . .
C10 C 0.6709(4) 0.0282(4) 1.0731(8) 0.0301(17) Uani 1 1 d . . . . .
H10A H 0.7202 0.0038 1.1069 0.036 Uiso 1 1 calc R U . . .
C11 C 0.4386(4) 0.2630(4) 1.2615(9) 0.0288(17) Uani 1 1 d . . . . .
H11A H 0.4000 0.2984 1.2487 0.035 Uiso 1 1 calc R U . . .
C12 C 0.4122(5) 0.1977(4) 1.2134(9) 0.0278(16) Uani 1 1 d . . . . .
H12A H 0.3566 0.1889 1.1678 0.033 Uiso 1 1 calc R U . . .
C13 C 0.4671(5) 0.1442(3) 1.2317(8) 0.0225(15) Uani 1 1 d . . . . .
C14 C 0.5477(4) 0.1611(4) 1.2987(8) 0.0254(16) Uani 1 1 d . . . . .
H14A H 0.5874 0.1266 1.3128 0.030 Uiso 1 1 calc R U . . .
C15 C 0.5696(4) 0.2279(4) 1.3445(8) 0.0248(15) Uani 1 1 d . . . . .
H15A H 0.6249 0.2379 1.3915 0.030 Uiso 1 1 calc R U . . .
C16 C 0.3738(4) -0.2555(4) 1.0485(9) 0.0308(18) Uani 1 1 d . . . . .
H16A H 0.4116 -0.2919 1.0640 0.037 Uiso 1 1 calc R U . . .
C17 C 0.4016(5) -0.1904(4) 1.0949(9) 0.0297(17) Uani 1 1 d . . . . .
H17A H 0.4575 -0.1826 1.1398 0.036 Uiso 1 1 calc R U . . .
C18 C 0.3485(4) -0.1353(4) 1.0768(8) 0.0226(15) Uani 1 1 d . . . . .
C19 C 0.2669(4) -0.1506(4) 1.0073(8) 0.0253(16) Uani 1 1 d . . . . .
H19A H 0.2278 -0.1153 0.9901 0.030 Uiso 1 1 calc R U . . .
C20 C 0.2447(4) -0.2176(4) 0.9647(8) 0.0256(15) Uani 1 1 d . . . . .
H20A H 0.1892 -0.2270 0.9197 0.031 Uiso 1 1 calc R U . . .
C21 C 0.3442(5) -0.0191(4) 1.1864(9) 0.0262(16) Uani 1 1 d . . . . .
C22 C 0.3791(4) -0.0641(4) 1.1213(8) 0.0246(15) Uani 1 1 d . . . . .
C23 C 0.4444(4) -0.0406(4) 1.0923(8) 0.0243(16) Uani 1 1 d . . . . .
H23A H 0.4689 -0.0714 1.0498 0.029 Uiso 1 1 calc R U . . .
C24 C 0.4742(4) 0.0263(4) 1.1237(8) 0.0239(15) Uani 1 1 d . . . . .
C25 C 0.4388(4) 0.0726(4) 1.1868(9) 0.0245(16) Uani 1 1 d . . . . .
C26 C 0.3742(4) 0.0485(4) 1.2175(9) 0.0260(16) Uani 1 1 d . . . . .
H26A H 0.3500 0.0792 1.2609 0.031 Uiso 1 1 calc R U . . .
C27 C 0.7680(4) 0.1333(4) 0.6231(8) 0.0248(15) Uani 1 1 d . . . . .
C28 C 0.8001(4) 0.1143(3) 0.5138(7) 0.0233(13) Uani 1 1 d . . . . .
C29 C 0.8486(3) 0.0563(3) 0.5307(7) 0.0230(13) Uani 1 1 d . . . . .
H29A H 0.8600 0.0277 0.6098 0.028 Uiso 1 1 calc R U . . .
C30 C 0.8809(3) 0.0396(3) 0.4330(7) 0.0223(12) Uani 1 1 d . . . . .
C31 C 0.8635(4) 0.0816(3) 0.3162(7) 0.0269(14) Uani 1 1 d . . . . .
H31A H 0.8865 0.0716 0.2507 0.032 Uiso 1 1 calc R U . . .
C32 C 0.8125(4) 0.1383(4) 0.2958(8) 0.0317(15) Uani 1 1 d . . . . .
H32A H 0.7991 0.1656 0.2145 0.038 Uiso 1 1 calc R U . . .
C33 C 0.7815(4) 0.1547(3) 0.3939(7) 0.0288(14) Uani 1 1 d . . . . .
H33A H 0.7474 0.1937 0.3800 0.035 Uiso 1 1 calc R U . . .
