#Supplementary Material (ESI) for Chemical Communications
#This journal is (c) The Royal Society of Chemistry 2001

data_abs 

_database_code_CSD	162720

_journal_coden_Cambridge      182

_publ_requested_journal       'Chemical Communications'

loop_
_publ_author_name
'Bagatur'yants, Alexander A.'
'Churakov, Andrei V.'
'Howard, Judith A. K.'
'Kuz'mina, Lyudmila G.'

_publ_contact_author_name     	'Lyudmila G Kuz'mina'  
_publ_contact_author_address 
;
Lyudmila G Kuz'mina
N.S. Kurnakov Inst of General & Inorganic Chemistry of Russian Academy of
Scienc
Leninskii pr. 31
Moscow
009991
RUSSIAN FEDERATION
;

_publ_contact_author_email       'KUZMINA@IGIC.RAS.RU'

_audit_creation_method            SHELXL 
_chemical_name_systematic 
; 
[5-methoxy-8-({2,4,6-trinitrophenyl}amino)quinolinyl-1]
(triphenylphosphine)gold(I)

; 
_chemical_name_common             ? 
_chemical_formula_moiety          ? 
_chemical_formula_structural      ? 
_chemical_formula_analytical      ? 
_chemical_formula_sum             'C34 H25 Au N5 O7 P' 
_chemical_formula_weight          843.53 
_chemical_melting_point           ? 
_chemical_compound_source         ? 

loop_ 
_atom_type_symbol 
_atom_type_description 
_atom_type_scat_dispersion_real 
_atom_type_scat_dispersion_imag 
_atom_type_scat_source 
'C'  'C'   0.0033   0.0016 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
'H'  'H'   0.0000   0.0000 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
'N'  'N'   0.0061   0.0033 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
'O'  'O'   0.0106   0.0060 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
'P'  'P'   0.1023   0.0942 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
'Au'  'Au'  -2.0133   8.8022 
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 

_symmetry_cell_setting            triclinic 
_symmetry_space_group_name_H-M    P-1 

loop_ 
_symmetry_equiv_pos_as_xyz 
'x, y, z' 
'-x, -y, -z' 

_cell_length_a                    7.581(2) 
_cell_length_b                    13.085(1) 
_cell_length_c                    16.626(1) 
_cell_angle_alpha                 74.43(1) 
_cell_angle_beta                  77.98(1) 
_cell_angle_gamma                 82.33(1) 
_cell_volume                      1548.68(9) 
_cell_formula_units_Z             2 
_cell_measurement_temperature     150.0(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 

_exptl_crystal_description        needle
_exptl_crystal_colour             black 
_exptl_crystal_size_max           0.46 
_exptl_crystal_size_mid           0.06 
_exptl_crystal_size_min           0.03 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.809 
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              828 
_exptl_absorpt_coefficient_mu     4.861 
_exptl_absorpt_correction_type    empirical
_exptl_absorpt_correction_T_min   0.74362
_exptl_absorpt_correction_T_max   0.97352

_exptl_special_details 
; 
? 
; 

_diffrn_ambient_temperature       150.0(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device        'Bruker SMART'
_diffrn_measurement_method        \w
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             10498 
_diffrn_reflns_av_R_equivalents   0.0702 
_diffrn_reflns_av_sigmaI/netI     0.1010 
_diffrn_reflns_limit_h_min        -9 
_diffrn_reflns_limit_h_max        8 
_diffrn_reflns_limit_k_min        -16 
_diffrn_reflns_limit_k_max        16 
_diffrn_reflns_limit_l_min        -20 
_diffrn_reflns_limit_l_max        21 
_diffrn_reflns_theta_min          1.29 
_diffrn_reflns_theta_max          26.50 
_reflns_number_total              6393 
_reflns_number_observed           4974 
_reflns_observed_criterion        I>2\s(I) 

_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-86 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-93 (Sheldrick, 1993)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 

