# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_2
_database_code_depnum_ccdc_archive 'CCDC 1876336'
loop_
_audit_author_name
_audit_author_address
'Liming Fan'
;North University of China
China
;
_audit_update_record             
;
2019-07-25 deposited with the CCDC.	2019-09-19 downloaded from the CCDC.
;
_audit_creation_date             2018-06-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H20 Cd Cl N4 O4'
_chemical_formula_sum            'C25 H20 Cd Cl N4 O4'
_chemical_formula_weight         588.30
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.431(4)
_cell_length_b                   13.316(4)
_cell_length_c                   18.540(7)
_cell_angle_alpha                90
_cell_angle_beta                 91.891(13)
_cell_angle_gamma                90
_cell_volume                     2326.9(14)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9034
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.56
_cell_measurement_theta_min      2.83
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.094
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1180
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0534
_diffrn_reflns_av_unetI/netI     0.0264
_diffrn_reflns_Laue_measured_fraction_full 0.978
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            21432
_diffrn_reflns_point_group_measured_fraction_full 0.978
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.022
_diffrn_reflns_theta_min         3.251
_diffrn_ambient_temperature      293.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4263
_reflns_number_total             4492
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.016
_refine_diff_density_min         -0.440
_refine_diff_density_rms         0.068
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     320
_refine_ls_number_reflns         4492
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0312
_refine_ls_R_factor_gt           0.0293
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0317P)²+2.3453P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0740
_refine_ls_wR_factor_ref         0.0754
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 C5-C4
 1.53 with sigma of 0.001
 O3-H3
 0.84 with sigma of 0.01
3.a Secondary CH2 refined with riding coordinates:
 C15(H11,H10), C22(H17,H16)
3.b Aromatic/amide H refined with riding coordinates:
 C3(H1), C18(H13), C12(H7), C20(H15), C25(H20), C23(H18),
 C6(H2), C14(H9), C17(H12), C19(H14), C24(H19), C11(H6),
 C13(H8), C9(H4), C10(H5)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cd1 Cd 0.06190(2) 0.40683(2) 0.42790(2) 0.02924(8) Uani 1 1 d . . . . .
O1 O 0.14849(17) 0.24111(13) 0.44577(11) 0.0343(4) Uani 1 1 d . . . . .
O2 O -0.07736(18) 0.26506(13) 0.46350(10) 0.0337(4) Uani 1 1 d . . . . .
N2 N 0.4493(2) 0.58392(16) 0.43617(13) 0.0351(5) Uani 1 1 d . . . . .
N1 N 0.2774(2) 0.47670(17) 0.41580(12) 0.0352(5) Uani 1 1 d . . . . .
O3 O 0.6129(2) -0.15218(19) 0.57379(12) 0.0504(5) Uani 1 1 d D . . . .
C5 C 0.2013(2) -0.08254(14) 0.61033(11) 0.0218(4) Uani 1 1 d D . . . .
N4 N -0.0078(2) 0.87674(18) 0.19111(12) 0.0362(5) Uani 1 1 d . . . . .
N3 N 0.1010(2) 0.89428(16) 0.29635(12) 0.0318(5) Uani 1 1 d . . . . .
C2 C 0.0133(2) 0.09974(15) 0.47910(12) 0.0209(4) Uani 1 1 d . . . . .
C1 C 0.0272(2) 0.20932(16) 0.46121(12) 0.0230(4) Uani 1 1 d . . . . .
C4 C 0.0990(2) -0.04244(16) 0.55100(10) 0.0202(4) Uani 1 1 d D . . . .
C3 C 0.1100(2) 0.05700(17) 0.52806(12) 0.0226(4) Uani 1 1 d . . . . .
H1 H 0.1847 0.0960 0.5462 0.027 Uiso 1 1 calc R . . . .
O4 O 0.6618(2) -0.1702(2) 0.69027(14) 0.0676(7) Uani 1 1 d . . . . .
C18 C 0.3675(3) 0.8073(2) 0.40468(13) 0.0324(5) Uani 1 1 d . . . . .
H13 H 0.2974 0.7887 0.4362 0.039 Uiso 1 1 calc R . . . .
C12 C 0.3152(3) 0.5596(2) 0.44924(16) 0.0373(6) Uani 1 1 d . . . . .
H7 H 0.2562 0.5968 0.4783 0.045 Uiso 1 1 calc R . . . .
