# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_lb165
_database_code_depnum_ccdc_archive 'CCDC 1579794'
loop_
_audit_author_name
_audit_author_address
'Lipiao Bao' 'Huazhong University of Science and Technology'
_audit_update_record             
;
2018-01-04 deposited with the CCDC.	2019-04-26 downloaded from the CCDC.
;

_vrf_PLAT308_lb165               
;
PROBLEM: Single Bonded Metal Atom in Structure (Unusual) Eu1 Check
RESPONSE: This is an endohedral Eu atom.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        'Eu@C2(5)-C82 Ni(OEP) 2(C6H6)'
_chemical_name_common            'Eu@C2(5)-C82 Ni(OEP) 2(C6H6)'
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu C82, C36 H44 N4 Ni, 2(C6 H6)'
_chemical_formula_sum            'C130 H56 Eu N4 Ni'
_chemical_formula_weight         1884.45

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0027 0.0014 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0053 0.0028 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3436 0.9622 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1666 3.2045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 2/m'
_space_group_name_Hall           '-C 2y'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   25.236(2)
_cell_length_b                   15.0375(14)
_cell_length_c                   19.8277(19)
_cell_angle_alpha                90
_cell_angle_beta                 94.3850(10)
_cell_angle_gamma                90
_cell_volume                     7502.3(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9950
_cell_measurement_theta_min      2.427
_cell_measurement_theta_max      25.029

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.668
_exptl_crystal_F_000             3820
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.170
_exptl_absorpt_coefficient_mu    0.913
_shelx_estimated_absorpt_T_min   0.838
_shelx_estimated_absorpt_T_max   0.860
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6347
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   SADABS
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.6525
_diffrn_radiation_type           synchrotron
_diffrn_source                   'SSRF, Beamline B17B1'
_diffrn_measurement_device_type  'CCD MX-300'
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            62921
_diffrn_reflns_av_unetI/netI     0.0288
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         0.946
_diffrn_reflns_theta_max         25.068
_diffrn_reflns_theta_full        23.048
_diffrn_measured_fraction_theta_max 0.947
_diffrn_measured_fraction_theta_full 0.954
_diffrn_reflns_Laue_measured_fraction_max 0.947
_diffrn_reflns_Laue_measured_fraction_full 0.954
_diffrn_reflns_point_group_measured_fraction_max 0.947
_diffrn_reflns_point_group_measured_fraction_full 0.954
_reflns_number_total             8461
_reflns_number_gt                6872
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1738P)²+36.6554P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8461
_refine_ls_number_parameters     998
_refine_ls_number_restraints     1087
_refine_ls_R_factor_all          0.1018
_refine_ls_R_factor_gt           0.0873
_refine_ls_wR_factor_ref         0.2663
_refine_ls_wR_factor_gt          0.2504
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.139
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C3 C 0.1319(5) 0.000000 0.8237(10) 0.110(4) Uani 1 2 d DS TU P . .
C9 C 0.2041(8) 0.000000 0.9737(8) 0.122(4) Uani 1 2 d S TU P . .
C26 C 0.2913(7) 0.000000 1.0193(5) 0.096(3) Uani 1 2 d S TU P . .
C48 C 0.4276(5) 0.000000 0.9640(7) 0.091(3) Uani 1 2 d S TU P . .
C81 C 0.4574(4) 0.000000 0.7933(6) 0.081(3) Uani 1 2 d DS TU P . .
C1 C 0.1699(8) -0.0264(12) 0.9294(10) 0.112(5) Uani 0.5 1 d D U P A -1
C2 C 0.1516(7) 0.0421(11) 0.8837(10) 0.103(4) Uani 0.5 1 d D U P A -1
C4 C 0.1420(7) -0.0905(10) 0.8340(10) 0.104(4) Uani 0.5 1 d D U P A -1
C5 C 0.1674(9) -0.1070(13) 0.8971(10) 0.110(5) Uani 0.5 1 d D U P A -1
C6 C 0.2118(9) -0.1752(15) 0.9078(10) 0.089(4) Uani 0.5 1 d D U P A -1
C7 C 0.2494(8) -0.1448(13) 0.9625(9) 0.109(4) Uani 0.5 1 d D U P A -1
C8 C 0.2427(12) -0.0583(15) 0.9962(10) 0.096(4) Uani 0.5 1 d . U P A -1
C10 C 0.2218(8) 0.0877(13) 0.9743(8) 0.096(4) Uani 0.5 1 d D U P A -1
C11 C 0.2107(10) 0.1550(15) 0.9261(10) 0.101(5) Uani 0.5 1 d D U P A -1
C12 C 0.1695(9) 0.1291(15) 0.8680(11) 0.095(4) Uani 0.5 1 d . U P A -1
C13 C 0.1721(7) 0.1631(12) 0.8123(9) 0.073(4) Uani 0.5 1 d . U P A -1
C14 C 0.1528(7) 0.1087(15) 0.7535(11) 0.085(4) Uani 0.5 1 d . U P A -1
C15 C 0.1345(6) 0.0260(12) 0.7618(12) 0.095(4) Uani 0.5 1 d . U P A -1
C16 C 0.1480(7) -0.0316(11) 0.7037(11) 0.099(4) Uani 0.5 1 d D U P A -1
C17 C 0.1599(7) -0.1174(11) 0.7203(10) 0.099(5) Uani 0.5 1 d D U P A -1
C18 C 0.1618(7) -0.1522(13) 0.7835(10) 0.091(4) Uani 0.5 1 d D U P A -1
C19 C 0.2015(7) -0.2107(10) 0.7860(7) 0.080(2) Uani 0.5 1 d D U P A -1
C20 C 0.2254(6) -0.2255(9) 0.8487(6) 0.083(3) Uani 0.5 1 d D U P A -1
C21 C 0.2847(7) -0.2570(11) 0.8433(8) 0.093(4) Uani 0.5 1 d D U P A -1
C22 C 0.3165(7) -0.2440(8) 0.9027(8) 0.070(3) Uani 0.5 1 d D U P A -1
C23 C 0.3027(9) -0.1836(14) 0.9601(10) 0.102(4) Uani 0.5 1 d D U P A -1
C24 C 0.3424(11) -0.1254(16) 0.9928(10) 0.078(4) Uani 0.5 1 d . U P A -1
C25 C 0.3417(9) -0.0282(9) 1.0156(5) 0.084(4) Uani 0.5 1 d . U P A -1
C27 C 0.2772(7) 0.0836(9) 1.0061(6) 0.080(3) Uani 0.5 1 d D U P A -1
C28 C 0.3122(8) 0.1490(8) 0.9881(6) 0.073(3) Uani 0.5 1 d D U P A -1
C29 C 0.2980(9) 0.2159(9) 0.9380(8) 0.089(4) Uani 0.5 1 d D U P A -1
C30 C 0.2497(8) 0.2151(10) 0.9085(8) 0.103(4) Uani 0.5 1 d D U P A -1
C31 C 0.2567(8) 0.2614(10) 0.8353(9) 0.095(4) Uani 0.5 1 d D U P A -1
C32 C 0.2197(7) 0.2325(10) 0.7896(9) 0.080(2) Uani 0.5 1 d D U P A -1
C33 C 0.2392(8) 0.2285(16) 0.7257(9) 0.071(4) Uani 0.5 1 d D U P A -1
C34 C 0.2131(10) 0.1609(14) 0.6682(10) 0.076(4) Uani 0.5 1 d . U P A -1
C35 C 0.1710(8) 0.0951(14) 0.6832(10) 0.092(4) Uani 0.5 1 d . U P A -1
C36 C 0.1745(7) 0.0167(13) 0.6546(8) 0.096(5) Uani 0.5 1 d D U P A -1
C37 C 0.2140(7) -0.0219(8) 0.6197(7) 0.081(4) Uani 0.5 1 d D U P A -1
C38 C 0.2237(7) -0.1111(9) 0.6364(8) 0.077(4) Uani 0.5 1 d D U P A -1
C39 C 0.1991(7) -0.1551(12) 0.6861(8) 0.083(4) Uani 0.5 1 d D U P A -1
C40 C 0.2246(6) -0.2168(12) 0.7241(8) 0.063(4) Uani 0.5 1 d D U P A -1
C41 C 0.2826(6) -0.2369(10) 0.7114(9) 0.073(4) Uani 0.5 1 d D U P A -1
C42 C 0.3134(8) -0.2674(16) 0.7799(10) 0.095(4) Uani 0.5 1 d D U P A -1
C43 C 0.3640(7) -0.2518(10) 0.7858(8) 0.080(4) Uani 0.5 1 d D U P A -1
C44 C 0.3978(6) -0.2262(9) 0.8433(7) 0.067(3) Uani 0.5 1 d D U P A -1
C45 C 0.3753(7) -0.2185(13) 0.9051(12) 0.061(4) Uani 0.5 1 d . U P A -1
C46 C 0.3852(9) -0.1509(14) 0.9599(11) 0.073(4) Uani 0.5 1 d . U P A -1
C47 C 0.4270(6) -0.0925(10) 0.9475(8) 0.077(3) Uani 0.5 1 d . U P A -1
C49 C 0.3839(9) 0.0287(10) 0.9992(7) 0.085(4) Uani 0.5 1 d . U P A -1
C50 C 0.3688(11) 0.1180(14) 0.9875(10) 0.080(4) Uani 0.5 1 d . U P A -1
C51 C 0.3981(10) 0.1697(13) 0.9378(9) 0.077(4) Uani 0.5 1 d . U P A -1
C52 C 0.3586(14) 0.2338(16) 0.9044(15) 0.089(5) Uani 0.5 1 d . U P A -1
C53 C 0.3561(7) 0.2606(10) 0.8385(9) 0.095(4) Uani 0.5 1 d D U P A -1
C54 C 0.3047(7) 0.2730(13) 0.8056(8) 0.092(4) Uani 0.5 1 d D U P A -1
C55 C 0.2931(7) 0.2545(12) 0.7355(8) 0.091(4) Uani 0.5 1 d D U P A -1
C56 C 0.3270(8) 0.2200(13) 0.6900(10) 0.098(4) Uani 0.5 1 d D U P A -1
C57 C 0.3053(9) 0.1567(11) 0.6430(8) 0.074(4) Uani 0.5 1 d . U P A -1
C58 C 0.2542(10) 0.1245(12) 0.6268(7) 0.071(4) Uani 0.5 1 d . U P A -1
C59 C 0.2579(8) 0.0304(9) 0.6031(5) 0.080(3) Uani 0.5 1 d . U P A -1
C60 C 0.3101(6) 0.0108(13) 0.6057(6) 0.090(4) Uani 0.5 1 d D U P A -1
C61 C 0.3194(7) -0.0784(11) 0.6148(10) 0.098(5) Uani 0.5 1 d D U P A -1
C62 C 0.2801(8) -0.1411(12) 0.6292(10) 0.081(4) Uani 0.5 1 d D U P A -1
C63 C 0.3066(6) -0.2020(11) 0.6720(9) 0.081(4) Uani 0.5 1 d D U P A -1
C64 C 0.3604(6) -0.1753(10) 0.6793(7) 0.093(4) Uani 0.5 1 d D U P A -1
C65 C 0.3878(9) -0.2018(17) 0.7384(11) 0.091(5) Uani 0.5 1 d D U P A -1
C66 C 0.4292(7) -0.1429(11) 0.7642(10) 0.085(4) Uani 0.5 1 d D U P A -1
C67 C 0.4355(16) -0.157(2) 0.8370(17) 0.072(5) Uani 0.5 1 d . U P A -1
C68 C 0.4520(7) -0.1024(14) 0.8769(10) 0.076(4) Uani 0.5 1 d D U P A -1
C69 C 0.4642(5) -0.0149(15) 0.8581(8) 0.078(4) Uani 0.5 1 d . U P A -1
C70 C 0.4508(6) 0.0488(12) 0.9091(9) 0.077(3) Uani 0.5 1 d . U P A -1
C71 C 0.4353(8) 0.1351(13) 0.8969(9) 0.082(4) Uani 0.5 1 d . U P A -1
C72 C 0.4333(18) 0.170(2) 0.8249(16) 0.071(5) Uani 0.5 1 d . U P A -1
C73 C 0.3932(7) 0.2258(11) 0.7923(8) 0.081(4) Uani 0.5 1 d D U P A -1
C74 C 0.3790(8) 0.2044(14) 0.7218(8) 0.080(4) Uani 0.5 1 d D U P A -1
C75 C 0.4081(7) 0.1236(12) 0.7150(7) 0.082(3) Uani 0.5 1 d D U P A -1
C76 C 0.3892(7) 0.0569(12) 0.6656(9) 0.091(4) Uani 0.5 1 d D U P A -1
C77 C 0.3416(7) 0.0800(13) 0.6286(8) 0.081(4) Uani 0.5 1 d D U P A -1
C78 C 0.4045(6) -0.0273(9) 0.6835(8) 0.082(4) Uani 0.5 1 d D U P A -1
C79 C 0.3685(7) -0.0960(11) 0.6494(9) 0.103(4) Uani 0.5 1 d D U P A -1
C80 C 0.4360(6) -0.0616(8) 0.7368(7) 0.073(3) Uani 0.5 1 d D U P A -1
C82 C 0.4441(6) 0.0949(12) 0.7758(8) 0.069(3) Uani 0.5 1 d . U P A -1
C83 C 0.27357(17) 0.1370(3) 0.4369(2) 0.0370(9) Uani 1 1 d . . . B 2
H83A H 0.289061 0.168412 0.477025 0.055 Uiso 1 1 calc R U . B 2
H83B H 0.253874 0.084923 0.450988 0.055 Uiso 1 1 calc R U . B 2
H83C H 0.249349 0.176973 0.410450 0.055 Uiso 1 1 calc R U . B 2
N3 N 0.53575(17) 0.000000 0.6574(2) 0.0197(8) Uani 1 2 d S T P B 2
N2 N 0.47980(11) 0.13027(18) 0.58356(14) 0.0188(6) Uani 1 1 d . . . B 2
N1 N 0.42393(16) 0.000000 0.5099(2) 0.0176(7) Uani 1 2 d S T P B 2
Ni Ni 0.48078(2) 0.000000 0.58233(3) 0.01625(19) Uani 1 2 d S T P B 2
C84 C 0.31773(15) 0.1072(2) 0.39383(18) 0.0260(7) Uani 1 1 d . . . B 2
H84A H 0.301843 0.077304 0.352647 0.031 Uiso 1 1 calc R U . B 2
H84B H 0.337346 0.160110 0.379437 0.031 Uiso 1 1 calc R U . B 2
C85 C 0.35583(14) 0.0450(2) 0.43128(17) 0.0213(7) Uani 1 1 d . . . B 2
C86 C 0.39794(14) 0.0724(2) 0.48010(16) 0.0197(6) Uani 1 1 d . . . B 2
C87 C 0.40963(14) 0.1594(2) 0.49496(17) 0.0210(6) Uani 1 1 d . . . B 2
H87 H 0.390319 0.203953 0.469582 0.025 Uiso 1 1 calc R U . B 2
C88 C 0.44741(14) 0.1865(2) 0.54410(17) 0.0203(6) Uani 1 1 d . . . B 2
C89 C 0.45757(15) 0.2783(2) 0.56161(19) 0.0248(7) Uani 1 1 d . . . B 2
C90 C 0.42766(16) 0.3553(2) 0.5285(2) 0.0322(9) Uani 1 1 d . . . B 2
H90A H 0.424041 0.345570 0.478978 0.039 Uiso 1 1 calc R U . B 2
H90B H 0.448504 0.410378 0.537284 0.039 Uiso 1 1 calc R U . B 2
C91 C 0.37243(18) 0.3678(3) 0.5537(3) 0.0403(10) Uani 1 1 d . . . B 2
H91A H 0.375721 0.378732 0.602540 0.061 Uiso 1 1 calc R U . B 2
H91B H 0.351227 0.314035 0.544114 0.061 Uiso 1 1 calc R U . B 2
H91C H 0.354921 0.418672 0.530515 0.061 Uiso 1 1 calc R U . B 2
C92 C 0.49613(15) 0.2785(2) 0.61246(19) 0.0254(7) Uani 1 1 d . . . B 2
C93 C 0.52025(16) 0.3555(2) 0.6517(2) 0.0321(9) Uani 1 1 d . . . B 2
H93A H 0.513491 0.410642 0.625245 0.039 Uiso 1 1 calc R U . B 2
H93B H 0.559206 0.346881 0.658049 0.039 Uiso 1 1 calc R U . B 2
C94 C 0.4983(2) 0.3666(3) 0.7211(2) 0.0428(11) Uani 1 1 d . . . B 2
H94A H 0.514468 0.418979 0.743746 0.064 Uiso 1 1 calc R U . B 2
H94B H 0.506672 0.313619 0.748604 0.064 Uiso 1 1 calc R U . B 2
H94C H 0.459652 0.374445 0.715292 0.064 Uiso 1 1 calc R U . B 2
C95 C 0.51002(14) 0.1863(2) 0.62563(18) 0.0214(7) Uani 1 1 d . . . B 2
C96 C 0.54794(14) 0.1597(2) 0.67455(17) 0.0221(7) Uani 1 1 d . . . B 2
H96 H 0.567775 0.204395 0.699121 0.027 Uiso 1 1 calc R U . B 2
C97 C 0.55906(14) 0.0724(2) 0.69029(17) 0.0212(7) Uani 1 1 d . . . B 2
C98 C 0.59616(15) 0.0450(2) 0.74530(18) 0.0248(7) Uani 1 1 d . . . B 2
C99 C 0.62524(16) 0.1076(3) 0.7937(2) 0.0299(8) Uani 1 1 d . . . B 2
H99A H 0.640696 0.156180 0.767754 0.036 Uiso 1 1 calc R U . B 2
H99B H 0.654927 0.075376 0.818368 0.036 Uiso 1 1 calc R U . B 2
C100 C 0.59016(18) 0.1480(3) 0.8447(2) 0.0359(9) Uani 1 1 d . . . B 2
H10A H 0.611406 0.187938 0.874973 0.054 Uiso 1 1 calc R U . B 2
H10B H 0.575230 0.100408 0.871203 0.054 Uiso 1 1 calc R U . B 2
H10C H 0.561238 0.181541 0.820719 0.054 Uiso 1 1 calc R U . B 2
C101 C 0.4470(5) 0.6323(11) 1.0037(10) 0.197(9) Uani 1 1 d . . . C 2
H10D H 0.409319 0.635440 1.002853 0.236 Uiso 1 1 calc R U . C 2
C102 C 0.4724(5) 0.6261(8) 0.9353(9) 0.144(5) Uani 1 1 d . . . C 2
H10E H 0.451759 0.617513 0.893770 0.173 Uiso 1 1 calc R U . C 2
C103 C 0.5263(4) 0.6336(7) 0.9384(7) 0.116(4) Uani 1 1 d . . . C 2
H103 H 0.544097 0.639773 0.898132 0.139 Uiso 1 1 calc R U . C 2
C104 C 0.2886(3) 0.500000 0.8318(3) 0.0476(16) Uani 1 2 d S T P D 2
H104 H 0.263745 0.500000 0.865454 0.057 Uiso 1 2 calc R U P D 2
C105 C 0.2713(3) 0.500000 0.7637(3) 0.0397(14) Uani 1 2 d S T P D 2
H105 H 0.234305 0.500000 0.750523 0.048 Uiso 1 2 calc R U P D 2
C106 C 0.3073(3) 0.500000 0.7151(3) 0.0368(13) Uani 1 2 d S T P D 2
H106 H 0.295130 0.500000 0.668539 0.044 Uiso 1 2 calc R U P D 2
C107 C 0.3608(3) 0.500000 0.7336(3) 0.0395(13) Uani 1 2 d S T P D 2
H107 H 0.385761 0.500000 0.700078 0.047 Uiso 1 2 calc R U P D 2
C108 C 0.3782(3) 0.500000 0.8012(4) 0.060(2) Uani 1 2 d S T P D 2
H108 H 0.415248 0.500000 0.814137 0.072 Uiso 1 2 calc R U P D 2
C109 C 0.3425(4) 0.500000 0.8498(4) 0.064(2) Uani 1 2 d S T P D 2
H109 H 0.354975 0.500000 0.896292 0.077 Uiso 1 2 calc R U P D 2
Eu1 Eu 0.25230(10) 0.0242(2) 0.86165(12) 0.1155(14) Uani 0.2326 1 d . . P A .
Eu2 Eu 0.32588(7) -0.09533(11) 0.79232(10) 0.0599(5) Uani 0.1818 1 d . . P . .
Eu3 Eu 0.28292(16) 0.000000 0.89286(15) 0.0983(16) Uani 0.1711 2 d S T P A .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C3 C15 1.30(2) . ?
C3 C4 1.397(15) . ?
C3 C2 1.406(17) . ?
C3 Eu1 3.097(14) . ?
C3 Eu1 3.097(14) 6 ?
C9 C1 1.25(2) . ?
C9 C8 1.36(3) . ?
C9 C10 1.39(2) . ?
C9 Eu1 2.638(12) . ?
C9 Eu1 2.638(12) 6 ?
C9 Eu3 2.647(14) . ?
C26 C27 1.327(15) . ?
C26 C25 1.35(2) . ?
C26 C8 1.55(3) . ?
C26 Eu3 2.501(10) . ?
C26 Eu1 3.226(12) . ?
C26 Eu1 3.226(12) 6 ?
C48 C49 1.42(2) . ?
C48 C47 1.428(17) . ?
C48 C70 1.47(2) . ?
C81 C69 1.302(18) . ?
C81 C82 1.500(19) . ?
C81 C80 1.520(18) . ?
C1 C5 1.370(17) . ?
C1 C2 1.425(16) . ?
C1 Eu1 2.671(16) . ?
C1 Eu3 3.022(18) . ?
C2 C12 1.43(3) . ?
C2 Eu1 2.626(18) . ?
C4 C5 1.384(18) . ?
C4 C18 1.48(3) . ?
C5 C6 1.52(3) . ?
C5 Eu1 3.034(19) . ?
C6 C7 1.458(19) . ?
C6 C20 1.458(16) . ?
C6 Eu3 3.21(2) . ?
C7 C23 1.471(19) . ?
C7 C8 1.48(3) . ?
C7 Eu3 2.746(16) . ?
C7 Eu1 3.238(16) . ?
C8 Eu3 2.512(18) . ?
C8 Eu1 2.968(19) . ?
C10 C11 1.405(19) . ?
C10 C27 1.490(19) . ?
C10 Eu1 2.600(14) . ?
C10 Eu3 2.667(14) . ?
C11 C30 1.40(2) . ?
C11 C12 1.54(3) . ?
C11 Eu1 2.61(2) . ?
C11 Eu3 3.06(2) . ?
C12 C13 1.22(2) . ?
C12 Eu1 2.628(18) . ?
C13 C14 1.48(3) . ?
C13 C32 1.68(2) . ?
C13 Eu1 3.018(14) . ?
C14 C15 1.34(3) . ?
C14 C35 1.52(3) . ?
C15 C16 1.50(2) . ?
C16 C17 1.360(18) . ?
C16 C36 1.422(18) . ?
C17 C18 1.355(16) . ?
C17 C39 1.365(13) . ?
C18 C19 1.331(15) . ?
C19 C20 1.359(16) . ?
C19 C40 1.402(12) . ?
C20 C21 1.582(17) . ?
C21 C22 1.388(16) . ?
C21 C42 1.506(18) . ?
C21 Eu2 2.858(15) . ?
C22 C23 1.517(18) . ?
C22 C45 1.53(2) . ?
C22 Eu2 3.151(13) . ?
C23 C24 1.45(3) . ?
C23 Eu3 3.090(19) . ?
C24 C46 1.36(3) . ?
C24 C25 1.53(3) . ?
C24 Eu3 3.05(2) . ?
C25 C49 1.42(2) . ?
C25 Eu3 2.784(13) . ?
C27 C28 1.386(17) . ?
C27 Eu3 2.587(11) . ?
C27 Eu1 3.020(12) . ?
C28 C29 1.440(15) . ?
C28 C50 1.50(3) . ?
C28 Eu3 2.987(12) . ?
C29 C30 1.313(18) . ?
C29 C52 1.73(4) . ?
C30 C31 1.63(2) . ?
C30 Eu1 3.018(14) . ?
C31 C32 1.322(15) . ?
C31 C54 1.397(16) . ?
C32 C33 1.395(15) . ?
C33 C55 1.416(16) . ?
C33 C34 1.63(3) . ?
C34 C58 1.48(3) . ?
C34 C35 1.50(3) . ?
C35 C36 1.31(3) . ?
C36 C37 1.383(17) . ?
C37 C38 1.398(16) . ?
C37 C59 1.42(2) . ?
C38 C39 1.374(18) . ?
C38 C62 1.51(2) . ?
C39 C40 1.329(15) . ?
C40 C41 1.532(16) . ?
C41 C63 1.15(2) . ?
C41 C42 1.581(18) . ?
C41 Eu2 2.834(13) . ?
C42 C43 1.295(19) . ?
C42 Eu2 2.62(2) . ?
C43 C65 1.38(2) . ?
C43 C44 1.422(17) . ?
C43 Eu2 2.549(14) . ?
C44 C45 1.39(3) . ?
C44 C67 1.42(5) . ?
C44 Eu2 2.812(11) . ?
C45 C46 1.50(3) . ?
C45 Eu2 3.09(2) . ?
C46 C47 1.41(3) . ?
C47 C68 1.59(3) . ?
C49 C50 1.41(2) . ?
C49 Eu3 3.209(15) . ?
C50 C51 1.50(3) . ?
C51 C71 1.39(3) . ?
C51 C52 1.50(3) . ?
C52 C53 1.36(3) . ?
C53 C54 1.420(18) . ?
C53 C73 1.457(18) . ?
C54 C55 1.425(13) . ?
C55 C56 1.390(18) . ?
C56 C57 1.41(2) . ?
C56 C74 1.430(19) . ?
C57 C58 1.39(3) . ?
C57 C77 1.52(3) . ?
C58 C59 1.50(2) . ?
C59 C60 1.35(2) . ?
C60 C77 1.366(17) . ?
C60 C61 1.372(18) . ?
C61 C79 1.395(13) . ?
C61 C62 1.412(16) . ?
C62 C63 1.385(16) . ?
C63 C64 1.413(15) . ?
C63 Eu2 2.886(14) . ?
C64 C79 1.354(13) . ?
C64 C65 1.374(18) . ?
C64 Eu2 2.743(12) . ?
C65 C66 1.436(19) . ?
C65 Eu2 2.53(3) . ?
C66 C80 1.354(16) . ?
C66 C67 1.46(4) . ?
C66 Eu2 2.801(16) . ?
C67 C68 1.20(4) . ?
C67 Eu2 2.99(4) . ?
C68 C69 1.41(3) . ?
C69 C70 1.45(2) . ?
C70 C71 1.37(3) . ?
C71 C72 1.52(3) . ?
C72 C73 1.43(4) . ?
C72 C82 1.53(5) . ?
C73 C74 1.453(17) . ?
C74 C75 1.43(3) . ?
C75 C76 1.46(2) . ?
C75 C82 1.51(2) . ?
C76 C78 1.364(16) . ?
C76 C77 1.401(18) . ?
C78 C80 1.373(16) . ?
C78 C79 1.503(16) . ?
C78 Eu2 3.209(16) . ?
C79 Eu2 3.106(18) . ?
C80 Eu2 3.109(14) . ?
C83 C84 1.523(6) . ?
N3 C97 1.377(4) . ?
N3 C97 1.377(4) 6 ?
N3 Ni 1.956(4) . ?
N2 C95 1.374(4) . ?
N2 C88 1.377(4) . ?
N2 Ni 1.959(3) . ?
N1 C86 1.381(4) . ?
N1 C86 1.381(4) 6 ?
N1 Ni 1.951(4) . ?
C84 C85 1.498(5) . ?
C85 C85 1.352(7) 6 ?
C85 C86 1.442(4) . ?
C86 C87 1.367(5) . ?
C87 C88 1.372(5) . ?
C88 C89 1.442(4) . ?
C89 C92 1.347(5) . ?
C89 C90 1.504(5) . ?
C90 C91 1.528(6) . ?
C92 C95 1.449(5) . ?
C92 C93 1.498(5) . ?
C93 C94 1.530(7) . ?
C95 C96 1.369(5) . ?
C96 C97 1.374(5) . ?
C97 C98 1.442(5) . ?
C98 C98 1.355(7) 6 ?
C98 C99 1.496(5) . ?
C99 C100 1.520(6) . ?
C101 C103 1.29(2) 2_657 ?
C101 C102 1.55(2) . ?
C102 C103 1.362(14) . ?
C104 C109 1.381(12) . ?
C104 C105 1.387(9) . ?
C105 C106 1.374(9) . ?
C106 C107 1.373(9) . ?
C107 C108 1.377(10) . ?
C108 C109 1.369(12) . ?
Eu1 Eu1 0.729(6) 6 ?
Eu1 Eu3 1.020(4) . ?
Eu1 Eu2 2.621(3) 6 ?
Eu1 Eu2 2.993(3) . ?
Eu2 Eu3 2.745(3) . ?
Eu2 Eu2 2.867(3) 6 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C15 C3 C4 114.3(13) . . ?
C15 C3 C2 128.7(12) . . ?
C4 C3 C2 105.4(11) . . ?
C15 C3 Eu1 94.2(9) . . ?
C4 C3 Eu1 85.0(9) . . ?
C2 C3 Eu1 57.6(8) . . ?
C15 C3 Eu1 98.3(9) . 6 ?
C4 C3 Eu1 71.6(8) . 6 ?
C2 C3 Eu1 64.5(8) . 6 ?
Eu1 C3 Eu1 13.51(13) . 6 ?
C1 C9 C8 117.8(14) . . ?
C1 C9 C10 120.7(17) . . ?
C8 C9 C10 113(2) . . ?
C1 C9 Eu1 77.9(10) . . ?
C8 C9 Eu1 90.0(10) . . ?
C10 C9 Eu1 73.1(7) . . ?
C1 C9 Eu1 72.7(9) . 6 ?
C8 C9 Eu1 79.8(9) . 6 ?
C10 C9 Eu1 88.3(8) . 6 ?
Eu1 C9 Eu1 15.88(15) . 6 ?
C1 C9 Eu3 94.9(10) . . ?
C8 C9 Eu3 69.3(10) . . ?
C10 C9 Eu3 75.6(8) . . ?
Eu1 C9 Eu3 22.25(13) . . ?
Eu1 C9 Eu3 22.24(13) 6 . ?
C27 C26 C25 121.8(14) . . ?
C27 C26 C8 106.4(18) . . ?
C25 C26 C8 122.3(11) . . ?
C27 C26 Eu3 78.5(6) . . ?
C25 C26 Eu3 87.3(6) . . ?
C8 C26 Eu3 72.4(8) . . ?
C27 C26 Eu1 69.1(7) . . ?
C25 C26 Eu1 101.6(6) . . ?
C8 C26 Eu1 66.4(8) . . ?
Eu3 C26 Eu1 14.49(15) . . ?
C27 C26 Eu1 81.8(7) . 6 ?
C25 C26 Eu1 97.5(6) . 6 ?
C8 C26 Eu1 58.1(8) . 6 ?
Eu3 C26 Eu1 14.49(15) . 6 ?
Eu1 C26 Eu1 12.97(12) . 6 ?
C49 C48 C47 114.5(13) . . ?
C49 C48 C70 125.6(10) . . ?
C47 C48 C70 108.3(14) . . ?
C69 C81 C82 113.7(13) . . ?
C69 C81 C80 129.4(11) . . ?
C82 C81 C80 110.4(12) . . ?
C9 C1 C5 127.8(17) . . ?
C9 C1 C2 113.0(15) . . ?
C5 C1 C2 110.0(12) . . ?
C9 C1 Eu1 74.9(10) . . ?
C5 C1 Eu1 91.5(10) . . ?
C2 C1 Eu1 72.7(10) . . ?
C9 C1 Eu3 60.8(10) . . ?
C5 C1 Eu3 90.8(11) . . ?
C2 C1 Eu3 91.1(11) . . ?
Eu1 C1 Eu3 19.40(15) . . ?
C3 C2 C1 106.8(11) . . ?
C3 C2 C12 109.0(15) . . ?
C1 C2 C12 135.1(19) . . ?
C3 C2 Eu1 95.6(9) . . ?
C1 C2 Eu1 76.2(10) . . ?
C12 C2 Eu1 74.4(10) . . ?
C5 C4 C3 112.0(12) . . ?
C5 C4 C18 110.0(15) . . ?
C3 C4 C18 125.3(15) . . ?
C1 C5 C4 105.3(13) . . ?
C1 C5 C6 121.7(17) . . ?
C4 C5 C6 122.2(16) . . ?
C1 C5 Eu1 61.6(9) . . ?
C4 C5 Eu1 87.8(10) . . ?
C6 C5 Eu1 86.9(12) . . ?
C7 C6 C20 125.6(16) . . ?
C7 C6 C5 108.8(16) . . ?
C20 C6 C5 116.9(18) . . ?
C7 C6 Eu3 58.4(10) . . ?
C20 C6 Eu3 100.6(11) . . ?
C5 C6 Eu3 81.1(12) . . ?
C6 C7 C23 113.2(17) . . ?
C6 C7 C8 122(2) . . ?
C23 C7 C8 120(2) . . ?
C6 C7 Eu3 94.7(12) . . ?
C23 C7 Eu3 88.9(11) . . ?
C8 C7 Eu3 65.1(9) . . ?
C6 C7 Eu1 80.3(11) . . ?
C23 C7 Eu1 103.1(10) . . ?
C8 C7 Eu1 66.2(9) . . ?
Eu3 C7 Eu1 17.22(14) . . ?
C9 C8 C7 122(2) . . ?
C9 C8 C26 105.3(18) . . ?
C7 C8 C26 121(2) . . ?
C9 C8 Eu3 80.3(10) . . ?
C7 C8 Eu3 82.7(10) . . ?
C26 C8 Eu3 71.6(8) . . ?
C9 C8 Eu1 62.7(9) . . ?
C7 C8 Eu1 86.7(10) . . ?
C26 C8 Eu1 85.0(9) . . ?
Eu3 C8 Eu1 19.22(19) . . ?
C9 C10 C11 128.9(19) . . ?
C9 C10 C27 104.7(17) . . ?
C11 C10 C27 116.7(16) . . ?
C9 C10 Eu1 76.1(8) . . ?
C11 C10 Eu1 74.7(11) . . ?
C27 C10 Eu1 91.0(7) . . ?
C9 C10 Eu3 74.0(8) . . ?
C11 C10 Eu3 92.2(11) . . ?
C27 C10 Eu3 70.6(7) . . ?
Eu1 C10 Eu3 22.28(14) . . ?
C30 C11 C10 121.9(18) . . ?
C30 C11 C12 115.0(17) . . ?
C10 C11 C12 114.5(19) . . ?
C30 C11 Eu1 92.7(12) . . ?
C10 C11 Eu1 74.0(10) . . ?
C12 C11 Eu1 73.6(11) . . ?
C30 C11 Eu3 89.8(11) . . ?
C10 C11 Eu3 60.5(9) . . ?
C12 C11 Eu3 91.5(12) . . ?
Eu1 C11 Eu3 18.61(17) . . ?
C13 C12 C2 128(2) . . ?
C13 C12 C11 119(2) . . ?
C2 C12 C11 106.0(18) . . ?
C13 C12 Eu1 96.3(10) . . ?
C2 C12 Eu1 74.2(10) . . ?
C11 C12 Eu1 72.2(11) . . ?
C12 C13 C14 116(2) . . ?
C12 C13 C32 126(2) . . ?
C14 C13 C32 109.5(14) . . ?
C12 C13 Eu1 59.9(9) . . ?
C14 C13 Eu1 92.6(9) . . ?
C32 C13 Eu1 92.3(8) . . ?
C15 C14 C13 120.9(19) . . ?
C15 C14 C35 96.8(19) . . ?
C13 C14 C35 134(2) . . ?
C3 C15 C14 116.1(17) . . ?
C3 C15 C16 125.7(15) . . ?
C14 C15 C16 110.0(19) . . ?
C17 C16 C36 122.9(16) . . ?
C17 C16 C15 114.9(17) . . ?
C36 C16 C15 112.1(15) . . ?
C18 C17 C16 125.5(18) . . ?
C18 C17 C39 108.8(12) . . ?
C16 C17 C39 115.4(16) . . ?
C19 C18 C17 105.2(12) . . ?
C19 C18 C4 132.9(18) . . ?
C17 C18 C4 113.3(16) . . ?
C18 C19 C20 115.0(15) . . ?
C18 C19 C40 112.0(11) . . ?
C20 C19 C40 127.2(14) . . ?
C19 C20 C6 122.4(16) . . ?
C19 C20 C21 110.1(11) . . ?
C6 C20 C21 119.4(13) . . ?
C22 C21 C42 116.1(15) . . ?
C22 C21 C20 112.9(14) . . ?
C42 C21 C20 127.2(13) . . ?
C22 C21 Eu2 88.8(9) . . ?
C42 C21 Eu2 65.3(10) . . ?
C20 C21 Eu2 98.1(8) . . ?
C21 C22 C23 124.7(16) . . ?
C21 C22 C45 123.9(16) . . ?
C23 C22 C45 96.1(14) . . ?
C21 C22 Eu2 65.1(8) . . ?
C23 C22 Eu2 97.5(9) . . ?
C45 C22 Eu2 73.7(9) . . ?
C24 C23 C7 110.4(19) . . ?
C24 C23 C22 120.4(17) . . ?
C7 C23 C22 121.8(18) . . ?
C24 C23 Eu3 74.7(11) . . ?
C7 C23 Eu3 62.7(9) . . ?
C22 C23 Eu3 104.5(9) . . ?
C46 C24 C23 99(2) . . ?
C46 C24 C25 116(2) . . ?
C23 C24 C25 133(2) . . ?
C46 C24 Eu3 103.4(11) . . ?
C23 C24 Eu3 78.0(11) . . ?
C25 C24 Eu3 65.4(8) . . ?
C26 C25 C49 123.3(12) . . ?
C26 C25 C24 110.4(17) . . ?
C49 C25 C24 118.8(16) . . ?
C26 C25 Eu3 63.8(7) . . ?
C49 C25 Eu3 93.8(7) . . ?
C24 C25 Eu3 84.5(9) . . ?
C26 C27 C28 123.8(15) . . ?
C26 C27 C10 110.6(16) . . ?
C28 C27 C10 117.2(13) . . ?
C26 C27 Eu3 71.3(6) . . ?
C28 C27 Eu3 92.5(7) . . ?
C10 C27 Eu3 76.5(7) . . ?
C26 C27 Eu1 86.6(7) . . ?
C28 C27 Eu1 93.2(7) . . ?
C10 C27 Eu1 59.4(6) . . ?
Eu3 C27 Eu1 19.01(13) . . ?
C27 C28 C29 123.0(16) . . ?
C27 C28 C50 114.0(15) . . ?
C29 C28 C50 113.3(16) . . ?
C27 C28 Eu3 59.9(6) . . ?
C29 C28 Eu3 93.0(8) . . ?
C50 C28 Eu3 87.2(9) . . ?
C30 C29 C28 118.3(17) . . ?
C30 C29 C52 130.3(17) . . ?
C28 C29 C52 101.2(15) . . ?
C29 C30 C11 122.8(17) . . ?
C29 C30 C31 103.4(16) . . ?
C11 C30 C31 128.6(17) . . ?
C29 C30 Eu1 96.0(9) . . ?
C11 C30 Eu1 59.7(10) . . ?
C31 C30 Eu1 97.2(8) . . ?
C32 C31 C54 110.0(12) . . ?
C32 C31 C30 110.5(15) . . ?
C54 C31 C30 125.7(16) . . ?
C31 C32 C33 111.0(12) . . ?
C31 C32 C13 120.2(15) . . ?
C33 C32 C13 121.7(15) . . ?
C32 C33 C55 105.3(11) . . ?
C32 C33 C34 120.8(16) . . ?
C55 C33 C34 127.0(17) . . ?
C58 C34 C35 113.8(19) . . ?
C58 C34 C33 110.9(17) . . ?
C35 C34 C33 121.9(17) . . ?
C36 C35 C34 116(2) . . ?
C36 C35 C14 124(2) . . ?
C34 C35 C14 111.3(17) . . ?
C35 C36 C37 131.8(18) . . ?
C35 C36 C16 96.4(17) . . ?
C37 C36 C16 121.5(15) . . ?
C36 C37 C38 113.8(14) . . ?
C36 C37 C59 119.3(13) . . ?
C38 C37 C59 117.5(15) . . ?
C39 C38 C37 123.5(16) . . ?
C39 C38 C62 113.8(15) . . ?
C37 C38 C62 114.4(15) . . ?
C40 C39 C17 110.3(11) . . ?
C40 C39 C38 121.2(15) . . ?
C17 C39 C38 122.6(16) . . ?
C39 C40 C19 103.5(11) . . ?
C39 C40 C41 118.1(14) . . ?
C19 C40 C41 128.6(14) . . ?
C63 C41 C40 125.4(17) . . ?
C63 C41 C42 117.7(16) . . ?
C40 C41 C42 109.2(13) . . ?
C63 C41 Eu2 80.9(9) . . ?
C40 C41 Eu2 95.1(9) . . ?
C42 C41 Eu2 65.7(10) . . ?
C43 C42 C21 116.0(17) . . ?
C43 C42 C41 116.3(17) . . ?
C21 C42 C41 116.8(14) . . ?
C43 C42 Eu2 72.6(12) . . ?
C21 C42 Eu2 83.1(11) . . ?
C41 C42 Eu2 80.9(10) . . ?
C42 C43 C65 120.9(18) . . ?
C42 C43 C44 130.4(18) . . ?
C65 C43 C44 97.7(16) . . ?
C42 C43 Eu2 78.4(12) . . ?
C65 C43 Eu2 73.5(14) . . ?
C44 C43 Eu2 85.1(8) . . ?
C45 C44 C67 109.8(18) . . ?
C45 C44 C43 117.9(16) . . ?
C67 C44 C43 119(2) . . ?
C45 C44 Eu2 87.9(9) . . ?
C67 C44 Eu2 82.9(15) . . ?
C43 C44 Eu2 64.6(7) . . ?
C44 C45 C46 129.7(18) . . ?
C44 C45 C22 114.3(17) . . ?
C46 C45 C22 107.5(18) . . ?
C44 C45 Eu2 65.4(9) . . ?
C46 C45 Eu2 98.9(11) . . ?
C22 C45 Eu2 78.0(9) . . ?
C24 C46 C47 123(2) . . ?
C24 C46 C45 117(2) . . ?
C47 C46 C45 112(2) . . ?
C46 C47 C48 124.1(18) . . ?
C46 C47 C68 116.6(18) . . ?
C48 C47 C68 107.2(15) . . ?
C50 C49 C48 114.9(18) . . ?
C50 C49 C25 114.4(19) . . ?
C48 C49 C25 123.6(12) . . ?
C50 C49 Eu3 80.2(10) . . ?
C48 C49 Eu3 104.2(7) . . ?
C25 C49 Eu3 60.0(7) . . ?
C49 C50 C51 117(2) . . ?
C49 C50 C28 123(2) . . ?
C51 C50 C28 111.3(18) . . ?
C71 C51 C50 126(2) . . ?
C71 C51 C52 116(2) . . ?
C50 C51 C52 106(2) . . ?
C53 C52 C51 126(2) . . ?
C53 C52 C29 116(2) . . ?
C51 C52 C29 108(2) . . ?
C52 C53 C54 117(2) . . ?
C52 C53 C73 120.8(19) . . ?
C54 C53 C73 111.5(14) . . ?
C31 C54 C53 125.6(16) . . ?
C31 C54 C55 105.5(11) . . ?
C53 C54 C55 122.3(15) . . ?
C56 C55 C33 116.1(16) . . ?
C56 C55 C54 128.0(16) . . ?
C33 C55 C54 108.1(11) . . ?
C55 C56 C57 116.9(17) . . ?
C55 C56 C74 111.4(16) . . ?
C57 C56 C74 118.5(17) . . ?
C58 C57 C56 134(2) . . ?
C58 C57 C77 104.8(15) . . ?
C56 C57 C77 115.3(17) . . ?
C57 C58 C34 114.9(16) . . ?
C57 C58 C59 108.8(19) . . ?
C34 C58 C59 126.0(17) . . ?
C60 C59 C37 130.4(14) . . ?
C60 C59 C58 106.2(15) . . ?
C37 C59 C58 112.6(15) . . ?
C59 C60 C77 112.9(16) . . ?
C59 C60 C61 112.1(14) . . ?
C77 C60 C61 127.7(15) . . ?
C60 C61 C79 112.7(14) . . ?
C60 C61 C62 124.3(17) . . ?
C79 C61 C62 112.7(12) . . ?
C63 C62 C61 104.6(12) . . ?
C63 C62 C38 123.6(16) . . ?
C61 C62 C38 120.1(16) . . ?
C41 C63 C62 117.6(17) . . ?
C41 C63 C64 127.7(17) . . ?
C62 C63 C64 106.8(12) . . ?
C41 C63 Eu2 75.9(10) . . ?
C62 C63 Eu2 100.4(10) . . ?
C64 C63 Eu2 69.9(7) . . ?
C79 C64 C65 123.1(15) . . ?
C79 C64 C63 112.5(12) . . ?
C65 C64 C63 115.0(16) . . ?
C79 C64 Eu2 92.3(10) . . ?
C65 C64 Eu2 66.5(13) . . ?
C63 C64 Eu2 81.1(8) . . ?
C64 C65 C43 121.6(18) . . ?
C64 C65 C66 115.5(17) . . ?
C43 C65 C66 115.9(17) . . ?
C64 C65 Eu2 83.7(13) . . ?
C43 C65 Eu2 75.0(13) . . ?
C66 C65 Eu2 85.1(14) . . ?
C80 C66 C65 121.6(16) . . ?
C80 C66 C67 122(2) . . ?
C65 C66 C67 106(2) . . ?
C80 C66 Eu2 89.9(9) . . ?
C65 C66 Eu2 64.2(13) . . ?
C67 C66 Eu2 82.7(17) . . ?
C68 C67 C44 130(3) . . ?
C68 C67 C66 124(3) . . ?
C44 C67 C66 100(2) . . ?
C68 C67 Eu2 104(2) . . ?
C44 C67 Eu2 69.0(15) . . ?
C66 C67 Eu2 68.4(15) . . ?
C67 C68 C69 123(3) . . ?
C67 C68 C47 121(3) . . ?
C69 C68 C47 104.8(17) . . ?
C81 C69 C68 114.1(17) . . ?
C81 C69 C70 123.6(17) . . ?
C68 C69 C70 111.4(18) . . ?
C71 C70 C69 125.4(18) . . ?
C71 C70 C48 118.6(18) . . ?
C69 C70 C48 108.3(15) . . ?
C70 C71 C51 117(2) . . ?
C70 C71 C72 119(2) . . ?
C51 C71 C72 116(2) . . ?
C73 C72 C71 127(3) . . ?
C73 C72 C82 107(2) . . ?
C71 C72 C82 111(2) . . ?
C72 C73 C74 115(2) . . ?
C72 C73 C53 113(2) . . ?
C74 C73 C53 124.2(17) . . ?
C56 C74 C75 124.0(16) . . ?
C56 C74 C73 122.6(17) . . ?
C75 C74 C73 100.8(14) . . ?
C74 C75 C76 120.1(16) . . ?
C74 C75 C82 116.7(14) . . ?
C76 C75 C82 119.0(17) . . ?
C78 C76 C77 125.5(17) . . ?
C78 C76 C75 113.0(14) . . ?
C77 C76 C75 113.9(16) . . ?
C60 C77 C76 116.1(15) . . ?
C60 C77 C57 107.2(15) . . ?
C76 C77 C57 126.6(16) . . ?
C76 C78 C80 133.3(13) . . ?
C76 C78 C79 111.8(14) . . ?
C80 C78 C79 112.5(12) . . ?
C76 C78 Eu2 107.1(13) . . ?
C80 C78 Eu2 73.4(8) . . ?
C79 C78 Eu2 72.5(9) . . ?
C64 C79 C61 102.9(11) . . ?
C64 C79 C78 121.0(13) . . ?
C61 C79 C78 125.2(14) . . ?
C64 C79 Eu2 61.9(8) . . ?
C61 C79 Eu2 95.2(12) . . ?
C78 C79 Eu2 80.1(9) . . ?
C66 C80 C78 124.4(15) . . ?
C66 C80 C81 107.6(13) . . ?
C78 C80 C81 119.3(11) . . ?
C66 C80 Eu2 64.3(8) . . ?
C78 C80 Eu2 81.5(9) . . ?
C81 C80 Eu2 96.6(7) . . ?
C81 C82 C75 124.4(15) . . ?
C81 C82 C72 126.9(16) . . ?
C75 C82 C72 99.8(19) . . ?
C97 N3 Ni 127.78(19) . . ?
C97 N3 Ni 127.78(19) 6 . ?
C95 N2 C88 104.3(3) . . ?
C95 N2 Ni 127.8(2) . . ?
C88 N2 Ni 127.9(2) . . ?
C86 N1 Ni 127.83(19) . . ?
C86 N1 Ni 127.83(19) 6 . ?
N1 Ni N3 177.86(17) . . ?
N1 Ni N2 89.99(8) . . ?
N3 Ni N2 89.97(8) . . ?
C85 C84 C83 112.1(3) . . ?
C85 C85 C86 106.65(18) 6 . ?
C85 C85 C84 128.70(19) 6 . ?
C86 C85 C84 124.5(3) . . ?
C87 C86 N1 125.1(3) . . ?
C87 C86 C85 123.7(3) . . ?
N1 C86 C85 111.3(3) . . ?
C86 C87 C88 124.3(3) . . ?
C87 C88 N2 124.8(3) . . ?
C87 C88 C89 123.8(3) . . ?
N2 C88 C89 111.4(3) . . ?
C92 C89 C88 106.7(3) . . ?
C92 C89 C90 129.4(3) . . ?
C88 C89 C90 123.9(3) . . ?
C89 C90 C91 113.1(4) . . ?
C89 C92 C95 106.5(3) . . ?
C89 C92 C93 129.2(3) . . ?
C95 C92 C93 124.2(3) . . ?
C92 C93 C94 113.0(3) . . ?
C96 C95 N2 125.2(3) . . ?
C96 C95 C92 123.6(3) . . ?
N2 C95 C92 111.2(3) . . ?
C95 C96 C97 124.0(3) . . ?
C96 C97 N3 125.1(3) . . ?
C96 C97 C98 123.6(3) . . ?
N3 C97 C98 111.2(3) . . ?
C98 C98 C97 106.6(2) 6 . ?
C98 C98 C99 129.0(2) 6 . ?
C97 C98 C99 124.3(3) . . ?
C98 C99 C100 113.3(3) . . ?
C103 C101 C102 124.0(11) 2_657 . ?
C103 C102 C101 115.9(13) . . ?
C101 C103 C102 119.5(13) 2_657 . ?
C109 C104 C105 118.9(7) . . ?
C106 C105 C104 120.5(6) . . ?
C107 C106 C105 120.1(6) . . ?
C106 C107 C108 119.6(6) . . ?
C109 C108 C107 120.5(7) . . ?
C108 C109 C104 120.4(6) . . ?
Eu1 Eu1 Eu3 69.06(18) 6 . ?
Eu1 Eu1 C10 111.6(5) 6 . ?
Eu3 Eu1 C10 82.5(5) . . ?
Eu1 Eu1 C11 138.9(5) 6 . ?
Eu3 Eu1 C11 106.6(5) . . ?
C10 Eu1 C11 31.3(4) . . ?
Eu1 Eu1 Eu2 114.07(7) 6 6 ?
Eu3 Eu1 Eu2 86.0(2) . 6 ?
C10 Eu1 Eu2 124.7(5) . 6 ?
C11 Eu1 Eu2 106.1(5) . 6 ?
Eu1 Eu1 C2 95.9(4) 6 . ?
Eu3 Eu1 C2 129.3(5) . . ?
C10 Eu1 C2 57.7(6) . . ?
C11 Eu1 C2 53.9(6) . . ?
Eu2 Eu1 C2 141.2(4) 6 . ?
Eu1 Eu1 C12 126.9(6) 6 . ?
Eu3 Eu1 C12 138.9(5) . . ?
C10 Eu1 C12 56.6(6) . . ?
C11 Eu1 C12 34.2(7) . . ?
Eu2 Eu1 C12 112.2(5) 6 . ?
C2 Eu1 C12 31.5(6) . . ?
Eu1 Eu1 C9 82.07(8) 6 . ?
Eu3 Eu1 C9 79.4(5) . . ?
C10 Eu1 C9 30.8(5) . . ?
C11 Eu1 C9 57.5(5) . . ?
Eu2 Eu1 C9 152.7(4) 6 . ?
C2 Eu1 C9 50.2(6) . . ?
C12 Eu1 C9 67.9(5) . . ?
Eu1 Eu1 C1 73.5(4) 6 . ?
Eu3 Eu1 C1 100.1(5) . . ?
C10 Eu1 C1 51.7(6) . . ?
C11 Eu1 C1 67.1(6) . . ?
Eu2 Eu1 C1 171.8(4) 6 . ?
C2 Eu1 C1 31.2(4) . . ?
C12 Eu1 C1 59.6(6) . . ?
C9 Eu1 C1 27.2(5) . . ?
Eu1 Eu1 C8 65.3(4) 6 . ?
Eu3 Eu1 C8 54.2(6) . . ?
C10 Eu1 C8 48.1(6) . . ?
C11 Eu1 C8 79.1(6) . . ?
Eu2 Eu1 C8 138.7(6) 6 . ?
C2 Eu1 C8 75.3(7) . . ?
C12 Eu1 C8 95.1(7) . . ?
C9 Eu1 C8 27.3(6) . . ?
C1 Eu1 C8 46.3(7) . . ?
Eu1 Eu1 Eu2 53.08(7) 6 . ?
Eu3 Eu1 Eu2 66.19(19) . . ?
C10 Eu1 Eu2 148.2(5) . . ?
C11 Eu1 Eu2 164.7(5) . . ?
Eu2 Eu1 Eu2 60.99(9) 6 . ?
C2 Eu1 Eu2 141.3(4) . . ?
C12 Eu1 Eu2 154.9(5) . . ?
C9 Eu1 Eu2 130.2(2) . . ?
C1 Eu1 Eu2 126.4(4) . . ?
C8 Eu1 Eu2 104.9(5) . . ?
Eu1 Eu1 C30 161.9(3) 6 . ?
Eu3 Eu1 C30 100.7(4) . . ?
C10 Eu1 C30 51.1(5) . . ?
C11 Eu1 C30 27.6(4) . . ?
Eu2 Eu1 C30 78.9(4) 6 . ?
C2 Eu1 C30 78.9(5) . . ?
C12 Eu1 C30 51.6(7) . . ?
C9 Eu1 C30 81.4(4) . . ?
C1 Eu1 C30 94.6(5) . . ?
C8 Eu1 C30 96.6(6) . . ?
Eu2 Eu1 C30 137.8(4) . . ?
C65 Eu2 C43 31.5(5) . . ?
C65 Eu2 C42 53.7(7) . . ?
C43 Eu2 C42 29.0(4) . . ?
C65 Eu2 Eu1 164.7(5) . 6 ?
C43 Eu2 Eu1 133.5(4) . 6 ?
C42 Eu2 Eu1 111.6(5) . 6 ?
C65 Eu2 C64 29.8(4) . . ?
C43 Eu2 C64 53.8(5) . . ?
C42 Eu2 C64 62.2(6) . . ?
Eu1 Eu2 C64 152.8(3) 6 . ?
C65 Eu2 Eu3 158.2(5) . . ?
C43 Eu2 Eu3 133.6(4) . . ?
C42 Eu2 Eu3 122.3(5) . . ?
Eu1 Eu2 Eu3 21.75(8) 6 . ?
C64 Eu2 Eu3 171.8(4) . . ?
C65 Eu2 C66 30.7(4) . . ?
C43 Eu2 C66 52.7(5) . . ?
C42 Eu2 C66 80.6(6) . . ?
Eu1 Eu2 C66 156.3(4) 6 . ?
C64 Eu2 C66 50.8(5) . . ?
Eu3 Eu2 C66 134.7(4) . . ?
C65 Eu2 C44 46.1(6) . . ?
C43 Eu2 C44 30.3(4) . . ?
C42 Eu2 C44 53.9(5) . . ?
Eu1 Eu2 C44 124.1(3) 6 . ?
C64 Eu2 C44 75.6(5) . . ?
Eu3 Eu2 C44 112.6(3) . . ?
C66 Eu2 C44 46.2(5) . . ?
C65 Eu2 C41 60.6(6) . . ?
C43 Eu2 C41 53.8(5) . . ?
C42 Eu2 C41 33.4(4) . . ?
Eu1 Eu2 C41 110.2(3) 6 . ?
C64 Eu2 C41 48.8(5) . . ?
Eu3 Eu2 C41 130.3(4) . . ?
C66 Eu2 C41 91.2(5) . . ?
C44 Eu2 C41 83.6(4) . . ?
C65 Eu2 C21 82.2(6) . . ?
C43 Eu2 C21 51.8(6) . . ?
C42 Eu2 C21 31.5(4) . . ?
Eu1 Eu2 C21 82.6(4) 6 . ?
C64 Eu2 C21 93.6(5) . . ?
Eu3 Eu2 C21 90.7(4) . . ?
C66 Eu2 C21 102.8(5) . . ?
C44 Eu2 C21 61.3(5) . . ?
C41 Eu2 C21 55.0(5) . . ?
C65 Eu2 Eu2 129.2(5) . 6 ?
C43 Eu2 Eu2 157.4(4) . 6 ?
C42 Eu2 Eu2 171.5(4) . 6 ?
Eu1 Eu2 Eu2 65.93(7) 6 6 ?
C64 Eu2 Eu2 116.0(3) . 6 ?
Eu3 Eu2 Eu2 58.52(5) . 6 ?
C66 Eu2 Eu2 104.8(3) . 6 ?
C44 Eu2 Eu2 134.4(3) . 6 ?
C41 Eu2 Eu2 138.7(4) . 6 ?
C21 Eu2 Eu2 148.3(4) . 6 ?
C65 Eu2 C63 50.9(5) . . ?
C43 Eu2 C63 59.1(5) . . ?
C42 Eu2 C63 50.3(6) . . ?
Eu1 Eu2 C63 125.4(3) 6 . ?
C64 Eu2 C63 28.9(3) . . ?
Eu3 Eu2 C63 147.1(3) . . ?
C66 Eu2 C63 78.2(5) . . ?
C44 Eu2 C63 88.4(5) . . ?
C41 Eu2 C63 23.2(5) . . ?
C21 Eu2 C63 77.1(5) . . ?
Eu2 Eu2 C63 123.8(4) 6 . ?
Eu1 Eu3 Eu1 41.9(4) 6 . ?
Eu1 Eu3 C26 127.7(5) 6 . ?
Eu1 Eu3 C26 127.6(5) . . ?
Eu1 Eu3 C8 92.1(7) 6 . ?
Eu1 Eu3 C8 106.6(7) . . ?
C26 Eu3 C8 36.0(7) . . ?
Eu1 Eu3 C27 127.6(5) 6 . ?
Eu1 Eu3 C27 105.3(4) . . ?
C26 Eu3 C27 30.2(3) . . ?
C8 Eu3 C27 53.8(6) . . ?
Eu1 Eu3 C9 78.4(5) 6 . ?
Eu1 Eu3 C9 78.3(5) . . ?
C26 Eu3 C9 53.3(6) . . ?
C8 Eu3 C9 30.4(6) . . ?
C27 Eu3 C9 51.7(5) . . ?
Eu1 Eu3 C10 95.6(5) 6 . ?
Eu1 Eu3 C10 75.2(5) . . ?
C26 Eu3 C10 53.2(5) . . ?
C8 Eu3 C10 52.4(6) . . ?
C27 Eu3 C10 32.9(4) . . ?
C9 Eu3 C10 30.4(5) . . ?
Eu1 Eu3 Eu2 93.9(2) 6 6 ?
Eu1 Eu3 Eu2 72.3(2) . 6 ?
C26 Eu3 Eu2 136.1(3) . 6 ?
C8 Eu3 Eu2 168.8(5) . 6 ?
C27 Eu3 Eu2 115.3(3) . 6 ?
C9 Eu3 Eu2 142.8(3) . 6 ?
C10 Eu3 Eu2 117.4(4) . 6 ?
Eu1 Eu3 Eu2 72.3(2) 6 . ?
Eu1 Eu3 Eu2 93.9(2) . . ?
C26 Eu3 Eu2 136.1(3) . . ?
C8 Eu3 Eu2 128.1(5) . . ?
C27 Eu3 Eu2 159.3(4) . . ?
C9 Eu3 Eu2 142.8(3) . . ?
C10 Eu3 Eu2 167.7(5) . . ?
Eu2 Eu3 Eu2 62.96(10) 6 . ?
Eu1 Eu3 C7 76.9(5) 6 . ?
Eu1 Eu3 C7 109.9(5) . . ?
C26 Eu3 C7 60.1(5) . . ?
C8 Eu3 C7 32.2(6) . . ?
C27 Eu3 C7 84.8(6) . . ?
C9 Eu3 C7 54.6(4) . . ?
C10 Eu3 C7 82.7(7) . . ?
Eu2 Eu3 C7 159.0(4) 6 . ?
Eu2 Eu3 C7 96.1(4) . . ?
Eu1 Eu3 C25 143.6(4) 6 . ?
Eu1 Eu3 C25 156.0(5) . . ?
C26 Eu3 C25 28.9(5) . . ?
C8 Eu3 C25 57.0(8) . . ?
C27 Eu3 C25 51.5(5) . . ?
C9 Eu3 C25 81.1(7) . . ?
C10 Eu3 C25 80.8(6) . . ?
Eu2 Eu3 C25 120.0(5) 6 . ?
Eu2 Eu3 C25 110.0(4) . . ?
C7 Eu3 C25 66.7(6) . . ?
Eu1 Eu3 C28 142.3(5) 6 . ?
Eu1 Eu3 C28 104.8(4) . . ?
C26 Eu3 C28 50.8(3) . . ?
C8 Eu3 C28 80.9(6) . . ?
C27 Eu3 C28 27.6(4) . . ?
C9 Eu3 C28 77.2(5) . . ?
C10 Eu3 C28 51.1(6) . . ?
Eu2 Eu3 C28 88.6(3) 6 . ?
Eu2 Eu3 C28 139.4(4) . . ?
C7 Eu3 C28 110.3(5) . . ?
C25 Eu3 C28 58.1(4) . . ?

