# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p
_database_code_depnum_ccdc_archive 'CCDC 1572857'
_audit_update_record             
;
2018-11-23 deposited with the CCDC.
2019-01-31 downloaded from the CCDC.
;
_audit_creation_date             2018-11-23
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelxl_version_number           2013-4
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C150 H132 Au18 Cl4 P12, 3(Cl), F6 P, 2(C6 H6)'
_chemical_formula_sum            'C162 H144 Au18 Cl7 F6 P13'
_chemical_formula_weight         6400.92
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.442(4)
_cell_length_b                   15.608(4)
_cell_length_c                   18.615(4)
_cell_angle_alpha                70.259(2)
_cell_angle_beta                 82.278(2)
_cell_angle_gamma                90.156(2)
_cell_volume                     4179.0(17)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9359
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.559
_cell_measurement_theta_min      2.284
_shelx_estimated_absorpt_T_max   0.361
_shelx_estimated_absorpt_T_min   0.297
_exptl_absorpt_coefficient_mu    16.017
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.2276
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1463 before and 0.0687 after correction. The Ratio of minimum to maximum transmission is 0.3053. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   sadabs
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.543
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2906
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1924
_diffrn_reflns_av_unetI/netI     0.1353
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            49605
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.388
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9077
_reflns_number_total             14723
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       'APEX3 (Bruker AXS Inc.,2015)'
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'Superflip (Palatinus & Chapuis, 2007)'
_refine_diff_density_max         5.195
_refine_diff_density_min         -3.299
_refine_diff_density_rms         0.486
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     928
_refine_ls_number_reflns         14723
_refine_ls_number_restraints     486
_refine_ls_R_factor_all          0.1272
_refine_ls_R_factor_gt           0.0761
_refine_ls_restrained_S_all      0.997
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1228P)²+148.9741P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1998
_refine_ls_wR_factor_ref         0.2566
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Uiso/Uaniso restraints and constraints
C51 \\sim C52 \\sim C53 \\sim C54 \\sim C55 \\sim C56: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C57 \\sim C57 \\sim C58 \\sim C58 \\sim C59 \\sim C60 \\sim C61 \\sim C62:
within 1.7A with sigma of 0.004 and sigma for terminal atoms of 0.008
C64 \\sim C65 \\sim C66 \\sim C67 \\sim C68 \\sim C69: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C70 \\sim C71 \\sim C72 \\sim C73 \\sim C74 \\sim C74 \\sim C75 \\sim C75:
within 1.7A with sigma of 0.004 and sigma for terminal atoms of 0.008
C20 \\sim C20 \\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25 \\sim C25:
within 1.7A with sigma of 0.004 and sigma for terminal atoms of 0.008
C26 \\sim C27 \\sim C28 \\sim C29 \\sim C30 \\sim C31: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C32 \\sim C33 \\sim C34 \\sim C35 \\sim C35 \\sim C36 \\sim C36 \\sim C37:
within 1.7A with sigma of 0.004 and sigma for terminal atoms of 0.008
C39 \\sim C40 \\sim C41 \\sim C42 \\sim C43 \\sim C44: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C45 \\sim C46 \\sim C47 \\sim C48 \\sim C49 \\sim C50: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C7 \\sim C8 \\sim C9 \\sim C10 \\sim C11 \\sim C12: within 1.7A with sigma of
0.004 and sigma for terminal atoms of 0.008
C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6: within 1.7A with sigma of
0.004 and sigma for terminal atoms of 0.008
C79 \\sim C79 \\sim C78 \\sim C77 \\sim C76 \\sim C81 \\sim C80 \\sim C80:
within 1.7A with sigma of 0.04 and sigma for terminal atoms of 0.08
P3 \\sim P4 \\sim C38: within 1.7A with sigma of 0.004 and sigma for terminal
atoms of 0.008
P1 \\sim P2 \\sim C13: within 1.7A with sigma of 0.004 and sigma for terminal
atoms of 0.008
C14 \\sim C15 \\sim C16 \\sim C17 \\sim C18 \\sim C19: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.008
C79 \\sim C78 \\sim C77 \\sim C76 \\sim C81 \\sim C80: within 1.7A with sigma
of 0.004 and sigma for terminal atoms of 0.08
Cl4 \\sim Cl4A: within 1.7A with sigma of 0.004 and sigma for terminal atoms of
0.008
Uanis(C13) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.1
Uanis(P5) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.1
Uanis(C38) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.1
3. Others
 Fixed Sof: Cl4(0.6) Cl4A(0.4)
4.a Secondary CH2 refined with riding coordinates:
 C13(H13A,H13B), C38(H38A,H38B), C63(H63A,H63B)
4.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C15(H15), C16(H16), C17(H17), C18(H18), C19(H19), C21(H21), C22(H22),
  C23(H23), C24(H24), C25(H25), C27(H27), C28(H28), C29(H29), C30(H30),
 C31(H31), C33(H33), C34(H34), C35(H35), C36(H36), C37(H37), C40(H40), C41(H41),
  C42(H42), C43(H43), C44(H44), C46(H46), C47(H47), C48(H48), C49(H49),
 C50(H50), C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C58(H58), C59(H59),
  C60(H60), C61(H61), C62(H62), C65(H65), C66(H66), C67(H67), C68(H68),
 C69(H69), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75), C79(H79), C78(H78),
  C77(H77), C76(H76), C81(H81), C80(H80)
4.c Fitted hexagon refined as free rotating group:
 C79(C78,C77,C76,C81,C80)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.50571(7) 0.59855(7) 0.27191(6) 0.0363(3) Uani 1 1 d . . . . .
Au2 Au 0.60602(7) 0.44683(7) 0.33238(6) 0.0350(3) Uani 1 1 d . . . . .
Au3 Au 0.42704(6) 0.43460(7) 0.37750(6) 0.0323(3) Uani 1 1 d . . . . .
Au4 Au 0.53453(7) 0.72511(7) 0.35002(6) 0.0347(3) Uani 1 1 d . . . . .
Au5 Au 0.67838(7) 0.62392(8) 0.31949(6) 0.0367(3) Uani 1 1 d . . . . .
Au6 Au 0.53374(6) 0.54043(7) 0.42434(5) 0.0288(2) Uani 1 1 d . . . . .
Au7 Au 0.54623(6) 0.34912(7) 0.49269(6) 0.0311(3) Uani 1 1 d . . . . .
Au8 Au 0.34724(7) 0.53907(7) 0.46858(6) 0.0365(3) Uani 1 1 d . . . . .
