# Electronic Supplementary Material (ESI) for Polymer Chemistry.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_zz
_database_code_depnum_ccdc_archive 'CCDC 1859816'
_audit_update_record             
;
2018-08-02 deposited with the CCDC.	2019-04-22 downloaded from the CCDC.
;
_audit_creation_date             2018-04-22
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.04.18 svn.r3501 for OlexSys, GUI svn.r5488)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H42 Ag5 F3 N2 O2 S4'
_chemical_formula_sum            'C25 H42 Ag5 F3 N2 O2 S4'
_chemical_formula_weight         1127.19
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.2226(4)
_cell_length_b                   24.7501(8)
_cell_length_c                   12.0798(4)
_cell_angle_alpha                90
_cell_angle_beta                 102.123(2)
_cell_angle_gamma                90
_cell_volume                     3572.8(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    6660
_cell_measurement_temperature    235
_cell_measurement_theta_max      62.364
_cell_measurement_theta_min      4.147
_shelx_estimated_absorpt_T_max   0.378
_shelx_estimated_absorpt_T_min   0.098
_exptl_absorpt_coefficient_mu    24.138
_exptl_absorpt_correction_T_max  0.7522
_exptl_absorpt_correction_T_min  0.4125
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1321 before and 0.0660 after correction. The Ratio of minimum to maximum transmission is 0.5484. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.096
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             2192
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0762
_diffrn_reflns_av_unetI/netI     0.0674
_diffrn_reflns_Laue_measured_fraction_full 0.980
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            20781
_diffrn_reflns_point_group_measured_fraction_full 0.980
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        62.427
_diffrn_reflns_theta_max         62.427
_diffrn_reflns_theta_min         4.147
_diffrn_ambient_temperature      235.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4037
_reflns_number_total             5569
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.584
_refine_diff_density_min         -2.302
_refine_diff_density_rms         0.181
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     382
_refine_ls_number_reflns         5569
_refine_ls_number_restraints     342
_refine_ls_R_factor_all          0.0893
_refine_ls_R_factor_gt           0.0582
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0402P)²+39.4972P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1224
_refine_ls_wR_factor_ref         0.1364
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
3.a Aromatic/amide H refined with riding coordinates:
 C1(H1), N2(H2), C6(H6), C3(H3), C5(H5), C4(H4)
3.b Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C11(H11A,H11B,H11C), C15(H15A,H15B,H15C), C12(H12A,H12B,
 H12C), C10(H10A,H10B,H10C), C24(H24A,H24B,H24C), C21(H21A,H21B,H21C), C20(H20A,
 H20B,H20C), C13(H13A,H13B,H13C), C23(H23A,H23B,H23C), C25(H25A,H25B,H25C),
 C19(H19A,H19B,H19C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.56664(6) 0.69739(3) 0.45740(7) 0.0360(2) Uani 1 1 d . U . . .
Ag4 Ag 0.72438(7) 0.70469(3) 0.04771(8) 0.0410(2) Uani 1 1 d . U . . .
Ag1 Ag 0.50269(7) 0.84209(3) 0.60051(9) 0.0470(3) Uani 1 1 d . U . . .
Ag5 Ag 0.65739(7) 0.70632(3) -0.21174(8) 0.0433(2) Uani 1 1 d . U . . .
Ag3 Ag 0.79127(11) 0.67267(5) 0.30580(11) 0.0841(4) Uani 1 1 d . U . . .
S4 S 0.6022(2) 0.64472(10) -0.0742(2) 0.0299(6) Uani 1 1 d . U . . .
S1 S 0.5102(2) 0.73767(10) 0.6156(2) 0.0295(6) Uani 1 1 d . U . . .
S2 S 0.6049(2) 0.63970(10) 0.3138(2) 0.0357(6) Uani 1 1 d . U . . .
S3 S 0.8121(2) 0.75633(14) 0.2062(3) 0.0595(10) Uani 1 1 d . U . . .
N1 N 0.3308(8) 0.8793(4) 0.5860(9) 0.042(2) Uani 1 1 d . U . . .
O00B O 0.9960(7) 0.5958(4) 0.2454(8) 0.062(2) Uani 1 1 d . U . . .
C9 C 0.3735(8) 0.7072(4) 0.6232(9) 0.034(2) Uani 1 1 d . U . . .
C7 C 0.2577(9) 0.8999(4) 0.4925(10) 0.035(2) Uani 1 1 d . U . . .
C8 C 0.3431(9) 0.7257(5) 0.7326(10) 0.041(3) Uani 1 1 d . U . . .
