# Supplementary Material (ESI) for ChemComm
# This journal is © The Royal Society of Chemistry, 1999
# CCDC Number: 182/1324

data_rem218

_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C32 H72 K4 Li4 O8'
_chemical_formula_weight          769.06

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Li'  'Li'  -0.0003   0.0001
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'K'  'K'   0.2009   0.2494
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting            monoclinic
_symmetry_space_group_name_H-M    P2(1)/m

loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, y+1/2, -z'
 '-x, -y, -z'
 'x, -y-1/2, z'

_cell_length_a                    11.5194(6)
_cell_length_b                    17.1506(10)
_cell_length_c                    13.0058(7)
_cell_angle_alpha                 90.00
_cell_angle_beta                  110.166(2)
_cell_angle_gamma                 90.00
_cell_volume                      2412.0(2)
_cell_formula_units_Z             2
_cell_measurement_temperature     160(2)
_cell_measurement_reflns_used     10011
_cell_measurement_theta_min       2.90
_cell_measurement_theta_max       29.00

_exptl_crystal_description        block
_exptl_crystal_colour             colourless
_exptl_crystal_size_max           0.62
_exptl_crystal_size_mid           0.44
_exptl_crystal_size_min           0.22
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.059
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              832
_exptl_absorpt_coefficient_mu     0.405
_exptl_absorpt_correction_type    empirical
_exptl_absorpt_correction_T_min   0.7874
_exptl_absorpt_correction_T_max   0.9162
_exptl_absorpt_process_details    ?

_exptl_special_details
;
 ?
;

_diffrn_ambient_temperature       160(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   'Siemens SMART CCD diffractometer'
_diffrn_measurement_method        '\w rotation with narrow frames'
_diffrn_detector_area_resol_mean  ?
_diffrn_standards_number          0
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         0
_diffrn_reflns_number             10325
_diffrn_reflns_av_R_equivalents   0.0192
_diffrn_reflns_av_sigmaI/netI     0.0262
_diffrn_reflns_limit_h_min        -13
_diffrn_reflns_limit_h_max        13
_diffrn_reflns_limit_k_min        -17
_diffrn_reflns_limit_k_max        20
_diffrn_reflns_limit_l_min        -15
_diffrn_reflns_limit_l_max        6
_diffrn_reflns_theta_min          1.88
_diffrn_reflns_theta_max          25.00
_reflns_number_total              4372
_reflns_number_gt                 3351
_reflns_threshold_expression      >2sigma(I)

_computing_data_collection        'Siemens SMART'
_computing_cell_refinement        'local programs'
_computing_data_reduction         'Siemens SAINT'
_computing_structure_solution     'Siemens SHELXTL'
_computing_structure_refinement   'Siemens SHELXTL'
_computing_molecular_graphics     'Siemens SHELXTL'
_computing_publication_material   'SHELXTL and local programs'

_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR 
and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and 
is
 not relevant to the choice of reflections for refinement.  R-factors 
based
 on F^2^ are statistically about twice as large as those based on F, and 
R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[\s^2^(Fo^2^)+(0.0537P)^2^+0.0508P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     mixed
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          4372
_refine_ls_number_parameters      266
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0441
_refine_ls_R_factor_gt            0.0324
_refine_ls_wR_factor_ref          0.0880
_refine_ls_wR_factor_gt           0.0853
_refine_ls_goodness_of_fit_ref    1.035
_refine_ls_restrained_S_all       1.035
_refine_ls_shift/su_max           0.000
_refine_ls_shift/su_mean          0.000

loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
K1 K 0.80487(3) 0.36146(2) 0.43194(3) 0.03428(12) Uani 1 1 d . . .
K2 K 0.68029(3) 0.36129(2) 0.11477(3) 0.03899(12) Uani 1 1 d . . .
Li1 Li 0.9845(3) 0.2500 0.3781(3) 0.0318(9) Uani 1 2 d S . .
Li2 Li 0.9068(3) 0.2500 0.1792(3) 0.0320(9) Uani 1 2 d S . .
Li3 Li 0.5434(2) 0.32121(16) 0.2729(2) 0.0313(6) Uani 1 1 d . . .
O1 O 0.61094(13) 0.2500 0.39250(12) 0.0269(3) Uani 1 2 d S . .
C1 C 0.5641(2) 0.2500 0.47963(18) 0.0309(5) Uani 1 2 d S . .
C2 C 0.6073(2) 0.32187(13) 0.55121(16) 0.0548(5) Uani 1 1 d . . .
H2A H 0.6971 0.3193 0.5885 0.082 Uiso 1 1 calc R . .
H2B H 0.5662 0.3239 0.6058 0.082 Uiso 1 1 calc R . .
H2C H 0.5865 0.3688 0.5054 0.082 Uiso 1 1 calc R . .
C3 C 0.4225(2) 0.2500 0.4328(3) 0.0704(10) Uani 1 2 d S . .
H3A H 0.3940 0.2077 0.3793 0.106 Uiso 0.50 1 calc PR . .
H3B H 0.3933 0.3001 0.3969 0.106 Uiso 0.50 1 calc PR . .
H3C H 0.3898 0.2422 0.4923 0.106 Uiso 0.50 1 calc PR . .
O2 O 0.96947(13) 0.2500 0.51351(12) 0.0326(4) Uani 1 2 d S . .
C4 C 1.0564(2) 0.2500 0.61918(18) 0.0315(5) Uani 1 2 d S . .
C5 C 1.04014(18) 0.32249(12) 0.68139(15) 0.0498(5) Uani 1 1 d . . .
H5A H 1.0531 0.3693 0.6436 0.075 Uiso 1 1 calc R . .
H5B H 1.1005 0.3214 0.7560 0.075 Uiso 1 1 calc R . .
H5C H 0.9563 0.3232 0.6845 0.075 Uiso 1 1 calc R . .
C6 C 1.1872(2) 0.2500 0.6145(2) 0.0477(7) Uani 1 2 d S . .
H6A H 1.2470 0.2399 0.6878 0.072 Uiso 0.50 1 calc PR . .
H6B H 1.2045 0.3009 0.5887 0.072 Uiso 0.50 1 calc PR . .
H6C H 1.1939 0.2092 0.5641 0.072 Uiso 0.50 1 calc PR . .
O3 O 0.51308(13) 0.2500 0.15350(12) 0.0297(4) Uani 1 2 d S . .
C7 C 0.3987(2) 0.2500 0.06593(19) 0.0355(6) Uani 1 2 d S . .
C8 C 0.4187(7) 0.2612(15) -0.0428(7) 0.083(7) Uani 0.325(9) 1 d P A -1
H8A H 0.4758 0.2212 -0.0509 0.125 Uiso 0.325(9) 1 calc PR A -1
H8B H 0.4538 0.3130 -0.0447 0.125 Uiso 0.325(9) 1 calc PR A -1
H8C H 0.3394 0.2565 -0.1030 0.125 Uiso 0.325(9) 1 calc PR A -1
C9 C 0.3361(18) 0.1665(10) 0.058(2) 0.081(6) Uani 0.325(9) 1 d P A -1
H9A H 0.3912 0.1267 0.0457 0.121 Uiso 0.325(9) 1 calc PR A -1
H9B H 0.2573 0.1660 -0.0036 0.121 Uiso 0.325(9) 1 calc PR A -1
H9C H 0.3211 0.1553 0.1260 0.121 Uiso 0.325(9) 1 calc PR A -1
C10 C 0.3052(19) 0.2998(14) 0.0803(18) 0.137(15) Uani 0.325(9) 1 d P A -1
H10A H 0.2983 0.2900 0.1523 0.206 Uiso 0.325(9) 1 calc PR A -1
H10B H 0.2256 0.2889 0.0229 0.206 Uiso 0.325(9) 1 calc PR A -1
H10C H 0.3277 0.3544 0.0756 0.206 Uiso 0.325(9) 1 calc PR A -1
C11 C 0.3047(13) 0.2500 0.125(2) 0.138(15) Uani 0.350(17) 2 d SP A 2
H11A H 0.3118 0.2988 0.1664 0.207 Uiso 0.175(9) 1 calc PR A 2