Au9 Au 0.64491(6) 0.65587(7) 0.45847(6) 0.0320(3) Uani 1 1 d . . . . .
Cl1 Cl 0.2066(5) 0.5437(6) 0.4338(5) 0.055(2) Uani 1 1 d . . . . .
Cl2 Cl 0.5731(5) 0.1987(5) 0.4950(4) 0.0447(17) Uani 1 1 d . . . . .
P1 P 0.4872(5) 0.7142(5) 0.1613(4) 0.0350(15) Uani 1 1 d . U . . .
P2 P 0.5057(5) 0.8482(5) 0.2492(4) 0.0355(16) Uani 1 1 d . U . . .
P3 P 0.3265(4) 0.3511(5) 0.3425(4) 0.0378(17) Uani 1 1 d . U . . .
P4 P 0.2460(4) 0.2669(5) 0.5113(4) 0.0370(16) Uani 1 1 d . U . . .
P5 P 0.7197(5) 0.4239(5) 0.2500(4) 0.0378(16) Uani 1 1 d . U . . .
P6 P 0.7890(5) 0.6218(5) 0.2254(4) 0.0383(16) Uani 1 1 d . . . . .
C1 C 0.374(2) 0.734(2) 0.1490(18) 0.048(4) Uani 1 1 d . U . . .
C2 C 0.348(2) 0.796(2) 0.0789(18) 0.049(4) Uani 1 1 d . U . . .
H2 H 0.3891 0.8274 0.0371 0.059 Uiso 1 1 calc R . . . .
C3 C 0.261(2) 0.806(2) 0.0756(19) 0.050(4) Uani 1 1 d . U . . .
H3 H 0.2440 0.8414 0.0291 0.060 Uiso 1 1 calc R . . . .
C4 C 0.195(2) 0.765(2) 0.1393(18) 0.051(4) Uani 1 1 d . U . . .
H4 H 0.1355 0.7750 0.1364 0.061 Uiso 1 1 calc R . . . .
C5 C 0.224(2) 0.709(2) 0.2065(18) 0.050(4) Uani 1 1 d . U . . .
H5 H 0.1822 0.6818 0.2494 0.060 Uiso 1 1 calc R . . . .
C6 C 0.307(2) 0.691(2) 0.2137(18) 0.049(4) Uani 1 1 d . U . . .
H6 H 0.3224 0.6515 0.2597 0.059 Uiso 1 1 calc R . . . .
C7 C 0.544(2) 0.703(2) 0.0721(16) 0.047(4) Uani 1 1 d . U . . .
C8 C 0.568(2) 0.616(2) 0.0725(17) 0.047(4) Uani 1 1 d . U . . .
H8 H 0.5530 0.5663 0.1175 0.057 Uiso 1 1 calc R . . . .
C9 C 0.613(2) 0.601(2) 0.0110(16) 0.048(4) Uani 1 1 d . U . . .
H9 H 0.6255 0.5419 0.0117 0.058 Uiso 1 1 calc R . . . .
C10 C 0.640(2) 0.675(2) -0.0521(17) 0.049(4) Uani 1 1 d . U . . .
H10 H 0.6728 0.6663 -0.0945 0.059 Uiso 1 1 calc R . . . .
C11 C 0.621(2) 0.762(2) -0.0565(17) 0.050(4) Uani 1 1 d . U . . .
H11 H 0.6402 0.8114 -0.1009 0.060 Uiso 1 1 calc R . . . .
C12 C 0.573(2) 0.774(2) 0.0081(16) 0.048(4) Uani 1 1 d . U . . .
H12 H 0.5609 0.8330 0.0070 0.058 Uiso 1 1 calc R . . . .
C13 C 0.5335(17) 0.8226(17) 0.1592(15) 0.034(6) Uani 1 1 d . U . . .
H13A H 0.5134 0.8711 0.1174 0.040 Uiso 1 1 calc R . . . .
H13B H 0.5967 0.8229 0.1477 0.040 Uiso 1 1 calc R . . . .
C14 C 0.390(2) 0.884(2) 0.2507(17) 0.047(3) Uani 1 1 d . U . . .
C15 C 0.361(2) 0.937(2) 0.1881(18) 0.048(3) Uani 1 1 d . U . . .
H15 H 0.3983 0.9581 0.1416 0.057 Uiso 1 1 calc R . . . .
C16 C 0.276(2) 0.961(2) 0.1916(18) 0.049(4) Uani 1 1 d . U . . .
H16 H 0.2562 1.0024 0.1489 0.059 Uiso 1 1 calc R . . . .
C17 C 0.219(2) 0.922(2) 0.2595(18) 0.050(4) Uani 1 1 d . U . . .
H17 H 0.1596 0.9316 0.2613 0.060 Uiso 1 1 calc R . . . .
C18 C 0.251(2) 0.869(2) 0.3229(18) 0.050(4) Uani 1 1 d . U . . .
H18 H 0.2132 0.8459 0.3692 0.060 Uiso 1 1 calc R . . . .
C19 C 0.338(2) 0.849(2) 0.3204(18) 0.049(4) Uani 1 1 d . U . . .
H19 H 0.3600 0.8126 0.3641 0.058 Uiso 1 1 calc R . . . .
C20 C 0.580(2) 0.948(2) 0.2301(19) 0.054(4) Uani 1 1 d . U . . .
C21 C 0.591(2) 1.018(2) 0.1618(19) 0.054(4) Uani 1 1 d . U . . .
H21 H 0.5582 1.0174 0.1234 0.065 Uiso 1 1 calc R . . . .
C22 C 0.652(2) 1.091(2) 0.1493(19) 0.055(4) Uani 1 1 d . U . . .
H22 H 0.6556 1.1414 0.1043 0.066 Uiso 1 1 calc R . . . .
C23 C 0.704(2) 1.089(2) 0.2018(19) 0.056(4) Uani 1 1 d . U . . .
H23 H 0.7470 1.1346 0.1920 0.068 Uiso 1 1 calc R . . . .
C24 C 0.693(2) 1.016(2) 0.2716(19) 0.057(4) Uani 1 1 d . U . . .
H24 H 0.7256 1.0163 0.3100 0.068 Uiso 1 1 calc R . . . .
C25 C 0.636(2) 0.944(2) 0.2845(19) 0.056(4) Uani 1 1 d . U . . .
H25 H 0.6334 0.8933 0.3290 0.067 Uiso 1 1 calc R . . . .
