# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_tcd459
_database_code_depnum_ccdc_archive 'CCDC 1912783'
loop_
_audit_author_name
_audit_author_address
'Brendan Twamley'
;TCD
Republic of Ireland
;
_audit_update_record             
;
2019-04-29 deposited with the CCDC.	2019-09-09 downloaded from the CCDC.
;
_audit_creation_date             2016-03-23
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C23 H16 F17 O2 P'
_chemical_formula_sum            'C23 H16 F17 O2 P'
_chemical_formula_weight         678.33
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.853(8)
_cell_length_b                   6.005(4)
_cell_length_c                   32.64(2)
_cell_angle_alpha                90
_cell_angle_beta                 101.13(4)
_cell_angle_gamma                90
_cell_volume                     2472(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    6318
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.14
_cell_measurement_theta_min      2.73
_shelx_estimated_absorpt_T_max   0.992
_shelx_estimated_absorpt_T_min   0.928
_exptl_absorpt_coefficient_mu    0.263
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0689 before and 0.0629 after correction.
The Ratio of minimum to maximum transmission is 0.8845.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.823
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1148
_diffrn_reflns_av_unetI/netI     0.0633
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            34276
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.454
_diffrn_reflns_theta_min         2.544
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean 5.12
_diffrn_detector_type            'CMOS area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       'D8 QUEST ECO'
_diffrn_measurement_device_type  'Bruker D8 QUEST Eco'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'sealed X-ray tube'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3043
_reflns_number_total             4553
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'

_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       'APEX 3 (Bruker, 2015) '
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'XP (Bruker, 2008-2014)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XT (Sheldrick, 2015)'

_refine_diff_density_max         0.581
_refine_diff_density_min         -0.402
_refine_diff_density_rms         0.080
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         4553
_refine_ls_number_restraints     103
_refine_ls_R_factor_all          0.1019
_refine_ls_R_factor_gt           0.0565
_refine_ls_restrained_S_all      1.112
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0446P)²+4.7812P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1302
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 O2-H2A
 0.89 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(F2) \\sim Ueq, Uanis(F3) \\sim Ueq, Uanis(F4) \\sim Ueq, Uanis(F5) \\sim
Ueq, Uanis(F6) \\sim Ueq, Uanis(F7) \\sim Ueq, Uanis(F8) \\sim Ueq, Uanis(F9)
\\sim Ueq, Uanis(F10) \\sim Ueq, Uanis(F11) \\sim Ueq, Uanis(F12) \\sim Ueq,
Uanis(F13) \\sim Ueq, Uanis(F14) \\sim Ueq, Uanis(F15) \\sim Ueq, Uanis(F16)
\\sim Ueq, Uanis(F17) \\sim Ueq, Uanis(F18) \\sim Ueq: with sigma of 0.005 and
sigma for terminal atoms of 0.01
4.a Ternary CH refined with riding coordinates:
 C14(H14)
4.b Secondary CH2 refined with riding coordinates:
 C13(H13A,H13B), C15(H15A,H15B)
4.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.48420(7) 0.33867(15) 0.81553(3) 0.0132(2) Uani 1 1 d . . . . .
O1 O 0.44978(19) 0.5602(4) 0.79762(8) 0.0187(6) Uani 1 1 d . . . . .
C1 C 0.4783(3) 0.3289(6) 0.87050(11) 0.0154(8) Uani 1 1 d . . . . .
C2 C 0.4433(3) 0.5169(6) 0.88805(13) 0.0230(9) Uani 1 1 d . . . . .
H2 H 0.4240 0.6460 0.8715 0.028 Uiso 1 1 calc R . . . .
O2 O 0.3570(2) -0.1591(4) 0.73688(8) 0.0234(6) Uani 1 1 d D . . . .
H2A H 0.391(4) -0.259(7) 0.7553(13) 0.069(18) Uiso 1 1 d D . . . .
F2 F 0.3459(3) 0.0111(4) 0.65456(8) 0.0740(11) Uani 1 1 d . U . . .
