Supplementary Material (ESI) for Chemical Communications
This journal is © The Royal Society of Chemistry 2002

data_dom11
_database_code_CSD                  162970

_audit_creation_date            2001-04-30T15:13:21-00:00
_audit_creation_method         'WinGX routine CIF_UPDATE'

_journal_coden_Cambridge      182

loop_
_publ_author_name
'Strohmann, Carsten'
'Auer, Dominik'
'Hornig, Jan'

_publ_contact_author_name     	'Dr Carsten Strohmann'  
_publ_contact_author_address 
;
Anorganische Chemie
Universität Würzburg
Am Hubland
Wurzburg
Bayern
97074
GERMANY
;

_publ_contact_author_email          c.strohmann@mail.uni-wuerzburg.de

_publ_requested_journal       'Chemical Communications'


_publ_section_title		
;
Synthesis of a highly enantiomerically enriched silyllithium
compound
;		   


#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_name_systematic
;
?
;
_chemical_formula_sum                   'C34 H43 N O4 Si2'
_chemical_formula_weight                585.87

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting                  Monoclinic
_symmetry_space_group_name_H-M          P21
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                          9.886(2)
_cell_length_b                          12.973(3)
_cell_length_c                          13.140(3)
_cell_angle_alpha                       90
_cell_angle_beta                        107.83(3)
_cell_angle_gamma                       90
_cell_volume                            1604.2(6)
_cell_formula_units_Z                   2
_cell_measurement_temperature           173(2)

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_size_max                 0.4
_exptl_crystal_size_mid                 0.4
_exptl_crystal_size_min                 0.2
_exptl_crystal_density_diffrn           1.213
_exptl_crystal_F_000                    628
_exptl_special_details
;
?
;

#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu           0.148

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_ambient_temperature             173(2)
_diffrn_radiation_wavelength            0.71073
_diffrn_radiation_type                  MoK\a
_diffrn_radiation_monochromator         graphite
_diffrn_measurement_device              Stoe_IPDS
_diffrn_measurement_method              image_plate
_diffrn_reflns_number                   18908
_diffrn_reflns_av_R_equivalents         0.0833
_diffrn_reflns_av_sigmaI/netI           0.0567
_diffrn_reflns_limit_h_min              -13
_diffrn_reflns_limit_h_max              13
_diffrn_reflns_limit_k_min              -17
_diffrn_reflns_limit_k_max              17
_diffrn_reflns_limit_l_min              -17
_diffrn_reflns_limit_l_max              17
_diffrn_reflns_theta_min                2.26
_diffrn_reflns_theta_max                25.99
_reflns_number_total                    6102
_reflns_number_gt                       5693
_reflns_threshold_expression            >2sigma(I)

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_structure_refinement         'SHELXL-93 (Sheldrick, 1993)'

#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_refine_special_details
;
Refinement on F^2^ for ALL reflections except for 0 with very negative F^2^
or flagged by the user for potential systematic errors.  Weighted R-factors
wR and all goodnesses of fit S are based on F^2^, conventional R-factors R
are based on F, with F set to zero for negative F^2^. The observed criterion
of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is
not relevant to the choice of reflections for refinement.  R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef        Fsqd
_refine_ls_matrix_type                  full
_refine_ls_weighting_scheme
'calc w=1/[\s^2^(Fo^2^)+(0.1018P)^2^+0.0818P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary            direct
_atom_sites_solution_secondary          difmap
_atom_sites_solution_hydrogens          geom
_refine_ls_hydrogen_treatment           riding_model,HO4A,HO4B_free
_refine_ls_extinction_method            none
_refine_ls_number_reflns                6102
_refine_ls_number_parameters            384
_refine_ls_number_restraints            1
_refine_ls_R_factor_all                 0.0556
_refine_ls_R_factor_gt                  0.0524
_refine_ls_wR_factor_gt                 0.1386
_refine_ls_wR_factor_all                0.1416
_refine_ls_goodness_of_fit_gt           1.08
_refine_ls_goodness_of_fit_all          1.064
_refine_ls_restrained_S_all             1.063
_refine_ls_restrained_S_obs             1.08
_refine_ls_shift/su_max                 0
_refine_ls_shift/su_mean                0
_refine_ls_abs_structure_details
'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack          -0.03(11)
_refine_diff_density_max                0.488
_refine_diff_density_min                -0.386
_refine_diff_density_rms                0.063

