# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2019

data_yano084
_audit_creation_date              2019-01-23
_audit_creation_method
;
Olex2 1.2-ac3
(compiled 2017.02.24 svn.r3390 for Rigaku Oxford Diffraction, GUI svn.r5318)
;
_shelx_SHELXL_version_number      '2017/1'
_publ_contact_author_address      ?
_publ_contact_author_email        ?
_publ_contact_author_id_orcid     ?
_publ_contact_author_name         ''
_publ_contact_author_phone        ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common             ?
_chemical_name_systematic         ?
_chemical_formula_moiety          '2(C6 H3 F3 O), C30 H24 N4'
_chemical_formula_sum             'C42 H30 F6 N4 O2'
_chemical_formula_weight          736.70
_chemical_melting_point           ?
_chemical_oxdiff_usercomment      1-b
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system       'triclinic'
_space_group_IT_number            2
_space_group_name_H-M_alt         'P -1'
_space_group_name_Hall            '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                    7.3705(6)
_cell_length_b                    11.0005(12)
_cell_length_c                    12.0029(13)
_cell_angle_alpha                 109.130(10)
_cell_angle_beta                  106.773(8)
_cell_angle_gamma                 90.454(8)
_cell_volume                      874.66(16)
_cell_formula_units_Z             1
_cell_measurement_reflns_used     2901
_cell_measurement_temperature     298
_cell_measurement_theta_max       32.6600
_cell_measurement_theta_min       2.9450
_shelx_estimated_absorpt_T_max    ?
_shelx_estimated_absorpt_T_min    ?
_exptl_absorpt_coefficient_mu     0.109
_exptl_absorpt_correction_T_max   1.00000
_exptl_absorpt_correction_T_min   0.92706
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.34a (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details    ?
_exptl_crystal_colour             colourless
_exptl_crystal_colour_primary     colourless
_exptl_crystal_density_diffrn     1.399
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     ?
_exptl_crystal_description        block
_exptl_crystal_F_000              380
_exptl_crystal_size_max           0.5
_exptl_crystal_size_mid           0.4
_exptl_crystal_size_min           0.3
_exptl_transmission_factor_max    ?
_exptl_transmission_factor_min    ?
_diffrn_reflns_av_R_equivalents   0.0366
_diffrn_reflns_av_unetI/netI      0.0442
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max        9
_diffrn_reflns_limit_h_min        -9
_diffrn_reflns_limit_k_max        13
_diffrn_reflns_limit_k_min        -13
_diffrn_reflns_limit_l_max        14
_diffrn_reflns_limit_l_min        -14
_diffrn_reflns_number             7431
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full         25.242
_diffrn_reflns_theta_max          26.373
_diffrn_reflns_theta_min          2.905
_diffrn_ambient_temperature       298
_diffrn_detector                  'CCD plate'
_diffrn_detector_area_resol_mean  6.827
_diffrn_detector_type             CCD
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -74.00 119.00   1.00   13.40    --   30.00  54.00 150.00  193
  2  ω    -74.00 -36.00   1.00   13.40    --   30.00  54.00-120.00   38
  3  ω     39.00 110.00   1.00   13.40    --   30.00  54.00-120.00   71
  4  ω    -70.00 114.00   1.00   13.40    --   30.00  54.00  30.00  184
;
_diffrn_measurement_device        'two-circle diffractometer'
_diffrn_measurement_device_type   'XtaLAB Mini (JP)'
_diffrn_measurement_method        'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11       0.0059495000
_diffrn_orient_matrix_UB_12       -0.0676492000
_diffrn_orient_matrix_UB_13       -0.0185600000
_diffrn_orient_matrix_UB_21       -0.1003023000
_diffrn_orient_matrix_UB_22       -0.0118240000
_diffrn_orient_matrix_UB_23       -0.0281766000
_diffrn_orient_matrix_UB_31       0.0117256000
_diffrn_orient_matrix_UB_32       0.0005495000
_diffrn_orient_matrix_UB_33       -0.0564730000
_diffrn_oxdiff_ac3_digest_frames
;
0195517a0161d2b33fc91b564aa46cb85c0048632bd
;
_diffrn_oxdiff_ac3_digest_hkl
;
01b559f685e097934b7bf21a2562d875e8814a
;
_diffrn_radiation_monochromator   graphite
_diffrn_radiation_probe           x-ray
_diffrn_radiation_type            MoK\a
_diffrn_radiation_wavelength      0.71073
_diffrn_source                    'fine-focus sealed X-ray tube'
_diffrn_source_type               'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_full     .
