# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_1
_database_code_depnum_ccdc_archive 'CCDC 1899278'
_audit_update_record             
;
2019-06-13 deposited with the CCDC.	2019-07-29 downloaded from the CCDC.
;
_audit_creation_date             2019-06-02
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C14 H10 N O8 Tb'
_chemical_formula_sum            'C14 H10 N O8 Tb'
_chemical_formula_weight         479.15
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   11.479(3)
_cell_length_b                   10.535(3)
_cell_length_c                   22.524(6)
_cell_angle_alpha                90
_cell_angle_beta                 93.233(5)
_cell_angle_gamma                90
_cell_volume                     2719.5(13)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    3449
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.33
_cell_measurement_theta_min      2.63
_shelx_estimated_absorpt_T_max   0.452
_shelx_estimated_absorpt_T_min   0.391
_exptl_absorpt_coefficient_mu    5.250
_exptl_absorpt_correction_T_max  0.389
_exptl_absorpt_correction_T_min  0.328
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0759 before and 0.0395 after correction.
The Ratio of minimum to maximum transmission is 0.8456.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    2.341
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       Block
_exptl_crystal_F_000             1840
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_av_unetI/netI     0.0359
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            8324
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.496
_diffrn_reflns_theta_min         1.811
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2395
_reflns_number_total             2813
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         2.288
_refine_diff_density_min         -2.001
_refine_diff_density_rms         0.184
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     217
_refine_ls_number_reflns         2813
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0464
_refine_ls_R_factor_gt           0.0365
_refine_ls_restrained_S_all      1.103
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0420P)²+20.4169P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0833
_refine_ls_wR_factor_ref         0.0863
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2.a Riding coordinates:
 O7(H7A,H7B), O8(H8A,H8B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C6(H6), C8(H8), C10(H10), C11(H11)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9239(6) -0.1403(6) 0.8386(3) 0.0250(15) Uani 1 1 d . . . . .
C2 C 0.9159(6) -0.0109(6) 0.8659(3) 0.0225(14) Uani 1 1 d . . . . .
C3 C 0.9987(6) 0.0334(7) 0.9081(3) 0.0288(16) Uani 1 1 d . . . . .
H3 H 1.061605 -0.017302 0.920852 0.035 Uiso 1 1 calc R . . . .
C4 C 0.9863(6) 0.1535(6) 0.9307(3) 0.0242(14) Uani 1 1 d . . . . .
H4 H 1.039719 0.184223 0.959730 0.029 Uiso 1 1 calc R . . . .
C5 C 0.8950(5) 0.2272(5) 0.9102(2) 0.0148(12) Uani 1 1 d . . . . .
C6 C 0.8167(6) 0.1752(6) 0.8689(3) 0.0189(13) Uani 1 1 d . . . . .
H6 H 0.754088 0.224959 0.854875 0.023 Uiso 1 1 calc R . . . .
C7 C 0.8741(5) 0.3590(5) 0.9308(2) 0.0144(12) Uani 1 1 d . . . . .
C8 C 0.8775(6) 0.3866(6) 0.9912(3) 0.0179(13) Uani 1 1 d . . . . .
H8 H 0.896061 0.322582 1.018605 0.022 Uiso 1 1 calc R . . . .
C9 C 0.8539(5) 0.5068(6) 1.0113(2) 0.0161(12) Uani 1 1 d . . . . .
C10 C 0.8227(6) 0.6012(6) 0.9708(3) 0.0204(14) Uani 1 1 d . . . . .
H10 H 0.804740 0.681858 0.984364 0.024 Uiso 1 1 calc R . . . .
C11 C 0.8181(6) 0.5770(6) 0.9110(3) 0.0191(13) Uani 1 1 d . . . . .
H11 H 0.797155 0.641184 0.884103 0.023 Uiso 1 1 calc R . . . .
C12 C 0.8446(5) 0.4567(6) 0.8905(2) 0.0147(12) Uani 1 1 d . . . . .
C13 C 0.8492(5) 0.4425(5) 0.8247(3) 0.0150(12) Uani 1 1 d . . . . .
C14 C 0.8628(5) 0.5361(6) 1.0758(3) 0.0183(13) Uani 1 1 d . . . . .
N1 N 0.8249(5) 0.0571(5) 0.8477(2) 0.0210(11) Uani 1 1 d . . . . .
O1 O 1.0136(5) -0.1975(5) 0.8458(3) 0.0423(14) Uani 1 1 d . . . . .
O2 O 0.8318(4) -0.1784(4) 0.80801(19) 0.0245(10) Uani 1 1 d . . . . .