C3 C 0.4363(3) 0.5169(7) 0.92994(13) 0.0264(10) Uani 1 1 d . . . . .
H3 H 0.4122 0.6463 0.9420 0.032 Uiso 1 1 calc R . . . .
F3 F 0.4951(2) 0.1712(6) 0.67734(9) 0.0755(12) Uani 1 1 d . U . . .
F4 F 0.25235(17) 0.4279(4) 0.64510(7) 0.0363(7) Uani 1 1 d . U . . .
C4 C 0.4640(3) 0.3323(7) 0.95390(12) 0.0229(9) Uani 1 1 d . . . . .
H4 H 0.4594 0.3341 0.9826 0.027 Uiso 1 1 calc R . . . .
C5 C 0.4986(3) 0.1435(7) 0.93673(12) 0.0220(9) Uani 1 1 d . . . . .
H5 H 0.5177 0.0154 0.9536 0.026 Uiso 1 1 calc R . . . .
F5 F 0.4094(2) 0.5689(4) 0.66076(7) 0.0404(7) Uani 1 1 d . U . . .
C6 C 0.5055(3) 0.1401(6) 0.89491(11) 0.0196(8) Uani 1 1 d . . . . .
H6 H 0.5287 0.0094 0.8829 0.023 Uiso 1 1 calc R . . . .
F6 F 0.2961(3) 0.2192(4) 0.58057(7) 0.0542(9) Uani 1 1 d . U . . .
C7 C 0.6190(3) 0.2807(6) 0.81066(10) 0.0148(8) Uani 1 1 d . . . . .
F7 F 0.4628(2) 0.2920(6) 0.59792(8) 0.0664(10) Uani 1 1 d . U . . .
F8 F 0.43708(19) 0.7092(5) 0.58331(7) 0.0426(7) Uani 1 1 d . U . . .
C8 C 0.6726(3) 0.4455(6) 0.79344(11) 0.0204(9) Uani 1 1 d . . . . .
H8 H 0.6368 0.5791 0.7836 0.024 Uiso 1 1 calc R . . . .
C9 C 0.7775(3) 0.4181(7) 0.79047(12) 0.0244(9) Uani 1 1 d . . . . .
H9 H 0.8130 0.5317 0.7783 0.029 Uiso 1 1 calc R . . . .
F9 F 0.26984(19) 0.6992(4) 0.58430(7) 0.0302(6) Uani 1 1 d . U . . .
F10 F 0.22601(18) 0.4683(4) 0.51490(7) 0.0298(6) Uani 1 1 d . U . . .
C10 C 0.8304(3) 0.2274(7) 0.80506(12) 0.0262(9) Uani 1 1 d . . . . .
H10 H 0.9032 0.2109 0.8039 0.031 Uiso 1 1 calc R . . . .
C11 C 0.7775(3) 0.0582(7) 0.82160(13) 0.0275(10) Uani 1 1 d . . . . .
H11 H 0.8137 -0.0754 0.8312 0.033 Uiso 1 1 calc R . . . .
F11 F 0.3921(2) 0.4055(4) 0.51526(7) 0.0363(6) Uani 1 1 d . U . . .
C12 C 0.6721(3) 0.0843(6) 0.82407(12) 0.0218(9) Uani 1 1 d . . . . .
H12 H 0.6357 -0.0324 0.8350 0.026 Uiso 1 1 calc R . . . .
F12 F 0.42818(18) 0.8400(4) 0.50596(7) 0.0374(6) Uani 1 1 d . U . . .
F13 F 0.2698(2) 0.9238(4) 0.51405(7) 0.0323(6) Uani 1 1 d . U . . .
C13 C 0.4029(3) 0.1095(6) 0.79240(11) 0.0134(8) Uani 1 1 d . . . . .
H13A H 0.4212 -0.0224 0.8105 0.016 Uiso 1 1 calc R . . . .
H13B H 0.3280 0.1470 0.7926 0.016 Uiso 1 1 calc R . . . .