C16 C 0.4981(3) 0.75931(19) 0.40859(14) 0.0326(5) Uani 1 1 d . . . . .
C21 C 0.3402(3) 0.8820(2) 0.35486(13) 0.0304(5) Uani 1 1 d . . . . .
C20 C 0.4467(3) 0.90972(19) 0.30858(15) 0.0355(6) Uani 1 1 d . . . . .
H15 H 0.4295 0.9598 0.2744 0.043 Uiso 1 1 calc R . . . .
C25 C 0.0874(3) 0.9281(2) 0.22871(14) 0.0356(6) Uani 1 1 d . . . . .
H20 H 0.1390 0.9814 0.2105 0.043 Uiso 1 1 calc R . . . .
C23 C 0.0082(3) 0.8166(2) 0.30263(16) 0.0413(6) Uani 1 1 d . . . . .
H18 H -0.0067 0.7781 0.3436 0.050 Uiso 1 1 calc R . . . .
C6 C 0.3365(3) -0.09865(18) 0.59648(14) 0.0316(5) Uani 1 1 d . . . . .
H2 H 0.3709 -0.0867 0.5508 0.038 Uiso 1 1 calc R . . . .
C14 C 0.4999(3) 0.5123(2) 0.39160(16) 0.0440(7) Uani 1 1 d . . . . .
H9 H 0.5902 0.5093 0.3731 0.053 Uiso 1 1 calc R . . . .
C15 C 0.5222(3) 0.6752(2) 0.46115(16) 0.0422(7) Uani 1 1 d . . . . .
H11 H 0.6231 0.6621 0.4669 0.051 Uiso 1 1 calc R . . . .
H10 H 0.4874 0.6945 0.5078 0.051 Uiso 1 1 calc R . . . .
C17 C 0.6026(3) 0.7885(2) 0.36232(15) 0.0358(6) Uani 1 1 d . . . . .
H12 H 0.6906 0.7570 0.3646 0.043 Uiso 1 1 calc R . . . .
C22 C 0.1988(3) 0.9345(2) 0.35195(15) 0.0369(6) Uani 1 1 d . . . . .
H17 H 0.1558 0.9284 0.3986 0.044 Uiso 1 1 calc R . . . .
H16 H 0.2137 1.0054 0.3428 0.044 Uiso 1 1 calc R . . . .
C19 C 0.5766(3) 0.8639(2) 0.31297(15) 0.0395(6) Uani 1 1 d . . . . .
H14 H 0.6476 0.8838 0.2824 0.047 Uiso 1 1 calc R . . . .
C24 C -0.0578(3) 0.8069(2) 0.23730(16) 0.0412(6) Uani 1 1 d . . . . .
H19 H -0.1272 0.7594 0.2256 0.049 Uiso 1 1 calc R . . . .
C11 C 0.1443(3) -0.0987(2) 0.67661(16) 0.0407(6) Uani 1 1 d . . . . .
H6 H 0.0486 -0.0871 0.6839 0.049 Uiso 1 1 calc R . . . .
C13 C 0.3935(3) 0.4468(2) 0.37959(16) 0.0422(6) Uani 1 1 d . . . . .
H8 H 0.3983 0.3897 0.3509 0.051 Uiso 1 1 calc R . . . .
C7 C 0.4258(3) -0.13406(19) 0.65235(14) 0.0330(5) Uani 1 1 d . . . . .
C8 C 0.5778(3) -0.1547(2) 0.64093(16) 0.0386(6) Uani 1 1 d . . . . .
C9 C 0.3735(3) -0.1496(2) 0.72037(16) 0.0428(7) Uani 1 1 d . . . . .
H4 H 0.4335 -0.1714 0.7579 0.051 Uiso 1 1 calc R . . . .
C10 C 0.2327(3) -0.1326(3) 0.73209(16) 0.0485(7) Uani 1 1 d . . . . .
H5 H 0.1969 -0.1439 0.7775 0.058 Uiso 1 1 calc R . . . .
Cl1 Cl -0.09478(8) 0.56381(5) 0.42744(4) 0.03975(16) Uani 1 1 d . . . . .
H3 H 0.692(3) -0.180(4) 0.568(3) 0.099(17) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 O1 2.3725(18) . ?
Cd1 O2 2.4045(18) . ?
Cd1 N1 2.253(2) . ?
Cd1 N4 2.283(2) 2_545 ?
Cd1 C1 2.724(2) . ?
