# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2020

data_cms31
_audit_creation_date               2019-11-26
_audit_creation_method
;
Olex2 1.3
(compiled 2019.09.11 svn.r3662 for OlexSys, GUI svn.r5938)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          CMS31
_chemical_formula_moiety           'C14 H7 Eu N2 O8'
_chemical_formula_sum              'C14 H7 Eu N2 O8'
_chemical_formula_weight           483.18
_chemical_melting_point            ?
_chemical_oxdiff_formula           'C14 H6 O6 N2 Eu1'
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Eu' 'Eu' -0.1578 3.6682
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/c 1'
_space_group_name_Hall             '-P 2ybc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'

_cell_length_a                     12.2655(3)
_cell_length_b                     8.3615(2)
_cell_length_c                     13.5192(3)
_cell_angle_alpha                  90
_cell_angle_beta                   102.388(3)
_cell_angle_gamma                  90
_cell_volume                       1354.22(6)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      11764
_cell_measurement_temperature      293(2)
_cell_measurement_theta_max        31.8520
_cell_measurement_theta_min        2.8470
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      4.686
_exptl_absorpt_correction_T_max    0.660
_exptl_absorpt_correction_T_min    0.428
_exptl_absorpt_correction_type     analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.61a (Rigaku Oxford Diffraction, 2019)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'clear light colourless'
_exptl_crystal_colour_lustre       clear
_exptl_crystal_colour_modifier     light
_exptl_crystal_colour_primary      colourless
_exptl_crystal_density_diffrn      2.370
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         prism
_exptl_crystal_F_000               928
loop_
  _exptl_crystal_face_index_h
  _exptl_crystal_face_index_k
  _exptl_crystal_face_index_l
  _exptl_crystal_face_perp_dist
 -1 1 0 0.0540
 1 -1 0 0.0540
 2 -8 14 0.1313
 -2 8 -14 0.1313
 -1 0 1 0.1506
 1 0 -1 0.1506
 1 1 0 0.0655
 2 8 13 0.1065
 -1 -1 0 0.0655
 -2 -8 -13 0.1065

_exptl_crystal_preparation         ?
_exptl_crystal_size_max            0.361
_exptl_crystal_size_mid            0.179
_exptl_crystal_size_min            0.108
loop_
  _exptl_oxdiff_crystal_face_indexfrac_h
  _exptl_oxdiff_crystal_face_indexfrac_k
  _exptl_oxdiff_crystal_face_indexfrac_l
  _exptl_oxdiff_crystal_face_x
  _exptl_oxdiff_crystal_face_y
  _exptl_oxdiff_crystal_face_z
 -0.9970 0.9965 -0.0022 0.0727 0.0636 -0.0361
 0.9970 -0.9965 0.0022 -0.0727 -0.0636 0.0361
 2.0046 -7.9853 14.0321 -0.7031 -0.6152 -0.4533
 -2.0046 7.9853 -14.0321 0.7031 0.6152 0.4533
 -0.9979 -0.0012 1.0013 0.0213 -0.0175 -0.0653
 0.9979 0.0012 -1.0013 -0.0213 0.0175 0.0653
 1.0031 0.9975 -0.0032 -0.0322 0.0980 0.0069
 2.0513 7.9670 12.9880 -0.3475 0.6780 -0.6436
 -1.0031 -0.9975 0.0032 0.0322 -0.0980 -0.0069
 -2.0513 -7.9670 -12.9880 0.3475 -0.6780 0.6436

_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0356
_diffrn_reflns_av_unetI/netI       0.0169
_diffrn_reflns_Laue_measured_fraction_full  0.999
_diffrn_reflns_Laue_measured_fraction_max  0.999
_diffrn_reflns_limit_h_max         14
_diffrn_reflns_limit_h_min         -14
_diffrn_reflns_limit_k_max         10
_diffrn_reflns_limit_k_min         -10
_diffrn_reflns_limit_l_max         16
_diffrn_reflns_limit_l_min         -16
_diffrn_reflns_number              24878
_diffrn_reflns_point_group_measured_fraction_full  0.999
_diffrn_reflns_point_group_measured_fraction_max  0.999
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           25.500
_diffrn_reflns_theta_min           2.883
_diffrn_ambient_temperature        293(2)
_diffrn_detector                   'CCD plate'
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.999
