# Copyright The Royal Society of Chemistry, 1999
# CCDC Number: 182/1247
data_2

_audit_creation_method            SHELXL
_chemical_name_systematic
;
 ?
;
_chemical_name_common             -
_chemical_formula_moiety          'C26 H25 Cl2 N3 Pt S2.C2 H3 N'
_chemical_formula_structural      'C28 H28 Cl2 N4 Pt S2'
_chemical_formula_analytical      'C28 H28 Cl2 N4 Pt S2'
_chemical_formula_sum             'C28 H28 Cl2 N4 Pt S2'
_chemical_formula_weight          750.65
_chemical_melting_point           -
_chemical_compound_source         'Paul Kelly'

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S'  'S'   0.1246   0.1234
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt'  'Pt'  -1.7033   8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting            ?
_symmetry_space_group_name_H-M    P2(1)/n

loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x+1/2, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x-1/2, -y-1/2, z-1/2'

_cell_length_a                    13.2226(2)
_cell_length_b                    10.9412(2)
_cell_length_c                    20.9116(3)
_cell_angle_alpha                 90.00
_cell_angle_beta                  100.3020(10)
_cell_angle_gamma                 90.00
_cell_volume                      2976.53(8)
_cell_formula_units_Z             4
_cell_measurement_temperature     293(2)
_cell_measurement_reflns_used     57

_exptl_crystal_description        plate
_exptl_crystal_colour             yellow
_exptl_crystal_size_max           .2
_exptl_crystal_size_mid           .1
_exptl_crystal_size_min           .05
_exptl_crystal_density_meas       -
_exptl_crystal_density_diffrn     1.675
_exptl_crystal_density_method     -
_exptl_crystal_F_000              1472
_exptl_absorpt_coefficient_mu     5.058
_exptl_absorpt_correction_type    sadabs
_exptl_absorpt_correction_T_min   0.727975
_exptl_absorpt_correction_T_max   1.000000

_exptl_special_details
;
 -
;

_diffrn_ambient_temperature       293(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device       CCD
_diffrn_reflns_number             12830
_diffrn_reflns_av_R_equivalents   0.0392
_diffrn_reflns_av_sigmaI/netI     0.0449
_diffrn_reflns_limit_h_min        -14
_diffrn_reflns_limit_h_max        14
_diffrn_reflns_limit_k_min        -12
_diffrn_reflns_limit_k_max        12
_diffrn_reflns_limit_l_min        -13
_diffrn_reflns_limit_l_max        23
_diffrn_reflns_theta_min          1.70
_diffrn_reflns_theta_max          23.26
_reflns_number_total              4267
_reflns_number_observed           3243
_reflns_observed_criterion        >2sigma(I)

_computing_data_collection        SHELXTL
_computing_cell_refinement        SHELXTL
_computing_data_reduction         SHELXTL
_computing_structure_solution     SHELXTL
_computing_structure_refinement   SHELXTL
_computing_molecular_graphics     SHELXTL
_computing_publication_material   SHELXTL

_refine_special_details
;
 Refinement on F^2^ for ALL reflections except for 50 with very negative F^2^
 or flagged by the user for potential systematic errors.  Weighted R-factors
 wR and all goodnesses of fit S are based on F^2^, conventional R-factors R
 are based on F, with F set to zero for negative F^2^. The observed criterion
 of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme
 'calc w=1/[\s^2^(Fo^2^)+(0.0232P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     riding
_refine_ls_extinction_method      SHELXL
_refine_ls_extinction_coef        0.00023(5)
_refine_ls_extinction_expression
 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^'
_refine_ls_number_reflns          4217
_refine_ls_number_parameters      344
_refine_ls_number_restraints      2
_refine_ls_R_factor_all           0.0460
_refine_ls_R_factor_obs           0.0268
_refine_ls_wR_factor_all          0.0569
_refine_ls_wR_factor_obs          0.0486
_refine_ls_goodness_of_fit_all    0.960
_refine_ls_goodness_of_fit_obs    1.017
_refine_ls_restrained_S_all       1.036
_refine_ls_restrained_S_obs       1.016
_refine_ls_shift/esd_max          -0.013
_refine_ls_shift/esd_mean         0.000

loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_thermal_displace_type
 _atom_site_occupancy
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_group
Pt1 Pt 1.24133(2) 0.30866(2) -0.028329(9) 0.03987(9) Uani 1 d . .
Cl1 Cl 1.13788(12) 0.14417(13) -0.06741(7) 0.0680(4) Uani 1 d . .
S1 S 1.19083(10) 0.43436(11) -0.10908(6) 0.0414(3) Uani 1 d . .
C1 C 1.0593(4) 0.4807(4) -0.1256(2) 0.0438(13) Uani 1 d . .
N1 N 1.2545(3) 0.5607(3) -0.0916(2) 0.0464(11) Uani 1 d . .
C2 C 1.0271(5) 0.5567(5) -0.1775(3) 0.063(2) Uani 1 d . .
H2A H 1.0703(5) 0.5758(5) -0.2066(3) 0.076 Uiso 1 calc R .
C3 C 0.9283(6) 0.6042(5) -0.1855(3) 0.074(2) Uani 1 d . .
H3A H 0.9046(6) 0.6554(5) -0.2205(3) 0.089 Uiso 1 calc R .
C4 C 0.8653(5) 0.5761(6) -0.1421(4) 0.077(2) Uani 1 d . .
H4A H 0.7998(5) 0.6097(6) -0.1467(4) 0.092 Uiso 1 calc R .
C5 C 0.9000(5) 0.4985(6) -0.0920(3) 0.076(2) Uani 1 d . .
H5A H 0.8568(5) 0.4777(6) -0.0632(3) 0.091 Uiso 1 calc R .
C6 C 0.9977(4) 0.4499(5) -0.0832(3) 0.059(2) Uani 1 d . .
H6A H 1.0207(4) 0.3972(5) -0.0488(3) 0.071 Uiso 1 calc R .
C7 C 1.2163(4) 0.3860(4) -0.1860(2) 0.0422(13) Uani 1 d . .
C8 C 1.3051(4) 0.4260(5) -0.2041(3) 0.0546(15) Uani 1 d . .
H8A H 1.3481(4) 0.4805(5) -0.1781(3) 0.066 Uiso 1 calc R .
C9 C 1.3298(5) 0.3838(5) -0.2617(3) 0.068(2) Uani 1 d . .
H9A H 1.3906(5) 0.4090(5) -0.2743(3) 0.082 Uiso 1 calc R .
C10 C 1.2650(6) 0.3047(6) -0.3006(3) 0.076(2) Uani 1 d . .
H10A H 1.2814(6) 0.2774(6) -0.3396(3) 0.092 Uiso 1 calc R .
C11 C 1.1759(6) 0.2664(6) -0.2816(3) 0.072(2) Uani 1 d . .
H11A H 1.1323(6) 0.2131(6) -0.3081(3) 0.087 Uiso 1 calc R .
C12 C 1.1502(4) 0.3056(5) -0.2239(3) 0.059(2) Uani 1 d . .
H12A H 1.0903(4) 0.2789(5) -0.2108(3) 0.071 Uiso 1 calc R .
C13 C 1.3202(4) 0.5508(5) -0.0340(2) 0.0405(12) Uani 1 d . .
C14 C 1.3870(4) 0.6602(4) -0.0136(3) 0.056(2) Uani 1 d . .
H14A H 1.3715(4) 0.7234(4) -0.0457(3) 0.084 Uiso 1 calc R .
H14B H 1.4579(4) 0.6373(4) -0.0094(3) 0.084 Uiso 1 calc R .
H14C H 1.3741(4) 0.6897(4) 0.0275(3) 0.084 Uiso 1 calc R .
