# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Compound1
_database_code_depnum_ccdc_archive 'CCDC 1899155'
loop_
_audit_author_name
_audit_author_address
'Antonio Rodriquez-Dieguez'
;University of Granada
Spain
;
_audit_update_record             
;
2019-02-24 deposited with the CCDC.	2019-11-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H31 Cl P Rh S2 Si'
_chemical_formula_weight         677.11

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.1830(7)
_cell_length_b                   10.8556(5)
_cell_length_c                   21.0205(8)
_cell_angle_alpha                90
_cell_angle_beta                 123.025(3)
_cell_angle_gamma                90
_cell_volume                     3096.2(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    82263
_cell_measurement_theta_min      2.40
_cell_measurement_theta_max      28.82

_exptl_crystal_description       Prismatic
_exptl_crystal_colour            Colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_F_000             1384
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_exptl_absorpt_coefficient_mu    0.884
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Empirical
_exptl_absorpt_correction_T_min  0.574
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_process_details   'Bruker SADABS (Bruker, 1999)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'Phi and Omega Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            130618
_diffrn_reflns_av_unetI/netI     0.0386
_diffrn_reflns_av_R_equivalents  0.0895
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.203
_diffrn_reflns_theta_max         28.835
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             8069
_reflns_number_gt                7262
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker ApexII'
_computing_cell_refinement       'Bruker Apex II'
_computing_data_reduction        'Bruker Apex II'
_computing_structure_solution    'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0768P)²+4.2278P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8069
_refine_ls_number_parameters     349
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0549
_refine_ls_R_factor_gt           0.0464
_refine_ls_wR_factor_ref         0.1318
_refine_ls_wR_factor_gt          0.1210
_refine_ls_goodness_of_fit_ref   1.173
_refine_ls_restrained_S_all      1.173
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.35312(2) 0.30653(2) 0.32469(2) 0.01058(8) Uani 1 1 d . . . . .
H01 H 0.3798 0.3911 0.2802 0.013 Uiso 1 1 d R U . . .
Cl1 Cl 0.28613(5) 0.45948(6) 0.37605(4) 0.01656(14) Uani 1 1 d . . . . .
S1 S 0.31644(5) 0.13691(6) 0.38169(4) 0.01663(14) Uani 1 1 d . . . . .
S2 S 0.50403(5) 0.35877(6) 0.43587(4) 0.01358(14) Uani 1 1 d . . . . .
P1 P 0.20799(5) 0.28998(6) 0.21064(4) 0.01274(14) Uani 1 1 d . . . . .
Si1 Si 0.44020(6) 0.16790(7) 0.30284(4) 0.01389(15) Uani 1 1 d . . . . .
C1 C 0.4050(3) 0.1308(3) 0.48329(17) 0.0286(7) Uani 1 1 d . . . . .
H1A H 0.3930 0.0589 0.5037 0.043 Uiso 1 1 d R U . . .
H1B H 0.3984 0.2032 0.5064 0.043 Uiso 1 1 d R U . . .
H1C H 0.4705 0.1272 0.4936 0.043 Uiso 1 1 d R U . . .
C2 C 0.5333(2) 0.5121(3) 0.42000(17) 0.0205(6) Uani 1 1 d . . . . .
H2A H 0.5934 0.5396 0.4647 0.031 Uiso 1 1 d R U . . .
H2B H 0.4808 0.5674 0.4089 0.031 Uiso 1 1 d R U . . .
H2C H 0.5413 0.5105 0.3780 0.031 Uiso 1 1 d R U . . .
C5 C 0.59983(19) 0.2712(3) 0.43977(15) 0.0148(5) Uani 1 1 d . . . . .
C6 C 0.6964(2) 0.2859(3) 0.50195(16) 0.0177(5) Uani 1 1 d . . . . .
H6 H 0.7107 0.3427 0.5398 0.021 Uiso 1 1 calc R U . . .
C7 C 0.7710(2) 0.2148(3) 0.50669(19) 0.0232(6) Uani 1 1 d . . . . .
H7 H 0.8357 0.2239 0.5477 0.028 Uiso 1 1 calc R U . . .
C8 C 0.7485(2) 0.1300(3) 0.4500(2) 0.0266(7) Uani 1 1 d . . . . .
H8 H 0.7983 0.0824 0.4531 0.032 Uiso 1 1 calc R U . . .
C9 C 0.6517(2) 0.1156(3) 0.38839(19) 0.0242(6) Uani 1 1 d . . . . .