H8A H 0.3996 0.7134 0.7964 0.062 Uiso 1 1 calc GR . . . .
H8B H 0.2710 0.7108 0.7378 0.062 Uiso 1 1 calc GR . . . .
H8C H 0.3393 0.7649 0.7335 0.062 Uiso 1 1 calc GR . . . .
O00F O 0.9327(10) 0.6173(6) 0.3964(10) 0.096(3) Uani 1 1 d . U . . .
C1 C 0.2740(10) 0.8816(5) 0.6679(12) 0.048(3) Uani 1 1 d . U . . .
H1 H 0.3036 0.8704 0.7425 0.057 Uiso 1 1 calc R . . . .
N2 N 0.1709(8) 0.9013(4) 0.6342(9) 0.046(2) Uani 1 1 d . U . . .
H2 H 0.1217 0.9057 0.6761 0.055 Uiso 1 1 calc R . . . .
C18 C 0.9587(9) 0.7756(5) 0.2145(11) 0.044(3) Uani 1 1 d . U . . .
C6 C 0.2703(10) 0.9070(5) 0.3811(11) 0.043(3) Uani 1 1 d . U . . .
H6 H 0.3369 0.8973 0.3589 0.052 Uiso 1 1 calc R . . . .
C11 C 0.2863(9) 0.7258(5) 0.5203(11) 0.049(3) Uani 1 1 d . U . . .
H11A H 0.2875 0.7649 0.5154 0.073 Uiso 1 1 calc GR . . . .
H11B H 0.2126 0.7140 0.5281 0.073 Uiso 1 1 calc GR . . . .
H11C H 0.3034 0.7103 0.4521 0.073 Uiso 1 1 calc GR . . . .
C2 C 0.1566(9) 0.9134(4) 0.5208(11) 0.037(2) Uani 1 1 d . U . . .
C15 C 0.6750(12) 0.5344(5) 0.3053(12) 0.056(3) Uani 1 1 d . U . . .
H15A H 0.6334 0.5342 0.2276 0.084 Uiso 1 1 calc GR . . . .
H15B H 0.6800 0.4978 0.3349 0.084 Uiso 1 1 calc GR . . . .
H15C H 0.7497 0.5483 0.3081 0.084 Uiso 1 1 calc GR . . . .
C22 C 0.6783(9) 0.5796(4) -0.0727(11) 0.040(2) Uani 1 1 d . U . . .
C12 C 0.4955(11) 0.5506(5) 0.3693(13) 0.058(3) Uani 1 1 d . U . . .
H12A H 0.4613 0.5706 0.4223 0.087 Uiso 1 1 calc GR . . . .
H12B H 0.4964 0.5124 0.3875 0.087 Uiso 1 1 calc GR . . . .
H12C H 0.4526 0.5562 0.2929 0.087 Uiso 1 1 calc GR . . . .
C10 C 0.3826(10) 0.6461(5) 0.6242(12) 0.050(3) Uani 1 1 d . U . . .
H10A H 0.3904 0.6336 0.5502 0.075 Uiso 1 1 calc GR . . . .
H10B H 0.3157 0.6306 0.6425 0.075 Uiso 1 1 calc GR . . . .
H10C H 0.4475 0.6351 0.6806 0.075 Uiso 1 1 calc GR . . . .
C24 C 0.7741(11) 0.5770(5) 0.0312(13) 0.061(3) Uani 1 1 d . U . . .
H24A H 0.8291 0.6045 0.0252 0.091 Uiso 1 1 calc GR . . . .
H24B H 0.8089 0.5416 0.0354 0.091 Uiso 1 1 calc GR . . . .
H24C H 0.7450 0.5832 0.0989 0.091 Uiso 1 1 calc GR . . . .
C3 C 0.0678(10) 0.9367(5) 0.4453(12) 0.050(3) Uani 1 1 d . U . . .
H3 H 0.0014 0.9472 0.4670 0.060 Uiso 1 1 calc R . . . .
C14 C 0.6147(10) 0.5703(4) 0.3773(11) 0.043(2) Uani 1 1 d . U . . .
C16 C 0.9983(12) 0.5965(6) 0.3457(13) 0.063(3) Uani 1 1 d . U . . .
C21 C 1.0094(12) 0.7862(6) 0.3405(13) 0.070(4) Uani 1 1 d . U . . .
H21A H 0.9637 0.8122 0.3701 0.105 Uiso 1 1 calc GR . . . .
H21B H 1.0847 0.8003 0.3483 0.105 Uiso 1 1 calc GR . . . .