C34 C 1.0180(5) 0.2139(4) 0.4634(9) 0.0452(19) Uani 1 1 d . . . . .
H34A H 1.0116 0.2431 0.5350 0.068 Uiso 1 1 calc R U . . .
H34B H 1.0488 0.2391 0.4192 0.068 Uiso 1 1 calc R U . . .
H34C H 0.9652 0.2022 0.3938 0.068 Uiso 1 1 calc R U . . .
C36 C 1.0614(5) 0.1486(4) 0.5280(8) 0.0376(17) Uani 1 1 d . . . . .
H36A H 1.1143 0.1606 0.5995 0.045 Uiso 1 1 calc R U . . .
H36B H 1.0307 0.1237 0.5740 0.045 Uiso 1 1 calc R U . . .
C38 C 0.9361(4) -0.0217(3) 0.4562(7) 0.0263(13) Uani 1 1 d . . . . .
O1W O 0.5932(3) 0.2014(3) 0.6805(6) 0.0361(12) Uani 1 1 d . . . . .
H1WA H 0.5830 0.2444 0.6783 0.043 Uiso 1 1 d R U . . .
H1WB H 0.6329 0.1959 0.6573 0.043 Uiso 1 1 d R U . . .
O2W O 0.7071(3) 0.3278(3) 0.6331(6) 0.0437(14) Uani 1 1 d . . . . .
H2WA H 0.6639 0.3344 0.6451 0.052 Uiso 1 1 d R U . . .
H2WB H 0.7126 0.2845 0.6246 0.052 Uiso 1 1 d R U . . .
O3W O 1.0607(3) -0.1509(3) 0.6728(6) 0.0332(12) Uani 1 1 d . . . . .
H3WA H 1.0199 -0.1290 0.6190 0.040 Uiso 1 1 d R U . . .
H3WB H 1.0689 -0.1394 0.7555 0.040 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N3 2.230(6) 3_445 ?
Ag1 O4 2.252(4) 1_456 ?
Ag1 N1 2.297(6) . ?
Ag2 O1 2.222(4) . ?
Ag2 N2 2.251(6) . ?
Ag2 N4 2.335(6) 3 ?
N1 C1 1.335(10) . ?
N1 C5 1.344(11) . ?
N2 C10 1.348(9) . ?
N2 C6 1.358(11) . ?
N3 C15 1.342(9) . ?
N3 C11 1.355(9) . ?
N3 Ag1 2.230(6) 3 ?
N4 C20 1.339(9) . ?
N4 C16 1.350(9) . ?
N4 Ag2 2.335(6) 3_445 ?
O1 C27 1.263(9) . ?
O2 C27 1.249(8) . ?
O3 C38 1.254(8) . ?
O4 C38 1.275(8) . ?
O4 Ag1 2.252(4) 1_654 ?
O5 C36 1.430(8) . ?
O5 H5B 0.8501 . ?
C1 C2 1.393(11) . ?
C1 H1A 0.9500 . ?
C2 C3 1.393(10) . ?
C2 H2A 0.9500 . ?
C3 C4 1.399(11) . ?
C3 C21 1.496(10) . ?
C4 C5 1.394(13) . ?
C4 H4A 0.9500 . ?
C5 H5A 0.9500 . ?
C6 C7 1.379(12) . ?
C6 H6A 0.9500 . ?
C7 C8 1.381(11) . ?
C7 H7A 0.9500 . ?
C8 C9 1.402(10) . ?
C8 C24 1.506(9) . ?
C9 C10 1.390(10) . ?
C9 H9A 0.9500 . ?
C10 H10A 0.9500 . ?
C11 C12 1.375(10) . ?
C11 H11A 0.9500 . ?
C12 C13 1.395(11) . ?
C12 H12A 0.9500 . ?
C13 C14 1.393(10) . ?
C13 C25 1.487(10) . ?
C14 C15 1.381(10) . ?
C14 H14A 0.9500 . ?
C15 H15A 0.9500 . ?
C16 C17 1.372(10) . ?
C16 H16A 0.9500 . ?
C17 C18 1.398(11) . ?
C17 H17A 0.9500 . ?
C18 C19 1.404(10) . ?
C18 C22 1.490(10) . ?
C19 C20 1.377(10) . ?
C19 H19A 0.9500 . ?
C20 H20A 0.9500 . ?
C21 C22 1.395(10) . ?
C21 C26 1.405(10) . ?
C22 C23 1.406(10) . ?
C23 C24 1.389(10) . ?
C23 H23A 0.9500 . ?
C24 C25 1.405(10) . ?