Cd1 Cl1 2.5596(9) . ?
Cd1 Cl1 2.7181(11) 3_566 ?
O1 C1 1.262(3) . ?
O2 C1 1.236(3) . ?
N2 C12 1.336(4) . ?
N2 C14 1.358(4) . ?
N2 C15 1.464(3) . ?
N1 C12 1.310(4) . ?
N1 C13 1.362(4) . ?
O3 C8 1.299(4) . ?
O3 H3 0.844(10) . ?
C5 C4 1.5347(11) . ?
C5 C6 1.327(4) . ?
C5 C11 1.374(4) . ?
N4 Cd1 2.284(2) 2 ?
N4 C25 1.311(4) . ?
N4 C24 1.359(4) . ?
N3 C25 1.335(4) . ?
N3 C23 1.363(4) . ?
N3 C22 1.462(3) . ?
C2 C1 1.503(3) . ?
C2 C4 1.406(3) 3_556 ?
C2 C3 1.387(3) . ?
C4 C2 1.406(3) 3_556 ?
C4 C3 1.396(3) . ?
C3 H1 0.9300 . ?
O4 C8 1.208(3) . ?
C18 H13 0.9300 . ?
C18 C16 1.387(4) . ?
C18 C21 1.376(4) . ?
C12 H7 0.9300 . ?
C16 C15 1.497(4) . ?
C16 C17 1.383(4) . ?
C21 C20 1.392(4) . ?
C21 C22 1.505(4) . ?
C20 H15 0.9300 . ?
C20 C19 1.368(4) . ?
C25 H20 0.9300 . ?
C23 H18 0.9300 . ?
C23 C24 1.350(4) . ?
C6 H2 0.9300 . ?
C6 C7 1.395(4) . ?
C14 H9 0.9300 . ?
C14 C13 1.343(4) . ?
C15 H11 0.9700 . ?
C15 H10 0.9700 . ?
C17 H12 0.9300 . ?
C17 C19 1.375(4) . ?
C22 H17 0.9700 . ?
C22 H16 0.9700 . ?
C19 H14 0.9300 . ?
C24 H19 0.9300 . ?
C11 H6 0.9300 . ?
C11 C10 1.378(4) . ?
C13 H8 0.9300 . ?
C7 C8 1.481(4) . ?
C7 C9 1.385(4) . ?
C9 H4 0.9300 . ?
C9 C10 1.371(4) . ?
C10 H5 0.9300 . ?
Cl1 Cd1 2.7180(11) 3_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Cd1 O2 54.55(6) . . ?
O1 Cd1 C1 27.58(6) . . ?
O1 Cd1 Cl1 162.95(5) . . ?
O1 Cd1 Cl1 88.19(5) . 3_566 ?
O2 Cd1 C1 26.98(6) . . ?
O2 Cd1 Cl1 83.55(5) . 3_566 ?
O2 Cd1 Cl1 108.76(5) . . ?
N1 Cd1 O1 95.20(7) . . ?
N1 Cd1 O2 148.67(7) . . ?
N1 Cd1 N4 98.62(8) . 2_545 ?
N1 Cd1 C1 122.48(7) . . ?
N1 Cd1 Cl1 100.66(7) . . ?
N1 Cd1 Cl1 87.99(6) . 3_566 ?
N4 Cd1 O1 92.10(8) 2_545 . ?
N4 Cd1 O2 91.19(8) 2_545 . ?
N4 Cd1 C1 91.43(8) 2_545 . ?
N4 Cd1 Cl1 173.33(6) 2_545 3_566 ?
N4 Cd1 Cl1 91.69(6) 2_545 . ?
Cl1 Cd1 C1 135.69(5) . . ?
Cl1 Cd1 C1 85.75(5) 3_566 . ?
Cl1 Cd1 Cl1 86.15(2) . 3_566 ?
C1 O1 Cd1 91.90(13) . . ?
C1 O2 Cd1 91.06(14) . . ?
C12 N2 C14 107.1(2) . . ?
C12 N2 C15 125.5(3) . . ?
C14 N2 C15 127.2(3) . . ?
C12 N1 Cd1 122.22(19) . . ?
C12 N1 C13 105.6(2) . . ?
C13 N1 Cd1 132.10(19) . . ?
C8 O3 H3 112(4) . . ?
C6 C5 C4 120.2(2) . . ?
C6 C5 C11 123.7(2) . . ?
C11 C5 C4 116.1(2) . . ?