C26 C 0.288(2) 0.409(3) 0.2509(18) 0.056(4) Uani 1 1 d . U . . .
C27 C 0.208(2) 0.384(3) 0.2327(19) 0.057(4) Uani 1 1 d . U . . .
H27 H 0.1722 0.3369 0.2690 0.069 Uiso 1 1 calc R . . . .
C28 C 0.182(2) 0.428(2) 0.1630(18) 0.058(4) Uani 1 1 d . U . . .
H28 H 0.1277 0.4130 0.1529 0.069 Uiso 1 1 calc R . . . .
C29 C 0.238(2) 0.493(2) 0.1073(19) 0.057(4) Uani 1 1 d . U . . .
H29 H 0.2232 0.5198 0.0580 0.068 Uiso 1 1 calc R . . . .
C30 C 0.313(2) 0.519(3) 0.1246(18) 0.056(4) Uani 1 1 d . U . . .
H30 H 0.3475 0.5679 0.0887 0.067 Uiso 1 1 calc R . . . .
C31 C 0.343(2) 0.473(2) 0.1971(18) 0.056(4) Uani 1 1 d . U . . .
H31 H 0.3976 0.4869 0.2066 0.068 Uiso 1 1 calc R . . . .
C32 C 0.370(2) 0.244(2) 0.334(2) 0.057(4) Uani 1 1 d . U . . .
C33 C 0.317(2) 0.185(2) 0.313(2) 0.058(4) Uani 1 1 d . U . . .
H33 H 0.2584 0.1957 0.3061 0.070 Uiso 1 1 calc R . . . .
C34 C 0.359(2) 0.109(2) 0.302(2) 0.059(4) Uani 1 1 d . U . . .
H34 H 0.3282 0.0701 0.2854 0.071 Uiso 1 1 calc R . . . .
C35 C 0.439(2) 0.090(2) 0.314(2) 0.060(4) Uani 1 1 d . U . . .
H35 H 0.4627 0.0367 0.3094 0.072 Uiso 1 1 calc R . . . .
C36 C 0.489(2) 0.150(2) 0.335(2) 0.059(4) Uani 1 1 d . U . . .
H36 H 0.5452 0.1359 0.3458 0.070 Uiso 1 1 calc R . . . .
C37 C 0.455(2) 0.230(2) 0.3408(19) 0.057(4) Uani 1 1 d . U . . .
H37 H 0.4900 0.2738 0.3488 0.068 Uiso 1 1 calc R . . . .
C38 C 0.2260(18) 0.319(2) 0.4110(16) 0.041(7) Uani 1 1 d . U . . .
H38A H 0.1906 0.2769 0.3979 0.050 Uiso 1 1 calc R . . . .
H38B H 0.1931 0.3733 0.4066 0.050 Uiso 1 1 calc R . . . .
C39 C 0.141(2) 0.263(2) 0.569(2) 0.057(4) Uani 1 1 d . U . . .
C40 C 0.066(2) 0.302(2) 0.538(2) 0.058(4) Uani 1 1 d . U . . .
H40 H 0.0682 0.3339 0.4856 0.069 Uiso 1 1 calc R . . . .
C41 C -0.012(2) 0.292(2) 0.588(2) 0.060(4) Uani 1 1 d . U . . .
H41 H -0.0621 0.3169 0.5685 0.072 Uiso 1 1 calc R . . . .
C42 C -0.017(2) 0.247(2) 0.667(2) 0.059(4) Uani 1 1 d . U . . .
H42 H -0.0693 0.2415 0.6998 0.071 Uiso 1 1 calc R . . . .
C43 C 0.056(2) 0.210(3) 0.695(2) 0.059(4) Uani 1 1 d . U . . .
H43 H 0.0524 0.1802 0.7482 0.071 Uiso 1 1 calc R . . . .
C44 C 0.137(2) 0.216(2) 0.647(2) 0.059(4) Uani 1 1 d . U . . .
H44 H 0.1865 0.1888 0.6676 0.070 Uiso 1 1 calc R . . . .
C45 C 0.260(2) 0.147(2) 0.523(2) 0.063(4) Uani 1 1 d . U . . .
C46 C 0.185(2) 0.087(2) 0.537(2) 0.064(4) Uani 1 1 d . U . . .
H46 H 0.1282 0.1060 0.5440 0.077 Uiso 1 1 calc R . . . .
C47 C 0.203(2) -0.002(2) 0.540(2) 0.065(4) Uani 1 1 d . U . . .
H47 H 0.1559 -0.0424 0.5472 0.078 Uiso 1 1 calc R . . . .
C48 C 0.285(2) -0.033(2) 0.534(2) 0.065(4) Uani 1 1 d . U . . .
H48 H 0.2925 -0.0932 0.5381 0.078 Uiso 1 1 calc R . . . .
C49 C 0.356(2) 0.025(2) 0.521(2) 0.064(4) Uani 1 1 d . U . . .
H49 H 0.4124 0.0043 0.5165 0.077 Uiso 1 1 calc R . . . .
C50 C 0.342(2) 0.120(2) 0.515(2) 0.063(4) Uani 1 1 d . U . . .
H50 H 0.3892 0.1608 0.5058 0.075 Uiso 1 1 calc R . . . .
C51 C 0.685(3) 0.371(2) 0.1832(19) 0.064(4) Uani 1 1 d . U . . .
C52 C 0.598(3) 0.361(2) 0.1822(19) 0.064(4) Uani 1 1 d . U . . .
H52 H 0.5597 0.3724 0.2209 0.077 Uiso 1 1 calc R . . . .
C53 C 0.562(3) 0.337(2) 0.1289(19) 0.066(4) Uani 1 1 d . U . . .
H53 H 0.5021 0.3333 0.1290 0.079 Uiso 1 1 calc R . . . .
C54 C 0.621(3) 0.316(2) 0.074(2) 0.067(4) Uani 1 1 d . U . . .
H54 H 0.6004 0.2940 0.0385 0.080 Uiso 1 1 calc R . . . .
C55 C 0.709(3) 0.328(2) 0.0715(19) 0.066(4) Uani 1 1 d . U . . .
H55 H 0.7466 0.3166 0.0330 0.079 Uiso 1 1 calc R . . . .
C56 C 0.744(3) 0.358(2) 0.1255(19) 0.064(4) Uani 1 1 d . U . . .
H56 H 0.8039 0.3678 0.1227 0.077 Uiso 1 1 calc R . . . .
