# Copyright The Royal Society of Chemistry, 1999 # CCDC Number: 182/1138 data_CRYSTALS_cif _audit_creation_date 98-12-16 _audit_creation_method CRYSTALS # LR2060 173K DIP #**************************************************************************** # The contents of this file between this point and the next #***** line # are held in the file CRYSTALS\SCRIPT\REF.CIF # This is a character file which you may edit to reflect local # conditions # # 1. SUBMISSION DETAILS _publ_contact_author ; Michael Leech Chemical Crystallography Laboratory 9 Parks Road OXFORD OX1 3PD ; _publ_contact_author_phone ' 01865 270 827 ' _publ_contact_author_fax ' 01865 272 699 ' _publ_contact_author_email ' michael.leech@server.icl.ox.ac.uk ' _publ_requested_journal 'Acta Crystallographica C' _publ_requested_coeditor_name ' Prof William Clegg ' _publ_contact_letter ; Please consider this CIF submission for publication as a Short Format Paper in Acta Crystallographica C. The figures have been sent by mail. ; #============================================================================= # 2. PROCESSING SUMMARY (IUCr Office Use Only) _journal_date_recd_electronic ? _journal_date_to_coeditor ? _journal_date_from_coeditor ? _journal_date_accepted ? _journal_date_printers_first ? _journal_date_printers_final ? _journal_date_proofs_out ? _journal_date_proofs_in ? _journal_coeditor_name ? _journal_coeditor_code ? _journal_coeditor_notes ; ? ; _journal_techeditor_code ? _journal_techeditor_notes ; ? ; _journal_coden_ASTM ? _journal_name_full ? _journal_year ? _journal_volume ? _journal_issue ? _journal_page_first ? _journal_page_last ? _journal_suppl_publ_number ? _journal_suppl_publ_pages ? #============================================================================= # 3. TITLE AND AUTHOR LIST _publ_section_title ; ? # Title of paper ; # The loop structure below should contain the names and addresses of all # authors, in the required order of publication. Repeat as necessary. loop_ _publ_author_name _publ_author_address 'Other, Anthony N.' #<--'Last name, first name' ; ? # Address ; 'Else, S. O.' ; ? # Address ; #============================================================================== # 4. TEXT _publ_section_abstract #Text of the abstract ; ? ; _publ_section_comment #Text of the paper ; ? ; _publ_section_exptl_prep ; ? ; _publ_section_exptl_refinement ; ? ; _publ_section_references ; Sheldrick, G.M. (1986). SHELXS86. Program for the solution of crystal structures. Univ. of Gottingen, Federal Republic of Germany. Altomare, A., Cascarano, G., Giacovazzo G., Guagliardi A., Burla M.C., Polidori, G. & Camalli, M. (1994) SIR92 - a program for automatic solution of crystal structures by direct methods. J. Appl. Cryst. (27), 435 Carruthers, J.R. and Watkin, D.J. (1979), (Chebychev Weighting) Acta Cryst, A35, 698-699 Watkin, D.J., Prout, C.K. Carruthers, R.J. & Betteridge, P. (1996) CRYSTALS Issue 10. Chemical Crystallography Laboratory, OXFORD, UK. Watkin, D.J., Prout, C.K. & Pearce, L.J. (1996) CAMERON, Chemical Crystallography Laboratory, OXFORD, UK. Otwinowski, Z. & Minor, W. (1996) DENZO - Processing of X-ray Diffraction data collected in oscillation mode. Methods in Enzymology (276). ; _publ_section_figure_captions ; ? ; _publ_section_acknowledgements ; ? ; #========================================================================== # Now, all the strucure specific goodies #========================================================================== _computing_data_collection 'DIP2000 software (Enraf-Nonius)' _computing_cell_refinement 'DENZO (Otwinowski & Minor, 1996)' _computing_data_reduction ; DENZO (Otwinowski & Minor, 1996) ; _computing_structure_refinement ; CRYSTALS Issue 10 (Watkin, Prout, Carruthers & Betteridge, 1996) ; _computing_publication_material ; CRYSTALS Issue 10 (Watkin, Prout, Carruthers & Betteridge, 1996) ; _computing_molecular_graphics ; CAMERON (Watkin, Prout & Pearce, 1996) ; # _computing_structure_solution 'SHELXS86 (Sheldrick, 1986)' _computing_structure_solution 'SIR92 (Giacovazzo et al, 1992)' #========================================================================== # NOW THE GOODIES TO BE ENTERED BY HAND #========================================================================== _chemical_melting_point ? _diffrn_radiation_monochromator graphite _diffrn_measurement_device ' Enraf-nonius DIP2020 ' _refine_ls_matrix_type full _refine_ls_weighting_scheme ; Chebychev polynomial (Carruthers & Watkin, 1979) ; _atom_sites_solution_primary Direct_Methods _atom_sites_solution_hydrogens Geometric _refine_ls_hydrogen_treatment noref #**************************************************************************** _chemical_name_systematic ; # IUPAC name, in full ? ; _cell_length_a 5.8070(7) _cell_angle_alpha 90 _cell_length_b 13.393(2) _cell_angle_beta 90 _cell_length_c 15.477(3) _cell_angle_gamma 90 _cell_volume 1203.70 _symmetry_cell_setting 'Orthorhombic ' _symmetry_space_group_name_H-M 'P 21 21 21 ' loop_ _symmetry_equiv_pos_as_xyz 'x,y,z' 'x+1/2,-y+1/2,-z' '-x,y+1/2,-z+1/2' '-x+1/2,-y,z+1/2' loop_ _atom_type_symbol _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_Cromer_Mann_a1 _atom_type_scat_Cromer_Mann_b1 _atom_type_scat_Cromer_Mann_a2 _atom_type_scat_Cromer_Mann_b2 _atom_type_scat_Cromer_Mann_a3 _atom_type_scat_Cromer_Mann_b3 _atom_type_scat_Cromer_Mann_a4 _atom_type_scat_Cromer_Mann_b4 _atom_type_scat_Cromer_Mann_c _atom_type_scat_source 'C ' 0.0020 0.0020 2.3100 20.8439 1.0200 10.2075 1.5886 0.5687 0.8650 51.6512 0.2156 'International_Tables_Vol_IV_Table_2.2B' 'H ' 0.0000 0.0000 0.4930 10.5109 0.3229 26.1257 0.1402 3.1424 0.0408 57.7997 0.0030 'International_Tables_Vol_IV_Table_2.2B' 'N ' 0.0040 0.0030 12.2126 0.0057 3.1322 9.8933 2.0125 28.9975 1.1663 0.5826 -11.5290 'International_Tables_Vol_IV_Table_2.2B' 'O ' 0.0080 0.0060 3.0485 13.2771 2.2868 5.7011 1.5463 0.3239 0.8670 32.9089 0.2508 'International_Tables_Vol_IV_Table_2.2B' _chemical_formula_sum ' C12 H20 O2 N1 ' _chemical_formula_moiety ' C12 H20 O2 N1 ' _chemical_compound_source ; ? ; _chemical_formula_weight 210.30 _cell_measurement_reflns_used 11596 _cell_measurement_theta_min 0 _cell_measurement_theta_max 27 _cell_measurement_temperature 173 _cell_formula_units_Z 4.00 _exptl_crystal_description ' prism ' _exptl_crystal_colour ' colourless ' _exptl_crystal_size_min 0.30 _exptl_crystal_size_mid 0.30 _exptl_crystal_size_max 0.60 _exptl_crystal_density_diffrn 1.16 _exptl_crystal_density_meas ? _exptl_crystal_F_000 460.11 _exptl_absorpt_coefficient_mu 0.07 _exptl_absorpt_correction_type none _diffrn_standards_interval_time ? _diffrn_standards_interval_count ? _diffrn_standards_number 0 _diffrn_standards_decay_% 0.00 _diffrn_ambient_temperature 173 _diffrn_reflns_number 11596 _reflns_number_total 1038 _diffrn_reflns_av_R_equivalents 0.00 _reflns_number_observed 718 _diffrn_reflns_theta_min 0.00 _diffrn_reflns_theta_max 26.57 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_h_max 6 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min 0 _diffrn_reflns_limit_l_max 18 _reflns_limit_h_min 0 _reflns_limit_h_max 6 _reflns_limit_k_min 0 _reflns_limit_k_max 15 _reflns_limit_l_min 0 _reflns_limit_l_max 18 _reflns_observed_criterion >8.00\s(I) _refine_diff_density_min -0.21 _refine_diff_density_max 0.29 _refine_ls_number_reflns 718 _refine_ls_number_parameters 137 _refine_ls_R_factor_obs 0.0638 _refine_ls_wR_factor_obs 0.0626 _refine_ls_goodness_of_fit_obs 1.0016 _refine_ls_shift/esd_max 0.316998 _refine_ls_structure_factor_coef F _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71069 _diffrn_measurement_method \wA loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z # Uequiv = arithmetic mean of Ui # i.e. Ueqiv = (U1+U2+U3)/3 _atom_site_U_iso_or_equiv _atom_site_occupancy _atom_site_thermal_displace_type O1 0.8566(9) 0.1426(3) 0.6034(3) 0.0422 1.0000 Uani C2 1.024(1) 0.0956(4) 0.6288(4) 0.0316 1.0000 Uani C3 1.118(1) 0.1180(5) 0.7190(4) 0.0397 1.0000 Uani C4 1.237(2) 0.2191(6) 0.7199(4) 0.0595 1.0000 Uani C5 0.919(2) 0.1153(6) 0.7830(4) 0.0546 1.0000 Uani C6 1.135(1) 0.0163(4) 0.5727(4) 0.0295 1.0000 Uani N7 0.994(1) -0.0058(3) 0.4957(3) 0.0321 1.0000 Uani C8 1.015(2) 0.0688(5) 0.4263(4) 0.0407 1.0000 Uani C9 1.258(1) 0.0993(5) 0.4047(4) 0.0388 1.0000 Uani C10 1.382(1) 0.1319(4) 0.4857(4) 0.0413 1.0000 Uani C11 1.384(1) 0.0480(5) 0.5533(4) 0.0394 1.0000 Uani O12 1.5162(9) -0.0341(3) 0.5230(3) 0.0429 1.0000 Uani C13 1.043(1) -0.1071(4) 0.4707(4) 0.0429 1.0000 Uani C14 1.056(2) -0.1625(5) 0.5547(5) 0.0655 1.0000 Uani C15 1.129(1) -0.0864(5) 0.6211(4) 0.0427 1.0000 Uani H31 1.2332 0.0659 0.7356 0.0373 1.0000 Uiso H41 1.2988 0.2333 0.7786 0.0572 1.0000 Uiso H42 1.3675 0.2187 0.6770 0.0572 1.0000 Uiso H43 1.1248 0.2726 0.7029 0.0572 1.0000 Uiso H51 0.9782 0.1300 0.8421 0.0512 1.0000 Uiso H52 0.8453 0.0478 0.7822 0.0512 1.0000 Uiso H53 0.8021 0.1669 0.7662 0.0512 1.0000 Uiso H81 0.9281 0.1304 0.4442 0.0427 1.0000 Uiso H82 0.9423 0.0410 0.3725 0.0427 1.0000 Uiso H91 1.3392 0.0411 0.3786 0.0367 1.0000 Uiso H92 1.2537 0.1557 0.3625 0.0367 1.0000 Uiso H101 1.5432 0.1499 0.4702 0.0429 1.0000 Uiso H102 1.3013 0.1915 0.5101 0.0429 1.0000 Uiso H111 1.4570 0.0730 0.6075 0.0390 1.0000 Uiso