_refine_diff_density_max         1.480
_refine_diff_density_min         -1.612
_refine_diff_density_rms         0.128

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_lb160
_database_code_depnum_ccdc_archive 'CCDC 1851767'
loop_
_audit_author_name
_audit_author_address
'Lipiao Bao'
;Huazhong University of Science and Technology
China
;
_audit_update_record             
;
2018-06-26 deposited with the CCDC.	2019-04-26 downloaded from the CCDC.
;

_vrf_PLAT308_lb160               
;
PROBLEM: Single Bonded Metal Atom in Structure (Unusual) Eu1 Check
RESPONSE: This is an endohedral Eu atom.
;


_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        'Eu@C2(13)-C80 Ni(OEP)'
_chemical_name_common            'Eu@C2(13)-C80 Ni(OEP)'
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu C84, C36 H44 N4 Ni, 1.61(C6 H6) 0.39(C S2)'
_chemical_formula_sum            'C130.05 H53.66 Eu N4 Ni S0.78'
_chemical_formula_weight         1907.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0027 0.0014 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0053 0.0028 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1098 0.1057 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3436 0.9622 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1666 3.2045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 2/m'
_space_group_name_Hall           '-C 2y'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   25.3346(8)
_cell_length_b                   15.1339(5)
_cell_length_c                   19.9751(6)
_cell_angle_alpha                90
_cell_angle_beta                 95.6590(10)
_cell_angle_gamma                90
_cell_volume                     7621.4(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9616
_cell_measurement_theta_min      2.429
_cell_measurement_theta_max      25.493

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_F_000             3862
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.310
_exptl_crystal_size_mid          0.270
_exptl_crystal_size_min          0.240
_exptl_absorpt_coefficient_mu    0.915
_shelx_estimated_absorpt_T_min   0.765
_shelx_estimated_absorpt_T_max   0.810
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6747
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   SADABS
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.6525
_diffrn_radiation_type           synchrotron
_diffrn_source                   'SSRF, Beamline B17B1'
_diffrn_measurement_device_type  'CCD MX-300'
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            66126
_diffrn_reflns_av_unetI/netI     0.0383
_diffrn_reflns_av_R_equivalents  0.0803
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.940
_diffrn_reflns_theta_max         25.501
_diffrn_reflns_theta_full        23.048
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             9504
_reflns_number_gt                8497
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1050P)²+52.2432P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9504
_refine_ls_number_parameters     1043
_refine_ls_number_restraints     734
_refine_ls_R_factor_all          0.0945
_refine_ls_R_factor_gt           0.0871
_refine_ls_wR_factor_ref         0.2284
_refine_ls_wR_factor_gt          0.2217
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.023
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3078(7) 0.5000 0.5185(4) 0.101(4) Uani 1 2 d S TU P . .
C20 C 0.4393(4) 0.5000 0.4563(5) 0.082(3) Uani 1 2 d S TU P . .
C33 C 0.2543(6) 0.5000 0.0975(5) 0.106(4) Uani 1 2 d DS TU P . .
C48 C 0.3027(4) 0.2259(5) 0.3297(5) 0.097(2) Uani 1 1 d . U . . .
C56 C 0.1749(4) 0.6640(6) 0.3112(5) 0.098(2) Uani 1 1 d . U . . .
C84 C 0.3121(4) 0.5000 0.1025(4) 0.069(2) Uani 1 2 d S TU P A .
C2 C 0.2629(10) 0.5568(18) 0.5021(8) 0.100(5) Uani 0.5 1 d . U P A -1
C3 C 0.3004(8) 0.6446(18) 0.4853(9) 0.080(5) Uani 0.5 1 d . U P A -1
C4 C 0.3514(10) 0.6169(12) 0.4931(7) 0.067(4) Uani 0.5 1 d . U P A -1
C5 C 0.3593(6) 0.5261(7) 0.5122(4) 0.068(3) Uani 0.5 1 d . U P A -1
C6 C 0.4013(6) 0.4710(8) 0.4906(5) 0.066(3) Uani 0.5 1 d . U P A -1
C7 C 0.3843(10) 0.3770(11) 0.4797(7) 0.070(4) Uani 0.5 1 d . U P A -1
C8 C 0.3290(10) 0.3490(11) 0.4851(7) 0.058(4) Uani 0.5 1 d . U P A -1
C9 C 0.2893(10) 0.4151(10) 0.5044(8) 0.082(5) Uani 0.5 1 d . U P A -1
C10 C 0.2362(10) 0.3962(16) 0.4777(11) 0.092(6) Uani 0.5 1 d . U P A -1
C11 C 0.1945(10) 0.4723(14) 0.4574(13) 0.113(7) Uani 0.5 1 d . U P A -1
C12 C 0.2209(11) 0.5604(19) 0.4745(11) 0.099(6) Uani 0.5 1 d . U P A -1
C13 C 0.1923(10) 0.6217(15) 0.4225(12) 0.102(5) Uani 0.5 1 d . U P A -1
C14 C 0.2232(9) 0.6908(13) 0.4070(13) 0.075(5) Uani 0.5 1 d . U P A -1
C15 C 0.2815(8) 0.7042(13) 0.4383(11) 0.070(4) Uani 0.5 1 d . U P A -1
C16 C 0.3152(7) 0.7420(9) 0.3999(10) 0.062(4) Uani 0.5 1 d . U P A -1
C17 C 0.3731(8) 0.7222(14) 0.4043(11) 0.062(4) Uani 0.5 1 d . U P A -1
C18 C 0.3904(7) 0.6531(12) 0.4535(10) 0.064(4) Uani 0.5 1 d . U P A -1
C19 C 0.4347(5) 0.5965(9) 0.4349(8) 0.072(3) Uani 0.5 1 d . U P A -1
C21 C 0.4622(4) 0.4564(10) 0.4057(6) 0.067(3) Uani 0.5 1 d . U P A -1
C22 C 0.4517(7) 0.3710(12) 0.3948(9) 0.070(4) Uani 0.5 1 d . U P A -1
C23 C 0.4139(7) 0.3303(11) 0.4350(7) 0.068(4) Uani 0.5 1 d . U P A -1
C24 C 0.3910(8) 0.2628(13) 0.3945(9) 0.066(4) Uani 0.5 1 d . U P A -1
C25 C 0.3383(9) 0.2366(10) 0.3970(8) 0.071(4) Uani 0.5 1 d . U P A -1
C26 C 0.3071(9) 0.2780(12) 0.4434(8) 0.077(4) Uani 0.5 1 d . U P A -1
C27 C 0.2494(13) 0.2760(13) 0.4128(11) 0.095(5) Uani 0.5 1 d . U P A -1
C28 C 0.2239(10) 0.3362(17) 0.4357(11) 0.101(6) Uani 0.5 1 d D U P A -1
C29 C 0.1780(8) 0.3648(14) 0.3778(10) 0.092(6) Uani 0.5 1 d D U P A -1
C30 C 0.1637(7) 0.4461(15) 0.3999(12) 0.099(5) Uani 0.5 1 d . U P A -1
C31 C 0.1444(6) 0.514(2) 0.3469(10) 0.108(7) Uani 0.5 1 d . U P A -1
C32 C 0.1541(7) 0.5956(15) 0.3573(14) 0.099(5) Uani 0.5 1 d . U P A -1
C34 C 0.2175(5) 0.7233(6) 0.3411(6) 0.054(2) Uani 0.5 1 d . U P A -1
C35 C 0.2493(7) 0.7521(8) 0.2983(8) 0.071(4) Uani 0.5 1 d . U P A -1
C37 C 0.3517(7) 0.7558(8) 0.2921(8) 0.069(3) Uani 0.5 1 d . U P A -1
C38 C 0.3936(7) 0.7275(12) 0.3400(9) 0.064(4) Uani 0.5 1 d . U P A -1
C39 C 0.4376(14) 0.6675(18) 0.3187(13) 0.053(5) Uani 0.5 1 d . U P A -1
C40 C 0.4550(6) 0.5999(11) 0.3713(9) 0.067(4) Uani 0.5 1 d . U P A -1
C41 C 0.4691(3) 0.5155(16) 0.3481(6) 0.069(5) Uani 0.5 1 d . U P A -1
C42 C 0.4590(3) 0.4842(16) 0.2849(5) 0.063(5) Uani 0.5 1 d . U P A -1
C43 C 0.4449(5) 0.3971(11) 0.2721(7) 0.057(3) Uani 0.5 1 d . U P A -1
C44 C 0.4409(17) 0.343(3) 0.3333(16) 0.075(8) Uani 0.5 1 d . U P A -1
C45 C 0.4127(7) 0.2695(16) 0.3275(10) 0.071(5) Uani 0.5 1 d . U P A -1
C46 C 0.3811(6) 0.2482(9) 0.2742(6) 0.060(3) Uani 0.5 1 d . U P A -1
C47 C 0.3230(7) 0.2183(9) 0.2781(6) 0.069(3) Uani 0.5 1 d . U P A -1
C49 C 0.2558(8) 0.2372(9) 0.3487(7) 0.078(4) Uani 0.5 1 d . U P A -1
C50 C 0.2124(8) 0.2769(10) 0.2868(8) 0.085(5) Uani 0.5 1 d . U P A -1
C52 C 0.1574(9) 0.3982(16) 0.2559(16) 0.095(6) Uani 0.5 1 d . U P A -1
C53 C 0.1391(5) 0.487(3) 0.2791(10) 0.099(6) Uani 0.5 1 d . U P A -1
C54 C 0.1448(5) 0.5566(14) 0.2297(8) 0.082(5) Uani 0.5 1 d . U P A -1
C55 C 0.1627(7) 0.6452(12) 0.2556(12) 0.074(4) Uani 0.5 1 d . U P A -1
C57 C 0.2019(8) 0.6805(13) 0.2039(9) 0.079(5) Uani 0.5 1 d . U P A -1
C58 C 0.2435(19) 0.729(3) 0.231(2) 0.079(8) Uani 0.5 1 d . U P A -1
C59 C 0.2928(8) 0.7169(12) 0.1906(10) 0.079(4) Uani 0.5 1 d . U P A -1
C60 C 0.3376(9) 0.7292(12) 0.2238(11) 0.110(5) Uani 0.5 1 d D U P A -1
C61 C 0.3855(7) 0.6779(13) 0.2021(8) 0.082(4) Uani 0.5 1 d D U P A -1
C62 C 0.4309(6) 0.6365(10) 0.2535(9) 0.065(4) Uani 0.5 1 d D U P A -1
C63 C 0.4387(4) 0.5516(8) 0.2329(6) 0.053(2) Uani 0.5 1 d . U P A -1
C64 C 0.4087(4) 0.5234(9) 0.1778(6) 0.063(4) Uani 0.5 1 d . U P A -1
C65 C 0.3866(6) 0.4386(12) 0.1634(5) 0.060(3) Uani 0.5 1 d . U P A -1
C66 C 0.4078(5) 0.3689(10) 0.2113(5) 0.063(3) Uani 0.5 1 d . U P A -1
C67 C 0.3757(7) 0.2928(9) 0.2161(7) 0.062(4) Uani 0.5 1 d . U P A -1
C68 C 0.3216(6) 0.2879(8) 0.1779(5) 0.048(2) Uani 0.5 1 d . U P A -1
C69 C 0.2892(5) 0.2445(7) 0.2236(6) 0.049(2) Uani 0.5 1 d . U P A -1
C70 C 0.2371(12) 0.272(2) 0.2223(16) 0.054(5) Uani 0.5 1 d . U P A -1
C71 C 0.2160(5) 0.3327(12) 0.1743(10) 0.058(3) Uani 0.5 1 d . U P A -1
C72 C 0.1731(5) 0.3898(11) 0.1942(9) 0.074(4) Uani 0.5 1 d . U P A -1
C73 C 0.1789(8) 0.4686(15) 0.1470(9) 0.090(6) Uani 0.5 1 d . U P A -1
C74 C 0.1639(9) 0.5416(18) 0.1719(11) 0.102(6) Uani 0.5 1 d . U P A -1
C75 C 0.1986(9) 0.6201(15) 0.1531(7) 0.087(4) Uani 0.5 1 d . U P A -1
C76 C 0.2412(12) 0.6034(12) 0.1167(10) 0.081(6) Uani 0.5 1 d D U P A -1
C77 C 0.2840(9) 0.6499(18) 0.1320(11) 0.068(5) Uani 0.5 1 d . U P A -1
C78 C 0.3317(13) 0.587(2) 0.1240(13) 0.079(4) Uani 0.5 1 d . U P A -1
C79 C 0.3754(7) 0.6008(12) 0.1510(8) 0.079(4) Uani 0.5 1 d D U P A -1
C80 C 0.3391(11) 0.4261(16) 0.1232(10) 0.069(6) Uani 0.5 1 d . U P A -1
C81 C 0.3028(6) 0.3514(14) 0.1379(12) 0.050(4) Uani 0.5 1 d . U P A -1
C82 C 0.2463(8) 0.3680(11) 0.1329(8) 0.053(3) Uani 0.5 1 d . U P A -1
C83 C 0.2228(6) 0.4587(13) 0.1138(7) 0.080(4) Uani 0.5 1 d . U P A -1
N1 N 0.42357(13) 0.5000 0.00914(17) 0.0167(6) Uani 1 2 d S T P B 2
Ni1 Ni 0.48181(2) 0.5000 0.08118(2) 0.01387(15) Uani 1 2 d S T P B 2
N2 N 0.48077(9) 0.36984(16) 0.08249(11) 0.0156(5) Uani 1 1 d . . . B 2
N3 N 0.53813(14) 0.5000 0.15572(17) 0.0174(7) Uani 1 2 d S T P B 2
C85 C 0.59428(16) 0.3527(3) 0.34273(17) 0.0351(8) Uani 1 1 d . . . B 2
H85A H 0.5652 0.3193 0.3186 0.053 Uiso 1 1 calc R U . B 2
H85B H 0.5796 0.4001 0.3687 0.053 Uiso 1 1 calc R U . B 2
H85C H 0.6157 0.3131 0.3733 0.053 Uiso 1 1 calc R U . B 2
C86 C 0.62901(13) 0.3927(2) 0.29232(17) 0.0291(7) Uani 1 1 d . . . B 2
H86A H 0.6589 0.4247 0.3172 0.035 Uiso 1 1 calc R U . B 2
H86B H 0.6441 0.3444 0.2668 0.035 Uiso 1 1 calc R U . B 2
C87 C 0.59943(12) 0.4549(2) 0.24386(15) 0.0222(6) Uani 1 1 d . . . B 2
C88 C 0.56171(11) 0.4280(2) 0.18849(14) 0.0189(6) Uani 1 1 d . . . B 2
C89 C 0.55033(11) 0.3413(2) 0.17337(15) 0.0195(5) Uani 1 1 d . . . B 2
H89 H 0.5704 0.2971 0.1982 0.023 Uiso 1 1 calc R U . B 2
C90 C 0.51156(11) 0.31414(19) 0.12427(14) 0.0182(5) Uani 1 1 d . . . B 2
C91 C 0.49785(12) 0.2226(2) 0.11160(16) 0.0228(6) Uani 1 1 d . . . B 2
C92 C 0.52227(14) 0.1461(2) 0.15063(19) 0.0317(7) Uani 1 1 d . . . B 2
H92A H 0.5612 0.1548 0.1576 0.038 Uiso 1 1 calc R U . B 2
H92B H 0.5155 0.0914 0.1239 0.038 Uiso 1 1 calc R U . B 2
C93 C 0.50082(18) 0.1344(3) 0.2190(2) 0.0435(10) Uani 1 1 d . . . B 2
H93A H 0.4623 0.1256 0.2125 0.065 Uiso 1 1 calc R U . B 2
H93B H 0.5088 0.1872 0.2465 0.065 Uiso 1 1 calc R U . B 2
H93C H 0.5175 0.0827 0.2419 0.065 Uiso 1 1 calc R U . B 2
C94 C 0.45808(12) 0.2227(2) 0.06045(16) 0.0221(6) Uani 1 1 d . . . B 2
C95 C 0.42789(13) 0.1463(2) 0.02798(19) 0.0281(7) Uani 1 1 d . . . B 2
H95A H 0.4492 0.0918 0.0361 0.034 Uiso 1 1 calc R U . B 2
H95B H 0.4227 0.1561 -0.0212 0.034 Uiso 1 1 calc R U . B 2
C96 C 0.37366(15) 0.1326(3) 0.0543(2) 0.0400(9) Uani 1 1 d . . . B 2
H96A H 0.3522 0.1862 0.0462 0.060 Uiso 1 1 calc R U . B 2
H96B H 0.3786 0.1204 0.1027 0.060 Uiso 1 1 calc R U . B 2
H96C H 0.3555 0.0826 0.0309 0.060 Uiso 1 1 calc R U . B 2
C97 C 0.44818(11) 0.31427(19) 0.04330(14) 0.0174(5) Uani 1 1 d . . . B 2
C98 C 0.40918(11) 0.34125(19) -0.00567(14) 0.0178(5) Uani 1 1 d . . . B 2
H98 H 0.3892 0.2970 -0.0305 0.021 Uiso 1 1 calc R U . B 2
C99 C 0.39748(11) 0.42841(19) -0.02070(14) 0.0162(5) Uani 1 1 d . . . B 2
C100 C 0.35452(11) 0.4554(2) -0.06929(14) 0.0186(6) Uani 1 1 d . . . B 2
C101 C 0.31573(12) 0.3932(2) -0.10673(15) 0.0231(6) Uani 1 1 d . . . B 2
H10A H 0.3350 0.3406 -0.1209 0.028 Uiso 1 1 calc R U . B 2
H10B H 0.2992 0.4229 -0.1478 0.028 Uiso 1 1 calc R U . B 2
C102 C 0.27227(14) 0.3639(3) -0.06364(18) 0.0338(8) Uani 1 1 d . . . B 2
H10C H 0.2534 0.4159 -0.0490 0.051 Uiso 1 1 calc R U . B 2
H10D H 0.2883 0.3318 -0.0241 0.051 Uiso 1 1 calc R U . B 2
H10E H 0.2472 0.3252 -0.0902 0.051 Uiso 1 1 calc R U . B 2
C103 C 0.2112(3) 0.5000 0.6647(3) 0.0509(16) Uani 1 2 d S T P C 2
H103 H 0.2361 0.5000 0.6321 0.061 Uiso 1 2 calc R U P C 2
C104 C 0.2273(3) 0.5000 0.7329(3) 0.0446(14) Uani 1 2 d S T P C 2
H104 H 0.2641 0.5000 0.7473 0.054 Uiso 1 2 calc R U P C 2
C105 C 0.1910(2) 0.5000 0.7812(3) 0.0410(13) Uani 1 2 d S T P C 2
H105 H 0.2031 0.5000 0.8277 0.049 Uiso 1 2 calc R U P C 2
C106 C 0.1382(3) 0.5000 0.7606(3) 0.0471(14) Uani 1 2 d S T P C 2
H106 H 0.1134 0.5000 0.7932 0.056 Uiso 1 2 calc R U P C 2
C107 C 0.1202(3) 0.5000 0.6935(5) 0.075(3) Uani 1 2 d S T P C 2
H107 H 0.0831 0.5000 0.6800 0.089 Uiso 1 2 calc R U P C 2
C108 C 0.1559(4) 0.5000 0.6459(4) 0.078(3) Uani 1 2 d S T P C 2
H108 H 0.1432 0.5000 0.5996 0.094 Uiso 1 2 calc R U P C 2
Eu1 Eu 0.2733(8) 0.5000 0.3848(7) 0.314(11) Uani 0.1172 2 d S T P A 3
Eu3 Eu 0.32904(6) 0.41344(8) 0.35909(6) 0.0449(3) Uani 0.1787 1 d . . P A 3
Eu4 Eu 0.3610(2) 0.4548(6) 0.3471(3) 0.110(3) Uani 0.0646 1 d . . P A 3
Eu5 Eu 0.33734(13) 0.41085(19) 0.2863(2) 0.0855(10) Uani 0.124 1 d . . P A 3
Eu6 Eu 0.3079(4) 0.4628(8) 0.2308(5) 0.063(2) Uiso 0.029 1 d . . P A 3
Eu7 Eu 0.3026(4) 0.3995(7) 0.2586(5) 0.092(3) Uani 0.0452 1 d . . P A 3
C109 C 0.0257(13) 0.372(2) 0.4423(14) 0.22(2) Uani 0.61 1 d D . P D 4
H109 H 0.0441 0.3543 0.4051 0.259 Uiso 0.61 1 calc R U P D 4
C110 C 0.0520(7) 0.392(3) 0.5052(17) 0.27(2) Uani 0.61 1 d D . P D 4
H110 H 0.0871 0.4154 0.5097 0.319 Uiso 0.61 1 calc R U P D 4
C111 C 0.0241(10) 0.3778(15) 0.5614(14) 0.187(12) Uani 0.61 1 d D . P D 4
H111 H 0.0436 0.3722 0.6043 0.224 Uiso 0.61 1 calc R U P D 4
S1 S 0.0321(5) 0.3429(12) 0.4407(5) 0.186(7) Uani 0.39 1 d D . P E 5
C112 C 0.0000 0.332(2) 0.5000 0.083(8) Uani 0.39 2 d DS T P E 5