C57 C 0.807(2) 0.360(2) 0.297(2) 0.059(4) Uani 1 1 d . U . . .
C58 C 0.788(2) 0.311(2) 0.372(2) 0.061(4) Uani 1 1 d . U . . .
H58 H 0.7316 0.3103 0.3975 0.073 Uiso 1 1 calc R . . . .
C59 C 0.854(2) 0.260(2) 0.413(2) 0.064(4) Uani 1 1 d . U . . .
H59 H 0.8412 0.2229 0.4648 0.077 Uiso 1 1 calc R . . . .
C60 C 0.936(2) 0.267(2) 0.373(2) 0.065(4) Uani 1 1 d . U . . .
H60 H 0.9803 0.2372 0.3992 0.078 Uiso 1 1 calc R . . . .
C61 C 0.956(2) 0.316(2) 0.297(2) 0.064(4) Uani 1 1 d . U . . .
H61 H 1.0118 0.3159 0.2713 0.076 Uiso 1 1 calc R . . . .
C62 C 0.893(2) 0.365(2) 0.258(2) 0.061(4) Uani 1 1 d . U . . .
H62 H 0.9067 0.4019 0.2064 0.073 Uiso 1 1 calc R . . . .
C63 C 0.768(2) 0.536(2) 0.1821(18) 0.047(7) Uani 1 1 d . . . . .
H63A H 0.8223 0.5264 0.1543 0.056 Uiso 1 1 calc R . . . .
H63B H 0.7282 0.5611 0.1445 0.056 Uiso 1 1 calc R . . . .
C64 C 0.891(2) 0.590(2) 0.258(2) 0.054(4) Uani 1 1 d . U . . .
C65 C 0.894(2) 0.550(2) 0.338(2) 0.054(4) Uani 1 1 d . U . . .
H65 H 0.8432 0.5458 0.3728 0.065 Uiso 1 1 calc R . . . .
C66 C 0.972(2) 0.519(2) 0.366(2) 0.056(4) Uani 1 1 d . U . . .
H66 H 0.9733 0.4928 0.4184 0.067 Uiso 1 1 calc R . . . .
C67 C 1.045(2) 0.526(2) 0.315(2) 0.056(4) Uani 1 1 d . U . . .
H67 H 1.0963 0.5048 0.3339 0.067 Uiso 1 1 calc R . . . .
C68 C 1.047(2) 0.564(2) 0.233(2) 0.055(4) Uani 1 1 d . U . . .
H68 H 1.0987 0.5675 0.2001 0.066 Uiso 1 1 calc R . . . .
C69 C 0.969(2) 0.596(2) 0.205(2) 0.055(4) Uani 1 1 d . U . . .
H69 H 0.9678 0.6203 0.1520 0.065 Uiso 1 1 calc R . . . .
C70 C 0.802(2) 0.727(2) 0.146(2) 0.063(4) Uani 1 1 d . U . . .
C71 C 0.828(2) 0.734(3) 0.068(2) 0.064(4) Uani 1 1 d . U . . .
H71 H 0.8429 0.6824 0.0567 0.076 Uiso 1 1 calc R . . . .
C72 C 0.832(2) 0.817(2) 0.010(2) 0.065(4) Uani 1 1 d . U . . .
H72 H 0.8512 0.8202 -0.0400 0.078 Uiso 1 1 calc R . . . .
C73 C 0.809(2) 0.896(3) 0.024(2) 0.065(4) Uani 1 1 d . U . . .
H73 H 0.8098 0.9509 -0.0159 0.078 Uiso 1 1 calc R . . . .
C74 C 0.784(2) 0.889(3) 0.103(2) 0.064(4) Uani 1 1 d . U . . .
H74 H 0.7708 0.9417 0.1143 0.077 Uiso 1 1 calc R . . . .
C75 C 0.778(2) 0.807(2) 0.160(2) 0.063(4) Uani 1 1 d . U . . .
H75 H 0.7569 0.8039 0.2100 0.076 Uiso 1 1 calc R . . . .
Cl3 Cl 0.5000 1.0000 0.0000 0.054(3) Uani 1 2 d S T P . .
Cl4 Cl 1.0541(10) 0.9321(12) 0.4225(11) 0.077(5) Uani 0.6 1 d . U . . .
Cl4A Cl 1.0946(17) 1.1104(19) 0.3037(18) 0.084(8) Uani 0.4 1 d . U . . .
P7 P 1.0000 0.5000 0.0000 0.058(3) Uani 1 2 d S T P . .
F1 F 0.9086(15) 0.536(2) 0.0239(15) 0.107(9) Uani 1 1 d . . . . .
F2 F 1.0523(14) 0.5732(17) 0.0230(13) 0.086(7) Uani 1 1 d . . . . .
F3 F 0.9965(17) 0.430(2) 0.0845(13) 0.109(9) Uani 1 1 d . . . . .
C79 C 0.939(3) 1.216(2) 0.104(3) 0.184(11) Uani 1 1 d . U . . .
H79 H 0.9355 1.2763 0.1007 0.221 Uiso 1 1 calc R . . . .
C78 C 0.952(3) 1.150(3) 0.173(3) 0.184(11) Uani 1 1 d G U . . .
H78 H 0.9581 1.1664 0.2159 0.221 Uiso 1 1 calc R . . . .
C77 C 0.958(3) 1.059(3) 0.178(3) 0.184(11) Uani 1 1 d G U . . .
H77 H 0.9667 1.0149 0.2247 0.221 Uiso 1 1 calc R . . . .
C76 C 0.949(3) 1.034(2) 0.115(3) 0.184(11) Uani 1 1 d G U . . .
H76 H 0.9527 0.9733 0.1182 0.220 Uiso 1 1 calc R . . . .
C81 C 0.936(3) 1.100(3) 0.046(3) 0.183(11) Uani 1 1 d G U . . .
H81 H 0.9300 1.0831 0.0030 0.220 Uiso 1 1 calc R . . . .
C80 C 0.930(3) 1.191(3) 0.040(3) 0.184(11) Uani 1 1 d G U . . .
H80 H 0.9214 1.2346 -0.0057 0.221 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au2 2.8216(16) . ?
Au1 Au3 2.7983(16) . ?
Au1 Au4 2.8850(14) . ?
Au1 Au5 2.9860(16) . ?
Au1 Au6 2.7668(15) . ?
Au1 P1 2.287(7) . ?
Au2 Au3 2.7649(15) . ?
Au2 Au5 2.8998(16) . ?