_refine_special_details 
; 
Refinement on F^2^ for ALL reflections except for 506 with very negative F^2^ 
or flagged by the user for potential systematic errors.  Weighted R-factors 
wR and all goodnesses of fit S are based on F^2^, conventional R-factors R 
are based on F, with F set to zero for negative F^2^. The observed criterion 
of F^2^ > 2sigma(F^2^) is used only for calculating R(obs) etc. and is 
not relevant to the choice of reflections for refinement.  R-factors based 
on F^2^ are statistically about twice as large as those based on F, and R- 
factors based on ALL data will be even larger. 
; 

_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme 
'calc w=1/[\s^2^(Fo^2^)+(0.0188P)^2^+21.9585P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          5887 
_refine_ls_number_parameters      434 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.1047 
_refine_ls_R_factor_obs           0.0694 
_refine_ls_wR_factor_all          0.1588 
_refine_ls_wR_factor_obs          0.1267 
_refine_ls_goodness_of_fit_all    1.141 
_refine_ls_goodness_of_fit_obs    1.166 
_refine_ls_restrained_S_all       1.279 
_refine_ls_restrained_S_obs       1.166 
_refine_ls_shift/esd_max          0.000 
_refine_ls_shift/esd_mean         0.000 

loop_ 
_atom_site_label 
_atom_site_type_symbol 
_atom_site_fract_x 
_atom_site_fract_y 
_atom_site_fract_z 
_atom_site_U_iso_or_equiv 
_atom_site_thermal_displace_type 
_atom_site_occupancy 
_atom_site_calc_flag 
_atom_site_refinement_flags 
_atom_site_disorder_group 
Au1 Au 0.26988(6) 0.18099(4) -0.23057(3) 0.02354(13) Uani 1 d . . 
P1 P 0.5107(4) 0.1807(2) -0.3338(2) 0.0243(6) Uani 1 d . . 
O1 O 0.4026(10) 0.1887(7) -0.0474(5) 0.038(2) Uani 1 d . . 
O2 O 0.4378(11) 0.2783(8) 0.0397(5) 0.049(3) Uani 1 d . . 
O3 O 0.8684(11) 0.5447(7) -0.1223(6) 0.043(2) Uani 1 d . . 
O4 O 0.8277(12) 0.6381(7) -0.2467(6) 0.049(2) Uani 1 d . . 
O5 O 0.2910(14) 0.5995(7) -0.3464(6) 0.053(3) Uani 1 d . . 
O6 O 0.2599(10) 0.4355(6) -0.3359(5) 0.032(2) Uani 1 d . . 