C25 N4 Cd1 123.3(2) . 2 ?
C25 N4 C24 105.5(2) . . ?
C24 N4 Cd1 131.11(18) . 2 ?
C25 N3 C23 107.1(2) . . ?
C25 N3 C22 125.3(2) . . ?
C23 N3 C22 127.6(2) . . ?
C4 C2 C1 120.61(19) 3_556 . ?
C3 C2 C1 118.9(2) . . ?
C3 C2 C4 120.49(19) . 3_556 ?
O1 C1 Cd1 60.52(11) . . ?
O1 C1 C2 117.51(19) . . ?
O2 C1 Cd1 61.96(12) . . ?
O2 C1 O1 122.5(2) . . ?
O2 C1 C2 120.0(2) . . ?
C2 C1 Cd1 178.03(16) . . ?
C2 C4 C5 122.89(18) 3_556 . ?
C3 C4 C5 119.84(18) . . ?
C3 C4 C2 117.15(17) . 3_556 ?
C2 C3 C4 122.3(2) . . ?
C2 C3 H1 118.8 . . ?
C4 C3 H1 118.8 . . ?
C16 C18 H13 119.5 . . ?
C21 C18 H13 119.5 . . ?
C21 C18 C16 120.9(2) . . ?
N2 C12 H7 124.4 . . ?
N1 C12 N2 111.3(3) . . ?
N1 C12 H7 124.4 . . ?
C18 C16 C15 119.6(2) . . ?
C17 C16 C18 119.2(2) . . ?
C17 C16 C15 121.2(2) . . ?
C18 C21 C20 118.8(2) . . ?
C18 C21 C22 120.4(2) . . ?
C20 C21 C22 120.8(2) . . ?
C21 C20 H15 119.7 . . ?
C19 C20 C21 120.5(3) . . ?
C19 C20 H15 119.7 . . ?
N4 C25 N3 111.5(2) . . ?
N4 C25 H20 124.2 . . ?
N3 C25 H20 124.2 . . ?
N3 C23 H18 127.0 . . ?
C24 C23 N3 105.9(2) . . ?
C24 C23 H18 127.0 . . ?
C5 C6 H2 120.9 . . ?
C5 C6 C7 118.1(2) . . ?
C7 C6 H2 120.9 . . ?
N2 C14 H9 126.8 . . ?
C13 C14 N2 106.4(3) . . ?
C13 C14 H9 126.8 . . ?
N2 C15 C16 110.8(2) . . ?
N2 C15 H11 109.5 . . ?
N2 C15 H10 109.5 . . ?
C16 C15 H11 109.5 . . ?
C16 C15 H10 109.5 . . ?
H11 C15 H10 108.1 . . ?
C16 C17 H12 119.9 . . ?
C19 C17 C16 120.2(3) . . ?
C19 C17 H12 119.9 . . ?
N3 C22 C21 113.1(2) . . ?
N3 C22 H17 109.0 . . ?
N3 C22 H16 109.0 . . ?
C21 C22 H17 109.0 . . ?
C21 C22 H16 109.0 . . ?
H17 C22 H16 107.8 . . ?
C20 C19 C17 120.3(3) . . ?
C20 C19 H14 119.8 . . ?
C17 C19 H14 119.8 . . ?
N4 C24 H19 125.1 . . ?
C23 C24 N4 109.9(2) . . ?
C23 C24 H19 125.1 . . ?
C5 C11 H6 120.9 . . ?
C5 C11 C10 118.3(3) . . ?
C10 C11 H6 120.9 . . ?
N1 C13 H8 125.2 . . ?
C14 C13 N1 109.7(3) . . ?
C14 C13 H8 125.2 . . ?
C6 C7 C8 121.3(2) . . ?
C9 C7 C6 120.1(2) . . ?
C9 C7 C8 118.6(2) . . ?
O3 C8 C7 114.2(2) . . ?
O4 C8 O3 123.3(3) . . ?
O4 C8 C7 122.5(3) . . ?
C7 C9 H4 120.1 . . ?
C10 C9 C7 119.7(2) . . ?
C10 C9 H4 120.1 . . ?
C11 C10 H5 120.0 . . ?
C9 C10 C11 120.0(3) . . ?
C9 C10 H5 120.0 . . ?
