# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1892249'
loop_
_audit_author_name
_audit_author_address
'D. Zhao'
;Henan Polytechnic University
China
;

_audit_update_record             
;
2019-01-21 deposited with the CCDC.	2019-10-21 downloaded from the CCDC.
;
_publcif_datablock.id            {fe972c1f-3e04-4493-a147-596e2ce37fc7}
# publcif _publ_body_element loop end

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'K5 O14 P4 Y'
_chemical_formula_weight         632.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.4195(5)
_cell_length_b                   11.4058(8)
_cell_length_c                   17.5955(12)
_cell_angle_alpha                92.0460(10)
_cell_angle_beta                 98.5820(10)
_cell_angle_gamma                92.0120(10)
_cell_volume                     1470.18(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    974
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      24.69

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.857
_exptl_crystal_F_000             1224
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    5.889
_shelx_estimated_absorpt_T_min   0.417
_shelx_estimated_absorpt_T_max   0.590
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.308
_exptl_absorpt_correction_T_max  0.823
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker Smart Apex2 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_reflns_number            18838
_diffrn_reflns_av_unetI/netI     0.0440
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.788
_diffrn_reflns_theta_max         28.303
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             7248
_reflns_number_gt                5762
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART Apex2 (Bruker, 2016)'
_computing_cell_refinement       'SAINT (Bruker, 2016)'
_computing_data_reduction        'SAINT (Bruker, 2016)'
_computing_structure_solution    'SHELXS (Sheldrick, 2016)'
_computing_structure_refinement  'SHELXL-2016 (Sheldrick, 2016)'
_computing_molecular_graphics    'SHELXL (Sheldrick, 2016)'
_computing_publication_material  'SHELXTL (Sheldrick, 2016)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0306P)²+0.0182P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_extinction_coef       0.00475(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         7248
_refine_ls_number_parameters     434
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0467
_refine_ls_R_factor_gt           0.0325
_refine_ls_wR_factor_ref         0.0743
_refine_ls_wR_factor_gt          0.0689
