# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_redu
_database_code_depnum_ccdc_archive 'CCDC 1840026'
loop_
_audit_author_name
_audit_author_address
'jing xiang'
;yangtze university
China
;
_audit_update_record             
;
2019-06-11 deposited with the CCDC.	2019-06-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C41 H32 N6 O2 Os P'
_chemical_formula_weight         861.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -4.9801 6.2216 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.76370(10)
_cell_length_b                   14.7379(3)
_cell_length_c                   20.9329(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3629.18(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    5736
_cell_measurement_theta_min      3.67
_cell_measurement_theta_max      67.24

_exptl_crystal_description       block
_exptl_crystal_colour            RED
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_F_000             1708
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.130
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    7.410
_shelx_estimated_absorpt_T_min   0.446
_shelx_estimated_absorpt_T_max   0.496
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4459
_exptl_absorpt_correction_T_max  0.4962
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            10828
_diffrn_reflns_av_unetI/netI     0.0224
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         3.668
_diffrn_reflns_theta_max         67.243
_diffrn_reflns_theta_full        67.243
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.882
_diffrn_reflns_point_group_measured_fraction_full 0.882
_reflns_number_total             5736
_reflns_number_gt                5059
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.589
_reflns_Friedel_fraction_max     0.744
_reflns_Friedel_fraction_full    0.744

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0470P)²+6.2906P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 1713 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.023(8)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         5736
_refine_ls_number_parameters     535
_refine_ls_number_restraints     515
_refine_ls_R_factor_all          0.0442
_refine_ls_R_factor_gt           0.0387
_refine_ls_wR_factor_ref         0.0990
_refine_ls_wR_factor_gt          0.0960
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.031
_refine_ls_shift/su_mean         0.004

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.75583(3) 0.37791(3) 0.91673(2) 0.06517(14) Uani 1 1 d . . . . .
P1 P 0.8799(2) 0.09239(19) 0.34262(11) 0.0593(6) Uani 1 1 d . U . . .
N1 N 0.4890(7) 0.3878(8) 0.8850(5) 0.086(3) Uani 1 1 d . U . . .
N2 N 1.0163(6) 0.3677(8) 0.9609(4) 0.077(3) Uani 1 1 d . U . . .
N3 N 0.8109(13) 0.2563(11) 0.7953(7) 0.142(6) Uani 1 1 d . U . . .
N6 N 0.7258(6) 0.4716(7) 0.9939(3) 0.073(3) Uani 1 1 d . U . . .
O1 O 0.7886(6) 0.4910(5) 0.8651(3) 0.0710(19) Uani 1 1 d . U . . .
O2 O 0.7498(9) 0.6025(6) 1.0486(3) 0.106(3) Uani 1 1 d . U . . .
C2 C 0.9263(7) 0.3744(9) 0.9437(4) 0.065(2) Uani 1 1 d . U . . .
C1 C 0.5849(7) 0.3841(9) 0.8946(5) 0.073(3) Uani 1 1 d . U . . .
C3 C 0.7876(11) 0.3010(11) 0.8380(7) 0.097(4) Uani 1 1 d . U . . .
C5 C 0.8402(8) 0.5644(8) 0.8833(5) 0.071(3) Uani 1 1 d . U . . .
C6 C 0.8977(9) 0.6193(11) 0.8374(7) 0.094(4) Uani 1 1 d . U . . .
H6 H 0.8971 0.6012 0.7949 0.113 Uiso 1 1 calc R U . . .
C7 C 0.9532(12) 0.6967(12) 0.8532(10) 0.112(5) Uani 1 1 d . U . . .
H7 H 0.9978 0.7262 0.8230 0.134 Uiso 1 1 calc R U . . .
C8 C 0.9435(12) 0.7309(11) 0.9131(10) 0.108(4) Uani 1 1 d . U . . .
H8 H 0.9752 0.7872 0.9224 0.129 Uiso 1 1 calc R U . . .
C9 C 0.8888(11) 0.6848(9) 0.9594(7) 0.092(4) Uani 1 1 d . U . . .
H9 H 0.8848 0.7091 1.0003 0.110 Uiso 1 1 calc R U . . .
C10 C 0.8361(9) 0.5979(8) 0.9463(6) 0.074(3) Uani 1 1 d . U . . .
C11 C 0.7743(9) 0.5544(8) 0.9938(5) 0.074(3) Uani 1 1 d . U . . .
C12 C 0.6819(9) 0.5479(8) 1.0823(5) 0.103(4) Uani 1 1 d D U . . .
C13 C 0.6636(9) 0.4656(8) 1.0524(4) 0.098(4) Uani 1 1 d D U . . .
C14 C 0.5899(9) 0.4074(8) 1.0793(5) 0.128(5) Uani 1 1 d D U . . .
H14 H 0.5708 0.3552 1.0567 0.153 Uiso 1 1 calc R U . . .
C15 C 0.5418(11) 0.4199(10) 1.1373(5) 0.137(6) Uani 1 1 d D U . . .
H1' H 0.4943 0.3764 1.1552 0.165 Uiso 1 1 calc R U . . .