H11B H 0.3213 0.2058 0.1763 0.207 Uiso 0.175(9) 1 calc PR A 2
H11C H 0.2209 0.2454 0.0718 0.207 Uiso 0.175(9) 1 calc PR A 2
C12 C 0.3891(8) 0.1785(5) 0.0004(7) 0.078(7) Uani 0.350(17) 1 d P A 2
H12A H 0.3991 0.1327 0.0477 0.117 Uiso 0.350(17) 1 calc PR A 2
H12B H 0.4540 0.1786 -0.0324 0.117 Uiso 0.350(17) 1 calc PR A 2
H12C H 0.3079 0.1767 -0.0578 0.117 Uiso 0.350(17) 1 calc PR A 2
O4 O 0.79008(14) 0.2500 0.04232(12) 0.0361(4) Uani 1 2 d S . .
C13 C 0.8064(2) 0.2500 -0.05929(19) 0.0426(7) Uani 1 2 d S . .
C14 C 0.7504(3) 0.32273(18) -0.12288(19) 0.0887(9) Uani 1 1 d . . .
H14A H 0.6606 0.3221 -0.1401 0.133 Uiso 1 1 calc R . .
H14B H 0.7687 0.3243 -0.1911 0.133 Uiso 1 1 calc R . .
H14C H 0.7856 0.3689 -0.0787 0.133 Uiso 1 1 calc R . .
C15 C 0.9446(3) 0.2500 -0.0429(3) 0.0719(10) Uani 1 2 d S . .
H15A H 0.9816 0.2007 -0.0092 0.108 Uiso 0.50 1 calc PR . .
H15B H 0.9852 0.2934 0.0049 0.108 Uiso 0.50 1 calc PR . .
H15C H 0.9555 0.2559 -0.1140 0.108 Uiso 0.50 1 calc PR . .
O5 O 0.61011(10) 0.41721(6) 0.27385(9) 0.0340(3) Uani 1 1 d . . .
C16 C 0.56607(15) 0.49229(10) 0.27788(15) 0.0397(4) Uani 1 1 d . . .
C17 C 0.6519(2) 0.53493(13) 0.3800(2) 0.0781(8) Uani 1 1 d . . .
H17A H 0.6547 0.5062 0.4460 0.117 Uiso 1 1 calc R . .
H17B H 0.6204 0.5877 0.3827 0.117 Uiso 1 1 calc R . .
H17C H 0.7354 0.5380 0.3764 0.117 Uiso 1 1 calc R . .
C18 C 0.43669(16) 0.48985(12) 0.28637(17) 0.0476(5) Uani 1 1 d . . .
H18A H 0.3799 0.4628 0.2224 0.071 Uiso 1 1 calc R . .
H18B H 0.4073 0.5432 0.2890 0.071 Uiso 1 1 calc R . .
H18C H 0.4402 0.4620 0.3532 0.071 Uiso 1 1 calc R . .
C19 C 0.5597(3) 0.53742(15) 0.1758(2) 0.0912(10) Uani 1 1 d . . .
H19A H 0.6420 0.5393 0.1696 0.137 Uiso 1 1 calc R . .
H19B H 0.5309 0.5906 0.1807 0.137 Uiso 1 1 calc R . .
H19C H 0.5021 0.5115 0.1112 0.137 Uiso 1 1 calc R . .
O6 O 0.92621(9) 0.33529(6) 0.27820(9) 0.0291(3) Uani 1 1 d . . .
C20 C 1.00458(14) 0.39845(10) 0.27798(14) 0.0344(4) Uani 1 1 d . . .
C21 C 1.0304(2) 0.44769(12) 0.38119(17) 0.0544(5) Uani 1 1 d . . .
H21A H 0.9537 0.4727 0.3806 0.082 Uiso 1 1 calc R . .
H21B H 1.0919 0.4878 0.3834 0.082 Uiso 1 1 calc R . .
H21C H 1.0623 0.4142 0.4459 0.082 Uiso 1 1 calc R . .
C22 C 1.1269(2) 0.36730(14) 0.2737(3) 0.0791(8) Uani 1 1 d . . .
H22A H 1.1667 0.3347 0.3381 0.119 Uiso 1 1 calc R . .
H22B H 1.1813 0.4111 0.2731 0.119 Uiso 1 1 calc R . .
H22C H 1.1114 0.3361 0.2071 0.119 Uiso 1 1 calc R . .
C23 C 0.9445(2) 0.45149(13) 0.17924(18) 0.0636(6) Uani 1 1 d . . .
H23A H 0.9222 0.4206 0.1118 0.095 Uiso 1 1 calc R . .
H23B H 1.0029 0.4925 0.1772 0.095 Uiso 1 1 calc R . .
H23C H 0.8699 0.4753 0.1855 0.095 Uiso 1 1 calc R . .

loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
K1 0.02937(18) 0.0348(2) 0.0376(2) -0.00015(17) 0.01010(15) 0.00338(16)
K2 0.0376(2) 0.0427(2) 0.0417(2) 0.00314(18) 0.02001(17) 0.00349(18)
Li1 0.0300(19) 0.033(2) 0.030(2) 0.000 0.0084(16) 0.000
Li2 0.0295(18) 0.035(2) 0.032(2) 0.000 0.0113(16) 0.000
Li3 0.0341(13) 0.0282(15) 0.0328(14) 0.0019(12) 0.0131(11) 0.0013(12)
O1 0.0288(7) 0.0291(9) 0.0248(8) 0.000 0.0117(6) 0.000
C1 0.0291(11) 0.0393(14) 0.0267(11) 0.000 0.0129(9) 0.000
C2 0.0777(14) 0.0538(13) 0.0445(11) -0.0132(10) 0.0359(11) -0.0074(11)
C3 0.0332(14) 0.128(3) 0.0553(19) 0.000 0.0227(14) 0.000
O2 0.0298(8) 0.0398(10) 0.0247(8) 0.000 0.0048(6) 0.000
C4 0.0303(11) 0.0335(14) 0.0258(12) 0.000 0.0033(9) 0.000
C5 0.0548(11) 0.0500(13) 0.0381(10) -0.0092(9) 0.0080(9) 0.0034(10)
C6 0.0311(13) 0.0566(19) 0.0486(16) 0.000 0.0050(12) 0.000
O3 0.0272(8) 0.0362(9) 0.0240(8) 0.000 0.0066(6) 0.000
C7 0.0274(11) 0.0454(16) 0.0302(12) 0.000 0.0054(10) 0.000
C8 0.054(4) 0.143(18) 0.037(4) 0.047(10) -0.004(3) -0.028(10)
C9 0.045(8) 0.075(8) 0.086(9) 0.013(7) -0.024(7) -0.031(6)
C10 0.057(12) 0.20(3) 0.10(2) -0.11(2) -0.035(10) 0.065(14)
C11 0.003(5) 0.34(5) 0.062(12) 0.000 -0.004(6) 0.000
C12 0.058(6) 0.071(9) 0.064(8) -0.036(7) -0.032(6) 0.009(7)
O4 0.0343(8) 0.0523(11) 0.0242(8) 0.000 0.0131(7) 0.000
C13 0.0391(13) 0.0672(19) 0.0240(12) 0.000 0.0142(10) 0.000
C14 0.107(2) 0.119(2) 0.0488(14) 0.0360(15) 0.0380(14) 0.0440(19)
C15 0.0519(17) 0.120(3) 0.0531(19) 0.000 0.0300(15) 0.000
O5 0.0344(6) 0.0243(6) 0.0452(7) 0.0016(5) 0.0162(5) 0.0046(5)
C16 0.0378(9) 0.0246(10) 0.0608(12) 0.0050(9) 0.0224(9) 0.0053(8)
C17 0.0456(12) 0.0449(14) 0.136(2) -0.0370(15) 0.0210(14) -0.0042(11)
C18 0.0383(9) 0.0393(11) 0.0671(13) -0.0036(10) 0.0204(9) 0.0067(9)
C19 0.118(2) 0.0560(16) 0.134(2) 0.0535(16) 0.087(2) 0.0454(15)
O6 0.0288(5) 0.0261(6) 0.0325(6) 0.0009(5) 0.0106(5) -0.0018(5)
C20 0.0313(8) 0.0311(10) 0.0424(9) 0.0001(8) 0.0149(7) -0.0051(8)
C21 0.0647(13) 0.0409(12) 0.0554(12) -0.0081(10) 0.0177(10) -0.0190(10)
C22 0.0455(12) 0.0609(16) 0.147(3) -0.0180(16) 0.0545(15) -0.0121(11)
C23 0.0754(15) 0.0498(13) 0.0583(13) 0.0170(11) 0.0136(11) -0.0227(12)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are 
taken
 into account individually in the estimation of esds in distances, 
angles
 and torsion angles; correlations between esds in cell parameters are 
only
 used when they are defined by crystal symmetry.  An approximate 
(isotropic)
 treatment of cell esds is used for estimating esds involving l.s. 
planes.
;

loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
K1 O2 2.6435(11) . ?
K1 O5 2.6447(12) . ?
K1 O6 2.8425(11) . ?
K1 O1 2.8492(11) . ?
K2 O4 2.6366(11) . ?
K2 O5 2.6472(12) . ?
K2 O3 2.8768(11) . ?
K2 O6 2.9309(11) . ?
Li1 O2 1.828(4) . ?
Li1 O6 1.918(3) 4_565 ?
Li1 O6 1.918(3) . ?
Li2 O4 1.824(4) . ?
Li2 O6 1.910(3) . ?
Li2 O6 1.910(3) 4_565 ?
Li3 O5 1.815(3) . ?
Li3 O3 1.911(3) . ?
Li3 O1 1.919(3) . ?
O1 C1 1.413(3) . ?
O1 Li3 1.919(3) 4_565 ?
O1 K1 2.8492(11) 4_565 ?
C1 C2 1.521(2) . ?
C1 C2 1.521(2) 4_565 ?
C1 C3 1.531(3) . ?
O2 C4 1.394(3) . ?
O2 Li1 1.828(4) 4_565 ?
O2 K1 2.6435(11) 4_565 ?
C4 C6 1.528(3) . ?
C4 C5 1.530(2) . ?
C4 C5 1.530(2) 4_565 ?
O3 C7 1.413(3) . ?
O3 Li3 1.911(3) 4_565 ?
O3 K2 2.8768(11) 4_565 ?
C7 C10 1.437(19) 4_565 ?
C7 C10 1.437(19) . ?
C7 C12 1.476(7) . ?
C7 C12 1.476(7) 4_565 ?
C7 C8 1.521(8) 4_565 ?
C7 C8 1.521(8) . ?
C7 C11 1.53(2) . ?
C7 C9 1.591(19) . ?
C7 C9 1.591(19) 4_565 ?
O4 C13 1.398(3) . ?
O4 K2 2.6366(11) 4_565 ?
C13 C14 1.513(3) 4_565 ?
C13 C14 1.513(3) . ?
C13 C15 1.531(4) . ?
O5 C16 1.392(2) . ?
C16 C19 1.517(3) . ?
C16 C18 1.533(2) . ?
C16 C17 1.540(3) . ?
O6 C20 1.4108(19) . ?
O6 Li1 1.918(3) 4_565 ?
C20 C21 1.526(3) . ?
C20 C22 1.526(3) . ?
C20 C23 1.531(3) . ?

loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
O2 K1 O5 150.73(4) . . ?
O2 K1 O6 73.11(4) . . ?
O5 K1 O6 90.07(3) . . ?
O2 K1 O1 89.80(3) . . ?
O5 K1 O1 72.56(3) . . ?
O6 K1 O1 108.21(4) . . ?
O4 K2 O5 148.75(4) . . ?
O4 K2 O3 90.85(3) . . ?
O5 K2 O3 72.55(3) . . ?
O4 K2 O6 71.72(4) . . ?
O5 K2 O6 88.14(3) . . ?
O3 K2 O6 108.07(4) . . ?
O2 Li1 O6 121.71(13) . 4_565 ?
O2 Li1 O6 121.71(13) . . ?
O6 Li1 O6 99.42(18) 4_565 . ?
O4 Li2 O6 122.23(12) . . ?
O4 Li2 O6 122.23(12) . 4_565 ?
O6 Li2 O6 99.93(18) . 4_565 ?
O5 Li3 O3 122.95(15) . . ?
O5 Li3 O1 121.30(15) . . ?
O3 Li3 O1 99.29(13) . . ?
C1 O1 Li3 119.34(12) . 4_565 ?
C1 O1 Li3 119.34(12) . . ?
Li3 O1 Li3 79.06(17) 4_565 . ?
C1 O1 K1 110.38(8) . . ?
Li3 O1 K1 130.28(10) 4_565 . ?
Li3 O1 K1 78.02(8) . . ?
C1 O1 K1 110.38(8) . 4_565 ?
Li3 O1 K1 78.02(8) 4_565 4_565 ?
Li3 O1 K1 130.28(10) . 4_565 ?
K1 O1 K1 84.28(4) . 4_565 ?
O1 C1 C2 110.83(12) . . ?
O1 C1 C2 110.84(12) . 4_565 ?
C2 C1 C2 108.2(2) . 4_565 ?
O1 C1 C3 109.26(19) . . ?
C2 C1 C3 108.81(14) . . ?
C2 C1 C3 108.81(14) 4_565 . ?
C4 O2 Li1 132.48(18) . 4_565 ?
C4 O2 Li1 132.48(18) . . ?
Li1 O2 Li1 0.00(2) 4_565 . ?
C4 O2 K1 124.61(7) . 4_565 ?
Li1 O2 K1 84.62(9) 4_565 4_565 ?
Li1 O2 K1 84.62(9) . 4_565 ?
C4 O2 K1 124.61(7) . . ?
Li1 O2 K1 84.62(9) 4_565 . ?
Li1 O2 K1 84.62(9) . . ?
K1 O2 K1 92.63(5) 4_565 . ?
O2 C4 C6 110.13(19) . . ?
O2 C4 C5 110.11(13) . . ?
C6 C4 C5 108.87(14) . . ?
O2 C4 C5 110.11(13) . 4_565 ?
C6 C4 C5 108.87(14) . 4_565 ?
C5 C4 C5 108.7(2) . 4_565 ?
C7 O3 Li3 120.89(12) . . ?
C7 O3 Li3 120.89(12) . 4_565 ?
Li3 O3 Li3 79.47(17) . 4_565 ?
C7 O3 K2 110.68(9) . . ?
Li3 O3 K2 76.83(8) . . ?
Li3 O3 K2 128.35(10) 4_565 . ?
C7 O3 K2 110.68(9) . 4_565 ?
Li3 O3 K2 128.35(10) . 4_565 ?
Li3 O3 K2 76.83(8) 4_565 4_565 ?
K2 O3 K2 83.13(4) . 4_565 ?
O3 C7 C10 115.3(7) . 4_565 ?
O3 C7 C10 115.3(7) . . ?
O3 C7 C12 109.2(3) . . ?
O3 C7 C12 109.2(3) . 4_565 ?
