# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Eu-MOF
_database_code_depnum_ccdc_archive 'CCDC 1849335'
loop_
_audit_author_name
_audit_author_address
'Wei-Ming Liao'
;Sun Yat-Sen university
China
;
_audit_update_record             
;
2018-06-14 deposited with the CCDC.	2019-02-25 downloaded from the CCDC.
;
_audit_creation_date             2018-06-14
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.08.25 svn.r3337 for OlexSys, GUI svn.r5221)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22 H11 Eu N O8, C2 H8 N, H2 O [+ solvent]'
_chemical_formula_sum            'C24 H21 Eu N2 O9 [+ solvent]'
_chemical_formula_weight         633.40
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.0077(6)
_cell_length_b                   10.3815(5)
_cell_length_c                   15.9271(7)
_cell_angle_alpha                71.109(4)
_cell_angle_beta                 85.541(4)
_cell_angle_gamma                64.379(5)
_cell_volume                     1407.91(13)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    5954
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      65.1380
_cell_measurement_theta_min      4.8870
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    16.372
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.74140
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.494
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             628
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0560
_diffrn_reflns_av_unetI/netI     0.0528
_diffrn_reflns_Laue_measured_fraction_full 0.969
_diffrn_reflns_Laue_measured_fraction_max 0.969
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            8447
_diffrn_reflns_point_group_measured_fraction_full 0.969
_diffrn_reflns_point_group_measured_fraction_max 0.969
_diffrn_reflns_theta_full        65.381
_diffrn_reflns_theta_max         65.381
_diffrn_reflns_theta_min         4.909
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'SuperNova (Cu) X-ray Source'
_diffrn_measurement_method       ?
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4437
_reflns_number_total             4680
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.395
_refine_diff_density_min         -2.672
_refine_diff_density_rms         0.179
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     369
_refine_ls_number_reflns         4680
_refine_ls_number_restraints     144
_refine_ls_R_factor_all          0.0588
_refine_ls_R_factor_gt           0.0573
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1256P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1509
_refine_ls_wR_factor_ref         0.1535
_refine_special_details          SQUEEZE
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
C13 \\sim C10A \\sim C14 \\sim C11A \\sim C13A \\sim C10 \\sim C14A \\sim C11:
within 2A with sigma of 0.04 and sigma for terminal atoms of 0.08
Uanis(O1) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C13A) \\sim Ueq, Uanis(C14A) \\sim Ueq, Uanis(C10A) \\sim Ueq,
Uanis(C11A) \\sim Ueq, Uanis(C11) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C13)
\\sim Ueq, Uanis(C14) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(O9) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(N2) = Uanis(N2A)
3. Others
 Fixed Sof: C13A(0.5) H13A(0.5) C14A(0.5) C10A(0.5) H10A(0.5) C11A(0.5)
 H11A(0.5) C11(0.5) H11(0.5) C10(0.5) H10(0.5) C13(0.5) H13(0.5) C14(0.5)
 N2A(0.5) H2AA(0.5) H2AB(0.5) N2(0.5) H2A(0.5) H2B(0.5)
4.a Free rotating group:
 O9(H9A,H9B)
4.b Secondary CH2 refined with riding coordinates:
 N1(H1A,H1B)
4.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C19(H19), C16(H16), C8(H8), C6(H6), C21(H21), C13A(H13A), C10A(H10A),
 C11A(H11A), C11(H11), C10(H10), C13(H13)
4.d X=CH2 refined with riding coordinates:
 N2A(H2AA,H2AB), N2(H2A,H2B)
4.e Idealised Me refined as rotating group:
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.09230(3) 0.27659(3) 0.08378(2) 0.01505(17) Uani 1 1 d . . . . .
O1 O 0.0046(4) 0.6120(5) 0.0634(3) 0.0230(9) Uani 1 1 d . U . . .
O5 O 0.1593(5) 0.5846(5) 0.8916(3) 0.0268(9) Uani 1 1 d . . . . .
O6 O 0.2609(5) 0.3706(5) 1.0040(3) 0.0241(9) Uani 1 1 d . . . . .