C25 C26 1.408(10) . ?
C26 H26A 0.9500 . ?
C27 C28 1.515(9) . ?
C28 C29 1.393(8) . ?
C28 C33 1.404(9) . ?
C29 C30 1.397(8) . ?
C29 H29A 0.9500 . ?
C30 C31 1.398(9) . ?
C30 C38 1.509(8) . ?
C31 C32 1.394(9) . ?
C31 H31A 0.9500 . ?
C32 C33 1.384(10) . ?
C32 H32A 0.9500 . ?
C33 H33A 0.9500 . ?
C34 C36 1.502(11) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
O1W H1WA 0.8499 . ?
O1W H1WB 0.8500 . ?
O2W H2WA 0.8501 . ?
O2W H2WB 0.8499 . ?
O3W H3WA 0.8501 . ?
O3W H3WB 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag1 O4 132.37(19) 3_445 1_456 ?
N3 Ag1 N1 117.8(2) 3_445 . ?
O4 Ag1 N1 105.52(18) 1_456 . ?
O1 Ag2 N2 135.1(2) . . ?
O1 Ag2 N4 108.86(19) . 3 ?
N2 Ag2 N4 111.7(2) . 3 ?
C1 N1 C5 117.3(7) . . ?
C1 N1 Ag1 120.4(5) . . ?
C5 N1 Ag1 120.8(5) . . ?
C10 N2 C6 116.7(6) . . ?
C10 N2 Ag2 125.3(5) . . ?
C6 N2 Ag2 117.7(5) . . ?
C15 N3 C11 116.5(6) . . ?
C15 N3 Ag1 121.9(5) . 3 ?
C11 N3 Ag1 121.5(5) . 3 ?
C20 N4 C16 116.0(6) . . ?
C20 N4 Ag2 123.8(5) . 3_445 ?
C16 N4 Ag2 120.2(5) . 3_445 ?
C27 O1 Ag2 121.4(4) . . ?
C38 O4 Ag1 119.5(4) . 1_654 ?
C36 O5 H5B 109.7 . . ?
N1 C1 C2 123.6(7) . . ?
N1 C1 H1A 118.2 . . ?
C2 C1 H1A 118.2 . . ?
C1 C2 C3 119.1(7) . . ?
C1 C2 H2A 120.5 . . ?
C3 C2 H2A 120.5 . . ?
C2 C3 C4 117.7(7) . . ?
C2 C3 C21 120.8(7) . . ?
C4 C3 C21 121.5(7) . . ?
C5 C4 C3 119.1(7) . . ?
C5 C4 H4A 120.5 . . ?
C3 C4 H4A 120.5 . . ?
N1 C5 C4 123.2(8) . . ?
N1 C5 H5A 118.4 . . ?
C4 C5 H5A 118.4 . . ?
N2 C6 C7 123.0(8) . . ?
N2 C6 H6A 118.5 . . ?
C7 C6 H6A 118.5 . . ?
C6 C7 C8 120.6(7) . . ?
C6 C7 H7A 119.7 . . ?
C8 C7 H7A 119.7 . . ?
C7 C8 C9 117.0(6) . . ?
C7 C8 C24 121.8(7) . . ?
C9 C8 C24 121.1(6) . . ?
C10 C9 C8 119.6(7) . . ?
C10 C9 H9A 120.2 . . ?
C8 C9 H9A 120.2 . . ?
N2 C10 C9 123.2(7) . . ?
N2 C10 H10A 118.4 . . ?
C9 C10 H10A 118.4 . . ?
N3 C11 C12 123.4(7) . . ?
N3 C11 H11A 118.3 . . ?
C12 C11 H11A 118.3 . . ?
C11 C12 C13 119.9(7) . . ?
C11 C12 H12A 120.1 . . ?
C13 C12 H12A 120.1 . . ?
C14 C13 C12 116.8(7) . . ?
C14 C13 C25 122.9(7) . . ?
C12 C13 C25 120.2(7) . . ?
C15 C14 C13 119.9(6) . . ?
C15 C14 H14A 120.0 . . ?
C13 C14 H14A 120.0 . . ?
N3 C15 C14 123.4(7) . . ?
N3 C15 H15A 118.3 . . ?
C14 C15 H15A 118.3 . . ?
N4 C16 C17 123.3(7) . . ?
N4 C16 H16A 118.4 . . ?
C17 C16 H16A 118.4 . . ?
C16 C17 C18 120.6(7) . . ?
C16 C17 H17A 119.7 . . ?
C18 C17 H17A 119.7 . . ?
C17 C18 C19 116.3(7) . . ?