N14 N 1.3277(3) 0.4533(4) 0.0022(2) 0.0436(11) Uani 1 d D .
H14N H 1.3773(23) 0.4607(34) 0.0426(11) 0.031(12) Uiso 1 d D .
N2 N 1.3119(4) 0.2201(4) 0.0516(2) 0.0562(13) Uani 1 d D .
H2N H 1.3689(34) 0.2680(50) 0.0755(29) 0.118(27) Uiso 1 d D .
S2 S 1.28725(11) 0.08444(12) 0.07545(7) 0.0539(4) Uani 1 d . .
C21 C 1.2550(5) 0.0982(6) 0.1551(3) 0.061(2) Uani 1 d . .
C22 C 1.3107(6) 0.1704(6) 0.2016(3) 0.074(2) Uani 1 d . .
H22A H 1.3680(6) 0.2124(6) 0.1932(3) 0.089 Uiso 1 calc R .
C23 C 1.2800(7) 0.1805(7) 0.2629(3) 0.094(2) Uani 1 d . .
H23A H 1.3159(7) 0.2302(7) 0.2953(3) 0.113 Uiso 1 calc R .
C24 C 1.1957(8) 0.1151(8) 0.2734(5) 0.107(3) Uani 1 d . .
H24A H 1.1753(8) 0.1207(8) 0.3136(5) 0.128 Uiso 1 calc R .
C25 C 1.1416(7) 0.0429(8) 0.2272(5) 0.108(3) Uani 1 d . .
H25A H 1.0851(7) -0.0005(8) 0.2357(5) 0.130 Uiso 1 calc R .
C26 C 1.1708(6) 0.0340(6) 0.1672(4) 0.084(2) Uani 1 d . .
H26A H 1.1337(6) -0.0152(6) 0.1350(4) 0.101 Uiso 1 calc R .
C27 C 1.4090(4) 0.0078(5) 0.0975(2) 0.0487(14) Uani 1 d . .
C28 C 1.4957(5) 0.0554(6) 0.0805(3) 0.086(2) Uani 1 d . .
H28A H 1.4937(5) 0.1296(6) 0.0586(3) 0.103 Uiso 1 calc R .
C29 C 1.5878(6) -0.0099(7) 0.0966(4) 0.102(3) Uani 1 d . .
H29A H 1.6480(6) 0.0226(7) 0.0865(4) 0.122 Uiso 1 calc R .
C30 C 1.5905(5) -0.1207(7) 0.1271(3) 0.076(2) Uani 1 d . .
H30A H 1.6520(5) -0.1634(7) 0.1383(3) 0.091 Uiso 1 calc R .
C31 C 1.5021(6) -0.1665(6) 0.1406(3) 0.082(2) Uani 1 d . .
H31A H 1.5032(6) -0.2428(6) 0.1604(3) 0.098 Uiso 1 calc R .
C32 C 1.4102(5) -0.1046(5) 0.1263(3) 0.066(2) Uani 1 d . .
H32A H 1.3502(5) -0.1384(5) 0.1360(3) 0.079 Uiso 1 calc R .
Cl2 Cl 1.45968(11) 0.41726(14) 0.14121(6) 0.0638(4) Uani 1 d . .
N40 N 0.8276(7) 0.2122(8) -0.0499(5) 0.146(3) Uani 1 d . .
C40 C 0.8822(8) 0.1938(8) -0.0035(5) 0.098(3) Uani 1 d . .
C41 C 0.9546(7) 0.1706(7) 0.0533(4) 0.122(3) Uani 1 d . .
H41A H 0.9202(10) 0.1664(53) 0.0900(6) 0.183 Uiso 1 calc R .
H41B H 1.0045(27) 0.2353(29) 0.0598(16) 0.183 Uiso 1 calc R .
H41C H 0.9886(33) 0.0943(28) 0.0488(12) 0.183 Uiso 1 calc R .

loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
Pt1 0.04029(13) 0.03704(13) 0.04291(13) 0.00568(10) 0.00920(8) 0.00369(11)
Cl1 0.0735(11) 0.0493(9) 0.0774(11) 0.0057(7) 0.0030(8) -0.0155(8)
S1 0.0437(8) 0.0365(7) 0.0424(8) 0.0016(6) 0.0036(6) 0.0019(6)
C1 0.042(3) 0.044(3) 0.042(3) 0.000(3) -0.001(3) 0.000(3)
N1 0.059(3) 0.030(2) 0.047(3) 0.000(2) 0.002(2) -0.007(2)
C2 0.058(4) 0.058(4) 0.071(4) 0.006(3) 0.004(3) 0.007(3)
C3 0.075(5) 0.059(4) 0.079(5) 0.001(4) -0.011(4) 0.024(4)
C4 0.064(5) 0.069(5) 0.089(5) -0.027(4) -0.013(4) 0.026(4)
C5 0.050(4) 0.098(5) 0.080(5) -0.018(4) 0.014(4) 0.014(4)
C6 0.051(4) 0.065(4) 0.060(4) 0.006(3) 0.007(3) 0.015(3)
C7 0.045(3) 0.042(3) 0.039(3) -0.001(2) 0.005(3) 0.002(3)
C8 0.060(4) 0.053(4) 0.050(4) -0.010(3) 0.006(3) -0.001(3)
C9 0.061(4) 0.079(5) 0.070(4) -0.013(4) 0.026(3) 0.000(4)
C10 0.088(5) 0.083(5) 0.059(4) -0.025(4) 0.015(4) 0.002(4)
C11 0.088(6) 0.064(4) 0.059(4) -0.027(3) -0.002(4) -0.007(4)
C12 0.060(4) 0.046(3) 0.069(4) -0.006(3) 0.002(3) -0.011(3)
C13 0.046(3) 0.045(3) 0.032(3) -0.001(3) 0.011(2) 0.000(3)
C14 0.062(4) 0.053(4) 0.051(4) -0.011(3) 0.005(3) -0.012(3)
N14 0.045(3) 0.047(3) 0.037(3) 0.002(2) 0.002(2) 0.000(2)
N2 0.063(3) 0.046(3) 0.057(3) 0.016(2) 0.003(3) 0.002(3)
S2 0.0521(9) 0.0503(9) 0.0591(10) 0.0171(7) 0.0097(7) 0.0052(7)
C21 0.065(4) 0.059(4) 0.065(4) 0.028(3) 0.029(4) 0.029(3)
C22 0.092(5) 0.066(5) 0.069(5) 0.024(4) 0.028(4) 0.022(4)
C23 0.138(8) 0.079(5) 0.073(5) 0.024(4) 0.039(5) 0.043(5)
C24 0.143(9) 0.093(7) 0.107(8) 0.053(6) 0.084(7) 0.060(6)
C25 0.104(7) 0.099(7) 0.143(9) 0.058(6) 0.078(7) 0.036(6)
C26 0.078(5) 0.081(5) 0.102(6) 0.036(4) 0.040(4) 0.018(4)
C27 0.049(4) 0.046(4) 0.050(3) 0.000(3) 0.006(3) 0.011(3)
C28 0.064(5) 0.064(4) 0.134(6) 0.024(4) 0.031(4) 0.006(4)
C29 0.049(5) 0.097(6) 0.166(8) -0.002(6) 0.037(5) 0.006(4)
C30 0.056(5) 0.073(5) 0.095(5) -0.010(4) 0.007(4) 0.018(4)
C31 0.090(6) 0.066(5) 0.089(5) 0.020(4) 0.017(4) 0.028(4)
C32 0.064(4) 0.054(4) 0.083(5) 0.021(3) 0.018(3) 0.013(3)
Cl2 0.0548(9) 0.0852(11) 0.0490(9) -0.0075(8) 0.0030(7) 0.0043(8)
N40 0.112(7) 0.146(7) 0.175(9) 0.000(7) 0.013(6) -0.023(6)
C40 0.096(8) 0.076(5) 0.127(8) -0.020(6) 0.035(6) -0.024(6)
C41 0.139(9) 0.115(7) 0.113(7) -0.015(6) 0.027(6) -0.040(6)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Pt1 N14 1.989(4) . ?
Pt1 N2 2.012(4) . ?
Pt1 S1 2.1876(12) . ?
Pt1 Cl1 2.3191(14) . ?
S1 N1 1.625(4) . ?
S1 C7 1.782(5) . ?
S1 C1 1.785(5) . ?
C1 C6 1.349(7) . ?
C1 C2 1.373(7) . ?
N1 C13 1.358(6) . ?
C2 C3 1.388(8) . ?
C3 C4 1.372(9) . ?
C4 C5 1.362(8) . ?
C5 C6 1.378(8) . ?
C7 C8 1.369(7) . ?
C7 C12 1.384(7) . ?
C8 C9 1.383(7) . ?
C9 C10 1.377(8) . ?
C10 C11 1.374(9) . ?
C11 C12 1.380(8) . ?
C13 N14 1.302(6) . ?
C13 C14 1.503(6) . ?
N2 S2 1.618(4) . ?
S2 C21 1.798(6) . ?
S2 C27 1.801(5) . ?
C21 C22 1.362(8) . ?
C21 C26 1.378(8) . ?
C22 C23 1.417(9) . ?
C23 C24 1.374(11) . ?
C24 C25 1.349(11) . ?
C25 C26 1.380(10) . ?
C27 C28 1.362(8) . ?
C27 C32 1.368(7) . ?
C28 C29 1.400(9) . ?
C29 C30 1.367(9) . ?
C30 C31 1.347(9) . ?
C31 C32 1.377(8) . ?
N40 C40 1.119(10) . ?
C40 C41 1.409(11) . ?

loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
N14 Pt1 N2 87.8(2) . . ?
N14 Pt1 S1 79.95(12) . . ?
N2 Pt1 S1 167.56(14) . . ?
N14 Pt1 Cl1 177.80(12) . . ?
N2 Pt1 Cl1 94.36(14) . . ?
S1 Pt1 Cl1 97.84(5) . . ?
N1 S1 C7 106.3(2) . . ?
N1 S1 C1 104.5(2) . . ?
C7 S1 C1 104.1(2) . . ?
N1 S1 Pt1 106.68(15) . . ?
C7 S1 Pt1 115.4(2) . . ?
C1 S1 Pt1 118.7(2) . . ?
C6 C1 C2 122.2(5) . . ?
C6 C1 S1 118.9(4) . . ?
C2 C1 S1 118.6(4) . . ?
C13 N1 S1 110.8(3) . . ?
C1 C2 C3 118.3(6) . . ?
C4 C3 C2 120.4(6) . . ?
C5 C4 C3 119.2(6) . . ?
C4 C5 C6 121.5(7) . . ?
C1 C6 C5 118.5(6) . . ?
C8 C7 C12 122.0(5) . . ?
C8 C7 S1 117.7(4) . . ?
C12 C7 S1 120.2(4) . . ?
C7 C8 C9 118.8(5) . . ?
C10 C9 C8 120.3(6) . . ?
C11 C10 C9 119.8(6) . . ?
C10 C11 C12 121.1(6) . . ?
C11 C12 C7 117.9(6) . . ?
N14 C13 N1 123.4(5) . . ?
N14 C13 C14 120.5(4) . . ?
N1 C13 C14 116.1(4) . . ?
C13 N14 Pt1 119.1(3) . . ?
S2 N2 Pt1 127.5(3) . . ?
N2 S2 C21 107.6(3) . . ?
N2 S2 C27 106.6(3) . . ?
C21 S2 C27 98.7(3) . . ?
C22 C21 C26 121.0(6) . . ?
C22 C21 S2 121.5(5) . . ?
C26 C21 S2 117.5(6) . . ?
C21 C22 C23 119.1(7) . . ?
C24 C23 C22 118.3(8) . . ?
C25 C24 C23 122.1(9) . . ?
C24 C25 C26 119.6(9) . . ?
C21 C26 C25 119.8(8) . . ?
C28 C27 C32 121.0(5) . . ?
C28 C27 S2 120.7(5) . . ?
C32 C27 S2 118.1(5) . . ?
C27 C28 C29 118.5(6) . . ?
C30 C29 C28 121.0(7) . . ?
C31 C30 C29 118.4(6) . . ?
C30 C31 C32 122.5(6) . . ?
C27 C32 C31 118.6(6) . . ?
N40 C40 C41 177.3(11) . . ?