C16 C 0.5658(14) 0.4996(11) 1.1687(5) 0.137(7) Uani 1 1 d D U . . .
H16 H 0.5344 0.5102 1.2087 0.164 Uiso 1 1 calc R U . . .
C17 C 0.6347(13) 0.5629(9) 1.1420(6) 0.142(6) Uani 1 1 d D U . . .
H17 H 0.6502 0.6165 1.1638 0.171 Uiso 1 1 calc R U . . .
C18 C 0.9866(8) 0.0070(7) 0.3337(4) 0.073(3) Uani 1 1 d D U . . .
C19 C 1.0140(17) -0.0455(15) 0.3842(6) 0.090(6) Uani 0.58(3) 1 d D U P A 1
H19 H 0.9773 -0.0378 0.4231 0.108 Uiso 0.58(3) 1 calc R U P A 1
C20 C 1.0973(19) -0.1112(16) 0.3773(8) 0.112(6) Uani 0.58(3) 1 d D U P A 1
H20 H 1.1163 -0.1487 0.4114 0.134 Uiso 0.58(3) 1 calc R U P A 1
C19' C 0.971(2) -0.0771(14) 0.3622(14) 0.110(7) Uani 0.42(3) 1 d D U P A 2
H19' H 0.9071 -0.0883 0.3876 0.132 Uiso 0.42(3) 1 calc R U P A 2
C20' C 1.051(2) -0.1441(13) 0.3520(16) 0.125(7) Uani 0.42(3) 1 d D U P A 2
H20' H 1.0409 -0.2020 0.3686 0.150 Uiso 0.42(3) 1 d R U P A 2
C21 C 1.1510(10) -0.1201(9) 0.3203(6) 0.121(5) Uani 1 1 d D U . . .
H21 H 1.1907 -0.1732 0.3116 0.145 Uiso 1 1 d R U . A .
C22 C 1.1439(10) -0.0528(10) 0.2753(7) 0.124(5) Uani 1 1 d D U . . .
H22 H 1.1961 -0.0494 0.2420 0.149 Uiso 1 1 calc R U . . .
C23 C 1.0571(10) 0.0100(8) 0.2806(6) 0.105(4) Uani 1 1 d D U . . .
H23 H 1.0462 0.0535 0.2491 0.125 Uiso 1 1 calc R U . . .
C24 C 0.7758(7) 0.0812(6) 0.2797(3) 0.061(2) Uani 1 1 d D U . . .
C25 C 0.7487(9) -0.0047(6) 0.2593(4) 0.074(2) Uani 1 1 d D U . . .
H25 H 0.7862 -0.0549 0.2760 0.089 Uiso 1 1 calc R U . . .
C26 C 0.6651(8) -0.0159(7) 0.2136(5) 0.081(3) Uani 1 1 d D U . . .
H26 H 0.6456 -0.0738 0.1997 0.097 Uiso 1 1 calc R U . . .
C27 C 0.6112(9) 0.0581(8) 0.1888(5) 0.090(4) Uani 1 1 d D U . . .
H27 H 0.5556 0.0503 0.1577 0.108 Uiso 1 1 calc R U . . .
C28 C 0.6380(10) 0.1432(8) 0.2091(6) 0.104(4) Uani 1 1 d D U . . .
H28 H 0.5998 0.1931 0.1925 0.125 Uiso 1 1 calc R U . . .
C29 C 0.7220(9) 0.1553(6) 0.2542(5) 0.087(3) Uani 1 1 d D U . . .
H29 H 0.7420 0.2135 0.2673 0.104 Uiso 1 1 calc R U . . .
C30 C 0.9461(8) 0.2040(7) 0.3404(5) 0.068(3) Uani 1 1 d D U . . .
C31 C 1.0543(13) 0.2185(9) 0.3142(9) 0.075(5) Uani 0.64(2) 1 d D U P B 1
H31 H 1.0950 0.1699 0.2975 0.089 Uiso 0.62(2) 1 calc R U P C 1
C32 C 1.1001(13) 0.3035(9) 0.3132(10) 0.078(5) Uani 0.62(2) 1 d D U P B 1
H32 H 1.1729 0.3128 0.2972 0.094 Uiso 0.62(2) 1 calc R U P C 1
C34 C 0.9521(17) 0.3553(10) 0.3792(10) 0.085(6) Uani 0.62(2) 1 d D U P B 1
H34 H 0.9251 0.4004 0.4062 0.102 Uiso 0.62(2) 1 calc R U P C 1
C35 C 0.9071(17) 0.2694(11) 0.3820(10) 0.081(6) Uani 0.62(2) 1 d D U P B 1
H35 H 0.8509 0.2555 0.4117 0.098 Uiso 0.62(2) 1 calc R U P C 1
C31' C 1.000(3) 0.218(2) 0.2846(17) 0.082(7) Uani 0.38(2) 1 d . U P B 2
H31' H 1.0005 0.1774 0.2505 0.099 Uiso 0.38(2) 1 calc R U P C 2
C32' C 1.054(4) 0.301(3) 0.285(2) 0.088(7) Uani 0.36(2) 1 d . U P B 2
H32' H 1.1041 0.3134 0.2523 0.106 Uiso 0.38(2) 1 calc R U P C 2
C34' C 0.925(3) 0.364(3) 0.354(2) 0.081(7) Uani 0.38(2) 1 d . U P B 2
H34' H 0.8797 0.4144 0.3630 0.098 Uiso 0.38(2) 1 calc R U P C 2
C35' C 0.885(3) 0.281(3) 0.3568(18) 0.075(7) Uani 0.38(2) 1 d . U P B 2
H35' H 0.8104 0.2732 0.3709 0.090 Uiso 0.38(2) 1 calc R U P C 2
C33 C 1.0381(10) 0.3746(8) 0.3357(6) 0.091(3) Uani 1 1 d D U . . .