C17 C18 C22 120.4(7) . . ?
C19 C18 C22 123.2(7) . . ?
C20 C19 C18 119.0(7) . . ?
C20 C19 H19A 120.5 . . ?
C18 C19 H19A 120.5 . . ?
N4 C20 C19 124.9(7) . . ?
N4 C20 H20A 117.6 . . ?
C19 C20 H20A 117.6 . . ?
C22 C21 C26 119.0(6) . . ?
C22 C21 C3 124.8(6) . . ?
C26 C21 C3 116.0(6) . . ?
C21 C22 C23 118.8(6) . . ?
C21 C22 C18 122.9(6) . . ?
C23 C22 C18 118.2(6) . . ?
C24 C23 C22 122.1(6) . . ?
C24 C23 H23A 119.0 . . ?
C22 C23 H23A 119.0 . . ?
C23 C24 C25 119.9(6) . . ?
C23 C24 C8 116.8(6) . . ?
C25 C24 C8 123.1(6) . . ?
C24 C25 C26 117.8(6) . . ?
C24 C25 C13 125.3(6) . . ?
C26 C25 C13 116.8(6) . . ?
C21 C26 C25 122.4(7) . . ?
C21 C26 H26A 118.8 . . ?
C25 C26 H26A 118.8 . . ?
O2 C27 O1 125.9(6) . . ?
O2 C27 C28 118.4(7) . . ?
O1 C27 C28 115.7(6) . . ?
C29 C28 C33 118.9(6) . . ?
C29 C28 C27 120.4(6) . . ?
C33 C28 C27 120.7(6) . . ?
C28 C29 C30 120.9(6) . . ?
C28 C29 H29A 119.5 . . ?
C30 C29 H29A 119.5 . . ?
C29 C30 C31 119.3(6) . . ?
C29 C30 C38 120.1(6) . . ?
C31 C30 C38 120.5(6) . . ?
C32 C31 C30 120.2(6) . . ?
C32 C31 H31A 119.9 . . ?
C30 C31 H31A 119.9 . . ?
C33 C32 C31 120.0(6) . . ?
C33 C32 H32A 120.0 . . ?
C31 C32 H32A 120.0 . . ?
C32 C33 C28 120.6(6) . . ?
C32 C33 H33A 119.7 . . ?
C28 C33 H33A 119.7 . . ?
C36 C34 H34A 109.5 . . ?
C36 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C36 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
O5 C36 C34 111.4(6) . . ?
O5 C36 H36A 109.3 . . ?
C34 C36 H36A 109.3 . . ?
O5 C36 H36B 109.3 . . ?
C34 C36 H36B 109.3 . . ?
H36A C36 H36B 108.0 . . ?
O3 C38 O4 125.4(6) . . ?
O3 C38 C30 118.7(5) . . ?
O4 C38 C30 115.9(6) . . ?
H1WA O1W H1WB 108.4 . . ?
H2WA O2W H2WB 108.4 . . ?
H3WA O3W H3WB 108.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 1.1(12) . . . . ?
Ag1 N1 C1 C2 -165.1(6) . . . . ?
N1 C1 C2 C3 -0.3(12) . . . . ?
C1 C2 C3 C4 0.6(11) . . . . ?
C1 C2 C3 C21 -176.5(7) . . . . ?
C2 C3 C4 C5 -1.7(12) . . . . ?
C21 C3 C4 C5 175.4(8) . . . . ?
C1 N1 C5 C4 -2.3(13) . . . . ?
Ag1 N1 C5 C4 163.8(7) . . . . ?
C3 C4 C5 N1 2.7(14) . . . . ?
C10 N2 C6 C7 0.1(12) . . . . ?
Ag2 N2 C6 C7 -173.8(7) . . . . ?
N2 C6 C7 C8 -1.0(14) . . . . ?
C6 C7 C8 C9 0.6(12) . . . . ?
C6 C7 C8 C24 -175.5(8) . . . . ?
C7 C8 C9 C10 0.7(11) . . . . ?
C24 C8 C9 C10 176.8(7) . . . . ?
C6 N2 C10 C9 1.3(11) . . . . ?
Ag2 N2 C10 C9 174.7(6) . . . . ?
C8 C9 C10 N2 -1.7(12) . . . . ?
C15 N3 C11 C12 -1.1(12) . . . . ?
Ag1 N3 C11 C12 174.8(7) 3 . . . ?
N3 C11 C12 C13 0.7(13) . . . . ?
C11 C12 C13 C14 -0.4(12) . . . . ?
C11 C12 C13 C25 176.7(7) . . . . ?
