# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1504806'
_audit_update_record             
;
2016-09-18 deposited with the CCDC.	2019-09-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C27 H23 N3 O2 Pt'
_chemical_formula_weight         616.57

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.0445(13)
_cell_length_b                   10.5520(15)
_cell_length_c                   13.010(2)
_cell_angle_alpha                81.909(9)
_cell_angle_beta                 70.755(9)
_cell_angle_gamma                84.493(9)
_cell_volume                     1159.0(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5202
_cell_measurement_theta_min      2.39
_cell_measurement_theta_max      23.75

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            YELLOW
_exptl_crystal_size_max          0.142
_exptl_crystal_size_mid          0.074
_exptl_crystal_size_min          0.010
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.767
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             600
_exptl_absorpt_coefficient_mu    6.083
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.300
_exptl_absorpt_correction_T_max  0.515
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            12146
_diffrn_reflns_av_R_equivalents  0.0297
_diffrn_reflns_av_sigmaI/netI    0.0331
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.67
_diffrn_reflns_theta_max         24.79
_reflns_number_total             3885
_reflns_number_gt                3410
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0441P)²+0.3358P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3885
_refine_ls_number_parameters     300
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0314
_refine_ls_R_factor_gt           0.0235
_refine_ls_wR_factor_ref         0.0590
_refine_ls_wR_factor_gt          0.0552
_refine_ls_goodness_of_fit_ref   0.866
_refine_ls_restrained_S_all      0.866
_refine_ls_shift/su_max          0.037
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.599236(18) 0.439656(16) 0.080136(14) 0.03489(8) Uani 1 1 d . . .
N1 N 0.7711(4) 0.5543(4) -0.0039(3) 0.0367(9) Uani 1 1 d . . .
N2 N 0.8841(5) 0.7493(4) -0.0034(3) 0.0484(10) Uani 1 1 d . . .
N3 N 0.2361(4) 0.7159(4) 0.4088(3) 0.0480(10) Uani 1 1 d . . .
O1 O 0.7053(4) 0.2900(3) -0.0128(3) 0.0460(8) Uani 1 1 d . . .
O2 O 0.4217(4) 0.3324(3) 0.1758(3) 0.0421(8) Uani 1 1 d . . .
C1 C 0.2779(7) 0.1523(5) 0.2542(5) 0.0614(15) Uani 1 1 d . . .
H1A H 0.2858 0.1527 0.3259 0.092 Uiso 1 1 calc R . .
H1B H 0.2752 0.0655 0.2408 0.092 Uiso 1 1 calc R . .
H1C H 0.1837 0.1995 0.2497 0.092 Uiso 1 1 calc R . .
C2 C 0.4161(6) 0.2127(5) 0.1706(4) 0.0445(12) Uani 1 1 d . . .
C3 C 0.5250(6) 0.1386(5) 0.0978(4) 0.0514(13) Uani 1 1 d . . .
H3 H 0.5053 0.0522 0.1064 0.062 Uiso 1 1 calc R . .
C4 C 0.6609(6) 0.1767(5) 0.0130(4) 0.0490(12) Uani 1 1 d . . .
C5 C 0.7667(8) 0.0778(6) -0.0534(5) 0.0788(19) Uani 1 1 d . . .
H5A H 0.7563 0.0878 -0.1252 0.118 Uiso 1 1 calc R . .
H5B H 0.7377 -0.0064 -0.0178 0.118 Uiso 1 1 calc R . .
H5C H 0.8735 0.0888 -0.0594 0.118 Uiso 1 1 calc R . .
C6 C 0.8878(5) 0.5309(5) -0.0965(4) 0.0464(12) Uani 1 1 d . . .
H6 H 0.8888 0.4573 -0.1286 0.056 Uiso 1 1 calc R . .
C7 C 1.0043(6) 0.6142(6) -0.1433(4) 0.0556(14) Uani 1 1 d . . .
H7 H 1.0845 0.5988 -0.2075 0.067 Uiso 1 1 calc R . .
