# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Complex_1
_database_code_depnum_ccdc_archive 'CCDC 1912162'
loop_
_audit_author_name
_audit_author_address
'Jose Maria Moreno'
;Universidad de Granada
Spain
;
_audit_update_record             
;
2019-09-03 deposited with the CCDC.	2019-09-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
'Olex2 1.2 (compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C54 H86 Co2 N8 O24 Y2'
_chemical_formula_weight         1526.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.959(3)
_cell_length_b                   12.394(3)
_cell_length_c                   19.345(4)
_cell_angle_alpha                90
_cell_angle_beta                 94.40(3)
_cell_angle_gamma                90
_cell_volume                     3097.9(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9067
_cell_measurement_theta_min      2.558
_cell_measurement_theta_max      26.415

_exptl_crystal_description       needle
_exptl_crystal_colour            pink
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.637
_exptl_crystal_F_000             1580
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.189
_exptl_crystal_size_mid          0.084
_exptl_crystal_size_min          0.054
_exptl_absorpt_coefficient_mu    2.468
_shelx_estimated_absorpt_T_min   0.653
_shelx_estimated_absorpt_T_max   0.878
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7630
_exptl_absorpt_correction_T_max  0.9449
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0536 before and 0.0290 after correction.
The Ratio of minimum to maximum transmission is 0.8075.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100.0
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'four-circle diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            60408
_diffrn_reflns_av_unetI/netI     0.0197
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.277
_diffrn_reflns_theta_max         26.475
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6376
_reflns_number_gt                5534
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro, Agilent Technologies (2014)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_refine_special_details          
; 
Solvent methanol molecules were refined with the hydroxyl group disordered over two positions. 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0265P)²+4.8892P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6376
_refine_ls_number_parameters     433
_refine_ls_number_restraints     3
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0305
_refine_ls_wR_factor_ref         0.0749
_refine_ls_wR_factor_gt          0.0695
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_restrained_S_all      1.125
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Y1 Y 0.37814(2) 0.41430(2) 0.02602(2) 0.01344(7) Uani 1 1 d . . . . .
Co2 Co 0.26210(2) 0.63284(3) 0.10305(2) 0.01398(8) Uani 1 1 d . . . . .
O3 O 0.27046(13) 0.55862(13) 0.00605(9) 0.0161(4) Uani 1 1 d . . . . .
O4 O 0.28398(13) 0.42084(13) -0.09358(9) 0.0182(4) Uani 1 1 d . . . . .
O1 O 0.50571(13) 0.36466(13) 0.12009(9) 0.0171(4) Uani 1 1 d . . . . .
O2 O 0.33128(12) 0.47904(13) 0.13020(9) 0.0148(3) Uani 1 1 d . . . . .
O9 O 0.32973(13) 0.23847(15) 0.08738(10) 0.0215(4) Uani 1 1 d . . . . .
O6 O 0.40307(13) 0.70744(14) 0.09272(10) 0.0186(4) Uani 1 1 d . . . . .
N7 N 0.24084(16) 0.23214(17) 0.05511(11) 0.0185(4) Uani 1 1 d . . . . .
O11 O 0.18054(16) 0.15891(16) 0.06511(12) 0.0325(5) Uani 1 1 d . . . . .
O7 O 0.45711(13) 0.26995(13) -0.03245(9) 0.0176(4) Uani 1 1 d . . . . .
O10 O 0.21821(13) 0.30688(14) 0.01149(10) 0.0212(4) Uani 1 1 d . . . . .
O5 O 0.48500(13) 0.56706(13) 0.04629(9) 0.0165(4) Uani 1 1 d . . . . .
N2 N 0.09979(15) 0.58956(17) 0.11474(11) 0.0163(4) Uani 1 1 d . . . . .
C6 C 0.45386(19) 0.5162(2) 0.30583(14) 0.0187(5) Uani 1 1 d . . . . .
H6 H 0.440602 0.550370 0.347025 0.022 Uiso 1 1 calc R U . . .
C2 C 0.49271(18) 0.41580(19) 0.18332(13) 0.0165(5) Uani 1 1 d . . . . .