C12 C13 C14 C15 0.7(11) . . . . ?
C25 C13 C14 C15 -176.4(7) . . . . ?
C11 N3 C15 C14 1.4(12) . . . . ?
Ag1 N3 C15 C14 -174.5(6) 3 . . . ?
C13 C14 C15 N3 -1.2(12) . . . . ?
C20 N4 C16 C17 -1.1(12) . . . . ?
Ag2 N4 C16 C17 179.6(6) 3_445 . . . ?
N4 C16 C17 C18 1.1(13) . . . . ?
C16 C17 C18 C19 -1.1(12) . . . . ?
C16 C17 C18 C22 -177.1(7) . . . . ?
C17 C18 C19 C20 1.2(11) . . . . ?
C22 C18 C19 C20 177.0(7) . . . . ?
C16 N4 C20 C19 1.3(12) . . . . ?
Ag2 N4 C20 C19 -179.4(6) 3_445 . . . ?
C18 C19 C20 N4 -1.4(12) . . . . ?
C2 C3 C21 C22 -133.5(9) . . . . ?
C4 C3 C21 C22 49.5(12) . . . . ?
C2 C3 C21 C26 51.6(11) . . . . ?
C4 C3 C21 C26 -125.4(8) . . . . ?
C26 C21 C22 C23 1.6(11) . . . . ?
C3 C21 C22 C23 -173.1(8) . . . . ?
C26 C21 C22 C18 -176.3(8) . . . . ?
C3 C21 C22 C18 9.0(13) . . . . ?
C17 C18 C22 C21 -139.4(9) . . . . ?
C19 C18 C22 C21 45.0(12) . . . . ?
C17 C18 C22 C23 42.7(11) . . . . ?
C19 C18 C22 C23 -133.0(8) . . . . ?
C21 C22 C23 C24 -1.3(12) . . . . ?
C18 C22 C23 C24 176.7(7) . . . . ?
C22 C23 C24 C25 0.1(11) . . . . ?
C22 C23 C24 C8 -175.5(8) . . . . ?
C7 C8 C24 C23 116.8(8) . . . . ?
C9 C8 C24 C23 -59.2(10) . . . . ?
C7 C8 C24 C25 -58.7(11) . . . . ?
C9 C8 C24 C25 125.4(8) . . . . ?
C23 C24 C25 C26 0.9(11) . . . . ?
C8 C24 C25 C26 176.2(7) . . . . ?
C23 C24 C25 C13 177.0(8) . . . . ?
C8 C24 C25 C13 -7.7(13) . . . . ?
C14 C13 C25 C24 -42.2(12) . . . . ?
C12 C13 C25 C24 140.8(9) . . . . ?
C14 C13 C25 C26 133.9(8) . . . . ?
C12 C13 C25 C26 -43.0(11) . . . . ?
C22 C21 C26 C25 -0.7(12) . . . . ?
C3 C21 C26 C25 174.5(8) . . . . ?
C24 C25 C26 C21 -0.6(12) . . . . ?
C13 C25 C26 C21 -177.0(7) . . . . ?
Ag2 O1 C27 O2 -4.6(10) . . . . ?
Ag2 O1 C27 C28 175.4(4) . . . . ?
O2 C27 C28 C29 -179.8(6) . . . . ?
O1 C27 C28 C29 0.3(9) . . . . ?
O2 C27 C28 C33 0.2(10) . . . . ?
O1 C27 C28 C33 -179.7(6) . . . . ?
C33 C28 C29 C30 2.2(9) . . . . ?
C27 C28 C29 C30 -177.8(6) . . . . ?
C28 C29 C30 C31 -0.4(9) . . . . ?
C28 C29 C30 C38 177.4(6) . . . . ?
C29 C30 C31 C32 -2.0(10) . . . . ?
C38 C30 C31 C32 -179.8(6) . . . . ?
C30 C31 C32 C33 2.6(11) . . . . ?
C31 C32 C33 C28 -0.8(10) . . . . ?
C29 C28 C33 C32 -1.6(10) . . . . ?
C27 C28 C33 C32 178.4(6) . . . . ?
Ag1 O4 C38 O3 16.6(9) 1_654 . . . ?
Ag1 O4 C38 C30 -164.7(4) 1_654 . . . ?
C29 C30 C38 O3 30.7(9) . . . . ?
C31 C30 C38 O3 -151.5(6) . . . . ?
C29 C30 C38 O4 -148.1(6) . . . . ?
C31 C30 C38 O4 29.7(9) . . . . ?

_refine_diff_density_max         1.164
_refine_diff_density_min         -0.804
_refine_diff_density_rms         0.094