O7 O 0.7108(5) -0.0426(5) 0.9340(3) 0.0281(10) Uani 1 1 d . . . . .
O2 O 0.1157(5) 0.4046(5) 0.1777(3) 0.0287(10) Uani 1 1 d . . . . .
O8 O 0.6583(5) -0.1101(4) 0.8283(3) 0.0257(9) Uani 1 1 d . . . . .
C0AA C 0.0640(6) 0.5464(6) 0.1411(4) 0.0197(12) Uani 1 1 d . . . . .
C2 C 0.0762(7) 0.6369(6) 0.1937(4) 0.0221(12) Uani 1 1 d . . . . .
C18 C 0.2427(6) 0.4464(6) 0.9221(4) 0.0181(11) Uani 1 1 d . . . . .
C3 C 0.0376(7) 0.7885(7) 0.1556(4) 0.0249(13) Uani 1 1 d . . . . .
H3 H -0.0002 0.8373 0.0966 0.030 Uiso 1 1 calc R . . . .
C20 C 0.5035(7) 0.1391(7) 0.8324(4) 0.0242(13) Uani 1 1 d . . . . .
C4 C 0.0550(7) 0.8692(7) 0.2056(4) 0.0230(12) Uani 1 1 d . . . . .
C17 C 0.3225(7) 0.3652(7) 0.8583(4) 0.0227(12) Uani 1 1 d . . . . .
C22 C 0.6308(7) -0.0139(7) 0.8665(4) 0.0250(13) Uani 1 1 d . . . . .
C7 C 0.1471(9) 0.6426(8) 0.3349(4) 0.0316(15) Uani 1 1 d . . . . .
C19 C 0.4330(7) 0.2197(7) 0.8907(4) 0.0221(12) Uani 1 1 d . . . . .
H19 H 0.4604 0.1754 0.9514 0.027 Uiso 1 1 calc R . . . .
C16 C 0.2830(7) 0.4310(7) 0.7681(4) 0.0294(14) Uani 1 1 d . . . . .
H16 H 0.2110 0.5302 0.7466 0.035 Uiso 1 1 calc R . . . .
C15 C 0.3485(8) 0.3523(7) 0.7083(4) 0.0326(15) Uani 1 1 d . . . . .
C8 C 0.1315(8) 0.5628(7) 0.2835(4) 0.0298(14) Uani 1 1 d . . . . .
H8 H 0.1578 0.4600 0.3087 0.036 Uiso 1 1 calc R . . . .
C6 C 0.1103(8) 0.7938(7) 0.2950(4) 0.0295(14) Uani 1 1 d . . . . .
H6 H 0.1223 0.8477 0.3282 0.035 Uiso 1 1 calc R . . . .
C12 C 0.3016(9) 0.4250(8) 0.6119(4) 0.0380(17) Uani 1 1 d . . . . .
C9 C 0.2039(9) 0.5642(8) 0.4304(4) 0.0353(16) Uani 1 1 d . . . . .
C21 C 0.4592(8) 0.2042(7) 0.7421(4) 0.0301(14) Uani 1 1 d . . . . .
H21 H 0.5034 0.1488 0.7037 0.036 Uiso 1 1 calc R . . . .
O9 O 0.2936(8) 0.8314(10) -0.0168(6) 0.073(2) Uani 1 1 d . U . . .
H9A H 0.2146 0.8421 -0.0405 0.109 Uiso 1 1 d G . . . .
H9B H 0.3092 0.9089 -0.0422 0.109 Uiso 1 1 d G . . . .
N1 N 0.5244(11) 0.2630(14) 0.1448(7) 0.084(3) Uani 1 1 d . . . . .
H1A H 0.5655 0.2451 0.0958 0.101 Uiso 1 1 calc R . . . .
H1B H 0.4521 0.2328 0.1547 0.101 Uiso 1 1 calc R . . . .
C23 C 0.4616(15) 0.4214(18) 0.1305(12) 0.098(5) Uani 1 1 d . . . . .
H23A H 0.3852 0.4734 0.0828 0.147 Uiso 1 1 calc GR . . . .
H23B H 0.5377 0.4562 0.1153 0.147 Uiso 1 1 calc GR . . . .