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C5 1.381(19) . ?
C1 C9 1.386(19) . ?
C1 C2 1.44(3) . ?
C1 Eu1 2.727(19) . ?
C20 C6 1.312(16) . ?
C20 C21 1.382(16) . ?
C20 C19 1.523(15) . ?
C20 Eu4 2.882(11) 6_565 ?
C20 Eu4 2.882(11) . ?
C33 C83 1.088(17) . ?
C33 C84 1.456(17) . ?
C33 C76 1.653(15) . ?
C33 Eu6 2.921(15) . ?
C33 Eu6 2.921(15) 6_565 ?
C48 C47 1.203(15) . ?
C48 C49 1.293(18) . ?
C48 C25 1.55(2) . ?
C48 Eu3 2.961(7) . ?
C48 Eu7 2.988(15) . ?
C48 Eu5 3.083(9) . ?
C56 C55 1.16(2) . ?
C56 C34 1.483(17) . ?
C56 C32 1.51(2) . ?
C84 C80 1.35(2) . ?
C84 C78 1.46(3) . ?
C84 Eu6 2.636(13) . ?
C84 Eu6 2.636(13) 6_565 ?
C2 C12 1.15(3) . ?
C2 C3 1.69(4) . ?
C3 C4 1.35(3) . ?
C3 C15 1.35(3) . ?
C4 C18 1.43(3) . ?
C4 C5 1.44(2) . ?
C5 C6 1.451(16) . ?
C6 C7 1.50(2) . ?
C7 C23 1.41(2) . ?
C7 C8 1.48(3) . ?
C8 C26 1.44(3) . ?
C8 C9 1.50(2) . ?
C9 C10 1.43(3) . ?
C10 C28 1.25(3) . ?
C10 C11 1.59(3) . ?
C11 C30 1.38(3) . ?
C11 C12 1.52(3) . ?
C12 C13 1.52(3) . ?
C13 C14 1.36(3) . ?
C13 C32 1.59(4) . ?
C14 C34 1.40(3) . ?
C14 C15 1.56(3) . ?
C15 C16 1.33(3) . ?
C16 C17 1.49(3) . ?
C17 C38 1.43(2) . ?
C17 C18 1.47(3) . ?
C18 C19 1.49(2) . ?
C19 C40 1.42(2) . ?
C21 C22 1.33(2) . ?
C21 C41 1.48(2) . ?
C22 C44 1.30(3) . ?
C22 C23 1.45(3) . ?
C23 C24 1.39(3) . ?
C24 C25 1.40(3) . ?
C24 C45 1.50(3) . ?
C25 C26 1.42(2) . ?
C26 C27 1.53(3) . ?
C27 C28 1.23(3) . ?
C27 C49 1.43(2) . ?
C28 C29 1.615(18) . ?
C29 C30 1.37(3) . ?
C30 C31 1.52(3) . ?
C31 C32 1.27(4) . ?
C31 C53 1.41(3) . ?
C34 C35 1.31(2) . ?
C35 C58 1.39(4) . ?
C37 C38 1.42(3) . ?
C37 C60 1.43(3) . ?
C38 C39 1.53(4) . ?
C39 C62 1.38(3) . ?
C39 C40 1.50(3) . ?
C40 C41 1.42(3) . ?
C41 C42 1.349(19) . ?
C42 C43 1.38(3) . ?
C42 C63 1.51(2) . ?
C43 C44 1.49(4) . ?
C43 C66 1.522(18) . ?
C44 C45 1.32(5) . ?
C45 C46 1.31(2) . ?
C46 C67 1.338(18) . ?
C46 C47 1.55(2) . ?
C47 C69 1.375(18) . ?
C49 C50 1.68(3) . ?
C50 C70 1.49(3) . ?
C52 C72 1.34(3) . ?
C52 C53 1.52(4) . ?
C53 C54 1.46(3) . ?
C54 C74 1.31(3) . ?
C54 C55 1.49(3) . ?
C55 C57 1.60(3) . ?
C57 C58 1.35(6) . ?
C57 C75 1.36(2) . ?
C58 C59 1.56(4) . ?
C59 C60 1.27(3) . ?
C59 C77 1.55(4) . ?
C60 C61 1.539(16) . ?
C61 C79 1.556(16) . ?
C61 C62 1.593(16) . ?
C62 C63 1.37(2) . ?
C63 C64 1.343(17) . ?
C64 C65 1.42(2) . ?
C64 C79 1.51(2) . ?
C65 C80 1.39(3) . ?
C65 C66 1.488(17) . ?
C66 C67 1.42(2) . ?
C67 C68 1.50(2) . ?
C68 C81 1.31(3) . ?
C68 C69 1.443(16) . ?
C69 C70 1.38(4) . ?
C70 C71 1.39(4) . ?
C71 C82 1.30(3) . ?
C71 C72 1.47(2) . ?
C72 C73 1.54(3) . ?
C73 C74 1.28(2) . ?
C73 C83 1.36(2) . ?
C74 C75 1.55(4) . ?
C75 C76 1.38(3) . ?
C76 C77 1.30(4) . ?
C77 C78 1.56(3) . ?
C78 C79 1.20(3) . ?
C80 C81 1.50(3) . ?
C81 C82 1.45(2) . ?
C82 C83 1.53(2) . ?
N1 C99 1.374(3) 6_565 ?
N1 C99 1.374(3) . ?
N1 Ni1 1.957(3) . ?
Ni1 N3 1.958(3) . ?
Ni1 N2 1.970(2) . ?
Ni1 N2 1.970(2) 6_565 ?
N2 C97 1.369(4) . ?
N2 C90 1.374(4) . ?
N3 C88 1.377(3) 6_565 ?
N3 C88 1.377(3) . ?
C85 C86 1.526(5) . ?
C85 H85A 0.9800 . ?
C85 H85B 0.9800 . ?
C85 H85C 0.9800 . ?
C86 C87 1.497(4) . ?
C86 H86A 0.9900 . ?
C86 H86B 0.9900 . ?
C87 C87 1.366(6) 6_565 ?
C87 C88 1.447(4) . ?
C88 C89 1.371(4) . ?
C89 C90 1.381(4) . ?
C89 H89 0.9500 . ?
C90 C91 1.444(4) . ?
C91 C94 1.362(4) . ?
C91 C92 1.496(4) . ?
C92 C93 1.530(6) . ?
C92 H92A 0.9900 . ?
C92 H92B 0.9900 . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
C94 C97 1.443(4) . ?
C94 C95 1.499(4) . ?
C95 C96 1.533(5) . ?
C95 H95A 0.9900 . ?
C95 H95B 0.9900 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C97 C98 1.382(4) . ?
C98 C99 1.379(4) . ?
C98 H98 0.9500 . ?
C99 C100 1.444(4) . ?
C100 C100 1.351(6) 6_565 ?
C100 C101 1.505(4) . ?
C101 C102 1.529(5) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C102 H10C 0.9800 . ?
C102 H10D 0.9800 . ?
C102 H10E 0.9800 . ?
C103 C104 1.383(9) . ?
C103 C108 1.414(12) . ?
C103 H103 0.9500 . ?
C104 C105 1.396(9) . ?
C104 H104 0.9500 . ?
C105 C106 1.360(9) . ?
C105 H105 0.9500 . ?
C106 C107 1.372(11) . ?
C106 H106 0.9500 . ?
C107 C108 1.377(13) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
Eu1 Eu3 2.029(12) 6_565 ?
Eu1 Eu3 2.029(12) . ?
Eu1 Eu4 2.509(16) . ?
Eu1 Eu4 2.509(16) 6_565 ?
Eu1 Eu5 2.992(7) 6_565 ?
Eu1 Eu5 2.992(7) . ?
Eu1 Eu7 3.097(9) 6_565 ?
Eu1 Eu7 3.097(9) . ?
Eu1 Eu6 3.329(13) 6_565 ?
Eu1 Eu6 3.329(13) . ?
Eu3 Eu4 1.068(8) . ?
Eu3 Eu5 1.489(4) . ?
Eu3 Eu7 2.064(10) . ?
Eu3 Eu4 2.174(9) 6_565 ?
Eu3 Eu3 2.620(2) 6_565 ?
Eu3 Eu6 2.672(11) . ?
Eu3 Eu5 3.047(3) 6_565 ?
Eu3 Eu6 3.177(11) 6_565 ?
Eu3 Eu7 3.497(7) 6_565 ?
Eu4 Eu4 1.368(19) 6_565 ?
Eu4 Eu5 1.460(9) . ?
Eu4 Eu3 2.174(9) 6_565 ?
Eu4 Eu7 2.345(12) . ?
Eu4 Eu5 2.413(8) 6_565 ?
Eu4 Eu6 2.570(13) . ?
Eu4 Eu6 2.854(12) 6_565 ?
Eu4 Eu7 3.108(9) 6_565 ?
Eu5 Eu7 1.008(10) . ?
Eu5 Eu6 1.497(12) . ?
Eu5 Eu6 2.298(12) 6_565 ?
Eu5 Eu4 2.413(8) 6_565 ?
Eu5 Eu5 2.698(6) 6_565 ?
Eu5 Eu7 3.036(8) 6_565 ?
Eu5 Eu3 3.047(3) 6_565 ?
Eu6 Eu7 1.121(14) . ?
Eu6 Eu6 1.13(2) 6_565 ?
Eu6 Eu7 2.163(17) 6_565 ?
Eu6 Eu5 2.298(12) 6_565 ?
Eu6 Eu4 2.854(12) 6_565 ?
Eu6 Eu3 3.177(11) 6_565 ?
Eu7 Eu6 2.163(17) 6_565 ?
Eu7 Eu5 3.037(8) 6_565 ?
Eu7 Eu7 3.04(2) 6_565 ?
Eu7 Eu4 3.108(9) 6_565 ?
Eu7 Eu3 3.497(7) 6_565 ?
C109 C111 1.26(3) 2_556 ?
C109 C110 1.399(10) . ?
C109 H109 0.9500 . ?
C110 C111 1.403(10) . ?
C110 H110 0.9500 . ?
C111 C109 1.26(3) 2_556 ?
C111 H111 0.9500 . ?
S1 C112 1.509(9) . ?
C112 S1 1.509(9) 2_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 C1 C9 123.3(14) . . ?
C5 C1 C2 122.8(12) . . ?
C9 C1 C2 105(2) . . ?
C6 C20 C21 127.3(8) . . ?
C6 C20 C19 115.4(11) . . ?
C21 C20 C19 106.2(12) . . ?
Eu4 C20 Eu4 27.5(3) 6_565 . ?
C83 C33 C84 137.9(12) . . ?
C83 C33 C76 108(2) . . ?
C84 C33 C76 102.0(13) . . ?
C84 C33 Eu6 64.2(5) . . ?
C84 C33 Eu6 64.2(5) . 6_565 ?
Eu6 C33 Eu6 22.2(5) . 6_565 ?
C47 C48 C49 138.4(14) . . ?
C47 C48 C25 119.4(13) . . ?
C49 C48 C25 101.8(13) . . ?
Eu3 C48 Eu7 40.60(19) . . ?
Eu3 C48 Eu5 28.43(10) . . ?
Eu7 C48 Eu5 19.03(19) . . ?
C55 C56 C34 130.4(14) . . ?
C55 C56 C32 109.8(17) . . ?
C34 C56 C32 116.9(14) . . ?
C80 C84 C78 120.5(12) . . ?
C80 C84 C33 119.7(12) . . ?
C78 C84 C33 109.4(13) . . ?
C33 C84 Eu6 86.0(5) . . ?
C33 C84 Eu6 86.0(5) . 6_565 ?
Eu6 C84 Eu6 24.7(5) . 6_565 ?
C12 C2 C1 144(3) . . ?
C12 C2 C3 112(2) . . ?
C1 C2 C3 94.0(16) . . ?
C4 C3 C15 124(2) . . ?
C4 C3 C2 106.4(19) . . ?
C15 C3 C2 119.8(18) . . ?
C3 C4 C18 121.3(19) . . ?
C3 C4 C5 115.7(18) . . ?
C18 C4 C5 115(2) . . ?
C1 C5 C4 101.0(14) . . ?
C1 C5 C6 126.2(10) . . ?
C4 C5 C6 123.9(14) . . ?
C20 C6 C5 124.1(10) . . ?
C20 C6 C7 117.2(12) . . ?
C5 C6 C7 112.4(14) . . ?
C23 C7 C8 117.9(15) . . ?
C23 C7 C6 113.9(18) . . ?
C8 C7 C6 121.6(17) . . ?
C26 C8 C7 119.1(15) . . ?
C26 C8 C9 115(2) . . ?
C7 C8 C9 119.5(18) . . ?
C1 C9 C10 123.3(19) . . ?
C1 C9 C8 117(2) . . ?
C10 C9 C8 113.7(19) . . ?
C28 C10 C9 124(2) . . ?
C28 C10 C11 104(2) . . ?
C9 C10 C11 122(2) . . ?
C30 C11 C12 129.9(19) . . ?
C30 C11 C10 108(2) . . ?
C12 C11 C10 108(2) . . ?
C2 C12 C11 116(3) . . ?
C2 C12 C13 135(3) . . ?
C11 C12 C13 102(2) . . ?
C14 C13 C12 112(3) . . ?
C14 C13 C32 109(2) . . ?
C12 C13 C32 128(2) . . ?
C13 C14 C34 118(2) . . ?
C13 C14 C15 124(2) . . ?
C34 C14 C15 110(2) . . ?
C16 C15 C3 119(2) . . ?
C16 C15 C14 117(2) . . ?
C3 C15 C14 117(2) . . ?
C15 C16 C17 124.3(19) . . ?
C38 C17 C18 122(2) . . ?
C38 C17 C16 112.2(19) . . ?
C18 C17 C16 114.0(15) . . ?
C4 C18 C17 117.7(15) . . ?
C4 C18 C19 119.7(18) . . ?
C17 C18 C19 115.1(18) . . ?
C40 C19 C18 123.5(15) . . ?
C40 C19 C20 105.2(12) . . ?
C18 C19 C20 121.3(16) . . ?
C22 C21 C20 119.3(14) . . ?
C22 C21 C41 119.8(15) . . ?
C20 C21 C41 111.7(12) . . ?
C44 C22 C21 119(2) . . ?
C44 C22 C23 107(2) . . ?
C21 C22 C23 117.1(16) . . ?
C24 C23 C7 121.3(18) . . ?
C24 C23 C22 104.5(15) . . ?
C7 C23 C22 124.0(17) . . ?
C23 C24 C25 122.0(17) . . ?
C23 C24 C45 107.5(18) . . ?
C25 C24 C45 119.2(15) . . ?
C24 C25 C26 119.5(16) . . ?
C24 C25 C48 118.3(14) . . ?
C26 C25 C48 107.3(17) . . ?
C25 C26 C8 120.0(19) . . ?
C25 C26 C27 107.6(16) . . ?
C8 C26 C27 123.1(18) . . ?
C28 C27 C49 138(3) . . ?
C28 C27 C26 111(2) . . ?
C49 C27 C26 100(2) . . ?
C27 C28 C10 133(3) . . ?
C27 C28 C29 107(3) . . ?
C10 C28 C29 114(2) . . ?
C30 C29 C28 102(2) . . ?
C29 C30 C11 112(2) . . ?
C29 C30 C31 117(2) . . ?
C11 C30 C31 120(2) . . ?
C32 C31 C53 116(3) . . ?
C32 C31 C30 120(3) . . ?
C53 C31 C30 118(3) . . ?
C31 C32 C56 130(2) . . ?
C31 C32 C13 118(2) . . ?
C56 C32 C13 96.2(16) . . ?
C35 C34 C14 136.0(16) . . ?
C35 C34 C56 114.3(11) . . ?
C14 C34 C56 99.8(13) . . ?
C34 C35 C58 122(3) . . ?
C38 C37 C60 130.9(17) . . ?
C37 C38 C17 107.9(16) . . ?
C37 C38 C39 120.5(17) . . ?
C17 C38 C39 124(2) . . ?
C62 C39 C40 115(2) . . ?
C62 C39 C38 116(2) . . ?
C40 C39 C38 112(2) . . ?
C41 C40 C19 112.8(15) . . ?
C41 C40 C39 116.8(17) . . ?
C19 C40 C39 123.1(18) . . ?
C42 C41 C40 126.3(18) . . ?
C42 C41 C21 119(2) . . ?
C40 C41 C21 103.7(12) . . ?
C41 C42 C43 122.0(18) . . ?
C41 C42 C63 115(2) . . ?
C43 C42 C63 116.9(11) . . ?
C42 C43 C44 114.4(18) . . ?
C42 C43 C66 122.9(13) . . ?
C44 C43 C66 115(2) . . ?
C22 C44 C45 115(3) . . ?
C22 C44 C43 125(3) . . ?
C45 C44 C43 118(3) . . ?
C46 C45 C44 124(2) . . ?
C46 C45 C24 117.4(17) . . ?
C44 C45 C24 103(2) . . ?
C45 C46 C67 125.7(18) . . ?
C45 C46 C47 122.7(14) . . ?
C67 C46 C47 100.1(12) . . ?
C48 C47 C69 111.5(15) . . ?
C48 C47 C46 120.3(11) . . ?
C69 C47 C46 113.4(11) . . ?
C48 C49 C27 120(2) . . ?
C48 C49 C50 112.6(11) . . ?
C27 C49 C50 112.7(19) . . ?
C70 C50 C49 109(2) . . ?
C72 C52 C53 120(3) . . ?
C31 C53 C54 116(3) . . ?
C31 C53 C52 123(3) . . ?
C54 C53 C52 112(2) . . ?
C74 C54 C53 123(2) . . ?
C74 C54 C55 110(2) . . ?
C53 C54 C55 117.2(17) . . ?
C56 C55 C54 126.7(18) . . ?
C56 C55 C57 114.5(17) . . ?
C54 C55 C57 105.2(17) . . ?
C58 C57 C75 130(3) . . ?
C58 C57 C55 116(2) . . ?
C75 C57 C55 105(2) . . ?
C57 C58 C35 122(4) . . ?
C57 C58 C59 111(3) . . ?
C35 C58 C59 121(4) . . ?
C60 C59 C77 123(2) . . ?
C60 C59 C58 116(3) . . ?
C77 C59 C58 114(2) . . ?
C59 C60 C37 132(2) . . ?
C59 C60 C61 118(2) . . ?
C37 C60 C61 106.2(19) . . ?
C60 C61 C79 118.7(16) . . ?
C60 C61 C62 123.9(15) . . ?
C79 C61 C62 100.9(15) . . ?
C63 C62 C39 126.5(18) . . ?
C63 C62 C61 106.9(14) . . ?
C39 C62 C61 119.2(19) . . ?
C64 C63 C62 117.3(12) . . ?
C64 C63 C42 118.4(12) . . ?
C62 C63 C42 118.4(13) . . ?
C63 C64 C65 129.2(12) . . ?
C63 C64 C79 107.1(13) . . ?
C65 C64 C79 115.7(11) . . ?
C80 C65 C64 122.7(15) . . ?
C80 C65 C66 120.7(17) . . ?
C64 C65 C66 113.7(11) . . ?
C67 C66 C65 116.5(14) . . ?
C67 C66 C43 119.1(12) . . ?
C65 C66 C43 118.0(14) . . ?
C46 C67 C66 117.3(14) . . ?
C46 C67 C68 115.1(15) . . ?
C66 C67 C68 120.4(11) . . ?
C81 C68 C69 121.8(15) . . ?
C81 C68 C67 122.1(13) . . ?
C69 C68 C67 104.4(11) . . ?
C47 C69 C70 128.4(17) . . ?
C47 C69 C68 106.5(12) . . ?
C70 C69 C68 116.7(16) . . ?
C69 C70 C71 121.0(18) . . ?
C69 C70 C50 119(3) . . ?
C71 C70 C50 114(3) . . ?
C82 C71 C70 119.8(17) . . ?
C82 C71 C72 115.4(19) . . ?
C70 C71 C72 116(2) . . ?
C52 C72 C71 127(2) . . ?
C52 C72 C73 123.1(18) . . ?
C71 C72 C73 99.9(16) . . ?
C74 C73 C83 125(2) . . ?
C74 C73 C72 112.3(17) . . ?
C83 C73 C72 110.3(16) . . ?
C73 C74 C54 130(2) . . ?
C73 C74 C75 111.7(18) . . ?
C54 C74 C75 110(2) . . ?
C57 C75 C76 121(3) . . ?
C57 C75 C74 109.2(19) . . ?
C76 C75 C74 118.7(19) . . ?
C77 C76 C75 117(2) . . ?
C77 C76 C33 113(2) . . ?
C75 C76 C33 119(2) . . ?
C76 C77 C78 106(2) . . ?
C76 C77 C59 125.8(19) . . ?
C78 C77 C59 115(2) . . ?
C79 C78 C84 124(3) . . ?
C79 C78 C77 122(3) . . ?
C84 C78 C77 110(2) . . ?
C78 C79 C64 119(2) . . ?
C78 C79 C61 121(2) . . ?
C64 C79 C61 107.4(14) . . ?
C84 C80 C65 117(2) . . ?
C84 C80 C81 112.4(19) . . ?
C65 C80 C81 120.0(14) . . ?
C68 C81 C82 118(2) . . ?
C68 C81 C80 118.7(14) . . ?
C82 C81 C80 118.3(18) . . ?
C71 C82 C81 121.8(17) . . ?
C71 C82 C83 106.8(17) . . ?
C81 C82 C83 122.1(18) . . ?
C33 C83 C73 138(2) . . ?
C33 C83 C82 108.1(16) . . ?
C73 C83 C82 107.1(17) . . ?
C99 N1 C99 104.1(3) 6_565 . ?
C99 N1 Ni1 127.92(16) 6_565 . ?
C99 N1 Ni1 127.92(16) . . ?
N1 Ni1 N3 177.86(14) . . ?
N1 Ni1 N2 89.98(7) . . ?
N3 Ni1 N2 89.97(7) . . ?
N1 Ni1 N2 89.98(7) . 6_565 ?
N3 Ni1 N2 89.97(7) . 6_565 ?
N2 Ni1 N2 177.74(14) . 6_565 ?
C97 N2 C90 104.2(2) . . ?
C97 N2 Ni1 127.92(19) . . ?
C90 N2 Ni1 127.89(19) . . ?
C88 N3 C88 104.6(3) 6_565 . ?
C88 N3 Ni1 127.67(17) 6_565 . ?
C88 N3 Ni1 127.66(17) . . ?
C86 C85 H85A 109.5 . . ?
C86 C85 H85B 109.5 . . ?
H85A C85 H85B 109.5 . . ?
C86 C85 H85C 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
C87 C86 C85 113.1(3) . . ?
C87 C86 H86A 109.0 . . ?
C85 C86 H86A 109.0 . . ?
C87 C86 H86B 109.0 . . ?
C85 C86 H86B 109.0 . . ?
H86A C86 H86B 107.8 . . ?
C87 C87 C88 106.32(17) 6_565 . ?
C87 C87 C86 128.95(18) 6_565 . ?
C88 C87 C86 124.6(3) . . ?
C89 C88 N3 125.5(3) . . ?
C89 C88 C87 123.1(3) . . ?
N3 C88 C87 111.3(3) . . ?
C88 C89 C90 124.1(3) . . ?
C88 C89 H89 117.9 . . ?
C90 C89 H89 117.9 . . ?
N2 C90 C89 124.8(3) . . ?
N2 C90 C91 111.7(2) . . ?
C89 C90 C91 123.5(3) . . ?
C94 C91 C90 106.1(3) . . ?
C94 C91 C92 129.0(3) . . ?
C90 C91 C92 124.8(3) . . ?
C91 C92 C93 113.0(3) . . ?
C91 C92 H92A 109.0 . . ?
C93 C92 H92A 109.0 . . ?
C91 C92 H92B 109.0 . . ?
C93 C92 H92B 109.0 . . ?
H92A C92 H92B 107.8 . . ?
C92 C93 H93A 109.5 . . ?
C92 C93 H93B 109.5 . . ?
H93A C93 H93B 109.5 . . ?
C92 C93 H93C 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
C91 C94 C97 106.1(3) . . ?
C91 C94 C95 129.2(3) . . ?
C97 C94 C95 124.7(3) . . ?
C94 C95 C96 113.0(3) . . ?
C94 C95 H95A 109.0 . . ?
C96 C95 H95A 109.0 . . ?
C94 C95 H95B 109.0 . . ?
C96 C95 H95B 109.0 . . ?
H95A C95 H95B 107.8 . . ?
C95 C96 H96A 109.5 . . ?
C95 C96 H96B 109.5 . . ?
H96A C96 H96B 109.5 . . ?
C95 C96 H96C 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
N2 C97 C98 124.9(3) . . ?
N2 C97 C94 111.9(2) . . ?
C98 C97 C94 123.2(3) . . ?
C99 C98 C97 124.1(3) . . ?
C99 C98 H98 118.0 . . ?
C97 C98 H98 118.0 . . ?
N1 C99 C98 125.2(3) . . ?
N1 C99 C100 111.5(3) . . ?
C98 C99 C100 123.3(3) . . ?
C100 C100 C99 106.41(16) 6_565 . ?
C100 C100 C101 128.67(17) 6_565 . ?
C99 C100 C101 124.7(3) . . ?
C100 C101 C102 111.9(3) . . ?
C100 C101 H10A 109.2 . . ?
C102 C101 H10A 109.2 . . ?
C100 C101 H10B 109.2 . . ?
C102 C101 H10B 109.2 . . ?
H10A C101 H10B 107.9 . . ?
C101 C102 H10C 109.5 . . ?
C101 C102 H10D 109.5 . . ?
H10C C102 H10D 109.5 . . ?
C101 C102 H10E 109.5 . . ?
H10C C102 H10E 109.5 . . ?
H10D C102 H10E 109.5 . . ?
C104 C103 C108 116.7(7) . . ?
C104 C103 H103 121.7 . . ?
C108 C103 H103 121.7 . . ?
C103 C104 C105 122.1(6) . . ?
C103 C104 H104 119.0 . . ?
C105 C104 H104 119.0 . . ?
C106 C105 C104 119.0(6) . . ?
C106 C105 H105 120.5 . . ?
C104 C105 H105 120.5 . . ?
C105 C106 C107 121.2(6) . . ?
C105 C106 H106 119.4 . . ?
C107 C106 H106 119.4 . . ?
C106 C107 C108 119.7(7) . . ?
C106 C107 H107 120.1 . . ?
C108 C107 H107 120.1 . . ?
C107 C108 C103 121.2(7) . . ?
C107 C108 H108 119.4 . . ?
C103 C108 H108 119.4 . . ?
Eu3 Eu1 Eu3 80.4(6) 6_565 . ?
Eu3 Eu1 Eu4 56.0(5) 6_565 . ?
Eu3 Eu1 Eu4 24.4(3) . . ?
Eu3 Eu1 Eu4 24.4(3) 6_565 6_565 ?
Eu3 Eu1 Eu4 56.0(5) . 6_565 ?
Eu4 Eu1 Eu4 31.6(5) . 6_565 ?
Eu3 Eu1 C1 94.8(8) 6_565 . ?
Eu3 Eu1 C1 94.8(8) . . ?
Eu4 Eu1 C1 94.9(8) . . ?
Eu4 Eu1 C1 94.9(8) 6_565 . ?
Eu3 Eu1 Eu5 26.66(13) 6_565 6_565 ?
Eu3 Eu1 Eu5 71.9(3) . 6_565 ?
Eu4 Eu1 Eu5 51.1(3) . 6_565 ?
Eu4 Eu1 Eu5 29.1(2) 6_565 6_565 ?
C1 Eu1 Eu5 120.1(8) . 6_565 ?
Eu3 Eu1 Eu5 71.9(3) 6_565 . ?
Eu3 Eu1 Eu5 26.66(13) . . ?
Eu4 Eu1 Eu5 29.1(2) . . ?
Eu4 Eu1 Eu5 51.1(3) 6_565 . ?
C1 Eu1 Eu5 120.1(8) . . ?
Eu5 Eu1 Eu5 53.61(18) 6_565 . ?
Eu3 Eu1 Eu7 41.3(3) 6_565 6_565 ?
Eu3 Eu1 Eu7 83.2(3) . 6_565 ?
Eu4 Eu1 Eu7 66.4(3) . 6_565 ?
Eu4 Eu1 Eu7 48.1(3) 6_565 6_565 ?
C1 Eu1 Eu7 135.9(7) . 6_565 ?
Eu5 Eu1 Eu7 18.96(19) 6_565 6_565 ?
Eu5 Eu1 Eu7 59.8(2) . 6_565 ?
Eu3 Eu1 Eu7 83.2(3) 6_565 . ?
Eu3 Eu1 Eu7 41.3(3) . . ?
Eu4 Eu1 Eu7 48.1(3) . . ?
Eu4 Eu1 Eu7 66.4(3) 6_565 . ?
C1 Eu1 Eu7 135.9(7) . . ?
Eu5 Eu1 Eu7 59.8(2) 6_565 . ?
Eu5 Eu1 Eu7 18.96(19) . . ?
Eu7 Eu1 Eu7 58.8(4) 6_565 . ?
Eu3 Eu1 Eu6 53.4(2) 6_565 6_565 ?
Eu3 Eu1 Eu6 67.8(3) . 6_565 ?
Eu4 Eu1 Eu6 56.5(3) . 6_565 ?
Eu4 Eu1 Eu6 49.9(3) 6_565 6_565 ?
C1 Eu1 Eu6 144.8(8) . 6_565 ?
Eu5 Eu1 Eu6 26.7(2) 6_565 6_565 ?
Eu5 Eu1 Eu6 42.2(2) . 6_565 ?
Eu7 Eu1 Eu6 19.7(3) 6_565 6_565 ?
Eu7 Eu1 Eu6 39.1(3) . 6_565 ?
Eu3 Eu1 Eu6 67.8(3) 6_565 . ?
Eu3 Eu1 Eu6 53.4(2) . . ?
Eu4 Eu1 Eu6 49.9(3) . . ?
Eu4 Eu1 Eu6 56.5(3) 6_565 . ?
C1 Eu1 Eu6 144.8(8) . . ?
Eu5 Eu1 Eu6 42.2(2) 6_565 . ?
Eu5 Eu1 Eu6 26.7(2) . . ?
Eu7 Eu1 Eu6 39.1(3) 6_565 . ?
Eu7 Eu1 Eu6 19.7(3) . . ?
Eu6 Eu1 Eu6 19.5(4) 6_565 . ?
Eu4 Eu3 Eu5 67.3(4) . . ?
Eu4 Eu3 Eu1 103.9(5) . . ?
Eu5 Eu3 Eu1 115.6(4) . . ?
Eu4 Eu3 Eu7 91.3(4) . . ?
Eu5 Eu3 Eu7 27.3(2) . . ?
Eu1 Eu3 Eu7 98.3(6) . . ?
Eu4 Eu3 Eu4 30.7(5) . 6_565 ?
Eu5 Eu3 Eu4 80.0(2) . 6_565 ?
Eu1 Eu3 Eu4 73.2(3) . 6_565 ?
Eu7 Eu3 Eu4 94.3(3) . 6_565 ?
Eu4 Eu3 Eu3 54.1(4) . 6_565 ?
Eu5 Eu3 Eu3 91.51(12) . 6_565 ?
Eu1 Eu3 Eu3 49.8(3) . 6_565 ?
Eu7 Eu3 Eu3 95.9(3) . 6_565 ?
Eu4 Eu3 Eu3 23.46(17) 6_565 6_565 ?
Eu4 Eu3 Eu6 72.9(4) . . ?
Eu5 Eu3 Eu6 26.6(3) . . ?
Eu1 Eu3 Eu6 89.1(5) . . ?
Eu7 Eu3 Eu6 23.1(3) . . ?
Eu4 Eu3 Eu6 71.3(3) 6_565 . ?
Eu3 Eu3 Eu6 73.8(2) 6_565 . ?
Eu4 Eu3 C48 132.7(5) . . ?
Eu5 Eu3 C48 80.3(2) . . ?
Eu1 Eu3 C48 121.3(5) . . ?
Eu7 Eu3 C48 70.4(3) . . ?
Eu4 Eu3 C48 159.5(2) 6_565 . ?
Eu3 Eu3 C48 163.45(19) 6_565 . ?
Eu6 Eu3 C48 93.3(3) . . ?
Eu4 Eu3 Eu5 45.0(3) . 6_565 ?
Eu5 Eu3 Eu5 62.27(17) . 6_565 ?
Eu1 Eu3 Eu5 68.89(14) . 6_565 ?
Eu7 Eu3 Eu5 69.9(3) . 6_565 ?
Eu4 Eu3 Eu5 26.27(19) 6_565 6_565 ?
Eu3 Eu3 Eu5 29.24(8) 6_565 6_565 ?
Eu6 Eu3 Eu5 46.8(3) . 6_565 ?
C48 Eu3 Eu5 140.1(2) . 6_565 ?
Eu4 Eu3 Eu6 62.9(3) . 6_565 ?
Eu5 Eu3 Eu6 42.0(2) . 6_565 ?
Eu1 Eu3 Eu6 76.0(4) . 6_565 ?
Eu7 Eu3 Eu6 42.5(4) . 6_565 ?
Eu4 Eu3 Eu6 53.5(3) 6_565 6_565 ?
Eu3 Eu3 Eu6 53.9(2) 6_565 6_565 ?
Eu6 Eu3 Eu6 19.9(4) . 6_565 ?
C48 Eu3 Eu6 112.9(3) . 6_565 ?
Eu5 Eu3 Eu6 27.7(2) 6_565 6_565 ?
Eu4 Eu3 Eu7 60.2(3) . 6_565 ?
Eu5 Eu3 Eu7 59.9(2) . 6_565 ?
Eu1 Eu3 Eu7 61.6(2) . 6_565 ?
Eu7 Eu3 Eu7 59.9(5) . 6_565 ?
Eu4 Eu3 Eu7 41.1(3) 6_565 6_565 ?
Eu3 Eu3 Eu7 36.0(2) 6_565 6_565 ?
Eu6 Eu3 Eu7 38.2(3) . 6_565 ?
C48 Eu3 Eu7 129.5(3) . 6_565 ?
Eu5 Eu3 Eu7 15.89(19) 6_565 6_565 ?
Eu6 Eu3 Eu7 18.6(3) 6_565 6_565 ?
Eu3 Eu4 Eu4 125.9(4) . 6_565 ?
Eu3 Eu4 Eu5 70.2(5) . . ?
Eu4 Eu4 Eu5 117.1(3) 6_565 . ?
Eu3 Eu4 Eu3 102.4(4) . 6_565 ?
Eu4 Eu4 Eu3 23.46(17) 6_565 6_565 ?
Eu5 Eu4 Eu3 112.5(3) . 6_565 ?
Eu3 Eu4 Eu7 61.6(5) . . ?
Eu4 Eu4 Eu7 110.9(4) 6_565 . ?
Eu5 Eu4 Eu7 15.0(2) . . ?
Eu3 Eu4 Eu7 101.3(3) 6_565 . ?
Eu3 Eu4 Eu5 116.8(3) . 6_565 ?
Eu4 Eu4 Eu5 32.6(2) 6_565 6_565 ?
Eu5 Eu4 Eu5 84.5(3) . 6_565 ?
Eu3 Eu4 Eu5 37.43(15) 6_565 6_565 ?
Eu7 Eu4 Eu5 79.3(3) . 6_565 ?
Eu3 Eu4 Eu1 51.7(3) . . ?
Eu4 Eu4 Eu1 74.2(2) 6_565 . ?
Eu5 Eu4 Eu1 94.1(5) . . ?
Eu3 Eu4 Eu1 50.74(16) 6_565 . ?
Eu7 Eu4 Eu1 79.2(5) . . ?
Eu5 Eu4 Eu1 74.8(2) 6_565 . ?
Eu3 Eu4 Eu6 83.7(5) . . ?
Eu4 Eu4 Eu6 87.3(3) 6_565 . ?
Eu5 Eu4 Eu6 30.1(3) . . ?
Eu3 Eu4 Eu6 83.6(3) 6_565 . ?
Eu7 Eu4 Eu6 25.9(3) . . ?
Eu5 Eu4 Eu6 54.8(3) 6_565 . ?
Eu1 Eu4 Eu6 81.9(5) . . ?
Eu3 Eu4 Eu6 97.6(4) . 6_565 ?
Eu4 Eu4 Eu6 64.1(3) 6_565 6_565 ?
Eu5 Eu4 Eu6 53.2(3) . 6_565 ?
Eu3 Eu4 Eu6 62.5(3) 6_565 6_565 ?
Eu7 Eu4 Eu6 48.0(4) . 6_565 ?
Eu5 Eu4 Eu6 31.6(3) 6_565 6_565 ?
Eu1 Eu4 Eu6 76.4(4) . 6_565 ?
Eu6 Eu4 Eu6 23.2(5) . 6_565 ?
Eu3 Eu4 C20 116.7(4) . . ?
Eu4 Eu4 C20 76.27(17) 6_565 . ?
Eu5 Eu4 C20 158.8(4) . . ?
Eu3 Eu4 C20 86.3(3) 6_565 . ?
Eu7 Eu4 C20 172.4(5) . . ?
Eu5 Eu4 C20 107.4(4) 6_565 . ?
Eu1 Eu4 C20 105.8(5) . . ?
Eu6 Eu4 C20 158.8(5) . . ?
Eu6 Eu4 C20 138.3(4) 6_565 . ?
Eu3 Eu4 Eu7 102.4(4) . 6_565 ?
Eu4 Eu4 Eu7 44.8(3) 6_565 6_565 ?
Eu5 Eu4 Eu7 73.5(3) . 6_565 ?
Eu3 Eu4 Eu7 41.5(2) 6_565 6_565 ?
Eu7 Eu4 Eu7 66.1(6) . 6_565 ?
Eu5 Eu4 Eu7 15.3(2) 6_565 6_565 ?
Eu1 Eu4 Eu7 65.9(3) . 6_565 ?
Eu6 Eu4 Eu7 43.5(4) . 6_565 ?
Eu6 Eu4 Eu7 21.1(3) 6_565 6_565 ?
C20 Eu4 Eu7 121.0(4) . 6_565 ?
Eu7 Eu5 Eu4 143.1(5) . . ?
Eu7 Eu5 Eu3 110.0(5) . . ?
Eu4 Eu5 Eu3 42.5(3) . . ?
Eu7 Eu5 Eu6 48.5(7) . . ?
Eu4 Eu5 Eu6 120.7(6) . . ?
Eu3 Eu5 Eu6 127.0(4) . . ?
Eu7 Eu5 Eu6 69.6(7) . 6_565 ?
Eu4 Eu5 Eu6 96.3(4) . 6_565 ?
Eu3 Eu5 Eu6 112.3(3) . 6_565 ?
Eu6 Eu5 Eu6 24.6(5) . 6_565 ?
Eu7 Eu5 Eu4 125.4(6) . 6_565 ?
Eu4 Eu5 Eu4 30.3(5) . 6_565 ?
Eu3 Eu5 Eu4 62.5(2) . 6_565 ?
Eu6 Eu5 Eu4 90.6(5) . 6_565 ?
Eu6 Eu5 Eu4 66.1(4) 6_565 6_565 ?
Eu7 Eu5 Eu5 99.8(7) . 6_565 ?
Eu4 Eu5 Eu5 62.9(3) . 6_565 ?
Eu3 Eu5 Eu5 88.49(12) . 6_565 ?
Eu6 Eu5 Eu5 58.3(5) . 6_565 ?
Eu6 Eu5 Eu5 33.7(3) 6_565 6_565 ?
Eu4 Eu5 Eu5 32.6(2) 6_565 6_565 ?
Eu7 Eu5 Eu1 86.4(6) . . ?
Eu4 Eu5 Eu1 56.8(5) . . ?
Eu3 Eu5 Eu1 37.7(3) . . ?
Eu6 Eu5 Eu1 89.3(5) . . ?
Eu6 Eu5 Eu1 76.8(4) 6_565 . ?
Eu4 Eu5 Eu1 54.1(3) 6_565 . ?
Eu5 Eu5 Eu1 63.19(9) 6_565 . ?
Eu7 Eu5 Eu7 80.7(9) . 6_565 ?
Eu4 Eu5 Eu7 79.0(4) . 6_565 ?
Eu3 Eu5 Eu7 95.0(2) . 6_565 ?
Eu6 Eu5 Eu7 41.8(5) . 6_565 ?
Eu6 Eu5 Eu7 18.4(3) 6_565 6_565 ?
Eu4 Eu5 Eu7 49.4(3) 6_565 6_565 ?
Eu5 Eu5 Eu7 19.1(2) 6_565 6_565 ?
Eu1 Eu5 Eu7 61.8(2) . 6_565 ?
Eu7 Eu5 Eu3 108.3(5) . 6_565 ?
Eu4 Eu5 Eu3 41.2(3) . 6_565 ?
Eu3 Eu5 Eu3 59.25(11) . 6_565 ?
Eu6 Eu5 Eu3 80.9(4) . 6_565 ?
Eu6 Eu5 Eu3 58.0(3) 6_565 6_565 ?
Eu4 Eu5 Eu3 18.23(15) 6_565 6_565 ?
Eu5 Eu5 Eu3 29.24(8) 6_565 6_565 ?
Eu1 Eu5 Eu3 39.3(2) . 6_565 ?
Eu7 Eu5 Eu3 39.7(2) 6_565 6_565 ?
Eu7 Eu5 C48 75.1(7) . . ?
Eu4 Eu5 C48 106.5(4) . . ?
Eu3 Eu5 C48 71.2(2) . . ?
Eu6 Eu5 C48 123.4(5) . . ?
Eu6 Eu5 C48 143.5(4) 6_565 . ?
Eu4 Eu5 C48 133.4(3) 6_565 . ?
Eu5 Eu5 C48 155.22(19) 6_565 . ?
Eu1 Eu5 C48 92.1(2) . . ?
Eu7 Eu5 C48 145.5(3) 6_565 . ?
Eu3 Eu5 C48 128.6(2) 6_565 . ?
Eu7 Eu6 Eu6 148.6(7) . 6_565 ?
Eu7 Eu6 Eu5 42.3(6) . . ?
Eu6 Eu6 Eu5 121.7(5) 6_565 . ?
Eu7 Eu6 Eu7 133.0(9) . 6_565 ?
Eu6 Eu6 Eu7 15.6(3) 6_565 6_565 ?
Eu5 Eu6 Eu7 110.8(7) . 6_565 ?
Eu7 Eu6 Eu5 121.4(9) . 6_565 ?
Eu6 Eu6 Eu5 33.7(3) 6_565 6_565 ?
Eu5 Eu6 Eu5 88.0(6) . 6_565 ?
Eu7 Eu6 Eu5 25.9(3) 6_565 6_565 ?
Eu7 Eu6 Eu4 65.8(7) . . ?
Eu6 Eu6 Eu4 92.7(3) 6_565 . ?
Eu5 Eu6 Eu4 29.2(3) . . ?
Eu7 Eu6 Eu4 81.6(5) 6_565 . ?
Eu5 Eu6 Eu4 59.1(4) 6_565 . ?
Eu7 Eu6 C84 133.0(8) . . ?
Eu6 Eu6 C84 77.7(3) 6_565 . ?
Eu5 Eu6 C84 140.2(6) . . ?
Eu7 Eu6 C84 93.0(4) 6_565 . ?
Eu5 Eu6 C84 104.5(4) 6_565 . ?
Eu4 Eu6 C84 145.2(5) . . ?
Eu7 Eu6 Eu3 46.3(6) . . ?
Eu6 Eu6 Eu3 106.2(2) 6_565 . ?
Eu5 Eu6 Eu3 26.4(3) . . ?
Eu7 Eu6 Eu3 92.0(5) 6_565 . ?
Eu5 Eu6 Eu3 75.2(3) 6_565 . ?
Eu4 Eu6 Eu3 23.40(19) . . ?
C84 Eu6 Eu3 165.6(5) . . ?
Eu7 Eu6 Eu4 92.3(8) . 6_565 ?
Eu6 Eu6 Eu4 64.1(3) 6_565 6_565 ?
Eu5 Eu6 Eu4 57.7(4) . 6_565 ?
Eu7 Eu6 Eu4 53.6(4) 6_565 6_565 ?
Eu5 Eu6 Eu4 30.6(3) 6_565 6_565 ?
Eu4 Eu6 Eu4 28.6(4) . 6_565 ?
C84 Eu6 Eu4 129.6(5) . 6_565 ?
Eu3 Eu6 Eu4 46.2(3) . 6_565 ?
Eu7 Eu6 C33 123.2(9) . . ?
Eu6 Eu6 C33 78.9(2) 6_565 . ?
Eu5 Eu6 C33 158.3(7) . . ?
Eu7 Eu6 C33 90.7(4) 6_565 . ?
Eu5 Eu6 C33 112.3(4) 6_565 . ?
Eu4 Eu6 C33 171.0(6) . . ?
C84 Eu6 C33 29.8(4) . . ?
Eu3 Eu6 C33 163.5(5) . . ?
Eu4 Eu6 C33 142.8(5) 6_565 . ?
Eu7 Eu6 Eu3 97.1(7) . 6_565 ?
Eu6 Eu6 Eu3 53.9(2) 6_565 6_565 ?
Eu5 Eu6 Eu3 71.3(4) . 6_565 ?
Eu7 Eu6 Eu3 40.1(3) 6_565 6_565 ?
Eu5 Eu6 Eu3 25.71(15) 6_565 6_565 ?
Eu4 Eu6 Eu3 42.8(3) . 6_565 ?
C84 Eu6 Eu3 129.7(4) . 6_565 ?
Eu3 Eu6 Eu3 52.4(2) . 6_565 ?
Eu4 Eu6 Eu3 19.47(17) 6_565 6_565 ?
C33 Eu6 Eu3 130.4(4) . 6_565 ?
Eu7 Eu6 Eu1 68.4(6) . . ?
Eu6 Eu6 Eu1 80.3(2) 6_565 . ?
Eu5 Eu6 Eu1 64.0(5) . . ?
Eu7 Eu6 Eu1 64.6(3) 6_565 . ?
Eu5 Eu6 Eu1 61.0(3) 6_565 . ?
Eu4 Eu6 Eu1 48.3(5) . . ?
C84 Eu6 Eu1 154.4(5) . . ?
Eu3 Eu6 Eu1 37.6(3) . . ?
Eu4 Eu6 Eu1 47.1(4) 6_565 . ?
C33 Eu6 Eu1 131.9(6) . . ?
Eu3 Eu6 Eu1 36.3(3) 6_565 . ?
Eu5 Eu7 Eu6 89.2(8) . . ?
Eu5 Eu7 Eu3 42.7(4) . . ?
Eu6 Eu7 Eu3 110.5(7) . . ?
Eu5 Eu7 Eu6 84.5(6) . 6_565 ?
Eu6 Eu7 Eu6 15.7(5) . 6_565 ?
Eu3 Eu7 Eu6 97.4(4) . 6_565 ?
Eu5 Eu7 Eu4 22.0(3) . . ?
Eu6 Eu7 Eu4 88.3(7) . . ?
Eu3 Eu7 Eu4 27.08(19) . . ?
Eu6 Eu7 Eu4 78.4(4) 6_565 . ?
Eu5 Eu7 C48 85.8(8) . . ?
Eu6 Eu7 C48 172.7(9) . . ?
Eu3 Eu7 C48 69.0(4) . . ?
Eu6 Eu7 C48 166.4(5) 6_565 . ?
Eu4 Eu7 C48 89.1(5) . . ?
Eu5 Eu7 Eu5 61.1(5) . 6_565 ?
Eu6 Eu7 Eu5 40.2(6) . 6_565 ?
Eu3 Eu7 Eu5 70.5(2) . 6_565 ?
Eu6 Eu7 Eu5 27.5(3) 6_565 6_565 ?
Eu4 Eu7 Eu5 51.3(3) . 6_565 ?
C48 Eu7 Eu5 139.2(4) . 6_565 ?
Eu5 Eu7 Eu7 80.2(7) . 6_565 ?
Eu6 Eu7 Eu7 31.4(7) . 6_565 ?
Eu3 Eu7 Eu7 84.1(3) . 6_565 ?
Eu6 Eu7 Eu7 15.6(3) 6_565 6_565 ?
Eu4 Eu7 Eu7 69.1(4) . 6_565 ?
C48 Eu7 Eu7 151.6(2) . 6_565 ?
Eu5 Eu7 Eu7 19.1(2) 6_565 6_565 ?
Eu5 Eu7 Eu1 74.6(6) . . ?
Eu6 Eu7 Eu1 91.9(7) . . ?
Eu3 Eu7 Eu1 40.4(4) . . ?
Eu6 Eu7 Eu1 76.2(4) 6_565 . ?
Eu4 Eu7 Eu1 52.7(5) . . ?
C48 Eu7 Eu1 91.9(3) . . ?
Eu5 Eu7 Eu1 58.4(2) 6_565 . ?
Eu7 Eu7 Eu1 60.6(2) 6_565 . ?
Eu5 Eu7 Eu4 39.2(4) . 6_565 ?
Eu6 Eu7 Eu4 66.6(7) . 6_565 ?
Eu3 Eu7 Eu4 44.2(2) . 6_565 ?
Eu6 Eu7 Eu4 54.9(4) 6_565 6_565 ?
Eu4 Eu7 Eu4 24.3(4) . 6_565 ?
C48 Eu7 Eu4 112.0(4) . 6_565 ?
Eu5 Eu7 Eu4 27.46(19) 6_565 6_565 ?
Eu7 Eu7 Eu4 44.8(3) 6_565 6_565 ?
Eu1 Eu7 Eu4 47.7(4) . 6_565 ?
Eu5 Eu7 Eu3 55.9(4) . 6_565 ?
Eu6 Eu7 Eu3 64.4(6) . 6_565 ?
Eu3 Eu7 Eu3 48.19(15) . 6_565 ?
Eu6 Eu7 Eu3 49.8(3) 6_565 6_565 ?
Eu4 Eu7 Eu3 37.6(2) . 6_565 ?
C48 Eu7 Eu3 116.6(4) . 6_565 ?
Eu5 Eu7 Eu3 25.10(9) 6_565 6_565 ?
Eu7 Eu7 Eu3 36.0(2) 6_565 6_565 ?
Eu1 Eu7 Eu3 35.2(2) . 6_565 ?
Eu4 Eu7 Eu3 17.36(14) 6_565 6_565 ?
C111 C109 C110 115(2) 2_556 . ?
C111 C109 H109 122.6 2_556 . ?
C110 C109 H109 122.6 . . ?
C109 C110 C111 116.8(15) . . ?
C109 C110 H110 121.6 . . ?
C111 C110 H110 121.6 . . ?
C109 C111 C110 123(2) 2_556 . ?
C109 C111 H111 118.4 2_556 . ?
C110 C111 H111 118.5 . . ?
S1 C112 S1 168(3) 2_556 . ?