Au2 Au6 2.7377(13) . ?
Au2 Au7 2.8741(15) . ?
Au2 P5 2.283(7) . ?
Au3 Au6 2.7473(14) . ?
Au3 Au7 2.9844(15) . ?
Au3 Au8 2.8930(14) . ?
Au3 Au9 2.9529(15) 2_666 ?
Au3 P3 2.316(7) . ?
Au4 Au5 2.8351(15) . ?
Au4 Au6 2.7430(15) . ?
Au4 Au7 2.8618(15) 2_666 ?
Au4 Au9 2.7585(15) . ?
Au4 P2 2.281(7) . ?
Au5 Au6 2.7552(15) . ?
Au5 Au9 2.7790(14) . ?
Au5 P6 2.286(7) . ?
Au6 Au6 2.723(2) 2_666 ?
Au6 Au7 2.8601(13) 2_666 ?
Au6 Au7 2.8415(15) . ?
Au6 Au8 2.8850(15) . ?
Au6 Au8 2.8664(15) 2_666 ?
Au6 Au9 2.7652(14) . ?
Au7 Au4 2.8619(15) 2_666 ?
Au7 Au6 2.8601(13) 2_666 ?
Au7 Au8 2.7248(14) 2_666 ?
Au7 Au9 2.9621(15) 2_666 ?
Au7 Cl2 2.373(7) . ?
Au8 Au6 2.8665(15) 2_666 ?
Au8 Au7 2.7247(14) 2_666 ?
Au8 Au9 2.8933(16) 2_666 ?
Au8 Cl1 2.344(7) . ?
Au9 Au3 2.9529(15) 2_666 ?
Au9 Au7 2.9621(15) 2_666 ?
Au9 Au8 2.8934(16) 2_666 ?
Au9 P4 2.304(7) 2_666 ?
P1 C1 1.81(3) . ?
P1 C7 1.83(3) . ?
P1 C13 1.82(3) . ?
P2 C13 1.85(2) . ?
P2 C14 1.88(3) . ?
P2 C20 1.84(3) . ?
P3 C26 1.82(3) . ?
P3 C32 1.85(3) . ?
P3 C38 1.82(3) . ?
P4 Au9 2.304(7) 2_666 ?
P4 C38 1.84(3) . ?
P4 C39 1.81(3) . ?
P4 C45 1.83(3) . ?
P5 C51 1.84(3) . ?
P5 C57 1.82(4) . ?
P5 C63 1.86(3) . ?
P6 C63 1.83(3) . ?
P6 C64 1.78(3) . ?
P6 C70 1.79(4) . ?
C1 C2 1.45(4) . ?
C1 C6 1.44(4) . ?
C2 C3 1.35(4) . ?
C3 C4 1.42(4) . ?
C4 C5 1.40(4) . ?
C5 C6 1.33(4) . ?
C7 C8 1.41(4) . ?
C7 C12 1.35(4) . ?
C8 C9 1.35(4) . ?
C9 C10 1.36(4) . ?
C10 C11 1.37(4) . ?
C11 C12 1.40(4) . ?
C14 C15 1.31(4) . ?
C14 C19 1.37(4) . ?
C15 C16 1.36(4) . ?
C16 C17 1.38(4) . ?
C17 C18 1.34(4) . ?
C18 C19 1.38(4) . ?
C20 C21 1.36(4) . ?
C20 C25 1.40(4) . ?
C21 C22 1.42(4) . ?
C22 C23 1.34(4) . ?
C23 C24 1.40(4) . ?
C24 C25 1.36(4) . ?
C26 C27 1.41(5) . ?
C26 C31 1.35(5) . ?
C27 C28 1.36(4) . ?
C28 C29 1.38(5) . ?
C29 C30 1.35(4) . ?
C30 C31 1.43(4) . ?
C32 C33 1.41(4) . ?
C32 C37 1.35(4) . ?
C33 C34 1.42(4) . ?
C34 C35 1.30(5) . ?
C35 C36 1.39(4) . ?
C36 C37 1.40(4) . ?
C39 C40 1.41(5) . ?
C39 C44 1.39(5) . ?
C40 C41 1.39(4) . ?
C41 C42 1.39(5) . ?
C42 C43 1.35(5) . ?
C43 C44 1.43(4) . ?
C45 C46 1.43(5) . ?
C45 C50 1.33(5) . ?
C46 C47 1.40(5) . ?
C47 C48 1.36(5) . ?
C48 C49 1.36(5) . ?
C49 C50 1.47(4) . ?
C51 C52 1.35(5) . ?
C51 C56 1.39(5) . ?
C52 C53 1.36(4) . ?
C53 C54 1.40(5) . ?
C54 C55 1.36(5) . ?
C55 C56 1.41(4) . ?
C57 C58 1.34(5) . ?
C57 C62 1.41(5) . ?
C58 C59 1.44(5) . ?
C59 C60 1.36(5) . ?
C60 C61 1.35(5) . ?
C61 C62 1.37(5) . ?
C64 C65 1.42(5) . ?
C64 C69 1.42(4) . ?
C65 C66 1.40(4) . ?
C66 C67 1.35(4) . ?
C67 C68 1.42(5) . ?
C68 C69 1.41(4) . ?
C70 C71 1.41(5) . ?
C70 C75 1.40(5) . ?
C71 C72 1.37(5) . ?
C72 C73 1.37(5) . ?
C73 C74 1.43(5) . ?
C74 C75 1.35(5) . ?
P7 F1 1.58(2) . ?
P7 F1 1.58(2) 2_765 ?
P7 F2 1.60(2) . ?
P7 F2 1.60(2) 2_765 ?
P7 F3 1.58(2) . ?
P7 F3 1.58(2) 2_765 ?
C79 C78 1.3900 . ?
C79 C80 1.3900 . ?
C78 C77 1.3900 . ?
C77 C76 1.3900 . ?
C76 C81 1.3900 . ?
C81 C80 1.3900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au2 Au1 Au4 107.14(5) . . ?
Au2 Au1 Au5 59.83(4) . . ?
Au3 Au1 Au2 58.94(4) . . ?
Au3 Au1 Au4 110.24(5) . . ?
Au3 Au1 Au5 106.94(5) . . ?
Au4 Au1 Au5 57.72(3) . . ?
Au6 Au1 Au2 58.66(3) . . ?
Au6 Au1 Au3 59.16(4) . . ?
Au6 Au1 Au4 58.02(4) . . ?