_diffrn_measured_fraction_theta_max  0.999
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -69.00 118.00   1.00    1.98    --   27.63  54.00-120.00  187
;
_diffrn_measurement_device         'two-circle diffractometer'
_diffrn_measurement_device_type    'XtaLAB Mini (ROW)'
_diffrn_measurement_method         'ω scans'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        -0.0524568000
_diffrn_orient_matrix_UB_12        0.0204177000
_diffrn_orient_matrix_UB_13        -0.0309970000
_diffrn_orient_matrix_UB_21        0.0171929000
_diffrn_orient_matrix_UB_22        0.0810032000
_diffrn_orient_matrix_UB_23        -0.0002030000
_diffrn_orient_matrix_UB_31        0.0214732000
_diffrn_orient_matrix_UB_32        -0.0148599000
_diffrn_orient_matrix_UB_33        -0.0438259000
_diffrn_radiation_monochromator    graphite
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             'Mo K\a'
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'fine-focus sealed X-ray tube'
_diffrn_source_type                'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  2325
_reflns_number_total               2518
_reflns_odcompleteness_completeness  77.99
_reflns_odcompleteness_iscentric   1
_reflns_odcompleteness_theta       26.32
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_data_collection         'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_data_reduction          'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_molecular_graphics      'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement    'XL n/a (Sheldrick, 2008)'
_computing_structure_solution      'ShelXT n/a (Sheldrick, 2015)'
_refine_diff_density_max           1.974
_refine_diff_density_min           -1.812
_refine_diff_density_rms           0.199
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.227
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       233
_refine_ls_number_reflns           2518
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0346
_refine_ls_R_factor_gt             0.0306
_refine_ls_restrained_S_all        1.227
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0293P)²+8.3459P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0723
_refine_ls_wR_factor_ref           0.0751
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C101(H101), C007(H007), C015(H015), C018(H018), C028(H028)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 C101 C -0.0936(5) 0.2971(7) 0.1079(5) 0.0305(13) Uani 1 1 d . . . . .
 H101 H -0.153827 0.227017 0.096007 0.037 Uiso 1 1 calc R U . . .
 Eu1 Eu 0.30185(2) 0.23362(3) 0.18215(2) 0.01148(10) Uani 1 1 d . . . . .
 O2 O 0.2687(4) 0.2747(4) 0.0029(3) 0.0234(8) Uani 1 1 d . . . . .
 O1 O 0.3885(3) 0.0036(4) 0.2768(3) 0.0192(7) Uani 1 1 d . . . . .
 O2W O 0.2803(3) 0.2900(5) 0.3461(3) 0.0216(8) Uani 1 1 d . . . . .
 O3 O 0.2833(3) 0.5137(4) 0.1725(3) 0.0208(8) Uani 1 1 d . . . . .
 O1W O 0.4863(3) 0.3092(4) 0.2135(2) 0.0181(7) Uani 1 1 d . . . . .
 C007 C 0.4339(4) -0.2493(6) 0.0733(4) 0.0159(10) Uani 1 1 d . . . . .
 H007 H 0.466461 -0.339889 0.107204 0.019 Uiso 1 1 calc R U . . .
 N2 N 0.1037(3) 0.3338(5) 0.1441(3) 0.0167(9) Uani 1 1 d . . . . .
 C009 C 0.4114(4) -0.1148(6) 0.1258(4) 0.0148(9) Uani 1 1 d . . . . .
 C010 C 0.4396(4) -0.1003(6) 0.2389(3) 0.0140(9) Uani 1 1 d . . . . .
 C011 C 0.3411(4) 0.0233(6) -0.0218(4) 0.0145(9) Uani 1 1 d . . . . .
 N1 N 0.3637(3) 0.0151(5) 0.0794(3) 0.0132(8) Uani 1 1 d . . . . .
 O4 O 0.1439(3) 0.0298(5) 0.1525(3) 0.0239(8) Uani 1 1 d . . . . .
 C014 C 0.2930(4) 0.1813(6) -0.0615(4) 0.0166(10) Uani 1 1 d . . . . .
 C015 C 0.3627(4) -0.1039(6) -0.0800(4) 0.0204(11) Uani 1 1 d . . . . .
 H015 H 0.348410 -0.096301 -0.150269 0.024 Uiso 1 1 calc R U . . .
 O5 O -0.0370(3) -0.0342(5) 0.1102(4) 0.0392(11) Uani 1 1 d . . . . .
 C017 C 0.0143(4) 0.2404(6) 0.1266(4) 0.0182(11) Uani 1 1 d . . . . .