C25 C 0.22811(18) 0.5881(2) -0.05627(13) 0.0159(5) Uani 1 1 d . . . . .
N3 N 0.18328(16) 0.77665(17) 0.05142(12) 0.0196(5) Uani 1 1 d . . . . .
C20 C 0.13734(18) 0.6373(2) -0.19001(14) 0.0194(5) Uani 1 1 d . . . . .
C1 C 0.5647(2) 0.2658(2) 0.12460(14) 0.0205(5) Uani 1 1 d . . . . .
H1A H 0.636694 0.282364 0.134631 0.031 Uiso 1 1 calc R U . . .
H1B H 0.555613 0.227944 0.081281 0.031 Uiso 1 1 calc R U . . .
H1C H 0.541140 0.221468 0.160889 0.031 Uiso 1 1 calc R U . . .
N1 N 0.25401(15) 0.67017(16) 0.21274(11) 0.0162(4) Uani 1 1 d . . . . .
C22 C 0.18499(18) 0.5367(2) -0.17650(14) 0.0191(5) Uani 1 1 d . . . . .
H22 H 0.186214 0.485490 -0.211559 0.023 Uiso 1 1 calc R U . . .
C40 C 0.52581(18) 0.33004(19) -0.05884(13) 0.0161(5) Uani 1 1 d . . . . .
C23 C 0.22978(18) 0.51430(19) -0.11128(13) 0.0161(5) Uani 1 1 d . . . . .
C14 C 0.03993(19) 0.6459(2) 0.05742(14) 0.0203(5) Uani 1 1 d . . . . .
H14A H -0.033373 0.639696 0.063713 0.024 Uiso 1 1 calc R U . . .
H14B H 0.052698 0.611683 0.013810 0.024 Uiso 1 1 calc R U . . .
C7 C 0.38057(18) 0.52254(19) 0.24886(14) 0.0166(5) Uani 1 1 d . . . . .
C3 C 0.56412(18) 0.4084(2) 0.23982(14) 0.0190(5) Uani 1 1 d . . . . .
H3 H 0.624608 0.369017 0.236511 0.023 Uiso 1 1 calc R U . . .
C13 C 0.08239(19) 0.4717(2) 0.10587(14) 0.0194(5) Uani 1 1 d . . . . .
H13A H 0.010185 0.455991 0.108177 0.029 Uiso 1 1 calc R U . . .
H13B H 0.121891 0.433431 0.142055 0.029 Uiso 1 1 calc R U . . .
H13C H 0.103842 0.449429 0.061648 0.029 Uiso 1 1 calc R U . . .
C8 C 0.39936(18) 0.47387(19) 0.18605(13) 0.0143(5) Uani 1 1 d . . . . .
C18 C 0.18724(18) 0.6908(2) -0.07061(14) 0.0175(5) Uani 1 1 d . . . . .
C9 C 0.27544(18) 0.5719(2) 0.25640(14) 0.0174(5) Uani 1 1 d . . . . .
H9A H 0.222730 0.518217 0.244014 0.021 Uiso 1 1 calc R U . . .
H9B H 0.270146 0.590837 0.304650 0.021 Uiso 1 1 calc R U . . .
C21 C 0.0845(2) 0.6581(2) -0.26091(16) 0.0277(6) Uani 1 1 d . . . . .
H21A H 0.068301 0.733424 -0.265614 0.042 Uiso 1 1 calc R U . . .
H21B H 0.021866 0.616587 -0.266565 0.042 Uiso 1 1 calc R U . . .
H21C H 0.129690 0.637441 -0.295690 0.042 Uiso 1 1 calc R U . . .
C19 C 0.14085(18) 0.7125(2) -0.13712(14) 0.0195(5) Uani 1 1 d . . . . .
H19 H 0.111371 0.779983 -0.145931 0.023 Uiso 1 1 calc R U . . .
C17 C 0.2116(2) 0.7834(2) -0.02162(14) 0.0207(5) Uani 1 1 d . . . . .
H17A H 0.285674 0.795899 -0.020224 0.025 Uiso 1 1 calc R U . . .
H17B H 0.178265 0.847148 -0.042079 0.025 Uiso 1 1 calc R U . . .