#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Si1 Si 0.51924(7) 0.73213(5) 0.88904(5) 0.0315(2) Uani 1 d . .
Si2 Si 0.55182(7) 0.57015(5) 0.81978(5) 0.0316(2) Uani 1 d . .
N N 0.4802(2) 0.4980(2) 0.5980(2) 0.0295(4) Uani 1 d . .
HN H 0.407(4) 0.464(2) 0.608(3) 0.039(8) Uiso 1 d . .
O1 O 0.7808(3) 0.8737(2) 1.4417(2) 0.0656(7) Uani 1 d . .
O2 O 0.8111(3) 1.0227(2) 1.3763(2) 0.0740(8) Uani 1 d . .
O3 O 1.0707(3) 1.0078(2) 1.4052(2) 0.0638(7) Uani 1 d . .
HO3 H 1.1088(3) 0.9935(2) 1.3579(2) 0.096 Uiso 1 calc R .
O4 O 1.2527(3) 1.1878(3) 1.4592(3) 0.0711(8) Uani 1 d . .
HO4A H 1.242(7) 1.254(6) 1.518(6) 0.13(2) Uiso 1 d . .
HO4B H 1.208(5) 1.143(4) 1.478(4) 0.071(13) Uiso 1 d . .
C1 C 0.6613(3) 0.8254(2) 0.8842(3) 0.0464(6) Uani 1 d . .
H1A H 0.6413(15) 0.8928(6) 0.9100(19) 0.07 Uiso 1 calc R .
H1B H 0.6635(18) 0.8318(15) 0.8105(4) 0.07 Uiso 1 calc R .
H1C H 0.7535(5) 0.8003(10) 0.9297(16) 0.07 Uiso 1 calc R .
C2 C 0.5305(3) 0.7081(2) 1.0323(2) 0.0332(5) Uani 1 d . .
C3 C 0.4100(3) 0.6885(3) 1.0632(2) 0.0444(6) Uani 1 d . .
H3 H 0.3193(3) 0.6867(3) 1.0105(2) 0.053 Uiso 1 calc R .
C4 C 0.4205(4) 0.6715(3) 1.1698(3) 0.0560(8) Uani 1 d . .
H4 H 0.3377(4) 0.6577(3) 1.1898(3) 0.067 Uiso 1 calc R .
C5 C 0.5527(4) 0.6749(2) 1.2468(2) 0.0489(7) Uani 1 d . .
H5 H 0.5605(4) 0.6639(2) 1.3198(2) 0.059 Uiso 1 calc R .
C6 C 0.6716(3) 0.6940(2) 1.2180(2) 0.0465(7) Uani 1 d . .
H6 H 0.7618(3) 0.6966(2) 1.2711(2) 0.056 Uiso 1 calc R .
C7 C 0.6617(3) 0.7094(2) 1.1124(2) 0.0409(6) Uani 1 d . .
H7 H 0.7458(3) 0.7212(2) 1.0935(2) 0.049 Uiso 1 calc R .
C8 C 0.3406(3) 0.7883(2) 0.8177(2) 0.0354(5) Uani 1 d . .
C9 C 0.3183(3) 0.8950(2) 0.8093(2) 0.0438(6) Uani 1 d . .
H9 H 0.3961(3) 0.9404(2) 0.8377(2) 0.053 Uiso 1 calc R .
C10 C 0.1841(3) 0.9354(3) 0.7601(3) 0.0559(8) Uani 1 d . .
H10 H 0.1714(3) 1.0079(3) 0.7538(3) 0.067 Uiso 1 calc R .
C11 C 0.0684(3) 0.8705(3) 0.7203(2) 0.0479(7) Uani 1 d . .
H11 H -0.0237(3) 0.8985(3) 0.6887(2) 0.057 Uiso 1 calc R .