H33 H 1.0527 0.4337 0.3226 0.109 Uiso 1 1 calc R U . B 1
C36 C 0.8090(7) 0.0768(7) 0.4194(4) 0.056(2) Uani 1 1 d D U . . .
C37 C 0.6996(9) 0.0463(9) 0.4222(6) 0.083(3) Uani 1 1 d D U . . .
H37 H 0.6594 0.0314 0.3854 0.100 Uiso 1 1 calc R U . . .
C38 C 0.6502(11) 0.0382(11) 0.4829(6) 0.097(4) Uani 1 1 d D U . . .
H38 H 0.5748 0.0201 0.4870 0.117 Uiso 1 1 calc R U . . .
C39 C 0.7149(10) 0.0575(10) 0.5375(5) 0.094(4) Uani 1 1 d D U . . .
H39 H 0.6906 0.0393 0.5778 0.113 Uiso 1 1 d R U . B .
C40 C 0.819(2) 0.097(2) 0.5304(9) 0.094(6) Uani 0.64(2) 1 d . U P B 1
H40 H 0.8587 0.1160 0.5665 0.113 Uiso 0.64(2) 1 calc R U P B 1
C41 C 0.8644(18) 0.109(2) 0.4746(8) 0.084(5) Uani 0.64(2) 1 d . U P B 1
H41 H 0.9337 0.1391 0.4710 0.101 Uiso 0.64(2) 1 calc R U P B 1
C40' C 0.8316(12) 0.052(3) 0.5309(7) 0.090(7) Uani 0.36(2) 1 d D U P B 2
H40' H 0.8783 0.0472 0.5665 0.108 Uiso 0.36(2) 1 d R U P B 2
C41' C 0.8790(10) 0.066(3) 0.4717(7) 0.076(7) Uani 0.36(2) 1 d D U P B 2
H41' H 0.9576 0.0686 0.4669 0.091 Uiso 0.36(2) 1 calc R U P B 2
N4 N 0.7248(7) 0.2600(7) 0.9660(4) 0.088(3) Uani 1 1 d D U . . .
H4 H 0.6649 0.2297 0.9562 0.106 Uiso 1 1 calc R U . . .
N5 N 0.7624(9) 0.1641(6) 1.0524(5) 0.095(3) Uani 1 1 d . U . . .
H5A H 0.6958 0.1403 1.0502 0.114 Uiso 1 1 calc R U . . .
H5B H 0.8097 0.1461 1.0810 0.114 Uiso 1 1 calc R U . . .
C4 C 0.7916(9) 0.2270(8) 1.0124(5) 0.075(3) Uani 1 1 d . U . . .
H4A H 0.8643 0.2511 1.0162 0.090 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 O1 2.024(7) . ?
Os1 C3 2.035(14) . ?
Os1 N4 2.053(9) . ?
Os1 C1 2.065(8) . ?
Os1 C2 2.084(8) . ?
Os1 N6 2.155(9) . ?
P1 C18 1.786(8) . ?
P1 C24 1.806(7) . ?
P1 C36 1.825(10) . ?
P1 C30 1.821(10) . ?
N1 C1 1.148(11) . ?
N2 C2 1.122(11) . ?
N3 C3 1.144(17) . ?
N6 C11 1.347(14) . ?
N6 C13 1.428(11) . ?
O1 C5 1.297(13) . ?
O2 C12 1.336(14) . ?
O2 C11 1.378(12) . ?
C5 C10 1.409(15) . ?
C5 C6 1.427(17) . ?
C6 C7 1.35(2) . ?
C7 C8 1.36(2) . ?
C8 C9 1.35(2) . ?
C9 C10 1.449(17) . ?
C10 C11 1.388(16) . ?
C12 C13 1.382(10) . ?
C12 C17 1.385(10) . ?
C13 C14 1.344(10) . ?
C14 C15 1.352(9) . ?
C15 C16 1.374(10) . ?
C16 C17 1.357(10) . ?
C18 C19 1.350(10) . ?
C18 C23 1.386(9) . ?
C18 C19' 1.390(11) . ?
C19 C20 1.385(11) . ?
C20 C21 1.356(10) . ?
C19' C20' 1.384(11) . ?
C20' C21 1.394(12) . ?
C21 C22 1.372(10) . ?
C22 C23 1.382(9) . ?
C24 C29 1.370(9) . ?
C24 C25 1.374(9) . ?
C25 C26 1.382(9) . ?
C26 C27 1.364(9) . ?
C27 C28 1.361(10) . ?