H9 H 0.6378 0.0584 0.3509 0.029 Uiso 1 1 calc R U . . .
C10 C 0.5750(2) 0.1863(2) 0.38219(17) 0.0164(5) Uani 1 1 d . . . . .
C11 C 0.4032(2) 0.0106(3) 0.31768(16) 0.0175(5) Uani 1 1 d . . . . .
C12 C 0.4268(2) -0.0999(3) 0.29570(18) 0.0240(6) Uani 1 1 d . . . . .
H12 H 0.4616 -0.0967 0.2722 0.029 Uiso 1 1 calc R U . . .
C13 C 0.3991(3) -0.2126(3) 0.3084(2) 0.0307(7) Uani 1 1 d . . . . .
H13 H 0.4161 -0.2845 0.2941 0.037 Uiso 1 1 calc R U . . .
C14 C 0.3460(3) -0.2198(3) 0.3425(2) 0.0308(7) Uani 1 1 d . . . . .
H14 H 0.3272 -0.2961 0.3507 0.037 Uiso 1 1 calc R U . . .
C15 C 0.3208(3) -0.1124(3) 0.36428(19) 0.0256(6) Uani 1 1 d . . . . .
H15 H 0.2844 -0.1165 0.3865 0.031 Uiso 1 1 calc R U . . .
C16 C 0.3503(2) 0.0009(3) 0.35264(16) 0.0176(5) Uani 1 1 d . . . . .
C17 C 0.1512(2) 0.4398(3) 0.16883(15) 0.0175(5) Uani 1 1 d . . . . .
C18 C 0.2041(2) 0.5490(3) 0.19350(17) 0.0220(6) Uani 1 1 d . . . . .
H18 H 0.2705 0.5477 0.2323 0.026 Uiso 1 1 calc R U . . .
C19 C 0.1582(3) 0.6608(3) 0.1603(2) 0.0290(7) Uani 1 1 d . . . . .
H19 H 0.1942 0.7336 0.1771 0.035 Uiso 1 1 calc R U . . .
C20 C 0.0605(3) 0.6642(3) 0.1031(2) 0.0331(8) Uani 1 1 d . . . . .
H20 H 0.0303 0.7389 0.0809 0.040 Uiso 1 1 calc R U . . .
C21 C 0.0077(3) 0.5572(4) 0.0790(3) 0.0514(12) Uani 1 1 d . . . . .
H21 H -0.0587 0.5594 0.0402 0.062 Uiso 1 1 calc R U . . .
C22 C 0.0519(3) 0.4452(4) 0.1115(2) 0.0407(10) Uani 1 1 d . . . . .
H22 H 0.0147 0.3733 0.0948 0.049 Uiso 1 1 calc R U . . .
C23 C 0.1071(2) 0.2155(3) 0.21145(17) 0.0195(6) Uani 1 1 d . . . . .
C24 C 0.0858(3) 0.2638(4) 0.2627(2) 0.0373(9) Uani 1 1 d . . . . .
H24 H 0.1251 0.3260 0.2959 0.045 Uiso 1 1 calc R U . . .
C25 C 0.0069(3) 0.2196(5) 0.2643(3) 0.0511(12) Uani 1 1 d . . . . .
H25 H -0.0073 0.2539 0.2978 0.061 Uiso 1 1 calc R U . . .
C26 C -0.0509(3) 0.1258(4) 0.2170(2) 0.0419(10) Uani 1 1 d . . . . .
H26 H -0.1032 0.0957 0.2191 0.050 Uiso 1 1 calc R U . . .
C27 C -0.0312(3) 0.0771(4) 0.1669(2) 0.0388(9) Uani 1 1 d . . . . .
H27 H -0.0700 0.0133 0.1351 0.047 Uiso 1 1 calc R U . . .
C28 C 0.0472(3) 0.1223(3) 0.1628(2) 0.0298(7) Uani 1 1 d . . . . .
H28 H 0.0590 0.0898 0.1275 0.036 Uiso 1 1 calc R U . . .
C29 C 0.2112(2) 0.2124(3) 0.13521(16) 0.0185(6) Uani 1 1 d . . . . .
C30 C 0.2089(2) 0.2785(4) 0.07771(18) 0.0275(7) Uani 1 1 d . . . . .
H30 H 0.2040 0.3639 0.0768 0.033 Uiso 1 1 calc R U . . .
C31 C 0.2140(3) 0.2183(5) 0.0213(2) 0.0389(9) Uani 1 1 d . . . . .
H31 H 0.2123 0.2634 -0.0170 0.047 Uiso 1 1 calc R U . . .