H131 1.1946 -0.1105 0.4396 0.0419 1.0000 Uiso H132 0.9194 -0.1345 0.4336 0.0419 1.0000 Uiso H141 1.1741 -0.2174 0.5508 0.0609 1.0000 Uiso H142 0.9038 -0.1917 0.5695 0.0609 1.0000 Uiso H151 1.2834 -0.1043 0.6451 0.0416 1.0000 Uiso H152 1.0133 -0.0850 0.6693 0.0416 1.0000 Uiso loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O1 0.038(4) 0.046(3) 0.043(2) -0.004(2) -0.002(2) 0.009(2) C2 0.019(5) 0.033(3) 0.043(3) 0.014(3) 0.002(3) 0.000(3) C3 0.046(5) 0.040(4) 0.033(3) 0.002(3) -0.004(3) 0.013(3) C4 0.062(7) 0.064(5) 0.052(4) -0.005(4) -0.016(4) 0.010(5) C5 0.060(7) 0.067(5) 0.037(4) 0.004(3) 0.006(4) 0.011(4) C6 0.027(5) 0.029(3) 0.033(3) 0.002(2) 0.003(3) -0.002(3) N7 0.028(3) 0.032(3) 0.037(3) 0.001(2) 0.002(2) -0.012(3) C8 0.035(5) 0.050(4) 0.037(3) -0.002(3) -0.010(4) 0.002(4) C9 0.037(5) 0.044(4) 0.036(3) 0.004(3) 0.009(3) -0.000(3) C10 0.040(5) 0.033(3) 0.051(4) -0.002(3) 0.011(3) -0.005(3) C11 0.038(6) 0.039(4) 0.041(4) 0.001(3) 0.003(3) -0.001(3) O12 0.032(3) 0.041(2) 0.056(3) 0.001(2) 0.002(3) 0.006(2) C13 0.044(7) 0.033(4) 0.052(3) -0.018(3) 0.006(4) -0.008(3) C14 0.086(9) 0.041(4) 0.069(5) 0.017(4) 0.002(5) 0.005(4) C15 0.038(5) 0.047(4) 0.043(3) 0.012(3) -0.002(4) 0.000(3) _refine_ls_extinction_method 'None' loop_ _geom_bond_atom_site_label_1 _geom_bond_site_symmetry_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag O1 . C2 . 1.222(8) yes C2 . C3 . 1.529(9) yes C2 . C6 . 1.517(9) yes C3 . C4 . 1.52(1) yes C3 . C5 . 1.52(1) yes C3 . H31 . 1.001(7) no C4 . H41 . 0.994(7) no C4 . H42 . 1.005(9) no C4 . H43 . 1.004(8) no C5 . H51 . 0.996(7) no C5 . H52 . 1.002(8) no C5 . H53 . 1.003(8) no C6 . N7 . 1.476(8) yes C6 . C11 . 1.54(1) yes C6 . C15 . 1.567(8) yes N7 . C8 . 1.472(7) yes N7 . C13 . 1.440(7) yes C8 . C9 . 1.50(1) yes C8 . H81 . 1.006(7) no C8 . H82 . 1.005(6) no C9 . C10 . 1.510(9) yes C9 . H91 . 0.998(7) no C9 . H92 . 0.999(6) no C10 . C11 . 1.536(8) yes C10 . H101 . 0.997(8) no C10 . H102 . 1.000(6) no C11 . O12 . 1.421(8) yes C11 . H111 . 0.996(6) no C13 . C14 . 1.498(9) yes C13 . H131 . 1.005(8) no C13 . H132 . 0.990(7) no C14 . C15 . 1.51(1) yes C14 . H141 . 1.005(9) no C14 . H142 . 1.00(1) no C15 . H151 . 1.002(8) no C15 . H152 . 1.003(7) no loop_ _geom_angle_atom_site_label_1 _geom_angle_site_symmetry_1 _geom_angle_atom_site_label_2 _geom_angle_site_symmetry_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag O1 . C2 . C3 . 118.4(6) yes O1 . C2 . C6 . 121.1(5) yes C3 . C2 . C6 . 120.5(6) yes C2 . C3 . C4 . 110.3(5) yes C2 . C3 . C5 . 108.6(7) yes C4 . C3 . C5 . 111.1(6) yes C2 . C3 . H31 . 109.7(5) no C4 . C3 . H31 . 108.2(8) no C5 . C3 . H31 . 108.9(5) no C3 . C4 . H41 . 110.0(7) no C3 . C4 . H42 . 109.3(6) no H41 . C4 . H42 . 109.5(9) no C3 . C4 . H43 . 109.5(8) no H41 . C4 . H43 . 109.7(7) no H42 . C4 . H43 . 108.7(7) no C3 . C5 . H51 . 109.5(8) no C3 . C5 . H52 . 109.8(6) no H51 . C5 . H52 . 109.7(6) no C3 . C5 . H53 . 109.3(5) no H51 . C5 . H53 . 109.5(7) no H52 . C5 . H53 . 109.1(8) no C2 . C6 . N7 . 111.4(6) yes C2 . C6 . C11 . 108.6(5) yes N7 . C6 . C11 . 114.9(5) yes C2 . C6 . C15 . 109.3(5) yes N7 . C6 . C15 . 101.3(5) yes C11 . C6 . C15 . 111.0(6) yes C6 . N7 . C8 . 114.0(5) yes C6 . N7 . C13 . 107.2(5) yes C8 . N7 . C13 . 115.3(5) yes N7 . C8 . C9 . 115.2(6) yes N7 . C8 . H81 . 108.3(6) no C9 . C8 . H81 . 108.0(6) no N7 . C8 . H82 . 108.6(6) no C9 . C8 . H82 . 108.1(6) no H81 . C8 . H82 . 108.6(7) no C8 . C9 . C10 . 109.9(5) yes C8 . C9 . H91 . 108.8(6) no C10 . C9 . H91 . 109.6(7) no C8 . C9 . H92 . 109.2(7) no C10 . C9 . H92 . 109.6(6) no H91 . C9 . H92 . 109.7(5) no C9 . C10 . C11 . 111.0(5) yes C9 . C10 . H101 . 108.6(6) no C11 . C10 . H101 . 109.3(6) no C9 . C10 . H102 . 108.8(7) no C11 . C10 . H102 . 109.3(5) no H101 . C10 . H102 . 109.7(6) no C6 . C11 . C10 . 109.0(6) yes C6 . C11 . O12 . 111.0(6) yes C10 . C11 . O12 . 110.3(5) yes C6 . C11 . H111 . 109.1(6) no C10 . C11 . H111 . 109.4(6) no O12 . C11 . H111 . 108.0(7) no N7 . C13 . C14 . 104.1(5) yes N7 . C13 . H131 . 110.2(5) no C14 . C13 . H131 . 110.4(7) no N7 . C13 . H132 . 111.2(6) no C14 . C13 . H132 . 111.0(6) no H131 . C13 . H132 . 109.9(6) no C13 . C14 . C15 . 105.7(5) yes C13 . C14 . H141 . 110.2(7) no C15 . C14 . H141 . 110.3(8) no C13 . C14 . H142 . 110.3(8) no C15 . C14 . H142 . 110.8(7) no H141 . C14 . H142 . 109.5(7) no C6 . C15 . C14 . 105.9(5) yes C6 . C15 . H151 . 111.4(6) no C14 . C15 . H151 . 110.0(6) no C6 . C15 . H152 . 110.8(6) no C14 . C15 . H152 . 109.6(7) no H151 . C15 . H152 . 