_refine_diff_density_max         1.730
_refine_diff_density_min         -1.408
_refine_diff_density_rms         0.110

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_lb192
_database_code_depnum_ccdc_archive 'CCDC 1579800'
_audit_update_record             
;
2017-10-13 deposited with the CCDC.	2019-04-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        Eu@C2(13)-C84-W
_chemical_name_common            Eu@C2(13)-C84-W
_chemical_melting_point          ?
_chemical_formula_moiety         'C113 H24 Eu O3 P2 W, C S2'
_chemical_formula_sum            'C114 H24 Eu O3 P2 S2 W'
_chemical_formula_weight         1903.20

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0027 0.0014 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0093 0.0052 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0898 0.0807 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1098 0.1057 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1666 3.2045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.5343 6.0454 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   22.3565(8)
_cell_length_b                   11.4569(4)
_cell_length_c                   27.6560(10)
_cell_angle_alpha                90
_cell_angle_beta                 112.8190(10)
_cell_angle_gamma                90
_cell_volume                     6529.3(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9887
_cell_measurement_theta_min      2.336
_cell_measurement_theta_max      24.103

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_F_000             3724
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.020
_exptl_absorpt_coefficient_mu    2.302
_shelx_estimated_absorpt_T_min   0.802
_shelx_estimated_absorpt_T_max   0.955
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_correction_T_min  0.4591
_exptl_absorpt_correction_T_max  0.7450
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   SADABS
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.6525
_diffrn_radiation_type           synchrotron
_diffrn_source                   'SSRF, Beamline B17B1'
_diffrn_measurement_device_type  'CCD MX-300'
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            96159
_diffrn_reflns_av_unetI/netI     0.0538
_diffrn_reflns_av_R_equivalents  0.0937
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_theta_min         0.919
_diffrn_reflns_theta_max         24.128
_diffrn_reflns_theta_full        23.048
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             13446
_reflns_number_gt                10343
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       HKL2000
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0809P)²+38.6574P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         13446
_refine_ls_number_parameters     1198
_refine_ls_number_restraints     270
_refine_ls_R_factor_all          0.0790
_refine_ls_R_factor_gt           0.0592
_refine_ls_wR_factor_ref         0.1609
_refine_ls_wR_factor_gt          0.1508
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7051(3) 0.5113(6) 0.4354(3) 0.0280(14) Uani 1 1 d . . . . .
C2 C 0.6470(3) 0.5059(6) 0.4491(3) 0.0282(15) Uani 1 1 d . . . . .
C3 C 0.6229(3) 0.3922(7) 0.4554(3) 0.0299(15) Uani 1 1 d . . . . .
C4 C 0.6545(4) 0.2860(6) 0.4538(3) 0.0297(15) Uani 1 1 d . . . . .
C5 C 0.7111(3) 0.2910(7) 0.4393(3) 0.0309(15) Uani 1 1 d . . . . .
C6 C 0.7318(3) 0.3987(6) 0.4276(3) 0.0286(15) Uani 1 1 d . . . . .
C7 C 0.7535(3) 0.4111(7) 0.3864(3) 0.0303(15) Uani 1 1 d . . . . .
C8 C 0.7290(4) 0.5179(6) 0.3590(3) 0.0317(16) Uani 1 1 d . . . . .
C9 C 0.6975(4) 0.5771(6) 0.3874(3) 0.0294(15) Uani 1 1 d . . . . .
C10 C 0.6440(4) 0.6463(7) 0.3601(3) 0.0346(17) Uani 1 1 d . . . . .
C11 C 0.5880(4) 0.6436(7) 0.3743(3) 0.0375(18) Uani 1 1 d . . . . .
C12 C 0.5886(4) 0.5710(7) 0.4142(3) 0.0354(17) Uani 1 1 d . . . . .
C13 C 0.5327(4) 0.5040(7) 0.4085(3) 0.0394(18) Uani 1 1 d . . . . .
C14 C 0.5541(4) 0.3990(8) 0.4364(3) 0.0388(19) Uani 1 1 d . . . . .
C15 C 0.5162(4) 0.2981(8) 0.4234(3) 0.0394(18) Uani 1 1 d . . . . .
C16 C 0.5468(4) 0.1940(8) 0.4304(3) 0.0422(19) Uani 1 1 d . . . . .
C17 C 0.6158(4) 0.1835(7) 0.4419(3) 0.0428(19) Uani 1 1 d . . . . .
C18 C 0.6319(4) 0.0861(7) 0.4197(3) 0.0423(19) Uani 1 1 d . . . . .
C19 C 0.6846(4) 0.0880(6) 0.4060(3) 0.0420(19) Uani 1 1 d . . . . .
C20 C 0.7242(4) 0.1892(7) 0.4139(3) 0.0378(18) Uani 1 1 d . . . . .
C21 C 0.7538(4) 0.2022(7) 0.3771(3) 0.0419(19) Uani 1 1 d . . . . .
C22 C 0.7640(3) 0.3153(7) 0.3604(3) 0.0341(17) Uani 1 1 d . . . . .
C23 C 0.7509(4) 0.3235(7) 0.3052(3) 0.0365(17) Uani 1 1 d . . . . .
C24 C 0.7215(4) 0.4248(8) 0.2768(3) 0.044(2) Uani 1 1 d . . . . .
C25 C 0.7070(4) 0.5257(7) 0.3037(3) 0.0359(17) Uani 1 1 d . . . . .
C26 C 0.6525(5) 0.6002(7) 0.2755(3) 0.044(2) Uani 1 1 d . . . . .
C27 C 0.6230(4) 0.6591(7) 0.3046(3) 0.0402(19) Uani 1 1 d . . . . .
C28 C 0.5515(5) 0.6751(7) 0.2841(3) 0.051(2) Uani 1 1 d . . . . .
C29 C 0.5305(4) 0.6540(7) 0.3283(3) 0.043(2) Uani 1 1 d . . . . .
C30 C 0.4738(4) 0.5880(7) 0.3205(4) 0.049(2) Uani 1 1 d . . . . .
C31 C 0.4747(4) 0.5092(8) 0.3619(4) 0.045(2) Uani 1 1 d . . . . .
C32 C 0.4339(4) 0.4043(8) 0.3501(3) 0.043(2) Uani 1 1 d . . . . .
C33 C 0.4534(4) 0.3011(9) 0.3810(3) 0.048(2) Uani 1 1 d . . . . .
C34 C 0.4331(5) 0.1890(9) 0.3582(4) 0.056(3) Uani 1 1 d . . . . .
C35 C 0.3934(4) 0.1766(8) 0.3042(4) 0.051(2) Uani 1 1 d . . . . .
C36 C 0.4091(4) 0.0762(8) 0.2810(4) 0.054(2) Uani 1 1 d . . . . .
C37 C 0.4050(5) 0.0828(9) 0.2293(5) 0.068(3) Uani 1 1 d . . . . .
C38 C 0.4600(5) 0.0066(8) 0.2231(4) 0.058(3) Uani 1 1 d . . . . .
C39 C 0.4976(5) -0.0474(8) 0.2712(4) 0.056(3) Uani 1 1 d . . . . .
C40 C 0.5643(6) -0.0675(8) 0.2854(5) 0.070(3) Uani 1 1 d D . . . .
C41 C 0.6032(5) -0.0526(8) 0.3369(4) 0.054(2) Uani 1 1 d . . . . .
C42 C 0.5900(5) -0.0408(8) 0.2478(4) 0.063(3) Uani 1 1 d D . . . .
C43 C 0.6585(5) 0.0906(8) 0.2206(4) 0.053(2) Uani 1 1 d . . . . .
C44 C 0.6960(5) 0.1959(10) 0.2296(4) 0.062(3) Uani 1 1 d . . . . .
C45 C 0.7377(5) 0.2113(9) 0.2815(4) 0.054(2) Uani 1 1 d . . . . .
C46 C 0.6716(5) 0.2930(9) 0.2001(3) 0.051(2) Uani 1 1 d . . . . .
C47 C 0.6833(5) 0.4107(10) 0.2228(4) 0.055(3) Uani 1 1 d . . . . .
C48 C 0.6275(6) 0.4812(9) 0.1951(4) 0.061(3) Uani 1 1 d . . . . .
C49 C 0.6114(6) 0.5744(8) 0.2203(3) 0.053(2) Uani 1 1 d . . . . .
C50 C 0.5415(6) 0.6023(8) 0.2006(3) 0.057(3) Uani 1 1 d . . . . .
C51 C 0.5134(5) 0.6457(7) 0.2346(4) 0.057(3) Uani 1 1 d . . . . .
C52 C 0.4497(4) 0.5947(7) 0.2235(4) 0.049(2) Uani 1 1 d . . . . .
C53 C 0.4316(5) 0.5634(8) 0.2654(4) 0.056(3) Uani 1 1 d . . . . .
C54 C 0.3885(4) 0.4655(10) 0.2566(4) 0.062(3) Uani 1 1 d . . . . .
C55 C 0.3894(4) 0.3884(8) 0.2980(4) 0.052(2) Uani 1 1 d . . . . .
C56 C 0.3700(4) 0.2774(8) 0.2755(4) 0.045(2) Uani 1 1 d . . . . .
C57 C 0.3609(4) 0.2782(10) 0.2206(5) 0.069(3) Uani 1 1 d . . . . .
C58 C 0.3821(5) 0.1817(10) 0.1988(4) 0.057(3) Uani 1 1 d . . . . .
C59 C 0.4086(5) 0.2075(9) 0.1599(4) 0.067(3) Uani 1 1 d . . . . .
C60 C 0.4586(4) 0.1372(7) 0.1550(3) 0.044(2) Uani 1 1 d . . . . .
C61 C 0.4879(6) 0.0411(9) 0.1879(4) 0.064(3) Uani 1 1 d . . . . .
C62 C 0.5519(5) 0.0123(8) 0.2002(4) 0.054(2) Uani 1 1 d . . . . .
C63 C 0.5942(6) 0.0911(9) 0.1832(4) 0.063(3) Uani 1 1 d . . . . .
C64 C 0.5666(5) 0.1921(10) 0.1521(3) 0.056(3) Uani 1 1 d . . . . .
C65 C 0.6063(6) 0.2944(10) 0.1586(4) 0.068(3) Uani 1 1 d . . . . .
C66 C 0.5794(6) 0.4105(9) 0.1548(3) 0.057(3) Uani 1 1 d . . . . .
C67 C 0.5114(6) 0.4299(8) 0.1409(3) 0.061(3) Uani 1 1 d . . . . .
C68 C 0.4939(6) 0.5287(9) 0.1628(4) 0.068(3) Uani 1 1 d . . . . .
C69 C 0.4367(5) 0.5231(9) 0.1782(4) 0.065(3) Uani 1 1 d . . . . .
C70 C 0.3978(5) 0.4222(8) 0.1694(4) 0.060(3) Uani 1 1 d . . . . .
C71 C 0.3713(5) 0.3995(9) 0.2082(4) 0.058(3) Uani 1 1 d . . . . .
C72 C 0.4127(5) 0.3240(9) 0.1452(4) 0.065(3) Uani 1 1 d . . . . .
C73 C 0.4724(5) 0.3274(8) 0.1295(3) 0.060(3) Uani 1 1 d . . . . .
C74 C 0.4983(6) 0.2119(9) 0.1366(3) 0.063(3) Uani 1 1 d . . . . .
C75A C 0.7355(9) 0.1332(15) 0.3276(8) 0.0463(15) Uani 0.548(7) 1 d . U P A 1
C76A C 0.6936(8) 0.0396(14) 0.3175(6) 0.044(2) Uani 0.548(7) 1 d . U P A 1
C77A C 0.6634(9) 0.0118(15) 0.3567(7) 0.0463(15) Uani 0.548(7) 1 d . U P A 1
C78A C 0.6547(9) 0.0101(16) 0.2617(7) 0.045(3) Uani 0.548(7) 1 d . U P A 1
C79A C 0.5624(10) -0.0501(16) 0.3586(8) 0.054(3) Uani 0.548(7) 1 d . U P A 1
C80A C 0.4950(10) -0.0482(16) 0.3172(8) 0.057(2) Uani 0.548(7) 1 d . U P A 1
C81A C 0.4509(10) 0.0142(16) 0.3221(9) 0.057(2) Uani 0.548(7) 1 d . U P A 1
C82A C 0.4626(10) 0.0806(14) 0.3670(8) 0.055(3) Uani 0.548(7) 1 d . U P A 1
C83A C 0.5219(10) 0.0863(15) 0.4085(8) 0.053(3) Uani 0.548(7) 1 d . U P A 1
C84A C 0.5740(9) 0.0172(15) 0.3993(8) 0.051(3) Uani 0.548(7) 1 d . U P A 1
C75B C 0.7474(10) 0.1054(18) 0.3520(9) 0.0463(15) Uani 0.452(7) 1 d . U P A 2
C76B C 0.7351(10) 0.1073(19) 0.3014(9) 0.050(3) Uani 0.452(7) 1 d . U P A 2
C77B C 0.6873(11) 0.0378(19) 0.2653(9) 0.051(3) Uani 0.452(7) 1 d D U P A 2
C78B C 0.6518(8) -0.0363(18) 0.2835(6) 0.054(3) Uani 0.452(7) 1 d D U P A 2
C79B C 0.6629(10) -0.0284(18) 0.3364(7) 0.0463(15) Uani 0.452(7) 1 d D U P A 2
C80B C 0.7017(11) 0.0265(17) 0.3697(8) 0.0463(15) Uani 0.452(7) 1 d . U P A 2
C81B C 0.5820(11) 0.0069(18) 0.3746(9) 0.044(3) Uani 0.452(7) 1 d . U P A 2
C82B C 0.5140(10) 0.0299(15) 0.3630(8) 0.047(2) Uani 0.452(7) 1 d . U P A 2
C83B C 0.4682(13) 0.004(2) 0.3057(11) 0.057(2) Uani 0.452(7) 1 d . U P A 2
C84B C 0.4954(12) 0.1229(17) 0.3875(9) 0.044(3) Uani 0.452(7) 1 d . U P A 2
C85 C 0.7015(3) 0.7503(6) 0.4789(3) 0.0298(15) Uani 1 1 d . . . B 3
C86 C 0.6521(4) 0.5936(6) 0.5361(3) 0.0328(16) Uani 1 1 d . . . B 3
C87 C 0.7566(3) 0.4358(7) 0.5506(3) 0.0294(15) Uani 1 1 d . . . B 3
C88 C 0.8810(3) 0.5105(6) 0.4939(2) 0.0225(13) Uani 1 1 d . . . B 3
C89 C 0.9048(4) 0.5330(7) 0.4552(3) 0.0333(16) Uani 1 1 d . . . B 3
H89 H 0.9035 0.6099 0.4421 0.040 Uiso 1 1 calc R U . B 3
C90 C 0.9302(4) 0.4429(7) 0.4362(3) 0.0382(18) Uani 1 1 d . . . B 3
H90 H 0.9461 0.4587 0.4095 0.046 Uiso 1 1 calc R U . B 3
C91 C 0.9334(3) 0.3307(7) 0.4546(3) 0.0336(16) Uani 1 1 d . . . B 3
H91 H 0.9510 0.2698 0.4408 0.040 Uiso 1 1 calc R U . B 3
C92 C 0.9107(4) 0.3080(6) 0.4932(3) 0.0312(16) Uani 1 1 d . . . B 3
H92 H 0.9132 0.2309 0.5065 0.037 Uiso 1 1 calc R U . B 3
C93 C 0.8844(4) 0.3955(6) 0.5130(3) 0.0297(15) Uani 1 1 d . . . B 3
H93 H 0.8685 0.3784 0.5395 0.036 Uiso 1 1 calc R U . B 3
C94 C 0.8624(3) 0.7584(5) 0.4957(3) 0.0238(13) Uani 1 1 d . . . B 3
C95 C 0.9138(3) 0.8315(6) 0.5259(3) 0.0278(14) Uani 1 1 d . . . B 3
H95 H 0.9418 0.8077 0.5601 0.033 Uiso 1 1 calc R U . B 3
C96 C 0.9243(4) 0.9377(7) 0.5064(3) 0.0370(18) Uani 1 1 d . . . B 3
H96 H 0.9585 0.9873 0.5275 0.044 Uiso 1 1 calc R U . B 3
C97 C 0.8848(4) 0.9706(6) 0.4564(3) 0.0375(18) Uani 1 1 d . . . B 3
H97 H 0.8924 1.0428 0.4429 0.045 Uiso 1 1 calc R U . B 3
C98 C 0.8346(4) 0.9005(7) 0.4258(3) 0.0421(19) Uani 1 1 d . . . B 3
H98 H 0.8078 0.9244 0.3913 0.051 Uiso 1 1 calc R U . B 3
C99 C 0.8229(4) 0.7955(6) 0.4451(3) 0.0337(16) Uani 1 1 d . . . B 3
H99 H 0.7877 0.7479 0.4238 0.040 Uiso 1 1 calc R U . B 3
C100 C 0.8958(3) 0.6224(6) 0.5902(2) 0.0253(14) Uani 1 1 d . . . B 3
H10A H 0.8963 0.5435 0.6050 0.030 Uiso 1 1 calc R U . B 3
H10B H 0.9407 0.6424 0.5948 0.030 Uiso 1 1 calc R U . B 3
C101 C 0.8718(3) 0.7098(6) 0.6198(2) 0.0250(14) Uani 1 1 d . . . B 3
H10C H 0.8829 0.7897 0.6124 0.030 Uiso 1 1 calc R U . B 3
H10D H 0.8939 0.6956 0.6579 0.030 Uiso 1 1 calc R U . B 3
C102 C 0.7557(3) 0.8511(6) 0.5977(3) 0.0266(14) Uani 1 1 d . . . B 3
C103 C 0.7769(4) 0.9321(6) 0.5714(3) 0.0316(16) Uani 1 1 d . . . B 3
H103 H 0.8084 0.9101 0.5579 0.038 Uiso 1 1 calc R U . B 3
C104 C 0.7530(4) 1.0463(6) 0.5642(3) 0.0356(17) Uani 1 1 d . . . B 3
H104 H 0.7690 1.1025 0.5470 0.043 Uiso 1 1 calc R U . B 3
C105 C 0.7055(4) 1.0762(7) 0.5825(3) 0.043(2) Uani 1 1 d . . . B 3
H105 H 0.6892 1.1538 0.5784 0.052 Uiso 1 1 calc R U . B 3
C106 C 0.6823(5) 0.9947(7) 0.6064(3) 0.046(2) Uani 1 1 d . . . B 3
H106 H 0.6486 1.0155 0.6176 0.055 Uiso 1 1 calc R U . B 3
C107 C 0.7071(4) 0.8802(7) 0.6150(3) 0.0362(17) Uani 1 1 d . . . B 3
H107 H 0.6908 0.8242 0.6322 0.043 Uiso 1 1 calc R U . B 3
C108 C 0.7753(3) 0.6427(6) 0.6602(3) 0.0266(14) Uani 1 1 d . . . B 3
C109 C 0.7450(3) 0.5361(6) 0.6602(3) 0.0289(15) Uani 1 1 d . . . B 3
H109 H 0.7253 0.4936 0.6285 0.035 Uiso 1 1 calc R U . B 3
C110 C 0.7436(4) 0.4919(7) 0.7070(3) 0.0380(18) Uani 1 1 d . . . B 3
H110 H 0.7233 0.4190 0.7071 0.046 Uiso 1 1 calc R U . B 3
C111 C 0.7718(4) 0.5549(8) 0.7529(3) 0.0402(19) Uani 1 1 d . . . B 3
H111 H 0.7701 0.5257 0.7845 0.048 Uiso 1 1 calc R U . B 3
C112 C 0.8027(4) 0.6610(7) 0.7534(3) 0.0357(17) Uani 1 1 d . . . B 3
H112 H 0.8224 0.7034 0.7851 0.043 Uiso 1 1 calc R U . B 3
C113 C 0.8042(4) 0.7038(6) 0.7069(3) 0.0298(15) Uani 1 1 d . . . B 3
H113 H 0.8253 0.7759 0.7071 0.036 Uiso 1 1 calc R U . B 3
C114 C 0.5054(5) 0.8183(9) 0.4623(4) 0.055(3) Uani 1 1 d . . . C 3
O1 O 0.6856(3) 0.8373(4) 0.4591(2) 0.0410(13) Uani 1 1 d . . . B 3
O2 O 0.6074(3) 0.5911(6) 0.5461(2) 0.0474(15) Uani 1 1 d . . . B 3
O3 O 0.7708(3) 0.3462(4) 0.5704(2) 0.0346(12) Uani 1 1 d . . . B 3
P1 P 0.84397(8) 0.62146(15) 0.52034(6) 0.0218(3) Uani 1 1 d . . . B 3
P2 P 0.78217(8) 0.69858(14) 0.60037(6) 0.0225(3) Uani 1 1 d . . . B 3
S1 S 0.5624(2) 0.8822(4) 0.50036(17) 0.0984(12) Uani 1 1 d . . . C 3
S2 S 0.4424(2) 0.7540(4) 0.42503(17) 0.1189(17) Uani 1 1 d . . . C 3
W W 0.72993(2) 0.59313(2) 0.51594(2) 0.02292(10) Uani 1 1 d . . . B 3
Eu1 Eu 0.56237(9) 0.30480(12) 0.22961(5) 0.0610(4) Uani 0.3636 1 d . . P A 4
Eu2 Eu 0.48024(6) 0.29891(13) 0.25400(6) 0.0437(3) Uani 0.319 1 d . . P A 4
Eu3 Eu 0.5823(3) 0.2134(7) 0.2528(2) 0.099(3) Uani 0.1093 1 d . . P A 4
Eu4 Eu 0.5034(3) 0.2037(7) 0.2754(3) 0.086(2) Uani 0.1054 1 d . . P A 4
Eu5 Eu 0.5298(10) 0.2304(18) 0.3338(8) 0.121(6) Uiso 0.0521 1 d . . P A 4
Eu6 Eu 0.6450(6) 0.2433(12) 0.3091(5) 0.075(3) Uiso 0.0506 1 d . . P A 4