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_restrained_S_all      1.027
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K 0.01132(11) 0.63096(7) 0.27435(4) 0.02500(18) Uani 1 1 d . . . . .
K2 K 0.40139(12) 0.39647(7) 0.22021(5) 0.0284(2) Uani 1 1 d . . . . .
K3 K -0.15400(11) 0.88382(6) 0.50840(4) 0.02022(17) Uani 1 1 d . . . . .
K4 K -0.33589(11) 0.12733(7) -0.00582(4) 0.02377(18) Uani 1 1 d . . . . .
K5 K -0.74332(10) 0.40659(7) 0.01942(4) 0.02124(17) Uani 1 1 d . . . . .
K6 K 0.45171(13) 0.85122(7) 0.24623(5) 0.0332(2) Uani 1 1 d . . . . .
K7 K 0.03046(11) 0.15365(6) 0.25445(4) 0.02362(18) Uani 1 1 d . . . . .
K8 K 0.22439(10) 0.60935(6) 0.47620(4) 0.01984(17) Uani 1 1 d . . . . .
K9 K 0.62839(9) 0.63013(6) 0.38383(4) 0.01580(15) Uani 1 1 d . . . . .
K10 K -0.13926(9) 0.38148(6) 0.13010(4) 0.01664(15) Uani 1 1 d . . . . .
Y1 Y -0.38803(4) 0.13282(2) 0.38279(2) 0.00729(8) Uani 1 1 d . . . . .
Y2 Y -0.13658(4) 0.88339(2) 0.11906(2) 0.00771(8) Uani 1 1 d . . . . .
P1 P 0.18154(11) 0.66568(7) 0.10358(5) 0.01095(17) Uani 1 1 d . . . . .
P2 P 0.34022(11) 0.32614(7) 0.39698(5) 0.01007(17) Uani 1 1 d . . . . .
P3 P -0.45755(10) 0.09365(7) 0.16778(4) 0.00897(16) Uani 1 1 d . . . . .
P4 P 0.57802(11) 0.62780(7) 0.14681(5) 0.00961(16) Uani 1 1 d . . . . .
P5 P -0.06581(10) 0.91474(7) 0.33425(4) 0.00833(16) Uani 1 1 d . . . . .
P6 P -0.05280(10) 0.37639(7) 0.36167(5) 0.00894(16) Uani 1 1 d . . . . .
P7 P 0.30910(10) 0.87845(7) 0.40921(4) 0.00721(16) Uani 1 1 d . . . . .
P8 P 0.17043(10) 0.13222(7) 0.09000(4) 0.00755(16) Uani 1 1 d . . . . .
O1 O 0.1560(3) 0.25337(18) 0.12303(13) 0.0161(5) Uani 1 1 d . . . . .
O2 O -0.0738(3) 0.49257(17) 0.40142(12) 0.0139(5) Uani 1 1 d . . . . .
O3 O 0.5563(3) 0.7301(2) 0.53285(13) 0.0206(5) Uani 1 1 d . . . . .
O4 O -0.0201(3) 0.38215(19) 0.28016(12) 0.0196(5) Uani 1 1 d . . . . .
O5 O -0.2750(3) 0.71078(19) 0.12354(14) 0.0229(6) Uani 1 1 d . . . . .
O6 O -0.1288(3) 0.68356(18) 0.59013(12) 0.0143(5) Uani 1 1 d . . . . .
O7 O -0.4369(3) 0.51230(18) 0.10263(12) 0.0154(5) Uani 1 1 d . . . . .
O8 O 0.2500(3) 0.87637(18) 0.48840(12) 0.0130(5) Uani 1 1 d . . . . .
O9 O -0.3870(3) 0.98908(18) 0.12510(12) 0.0136(5) Uani 1 1 d . . . . .
O10 O 0.5960(4) 0.6210(2) 0.23186(13) 0.0297(6) Uani 1 1 d . . . . .
O11 O -0.4053(3) 0.20922(19) 0.13910(13) 0.0191(5) Uani 1 1 d . . . . .
O12 O 0.1478(3) 0.55999(19) 0.14756(14) 0.0240(6) Uani 1 1 d . . . . .
O13 O -0.2282(3) 0.87340(19) -0.01069(12) 0.0168(5) Uani 1 1 d . . . . .
O14 O 0.5797(3) 1.08232(19) 0.25417(12) 0.0162(5) Uani 1 1 d . . . . .