 C018 C 0.4061(5) -0.2434(6) -0.0313(4) 0.0194(11) Uani 1 1 d . . . . .
 H018 H 0.416441 -0.332964 -0.068997 0.023 Uiso 1 1 calc R U . . .
 C019 C 0.0347(5) 0.0643(6) 0.1277(4) 0.0239(11) Uani 1 1 d . . . . .
 C020 C 0.0869(5) 0.4927(6) 0.1427(4) 0.0208(11) Uani 1 1 d . . . . .
 C022 C 0.1936(5) 0.5900(6) 0.1623(4) 0.0222(11) Uani 1 1 d . . . . .
 O6 O 0.1868(4) 0.7366(5) 0.1680(5) 0.0467(14) Uani 1 1 d . . . . .
 C027 C -0.0189(5) 0.5590(7) 0.1246(5) 0.0277(12) Uani 1 1 d . . . . .
 H027 H -0.025(6) 0.662(9) 0.129(5) 0.033 Uiso 1 1 d . U . . .
 C028 C -0.1102(5) 0.4605(7) 0.1072(5) 0.0321(14) Uani 1 1 d . . . . .
 H028 H -0.181968 0.502827 0.095224 0.039 Uiso 1 1 calc R U . . .
 H4 H 0.160(7) -0.060(11) 0.153(6) 0.06(3) Uiso 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 C101 H101 0.9300 . ?
 C101 C017 1.376(8) . ?
 C101 C028 1.381(8) . ?
 Eu1 O2 2.395(4) . ?
 Eu1 O1 2.426(3) . ?
 Eu1 O2W 2.336(3) . ?
 Eu1 O3 2.354(4) . ?
 Eu1 O1W 2.299(3) . ?
 Eu1 N2 2.517(4) . ?
 Eu1 C010 3.269(5) . ?
 Eu1 N1 2.509(4) . ?
 Eu1 O4 2.547(4) . ?
 Eu1 C022 3.250(5) . ?
 O2 C014 1.251(6) . ?
 O1 C010 1.245(6) . ?
 O2W C014 1.248(6) 4_566 ?
 O3 C022 1.253(6) . ?
 O1W C010 1.249(6) 2_655 ?
 C007 H007 0.9300 . ?
 C007 C009 1.388(7) . ?
 C007 C018 1.382(8) . ?
 N2 C017 1.326(7) . ?
 N2 C020 1.345(7) . ?
 C009 C010 1.500(7) . ?
 C009 N1 1.327(6) . ?
 C011 N1 1.338(6) . ?
 C011 C014 1.498(7) . ?
 C011 C015 1.382(7) . ?
 O4 C019 1.340(7) . ?
 O4 H4 0.78(9) . ?
 C015 H015 0.9300 . ?
 C015 C018 1.388(7) . ?
 O5 C019 1.192(7) . ?
 C017 C019 1.493(7) . ?
 C018 H018 0.9300 . ?
 C020 C022 1.515(8) . ?
 C020 C027 1.384(8) . ?
 C022 O6 1.232(7) . ?
 C027 H027 0.86(7) . ?
 C027 C028 1.369(9) . ?
 C028 H028 0.9300 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C017 C101 H101 120.8 . . ?
 C017 C101 C028 118.5(6) . . ?
 C028 C101 H101 120.8 . . ?
 O2 Eu1 O1 127.43(12) . . ?
 O2 Eu1 N2 78.38(13) . . ?
 O2 Eu1 C010 109.09(12) . . ?
 O2 Eu1 N1 63.23(12) . . ?
 O2 Eu1 O4 88.77(14) . . ?
 O2 Eu1 C022 78.89(13) . . ?
 O1 Eu1 N2 131.78(13) . . ?
 O1 Eu1 C010 18.70(11) . . ?
 O1 Eu1 N1 64.19(12) . . ?
 O1 Eu1 O4 77.57(12) . . ?
 O1 Eu1 C022 153.59(12) . . ?
 O2W Eu1 O2 154.45(13) . . ?
 O2W Eu1 O1 77.60(12) . . ?
 O2W Eu1 O3 79.75(13) . . ?
 O2W Eu1 N2 79.98(13) . . ?
 O2W Eu1 C010 96.18(12) . . ?
 O2W Eu1 N1 141.42(13) . . ?
 O2W Eu1 O4 92.71(13) . . ?
 O2W Eu1 C022 76.46(13) . . ?