loop_
 _geom_torsion_atom_site_label_1
 _geom_torsion_atom_site_label_2
 _geom_torsion_atom_site_label_3
 _geom_torsion_atom_site_label_4
 _geom_torsion
 _geom_torsion_site_symmetry_1
 _geom_torsion_site_symmetry_2
 _geom_torsion_site_symmetry_3
 _geom_torsion_site_symmetry_4
 _geom_torsion_publ_flag
 N14 Pt1 S1 N1 -0.4(2) . . . . ?
 N2 Pt1 S1 N1 -11.8(7) . . . . ?
 Cl1 Pt1 S1 N1 179.6(2) . . . . ?
 N14 Pt1 S1 C7 117.5(2) . . . . ?
 N2 Pt1 S1 C7 106.1(7) . . . . ?
 Cl1 Pt1 S1 C7 -62.5(2) . . . . ?
 N14 Pt1 S1 C1 -117.9(2) . . . . ?
 N2 Pt1 S1 C1 -129.3(7) . . . . ?
 Cl1 Pt1 S1 C1 62.1(2) . . . . ?
 N1 S1 C1 C6 -110.2(5) . . . . ?
 C7 S1 C1 C6 138.4(4) . . . . ?
 Pt1 S1 C1 C6 8.4(5) . . . . ?
 N1 S1 C1 C2 63.3(5) . . . . ?
 C7 S1 C1 C2 -48.1(5) . . . . ?
 Pt1 S1 C1 C2 -178.1(4) . . . . ?
 C7 S1 N1 C13 -122.6(4) . . . . ?
 C1 S1 N1 C13 127.7(4) . . . . ?
 Pt1 S1 N1 C13 1.1(4) . . . . ?
 C6 C1 C2 C3 0.9(8) . . . . ?
 S1 C1 C2 C3 -172.3(4) . . . . ?
 C1 C2 C3 C4 0.5(9) . . . . ?
 C2 C3 C4 C5 -1.8(10) . . . . ?
 C3 C4 C5 C6 1.6(10) . . . . ?
 C2 C1 C6 C5 -1.1(9) . . . . ?
 S1 C1 C6 C5 172.2(4) . . . . ?
 C4 C5 C6 C1 -0.2(9) . . . . ?
 N1 S1 C7 C8 24.1(5) . . . . ?
 C1 S1 C7 C8 134.1(4) . . . . ?
 Pt1 S1 C7 C8 -94.0(4) . . . . ?
 N1 S1 C7 C12 -159.3(4) . . . . ?
 C1 S1 C7 C12 -49.3(4) . . . . ?
 Pt1 S1 C7 C12 82.7(4) . . . . ?
 C12 C7 C8 C9 -0.5(8) . . . . ?
 S1 C7 C8 C9 176.1(4) . . . . ?
 C7 C8 C9 C10 1.1(9) . . . . ?
 C8 C9 C10 C11 -0.8(9) . . . . ?
 C9 C10 C11 C12 -0.1(10) . . . . ?
 C10 C11 C12 C7 0.7(9) . . . . ?
 C8 C7 C12 C11 -0.4(8) . . . . ?
 S1 C7 C12 C11 -176.9(4) . . . . ?
 S1 N1 C13 N14 -1.7(6) . . . . ?
 S1 N1 C13 C14 177.6(4) . . . . ?
 N1 C13 N14 Pt1 1.4(7) . . . . ?
 C14 C13 N14 Pt1 -177.9(4) . . . . ?
 N2 Pt1 N14 C13 177.1(4) . . . . ?
 S1 Pt1 N14 C13 -0.4(4) . . . . ?
 Cl1 Pt1 N14 C13 -1.1(36) . . . . ?
 N14 Pt1 N2 S2 175.6(4) . . . . ?
 S1 Pt1 N2 S2 -173.2(3) . . . . ?
 Cl1 Pt1 N2 S2 -4.4(3) . . . . ?
 Pt1 N2 S2 C21 -121.4(4) . . . . ?
 Pt1 N2 S2 C27 133.5(3) . . . . ?
 N2 S2 C21 C22 -44.1(5) . . . . ?
 C27 S2 C21 C22 66.5(5) . . . . ?
 N2 S2 C21 C26 135.1(5) . . . . ?
 C27 S2 C21 C26 -114.3(5) . . . . ?
 C26 C21 C22 C23 -1.0(9) . . . . ?
 S2 C21 C22 C23 178.2(4) . . . . ?
 C21 C22 C23 C24 1.0(9) . . . . ?
 C22 C23 C24 C25 -0.5(11) . . . . ?
 C23 C24 C25 C26 -0.2(13) . . . . ?
 C22 C21 C26 C25 0.3(9) . . . . ?
 S2 C21 C26 C25 -178.9(5) . . . . ?
 C24 C25 C26 C21 0.3(11) . . . . ?
 N2 S2 C27 C28 -13.2(6) . . . . ?
 C21 S2 C27 C28 -124.6(5) . . . . ?
 N2 S2 C27 C32 172.8(4) . . . . ?
 C21 S2 C27 C32 61.4(5) . . . . ?
 C32 C27 C28 C29 -3.8(10) . . . . ?
 S2 C27 C28 C29 -177.7(5) . . . . ?
 C27 C28 C29 C30 1.9(11) . . . . ?
 C28 C29 C30 C31 0.8(11) . . . . ?
 C29 C30 C31 C32 -1.6(11) . . . . ?
 C28 C27 C32 C31 3.0(9) . . . . ?
 S2 C27 C32 C31 177.1(5) . . . . ?
 C30 C31 C32 C27 -0.2(10) . . . . ?

_refine_diff_density_max    1.042
_refine_diff_density_min   -0.427
_refine_diff_density_rms    0.080