C32 C 0.2218(3) 0.0914(5) 0.0226(2) 0.0410(10) Uani 1 1 d . . . . .
H32 H 0.2231 0.0511 -0.0158 0.049 Uiso 1 1 calc R U . . .
C33 C 0.2275(3) 0.0242(4) 0.0806(2) 0.0358(9) Uani 1 1 d . . . . .
H33 H 0.2346 -0.0610 0.0821 0.043 Uiso 1 1 calc R U . . .
C34 C 0.2226(2) 0.0844(3) 0.13712(18) 0.0269(7) Uani 1 1 d . . . . .
H34 H 0.2269 0.0391 0.1764 0.032 Uiso 1 1 calc R U . . .
H1 H 0.435(2) 0.159(3) 0.2301(18) 0.008(7) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.2712(7) . ?
Rh1 Si1 2.2731(8) . ?
Rh1 S2 2.3508(7) . ?
Rh1 S1 2.4400(7) . ?
Rh1 Cl1 2.5245(7) . ?
Rh1 H01 1.5309 . ?
S1 C16 1.793(3) . ?
S1 C1 1.812(3) . ?
S2 C5 1.782(3) . ?
S2 C2 1.811(3) . ?
P1 C29 1.821(3) . ?
P1 C23 1.831(3) . ?
P1 C17 1.839(3) . ?
Si1 C11 1.891(3) . ?
Si1 C10 1.901(3) . ?
Si1 H1 1.49(3) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C5 C10 1.395(4) . ?
C5 C6 1.396(4) . ?
C6 C7 1.391(4) . ?
C6 H6 0.9300 . ?
C7 C8 1.388(5) . ?
C7 H7 0.9300 . ?
C8 C9 1.394(4) . ?
C8 H8 0.9300 . ?
C9 C10 1.404(4) . ?
C9 H9 0.9300 . ?
C11 C16 1.404(4) . ?
C11 C12 1.411(4) . ?
C12 C13 1.379(5) . ?
C12 H12 0.9300 . ?
C13 C14 1.389(5) . ?
C13 H13 0.9300 . ?
C14 C15 1.393(5) . ?
C14 H14 0.9300 . ?
C15 C16 1.388(4) . ?
C15 H15 0.9300 . ?
C17 C18 1.387(4) . ?
C17 C22 1.388(4) . ?
C18 C19 1.395(4) . ?
C18 H18 0.9300 . ?
C19 C20 1.369(5) . ?
C19 H19 0.9300 . ?
C20 C21 1.365(6) . ?
C20 H20 0.9300 . ?
C21 C22 1.387(5) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C28 1.388(4) . ?
C23 C24 1.398(5) . ?
C24 C25 1.382(5) . ?
C24 H24 0.9300 . ?
C25 C26 1.374(6) . ?
C25 H25 0.9300 . ?
C26 C27 1.362(6) . ?
C26 H26 0.9300 . ?
C27 C28 1.406(5) . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?
C29 C30 1.389(4) . ?
C29 C34 1.399(4) . ?
C30 C31 1.394(5) . ?
C30 H30 0.9300 . ?
C31 C32 1.382(6) . ?
C31 H31 0.9300 . ?
C32 C33 1.380(6) . ?
C32 H32 0.9300 . ?
C33 C34 1.395(4) . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 Si1 97.62(3) . . ?
P1 Rh1 S2 170.00(3) . . ?
Si1 Rh1 S2 86.45(3) . . ?
P1 Rh1 S1 94.03(3) . . ?
Si1 Rh1 S1 86.74(3) . . ?
S2 Rh1 S1 95.33(2) . . ?
P1 Rh1 Cl1 93.75(2) . . ?
Si1 Rh1 Cl1 168.47(3) . . ?
S2 Rh1 Cl1 82.63(2) . . ?
S1 Rh1 Cl1 90.58(2) . . ?
P1 Rh1 H01 82.9 . . ?
Si1 Rh1 H01 82.0 . . ?
S2 Rh1 H01 88.7 . . ?
S1 Rh1 H01 167.8 . . ?
Cl1 Rh1 H01 101.3 . . ?
C16 S1 C1 100.33(15) . . ?
C16 S1 Rh1 104.65(10) . . ?
C1 S1 Rh1 111.01(12) . . ?
C5 S2 C2 100.95(14) . . ?
C5 S2 Rh1 108.88(9) . . ?
C2 S2 Rh1 105.85(10) . . ?
C29 P1 C23 104.64(14) . . ?
C29 P1 C17 103.72(13) . . ?
