# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

 
data_RhClP2Anil2 
  
_audit_creation_method            'SHELXL-2014/7' 
_shelx_SHELXL_version_number      '2014/7' 
_chemical_name_systematic         ? 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'C22 H40 B10 Cl N2 P2 Rh S2' 
_chemical_formula_weight          705.08 
  
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'B'  'B'   0.0013   0.0007 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'S'  'S'   0.1246   0.1234 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cl'  'Cl'   0.1484   0.1585 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Rh'  'Rh'  -1.1178   0.9187 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
  
_space_group_crystal_system       triclinic 
_space_group_IT_number            2 
_space_group_name_H-M_alt         'P -1' 
_space_group_name_Hall            '-P 1' 
  
_shelx_space_group_comment 
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
; 
  
loop_ 
 _space_group_symop_operation_xyz 
 'x, y, z' 
 '-x, -y, -z' 
  
_cell_length_a                    9.4717(2) 
_cell_length_b                    10.4441(3) 
_cell_length_c                    16.3936(4) 
_cell_angle_alpha                 88.649(2) 
_cell_angle_beta                  75.070(2) 
_cell_angle_gamma                 89.069(2) 
_cell_volume                      1566.44(7) 
_cell_formula_units_Z             2 
_cell_measurement_temperature     130 
_cell_measurement_reflns_used     7688 
_cell_measurement_theta_min       2.5630 
_cell_measurement_theta_max       28.0580 
  
_exptl_crystal_description        prism 
_exptl_crystal_colour             'clear orange' 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_method     ? 
_exptl_crystal_density_diffrn     1.495 
_exptl_crystal_F_000              720 
_exptl_transmission_factor_min    ? 
_exptl_transmission_factor_max    ? 
_exptl_crystal_size_max           0.2200 
_exptl_crystal_size_mid           0.1000 
_exptl_crystal_size_min           0.0300 
_exptl_absorpt_coefficient_mu     0.885 
_shelx_estimated_absorpt_T_min    ? 
_shelx_estimated_absorpt_T_max    ? 
_exptl_absorpt_correction_type    multi-scan 
_exptl_absorpt_correction_T_min   0.99008 
_exptl_absorpt_correction_T_max   1.00000 
_exptl_absorpt_process_details     
; 
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
; 
_exptl_absorpt_special_details    ? 
_diffrn_ambient_temperature       130
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_source                    'Enhance (Mo) X-ray Source' 
_diffrn_measurement_device_type   'Xcalibur, Sapphire3, Gemini' 
_diffrn_measurement_method        'ω scans' 
_diffrn_detector_area_resol_mean  16.3560 
_diffrn_reflns_number             24286 
_diffrn_reflns_av_unetI/netI      0.0591 
_diffrn_reflns_av_R_equivalents   0.0492 
_diffrn_reflns_limit_h_min        -12 
_diffrn_reflns_limit_h_max        12 
_diffrn_reflns_limit_k_min        -13 
_diffrn_reflns_limit_k_max        13 
_diffrn_reflns_limit_l_min        -21 
_diffrn_reflns_limit_l_max        21 
_diffrn_reflns_theta_min          2.225 
_diffrn_reflns_theta_max          28.281 
_diffrn_reflns_theta_full         25.242 
_diffrn_measured_fraction_theta_max   0.945 
_diffrn_measured_fraction_theta_full  1.000 
_diffrn_reflns_Laue_measured_fraction_max    0.945 
_diffrn_reflns_Laue_measured_fraction_full   1.000 
_diffrn_reflns_point_group_measured_fraction_max   0.945 
_diffrn_reflns_point_group_measured_fraction_full  1.000 
_reflns_number_total              7337 
_reflns_number_gt                 5847 
_reflns_threshold_expression      'I > 2σ(I)' 
_reflns_Friedel_coverage          0.000 
_reflns_Friedel_fraction_max      . 
_reflns_Friedel_fraction_full     . 
  