O15 O -0.1430(3) 1.01969(18) 0.37231(12) 0.0135(5) Uani 1 1 d . . . . .
O16 O 0.3607(3) 0.24206(18) 0.32930(12) 0.0149(5) Uani 1 1 d . . . . .
O17 O -0.1299(4) 0.3498(2) -0.01882(14) 0.0376(7) Uani 1 1 d . . . . .
O18 O 0.0016(3) 0.05396(18) 0.09436(12) 0.0144(5) Uani 1 1 d . . . . .
O19 O 0.1515(3) 0.94575(18) 0.35486(12) 0.0123(5) Uani 1 1 d . . . . .
O20 O -0.2018(3) 0.28569(19) 0.37393(13) 0.0174(5) Uani 1 1 d . . . . .
O21 O 0.1130(3) 0.78032(19) 0.13495(15) 0.0274(6) Uani 1 1 d . . . . .
O22 O -0.0989(3) 0.91586(19) 0.24700(12) 0.0167(5) Uani 1 1 d . . . . .
O23 O 0.3989(3) 0.7004(2) 0.11720(15) 0.0251(6) Uani 1 1 d . . . . .
O24 O 0.3880(3) 0.45203(19) 0.38678(15) 0.0245(6) Uani 1 1 d . . . . .
O25 O 0.3237(3) 0.76054(17) 0.37080(12) 0.0135(5) Uani 1 1 d . . . . .
O26 O 0.3235(3) 0.06791(18) 0.14734(12) 0.0142(5) Uani 1 1 d . . . . .
O27 O -0.1125(3) 0.80014(18) 0.36637(13) 0.0170(5) Uani 1 1 d . . . . .
O28 O 0.4726(3) 0.96226(18) 0.40641(12) 0.0141(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
K1 O12 2.694(2) . ?
K1 O27 2.745(2) . ?
K1 O4 2.846(2) . ?
K1 O2 2.914(2) . ?
K1 O25 2.974(2) . ?
K1 O10 3.057(3) 1_455 ?
K1 O21 3.201(3) . ?
K1 O5 3.318(3) . ?
K1 O22 3.412(2) . ?
K2 O16 2.693(2) . ?
K2 O1 2.751(2) . ?
K2 O7 2.879(2) 1_655 ?
K2 O10 2.881(2) . ?
K2 O12 2.890(2) . ?
K2 O24 2.993(3) . ?
K2 O11 3.044(2) 1_655 ?
K3 O27 2.708(2) . ?
K3 O6 2.739(2) . ?
K3 O3 2.818(2) 1_455 ?
K3 O8 2.851(2) 2_576 ?
K3 O15 2.908(2) . ?
K3 O15 2.959(2) 2_576 ?
K3 O19 3.036(2) 2_576 ?
K3 O8 3.073(2) . ?
K3 O28 3.241(2) 1_455 ?
K4 O11 2.810(2) . ?
K4 O23 2.826(2) 2_565 ?
K4 O9 2.901(2) 1_545 ?
K4 O17 2.950(3) . ?
K4 O9 2.952(2) 2_465 ?
K4 O18 3.002(2) . ?
K4 O13 3.033(2) 1_545 ?
K4 O21 3.190(3) 2_565 ?
K4 O13 3.290(2) 2_465 ?
K4 O26 3.295(2) 2 ?
K5 O7 2.730(2) . ?
K5 O1 2.734(2) 1_455 ?
K5 O5 2.831(2) 2_465 ?
K5 O7 2.858(2) 2_465 ?
K5 O17 2.891(3) 1_455 ?
K5 O17 2.965(3) 2_465 ?
K5 O12 3.026(2) 1_455 ?
K5 O13 3.190(2) 2_465 ?
K6 O25 2.737(2) . ?
K6 O14 2.762(2) . ?
K6 O23 2.771(3) . ?
K6 O10 2.888(3) . ?
K6 O21 3.013(3) . ?
K6 O28 3.029(2) . ?
K6 O9 3.052(2) 1_655 ?
K6 O26 3.165(2) 1_565 ?
K6 O19 3.327(2) . ?
K7 O4 2.678(2) . ?
K7 O16 2.743(2) . ?
K7 O22 2.837(2) 1_545 ?
K7 O1 2.875(2) . ?
K7 O18 2.975(2) . ?
K7 O15 3.029(2) 1_545 ?
K7 O19 3.086(2) 1_545 ?
K7 O6 3.226(2) 2_566 ?
K7 O26 3.237(2) . ?
K8 O2 2.683(2) . ?
K8 O25 2.739(2) . ?
K8 O24 2.773(2) . ?
K8 O3 2.808(2) . ?
K8 O2 2.836(2) 2_566 ?
K8 O20 2.887(2) 2_566 ?
K8 O8 3.043(2) . ?
K9 O10 2.647(2) . ?
K9 O24 2.663(2) . ?
K9 O25 2.735(2) . ?
K9 O27 2.740(2) 1_655 ?
K9 O2 2.741(2) 1_655 ?
