# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p
_database_code_depnum_ccdc_archive 'CCDC 1937449'
loop_
_audit_author_name
_audit_author_address
'Xing-Dong Xu'
;Shandong University
China
;
_audit_update_record             
;
2019-07-01 deposited with the CCDC.	2019-10-04 downloaded from the CCDC.
;
_audit_creation_date             2017-12-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            1M
_chemical_name_systematic        ?
_chemical_formula_moiety         'C31 H19 N O'
_chemical_formula_sum            'C31 H19 N O'
_chemical_formula_weight         421.47
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'

_cell_length_a                   5.0685(13)
_cell_length_b                   12.330(3)
_cell_length_c                   34.435(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2152.1(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2817
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.023
_cell_measurement_theta_min      2.366
_shelx_estimated_absorpt_T_max   0.998
_shelx_estimated_absorpt_T_min   0.992
_exptl_absorpt_coefficient_mu    0.078
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6216
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1321 before and 0.0444 after correction.
The Ratio of minimum to maximum transmission is 0.8337.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'Pale yellow'
_exptl_crystal_density_diffrn    1.301
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       ?
_exptl_crystal_F_000             880
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0333
_diffrn_reflns_av_unetI/netI     0.0367
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -4
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            12971
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        24.997
_diffrn_reflns_theta_max         24.997
_diffrn_reflns_theta_min         1.752
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.710
_diffrn_source                   ?
_reflns_Friedel_coverage         0.686
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                2894
_reflns_number_total             3779
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_refine_diff_density_max         0.102
_refine_diff_density_min         -0.133
_refine_diff_density_rms         0.028
_refine_ls_abs_structure_details 
;
 Flack x determined using 983 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.1(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         3779
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0597
_refine_ls_R_factor_gt           0.0380
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0350P)²+0.1930P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0773
_refine_ls_wR_factor_ref         0.0876
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 N1(H1), C23(H23), C15(H15), C24(H24), C27(H27), C11(H11), C21(H21), C31(H31),
 C20(H20), C29(H29), C8(H8), C16(H16), C10(H10), C30(H30), C28(H28), C7(H7),
 C6(H6), C2(H2), C1(H1A)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.5712(4) 0.69173(17) 0.44825(5) 0.0638(6) Uani 1 1 d . . . . .
N1 N 0.1412(4) 0.64372(17) 0.45390(6) 0.0474(6) Uani 1 1 d . . . . .
H1 H -0.0160 0.6594 0.4464 0.057 Uiso 1 1 calc R . . . .
C26 C 0.2600(5) 0.7873(2) 0.40945(7) 0.0420(6) Uani 1 1 d . . . . .
C22 C 0.1656(5) 0.5570(2) 0.48078(7) 0.0432(6) Uani 1 1 d . . . . .
C13 C 0.4040(5) 0.1557(2) 0.64455(7) 0.0425(6) Uani 1 1 d . . . . .
C12 C 0.2173(6) 0.1458(2) 0.61440(7) 0.0471(7) Uani 1 1 d . . . . .
C14 C 0.4230(6) 0.0722(2) 0.67286(7) 0.0429(7) Uani 1 1 d . . . . .
C19 C 0.1823(6) 0.3867(2) 0.53388(7) 0.0483(7) Uani 1 1 d . . . . .
C9 C 0.2552(6) -0.0196(2) 0.67057(7) 0.0501(7) Uani 1 1 d . . . . .
C25 C 0.3387(6) 0.7042(2) 0.43887(7) 0.0449(6) Uani 1 1 d . . . . .
C4 C 0.6079(6) 0.0821(2) 0.70375(7) 0.0477(7) Uani 1 1 d . . . . .
C23 C 0.3607(6) 0.5544(2) 0.50900(7) 0.0547(8) Uani 1 1 d . . . . .
H23 H 0.4863 0.6092 0.5104 0.066 Uiso 1 1 calc R . . . .
C15 C 0.5752(6) 0.2466(2) 0.64764(7) 0.0534(8) Uani 1 1 d . . . . .
H15 H 0.5648 0.3017 0.6292 0.064 Uiso 1 1 calc R . . . .
C18 C 0.1863(6) 0.2999(2) 0.56200(7) 0.0550(7) Uani 1 1 d . . . . .