O3 O 0.9045(4) 0.4541(4) 1.11158(18) 0.0212(10) Uani 1 1 d . . . . .
O4 O 0.8279(4) 0.6414(4) 1.09462(17) 0.0242(10) Uani 1 1 d . . . . .
O5 O 0.9404(4) 0.4018(4) 0.80153(17) 0.0164(9) Uani 1 1 d . . . . .
O6 O 0.7622(4) 0.4774(5) 0.79198(18) 0.0258(10) Uani 1 1 d . . . . .
O7 O 1.1136(4) 0.6411(4) 0.77591(19) 0.0239(10) Uani 1 1 d . . . . .
H7A H 1.182041 0.669690 0.772218 0.036 Uiso 1 1 d R . . . .
H7B H 1.080091 0.690260 0.799548 0.036 Uiso 1 1 d R . . . .
O8 O 1.1106(5) 0.2000(5) 0.7891(2) 0.0398(13) Uani 1 1 d . . . . .
H8A H 1.159615 0.141525 0.797817 0.060 Uiso 1 1 d R . . . .
H8B H 1.045705 0.164445 0.779517 0.060 Uiso 1 1 d R . . . .
Tb1 Tb 1.15260(2) 0.43072(3) 0.80327(2) 0.01441(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.501(9) . ?
C1 O1 1.195(8) . ?
C1 O2 1.293(8) . ?
C2 C3 1.387(10) . ?
C2 N1 1.313(9) . ?
C3 H3 0.9300 . ?
C3 C4 1.374(9) . ?
C4 H4 0.9300 . ?
C4 C5 1.363(9) . ?
C5 C6 1.371(9) . ?
C5 C7 1.488(8) . ?
C6 H6 0.9300 . ?
C6 N1 1.338(8) . ?
C7 C8 1.390(8) . ?
C7 C12 1.401(8) . ?
C8 H8 0.9300 . ?
C8 C9 1.377(8) . ?
C9 C10 1.383(9) . ?
C9 C14 1.484(8) . ?
C10 H10 0.9300 . ?
C10 C11 1.370(8) . ?
C11 H11 0.9300 . ?
C11 C12 1.389(8) . ?
C12 C13 1.493(8) . ?
C13 O5 1.271(7) . ?
C13 O6 1.262(7) . ?
C13 Tb1 2.884(6) 2_756 ?
C14 O3 1.257(7) . ?
C14 O4 1.260(7) . ?
C14 Tb1 2.761(6) 5_767 ?
N1 Tb1 2.542(5) 3_445 ?
O2 Tb1 2.353(5) 3_445 ?
O3 Tb1 2.392(4) 5_767 ?
O4 Tb1 2.421(4) 5_767 ?
O5 Tb1 2.553(4) 2_756 ?
O5 Tb1 2.453(4) . ?
O6 Tb1 2.457(4) 2_756 ?
O7 H7A 0.8501 . ?
O7 H7B 0.8500 . ?
O7 Tb1 2.337(4) . ?
O8 H8A 0.8501 . ?
O8 H8B 0.8501 . ?
O8 Tb1 2.495(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C2 118.3(7) . . ?
O1 C1 O2 126.1(6) . . ?
O2 C1 C2 115.6(6) . . ?
C3 C2 C1 122.0(6) . . ?
N1 C2 C1 115.7(6) . . ?
N1 C2 C3 122.2(6) . . ?
C2 C3 H3 120.6 . . ?
C4 C3 C2 118.8(7) . . ?
C4 C3 H3 120.6 . . ?
C3 C4 H4 120.2 . . ?
C5 C4 C3 119.6(6) . . ?
C5 C4 H4 120.2 . . ?
C4 C5 C6 117.6(6) . . ?
C4 C5 C7 124.1(6) . . ?
C6 C5 C7 118.2(6) . . ?
C5 C6 H6 118.1 . . ?
N1 C6 C5 123.9(6) . . ?
N1 C6 H6 118.1 . . ?
C8 C7 C5 120.3(5) . . ?
C8 C7 C12 118.3(5) . . ?
C12 C7 C5 121.4(5) . . ?
C7 C8 H8 119.4 . . ?
C9 C8 C7 121.2(6) . . ?
C9 C8 H8 119.4 . . ?
C8 C9 C10 119.6(5) . . ?
C8 C9 C14 120.6(6) . . ?
C10 C9 C14 119.8(5) . . ?
C9 C10 H10 119.7 . . ?
C11 C10 C9 120.6(6) . . ?
C11 C10 H10 119.7 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 120.0(6) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C13 123.3(5) . . ?
C11 C12 C7 120.3(5) . . ?
C11 C12 C13 116.2(5) . . ?