_reflns_Friedel_fraction_max      .
_reflns_number_gt                 2740
_reflns_number_total              3571
_reflns_odcompleteness_completeness 99.86
_reflns_odcompleteness_iscentric  1
_reflns_odcompleteness_theta      26.32
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression      'I > 2σ(I)'
_computing_cell_refinement        'CrysAlisPro 1.171.39.34a (Rigaku OD, 2017)'
_computing_data_collection        'CrysAlisPro 1.171.39.34a (Rigaku OD, 2017)'
_computing_data_reduction         'CrysAlisPro 1.171.39.34a (Rigaku OD, 2017)'
_computing_molecular_graphics     'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material   'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement   'ShelXL (Sheldrick, 2015)'
_computing_structure_solution     'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max          0.226
_refine_diff_density_min          -0.255
_refine_diff_density_rms          0.056
_refine_ls_extinction_coef        .
_refine_ls_extinction_method      none
_refine_ls_goodness_of_fit_ref    1.067
_refine_ls_hydrogen_treatment     mixed
_refine_ls_matrix_type            full
_refine_ls_number_parameters      249
_refine_ls_number_reflns          3571
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0733
_refine_ls_R_factor_gt            0.0578
_refine_ls_restrained_S_all       1.067
_refine_ls_shift/su_max           0.000
_refine_ls_shift/su_mean          0.000
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0868P)²+0.1906P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme       calc
_refine_ls_wR_factor_gt           0.1525
_refine_ls_wR_factor_ref          0.1729
_refine_special_details           ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C5(H5), C8(H8), C3(H3), C14(H14), C2A(H2A), C10(H10), C13(H13), C7(H7),
 C6(H6), C6A(H6A), C11(H11)
2.b Idealised Me refined as rotating group:
 C15(H15A,H15B,H15C)
;
_atom_sites_solution_hydrogens    mixed
_atom_sites_solution_primary      dual
_atom_sites_solution_secondary    ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 F3A F 0.3307(2) 0.43017(13) 0.39610(13) 0.0773(5) Uani 1 1 d . . . . .
 F4A F 0.2980(2) 0.31676(14) 0.15458(13) 0.0772(5) Uani 1 1 d . . . . .
 O1A O 0.2412(2) 0.01513(16) 0.42803(14) 0.0611(4) Uani 1 1 d . . . . .
 N1 N 0.8402(2) 0.41889(15) 1.03966(12) 0.0399(4) Uani 1 1 d . . . . .
 F5A F 0.2287(4) 0.05875(16) 0.04938(13) 0.1091(7) Uani 1 1 d . . . . .
 N2 N 0.3232(2) 0.15267(17) 0.67315(15) 0.0524(5) Uani 1 1 d . . . . .
 C1 C 1.0009(3) 0.49754(17) 1.05687(15) 0.0385(4) Uani 1 1 d . . . . .
 C4 C 0.5511(3) 0.29967(17) 0.85842(16) 0.0393(4) Uani 1 1 d . . . . .
 C5 C 0.4959(3) 0.21940(19) 0.73412(16) 0.0454(5) Uani 1 1 d . . . . .
 H5 H 0.584391 0.211906 0.691201 0.055 Uiso 1 1 calc R . . . .
 C9 C 0.8155(2) 0.37296(18) 1.13328(15) 0.0386(4) Uani 1 1 d . . . . .
 C8 C 0.4176(3) 0.30733(19) 0.92144(17) 0.0449(5) Uani 1 1 d . . . . .
 H8 H 0.446935 0.359981 1.004142 0.054 Uiso 1 1 calc R . . . .
 C3 C 0.8354(3) 0.42652(18) 0.85164(15) 0.0412(4) Uani 1 1 d . . . . .
 H3 H 0.799127 0.413341 0.767270 0.049 Uiso 1 1 calc R . . . .
 C3A C 0.2999(3) 0.2999(2) 0.34587(19) 0.0503(5) Uani 1 1 d . . . . .
 C14 C 0.7898(3) 0.2417(2) 1.11193(18) 0.0484(5) Uani 1 1 d . . . . .