C23 P1 C17 100.28(14) . . ?
C29 P1 Rh1 116.87(10) . . ?
C23 P1 Rh1 116.08(10) . . ?
C17 P1 Rh1 113.24(9) . . ?
C11 Si1 C10 105.38(12) . . ?
C11 Si1 Rh1 106.12(9) . . ?
C10 Si1 Rh1 107.11(9) . . ?
C11 Si1 H1 105.4(13) . . ?
C10 Si1 H1 107.5(13) . . ?
Rh1 Si1 H1 124.0(13) . . ?
S1 C1 H1A 109.5 . . ?
S1 C1 H1B 109.4 . . ?
H1A C1 H1B 109.5 . . ?
S1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
S2 C2 H2A 109.5 . . ?
S2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
S2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C10 C5 C6 122.3(3) . . ?
C10 C5 S2 118.7(2) . . ?
C6 C5 S2 119.0(2) . . ?
C7 C6 C5 119.3(3) . . ?
C7 C6 H6 120.4 . . ?
C5 C6 H6 120.4 . . ?
C8 C7 C6 119.7(3) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 120.5(3) . . ?
C7 C8 H8 119.7 . . ?
C9 C8 H8 119.7 . . ?
C8 C9 C10 120.9(3) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
C5 C10 C9 117.3(3) . . ?
C5 C10 Si1 118.8(2) . . ?
C9 C10 Si1 123.9(2) . . ?
C16 C11 C12 117.3(3) . . ?
C16 C11 Si1 119.5(2) . . ?
C12 C11 Si1 123.2(2) . . ?
C13 C12 C11 121.1(3) . . ?
C13 C12 H12 119.5 . . ?
C11 C12 H12 119.5 . . ?
C12 C13 C14 120.5(3) . . ?
C12 C13 H13 119.7 . . ?
C14 C13 H13 119.7 . . ?
C13 C14 C15 119.8(3) . . ?
C13 C14 H14 120.1 . . ?
C15 C14 H14 120.1 . . ?
C16 C15 C14 119.6(3) . . ?
C16 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
C15 C16 C11 121.7(3) . . ?
C15 C16 S1 118.1(2) . . ?
C11 C16 S1 120.2(2) . . ?
C18 C17 C22 118.4(3) . . ?
C18 C17 P1 122.1(2) . . ?
C22 C17 P1 119.5(3) . . ?
C17 C18 C19 120.3(3) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 H18 119.9 . . ?
C20 C19 C18 120.6(3) . . ?
C20 C19 H19 119.7 . . ?
C18 C19 H19 119.7 . . ?
C21 C20 C19 119.5(3) . . ?
C21 C20 H20 120.3 . . ?
C19 C20 H20 120.3 . . ?
C20 C21 C22 120.9(4) . . ?
C20 C21 H21 119.6 . . ?
C22 C21 H21 119.6 . . ?
C21 C22 C17 120.4(4) . . ?
C21 C22 H22 119.8 . . ?
C17 C22 H22 119.8 . . ?
C28 C23 C24 118.3(3) . . ?
C28 C23 P1 125.6(3) . . ?
C24 C23 P1 115.9(2) . . ?
C25 C24 C23 120.5(4) . . ?
C25 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C26 C25 C24 120.9(4) . . ?
C26 C25 H25 119.5 . . ?
C24 C25 H25 119.5 . . ?
C27 C26 C25 119.5(3) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C26 C27 C28 120.8(3) . . ?
C26 C27 H27 119.6 . . ?
C28 C27 H27 119.6 . . ?
C23 C28 C27 120.0(3) . . ?
C23 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C30 C29 C34 118.6(3) . . ?
C30 C29 P1 121.3(2) . . ?
C34 C29 P1 120.0(2) . . ?
C29 C30 C31 120.8(4) . . ?
C29 C30 H30 119.6 . . ?
C31 C30 H30 119.6 . . ?
C32 C31 C30 119.8(4) . . ?
C32 C31 H31 120.1 . . ?
C30 C31 H31 120.1 . . ?
C33 C32 C31 120.4(3) . . ?
C33 C32 H32 119.8 . . ?
C31 C32 H32 119.8 . . ?
C32 C33 C34 119.8(4) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C33 C34 C29 120.6(3) . . ?
C33 C34 H34 119.7 . . ?
C29 C34 H34 119.7 . . ?

_refine_diff_density_max         2.645
_refine_diff_density_min         -2.168
_refine_diff_density_rms         0.265

_shelxl_version_number           2014-3