109.1(6) no # data_CRYSTALS_cif # LR2060 173K DIP # _audit_creation_date 98-12-16 # _audit_creation_method CRYSTALS # NOTE Fc on scale of Fo, 1.23727 loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_meas _refln_F_calc _refln_F_sigma 1 1 0 85.81 91.61 2.09 1 2 0 19.75 20.39 0.81 2 2 0 74.33 75.26 1.01 1 3 0 5.48 3.95 0.24 3 3 0 8.08 8.28 0.44 0 4 0 81.27 85.46 0.84 1 4 0 41.26 38.84 0.48 2 4 0 2.93 2.56 0.39 3 4 0 34.38 34.58 1.24 1 5 0 14.80 14.36 0.46 2 5 0 16.52 16.91 0.41 3 5 0 11.48 13.14 0.39 4 5 0 3.70 2.14 0.35 1 6 0 6.32 3.71 0.38 2 6 0 8.20 8.75 0.41 3 6 0 19.72 21.71 0.66 4 6 0 9.43 10.35 0.29 1 7 0 24.71 25.04 1.29 2 7 0 2.55 0.53 0.59 4 7 0 5.54 5.68 0.38 0 8 0 35.46 38.11 0.58 1 8 0 7.13 7.17 0.28 2 8 0 4.77 3.77 0.40 3 8 0 9.87 9.94 0.50 4 8 0 8.07 8.30 0.29 1 9 0 16.76 18.39 0.32 2 9 0 9.49 11.26 0.53 3 9 0 6.43 6.03 0.41 4 9 0 7.20 7.59 0.39 0 10 0 9.74 10.53 0.53 1 10 0 11.93 12.11 0.51 2 10 0 5.05 3.89 0.48 3 10 0 9.26 9.04 0.31 4 10 0 12.51 12.98 0.50 1 11 0 7.17 5.12 0.41 2 11 0 8.29 8.08 0.62 3 11 0 5.44 1.78 0.48 4 11 0 5.59 7.40 0.51 0 12 0 5.66 4.68 0.63 1 12 0 6.58 3.70 0.45 2 12 0 7.50 5.30 0.72 3 12 0 6.33 3.54 0.57 4 12 0 7.21 8.57 0.58 1 13 0 5.37 2.69 0.63 2 13 0 8.97 7.96 0.46 3 13 0 6.43 2.08 0.49 1 14 0 6.14 0.95 0.89 2 14 0 7.52 3.98 0.78 3 14 0 6.99 3.97 0.85 1 15 0 7.85 4.14 0.59 2 15 0 6.78 0.63 0.52 0 1 1 36.87 35.64 1.14 1 1 1 63.80 66.48 1.19 0 2 1 63.90 63.24 1.44 1 2 1 12.67 14.23 0.48 0 3 1 34.58 38.05 1.27 1 3 1 48.40 47.92 0.95 2 3 1 17.67 17.92 0.76 3 3 1 11.68 10.62 0.22 0 4 1 16.09 15.64 0.35 1 4 1 54.26 55.88 0.63 2 4 1 22.60 22.44 0.37 3 4 1 15.26 14.96 0.65 4 4 1 13.57 14.87 0.74 0 5 1 5.79 6.34 0.29 1 5 1 28.72 30.14 0.61 2 5 1 3.42 4.89 0.26 3 5 1 9.12 10.22 0.20 4 5 1 3.55 1.10 0.54 1 6 1 16.35 17.57 0.44 2 6 1 27.05 27.71 0.45 3 6 1 13.33 13.96 0.26 4 6 1 8.28 7.49 0.42 0 7 1 11.78 11.69 0.74 1 7 1 13.00 12.98 0.39 2 7 1 11.15 13.01 0.38 3 7 1 6.63 7.17 0.20 4 7 1 19.81 20.66 0.47 0 8 1 4.04 4.72 0.35 1 8 1 16.30 18.85 0.41 2 8 1 8.37 9.86 0.23 3 8 1 9.42 9.66 0.21 4 8 1 11.38 10.84 0.20 5 8 1 7.87 8.05 0.34 0 9 1 3.71 5.11 0.78 1 9 1 17.95 19.28 0.43 2 9 1 18.25 18.58 0.21 3 9 1 7.48 5.82 0.21 4 9 1 26.69 29.04 0.24 5 9 1 5.73 4.79 0.43 0 10 1 23.08 24.17 0.39 1 10 1 12.55 12.78 0.22 2 10 1 19.07 19.34 0.30 3 10 1 9.32 8.70 0.26 4 10 1 6.46 5.63 0.24 5 10 1 5.18 5.27 0.45 0 11 1 6.99 6.71 0.69 1 11 1 26.84 28.83 0.39 2 11 1 15.12 15.90 0.24 3 11 1 11.58 11.91 0.25 4 11 1 8.22 9.56 0.33 0 12 1 5.58 2.42 0.54 1 12 1 7.87 6.42 0.29 2 12 1 16.40 16.34 0.28 3 12 1 6.20 2.46 0.42 4 12 1 5.70 1.43 0.55 0 13 1 14.30 14.07 0.41 1 13 1 17.24 17.32 0.32 2 13 1 8.99 8.78 0.34 3 13 1 7.69 6.17 0.31 0 14 1 7.38 3.68 0.86 1 14 1 7.06 2.46 0.44 2 14 1 7.74 6.24 0.39 3 14 1 7.14 7.09 0.45 0 15 1 4.24 1.88 0.48 1 15 1 6.27 1.26 0.51 2 15 1 6.58 1.74 0.46 0 0 2 142.25 136.55 1.15 1 0 2 19.42 19.40 0.68 0 1 2 69.35 62.06 1.31 1 1 2 32.02 34.21 0.80 2 1 2 37.91 38.32 1.66 0 2 2 113.52 107.43 1.17 1 2 2 70.58 71.60 0.69 2 2 2 39.42 38.70 0.65 0 3 2 9.58 11.14 0.53 1 3 2 4.09 7.55 0.34 2 3 2 26.80 26.32 0.43 3 3 2 8.32 9.24 0.18 0 4 2 13.50 13.44 0.45 1 4 2 38.17 37.19 0.76 2 4 2 31.56 33.06 0.62 3 4 2 20.49 20.33 0.39 0 5 2 15.01 15.22 0.77 1 5 2 22.65 22.38 0.37 2 5 2 16.89 16.77 0.27 3 5 2 15.07 15.93 0.26 4 5 2 6.73 6.36 0.45 0 6 2 45.64 43.61 0.66 1 6 2 46.75 47.46 0.58 2 6 2 11.88 13.80 0.28 3 6 2 15.60 15.80 0.36 4 6 2 10.76 10.07 0.27 0 7 2 8.11 8.99 0.39 1 7 2 12.58 13.44 0.33 2 7 2 5.26 4.58 0.28 3 7 2 7.27 7.46 0.29 4 7 2 5.80 5.52 0.27 0 8 2 7.09 6.33 0.33 1 8 2 13.28 13.80 0.26 2 8 2 7.18 6.75 0.20 3 8 2 5.01 3.79 0.31 4 8 2 7.14 6.92 0.26 0 9 2 2.83 0.00 1.01 1 9 2 14.37 14.35 0.32 2 9 2 10.10 10.47 0.26 3 9 2 13.28 14.29 0.19 4 9 2 5.27 4.58 0.37 5 9 2 5.34 3.95 0.44 0 10 2 8.38 5.79 0.60 1 10 2 7.85 8.37 0.29 2 10 2 10.45 10.08 0.26 3 10 2 8.56 8.03 0.26 4 10 2 10.11 9.67 0.59 5 10 2 7.06 6.89 0.38 0 11 2 5.03 2.39 0.50 1 11 2 15.47 15.04 0.30 2 11 2 9.84 9.34 0.35 3 11 2 8.12 6.98 0.32 4 11 2 6.20 3.53 0.39 0 12 2 7.17 5.39 0.52 1 12 2 6.13 5.07 0.31 2 12 2 13.27 13.64 0.29 3 12 2 7.98 7.05 0.49 4 12 2 6.58 4.89 0.43 0 13 2 7.20 6.33 0.49 1 13 2 7.78 6.87 0.42 2 13 2 8.44 7.22 0.41 3 13 2 7.40 6.90 0.45 1 14 2 7.14 4.55 0.43 2 14 2 6.83 1.47 0.32 3 14 2 8.47 9.50 0.25 0 15 2 7.54 4.05 0.56 1 15 2 6.86 2.07 0.44 2 15 2 10.63 9.55 0.74 1 0 3 21.53 20.13 0.42 0 1 3 33.75 34.17 1.66 1 1 3 64.24 61.94 1.00 2 1 3 9.84 9.68 0.39 3 1 3 14.16 14.86 1.05 0 2 3 69.10 66.41 1.24 1 2 3 35.17 35.13 0.96 2 2 3 6.43 8.18 0.30 3 2 3 19.64 19.19 0.40 0 3 3 5.24 4.06 0.23 1 3 3 8.38 9.46 0.15 2 3 3 31.85 31.18 0.28 3 3 3 15.39 15.10 0.34 0 4 3 3.02 3.18 0.50 1 4 3 10.98 10.11 0.36 2 4 3 19.24 