_reflns_special_details 
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
; 
  
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_structure_solution     'SHELXS' 
_computing_structure_refinement 'SHELXL-2014/7 (Sheldrick, 2014)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
_refine_special_details           ? 
_refine_ls_structure_factor_coef  Fsqd 
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc 
_refine_ls_weighting_details 
'w=1/[σ²(Fo²)+(0.0279P)²+1.1115P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      ? 
_atom_sites_solution_secondary    ? 
_atom_sites_solution_hydrogens    mixed 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        . 
_refine_ls_number_reflns          7337 
_refine_ls_number_parameters      375 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0615 
_refine_ls_R_factor_gt            0.0415 
_refine_ls_wR_factor_ref          0.0823 
_refine_ls_wR_factor_gt           0.0763 
_refine_ls_goodness_of_fit_ref    1.034 
_refine_ls_restrained_S_all       1.034 
_refine_ls_shift/su_max           0.001 
_refine_ls_shift/su_mean          0.000 
  
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_site_symmetry_order 
 _atom_site_calc_flag 
 _atom_site_refinement_flags_posn 
 _atom_site_refinement_flags_adp 
 _atom_site_refinement_flags_occupancy 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
B1 B 0.7257(4) 0.7050(4) 0.1139(2) 0.0238(8) Uani 1 1 d . . . . . 
H1 H 0.7041 0.6118 0.0898 0.029 Uiso 1 1 calc R U . . . 
B2 B 0.6336(4) 0.8476(4) 0.0953(2) 0.0278(8) Uani 1 1 d . . . . . 
H2 H 0.5523 0.8487 0.0579 0.033 Uiso 1 1 calc R U . . . 
C3 C 0.4510(3) 0.7630(3) 0.4733(2) 0.0279(7) Uani 1 1 d . . . . . 
H3 H 0.3794 0.7700 0.4438 0.033 Uiso 1 1 calc R U . . . 
B3 B 0.6140(4) 0.9458(4) 0.1849(2) 0.0256(8) Uani 1 1 d . . . . . 
H3A H 0.5194 1.0103 0.2065 0.031 Uiso 1 1 calc R U . . . 
C4 C 0.8795(3) 0.8474(3) 0.20401(18) 0.0180(6) Uani 1 1 d . . . . . 
B4 B 0.5960(4) 0.7788(4) 0.1985(2) 0.0249(8) Uani 1 1 d . . . . . 
H4 H 0.4906 0.7343 0.2289 0.030 Uiso 1 1 calc R U . . . 
C5 C 1.2989(3) 0.5771(3) 0.08761(19) 0.0235(7) Uani 1 1 d . . . . . 