C12 C 0.0875(3) 0.7668(3) 0.7265(2) 0.0496(7) Uani 1 d . .
H12 H 0.0088(3) 0.7223(3) 0.6979(2) 0.059 Uiso 1 calc R .
C13 C 0.2221(3) 0.7254(2) 0.7747(2) 0.0430(6) Uani 1 d . .
H13 H 0.2335(3) 0.6527(2) 0.7783(2) 0.052 Uiso 1 calc R .
C14 C 0.4402(3) 0.4688(2) 0.8557(2) 0.0439(6) Uani 1 d . .
H14A H 0.4601(19) 0.4672(13) 0.9335(3) 0.066 Uiso 1 calc R .
H14B H 0.4624(18) 0.4015(3) 0.8309(17) 0.066 Uiso 1 calc R .
H14C H 0.3395(3) 0.4846(10) 0.8216(16) 0.066 Uiso 1 calc R .
C15 C 0.7466(3) 0.5396(2) 0.8802(2) 0.0369(5) Uani 1 d . .
C16 C 0.7923(4) 0.4617(3) 0.9552(3) 0.0518(7) Uani 1 d . .
H16 H 0.7245(4) 0.4191(3) 0.9726(3) 0.062 Uiso 1 calc R .
C17 C 0.9374(4) 0.4454(3) 1.0053(3) 0.0643(10) Uani 1 d . .
H17 H 0.9677(4) 0.3911(3) 1.0558(3) 0.077 Uiso 1 calc R .
C18 C 1.0361(4) 0.5075(3) 0.9818(3) 0.0608(9) Uani 1 d . .
H18 H 1.1343(4) 0.4973(3) 1.0176(3) 0.073 Uiso 1 calc R .
C19 C 0.9942(3) 0.5839(3) 0.9075(3) 0.0621(9) Uani 1 d . .
H19 H 1.0630(3) 0.6265(3) 0.8911(3) 0.075 Uiso 1 calc R .
C20 C 0.8505(3) 0.5992(2) 0.8558(3) 0.0486(7) Uani 1 d . .
H20 H 0.8221(3) 0.6513(2) 0.8027(3) 0.058 Uiso 1 calc R .
C21 C 0.5043(3) 0.5896(2) 0.6694(2) 0.0329(5) Uani 1 d . .
H21A H 0.4171(3) 0.6322(2) 0.6469(2) 0.039 Uiso 1 calc R .
H21B H 0.5813(3) 0.6308(2) 0.6558(2) 0.039 Uiso 1 calc R .
C22 C 0.6020(2) 0.4233(2) 0.6288(2) 0.0340(5) Uani 1 d . .
H22A H 0.6138(2) 0.3970(2) 0.7017(2) 0.041 Uiso 1 calc R .
H22B H 0.6906(2) 0.4594(2) 0.6297(2) 0.041 Uiso 1 calc R .
C23 C 0.5776(3) 0.3336(2) 0.5516(2) 0.0395(6) Uani 1 d . .
H23A H 0.4926(3) 0.2945(2) 0.5541(2) 0.047 Uiso 1 calc R .
H23B H 0.6604(3) 0.2866(2) 0.5730(2) 0.047 Uiso 1 calc R .
C24 C 0.5563(3) 0.3720(2) 0.4385(2) 0.0471(7) Uani 1 d . .
H24A H 0.5382(3) 0.3130(2) 0.3884(2) 0.057 Uiso 1 calc R .
H24B H 0.6430(3) 0.4080(2) 0.4348(2) 0.057 Uiso 1 calc R .
C25 C 0.4305(3) 0.4456(2) 0.4074(2) 0.0443(6) Uani 1 d . .
H25A H 0.4182(3) 0.4728(2) 0.3348(2) 0.053 Uiso 1 calc R .