C28 C29 1.379(9) . ?
C30 C31' 1.34(3) . ?
C30 C35' 1.39(4) . ?
C30 C35 1.377(11) . ?
C30 C31 1.403(10) . ?
C31 C32 1.363(11) . ?
C32 C33 1.362(11) . ?
C34 C35 1.373(11) . ?
C34 C33 1.390(11) . ?
C31' C32' 1.38(5) . ?
C32' C33 1.52(5) . ?
C34' C35' 1.32(5) . ?
C34' C33 1.39(4) . ?
C36 C37 1.365(13) . ?
C36 C41' 1.379(11) . ?
C36 C41 1.41(2) . ?
C37 C38 1.402(17) . ?
C38 C39 1.401(16) . ?
C39 C40 1.37(3) . ?
C39 C40' 1.382(12) . ?
C40 C41 1.29(2) . ?
C40' C41' 1.375(11) . ?
N4 C4 1.341(13) . ?
N5 C4 1.294(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Os1 C3 89.5(5) . . ?
O1 Os1 N4 177.6(3) . . ?
C3 Os1 N4 88.1(5) . . ?
O1 Os1 C1 91.7(4) . . ?
C3 Os1 C1 91.3(5) . . ?
N4 Os1 C1 88.7(4) . . ?
O1 Os1 C2 89.0(4) . . ?
C3 Os1 C2 91.6(5) . . ?
N4 Os1 C2 90.8(4) . . ?
C1 Os1 C2 177.0(4) . . ?
O1 Os1 N6 84.5(3) . . ?
C3 Os1 N6 174.0(5) . . ?
N4 Os1 N6 97.9(4) . . ?
C1 Os1 N6 88.9(4) . . ?
C2 Os1 N6 88.3(4) . . ?
C18 P1 C24 109.6(4) . . ?
C18 P1 C36 109.0(4) . . ?
C24 P1 C36 108.7(4) . . ?
C18 P1 C30 109.5(5) . . ?
C24 P1 C30 110.7(4) . . ?
C36 P1 C30 109.3(4) . . ?
C11 N6 C13 106.0(9) . . ?
C11 N6 Os1 120.6(6) . . ?
C13 N6 Os1 133.3(9) . . ?
C5 O1 Os1 128.3(6) . . ?
C12 O2 C11 104.8(10) . . ?
N2 C2 Os1 175.3(11) . . ?
N1 C1 Os1 177.2(10) . . ?
N3 C3 Os1 176.3(14) . . ?
O1 C5 C10 123.5(11) . . ?
O1 C5 C6 119.8(11) . . ?
C10 C5 C6 116.6(12) . . ?
C7 C6 C5 122.8(15) . . ?
C6 C7 C8 119.9(16) . . ?
C9 C8 C7 121.1(15) . . ?
C8 C9 C10 121.0(14) . . ?
C11 C10 C5 121.8(11) . . ?
C11 C10 C9 119.8(12) . . ?
C5 C10 C9 118.1(12) . . ?
N6 C11 O2 112.1(10) . . ?
N6 C11 C10 129.9(10) . . ?
O2 C11 C10 117.9(12) . . ?
O2 C12 C13 112.5(9) . . ?
O2 C12 C17 128.3(11) . . ?
C13 C12 C17 119.2(8) . . ?
C14 C13 C12 118.1(8) . . ?
C14 C13 N6 136.8(11) . . ?
C12 C13 N6 104.7(10) . . ?
C13 C14 C15 124.0(9) . . ?
C14 C15 C16 117.4(9) . . ?
C17 C16 C15 121.0(8) . . ?
C16 C17 C12 120.0(9) . . ?
C19 C18 C23 120.1(8) . . ?
C23 C18 C19' 116.9(9) . . ?
C19 C18 P1 119.3(7) . . ?
C23 C18 P1 118.9(7) . . ?
C19' C18 P1 119.2(8) . . ?
C18 C19 C20 119.3(9) . . ?
C21 C20 C19 119.2(9) . . ?
C20' C19' C18 118.5(9) . . ?
C19' C20' C21 118.0(10) . . ?
C20 C21 C22 120.4(9) . . ?
C22 C21 C20' 117.3(10) . . ?
C21 C22 C23 118.2(7) . . ?
C22 C23 C18 119.1(7) . . ?
C29 C24 C25 120.4(6) . . ?
C29 C24 P1 121.6(6) . . ?
C25 C24 P1 117.9(6) . . ?
C24 C25 C26 119.4(7) . . ?
C27 C26 C25 119.9(7) . . ?
C28 C27 C26 120.7(7) . . ?
C27 C28 C29 120.0(7) . . ?
C24 C29 C28 119.6(7) . . ?
C31' C30 C35' 110(3) . . ?
C35 C30 C31 116.3(9) . . ?
C31' C30 P1 111.0(19) . . ?
C35' C30 P1 120.7(17) . . ?
C35 C30 P1 118.3(7) . . ?
C31 C30 P1 122.3(7) . . ?
C32 C31 C30 120.3(9) . . ?
C31 C32 C33 119.3(9) . . ?
C35 C34 C33 119.8(9) . . ?