C14 C 0.4109(3) 0.0432(6) 0.74779(11) 0.0148(8) Uani 1 1 d . . . . .
H14 H 0.4873 0.0231 0.7463 0.018 Uiso 1 1 calc R . . . .
F14 F 0.1850(2) 0.6935(6) 0.44556(9) 0.0674(10) Uani 1 1 d . U . . .
C15 C 0.3633(3) 0.2196(6) 0.71625(11) 0.0159(8) Uani 1 1 d . . . . .
H15A H 0.2852 0.2159 0.7133 0.019 Uiso 1 1 calc R . . . .
H15B H 0.3879 0.3678 0.7274 0.019 Uiso 1 1 calc R . . . .
F15 F 0.3417(3) 0.5834(4) 0.43841(8) 0.0610(9) Uani 1 1 d . U . . .
C16 C 0.3902(3) 0.1933(6) 0.67427(11) 0.0209(9) Uani 1 1 d . . . . .
F16 F 0.2566(2) 0.9125(4) 0.38702(7) 0.0506(8) Uani 1 1 d . U . . .
C17 C 0.3551(3) 0.3916(6) 0.64492(11) 0.0144(8) Uani 1 1 d . . . . .
F17 F 0.3938(2) 1.0183(5) 0.42956(9) 0.0541(8) Uani 1 1 d . U . . .
F18 F 0.2425(2) 1.1185(4) 0.43785(8) 0.0516(8) Uani 1 1 d . U . . .
C18 C 0.3664(3) 0.3684(6) 0.59909(12) 0.0208(9) Uani 1 1 d . . . . .
C19 C 0.3497(3) 0.5862(6) 0.57364(11) 0.0164(8) Uani 1 1 d . . . . .
C20 C 0.3243(3) 0.5536(6) 0.52571(11) 0.0164(8) Uani 1 1 d . . . . .
C21 C 0.3278(3) 0.7681(6) 0.49990(11) 0.0166(8) Uani 1 1 d . . . . .
C22 C 0.2870(3) 0.7467(6) 0.45251(12) 0.0240(9) Uani 1 1 d . . . . .
C23 C 0.2959(3) 0.9523(7) 0.42623(12) 0.0220(9) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.486(3) . ?
P1 C1 1.811(4) . ?
P1 C7 1.805(4) . ?
P1 C13 1.803(4) . ?
C1 C2 1.380(5) . ?
C1 C6 1.391(5) . ?
C2 H2 0.9500 . ?
C2 C3 1.387(6) . ?
O2 H2A 0.90(2) . ?
O2 C14 1.410(4) . ?
F2 C16 1.339(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.364(6) . ?
F3 C16 1.338(5) . ?
F4 C17 1.340(4) . ?
C4 H4 0.9500 . ?
C4 C5 1.376(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.385(5) . ?
F5 C17 1.323(4) . ?
C6 H6 0.9500 . ?
F6 C18 1.332(5) . ?
C7 C8 1.385(5) . ?
C7 C12 1.390(5) . ?
F7 C18 1.328(4) . ?
F8 C19 1.330(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.379(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.369(6) . ?
F9 C19 1.331(4) . ?
F10 C20 1.345(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.389(6) . ?
C11 H11 0.9500 . ?
C11 C12 1.382(5) . ?
F11 C20 1.335(4) . ?
C12 H12 0.9500 . ?
F12 C21 1.338(4) . ?
F13 C21 1.333(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C13 C14 1.532(5) . ?
C14 H14 1.0000 . ?
C14 C15 1.521(5) . ?
F14 C22 1.326(5) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.485(5) . ?
F15 C22 1.339(5) . ?
C16 C17 1.541(5) . ?
F16 C23 1.304(4) . ?
C17 C18 1.537(5) . ?
F17 C23 1.304(4) . ?
F18 C23 1.308(5) . ?
C18 C19 1.542(5) . ?
C19 C20 1.547(5) . ?
C20 C21 1.545(5) . ?
C21 C22 1.540(5) . ?