H23C H 0.4197 0.4412 0.1838 0.147 Uiso 1 1 calc GR . . . .
C13A C 0.2812(16) 0.6199(16) 0.4711(9) 0.033(3) Uani 0.5 1 d . U P A 2
H13A H 0.2990 0.7020 0.4375 0.039 Uiso 0.5 1 calc R . P A 2
C14A C 0.3292(15) 0.5518(14) 0.5604(8) 0.029(3) Uani 0.5 1 d . U P A 2
C10A C 0.2390(18) 0.3676(16) 0.5692(9) 0.038(3) Uani 0.5 1 d . U P A 2
H10A H 0.2294 0.2798 0.6008 0.045 Uiso 0.5 1 calc R . P A 2
C11A C 0.1895(17) 0.4363(15) 0.4803(9) 0.033(3) Uani 0.5 1 d . U P A 2
H11A H 0.1455 0.3951 0.4538 0.039 Uiso 0.5 1 calc R . P A 2
C11 C 0.160(2) 0.542(2) 0.5838(13) 0.065(5) Uani 0.5 1 d . U P A 1
H11 H 0.0948 0.5706 0.6263 0.078 Uiso 0.5 1 calc R . P A 1
C10 C 0.114(3) 0.615(3) 0.4964(13) 0.069(5) Uani 0.5 1 d . U P A 1
H10 H 0.0222 0.6988 0.4799 0.083 Uiso 0.5 1 calc R . P A 1
C13 C 0.375(3) 0.372(3) 0.5469(14) 0.076(5) Uani 0.5 1 d . U P A 1
H13 H 0.4642 0.2845 0.5627 0.091 Uiso 0.5 1 calc R . P A 1
C14 C 0.326(3) 0.440(3) 0.4595(15) 0.079(6) Uani 0.5 1 d . U P A 1
N2A N 0.397(3) 0.621(4) 0.5956(17) 0.140(8) Uani 0.5 1 d . . P A 2
H2AA H 0.4053 0.6996 0.5619 0.168 Uiso 0.5 1 calc R . P A 2
H2AB H 0.4285 0.5831 0.6508 0.168 Uiso 0.5 1 calc R . P A 2
N2 N 0.431(3) 0.381(4) 0.3937(17) 0.140(8) Uani 0.5 1 d . . P A 1
H2A H 0.4100 0.4293 0.3377 0.168 Uiso 0.5 1 calc R . P A 1
H2B H 0.5112 0.2995 0.4121 0.168 Uiso 0.5 1 calc R . P A 1
C24 C 0.643(2) 0.170(2) 0.2237(11) 0.133(6) Uani 1 1 d . . . . .
H24A H 0.7264 0.1932 0.2104 0.199 Uiso 1 1 calc GR . . . .
H24B H 0.6739 0.0643 0.2340 0.199 Uiso 1 1 calc GR . . . .
H24C H 0.6010 0.1943 0.2760 0.199 Uiso 1 1 calc GR . . . .
O3 O -0.0168(5) 1.0997(5) 0.0841(3) 0.0274(9) Uani 1 1 d . . . . .
O4 O 0.0619(5) 1.0914(5) 0.2120(3) 0.0285(10) Uani 1 1 d . . . . .
C5 C 0.0297(7) 1.0297(7) 0.1647(4) 0.0235(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.324(4) 2_565 ?
Eu1 O1 3.110(4) . ?
Eu1 O5 2.376(4) 2_566 ?
Eu1 O6 2.388(4) 1_554 ?
Eu1 O7 2.467(4) 2_656 ?
Eu1 O2 2.381(4) . ?
Eu1 O8 2.534(4) 2_656 ?
Eu1 C0AA 3.113(5) . ?
Eu1 C22 2.855(6) 2_656 ?
Eu1 O3 2.508(4) 1_545 ?
Eu1 O4 2.414(4) 1_545 ?
Eu1 C5 2.783(6) 1_545 ?
O1 Eu1 2.324(4) 2_565 ?
O1 C0AA 1.251(7) . ?
O5 Eu1 2.376(4) 2_566 ?