C34 C35 C30 119.3(9) . . ?
C30 C31' C32' 110(3) . . ?
C31' C32' C33 126(3) . . ?
C35' C34' C33 117(4) . . ?
C34' C35' C30 124(3) . . ?
C32 C33 C34 117.4(9) . . ?
C34' C33 C32' 103(3) . . ?
C37 C36 C41' 119.4(10) . . ?
C37 C36 C41 120.7(14) . . ?
C37 C36 P1 120.8(9) . . ?
C41' C36 P1 116.1(8) . . ?
C41 C36 P1 117.9(10) . . ?
C36 C37 C38 117.3(11) . . ?
C39 C38 C37 119.7(10) . . ?
C40 C39 C38 119.1(14) . . ?
C40' C39 C38 116.5(12) . . ?
C41 C40 C39 121.6(19) . . ?
C40 C41 C36 120.2(19) . . ?
C41' C40' C39 119.0(11) . . ?
C40' C41' C36 119.4(9) . . ?
C4 N4 Os1 124.6(8) . . ?
N5 C4 N4 125.0(11) . . ?

_refine_diff_density_max         1.088
_refine_diff_density_min         -0.764
_refine_diff_density_rms         0.076

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AMG
_database_code_depnum_ccdc_archive 'CCDC 1840027'
loop_
_audit_author_name
_audit_author_address
'jing xiang'
;yangtze university
China
;
_audit_update_record             
;
2019-06-11 deposited with the CCDC.	2019-06-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H38 N8 O3 Os P'
_chemical_formula_weight         923.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -4.9801 6.2216 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.73820(10)
_cell_length_b                   16.3662(2)
_cell_length_c                   20.8351(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     4002.62(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    7164
_cell_measurement_theta_min      3.43
_cell_measurement_theta_max      67.24

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            Red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.533
_exptl_crystal_F_000             1844
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    6.793
_shelx_estimated_absorpt_T_min   0.496
_shelx_estimated_absorpt_T_max   0.522
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4961
_exptl_absorpt_correction_T_max  0.5220
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14400
_diffrn_reflns_av_unetI/netI     0.0257
_diffrn_reflns_av_R_equivalents  0.0233
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         3.434
_diffrn_reflns_theta_max         67.237
_diffrn_reflns_theta_full        67.238
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             7164
_reflns_number_gt                6911
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.789
_reflns_Friedel_fraction_max     0.997
_reflns_Friedel_fraction_full    0.997

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker FRAMBO'
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0464P)²+1.3355P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 2952 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.038(6)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         7164
_refine_ls_number_parameters     498
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0287
_refine_ls_R_factor_gt           0.0274
_refine_ls_wR_factor_ref         0.0708
_refine_ls_wR_factor_gt          0.0702
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_restrained_S_all      1.132
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.26427(2) 0.57029(2) 0.56017(2) 0.03753(8) Uani 1 1 d . . . . .
P1 P 0.62077(14) 0.38625(10) 0.33049(8) 0.0434(3) Uani 1 1 d . . . . .
N1 N 0.2522(5) 0.6713(3) 0.5057(2) 0.0474(12) Uani 1 1 d D . . . .
H1 H 0.297501 0.668900 0.473324 0.057 Uiso 1 1 calc R U . . .
N8 N 0.2400(5) 0.4874(3) 0.4824(2) 0.0449(12) Uani 1 1 d . . . . .
N6 N 0.2952(8) 0.6739(4) 0.6870(3) 0.079(2) Uani 1 1 d . . . . .
N5 N 0.5252(5) 0.5835(4) 0.5183(3) 0.0553(15) Uani 1 1 d . . . . .
N7 N -0.0028(5) 0.5694(5) 0.5927(3) 0.0599(15) Uani 1 1 d . . . . .
N2 N 0.1045(7) 0.7499(5) 0.5436(4) 0.087(3) Uani 1 1 d . . . . .
H2A H 0.083415 0.710870 0.568537 0.104 Uiso 1 1 calc R U . . .
H2B H 0.067423 0.795211 0.543220 0.104 Uiso 1 1 calc R U . . .
N3 N 0.2209(6) 0.8042(4) 0.4673(4) 0.0676(18) Uani 1 1 d . . . . .
H7 H 0.180776 0.847999 0.469818 0.081 Uiso 1 1 calc R U . . .
N4 N 0.3144(6) 0.8014(5) 0.4223(4) 0.082(2) Uani 1 1 d D . . . .
H8A H 0.355452 0.758040 0.419227 0.099 Uiso 1 1 calc R U . . .
H8B H 0.329041 0.843101 0.398599 0.099 Uiso 1 1 calc R U . . .
O1 O 0.2924(4) 0.4687(3) 0.6142(2) 0.0497(11) Uani 1 1 d . . . . .
O2 O 0.2596(6) 0.3721(3) 0.4271(2) 0.0689(15) Uani 1 1 d . . . . .
C17 C 0.3487(6) 0.4039(4) 0.5951(4) 0.0506(17) Uani 1 1 d . . . . .
C16 C 0.4124(8) 0.3598(5) 0.6416(5) 0.073(2) Uani 1 1 d . . . . .