B5 B 0.6964(3) 0.8649(3) 0.2574(2) 0.0183(7) Uani 1 1 d . . . . . 
H5 H 0.6583 0.8751 0.3262 0.022 Uiso 1 1 calc R U . . . 
C7 C 0.6669(3) 0.6594(3) 0.49661(19) 0.0221(7) Uani 1 1 d . . . . . 
B7 B 0.8240(4) 0.8268(4) 0.0466(2) 0.0242(8) Uani 1 1 d . . . . . 
H7 H 0.8657 0.8136 -0.0218 0.029 Uiso 1 1 calc R U . . . 
B6 B 0.7919(4) 0.9881(3) 0.1899(2) 0.0213(7) Uani 1 1 d . . . . . 
H6 H 0.8133 1.0804 0.2151 0.026 Uiso 1 1 calc R U . . . 
C10 C 0.7618(3) 0.7244(3) 0.20911(18) 0.0170(6) Uani 1 1 d . . . . . 
B10 B 0.9044(4) 0.7474(3) 0.1197(2) 0.0199(7) Uani 1 1 d . . . . . 
H10 H 0.9988 0.6821 0.1003 0.024 Uiso 1 1 calc R U . . . 
B9 B 0.9212(4) 0.9152(3) 0.1053(2) 0.0211(7) Uani 1 1 d . . . . . 
H9 H 1.0268 0.9598 0.0754 0.025 Uiso 1 1 calc R U . . . 
B8 B 0.7545(4) 0.9774(3) 0.0908(2) 0.0229(8) Uani 1 1 d . . . . . 
H8 H 0.7513 1.0630 0.0508 0.027 Uiso 1 1 calc R U . . . 
C12 C 1.2575(3) 0.6285(3) 0.16898(19) 0.0202(6) Uani 1 1 d . . . . . 
H12 H 1.282(4) 0.728(4) 0.020(2) 0.040(12) Uiso 1 1 d . . . . . 
H11 H 1.345(5) 0.619(4) -0.029(3) 0.063(15) Uiso 1 1 d . . . . . 
C13 C 0.9385(3) 0.4341(3) 0.1616(2) 0.0274(7) Uani 1 1 d . . . . . 
H13A H 0.9645 0.3469 0.1466 0.041 Uiso 1 1 calc R U . . . 
H13B H 1.0207 0.4761 0.1729 0.041 Uiso 1 1 calc R U . . . 
H13C H 0.9108 0.4778 0.1158 0.041 Uiso 1 1 calc R U . . . 
C14 C 0.5613(3) 0.6720(3) 0.45158(19) 0.0230(7) Uani 1 1 d . . . . . 
C16 C 1.0562(3) 0.9720(3) 0.31094(19) 0.0217(6) Uani 1 1 d . . . . . 
C17 C 0.8482(4) 0.3500(3) 0.3088(2) 0.0286(7) Uani 1 1 d . . . . . 
H17A H 0.8667 0.2644 0.2883 0.043 Uiso 1 1 calc R U . . . 
H17B H 0.7680 0.3496 0.3585 0.043 Uiso 1 1 calc R U . . . 
H17C H 0.9338 0.3818 0.3223 0.043 Uiso 1 1 calc R U . . . 
C18 C 1.3410(3) 0.4476(3) 0.0809(2) 0.0268(7) Uani 1 1 d . . . . . 
H18 H 1.3707 0.4117 0.0278 0.032 Uiso 1 1 calc R U . . . 
C20 C 1.2594(3) 0.5522(3) 0.2394(2) 0.0235(7) Uani 1 1 d . . . . . 
H20 H 1.2348 0.5876 0.2929 0.028 Uiso 1 1 calc R U . . . 
C21 C 0.8100(3) 0.4364(3) 0.24069(19) 0.0213(6) Uani 1 1 d . . . . . 
C23 C 0.6636(4) 0.7425(3) 0.5617(2) 0.0312(8) Uani 1 1 d . . . . . 
H23 H 0.7352 0.7367 0.5912 0.037 Uiso 1 1 calc R U . . . 