O5 C18 1.252(7) . ?
O6 Eu1 2.388(4) 1_556 ?
O6 C18 1.265(7) . ?
O7 Eu1 2.467(4) 2_656 ?
O7 C22 1.267(8) . ?
O2 C0AA 1.267(7) . ?
O8 Eu1 2.534(4) 2_656 ?
O8 C22 1.254(7) . ?
C0AA C2 1.490(8) . ?
C2 C3 1.374(8) . ?
C2 C8 1.409(8) . ?
C18 C17 1.493(8) . ?
C3 H3 0.9300 . ?
C3 C4 1.394(8) . ?
C20 C22 1.497(9) . ?
C20 C19 1.397(9) . ?
C20 C21 1.389(9) . ?
C4 C6 1.405(8) . ?
C4 C5 1.492(8) . ?
C17 C19 1.382(8) . ?
C17 C16 1.381(8) . ?
C22 Eu1 2.855(6) 2_656 ?
C7 C8 1.398(9) . ?
C7 C6 1.376(9) . ?
C7 C9 1.493(9) . ?
C19 H19 0.9300 . ?
C16 H16 0.9300 . ?
C16 C15 1.395(9) . ?
C15 C12 1.485(8) . ?
C15 C21 1.402(9) . ?
C8 H8 0.9300 . ?
C6 H6 0.9300 . ?
C12 C14A 1.437(16) . ?
C12 C10A 1.363(15) . ?
C12 C11 1.39(2) . ?
C12 C13 1.35(2) . ?
C9 C13A 1.436(14) . ?
C9 C11A 1.371(15) . ?
C9 C10 1.41(2) . ?
C9 C14 1.31(2) . ?
C21 H21 0.9300 . ?
O9 H9A 0.8501 . ?
O9 H9B 0.8501 . ?
N1 H1A 0.8900 . ?
N1 H1B 0.8900 . ?
N1 C23 1.428(18) . ?
N1 C24 1.54(2) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C13A H13A 0.9300 . ?
C13A C14A 1.383(18) . ?
C14A N2A 1.42(3) . ?
C10A H10A 0.9300 . ?
C10A C11A 1.382(18) . ?
C11A H11A 0.9300 . ?
C11 H11 0.9300 . ?
C11 C10 1.35(3) . ?
C10 H10 0.9300 . ?
C13 H13 0.9300 . ?
C13 C14 1.36(3) . ?
C14 N2 1.50(3) . ?
N2A H2AA 0.8600 . ?
N2A H2AB 0.8600 . ?
N2 H2A 0.8600 . ?
N2 H2B 0.8600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
O3 Eu1 2.508(4) 1_565 ?
O3 C5 1.260(7) . ?
O4 Eu1 2.414(4) 1_565 ?
O4 C5 1.269(8) . ?
C5 Eu1 2.783(6) 1_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O1 80.79(13) 2_565 . ?
O1 Eu1 O5 81.60(14) 2_565 2_566 ?
O1 Eu1 O6 74.56(14) 2_565 1_554 ?
O1 Eu1 O7 96.53(14) 2_565 2_656 ?
O1 Eu1 O2 125.85(14) 2_565 . ?
O1 Eu1 O8 139.10(14) 2_565 2_656 ?
O1 Eu1 C0AA 23.20(13) . . ?
O1 Eu1 C0AA 103.96(14) 2_565 . ?
O1 Eu1 C22 120.48(16) 2_565 2_656 ?
O1 Eu1 O3 82.69(13) 2_565 1_545 ?
O1 Eu1 O4 134.56(14) 2_565 1_545 ?
O1 Eu1 C5 109.61(16) 2_565 1_545 ?
O5 Eu1 O1 65.27(13) 2_566 . ?
O5 Eu1 O6 128.34(14) 2_566 1_554 ?
O5 Eu1 O7 149.06(15) 2_566 2_656 ?
O5 Eu1 O2 77.83(16) 2_566 . ?
O5 Eu1 O8 139.13(14) 2_566 2_656 ?
O5 Eu1 C0AA 70.44(15) 2_566 . ?
O5 Eu1 C22 151.28(16) 2_566 2_656 ?