K9 O3 2.951(2) . ?
K10 O17 2.644(3) . ?
K10 O4 2.656(2) . ?
K10 O1 2.691(2) . ?
K10 O7 2.702(2) . ?
K10 O11 2.761(2) . ?
K10 O12 2.869(2) . ?
Y1 O20 2.211(2) . ?
Y1 O28 2.252(2) 1_445 ?
Y1 O14 2.291(2) 1_445 ?
Y1 O15 2.292(2) 1_545 ?
Y1 O8 2.351(2) 2_566 ?
Y1 O16 2.374(2) 1_455 ?
Y1 O3 2.595(2) 2_566 ?
Y2 O5 2.198(2) . ?
Y2 O21 2.216(2) . ?
Y2 O22 2.242(2) . ?
Y2 O18 2.254(2) 1_565 ?
Y2 O9 2.263(2) . ?
Y2 O13 2.280(2) . ?
P1 O17 1.486(3) 2_565 ?
P1 O12 1.489(2) . ?
P1 O21 1.534(2) . ?
P1 O23 1.627(2) . ?
P2 O24 1.490(2) . ?
P2 O3 1.528(2) 2_666 ?
P2 O16 1.531(2) . ?
P2 O6 1.619(2) 2_566 ?
P3 O11 1.487(2) . ?
P3 O14 1.515(2) 1_445 ?
P3 O9 1.536(2) 1_545 ?
P3 O26 1.624(2) 1_455 ?
P4 O10 1.488(2) . ?
P4 O7 1.498(2) 1_655 ?
P4 O5 1.530(2) 1_655 ?
P4 O23 1.620(2) . ?
P5 O27 1.492(2) . ?
P5 O22 1.519(2) . ?
P5 O15 1.522(2) . ?
P5 O19 1.622(2) . ?
P6 O4 1.493(2) . ?
P6 O2 1.500(2) . ?
P6 O20 1.532(2) . ?
P6 O6 1.664(2) 2_566 ?
P7 O25 1.498(2) . ?
P7 O8 1.523(2) . ?
P7 O28 1.526(2) . ?
P7 O19 1.629(2) . ?
P8 O1 1.493(2) . ?
P8 O13 1.520(2) 2_565 ?
P8 O18 1.525(2) . ?
P8 O26 1.617(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O17 P1 O12 114.96(15) 2_565 . ?
O17 P1 O21 111.98(15) 2_565 . ?
O12 P1 O21 114.98(14) . . ?
O17 P1 O23 105.22(15) 2_565 . ?
O12 P1 O23 109.32(13) . . ?
O21 P1 O23 98.56(13) . . ?
O24 P2 O3 116.44(14) . 2_666 ?
O24 P2 O16 115.51(13) . . ?
O3 P2 O16 104.50(13) 2_666 . ?
O24 P2 O6 107.90(12) . 2_566 ?
O3 P2 O6 104.34(12) 2_666 2_566 ?
O16 P2 O6 107.28(12) . 2_566 ?
O11 P3 O14 115.84(13) . 1_445 ?
O11 P3 O9 113.24(13) . 1_545 ?
O14 P3 O9 111.57(12) 1_445 1_545 ?
O11 P3 O26 110.51(12) . 1_455 ?
O14 P3 O26 103.26(12) 1_445 1_455 ?
O9 P3 O26 100.86(12) 1_545 1_455 ?
O10 P4 O7 115.56(13) . 1_655 ?
O10 P4 O5 111.36(14) . 1_655 ?
O7 P4 O5 112.28(13) 1_655 1_655 ?
O10 P4 O23 108.57(15) . . ?
O7 P4 O23 108.28(13) 1_655 . ?
O5 P4 O23 99.45(13) 1_655 . ?
O27 P5 O22 114.54(13) . . ?
O27 P5 O15 113.61(13) . . ?
O22 P5 O15 113.01(12) . . ?
O27 P5 O19 110.43(12) . . ?
O22 P5 O19 102.74(12) . . ?
O15 P5 O19 101.02(12) . . ?
O4 P6 O2 115.31(13) . . ?
O4 P6 O20 114.05(13) . . ?
O2 P6 O20 112.14(13) . . ?
O4 P6 O6 106.63(12) . 2_566 ?
O2 P6 O6 107.09(12) . 2_566 ?
O20 P6 O6 100.03(12) . 2_566 ?
O25 P7 O8 115.40(12) . . ?
O25 P7 O28 113.81(12) . . ?
O8 P7 O28 113.09(12) . . ?
O25 P7 O19 106.69(12) . . ?
O8 P7 O19 106.04(12) . . ?
O28 P7 O19 100.03(11) . . ?
O1 P8 O13 114.91(13) . 2_565 ?
O1 P8 O18 112.52(12) . . ?
O13 P8 O18 112.47(12) 2_565 . ?
O1 P8 O26 107.44(12) . . ?
O13 P8 O26 107.11(12) 2_565 . ?
O18 P8 O26 101.16(12) . . ?