C26 C 1.1118(3) 1.0723(3) 0.2402(2) 0.0267(7) Uani 1 1 d . . . . . 
H26A H 1.2042 1.0446 0.2050 0.040 Uiso 1 1 calc R U . . . 
H26B H 1.1235 1.1529 0.2646 0.040 Uiso 1 1 calc R U . . . 
H26C H 1.0426 1.0822 0.2067 0.040 Uiso 1 1 calc R U . . . 
C27 C 1.2980(3) 0.4234(3) 0.2303(2) 0.0278(7) Uani 1 1 d . . . . . 
H27 H 1.2960 0.3716 0.2774 0.033 Uiso 1 1 calc R U . . . 
C30 C 1.3391(3) 0.3735(3) 0.1505(2) 0.0296(8) Uani 1 1 d . . . . . 
H30 H 1.3660 0.2876 0.1441 0.035 Uiso 1 1 calc R U . . . 
C31 C 1.1782(3) 0.9521(3) 0.3561(2) 0.0308(8) Uani 1 1 d . . . . . 
H31A H 1.2635 0.9178 0.3174 0.046 Uiso 1 1 calc R U . . . 
H31B H 1.1461 0.8934 0.4030 0.046 Uiso 1 1 calc R U . . . 
H31C H 1.2013 1.0327 0.3762 0.046 Uiso 1 1 calc R U . . . 
C33 C 0.9184(3) 1.0172(3) 0.3756(2) 0.0253(7) Uani 1 1 d . . . . . 
H33A H 0.8422 1.0344 0.3478 0.038 Uiso 1 1 calc R U . . . 
H33B H 0.9391 1.0939 0.4013 0.038 Uiso 1 1 calc R U . . . 
H33C H 0.8873 0.9517 0.4183 0.038 Uiso 1 1 calc R U . . . 
C34 C 0.4485(4) 0.8434(3) 0.5392(2) 0.0364(9) Uani 1 1 d . . . . . 
H34 H 0.3745 0.9046 0.5542 0.044 Uiso 1 1 calc R U . . . 
C35 C 0.6725(3) 0.3859(3) 0.2197(2) 0.0285(7) Uani 1 1 d . . . . . 
H35A H 0.6367 0.4488 0.1861 0.043 Uiso 1 1 calc R U . . . 
H35B H 0.5988 0.3693 0.2711 0.043 Uiso 1 1 calc R U . . . 
H35C H 0.6960 0.3082 0.1887 0.043 Uiso 1 1 calc R U . . . 
C37 C 0.5539(4) 0.8340(4) 0.5829(2) 0.0361(9) Uani 1 1 d . . . . . 
H37 H 0.5517 0.8894 0.6268 0.043 Uiso 1 1 calc R U . . . 
N1 N 0.7821(3) 0.5672(3) 0.47206(16) 0.0257(6) Uani 1 1 d . . . . . 
H1A H 0.7494 0.4938 0.4577 0.031 Uiso 1 1 calc R U . . . 
H1B H 0.8266 0.5520 0.5130 0.031 Uiso 1 1 calc R U . . . 
N2 N 1.2953(4) 0.6484(4) 0.0169(2) 0.0348(7) Uani 1 1 d . . . . . 
P1 P 1.01685(8) 0.81162(7) 0.27042(5) 0.01683(16) Uani 1 1 d . . . . . 
P5 P 0.78269(8) 0.59962(7) 0.28964(5) 0.01700(16) Uani 1 1 d . . . . . 
S1 S 0.56535(8) 0.56972(8) 0.36616(5) 0.02257(17) Uani 1 1 d . . . . . 
S2 S 1.21920(8) 0.79484(7) 0.17784(5) 0.02228(17) Uani 1 1 d . . . . . 
Cl1 Cl 1.07185(9) 0.68089(8) 0.46271(5) 0.03001(19) Uani 1 1 d . . . . . 
Rh1 Rh 0.92478(2) 0.66210(2) 0.36464(2) 0.01793(7) Uani 1 1 d . . . . . 
  