O5 Eu1 O3 78.80(15) 2_566 1_545 ?
O5 Eu1 O4 79.97(15) 2_566 1_545 ?
O5 Eu1 C5 83.10(17) 2_566 1_545 ?
O6 Eu1 O1 66.09(13) 1_554 . ?
O6 Eu1 O7 79.73(15) 1_554 2_656 ?
O6 Eu1 O8 74.40(15) 1_554 2_656 ?
O6 Eu1 C0AA 71.93(14) 1_554 . ?
O6 Eu1 C22 78.24(17) 1_554 2_656 ?
O6 Eu1 O3 139.81(14) 1_554 1_545 ?
O6 Eu1 O4 146.06(16) 1_554 1_545 ?
O6 Eu1 C5 148.04(17) 1_554 1_545 ?
O7 Eu1 O1 145.25(13) 2_656 . ?
O7 Eu1 O8 52.05(13) 2_656 2_656 ?
O7 Eu1 C0AA 138.67(15) 2_656 . ?
O7 Eu1 C22 26.26(16) 2_656 2_656 ?
O7 Eu1 O3 70.35(15) 2_656 1_545 ?
O7 Eu1 C5 68.35(17) 2_656 1_545 ?
O2 Eu1 O1 45.11(13) . . ?
O2 Eu1 O6 80.27(15) . 1_554 ?
O2 Eu1 O7 125.11(14) . 2_656 ?
O2 Eu1 O8 73.43(14) . 2_656 ?
O2 Eu1 C0AA 21.91(15) . . ?
O2 Eu1 C22 99.47(16) . 2_656 ?
O2 Eu1 O3 139.15(15) . 1_545 ?
O2 Eu1 O4 89.93(14) . 1_545 ?
O2 Eu1 C5 116.74(17) . 1_545 ?
O8 Eu1 O1 109.63(12) 2_656 . ?
O8 Eu1 C0AA 90.95(14) 2_656 . ?
O8 Eu1 C22 26.04(16) 2_656 2_656 ?
O8 Eu1 C5 84.53(16) 2_656 1_545 ?
C22 Eu1 O1 131.84(15) 2_656 . ?
C22 Eu1 C0AA 116.17(17) 2_656 . ?
O3 Eu1 O1 142.16(12) 1_545 . ?
O3 Eu1 O8 105.15(13) 1_545 2_656 ?
O3 Eu1 C0AA 146.95(15) 1_545 . ?
O3 Eu1 C22 85.73(16) 1_545 2_656 ?
O3 Eu1 C5 26.93(16) 1_545 1_545 ?
O4 Eu1 O1 126.32(13) 1_545 . ?
O4 Eu1 O7 79.70(15) 1_545 2_656 ?
O4 Eu1 O8 71.66(15) 1_545 2_656 ?
O4 Eu1 C0AA 108.23(14) 1_545 . ?
O4 Eu1 C22 71.40(17) 1_545 2_656 ?
O4 Eu1 O3 53.15(13) 1_545 1_545 ?
O4 Eu1 C5 27.08(16) 1_545 1_545 ?
C5 Eu1 O1 145.26(15) 1_545 . ?
C5 Eu1 C0AA 133.21(16) 1_545 . ?
C5 Eu1 C22 72.53(18) 1_545 2_656 ?
Eu1 O1 Eu1 99.22(13) 2_565 . ?
C0AA O1 Eu1 78.5(3) . . ?
C0AA O1 Eu1 176.4(4) . 2_565 ?
C18 O5 Eu1 130.2(4) . 2_566 ?
C18 O6 Eu1 124.8(4) . 1_556 ?
C22 O7 Eu1 94.2(3) . 2_656 ?
C0AA O2 Eu1 113.6(3) . . ?
C22 O8 Eu1 91.4(4) . 2_656 ?
O1 C0AA Eu1 78.3(3) . . ?
O1 C0AA O2 122.8(5) . . ?
O1 C0AA C2 119.4(5) . . ?
O2 C0AA Eu1 44.5(3) . . ?
O2 C0AA C2 117.8(5) . . ?