_refine_diff_density_max         0.978
_refine_diff_density_min         -0.595
_refine_diff_density_rms         0.117


loop_
_publcif_info_exptl_table_extra_item
sin_theta_over_lambda_max

loop_
_publcif_info_exptl_table_header_item
?



_publcif_funding_html            
;
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Tb
_database_code_depnum_ccdc_archive 'CCDC 1959077'
loop_
_audit_author_name
_audit_author_address
'Dan Zhao'
;Henan polytenchnic University
China
;

_audit_update_record             
;
2019-10-13 deposited with the CCDC.	2019-10-21 downloaded from the CCDC.
;
_publcif_datablock.id            {738ef42a-445a-4b42-adff-194e71af7413}
# publcif _publ_body_element loop end

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'K5 O14 P4 Tb'
_chemical_formula_weight         702.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.3833(10)
_cell_length_b                   9.0651(12)
_cell_length_c                   11.4076(16)
_cell_angle_alpha                86.938(2)
_cell_angle_beta                 88.610(2)
_cell_angle_gamma                74.176(2)
_cell_volume                     733.49(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    394
_cell_measurement_theta_min      3.64
_cell_measurement_theta_max      24.90

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.180
_exptl_crystal_F_000             664
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.130
_exptl_absorpt_coefficient_mu    6.747
_shelx_estimated_absorpt_T_min   0.393
_shelx_estimated_absorpt_T_max   0.474
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.305
_exptl_absorpt_correction_T_max  0.582
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker Smart Apex2 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_reflns_number            9353
_diffrn_reflns_av_unetI/netI     0.0729
_diffrn_reflns_av_R_equivalents  0.0532
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.788
_diffrn_reflns_theta_max         28.291
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             3608
_reflns_number_gt                2876
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART Apex2 (Bruker, 2017)'
_computing_cell_refinement       'SAINT (Bruker, 2017)'
_computing_data_reduction        'SAINT (Bruker, 2017)'
_computing_structure_solution    'SHELXS (Sheldrick, 2017)'
_computing_structure_refinement  'SHELXL-2016 (Sheldrick, 2017)'
_computing_molecular_graphics    'SHELXL (Sheldrick, 2017'
_computing_publication_material  'SHELXTL (Sheldrick, 2017)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0276P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_extinction_coef       0.0030(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         3608
_refine_ls_number_parameters     218
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0540
_refine_ls_R_factor_gt           0.0397
_refine_ls_wR_factor_ref         0.0806
_refine_ls_wR_factor_gt          0.0735
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_restrained_S_all      1.010
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K 0.2513(2) 0.04367(16) 0.10704(13) 0.0233(3) Uani 1 1 d . . . . .
K2 K 0.2074(3) 0.43855(19) 0.11776(15) 0.0419(5) Uani 1 1 d . . . . .
K3 K 0.74535(19) 0.24544(17) 0.12685(13) 0.0191(3) Uani 1 1 d . . . . .
K4 K 0.2218(2) 0.49369(16) 0.64871(13) 0.0235(3) Uani 1 1 d . . . . .
K5 K 0.3385(2) 0.01301(16) 0.61874(13) 0.0212(3) Uani 1 1 d . . . . .
Tb1 Tb 0.76682(4) 0.23314(3) 0.63000(3) 0.00926(10) Uani 1 1 d . . . . .