 O3 Eu1 O2 78.94(12) . . ?
 O3 Eu1 O1 147.60(12) . . ?
 O3 Eu1 N2 65.15(13) . . ?
 O3 Eu1 C010 154.41(12) . . ?
 O3 Eu1 N1 136.98(12) . . ?
 O3 Eu1 O4 126.56(12) . . ?
 O3 Eu1 C022 18.22(13) . . ?
 O1W Eu1 O2 95.37(13) . . ?
 O1W Eu1 O1 79.55(13) . . ?
 O1W Eu1 O2W 94.41(13) . . ?
 O1W Eu1 O3 79.42(13) . . ?
 O1W Eu1 N2 144.57(14) . . ?
 O1W Eu1 C010 75.70(12) . . ?
 O1W Eu1 N1 84.26(13) . . ?
 O1W Eu1 O4 153.94(13) . . ?
 O1W Eu1 C022 97.55(14) . . ?
 N2 Eu1 C010 139.47(13) . . ?
 N2 Eu1 O4 61.44(13) . . ?
 N2 Eu1 C022 47.05(14) . . ?
 N1 Eu1 N2 121.48(13) . . ?
 N1 Eu1 C010 46.03(12) . . ?
 N1 Eu1 O4 74.67(13) . . ?
 N1 Eu1 C022 142.04(13) . . ?
 O4 Eu1 C010 78.63(12) . . ?
 O4 Eu1 C022 108.49(13) . . ?
 C022 Eu1 C010 169.77(13) . . ?
 C014 O2 Eu1 126.9(3) . . ?
 C010 O1 Eu1 122.6(3) . . ?
 C014 O2W Eu1 166.6(4) 4_566 . ?
 C022 O3 Eu1 125.8(3) . . ?
 C010 O1W Eu1 147.1(3) 2_655 . ?
 C009 C007 H007 121.3 . . ?
 C018 C007 H007 121.3 . . ?
 C018 C007 C009 117.5(5) . . ?
 C017 N2 Eu1 124.5(3) . . ?
 C017 N2 C020 117.4(5) . . ?
 C020 N2 Eu1 118.0(3) . . ?
 C007 C009 C010 124.0(4) . . ?
 N1 C009 C007 122.5(5) . . ?
 N1 C009 C010 113.4(4) . . ?
 O1 C010 Eu1 38.7(2) . . ?
 O1 C010 O1W 125.9(4) . 2_645 ?
 O1 C010 C009 116.8(4) . . ?
 O1W C010 Eu1 157.0(3) 2_645 . ?
 O1W C010 C009 117.4(4) 2_645 . ?
 C009 C010 Eu1 80.5(3) . . ?
 N1 C011 C014 112.9(4) . . ?
 N1 C011 C015 121.3(4) . . ?
 C015 C011 C014 125.7(4) . . ?
 C009 N1 Eu1 119.3(3) . . ?
 C009 N1 C011 119.9(4) . . ?
 C011 N1 Eu1 120.6(3) . . ?
 Eu1 O4 H4 117(6) . . ?
 C019 O4 Eu1 125.5(3) . . ?
 C019 O4 H4 117(6) . . ?
 O2 C014 C011 115.8(4) . . ?
 O2W C014 O2 125.4(5) 4_565 . ?
 O2W C014 C011 118.8(4) 4_565 . ?
 C011 C015 H015 120.8 . . ?
 C011 C015 C018 118.5(5) . . ?
 C018 C015 H015 120.8 . . ?
 C101 C017 C019 119.6(5) . . ?
 N2 C017 C101 123.8(5) . . ?
 N2 C017 C019 116.6(5) . . ?
 C007 C018 C015 120.1(5) . . ?
 C007 C018 H018 120.0 . . ?
 C015 C018 H018 120.0 . . ?
 O4 C019 C017 111.8(5) . . ?
 O5 C019 O4 123.8(5) . . ?
 O5 C019 C017 124.4(5) . . ?
 N2 C020 C022 113.9(5) . . ?
 N2 C020 C027 122.2(5) . . ?
 C027 C020 C022 123.9(5) . . ?
 O3 C022 Eu1 36.0(2) . . ?
 O3 C022 C020 116.8(4) . . ?
 C020 C022 Eu1 81.0(3) . . ?
 O6 C022 Eu1 159.9(5) . . ?
 O6 C022 O3 124.7(6) . . ?