C22 C23 1.520(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 C1 110.63(16) . . ?
O1 P1 C7 110.87(16) . . ?
O1 P1 C13 114.49(16) . . ?
C7 P1 C1 107.78(16) . . ?
C13 P1 C1 104.98(17) . . ?
C13 P1 C7 107.73(17) . . ?
C2 C1 P1 117.6(3) . . ?
C2 C1 C6 119.7(3) . . ?
C6 C1 P1 122.7(3) . . ?
C1 C2 H2 120.1 . . ?
C1 C2 C3 119.8(4) . . ?
C3 C2 H2 120.1 . . ?
C14 O2 H2A 105(4) . . ?
C2 C3 H3 119.8 . . ?
C4 C3 C2 120.4(4) . . ?
C4 C3 H3 119.8 . . ?
C3 C4 H4 119.8 . . ?
C3 C4 C5 120.4(4) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 120.0 . . ?
C4 C5 C6 120.0(4) . . ?
C6 C5 H5 120.0 . . ?
C1 C6 H6 120.1 . . ?
C5 C6 C1 119.7(3) . . ?
C5 C6 H6 120.1 . . ?
C8 C7 P1 117.3(3) . . ?
C8 C7 C12 118.8(3) . . ?
C12 C7 P1 123.8(3) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 C7 120.8(4) . . ?
C9 C8 H8 119.6 . . ?
C8 C9 H9 119.9 . . ?
C10 C9 C8 120.1(4) . . ?
C10 C9 H9 119.9 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.0(4) . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 C10 119.9(4) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 H12 119.8 . . ?
C11 C12 C7 120.3(4) . . ?
C11 C12 H12 119.8 . . ?
P1 C13 H13A 108.0 . . ?
P1 C13 H13B 108.0 . . ?
H13A C13 H13B 107.2 . . ?
C14 C13 P1 117.2(2) . . ?
C14 C13 H13A 108.0 . . ?
C14 C13 H13B 108.0 . . ?
O2 C14 C13 110.1(3) . . ?
O2 C14 H14 108.9 . . ?
O2 C14 C15 108.4(3) . . ?
C13 C14 H14 108.9 . . ?
C15 C14 C13 111.7(3) . . ?
C15 C14 H14 108.9 . . ?
C14 C15 H15A 108.6 . . ?
C14 C15 H15B 108.6 . . ?
H15A C15 H15B 107.6 . . ?
C16 C15 C14 114.5(3) . . ?
C16 C15 H15A 108.6 . . ?
C16 C15 H15B 108.6 . . ?
F2 C16 C15 112.1(3) . . ?
F2 C16 C17 106.6(3) . . ?
F3 C16 F2 106.5(4) . . ?
F3 C16 C15 110.6(3) . . ?
F3 C16 C17 107.0(3) . . ?
C15 C16 C17 113.5(3) . . ?
F4 C17 C16 107.1(3) . . ?
F4 C17 C18 107.3(3) . . ?
F5 C17 F4 108.3(3) . . ?
F5 C17 C16 108.1(3) . . ?
F5 C17 C18 108.2(3) . . ?
C18 C17 C16 117.6(3) . . ?
F6 C18 C17 108.6(3) . . ?
F6 C18 C19 108.3(3) . . ?
F7 C18 F6 108.0(3) . . ?
F7 C18 C17 108.9(3) . . ?
F7 C18 C19 108.1(3) . . ?
C17 C18 C19 114.7(3) . . ?
F8 C19 F9 108.3(3) . . ?
F8 C19 C18 108.6(3) . . ?
F8 C19 C20 108.3(3) . . ?
F9 C19 C18 109.0(3) . . ?
F9 C19 C20 107.8(3) . . ?
C18 C19 C20 114.6(3) . . ?
F10 C20 C19 108.5(3) . . ?
F10 C20 C21 107.4(3) . . ?
F11 C20 F10 107.8(3) . . ?
F11 C20 C19 108.8(3) . . ?