H21C H 1.0118 0.7526 0.3825 0.105 Uiso 1 1 calc GR . . . .
C20 C 1.0179(11) 0.7312(6) 0.1657(15) 0.070(4) Uani 1 1 d . U . . .
H20A H 1.0289 0.7006 0.2170 0.105 Uiso 1 1 calc GR . . . .
H20B H 1.0899 0.7442 0.1553 0.105 Uiso 1 1 calc GR . . . .
H20C H 0.9730 0.7201 0.0932 0.105 Uiso 1 1 calc GR . . . .
C13 C 0.6776(13) 0.5728(5) 0.4984(12) 0.061(3) Uani 1 1 d . U . . .
H13A H 0.7520 0.5872 0.5012 0.091 Uiso 1 1 calc GR . . . .
H13B H 0.6835 0.5368 0.5307 0.091 Uiso 1 1 calc GR . . . .
H13C H 0.6379 0.5961 0.5413 0.091 Uiso 1 1 calc GR . . . .
C5 C 0.1831(11) 0.9283(5) 0.3065(12) 0.054(3) Uani 1 1 d . U . . .
H5 H 0.1899 0.9332 0.2311 0.064 Uiso 1 1 calc R . . . .
C23 C 0.7225(14) 0.5737(6) -0.1776(14) 0.076(4) Uani 1 1 d . U . . .
H23A H 0.6610 0.5752 -0.2430 0.114 Uiso 1 1 calc GR . . . .
H23B H 0.7608 0.5393 -0.1765 0.114 Uiso 1 1 calc GR . . . .
H23C H 0.7746 0.6029 -0.1819 0.114 Uiso 1 1 calc GR . . . .
F2 F 1.1914(11) 0.5819(7) 0.4072(13) 0.160(5) Uani 1 1 d . U . . .
C4 C 0.0834(11) 0.9433(5) 0.3370(13) 0.057(3) Uani 1 1 d . U . . .
H4 H 0.0255 0.9584 0.2819 0.068 Uiso 1 1 calc R . . . .
F3 F 1.1008(12) 0.5164(6) 0.3849(14) 0.167(5) Uani 1 1 d . U . . .
F1 F 1.1020(13) 0.5662(7) 0.5230(13) 0.173(5) Uani 1 1 d . U . . .
C25 C 0.5940(13) 0.5359(5) -0.0650(16) 0.076(4) Uani 1 1 d . U . . .
H25A H 0.5688 0.5395 0.0056 0.114 Uiso 1 1 calc GR . . . .
H25B H 0.6285 0.5007 -0.0676 0.114 Uiso 1 1 calc GR . . . .
H25C H 0.5305 0.5392 -0.1281 0.114 Uiso 1 1 calc GR . . . .
C17 C 1.0907(18) 0.5656(11) 0.417(2) 0.108(4) Uani 1 1 d . U . . .
C19 C 0.9586(16) 0.8273(6) 0.1466(16) 0.090(5) Uani 1 1 d . U . . .
H19A H 0.9325 0.8195 0.0667 0.134 Uiso 1 1 calc GR . . . .
H19B H 1.0339 0.8418 0.1593 0.134 Uiso 1 1 calc GR . . . .
H19C H 0.9093 0.8535 0.1704 0.134 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 Ag4 3.1459(11) 4_576 ?
Ag2 S1 2.383(3) . ?
Ag2 S2 2.368(3) . ?
Ag4 Ag2 3.1460(11) 4_575 ?
Ag4 Ag1 3.1329(12) 4_575 ?
Ag4 Ag5 3.0686(13) . ?
Ag4 Ag3 3.1538(17) . ?
Ag4 S4 2.382(3) . ?
Ag4 S3 2.364(3) . ?
Ag1 Ag4 3.1330(12) 4_576 ?
Ag1 S4 2.668(3) 4_576 ?
Ag1 S1 2.591(3) . ?
Ag1 S2 2.655(3) 4_576 ?
Ag1 N1 2.266(9) . ?
Ag5 S4 2.452(3) . ?
Ag5 S1 2.571(3) 1_554 ?
Ag5 S3 2.490(3) 4_575 ?
Ag3 S2 2.441(3) . ?
Ag3 S3 2.435(4) . ?
Ag3 O00F 2.296(14) . ?
S4 Ag1 2.668(3) 4_575 ?
S4 C22 1.860(10) . ?
S1 Ag5 2.571(3) 1_556 ?
S1 C9 1.853(10) . ?
S2 Ag1 2.655(3) 4_575 ?