C2 C0AA Eu1 162.3(4) . . ?
C3 C2 C0AA 121.2(5) . . ?
C3 C2 C8 120.2(5) . . ?
C8 C2 C0AA 118.5(5) . . ?
O5 C18 O6 123.8(5) . . ?
O5 C18 C17 118.3(5) . . ?
O6 C18 C17 118.0(5) . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 120.0(5) . . ?
C4 C3 H3 120.0 . . ?
C19 C20 C22 120.0(5) . . ?
C21 C20 C22 120.2(5) . . ?
C21 C20 C19 119.8(6) . . ?
C3 C4 C6 119.2(5) . . ?
C3 C4 C5 121.8(5) . . ?
C6 C4 C5 118.8(5) . . ?
C19 C17 C18 119.3(5) . . ?
C16 C17 C18 120.9(5) . . ?
C16 C17 C19 119.8(6) . . ?
O7 C22 Eu1 59.5(3) . 2_656 ?
O7 C22 C20 118.3(5) . . ?
O8 C22 Eu1 62.5(3) . 2_656 ?
O8 C22 O7 121.1(6) . . ?
O8 C22 C20 120.6(6) . . ?
C20 C22 Eu1 169.1(4) . 2_656 ?
C8 C7 C9 120.4(6) . . ?
C6 C7 C8 118.2(6) . . ?
C6 C7 C9 121.4(6) . . ?
C20 C19 H19 120.0 . . ?
C17 C19 C20 120.0(6) . . ?
C17 C19 H19 120.0 . . ?
C17 C16 H16 119.2 . . ?
C17 C16 C15 121.6(6) . . ?
C15 C16 H16 119.2 . . ?
C16 C15 C12 120.4(6) . . ?
C16 C15 C21 118.1(6) . . ?
C21 C15 C12 121.5(6) . . ?
C2 C8 H8 119.7 . . ?
C7 C8 C2 120.5(6) . . ?
C7 C8 H8 119.7 . . ?
C4 C6 H6 119.1 . . ?
C7 C6 C4 121.9(6) . . ?
C7 C6 H6 119.1 . . ?
C14A C12 C15 120.6(7) . . ?
C10A C12 C15 120.8(8) . . ?
C10A C12 C14A 118.5(9) . . ?
C11 C12 C15 119.9(10) . . ?
C13 C12 C15 125.0(11) . . ?
C13 C12 C11 114.1(13) . . ?
C13A C9 C7 119.6(8) . . ?
C11A C9 C7 122.1(8) . . ?
C11A C9 C13A 118.3(9) . . ?
C10 C9 C7 119.1(10) . . ?
C14 C9 C7 124.7(11) . . ?
C14 C9 C10 115.8(14) . . ?
C20 C21 C15 120.7(6) . . ?
C20 C21 H21 119.7 . . ?
C15 C21 H21 119.7 . . ?
H9A O9 H9B 109.5 . . ?
H1A N1 H1B 107.8 . . ?
C23 N1 H1A 109.0 . . ?
C23 N1 H1B 109.0 . . ?
C23 N1 C24 112.9(11) . . ?
C24 N1 H1A 109.0 . . ?
C24 N1 H1B 109.0 . . ?
N1 C23 H23A 109.5 . . ?
N1 C23 H23B 109.5 . . ?
N1 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C9 C13A H13A 119.9 . . ?
C14A C13A C9 120.1(12) . . ?
C14A C13A H13A 119.9 . . ?
C13A C14A C12 119.6(10) . . ?
C13A C14A N2A 115.8(16) . . ?
N2A C14A C12 124.5(15) . . ?
C12 C10A H10A 119.1 . . ?
C12 C10A C11A 121.8(12) . . ?
C11A C10A H10A 119.1 . . ?
C9 C11A C10A 121.3(11) . . ?
C9 C11A H11A 119.4 . . ?
C10A C11A H11A 119.4 . . ?
C12 C11 H11 119.0 . . ?
C10 C11 C12 122.1(18) . . ?
C10 C11 H11 119.0 . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.3(18) . . ?
C11 C10 H10 119.8 . . ?
C12 C13 H13 118.5 . . ?