H2 H 0.418980 0.379748 0.683240 0.088 Uiso 1 1 calc R U . . .
C15 C 0.4642(9) 0.2877(7) 0.6249(6) 0.090(3) Uani 1 1 d . . . . .
H3A H 0.506877 0.259972 0.655574 0.108 Uiso 1 1 calc R U . . .
C14 C 0.4550(9) 0.2552(6) 0.5645(7) 0.094(4) Uani 1 1 d . . . . .
H4 H 0.490107 0.205822 0.554752 0.113 Uiso 1 1 calc R U . . .
C13 C 0.3950(8) 0.2953(5) 0.5194(5) 0.074(3) Uani 1 1 d . . . . .
H5 H 0.387578 0.272261 0.478795 0.089 Uiso 1 1 calc R U . . .
C12 C 0.3423(6) 0.3723(4) 0.5320(4) 0.0529(17) Uani 1 1 d . . . . .
C11 C 0.2811(6) 0.4134(4) 0.4822(3) 0.0514(16) Uani 1 1 d . . . . .
C5 C 0.1810(6) 0.4969(5) 0.4241(3) 0.0538(18) Uani 1 1 d . . . . .
C6 C 0.1183(6) 0.5617(7) 0.3984(4) 0.069(2) Uani 1 1 d . . . . .
H9 H 0.106306 0.610342 0.420533 0.083 Uiso 1 1 calc R U . . .
C7 C 0.0750(9) 0.5475(8) 0.3366(5) 0.088(4) Uani 1 1 d . . . . .
H10 H 0.032744 0.588319 0.316671 0.105 Uiso 1 1 calc R U . . .
C8 C 0.0933(10) 0.4746(10) 0.3043(5) 0.101(4) Uani 1 1 d . . . . .
H11 H 0.061493 0.468655 0.263719 0.122 Uiso 1 1 calc R U . . .
C9 C 0.1540(10) 0.4122(8) 0.3281(5) 0.091(3) Uani 1 1 d . . . . .
H12 H 0.166807 0.364212 0.305269 0.109 Uiso 1 1 calc R U . . .
C10 C 0.1969(7) 0.4249(6) 0.3904(4) 0.066(2) Uani 1 1 d . . . . .
C3 C 0.2863(7) 0.6379(4) 0.6399(3) 0.0527(16) Uani 1 1 d . . . . .
C2 C 0.4339(5) 0.5743(4) 0.5355(3) 0.0408(13) Uani 1 1 d . . . . .
C4 C 0.0918(5) 0.5685(5) 0.5807(3) 0.0428(13) Uani 1 1 d . . . . .
C1 C 0.1942(6) 0.7403(4) 0.5058(4) 0.0514(16) Uani 1 1 d . . . . .
C18 C 0.7238(6) 0.3804(5) 0.2661(3) 0.0547(16) Uani 1 1 d . . . . .
C19 C 0.7854(8) 0.3091(6) 0.2577(4) 0.074(2) Uani 1 1 d . . . . .
H19 H 0.766831 0.262503 0.281016 0.088 Uiso 1 1 calc R U . . .
C20 C 0.8748(9) 0.3074(9) 0.2142(5) 0.097(4) Uani 1 1 d . . . . .
H20 H 0.917782 0.260103 0.209191 0.117 Uiso 1 1 calc R U . . .
C21 C 0.8998(9) 0.3748(10) 0.1789(5) 0.098(4) Uani 1 1 d . . . . .
H21 H 0.959887 0.373380 0.149810 0.118 Uiso 1 1 calc R U . . .
C22 C 0.8383(9) 0.4434(9) 0.1857(5) 0.100(4) Uani 1 1 d . . . . .
H22 H 0.855550 0.488565 0.160417 0.120 Uiso 1 1 calc R U . . .
C23 C 0.7485(8) 0.4487(7) 0.2302(4) 0.084(3) Uani 1 1 d . . . . .
H23 H 0.707131 0.496723 0.235195 0.101 Uiso 1 1 calc R U . . .
C24 C 0.5204(5) 0.4652(4) 0.3140(3) 0.0469(14) Uani 1 1 d . . . . .
C25 C 0.4613(7) 0.4653(5) 0.2551(4) 0.0578(18) Uani 1 1 d . . . . .
H25 H 0.477036 0.425891 0.224216 0.069 Uiso 1 1 calc R U . . .
C26 C 0.3806(7) 0.5238(6) 0.2439(4) 0.064(2) Uani 1 1 d . . . . .
H26 H 0.339890 0.522626 0.205598 0.076 Uiso 1 1 calc R U . . .
C27 C 0.3585(7) 0.5835(6) 0.2874(4) 0.067(2) Uani 1 1 d . . . . .
H27 H 0.304248 0.623425 0.278554 0.080 Uiso 1 1 calc R U . . .
C28 C 0.4176(8) 0.5847(6) 0.3454(4) 0.069(2) Uani 1 1 d . . . . .
H28 H 0.402798 0.625639 0.375206 0.083 Uiso 1 1 calc R U . . .
C29 C 0.4973(7) 0.5260(5) 0.3589(4) 0.0584(18) Uani 1 1 d . . . . .