H25B H 0.3429(3) 0.4077(2) 0.4059(2) 0.053 Uiso 1 calc R .
C26 C 0.4521(3) 0.5337(2) 0.4851(2) 0.0380(6) Uani 1 d . .
H26A H 0.5333(3) 0.5760(2) 0.4802(2) 0.046 Uiso 1 calc R .
H26B H 0.3664(3) 0.5779(2) 0.4650(2) 0.046 Uiso 1 calc R .
C27 C 1.0135(2) 0.9179(2) 1.4350(2) 0.0365(5) Uani 1 d . .
H27 H 1.0606(2) 0.9060(2) 1.5130(2) 0.044 Uiso 1 calc R .
C28 C 0.8538(3) 0.9373(2) 1.4172(2) 0.0441(7) Uani 1 d . .
C29 C 1.0363(2) 0.8235(2) 1.3746(2) 0.0334(5) Uani 1 d . .
C30 C 1.0349(3) 0.8315(2) 1.2686(2) 0.0387(6) Uani 1 d . .
H30 H 1.0198(3) 0.8967(2) 1.2339(2) 0.046 Uiso 1 calc R .
C31 C 1.0553(3) 0.7450(3) 1.2137(2) 0.0472(7) Uani 1 d . .
H31 H 1.0561(3) 0.7513(3) 1.1419(2) 0.057 Uiso 1 calc R .
C32 C 1.0746(3) 0.6496(2) 1.2623(3) 0.0468(7) Uani 1 d . .
H32 H 1.0866(3) 0.5902(2) 1.2238(3) 0.056 Uiso 1 calc R .
C33 C 1.0762(3) 0.6411(2) 1.3676(3) 0.0442(6) Uani 1 d . .
H33 H 1.0895(3) 0.5755(2) 1.4015(3) 0.053 Uiso 1 calc R .
C34 C 1.0587(3) 0.7275(2) 1.4240(2) 0.0367(5) Uani 1 d . .
H34 H 1.0621(3) 0.7212(2) 1.4967(2) 0.044 Uiso 1 calc R .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Si1 0.0300(3) 0.0336(3) 0.0293(3) -0.0021(2) 0.0066(2) -0.0006(2)
Si2 0.0328(3) 0.0320(3) 0.0300(3) -0.0002(2) 0.0093(2) -0.0002(3)
N 0.0268(10) 0.0351(9) 0.0265(10) 0.0003(8) 0.0080(8) -0.0010(8)
O1 0.0463(12) 0.0764(15) 0.087(2) -0.0203(14) 0.0394(13) -0.0144(12)
O2 0.0601(15) 0.075(2) 0.075(2) 0.0032(13) 0.0033(13) 0.0343(13)
O3 0.073(2) 0.0463(12) 0.088(2) -0.0166(12) 0.0490(14) -0.0201(11)
O4 0.0409(12) 0.076(2) 0.097(2) -0.009(2) 0.0210(13) -0.0115(12)
C1 0.0381(13) 0.0466(14) 0.052(2) -0.0002(12) 0.0102(12) -0.0073(11)
C2 0.0313(11) 0.0359(12) 0.0292(12) -0.0031(9) 0.0046(9) 0.0026(9)
C3 0.0307(12) 0.063(2) 0.0374(14) 0.0029(12) 0.0078(11) -0.0022(12)
C4 0.045(2) 0.079(2) 0.050(2) 0.009(2) 0.0237(14) 0.004(2)
C5 0.066(2) 0.053(2) 0.0279(13) 0.0018(11) 0.0146(13) 0.0065(14)