C12 C13 Tb1 175.9(4) . 2_756 ?
O5 C13 C12 121.2(5) . . ?
O5 C13 Tb1 62.2(3) . 2_756 ?
O6 C13 C12 118.7(5) . . ?
O6 C13 O5 120.1(5) . . ?
O6 C13 Tb1 57.9(3) . 2_756 ?
C9 C14 Tb1 171.0(4) . 5_767 ?
O3 C14 C9 119.1(5) . . ?
O3 C14 O4 120.4(5) . . ?
O3 C14 Tb1 59.9(3) . 5_767 ?
O4 C14 C9 120.4(6) . . ?
O4 C14 Tb1 61.2(3) . 5_767 ?
C2 N1 C6 117.8(6) . . ?
C2 N1 Tb1 115.1(4) . 3_445 ?
C6 N1 Tb1 124.0(4) . 3_445 ?
C1 O2 Tb1 124.0(4) . 3_445 ?
C14 O3 Tb1 93.1(3) . 5_767 ?
C14 O4 Tb1 91.6(4) . 5_767 ?
C13 O5 Tb1 142.4(4) . . ?
C13 O5 Tb1 91.6(3) . 2_756 ?
Tb1 O5 Tb1 111.28(15) . 2_756 ?
C13 O6 Tb1 96.4(4) . 2_756 ?
H7A O7 H7B 107.4 . . ?
Tb1 O7 H7A 101.4 . . ?
Tb1 O7 H7B 120.0 . . ?
H8A O8 H8B 107.4 . . ?
Tb1 O8 H8A 123.7 . . ?
Tb1 O8 H8B 128.4 . . ?
C14 Tb1 C13 169.43(18) 5_767 2_756 ?
N1 Tb1 C13 109.41(17) 3 2_756 ?
N1 Tb1 C14 68.73(18) 3 5_767 ?
N1 Tb1 O5 134.57(15) 3 2_756 ?
O2 Tb1 C13 91.34(16) 3 2_756 ?
O2 Tb1 C14 96.97(17) 3 5_767 ?
O2 Tb1 N1 65.12(16) 3 3 ?
O2 Tb1 O3 119.31(15) 3 5_767 ?
O2 Tb1 O4 76.69(15) 3 5_767 ?
O2 Tb1 O5 143.59(14) 3 . ?
O2 Tb1 O5 107.61(14) 3 2_756 ?
O2 Tb1 O6 75.37(16) 3 2_756 ?
O2 Tb1 O8 72.09(17) 3 . ?
O3 Tb1 C13 142.44(15) 5_767 2_756 ?
O3 Tb1 C14 27.04(16) 5_767 5_767 ?
O3 Tb1 N1 70.18(17) 5_767 3 ?
O3 Tb1 O4 53.99(14) 5_767 5_767 ?
O3 Tb1 O5 133.05(14) 5_767 2_756 ?
O3 Tb1 O5 76.06(14) 5_767 . ?
O3 Tb1 O6 137.65(15) 5_767 2_756 ?
O3 Tb1 O8 122.48(16) 5_767 . ?
O4 Tb1 C13 163.39(15) 5_767 2_756 ?
O4 Tb1 C14 27.15(17) 5_767 5_767 ?
O4 Tb1 N1 76.24(17) 5_767 3 ?
O4 Tb1 O5 148.47(14) 5_767 2_756 ?
O4 Tb1 O5 90.85(15) 5_767 . ?
O4 Tb1 O6 150.73(16) 5_767 2_756 ?
O4 Tb1 O8 79.80(16) 5_767 . ?
O5 Tb1 C13 92.19(15) . 2_756 ?
O5 Tb1 C13 26.13(15) 2_756 2_756 ?
O5 Tb1 C14 151.66(16) 2_756 5_767 ?
O5 Tb1 C14 84.99(16) . 5_767 ?
O5 Tb1 N1 145.20(15) . 3 ?
O5 Tb1 O5 66.88(15) . 2_756 ?
O5 Tb1 O6 117.05(14) . 2_756 ?
O5 Tb1 O8 72.08(16) . . ?
O6 Tb1 C13 25.79(16) 2_756 2_756 ?
O6 Tb1 C14 152.44(17) 2_756 5_767 ?
O6 Tb1 N1 84.23(16) 2_756 3 ?
O6 Tb1 O5 51.91(14) 2_756 2_756 ?
O6 Tb1 O8 99.61(17) 2_756 . ?
O7 Tb1 C13 72.85(15) . 2_756 ?
O7 Tb1 C14 96.78(17) . 5_767 ?
O7 Tb1 N1 74.95(17) . 3 ?
