File Name : fig s1-600dpi-__.tif Caption : fig. s1 the enlargement of the 2θ region from 5.5° to 10° in fig. 1 (a) File Name : fig s2 n2 and bjh-600dpi-__.tif Caption : fig. s2 (a) n2 adsorption-desorption isotherms at 77k and (b) mesopore size distribution of ti functionalized h-uio-66(zr/ti) prepared with different ti source File Name : ______-600 __.tif Caption : fig. s3 micropore size distribution of synthesized samples File Name : uio_zr_and h-uio_zr_-600dpi-__.tif Caption : fig. s4 sem images of (a) uio-66(zr), (b) h-uio-66(zr) File Name : fig. s5 7_____ yuantu.tif Caption : fig. s5 tg curve of the synthesized samples File Name : fig. s6 ts-1 and ti-ts-1 xps-yuantu.tif Caption : fig. s6 ti 2p xps spectra of ts-1 and 20%tio(acac)2-ts-1 File Name : fig.s7 ______bet____ __ 8.tif Caption : fig. s7 (a) n2 adsorption-desorption isotherms at 77k; (b) mesopore size distributions and (c) micropore size distribution of conventional uio-66(zr/ti), h-uio-66(zr) precursor and ts-1 File Name : ___xrd__-600.tif Caption : fig s8 the enlargement of the 2θ region from 6° to 10.5° in fig. 7 (a)