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.472(10) . ?
C1 C9 1.479(10) . ?
C1 C2 1.489(9) . ?
C1 W 2.278(7) . ?
C2 C3 1.446(10) . ?
C2 C12 1.489(10) . ?
C2 W 2.279(7) . ?
C3 C4 1.417(11) . ?
C3 C14 1.422(10) . ?
C4 C17 1.420(11) . ?
C4 C5 1.469(10) . ?
C5 C6 1.399(10) . ?
C5 C20 1.449(11) . ?
C6 C7 1.407(10) . ?
C7 C22 1.383(11) . ?
C7 C8 1.431(10) . ?
C7 Eu6 3.181(15) . ?
C8 C9 1.414(10) . ?
C8 C25 1.417(10) . ?
C9 C10 1.388(11) . ?
C10 C27 1.427(11) . ?
C10 C11 1.451(11) . ?
C11 C12 1.378(12) . ?
C11 C29 1.421(11) . ?
C12 C13 1.423(11) . ?
C13 C14 1.409(12) . ?
C13 C31 1.430(11) . ?
C14 C15 1.394(11) . ?
C15 C16 1.351(12) . ?
C15 C33 1.438(11) . ?
C15 Eu5 2.72(2) . ?
C16 C83A 1.393(18) . ?
C16 C17 1.452(12) . ?
C16 C84B 1.53(2) . ?
C16 Eu5 2.58(2) . ?
C17 C18 1.388(12) . ?
C17 Eu5 2.91(2) . ?
C18 C19 1.370(13) . ?
C18 C84A 1.43(2) . ?
C18 C81B 1.60(3) . ?
C18 Eu5 3.06(2) . ?
C19 C80B 1.40(2) . ?
C19 C20 1.422(11) . ?
C19 C77A 1.53(2) . ?
C19 Eu6 3.047(15) . ?
C20 C21 1.423(12) . ?
C20 Eu6 2.817(16) . ?
C21 C75B 1.29(2) . ?
C21 C22 1.424(11) . ?
C21 C75A 1.49(2) . ?
C21 Eu6 2.474(16) . ?
C22 C23 1.441(10) . ?
C22 Eu6 2.615(15) . ?
C23 C24 1.412(12) . ?
C23 C45 1.421(12) . ?
C23 Eu6 2.580(15) . ?
C24 C47 1.414(12) . ?
C24 C25 1.477(12) . ?
C24 Eu6 3.038(16) . ?
C25 C26 1.444(12) . ?
C26 C27 1.397(12) . ?
C26 C49 1.473(12) . ?
C27 C28 1.485(13) . ?
C28 C51 1.345(12) . ?
C28 C29 1.489(14) . ?
C29 C30 1.419(13) . ?
C30 C31 1.453(14) . ?
C30 C53 1.474(13) . ?
C31 C32 1.467(12) . ?
C32 C55 1.410(13) . ?
C32 C33 1.425(13) . ?
C32 Eu5 3.08(2) . ?
C33 C34 1.425(14) . ?
C33 Eu5 2.65(2) . ?
C34 C82A 1.38(2) . ?
C34 C35 1.418(14) . ?
C34 C84B 1.52(3) . ?
C34 Eu5 2.55(2) . ?
C34 Eu4 3.247(12) . ?
C35 C56 1.385(13) . ?
C35 C36 1.425(13) . ?
C35 Eu4 2.880(11) . ?
C35 Eu5 2.90(2) . ?
C35 Eu2 3.123(9) . ?
C36 C81A 1.36(2) . ?
C36 C37 1.401(16) . ?
C36 C83B 1.48(3) . ?
C36 Eu4 2.619(10) . ?
C36 Eu5 3.08(2) . ?
C36 Eu2 3.244(9) . ?
C37 C58 1.386(15) . ?
C37 C38 1.570(16) . ?
C37 Eu4 2.491(10) . ?
C37 Eu2 2.921(9) . ?
C38 C61 1.403(16) . ?
C38 C39 1.411(13) . ?
C38 Eu4 2.655(10) . ?
C39 C80A 1.30(2) . ?
C39 C40 1.406(16) . ?
C39 C83B 1.47(3) . ?
C39 Eu4 2.881(11) . ?
C40 C41 1.361(15) . ?
C40 C42 1.403(13) . ?
C40 C78B 2.01(2) . ?
C41 C79A 1.27(2) . ?
C41 C79B 1.37(2) . ?
C41 C77A 1.44(2) . ?
C41 C81B 1.47(3) . ?
C42 C78B 1.353(14) . ?
C42 C62 1.399(13) . ?
C42 C78A 1.47(2) . ?
C42 Eu3 2.924(12) . ?
C43 C77B 1.30(2) . ?
C43 C63 1.407(15) . ?
C43 C44 1.435(15) . ?
C43 C78A 1.49(2) . ?
C43 Eu3 2.617(10) . ?
C43 Eu6 3.117(15) . ?
C44 C46 1.361(15) . ?
C44 C45 1.387(14) . ?
C44 Eu3 2.859(12) . ?
C44 Eu6 2.893(16) . ?
C44 Eu1 3.237(9) . ?
C45 C76B 1.32(2) . ?
C45 C75A 1.57(2) . ?
C45 Eu6 2.497(16) . ?
C45 Eu3 3.250(12) . ?
C46 C65 1.466(15) . ?
C46 C47 1.467(14) . ?
C46 Eu1 2.863(9) . ?
C46 Eu3 3.033(12) . ?
C47 C48 1.433(15) . ?
C47 Eu1 3.036(10) . ?
C48 C49 1.398(14) . ?
C48 C66 1.457(14) . ?
C48 Eu1 2.862(10) . ?
C49 C50 1.477(16) . ?
C50 C51 1.408(15) . ?
C50 C68 1.440(15) . ?
C51 C52 1.458(14) . ?
C52 C53 1.415(15) . ?
C52 C69 1.431(14) . ?
C53 C54 1.436(15) . ?
C54 C55 1.440(15) . ?
C54 C71 1.454(14) . ?
C54 Eu2 2.822(10) . ?
C55 C56 1.408(12) . ?
C55 Eu2 2.928(10) . ?
C56 C57 1.451(15) . ?
C56 Eu2 2.762(8) . ?
C56 Eu4 3.100(12) . ?
C57 C58 1.426(15) . ?
C57 C71 1.472(15) . ?
C57 Eu2 2.473(9) . ?
C57 Eu4 3.069(12) . ?
C58 C59 1.445(16) . ?
C58 Eu2 2.520(9) . ?
C58 Eu4 2.729(11) . ?
C59 C72 1.408(15) . ?
C59 C60 1.427(15) . ?
C59 Eu2 2.684(9) . ?
C59 Eu4 3.074(11) . ?
C60 C61 1.416(13) . ?
C60 C74 1.458(15) . ?
C60 Eu1 3.101(8) . ?
C60 Eu3 3.150(10) . ?
C60 Eu4 3.176(10) . ?
C60 Eu2 3.184(8) . ?
C61 C62 1.376(15) . ?
C61 Eu3 2.939(12) . ?
C61 Eu4 2.967(11) . ?
C62 C63 1.508(16) . ?
C62 Eu3 2.668(11) . ?
C63 C64 1.432(14) . ?
C63 Eu3 2.477(10) . ?
C63 Eu1 2.976(9) . ?
C64 C74 1.436(15) . ?
C64 C65 1.440(16) . ?
C64 Eu1 2.536(8) . ?
C64 Eu3 2.680(10) . ?
C65 C66 1.447(15) . ?
C65 Eu1 2.517(10) . ?
C65 Eu3 3.003(13) . ?
C66 C67 1.433(16) . ?
C66 Eu1 2.551(9) . ?
C67 C68 1.409(15) . ?
C67 C73 1.423(14) . ?
C67 Eu1 2.684(9) . ?
C68 C69 1.498(17) . ?
C68 Eu1 3.185(9) . ?
C69 C70 1.410(15) . ?
C69 Eu2 3.218(9) . ?
C70 C72 1.415(14) . ?
C70 C71 1.434(16) . ?
C70 Eu2 2.742(9) . ?
C71 Eu2 2.543(9) . ?
C72 C73 1.554(17) . ?
C72 Eu2 2.810(9) . ?
C72 Eu1 3.261(10) . ?
C73 C74 1.428(14) . ?
C73 Eu1 2.731(8) . ?
C74 Eu1 2.635(9) . ?
C74 Eu3 3.028(11) . ?
C75A C76A 1.38(3) . ?
C76A C78A 1.49(2) . ?
C76A C77A 1.52(3) . ?
C79A C84A 1.31(3) . ?
C79A C80A 1.50(3) . ?
C80A C81A 1.27(3) . ?
C81A C82A 1.39(3) . ?
C82A C83A 1.38(3) . ?
C83A C84A 1.51(3) . ?
C75B C76B 1.32(3) . ?
C75B C80B 1.58(3) . ?
C76B C77B 1.40(3) . ?
C77B C78B 1.384(16) . ?
C78B C79B 1.387(16) . ?
C79B C80B 1.17(3) . ?
C81B C82B 1.45(3) . ?
C82B C84B 1.41(3) . ?
C82B C83B 1.55(3) . ?
C85 O1 1.126(9) . ?
C85 W 2.048(7) . ?
C86 O2 1.137(10) . ?
C86 W 2.023(8) . ?
C87 O3 1.148(9) . ?
C87 W 2.020(8) . ?
C88 C89 1.391(10) . ?
C88 C93 1.410(9) . ?
C88 P1 1.819(7) . ?
C89 C90 1.378(11) . ?
C89 H89 0.9500 . ?
C90 C91 1.374(11) . ?
C90 H90 0.9500 . ?
C91 C92 1.373(10) . ?
C91 H91 0.9500 . ?
C92 C93 1.379(10) . ?
C92 H92 0.9500 . ?
C93 H93 0.9500 . ?
C94 C99 1.402(9) . ?
C94 C95 1.405(9) . ?
C94 P1 1.820(7) . ?
C95 C96 1.387(10) . ?
C95 H95 0.9500 . ?
C96 C97 1.372(11) . ?
C96 H96 0.9500 . ?
C97 C98 1.373(11) . ?
C97 H97 0.9500 . ?
C98 C99 1.382(10) . ?
C98 H98 0.9500 . ?
C99 H99 0.9500 . ?
C100 C101 1.516(9) . ?
C100 P1 1.828(6) . ?
C100 H10A 0.9900 . ?
C100 H10B 0.9900 . ?
C101 P2 1.867(7) . ?
C101 H10C 0.9900 . ?
C101 H10D 0.9900 . ?
C102 C103 1.373(10) . ?
C102 C107 1.386(10) . ?
C102 P2 1.837(7) . ?
C103 C104 1.399(10) . ?
C103 H103 0.9500 . ?
C104 C105 1.385(12) . ?
C104 H104 0.9500 . ?
C105 C106 1.358(12) . ?
C105 H105 0.9500 . ?
C106 C107 1.409(11) . ?
C106 H106 0.9500 . ?
C107 H107 0.9500 . ?
C108 C113 1.390(10) . ?
C108 C109 1.396(10) . ?
C108 P2 1.835(7) . ?
C109 C110 1.401(10) . ?
C109 H109 0.9500 . ?
C110 C111 1.382(12) . ?
C110 H110 0.9500 . ?
C111 C112 1.395(12) . ?
C111 H111 0.9500 . ?
C112 C113 1.387(10) . ?
C112 H112 0.9500 . ?
C113 H113 0.9500 . ?
C114 S1 1.492(12) . ?
C114 S2 1.568(12) . ?
P1 W 2.5259(17) . ?
P2 W 2.4820(16) . ?
Eu1 Eu3 1.218(8) . ?
Eu1 Eu2 2.189(2) . ?
Eu1 Eu6 2.366(14) . ?
Eu1 Eu4 2.445(6) . ?
Eu2 Eu4 1.253(8) . ?
Eu2 Eu5 2.19(2) . ?
Eu2 Eu3 2.495(6) . ?
Eu3 Eu6 1.679(15) . ?
Eu3 Eu4 2.091(11) . ?
Eu3 Eu5 2.91(2) . ?
Eu4 Eu5 1.52(2) . ?
Eu4 Eu6 2.970(15) . ?
Eu5 Eu6 2.91(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C9 103.1(6) . . ?
C6 C1 C2 116.4(6) . . ?
C9 C1 C2 116.2(6) . . ?
C6 C1 W 123.1(5) . . ?
C9 C1 W 124.7(5) . . ?
C2 C1 W 71.0(4) . . ?
C3 C2 C12 104.8(6) . . ?
C3 C2 C1 118.1(6) . . ?
C12 C2 C1 116.5(6) . . ?
C3 C2 W 121.4(5) . . ?
C12 C2 W 122.6(5) . . ?
C1 C2 W 70.9(4) . . ?
C4 C3 C14 121.1(7) . . ?
C4 C3 C2 123.8(6) . . ?
C14 C3 C2 107.8(7) . . ?
C3 C4 C17 116.7(7) . . ?
C3 C4 C5 117.9(6) . . ?
C17 C4 C5 118.9(7) . . ?
C6 C5 C20 116.8(7) . . ?
C6 C5 C4 119.7(7) . . ?
C20 C5 C4 117.2(6) . . ?
C5 C6 C7 121.7(7) . . ?
C5 C6 C1 123.3(6) . . ?
C7 C6 C1 108.4(6) . . ?
C22 C7 C6 121.5(7) . . ?
C22 C7 C8 120.7(7) . . ?
C6 C7 C8 109.5(7) . . ?
C22 C7 Eu6 53.8(4) . . ?
C6 C7 Eu6 94.1(5) . . ?
C8 C7 Eu6 97.3(5) . . ?
C9 C8 C25 122.0(7) . . ?
C9 C8 C7 106.7(6) . . ?
C25 C8 C7 121.8(7) . . ?
C10 C9 C8 118.8(6) . . ?
C10 C9 C1 123.7(7) . . ?
C8 C9 C1 110.2(6) . . ?
C9 C10 C27 119.9(7) . . ?
C9 C10 C11 119.5(7) . . ?
C27 C10 C11 109.5(7) . . ?
C12 C11 C29 119.5(8) . . ?
C12 C11 C10 119.3(7) . . ?
C29 C11 C10 109.4(7) . . ?
C11 C12 C13 120.1(7) . . ?
C11 C12 C2 123.7(7) . . ?
C13 C12 C2 108.3(7) . . ?
C14 C13 C12 107.6(7) . . ?
C14 C13 C31 121.7(8) . . ?
C12 C13 C31 121.9(8) . . ?
C15 C14 C13 121.5(7) . . ?
C15 C14 C3 120.8(8) . . ?
C13 C14 C3 109.8(7) . . ?
C16 C15 C14 118.1(7) . . ?
C16 C15 C33 114.7(8) . . ?
C14 C15 C33 119.6(8) . . ?
C16 C15 Eu5 69.5(7) . . ?
C14 C15 Eu5 101.5(7) . . ?
C33 C15 Eu5 71.6(6) . . ?
C15 C16 C83A 128.7(11) . . ?
C15 C16 C17 122.7(8) . . ?
C83A C16 C17 103.5(11) . . ?
C15 C16 C84B 99.9(11) . . ?
C17 C16 C84B 122.7(11) . . ?
C15 C16 Eu5 81.1(7) . . ?
C17 C16 Eu5 87.6(7) . . ?
C18 C17 C4 121.8(8) . . ?
C18 C17 C16 114.0(8) . . ?
C4 C17 C16 118.9(8) . . ?
C18 C17 Eu5 82.8(7) . . ?
C4 C17 Eu5 100.7(6) . . ?
C16 C17 Eu5 62.5(6) . . ?
C19 C18 C17 120.6(8) . . ?
C19 C18 C84A 130.0(12) . . ?
C17 C18 C84A 105.4(11) . . ?
C19 C18 C81B 102.1(11) . . ?
C17 C18 C81B 125.4(11) . . ?
C19 C18 Eu5 103.8(6) . . ?
C17 C18 Eu5 70.4(6) . . ?
C18 C19 C80B 134.0(13) . . ?
C18 C19 C20 121.4(8) . . ?
C80B C19 C20 101.3(12) . . ?
C18 C19 C77A 103.5(10) . . ?
C20 C19 C77A 124.1(10) . . ?
C18 C19 Eu6 105.3(6) . . ?
C20 C19 Eu6 67.1(5) . . ?
C19 C20 C21 114.2(8) . . ?
C19 C20 C5 120.0(7) . . ?
C21 C20 C5 120.1(7) . . ?
C19 C20 Eu6 85.2(6) . . ?
C21 C20 Eu6 61.4(5) . . ?
C5 C20 Eu6 99.1(5) . . ?
C75B C21 C20 108.0(13) . . ?
C75B C21 C22 127.6(13) . . ?
C20 C21 C22 120.3(7) . . ?
C20 C21 C75A 124.2(11) . . ?
C22 C21 C75A 101.9(10) . . ?
C20 C21 Eu6 88.3(6) . . ?
C22 C21 Eu6 79.3(5) . . ?
C7 C22 C21 118.2(7) . . ?
C7 C22 C23 119.6(7) . . ?
C21 C22 C23 114.2(7) . . ?
C7 C22 Eu6 100.9(5) . . ?
C21 C22 Eu6 68.4(5) . . ?
C23 C22 Eu6 72.5(5) . . ?
C24 C23 C45 121.3(8) . . ?
C24 C23 C22 120.1(7) . . ?
C45 C23 C22 110.5(8) . . ?
C24 C23 Eu6 94.5(6) . . ?
C45 C23 Eu6 70.6(6) . . ?
C22 C23 Eu6 75.3(5) . . ?
C23 C24 C47 117.0(8) . . ?
C23 C24 C25 120.6(7) . . ?
C47 C24 C25 117.5(9) . . ?
C23 C24 Eu6 57.9(5) . . ?
C47 C24 Eu6 93.2(6) . . ?
C25 C24 Eu6 97.5(5) . . ?
C8 C25 C26 119.2(7) . . ?
C8 C25 C24 116.3(7) . . ?
C26 C25 C24 119.6(7) . . ?
C27 C26 C25 117.5(7) . . ?
C27 C26 C49 116.7(9) . . ?
C25 C26 C49 119.9(8) . . ?
C26 C27 C10 122.5(8) . . ?
C26 C27 C28 121.3(8) . . ?
C10 C27 C28 106.2(8) . . ?
C51 C28 C27 121.3(10) . . ?
C51 C28 C29 121.3(9) . . ?
C27 C28 C29 107.6(7) . . ?
C30 C29 C11 122.5(8) . . ?
C30 C29 C28 120.6(8) . . ?
C11 C29 C28 106.5(8) . . ?
C29 C30 C31 118.2(8) . . ?
C29 C30 C53 115.8(9) . . ?
C31 C30 C53 120.2(8) . . ?
C13 C31 C30 117.8(8) . . ?
C13 C31 C32 115.8(8) . . ?
C30 C31 C32 121.0(8) . . ?
C55 C32 C33 115.9(8) . . ?
C55 C32 C31 117.7(9) . . ?
C33 C32 C31 121.8(7) . . ?
C55 C32 Eu5 91.3(6) . . ?
C33 C32 Eu5 59.0(6) . . ?
C31 C32 Eu5 98.9(6) . . ?
C34 C33 C32 120.7(8) . . ?
C34 C33 C15 112.5(9) . . ?
C32 C33 C15 118.8(8) . . ?
C34 C33 Eu5 70.3(7) . . ?
C32 C33 Eu5 93.6(7) . . ?
C15 C33 Eu5 77.4(7) . . ?
C82A C34 C35 99.0(12) . . ?
C82A C34 C33 133.0(12) . . ?
C35 C34 C33 121.2(9) . . ?
C35 C34 C84B 125.6(12) . . ?
C33 C34 C84B 98.3(11) . . ?
C35 C34 Eu5 89.3(7) . . ?
C33 C34 Eu5 78.0(7) . . ?
C35 C34 Eu4 62.5(5) . . ?
C33 C34 Eu4 96.1(5) . . ?
Eu5 C34 Eu4 27.2(5) . . ?
C56 C35 C34 117.6(8) . . ?
C56 C35 C36 121.3(9) . . ?
C34 C35 C36 113.1(9) . . ?
C56 C35 Eu4 85.7(5) . . ?
C34 C35 Eu4 91.6(5) . . ?
C36 C35 Eu4 65.0(5) . . ?
C56 C35 Eu5 96.1(6) . . ?
C34 C35 Eu5 61.5(6) . . ?
C36 C35 Eu5 83.3(7) . . ?
Eu4 C35 Eu5 30.5(4) . . ?
C56 C35 Eu2 62.1(5) . . ?
C34 C35 Eu2 100.4(5) . . ?
C36 C35 Eu2 81.9(5) . . ?
Eu4 C35 Eu2 23.64(17) . . ?
Eu5 C35 Eu2 42.5(4) . . ?
C81A C36 C37 129.3(14) . . ?
C81A C36 C35 104.8(12) . . ?
C37 C36 C35 119.1(10) . . ?
C37 C36 C83B 101.1(14) . . ?
C35 C36 C83B 125.0(13) . . ?
C37 C36 Eu4 69.1(5) . . ?
C35 C36 Eu4 85.4(5) . . ?
C37 C36 Eu5 98.7(7) . . ?
C35 C36 Eu5 69.3(6) . . ?
Eu4 C36 Eu5 29.6(4) . . ?
C37 C36 Eu2 64.2(5) . . ?
C35 C36 Eu2 72.4(5) . . ?
Eu4 C36 Eu2 21.5(2) . . ?
Eu5 C36 Eu2 40.5(4) . . ?
C58 C37 C36 121.9(11) . . ?
C58 C37 C38 120.6(11) . . ?
C36 C37 C38 109.7(9) . . ?
C58 C37 Eu4 84.4(6) . . ?
C36 C37 Eu4 79.2(5) . . ?
C38 C37 Eu4 78.0(5) . . ?
C58 C37 Eu2 59.6(5) . . ?
C36 C37 Eu2 90.2(6) . . ?
C38 C37 Eu2 95.3(5) . . ?
Eu4 C37 Eu2 25.2(2) . . ?
C61 C38 C39 121.0(11) . . ?
C61 C38 C37 119.8(9) . . ?
C39 C38 C37 110.3(10) . . ?
C61 C38 Eu4 88.4(5) . . ?
C39 C38 Eu4 84.3(5) . . ?
C37 C38 Eu4 66.6(5) . . ?
C80A C39 C40 99.9(12) . . ?
C80A C39 C38 133.7(14) . . ?
C40 C39 C38 121.0(11) . . ?
C40 C39 C83B 125.1(13) . . ?
C38 C39 C83B 100.5(14) . . ?
C40 C39 Eu4 97.3(6) . . ?
C38 C39 Eu4 66.5(5) . . ?
C41 C40 C42 117.9(11) . . ?
C41 C40 C39 116.7(11) . . ?
C42 C40 C39 116.9(10) . . ?
C41 C40 C78B 76.7(9) . . ?
C42 C40 C78B 42.2(6) . . ?
C39 C40 C78B 154.4(9) . . ?
C79A C41 C40 102.2(13) . . ?
C40 C41 C79B 104.2(13) . . ?
C79A C41 C77A 122.9(14) . . ?
C40 C41 C77A 125.8(12) . . ?
C40 C41 C81B 123.4(13) . . ?
C79B C41 C81B 119.8(14) . . ?
C78B C42 C62 138.4(13) . . ?
C78B C42 C40 93.6(11) . . ?
C62 C42 C40 121.1(10) . . ?
C62 C42 C78A 104.6(11) . . ?
C40 C42 C78A 122.6(11) . . ?
C62 C42 Eu3 65.5(5) . . ?
C40 C42 Eu3 97.7(6) . . ?
C77B C43 C63 133.5(15) . . ?
C77B C43 C44 100.7(13) . . ?
C63 C43 C44 119.0(10) . . ?
C63 C43 C78A 102.6(11) . . ?
C44 C43 C78A 126.2(10) . . ?
C63 C43 Eu3 68.5(5) . . ?
C44 C43 Eu3 84.4(5) . . ?
C63 C43 Eu6 101.1(6) . . ?
C44 C43 Eu6 67.6(5) . . ?
Eu3 C43 Eu6 32.6(3) . . ?
C46 C44 C45 118.0(10) . . ?
C46 C44 C43 120.8(10) . . ?
C45 C44 C43 113.5(10) . . ?
C46 C44 Eu3 83.9(6) . . ?
C45 C44 Eu3 93.4(6) . . ?
C43 C44 Eu3 65.7(5) . . ?
C46 C44 Eu6 96.8(6) . . ?
C45 C44 Eu6 59.6(6) . . ?
C43 C44 Eu6 85.1(6) . . ?
Eu3 C44 Eu6 33.9(3) . . ?
C46 C44 Eu1 62.0(5) . . ?
C45 C44 Eu1 101.6(5) . . ?
C43 C44 Eu1 81.2(5) . . ?
Eu3 C44 Eu1 21.95(19) . . ?
Eu6 C44 Eu1 45.0(3) . . ?
C76B C45 C44 101.3(13) . . ?
C76B C45 C23 131.2(13) . . ?
C44 C45 C23 121.8(10) . . ?
C44 C45 C75A 123.1(11) . . ?
C23 C45 C75A 102.0(9) . . ?
C44 C45 Eu6 91.7(7) . . ?
C23 C45 Eu6 77.0(5) . . ?
C44 C45 Eu3 61.4(5) . . ?
C23 C45 Eu3 96.7(5) . . ?
Eu6 C45 Eu3 30.5(3) . . ?
C44 C46 C65 121.6(10) . . ?
C44 C46 C47 122.1(8) . . ?
C65 C46 C47 106.4(9) . . ?
C44 C46 Eu1 93.2(6) . . ?
C65 C46 Eu1 61.5(5) . . ?
C47 C46 Eu1 82.3(5) . . ?
C44 C46 Eu3 69.6(5) . . ?
C65 C46 Eu3 74.8(5) . . ?
C47 C46 Eu3 96.5(5) . . ?
Eu1 C46 Eu3 23.62(15) . . ?
C24 C47 C48 123.0(9) . . ?
C24 C47 C46 119.4(9) . . ?
C48 C47 C46 108.4(9) . . ?
C24 C47 Eu1 99.6(5) . . ?
C48 C47 Eu1 69.3(6) . . ?
C46 C47 Eu1 69.1(5) . . ?
C49 C48 C47 120.2(9) . . ?
C49 C48 C66 123.4(11) . . ?
C47 C48 C66 109.1(9) . . ?
C49 C48 Eu1 96.3(6) . . ?
C47 C48 Eu1 82.8(6) . . ?
C66 C48 Eu1 62.8(5) . . ?
C48 C49 C26 119.5(9) . . ?
C48 C49 C50 114.9(9) . . ?
C26 C49 C50 119.0(9) . . ?
C51 C50 C68 107.3(10) . . ?
C51 C50 C49 120.8(8) . . ?
C68 C50 C49 121.3(10) . . ?
C28 C51 C50 119.9(11) . . ?
C28 C51 C52 119.7(10) . . ?
C50 C51 C52 111.7(9) . . ?
C53 C52 C69 123.2(9) . . ?
C53 C52 C51 119.8(8) . . ?
C69 C52 C51 105.3(10) . . ?
C52 C53 C54 116.4(9) . . ?
C52 C53 C30 121.7(9) . . ?
C54 C53 C30 116.3(10) . . ?
C53 C54 C55 122.8(9) . . ?
C53 C54 C71 118.9(11) . . ?
C55 C54 C71 109.3(10) . . ?
C53 C54 Eu2 95.0(6) . . ?
C55 C54 Eu2 79.6(5) . . ?
C71 C54 Eu2 63.9(5) . . ?
C56 C55 C32 122.9(9) . . ?
C56 C55 C54 107.2(9) . . ?
C32 C55 C54 121.4(9) . . ?
C56 C55 Eu2 69.2(5) . . ?
C32 C55 Eu2 98.1(5) . . ?
C54 C55 Eu2 71.5(5) . . ?
C35 C56 C55 121.1(8) . . ?
C35 C56 C57 118.2(9) . . ?
C55 C56 C57 110.5(9) . . ?
C35 C56 Eu2 91.5(5) . . ?
C55 C56 Eu2 82.3(5) . . ?
C57 C56 Eu2 63.2(5) . . ?
C35 C56 Eu4 67.9(5) . . ?
C55 C56 Eu4 96.5(5) . . ?
C57 C56 Eu4 75.2(5) . . ?
Eu2 C56 Eu4 23.78(14) . . ?
C58 C57 C56 120.3(10) . . ?
C58 C57 C71 121.6(11) . . ?
C56 C57 C71 106.2(9) . . ?
C58 C57 Eu2 75.2(5) . . ?
C56 C57 Eu2 85.3(5) . . ?
C71 C57 Eu2 75.6(5) . . ?
C58 C57 Eu4 62.8(5) . . ?
C56 C57 Eu4 77.6(5) . . ?
C71 C57 Eu4 98.6(6) . . ?
Eu2 C57 Eu4 23.06(15) . . ?
C37 C58 C57 118.7(10) . . ?
C37 C58 C59 117.3(10) . . ?
C57 C58 C59 117.1(11) . . ?
C37 C58 Eu2 92.1(6) . . ?
C57 C58 Eu2 71.6(5) . . ?
C59 C58 Eu2 80.2(6) . . ?
C37 C58 Eu4 65.3(5) . . ?
C57 C58 Eu4 89.5(6) . . ?
C59 C58 Eu4 89.4(6) . . ?
Eu2 C58 Eu4 27.24(18) . . ?
C72 C59 C60 111.5(11) . . ?
C72 C59 C58 120.0(11) . . ?
C60 C59 C58 121.1(10) . . ?
C72 C59 Eu2 80.2(5) . . ?
C60 C59 Eu2 96.7(5) . . ?
C58 C59 Eu2 67.7(5) . . ?
C72 C59 Eu4 102.6(6) . . ?
C60 C59 Eu4 80.8(5) . . ?
C58 C59 Eu4 62.6(5) . . ?
Eu2 C59 Eu4 23.92(17) . . ?
C61 C60 C59 124.2(10) . . ?
C61 C60 C74 119.2(9) . . ?
C59 C60 C74 107.8(9) . . ?
C61 C60 Eu1 90.8(5) . . ?
C59 C60 Eu1 89.9(5) . . ?
C74 C60 Eu1 58.0(4) . . ?
C61 C60 Eu3 68.4(5) . . ?
C59 C60 Eu3 102.8(5) . . ?
C74 C60 Eu3 71.7(5) . . ?
Eu1 C60 Eu3 22.45(17) . . ?
C61 C60 Eu4 68.6(5) . . ?
C59 C60 Eu4 72.8(5) . . ?
C74 C60 Eu4 103.7(5) . . ?
Eu1 C60 Eu4 45.84(15) . . ?
Eu3 C60 Eu4 38.6(2) . . ?
C61 C60 Eu2 91.3(5) . . ?
C59 C60 Eu2 56.8(4) . . ?
C74 C60 Eu2 92.8(5) . . ?
Eu1 C60 Eu2 40.74(10) . . ?
Eu3 C60 Eu2 46.39(14) . . ?
Eu4 C60 Eu2 22.71(16) . . ?
C62 C61 C38 117.4(10) . . ?
C62 C61 C60 121.5(11) . . ?
C38 C61 C60 116.5(11) . . ?
C62 C61 Eu3 65.0(5) . . ?
C38 C61 Eu3 99.9(5) . . ?
C60 C61 Eu3 85.0(6) . . ?
C62 C61 Eu4 99.6(5) . . ?
C38 C61 Eu4 63.4(5) . . ?
C60 C61 Eu4 85.1(5) . . ?
Eu3 C61 Eu4 41.5(2) . . ?
C61 C62 C42 122.2(11) . . ?
C61 C62 C63 119.8(9) . . ?
C42 C62 C63 109.0(9) . . ?
C61 C62 Eu3 87.1(6) . . ?
C42 C62 Eu3 86.0(5) . . ?
C63 C62 Eu3 66.1(5) . . ?
C43 C63 C64 121.6(10) . . ?
C43 C63 C62 110.7(9) . . ?
C64 C63 C62 119.6(10) . . ?
C43 C63 Eu3 79.5(5) . . ?
C64 C63 Eu3 81.9(6) . . ?
C62 C63 Eu3 80.1(6) . . ?
C43 C63 Eu1 91.9(5) . . ?
C64 C63 Eu1 58.3(5) . . ?
C62 C63 Eu1 94.3(5) . . ?
Eu3 C63 Eu1 23.6(2) . . ?
C63 C64 C74 117.9(10) . . ?
C63 C64 C65 118.8(10) . . ?
C74 C64 C65 116.2(10) . . ?
C63 C64 Eu1 93.0(5) . . ?
C74 C64 Eu1 77.7(5) . . ?
C65 C64 Eu1 72.7(5) . . ?
C63 C64 Eu3 66.2(5) . . ?
C74 C64 Eu3 89.5(6) . . ?
C65 C64 Eu3 88.3(5) . . ?