O7 Tb1 O2 128.99(16) . 3 ?
O7 Tb1 O3 70.93(14) . 5_767 ?
O7 Tb1 O4 123.66(15) . 5_767 ?
O7 Tb1 O5 86.45(15) . . ?
O7 Tb1 O5 78.78(14) . 2_756 ?
O7 Tb1 O6 70.10(16) . 2_756 ?
O7 Tb1 O8 149.01(17) . . ?
O8 Tb1 C13 85.61(17) . 2_756 ?
O8 Tb1 C14 103.11(18) . 5_767 ?
O8 Tb1 N1 134.53(17) . 3 ?
O8 Tb1 O5 72.40(15) . 2_756 ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C6 H6 O7 0.93 2.49 3.066(8) 119.9 3_445
O7 H7B O1 0.85 1.78 2.625(7) 175.8 1_565
O8 H8A O6 0.85 2.10 2.918(7) 161.5 3_545

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 179.3(6) . . . . ?
C1 C2 N1 C6 -177.2(5) . . . . ?
C1 C2 N1 Tb1 21.9(7) . . . 3_445 ?
C2 C1 O2 Tb1 -7.4(8) . . . 3_445 ?
C2 C3 C4 C5 -1.7(10) . . . . ?
C3 C2 N1 C6 3.4(9) . . . . ?
C3 C2 N1 Tb1 -157.5(5) . . . 3_445 ?
C3 C4 C5 C6 2.3(9) . . . . ?
C3 C4 C5 C7 -179.1(6) . . . . ?
C4 C5 C6 N1 -0.2(9) . . . . ?
C4 C5 C7 C8 -48.5(9) . . . . ?
C4 C5 C7 C12 134.8(7) . . . . ?
C5 C6 N1 C2 -2.7(9) . . . . ?
C5 C6 N1 Tb1 156.4(5) . . . 3_445 ?
C5 C7 C8 C9 -177.4(6) . . . . ?
C5 C7 C12 C11 175.8(6) . . . . ?
C5 C7 C12 C13 -9.4(9) . . . . ?
C6 C5 C7 C8 130.1(6) . . . . ?
C6 C5 C7 C12 -46.6(8) . . . . ?
C7 C5 C6 N1 -178.9(5) . . . . ?
C7 C8 C9 C10 2.0(10) . . . . ?
C7 C8 C9 C14 -177.4(6) . . . . ?
C7 C12 C13 O5 -52.0(8) . . . . ?
C7 C12 C13 O6 131.2(6) . . . . ?
C8 C7 C12 C11 -0.9(9) . . . . ?
C8 C7 C12 C13 173.9(6) . . . . ?
C8 C9 C10 C11 -1.7(10) . . . . ?
C8 C9 C14 O3 7.8(9) . . . . ?
C8 C9 C14 O4 -171.5(6) . . . . ?
C9 C10 C11 C12 0.1(10) . . . . ?
C9 C14 O3 Tb1 -169.7(5) . . . 5_767 ?
C9 C14 O4 Tb1 169.8(5) . . . 5_767 ?
C10 C9 C14 O3 -171.6(6) . . . . ?
C10 C9 C14 O4 9.2(9) . . . . ?
C10 C11 C12 C7 1.2(10) . . . . ?
C10 C11 C12 C13 -173.9(6) . . . . ?
C11 C12 C13 O5 123.0(6) . . . . ?
C11 C12 C13 O6 -53.8(8) . . . . ?
C12 C7 C8 C9 -0.7(9) . . . . ?
C12 C13 O5 Tb1 -177.5(5) . . . 2_756 ?
C12 C13 O5 Tb1 -48.3(9) . . . . ?
C12 C13 O6 Tb1 177.6(4) . . . 2_756 ?
C14 C9 C10 C11 177.7(6) . . . . ?
N1 C2 C3 C4 -1.3(10) . . . . ?
O1 C1 C2 C3 -12.8(10) . . . . ?
O1 C1 C2 N1 167.7(6) . . . . ?
O1 C1 O2 Tb1 173.9(6) . . . 3_445 ?
O2 C1 C2 C3 168.4(6) . . . . ?
O2 C1 C2 N1 -11.0(8) . . . . ?
O3 C14 O4 Tb1 -9.4(6) . . . 5_767 ?
O4 C14 O3 Tb1 9.5(6) . . . 5_767 ?
O5 C13 O6 Tb1 0.8(6) . . . 2_756 ?
O6 C13 O5 Tb1 -0.7(6) . . . 2_756 ?
O6 C13 O5 Tb1 128.4(6) . . . . ?
Tb1 C13 O5 Tb1 129.2(6) 2_756 . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