C17 C 0.1957(6) 0.2292(2) 0.58566(7) 0.0541(8) Uani 1 1 d . . . . .
C24 C 0.3656(6) 0.4689(2) 0.53506(7) 0.0577(8) Uani 1 1 d . . . . .
H24 H 0.4968 0.4671 0.5539 0.069 Uiso 1 1 calc R . . . .
C27 C 0.0546(6) 0.7724(2) 0.38355(8) 0.0572(8) Uani 1 1 d . . . . .
H27 H -0.0458 0.7094 0.3844 0.069 Uiso 1 1 calc R . . . .
C5 C 0.6248(7) -0.0006(3) 0.73255(7) 0.0596(9) Uani 1 1 d . . . . .
C11 C 0.0537(6) 0.0545(2) 0.61290(8) 0.0583(8) Uani 1 1 d . . . . .
H11 H -0.0701 0.0482 0.5931 0.070 Uiso 1 1 calc R . . . .
C21 C -0.0181(6) 0.4752(2) 0.47936(8) 0.0552(8) Uani 1 1 d . . . . .
H21 H -0.1494 0.4772 0.4605 0.066 Uiso 1 1 calc R . . . .
C31 C 0.4035(6) 0.8819(2) 0.40763(8) 0.0596(8) Uani 1 1 d . . . . .
H31 H 0.5439 0.8923 0.4246 0.072 Uiso 1 1 calc R . . . .
C20 C -0.0115(6) 0.3903(2) 0.50540(7) 0.0596(8) Uani 1 1 d . . . . .
H20 H -0.1369 0.3354 0.5039 0.072 Uiso 1 1 calc R . . . .
C3 C 0.7756(6) 0.1735(2) 0.70594(7) 0.0533(8) Uani 1 1 d . . . . .
C29 C 0.1396(7) 0.9459(2) 0.35531(8) 0.0612(8) Uani 1 1 d . . . . .
H29 H 0.0980 0.9994 0.3373 0.073 Uiso 1 1 calc R . . . .
C8 C 0.2809(7) -0.1024(2) 0.69977(9) 0.0670(9) Uani 1 1 d . . . . .
H8 H 0.1748 -0.1638 0.6985 0.080 Uiso 1 1 calc R . . . .
C16 C 0.7528(6) 0.2548(2) 0.67680(8) 0.0589(8) Uani 1 1 d . . . . .
H16 H 0.8630 0.3150 0.6778 0.071 Uiso 1 1 calc R . . . .
C10 C 0.0736(6) -0.0261(2) 0.64040(8) 0.0600(8) Uani 1 1 d . . . . .
H10 H -0.0367 -0.0862 0.6388 0.072 Uiso 1 1 calc R . . . .
C30 C 0.3417(7) 0.9615(2) 0.38092(8) 0.0676(9) Uani 1 1 d . . . . .
H30 H 0.4379 1.0257 0.3804 0.081 Uiso 1 1 calc R . . . .
C28 C -0.0009(7) 0.8518(3) 0.35631(8) 0.0656(9) Uani 1 1 d . . . . .
H28 H -0.1359 0.8407 0.3385 0.079 Uiso 1 1 calc R . . . .
C7 C 0.4561(8) -0.0924(3) 0.72891(9) 0.0724(10) Uani 1 1 d . . . . .
H7 H 0.4674 -0.1474 0.7473 0.087 Uiso 1 1 calc R . . . .
C6 C 0.8050(8) 0.0120(3) 0.76280(8) 0.0761(11) Uani 1 1 d . . . . .
H6 H 0.8155 -0.0406 0.7821 0.091 Uiso 1 1 calc R . . . .
C2 C 0.9554(7) 0.1804(3) 0.73653(8) 0.0709(9) Uani 1 1 d . . . . .
H2 H 1.0687 0.2396 0.7380 0.085 Uiso 1 1 calc R . . . .
C1 C 0.9680(9) 0.1013(4) 0.76447(9) 0.0832(12) Uani 1 1 d . . . . .
H1A H 1.0878 0.1081 0.7848 0.100 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C25 1.231(3) . ?
N1 C22 1.419(3) . ?