H29 H 0.535820 0.526745 0.397862 0.070 Uiso 1 1 calc R U . . .
C30 C 0.6949(6) 0.4089(4) 0.4037(3) 0.0470(16) Uani 1 1 d . . . . .
C31 C 0.6391(7) 0.3953(5) 0.4618(4) 0.0597(19) Uani 1 1 d . . . . .
H31 H 0.567632 0.370768 0.462431 0.072 Uiso 1 1 calc R U . . .
C32 C 0.6911(8) 0.4188(6) 0.5184(3) 0.067(2) Uani 1 1 d . . . . .
H32 H 0.655364 0.408949 0.557440 0.080 Uiso 1 1 calc R U . . .
C33 C 0.7959(9) 0.4568(6) 0.5169(4) 0.076(3) Uani 1 1 d . . . . .
H33 H 0.828962 0.474838 0.554888 0.091 Uiso 1 1 calc R U . . .
C34 C 0.8500(9) 0.4678(7) 0.4614(5) 0.089(3) Uani 1 1 d . . . . .
H34 H 0.921325 0.492605 0.461276 0.106 Uiso 1 1 calc R U . . .
C35 C 0.8018(7) 0.4430(6) 0.4035(4) 0.072(3) Uani 1 1 d . . . . .
H35 H 0.841550 0.449332 0.365198 0.086 Uiso 1 1 calc R U . . .
C36 C 0.5501(6) 0.2896(4) 0.3399(3) 0.0469(14) Uani 1 1 d . . . . .
C37 C 0.6023(7) 0.2279(5) 0.3752(4) 0.0595(19) Uani 1 1 d . . . . .
H37 H 0.672626 0.237257 0.394422 0.071 Uiso 1 1 calc R U . . .
C38 C 0.5507(8) 0.1539(5) 0.3818(4) 0.068(2) Uani 1 1 d . . . . .
H38 H 0.585472 0.113432 0.406171 0.082 Uiso 1 1 calc R U . . .
C39 C 0.4480(9) 0.1383(6) 0.3528(5) 0.075(2) Uani 1 1 d . . . . .
H39 H 0.414766 0.086888 0.356395 0.091 Uiso 1 1 calc R U . . .
C40 C 0.3948(8) 0.1982(6) 0.3187(5) 0.083(3) Uani 1 1 d . . . . .
H40 H 0.324446 0.187844 0.299925 0.100 Uiso 1 1 calc R U . . .
C41 C 0.4447(8) 0.2744(5) 0.3118(5) 0.071(2) Uani 1 1 d . . . . .
H41 H 0.407948 0.315081 0.288526 0.085 Uiso 1 1 calc R U . . .
O3 O 0.8520(14) 0.6703(7) 0.2818(8) 0.174(5) Uani 1 1 d . . . . .
H3 H 0.838499 0.719191 0.277645 0.260 Uiso 1 1 calc R U . . .
C43 C 0.791(2) 0.6399(11) 0.3334(13) 0.254(17) Uani 1 1 d . . . . .
H43A H 0.799136 0.581521 0.334802 0.381 Uiso 1 1 calc R U . . .
H43B H 0.712445 0.653994 0.328875 0.381 Uiso 1 1 calc R U . . .
H43C H 0.820630 0.663034 0.372418 0.381 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 N1 2.011(5) . ?
Os1 C3 2.013(7) . ?
Os1 O1 2.035(4) . ?
Os1 C2 2.057(6) . ?
Os1 C4 2.069(6) . ?
Os1 N8 2.132(5) . ?
P1 C24 1.782(7) . ?
P1 C30 1.794(7) . ?
P1 C36 1.797(7) . ?
P1 C18 1.809(7) . ?
N1 C1 1.318(8) . ?
N8 C11 1.305(9) . ?
N8 C5 1.407(9) . ?
N6 C3 1.149(9) . ?
N5 C2 1.140(9) . ?
N7 C4 1.138(8) . ?
N2 C1 1.323(10) . ?
N3 C1 1.355(9) . ?
N3 N4 1.444(10) . ?
O1 C17 1.313(8) . ?
O2 C11 1.356(8) . ?
O2 C10 1.369(11) . ?
C17 C12 1.415(11) . ?
C17 C16 1.420(11) . ?
C16 C15 1.372(13) . ?
C15 C14 1.370(17) . ?
C14 C13 1.346(16) . ?
C13 C12 1.427(10) . ?
C12 C11 1.429(11) . ?
C5 C10 1.384(11) . ?
C5 C6 1.397(12) . ?
C6 C7 1.405(12) . ?
C7 C8 1.386(19) . ?
C8 C9 1.341(18) . ?
C9 C10 1.407(12) . ?
C18 C23 1.374(11) . ?
C18 C19 1.385(12) . ?
C19 C20 1.387(12) . ?
C20 C21 1.357(18) . ?
C21 C22 1.343(18) . ?
C22 C23 1.407(14) . ?
C24 C29 1.391(10) . ?
C24 C25 1.410(10) . ?
C25 C26 1.367(12) . ?
C26 C27 1.359(13) . ?
C27 C28 1.393(12) . ?
C28 C29 1.370(12) . ?
