# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1951243'
loop_
_audit_author_name
_audit_author_address
ding
;Harbin Institute of Technology
China
;
_audit_update_record             
;
2019-09-03 deposited with the CCDC.	2019-10-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C37 H48 N2 O Si2'
_chemical_formula_weight         592.95

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7016(9)
_cell_length_b                   12.9670(10)
_cell_length_c                   13.0146(10)
_cell_angle_alpha                79.414(2)
_cell_angle_beta                 72.908(2)
_cell_angle_gamma                87.393(3)
_cell_volume                     1696.8(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    8376
_cell_measurement_theta_min      2.192
_cell_measurement_theta_max      28.324

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.161
_exptl_crystal_F_000             640
_exptl_transmission_factor_min   0.729
_exptl_transmission_factor_max   0.788
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_exptl_absorpt_coefficient_mu    0.135
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            18939
_diffrn_reflns_av_unetI/netI     0.0787
_diffrn_reflns_av_R_equivalents  0.0512
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.192
_diffrn_reflns_theta_max         28.324
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 0.992
_reflns_number_total             8376
_reflns_number_gt                5474
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0724P)²+1.3390P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8376
_refine_ls_number_parameters     379
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1127
_refine_ls_R_factor_gt           0.0697
_refine_ls_wR_factor_ref         0.1893
_refine_ls_wR_factor_gt          0.1626
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.77528(7) 0.76070(6) 0.28977(6) 0.03024(19) Uani 1 1 d . . . . .
Si2 Si 1.68908(7) 1.31136(6) 0.09206(6) 0.0329(2) Uani 1 1 d . . . . .
N2 N 1.2352(2) 1.20386(18) 0.26616(18) 0.0334(5) Uani 1 1 d . . . . .
N1 N 1.0182(2) 1.05807(19) 0.33878(18) 0.0354(5) Uani 1 1 d . . . . .
C37 C 1.3643(2) 1.07878(19) 0.1654(2) 0.0267(5) Uani 1 1 d . . . . .
C36 C 1.1339(2) 1.0382(2) 0.2643(2) 0.0286(5) Uani 1 1 d . . . . .
C35 C 1.2431(2) 1.10764(19) 0.2329(2) 0.0278(5) Uani 1 1 d . . . . .
C34 C 1.3731(2) 0.98417(19) 0.1302(2) 0.0277(5) Uani 1 1 d . . . . .
H34A H 1.455542 0.962495 0.088680 0.033 Uiso 1 1 calc R U . . .
C33 C 1.1440(2) 0.9441(2) 0.2197(2) 0.0281(5) Uani 1 1 d . . . . .
C32 C 1.2636(2) 0.9190(2) 0.1540(2) 0.0297(6) Uani 1 1 d . . . . .
H32A H 1.272046 0.856424 0.124409 0.036 Uiso 1 1 calc R U . . .
O1 O 1.1469(2) 1.39592(17) 0.37269(19) 0.0540(6) Uani 1 1 d . . . . .
C31 C 1.4755(2) 1.1489(2) 0.1343(2) 0.0308(6) Uani 1 1 d . . . . .
C30 C 1.1243(3) 1.2205(2) 0.3332(2) 0.0354(6) Uani 1 1 d . . . . .
C29 C 0.9337(3) 0.8282(2) 0.2597(2) 0.0359(6) Uani 1 1 d . . . . .
C28 C 1.5674(3) 1.2082(2) 0.1084(2) 0.0344(6) Uani 1 1 d . . . . .
C27 C 1.0836(3) 1.3166(2) 0.3886(2) 0.0413(7) Uani 1 1 d . . . . .
C26 C 1.6333(3) 1.3649(2) 0.2233(2) 0.0397(7) Uani 1 1 d . . . . .
H26A H 1.695084 1.422764 0.217383 0.048 Uiso 1 1 calc R U . . .
C25 C 1.0306(3) 0.8795(2) 0.2430(2) 0.0335(6) Uani 1 1 d . . . . .