Eu1 C64 Eu3 26.83(18) . . ?
C64 C65 C66 121.4(11) . . ?
C64 C65 C46 117.9(10) . . ?
C66 C65 C46 109.1(9) . . ?
C64 C65 Eu1 74.2(6) . . ?
C66 C65 Eu1 74.7(5) . . ?
C46 C65 Eu1 87.8(5) . . ?
C64 C65 Eu3 63.1(5) . . ?
C66 C65 Eu3 98.0(6) . . ?
C46 C65 Eu3 77.1(5) . . ?
Eu1 C65 Eu3 23.44(15) . . ?
C67 C66 C65 122.0(10) . . ?
C67 C66 C48 120.7(10) . . ?
C65 C66 C48 107.0(10) . . ?
C67 C66 Eu1 79.3(6) . . ?
C65 C66 Eu1 72.1(5) . . ?
C48 C66 Eu1 86.6(5) . . ?
C68 C67 C73 120.6(12) . . ?
C68 C67 C66 116.9(10) . . ?
C73 C67 C66 115.3(9) . . ?
C68 C67 Eu1 97.2(6) . . ?
C73 C67 Eu1 76.6(5) . . ?
C66 C67 Eu1 69.1(5) . . ?
C67 C68 C50 122.2(12) . . ?
C67 C68 C69 119.9(10) . . ?
C50 C68 C69 106.9(9) . . ?
C67 C68 Eu1 56.7(5) . . ?
C50 C68 Eu1 89.8(6) . . ?
C69 C68 Eu1 94.1(5) . . ?
C70 C69 C52 121.6(11) . . ?
C70 C69 C68 121.6(10) . . ?
C52 C69 C68 108.6(9) . . ?
C70 C69 Eu2 57.9(5) . . ?
C52 C69 Eu2 88.9(5) . . ?
C68 C69 Eu2 98.3(5) . . ?
C69 C70 C72 119.4(12) . . ?
C69 C70 C71 115.1(10) . . ?
C72 C70 C71 116.9(10) . . ?
C69 C70 Eu2 96.3(5) . . ?
C72 C70 Eu2 77.9(5) . . ?
C71 C70 Eu2 66.7(5) . . ?
C70 C71 C54 123.8(10) . . ?
C70 C71 C57 119.6(10) . . ?
C54 C71 C57 106.6(10) . . ?
C70 C71 Eu2 82.1(6) . . ?
C54 C71 Eu2 85.2(5) . . ?
C57 C71 Eu2 70.3(5) . . ?
C59 C72 C70 124.2(12) . . ?
C59 C72 C73 105.3(9) . . ?
C70 C72 C73 119.8(10) . . ?
C59 C72 Eu2 70.3(5) . . ?
C70 C72 Eu2 72.6(5) . . ?
C73 C72 Eu2 98.0(5) . . ?
C59 C72 Eu1 83.9(6) . . ?
C70 C72 Eu1 94.6(5) . . ?
C73 C72 Eu1 56.5(4) . . ?
Eu2 C72 Eu1 41.44(12) . . ?
C67 C73 C74 123.6(11) . . ?
C67 C73 C72 118.6(9) . . ?
C74 C73 C72 106.5(9) . . ?
C67 C73 Eu1 73.0(5) . . ?
C74 C73 Eu1 70.9(5) . . ?
C72 C73 Eu1 95.1(5) . . ?
C73 C74 C64 121.0(10) . . ?
C73 C74 C60 108.9(10) . . ?
C64 C74 C60 121.6(9) . . ?
C73 C74 Eu1 78.3(5) . . ?
C64 C74 Eu1 70.1(5) . . ?
C60 C74 Eu1 94.1(5) . . ?
C73 C74 Eu3 101.1(5) . . ?
C64 C74 Eu3 62.2(5) . . ?
C60 C74 Eu3 81.1(5) . . ?
Eu1 C74 Eu3 23.55(17) . . ?
C76A C75A C21 121.4(17) . . ?
C76A C75A C45 120.7(16) . . ?
C21 C75A C45 110.9(12) . . ?
C75A C76A C78A 117.7(17) . . ?
C75A C76A C77A 118.3(16) . . ?
C78A C76A C77A 116.8(16) . . ?
C41 C77A C76A 116.3(15) . . ?
C41 C77A C19 123.5(14) . . ?
C76A C77A C19 116.5(15) . . ?
C42 C78A C76A 118.8(16) . . ?
C42 C78A C43 112.8(13) . . ?
C76A C78A C43 117.9(15) . . ?
C41 C79A C84A 118.8(19) . . ?
C41 C79A C80A 109.4(17) . . ?
C84A C79A C80A 117.1(18) . . ?
C81A C80A C39 116(2) . . ?
C81A C80A C79A 121.3(19) . . ?
C39 C80A C79A 109.6(18) . . ?
C80A C81A C36 121(2) . . ?
C80A C81A C82A 121(2) . . ?
C36 C81A C82A 106.9(16) . . ?
C83A C82A C34 110.1(16) . . ?
C83A C82A C81A 123.8(19) . . ?
C34 C82A C81A 115.0(17) . . ?
C82A C83A C16 119.8(17) . . ?
C82A C83A C84A 113.1(17) . . ?
C16 C83A C84A 109.5(14) . . ?
C79A C84A C18 120.8(19) . . ?
C79A C84A C83A 123.2(18) . . ?
C18 C84A C83A 106.5(14) . . ?
C21 C75B C76B 119(2) . . ?
C21 C75B C80B 106.2(16) . . ?
C76B C75B C80B 117(2) . . ?
C75B C76B C45 116(2) . . ?
C75B C76B C77B 122(2) . . ?
C45 C76B C77B 111.2(18) . . ?
C43 C77B C78B 119(2) . . ?
C43 C77B C76B 112.0(19) . . ?
C78B C77B C76B 119(2) . . ?
C42 C78B C77B 108.9(17) . . ?
C42 C78B C79B 119.1(16) . . ?
C77B C78B C79B 116.8(18) . . ?
C42 C78B C40 44.2(7) . . ?
C77B C78B C40 145.1(16) . . ?
C79B C78B C40 76.3(13) . . ?
C80B C79B C41 122(2) . . ?
C80B C79B C78B 130(2) . . ?
C41 C79B C78B 102.8(16) . . ?
C79B C80B C19 121(2) . . ?
C79B C80B C75B 116(2) . . ?
C19 C80B C75B 108.9(16) . . ?
C82B C81B C41 121.7(19) . . ?
C82B C81B C18 115.2(18) . . ?
C41 C81B C18 119.9(16) . . ?
C84B C82B C81B 121(2) . . ?
C84B C82B C83B 116(2) . . ?
C81B C82B C83B 114(2) . . ?
C39 C83B C36 118(2) . . ?
C39 C83B C82B 117(2) . . ?
C36 C83B C82B 119(2) . . ?
C82B C84B C34 120.2(19) . . ?
C82B C84B C16 120.2(19) . . ?
C34 C84B C16 114.0(14) . . ?
O1 C85 W 178.8(7) . . ?
O2 C86 W 177.6(6) . . ?
O3 C87 W 179.0(6) . . ?
C89 C88 C93 118.7(6) . . ?
C89 C88 P1 123.3(5) . . ?
C93 C88 P1 118.0(5) . . ?
C90 C89 C88 119.5(7) . . ?
C90 C89 H89 120.2 . . ?
C88 C89 H89 120.2 . . ?
C91 C90 C89 121.9(7) . . ?
C91 C90 H90 119.1 . . ?
C89 C90 H90 119.1 . . ?
C92 C91 C90 119.0(7) . . ?
C92 C91 H91 120.5 . . ?
C90 C91 H91 120.5 . . ?
C91 C92 C93 120.9(7) . . ?
C91 C92 H92 119.5 . . ?
C93 C92 H92 119.5 . . ?
C92 C93 C88 120.0(7) . . ?
C92 C93 H93 120.0 . . ?
C88 C93 H93 120.0 . . ?
C99 C94 C95 117.8(6) . . ?
C99 C94 P1 119.3(5) . . ?
C95 C94 P1 122.9(5) . . ?
C96 C95 C94 121.0(7) . . ?
C96 C95 H95 119.5 . . ?
C94 C95 H95 119.5 . . ?
C97 C96 C95 119.5(7) . . ?
C97 C96 H96 120.2 . . ?
C95 C96 H96 120.2 . . ?
C96 C97 C98 120.8(7) . . ?
C96 C97 H97 119.6 . . ?
C98 C97 H97 119.6 . . ?
C97 C98 C99 120.3(7) . . ?
C97 C98 H98 119.9 . . ?
C99 C98 H98 119.9 . . ?
C98 C99 C94 120.6(7) . . ?
C98 C99 H99 119.7 . . ?
C94 C99 H99 119.7 . . ?
C101 C100 P1 111.3(5) . . ?
C101 C100 H10A 109.4 . . ?
P1 C100 H10A 109.4 . . ?
C101 C100 H10B 109.4 . . ?
P1 C100 H10B 109.4 . . ?
H10A C100 H10B 108.0 . . ?
C100 C101 P2 111.3(4) . . ?
C100 C101 H10C 109.4 . . ?
P2 C101 H10C 109.4 . . ?
C100 C101 H10D 109.4 . . ?
P2 C101 H10D 109.4 . . ?
H10C C101 H10D 108.0 . . ?
C103 C102 C107 119.9(7) . . ?
C103 C102 P2 119.4(6) . . ?
C107 C102 P2 119.9(6) . . ?
C102 C103 C104 121.1(7) . . ?
C102 C103 H103 119.5 . . ?
C104 C103 H103 119.5 . . ?
C105 C104 C103 119.0(7) . . ?
C105 C104 H104 120.5 . . ?
C103 C104 H104 120.5 . . ?
C106 C105 C104 120.0(7) . . ?
C106 C105 H105 120.0 . . ?
C104 C105 H105 120.0 . . ?
C105 C106 C107 121.5(8) . . ?
C105 C106 H106 119.2 . . ?
C107 C106 H106 119.2 . . ?
C102 C107 C106 118.4(7) . . ?
C102 C107 H107 120.8 . . ?
C106 C107 H107 120.8 . . ?
C113 C108 C109 119.4(6) . . ?
C113 C108 P2 119.4(5) . . ?
C109 C108 P2 121.1(5) . . ?
C108 C109 C110 120.1(7) . . ?
C108 C109 H109 119.9 . . ?
C110 C109 H109 119.9 . . ?
C111 C110 C109 119.5(7) . . ?
C111 C110 H110 120.2 . . ?
C109 C110 H110 120.2 . . ?
C110 C111 C112 120.8(7) . . ?
C110 C111 H111 119.6 . . ?
C112 C111 H111 119.6 . . ?
C113 C112 C111 119.2(7) . . ?
C113 C112 H112 120.4 . . ?
C111 C112 H112 120.4 . . ?
C112 C113 C108 120.9(7) . . ?
C112 C113 H113 119.5 . . ?
C108 C113 H113 119.5 . . ?
S1 C114 S2 175.5(7) . . ?
C88 P1 C94 104.4(3) . . ?
C88 P1 C100 103.2(3) . . ?
C94 P1 C100 104.4(3) . . ?
C88 P1 W 120.0(2) . . ?
C94 P1 W 117.6(2) . . ?
C100 P1 W 105.4(2) . . ?
C108 P2 C102 103.2(3) . . ?
C108 P2 C101 102.8(3) . . ?
C102 P2 C101 103.9(3) . . ?
C108 P2 W 120.3(2) . . ?
C102 P2 W 113.5(2) . . ?
C101 P2 W 111.4(2) . . ?
C87 W C86 89.9(3) . . ?
C87 W C85 178.4(3) . . ?
C86 W C85 90.2(3) . . ?
C87 W C1 90.7(3) . . ?
C86 W C1 111.2(3) . . ?
C85 W C1 87.8(3) . . ?
C87 W C2 89.5(3) . . ?
C86 W C2 73.1(3) . . ?
C85 W C2 89.0(3) . . ?
C1 W C2 38.2(2) . . ?
C87 W P2 92.48(19) . . ?
C86 W P2 83.13(19) . . ?
C85 W P2 89.12(19) . . ?
C1 W P2 165.33(18) . . ?
C2 W P2 156.12(17) . . ?
C87 W P1 89.2(2) . . ?
C86 W P1 161.18(19) . . ?
C85 W P1 91.3(2) . . ?
C1 W P1 87.60(18) . . ?
C2 W P1 125.71(17) . . ?
P2 W P1 78.13(6) . . ?
Eu3 Eu1 Eu2 89.5(4) . . ?
Eu3 Eu1 Eu6 42.3(5) . . ?
Eu2 Eu1 Eu6 98.7(3) . . ?
Eu3 Eu1 Eu4 58.8(4) . . ?
Eu2 Eu1 Eu4 30.7(2) . . ?
Eu6 Eu1 Eu4 76.2(4) . . ?
Eu3 Eu1 C65 101.3(4) . . ?
Eu2 Eu1 C65 150.1(3) . . ?
Eu6 Eu1 C65 108.1(4) . . ?
Eu4 Eu1 C65 146.5(3) . . ?
Eu3 Eu1 C64 83.2(4) . . ?
Eu2 Eu1 C64 123.8(3) . . ?
Eu6 Eu1 C64 111.2(4) . . ?
Eu4 Eu1 C64 113.7(3) . . ?
C65 Eu1 C64 33.1(4) . . ?
Eu3 Eu1 C66 134.1(4) . . ?
Eu2 Eu1 C66 132.2(3) . . ?
Eu6 Eu1 C66 125.9(4) . . ?
Eu4 Eu1 C66 157.7(3) . . ?
C65 Eu1 C66 33.2(3) . . ?
C64 Eu1 C66 59.3(3) . . ?
Eu3 Eu1 C74 96.6(4) . . ?
Eu2 Eu1 C74 94.9(3) . . ?
Eu6 Eu1 C74 136.1(4) . . ?
Eu4 Eu1 C74 96.6(3) . . ?
C65 Eu1 C74 56.5(4) . . ?
C64 Eu1 C74 32.2(3) . . ?
C66 Eu1 C74 66.2(3) . . ?
Eu3 Eu1 C67 151.5(3) . . ?
Eu2 Eu1 C67 100.9(3) . . ?
Eu6 Eu1 C67 155.6(4) . . ?
Eu4 Eu1 C67 127.1(3) . . ?
C65 Eu1 C67 57.8(4) . . ?
C64 Eu1 C67 68.9(3) . . ?
C66 Eu1 C67 31.6(4) . . ?
C74 Eu1 C67 56.4(3) . . ?
Eu3 Eu1 C73 126.2(4) . . ?
Eu2 Eu1 C73 86.5(3) . . ?
Eu6 Eu1 C73 166.8(4) . . ?
Eu4 Eu1 C73 103.7(3) . . ?
C65 Eu1 C73 64.6(4) . . ?
C64 Eu1 C73 56.3(3) . . ?
C66 Eu1 C73 54.2(3) . . ?
C74 Eu1 C73 30.8(3) . . ?
C67 Eu1 C73 30.5(3) . . ?
Eu3 Eu1 C46 86.0(4) . . ?
Eu2 Eu1 C46 175.3(2) . . ?
Eu6 Eu1 C46 78.8(4) . . ?
Eu4 Eu1 C46 144.7(3) . . ?
C65 Eu1 C46 30.8(3) . . ?
C64 Eu1 C46 54.5(3) . . ?
C66 Eu1 C46 51.6(3) . . ?
C74 Eu1 C46 84.5(3) . . ?
C67 Eu1 C46 82.6(3) . . ?
C73 Eu1 C46 95.2(3) . . ?
Eu3 Eu1 C48 130.7(5) . . ?
Eu2 Eu1 C48 136.1(2) . . ?
Eu6 Eu1 C48 101.9(4) . . ?
Eu4 Eu1 C48 162.4(3) . . ?
C65 Eu1 C48 50.9(3) . . ?
C64 Eu1 C48 83.5(3) . . ?
C66 Eu1 C48 30.5(3) . . ?
C74 Eu1 C48 96.5(3) . . ?
C67 Eu1 C48 53.7(3) . . ?
C73 Eu1 C48 82.2(3) . . ?
C46 Eu1 C48 48.5(3) . . ?
Eu4 Eu2 Eu1 86.0(3) . . ?
Eu4 Eu2 Eu5 42.2(6) . . ?
Eu1 Eu2 Eu5 99.4(5) . . ?
Eu4 Eu2 C57 106.3(4) . . ?
Eu1 Eu2 C57 143.2(3) . . ?
Eu5 Eu2 C57 113.1(6) . . ?
Eu4 Eu2 Eu3 56.8(4) . . ?
Eu1 Eu2 Eu3 29.2(2) . . ?
Eu5 Eu2 Eu3 76.4(6) . . ?
C57 Eu2 Eu3 144.8(3) . . ?
Eu4 Eu2 C58 85.7(4) . . ?
Eu1 Eu2 C58 117.8(2) . . ?
Eu5 Eu2 C58 113.6(6) . . ?
C57 Eu2 C58 33.2(4) . . ?
Eu3 Eu2 C58 111.6(3) . . ?
Eu4 Eu2 C71 140.3(4) . . ?
Eu1 Eu2 C71 126.0(3) . . ?
Eu5 Eu2 C71 132.5(6) . . ?
C57 Eu2 C71 34.1(4) . . ?
Eu3 Eu2 C71 151.0(3) . . ?
C58 Eu2 C71 60.0(3) . . ?
Eu4 Eu2 C59 95.8(4) . . ?
Eu1 Eu2 C59 88.3(3) . . ?
Eu5 Eu2 C59 135.6(6) . . ?
C57 Eu2 C59 56.6(4) . . ?
Eu3 Eu2 C59 92.2(3) . . ?
C58 Eu2 C59 32.1(3) . . ?
C71 Eu2 C59 66.3(3) . . ?
Eu4 Eu2 C70 150.3(3) . . ?
Eu1 Eu2 C70 95.0(3) . . ?
Eu5 Eu2 C70 162.2(6) . . ?
C57 Eu2 C70 57.3(4) . . ?
Eu3 Eu2 C70 120.4(3) . . ?
C58 Eu2 C70 67.5(3) . . ?
C71 Eu2 C70 31.2(4) . . ?
C59 Eu2 C70 54.7(3) . . ?
Eu4 Eu2 C56 93.4(4) . . ?
Eu1 Eu2 C56 173.97(19) . . ?
Eu5 Eu2 C56 84.1(6) . . ?
C57 Eu2 C56 31.6(3) . . ?
Eu3 Eu2 C56 149.9(3) . . ?
C58 Eu2 C56 56.2(3) . . ?
C71 Eu2 C56 52.1(3) . . ?
C59 Eu2 C56 85.8(3) . . ?
C70 Eu2 C56 82.4(3) . . ?
Eu4 Eu2 C72 123.1(4) . . ?
Eu1 Eu2 C72 80.4(3) . . ?
Eu5 Eu2 C72 164.9(6) . . ?
C57 Eu2 C72 63.7(4) . . ?
Eu3 Eu2 C72 98.0(3) . . ?
C58 Eu2 C72 54.9(4) . . ?
C71 Eu2 C72 53.7(3) . . ?
C59 Eu2 C72 29.6(3) . . ?
C70 Eu2 C72 29.5(3) . . ?
C56 Eu2 C72 94.9(3) . . ?
Eu4 Eu2 C54 138.4(4) . . ?
Eu1 Eu2 C54 133.7(3) . . ?
Eu5 Eu2 C54 107.7(6) . . ?
C57 Eu2 C54 52.1(4) . . ?
Eu3 Eu2 C54 160.5(3) . . ?
C58 Eu2 C54 84.6(3) . . ?
C71 Eu2 C54 30.9(3) . . ?
C59 Eu2 C54 97.0(3) . . ?
C70 Eu2 C54 54.5(3) . . ?
C56 Eu2 C54 48.5(3) . . ?
C72 Eu2 C54 82.2(3) . . ?
Eu1 Eu3 Eu6 108.5(7) . . ?
Eu1 Eu3 Eu4 91.4(4) . . ?
Eu6 Eu3 Eu4 103.4(6) . . ?
Eu1 Eu3 C63 101.8(4) . . ?
Eu6 Eu3 C63 122.2(6) . . ?
Eu4 Eu3 C63 124.0(5) . . ?
Eu1 Eu3 Eu2 61.3(3) . . ?
Eu6 Eu3 Eu2 110.3(5) . . ?
Eu4 Eu3 Eu2 30.1(2) . . ?
C63 Eu3 Eu2 127.4(4) . . ?
Eu1 Eu3 C43 115.9(5) . . ?
Eu6 Eu3 C43 90.3(6) . . ?
Eu4 Eu3 C43 144.0(5) . . ?
C63 Eu3 C43 31.9(3) . . ?
Eu2 Eu3 C43 159.2(3) . . ?
Eu1 Eu3 C62 119.4(4) . . ?
Eu6 Eu3 C62 128.8(6) . . ?
Eu4 Eu3 C62 92.9(4) . . ?
C63 Eu3 C62 33.8(4) . . ?
Eu2 Eu3 C62 107.8(4) . . ?
C43 Eu3 C62 54.0(3) . . ?
Eu1 Eu3 C64 70.0(4) . . ?
Eu6 Eu3 C64 135.1(7) . . ?
Eu4 Eu3 C64 121.4(4) . . ?
C63 Eu3 C64 31.9(3) . . ?
Eu2 Eu3 C64 107.3(3) . . ?
C43 Eu3 C64 55.8(3) . . ?
C62 Eu3 C64 56.7(3) . . ?
Eu1 Eu3 C44 96.8(6) . . ?
Eu6 Eu3 C44 74.2(6) . . ?
Eu4 Eu3 C44 171.9(5) . . ?
C63 Eu3 C44 54.1(4) . . ?
Eu2 Eu3 C44 158.0(5) . . ?
C43 Eu3 C44 30.0(3) . . ?
C62 Eu3 C44 83.0(4) . . ?
C64 Eu3 C44 62.0(3) . . ?
Eu1 Eu3 Eu5 100.0(5) . . ?
Eu6 Eu3 Eu5 73.3(6) . . ?
Eu4 Eu3 Eu5 30.1(5) . . ?
C63 Eu3 Eu5 146.4(6) . . ?
Eu2 Eu3 Eu5 47.1(4) . . ?
C43 Eu3 Eu5 143.8(6) . . ?
C62 Eu3 Eu5 112.6(6) . . ?
C64 Eu3 Eu5 151.2(6) . . ?
C44 Eu3 Eu5 146.7(5) . . ?
Eu1 Eu3 C42 147.9(4) . . ?
Eu6 Eu3 C42 101.8(6) . . ?
Eu4 Eu3 C42 91.9(5) . . ?
C63 Eu3 C42 51.2(4) . . ?
Eu2 Eu3 C42 117.5(4) . . ?
C43 Eu3 C42 52.4(4) . . ?
C62 Eu3 C42 28.5(3) . . ?
C64 Eu3 C42 81.2(4) . . ?
C44 Eu3 C42 81.1(4) . . ?
Eu5 Eu3 C42 98.7(6) . . ?
Eu1 Eu3 C61 103.1(4) . . ?
Eu6 Eu3 C61 148.0(7) . . ?
Eu4 Eu3 C61 70.0(4) . . ?
C63 Eu3 C61 54.1(4) . . ?
Eu2 Eu3 C61 80.1(3) . . ?
C43 Eu3 C61 80.7(4) . . ?
C62 Eu3 C61 27.9(3) . . ?
C64 Eu3 C61 62.0(4) . . ?
C44 Eu3 C61 107.8(4) . . ?
Eu5 Eu3 C61 96.1(6) . . ?
C42 Eu3 C61 49.0(3) . . ?
Eu2 Eu4 Eu5 104.3(10) . . ?
Eu2 Eu4 Eu3 93.1(4) . . ?
Eu5 Eu4 Eu3 106.3(9) . . ?
Eu2 Eu4 Eu1 63.2(3) . . ?
Eu5 Eu4 Eu1 112.9(8) . . ?
Eu3 Eu4 Eu1 29.9(2) . . ?
Eu2 Eu4 C37 97.0(4) . . ?
Eu5 Eu4 C37 124.0(9) . . ?
Eu3 Eu4 C37 123.8(5) . . ?
Eu1 Eu4 C37 123.0(4) . . ?
Eu2 Eu4 C36 108.6(5) . . ?
Eu5 Eu4 C36 92.3(9) . . ?
Eu3 Eu4 C36 147.1(5) . . ?
Eu1 Eu4 C36 154.6(4) . . ?
C37 Eu4 C36 31.7(4) . . ?
Eu2 Eu4 C38 119.1(4) . . ?
Eu5 Eu4 C38 131.3(9) . . ?
Eu3 Eu4 C38 93.1(4) . . ?
Eu1 Eu4 C38 106.1(4) . . ?
C37 Eu4 C38 35.3(4) . . ?
C36 Eu4 C38 54.9(4) . . ?
Eu2 Eu4 C58 67.1(4) . . ?
Eu5 Eu4 C58 134.7(9) . . ?
Eu3 Eu4 C58 118.2(4) . . ?
Eu1 Eu4 C58 102.4(3) . . ?
C37 Eu4 C58 30.4(3) . . ?
C36 Eu4 C58 54.2(3) . . ?
C38 Eu4 C58 57.0(3) . . ?
Eu2 Eu4 C35 89.1(5) . . ?
Eu5 Eu4 C35 75.5(9) . . ?
Eu3 Eu4 C35 176.6(4) . . ?
Eu1 Eu4 C35 152.2(4) . . ?
C37 Eu4 C35 53.4(4) . . ?
C36 Eu4 C35 29.5(3) . . ?
C38 Eu4 C35 83.6(3) . . ?
C58 Eu4 C35 60.5(3) . . ?
Eu2 Eu4 C39 147.8(4) . . ?
Eu5 Eu4 C39 103.7(9) . . ?
Eu3 Eu4 C39 94.0(5) . . ?
Eu1 Eu4 C39 118.5(4) . . ?
C37 Eu4 C39 53.6(4) . . ?
C36 Eu4 C39 54.6(4) . . ?
C38 Eu4 C39 29.2(3) . . ?
C58 Eu4 C39 82.0(3) . . ?
C35 Eu4 C39 82.7(3) . . ?
Eu2 Eu4 C61 105.4(4) . . ?
Eu5 Eu4 C61 150.2(9) . . ?
Eu3 Eu4 C61 68.5(4) . . ?
Eu1 Eu4 C61 77.9(3) . . ?
C37 Eu4 C61 55.4(4) . . ?
C36 Eu4 C61 81.7(4) . . ?
C38 Eu4 C61 28.2(3) . . ?
C58 Eu4 C61 62.7(3) . . ?
C35 Eu4 C61 108.4(3) . . ?
C39 Eu4 C61 49.5(3) . . ?
Eu2 Eu4 Eu6 102.1(4) . . ?
Eu5 Eu4 Eu6 73.0(9) . . ?
Eu3 Eu4 Eu6 33.4(3) . . ?
Eu1 Eu4 Eu6 50.7(3) . . ?
C37 Eu4 Eu6 150.2(5) . . ?
C36 Eu4 Eu6 148.4(5) . . ?
C38 Eu4 Eu6 114.9(5) . . ?
C58 Eu4 Eu6 151.1(4) . . ?
C35 Eu4 Eu6 148.3(4) . . ?
C39 Eu4 Eu6 101.0(4) . . ?
C61 Eu4 Eu6 97.2(4) . . ?
Eu4 Eu5 Eu2 33.6(6) . . ?
Eu4 Eu5 C34 102.9(11) . . ?
Eu2 Eu5 C34 100.6(8) . . ?
Eu4 Eu5 C16 155.1(13) . . ?
Eu2 Eu5 C16 155.8(10) . . ?
C34 Eu5 C16 59.7(5) . . ?
Eu4 Eu5 C33 121.7(12) . . ?
Eu2 Eu5 C33 102.5(8) . . ?
C34 Eu5 C33 31.8(4) . . ?
C16 Eu5 C33 53.4(5) . . ?
Eu4 Eu5 C15 152.8(13) . . ?
Eu2 Eu5 C15 128.5(9) . . ?
C34 Eu5 C15 53.6(5) . . ?
C16 Eu5 C15 29.4(3) . . ?
C33 Eu5 C15 31.0(3) . . ?
Eu4 Eu5 C35 74.0(9) . . ?
Eu2 Eu5 C35 74.1(6) . . ?
C34 Eu5 C35 29.3(4) . . ?
C16 Eu5 C35 88.5(7) . . ?
C33 Eu5 C35 52.8(5) . . ?
C15 Eu5 C35 80.9(6) . . ?
Eu4 Eu5 C17 152.2(12) . . ?
Eu2 Eu5 C17 166.9(10) . . ?
C34 Eu5 C17 89.0(7) . . ?
C16 Eu5 C17 29.9(3) . . ?
C33 Eu5 C17 81.1(6) . . ?
C15 Eu5 C17 51.7(5) . . ?
C35 Eu5 C17 117.0(7) . . ?
Eu4 Eu5 Eu3 43.6(6) . . ?
Eu2 Eu5 Eu3 56.4(5) . . ?
C34 Eu5 Eu3 146.0(9) . . ?
C16 Eu5 Eu3 147.5(9) . . ?
C33 Eu5 Eu3 158.4(9) . . ?
C15 Eu5 Eu3 160.0(9) . . ?
C35 Eu5 Eu3 117.5(8) . . ?
C17 Eu5 Eu3 118.4(7) . . ?
Eu4 Eu5 Eu6 77.1(9) . . ?
Eu2 Eu5 Eu6 83.9(7) . . ?
C34 Eu5 Eu6 171.9(9) . . ?
C16 Eu5 Eu6 117.5(8) . . ?
C33 Eu5 Eu6 153.9(9) . . ?
C15 Eu5 Eu6 128.3(8) . . ?
C35 Eu5 Eu6 150.8(9) . . ?
C17 Eu5 Eu6 87.6(7) . . ?
Eu3 Eu5 Eu6 33.5(4) . . ?
Eu4 Eu5 C18 125.5(11) . . ?
Eu2 Eu5 C18 155.0(9) . . ?
C34 Eu5 C18 98.5(7) . . ?
C16 Eu5 C18 49.0(4) . . ?
C33 Eu5 C18 102.2(7) . . ?
C15 Eu5 C18 76.2(6) . . ?
C35 Eu5 C18 119.3(7) . . ?
C17 Eu5 C18 26.7(3) . . ?
Eu3 Eu5 C18 99.1(7) . . ?
Eu6 Eu5 C18 75.4(6) . . ?
Eu4 Eu5 C36 58.2(7) . . ?
Eu2 Eu5 C36 73.8(6) . . ?
C34 Eu5 C36 48.7(5) . . ?
C16 Eu5 C36 98.5(7) . . ?
C33 Eu5 C36 78.1(6) . . ?
C15 Eu5 C36 102.0(7) . . ?
C35 Eu5 C36 27.4(3) . . ?
C17 Eu5 C36 119.3(7) . . ?
Eu3 Eu5 C36 97.9(7) . . ?
Eu6 Eu5 C36 127.6(8) . . ?
C18 Eu5 C36 108.1(7) . . ?
Eu3 Eu6 Eu1 29.2(4) . . ?
Eu3 Eu6 C21 152.6(8) . . ?
Eu1 Eu6 C21 161.1(7) . . ?
Eu3 Eu6 C45 100.4(7) . . ?
Eu1 Eu6 C45 101.6(5) . . ?
C21 Eu6 C45 61.1(4) . . ?
Eu3 Eu6 C23 118.9(7) . . ?
Eu1 Eu6 C23 104.7(5) . . ?
C21 Eu6 C23 56.8(4) . . ?
C45 Eu6 C23 32.5(3) . . ?
Eu3 Eu6 C22 151.1(8) . . ?
Eu1 Eu6 C22 132.3(6) . . ?
C21 Eu6 C22 32.3(3) . . ?
C45 Eu6 C22 54.7(4) . . ?
C23 Eu6 C22 32.2(3) . . ?
Eu3 Eu6 C20 151.1(8) . . ?
Eu1 Eu6 C20 167.0(6) . . ?
C21 Eu6 C20 30.3(3) . . ?
C45 Eu6 C20 91.0(5) . . ?
C23 Eu6 C20 84.3(5) . . ?
C22 Eu6 C20 53.9(3) . . ?
Eu3 Eu6 C44 71.9(5) . . ?
Eu1 Eu6 C44 75.2(4) . . ?
C21 Eu6 C44 88.9(5) . . ?
C45 Eu6 C44 28.6(3) . . ?
C23 Eu6 C44 52.9(4) . . ?
C22 Eu6 C44 81.6(5) . . ?
C20 Eu6 C44 117.7(5) . . ?
Eu3 Eu6 Eu5 73.2(7) . . ?
Eu1 Eu6 Eu5 77.9(6) . . ?
C21 Eu6 Eu5 120.7(7) . . ?
C45 Eu6 Eu5 167.9(7) . . ?
C23 Eu6 Eu5 159.5(7) . . ?
C22 Eu6 Eu5 134.0(7) . . ?
C20 Eu6 Eu5 90.4(6) . . ?
C44 Eu6 Eu5 144.4(7) . . ?
Eu3 Eu6 Eu4 43.2(4) . . ?
Eu1 Eu6 Eu4 53.1(3) . . ?
C21 Eu6 Eu4 145.5(6) . . ?
C45 Eu6 Eu4 142.3(6) . . ?
C23 Eu6 Eu4 157.7(6) . . ?
C22 Eu6 Eu4 162.8(6) . . ?
C20 Eu6 Eu4 117.2(5) . . ?
C44 Eu6 Eu4 114.8(5) . . ?
Eu5 Eu6 Eu4 29.9(5) . . ?
Eu3 Eu6 C24 103.3(7) . . ?
Eu1 Eu6 C24 81.3(4) . . ?
C21 Eu6 C24 81.6(5) . . ?
C45 Eu6 C24 51.9(4) . . ?
C23 Eu6 C24 27.6(3) . . ?
C22 Eu6 C24 51.2(3) . . ?
C20 Eu6 C24 104.6(5) . . ?
C44 Eu6 C24 58.2(4) . . ?
Eu5 Eu6 C24 138.8(7) . . ?
Eu4 Eu6 C24 131.7(5) . . ?
Eu3 Eu6 C19 123.4(7) . . ?
Eu1 Eu6 C19 147.9(6) . . ?
C21 Eu6 C19 50.0(4) . . ?
C45 Eu6 C19 101.0(5) . . ?
C23 Eu6 C19 106.7(5) . . ?
C22 Eu6 C19 79.7(4) . . ?
C20 Eu6 C19 27.7(3) . . ?
C44 Eu6 C19 119.6(5) . . ?
Eu5 Eu6 C19 75.3(5) . . ?
Eu4 Eu6 C19 95.6(4) . . ?
C24 Eu6 C19 130.8(5) . . ?