C8 C 1.0001(6) 0.7206(6) -0.0937(4) 0.0556(14) Uani 1 1 d . . .
H8 H 1.0815 0.7760 -0.1239 0.067 Uiso 1 1 calc R . .
C9 C 0.7729(5) 0.6654(4) 0.0382(4) 0.0381(11) Uani 1 1 d . . .
C10 C 0.6375(5) 0.6842(4) 0.1357(4) 0.0364(10) Uani 1 1 d . . .
C11 C 0.6126(5) 0.7902(5) 0.1929(4) 0.0444(11) Uani 1 1 d . . .
H11 H 0.6841 0.8544 0.1701 0.053 Uiso 1 1 calc R . .
C12 C 0.4815(5) 0.7995(5) 0.2837(4) 0.0451(12) Uani 1 1 d . . .
H12 H 0.4658 0.8692 0.3233 0.054 Uiso 1 1 calc R . .
C13 C 0.3718(5) 0.7045(5) 0.3165(4) 0.0384(10) Uani 1 1 d . . .
C14 C 0.3984(5) 0.5982(4) 0.2590(4) 0.0372(10) Uani 1 1 d . . .
H14 H 0.3260 0.5347 0.2820 0.045 Uiso 1 1 calc R . .
C15 C 0.5315(5) 0.5849(4) 0.1674(3) 0.0335(10) Uani 1 1 d . . .
C16 C 0.0850(5) 0.6938(5) 0.4060(4) 0.0413(11) Uani 1 1 d . . .
C17 C 0.0553(5) 0.7002(5) 0.3088(4) 0.0491(12) Uani 1 1 d . . .
H17 H 0.1354 0.7183 0.2430 0.059 Uiso 1 1 calc R . .
C18 C -0.0933(6) 0.6800(6) 0.3076(5) 0.0594(15) Uani 1 1 d . . .
H18 H -0.1115 0.6830 0.2409 0.071 Uiso 1 1 calc R . .
C19 C -0.2131(7) 0.6556(6) 0.4030(6) 0.0702(17) Uani 1 1 d . . .
H19 H -0.3129 0.6429 0.4018 0.084 Uiso 1 1 calc R . .
C20 C -0.1848(6) 0.6499(6) 0.5007(5) 0.0682(17) Uani 1 1 d . . .
H20 H -0.2663 0.6342 0.5660 0.082 Uiso 1 1 calc R . .
C21 C -0.0373(6) 0.6673(5) 0.5033(4) 0.0558(14) Uani 1 1 d . . .
H21 H -0.0192 0.6613 0.5702 0.067 Uiso 1 1 calc R . .
C22 C 0.2494(5) 0.7773(5) 0.4968(4) 0.0443(11) Uani 1 1 d . . .
C23 C 0.1811(7) 0.8964(6) 0.5167(5) 0.0684(17) Uani 1 1 d . . .
H23 H 0.1224 0.9376 0.4738 0.082 Uiso 1 1 calc R . .
C24 C 0.1981(10) 0.9562(7) 0.5993(6) 0.090(2) Uani 1 1 d . . .
H24 H 0.1492 1.0365 0.6132 0.108 Uiso 1 1 calc R . .
C25 C 0.2862(9) 0.8974(9) 0.6601(6) 0.089(2) Uani 1 1 d . . .
H25 H 0.2995 0.9389 0.7148 0.107 Uiso 1 1 calc R . .
C26 C 0.3365(6) 0.7174(6) 0.5600(4) 0.0569(14) Uani 1 1 d . . .
H26 H 0.3824 0.6359 0.5473 0.068 Uiso 1 1 calc R . .
C27 C 0.3569(8) 0.7764(9) 0.6424(5) 0.080(2) Uani 1 1 d . . .
H27 H 0.4166 0.7359 0.6849 0.096 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C15 1.966(4) . ?
Pt1 N1 1.986(4) . ?
Pt1 O2 2.011(3) . ?
Pt1 O1 2.087(3) . ?
Pt1 Pt1 3.2362(5) 2_665 ?