S2 C14 1.874(11) . ?
S3 Ag5 2.490(3) 4_576 ?
S3 C18 1.836(11) . ?
N1 C7 1.382(15) . ?
N1 C1 1.324(15) . ?
O00B C16 1.206(16) . ?
C9 C8 1.517(15) . ?
C9 C11 1.529(16) . ?
C9 C10 1.515(16) . ?
C7 C6 1.397(17) . ?
C7 C2 1.390(15) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 H8C 0.9700 . ?
O00F C16 1.220(17) . ?
C1 H1 0.9400 . ?
C1 N2 1.333(15) . ?
N2 H2 0.8700 . ?
N2 C2 1.378(15) . ?
C18 C21 1.54(2) . ?
C18 C20 1.503(18) . ?
C18 C19 1.520(19) . ?
C6 H6 0.9400 . ?
C6 C5 1.349(17) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 H11C 0.9700 . ?
C2 C3 1.388(16) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C15 C14 1.537(16) . ?
C22 C24 1.527(18) . ?
C22 C23 1.486(18) . ?
C22 C25 1.510(17) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
C12 C14 1.520(17) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 H10C 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C24 H24C 0.9700 . ?
C3 H3 0.9400 . ?
C3 C4 1.37(2) . ?
C14 C13 1.504(19) . ?
C16 C17 1.48(3) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C21 H21C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 H13C 0.9700 . ?
C5 H5 0.9400 . ?
C5 C4 1.396(19) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
F2 C17 1.33(2) . ?
C4 H4 0.9400 . ?
F3 C17 1.29(3) . ?
F1 C17 1.25(2) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C25 H25C 0.9700 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 Ag2 Ag4 70.07(6) . 4_576 ?
S2 Ag2 Ag4 121.18(7) . 4_576 ?
S2 Ag2 S1 167.15(9) . . ?
Ag2 Ag4 Ag3 123.31(4) 4_575 . ?
Ag1 Ag4 Ag2 82.07(3) 4_575 4_575 ?
Ag1 Ag4 Ag3 76.21(3) 4_575 . ?
Ag5 Ag4 Ag2 67.86(3) . 4_575 ?
Ag5 Ag4 Ag1 98.98(3) . 4_575 ?
Ag5 Ag4 Ag3 166.20(4) . . ?
S4 Ag4 Ag2 90.39(7) . 4_575 ?
S4 Ag4 Ag1 55.88(6) . 4_575 ?
S4 Ag4 Ag5 51.60(7) . . ?
S4 Ag4 Ag3 116.94(7) . . ?
S3 Ag4 Ag2 90.29(10) . 4_575 ?
S3 Ag4 Ag1 107.43(8) . 4_575 ?
S3 Ag4 Ag5 142.99(11) . . ?
S3 Ag4 Ag3 49.89(11) . . ?
S3 Ag4 S4 162.99(11) . . ?
S4 Ag1 Ag4 47.67(6) 4_576 4_576 ?
S1 Ag1 Ag4 68.06(6) . 4_576 ?
S1 Ag1 S4 99.35(8) . 4_576 ?
S1 Ag1 S2 95.64(9) . 4_576 ?
S2 Ag1 Ag4 90.55(6) 4_576 4_576 ?
S2 Ag1 S4 123.16(9) 4_576 4_576 ?
N1 Ag1 Ag4 164.1(3) . 4_576 ?
N1 Ag1 S4 117.3(3) . 4_576 ?
N1 Ag1 S1 115.4(2) . . ?
N1 Ag1 S2 104.2(3) . 4_576 ?
S4 Ag5 Ag4 49.60(7) . . ?
S4 Ag5 S1 119.49(9) . 1_554 ?
S4 Ag5 S3 147.19(10) . 4_575 ?
S1 Ag5 Ag4 145.43(7) 1_554 . ?
S3 Ag5 Ag4 110.44(10) 4_575 . ?
S3 Ag5 S1 91.47(10) 4_575 1_554 ?
S2 Ag3 Ag4 94.17(8) . . ?
S3 Ag3 Ag4 47.95(8) . . ?
S3 Ag3 S2 119.95(12) . . ?
O00F Ag3 Ag4 129.4(3) . . ?
O00F Ag3 S2 113.4(3) . . ?
O00F Ag3 S3 126.6(3) . . ?
Ag4 S4 Ag1 76.45(8) . 4_575 ?
Ag4 S4 Ag5 78.80(8) . . ?
Ag5 S4 Ag1 134.11(10) . 4_575 ?
C22 S4 Ag4 106.7(4) . . ?