C24 C 1.0186(3) 1.1486(2) 0.3733(2) 0.0359(6) Uani 1 1 d . . . . .
C23 C 1.6776(3) 1.4157(2) -0.0258(2) 0.0366(6) Uani 1 1 d . . . . .
H23A H 1.583857 1.437039 -0.009995 0.044 Uiso 1 1 calc R U . . .
C22 C 0.7432(3) 0.7629(2) 0.1543(2) 0.0371(6) Uani 1 1 d . . . . .
H22A H 0.802520 0.709385 0.119036 0.045 Uiso 1 1 calc R U . . .
C21 C 0.6519(3) 0.8322(2) 0.3869(2) 0.0359(6) Uani 1 1 d . . . . .
H21A H 0.567489 0.792377 0.409593 0.043 Uiso 1 1 calc R U . . .
C20 C 1.8587(3) 1.2538(2) 0.0650(3) 0.0444(7) Uani 1 1 d . . . . .
H20A H 1.893299 1.257491 -0.015785 0.053 Uiso 1 1 calc R U . . .
C19 C 0.7937(3) 0.6220(2) 0.3582(2) 0.0375(6) Uani 1 1 d . . . . .
H19A H 0.833262 0.627020 0.417787 0.045 Uiso 1 1 calc R U . . .
C18 C 1.7129(3) 1.3758(2) -0.1342(2) 0.0425(7) Uani 1 1 d . . . . .
H18A H 1.661602 1.312384 -0.125524 0.064 Uiso 1 1 calc R U . . .
H18B H 1.693366 1.430021 -0.190444 0.064 Uiso 1 1 calc R U . . .
H18C H 1.806251 1.359446 -0.156229 0.064 Uiso 1 1 calc R U . . .
C17 C 0.9125(3) 1.1906(3) 0.4561(2) 0.0413(7) Uani 1 1 d . . . . .
C16 C 0.9530(3) 1.2883(3) 0.4643(2) 0.0428(7) Uani 1 1 d . . . . .
C15 C 0.7775(3) 0.8666(3) 0.0746(2) 0.0505(8) Uani 1 1 d . . . . .
H15A H 0.866569 0.887931 0.068143 0.076 Uiso 1 1 calc R U . . .
H15B H 0.771974 0.857999 0.002820 0.076 Uiso 1 1 calc R U . . .
H15C H 0.715932 0.920613 0.101705 0.076 Uiso 1 1 calc R U . . .
C14 C 1.4968(3) 1.4123(3) 0.2387(3) 0.0466(7) Uani 1 1 d . . . . .
H14A H 1.496334 1.464434 0.173959 0.070 Uiso 1 1 calc R U . . .
H14B H 1.433021 1.356626 0.248879 0.070 Uiso 1 1 calc R U . . .
H14C H 1.473585 1.446106 0.303162 0.070 Uiso 1 1 calc R U . . .
C13 C 0.7142(3) 1.2057(3) 0.5935(2) 0.0547(9) Uani 1 1 d . . . . .
H13A H 0.631681 1.178335 0.639204 0.066 Uiso 1 1 calc R U . . .
C12 C 0.6628(3) 0.5631(2) 0.4133(3) 0.0519(8) Uani 1 1 d . . . . .
H12A H 0.603640 0.605039 0.462217 0.078 Uiso 1 1 calc R U . . .
H12B H 0.623336 0.551327 0.357295 0.078 Uiso 1 1 calc R U . . .
H12C H 0.677934 0.495449 0.455527 0.078 Uiso 1 1 calc R U . . .
C11 C 0.6039(3) 0.7290(3) 0.1648(3) 0.0509(8) Uani 1 1 d . . . . .
H11A H 0.582384 0.662359 0.216063 0.076 Uiso 1 1 calc R U . . .
H11B H 0.542125 0.782802 0.192053 0.076 Uiso 1 1 calc R U . . .
H11C H 0.598166 0.720188 0.093168 0.076 Uiso 1 1 calc R U . . .
C10 C 0.6256(4) 0.9446(3) 0.3379(3) 0.0551(9) Uani 1 1 d . . . . .