Cd1 Cl1 Cd1 93.85(2) . 3_566 ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1943131'
loop_
_audit_author_name
_audit_author_address
'Liming Fan'
;North University of China
China
;
_audit_update_record             
;
2019-07-25 deposited with the CCDC.	2019-09-19 downloaded from the CCDC.
;
_audit_creation_date             2018-06-05
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H19 Cd N4 O4'
_chemical_formula_sum            'C25 H19 Cd N4 O4'
_chemical_formula_weight         551.84
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   6.972(3)
_cell_length_b                   17.311(9)
_cell_length_c                   17.837(8)
_cell_angle_alpha                90
_cell_angle_beta                 93.913(14)
_cell_angle_gamma                90
_cell_volume                     2147.7(17)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9846
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      3.07
_shelx_estimated_absorpt_T_min   0.844
_shelx_estimated_absorpt_T_max   0.868
_exptl_absorpt_coefficient_mu    1.059
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7591
_exptl_absorpt_correction_T_max  0.8183
_exptl_absorpt_process_details   
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.707
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1108
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.19
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0451
_diffrn_reflns_av_unetI/netI     0.0231
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            50234
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.022
_diffrn_reflns_theta_min         3.071
_diffrn_ambient_temperature      293.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3678
_reflns_number_total             4230
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.371
_refine_diff_density_min         -0.569
_refine_diff_density_rms         0.083
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         4230
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0522
_refine_ls_R_factor_gt           0.0425
_refine_ls_restrained_S_all      1.107
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0260P)²+6.1964P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0859
_refine_ls_wR_factor_ref         0.0892
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C20(H1,H2), C21(H3,H4)
2.b Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C9(H9), C11(H11), C12(H12), C13(H13),
 C14(H14), C15(H15), C17(H17), C18(H18), C19(H19), C22(H22),
 C23(H23), C24(H24), C25(H25)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cd1 Cd 0.40752(4) 0.61723(2) 0.30327(2) 0.02961(10) Uani 1 1 d . . . . .
O1 O 0.6340(4) 0.51587(17) 0.33994(16) 0.0417(7) Uani 1 1 d . . . . .
O2 O 0.6116(4) 0.61691(18) 0.41207(17) 0.0478(8) Uani 1 1 d . . . . .
N1 N -0.0402(5) 0.4567(2) 0.21512(19) 0.0366(8) Uani 1 1 d . . . . .
N2 N -0.4704(5) 0.26707(19) 0.0998(2) 0.0378(8) Uani 1 1 d . . . . .
N3 N 0.2074(5) 0.5229(2) 0.2623(2) 0.0370(8) Uani 1 1 d . . . . .
N4 N -0.7117(5) 0.1983(2) 0.1368(2) 0.0408(9) Uani 1 1 d . . . . .
O3 O 0.9126(5) 0.7861(2) 0.7054(2) 0.0684(11) Uani 1 1 d . . . . .
C2 C 0.6843(5) 0.5527(2) 0.3975(2) 0.0256(8) Uani 1 1 d . . . . .
C1 C 1.2099(5) 0.6218(2) 0.5886(2) 0.0313(9) Uani 1 1 d . . . . .
O4 O 1.1713(5) 0.8496(2) 0.7320(2) 0.0757(12) Uani 1 1 d . . . . .
C3 C 0.8427(5) 0.5225(2) 0.4513(2) 0.0249(8) Uani 1 1 d . . . . .
C4 C 1.0832(6) 0.7966(2) 0.7011(2) 0.0347(9) Uani 1 1 d . . . . .
C5 C 1.1112(6) 0.6709(3) 0.6233(2) 0.0362(10) Uani 1 1 d . . . . .
H5 H 0.9806 0.6623 0.6271 0.043 Uiso 1 1 calc R . . . .
C6 C 0.9463(5) 0.5756(2) 0.4960(2) 0.0288(8) Uani 1 1 d . . . . .
H6 H 0.9086 0.6271 0.4936 0.035 Uiso 1 1 calc R . . . .
C7 C 1.1042(5) 0.5557(2) 0.5444(2) 0.0262(8) Uani 1 1 d . . . . .
C8 C 1.1982(6) 0.7388(2) 0.6563(2) 0.0345(9) Uani 1 1 d . . . . .
C9 C 0.0231(6) 0.5255(3) 0.2396(2) 0.0385(10) Uani 1 1 d . . . . .
H9 H -0.0526 0.5697 0.2405 0.046 Uiso 1 1 calc R . . . .