  
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
  
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
B1 C10 1.699(4) . ? 
B1 B7 1.774(5) . ? 
B1 B2 1.774(5) . ? 
B1 B4 1.780(5) . ? 
B1 B10 1.783(5) . ? 
B2 B4 1.774(5) . ? 
B2 B8 1.777(5) . ? 
B2 B3 1.781(5) . ? 
B2 B7 1.786(5) . ? 
C3 C34 1.379(5) . ? 
C3 C14 1.384(4) . ? 
B3 B4 1.758(5) . ? 
B3 B6 1.771(5) . ? 
B3 B5 1.773(5) . ? 
B3 B8 1.787(5) . ? 
C4 C10 1.701(4) . ? 
C4 B9 1.703(4) . ? 
C4 B6 1.716(4) . ? 
C4 B10 1.718(4) . ? 
C4 B5 1.738(4) . ? 
C4 P1 1.927(3) . ? 
B4 C10 1.711(4) . ? 
B4 B5 1.785(5) . ? 
C5 N2 1.370(4) . ? 
C5 C18 1.402(4) . ? 
C5 C12 1.406(4) . ? 
B5 C10 1.713(4) . ? 
B5 B6 1.775(5) . ? 
C7 C23 1.385(4) . ? 
C7 C14 1.391(4) . ? 
C7 N1 1.427(4) . ? 
B7 B10 1.763(5) . ? 
B7 B9 1.775(5) . ? 
B7 B8 1.791(5) . ? 
B6 B8 1.757(5) . ? 
B6 B9 1.774(5) . ? 
C10 B10 1.733(4) . ? 
C10 P5 1.878(3) . ? 
B10 B9 1.767(5) . ? 
B9 B8 1.768(5) . ? 
C12 C20 1.391(4) . ? 
C12 S2 1.771(3) . ? 
C13 C21 1.533(4) . ? 
C14 S1 1.773(3) . ? 
C16 C33 1.530(4) . ? 
C16 C31 1.534(4) . ? 
C16 C26 1.539(4) . ? 
C16 P1 1.894(3) . ? 
C17 C21 1.530(4) . ? 
C18 C30 1.359(5) . ? 
C20 C27 1.389(4) . ? 
C21 C35 1.534(4) . ? 
C21 P5 1.887(3) . ? 
C23 C37 1.382(5) . ? 
C27 C30 1.378(5) . ? 
C34 C37 1.372(5) . ? 
N1 Rh1 2.155(2) . ? 
P1 S2 2.1237(10) . ? 
P1 Rh1 2.1957(8) . ? 
P5 S1 2.1402(10) . ? 
P5 Rh1 2.1604(7) . ? 
Cl1 Rh1 2.3962(8) . ? 
  