_refine_diff_density_max         2.563
_refine_diff_density_min         -2.095
_refine_diff_density_rms         0.163

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_lb191
_database_code_depnum_ccdc_archive 'CCDC 1579799'
loop_
_audit_author_name
_audit_author_address
'Lipiao Bao' 'Huazhong University of Science and Technology'
_audit_update_record             
;
2017-10-24 deposited with the CCDC.	2019-04-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        Eu@C2(5)-C82-W
_chemical_name_common            Eu@C2(5)-C82-W
_chemical_melting_point          ?
_chemical_formula_moiety         'C111 H24 Eu O3 P2 W, C S2'
_chemical_formula_sum            'C112 H24 Eu O3 P2 S2 W'
_chemical_formula_weight         1879.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0027 0.0014 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0093 0.0052 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0898 0.0807 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1098 0.1057 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1666 3.2045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.5343 6.0454 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   22.367(2)
_cell_length_b                   11.2378(10)
_cell_length_c                   27.520(3)
_cell_angle_alpha                90
_cell_angle_beta                 112.0420(10)
_cell_angle_gamma                90
_cell_volume                     6411.8(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9900
_cell_measurement_theta_min      2.593
_cell_measurement_theta_max      25.761

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.947
_exptl_crystal_F_000             3676
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    2.343
_shelx_estimated_absorpt_T_min   0.540
_shelx_estimated_absorpt_T_max   0.912
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_correction_T_min  0.4555
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.6525
_diffrn_radiation_type           synchrotron
_diffrn_source                   'SSRF, Beamline B17B1'
_diffrn_measurement_device_type  'CCD MX-300'
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            111667
_diffrn_reflns_av_unetI/netI     0.0304
_diffrn_reflns_av_R_equivalents  0.0502
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         0.924
_diffrn_reflns_theta_max         25.763
_diffrn_reflns_theta_full        23.048
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measured_fraction_theta_full 0.977
_diffrn_reflns_Laue_measured_fraction_max 0.970
_diffrn_reflns_Laue_measured_fraction_full 0.977
_diffrn_reflns_point_group_measured_fraction_max 0.970
_diffrn_reflns_point_group_measured_fraction_full 0.977
_reflns_number_total             15400
_reflns_number_gt                14259
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0694P)²+31.3620P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15400
_refine_ls_number_parameters     1118
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0480
_refine_ls_R_factor_gt           0.0448
_refine_ls_wR_factor_ref         0.1248
_refine_ls_wR_factor_gt          0.1207
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C18A C 0.5190(8) 0.6836(12) 0.2840(5) 0.0383(13) Uani 0.365(6) 1 d . . P A 1
C19A C 0.5735(8) 0.6877(13) 0.2675(6) 0.0383(13) Uani 0.365(6) 1 d . . P A 1
C28A C 0.6721(5) 0.1223(10) 0.4219(5) 0.0336(10) Uani 0.365(6) 1 d D . P A 1
C29A C 0.6454(5) 0.0267(11) 0.3843(4) 0.0336(10) Uani 0.365(6) 1 d D . P A 1
C18B C 0.5222(4) 0.6629(7) 0.2402(3) 0.0383(13) Uani 0.635(6) 1 d . . P A 2
C19B C 0.5614(5) 0.6897(7) 0.2878(4) 0.0383(13) Uani 0.635(6) 1 d . . P A 2
C28B C 0.6862(4) 0.0797(6) 0.4044(3) 0.0336(10) Uani 0.635(6) 1 d . . P A 2
C29B C 0.6354(4) 0.0719(6) 0.4176(3) 0.0336(10) Uani 0.635(6) 1 d . . P A 2
C1 C 0.70875(17) 0.5058(3) 0.43622(13) 0.0173(7) Uani 1 1 d . . . . .
C2 C 0.65107(18) 0.5005(4) 0.45013(14) 0.0179(7) Uani 1 1 d . . . . .
C3 C 0.59355(19) 0.5658(4) 0.41727(15) 0.0213(7) Uani 1 1 d . . . . .
C4 C 0.5926(2) 0.6440(4) 0.37742(16) 0.0235(8) Uani 1 1 d . . . . .
C5 C 0.6491(2) 0.6498(4) 0.36258(15) 0.0218(8) Uani 1 1 d . . . . .
C6 C 0.70236(19) 0.5762(4) 0.38940(15) 0.0188(7) Uani 1 1 d . . . . .
C7 C 0.73476(18) 0.5175(4) 0.36106(14) 0.0195(7) Uani 1 1 d . . . . .
C8 C 0.75643(18) 0.4030(4) 0.38594(15) 0.0200(8) Uani 1 1 d . . . . .
C9 C 0.73642(18) 0.3920(4) 0.42881(14) 0.0183(7) Uani 1 1 d . . . . .
C10 C 0.7175(2) 0.2805(4) 0.44141(15) 0.0230(8) Uani 1 1 d D . . . .
C11 C 0.6612(2) 0.2753(4) 0.45634(15) 0.0246(8) Uani 1 1 d D . . . .
C12 C 0.62772(19) 0.3820(4) 0.45673(14) 0.0210(8) Uani 1 1 d . . . . .
C13 C 0.5594(2) 0.3844(5) 0.43669(15) 0.0277(9) Uani 1 1 d . . . . .
C14 C 0.5383(2) 0.4971(4) 0.41177(17) 0.0280(9) Uani 1 1 d . . . . .
C15 C 0.4794(2) 0.5080(5) 0.3687(2) 0.0368(11) Uani 1 1 d . . . . .
C16 C 0.4767(3) 0.5960(5) 0.3315(3) 0.0535(19) Uani 1 1 d . . . . .
C17 C 0.5331(2) 0.6622(4) 0.33549(19) 0.0345(11) Uani 1 1 d . . . . .
C20 C 0.6332(2) 0.6702(4) 0.30842(16) 0.0274(9) Uani 1 1 d . . . . .
C21 C 0.6663(3) 0.6115(5) 0.27960(17) 0.0377(12) Uani 1 1 d . . . . .
C22 C 0.7171(2) 0.5321(4) 0.30624(16) 0.0268(9) Uani 1 1 d . . . . .
C23 C 0.7287(2) 0.4340(5) 0.27781(17) 0.0295(9) Uani 1 1 d . . . . .
C24 C 0.7519(2) 0.3229(5) 0.30250(18) 0.0296(9) Uani 1 1 d . . . . .
C25 C 0.7631(2) 0.3035(4) 0.35691(17) 0.0270(9) Uani 1 1 d . . . . .
C26 C 0.7501(2) 0.1902(4) 0.3728(2) 0.0335(10) Uani 1 1 d . . . . .
C27 C 0.7272(2) 0.1801(4) 0.41455(16) 0.0263(8) Uani 1 1 d D . . . .
C30 C 0.6232(3) 0.1705(4) 0.44299(18) 0.0400(12) Uani 1 1 d D . . . .
C31 C 0.5543(3) 0.1745(5) 0.4273(2) 0.0509(17) Uani 1 1 d . . . . .
C32 C 0.5219(3) 0.2804(5) 0.42002(19) 0.0415(13) Uani 1 1 d . . . . .
C33 C 0.4583(2) 0.2910(5) 0.37876(19) 0.0377(12) Uani 1 1 d . . . . .
C34 C 0.4377(2) 0.4039(5) 0.3532(2) 0.0345(11) Uani 1 1 d . . . . .
C35 C 0.3905(2) 0.4005(5) 0.3019(2) 0.0387(12) Uani 1 1 d . . . . .
C36 C 0.3916(2) 0.4860(6) 0.2632(3) 0.0514(16) Uani 1 1 d . . . . .
C37 C 0.4342(3) 0.5817(5) 0.2770(3) 0.066(2) Uani 1 1 d . . . . .
C38 C 0.4595(3) 0.6248(7) 0.2421(5) 0.077(3) Uani 1 1 d . . . . .
C39 C 0.4509(4) 0.5614(10) 0.1949(6) 0.104(5) Uani 1 1 d . . . . .
C40 C 0.5056(4) 0.5651(9) 0.1770(4) 0.085(3) Uani 1 1 d . . . . .
C41 C 0.5597(4) 0.6302(6) 0.2130(3) 0.063(2) Uani 1 1 d . . . . .
C42 C 0.6244(3) 0.5902(5) 0.22508(19) 0.0431(14) Uani 1 1 d . . . . .
C43 C 0.6359(3) 0.4907(5) 0.19773(16) 0.0386(12) Uani 1 1 d . . . . .
C44 C 0.6900(3) 0.4153(5) 0.22373(19) 0.0359(12) Uani 1 1 d . . . . .
C45 C 0.6894(3) 0.2886(6) 0.2138(2) 0.0473(15) Uani 1 1 d . . . . .
C46 C 0.7283(3) 0.2291(5) 0.2649(2) 0.0414(13) Uani 1 1 d . . . . .
C47 C 0.7106(3) 0.1165(6) 0.2807(3) 0.0486(15) Uani 1 1 d . . . . .
C48 C 0.7226(3) 0.0985(5) 0.3339(3) 0.0477(15) Uani 1 1 d . . . . .
C49 C 0.6804(3) 0.0250(5) 0.3503(3) 0.0556(18) Uani 1 1 d D . . . .
C50 C 0.6233(4) -0.0221(6) 0.3151(4) 0.070(2) Uani 1 1 d D . . . .
C51 C 0.5680(3) -0.0277(6) 0.3298(4) 0.080(3) Uani 1 1 d D . . . .
C52 C 0.5770(3) 0.0151(6) 0.3815(3) 0.0577(18) Uani 1 1 d D . . . .
C53 C 0.5289(4) 0.0726(7) 0.3909(3) 0.072(3) Uani 1 1 d . . . . .
C54 C 0.4687(3) 0.0801(6) 0.3544(3) 0.0557(18) Uani 1 1 d . . . . .
C55 C 0.4315(2) 0.1853(6) 0.3510(2) 0.0419(13) Uani 1 1 d . . . . .
C56 C 0.3865(2) 0.1872(6) 0.2987(2) 0.0427(13) Uani 1 1 d . . . . .
C57 C 0.3661(2) 0.2925(6) 0.2757(2) 0.0409(12) Uani 1 1 d . . . . .
C58 C 0.3564(2) 0.3115(7) 0.2198(2) 0.0505(15) Uani 1 1 d . . . . .
C59 C 0.3754(2) 0.4299(6) 0.2133(2) 0.0498(16) Uani 1 1 d . . . . .
C60 C 0.4078(3) 0.4597(8) 0.1802(3) 0.064(2) Uani 1 1 d . . . . .
C61 C 0.4212(3) 0.3618(8) 0.1501(2) 0.062(2) Uani 1 1 d . . . . .
C62 C 0.4759(3) 0.3680(9) 0.1350(2) 0.068(2) Uani 1 1 d . . . . .
C63 C 0.5180(3) 0.4714(8) 0.1499(3) 0.066(2) Uani 1 1 d . . . . .
C64 C 0.5820(3) 0.4352(7) 0.15870(18) 0.0463(14) Uani 1 1 d . . . . .
C65 C 0.5815(3) 0.3050(7) 0.1498(2) 0.0562(18) Uani 1 1 d . . . . .
C66 C 0.6324(3) 0.2322(7) 0.1784(2) 0.0560(19) Uani 1 1 d . . . . .
C67 C 0.6185(4) 0.1146(7) 0.1925(3) 0.063(2) Uani 1 1 d . . . . .
C68 C 0.6557(3) 0.0580(6) 0.2428(3) 0.0550(18) Uani 1 1 d . . . . .
C69 C 0.6128(3) -0.0103(5) 0.2610(4) 0.065(2) Uani 1 1 d . . . . .
C70 C 0.5487(4) 0.0008(5) 0.2201(4) 0.063(2) Uani 1 1 d . . . . .
C71 C 0.4925(3) -0.0032(5) 0.2333(3) 0.0559(18) Uani 1 1 d . . . . .
C72 C 0.5020(3) -0.0197(5) 0.2884(3) 0.0556(17) Uani 1 1 d . . . . .
C73 C 0.4534(3) 0.0271(5) 0.3034(3) 0.0463(14) Uani 1 1 d . . . . .
C74 C 0.4004(3) 0.0910(5) 0.2690(3) 0.0463(15) Uani 1 1 d . . . . .
C75 C 0.3923(3) 0.1077(6) 0.2190(3) 0.0481(15) Uani 1 1 d . . . . .
C76 C 0.3695(3) 0.2236(8) 0.1928(2) 0.0576(19) Uani 1 1 d . . . . .
C77 C 0.4013(3) 0.2483(7) 0.1583(2) 0.0508(16) Uani 1 1 d . . . . .
C78 C 0.4416(3) 0.1458(7) 0.1607(2) 0.0565(18) Uani 1 1 d . . . . .
C79 C 0.4996(3) 0.1538(7) 0.1509(2) 0.0567(19) Uani 1 1 d . . . . .
C80 C 0.5146(3) 0.2671(8) 0.13540(19) 0.0567(19) Uani 1 1 d . . . . .
C81 C 0.5511(3) 0.0768(6) 0.1788(3) 0.059(2) Uani 1 1 d . . . . .
C82 C 0.4381(3) 0.0624(6) 0.2007(3) 0.0525(17) Uani 1 1 d . . . . .
Eu1 Eu 0.62259(7) 0.27578(18) 0.27291(5) 0.0379(3) Uani 0.406 1 d . . P A 1
Eu2 Eu 0.60740(5) 0.34226(12) 0.25633(4) 0.0389(2) Uani 0.3 1 d . . P A 1
Eu3 Eu 0.50277(17) 0.2692(4) 0.30606(17) 0.1009(13) Uani 0.157 1 d . . P A 1
Eu4 Eu 0.6332(3) 0.2730(7) 0.2878(3) 0.104(3) Uani 0.137 1 d . . P A 1
C83 C 0.75990(19) 0.4298(4) 0.55100(14) 0.0191(7) Uani 1 1 d . . . B 2
C84 C 0.6551(2) 0.5898(3) 0.53786(15) 0.0204(8) Uani 1 1 d . . . B 2
C85 C 0.70442(18) 0.7488(4) 0.48154(14) 0.0208(7) Uani 1 1 d . . . B 2
C86 C 0.88317(17) 0.5077(4) 0.49344(14) 0.0185(7) Uani 1 1 d . . . B 2
C87 C 0.9040(2) 0.5308(4) 0.45273(16) 0.0241(8) Uani 1 1 d . . . B 2
H87 H 0.901342 0.609149 0.439074 0.029 Uiso 1 1 calc R U . B 2
C88 C 0.9287(2) 0.4387(5) 0.43205(19) 0.0313(10) Uani 1 1 d . . . B 2
H88 H 0.942145 0.454441 0.403796 0.038 Uiso 1 1 calc R U . B 2
C89 C 0.9339(2) 0.3248(4) 0.45204(18) 0.0284(9) Uani 1 1 d . . . B 2
H89 H 0.950584 0.262417 0.437508 0.034 Uiso 1 1 calc R U . B 2
C90 C 0.9145(2) 0.3020(4) 0.49360(16) 0.0256(8) Uani 1 1 d . . . B 2
H90 H 0.919271 0.224407 0.508271 0.031 Uiso 1 1 calc R U . B 2
C91 C 0.8884(2) 0.3919(4) 0.51358(16) 0.0224(8) Uani 1 1 d . . . B 2
H91 H 0.873831 0.375170 0.541157 0.027 Uiso 1 1 calc R U . B 2
C92 C 0.86357(18) 0.7620(3) 0.49588(14) 0.0178(7) Uani 1 1 d . . . B 2
C93 C 0.91396(19) 0.8368(4) 0.52587(15) 0.0226(8) Uani 1 1 d . . . B 2
H93 H 0.941245 0.813673 0.560265 0.027 Uiso 1 1 calc R U . B 2
C94 C 0.9243(2) 0.9445(4) 0.50564(17) 0.0250(8) Uani 1 1 d . . . B 2
H94 H 0.958416 0.995050 0.526230 0.030 Uiso 1 1 calc R U . B 2
C95 C 0.8848(2) 0.9782(4) 0.45553(17) 0.0256(8) Uani 1 1 d . . . B 2
H95 H 0.891948 1.052075 0.441782 0.031 Uiso 1 1 calc R U . B 2
C96 C 0.8351(2) 0.9050(4) 0.42530(17) 0.0248(8) Uani 1 1 d . . . B 2
H96 H 0.808559 0.928101 0.390703 0.030 Uiso 1 1 calc R U . B 2
C97 C 0.82393(19) 0.7976(4) 0.44547(15) 0.0222(8) Uani 1 1 d . . . B 2
H97 H 0.789182 0.748216 0.424871 0.027 Uiso 1 1 calc R U . B 2
C98 C 0.89785(18) 0.6203(4) 0.59022(14) 0.0193(7) Uani 1 1 d . . . B 2
H98A H 0.899562 0.538863 0.604432 0.023 Uiso 1 1 calc R U . B 2
H98B H 0.942198 0.643513 0.594378 0.023 Uiso 1 1 calc R U . B 2
C99 C 0.87258(18) 0.7062(4) 0.62100(14) 0.0189(7) Uani 1 1 d . . . B 2
H99A H 0.883394 0.788676 0.614687 0.023 Uiso 1 1 calc R U . B 2
H99B H 0.894209 0.689467 0.658935 0.023 Uiso 1 1 calc R U . B 2
C100 C 0.75754(18) 0.8473(3) 0.60041(14) 0.0188(7) Uani 1 1 d . . . B 2
C101 C 0.7803(2) 0.9343(4) 0.57515(16) 0.0236(8) Uani 1 1 d . . . B 2
H101 H 0.813032 0.914403 0.562400 0.028 Uiso 1 1 calc R U . B 2
C102 C 0.7560(2) 1.0479(4) 0.56854(17) 0.0278(9) Uani 1 1 d . . . B 2
H102 H 0.772280 1.106008 0.551687 0.033 Uiso 1 1 calc R U . B 2
C103 C 0.7080(3) 1.0778(4) 0.5862(2) 0.0316(10) Uani 1 1 d . . . B 2
H103 H 0.691751 1.156851 0.582185 0.038 Uiso 1 1 calc R U . B 2
C104 C 0.6835(3) 0.9922(5) 0.6101(2) 0.0350(10) Uani 1 1 d . . . B 2
H104 H 0.649529 1.012079 0.621375 0.042 Uiso 1 1 calc R U . B 2
C105 C 0.7085(2) 0.8780(4) 0.61736(17) 0.0270(8) Uani 1 1 d . . . B 2
H105 H 0.691847 0.820127 0.634122 0.032 Uiso 1 1 calc R U . B 2
C106 C 0.77601(18) 0.6328(4) 0.66088(14) 0.0193(7) Uani 1 1 d . . . B 2
C107 C 0.8045(2) 0.6935(4) 0.70882(15) 0.0235(8) Uani 1 1 d . . . B 2
H107 H 0.826008 0.767000 0.709930 0.028 Uiso 1 1 calc R U . B 2
C109 C 0.8015(2) 0.6471(4) 0.75400(16) 0.0287(9) Uani 1 1 d . . . B 2
H109 H 0.821286 0.688199 0.786268 0.034 Uiso 1 1 calc R U . B 2
C110 C 0.7694(2) 0.5400(5) 0.75271(17) 0.0298(10) Uani 1 1 d . . . B 2
H110 H 0.766920 0.508855 0.783978 0.036 Uiso 1 1 calc R U . B 2
C111 C 0.7412(2) 0.4790(4) 0.70583(17) 0.0292(9) Uani 1 1 d . . . B 2
H111 H 0.719680 0.405743 0.705012 0.035 Uiso 1 1 calc R U . B 2
C112 C 0.7445(2) 0.5253(4) 0.65984(16) 0.0226(8) Uani 1 1 d . . . B 2
H112 H 0.725224 0.483425 0.627732 0.027 Uiso 1 1 calc R U . B 2
C113 C 0.5051(4) 0.8213(6) 0.4664(2) 0.0567(19) Uani 1 1 d . . . C 2
O1 O 0.77421(15) 0.3384(3) 0.57074(11) 0.0261(6) Uani 1 1 d . . . B 2
O2 O 0.61057(16) 0.5878(3) 0.54845(13) 0.0318(8) Uani 1 1 d . . . B 2
O3 O 0.68827(16) 0.8398(3) 0.46223(13) 0.0323(7) Uani 1 1 d . . . B 2
P1 P 0.84620(4) 0.62090(9) 0.52075(3) 0.01592(17) Uani 1 1 d . . . B 2
P2 P 0.78405(5) 0.69322(9) 0.60204(3) 0.01593(18) Uani 1 1 d . . . B 2
S1 S 0.56477(11) 0.8856(2) 0.50315(9) 0.0682(5) Uani 1 1 d . . . C 2
S2 S 0.44279(14) 0.7551(3) 0.43102(10) 0.1021(10) Uani 1 1 d . . . C 2
W W 0.73264(2) 0.58932(2) 0.51704(2) 0.01425(6) Uani 1 1 d . . . B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C18A C17 1.351(15) . ?
C18A C19A 1.45(3) . ?
C18A C38 1.544(17) . ?
C19A C20 1.402(16) . ?
C19A C41 1.554(19) . ?
C28A C29A 1.455(19) . ?
C28A C27 1.474(10) . ?
C28A C30 1.517(10) . ?
C28A C10 2.017(11) . ?
C28A C11 2.022(12) . ?
C29A C49 1.429(10) . ?
C29A C52 1.510(10) . ?
C29A C50 1.863(13) . ?
C29A C51 1.917(13) . ?
C18B C19B 1.309(12) . ?
C18B C41 1.368(12) . ?
C18B C38 1.485(12) . ?
C18B C40 1.972(16) . ?
C18B C39 1.976(16) . ?
C19B C20 1.506(11) . ?
C19B C17 1.685(12) . ?
C28B C29B 1.316(13) . ?
C28B C27 1.415(9) . ?
C28B C49 1.573(11) . ?
C29B C30 1.391(10) . ?
C29B C52 1.459(11) . ?
C1 C9 1.468(5) . ?
C1 C6 1.472(5) . ?
C1 C2 1.478(5) . ?
C1 W 2.285(4) . ?
C2 C3 1.462(5) . ?
C2 C12 1.467(6) . ?
C2 W 2.279(4) . ?
C3 C4 1.399(6) . ?
C3 C14 1.416(6) . ?
C4 C17 1.411(6) . ?
C4 C5 1.467(6) . ?
C5 C6 1.411(6) . ?
C5 C20 1.416(5) . ?
C6 C7 1.412(6) . ?
C7 C22 1.418(5) . ?
C7 C8 1.453(6) . ?
C8 C25 1.414(6) . ?
C8 C9 1.416(5) . ?
C9 C10 1.408(6) . ?
C10 C27 1.410(6) . ?
C10 C11 1.464(6) . ?
C11 C12 1.416(6) . ?
C11 C30 1.419(6) . ?
C12 C13 1.417(6) . ?
C13 C32 1.411(7) . ?
C13 C14 1.434(7) . ?
C14 C15 1.408(6) . ?
C15 C16 1.408(10) . ?
C15 C34 1.457(7) . ?
C16 C17 1.433(9) . ?
C16 C37 1.452(9) . ?
C20 C21 1.433(8) . ?
C21 C22 1.414(7) . ?
C21 C42 1.460(7) . ?
C21 Eu2 3.266(5) . ?
C22 C23 1.430(7) . ?
C22 Eu2 3.151(4) . ?
C23 C24 1.423(7) . ?
C23 C44 1.429(6) . ?
C23 Eu2 2.751(5) . ?
C23 Eu4 2.890(9) . ?
C23 Eu1 2.927(5) . ?
C24 C46 1.432(7) . ?
C24 C25 1.439(6) . ?
C24 Eu4 2.592(7) . ?
C24 Eu1 2.746(5) . ?
C24 Eu2 3.004(5) . ?
C25 C26 1.413(7) . ?
C25 Eu4 2.833(8) . ?
C25 Eu1 3.141(5) . ?
C26 C27 1.426(6) . ?
C26 C48 1.447(8) . ?
C26 Eu4 2.930(9) . ?
C30 C31 1.437(9) . ?
C31 C32 1.368(10) . ?
C31 C53 1.486(10) . ?
C32 C33 1.453(7) . ?
C32 Eu3 3.005(6) . ?
C33 C55 1.418(8) . ?
C33 C34 1.440(8) . ?
C33 Eu3 2.558(6) . ?
C34 C35 1.411(7) . ?
C34 Eu3 2.740(6) . ?
C35 C57 1.412(8) . ?
C35 C36 1.440(9) . ?
C35 Eu3 2.877(6) . ?
C36 C37 1.391(9) . ?
C36 C59 1.428(10) . ?
C37 C38 1.373(14) . ?
C38 C39 1.430(17) . ?
C39 C60 1.451(14) . ?
C39 C40 1.481(12) . ?
C40 C63 1.378(14) . ?
C40 C41 1.443(14) . ?
C41 C42 1.430(10) . ?
C42 C43 1.424(8) . ?
C42 Eu2 2.983(5) . ?
C43 C64 1.424(7) . ?
C43 C44 1.429(8) . ?
C43 Eu2 2.562(5) . ?
C43 Eu1 3.266(5) . ?
C44 C45 1.450(8) . ?
C44 Eu2 2.477(5) . ?
C44 Eu1 2.845(5) . ?
C44 Eu4 2.994(10) . ?
C45 C66 1.430(8) . ?
C45 C46 1.505(9) . ?
C45 Eu2 2.589(5) . ?
C45 Eu1 2.592(5) . ?
C45 Eu4 2.771(8) . ?
C46 C47 1.441(9) . ?
C46 Eu4 2.484(7) . ?
C46 Eu1 2.511(5) . ?
C46 Eu2 2.917(6) . ?
C47 C48 1.402(9) . ?
C47 C68 1.437(9) . ?
C47 Eu4 2.526(9) . ?
C47 Eu1 2.609(6) . ?
C48 C49 1.445(9) . ?
C48 Eu4 2.747(10) . ?
C48 Eu1 2.995(6) . ?
C49 C50 1.388(12) . ?
C49 Eu4 3.235(11) . ?
C50 C69 1.422(12) . ?
C50 C51 1.441(10) . ?
C51 C52 1.442(13) . ?
C51 C72 1.491(11) . ?
C52 C53 1.361(13) . ?
C53 C54 1.348(10) . ?
C53 Eu3 3.107(9) . ?
C54 C55 1.428(10) . ?
C54 C73 1.444(10) . ?
C54 Eu3 2.762(7) . ?
C55 C56 1.412(8) . ?
C55 Eu3 2.536(6) . ?
C56 C57 1.339(9) . ?
C56 C74 1.457(8) . ?
C56 Eu3 2.694(5) . ?
C57 C58 1.487(8) . ?
C57 Eu3 2.862(6) . ?
C58 C76 1.332(10) . ?
C58 C59 1.427(9) . ?
C59 C60 1.403(10) . ?
C60 C61 1.474(13) . ?
C61 C77 1.396(11) . ?
C61 C62 1.434(10) . ?
C62 C80 1.424(12) . ?
C62 C63 1.455(12) . ?
C63 C64 1.417(9) . ?
C63 Eu2 3.208(5) . ?
C64 C65 1.483(11) . ?
C64 Eu2 2.736(5) . ?
C65 C66 1.383(11) . ?
C65 C80 1.461(9) . ?
C65 Eu2 2.799(5) . ?
C65 Eu1 3.178(5) . ?
C66 C67 1.443(11) . ?
C66 Eu2 2.710(5) . ?
C66 Eu1 2.736(5) . ?
C66 Eu4 3.041(9) . ?
C67 C68 1.467(12) . ?
C67 C81 1.472(9) . ?
C67 Eu1 2.835(5) . ?
C67 Eu4 3.085(8) . ?
C67 Eu2 3.166(6) . ?
C68 C69 1.455(10) . ?
C68 Eu1 2.771(6) . ?
C68 Eu4 2.844(8) . ?
C69 C70 1.458(12) . ?
C69 Eu1 3.230(6) . ?
C69 Eu4 3.261(9) . ?
C70 C71 1.436(8) . ?
C70 C81 1.439(12) . ?
C71 C82 1.418(11) . ?
C71 C72 1.461(11) . ?
C72 C73 1.400(9) . ?
C73 C74 1.406(10) . ?
C73 Eu3 2.927(6) . ?
C74 C75 1.332(10) . ?
C74 Eu3 2.923(6) . ?
C75 C82 1.395(9) . ?
C75 C76 1.482(11) . ?
C75 Eu3 3.270(6) . ?
C76 C77 1.411(9) . ?
C77 C78 1.449(11) . ?
C78 C79 1.424(9) . ?
C78 C82 1.470(11) . ?
C79 C81 1.415(11) . ?
C79 C80 1.422(11) . ?
Eu1 Eu2 0.875(2) . ?
Eu1 Eu3 3.139(3) . ?
Eu2 Eu4 1.147(9) . ?
C83 O1 1.150(5) . ?
C83 W 2.007(4) . ?
C84 O2 1.138(5) . ?
C84 W 2.020(4) . ?
C85 O3 1.147(5) . ?
C85 W 2.025(4) . ?
C86 C87 1.389(5) . ?
C86 C91 1.403(6) . ?
C86 P1 1.825(4) . ?
C87 C88 1.392(6) . ?
C87 H87 0.9500 . ?
C88 C89 1.381(7) . ?
C88 H88 0.9500 . ?
C89 C90 1.390(6) . ?
C89 H89 0.9500 . ?
C90 C91 1.381(6) . ?
C90 H90 0.9500 . ?
C91 H91 0.9500 . ?
C92 C97 1.395(5) . ?
C92 C93 1.400(5) . ?
C92 P1 1.826(4) . ?
C93 C94 1.387(6) . ?
C93 H93 0.9500 . ?
C94 C95 1.382(6) . ?
C94 H94 0.9500 . ?
C95 C96 1.383(6) . ?
C95 H95 0.9500 . ?
C96 C97 1.390(6) . ?
C96 H96 0.9500 . ?
C97 H97 0.9500 . ?
C98 C99 1.526(6) . ?
C98 P1 1.825(4) . ?
C98 H98A 0.9900 . ?
C98 H98B 0.9900 . ?
C99 P2 1.854(4) . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
C100 C105 1.388(6) . ?
C100 C101 1.402(6) . ?
C100 P2 1.825(4) . ?
C101 C102 1.372(6) . ?
C101 H101 0.9500 . ?
C102 C103 1.376(7) . ?
C102 H102 0.9500 . ?
C103 C104 1.387(7) . ?
C103 H103 0.9500 . ?
C104 C105 1.384(7) . ?
C104 H104 0.9500 . ?
C105 H105 0.9500 . ?
C106 C112 1.393(6) . ?
C106 C107 1.408(5) . ?
C106 P2 1.826(4) . ?
C107 C109 1.373(6) . ?
C107 H107 0.9500 . ?
C109 C110 1.395(7) . ?
C109 H109 0.9500 . ?
C110 C111 1.386(7) . ?
C110 H110 0.9500 . ?
C111 C112 1.396(5) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 S1 1.521(9) . ?
C113 S2 1.557(9) . ?
P1 W 2.5285(10) . ?
P2 W 2.4776(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C17 C18A C19A 116.1(12) . . ?
C17 C18A C38 120.3(13) . . ?
C19A C18A C38 111.6(12) . . ?
C20 C19A C18A 113.8(13) . . ?
C20 C19A C41 120.1(13) . . ?
C18A C19A C41 113.8(12) . . ?
C29A C28A C27 111.6(8) . . ?
C29A C28A C30 112.0(8) . . ?
C27 C28A C30 131.0(8) . . ?
C29A C28A C10 150.5(8) . . ?
C27 C28A C10 44.3(4) . . ?
C30 C28A C10 87.0(6) . . ?
C29A C28A C11 150.7(8) . . ?
C27 C28A C11 86.8(6) . . ?
C30 C28A C11 44.5(4) . . ?
C10 C28A C11 42.5(3) . . ?
C49 C29A C28A 107.3(8) . . ?
C49 C29A C52 139.5(9) . . ?
C28A C29A C52 103.7(8) . . ?
C49 C29A C50 47.6(5) . . ?
C28A C29A C50 145.7(9) . . ?
C52 C29A C50 92.7(7) . . ?
C49 C29A C51 92.3(7) . . ?
C28A C29A C51 143.2(9) . . ?
C52 C29A C51 48.0(5) . . ?
C50 C29A C51 44.8(4) . . ?
C19B C18B C41 106.9(9) . . ?
C19B C18B C38 108.5(10) . . ?
C41 C18B C38 136.3(9) . . ?
C19B C18B C40 147.6(8) . . ?
C41 C18B C40 47.0(5) . . ?
C38 C18B C40 90.1(7) . . ?
C19B C18B C39 147.4(8) . . ?
C41 C18B C39 90.9(7) . . ?
C38 C18B C39 46.1(6) . . ?
C40 C18B C39 44.1(5) . . ?
C18B C19B C20 124.3(9) . . ?
C18B C19B C17 115.5(9) . . ?
C20 C19B C17 109.8(6) . . ?
C29B C28B C27 124.1(7) . . ?
C29B C28B C49 117.5(7) . . ?
C27 C28B C49 108.3(6) . . ?
C28B C29B C30 116.0(7) . . ?
C28B C29B C52 119.1(8) . . ?
C30 C29B C52 113.3(7) . . ?
C9 C1 C6 104.7(3) . . ?
C9 C1 C2 117.1(3) . . ?
C6 C1 C2 116.1(3) . . ?
C9 C1 W 122.4(2) . . ?
C6 C1 W 122.8(3) . . ?
C2 C1 W 70.9(2) . . ?
C3 C2 C12 105.1(3) . . ?
C3 C2 C1 118.1(3) . . ?
C12 C2 C1 117.0(3) . . ?
C3 C2 W 122.1(3) . . ?
C12 C2 W 120.8(2) . . ?
C1 C2 W 71.3(2) . . ?
C4 C3 C14 120.2(4) . . ?
C4 C3 C2 123.4(4) . . ?
C14 C3 C2 108.8(4) . . ?
C3 C4 C17 117.6(4) . . ?
C3 C4 C5 119.0(4) . . ?
C17 C4 C5 114.3(4) . . ?
C6 C5 C20 118.3(4) . . ?
C6 C5 C4 118.3(3) . . ?
C20 C5 C4 113.5(4) . . ?
C5 C6 C7 119.6(4) . . ?
C5 C6 C1 124.0(4) . . ?
C7 C6 C1 109.3(3) . . ?
C6 C7 C22 122.5(4) . . ?
C6 C7 C8 107.6(3) . . ?
C22 C7 C8 121.0(4) . . ?
C25 C8 C9 122.4(4) . . ?
C25 C8 C7 121.4(4) . . ?
C9 C8 C7 108.4(3) . . ?
C10 C9 C8 120.1(4) . . ?
C10 C9 C1 124.1(4) . . ?
C8 C9 C1 108.7(3) . . ?
C9 C10 C27 117.6(4) . . ?
C9 C10 C11 118.3(4) . . ?
C27 C10 C11 115.7(4) . . ?
C9 C10 C28A 152.5(5) . . ?
C27 C10 C28A 46.9(3) . . ?
C11 C10 C28A 68.9(4) . . ?
C12 C11 C30 115.9(4) . . ?
C12 C11 C10 118.8(4) . . ?
C30 C11 C10 117.1(4) . . ?
C12 C11 C28A 151.8(5) . . ?
C30 C11 C28A 48.5(4) . . ?
C10 C11 C28A 68.6(3) . . ?