 H14 H 0.781148 0.182099 1.034403 0.058 Uiso 1 1 calc R . . . .
 C2 C 0.7392(3) 0.37539(17) 0.91244(15) 0.0391(4) Uani 1 1 d . . . . .
 C1A C 0.2545(3) 0.0938(2) 0.36402(17) 0.0475(5) Uani 1 1 d . . . . .
 C2A C 0.2867(3) 0.2278(2) 0.41781(17) 0.0493(5) Uani 1 1 d . . . . .
 H2A H 0.299050 0.268069 0.501330 0.059 Uiso 1 1 calc R . . . .
 C12 C 0.7920(3) 0.2849(2) 1.3231(2) 0.0516(5) Uani 1 1 d . . . . .
 C4A C 0.2831(3) 0.2440(2) 0.22288(19) 0.0528(5) Uani 1 1 d . . . . .
 C10 C 0.8264(3) 0.4595(2) 1.24817(17) 0.0498(5) Uani 1 1 d . . . . .
 H10 H 0.841557 0.548058 1.263114 0.060 Uiso 1 1 calc R . . . .
 C13 C 0.7769(3) 0.1990(2) 1.2062(2) 0.0538(5) Uani 1 1 d . . . . .
 H13 H 0.757675 0.110580 1.190465 0.065 Uiso 1 1 calc R . . . .
 C7 C 0.2406(3) 0.2356(2) 0.85950(19) 0.0522(5) Uani 1 1 d . . . . .
 H7 H 0.151020 0.237797 0.900918 0.063 Uiso 1 1 calc R . . . .
 C6 C 0.1981(3) 0.1610(2) 0.73630(19) 0.0548(5) Uani 1 1 d . . . . .
 H6 H 0.077830 0.114623 0.695270 0.066 Uiso 1 1 calc R . . . .
 C6A C 0.2328(4) 0.0360(2) 0.23880(19) 0.0587(6) Uani 1 1 d . . . . .
 H6A H 0.207911 -0.053498 0.201193 0.070 Uiso 1 1 calc R . . . .
 C5A C 0.2484(4) 0.1123(2) 0.17115(19) 0.0615(6) Uani 1 1 d . . . . .
 C11 C 0.8150(3) 0.4152(2) 1.34195(19) 0.0569(6) Uani 1 1 d . . . . .
 H11 H 0.823070 0.474824 1.419322 0.068 Uiso 1 1 calc R . . . .
 C15 C 0.7886(4) 0.2373(3) 1.4273(2) 0.0741(8) Uani 1 1 d . . . . .
 H15A H 0.702192 0.159321 1.394678 0.111 Uiso 1 1 calc GR . . . .
 H15B H 0.747220 0.302313 1.487682 0.111 Uiso 1 1 calc GR . . . .
 H15C H 0.914346 0.219880 1.465717 0.111 Uiso 1 1 calc GR . . . .
 H1A H 0.262(4) 0.063(3) 0.510(3) 0.079(8) Uiso 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 F3A C3A 1.348(2) . ?
 F4A C4A 1.343(2) . ?
 O1A C1A 1.352(2) . ?
 O1A H1A 0.92(3) . ?
 N1 C1 1.385(2) . ?
 N1 C9 1.428(2) . ?
 N1 C2 1.405(2) . ?
 F5A C5A 1.348(2) . ?
 N2 C5 1.338(2) . ?
 N2 C6 1.339(3) . ?
 C1 C1 1.380(3) 2_767 ?
 C1 C3 1.406(2) 2_767 ?
 C4 C5 1.397(2) . ?
 C4 C8 1.392(3) . ?
 C4 C2 1.464(2) . ?
 C5 H5 0.9300 . ?
 C9 C14 1.383(3) . ?
 C9 C10 1.374(3) . ?
 C8 H8 0.9300 . ?
 C8 C7 1.385(3) . ?
 C3 H3 0.9300 . ?
 C3 C2 1.383(2) . ?
 C3A C2A 1.371(3) . ?
 C3A C4A 1.368(3) . ?
 C14 H14 0.9300 . ?
 C14 C13 1.384(3) . ?
 C1A C2A 1.389(3) . ?
 C1A C6A 1.386(3) . ?
 C2A H2A 0.9300 . ?