P1 P 0.0958(2) 0.18172(17) 0.37505(14) 0.0086(3) Uani 1 1 d . . . . .
P2 P 0.3919(2) 0.33562(18) 0.40901(14) 0.0103(3) Uani 1 1 d . . . . .
P3 P 0.0571(2) 0.21211(19) 0.82628(14) 0.0130(3) Uani 1 1 d . . . . .
P4 P 0.4149(2) 0.28157(18) 0.87624(14) 0.0112(3) Uani 1 1 d . . . . .
O1 O 0.0366(6) 0.2514(5) 0.2552(4) 0.0141(9) Uani 1 1 d . . . . .
O2 O -0.0689(6) 0.1842(5) 0.4584(4) 0.0171(10) Uani 1 1 d . . . . .
O3 O 0.2418(6) 0.0259(5) 0.3757(4) 0.0139(9) Uani 1 1 d . . . . .
O4 O 0.1908(6) 0.2982(5) 0.4373(4) 0.0156(10) Uani 1 1 d . . . . .
O5 O 0.4679(6) 0.2766(5) 0.2927(4) 0.0188(10) Uani 1 1 d . . . . .
O6 O 0.3434(6) 0.5084(4) 0.4163(4) 0.0169(10) Uani 1 1 d . . . . .
O7 O 0.5082(6) 0.2506(5) 0.5138(4) 0.0145(9) Uani 1 1 d . . . . .
O8 O 0.0264(6) 0.0681(5) 0.7764(4) 0.0266(12) Uani 1 1 d . . . . .
O9 O 0.0002(6) 0.2408(6) 0.9509(4) 0.0272(12) Uani 1 1 d . . . . .
O10 O -0.0338(6) 0.3430(5) 0.7383(4) 0.0172(10) Uani 1 1 d . . . . .
O11 O 0.2822(6) 0.1882(5) 0.8142(4) 0.0190(10) Uani 1 1 d . . . . .
O12 O 0.4714(6) 0.2020(5) 0.9933(4) 0.0153(10) Uani 1 1 d . . . . .
O13 O 0.3040(7) 0.4460(5) 0.8803(4) 0.0232(11) Uani 1 1 d . . . . .
O14 O 0.5787(6) 0.2540(5) 0.7884(4) 0.0206(10) Uani 1 1 d . . . . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes) are
estimated using the full covariance matrix. The cell esds are taken into
account individually in the estimation of esds in distances, angles and
torsion angles; correlations between esds in cell parameters are only used
when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
K1 O12 2.712(4) 1_554 ?
K1 O1 2.738(4) . ?
K1 O9 2.795(5) 1_554 ?
K1 O8 2.803(5) 2_556 ?
K1 O12 2.852(4) 2_656 ?
K1 O14 2.857(5) 2_656 ?
K1 O3 3.061(4) . ?
K2 O10 2.669(5) 2_566 ?
K2 O1 2.777(4) . ?
K2 O13 2.787(5) 1_554 ?
K2 O5 2.859(5) . ?
K2 O12 2.886(4) 1_554 ?
K2 O9 2.966(5) 2_566 ?
K2 O9 3.343(5) 1_554 ?
K3 O1 2.645(4) 1_655 ?
K3 O12 2.686(4) 1_554 ?
K3 O9 2.711(5) 1_654 ?
K3 O13 2.717(4) 2_666 ?
K3 O5 2.722(4) . ?
K3 O8 3.047(5) 2_656 ?
K4 O13 2.710(5) . ?
K4 O10 2.764(4) . ?
K4 O6 2.786(5) . ?
K4 O1 2.819(4) 2_566 ?
K4 O2 3.030(4) 2_566 ?
K4 O7 3.059(4) . ?
K4 O4 3.117(4) . ?
K4 O11 3.200(5) . ?
K4 O4 3.258(4) 2_566 ?
K5 O11 2.763(4) . ?
K5 O5 2.774(4) 2_656 ?
K5 O8 2.839(5) . ?
K5 O7 2.847(4) 2_656 ?
K5 O3 2.868(4) . ?
K5 O7 2.961(4) . ?
K5 O3 3.024(4) 2_656 ?
K5 O2 3.182(4) 2_556 ?
K5 O4 3.187(4) . ?
Tb1 O14 2.237(4) . ?
Tb1 O2 2.276(4) 1_655 ?
Tb1 O6 2.298(4) 2_666 ?
Tb1 O7 2.316(4) . ?
Tb1 O3 2.371(4) 2_656 ?
Tb1 O10 2.388(4) 1_655 ?
Tb1 O8 2.650(5) 1_655 ?
P1 O1 1.499(4) . ?
P1 O2 1.522(4) . ?
P1 O3 1.525(4) . ?
P1 O4 1.618(4) . ?
P2 O5 1.496(4) . ?
P2 O6 1.515(4) . ?
P2 O7 1.533(4) . ?
P2 O4 1.632(4) . ?
P3 O9 1.489(5) . ?
P3 O8 1.525(5) . ?
P3 O10 1.528(4) . ?
P3 O11 1.620(4) . ?
P4 O13 1.495(4) . ?
P4 O12 1.496(4) . ?
P4 O14 1.527(4) . ?
P4 O11 1.652(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 O2 113.4(2) . . ?
O1 P1 O3 114.6(2) . . ?
O2 P1 O3 113.0(2) . . ?
O1 P1 O4 106.8(2) . . ?
O2 P1 O4 100.5(2) . . ?
O3 P1 O4 107.1(2) . . ?
O5 P2 O6 115.1(2) . . ?
O5 P2 O7 113.8(3) . . ?
O6 P2 O7 112.4(2) . . ?
O5 P2 O4 110.3(2) . . ?
O6 P2 O4 102.9(2) . . ?
O7 P2 O4 100.7(2) . . ?
O9 P3 O8 117.0(3) . . ?
O9 P3 O10 114.9(3) . . ?
O8 P3 O10 105.2(3) . . ?
O9 P3 O11 108.6(3) . . ?
O8 P3 O11 104.0(3) . . ?
O10 P3 O11 106.2(2) . . ?
O13 P4 O12 115.1(3) . . ?
O13 P4 O14 113.8(3) . . ?
O12 P4 O14 112.4(3) . . ?
O13 P4 O11 107.6(3) . . ?
O12 P4 O11 106.9(2) . . ?
O14 P4 O11 99.5(2) . . ?