18.28 0.23 3 4 3 3.46 2.51 0.39 0 5 3 13.99 12.83 0.29 1 5 3 31.24 30.66 0.42 2 5 3 16.96 17.09 0.21 3 5 3 20.72 21.70 0.49 4 5 3 12.55 13.63 0.49 1 6 3 27.43 27.62 1.00 2 6 3 15.94 15.22 0.38 3 6 3 13.42 13.44 0.34 4 6 3 17.03 17.54 0.27 1 7 3 26.52 27.56 0.80 2 7 3 9.50 10.48 0.31 3 7 3 14.13 14.71 0.22 4 7 3 7.97 7.49 0.26 0 8 3 21.08 22.65 0.47 1 8 3 12.82 12.82 0.33 2 8 3 25.69 25.67 0.33 3 8 3 7.87 8.33 0.23 4 8 3 13.71 14.94 0.26 5 8 3 6.40 6.11 0.41 0 9 3 8.60 7.42 0.36 1 9 3 13.00 13.60 0.30 2 9 3 9.69 8.99 0.19 3 9 3 8.64 8.19 0.30 4 9 3 6.00 3.04 0.47 5 9 3 5.55 4.23 0.59 0 10 3 7.52 5.44 0.35 1 10 3 5.07 1.79 0.39 2 10 3 6.29 3.13 0.39 3 10 3 5.84 3.03 0.33 4 10 3 5.97 4.44 0.29 5 10 3 4.80 2.92 0.69 0 11 3 12.73 12.50 0.32 1 11 3 14.53 15.14 0.21 2 11 3 16.24 16.07 0.31 3 11 3 11.46 11.52 0.33 4 11 3 8.23 7.96 0.26 0 12 3 5.50 0.68 0.64 1 12 3 14.33 14.65 0.23 2 12 3 9.33 8.26 0.33 3 12 3 8.25 7.14 0.41 4 12 3 7.32 4.68 0.51 0 13 3 11.72 12.19 0.46 1 13 3 9.75 8.95 0.40 2 13 3 10.18 12.06 0.69 3 13 3 8.23 7.22 0.53 0 14 3 7.21 0.37 0.52 1 14 3 7.07 4.58 0.53 2 14 3 7.06 4.37 0.43 0 15 3 5.50 2.95 0.66 1 15 3 7.25 4.64 0.59 0 0 4 47.32 44.09 2.84 1 0 4 38.34 36.59 0.98 2 0 4 37.92 37.54 0.77 4 0 4 13.26 12.72 0.44 0 1 4 21.32 21.06 0.90 1 1 4 8.23 7.79 0.24 2 1 4 7.08 7.10 0.18 3 1 4 2.95 4.24 0.32 4 1 4 24.74 25.07 0.47 0 2 4 5.43 4.42 0.32 1 2 4 33.74 33.87 0.39 2 2 4 52.35 52.07 0.73 4 2 4 13.30 12.54 0.21 0 3 4 24.34 24.49 1.11 1 3 4 35.33 32.99 0.57 2 3 4 6.86 6.87 0.17 3 3 4 16.18 17.07 0.48 0 4 4 47.25 44.58 0.60 1 4 4 39.42 38.98 0.49 2 4 4 5.68 5.55 0.21 3 4 4 18.87 18.57 0.31 4 4 4 24.38 25.06 0.32 0 5 4 52.39 49.96 2.56 1 5 4 13.84 15.03 0.31 2 5 4 11.36 12.35 0.18 3 5 4 14.12 13.86 0.35 5 5 4 7.80 6.46 0.28 0 6 4 33.29 32.28 0.55 1 6 4 28.02 27.95 0.38 2 6 4 21.95 22.65 0.55 3 6 4 6.69 6.41 0.22 4 6 4 15.68 16.03 0.45 5 6 4 10.42 9.57 0.26 0 7 4 25.31 25.09 0.34 1 7 4 14.55 15.62 0.18 2 7 4 4.05 4.09 0.27 3 7 4 14.47 14.32 0.22 4 7 4 8.82 8.55 0.28 5 7 4 9.40 8.27 0.40 0 8 4 21.26 21.17 0.41 1 8 4 11.33 11.53 0.20 2 8 4 18.51 19.53 0.24 3 8 4 24.61 24.33 0.24 4 8 4 6.09 5.17 0.41 5 8 4 10.66 11.08 0.33 0 9 4 23.28 23.16 0.54 1 9 4 13.46 14.31 0.38 2 9 4 5.39 4.67 0.37 3 9 4 5.00 1.50 0.44 4 9 4 5.40 2.83 0.37 5 9 4 4.98 2.14 0.75 0 10 4 4.99 1.03 0.79 1 10 4 7.54 6.53 0.45 2 10 4 6.15 4.54 0.33 3 10 4 10.45 9.64 0.22 4 10 4 6.24 1.51 0.40 5 10 4 7.50 7.93 0.32 0 11 4 9.02 7.17 0.65 1 11 4 23.61 23.97 0.29 2 11 4 9.11 8.59 0.31 3 11 4 9.24 8.01 0.31 4 11 4 7.06 6.16 0.32 0 12 4 16.00 17.09 0.38 1 12 4 6.40 4.92 0.56 2 12 4 8.73 7.70 0.33 3 12 4 10.27 9.57 0.32 4 12 4 6.38 4.53 0.36 0 13 4 6.86 0.62 0.65 1 13 4 6.52 5.60 0.38 2 13 4 6.78 3.13 0.38 3 13 4 7.29 4.60 0.48 0 14 4 7.20 1.96 0.52 1 14 4 6.64 2.64 0.45 2 14 4 8.04 6.52 0.50 0 15 4 5.66 3.25 0.98 1 15 4 6.80 7.03 0.42 1 0 5 38.29 35.81 0.48 2 0 5 22.66 21.71 0.32 1 1 5 49.46 46.59 0.54 2 1 5 15.54 16.61 0.28 3 1 5 11.85 12.78 0.55 0 2 5 9.15 9.18 0.27 1 2 5 60.75 57.80 0.56 2 2 5 28.27 27.10 0.34 3 2 5 30.47 29.80 0.36 0 3 5 71.96 69.70 0.70 1 3 5 28.60 27.28 0.39 2 3 5 17.56 17.31 0.50 3 3 5 11.59 12.78 0.59 4 3 5 25.76 26.30 0.39 1 4 5 19.57 19.29 0.28 2 4 5 23.51 22.13 0.35 3 4 5 4.37 4.79 0.35 4 4 5 22.63 23.02 0.48 0 5 5 17.60 16.52 0.27 1 5 5 25.75 26.24 0.36 2 5 5 29.24 29.61 0.41 3 5 5 13.80 13.94 0.31 4 5 5 11.91 11.89 0.33 5 5 5 5.10 5.03 0.49 0 6 5 2.97 2.99 0.51 1 6 5 33.53 33.67 0.52 2 6 5 17.15 15.54 0.35 3 6 5 21.97 22.64 0.37 4 6 5 10.27 9.09 0.26 0 7 5 10.55 12.16 0.51 1 7 5 4.29 4.56 0.27 2 7 5 22.70 22.79 0.29 3 7 5 21.29 21.56 0.29 4 7 5 10.96 11.10 0.27 5 7 5 9.50 9.41 0.36 0 8 5 12.52 12.62 0.24 1 8 5 11.40 11.12 0.19 2 8 5 10.07 9.75 0.25 3 8 5 8.38 7.79 0.27 4 8 5 5.75 3.94 0.32 5 8 5 7.69 7.74 0.31 0 9 5 10.58 11.71 0.33 1 9 5 12.42 12.74 0.23 2 9 5 7.57 6.42 0.26 3 9 5 10.66 10.50 0.22 4 9 5 9.13 8.91 0.24 5 9 5 6.97 6.97 0.32 0 10 5 9.77 10.14 0.30 1 10 5 9.22 8.62 0.25 2 10 5 7.84 6.67 0.40 3 10 5 9.43 9.20 0.28 4 10 5 6.38 2.06 0.32 0 11 5 5.22 6.55 0.64 1 11 5 11.60 12.16 0.44 2 11 5 6.50 5.54 0.38 3 11 5 7.80 6.89 0.28 4 11 5 7.11 5.54 0.37 0 12 5 6.86 5.27 0.56 1 12 5 10.99 10.76 0.31 2 12 5 8.83 9.17 0.40 3 12 5 6.08 1.68 0.52 4 12 5 6.47 5.14 0.34 0 13 5 9.26 11.40 0.61 1 13 5 6.35 0.60 0.70 2 13 5 7.66 2.95 0.59 3 13 5 7.54 7.46 0.55 0 14 5 6.89 2.61 0.52 1 14 5 7.26 6.64 0.43 2 14 5 7.69 5.57 0.62 0 15 5 6.89 5.27 0.61 0 0 6 39.43 40.43 0.58 1 0 6 50.58 49.70 1.32 2 0 6 37.95 38.42 0.45 3 0 6 2.12 0.00 0.66 4 0 6 17.70 17.80 0.33 5 0 6 8.41 7.00 0.37 0 1 6 8.85 11.42 0.25 1 1 6 19.33 17.91 0.28 2 1 6 