# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_NV1102
_database_code_depnum_ccdc_archive 'CCDC 1008765'
loop_
_audit_author_name
_audit_author_address
Anthony
;University of Zurich
Switzerland
;
_audit_update_record             
;
2019-07-26 deposited with the CCDC.	2019-07-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_audit_creation_date             9-Aug-2016

_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac          ?
_chemical_formula_moiety         'C22 H18 Au Cl2 O2 P, 0.5(C H2 Cl2)'
_chemical_formula_sum            'C22.50 H19 Au Cl3 O2 P'
_chemical_formula_weight         655.69
_chemical_melting_point          ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 90 0.0033 0.0016
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
H H 76 0.0000 0.0000
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Au Au 4 -2.0133 8.8022
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Cl Cl 12 0.1484 0.1585
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
O O 8 0.0106 0.0060
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
P P 4 0.1023 0.0942
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_symmetry_space_group_name_Hall  ?
_symmetry_Int_Tables_number      14

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.59949(18)
_cell_length_b                   10.66900(13)
_cell_length_c                   17.9124(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 108.3351(15)
_cell_angle_gamma                90.00
_cell_volume                     2285.61(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    160(1)
_cell_measurement_reflns_used    14109
_cell_measurement_theta_min      2.2491
_cell_measurement_theta_max      30.3908

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.905
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1260
_exptl_absorpt_coefficient_mu    6.896
_exptl_absorpt_correction_T_min  0.55221
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
CrysAlisPro, Version 1.171.35.4 (Agilent Technologies, 2010)
;

_exptl_special_details           
;
Data collection and full structure determination
done by Prof. Anthony Linden: anthony.linden@chem.uzh.ch

Solvent used: dichloromethane / hexane
Cooling Device: Oxford Instruments Cryojet XL
Crystal mount: on a glass fibre
Frames collected: 379
Seconds exposure per frame: 4.3
Degrees rotation per frame: 1.0
Crystal-detector distance (mm): 55.0
Client: De Haro Teresa
Sample code: HAR-HM-42  (NV1102)
;

_diffrn_ambient_temperature      160(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  
'Oxford Diffraction SuperNova, dual radiation diffractometer'
_diffrn_detector_area_resol_mean 10.3801
_diffrn_detector                 'Atlas CCD camera on \k goniostat'
_diffrn_measurement_method       'ω scans'
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0

loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?

_diffrn_reflns_number            23037
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0294
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.25
_diffrn_reflns_theta_max         30.46
_diffrn_measured_fraction_theta_max 0.900
_diffrn_reflns_theta_full        27.50
_diffrn_measured_fraction_theta_full 0.999
_reflns_number_total             6250
_reflns_number_gt                5692
_reflns_threshold_expression     'I > 2σ(I)'

_computing_data_collection       
'CrysAlisPro, Version 1.171.35.4 (Agilent Technologies, 2010)'
_computing_cell_refinement       
'CrysAlisPro, Version 1.171.35.4 (Agilent Technologies, 2010)'
_computing_data_reduction        
'CrysAlisPro, Version 1.171.35.4 (Agilent Technologies, 2010)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2015)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL-2014 and PLATON (Spek, 2015)'

_refine_special_details          ?