_refine_diff_density_max         1.008
_refine_diff_density_min         -1.205
_refine_diff_density_rms         0.251


loop_
_publcif_info_exptl_table_extra_item
sin_theta_over_lambda_max

loop_
_publcif_info_exptl_table_header_item
?



_publcif_funding_html            
;
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Eu
_database_code_depnum_ccdc_archive 'CCDC 1959076'
loop_
_audit_author_name
_audit_author_address
'Dan Zhao'
;Henan polytenchnic University
China
;
# Add footnote if necessary


_audit_update_record             
;
2019-10-13 deposited with the CCDC.	2019-10-21 downloaded from the CCDC.
;
_publcif_datablock.id            {c1d77402-e981-4149-977f-4cd2ad49c1bc}
# publcif _publ_body_element loop end

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Eu K5 O14 P4'
_chemical_formula_weight         695.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.3867(12)
_cell_length_b                   9.1049(15)
_cell_length_c                   11.4427(19)
_cell_angle_alpha                86.823(2)
_cell_angle_beta                 88.518(2)
_cell_angle_gamma                74.095(2)
_cell_volume                     738.9(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    409
_cell_measurement_theta_min      3.18
_cell_measurement_theta_max      24.45

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.125
_exptl_crystal_F_000             660
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.140
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    6.156
_shelx_estimated_absorpt_T_min   0.479
_shelx_estimated_absorpt_T_max   0.709
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.462
_exptl_absorpt_correction_T_max  0.750
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker Smart Apex2 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 83.33
_diffrn_reflns_number            9439
_diffrn_reflns_av_unetI/netI     0.0829
_diffrn_reflns_av_R_equivalents  0.0608
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.783
_diffrn_reflns_theta_max         28.283
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             3635
_reflns_number_gt                2822
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART Apex2 (Bruker, 2017)'
_computing_cell_refinement       'SAINT (Bruker, 2017)'
_computing_data_reduction        'SAINT (Bruker, 2017)'
_computing_structure_solution    'SHELXS (Sheldrick, 2017)'
_computing_structure_refinement  'SHELXL-2016 (Sheldrick, 2017)'
_computing_molecular_graphics    'SHELXL (Sheldrick, 2017'
_computing_publication_material  'SHELXTL (Sheldrick, 2017)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0452P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_extinction_coef       0.0066(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         3635
_refine_ls_number_parameters     218
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0635
_refine_ls_R_factor_gt           0.0461
_refine_ls_wR_factor_ref         0.1064
_refine_ls_wR_factor_gt          0.0969
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_restrained_S_all      0.994
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K 0.2956(3) 0.5623(2) 0.38238(17) 0.0425(6) Uani 1 1 d . . . . .
K2 K 0.2444(2) 0.24697(19) 0.62682(14) 0.0198(4) Uani 1 1 d . . . . .
K3 K 0.7507(3) 0.04211(19) 0.60584(15) 0.0244(4) Uani 1 1 d . . . . .
K4 K 0.8398(2) 0.01166(19) 0.11869(15) 0.0223(4) Uani 1 1 d . . . . .
K5 K 0.7225(3) 0.4945(2) 0.15006(15) 0.0254(4) Uani 1 1 d . . . . .