C12 C13 C14 123(2) . . ?
C14 C13 H13 118.5 . . ?
C9 C14 C13 123.2(19) . . ?
C9 C14 N2 119(2) . . ?
C13 C14 N2 117(2) . . ?
C14A N2A H2AA 120.0 . . ?
C14A N2A H2AB 120.0 . . ?
H2AA N2A H2AB 120.0 . . ?
C14 N2 H2A 120.0 . . ?
C14 N2 H2B 120.0 . . ?
H2A N2 H2B 120.0 . . ?
N1 C24 H24A 109.5 . . ?
N1 C24 H24B 109.5 . . ?
N1 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C5 O3 Eu1 88.8(4) . 1_565 ?
C5 O4 Eu1 92.9(3) . 1_565 ?
C4 C5 Eu1 159.2(4) . 1_565 ?
O3 C5 Eu1 64.3(3) . 1_565 ?
O3 C5 C4 120.4(5) . . ?
O3 C5 O4 121.2(6) . . ?
O4 C5 Eu1 60.0(3) . 1_565 ?
O4 C5 C4 118.3(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C0AA O2 -0.7(5) . . . . ?
Eu1 O1 C0AA C2 179.0(5) . . . . ?
Eu1 O5 C18 O6 -50.0(8) 2_566 . . . ?
Eu1 O5 C18 C17 128.4(5) 2_566 . . . ?
Eu1 O6 C18 O5 79.6(7) 1_556 . . . ?
Eu1 O6 C18 C17 -98.8(5) 1_556 . . . ?
Eu1 O7 C22 O8 11.3(6) 2_656 . . . ?
Eu1 O7 C22 C20 -167.7(5) 2_656 . . . ?
Eu1 O2 C0AA O1 1.0(7) . . . . ?
Eu1 O2 C0AA C2 -178.7(4) . . . . ?
Eu1 O8 C22 O7 -11.0(6) 2_656 . . . ?
Eu1 O8 C22 C20 168.0(5) 2_656 . . . ?
Eu1 C0AA C2 C3 169.9(10) . . . . ?
Eu1 C0AA C2 C8 -8.8(17) . . . . ?
Eu1 O3 C5 C4 -157.0(5) 1_565 . . . ?
Eu1 O3 C5 O4 20.0(6) 1_565 . . . ?
Eu1 O4 C5 C4 156.2(5) 1_565 . . . ?
Eu1 O4 C5 O3 -20.8(6) 1_565 . . . ?
O1 C0AA C2 C3 -6.8(9) . . . . ?
O1 C0AA C2 C8 174.5(6) . . . . ?
O5 C18 C17 C19 169.5(5) . . . . ?
O5 C18 C17 C16 -13.3(9) . . . . ?
O6 C18 C17 C19 -12.0(8) . . . . ?
O6 C18 C17 C16 165.2(6) . . . . ?
O2 C0AA C2 C3 172.9(6) . . . . ?
O2 C0AA C2 C8 -5.8(9) . . . . ?
C0AA C2 C3 C4 -177.8(6) . . . . ?
C0AA C2 C8 C7 179.0(6) . . . . ?
C2 C3 C4 C6 -0.9(10) . . . . ?
C2 C3 C4 C5 173.5(6) . . . . ?
C18 C17 C19 C20 176.7(6) . . . . ?
C18 C17 C16 C15 -174.9(6) . . . . ?
C3 C2 C8 C7 0.2(10) . . . . ?
C3 C4 C6 C7 -0.3(11) . . . . ?
C3 C4 C5 Eu1 -93.4(13) . . . 1_565 ?
C3 C4 C5 O3 4.1(10) . . . . ?
C3 C4 C5 O4 -173.0(6) . . . . ?
C17 C16 C15 C12 178.7(7) . . . . ?
C17 C16 C15 C21 -1.5(11) . . . . ?
C22 C20 C19 C17 175.4(6) . . . . ?
C22 C20 C21 C15 -174.6(6) . . . . ?
C7 C9 C13A C14A 177.5(11) . . . . ?
C7 C9 C11A C10A -178.2(12) . . . . ?