O7 O -0.2798(9) 0.1696(6) 0.1419(4) 0.028(2) Uani 1 d . . 
N1 N 0.1871(11) 0.3434(7) -0.1617(5) 0.021(2) Uani 1 d . . 
N2 N 0.0348(10) 0.1507(7) -0.1358(5) 0.018(2) Uani 1 d . . 
N3 N 0.4288(11) 0.2702(8) -0.0303(6) 0.029(2) Uani 1 d . . 
N4 N 0.7861(12) 0.5668(7) -0.1812(6) 0.030(2) Uani 1 d . . 
N5 N 0.3077(12) 0.5040(7) -0.3114(5) 0.026(2) Uani 1 d . . 
C1 C 0.3318(13) 0.3897(8) -0.1660(6) 0.017(2) Uani 1 d . . 
C2 C 0.4489(14) 0.3679(8) -0.1019(6) 0.021(2) Uani 1 d . . 
C3 C 0.5895(14) 0.4247(8) -0.1048(7) 0.025(2) Uani 1 d . . 
H3A H 0.6554(14) 0.4075(8) -0.0595(7) 0.029 Uiso 1 calc R . 
C4 C 0.6344(14) 0.5079(8) -0.1751(7) 0.024(2) Uani 1 d . . 
C5 C 0.5382(14) 0.5324(8) -0.2415(6) 0.022(2) Uani 1 d . . 
H5A H 0.5701(14) 0.5897(8) -0.2894(6) 0.027 Uiso 1 calc R . 
C6 C 0.4003(13) 0.4756(7) -0.2383(6) 0.018(2) Uani 1 d . . 
C7 C 0.0802(13) 0.2977(8) -0.0808(6) 0.020(2) Uani 1 d . . 
C8 C 0.0418(13) 0.3466(8) -0.0160(6) 0.019(2) Uani 1 d . . 
H8A H 0.0973(13) 0.4097(8) -0.0218(6) 0.023 Uiso 1 calc R . 
C9 C -0.0795(14) 0.3055(9) 0.0601(6) 0.025(2) Uani 1 d . . 
H9A H -0.1014(14) 0.3403(9) 0.1050(6) 0.030 Uiso 1 calc R . 
C10 C -0.1644(13) 0.2168(8) 0.0695(6) 0.022(2) Uani 1 d . . 
C11 C -0.1341(13) 0.1661(8) 0.0011(6) 0.018(2) Uani 1 d . . 
C12 C -0.2236(13) 0.0762(9) 0.0035(6) 0.024(2) Uani 1 d . . 
H12A H -0.3102(13) 0.0486(9) 0.0523(6) 0.029 Uiso 1 calc R . 
C13 C -0.1885(14) 0.0290(8) -0.0620(6) 0.025(2) Uani 1 d . . 
H13A H -0.2550(14) -0.0279(8) -0.0616(6) 0.030 Uiso 1 calc R . 
C14 C -0.0515(13) 0.0664(8) -0.1302(6) 0.021(2) Uani 1 d . . 
H14A H -0.0187(13) 0.0302(8) -0.1743(6) 0.025 Uiso 1 calc R . 
C15 C -0.0022(12) 0.2037(7) -0.0732(6) 0.015(2) Uani 1 d . . 
C16 C 0.4382(15) 0.1846(9) -0.4329(6) 0.029(3) Uani 1 d . . 
C17 C 0.2744(15) 0.2393(9) -0.4456(7) 0.028(2) Uani 1 d . . 
H17A H 0.2030(15) 0.2715(9) -0.4034(7) 0.034 Uiso 1 calc R . 
C18 C 0.2130(19) 0.2473(11) -0.5220(8) 0.045(3) Uani 1 d . . 
H18A H 0.1019(19) 0.2870(11) -0.5322(8) 0.054 Uiso 1 calc R . 