N1 C6 1.349(6) . ?
N1 C9 1.366(6) . ?
N2 C9 1.329(6) . ?
N2 C8 1.341(6) . ?
N3 C13 1.416(5) . ?
N3 C16 1.421(6) . ?
N3 C22 1.436(6) . ?
O1 C4 1.263(6) . ?
O2 C2 1.281(6) . ?
C1 C2 1.487(7) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C3 1.387(7) . ?
C3 C4 1.402(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.506(7) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C7 1.363(7) . ?
C6 H6 0.9300 . ?
C7 C8 1.364(8) . ?
C7 H7 0.9300 . ?
C8 H8 0.9300 . ?
C9 C10 1.465(6) . ?
C10 C11 1.391(7) . ?
C10 C15 1.412(6) . ?
C11 C12 1.377(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.401(7) . ?
C12 H12 0.9300 . ?
C13 C14 1.393(6) . ?
C14 C15 1.400(6) . ?
C14 H14 0.9300 . ?
C16 C17 1.369(6) . ?
C16 C21 1.393(7) . ?
C17 C18 1.387(7) . ?
C17 H17 0.9300 . ?
C18 C19 1.363(8) . ?
C18 H18 0.9300 . ?
C19 C20 1.368(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.376(8) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C22 C23 1.365(7) . ?
C22 C26 1.371(7) . ?
C23 C24 1.377(9) . ?
C23 H23 0.9300 . ?
C24 C25 1.352(11) . ?
C24 H24 0.9300 . ?
C25 C27 1.387(11) . ?
C25 H25 0.9300 . ?
C26 C27 1.382(8) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C15 Pt1 N1 81.48(16) . . ?
C15 Pt1 O2 93.97(16) . . ?
N1 Pt1 O2 175.18(13) . . ?
C15 Pt1 O1 171.31(14) . . ?
N1 Pt1 O1 92.06(14) . . ?
O2 Pt1 O1 92.31(13) . . ?
C15 Pt1 Pt1 91.36(12) . 2_665 ?
N1 Pt1 Pt1 89.65(10) . 2_665 ?
O2 Pt1 Pt1 92.04(9) . 2_665 ?
O1 Pt1 Pt1 94.42(9) . 2_665 ?
C6 N1 C9 117.4(4) . . ?
C6 N1 Pt1 126.1(3) . . ?
C9 N1 Pt1 116.5(3) . . ?
C9 N2 C8 116.1(4) . . ?
C13 N3 C16 121.5(4) . . ?
C13 N3 C22 117.7(4) . . ?
C16 N3 C22 119.5(4) . . ?
C4 O1 Pt1 123.2(3) . . ?
C2 O2 Pt1 123.8(3) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O2 C2 C3 126.4(5) . . ?
O2 C2 C1 113.9(5) . . ?
C3 C2 C1 119.6(5) . . ?
C2 C3 C4 128.6(5) . . ?
C2 C3 H3 115.7 . . ?
C4 C3 H3 115.7 . . ?
O1 C4 C3 124.9(5) . . ?
O1 C4 C5 115.6(5) . . ?
C3 C4 C5 119.5(5) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
N1 C6 C7 120.6(5) . . ?
N1 C6 H6 119.7 . . ?
C7 C6 H6 119.7 . . ?
C6 C7 C8 118.2(5) . . ?
C6 C7 H7 120.9 . . ?
C8 C7 H7 120.9 . . ?
N2 C8 C7 123.1(5) . . ?
N2 C8 H8 118.4 . . ?
C7 C8 H8 118.4 . . ?
N2 C9 N1 124.6(4) . . ?
N2 C9 C10 122.5(4) . . ?
N1 C9 C10 112.9(4) . . ?
C11 C10 C15 122.0(4) . . ?
C11 C10 C9 123.7(4) . . ?
C15 C10 C9 114.3(4) . . ?
C12 C11 C10 119.5(5) . . ?
C12 C11 H11 120.2 . . ?
C10 C11 H11 120.2 . . ?