N1 C25 1.352(3) . ?
C26 C25 1.495(3) . ?
C26 C27 1.383(3) . ?
C26 C31 1.376(4) . ?
C22 C23 1.387(3) . ?
C22 C21 1.374(4) . ?
C13 C12 1.410(4) . ?
C13 C14 1.420(3) . ?
C13 C15 1.422(4) . ?
C12 C17 1.431(4) . ?
C12 C11 1.400(4) . ?
C14 C9 1.418(4) . ?
C14 C4 1.423(4) . ?
C19 C18 1.443(4) . ?
C19 C24 1.376(4) . ?
C19 C20 1.389(4) . ?
C9 C8 1.439(4) . ?
C9 C10 1.390(4) . ?
C4 C5 1.425(4) . ?
C4 C3 1.413(4) . ?
C23 C24 1.384(4) . ?
C15 C16 1.352(4) . ?
C18 C17 1.194(3) . ?
C27 C28 1.384(4) . ?
C5 C7 1.424(5) . ?
C5 C6 1.394(4) . ?
C11 C10 1.376(4) . ?
C21 C20 1.379(4) . ?
C31 C30 1.381(4) . ?
C3 C16 1.423(4) . ?
C3 C2 1.396(4) . ?
C29 C30 1.365(4) . ?
C29 C28 1.362(4) . ?
C8 C7 1.346(5) . ?
C6 C1 1.378(5) . ?
C2 C1 1.371(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C25 N1 C22 126.9(2) . . ?
C27 C26 C25 123.2(2) . . ?
C31 C26 C25 118.1(2) . . ?
C31 C26 C27 118.7(2) . . ?
C23 C22 N1 122.5(3) . . ?
C21 C22 N1 118.1(2) . . ?
C21 C22 C23 119.4(2) . . ?
C12 C13 C14 119.2(2) . . ?
C12 C13 C15 122.2(2) . . ?
C14 C13 C15 118.6(2) . . ?
C13 C12 C17 119.9(3) . . ?
C11 C12 C13 119.6(2) . . ?
C11 C12 C17 120.5(3) . . ?
C13 C14 C4 119.7(2) . . ?
C9 C14 C13 120.0(2) . . ?
C9 C14 C4 120.3(2) . . ?
C24 C19 C18 121.2(3) . . ?
C24 C19 C20 118.4(2) . . ?
C20 C19 C18 120.5(3) . . ?
C14 C9 C8 118.3(3) . . ?
C10 C9 C14 119.0(2) . . ?
C10 C9 C8 122.8(3) . . ?
O1 C25 N1 122.6(2) . . ?
O1 C25 C26 121.3(3) . . ?
N1 C25 C26 116.1(2) . . ?
C14 C4 C5 119.9(3) . . ?
C3 C4 C14 120.3(2) . . ?
C3 C4 C5 119.8(3) . . ?
C24 C23 C22 119.0(3) . . ?
C16 C15 C13 121.3(2) . . ?
C17 C18 C19 178.2(3) . . ?
C18 C17 C12 177.7(3) . . ?
C19 C24 C23 122.0(3) . . ?
C26 C27 C28 119.8(3) . . ?
C7 C5 C4 118.1(3) . . ?
C6 C5 C4 118.7(3) . . ?
C6 C5 C7 123.2(3) . . ?
C10 C11 C12 120.8(3) . . ?
C22 C21 C20 121.2(3) . . ?
C26 C31 C30 120.9(3) . . ?
C21 C20 C19 120.0(3) . . ?
C4 C3 C16 118.4(3) . . ?
C2 C3 C4 118.8(3) . . ?
C2 C3 C16 122.8(3) . . ?
C28 C29 C30 119.7(3) . . ?
C7 C8 C9 121.0(3) . . ?
C15 C16 C3 121.7(3) . . ?
C11 C10 C9 121.4(3) . . ?
C29 C30 C31 120.0(3) . . ?
C29 C28 C27 120.9(3) . . ?
C8 C7 C5 122.3(3) . . ?
C1 C6 C5 120.8(3) . . ?
C1 C2 C3 121.1(3) . . ?
C2 C1 C6 120.8(3) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: DCM/MeOH'
_exptl_crystal_preparation       Luminescent