C19 C 0.3132(21) 0.1980(11) -0.5809(8) 0.047(3) Uani 1 d . . 
H19A H 0.2711(21) 0.2020(11) -0.6317(8) 0.056 Uiso 1 calc R . 
C20 C 0.4750(24) 0.1426(13) -0.5670(8) 0.063(5) Uani 1 d . . 
H20A H 0.5442(24) 0.1079(13) -0.6081(8) 0.076 Uiso 1 calc R . 
C21 C 0.5380(20) 0.1366(11) -0.4942(8) 0.052(4) Uani 1 d . . 
H21A H 0.6516(20) 0.0991(11) -0.4859(8) 0.063 Uiso 1 calc R . 
C22 C 0.6741(15) 0.0668(9) -0.3128(7) 0.029(3) Uani 1 d . . 
C23 C 0.6330(17) -0.0215(9) -0.2467(7) 0.032(3) Uani 1 d . . 
H23A H 0.5160(17) -0.0233(9) -0.2122(7) 0.039 Uiso 1 calc R . 
C24 C 0.7602(19) -0.1077(10) -0.2299(8) 0.041(3) Uani 1 d . . 
H24A H 0.7293(19) -0.1677(10) -0.1842(8) 0.050 Uiso 1 calc R . 
C25 C 0.9307(18) -0.1069(11) -0.2791(9) 0.047(4) Uani 1 d . . 
H25A H 1.0170(18) -0.1661(11) -0.2678(9) 0.057 Uiso 1 calc R . 
C26 C 0.9744(17) -0.0195(11) -0.3446(9) 0.048(4) Uani 1 d . . 
H26A H 1.0920(17) -0.0188(11) -0.3784(9) 0.058 Uiso 1 calc R . 
C27 C 0.8523(16) 0.0664(11) -0.3620(8) 0.043(3) Uani 1 d . . 
H27A H 0.8862(16) 0.1262(11) -0.4073(8) 0.052 Uiso 1 calc R . 
C28 C 0.6495(14) 0.2927(9) -0.3567(6) 0.025(2) Uani 1 d . . 
C29 C 0.6616(14) 0.3741(9) -0.4306(7) 0.029(3) Uani 1 d . . 
H29A H 0.5962(14) 0.3732(9) -0.4733(7) 0.034 Uiso 1 calc R . 
C30 C 0.7660(15) 0.4547(10) -0.4420(7) 0.036(3) Uani 1 d . . 
H30A H 0.7684(15) 0.5120(10) -0.4913(7) 0.044 Uiso 1 calc R . 
C31 C 0.8714(15) 0.4544(10) -0.3812(7) 0.033(3) Uani 1 d . . 
H31A H 0.9459(15) 0.5108(10) -0.3900(7) 0.040 Uiso 1 calc R . 
C32 C 0.8658(13) 0.3710(9) -0.3082(7) 0.027(2) Uani 1 d . . 
H32A H 0.9385(13) 0.3691(9) -0.2675(7) 0.032 Uiso 1 calc R . 
C33 C 0.7530(15) 0.2913(9) -0.2957(7) 0.032(3) Uani 1 d . . 
H33A H 0.7455(15) 0.2352(9) -0.2454(7) 0.038 Uiso 1 calc R . 
C34 C -0.3549(16) 0.2350(10) 0.1965(7) 0.035(3) Uani 1 d . . 
H34A H -0.4450(76) 0.1975(25) 0.2424(28) 0.053 Uiso 1 calc R . 
H34B H -0.4132(89) 0.3005(28) 0.1649(12) 0.053 Uiso 1 calc R . 
H34C H -0.2592(22) 0.2529(50) 0.2207(38) 0.053 Uiso 1 calc R . 