Au6 Au1 Au5 57.08(3) . . ?
P1 Au1 Au2 143.44(18) . . ?
P1 Au1 Au3 142.48(19) . . ?
P1 Au1 Au4 91.93(18) . . ?
P1 Au1 Au5 110.50(19) . . ?
P1 Au1 Au6 149.91(18) . . ?
Au1 Au2 Au5 62.90(4) . . ?
Au1 Au2 Au7 112.14(4) . . ?
Au3 Au2 Au1 60.11(4) . . ?
Au3 Au2 Au5 110.30(4) . . ?
Au3 Au2 Au7 63.87(4) . . ?
Au6 Au2 Au1 59.67(4) . . ?
Au6 Au2 Au3 59.90(3) . . ?
Au6 Au2 Au5 58.43(4) . . ?
Au6 Au2 Au7 60.78(4) . . ?
Au7 Au2 Au5 107.92(4) . . ?
P5 Au2 Au1 116.7(2) . . ?
P5 Au2 Au3 147.23(19) . . ?
P5 Au2 Au5 93.13(19) . . ?
P5 Au2 Au6 150.60(19) . . ?
P5 Au2 Au7 131.2(2) . . ?
Au1 Au3 Au7 109.58(4) . . ?
Au1 Au3 Au8 87.66(4) . . ?
Au1 Au3 Au9 142.83(4) . 2_666 ?
Au2 Au3 Au1 60.95(4) . . ?
Au2 Au3 Au7 59.84(4) . . ?
Au2 Au3 Au8 120.96(4) . . ?
Au2 Au3 Au9 119.63(4) . 2_666 ?
Au6 Au3 Au1 59.85(4) . . ?
Au6 Au3 Au2 59.56(4) . . ?
Au6 Au3 Au7 59.27(4) . . ?
Au6 Au3 Au8 61.46(4) . . ?
Au6 Au3 Au9 87.57(4) . 2_666 ?
Au8 Au3 Au7 92.25(4) . . ?
Au8 Au3 Au9 59.32(4) . 2_666 ?
Au9 Au3 Au7 59.85(4) 2_666 . ?
P3 Au3 Au1 120.8(2) . . ?
P3 Au3 Au2 125.51(17) . . ?
P3 Au3 Au6 174.86(18) . . ?
P3 Au3 Au7 123.1(2) . . ?
P3 Au3 Au8 113.43(17) . . ?
P3 Au3 Au9 90.06(19) . 2_666 ?
Au5 Au4 Au1 62.93(4) . . ?
Au5 Au4 Au7 111.50(5) . 2_666 ?
Au6 Au4 Au1 58.83(4) . . ?
Au6 Au4 Au5 59.17(4) . . ?
Au6 Au4 Au7 61.32(3) . 2_666 ?
Au6 Au4 Au9 60.35(4) . . ?
Au7 Au4 Au1 109.37(5) 2_666 . ?
Au9 Au4 Au1 110.76(5) . . ?
Au9 Au4 Au5 59.56(4) . . ?
Au9 Au4 Au7 63.58(4) . 2_666 ?
P2 Au4 Au1 93.15(17) . . ?
P2 Au4 Au5 116.27(18) . . ?
P2 Au4 Au6 151.27(18) . . ?
P2 Au4 Au7 132.22(18) . 2_666 ?
P2 Au4 Au9 145.53(19) . . ?
Au2 Au5 Au1 57.27(4) . . ?
Au4 Au5 Au1 59.35(4) . . ?
Au4 Au5 Au2 106.38(5) . . ?
Au6 Au5 Au1 57.45(4) . . ?
Au6 Au5 Au2 57.84(4) . . ?
Au6 Au5 Au4 58.75(4) . . ?
Au6 Au5 Au9 59.95(4) . . ?
Au9 Au5 Au1 107.30(4) . . ?
Au9 Au5 Au2 111.56(5) . . ?
Au9 Au5 Au4 58.85(3) . . ?
P6 Au5 Au1 109.88(19) . . ?
P6 Au5 Au2 92.38(19) . . ?
P6 Au5 Au4 142.5(2) . . ?
P6 Au5 Au6 150.18(19) . . ?
P6 Au5 Au9 142.55(19) . . ?
Au1 Au6 Au7 114.83(4) . . ?
Au1 Au6 Au7 112.88(4) . 2_666 ?
Au1 Au6 Au8 88.42(4) . . ?
Au1 Au6 Au8 146.32(5) . 2_666 ?
Au2 Au6 Au1 61.67(4) . . ?
Au2 Au6 Au3 60.54(4) . . ?
Au2 Au6 Au4 113.81(5) . . ?
Au2 Au6 Au5 63.73(4) . . ?
Au2 Au6 Au7 61.98(4) . . ?
Au2 Au6 Au7 174.50(5) . 2_666 ?
Au2 Au6 Au8 89.47(4) . 2_666 ?
Au2 Au6 Au8 122.23(4) . . ?
Au2 Au6 Au9 117.17(5) . . ?
Au3 Au6 Au1 60.99(4) . . ?
Au3 Au6 Au5 115.33(4) . . ?
Au3 Au6 Au7 64.53(4) . . ?
Au3 Au6 Au7 118.29(4) . 2_666 ?
Au3 Au6 Au8 121.52(5) . 2_666 ?
Au3 Au6 Au8 61.76(4) . . ?
Au3 Au6 Au9 175.14(5) . . ?
Au4 Au6 Au1 63.15(4) . . ?
Au4 Au6 Au3 116.26(5) . . ?
Au4 Au6 Au5 62.08(4) . . ?
Au4 Au6 Au7 175.09(5) . . ?
Au4 Au6 Au7 61.39(4) . 2_666 ?
Au4 Au6 Au8 89.02(4) . . ?
Au4 Au6 Au8 121.81(4) . 2_666 ?
Au4 Au6 Au9 60.11(4) . . ?
Au5 Au6 Au1 65.47(4) . . ?
Au5 Au6 Au7 113.97(5) . 2_666 ?
Au5 Au6 Au7 113.06(4) . . ?
Au5 Au6 Au8 147.15(5) . . ?
Au5 Au6 Au8 87.03(4) . 2_666 ?
Au5 Au6 Au9 60.45(4) . . ?
Au6 Au6 Au1 147.85(6) 2_666 . ?
Au6 Au6 Au2 123.73(6) 2_666 . ?
Au6 Au6 Au3 92.81(5) 2_666 . ?
Au6 Au6 Au4 122.45(5) 2_666 . ?