 C12 C13 1.384(3) . ?
 C12 C11 1.376(3) . ?
 C12 C15 1.513(3) . ?
 C4A C5A 1.365(3) . ?
 C10 H10 0.9300 . ?
 C10 C11 1.388(3) . ?
 C13 H13 0.9300 . ?
 C7 H7 0.9300 . ?
 C7 C6 1.375(3) . ?
 C6 H6 0.9300 . ?
 C6A H6A 0.9300 . ?
 C6A C5A 1.370(3) . ?
 C11 H11 0.9300 . ?
 C15 H15A 0.9600 . ?
 C15 H15B 0.9600 . ?
 C15 H15C 0.9600 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C1A O1A H1A 109.8(17) . . ?
 C1 N1 C9 122.82(14) . . ?
 C1 N1 C2 107.02(14) . . ?
 C2 N1 C9 128.81(15) . . ?
 C5 N2 C6 117.79(17) . . ?
 N1 C1 C3 142.58(16) . 2_767 ?
 C1 C1 N1 108.29(19) 2_767 . ?
 C1 C1 C3 109.1(2) 2_767 2_767 ?
 C5 C4 C2 118.86(16) . . ?
 C8 C4 C5 117.02(17) . . ?
 C8 C4 C2 124.04(16) . . ?
 N2 C5 C4 123.91(18) . . ?
 N2 C5 H5 118.0 . . ?
 C4 C5 H5 118.0 . . ?
 C14 C9 N1 120.78(16) . . ?
 C10 C9 N1 119.92(17) . . ?
 C10 C9 C14 119.22(17) . . ?
 C4 C8 H8 120.4 . . ?
 C7 C8 C4 119.19(17) . . ?
 C7 C8 H8 120.4 . . ?
 C1 C3 H3 126.9 2_767 . ?
 C2 C3 C1 106.14(15) . 2_767 ?
 C2 C3 H3 126.9 . . ?
 F3A C3A C2A 119.98(18) . . ?
 F3A C3A C4A 117.92(19) . . ?
 C4A C3A C2A 122.1(2) . . ?
 C9 C14 H14 120.1 . . ?
 C9 C14 C13 119.90(19) . . ?
 C13 C14 H14 120.1 . . ?
 N1 C2 C4 123.70(15) . . ?
 C3 C2 N1 109.42(15) . . ?
 C3 C2 C4 126.55(15) . . ?
 O1A C1A C2A 123.01(18) . . ?
 O1A C1A C6A 117.43(19) . . ?
 C6A C1A C2A 119.56(19) . . ?
 C3A C2A C1A 118.97(18) . . ?
 C3A C2A H2A 120.5 . . ?
 C1A C2A H2A 120.5 . . ?
 C13 C12 C15 121.1(2) . . ?
 C11 C12 C13 117.60(18) . . ?
 C11 C12 C15 121.2(2) . . ?
 F4A C4A C3A 121.0(2) . . ?
 F4A C4A C5A 120.93(19) . . ?
 C5A C4A C3A 118.1(2) . . ?
 C9 C10 H10 119.9 . . ?
 C9 C10 C11 120.14(19) . . ?
 C11 C10 H10 119.9 . . ?
 C14 C13 H13 119.2 . . ?
 C12 C13 C14 121.6(2) . . ?
 C12 C13 H13 119.2 . . ?
 C8 C7 H7 120.2 . . ?
 C6 C7 C8 119.52(19) . . ?
 C6 C7 H7 120.2 . . ?
 N2 C6 C7 122.54(18) . . ?
 N2 C6 H6 118.7 . . ?
 C7 C6 H6 118.7 . . ?
 C1A C6A H6A 120.4 . . ?
 C5A C6A C1A 119.2(2) . . ?
 C5A C6A H6A 120.4 . . ?
 F5A C5A C4A 117.5(2) . . ?
 F5A C5A C6A 120.5(2) . . ?
 C4A C5A C6A 122.06(19) . . ?
 C12 C11 C10 121.6(2) . . ?
 C12 C11 H11 119.2 . . ?
 C10 C11 H11 119.2 . . ?
 C12 C15 H15A 109.5 . . ?
 C12 C15 H15B 109.5 . . ?
 C12 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.152
_oxdiff_exptl_absorpt_empirical_full_min 0.839