C4 C 0.54596(19) 0.4599(2) 0.30201(15) 0.0211(5) Uani 1 1 d . . . . .
C11 C 0.14499(18) 0.7039(2) 0.21982(14) 0.0181(5) Uani 1 1 d . . . . .
H11A H 0.133772 0.774932 0.199596 0.022 Uiso 1 1 calc R U . . .
H11B H 0.132866 0.708452 0.268591 0.022 Uiso 1 1 calc R U . . .
C24 C 0.2843(3) 0.3390(2) -0.14586(16) 0.0316(7) Uani 1 1 d . . . . .
H24A H 0.214371 0.320274 -0.161077 0.047 Uiso 1 1 calc R U . . .
H24B H 0.319758 0.276265 -0.127069 0.047 Uiso 1 1 calc R U . . .
H24C H 0.319125 0.365586 -0.184479 0.047 Uiso 1 1 calc R U . . .
C5 C 0.6251(2) 0.4525(2) 0.36343(16) 0.0287(6) Uani 1 1 d . . . . .
H5A H 0.645580 0.378684 0.370485 0.043 Uiso 1 1 calc R U . . .
H5B H 0.595341 0.478990 0.404114 0.043 Uiso 1 1 calc R U . . .
H5C H 0.684480 0.495240 0.354717 0.043 Uiso 1 1 calc R U . . .
C15 C 0.06903(19) 0.7645(2) 0.05441(15) 0.0220(6) Uani 1 1 d . . . . .
H15A H 0.033605 0.797415 0.013745 0.026 Uiso 1 1 calc R U . . .
H15B H 0.047249 0.801251 0.095084 0.026 Uiso 1 1 calc R U . . .
C12 C 0.06866(19) 0.6245(2) 0.18407(14) 0.0186(5) Uani 1 1 d . . . . .
H12A H 0.063422 0.561505 0.213353 0.022 Uiso 1 1 calc R U . . .
H12B H 0.000846 0.657898 0.178394 0.022 Uiso 1 1 calc R U . . .
C10 C 0.3238(2) 0.7569(2) 0.24023(16) 0.0239(6) Uani 1 1 d . . . . .
H10A H 0.308667 0.773758 0.286829 0.036 Uiso 1 1 calc R U . . .
H10B H 0.313651 0.819998 0.211729 0.036 Uiso 1 1 calc R U . . .
H10C H 0.394295 0.733320 0.239999 0.036 Uiso 1 1 calc R U . . .
C16 C 0.2174(2) 0.8814(2) 0.08283(16) 0.0266(6) Uani 1 1 d . . . . .
H16A H 0.186195 0.939523 0.055835 0.040 Uiso 1 1 calc R U . . .
H16B H 0.291332 0.886932 0.083614 0.040 Uiso 1 1 calc R U . . .
H16C H 0.196560 0.885550 0.129331 0.040 Uiso 1 1 calc R U . . .
O1W O 0.42597(18) 0.03479(19) 0.15435(12) 0.0369(5) Uani 1 1 d G . . . .
H1WA H 0.466930 0.001230 0.129638 0.055 Uiso 1 1 d G U . . .
H1WB H 0.394459 0.083629 0.130190 0.055 Uiso 1 1 d G U . . .
C1M C 0.3845(9) 0.0304(17) -0.0546(7) 0.065(3) Uani 0.548(10) 1 d D . P A 1
H1MA H 0.364016 0.025955 -0.103262 0.097 Uiso 0.548(10) 1 calc R U P A 1
H1MB H 0.341992 0.082360 -0.033367 0.097 Uiso 0.548(10) 1 calc R U P A 1
H1MC H 0.376308 -0.038926 -0.033551 0.097 Uiso 0.548(10) 1 calc R U P A 1
O1M1 O 0.4862(6) 0.0615(4) -0.0454(4) 0.059(3) Uani 0.548(10) 1 d D . P A 1
H1M1 H 0.489392 0.127208 -0.040723 0.071 Uiso 0.548(10) 1 calc R U P A 1
O1M2 O 0.4241(5) 0.0656(4) -0.0801(3) 0.0287(16) Uani 0.452(10) 1 d D . P A 2
H1M2 H 0.430835 0.129954 -0.070951 0.034 Uiso 0.452(10) 1 calc R U P A 2
C1N C 0.3784(15) 0.016(2) -0.0284(8) 0.065(3) Uani 0.452(10) 1 d D . P A 2
H1NA H 0.304843 0.013805 -0.039162 0.097 Uiso 0.452(10) 1 calc R U P A 2
H1NB H 0.393627 0.054091 0.014234 0.097 Uiso 0.452(10) 1 calc R U P A 2
H1NC H 0.404190 -0.056893 -0.023452 0.097 Uiso 0.452(10) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Y1 O3 2.2833(17) . ?