C10 C -0.2465(5) 0.4386(2) 0.0982(2) 0.0351(9) Uani 1 1 d . . . . .
C11 C -0.7692(6) 0.2373(3) 0.0733(3) 0.0439(11) Uani 1 1 d . . . . .
H11 H -0.8922 0.2352 0.0497 0.053 Uiso 1 1 calc R . . . .
C12 C -0.6234(6) 0.2794(3) 0.0490(3) 0.0453(11) Uani 1 1 d . . . . .
H12 H -0.6261 0.3106 0.0065 0.054 Uiso 1 1 calc R . . . .
C13 C -0.5296(7) 0.2176(3) 0.1504(3) 0.0456(11) Uani 1 1 d . . . . .
H13 H -0.4517 0.1989 0.1908 0.055 Uiso 1 1 calc R . . . .
C14 C 1.3954(6) 0.7489(3) 0.6500(3) 0.0428(11) Uani 1 1 d . . . . .
H14 H 1.4574 0.7922 0.6709 0.051 Uiso 1 1 calc R . . . .
C15 C 0.2619(6) 0.4474(2) 0.2522(3) 0.0406(10) Uani 1 1 d . . . . .
H15 H 0.3844 0.4278 0.2640 0.049 Uiso 1 1 calc R . . . .
C16 C -0.2573(6) 0.3702(2) 0.0572(2) 0.0371(10) Uani 1 1 d . . . . .
C17 C 0.1125(6) 0.4065(3) 0.2228(3) 0.0445(11) Uani 1 1 d . . . . .
H17 H 0.1120 0.3544 0.2101 0.053 Uiso 1 1 calc R . . . .
C18 C 1.4975(6) 0.6946(3) 0.6127(3) 0.0440(11) Uani 1 1 d . . . . .
H18 H 1.6291 0.7009 0.6093 0.053 Uiso 1 1 calc R . . . .
C19 C 1.4061(6) 0.6307(2) 0.5801(2) 0.0365(9) Uani 1 1 d . . . . .
H19 H 1.4735 0.5948 0.5534 0.044 Uiso 1 1 calc R . . . .
C20 C -0.2368(6) 0.4408(3) 0.1835(3) 0.0459(11) Uani 1 1 d . . . . .
H1 H -0.3228 0.4806 0.1998 0.055 Uiso 1 1 calc R . . . .
H2 H -0.2796 0.3917 0.2024 0.055 Uiso 1 1 calc R . . . .
C21 C -0.2704(6) 0.2916(3) 0.0923(3) 0.0491(12) Uani 1 1 d . . . . .
H3 H -0.2075 0.2542 0.0617 0.059 Uiso 1 1 calc R . . . .
H4 H -0.2026 0.2923 0.1416 0.059 Uiso 1 1 calc R . . . .
C22 C -0.2409(6) 0.5084(3) 0.0606(3) 0.0491(12) Uani 1 1 d . . . . .
H22 H -0.2342 0.5542 0.0879 0.059 Uiso 1 1 calc R . . . .
C23 C -0.2605(7) 0.3749(3) -0.0212(3) 0.0553(13) Uani 1 1 d . . . . .
H23 H -0.2667 0.3298 -0.0496 0.066 Uiso 1 1 calc R . . . .
C24 C -0.2545(7) 0.4452(4) -0.0570(3) 0.0663(16) Uani 1 1 d . . . . .
H24 H -0.2570 0.4473 -0.1091 0.080 Uiso 1 1 calc R . . . .
C25 C -0.2451(7) 0.5112(4) -0.0166(3) 0.0618(15) Uani 1 1 d . . . . .
H25 H -0.2415 0.5586 -0.0410 0.074 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 O1 2.420(3) . ?
Cd1 O2 2.327(3) . ?
Cd1 N3 2.237(3) . ?
Cd1 N4 2.275(4) 2_455 ?
Cd1 O3 2.420(4) 4_575 ?
Cd1 C2 2.712(4) . ?
Cd1 O4 2.376(4) 4_575 ?
Cd1 C4 2.711(4) 4_575 ?
O1 C2 1.239(4) . ?
O2 C2 1.257(5) . ?
N1 C9 1.334(5) . ?
N1 C17 1.374(6) . ?
N1 C20 1.472(5) . ?
N2 C12 1.368(6) . ?
N2 C13 1.330(6) . ?
N2 C21 1.472(5) . ?
N3 C9 1.321(5) . ?
N3 C15 1.376(5) . ?