 O6 C022 C020 118.5(5) . . ?
 C020 C027 H027 119(5) . . ?
 C028 C027 C020 119.4(5) . . ?
 C028 C027 H027 122(5) . . ?
 C101 C028 H028 120.7 . . ?
 C027 C028 C101 118.7(5) . . ?
 C027 C028 H028 120.7 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 C101 C017 C019 O4 -176.6(5) . . . . ?
 C101 C017 C019 O5 2.5(9) . . . . ?
 Eu1 O2 C014 O2W -175.8(4) . . . 4_565 ?
 Eu1 O2 C014 C011 4.3(6) . . . . ?
 Eu1 O1 C010 O1W 156.1(4) . . . 2_645 ?
 Eu1 O1 C010 C009 -22.3(6) . . . . ?
 Eu1 O3 C022 C020 -7.2(7) . . . . ?
 Eu1 O3 C022 O6 172.0(5) . . . . ?
 Eu1 N2 C017 C101 178.6(4) . . . . ?
 Eu1 N2 C017 C019 -1.4(7) . . . . ?
 Eu1 N2 C020 C022 1.6(6) . . . . ?
 Eu1 N2 C020 C027 -178.6(4) . . . . ?
 Eu1 O4 C019 O5 176.7(5) . . . . ?
 Eu1 O4 C019 C017 -4.3(7) . . . . ?
 C007 C009 C010 Eu1 -174.2(5) . . . . ?
 C007 C009 C010 O1 -160.3(5) . . . . ?
 C007 C009 C010 O1W 21.2(7) . . . 2_645 ?
 C007 C009 N1 Eu1 171.0(4) . . . . ?
 C007 C009 N1 C011 -3.8(7) . . . . ?
 N2 C017 C019 O4 3.5(7) . . . . ?
 N2 C017 C019 O5 -177.5(6) . . . . ?
 N2 C020 C022 Eu1 -1.1(4) . . . . ?
 N2 C020 C022 O3 3.2(7) . . . . ?
 N2 C020 C022 O6 -176.1(6) . . . . ?
 N2 C020 C027 C028 -0.1(9) . . . . ?
 C009 C007 C018 C015 3.2(8) . . . . ?
 C010 C009 N1 Eu1 -9.8(5) . . . . ?
 C010 C009 N1 C011 175.3(4) . . . . ?
 C011 C015 C018 C007 -4.4(8) . . . . ?
 N1 C009 C010 Eu1 6.6(4) . . . . ?
 N1 C009 C010 O1 20.5(6) . . . . ?
 N1 C009 C010 O1W -157.9(4) . . . 2_645 ?
 N1 C011 C014 O2 -8.0(6) . . . . ?
 N1 C011 C014 O2W 172.0(4) . . . 4_565 ?
 N1 C011 C015 C018 1.6(8) . . . . ?
 C014 C011 N1 Eu1 8.3(5) . . . . ?
 C014 C011 N1 C009 -176.9(4) . . . . ?
 C014 C011 C015 C018 -179.1(5) . . . . ?
 C015 C011 N1 Eu1 -172.3(4) . . . . ?
 C015 C011 N1 C009 2.5(7) . . . . ?
 C015 C011 C014 O2 172.6(5) . . . . ?
 C015 C011 C014 O2W -7.3(8) . . . 4_565 ?
 C017 C101 C028 C027 0.3(10) . . . . ?
 C017 N2 C020 C022 -179.4(5) . . . . ?
 C017 N2 C020 C027 0.4(8) . . . . ?
 C018 C007 C009 C010 -178.1(5) . . . . ?
 C018 C007 C009 N1 1.0(7) . . . . ?
 C020 N2 C017 C101 -0.3(8) . . . . ?
 C020 N2 C017 C019 179.6(5) . . . . ?
 C020 C027 C028 C101 -0.3(10) . . . . ?
 C022 C020 C027 C028 179.6(6) . . . . ?
 C027 C020 C022 Eu1 179.1(5) . . . . ?
 C027 C020 C022 O3 -176.6(5) . . . . ?
 C027 C020 C022 O6 4.2(9) . . . . ?
 C028 C101 C017 N2 0.0(10) . . . . ?
 C028 C101 C017 C019 -180.0(6) . . . . ?

_smtbx_masks_void_probe_radius     1.2
_smtbx_masks_void_truncation_radius  1.2
_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  1.099
_oxdiff_exptl_absorpt_empirical_full_min  0.929