F11 C20 C21 109.1(3) . . ?
C21 C20 C19 115.0(3) . . ?
F12 C21 C20 108.5(3) . . ?
F12 C21 C22 107.9(3) . . ?
F13 C21 F12 108.1(3) . . ?
F13 C21 C20 108.6(3) . . ?
F13 C21 C22 107.6(3) . . ?
C22 C21 C20 116.0(3) . . ?
F14 C22 F15 109.4(4) . . ?
F14 C22 C21 109.0(3) . . ?
F14 C22 C23 106.1(3) . . ?
F15 C22 C21 107.9(3) . . ?
F15 C22 C23 107.4(3) . . ?
C23 C22 C21 116.8(3) . . ?
F16 C23 F17 108.8(3) . . ?
F16 C23 F18 107.4(3) . . ?
F16 C23 C22 110.4(3) . . ?
F17 C23 F18 107.2(3) . . ?
F17 C23 C22 112.1(3) . . ?
F18 C23 C22 110.9(3) . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2A O1 0.90(2) 1.80(2) 2.698(4) 171(5) 1_545
C13 H13A O1 0.99 2.58 3.351(5) 135 1_545
C13 H13B O2 0.99 2.66 3.574(5) 154 2_556
C15 H15B O1 0.99 2.55 3.367(5) 139 .

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 C2 C3 179.3(3) . . . . ?
P1 C1 C6 C5 -179.6(3) . . . . ?
P1 C7 C8 C9 176.9(3) . . . . ?
P1 C7 C12 C11 -176.0(3) . . . . ?
P1 C13 C14 O2 170.2(2) . . . . ?
P1 C13 C14 C15 -69.3(4) . . . . ?
O1 P1 C1 C2 0.8(3) . . . . ?
O1 P1 C1 C6 179.5(3) . . . . ?
O1 P1 C7 C8 2.7(3) . . . . ?
O1 P1 C7 C12 -179.0(3) . . . . ?
O1 P1 C13 C14 71.2(3) . . . . ?
C1 P1 C7 C8 -118.5(3) . . . . ?
C1 P1 C7 C12 59.8(3) . . . . ?
C1 P1 C13 C14 -167.3(3) . . . . ?
C1 C2 C3 C4 0.1(6) . . . . ?
C2 C1 C6 C5 -0.9(5) . . . . ?
C2 C3 C4 C5 -0.4(6) . . . . ?
O2 C14 C15 C16 -72.2(4) . . . . ?
F2 C16 C17 F4 72.4(4) . . . . ?
F2 C16 C17 F5 -171.2(3) . . . . ?
F2 C16 C17 C18 -48.5(4) . . . . ?
C3 C4 C5 C6 0.0(6) . . . . ?
F3 C16 C17 F4 -174.0(3) . . . . ?
F3 C16 C17 F5 -57.5(4) . . . . ?
F3 C16 C17 C18 65.2(4) . . . . ?
F4 C17 C18 F6 -51.2(4) . . . . ?
F4 C17 C18 F7 -168.6(3) . . . . ?
F4 C17 C18 C19 70.1(4) . . . . ?
C4 C5 C6 C1 0.6(6) . . . . ?
F5 C17 C18 F6 -167.8(3) . . . . ?
F5 C17 C18 F7 74.8(4) . . . . ?
F5 C17 C18 C19 -46.5(4) . . . . ?
C6 C1 C2 C3 0.6(6) . . . . ?
F6 C18 C19 F8 -160.6(3) . . . . ?
F6 C18 C19 F9 81.6(4) . . . . ?
F6 C18 C19 C20 -39.3(4) . . . . ?
C7 P1 C1 C2 122.1(3) . . . . ?
C7 P1 C1 C6 -59.2(3) . . . . ?
C7 P1 C13 C14 -52.6(3) . . . . ?
C7 C8 C9 C10 -0.8(6) . . . . ?
F7 C18 C19 F8 -43.8(4) . . . . ?
F7 C18 C19 F9 -161.5(3) . . . . ?