N4 Cd1 2.275(4) 2_445 ?
N4 C11 1.356(6) . ?
N4 C13 1.319(5) . ?
O3 Cd1 2.420(4) 4_676 ?
O3 C4 1.211(5) . ?
C2 C3 1.506(5) . ?
C1 C5 1.279(6) . ?
C1 C7 1.547(5) . ?
C1 C19 1.396(6) . ?
O4 Cd1 2.376(4) 4_676 ?
O4 C4 1.215(5) . ?
C3 C6 1.388(5) . ?
C3 C7 1.404(5) 3_766 ?
C4 Cd1 2.711(4) 4_676 ?
C4 C8 1.540(6) . ?
C5 H5 0.9300 . ?
C5 C8 1.431(6) . ?
C6 H6 0.9300 . ?
C6 C7 1.394(5) . ?
C7 C3 1.404(5) 3_766 ?
C8 C14 1.398(6) . ?
C9 H9 0.9300 . ?
C10 C16 1.391(6) . ?
C10 C20 1.519(6) . ?
C10 C22 1.384(6) . ?
C11 H11 0.9300 . ?
C11 C12 1.346(6) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C14 C18 1.378(6) . ?
C15 H15 0.9300 . ?
C15 C17 1.337(6) . ?
C16 C21 1.503(6) . ?
C16 C23 1.399(7) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C18 C19 1.384(6) . ?
C19 H19 0.9300 . ?
C20 H1 0.9700 . ?
C20 H2 0.9700 . ?
C21 H3 0.9700 . ?
C21 H4 0.9700 . ?
C22 H22 0.9300 . ?
C22 C25 1.377(8) . ?
C23 H23 0.9300 . ?
C23 C24 1.376(8) . ?
C24 H24 0.9300 . ?
C24 C25 1.349(8) . ?
C25 H25 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Cd1 C2 27.18(10) . . ?
O1 Cd1 C4 105.31(12) . 4_575 ?
O2 Cd1 O1 54.72(10) . . ?
O2 Cd1 O3 124.39(14) . 4_575 ?
O2 Cd1 C2 27.54(10) . . ?
O2 Cd1 O4 89.71(14) . 4_575 ?
O2 Cd1 C4 106.46(13) . 4_575 ?
N3 Cd1 O1 86.56(12) . . ?
N3 Cd1 O2 127.07(12) . . ?
N3 Cd1 N4 102.86(14) . 2_455 ?
N3 Cd1 O3 107.99(14) . 4_575 ?
N3 Cd1 C2 107.65(12) . . ?
N3 Cd1 O4 119.35(15) . 4_575 ?
N3 Cd1 C4 118.83(13) . 4_575 ?
N4 Cd1 O1 136.17(12) 2_455 . ?
N4 Cd1 O2 87.81(12) 2_455 . ?
N4 Cd1 O3 87.21(13) 2_455 4_575 ?
N4 Cd1 C2 112.78(12) 2_455 . ?
N4 Cd1 O4 127.84(14) 2_455 4_575 ?
N4 Cd1 C4 106.85(13) 2_455 4_575 ?
O3 Cd1 O1 130.91(12) 4_575 . ?
O3 Cd1 C2 133.40(12) 4_575 . ?
O3 Cd1 C4 26.53(12) 4_575 4_575 ?
O4 Cd1 O1 78.78(12) 4_575 . ?
O4 Cd1 O3 52.93(12) 4_575 4_575 ?
O4 Cd1 C2 83.51(12) 4_575 . ?
O4 Cd1 C4 26.60(12) 4_575 4_575 ?
C4 Cd1 C2 107.95(12) 4_575 . ?
C2 O1 Cd1 89.6(2) . . ?
C2 O2 Cd1 93.6(2) . . ?
C9 N1 C17 107.2(3) . . ?
C9 N1 C20 124.8(4) . . ?
C17 N1 C20 128.0(4) . . ?
C12 N2 C21 126.5(4) . . ?
C13 N2 C12 106.6(4) . . ?
C13 N2 C21 126.0(4) . . ?
C9 N3 Cd1 130.3(3) . . ?
C9 N3 C15 105.3(3) . . ?
C15 N3 Cd1 124.3(3) . . ?
C11 N4 Cd1 123.2(3) . 2_445 ?
C13 N4 Cd1 132.1(3) . 2_445 ?
C13 N4 C11 104.7(4) . . ?