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0197P)²+2.9702P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.00076(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         6250
_refine_ls_number_parameters     282
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0281
_refine_ls_R_factor_gt           0.0239
_refine_ls_wR_factor_ref         0.0536
_refine_ls_wR_factor_gt          0.0518
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.91933(2) 0.93185(2) 0.18253(2) 0.01542(4) Uani 1 1 d . . . . .
Cl1 Cl 1.05208(6) 1.07962(7) 0.18004(5) 0.02639(16) Uani 1 1 d . . . . .
Cl2 Cl 0.77698(6) 1.08128(7) 0.15035(5) 0.02647(16) Uani 1 1 d . . . . .
P1 P 1.06196(6) 0.78481(7) 0.21771(4) 0.01557(14) Uani 1 1 d . . . . .
O3 O 0.5592(2) 0.6279(3) 0.1482(2) 0.0498(8) Uani 1 1 d . . . . .
O4 O 0.6933(2) 0.5232(2) 0.11833(16) 0.0403(6) Uani 1 1 d . . . . .
C1 C 0.8023(2) 0.8012(2) 0.17476(16) 0.0156(5) Uani 1 1 d . . . . .
C2 C 0.7337(3) 0.7250(3) 0.15995(19) 0.0269(7) Uani 1 1 d . . . . .
C3 C 0.6511(3) 0.6241(3) 0.1426(2) 0.0295(7) Uani 1 1 d . . . . .
C5 C 0.6221(4) 0.4092(4) 0.1006(3) 0.0449(10) Uani 1 1 d . . . . .
H51 H 0.5574 0.4242 0.0540 0.067 Uiso 1 1 calc R U . . .
H52 H 0.5963 0.3896 0.1455 0.067 Uiso 1 1 calc R U . . .
H53 H 0.6656 0.3386 0.0907 0.067 Uiso 1 1 calc R U . . .
C6 C 1.0150(2) 0.6244(3) 0.20989(16) 0.0184(5) Uani 1 1 d . . . . .
C7 C 1.0348(3) 0.5435(3) 0.15509(19) 0.0263(7) Uani 1 1 d . . . . .
H7 H 1.0726 0.5723 0.1200 0.032 Uiso 1 1 calc R U . . .
C8 C 0.9990(3) 0.4197(3) 0.1520(2) 0.0369(8) Uani 1 1 d . . . . .
H8 H 1.0125 0.3637 0.1148 0.044 Uiso 1 1 calc R U . . .
C9 C 0.9439(3) 0.3780(3) 0.2027(2) 0.0360(8) Uani 1 1 d . . . . .
H9 H 0.9185 0.2938 0.1996 0.043 Uiso 1 1 calc R U . . .
C10 C 0.9254(3) 0.4585(3) 0.2582(2) 0.0316(8) Uani 1 1 d . . . . .
H10 H 0.8888 0.4288 0.2937 0.038 Uiso 1 1 calc R U . . .
C11 C 0.9601(3) 0.5811(3) 0.26188(19) 0.0238(6) Uani 1 1 d . . . . .
H11 H 0.9470 0.6364 0.2996 0.029 Uiso 1 1 calc R U . . .
C12 C 1.1485(2) 0.8065(3) 0.31895(16) 0.0183(5) Uani 1 1 d . . . . .
C13 C 1.2076(3) 0.7032(3) 0.35875(19) 0.0283(7) Uani 1 1 d . . . . .
H13 H 1.2011 0.6243 0.3332 0.034 Uiso 1 1 calc R U . . .
C14 C 1.2758(3) 0.7165(4) 0.4357(2) 0.0374(8) Uani 1 1 d . . . . .
H14 H 1.3162 0.6464 0.4632 0.045 Uiso 1 1 calc R U . . .
C15 C 1.2853(3) 0.8316(4) 0.47283(19) 0.0350(8) Uani 1 1 d . . . . .
H15 H 1.3317 0.8400 0.5259 0.042 Uiso 1 1 calc R U . . .
C16 C 1.2283(3) 0.9336(3) 0.4336(2) 0.0353(8) Uani 1 1 d . . . . .
H16 H 1.2362 1.0126 0.4593 0.042 Uiso 1 1 calc R U . . .
C17 C 1.1590(3) 0.9222(3) 0.35625(19) 0.0276(7) Uani 1 1 d . . . . .
H17 H 1.1191 0.9928 0.3292 0.033 Uiso 1 1 calc R U . . .
C18 C 1.1441(2) 0.8016(3) 0.15225(16) 0.0182(5) Uani 1 1 d . . . . .
C19 C 1.2591(2) 0.7877(3) 0.17963(18) 0.0244(6) Uani 1 1 d . . . . .
H19 H 1.2966 0.7761 0.2342 0.029 Uiso 1 1 calc R U . . .
C20 C 1.3193(3) 0.7909(4) 0.1265(2) 0.0368(8) Uani 1 1 d . . . . .
H20 H 1.3982 0.7807 0.1447 0.044 Uiso 1 1 calc R U . . .