C30 C35 1.373(11) . ?
C30 C31 1.394(10) . ?
C31 C32 1.382(11) . ?
C32 C33 1.379(13) . ?
C33 C34 1.332(14) . ?
C34 C35 1.393(13) . ?
C36 C41 1.391(11) . ?
C36 C37 1.392(10) . ?
C37 C38 1.361(12) . ?
C38 C39 1.372(14) . ?
C39 C40 1.362(14) . ?
C40 C41 1.385(13) . ?
O3 C43 1.38(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Os1 C3 91.3(2) . . ?
N1 Os1 O1 174.7(2) . . ?
C3 Os1 O1 88.4(2) . . ?
N1 Os1 C2 84.3(3) . . ?
C3 Os1 C2 93.7(3) . . ?
O1 Os1 C2 90.5(2) . . ?
N1 Os1 C4 93.4(3) . . ?
C3 Os1 C4 87.9(3) . . ?
O1 Os1 C4 91.9(2) . . ?
C2 Os1 C4 177.2(3) . . ?
N1 Os1 N8 94.9(2) . . ?
C3 Os1 N8 173.8(2) . . ?
O1 Os1 N8 85.6(2) . . ?
C2 Os1 N8 87.7(2) . . ?
C4 Os1 N8 90.9(2) . . ?
C24 P1 C30 109.5(3) . . ?
C24 P1 C36 110.7(3) . . ?
C30 P1 C36 108.2(3) . . ?
C24 P1 C18 109.7(3) . . ?
C30 P1 C18 108.5(3) . . ?
C36 P1 C18 110.1(3) . . ?
C1 N1 Os1 137.7(5) . . ?
C11 N8 C5 106.4(6) . . ?
C11 N8 Os1 122.9(5) . . ?
C5 N8 Os1 130.7(5) . . ?
C1 N3 N4 122.4(6) . . ?
C17 O1 Os1 125.1(4) . . ?
C11 O2 C10 105.0(6) . . ?
O1 C17 C12 123.4(7) . . ?
O1 C17 C16 118.0(8) . . ?
C12 C17 C16 118.4(7) . . ?
C15 C16 C17 119.8(10) . . ?
C14 C15 C16 122.1(10) . . ?
C13 C14 C15 119.6(9) . . ?
C14 C13 C12 121.9(10) . . ?
C17 C12 C13 118.1(8) . . ?
C17 C12 C11 121.9(6) . . ?
C13 C12 C11 119.9(8) . . ?
N8 C11 O2 113.3(7) . . ?
N8 C11 C12 128.4(6) . . ?
O2 C11 C12 118.3(6) . . ?
C10 C5 C6 121.6(7) . . ?
C10 C5 N8 106.1(7) . . ?
C6 C5 N8 132.3(7) . . ?
C5 C6 C7 114.6(10) . . ?
C8 C7 C6 122.1(11) . . ?
C9 C8 C7 124.0(9) . . ?
C8 C9 C10 114.7(10) . . ?
O2 C10 C5 109.0(6) . . ?
O2 C10 C9 127.9(9) . . ?
C5 C10 C9 123.1(10) . . ?
N6 C3 Os1 176.5(7) . . ?
N5 C2 Os1 173.1(7) . . ?
N7 C4 Os1 178.2(8) . . ?
N1 C1 N2 120.9(7) . . ?
N1 C1 N3 122.7(7) . . ?
N2 C1 N3 116.4(6) . . ?
C23 C18 C19 120.4(7) . . ?
C23 C18 P1 120.1(7) . . ?
C19 C18 P1 119.1(6) . . ?
C18 C19 C20 119.6(10) . . ?
C21 C20 C19 120.1(12) . . ?
C22 C21 C20 120.4(9) . . ?
C21 C22 C23 121.6(10) . . ?
C18 C23 C22 117.8(10) . . ?
C29 C24 C25 119.2(7) . . ?
C29 C24 P1 121.2(5) . . ?
C25 C24 P1 119.6(6) . . ?
C26 C25 C24 119.4(8) . . ?
C27 C26 C25 121.5(8) . . ?
C26 C27 C28 119.5(8) . . ?
C29 C28 C27 120.5(8) . . ?
C28 C29 C24 119.8(7) . . ?
C35 C30 C31 119.8(7) . . ?
C35 C30 P1 121.6(5) . . ?
C31 C30 P1 118.5(5) . . ?
C32 C31 C30 119.3(7) . . ?
C33 C32 C31 120.0(7) . . ?
C34 C33 C32 120.4(8) . . ?
C33 C34 C35 121.2(9) . . ?
C30 C35 C34 119.2(8) . . ?
C41 C36 C37 118.9(7) . . ?
C41 C36 P1 121.5(6) . . ?
C37 C36 P1 119.6(5) . . ?
C38 C37 C36 120.2(8) . . ?
C37 C38 C39 120.9(9) . . ?
C40 C39 C38 119.8(8) . . ?
C39 C40 C41 120.6(9) . . ?
C40 C41 C36 119.6(8) . . ?

_refine_diff_density_max         1.131
_refine_diff_density_min         -0.692
_refine_diff_density_rms         0.069