14.08 12.90 0.32 3 1 6 3.62 3.31 0.29 4 1 6 3.85 3.22 0.35 0 2 6 6.13 7.85 0.91 1 2 6 28.47 28.17 0.38 2 2 6 40.74 41.38 0.50 3 2 6 10.27 10.29 0.30 4 2 6 18.24 17.45 0.32 5 2 6 9.31 9.41 0.35 0 3 6 36.48 34.01 0.51 1 3 6 27.20 25.92 0.36 2 3 6 13.34 14.39 0.27 3 3 6 19.32 19.66 0.56 4 3 6 11.31 12.14 0.23 5 3 6 10.03 7.60 0.38 0 4 6 28.03 27.93 1.15 1 4 6 2.51 0.00 0.72 2 4 6 11.56 11.44 0.29 3 4 6 9.85 10.70 0.21 4 4 6 14.13 13.40 0.25 0 5 6 57.90 57.70 1.09 1 5 6 14.42 13.96 0.23 2 5 6 21.01 21.72 0.25 3 5 6 13.95 14.78 0.26 0 6 6 14.97 15.72 0.24 1 6 6 16.82 17.06 0.18 2 6 6 32.26 32.17 0.47 3 6 6 14.49 14.02 0.19 4 6 6 19.24 19.10 0.25 0 7 6 6.74 5.08 0.38 1 7 6 11.88 12.85 0.25 2 7 6 11.36 12.32 0.20 3 7 6 13.96 14.27 0.24 4 7 6 5.68 3.43 0.32 1 8 6 6.75 6.61 0.60 2 8 6 19.10 20.59 0.24 3 8 6 12.50 13.22 0.36 4 8 6 11.57 12.17 0.36 5 8 6 5.55 4.24 0.41 0 9 6 15.73 15.36 0.41 1 9 6 9.15 8.67 0.23 2 9 6 18.85 18.50 0.25 3 9 6 13.56 13.82 0.44 4 9 6 5.50 2.34 0.35 5 9 6 6.40 6.22 0.35 0 10 6 7.01 5.86 0.39 1 10 6 8.31 7.77 0.24 2 10 6 15.24 15.54 0.23 3 10 6 13.63 14.08 0.40 4 10 6 5.94 3.25 0.45 0 11 6 12.66 12.40 0.29 1 11 6 15.30 15.11 0.27 2 11 6 12.47 13.52 0.33 3 11 6 5.76 2.39 0.50 4 11 6 6.35 5.00 0.45 1 12 6 8.14 6.35 0.44 2 12 6 6.93 3.14 0.47 3 12 6 6.57 2.66 0.50 0 13 6 7.53 5.53 0.56 1 13 6 6.68 2.53 0.40 2 13 6 6.18 2.65 0.47 3 13 6 6.12 4.38 0.43 1 14 6 6.59 0.38 0.56 2 14 6 5.52 3.13 0.48 1 0 7 51.80 50.93 0.54 2 0 7 28.83 26.60 0.36 3 0 7 4.90 5.25 0.28 5 0 7 7.05 4.42 0.46 0 1 7 7.18 9.17 0.24 1 1 7 19.33 19.53 0.37 2 1 7 12.22 12.37 0.29 3 1 7 10.42 10.87 0.20 4 1 7 4.74 3.14 0.28 0 2 7 20.23 19.42 0.48 1 2 7 36.41 36.28 0.33 2 2 7 11.75 11.61 0.19 3 2 7 10.26 10.77 0.18 4 2 7 5.25 5.89 0.27 0 3 7 21.79 21.74 0.33 1 3 7 30.89 30.56 0.27 2 3 7 19.83 18.83 0.45 3 3 7 3.83 4.37 0.35 4 3 7 5.73 6.28 0.25 0 4 7 23.48 24.49 0.36 1 4 7 18.34 18.33 0.22 2 4 7 12.92 13.20 0.21 3 4 7 16.34 17.05 0.24 4 4 7 13.60 13.15 0.51 6 4 7 6.42 5.45 0.42 0 5 7 42.88 42.91 1.60 1 5 7 3.78 4.34 0.44 2 5 7 12.30 14.80 0.81 3 5 7 9.28 10.06 0.23 4 5 7 8.89 8.64 0.35 5 5 7 5.17 2.92 0.52 0 6 7 3.46 2.05 0.84 1 6 7 10.47 11.91 0.52 2 6 7 11.14 12.05 0.25 3 6 7 4.20 2.75 0.35 4 6 7 18.73 17.82 0.21 5 6 7 5.46 2.79 0.58 0 7 7 9.36 10.68 0.26 1 7 7 6.43 6.50 0.23 2 7 7 24.42 25.74 0.34 3 7 7 20.23 20.21 0.26 4 7 7 4.82 1.02 0.35 5 7 7 12.22 12.97 0.29 0 8 7 24.39 25.70 0.32 1 8 7 11.38 10.81 0.31 2 8 7 16.88 17.97 0.26 3 8 7 5.33 3.46 0.28 4 8 7 5.16 1.85 0.53 5 8 7 7.10 4.52 0.56 0 9 7 5.65 3.55 0.42 1 9 7 12.99 13.06 0.28 2 9 7 6.61 6.67 0.31 3 9 7 19.35 20.77 0.27 4 9 7 6.38 3.72 0.33 0 10 7 9.44 8.52 0.60 1 10 7 8.26 8.33 0.49 2 10 7 6.28 4.36 0.45 3 10 7 7.64 6.43 0.30 4 10 7 6.24 4.08 0.46 0 11 7 8.76 8.40 0.52 1 11 7 11.98 11.47 0.37 2 11 7 8.47 7.32 0.32 3 11 7 7.42 5.74 0.37 4 11 7 5.41 0.98 0.42 0 12 7 9.06 7.96 0.73 1 12 7 8.44 7.15 0.52 2 12 7 7.28 5.09 0.57 3 12 7 6.80 4.78 0.42 0 13 7 6.38 1.60 0.96 1 13 7 6.66 2.42 0.47 2 13 7 6.86 4.54 0.42 0 14 7 6.88 0.89 0.89 1 14 7 7.03 5.27 0.38 0 0 8 23.90 22.57 0.51 1 0 8 9.98 7.89 0.49 2 0 8 6.89 7.47 0.33 3 0 8 13.63 14.53 0.54 4 0 8 8.25 9.68 0.44 5 0 8 4.67 0.91 0.57 6 0 8 7.69 5.92 0.49 0 1 8 1.95 0.00 0.56 1 1 8 6.42 6.10 0.30 2 1 8 10.71 11.35 0.24 3 1 8 16.91 17.18 0.28 4 1 8 19.01 18.40 0.38 5 1 8 5.74 3.73 0.58 0 2 8 12.19 11.95 0.27 1 2 8 7.28 7.85 0.27 2 2 8 17.33 16.82 0.25 3 2 8 12.87 12.70 0.21 4 2 8 15.54 14.79 0.30 5 2 8 7.32 5.87 0.48 0 3 8 30.85 29.57 0.59 1 3 8 23.25 23.44 0.25 2 3 8 10.64 11.22 0.23 3 3 8 19.69 19.65 0.23 4 3 8 6.19 5.13 0.27 5 3 8 7.01 5.98 0.52 0 4 8 12.29 13.57 0.59 1 4 8 10.58 10.65 0.20 2 4 8 16.29 16.04 0.25 3 4 8 17.36 17.76 0.20 4 4 8 18.24 18.62 0.19 5 4 8 4.66 2.16 0.57 0 5 8 1.64 0.00 0.88 1 5 8 18.94 18.50 0.25 2 5 8 14.82 15.28 0.21 3 5 8 14.17 14.44 0.18 4 5 8 10.05 9.63 0.33 5 5 8 6.72 5.45 0.30 0 6 8 2.66 2.46 0.49 1 6 8 2.77 2.39 0.41 2 6 8 11.66 12.61 0.24 3 6 8 9.31 8.88 0.21 4 6 8 8.90 9.01 0.29 5 6 8 6.77 6.13 0.39 0 7 8 20.72 20.85 0.56 1 7 8 9.15 9.33 0.39 2 7 8 6.83 4.26 0.42 3 7 8 4.54 4.36 0.43 4 7 8 9.46 9.17 0.26 5 7 8 7.36 5.85 0.24 0 8 8 14.60 15.59 0.38 1 8 8 8.52 7.61 0.24 2 8 8 13.04 13.10 0.27 3 8 8 13.18 13.58 0.26 4 8 8 8.46 7.76 0.24 5 8 8 6.07 4.98 0.35 0 9 8 15.16 15.24 0.95 1 9 8 5.79 3.97 0.52 2 9 8 9.54 9.43 0.35 3 9 8 10.75 10.94 0.26 4 9 8 6.07 1.44 0.39 0 10 8 12.19 12.75 0.66 1 10 8 7.18 5.52 0.33 2 10 8 10.62 11.87 0.36 3 10 8 9.95 10.84 0.32 4 10 8 7.04 6.80 0.38 0 11 8 8.15 5.32 0.44 1 11 8 9.06 8.03 0.31 2 11 8 11.49 11.40 0.31 3 11 8 6.97 5.36 0.47 0 12 8 6.55 2.70 0.87 1 12 8 7.50 5.65 