C21 C 1.2646(3) 0.8090(4) 0.0477(2) 0.0379(9) Uani 1 1 d . . . . .
H21 H 1.3063 0.8115 0.0119 0.046 Uiso 1 1 calc R U . . .
C22 C 1.1498(3) 0.8237(4) 0.02002(19) 0.0335(8) Uani 1 1 d . . . . .
H22 H 1.1128 0.8357 -0.0346 0.040 Uiso 1 1 calc R U . . .
C23 C 1.0892(3) 0.8206(3) 0.07229(17) 0.0255(7) Uani 1 1 d . . . . .
H23 H 1.0104 0.8315 0.0538 0.031 Uiso 1 1 calc R U . . .
Cl3 Cl 0.5197(2) 0.8287(3) -0.01491(17) 0.0622(7) Uani 0.5 1 d . . P . .
Cl4 Cl 0.4726(3) 1.0917(4) 0.0108(2) 0.0771(10) Uani 0.5 1 d . . P . .
C24 C 0.5485(14) 0.9789(14) -0.0203(7) 0.103(6) Uani 0.5 1 d . . P . .
H241 H 0.5410 0.9973 -0.0758 0.124 Uiso 0.5 1 calc R U P . .
H242 H 0.6282 0.9910 0.0104 0.124 Uiso 0.5 1 calc R U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.002(3) . ?
Au1 Cl1 2.3091(7) . ?
Au1 P1 2.3185(7) . ?
Au1 Cl2 2.3324(7) . ?
P1 C18 1.800(3) . ?
P1 C6 1.801(3) . ?
P1 C12 1.813(3) . ?
O3 C3 1.193(4) . ?
O4 C3 1.333(4) . ?
O4 C5 1.484(5) . ?
C1 C2 1.155(4) . ?
C2 C3 1.461(5) . ?
C5 H51 0.9800 . ?
C5 H52 0.9800 . ?
C5 H53 0.9800 . ?
C6 C7 1.388(4) . ?
C6 C11 1.401(4) . ?
C7 C8 1.391(5) . ?
C7 H7 0.9500 . ?
C8 C9 1.378(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.388(5) . ?
C9 H9 0.9500 . ?
C10 C11 1.374(4) . ?
C10 H10 0.9500 . ?
C11 H11 0.9500 . ?
C12 C17 1.390(4) . ?
C12 C13 1.394(4) . ?
C13 C14 1.383(5) . ?
C13 H13 0.9500 . ?
C14 C15 1.384(5) . ?
C14 H14 0.9500 . ?
C15 C16 1.370(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.392(5) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 C19 1.384(4) . ?
C18 C23 1.395(4) . ?
C19 C20 1.391(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.375(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.383(5) . ?
C21 H21 0.9500 . ?
C22 C23 1.382(4) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
Cl3 Cl4 0.856(4) 3_675 ?
Cl3 C24 1.653(14) . ?
Cl4 C24 0.833(12) 3_675 ?
Cl4 Cl3 0.856(4) 3_675 ?
Cl4 C24 1.734(15) . ?
Cl4 Cl4 2.150(7) 3_675 ?
C24 H241 0.9900 . ?
C24 H242 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 Cl1 175.02(8) . . ?
C1 Au1 P1 92.22(8) . . ?
Cl1 Au1 P1 87.88(3) . . ?
C1 Au1 Cl2 88.08(8) . . ?
Cl1 Au1 Cl2 91.94(3) . . ?
P1 Au1 Cl2 178.60(3) . . ?
C18 P1 C6 106.60(13) . . ?
C18 P1 C12 110.53(13) . . ?
C6 P1 C12 106.18(13) . . ?
C18 P1 Au1 108.12(10) . . ?
C6 P1 Au1 114.45(9) . . ?
C12 P1 Au1 110.88(10) . . ?
C3 O4 C5 117.1(3) . . ?
C2 C1 Au1 171.0(3) . . ?
C1 C2 C3 177.3(4) . . ?
O3 C3 O4 123.4(3) . . ?
O3 C3 C2 127.1(3) . . ?
O4 C3 C2 109.5(3) . . ?
O4 C5 H51 109.5 . . ?
O4 C5 H52 109.5 . . ?
H51 C5 H52 109.5 . . ?
O4 C5 H53 109.5 . . ?
H51 C5 H53 109.5 . . ?
H52 C5 H53 109.5 . . ?
C7 C6 C11 120.1(3) . . ?
C7 C6 P1 121.2(2) . . ?
C11 C6 P1 118.7(2) . . ?
C6 C7 C8 119.3(3) . . ?
C6 C7 H7 120.3 . . ?
C8 C7 H7 120.3 . . ?
C9 C8 C7 120.4(3) . . ?
C9 C8 H8 119.8 . . ?
C7 C8 H8 119.8 . . ?
C8 C9 C10 120.3(3) . . ?
C8 C9 H9 119.8 . . ?
C10 C9 H9 119.8 . . ?
C11 C10 C9 120.0(3) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C6 119.9(3) . . ?
C10 C11 H11 120.1 . . ?
C6 C11 H11 120.1 . . ?
C17 C12 C13 120.1(3) . . ?