C11 C12 C13 120.6(4) . . ?
C11 C12 C2 123.6(4) . . ?
C13 C12 C2 108.5(4) . . ?
C32 C13 C12 122.3(5) . . ?
C32 C13 C14 121.8(4) . . ?
C12 C13 C14 108.4(4) . . ?
C15 C14 C3 123.1(5) . . ?
C15 C14 C13 121.1(4) . . ?
C3 C14 C13 108.2(4) . . ?
C14 C15 C16 116.4(5) . . ?
C14 C15 C34 118.1(5) . . ?
C16 C15 C34 120.2(5) . . ?
C15 C16 C17 120.8(5) . . ?
C15 C16 C37 120.4(5) . . ?
C17 C16 C37 110.7(7) . . ?
C18A C17 C4 131.4(9) . . ?
C18A C17 C16 99.1(8) . . ?
C4 C17 C16 121.4(5) . . ?
C4 C17 C19B 98.6(5) . . ?
C16 C17 C19B 127.8(5) . . ?
C19A C20 C5 130.9(9) . . ?
C19A C20 C21 98.9(9) . . ?
C5 C20 C21 122.1(4) . . ?
C5 C20 C19B 103.3(5) . . ?
C21 C20 C19B 123.9(5) . . ?
C22 C21 C20 119.0(4) . . ?
C22 C21 C42 120.7(5) . . ?
C20 C21 C42 112.2(5) . . ?
C22 C21 Eu2 72.7(3) . . ?
C20 C21 Eu2 106.3(3) . . ?
C42 C21 Eu2 65.8(3) . . ?
C21 C22 C7 118.3(4) . . ?
C21 C22 C23 118.5(4) . . ?
C7 C22 C23 117.2(4) . . ?
C21 C22 Eu2 81.9(3) . . ?
C7 C22 Eu2 104.2(3) . . ?
C23 C22 Eu2 60.7(2) . . ?
C24 C23 C44 109.8(4) . . ?
C24 C23 C22 121.6(4) . . ?
C44 C23 C22 121.3(5) . . ?
C24 C23 Eu2 85.8(3) . . ?
C44 C23 Eu2 63.8(3) . . ?
C22 C23 Eu2 92.3(3) . . ?
C24 C23 Eu4 63.6(3) . . ?
C44 C23 Eu4 80.1(3) . . ?
C22 C23 Eu4 98.0(3) . . ?
Eu2 C23 Eu4 23.30(17) . . ?
C24 C23 Eu1 68.5(3) . . ?
C44 C23 Eu1 72.5(3) . . ?
C22 C23 Eu1 100.6(3) . . ?
Eu2 C23 Eu1 17.36(5) . . ?
Eu4 C23 Eu1 7.68(17) . . ?
C23 C24 C46 109.4(4) . . ?
C23 C24 C25 121.3(4) . . ?
C46 C24 C25 120.9(5) . . ?
C23 C24 Eu4 87.0(3) . . ?
C46 C24 Eu4 69.5(3) . . ?
C25 C24 Eu4 84.1(3) . . ?
C23 C24 Eu1 82.7(3) . . ?
C46 C24 Eu1 65.3(3) . . ?
C25 C24 Eu1 91.9(3) . . ?
Eu4 C24 Eu1 7.74(19) . . ?
C23 C24 Eu2 66.0(2) . . ?
C46 C24 Eu2 72.6(3) . . ?
C25 C24 Eu2 101.0(3) . . ?
Eu4 C24 Eu2 22.1(2) . . ?
Eu1 C24 Eu2 16.73(5) . . ?
C26 C25 C8 117.4(4) . . ?
C26 C25 C24 118.9(4) . . ?
C8 C25 C24 117.0(4) . . ?
C26 C25 Eu4 79.7(3) . . ?
C8 C25 Eu4 100.1(3) . . ?
C24 C25 Eu4 65.5(3) . . ?
C26 C25 Eu1 82.7(3) . . ?
C8 C25 Eu1 101.9(2) . . ?
C24 C25 Eu1 60.9(2) . . ?
Eu4 C25 Eu1 4.64(17) . . ?
C25 C26 C27 119.9(4) . . ?
C25 C26 C48 119.5(5) . . ?
C27 C26 C48 111.0(5) . . ?
C25 C26 Eu4 72.0(3) . . ?
C27 C26 Eu4 100.7(3) . . ?
C48 C26 Eu4 68.3(3) . . ?
C10 C27 C28B 121.6(5) . . ?
C10 C27 C26 122.1(4) . . ?
C28B C27 C26 107.9(5) . . ?
C10 C27 C28A 88.8(5) . . ?
C26 C27 C28A 135.9(6) . . ?
C29B C30 C11 125.4(6) . . ?
C29B C30 C31 105.4(6) . . ?
C11 C30 C31 121.6(5) . . ?
C11 C30 C28A 87.0(5) . . ?
C31 C30 C28A 137.9(6) . . ?
C32 C31 C30 121.4(5) . . ?
C32 C31 C53 121.6(5) . . ?
C30 C31 C53 105.9(7) . . ?
C31 C32 C13 117.1(5) . . ?
C31 C32 C33 119.6(5) . . ?
C13 C32 C33 118.3(5) . . ?
C31 C32 Eu3 88.6(4) . . ?
C13 C32 Eu3 102.0(3) . . ?
C33 C32 Eu3 58.2(3) . . ?
C55 C33 C34 118.7(4) . . ?
C55 C33 C32 116.4(6) . . ?
C34 C33 C32 119.6(4) . . ?
C55 C33 Eu3 73.0(3) . . ?
C34 C33 Eu3 81.3(3) . . ?
C32 C33 Eu3 92.9(3) . . ?
C35 C34 C33 116.6(4) . . ?
C35 C34 C15 118.1(5) . . ?
C33 C34 C15 120.8(4) . . ?
C35 C34 Eu3 80.9(3) . . ?
C33 C34 Eu3 67.4(3) . . ?
C15 C34 Eu3 100.8(3) . . ?
C34 C35 C57 122.3(5) . . ?
C34 C35 C36 120.6(5) . . ?
C57 C35 C36 107.9(5) . . ?
C34 C35 Eu3 70.1(3) . . ?
C57 C35 Eu3 75.2(3) . . ?
C36 C35 Eu3 96.7(4) . . ?
C37 C36 C59 120.3(7) . . ?
C37 C36 C35 120.9(6) . . ?
C59 C36 C35 110.3(6) . . ?
C38 C37 C36 120.1(8) . . ?
C38 C37 C16 113.6(7) . . ?
C36 C37 C16 118.9(7) . . ?
C37 C38 C39 120.6(8) . . ?
C37 C38 C18B 140.3(8) . . ?
C39 C38 C18B 85.3(8) . . ?
C37 C38 C18A 95.4(10) . . ?
C39 C38 C18A 132.6(10) . . ?
C38 C39 C60 119.7(8) . . ?
C38 C39 C40 116.3(11) . . ?
C60 C39 C40 118.3(12) . . ?
C38 C39 C18B 48.5(7) . . ?
C60 C39 C18B 157.6(7) . . ?
C40 C39 C18B 67.8(7) . . ?
C63 C40 C41 118.1(7) . . ?
C63 C40 C39 121.3(9) . . ?
C41 C40 C39 111.7(11) . . ?
C63 C40 C18B 153.4(6) . . ?
C41 C40 C18B 43.9(5) . . ?
C39 C40 C18B 68.1(9) . . ?
C18B C41 C42 137.1(7) . . ?
C18B C41 C40 89.0(7) . . ?
C42 C41 C40 121.0(7) . . ?
C42 C41 C19A 95.2(9) . . ?
C40 C41 C19A 133.2(10) . . ?
C43 C42 C41 119.4(6) . . ?
C43 C42 C21 119.9(5) . . ?
C41 C42 C21 113.0(6) . . ?
C43 C42 Eu2 59.1(3) . . ?
C41 C42 Eu2 97.6(4) . . ?
C21 C42 Eu2 87.6(3) . . ?
C64 C43 C42 118.2(6) . . ?
C64 C43 C44 115.8(6) . . ?
C42 C43 C44 119.2(4) . . ?
C64 C43 Eu2 81.3(3) . . ?
C42 C43 Eu2 92.4(3) . . ?
C44 C43 Eu2 70.3(3) . . ?
C64 C43 Eu1 84.3(3) . . ?
C42 C43 Eu1 99.7(3) . . ?
C44 C43 Eu1 60.4(3) . . ?
Eu2 C43 Eu1 10.30(6) . . ?
C23 C44 C43 120.1(5) . . ?
C23 C44 C45 107.4(5) . . ?
C43 C44 C45 122.8(5) . . ?
C23 C44 Eu2 85.1(3) . . ?
C43 C44 Eu2 76.8(3) . . ?
C45 C44 Eu2 77.7(3) . . ?
C23 C44 Eu1 78.9(3) . . ?
C43 C44 Eu1 93.7(3) . . ?
C45 C44 Eu1 65.1(3) . . ?
Eu2 C44 Eu1 17.19(6) . . ?
C23 C44 Eu4 71.9(3) . . ?
C43 C44 Eu4 98.4(3) . . ?
C45 C44 Eu4 67.0(3) . . ?
Eu2 C44 Eu4 21.67(14) . . ?
Eu1 C44 Eu4 7.11(14) . . ?
C66 C45 C44 120.5(6) . . ?
C66 C45 C46 119.7(6) . . ?
C44 C45 C46 107.4(4) . . ?
C66 C45 Eu2 79.1(3) . . ?
C44 C45 Eu2 69.2(3) . . ?
C46 C45 Eu2 86.6(3) . . ?
C66 C45 Eu1 80.0(3) . . ?
C44 C45 Eu1 84.4(3) . . ?
C46 C45 Eu1 69.9(3) . . ?
Eu2 C45 Eu1 19.44(6) . . ?
C66 C45 Eu4 86.5(3) . . ?
C44 C45 Eu4 84.2(3) . . ?
C46 C45 Eu4 63.1(3) . . ?
Eu2 C45 Eu4 24.41(17) . . ?
Eu1 C45 Eu4 7.45(16) . . ?
C24 C46 C47 119.8(5) . . ?
C24 C46 C45 106.0(5) . . ?
C47 C46 C45 122.9(5) . . ?
C24 C46 Eu4 77.8(3) . . ?
C47 C46 Eu4 74.9(4) . . ?
C45 C46 Eu4 84.2(4) . . ?
C24 C46 Eu1 83.5(3) . . ?
C47 C46 Eu1 77.4(3) . . ?
C45 C46 Eu1 75.8(3) . . ?
Eu4 C46 Eu1 8.97(19) . . ?
C24 C46 Eu2 79.4(3) . . ?
C47 C46 Eu2 93.2(3) . . ?
C45 C46 Eu2 62.4(3) . . ?
Eu4 C46 Eu2 22.8(2) . . ?
Eu1 C46 Eu2 16.47(6) . . ?
C48 C47 C68 117.9(6) . . ?
C48 C47 C46 118.4(5) . . ?
C68 C47 C46 116.1(7) . . ?
C48 C47 Eu4 83.5(4) . . ?
C68 C47 Eu4 87.2(4) . . ?
C46 C47 Eu4 71.7(4) . . ?
C48 C47 Eu1 91.6(3) . . ?
C68 C47 Eu1 80.9(4) . . ?
C46 C47 Eu1 70.0(3) . . ?
Eu4 C47 Eu1 8.55(18) . . ?
C47 C48 C49 121.1(7) . . ?
C47 C48 C26 122.1(6) . . ?
C49 C48 C26 108.8(6) . . ?
C47 C48 Eu4 66.0(4) . . ?
C49 C48 Eu4 96.0(4) . . ?
C26 C48 Eu4 82.4(3) . . ?
C47 C48 Eu1 60.5(3) . . ?
C49 C48 Eu1 96.8(4) . . ?
C26 C48 Eu1 87.8(3) . . ?
Eu4 C48 Eu1 6.05(15) . . ?
C50 C49 C29A 82.8(6) . . ?
C50 C49 C48 122.6(7) . . ?
C29A C49 C48 141.1(8) . . ?
C50 C49 C28B 122.5(6) . . ?
C48 C49 C28B 104.0(6) . . ?
C50 C49 Eu4 85.8(4) . . ?
C29A C49 Eu4 100.8(5) . . ?
C48 C49 Eu4 57.6(3) . . ?
C49 C50 C69 116.1(6) . . ?
C49 C50 C51 118.9(8) . . ?
C69 C50 C51 118.5(7) . . ?
C49 C50 C29A 49.5(5) . . ?
C69 C50 C29A 156.6(7) . . ?
C51 C50 C29A 69.6(6) . . ?
C50 C51 C52 116.5(7) . . ?
C50 C51 C72 119.3(8) . . ?
C52 C51 C72 117.8(6) . . ?
C50 C51 C29A 65.6(5) . . ?
C52 C51 C29A 51.1(5) . . ?
C72 C51 C29A 157.5(6) . . ?
C53 C52 C51 121.2(7) . . ?
C53 C52 C29B 103.5(7) . . ?
C51 C52 C29B 125.1(7) . . ?
C53 C52 C29A 143.9(8) . . ?
C51 C52 C29A 81.0(6) . . ?
C54 C53 C52 121.9(9) . . ?
C54 C53 C31 118.5(8) . . ?
C52 C53 C31 111.4(7) . . ?
C54 C53 Eu3 62.7(4) . . ?
C52 C53 Eu3 97.7(5) . . ?
C31 C53 Eu3 82.8(3) . . ?
C53 C54 C55 119.7(7) . . ?
C53 C54 C73 120.3(8) . . ?
C55 C54 C73 111.0(6) . . ?
C53 C54 Eu3 91.6(4) . . ?
C55 C54 Eu3 65.8(3) . . ?
C73 C54 Eu3 81.7(4) . . ?
C56 C55 C33 122.2(6) . . ?
C56 C55 C54 104.7(6) . . ?
C33 C55 C54 122.7(5) . . ?
C56 C55 Eu3 80.6(3) . . ?
C33 C55 Eu3 74.7(3) . . ?
C54 C55 Eu3 83.3(4) . . ?
C57 C56 C55 118.7(5) . . ?
C57 C56 C74 119.8(6) . . ?
C55 C56 C74 109.9(6) . . ?
C57 C56 Eu3 83.2(3) . . ?
C55 C56 Eu3 68.3(3) . . ?
C74 C56 Eu3 83.9(3) . . ?
C56 C57 C35 121.4(5) . . ?
C56 C57 C58 120.5(5) . . ?
C35 C57 C58 106.4(5) . . ?
C56 C57 Eu3 69.1(3) . . ?
C35 C57 Eu3 76.3(3) . . ?
C58 C57 Eu3 92.3(3) . . ?
C76 C58 C59 119.0(7) . . ?
C76 C58 C57 119.6(6) . . ?
C59 C58 C57 109.1(6) . . ?
C60 C59 C58 123.6(7) . . ?
C60 C59 C36 120.8(6) . . ?
C58 C59 C36 105.8(6) . . ?
C59 C60 C39 117.3(9) . . ?
C59 C60 C61 116.8(7) . . ?
C39 C60 C61 119.4(8) . . ?
C77 C61 C62 116.7(8) . . ?
C77 C61 C60 116.5(6) . . ?
C62 C61 C60 120.1(8) . . ?
C80 C62 C61 122.7(7) . . ?
C80 C62 C63 107.9(6) . . ?
C61 C62 C63 119.3(9) . . ?
C40 C63 C64 121.5(7) . . ?
C40 C63 C62 121.4(7) . . ?
C64 C63 C62 108.9(8) . . ?
C40 C63 Eu2 92.0(4) . . ?
C64 C63 Eu2 58.0(3) . . ?
C62 C63 Eu2 90.7(4) . . ?
C63 C64 C43 121.2(7) . . ?
C63 C64 C65 108.1(6) . . ?
C43 C64 C65 120.6(6) . . ?
C63 C64 Eu2 95.9(3) . . ?
C43 C64 Eu2 67.8(3) . . ?
C65 C64 Eu2 76.8(3) . . ?
C66 C65 C80 121.5(7) . . ?
C66 C65 C64 122.4(6) . . ?
C80 C65 C64 106.0(7) . . ?
C66 C65 Eu2 71.9(3) . . ?
C80 C65 Eu2 96.6(3) . . ?
C64 C65 Eu2 72.1(3) . . ?
C66 C65 Eu1 59.0(3) . . ?
C80 C65 Eu1 96.6(3) . . ?
C64 C65 Eu1 86.8(3) . . ?
Eu2 C65 Eu1 15.19(6) . . ?
C65 C66 C45 117.3(7) . . ?
C65 C66 C67 118.8(6) . . ?
C45 C66 C67 116.7(7) . . ?
C65 C66 Eu2 79.1(3) . . ?
C45 C66 Eu2 69.7(3) . . ?
C67 C66 Eu2 94.4(3) . . ?
C65 C66 Eu1 95.3(3) . . ?
C45 C66 Eu1 69.0(3) . . ?
C67 C66 Eu1 78.8(3) . . ?
Eu2 C66 Eu1 18.48(6) . . ?
C65 C66 Eu4 99.9(4) . . ?
C45 C66 Eu4 65.5(3) . . ?
C67 C66 Eu4 78.1(4) . . ?
Eu2 C66 Eu4 22.06(16) . . ?
Eu1 C66 Eu4 4.88(15) . . ?
C66 C67 C68 123.2(6) . . ?
C66 C67 C81 119.9(8) . . ?
C68 C67 C81 106.2(6) . . ?
C66 C67 Eu1 71.2(3) . . ?
C68 C67 Eu1 72.4(3) . . ?
C81 C67 Eu1 96.5(3) . . ?
C66 C67 Eu4 74.7(3) . . ?
C68 C67 Eu4 66.7(3) . . ?
C81 C67 Eu4 99.0(3) . . ?
Eu1 C67 Eu4 5.84(18) . . ?
C66 C67 Eu2 58.6(3) . . ?
C68 C67 Eu2 87.7(3) . . ?
C81 C67 Eu2 95.1(3) . . ?
Eu1 C67 Eu2 15.53(5) . . ?
Eu4 C67 Eu2 21.10(17) . . ?
C47 C68 C69 119.1(7) . . ?
C47 C68 C67 120.9(7) . . ?
C69 C68 C67 109.9(6) . . ?
C47 C68 Eu1 68.4(3) . . ?
C69 C68 Eu1 94.5(3) . . ?
C67 C68 Eu1 77.3(3) . . ?
C47 C68 Eu4 62.5(3) . . ?
C69 C68 Eu4 93.0(4) . . ?
C67 C68 Eu4 85.0(4) . . ?
Eu1 C68 Eu4 7.86(18) . . ?
C50 C69 C68 122.6(7) . . ?
C50 C69 C70 122.9(6) . . ?
C68 C69 C70 105.8(8) . . ?
C50 C69 Eu1 90.5(4) . . ?
C68 C69 Eu1 58.8(3) . . ?
C70 C69 Eu1 90.1(3) . . ?
C50 C69 Eu4 84.3(4) . . ?
C68 C69 Eu4 60.6(3) . . ?
C70 C69 Eu4 96.0(4) . . ?
Eu1 C69 Eu4 6.89(15) . . ?
C71 C70 C81 121.0(7) . . ?
C71 C70 C69 120.2(8) . . ?
C81 C70 C69 110.1(6) . . ?
C82 C71 C70 116.6(7) . . ?
C82 C71 C72 118.7(5) . . ?
C70 C71 C72 117.8(7) . . ?
C73 C72 C71 115.5(6) . . ?
C73 C72 C51 116.9(7) . . ?
C71 C72 C51 121.2(6) . . ?
C72 C73 C74 123.1(6) . . ?
C72 C73 C54 121.0(6) . . ?
C74 C73 C54 106.0(6) . . ?
C72 C73 Eu3 91.7(3) . . ?
C74 C73 Eu3 76.0(3) . . ?
C54 C73 Eu3 69.1(3) . . ?
C75 C74 C73 121.3(6) . . ?
C75 C74 C56 120.0(6) . . ?
C73 C74 C56 107.7(6) . . ?
C75 C74 Eu3 92.7(4) . . ?
C73 C74 Eu3 76.2(3) . . ?
C56 C74 Eu3 66.4(3) . . ?
C74 C75 C82 119.2(7) . . ?
C74 C75 C76 120.9(6) . . ?
C82 C75 C76 108.1(6) . . ?
C74 C75 Eu3 63.3(3) . . ?
C82 C75 Eu3 90.7(3) . . ?
C76 C75 Eu3 84.0(3) . . ?
C58 C76 C77 120.0(8) . . ?
C58 C76 C75 119.2(6) . . ?
C77 C76 C75 109.3(6) . . ?
C61 C77 C76 124.1(7) . . ?
C61 C77 C78 120.2(6) . . ?
C76 C77 C78 106.0(6) . . ?
C79 C78 C77 122.5(7) . . ?
C79 C78 C82 119.4(7) . . ?
C77 C78 C82 109.5(5) . . ?
C81 C79 C80 118.4(6) . . ?
C81 C79 C78 118.2(7) . . ?
C80 C79 C78 116.5(7) . . ?
C79 C80 C62 120.4(6) . . ?
C79 C80 C65 120.8(7) . . ?
C62 C80 C65 109.1(7) . . ?
C79 C81 C70 121.9(6) . . ?
C79 C81 C67 120.6(7) . . ?
C70 C81 C67 107.9(7) . . ?
C75 C82 C71 122.2(7) . . ?
C75 C82 C78 106.9(7) . . ?
C71 C82 C78 122.1(6) . . ?
Eu2 Eu1 C46 109.08(19) . . ?
Eu2 Eu1 C45 80.10(19) . . ?
C46 Eu1 C45 34.2(2) . . ?
Eu2 Eu1 C47 139.64(19) . . ?
C46 Eu1 C47 32.6(2) . . ?
C45 Eu1 C47 59.7(2) . . ?
Eu2 Eu1 C66 79.1(2) . . ?
C46 Eu1 C66 57.7(2) . . ?
C45 Eu1 C66 31.00(17) . . ?
C47 Eu1 C66 68.2(2) . . ?
Eu2 Eu1 C24 98.60(16) . . ?
C46 Eu1 C24 31.21(15) . . ?
C45 Eu1 C24 52.03(16) . . ?
C47 Eu1 C24 55.25(18) . . ?
C66 Eu1 C24 82.28(16) . . ?
Eu2 Eu1 C68 133.9(2) . . ?
C46 Eu1 C68 54.80(18) . . ?
C45 Eu1 C68 65.2(2) . . ?
C47 Eu1 C68 30.8(2) . . ?
C66 Eu1 C68 55.4(3) . . ?
C24 Eu1 C68 83.65(17) . . ?
Eu2 Eu1 C67 104.2(2) . . ?
C46 Eu1 C67 63.5(2) . . ?
C45 Eu1 C67 53.34(19) . . ?
C47 Eu1 C67 55.1(2) . . ?
C66 Eu1 C67 30.0(2) . . ?
C24 Eu1 C67 94.40(18) . . ?
C68 Eu1 C67 30.3(3) . . ?
Eu2 Eu1 C44 56.81(15) . . ?
C46 Eu1 C44 52.35(19) . . ?
C45 Eu1 C44 30.48(18) . . ?
C47 Eu1 C44 84.21(19) . . ?
C66 Eu1 C44 53.19(17) . . ?
C24 Eu1 C44 49.28(15) . . ?
C68 Eu1 C44 95.52(19) . . ?
C67 Eu1 C44 81.28(17) . . ?
Eu2 Eu1 C23 69.79(15) . . ?
C46 Eu1 C23 50.01(17) . . ?
C45 Eu1 C23 49.26(15) . . ?
C47 Eu1 C23 80.77(18) . . ?
C66 Eu1 C23 78.47(16) . . ?
C24 Eu1 C23 28.83(15) . . ?
C68 Eu1 C23 104.33(17) . . ?
C67 Eu1 C23 102.25(16) . . ?
C44 Eu1 C23 28.61(12) . . ?
Eu2 Eu1 C48 157.29(19) . . ?
C46 Eu1 C48 51.7(2) . . ?
C45 Eu1 C48 84.5(2) . . ?
C47 Eu1 C48 27.89(19) . . ?
C66 Eu1 C48 96.0(2) . . ?
C24 Eu1 C48 58.70(18) . . ?
C68 Eu1 C48 49.7(2) . . ?
C67 Eu1 C48 79.1(2) . . ?
C44 Eu1 C48 102.48(18) . . ?
C23 Eu1 C48 87.51(17) . . ?
Eu2 Eu1 Eu3 87.99(15) . . ?
C46 Eu1 Eu3 162.78(19) . . ?
C45 Eu1 Eu3 159.95(18) . . ?
C47 Eu1 Eu3 131.29(18) . . ?
C66 Eu1 Eu3 130.82(16) . . ?
C24 Eu1 Eu3 146.85(12) . . ?
C68 Eu1 Eu3 114.75(16) . . ?
C67 Eu1 Eu3 115.53(16) . . ?
C44 Eu1 Eu3 144.46(17) . . ?
C23 Eu1 Eu3 140.04(13) . . ?
C48 Eu1 Eu3 111.13(16) . . ?
Eu1 Eu2 Eu4 16.1(4) . . ?
Eu1 Eu2 C44 106.00(19) . . ?
Eu4 Eu2 C44 105.5(3) . . ?
Eu1 Eu2 C43 138.14(18) . . ?
Eu4 Eu2 C43 138.1(3) . . ?
C44 Eu2 C43 32.90(18) . . ?
Eu1 Eu2 C45 80.5(2) . . ?
Eu4 Eu2 C45 86.7(3) . . ?
C44 Eu2 C45 33.16(19) . . ?
C43 Eu2 C45 58.8(2) . . ?
Eu1 Eu2 C66 82.4(2) . . ?
Eu4 Eu2 C66 95.4(4) . . ?
C44 Eu2 C66 57.42(18) . . ?
C43 Eu2 C66 68.0(2) . . ?
C45 Eu2 C66 31.21(17) . . ?
Eu1 Eu2 C64 137.3(2) . . ?
Eu4 Eu2 C64 149.5(3) . . ?
C44 Eu2 C64 54.99(18) . . ?
C43 Eu2 C64 30.96(17) . . ?
C45 Eu2 C64 64.3(2) . . ?
C66 Eu2 C64 54.9(2) . . ?
Eu1 Eu2 C23 92.84(16) . . ?
Eu4 Eu2 C23 85.2(3) . . ?
C44 Eu2 C23 31.16(14) . . ?
C43 Eu2 C23 55.44(16) . . ?
C45 Eu2 C23 51.41(16) . . ?
C66 Eu2 C23 82.06(16) . . ?
C64 Eu2 C23 83.85(16) . . ?
Eu1 Eu2 C65 107.8(2) . . ?
Eu4 Eu2 C65 122.6(4) . . ?
C44 Eu2 C65 63.86(18) . . ?
C43 Eu2 C65 55.98(19) . . ?
C45 Eu2 C65 52.8(2) . . ?
C66 Eu2 C65 29.0(2) . . ?
C64 Eu2 C65 31.0(2) . . ?
C23 Eu2 C65 94.64(16) . . ?
Eu1 Eu2 C46 54.45(16) . . ?
Eu4 Eu2 C46 56.9(3) . . ?
C44 Eu2 C46 51.62(19) . . ?
C43 Eu2 C46 83.84(18) . . ?
C45 Eu2 C46 30.99(19) . . ?
C66 Eu2 C46 53.48(19) . . ?
C64 Eu2 C46 95.20(18) . . ?
C23 Eu2 C46 48.44(16) . . ?
C65 Eu2 C46 80.83(19) . . ?
Eu1 Eu2 C42 151.85(18) . . ?
Eu4 Eu2 C42 140.3(4) . . ?
C44 Eu2 C42 52.59(19) . . ?
C43 Eu2 C42 28.49(17) . . ?
C45 Eu2 C42 84.2(2) . . ?
C66 Eu2 C42 96.4(2) . . ?
C64 Eu2 C42 50.38(18) . . ?
C23 Eu2 C42 59.30(18) . . ?
C65 Eu2 C42 80.6(2) . . ?
C46 Eu2 C42 102.47(18) . . ?
Eu1 Eu2 C24 64.67(15) . . ?
Eu4 Eu2 C24 58.3(3) . . ?
C44 Eu2 C24 49.24(16) . . ?
C43 Eu2 C24 80.27(16) . . ?
C45 Eu2 C24 48.89(16) . . ?
C66 Eu2 C24 78.08(16) . . ?
C64 Eu2 C24 103.72(16) . . ?
C23 Eu2 C24 28.20(15) . . ?
C65 Eu2 C24 101.49(17) . . ?
C46 Eu2 C24 27.94(13) . . ?
C42 Eu2 C24 87.49(17) . . ?
C55 Eu3 C33 32.33(18) . . ?
C55 Eu3 C56 31.15(17) . . ?
C33 Eu3 C56 56.24(17) . . ?
C55 Eu3 C34 55.4(2) . . ?
C33 Eu3 C34 31.30(19) . . ?
C56 Eu3 C34 63.61(18) . . ?
C55 Eu3 C54 30.9(2) . . ?
C33 Eu3 C54 55.8(2) . . ?
C56 Eu3 C54 48.7(2) . . ?
C34 Eu3 C54 84.6(2) . . ?
C55 Eu3 C57 51.59(19) . . ?
C33 Eu3 C57 62.21(17) . . ?
C56 Eu3 C57 27.69(19) . . ?
C34 Eu3 C57 52.33(16) . . ?
C54 Eu3 C57 75.7(2) . . ?
C55 Eu3 C35 60.8(2) . . ?
C33 Eu3 C35 52.62(19) . . ?
C56 Eu3 C35 50.91(19) . . ?
C34 Eu3 C35 28.97(15) . . ?
C54 Eu3 C35 91.1(2) . . ?
C57 Eu3 C35 28.49(16) . . ?
C55 Eu3 C74 50.38(19) . . ?
C33 Eu3 C74 81.68(19) . . ?
C56 Eu3 C74 29.72(17) . . ?
C34 Eu3 C74 93.33(18) . . ?
C54 Eu3 C74 47.1(2) . . ?
C57 Eu3 C74 49.45(18) . . ?
C35 Eu3 C74 77.29(18) . . ?
C55 Eu3 C73 50.7(2) . . ?
C33 Eu3 C73 81.7(2) . . ?
C56 Eu3 C73 48.37(19) . . ?
C34 Eu3 C73 105.27(19) . . ?
C54 Eu3 C73 29.2(2) . . ?
C57 Eu3 C73 74.13(19) . . ?
C35 Eu3 C73 99.26(19) . . ?
C74 Eu3 C73 27.81(19) . . ?
C55 Eu3 C32 51.42(17) . . ?
C33 Eu3 C32 28.89(16) . . ?
C56 Eu3 C32 81.26(17) . . ?
C34 Eu3 C32 51.37(18) . . ?
C54 Eu3 C32 59.1(2) . . ?
C57 Eu3 C32 91.08(18) . . ?
C35 Eu3 C32 78.50(19) . . ?
C74 Eu3 C32 100.32(19) . . ?
C73 Eu3 C32 88.3(2) . . ?
C55 Eu3 C53 49.1(2) . . ?
C33 Eu3 C53 59.9(3) . . ?
C56 Eu3 C53 73.6(2) . . ?
C34 Eu3 C53 91.2(3) . . ?
C54 Eu3 C53 25.7(2) . . ?
C57 Eu3 C53 99.4(2) . . ?
C35 Eu3 C53 108.1(3) . . ?
C74 Eu3 C53 71.2(2) . . ?
C73 Eu3 C53 47.2(2) . . ?
C32 Eu3 C53 48.1(2) . . ?
C55 Eu3 Eu1 155.7(3) . . ?
C33 Eu3 Eu1 148.18(19) . . ?
C56 Eu3 Eu1 153.05(18) . . ?
C34 Eu3 Eu1 141.95(17) . . ?
C54 Eu3 Eu1 125.3(2) . . ?
C57 Eu3 Eu1 147.9(2) . . ?
C35 Eu3 Eu1 143.5(2) . . ?
C74 Eu3 Eu1 123.86(17) . . ?
C73 Eu3 Eu1 111.69(18) . . ?
C32 Eu3 Eu1 119.98(16) . . ?
C53 Eu3 Eu1 107.2(2) . . ?
Eu2 Eu4 C46 100.3(5) . . ?
Eu2 Eu4 C47 125.3(5) . . ?
C46 Eu4 C47 33.4(2) . . ?
Eu2 Eu4 C24 99.6(5) . . ?
C46 Eu4 C24 32.68(17) . . ?
C47 Eu4 C24 58.1(2) . . ?
Eu2 Eu4 C48 155.0(5) . . ?
C46 Eu4 C48 55.4(2) . . ?
C47 Eu4 C48 30.5(2) . . ?
C24 Eu4 C48 63.8(2) . . ?
Eu2 Eu4 C45 68.9(4) . . ?
C46 Eu4 C45 32.7(2) . . ?
C47 Eu4 C45 58.3(3) . . ?
C24 Eu4 C45 51.7(2) . . ?
C48 Eu4 C45 86.1(3) . . ?
Eu2 Eu4 C25 121.6(5) . . ?
C46 Eu4 C25 55.56(19) . . ?
C47 Eu4 C25 65.0(2) . . ?
C24 Eu4 C25 30.35(15) . . ?
C48 Eu4 C25 52.5(2) . . ?
C45 Eu4 C25 81.5(2) . . ?
Eu2 Eu4 C68 111.6(5) . . ?
C46 Eu4 C68 54.0(2) . . ?
C47 Eu4 C68 30.3(2) . . ?
C24 Eu4 C68 85.1(2) . . ?
C48 Eu4 C68 51.5(3) . . ?
C45 Eu4 C68 62.0(2) . . ?
C25 Eu4 C68 95.2(3) . . ?
Eu2 Eu4 C23 71.5(4) . . ?
C46 Eu4 C23 50.7(2) . . ?
C47 Eu4 C23 82.9(2) . . ?
C24 Eu4 C23 29.46(17) . . ?
C48 Eu4 C23 93.2(2) . . ?
C45 Eu4 C23 48.34(19) . . ?
C25 Eu4 C23 51.68(17) . . ?
C68 Eu4 C23 103.5(2) . . ?
Eu2 Eu4 C26 149.8(5) . . ?
C46 Eu4 C26 63.1(2) . . ?
C47 Eu4 C26 53.8(2) . . ?
C24 Eu4 C26 52.39(19) . . ?
C48 Eu4 C26 29.31(19) . . ?
C45 Eu4 C26 95.3(2) . . ?
C25 Eu4 C26 28.31(16) . . ?
C68 Eu4 C26 80.1(3) . . ?
C23 Eu4 C26 78.8(2) . . ?
Eu2 Eu4 C44 52.9(3) . . ?
C46 Eu4 C44 50.5(2) . . ?
C47 Eu4 C44 82.6(3) . . ?
C24 Eu4 C44 48.7(2) . . ?
C48 Eu4 C44 104.9(3) . . ?
C45 Eu4 C44 28.80(19) . . ?
C25 Eu4 C44 77.0(2) . . ?
C68 Eu4 C44 90.8(3) . . ?
C23 Eu4 C44 28.03(14) . . ?
C26 Eu4 C44 101.0(2) . . ?
Eu2 Eu4 C66 62.5(4) . . ?
C46 Eu4 C66 53.6(2) . . ?
C47 Eu4 C66 64.4(3) . . ?
C24 Eu4 C66 79.2(2) . . ?
C48 Eu4 C66 94.7(3) . . ?
C45 Eu4 C66 28.01(17) . . ?
C25 Eu4 C66 107.9(2) . . ?
C68 Eu4 C66 51.4(3) . . ?
C23 Eu4 C66 74.3(2) . . ?
C26 Eu4 C66 114.5(3) . . ?
C44 Eu4 C66 48.9(2) . . ?
O1 C83 W 178.3(4) . . ?
O2 C84 W 178.0(4) . . ?
O3 C85 W 178.8(4) . . ?
C87 C86 C91 119.3(4) . . ?
C87 C86 P1 122.8(3) . . ?
C91 C86 P1 117.9(3) . . ?
C86 C87 C88 119.7(4) . . ?
C86 C87 H87 120.2 . . ?
C88 C87 H87 120.2 . . ?
C89 C88 C87 120.9(4) . . ?
C89 C88 H88 119.5 . . ?
C87 C88 H88 119.5 . . ?
C88 C89 C90 119.5(4) . . ?
C88 C89 H89 120.3 . . ?
C90 C89 H89 120.3 . . ?
C91 C90 C89 120.2(4) . . ?
C91 C90 H90 119.9 . . ?
C89 C90 H90 119.9 . . ?
C90 C91 C86 120.4(4) . . ?
C90 C91 H91 119.8 . . ?
C86 C91 H91 119.8 . . ?
C97 C92 C93 119.0(4) . . ?
C97 C92 P1 118.4(3) . . ?
C93 C92 P1 122.5(3) . . ?
C94 C93 C92 120.4(4) . . ?
C94 C93 H93 119.8 . . ?
C92 C93 H93 119.8 . . ?
C95 C94 C93 120.0(4) . . ?
C95 C94 H94 120.0 . . ?
C93 C94 H94 120.0 . . ?
C94 C95 C96 120.3(4) . . ?
C94 C95 H95 119.8 . . ?
C96 C95 H95 119.8 . . ?
C95 C96 C97 120.1(4) . . ?
C95 C96 H96 120.0 . . ?
C97 C96 H96 120.0 . . ?
C96 C97 C92 120.2(4) . . ?
C96 C97 H97 119.9 . . ?
C92 C97 H97 119.9 . . ?
C99 C98 P1 111.0(3) . . ?
C99 C98 H98A 109.4 . . ?
P1 C98 H98A 109.4 . . ?
C99 C98 H98B 109.4 . . ?
P1 C98 H98B 109.4 . . ?
H98A C98 H98B 108.0 . . ?
C98 C99 P2 111.9(3) . . ?
C98 C99 H99A 109.2 . . ?
P2 C99 H99A 109.2 . . ?
C98 C99 H99B 109.2 . . ?
P2 C99 H99B 109.2 . . ?
H99A C99 H99B 107.9 . . ?
C105 C100 C101 118.2(4) . . ?
C105 C100 P2 121.2(3) . . ?
C101 C100 P2 119.9(3) . . ?
C102 C101 C100 121.0(4) . . ?
C102 C101 H101 119.5 . . ?
C100 C101 H101 119.5 . . ?
C101 C102 C103 120.3(4) . . ?
C101 C102 H102 119.9 . . ?
C103 C102 H102 119.9 . . ?
C102 C103 C104 119.7(4) . . ?
C102 C103 H103 120.1 . . ?
C104 C103 H103 120.1 . . ?
C105 C104 C103 120.2(4) . . ?
C105 C104 H104 119.9 . . ?
C103 C104 H104 119.9 . . ?
C104 C105 C100 120.6(4) . . ?
C104 C105 H105 119.7 . . ?
C100 C105 H105 119.7 . . ?
C112 C106 C107 119.2(4) . . ?
C112 C106 P2 121.4(3) . . ?
C107 C106 P2 119.4(3) . . ?
C109 C107 C106 120.4(4) . . ?
C109 C107 H107 119.8 . . ?
C106 C107 H107 119.8 . . ?
C107 C109 C110 120.3(4) . . ?
C107 C109 H109 119.9 . . ?
C110 C109 H109 119.9 . . ?
C111 C110 C109 120.0(4) . . ?
C111 C110 H110 120.0 . . ?
C109 C110 H110 120.0 . . ?
C110 C111 C112 119.9(4) . . ?
C110 C111 H111 120.0 . . ?
C112 C111 H111 120.0 . . ?
C106 C112 C111 120.2(4) . . ?
C106 C112 H112 119.9 . . ?
C111 C112 H112 119.9 . . ?
S1 C113 S2 177.1(5) . . ?
C86 P1 C98 102.84(18) . . ?
C86 P1 C92 104.93(18) . . ?
C98 P1 C92 104.83(18) . . ?
C86 P1 W 119.27(13) . . ?
C98 P1 W 105.84(13) . . ?
C92 P1 W 117.30(13) . . ?
C100 P2 C106 103.61(18) . . ?
C100 P2 C99 103.61(18) . . ?
C106 P2 C99 103.28(17) . . ?
C100 P2 W 113.11(12) . . ?
C106 P2 W 119.79(14) . . ?
C99 P2 W 111.77(13) . . ?
C83 W C84 90.77(16) . . ?
C83 W C85 178.98(16) . . ?
C84 W C85 89.38(16) . . ?
C83 W C2 89.80(15) . . ?
C84 W C2 73.63(14) . . ?
C85 W C2 89.28(15) . . ?
C83 W C1 90.33(14) . . ?
C84 W C1 111.41(14) . . ?
C85 W C1 88.68(14) . . ?
C2 W C1 37.80(13) . . ?
C83 W P2 91.66(11) . . ?
C84 W P2 82.80(11) . . ?
C85 W P2 89.36(11) . . ?
C2 W P2 156.40(10) . . ?
C1 W P2 165.62(10) . . ?
C83 W P1 88.94(12) . . ?
C84 W P1 160.80(11) . . ?
C85 W P1 91.25(11) . . ?
C2 W P1 125.56(10) . . ?
C1 W P1 87.78(10) . . ?
P2 W P1 78.02(3) . . ?

_refine_diff_density_max         2.677
_refine_diff_density_min         -3.164
_refine_diff_density_rms         0.163