C11 C12 C13 120.3(4) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C14 C13 C12 119.7(4) . . ?
C14 C13 N3 120.4(4) . . ?
C12 C13 N3 119.9(4) . . ?
C13 C14 C15 121.4(4) . . ?
C13 C14 H14 119.3 . . ?
C15 C14 H14 119.3 . . ?
C14 C15 C10 117.0(4) . . ?
C14 C15 Pt1 128.4(3) . . ?
C10 C15 Pt1 114.5(3) . . ?
C17 C16 C21 118.6(5) . . ?
C17 C16 N3 121.2(4) . . ?
C21 C16 N3 120.2(4) . . ?
C16 C17 C18 120.5(5) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C19 C18 C17 120.7(5) . . ?
C19 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C18 C19 C20 119.2(5) . . ?
C18 C19 H19 120.4 . . ?
C20 C19 H19 120.4 . . ?
C19 C20 C21 120.9(5) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 H20 119.6 . . ?
C20 C21 C16 120.1(5) . . ?
C20 C21 H21 119.9 . . ?
C16 C21 H21 119.9 . . ?
C23 C22 C26 119.3(5) . . ?
C23 C22 N3 121.2(5) . . ?
C26 C22 N3 119.5(5) . . ?
C22 C23 C24 120.8(6) . . ?
C22 C23 H23 119.6 . . ?
C24 C23 H23 119.6 . . ?
C25 C24 C23 119.6(7) . . ?
C25 C24 H24 120.2 . . ?
C23 C24 H24 120.2 . . ?
C24 C25 C27 121.1(6) . . ?
C24 C25 H25 119.5 . . ?
C27 C25 H25 119.5 . . ?
C22 C26 C27 120.9(6) . . ?
C22 C26 H26 119.6 . . ?
C27 C26 H26 119.6 . . ?
C26 C27 C25 118.3(6) . . ?
C26 C27 H27 120.8 . . ?
C25 C27 H27 120.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C15 Pt1 N1 C6 -176.5(4) . . . . ?
O2 Pt1 N1 C6 164.3(13) . . . . ?
O1 Pt1 N1 C6 9.3(4) . . . . ?
Pt1 Pt1 N1 C6 -85.1(4) 2_665 . . . ?
C15 Pt1 N1 C9 5.4(3) . . . . ?
O2 Pt1 N1 C9 -13.7(16) . . . . ?
O1 Pt1 N1 C9 -168.8(3) . . . . ?
Pt1 Pt1 N1 C9 96.8(3) 2_665 . . . ?
C15 Pt1 O1 C4 126.9(10) . . . . ?
N1 Pt1 O1 C4 168.7(4) . . . . ?
O2 Pt1 O1 C4 -9.3(4) . . . . ?
Pt1 Pt1 O1 C4 -101.5(4) 2_665 . . . ?
C15 Pt1 O2 C2 -167.6(4) . . . . ?
N1 Pt1 O2 C2 -148.7(14) . . . . ?
O1 Pt1 O2 C2 6.4(4) . . . . ?
Pt1 Pt1 O2 C2 100.9(3) 2_665 . . . ?
Pt1 O2 C2 C3 -2.4(7) . . . . ?
Pt1 O2 C2 C1 176.5(3) . . . . ?
O2 C2 C3 C4 -2.0(9) . . . . ?
C1 C2 C3 C4 179.2(5) . . . . ?
Pt1 O1 C4 C3 8.3(7) . . . . ?
Pt1 O1 C4 C5 -170.6(4) . . . . ?
C2 C3 C4 O1 -1.5(9) . . . . ?
C2 C3 C4 C5 177.4(6) . . . . ?
C9 N1 C6 C7 1.8(6) . . . . ?
Pt1 N1 C6 C7 -176.3(4) . . . . ?
N1 C6 C7 C8 0.5(7) . . . . ?
C9 N2 C8 C7 1.8(8) . . . . ?
C6 C7 C8 N2 -2.4(8) . . . . ?
C8 N2 C9 N1 0.7(7) . . . . ?