C17 C12 P1 122.0(2) . . ?
C13 C12 P1 117.8(2) . . ?
C14 C13 C12 119.6(3) . . ?
C14 C13 H13 120.2 . . ?
C12 C13 H13 120.2 . . ?
C13 C14 C15 120.1(3) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C16 C15 C14 120.4(3) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C15 C16 C17 120.3(3) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 H16 119.8 . . ?
C12 C17 C16 119.4(3) . . ?
C12 C17 H17 120.3 . . ?
C16 C17 H17 120.3 . . ?
C19 C18 C23 120.3(3) . . ?
C19 C18 P1 120.7(2) . . ?
C23 C18 P1 118.9(2) . . ?
C18 C19 C20 119.4(3) . . ?
C18 C19 H19 120.3 . . ?
C20 C19 H19 120.3 . . ?
C21 C20 C19 120.0(3) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 120.9(3) . . ?
C20 C21 H21 119.5 . . ?
C22 C21 H21 119.5 . . ?
C23 C22 C21 119.5(3) . . ?
C23 C22 H22 120.3 . . ?
C21 C22 H22 120.3 . . ?
C22 C23 C18 119.9(3) . . ?
C22 C23 H23 120.1 . . ?
C18 C23 H23 120.1 . . ?
Cl4 Cl3 C24 11.7(5) 3_675 . ?
C24 Cl4 Cl3 156.2(11) 3_675 3_675 ?
C24 Cl4 C24 71.4(11) 3_675 . ?
Cl3 Cl4 C24 131.1(7) 3_675 . ?
C24 Cl4 Cl4 49.9(10) 3_675 3_675 ?
Cl3 Cl4 Cl4 152.2(5) 3_675 3_675 ?
C24 Cl4 Cl4 21.6(4) . 3_675 ?
Cl3 C24 Cl4 120.1(7) . . ?
Cl3 C24 H241 107.3 . . ?
Cl4 C24 H241 107.3 . . ?
Cl3 C24 H242 107.3 . . ?
Cl4 C24 H242 107.3 . . ?
H241 C24 H242 106.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 O4 C3 O3 -2.5(5) . . . . ?
C5 O4 C3 C2 177.9(3) . . . . ?
C18 P1 C6 C7 -5.9(3) . . . . ?
C12 P1 C6 C7 -123.8(3) . . . . ?
Au1 P1 C6 C7 113.6(2) . . . . ?
C18 P1 C6 C11 172.4(2) . . . . ?
C12 P1 C6 C11 54.5(3) . . . . ?
Au1 P1 C6 C11 -68.2(3) . . . . ?
C11 C6 C7 C8 0.5(5) . . . . ?
P1 C6 C7 C8 178.8(3) . . . . ?
C6 C7 C8 C9 0.2(6) . . . . ?
C7 C8 C9 C10 -1.1(6) . . . . ?
C8 C9 C10 C11 1.3(6) . . . . ?
C9 C10 C11 C6 -0.5(5) . . . . ?
C7 C6 C11 C10 -0.4(5) . . . . ?
P1 C6 C11 C10 -178.7(3) . . . . ?
C18 P1 C12 C17 93.8(3) . . . . ?
C6 P1 C12 C17 -151.0(3) . . . . ?
Au1 P1 C12 C17 -26.1(3) . . . . ?
C18 P1 C12 C13 -84.7(3) . . . . ?
C6 P1 C12 C13 30.5(3) . . . . ?
Au1 P1 C12 C13 155.4(2) . . . . ?
C17 C12 C13 C14 0.6(5) . . . . ?
P1 C12 C13 C14 179.1(3) . . . . ?
C12 C13 C14 C15 -0.1(5) . . . . ?
C13 C14 C15 C16 -0.6(6) . . . . ?
C14 C15 C16 C17 0.9(6) . . . . ?
C13 C12 C17 C16 -0.4(5) . . . . ?
P1 C12 C17 C16 -178.8(3) . . . . ?
C15 C16 C17 C12 -0.4(5) . . . . ?
C6 P1 C18 C19 -94.3(3) . . . . ?
C12 P1 C18 C19 20.7(3) . . . . ?
Au1 P1 C18 C19 142.2(2) . . . . ?
C6 P1 C18 C23 81.5(3) . . . . ?
C12 P1 C18 C23 -163.5(2) . . . . ?
Au1 P1 C18 C23 -42.0(3) . . . . ?
C23 C18 C19 C20 -1.0(5) . . . . ?
P1 C18 C19 C20 174.8(3) . . . . ?
C18 C19 C20 C21 0.6(6) . . . . ?
C19 C20 C21 C22 -0.3(6) . . . . ?
C20 C21 C22 C23 0.3(6) . . . . ?
C21 C22 C23 C18 -0.7(5) . . . . ?
C19 C18 C23 C22 1.1(5) . . . . ?
P1 C18 C23 C22 -174.8(3) . . . . ?
Cl4 Cl3 C24 Cl4 -19(2) 3_675 . . . ?
C24 Cl4 C24 Cl3 4.1(5) 3_675 . . . ?
Cl3 Cl4 C24 Cl3 174.9(6) 3_675 . . . ?
Cl4 Cl4 C24 Cl3 4.1(5) 3_675 . . . ?

_refine_diff_density_max         1.240
_refine_diff_density_min         -1.192
_refine_diff_density_rms         0.120