0.42 2 12 8 8.18 7.00 0.46 3 12 8 7.38 7.91 0.33 0 13 8 7.85 6.30 0.96 1 13 8 5.62 3.03 0.53 2 13 8 6.75 1.02 0.49 0 14 8 5.20 2.38 0.69 1 0 9 12.04 13.19 0.44 2 0 9 4.94 6.00 0.31 3 0 9 4.45 0.58 0.43 4 0 9 5.67 4.87 0.39 0 1 9 29.23 30.82 1.83 1 1 9 7.73 8.88 0.34 2 1 9 8.86 10.31 0.24 3 1 9 5.43 5.61 0.26 4 1 9 6.06 5.85 0.40 5 1 9 6.61 6.73 0.51 0 2 9 2.05 0.00 0.76 1 2 9 16.23 16.67 0.19 2 2 9 9.70 9.87 0.23 3 2 9 3.99 1.39 0.34 4 2 9 18.43 18.48 0.27 5 2 9 12.40 12.07 0.36 1 3 9 12.15 12.15 0.23 2 3 9 10.31 10.80 0.34 3 3 9 14.01 15.16 0.21 4 3 9 5.42 5.73 0.30 0 4 9 6.21 6.90 0.39 1 4 9 15.15 15.18 0.24 2 4 9 3.92 2.61 0.32 3 4 9 6.89 6.22 0.25 4 4 9 9.08 9.01 0.20 5 4 9 6.26 3.91 0.63 0 5 9 32.33 33.05 0.48 1 5 9 4.09 3.28 0.32 2 5 9 9.94 10.10 0.21 3 5 9 11.78 12.46 0.23 4 5 9 13.10 13.21 0.26 5 5 9 7.15 6.77 0.41 0 6 9 8.11 9.46 0.28 1 6 9 15.54 15.79 0.22 2 6 9 21.44 22.24 0.51 3 6 9 15.04 15.18 0.23 4 6 9 11.52 10.52 0.29 5 6 9 5.83 2.50 0.49 1 7 9 5.74 4.73 0.42 2 7 9 4.36 2.40 0.36 3 7 9 7.33 6.44 0.26 4 7 9 5.50 1.75 0.38 5 7 9 9.57 8.84 0.50 0 8 9 24.15 25.42 0.48 1 8 9 15.64 16.09 0.24 2 8 9 12.11 11.44 0.38 3 8 9 5.14 1.75 0.40 4 8 9 8.45 8.13 0.31 0 9 9 3.91 0.95 0.81 1 9 9 8.28 8.33 0.28 2 9 9 6.72 5.70 0.37 3 9 9 9.75 9.04 0.26 4 9 9 9.17 10.59 0.28 1 10 9 6.05 3.56 0.50 2 10 9 8.19 7.07 0.37 3 10 9 6.38 2.25 0.34 4 10 9 5.51 1.19 0.42 0 11 9 6.37 2.43 0.46 1 11 9 6.48 3.00 0.35 2 11 9 7.93 6.40 0.53 3 11 9 8.06 8.81 0.32 0 12 9 7.12 3.62 0.65 1 12 9 8.34 6.42 0.46 2 12 9 7.38 4.82 0.43 0 13 9 6.77 3.85 0.55 1 13 9 7.02 1.66 0.47 0 0 10 25.99 25.11 0.70 1 0 10 8.77 9.12 0.35 2 0 10 7.33 5.55 0.58 3 0 10 4.74 3.35 0.38 4 0 10 4.10 3.22 0.50 0 1 10 10.88 11.79 0.45 1 1 10 17.92 19.19 0.49 2 1 10 11.00 11.46 0.20 3 1 10 12.03 12.34 0.25 4 1 10 14.01 13.64 0.26 5 1 10 5.63 4.94 0.45 0 2 10 5.82 3.59 0.32 1 2 10 15.13 14.83 0.28 2 2 10 17.54 17.07 0.24 3 2 10 6.63 6.20 0.32 4 2 10 15.80 15.74 0.27 5 2 10 5.76 4.22 0.63 0 3 10 3.22 0.58 0.43 1 3 10 20.97 22.11 0.52 2 3 10 13.71 14.01 0.21 3 3 10 19.18 19.85 0.24 4 3 10 7.37 7.15 0.33 5 3 10 8.09 7.76 0.26 0 4 10 7.30 8.76 0.63 1 4 10 8.25 8.23 0.31 2 4 10 14.90 15.05 0.27 3 4 10 8.73 9.30 0.26 4 4 10 16.36 17.06 0.49 5 4 10 6.40 4.47 0.54 0 5 10 12.68 13.03 0.36 1 5 10 8.07 6.98 0.51 2 5 10 13.69 12.89 0.20 3 5 10 14.84 16.04 0.30 4 5 10 6.86 5.07 0.36 5 5 10 8.77 9.29 0.38 0 6 10 6.86 4.28 0.46 1 6 10 14.47 14.97 0.25 2 6 10 16.28 17.02 0.23 3 6 10 8.24 7.97 0.29 4 6 10 8.08 8.31 0.27 5 6 10 5.71 2.41 0.48 1 7 10 7.75 6.96 0.32 2 7 10 9.38 8.67 0.29 3 7 10 5.62 3.07 0.40 4 7 10 6.28 3.33 0.37 0 8 10 20.21 20.57 0.38 1 8 10 8.97 7.46 0.30 2 8 10 7.50 6.70 0.39 3 8 10 6.48 5.83 0.30 4 8 10 6.36 6.16 0.37 0 9 10 5.60 4.71 0.54 1 9 10 9.14 9.09 0.31 2 9 10 10.49 10.94 0.35 3 9 10 7.09 4.97 0.32 4 9 10 5.24 0.40 0.39 1 10 10 7.71 6.95 0.38 2 10 10 6.79 5.33 0.41 3 10 10 6.28 4.93 0.37 0 11 10 6.83 2.19 0.63 1 11 10 7.53 5.75 0.33 2 11 10 6.75 1.96 0.55 3 11 10 6.50 2.86 0.33 0 12 10 6.46 1.00 0.65 1 12 10 6.84 5.59 0.62 2 12 10 5.99 2.13 0.46 0 13 10 5.57 1.80 0.66 1 0 11 7.42 6.97 0.42 2 0 11 21.04 21.03 0.32 3 0 11 12.79 13.79 0.34 4 0 11 5.59 3.78 0.72 0 1 11 10.34 10.88 0.30 1 1 11 6.00 8.33 0.46 2 1 11 4.36 1.01 0.33 3 1 11 4.97 3.10 0.35 4 1 11 6.65 4.65 0.30 5 1 11 7.83 7.81 0.40 0 2 11 13.49 13.39 0.25 1 2 11 8.01 7.70 0.28 2 2 11 12.64 12.78 0.29 3 2 11 8.02 8.07 0.22 4 2 11 6.66 5.53 0.35 5 2 11 6.21 4.39 0.43 0 3 11 10.29 10.61 0.45 1 3 11 20.70 21.79 0.22 2 3 11 8.77 9.88 0.33 3 3 11 7.05 5.69 0.25 4 3 11 6.25 6.34 0.38 0 4 11 10.82 10.73 0.26 1 4 11 22.32 22.47 0.49 2 4 11 21.23 21.57 0.23 3 4 11 11.27 11.47 0.24 4 4 11 8.19 7.86 0.29 5 4 11 5.50 1.98 0.44 0 5 11 13.78 13.21 0.25 1 5 11 13.97 14.42 0.21 2 5 11 8.26 7.38 0.33 3 5 11 6.77 5.61 0.38 4 5 11 6.32 4.58 0.28 5 5 11 5.59 3.89 0.73 0 6 11 15.79 17.37 0.40 1 6 11 14.73 14.62 0.51 2 6 11 8.89 8.86 0.31 3 6 11 8.13 7.64 0.26 4 6 11 6.19 3.94 0.35 0 7 11 5.40 4.08 0.41 1 7 11 7.09 7.30 0.37 2 7 11 11.45 11.10 0.28 3 7 11 6.07 2.58 0.38 4 7 11 5.88 1.44 0.37 0 8 11 11.49 11.57 0.36 1 8 11 6.04 5.42 0.34 2 8 11 13.22 13.30 0.25 3 8 11 7.18 6.58 0.30 4 8 11 6.75 6.00 0.36 0 9 11 6.28 2.64 0.63 1 9 11 6.52 4.76 0.37 2 9 11 6.07 2.44 0.37 3 9 11 7.84 5.93 0.45 0 10 11 6.33 5.43 0.97 1 10 11 8.13 5.91 0.50 2 10 11 8.52 8.02 0.32 3 10 11 6.60 4.19 0.49 1 11 11 7.46 3.12 0.50 2 11 11 6.07 4.45 0.45 0 12 11 5.67 5.41 0.47 1 12 11 5.27 4.04 0.38 0 0 12 11.30 12.46 0.51 1 0 12 30.98 32.20 0.34 2 0 12 5.37 2.18 0.50 3 0 12 13.19 14.14 0.28 4 0 12 6.50 7.02 0.74 0 1 12 6.43 5.92 0.42 1 1 12 13.38 13.77 0.32 