Y1 O2 2.2939(17) . ?
Y1 O5 2.3530(17) 3_665 ?
Y1 O5 2.3607(17) . ?
Y1 O7 2.3886(17) . ?
Y1 O1 2.4415(19) . ?
Y1 O10 2.4613(18) . ?
Y1 O4 2.5328(19) . ?
Y1 O9 2.5818(18) . ?
Y1 C40 2.816(2) . ?
Y1 N7 2.955(2) . ?
Y1 Co2 3.4873(7) . ?
Co2 O6 2.0708(17) . ?
Co2 O3 2.0998(18) . ?
Co2 O2 2.1542(17) . ?
Co2 N1 2.182(2) . ?
Co2 N2 2.199(2) . ?
Co2 N3 2.250(2) . ?
O3 C25 1.337(3) . ?
O4 C23 1.384(3) . ?
O4 C24 1.433(3) . ?
O1 C2 1.399(3) . ?
O1 C1 1.443(3) . ?
O2 C8 1.343(3) . ?
O9 N7 1.270(3) . ?
O6 C40 1.260(3) 3_665 ?
N7 O11 1.223(3) . ?
N7 O10 1.272(3) . ?
O7 C40 1.295(3) . ?
O5 C40 1.308(3) 3_665 ?
N2 C14 1.479(3) . ?
N2 C13 1.486(3) . ?
N2 C12 1.494(3) . ?
C6 C4 1.389(4) . ?
C6 C7 1.401(4) . ?
C2 C3 1.380(4) . ?
C2 C8 1.412(3) . ?
C25 C18 1.398(3) . ?
C25 C23 1.405(4) . ?
N3 C16 1.487(3) . ?
N3 C17 1.489(3) . ?
N3 C15 1.494(3) . ?
C20 C19 1.382(4) . ?
C20 C22 1.407(4) . ?
C20 C21 1.507(4) . ?
N1 C10 1.477(3) . ?
N1 C11 1.490(3) . ?
N1 C9 1.496(3) . ?
C22 C23 1.376(4) . ?
C14 C15 1.519(4) . ?
C7 C8 1.395(4) . ?
C7 C9 1.510(3) . ?
C3 C4 1.398(4) . ?
C18 C19 1.404(4) . ?
C18 C17 1.507(4) . ?
C4 C5 1.511(4) . ?
C11 C12 1.523(3) . ?
C1M O1M1 1.372(7) . ?
O1M2 C1N 1.352(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Y1 O2 71.04(6) . . ?
O3 Y1 O5 107.54(6) . 3_665 ?
O2 Y1 O5 138.63(6) . 3_665 ?
O3 Y1 O5 75.10(6) . . ?
O2 Y1 O5 76.41(6) . . ?
O5 Y1 O5 63.94(7) 3_665 . ?
O3 Y1 O7 141.74(6) . . ?
O2 Y1 O7 146.10(6) . . ?
O5 Y1 O7 54.70(6) 3_665 . ?
O5 Y1 O7 114.34(6) . . ?
O3 Y1 O1 133.92(6) . . ?
O2 Y1 O1 69.09(6) . . ?
O5 Y1 O1 88.26(6) 3_665 . ?
O5 Y1 O1 73.94(6) . . ?
O7 Y1 O1 82.76(6) . . ?
O3 Y1 O10 84.61(6) . . ?
O2 Y1 O10 90.70(6) . . ?
O5 Y1 O10 130.67(6) 3_665 . ?