C7 C9 C10 C11 177.2(18) . . . . ?
C7 C9 C14 C13 179(2) . . . . ?
C7 C9 C14 N2 10(3) . . . . ?
C19 C20 C22 Eu1 -104(2) . . . 2_656 ?
C19 C20 C22 O7 -28.7(9) . . . . ?
C19 C20 C22 O8 152.3(6) . . . . ?
C19 C20 C21 C15 2.7(11) . . . . ?
C19 C17 C16 C15 2.3(10) . . . . ?
C16 C17 C19 C20 -0.6(9) . . . . ?
C16 C15 C12 C14A 65.9(12) . . . . ?
C16 C15 C12 C10A -117.8(11) . . . . ?
C16 C15 C12 C11 -25.3(15) . . . . ?
C16 C15 C12 C13 166.5(15) . . . . ?
C16 C15 C21 C20 -1.0(11) . . . . ?
C15 C12 C14A C13A -178.4(11) . . . . ?
C15 C12 C14A N2A -2(2) . . . . ?
C15 C12 C10A C11A 177.6(12) . . . . ?
C15 C12 C11 C10 177.8(18) . . . . ?
C15 C12 C13 C14 178(2) . . . . ?
C8 C2 C3 C4 0.9(10) . . . . ?
C8 C7 C6 C4 1.4(11) . . . . ?
C8 C7 C9 C13A 152.2(9) . . . . ?
C8 C7 C9 C11A -25.5(14) . . . . ?
C8 C7 C9 C10 -120.7(13) . . . . ?
C8 C7 C9 C14 51.4(18) . . . . ?
C6 C4 C5 Eu1 81.0(13) . . . 1_565 ?
C6 C4 C5 O3 178.5(6) . . . . ?
C6 C4 C5 O4 1.4(9) . . . . ?
C6 C7 C8 C2 -1.4(11) . . . . ?
C6 C7 C9 C13A -27.2(13) . . . . ?
C6 C7 C9 C11A 155.2(10) . . . . ?
C6 C7 C9 C10 60.0(15) . . . . ?
C6 C7 C9 C14 -127.9(17) . . . . ?
C12 C15 C21 C20 178.8(7) . . . . ?
C12 C10A C11A C9 1(2) . . . . ?
C12 C11 C10 C9 6(3) . . . . ?
C12 C13 C14 C9 1(4) . . . . ?
C12 C13 C14 N2 171(2) . . . . ?
C9 C7 C8 C2 179.2(7) . . . . ?
C9 C7 C6 C4 -179.2(7) . . . . ?
C9 C13A C14A C12 0.1(19) . . . . ?
C9 C13A C14A N2A -176.4(16) . . . . ?
C21 C20 C22 Eu1 73(2) . . . 2_656 ?
C21 C20 C22 O7 148.6(7) . . . . ?
C21 C20 C22 O8 -30.4(9) . . . . ?
C21 C20 C19 C17 -1.9(10) . . . . ?
C21 C15 C12 C14A -113.9(10) . . . . ?
C21 C15 C12 C10A 62.4(13) . . . . ?
C21 C15 C12 C11 154.9(13) . . . . ?
C21 C15 C12 C13 -13.3(18) . . . . ?
C13A C9 C11A C10A 4(2) . . . . ?
C14A C12 C10A C11A -6(2) . . . . ?
C10A C12 C14A C13A 5.2(18) . . . . ?
C10A C12 C14A N2A -178.5(18) . . . . ?
C11A C9 C13A C14A -4.8(18) . . . . ?
C11 C12 C13 C14 9(3) . . . . ?
C10 C9 C14 C13 -8(3) . . . . ?
C10 C9 C14 N2 -178(2) . . . . ?
C13 C12 C11 C10 -13(3) . . . . ?
C14 C9 C10 C11 4(3) . . . . ?
C5 C4 C6 C7 -174.9(6) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'

# SQUEEZE RESULTS (APPEND TO CIF)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.023 0.000 0.500 236 63 ' '
_platon_squeeze_details          ?
_exptl_crystal_recrystallization_method 'solvothermal method'
_exptl_crystal_preparation       Luminescent