C12 C7 C12 112.4(9) . 4_565 ?
O3 C7 C8 110.6(3) . 4_565 ?
C10 C7 C8 114.0(11) 4_565 4_565 ?
O3 C7 C8 110.6(3) . . ?
C10 C7 C8 114.0(11) . . ?
O3 C7 C11 102.6(8) . . ?
C12 C7 C11 111.5(6) . . ?
C12 C7 C11 111.5(6) 4_565 . ?
O3 C7 C9 109.2(6) . . ?
C10 C7 C9 101.6(10) . . ?
C8 C7 C9 105.2(12) . . ?
O3 C7 C9 109.2(6) . 4_565 ?
C10 C7 C9 101.6(10) 4_565 4_565 ?
C8 C7 C9 105.2(12) 4_565 4_565 ?
C13 O4 Li2 128.92(18) . . ?
C13 O4 K2 125.14(7) . 4_565 ?
Li2 O4 K2 86.24(9) . 4_565 ?
C13 O4 K2 125.14(7) . . ?
Li2 O4 K2 86.24(9) . . ?
K2 O4 K2 92.75(5) 4_565 . ?
O4 C13 C14 110.23(14) . 4_565 ?
O4 C13 C14 110.23(14) . . ?
C14 C13 C14 111.1(3) 4_565 . ?
O4 C13 C15 109.9(2) . . ?
C14 C13 C15 107.65(16) 4_565 . ?
C14 C13 C15 107.65(16) . . ?
C16 O5 Li3 132.90(13) . . ?
C16 O5 K1 121.86(10) . . ?
Li3 O5 K1 85.47(9) . . ?
C16 O5 K2 125.32(10) . . ?
Li3 O5 K2 84.75(9) . . ?
K1 O5 K2 94.06(4) . . ?
O5 C16 C19 110.34(16) . . ?
O5 C16 C18 110.71(15) . . ?
C19 C16 C18 108.80(17) . . ?
O5 C16 C17 109.74(15) . . ?
C19 C16 C17 109.6(2) . . ?
C18 C16 C17 107.59(16) . . ?
C20 O6 Li2 120.84(13) . . ?
C20 O6 Li1 120.82(13) . 4_565 ?
Li2 O6 Li1 78.76(13) . 4_565 ?
C20 O6 Li1 120.82(13) . . ?
Li2 O6 Li1 78.76(13) . . ?
Li1 O6 Li1 0.00(19) 4_565 . ?
C20 O6 K1 110.51(9) . . ?
Li2 O6 K1 128.58(11) . . ?
Li1 O6 K1 77.64(11) 4_565 . ?
Li1 O6 K1 77.64(11) . . ?
C20 O6 K2 109.93(9) . . ?
Li2 O6 K2 76.62(11) . . ?
Li1 O6 K2 129.23(11) 4_565 . ?
Li1 O6 K2 129.23(11) . . ?
K1 O6 K2 84.23(3) . . ?
O6 C20 C21 110.74(14) . . ?
O6 C20 C22 109.32(15) . . ?
C21 C20 C22 108.86(17) . . ?
O6 C20 C23 110.71(14) . . ?
C21 C20 C23 107.69(16) . . ?
C22 C20 C23 109.48(18) . . ?

_diffrn_measured_fraction_theta_max    0.991
_diffrn_reflns_theta_full              25.00
_diffrn_measured_fraction_theta_full   0.991
_refine_diff_density_max    0.231
_refine_diff_density_min   -0.309
_refine_diff_density_rms    0.039