H10A H 0.599219 0.944423 0.271915 0.083 Uiso 1 1 calc R U . . .
H10B H 0.555546 0.974333 0.391300 0.083 Uiso 1 1 calc R U . . .
H10C H 0.705291 0.987075 0.319023 0.083 Uiso 1 1 calc R U . . .
C9 C 0.7938(3) 1.1456(3) 0.5189(2) 0.0485(8) Uani 1 1 d . . . . .
H9A H 0.767276 1.078728 0.512519 0.058 Uiso 1 1 calc R U . . .
C8 C 0.8888(3) 0.5597(3) 0.2813(3) 0.0549(9) Uani 1 1 d . . . . .
H8A H 0.971115 0.599009 0.247414 0.082 Uiso 1 1 calc R U . . .
H8B H 0.905591 0.491972 0.322543 0.082 Uiso 1 1 calc R U . . .
H8C H 0.850993 0.547850 0.224311 0.082 Uiso 1 1 calc R U . . .
C7 C 0.8707(3) 1.3475(3) 0.5392(3) 0.0546(9) Uani 1 1 d . . . . .
H7A H 0.895995 1.414640 0.545861 0.065 Uiso 1 1 calc R U . . .
C6 C 0.6934(3) 0.8319(3) 0.4904(2) 0.0463(8) Uani 1 1 d . . . . .
H6A H 0.710186 0.759760 0.521535 0.069 Uiso 1 1 calc R U . . .
H6B H 0.773147 0.874306 0.471688 0.069 Uiso 1 1 calc R U . . .
H6C H 0.623402 0.861564 0.543966 0.069 Uiso 1 1 calc R U . . .
C5 C 1.9524(3) 1.3182(3) 0.0972(3) 0.0599(10) Uani 1 1 d . . . . .
H5A H 1.949367 1.391947 0.063522 0.090 Uiso 1 1 calc R U . . .
H5B H 1.926380 1.311963 0.176900 0.090 Uiso 1 1 calc R U . . .
H5C H 2.041458 1.291913 0.072000 0.090 Uiso 1 1 calc R U . . .
C4 C 1.8617(4) 1.1399(3) 0.1160(4) 0.0681(11) Uani 1 1 d . . . . .
H4A H 1.801211 1.099600 0.094690 0.102 Uiso 1 1 calc R U . . .
H4B H 1.950507 1.113066 0.090866 0.102 Uiso 1 1 calc R U . . .
H4C H 1.835428 1.133116 0.195765 0.102 Uiso 1 1 calc R U . . .
C3 C 0.7533(4) 1.3024(3) 0.6012(3) 0.0549(9) Uani 1 1 d . . . . .
H3A H 0.696092 1.339935 0.652012 0.066 Uiso 1 1 calc R U . . .
C2 C 1.7568(4) 1.5147(3) -0.0379(3) 0.0624(10) Uani 1 1 d . . . . .
H2B H 1.733410 1.539539 0.031970 0.094 Uiso 1 1 calc R U . . .
H2C H 1.850282 1.498736 -0.059652 0.094 Uiso 1 1 calc R U . . .
H2D H 1.737397 1.569311 -0.093867 0.094 Uiso 1 1 calc R U . . .
C1 C 1.6362(4) 1.2830(3) 0.3238(3) 0.0626(10) Uani 1 1 d . . . . .
H1B H 1.724062 1.253302 0.312880 0.094 Uiso 1 1 calc R U . . .
H1C H 1.613508 1.316355 0.388551 0.094 Uiso 1 1 calc R U . . .
H1D H 1.572943 1.226875 0.334268 0.094 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C29 1.848(3) . ?
Si1 C21 1.881(3) . ?
Si1 C19 1.884(3) . ?
Si1 C22 1.888(3) . ?
Si2 C28 1.850(3) . ?
Si2 C23 1.879(3) . ?
Si2 C26 1.885(3) . ?
Si2 C20 1.891(3) . ?
N2 C30 1.286(3) . ?
N2 C35 1.385(3) . ?