C6 0.0457(15) 0.0520(15) 0.0328(14) -0.0005(11) -0.0010(12) 0.0087(12)
C7 0.0306(11) 0.0521(15) 0.0352(13) -0.0035(11) 0.0031(10) 0.0014(10)
C8 0.0358(12) 0.0412(13) 0.0274(12) -0.0045(10) 0.0071(10) 0.0007(10)
C9 0.0452(15) 0.0361(13) 0.046(2) 0.0030(11) 0.0076(12) 0.0028(10)
C10 0.049(2) 0.048(2) 0.064(2) 0.0134(14) 0.0082(15) 0.0106(13)
C11 0.0418(15) 0.061(2) 0.0359(14) 0.0063(13) 0.0041(12) 0.0128(13)
C12 0.0392(15) 0.061(2) 0.0406(15) -0.0073(12) 0.0002(12) 0.0045(13)
C13 0.0394(13) 0.0396(12) 0.0441(14) -0.0058(11) 0.0039(11) 0.0018(11)
C14 0.0483(15) 0.0424(13) 0.044(2) 0.0038(11) 0.0186(12) -0.0065(11)
C15 0.0411(13) 0.0383(12) 0.0297(12) -0.0013(9) 0.0085(10) 0.0065(10)
C16 0.052(2) 0.058(2) 0.044(2) 0.0087(13) 0.0125(13) 0.0091(13)
C17 0.066(2) 0.075(2) 0.043(2) 0.011(2) 0.003(2) 0.026(2)
C18 0.040(2) 0.083(2) 0.051(2) 0.001(2) 0.0001(14) 0.016(2)
C19 0.0358(14) 0.072(2) 0.074(2) 0.004(2) 0.0087(15) 0.0051(15)
C20 0.0365(14) 0.054(2) 0.054(2) 0.0082(13) 0.0114(13) 0.0078(11)
C21 0.0344(12) 0.0307(11) 0.0338(12) -0.0006(9) 0.0107(10) 0.0028(9)
C22 0.0260(10) 0.0382(12) 0.0360(13) -0.0007(10) 0.0068(9) 0.0005(9)
C23 0.0351(13) 0.0371(12) 0.046(2) -0.0068(10) 0.0125(11) -0.0009(10)
C24 0.051(2) 0.0488(14) 0.047(2) -0.0155(13) 0.0242(13) -0.0065(12)
C25 0.050(2) 0.0486(15) 0.0314(13) -0.0021(11) 0.0089(11) -0.0092(12)
C26 0.0438(14) 0.0397(12) 0.0269(12) 0.0023(9) 0.0056(10) -0.0032(10)
C27 0.0237(10) 0.0433(13) 0.0405(14) -0.0027(11) 0.0070(9) -0.0015(10)
C28 0.0299(12) 0.055(2) 0.0441(15) -0.0162(12) 0.0061(11) 0.0031(12)
C29 0.0209(10) 0.0391(12) 0.0382(13) -0.0005(10) 0.0060(9) -0.0015(9)
C30 0.0345(13) 0.0451(13) 0.0353(14) 0.0044(10) 0.0089(10) -0.0007(10)
C31 0.0390(13) 0.067(2) 0.0385(14) -0.0062(13) 0.0163(11) -0.0047(13)
C32 0.0356(13) 0.0464(14) 0.061(2) -0.0127(13) 0.0184(13) -0.0039(11)
C33 0.0335(12) 0.0396(12) 0.057(2) -0.0013(12) 0.0100(12) -0.0025(10)
C34 0.0276(11) 0.0425(12) 0.0390(13) 0.0035(11) 0.0087(9) 0.0002(10)