2 1 12 7.36 7.48 0.35 3 1 12 6.36 4.66 0.27 4 1 12 7.27 5.84 0.29 5 1 12 5.87 1.99 0.70 0 2 12 8.71 7.70 0.63 1 2 12 5.87 4.40 0.34 2 2 12 8.96 8.63 0.29 3 2 12 6.23 5.45 0.32 4 2 12 9.13 8.56 0.32 0 3 12 5.47 1.24 0.41 1 3 12 14.80 15.34 0.23 2 3 12 9.90 10.02 0.28 3 3 12 5.16 4.32 0.47 4 3 12 9.89 10.03 0.37 5 3 12 4.77 3.88 0.44 0 4 12 16.98 16.71 0.32 1 4 12 11.23 11.29 0.24 2 4 12 15.77 15.00 0.20 3 4 12 9.70 9.26 0.29 4 4 12 6.07 2.82 0.44 0 5 12 4.65 0.30 0.94 1 5 12 5.07 1.09 0.36 2 5 12 9.57 9.29 0.31 3 5 12 11.75 12.47 0.21 4 5 12 6.51 4.25 0.41 0 6 12 16.07 16.55 0.27 1 6 12 10.57 10.30 0.22 2 6 12 8.94 8.60 0.30 3 6 12 8.77 7.91 0.30 4 6 12 6.58 3.13 0.46 0 7 12 6.27 3.28 1.01 1 7 12 9.49 9.03 0.45 2 7 12 10.68 10.72 0.32 3 7 12 6.40 4.28 0.45 4 7 12 6.31 0.15 0.42 0 8 12 5.90 4.19 0.47 1 8 12 8.41 9.03 0.31 2 8 12 6.20 0.77 0.40 3 8 12 6.29 6.80 0.39 0 9 12 10.51 12.18 0.46 1 9 12 7.94 8.30 0.33 2 9 12 6.74 2.58 0.40 3 9 12 6.28 1.32 0.62 0 10 12 7.10 0.93 0.66 1 10 12 8.40 7.81 0.39 2 10 12 7.25 5.96 0.38 0 11 12 5.88 3.57 0.44 1 11 12 4.75 4.47 0.81 1 0 13 15.78 16.10 0.36 2 0 13 8.83 7.79 0.40 3 0 13 13.92 13.89 0.37 4 0 13 6.72 3.95 0.47 0 1 13 7.95 6.11 0.47 1 1 13 12.66 13.95 0.33 2 1 13 5.82 2.34 0.38 3 1 13 6.98 6.38 0.29 4 1 13 5.74 1.44 0.40 1 2 13 14.79 15.29 0.23 2 2 13 6.17 3.68 0.45 3 2 13 10.34 9.90 0.25 4 2 13 5.90 1.61 0.44 0 3 13 7.66 6.99 0.34 1 3 13 17.72 18.13 0.25 2 3 13 9.56 9.00 0.30 3 3 13 5.80 2.06 0.48 4 3 13 5.91 2.90 0.47 0 4 13 14.11 14.95 0.41 1 4 13 5.89 1.15 0.48 2 4 13 7.42 6.11 0.69 3 4 13 7.30 5.09 0.39 4 4 13 5.51 2.27 0.50 0 5 13 7.38 6.88 0.37 1 5 13 13.99 14.14 0.27 2 5 13 5.57 2.63 0.66 3 5 13 6.91 1.70 0.64 4 5 13 6.16 3.59 0.69 1 6 13 6.58 3.77 0.36 2 6 13 6.81 5.69 0.56 3 6 13 7.94 7.05 0.42 4 6 13 5.82 3.46 0.65 0 7 13 6.35 1.58 0.44 1 7 13 7.19 5.70 0.36 2 7 13 5.67 3.45 0.42 3 7 13 6.53 4.31 0.38 0 8 13 7.34 6.59 0.44 1 8 13 6.91 6.27 0.41 2 8 13 7.69 6.09 0.33 3 8 13 5.49 3.93 0.34 0 9 13 6.51 4.93 0.91 1 9 13 7.25 3.98 0.35 2 9 13 6.20 2.48 0.54 0 10 13 10.54 10.91 0.45 1 10 13 9.58 10.51 0.31 2 10 13 5.86 4.09 0.88 0 11 13 6.57 4.83 0.97 0 0 14 14.92 16.32 0.39 1 0 14 10.45 11.78 0.61 2 0 14 8.23 8.17 0.37 3 0 14 9.49 9.93 0.43 4 0 14 5.34 0.94 0.51 1 1 14 9.79 9.80 0.28 2 1 14 8.09 7.01 0.33 3 1 14 8.03 7.11 0.35 4 1 14 6.28 1.65 0.41 0 2 14 8.47 7.88 0.51 1 2 14 11.97 11.80 0.27 2 2 14 13.08 13.66 0.32 3 2 14 7.36 5.55 0.33 4 2 14 6.01 2.30 0.41 0 3 14 6.33 5.86 0.56 1 3 14 7.93 7.64 0.37 2 3 14 8.65 7.52 0.30 3 3 14 8.43 6.59 0.40 4 3 14 6.25 2.98 0.47 0 4 14 8.85 7.90 0.68 1 4 14 11.70 11.74 0.36 2 4 14 7.99 5.74 0.41 3 4 14 6.21 0.99 0.38 4 4 14 6.05 3.02 0.45 0 5 14 13.68 13.67 0.42 1 5 14 7.78 5.90 0.30 2 5 14 6.69 1.18 0.33 3 5 14 6.71 0.56 0.43 0 6 14 6.45 3.28 0.64 1 6 14 7.10 5.45 0.44 2 6 14 6.30 1.69 0.38 3 6 14 7.23 5.01 0.43 1 7 14 8.60 8.66 0.31 2 7 14 5.96 1.67 0.61 3 7 14 6.97 6.75 0.55 0 8 14 8.08 7.80 0.45 1 8 14 9.41 9.50 0.43 2 8 14 6.41 4.31 0.63 0 9 14 5.31 2.64 0.69 1 9 14 8.01 8.60 0.78 0 10 14 7.07 5.81 0.83 1 0 15 5.43 1.24 0.44 2 0 15 7.04 5.41 0.57 3 0 15 12.61 12.71 0.41 0 1 15 6.65 3.08 0.62 1 1 15 10.90 11.51 0.28 2 1 15 9.41 9.03 0.32 3 1 15 8.07 7.97 0.28 0 2 15 6.91 4.74 0.62 1 2 15 5.47 2.88 0.51 2 2 15 5.96 2.18 0.40 3 2 15 10.34 10.31 0.29 1 3 15 11.19 11.98 0.25 2 3 15 11.93 12.09 0.29 3 3 15 6.66 1.45 0.50 0 4 15 9.10 7.30 0.51 1 4 15 7.30 5.09 0.34 2 4 15 7.32 4.23 0.61 3 4 15 6.53 2.93 0.42 0 5 15 9.42 9.79 0.36 1 5 15 7.03 4.08 0.46 2 5 15 6.81 4.52 0.35 3 5 15 5.22 3.08 0.43 0 6 15 7.64 5.75 0.60 1 6 15 5.40 0.58 0.46 2 6 15 8.81 9.70 0.41 0 7 15 6.47 1.41 0.63 1 7 15 6.43 1.00 0.53 2 7 15 8.79 8.37 0.31 0 8 15 5.59 5.60 0.88 1 8 15 7.56 8.33 0.28 1 0 16 5.45 0.42 0.52 2 0 16 9.13 9.15 0.47 3 0 16 6.88 3.13 0.48 1 1 16 6.87 3.08 0.56 2 1 16 6.70 3.28 0.43 3 1 16 7.89 7.78 0.31 1 2 16 7.73 6.86 0.78 2 2 16 9.48 9.68 0.39 3 2 16 8.47 8.26 0.36 0 3 16 8.31 8.44 0.40 1 3 16 7.22 4.67 0.37 2 3 16 7.04 2.60 0.61 3 3 16 6.34 3.13 0.49 0 4 16 10.95 11.83 0.39 1 4 16 6.89 1.71 0.43 2 4 16 6.44 2.17 0.38 0 5 16 7.58 5.13 0.44 1 5 16 6.56 2.02 0.69 2 5 16 5.74 2.26 0.48 1 6 16 6.33 2.86 0.39 2 6 16 6.48 3.67 0.96 0 7 16 6.36 1.59 1.04 1 7 16 6.30 3.00 0.51 2 0 17 7.31 1.82 0.61 0 1 17 6.69 0.62 0.55 1 1 17 6.84 5.55 0.50 2 1 17 9.42 9.64 0.34 0 2 17 11.30 12.20 0.64 1 2 17 6.13 5.18 0.65 2 2 17 6.72 3.20 0.38 0 3 17 2.97 0.64 0.56 1 3 17 5.06 3.47 0.37 2 3 17 6.66 6.11 0.35 0 4 17 6.88 1.56 0.47 1 4 17 7.01 3.42 0.57 1 5 17 6.02 3.37 0.46 0 0 18 9.18 9.21 0.50 1 0 18 7.11 4.47 0.49 0 1 18 4.04 4.00 0.53 0 2 18 5.60 1.71 0.66