F7 C18 C19 C20 77.5(4) . . . . ?
F8 C19 C20 F10 -168.1(3) . . . . ?
F8 C19 C20 F11 74.9(4) . . . . ?
F8 C19 C20 C21 -47.7(4) . . . . ?
C8 C7 C12 C11 2.3(6) . . . . ?
C8 C9 C10 C11 2.2(6) . . . . ?
C9 C10 C11 C12 -1.3(6) . . . . ?
F9 C19 C20 F10 -51.1(4) . . . . ?
F9 C19 C20 F11 -168.2(3) . . . . ?
F9 C19 C20 C21 69.2(4) . . . . ?
F10 C20 C21 F12 -171.9(3) . . . . ?
F10 C20 C21 F13 70.8(4) . . . . ?
F10 C20 C21 C22 -50.4(4) . . . . ?
C10 C11 C12 C7 -1.0(6) . . . . ?
F11 C20 C21 F12 -55.3(4) . . . . ?
F11 C20 C21 F13 -172.6(3) . . . . ?
F11 C20 C21 C22 66.2(4) . . . . ?
C12 C7 C8 C9 -1.4(5) . . . . ?
F12 C21 C22 F14 -174.8(3) . . . . ?
F12 C21 C22 F15 66.4(4) . . . . ?
F12 C21 C22 C23 -54.6(4) . . . . ?
F13 C21 C22 F14 -58.5(4) . . . . ?
F13 C21 C22 F15 -177.2(3) . . . . ?
F13 C21 C22 C23 61.8(4) . . . . ?
C13 P1 C1 C2 -123.2(3) . . . . ?
C13 P1 C1 C6 55.5(3) . . . . ?
C13 P1 C7 C8 128.7(3) . . . . ?
C13 P1 C7 C12 -53.0(3) . . . . ?
C13 C14 C15 C16 166.3(3) . . . . ?
C14 C15 C16 F2 67.6(4) . . . . ?
C14 C15 C16 F3 -51.2(4) . . . . ?
C14 C15 C16 C17 -171.5(3) . . . . ?
F14 C22 C23 F16 -56.9(4) . . . . ?
F14 C22 C23 F17 -178.3(3) . . . . ?
F14 C22 C23 F18 61.9(4) . . . . ?
C15 C16 C17 F4 -51.6(4) . . . . ?
C15 C16 C17 F5 64.9(4) . . . . ?
C15 C16 C17 C18 -172.4(3) . . . . ?
F15 C22 C23 F16 60.1(4) . . . . ?
F15 C22 C23 F17 -61.3(4) . . . . ?
F15 C22 C23 F18 178.9(3) . . . . ?
C16 C17 C18 F6 69.5(4) . . . . ?
C16 C17 C18 F7 -47.9(4) . . . . ?
C16 C17 C18 C19 -169.2(3) . . . . ?
C17 C18 C19 F8 77.9(4) . . . . ?
C17 C18 C19 F9 -39.9(4) . . . . ?
C17 C18 C19 C20 -160.8(3) . . . . ?
C18 C19 C20 F10 70.5(4) . . . . ?
C18 C19 C20 F11 -46.6(4) . . . . ?
C18 C19 C20 C21 -169.2(3) . . . . ?
C19 C20 C21 F12 67.2(4) . . . . ?
C19 C20 C21 F13 -50.1(4) . . . . ?
C19 C20 C21 C22 -171.3(3) . . . . ?
C20 C21 C22 F14 63.3(4) . . . . ?
C20 C21 C22 F15 -55.5(4) . . . . ?
C20 C21 C22 C23 -176.5(3) . . . . ?
C21 C22 C23 F16 -178.7(3) . . . . ?
C21 C22 C23 F17 59.9(5) . . . . ?
C21 C22 C23 F18 -59.8(5) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_exptl_crystal_mounting_method 'Mitegen holder in oil'
_olex2_submission_original_sample_id FSZ_DP6
_olex2_submission_special_instructions 'No special instructions were received'