N1 C24 1.332(4) . ?
N1 C36 1.378(3) . ?
C37 C34 1.376(3) . ?
C37 C35 1.415(4) . ?
C37 C31 1.444(3) . ?
C36 C35 1.423(3) . ?
C36 C33 1.431(4) . ?
C34 C32 1.401(3) . ?
C34 H34A 0.9500 . ?
C33 C32 1.377(4) . ?
C33 C25 1.432(3) . ?
C32 H32A 0.9500 . ?
O1 C27 1.209(4) . ?
C31 C28 1.204(3) . ?
C30 C24 1.411(4) . ?
C30 C27 1.537(4) . ?
C29 C25 1.200(3) . ?
C27 C16 1.471(4) . ?
C26 C14 1.532(4) . ?
C26 C1 1.533(4) . ?
C26 H26A 1.0000 . ?
C24 C17 1.479(4) . ?
C23 C2 1.529(4) . ?
C23 C18 1.529(4) . ?
C23 H23A 1.0000 . ?
C22 C15 1.526(4) . ?
C22 C11 1.533(4) . ?
C22 H22A 1.0000 . ?
C21 C10 1.528(4) . ?
C21 C6 1.537(4) . ?
C21 H21A 1.0000 . ?
C20 C4 1.506(4) . ?
C20 C5 1.526(4) . ?
C20 H20A 1.0000 . ?
C19 C8 1.521(4) . ?
C19 C12 1.538(4) . ?
C19 H19A 1.0000 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C17 C9 1.380(4) . ?
C17 C16 1.389(4) . ?
C16 C7 1.422(4) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C13 C3 1.369(5) . ?
C13 C9 1.417(5) . ?
C13 H13A 0.9500 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C9 H9A 0.9500 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C7 C3 1.367(5) . ?
C7 H7A 0.9500 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C3 H3A 0.9500 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C2 H2D 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C1 H1D 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C29 Si1 C21 106.45(13) . . ?
C29 Si1 C19 107.16(13) . . ?
C21 Si1 C19 110.23(12) . . ?
C29 Si1 C22 106.70(12) . . ?
C21 Si1 C22 115.03(13) . . ?
C19 Si1 C22 110.83(13) . . ?
C28 Si2 C23 107.38(13) . . ?
C28 Si2 C26 104.57(12) . . ?
C23 Si2 C26 110.03(13) . . ?
C28 Si2 C20 110.08(13) . . ?
C23 Si2 C20 110.78(14) . . ?
C26 Si2 C20 113.65(14) . . ?
C30 N2 C35 114.0(2) . . ?
C24 N1 C36 113.6(2) . . ?
C34 C37 C35 118.9(2) . . ?
C34 C37 C31 121.4(2) . . ?
C35 C37 C31 119.7(2) . . ?
N1 C36 C35 121.5(2) . . ?
N1 C36 C33 118.6(2) . . ?
C35 C36 C33 119.8(2) . . ?
N2 C35 C37 118.2(2) . . ?
N2 C35 C36 122.1(2) . . ?
C37 C35 C36 119.7(2) . . ?
C37 C34 C32 121.7(2) . . ?
C37 C34 H34A 119.1 . . ?
C32 C34 H34A 119.1 . . ?
C32 C33 C36 118.5(2) . . ?
C32 C33 C25 121.7(2) . . ?
C36 C33 C25 119.7(2) . . ?
C33 C32 C34 121.1(2) . . ?
C33 C32 H32A 119.5 . . ?
C34 C32 H32A 119.5 . . ?
C28 C31 C37 179.3(3) . . ?
N2 C30 C24 124.8(3) . . ?
N2 C30 C27 127.7(3) . . ?
C24 C30 C27 107.4(2) . . ?
C25 C29 Si1 174.4(3) . . ?
C31 C28 Si2 168.5(3) . . ?
O1 C27 C16 129.2(3) . . ?
O1 C27 C30 126.9(3) . . ?
C16 C27 C30 103.9(2) . . ?
C14 C26 C1 110.3(3) . . ?