O5 Y1 O10 158.58(6) . . ?
O7 Y1 O10 85.89(6) . . ?
O1 Y1 O10 117.70(6) . . ?
O3 Y1 O4 64.85(6) . . ?
O2 Y1 O4 130.53(6) . . ?
O5 Y1 O4 77.65(6) 3_665 . ?
O5 Y1 O4 111.19(6) . . ?
O7 Y1 O4 77.60(6) . . ?
O1 Y1 O4 160.06(6) . . ?
O10 Y1 O4 64.57(6) . . ?
O3 Y1 O9 124.90(6) . . ?
O2 Y1 O9 78.54(6) . . ?
O5 Y1 O9 125.24(6) 3_665 . ?
O5 Y1 O9 139.53(6) . . ?
O7 Y1 O9 73.35(6) . . ?
O1 Y1 O9 67.61(6) . . ?
O10 Y1 O9 50.49(6) . . ?
O4 Y1 O9 109.27(6) . . ?
O3 Y1 C40 128.74(7) . . ?
O2 Y1 C40 151.58(7) . . ?
O5 Y1 C40 27.49(6) 3_665 . ?
O5 Y1 C40 88.74(6) . . ?
O7 Y1 C40 27.27(6) . . ?
O1 Y1 C40 83.65(7) . . ?
O10 Y1 C40 109.68(7) . . ?
O4 Y1 C40 77.33(7) . . ?
O9 Y1 C40 98.91(7) . . ?
O3 Y1 N7 105.17(6) . . ?
O2 Y1 N7 84.03(6) . . ?
O5 Y1 N7 132.88(6) 3_665 . ?
O5 Y1 N7 159.26(6) . . ?
O7 Y1 N7 78.70(6) . . ?
O1 Y1 N7 92.79(6) . . ?
O10 Y1 N7 25.11(6) . . ?
O4 Y1 N7 86.76(6) . . ?
O9 Y1 N7 25.38(6) . . ?
C40 Y1 N7 105.89(7) . . ?
O3 Y1 Co2 35.50(5) . . ?
O2 Y1 Co2 36.97(4) . . ?
O5 Y1 Co2 123.17(4) 3_665 . ?
O5 Y1 Co2 64.71(4) . . ?
O7 Y1 Co2 176.92(4) . . ?
O1 Y1 Co2 99.60(4) . . ?
O10 Y1 Co2 94.70(5) . . ?
O4 Y1 Co2 99.91(4) . . ?
O9 Y1 Co2 109.34(5) . . ?
C40 Y1 Co2 150.66(5) . . ?
N7 Y1 Co2 103.08(5) . . ?
O6 Co2 O3 90.17(7) . . ?
O6 Co2 O2 93.72(7) . . ?
O3 Co2 O2 77.37(7) . . ?
O6 Co2 N1 96.18(8) . . ?
O3 Co2 N1 166.25(7) . . ?
O2 Co2 N1 90.04(7) . . ?
O6 Co2 N2 167.60(7) . . ?
O3 Co2 N2 95.76(8) . . ?
O2 Co2 N2 98.20(7) . . ?
N1 Co2 N2 80.44(8) . . ?
O6 Co2 N3 88.70(8) . . ?
O3 Co2 N3 90.18(8) . . ?
O2 Co2 N3 167.31(7) . . ?
N1 Co2 N3 102.10(8) . . ?
N2 Co2 N3 80.42(8) . . ?
O6 Co2 Y1 83.86(5) . . ?
O3 Co2 Y1 39.15(5) . . ?
O2 Co2 Y1 39.82(5) . . ?
N1 Co2 Y1 129.39(6) . . ?
N2 Co2 Y1 107.56(6) . . ?
N3 Co2 Y1 128.44(6) . . ?
C25 O3 Co2 129.82(15) . . ?
C25 O3 Y1 124.76(15) . . ?
Co2 O3 Y1 105.35(7) . . ?
C23 O4 C24 116.6(2) . . ?
C23 O4 Y1 116.91(15) . . ?
C24 O4 Y1 126.50(15) . . ?
C2 O1 C1 115.50(19) . . ?