loop_ 
_atom_site_aniso_label 
_atom_site_aniso_U_11 
_atom_site_aniso_U_22 
_atom_site_aniso_U_33 
_atom_site_aniso_U_23 
_atom_site_aniso_U_13 
_atom_site_aniso_U_12 
Au1 0.0222(2) 0.0287(2) 0.0177(2) -0.00206(15) -0.00094(14) -0.0073(2) 
P1 0.0237(14) 0.027(2) 0.0180(14) 0.0001(12) -0.0003(11) -0.0060(12) 
O1 0.022(4) 0.034(5) 0.046(5) 0.019(4) -0.011(4) -0.008(4) 
O2 0.035(5) 0.083(7) 0.014(4) 0.021(4) -0.009(4) -0.015(5) 
O3 0.046(5) 0.039(5) 0.054(6) -0.004(4) -0.034(5) -0.011(4) 
O4 0.043(5) 0.038(5) 0.061(6) 0.012(5) -0.017(5) -0.025(4) 
O5 0.087(7) 0.028(5) 0.049(6) 0.007(4) -0.044(5) -0.006(5) 
O6 0.031(4) 0.040(5) 0.028(4) -0.002(4) -0.014(3) -0.016(4) 
O7 0.021(4) 0.038(5) 0.019(4) -0.002(3) 0.007(3) -0.008(3) 
N1 0.020(4) 0.028(5) 0.014(4) -0.003(4) -0.003(3) -0.009(4) 
N2 0.014(4) 0.023(5) 0.018(4) 0.002(4) -0.008(3) -0.005(3) 
N3 0.016(4) 0.027(5) 0.032(6) 0.018(4) -0.010(4) -0.007(4) 
N4 0.031(5) 0.027(5) 0.042(6) -0.008(5) -0.021(5) -0.014(4) 
N5 0.029(5) 0.029(5) 0.023(5) 0.002(4) -0.010(4) -0.015(4) 
C1 0.019(5) 0.018(5) 0.013(5) -0.001(4) -0.003(4) -0.001(4) 
C2 0.032(6) 0.022(6) 0.007(4) 0.002(4) -0.004(4) -0.005(4) 
C3 0.030(6) 0.023(6) 0.027(6) -0.013(5) -0.011(5) -0.005(5) 
C4 0.029(6) 0.022(6) 0.029(6) -0.014(5) -0.011(5) -0.008(5) 
C5 0.028(6) 0.018(5) 0.017(5) 0.006(4) -0.005(4) -0.007(4) 
C6 0.023(5) 0.013(5) 0.014(5) 0.005(4) -0.010(4) -0.001(4) 
C7 0.016(5) 0.020(5) 0.021(5) 0.010(4) -0.013(4) -0.002(4) 
C8 0.019(5) 0.015(5) 0.024(5) -0.006(4) -0.008(4) -0.001(4) 
C9 0.025(6) 0.034(6) 0.013(5) -0.005(4) 0.000(4) -0.006(5) 
C10 0.013(5) 0.029(6) 0.021(5) 0.003(4) -0.009(4) 0.001(4) 
C11 0.017(5) 0.015(5) 0.018(5) 0.001(4) -0.006(4) 0.004(4) 
C12 0.012(5) 0.039(7) 0.015(5) 0.004(5) -0.001(4) 0.000(4) 
C13 0.029(6) 0.021(6) 0.024(6) -0.001(4) -0.007(5) -0.010(5) 
C14 0.020(5) 0.027(6) 0.020(5) -0.012(4) -0.008(4) 0.000(4) 
C15 0.010(4) 0.019(5) 0.014(5) -0.002(4) -0.003(4) 0.009(4) 
C16 0.038(7) 0.032(6) 0.015(5) 0.005(5) -0.005(5) -0.016(5) 
C17 0.036(6) 0.029(6) 0.021(5) -0.003(5) -0.012(5) -0.004(5) 
C18 0.051(8) 0.045(8) 0.035(7) 0.002(6) -0.011(6) -0.008(6) 
C19 0.075(10) 0.044(8) 0.025(7) -0.008(6) -0.014(7) -0.009(7) 
C20 0.100(13) 0.072(11) 0.020(7) -0.020(7) -0.012(8) 0.001(10) 
C21 0.065(10) 0.060(10) 0.033(7) -0.017(7) -0.023(7) 0.025(7) 
C22 0.033(6) 0.031(6) 0.022(6) 0.001(5) -0.009(5) -0.005(5) 
C23 0.044(7) 0.021(6) 0.033(6) 0.004(5) -0.018(5) -0.013(5) 
C24 0.068(9) 0.026(7) 0.039(7) -0.014(6) -0.017(7) -0.012(6) 
C25 0.043(8) 0.036(8) 0.074(10) -0.012(7) -0.042(8) 0.002(6) 
C26 0.027(7) 0.042(8) 0.069(10) -0.008(7) -0.008(6) 0.006(6) 
C27 0.033(7) 0.046(8) 0.043(8) 0.007(6) -0.004(6) -0.018(6) 
C28 0.022(5) 0.032(6) 0.015(5) 0.002(4) -0.002(4) -0.002(5) 
C29 0.023(6) 0.044(7) 0.019(5) 0.000(5) -0.005(4) -0.015(5) 
C30 0.028(6) 0.038(7) 0.026(6) 0.014(5) 0.002(5) -0.003(5) 
C31 0.025(6) 0.038(7) 0.036(7) -0.008(5) -0.004(5) -0.010(5) 
C32 0.018(5) 0.039(7) 0.026(6) -0.005(5) -0.014(4) 0.002(5) 
C33 0.036(7) 0.031(7) 0.023(6) 0.001(5) -0.004(5) 0.001(5) 
C34 0.036(7) 0.050(8) 0.022(6) -0.016(5) 0.007(5) -0.014(6) 