Au6 Au6 Au5 146.67(6) 2_666 . ?
Au6 Au6 Au7 61.82(4) 2_666 . ?
Au6 Au6 Au7 61.13(4) 2_666 2_666 ?
Au6 Au6 Au8 61.40(4) 2_666 . ?
Au6 Au6 Au8 62.08(4) 2_666 2_666 ?
Au6 Au6 Au9 91.96(5) 2_666 . ?
Au7 Au6 Au7 122.94(4) . 2_666 ?
Au7 Au6 Au8 56.62(3) 2_666 . ?
Au7 Au6 Au8 95.45(4) 2_666 2_666 ?
Au7 Au6 Au8 57.02(3) . 2_666 ?
Au7 Au6 Au8 95.45(4) . . ?
Au8 Au6 Au8 123.48(4) 2_666 . ?
Au9 Au6 Au1 114.21(5) . . ?
Au9 Au6 Au7 118.79(5) . . ?
Au9 Au6 Au7 63.52(4) . 2_666 ?
Au9 Au6 Au8 120.12(4) . . ?
Au9 Au6 Au8 61.80(4) . 2_666 ?
Au2 Au7 Au3 56.28(4) . . ?
Au2 Au7 Au9 115.77(4) . 2_666 ?
Au4 Au7 Au2 170.33(5) 2_666 . ?
Au4 Au7 Au3 115.95(4) 2_666 . ?
Au4 Au7 Au9 56.51(3) 2_666 2_666 ?
Au6 Au7 Au2 57.23(3) . . ?
Au6 Au7 Au2 114.24(5) 2_666 . ?
Au6 Au7 Au3 56.21(3) . . ?
Au6 Au7 Au3 85.33(4) 2_666 . ?
Au6 Au7 Au4 114.30(4) . 2_666 ?
Au6 Au7 Au4 57.29(4) 2_666 2_666 ?
Au6 Au7 Au6 57.06(4) . 2_666 ?
Au6 Au7 Au9 56.68(3) 2_666 2_666 ?
Au6 Au7 Au9 85.67(4) . 2_666 ?
Au8 Au7 Au2 89.56(4) 2_666 . ?
Au8 Au7 Au3 118.13(5) 2_666 . ?
Au8 Au7 Au4 89.86(4) 2_666 2_666 ?
Au8 Au7 Au6 61.95(4) 2_666 . ?
Au8 Au7 Au6 62.15(4) 2_666 2_666 ?
Au8 Au7 Au9 118.81(4) 2_666 2_666 ?
Au9 Au7 Au3 59.55(4) 2_666 . ?
Cl2 Au7 Au2 99.22(19) . . ?
Cl2 Au7 Au3 109.89(18) . . ?
Cl2 Au7 Au4 88.83(19) . 2_666 ?
Cl2 Au7 Au6 156.22(19) . . ?
Cl2 Au7 Au6 145.99(19) . 2_666 ?
Cl2 Au7 Au8 126.82(18) . 2_666 ?
Cl2 Au7 Au9 104.07(18) . 2_666 ?
Au3 Au8 Au9 61.37(4) . 2_666 ?
Au6 Au8 Au3 86.93(4) 2_666 . ?
Au6 Au8 Au3 56.78(3) . . ?
Au6 Au8 Au6 56.52(4) 2_666 . ?
Au6 Au8 Au9 57.38(3) 2_666 2_666 ?
Au6 Au8 Au9 86.17(4) . 2_666 ?
Au7 Au8 Au3 117.92(5) 2_666 . ?
Au7 Au8 Au6 61.23(4) 2_666 . ?
Au7 Au8 Au6 61.03(4) 2_666 2_666 ?
Au7 Au8 Au9 118.38(5) 2_666 2_666 ?
Cl1 Au8 Au3 98.51(19) . . ?
Cl1 Au8 Au6 148.4(2) . . ?
Cl1 Au8 Au6 149.7(2) . 2_666 ?
Cl1 Au8 Au7 136.4(2) . 2_666 ?
Cl1 Au8 Au9 99.2(2) . 2_666 ?
Au3 Au9 Au7 60.60(3) 2_666 2_666 ?
Au4 Au9 Au3 120.39(5) . 2_666 ?
Au4 Au9 Au5 61.59(4) . . ?
Au4 Au9 Au6 59.55(4) . . ?
Au4 Au9 Au7 59.91(4) . 2_666 ?
Au4 Au9 Au8 120.28(4) . 2_666 ?
Au5 Au9 Au3 141.83(5) . 2_666 ?
Au5 Au9 Au7 110.17(4) . 2_666 ?
Au5 Au9 Au8 86.06(4) . 2_666 ?
Au6 Au9 Au3 87.65(4) . 2_666 ?
Au6 Au9 Au5 59.60(4) . . ?
Au6 Au9 Au7 59.80(3) . 2_666 ?
Au6 Au9 Au8 60.82(4) . 2_666 ?
Au8 Au9 Au3 59.31(3) 2_666 2_666 ?
Au8 Au9 Au7 92.70(4) 2_666 2_666 ?
P4 Au9 Au3 92.20(19) 2_666 2_666 ?
P4 Au9 Au4 127.9(2) 2_666 . ?
P4 Au9 Au5 116.75(18) 2_666 . ?
P4 Au9 Au6 170.38(19) 2_666 . ?
P4 Au9 Au7 128.03(17) 2_666 2_666 ?
P4 Au9 Au8 111.0(2) 2_666 2_666 ?
C1 P1 Au1 114.0(11) . . ?
C1 P1 C7 107.5(14) . . ?
C1 P1 C13 105.0(13) . . ?
C7 P1 Au1 115.1(10) . . ?
C13 P1 Au1 111.6(9) . . ?
C13 P1 C7 102.5(13) . . ?
C13 P2 Au4 108.6(8) . . ?
C13 P2 C14 106.0(12) . . ?
C14 P2 Au4 117.0(11) . . ?
C20 P2 Au4 113.1(11) . . ?
C20 P2 C13 100.9(14) . . ?
C20 P2 C14 109.8(15) . . ?
C26 P3 Au3 115.6(12) . . ?
C26 P3 C32 105.1(15) . . ?
C32 P3 Au3 112.7(11) . . ?
C38 P3 Au3 112.8(9) . . ?
C38 P3 C26 103.3(14) . . ?
C38 P3 C32 106.5(15) . . ?
C38 P4 Au9 112.8(10) . 2_666 ?