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
C10 B1 B7 105.7(2) . . ? 
C10 B1 B2 105.2(2) . . ? 
B7 B1 B2 60.4(2) . . ? 
C10 B1 B4 58.85(18) . . ? 
B7 B1 B4 108.5(3) . . ? 
B2 B1 B4 59.9(2) . . ? 
C10 B1 B10 59.64(17) . . ? 
B7 B1 B10 59.41(19) . . ? 
B2 B1 B10 107.8(3) . . ? 
B4 B1 B10 108.4(2) . . ? 
B1 B2 B4 60.2(2) . . ? 
B1 B2 B8 107.9(2) . . ? 
B4 B2 B8 107.9(3) . . ? 
B1 B2 B3 107.5(2) . . ? 
B4 B2 B3 59.3(2) . . ? 
B8 B2 B3 60.3(2) . . ? 
B1 B2 B7 59.8(2) . . ? 
B4 B2 B7 108.2(2) . . ? 
B8 B2 B7 60.3(2) . . ? 
B3 B2 B7 108.4(2) . . ? 
C34 C3 C14 119.2(3) . . ? 
B4 B3 B6 108.7(2) . . ? 
B4 B3 B5 60.72(19) . . ? 
B6 B3 B5 60.13(19) . . ? 
B4 B3 B2 60.2(2) . . ? 
B6 B3 B2 107.3(3) . . ? 
B5 B3 B2 108.2(3) . . ? 
B4 B3 B8 108.1(3) . . ? 
B6 B3 B8 59.16(19) . . ? 
B5 B3 B8 107.5(2) . . ? 
B2 B3 B8 59.7(2) . . ? 
C10 C4 B9 109.8(2) . . ? 
C10 C4 B6 108.6(2) . . ? 
B9 C4 B6 62.51(19) . . ? 
C10 C4 B10 60.94(17) . . ? 
B9 C4 B10 62.20(19) . . ? 
B6 C4 B10 113.0(2) . . ? 
C10 C4 B5 59.74(17) . . ? 
B9 C4 B5 113.3(2) . . ? 
B6 C4 B5 61.85(18) . . ? 
B10 C4 B5 112.3(2) . . ? 
C10 C4 P1 111.82(18) . . ? 
B9 C4 P1 125.36(19) . . ? 
B6 C4 P1 129.8(2) . . ? 
B10 C4 P1 112.07(19) . . ? 
B5 C4 P1 117.65(19) . . ? 
C10 B4 B3 105.3(2) . . ? 
C10 B4 B2 104.7(2) . . ? 
B3 B4 B2 60.5(2) . . ? 
C10 B4 B1 58.23(18) . . ? 
B3 B4 B1 108.2(3) . . ? 
B2 B4 B1 59.9(2) . . ? 
C10 B4 B5 58.64(17) . . ? 
B3 B4 B5 60.0(2) . . ? 
B2 B4 B5 108.0(3) . . ? 
B1 B4 B5 107.2(2) . . ? 
N2 C5 C18 120.4(3) . . ? 
N2 C5 C12 122.1(3) . . ? 
C18 C5 C12 117.5(3) . . ? 
C10 B5 C4 59.05(17) . . ? 
C10 B5 B3 104.5(2) . . ? 
C4 B5 B3 105.3(2) . . ? 
C10 B5 B6 105.4(2) . . ? 
C4 B5 B6 58.46(18) . . ? 
B3 B5 B6 59.91(19) . . ? 
C10 B5 B4 58.52(18) . . ? 
C4 B5 B4 106.1(2) . . ? 
B3 B5 B4 59.2(2) . . ? 
B6 B5 B4 107.3(2) . . ? 
C23 C7 C14 119.1(3) . . ? 
C23 C7 N1 120.8(3) . . ? 
C14 C7 N1 119.9(3) . . ? 
B10 B7 B1 60.57(19) . . ? 
B10 B7 B9 59.92(19) . . ? 
B1 B7 B9 108.1(2) . . ? 
B10 B7 B2 108.2(2) . . ? 
B1 B7 B2 59.8(2) . . ? 
B9 B7 B2 107.5(3) . . ? 
B10 B7 B8 107.4(2) . . ? 
B1 B7 B8 107.3(2) . . ? 
B9 B7 B8 59.44(19) . . ? 
B2 B7 B8 59.6(2) . . ? 
C4 B6 B8 105.6(2) . . ? 
C4 B6 B3 106.2(2) . . ? 
B8 B6 B3 60.9(2) . . ? 
C4 B6 B9 58.39(18) . . ? 
B8 B6 B9 60.1(2) . . ? 
B3 B6 B9 108.7(3) . . ? 
C4 B6 B5 59.68(18) . . ? 
B8 B6 B5 108.7(2) . . ? 
B3 B6 B5 59.96(19) . . ? 
B9 B6 B5 108.1(2) . . ? 
B1 C10 C4 110.5(2) . . ? 
B1 C10 B4 62.9(2) . . ? 
C4 C10 B4 111.2(2) . . ? 