C14 C26 Si2 110.8(2) . . ?
C1 C26 Si2 113.0(2) . . ?
C14 C26 H26A 107.5 . . ?
C1 C26 H26A 107.5 . . ?
Si2 C26 H26A 107.5 . . ?
C29 C25 C33 177.3(3) . . ?
N1 C24 C30 123.5(2) . . ?
N1 C24 C17 127.1(3) . . ?
C30 C24 C17 109.4(3) . . ?
C2 C23 C18 110.2(2) . . ?
C2 C23 Si2 113.4(2) . . ?
C18 C23 Si2 113.0(2) . . ?
C2 C23 H23A 106.6 . . ?
C18 C23 H23A 106.6 . . ?
Si2 C23 H23A 106.6 . . ?
C15 C22 C11 109.8(2) . . ?
C15 C22 Si1 114.5(2) . . ?
C11 C22 Si1 113.7(2) . . ?
C15 C22 H22A 106.1 . . ?
C11 C22 H22A 106.1 . . ?
Si1 C22 H22A 106.1 . . ?
C10 C21 C6 109.7(3) . . ?
C10 C21 Si1 114.5(2) . . ?
C6 C21 Si1 110.3(2) . . ?
C10 C21 H21A 107.3 . . ?
C6 C21 H21A 107.3 . . ?
Si1 C21 H21A 107.3 . . ?
C4 C20 C5 110.4(3) . . ?
C4 C20 Si2 114.0(2) . . ?
C5 C20 Si2 112.2(2) . . ?
C4 C20 H20A 106.6 . . ?
C5 C20 H20A 106.6 . . ?
Si2 C20 H20A 106.6 . . ?
C8 C19 C12 111.3(3) . . ?
C8 C19 Si1 112.1(2) . . ?
C12 C19 Si1 113.5(2) . . ?
C8 C19 H19A 106.4 . . ?
C12 C19 H19A 106.4 . . ?
Si1 C19 H19A 106.4 . . ?
C23 C18 H18A 109.5 . . ?
C23 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C23 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C9 C17 C16 123.0(3) . . ?
C9 C17 C24 129.3(3) . . ?
C16 C17 C24 107.7(3) . . ?
C17 C16 C7 120.3(3) . . ?
C17 C16 C27 111.5(3) . . ?
C7 C16 C27 128.2(3) . . ?
C22 C15 H15A 109.5 . . ?
C22 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C22 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C26 C14 H14A 109.5 . . ?
C26 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C26 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C3 C13 C9 121.6(3) . . ?
C3 C13 H13A 119.2 . . ?
C9 C13 H13A 119.2 . . ?
C19 C12 H12A 109.5 . . ?
C19 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C19 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C22 C11 H11A 109.5 . . ?
C22 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C22 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C21 C10 H10A 109.5 . . ?
C21 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C21 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C17 C9 C13 115.6(3) . . ?
C17 C9 H9A 122.2 . . ?
C13 C9 H9A 122.2 . . ?
C19 C8 H8A 109.5 . . ?
C19 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C19 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C3 C7 C16 116.4(3) . . ?
C3 C7 H7A 121.8 . . ?
C16 C7 H7A 121.8 . . ?
C21 C6 H6A 109.5 . . ?
C21 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C21 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C20 C5 H5A 109.5 . . ?
C20 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C20 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C20 C4 H4A 109.5 . . ?
C20 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C20 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C7 C3 C13 123.1(3) . . ?
C7 C3 H3A 118.4 . . ?
C13 C3 H3A 118.4 . . ?
C23 C2 H2B 109.5 . . ?
C23 C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C23 C2 H2D 109.5 . . ?
H2B C2 H2D 109.5 . . ?
H2C C2 H2D 109.5 . . ?
C26 C1 H1B 109.5 . . ?
C26 C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C26 C1 H1D 109.5 . . ?
H1B C1 H1D 109.5 . . ?
H1C C1 H1D 109.5 . . ?

_refine_diff_density_max         0.778
_refine_diff_density_min         -0.553
_refine_diff_density_rms         0.060