Eu1 Eu 0.26830(5) 0.23221(4) 0.13022(3) 0.01036(13) Uani 1 1 d . . . . .
P1 P 0.4031(2) 0.8182(2) 0.12696(16) 0.0101(4) Uani 1 1 d . . . . .
P2 P 0.1100(3) 0.6630(2) 0.09006(16) 0.0115(4) Uani 1 1 d . . . . .
P3 P 0.9133(3) 0.2811(2) 0.37781(16) 0.0118(4) Uani 1 1 d . . . . .
P4 P 0.5569(3) 0.2116(2) 0.32644(16) 0.0129(4) Uani 1 1 d . . . . .
O1 O -0.0039(7) 0.7494(5) -0.0146(4) 0.0158(11) Uani 1 1 d . . . . .
O2 O 0.0332(7) 0.7198(6) 0.2048(4) 0.0209(12) Uani 1 1 d . . . . .
O3 O 0.1583(7) 0.4910(5) 0.0806(4) 0.0193(12) Uani 1 1 d . . . . .
O4 O 0.3130(7) 0.6997(5) 0.0647(4) 0.0151(11) Uani 1 1 d . . . . .
O5 O 0.2555(7) 0.9723(5) 0.1256(4) 0.0132(10) Uani 1 1 d . . . . .
O6 O 0.5688(7) 0.8171(6) 0.0443(4) 0.0180(11) Uani 1 1 d . . . . .
O7 O 0.4615(7) 0.7495(5) 0.2461(4) 0.0149(11) Uani 1 1 d . . . . .
O8 O 0.5256(7) 0.0699(6) 0.2753(5) 0.0234(13) Uani 1 1 d . . . . .
O9 O 0.4677(7) 0.3446(6) 0.2391(4) 0.0168(11) Uani 1 1 d . . . . .
O10 O 0.4993(8) 0.2367(7) 0.4504(4) 0.0261(13) Uani 1 1 d . . . . .
O11 O 0.7823(7) 0.1854(6) 0.3164(4) 0.0193(12) Uani 1 1 d . . . . .
O12 O 0.8009(8) 0.4451(6) 0.3810(5) 0.0225(12) Uani 1 1 d . . . . .
O13 O 1.0764(7) 0.2545(6) 0.2905(4) 0.0219(12) Uani 1 1 d . . . . .
O14 O 0.9706(7) 0.2023(6) 0.4944(4) 0.0181(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
K1 O9 2.666(5) . ?
K1 O7 2.755(5) . ?
K1 O12 2.784(6) 2_666 ?
K1 O2 2.881(6) . ?
K1 O14 2.886(5) 2_666 ?
K1 O10 3.003(6) . ?
K1 O10 3.371(6) 2_666 ?
K2 O7 2.653(5) 2_666 ?
K2 O14 2.689(5) 1_455 ?
K2 O10 2.712(6) . ?
K2 O12 2.727(5) 2_666 ?
K2 O2 2.744(5) 2_566 ?
K2 O8 3.085(6) 2_656 ?
K3 O14 2.716(5) . ?
K3 O7 2.742(5) 2_666 ?
K3 O10 2.787(5) . ?
K3 O8 2.810(6) 2_656 ?
K3 O14 2.856(5) 2_756 ?
K3 O13 2.857(6) 2_756 ?
K3 O5 3.068(5) 2_666 ?
K4 O2 2.788(5) 1_645 ?
K4 O11 2.789(5) . ?
K4 O8 2.845(6) . ?
K4 O1 2.857(5) 1_645 ?
K4 O5 2.887(5) 2_665 ?
K4 O1 2.950(5) 2_665 ?
K4 O5 2.995(5) 1_645 ?
K4 O6 3.173(5) 1_545 ?
K4 O4 3.236(5) 2_665 ?
K5 O12 2.706(5) . ?
K5 O9 2.756(5) . ?
K5 O3 2.768(5) 2_665 ?
K5 O7 2.835(5) . ?
K5 O6 3.039(5) . ?
K5 O1 3.056(5) 2_665 ?
K5 O4 3.163(5) 2_665 ?
K5 O4 3.232(5) . ?
K5 O11 3.241(6) . ?
Eu1 O13 2.273(5) 1_455 ?
Eu1 O6 2.306(5) 2_665 ?
Eu1 O3 2.315(5) . ?
Eu1 O1 2.350(5) 2_565 ?
Eu1 O5 2.398(5) 1_545 ?
Eu1 O9 2.414(5) . ?
Eu1 O8 2.628(5) . ?
P1 O7 1.491(5) . ?
P1 O5 1.522(5) . ?
P1 O6 1.526(5) . ?
P1 O4 1.618(5) . ?
P2 O2 1.480(5) . ?
P2 O3 1.517(5) . ?
P2 O1 1.531(5) . ?
P2 O4 1.639(5) . ?
P3 O14 1.493(5) . ?
P3 O12 1.499(5) . ?
P3 O13 1.520(5) . ?
P3 O11 1.660(5) . ?
P4 O10 1.482(5) . ?
P4 O8 1.522(5) . ?
P4 O9 1.537(5) . ?
P4 O11 1.618(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 P1 O5 114.7(3) . . ?
O7 P1 O6 113.3(3) . . ?
O5 P1 O6 113.0(3) . . ?
O7 P1 O4 106.5(3) . . ?
O5 P1 O4 107.6(3) . . ?
O6 P1 O4 100.3(3) . . ?
O2 P2 O3 115.5(3) . . ?
O2 P2 O1 113.9(3) . . ?
O3 P2 O1 112.1(3) . . ?
O2 P2 O4 109.9(3) . . ?
O3 P2 O4 102.8(3) . . ?
O1 P2 O4 101.0(3) . . ?
O14 P3 O12 115.3(3) . . ?
O14 P3 O13 112.3(3) . . ?
O12 P3 O13 113.6(3) . . ?
O14 P3 O11 106.6(3) . . ?
O12 P3 O11 108.0(3) . . ?
O13 P3 O11 99.5(3) . . ?
O10 P4 O8 116.3(3) . . ?
O10 P4 O9 115.3(3) . . ?
O8 P4 O9 105.4(3) . . ?
O10 P4 O11 108.3(3) . . ?
O8 P4 O11 103.9(3) . . ?
O9 P4 O11 106.6(3) . . ?

_refine_diff_density_max         1.983
_refine_diff_density_min         -1.250
_refine_diff_density_rms         0.277


loop_
_publcif_info_exptl_table_extra_item
sin_theta_over_lambda_max

loop_
_publcif_info_exptl_table_header_item
?



_publcif_funding_html            
;
;