C22 S4 Ag1 114.1(4) . 4_575 ?
C22 S4 Ag5 109.7(4) . . ?
Ag2 S1 Ag1 111.88(10) . . ?
Ag2 S1 Ag5 104.68(9) . 1_556 ?
Ag5 S1 Ag1 111.51(10) 1_556 . ?
C9 S1 Ag2 106.6(4) . . ?
C9 S1 Ag1 113.0(4) . . ?
C9 S1 Ag5 108.8(4) . 1_556 ?
Ag2 S2 Ag1 118.92(11) . 4_575 ?
Ag2 S2 Ag3 99.02(10) . . ?
Ag3 S2 Ag1 99.07(10) . 4_575 ?
C14 S2 Ag2 104.9(4) . . ?
C14 S2 Ag1 122.0(4) . 4_575 ?
C14 S2 Ag3 110.0(4) . . ?
Ag4 S3 Ag5 105.65(11) . 4_576 ?
Ag4 S3 Ag3 82.16(11) . . ?
Ag3 S3 Ag5 87.24(12) . 4_576 ?
C18 S3 Ag4 117.2(4) . . ?
C18 S3 Ag5 134.1(4) . 4_576 ?
C18 S3 Ag3 113.3(4) . . ?
C7 N1 Ag1 130.0(8) . . ?
C1 N1 Ag1 125.6(9) . . ?
C1 N1 C7 104.1(10) . . ?
C8 C9 S1 107.9(7) . . ?
C8 C9 C11 111.1(9) . . ?
C11 C9 S1 108.6(7) . . ?
C10 C9 S1 110.0(7) . . ?
C10 C9 C8 109.0(10) . . ?
C10 C9 C11 110.1(10) . . ?
N1 C7 C6 130.6(10) . . ?
N1 C7 C2 110.1(10) . . ?
C2 C7 C6 119.3(11) . . ?
C9 C8 H8A 109.5 . . ?
C9 C8 H8B 109.5 . . ?
C9 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C16 O00F Ag3 121.4(12) . . ?
N1 C1 H1 123.3 . . ?
N1 C1 N2 113.5(12) . . ?
N2 C1 H1 123.3 . . ?
C1 N2 H2 126.4 . . ?
C1 N2 C2 107.3(10) . . ?
C2 N2 H2 126.4 . . ?
C21 C18 S3 106.5(9) . . ?
C20 C18 S3 109.4(8) . . ?
C20 C18 C21 112.6(12) . . ?
C20 C18 C19 110.5(13) . . ?
C19 C18 S3 107.4(10) . . ?
C19 C18 C21 110.2(12) . . ?
C7 C6 H6 121.3 . . ?
C5 C6 C7 117.5(12) . . ?
C5 C6 H6 121.3 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C2 C7 105.0(10) . . ?
N2 C2 C3 131.5(11) . . ?
C3 C2 C7 123.5(12) . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
C24 C22 S4 109.8(8) . . ?
C23 C22 S4 110.3(9) . . ?
C23 C22 C24 110.1(12) . . ?
C23 C22 C25 111.0(12) . . ?
C25 C22 S4 106.0(8) . . ?
C25 C22 C24 109.6(11) . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C12 H12A 109.5 . . ?
C14 C12 H12B 109.5 . . ?
C14 C12 H12C 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C2 C3 H3 122.2 . . ?
C4 C3 C2 115.5(12) . . ?
C4 C3 H3 122.2 . . ?
C15 C14 S2 107.2(8) . . ?
C12 C14 S2 106.9(8) . . ?
C12 C14 C15 110.2(11) . . ?
C13 C14 S2 109.6(8) . . ?
C13 C14 C15 111.5(11) . . ?
C13 C14 C12 111.3(11) . . ?
O00B C16 O00F 129.1(16) . . ?
O00B C16 C17 115.8(16) . . ?
O00F C16 C17 115.1(17) . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C14 C13 H13A 109.5 . . ?
C14 C13 H13B 109.5 . . ?
C14 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C6 C5 H5 118.7 . . ?
C6 C5 C4 122.6(14) . . ?
C4 C5 H5 118.7 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C3 C4 C5 121.6(13) . . ?
C3 C4 H4 119.2 . . ?
C5 C4 H4 119.2 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
F2 C17 C16 113(2) . . ?
F3 C17 C16 114.6(19) . . ?
F3 C17 F2 96.2(19) . . ?
F1 C17 C16 120(2) . . ?
F1 C17 F2 100.7(19) . . ?
F1 C17 F3 109(2) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