_geom_special_details 
; 
All esds (except the esd in the dihedral angle between two l.s. planes) 
are estimated using the full covariance matrix.  The cell esds are taken 
into account individually in the estimation of esds in distances, angles 
and torsion angles; correlations between esds in cell parameters are only 
used when they are defined by crystal symmetry.  An approximate (isotropic) 
treatment of cell esds is used for estimating esds involving l.s. planes. 
; 

loop_ 
_geom_bond_atom_site_label_1 
_geom_bond_atom_site_label_2 
_geom_bond_distance 
_geom_bond_site_symmetry_2 
_geom_bond_publ_flag 
Au1 N2 2.121(8) . ? 
Au1 P1 2.231(3) . ? 
Au1 N1 2.621(9) . ? 
P1 C22 1.813(12) . ? 
P1 C16 1.829(11) . ? 
P1 C28 1.829(11) . ? 
O1 N3 1.226(12) . ? 
O2 N3 1.211(12) . ? 
O3 N4 1.219(11) . ? 
O4 N4 1.244(12) . ? 
O5 N5 1.231(12) . ? 
O6 N5 1.202(11) . ? 
O7 C10 1.379(11) . ? 
O7 C34 1.398(13) . ? 
N1 C1 1.303(12) . ? 
N1 C7 1.438(12) . ? 
N2 C14 1.329(12) . ? 
N2 C15 1.364(12) . ? 
N3 C2 1.495(12) . ? 
N4 C4 1.441(12) . ? 
N5 C6 1.466(12) . ? 
C1 C6 1.467(12) . ? 
C1 C2 1.472(13) . ? 
C2 C3 1.364(14) . ? 
C3 C4 1.384(15) . ? 
C4 C5 1.391(14) . ? 
C5 C6 1.346(13) . ? 
C7 C8 1.357(14) . ? 
C7 C15 1.416(14) . ? 
C8 C9 1.421(13) . ? 
C9 C10 1.359(14) . ? 
C10 C11 1.428(14) . ? 
C11 C12 1.422(14) . ? 
C11 C15 1.434(13) . ? 
C12 C13 1.356(15) . ? 
C13 C14 1.397(14) . ? 
C16 C17 1.37(2) . ? 
C16 C21 1.38(2) . ? 
C17 C18 1.42(2) . ? 
C18 C19 1.36(2) . ? 
C19 C20 1.37(2) . ? 
C20 C21 1.37(2) . ? 
C22 C23 1.382(14) . ? 
C22 C27 1.43(2) . ? 
C23 C24 1.39(2) . ? 
C24 C25 1.38(2) . ? 
C25 C26 1.37(2) . ? 
C26 C27 1.36(2) . ? 
C28 C29 1.389(14) . ? 
C28 C33 1.402(15) . ? 
C29 C30 1.35(2) . ? 
C30 C31 1.41(2) . ? 
C31 C32 1.40(2) . ? 
C32 C33 1.38(2) . ? 