C4 O3 Cd1 90.3(3) . 4_676 ?
O1 C2 Cd1 63.2(2) . . ?
O1 C2 O2 122.1(3) . . ?
O1 C2 C3 120.2(3) . . ?
O2 C2 Cd1 58.89(19) . . ?
O2 C2 C3 117.7(3) . . ?
C3 C2 Cd1 176.0(3) . . ?
C5 C1 C7 119.0(3) . . ?
C5 C1 C19 122.9(4) . . ?
C19 C1 C7 117.6(4) . . ?
C4 O4 Cd1 92.3(3) . 4_676 ?
C6 C3 C2 117.8(3) . . ?
C6 C3 C7 118.8(3) . 3_766 ?
C7 C3 C2 123.3(3) 3_766 . ?
O3 C4 Cd1 63.2(2) . 4_676 ?
O3 C4 O4 123.6(4) . . ?
O3 C4 C8 118.9(4) . . ?
O4 C4 Cd1 61.1(3) . 4_676 ?
O4 C4 C8 117.4(4) . . ?
C8 C4 Cd1 169.0(3) . 4_676 ?
C1 C5 H5 119.4 . . ?
C1 C5 C8 121.2(4) . . ?
C8 C5 H5 119.4 . . ?
C3 C6 H6 118.3 . . ?
C3 C6 C7 123.4(3) . . ?
C7 C6 H6 118.3 . . ?
C3 C7 C1 124.7(3) 3_766 . ?
C6 C7 C1 117.5(3) . . ?
C6 C7 C3 117.8(3) . 3_766 ?
C5 C8 C4 121.8(4) . . ?
C14 C8 C4 120.7(4) . . ?
C14 C8 C5 117.4(4) . . ?
N1 C9 H9 124.4 . . ?
N3 C9 N1 111.3(4) . . ?
N3 C9 H9 124.4 . . ?
C16 C10 C20 123.1(4) . . ?
C22 C10 C16 119.3(4) . . ?
C22 C10 C20 117.5(4) . . ?
N4 C11 H11 124.7 . . ?
C12 C11 N4 110.6(4) . . ?
C12 C11 H11 124.7 . . ?
N2 C12 H12 127.0 . . ?
C11 C12 N2 105.9(4) . . ?
C11 C12 H12 127.0 . . ?
N2 C13 H13 123.9 . . ?
N4 C13 N2 112.1(4) . . ?
N4 C13 H13 123.9 . . ?
C8 C14 H14 120.1 . . ?
C18 C14 C8 119.8(4) . . ?
C18 C14 H14 120.1 . . ?
N3 C15 H15 125.1 . . ?
C17 C15 N3 109.9(4) . . ?
C17 C15 H15 125.1 . . ?
C10 C16 C21 123.6(4) . . ?
C10 C16 C23 118.2(4) . . ?
C23 C16 C21 118.2(4) . . ?
N1 C17 H17 126.8 . . ?
C15 C17 N1 106.4(4) . . ?
C15 C17 H17 126.8 . . ?
C14 C18 H18 119.7 . . ?
C14 C18 C19 120.6(4) . . ?
C19 C18 H18 119.7 . . ?
C1 C19 H19 121.0 . . ?
C18 C19 C1 118.0(4) . . ?
C18 C19 H19 121.0 . . ?
N1 C20 C10 111.4(3) . . ?
N1 C20 H1 109.4 . . ?
N1 C20 H2 109.4 . . ?
C10 C20 H1 109.4 . . ?
C10 C20 H2 109.4 . . ?
H1 C20 H2 108.0 . . ?
N2 C21 C16 112.6(4) . . ?
N2 C21 H3 109.1 . . ?
N2 C21 H4 109.1 . . ?
C16 C21 H3 109.1 . . ?
C16 C21 H4 109.1 . . ?
H3 C21 H4 107.8 . . ?
C10 C22 H22 119.5 . . ?
C25 C22 C10 121.1(5) . . ?
C25 C22 H22 119.5 . . ?
C16 C23 H23 119.5 . . ?
C24 C23 C16 121.1(5) . . ?
C24 C23 H23 119.5 . . ?
C23 C24 H24 119.9 . . ?
C25 C24 C23 120.2(5) . . ?
C25 C24 H24 119.9 . . ?
C22 C25 H25 120.0 . . ?
C24 C25 C22 120.0(5) . . ?
C24 C25 H25 120.0 . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