C39 P4 Au9 113.3(11) . 2_666 ?
C39 P4 C38 104.7(15) . . ?
C39 P4 C45 102.7(16) . . ?
C45 P4 Au9 117.6(12) . 2_666 ?
C45 P4 C38 104.3(16) . . ?
C51 P5 Au2 113.1(13) . . ?
C51 P5 C63 101.5(14) . . ?
C57 P5 Au2 114.6(12) . . ?
C57 P5 C51 109.6(17) . . ?
C57 P5 C63 107.9(15) . . ?
C63 P5 Au2 109.1(9) . . ?
C63 P6 Au5 112.4(10) . . ?
C64 P6 Au5 115.1(11) . . ?
C64 P6 C63 101.8(14) . . ?
C64 P6 C70 110.4(17) . . ?
C70 P6 Au5 111.9(12) . . ?
C70 P6 C63 104.3(15) . . ?
C2 C1 P1 123(2) . . ?
C6 C1 P1 118(2) . . ?
C6 C1 C2 119(3) . . ?
C3 C2 C1 118(3) . . ?
C2 C3 C4 124(3) . . ?
C5 C4 C3 115(3) . . ?
C6 C5 C4 125(3) . . ?
C5 C6 C1 119(3) . . ?
C8 C7 P1 119(2) . . ?
C12 C7 P1 124(2) . . ?
C12 C7 C8 117(3) . . ?
C9 C8 C7 124(3) . . ?
C8 C9 C10 117(3) . . ?
C9 C10 C11 124(3) . . ?
C10 C11 C12 118(3) . . ?
C7 C12 C11 122(3) . . ?
P1 C13 P2 115.0(15) . . ?
C15 C14 P2 122(2) . . ?
C15 C14 C19 123(3) . . ?
C19 C14 P2 115(2) . . ?
C14 C15 C16 120(3) . . ?
C15 C16 C17 119(3) . . ?
C18 C17 C16 119(3) . . ?
C17 C18 C19 121(3) . . ?
C14 C19 C18 117(3) . . ?
C21 C20 P2 122(2) . . ?
C21 C20 C25 120(3) . . ?
C25 C20 P2 118(2) . . ?
C20 C21 C22 120(3) . . ?
C23 C22 C21 121(3) . . ?
C22 C23 C24 119(3) . . ?
C25 C24 C23 121(3) . . ?
C24 C25 C20 119(3) . . ?
C27 C26 P3 123(3) . . ?
C31 C26 P3 117(2) . . ?
C31 C26 C27 120(3) . . ?
C28 C27 C26 121(4) . . ?
C27 C28 C29 119(3) . . ?
C30 C29 C28 120(3) . . ?
C29 C30 C31 122(4) . . ?
C26 C31 C30 118(3) . . ?
C33 C32 P3 120(3) . . ?
C37 C32 P3 117(2) . . ?
C37 C32 C33 122(3) . . ?
C32 C33 C34 114(3) . . ?
C35 C34 C33 125(3) . . ?
C34 C35 C36 118(3) . . ?
C35 C36 C37 121(3) . . ?
C32 C37 C36 118(3) . . ?
P3 C38 P4 112.9(14) . . ?
C40 C39 P4 124(3) . . ?
C44 C39 P4 115(3) . . ?
C44 C39 C40 121(3) . . ?
C41 C40 C39 118(3) . . ?
C42 C41 C40 122(3) . . ?
C43 C42 C41 119(3) . . ?
C42 C43 C44 123(3) . . ?
C39 C44 C43 117(3) . . ?
C46 C45 P4 119(3) . . ?
C50 C45 P4 118(3) . . ?
C50 C45 C46 123(3) . . ?
C47 C46 C45 115(3) . . ?
C48 C47 C46 124(3) . . ?
C49 C48 C47 120(3) . . ?
C48 C49 C50 118(3) . . ?
C45 C50 C49 119(3) . . ?
C52 C51 P5 118(3) . . ?
C52 C51 C56 120(3) . . ?
C56 C51 P5 121(3) . . ?
C51 C52 C53 125(4) . . ?
C52 C53 C54 116(4) . . ?
C55 C54 C53 121(3) . . ?
C54 C55 C56 122(4) . . ?
C51 C56 C55 117(4) . . ?
C58 C57 P5 117(3) . . ?
C58 C57 C62 121(3) . . ?
C62 C57 P5 122(3) . . ?
C57 C58 C59 120(3) . . ?
C60 C59 C58 117(4) . . ?
C61 C60 C59 123(4) . . ?
C60 C61 C62 120(3) . . ?
C61 C62 C57 119(4) . . ?
P6 C63 P5 116.1(16) . . ?
C65 C64 P6 119(3) . . ?
C65 C64 C69 120(3) . . ?
C69 C64 P6 122(3) . . ?
C66 C65 C64 120(3) . . ?
C67 C66 C65 119(3) . . ?
C66 C67 C68 123(3) . . ?
C69 C68 C67 118(3) . . ?
C68 C69 C64 119(3) . . ?
C71 C70 P6 124(3) . . ?
C75 C70 P6 119(3) . . ?
C75 C70 C71 117(3) . . ?
C72 C71 C70 121(3) . . ?
C71 C72 C73 122(4) . . ?
C72 C73 C74 118(4) . . ?
C75 C74 C73 120(3) . . ?
C74 C75 C70 122(4) . . ?
F1 P7 F1 180.0(8) 2_765 . ?
F1 P7 F2 92.0(13) 2_765 2_765 ?
F1 P7 F2 92.0(13) . . ?
F1 P7 F2 88.0(13) 2_765 . ?
F1 P7 F2 88.0(13) . 2_765 ?
F2 P7 F2 180.0 2_765 . ?
F3 P7 F1 90.3(15) . . ?
F3 P7 F1 89.7(15) . 2_765 ?
F3 P7 F1 89.7(15) 2_765 . ?
F3 P7 F1 90.3(15) 2_765 2_765 ?
F3 P7 F2 90.1(13) . . ?
F3 P7 F2 90.1(13) 2_765 2_765 ?
F3 P7 F2 89.9(13) 2_765 . ?
F3 P7 F2 89.9(13) . 2_765 ?
F3 P7 F3 180.0 . 2_765 ?
C78 C79 C80 120.0 . . ?
C77 C78 C79 120.0 . . ?
C76 C77 C78 120.0 . . ?
C77 C76 C81 120.0 . . ?
C76 C81 C80 120.0 . . ?
C81 C80 C79 120.0 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