C8 N2 C9 C10 -179.2(4) . . . . ?
C6 N1 C9 N2 -2.5(6) . . . . ?
Pt1 N1 C9 N2 175.8(3) . . . . ?
C6 N1 C9 C10 177.4(4) . . . . ?
Pt1 N1 C9 C10 -4.4(5) . . . . ?
N2 C9 C10 C11 0.1(7) . . . . ?
N1 C9 C10 C11 -179.7(4) . . . . ?
N2 C9 C10 C15 179.8(4) . . . . ?
N1 C9 C10 C15 -0.1(5) . . . . ?
C15 C10 C11 C12 0.2(7) . . . . ?
C9 C10 C11 C12 179.9(4) . . . . ?
C10 C11 C12 C13 -1.6(7) . . . . ?
C11 C12 C13 C14 2.0(7) . . . . ?
C11 C12 C13 N3 -179.0(4) . . . . ?
C16 N3 C13 C14 -47.2(7) . . . . ?
C22 N3 C13 C14 146.3(4) . . . . ?
C16 N3 C13 C12 133.9(5) . . . . ?
C22 N3 C13 C12 -32.6(6) . . . . ?
C12 C13 C14 C15 -1.1(7) . . . . ?
N3 C13 C14 C15 179.9(4) . . . . ?
C13 C14 C15 C10 -0.2(6) . . . . ?
C13 C14 C15 Pt1 175.8(3) . . . . ?
C11 C10 C15 C14 0.6(6) . . . . ?
C9 C10 C15 C14 -179.0(4) . . . . ?
C11 C10 C15 Pt1 -175.9(4) . . . . ?
C9 C10 C15 Pt1 4.4(5) . . . . ?
N1 Pt1 C15 C14 178.7(4) . . . . ?
O2 Pt1 C15 C14 -2.9(4) . . . . ?
O1 Pt1 C15 C14 -139.0(8) . . . . ?
Pt1 Pt1 C15 C14 89.3(4) 2_665 . . . ?
N1 Pt1 C15 C10 -5.2(3) . . . . ?
O2 Pt1 C15 C10 173.2(3) . . . . ?
O1 Pt1 C15 C10 37.0(11) . . . . ?
Pt1 Pt1 C15 C10 -94.7(3) 2_665 . . . ?
C13 N3 C16 C17 -20.6(7) . . . . ?
C22 N3 C16 C17 145.6(5) . . . . ?
C13 N3 C16 C21 160.6(5) . . . . ?
C22 N3 C16 C21 -33.2(7) . . . . ?
C21 C16 C17 C18 -0.4(8) . . . . ?
N3 C16 C17 C18 -179.2(5) . . . . ?
C16 C17 C18 C19 1.2(9) . . . . ?
C17 C18 C19 C20 -0.7(9) . . . . ?
C18 C19 C20 C21 -0.6(10) . . . . ?
C19 C20 C21 C16 1.4(9) . . . . ?
C17 C16 C21 C20 -0.9(8) . . . . ?
N3 C16 C21 C20 177.9(5) . . . . ?
C13 N3 C22 C23 108.6(6) . . . . ?
C16 N3 C22 C23 -58.2(7) . . . . ?
C13 N3 C22 C26 -69.3(6) . . . . ?
C16 N3 C22 C26 123.9(5) . . . . ?
C26 C22 C23 C24 -0.3(9) . . . . ?
N3 C22 C23 C24 -178.2(6) . . . . ?
C22 C23 C24 C25 1.4(11) . . . . ?
C23 C24 C25 C27 -1.5(11) . . . . ?
C23 C22 C26 C27 -0.6(8) . . . . ?
N3 C22 C26 C27 177.3(5) . . . . ?
C22 C26 C27 C25 0.5(9) . . . . ?
C24 C25 C27 C26 0.6(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.971
_diffrn_reflns_theta_full        24.79
_diffrn_measured_fraction_theta_full 0.971
_refine_diff_density_max         1.332
_refine_diff_density_min         -0.551
_refine_diff_density_rms         0.095