loop_ 
_geom_angle_atom_site_label_1 
_geom_angle_atom_site_label_2 
_geom_angle_atom_site_label_3 
_geom_angle 
_geom_angle_site_symmetry_1 
_geom_angle_site_symmetry_3 
_geom_angle_publ_flag 
N2 Au1 P1 168.4(2) . . ? 
N2 Au1 N1 71.6(3) . . ? 
P1 Au1 N1 120.0(2) . . ? 
C22 P1 C16 107.9(5) . . ? 
C22 P1 C28 102.4(5) . . ? 
C16 P1 C28 106.5(5) . . ? 
C22 P1 Au1 114.5(4) . . ? 
C16 P1 Au1 109.9(4) . . ? 
C28 P1 Au1 115.1(4) . . ? 
C10 O7 C34 115.5(8) . . ? 
C1 N1 C7 120.5(8) . . ? 
C1 N1 Au1 110.5(6) . . ? 
C7 N1 Au1 102.5(6) . . ? 
C14 N2 C15 121.4(8) . . ? 
C14 N2 Au1 117.9(7) . . ? 
C15 N2 Au1 119.4(6) . . ? 
O2 N3 O1 125.5(9) . . ? 
O2 N3 C2 117.7(10) . . ? 
O1 N3 C2 116.8(9) . . ? 
O3 N4 O4 122.9(9) . . ? 
O3 N4 C4 118.9(9) . . ? 
O4 N4 C4 118.3(9) . . ? 
O6 N5 O5 123.9(9) . . ? 
O6 N5 C6 120.1(9) . . ? 
O5 N5 C6 115.8(9) . . ? 
N1 C1 C6 123.1(8) . . ? 
N1 C1 C2 127.4(8) . . ? 
C6 C1 C2 109.5(8) . . ? 
C3 C2 C1 125.8(9) . . ? 
C3 C2 N3 114.5(9) . . ? 
C1 C2 N3 119.4(9) . . ? 
C2 C3 C4 118.7(10) . . ? 
C3 C4 C5 120.5(9) . . ? 
C3 C4 N4 119.8(9) . . ? 
C5 C4 N4 119.7(9) . . ? 
C6 C5 C4 120.5(9) . . ? 
C5 C6 N5 117.7(8) . . ? 
C5 C6 C1 124.8(9) . . ? 
N5 C6 C1 117.5(8) . . ? 
C8 C7 C15 119.8(9) . . ? 
C8 C7 N1 122.6(9) . . ? 
C15 C7 N1 117.3(9) . . ? 
C7 C8 C9 121.5(9) . . ? 
C10 C9 C8 120.7(10) . . ? 
C9 C10 O7 124.6(10) . . ? 
C9 C10 C11 119.4(9) . . ? 
O7 C10 C11 116.0(9) . . ? 
C12 C11 C10 123.4(9) . . ? 
C12 C11 C15 117.1(9) . . ? 
C10 C11 C15 119.5(9) . . ? 
C13 C12 C11 121.6(9) . . ? 
C12 C13 C14 118.0(9) . . ? 
N2 C14 C13 122.5(9) . . ? 
N2 C15 C7 121.9(8) . . ? 
N2 C15 C11 119.2(9) . . ? 
C7 C15 C11 118.8(9) . . ? 
C17 C16 C21 119.4(11) . . ? 
C17 C16 P1 116.8(9) . . ? 
C21 C16 P1 123.8(10) . . ? 
C16 C17 C18 119.4(11) . . ? 
C19 C18 C17 119.9(13) . . ? 
C18 C19 C20 120.0(13) . . ? 
C19 C20 C21 120.6(14) . . ? 
C20 C21 C16 120.7(13) . . ? 
C23 C22 C27 117.4(11) . . ? 
C23 C22 P1 121.4(9) . . ? 
C27 C22 P1 121.2(8) . . ? 
C22 C23 C24 121.0(12) . . ? 
C25 C24 C23 120.5(12) . . ? 
C26 C25 C24 119.3(12) . . ? 
C27 C26 C25 121.3(12) . . ? 
C26 C27 C22 120.4(11) . . ? 
C29 C28 C33 119.8(10) . . ? 
C29 C28 P1 124.1(8) . . ? 
C33 C28 P1 116.0(8) . . ? 
C30 C29 C28 120.3(10) . . ? 
C29 C30 C31 120.6(10) . . ? 
C32 C31 C30 119.7(10) . . ? 
C33 C32 C31 119.1(10) . . ? 
C32 C33 C28 120.4(10) . . ? 

_refine_diff_density_max    1.770 
_refine_diff_density_min   -1.561 
_refine_diff_density_rms    0.233