C2 O1 Y1 114.66(14) . . ?
C1 O1 Y1 125.76(15) . . ?
C8 O2 Co2 118.28(14) . . ?
C8 O2 Y1 119.23(14) . . ?
Co2 O2 Y1 103.21(7) . . ?
N7 O9 Y1 93.98(13) . . ?
C40 O6 Co2 124.86(16) 3_665 . ?
O11 N7 O9 122.3(2) . . ?
O11 N7 O10 121.9(2) . . ?
O9 N7 O10 115.8(2) . . ?
O11 N7 Y1 177.02(18) . . ?
O9 N7 Y1 60.64(12) . . ?
O10 N7 Y1 55.17(11) . . ?
C40 O7 Y1 95.07(14) . . ?
N7 O10 Y1 99.72(14) . . ?
C40 O5 Y1 96.38(14) 3_665 3_665 ?
C40 O5 Y1 137.99(15) 3_665 . ?
Y1 O5 Y1 116.06(7) 3_665 . ?
C14 N2 C13 108.2(2) . . ?
C14 N2 C12 111.95(19) . . ?
C13 N2 C12 109.8(2) . . ?
C14 N2 Co2 104.97(14) . . ?
C13 N2 Co2 111.45(14) . . ?
C12 N2 Co2 110.37(15) . . ?
C4 C6 C7 121.3(2) . . ?
C3 C2 O1 123.0(2) . . ?
C3 C2 C8 121.9(2) . . ?
O1 C2 C8 115.1(2) . . ?
O3 C25 C18 123.4(2) . . ?
O3 C25 C23 118.4(2) . . ?
C18 C25 C23 118.1(2) . . ?
C16 N3 C17 104.5(2) . . ?
C16 N3 C15 109.7(2) . . ?
C17 N3 C15 111.1(2) . . ?
C16 N3 Co2 113.59(17) . . ?
C17 N3 Co2 109.22(15) . . ?
C15 N3 Co2 108.68(15) . . ?
C19 C20 C22 118.1(2) . . ?
C19 C20 C21 123.0(2) . . ?
C22 C20 C21 118.9(2) . . ?
C10 N1 C11 108.74(19) . . ?
C10 N1 C9 107.9(2) . . ?
C11 N1 C9 108.22(19) . . ?
C10 N1 Co2 115.51(16) . . ?
C11 N1 Co2 105.40(15) . . ?
C9 N1 Co2 110.83(15) . . ?
C23 C22 C20 119.8(2) . . ?
O6 C40 O7 123.1(2) 3_665 . ?
O6 C40 O5 123.3(2) 3_665 3_665 ?
O7 C40 O5 113.6(2) . 3_665 ?
O6 C40 Y1 175.51(19) 3_665 . ?
O7 C40 Y1 57.66(12) . . ?
O5 C40 Y1 56.14(11) 3_665 . ?
C22 C23 O4 124.5(2) . . ?
C22 C23 C25 122.2(2) . . ?
O4 C23 C25 113.3(2) . . ?
N2 C14 C15 111.6(2) . . ?
C8 C7 C6 120.5(2) . . ?
C8 C7 C9 118.6(2) . . ?
C6 C7 C9 120.6(2) . . ?
C2 C3 C4 120.3(2) . . ?
O2 C8 C7 122.2(2) . . ?
O2 C8 C2 120.4(2) . . ?
C7 C8 C2 117.4(2) . . ?
C25 C18 C19 119.0(2) . . ?
C25 C18 C17 120.7(2) . . ?
C19 C18 C17 119.0(2) . . ?
N1 C9 C7 113.9(2) . . ?
C20 C19 C18 122.5(2) . . ?
N3 C17 C18 119.9(2) . . ?
C6 C4 C3 118.5(2) . . ?
C6 C4 C5 121.5(2) . . ?
C3 C4 C5 120.0(2) . . ?
N1 C11 C12 111.38(19) . . ?
N3 C15 C14 110.4(2) . . ?
N2 C12 C11 112.6(2) . . ?

_refine_diff_density_max         0.432
_refine_diff_density_min         -0.866
_refine_diff_density_rms         0.083