B1 C10 B5 114.4(2) . . ? 
C4 C10 B5 61.22(17) . . ? 
B4 C10 B5 62.84(19) . . ? 
B1 C10 B10 62.59(19) . . ? 
C4 C10 B10 60.01(17) . . ? 
B4 C10 B10 114.1(2) . . ? 
B5 C10 B10 112.8(2) . . ? 
B1 C10 P5 129.1(2) . . ? 
C4 C10 P5 111.42(17) . . ? 
B4 C10 P5 123.4(2) . . ? 
B5 C10 P5 110.41(19) . . ? 
B10 C10 P5 118.87(19) . . ? 
C4 B10 C10 59.05(17) . . ? 
C4 B10 B7 105.9(2) . . ? 
C10 B10 B7 104.7(2) . . ? 
C4 B10 B9 58.51(18) . . ? 
C10 B10 B9 105.4(2) . . ? 
B7 B10 B9 60.4(2) . . ? 
C4 B10 B1 105.8(2) . . ? 
C10 B10 B1 57.77(18) . . ? 
B7 B10 B1 60.01(19) . . ? 
B9 B10 B1 108.0(2) . . ? 
C4 B9 B10 59.29(18) . . ? 
C4 B9 B8 105.7(2) . . ? 
B10 B9 B8 108.2(2) . . ? 
C4 B9 B6 59.10(18) . . ? 
B10 B9 B6 107.9(2) . . ? 
B8 B9 B6 59.47(19) . . ? 
C4 B9 B7 105.9(2) . . ? 
B10 B9 B7 59.68(19) . . ? 
B8 B9 B7 60.7(2) . . ? 
B6 B9 B7 108.1(2) . . ? 
B6 B8 B9 60.44(19) . . ? 
B6 B8 B2 108.1(2) . . ? 
B9 B8 B2 108.2(3) . . ? 
B6 B8 B3 59.97(19) . . ? 
B9 B8 B3 108.3(2) . . ? 
B2 B8 B3 59.9(2) . . ? 
B6 B8 B7 108.1(2) . . ? 
B9 B8 B7 59.85(19) . . ? 
B2 B8 B7 60.1(2) . . ? 
B3 B8 B7 107.9(2) . . ? 
C20 C12 C5 120.4(3) . . ? 
C20 C12 S2 121.3(2) . . ? 
C5 C12 S2 118.1(2) . . ? 
C3 C14 C7 120.6(3) . . ? 
C3 C14 S1 119.2(2) . . ? 
C7 C14 S1 120.2(2) . . ? 
C33 C16 C31 108.3(3) . . ? 
C33 C16 C26 112.3(3) . . ? 
C31 C16 C26 106.5(2) . . ? 
C33 C16 P1 108.19(19) . . ? 
C31 C16 P1 108.0(2) . . ? 
C26 C16 P1 113.3(2) . . ? 
C30 C18 C5 121.4(3) . . ? 
C27 C20 C12 120.2(3) . . ? 
C17 C21 C13 108.6(3) . . ? 
C17 C21 C35 109.4(2) . . ? 
C13 C21 C35 109.7(2) . . ? 
C17 C21 P5 103.9(2) . . ? 
C13 C21 P5 111.9(2) . . ? 
C35 C21 P5 113.2(2) . . ? 
C37 C23 C7 120.1(3) . . ? 
C30 C27 C20 119.2(3) . . ? 
C18 C30 C27 121.2(3) . . ? 
C37 C34 C3 120.7(3) . . ? 
C34 C37 C23 120.2(3) . . ? 
C7 N1 Rh1 101.65(18) . . ? 
C16 P1 C4 105.57(13) . . ? 
C16 P1 S2 95.95(10) . . ? 
C4 P1 S2 103.12(9) . . ? 
C16 P1 Rh1 117.38(10) . . ? 
C4 P1 Rh1 108.21(9) . . ? 
S2 P1 Rh1 124.41(4) . . ? 
C10 P5 C21 110.17(13) . . ? 
C10 P5 S1 104.62(9) . . ? 
C21 P5 S1 96.91(10) . . ? 
C10 P5 Rh1 111.93(9) . . ? 
C21 P5 Rh1 120.09(10) . . ? 
S1 P5 Rh1 111.14(4) . . ? 
C14 S1 P5 101.13(10) . . ? 
C12 S2 P1 105.64(10) . . ? 
N1 Rh1 P5 88.08(7) . . ? 
N1 Rh1 P1 160.47(7) . . ? 
P5 Rh1 P1 91.20(3) . . ? 
N1 Rh1 Cl1 81.42(7) . . ? 
P5 Rh1 Cl1 166.21(3) . . ? 
P1 Rh1 Cl1 101.68(3) . . ? 
  
_refine_diff_density_max    0.775 
_refine_diff_density_min   -0.496 
_refine_diff_density_rms    0.094 
  
  
  