#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C1 1.869(3) . ?
Si1 C8 1.874(3) . ?
Si1 C2 1.878(3) . ?
Si1 Si2 2.3509(10) . ?
Si2 C14 1.867(3) . ?
Si2 C15 1.887(3) . ?
Si2 C21 1.903(3) . ?
N C21 1.488(3) . ?
N C26 1.497(3) . ?
N C22 1.501(3) . ?
O1 C28 1.203(4) . ?
O2 C28 1.248(4) . ?
O3 C27 1.403(3) . ?
C2 C3 1.394(4) . ?
C2 C7 1.398(4) . ?
C3 C4 1.390(5) . ?
C4 C5 1.387(5) . ?
C5 C6 1.363(5) . ?
C6 C7 1.375(4) . ?
C8 C13 1.397(4) . ?
C8 C9 1.401(4) . ?
C9 C10 1.388(4) . ?
C10 C11 1.386(5) . ?
C11 C12 1.357(5) . ?
C12 C13 1.394(4) . ?
C15 C16 1.386(4) . ?
C15 C20 1.399(4) . ?
C16 C17 1.400(5) . ?
C17 C18 1.371(6) . ?
C18 C19 1.364(6) . ?
C19 C20 1.389(4) . ?
C22 C23 1.513(4) . ?
C23 C24 1.519(4) . ?
C24 C25 1.521(4) . ?
C25 C26 1.503(4) . ?
C27 C29 1.513(4) . ?
C27 C28 1.543(3) . ?
C29 C34 1.390(4) . ?
C29 C30 1.393(4) . ?
C30 C31 1.382(4) . ?
C31 C32 1.378(5) . ?
C32 C33 1.384(5) . ?
C33 C34 1.382(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Si1 C8 109.52(13) . . ?
C1 Si1 C2 109.07(13) . . ?
C8 Si1 C2 108.86(12) . . ?
C1 Si1 Si2 111.84(11) . . ?
C8 Si1 Si2 111.93(8) . . ?
C2 Si1 Si2 105.48(8) . . ?
C14 Si2 C15 110.58(13) . . ?
C14 Si2 C21 112.27(13) . . ?
C15 Si2 C21 111.13(12) . . ?
C14 Si2 Si1 111.70(11) . . ?
C15 Si2 Si1 105.56(8) . . ?
C21 Si2 Si1 105.29(8) . . ?
C21 N C26 108.9(2) . . ?
C21 N C22 112.7(2) . . ?
C26 N C22 110.9(2) . . ?
C3 C2 C7 117.5(3) . . ?
C3 C2 Si1 121.9(2) . . ?
C7 C2 Si1 120.6(2) . . ?
C4 C3 C2 121.0(3) . . ?
C5 C4 C3 119.6(3) . . ?
C6 C5 C4 120.2(3) . . ?
C5 C6 C7 120.4(3) . . ?
C6 C7 C2 121.4(3) . . ?
C13 C8 C9 116.9(2) . . ?
C13 C8 Si1 121.4(2) . . ?
C9 C8 Si1 121.7(2) . . ?
C10 C9 C8 121.0(3) . . ?
C11 C10 C9 120.5(3) . . ?
C12 C11 C10 119.7(3) . . ?
C11 C12 C13 120.3(3) . . ?
C12 C13 C8 121.6(3) . . ?
C16 C15 C20 117.6(3) . . ?
C16 C15 Si2 121.4(2) . . ?
C20 C15 Si2 120.9(2) . . ?
C15 C16 C17 120.6(3) . . ?
C18 C17 C16 120.1(3) . . ?
C19 C18 C17 120.5(3) . . ?
C18 C19 C20 119.7(3) . . ?
C19 C20 C15 121.4(3) . . ?
N C21 Si2 119.3(2) . . ?
N C22 C23 111.4(2) . . ?
C22 C23 C24 110.5(2) . . ?
C23 C24 C25 109.0(2) . . ?
C26 C25 C24 111.1(2) . . ?
N C26 C25 112.4(2) . . ?
O3 C27 C29 112.9(2) . . ?
O3 C27 C28 107.7(2) . . ?
C29 C27 C28 111.2(2) . . ?
O1 C28 O2 124.9(3) . . ?
O1 C28 C27 121.2(3) . . ?
O2 C28 C27 113.9(3) . . ?
C34 C29 C30 119.0(2) . . ?
C34 C29 C27 120.6(2) . . ?
C30 C29 C27 120.4(2) . . ?
C31 C30 C29 120.2(2) . . ?
C32 C31 C30 120.6(3) . . ?
C31 C32 C33 119.5(3) . . ?
C34 C33 C32 120.4(3) . . ?
C33 C34 C29 120.3(3) . . ?