# Supplementary Material (ESI) for Chemical Communications # This journal is © The Royal Society of Chemistry 2003 data_global _journal_name_full Chem.Commun. _journal_coden_Cambridge 0182 _journal_year ? _journal_volume ? _journal_page_first ? loop_ _publ_author_name _publ_author_address 'Roland Fischer' ; Lehrstuhl for Anorganische Chemie II Ruhr-University Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Tobias Steinke' ; Lehrstuhl for Anorganische Chemie II Ruhr-University Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Christian Gemel' ; Lehrstuhl for Anorganische Chemie II Ruhr-University Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Mirza Cokoja' ; Lehrstuhl for Anorganische Chemie II Ruhr-University Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; _publ_contact_author_address ; 'Roland Fischer' Lehrstuhl for Anorganische Chemie II Ruhr-University Bochum Universitaet sstrasse 150 44780 Bochum (Germany) ; _publ_contact_author_email roland.fischer@ruhr-uni-bochum.de _publ_contact_author_fax '049 234 3214174' _publ_contact_author_phone '049 234 3224174' _publ_contact_author_name 'Roland A. Fischer' _publ_requested_coeditor_name ? data_1 _database_code_CSD 204637 _publ_section_title ; Insertion of organoindium carbenoids into Rhodium halide bonds: Revisiting a classic type of transitionmetal-Group 13 metal bond formation. ; _publ_section_abstract ; The insertion of InCp* and InC(SiMe3)3 into the Rh-Cl bonds of (RhCp*Cl2)2 is presented. The crystal structures of the two insertion products are given. ; _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C40 H96 Cl2 In3 Rh Si9' _chemical_formula_weight 1348.25 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P2(1)/n loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 14.509(3) _cell_length_b 18.830(4) _cell_length_c 22.633(4) _cell_angle_alpha 90.00 _cell_angle_beta 92.882(4) _cell_angle_gamma 90.00 _cell_volume 6176(2) _cell_formula_units_Z 4 _cell_measurement_temperature 213(2) _cell_measurement_reflns_used 60 _cell_measurement_theta_min 10.0 _cell_measurement_theta_max 15.0 _exptl_crystal_description prism _exptl_crystal_colour orange-red _exptl_crystal_size_max 0.30 _exptl_crystal_size_mid 0.28 _exptl_crystal_size_min 0.25 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.450 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2752 _exptl_absorpt_coefficient_mu 1.655 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.861 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 213(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 34096 _diffrn_reflns_av_R_equivalents 0.0438 _diffrn_reflns_av_sigmaI/netI 0.0490 _diffrn_reflns_limit_h_min -8 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_k_min -22 _diffrn_reflns_limit_k_max 22 _diffrn_reflns_limit_l_min -26 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_theta_min 2.58 _diffrn_reflns_theta_max 25.05 _reflns_number_total 10683 _reflns_number_gt 8135 _reflns_threshold_expression >2sigma(I) _computing_data_collection SMART _computing_cell_refinement SMART _computing_data_reduction SAINT _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker axs SHELXTL-PLUS' _computing_publication_material SHELXL-97 _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w==1/[\s^2^(Fo^2^)+(0.0442P)^2^+17.5705P] where P==(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 10683 _refine_ls_number_parameters 528 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0617 _refine_ls_R_factor_gt 0.0417 _refine_ls_wR_factor_ref 0.1039 _refine_ls_wR_factor_gt 0.0943 _refine_ls_goodness_of_fit_ref 1.023 _refine_ls_restrained_S_all 1.023 _refine_ls_shift/su_max 0.135 _refine_ls_shift/su_mean 0.001 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Cl1 Cl 0.33411(12) 0.90803(9) 0.24487(9) 0.0549(5) Uani 1 1 d . . . Cl2 Cl 0.53187(14) 0.89244(8) 0.12690(7) 0.0485(4) Uani 1 1 d . . . Rh1 Rh 0.42644(3) 0.72468(2) 0.193916(18) 0.01952(10) Uani 1 1 d . . . C4 C 0.3679(4) 0.6139(3) 0.1885(3) 0.0351(14) Uani 1 1 d . . . C9 C 0.3093(6) 0.5742(4) 0.1414(4) 0.070(3) Uani 1 1 d . . . H41A H 0.3007 0.5255 0.1540 0.105 Uiso 1 1 calc R . . H41B H 0.3404 0.5746 0.1044 0.105 Uiso 1 1 calc R . . H41C H 0.2498 0.5973 0.1358 0.105 Uiso 1 1 calc R . . C3 C 0.3310(4) 0.6492(3) 0.2366(3) 0.0336(14) Uani 1 1 d . . . C8 C 0.2303(5) 0.6526(4) 0.2499(5) 0.073(3) Uani 1 1 d . . . H42A H 0.1933 0.6573 0.2132 0.110 Uiso 1 1 calc R . . H42B H 0.2197 0.6933 0.2750 0.110 Uiso 1 1 calc R . . H42C H 0.2130 0.6095 0.2700 0.110 Uiso 1 1 calc R . . C2 C 0.4057(6) 0.6671(3) 0.2777(3) 0.0455(18) Uani 1 1 d . . . C7 C 0.3966(8) 0.6922(5) 0.3395(3) 0.087(3) Uani 1 1 d . . . H43A H 0.3797 0.6526 0.3641 0.130 Uiso 1 1 calc R . . H43B H 0.3491 0.7284 0.3401 0.130 Uiso 1 1 calc R . . H43C H 0.4549 0.7119 0.3545 0.130 Uiso 1 1 calc R . . C1 C 0.4881(4) 0.6413(3) 0.2530(3) 0.0460(18) Uani 1 1 d . . . C6 C 0.5817(6) 0.6348(5) 0.2839(5) 0.090(4) Uani 1 1 d . . . H44A H 0.5912 0.5862 0.2972 0.135 Uiso 1 1 calc R . . H44B H 0.5857 0.6665 0.3177 0.135 Uiso 1 1 calc R . . H44C H 0.6287 0.6473 0.2567 0.135 Uiso 1 1 calc R . . C5 C 0.4631(4) 0.6090(3) 0.1985(3) 0.0403(16) Uani 1 1 d . . . C10 C 0.5235(6) 0.5628(4) 0.1618(5) 0.081(3) Uani 1 1 d . . . H45A H 0.5878 0.5752 0.1701 0.122 Uiso 1 1 calc R . . H45B H 0.5075 0.5703 0.1202 0.122 Uiso 1 1 calc R . . H45C H 0.5140 0.5133 0.1717 0.122 Uiso 1 1 calc R . . In1 In 0.49995(3) 0.842806(19) 0.235937(16) 0.02322(10) Uani 1 1 d . . . C11 C 0.5890(4) 0.9165(3) 0.2929(2) 0.0279(12) Uani 1 1 d . . . Si1 Si 0.69543(12) 0.86228(10) 0.31270(9) 0.0432(5) Uani 1 1 d . . . C111 C 0.7998(5) 0.9147(4) 0.3390(4) 0.072(3) Uani 1 1 d . . . H11A H 0.7872 0.9390 0.3755 0.109 Uiso 1 1 calc R . . H11B H 0.8144 0.9494 0.3091 0.109 Uiso 1 1 calc R . . H11C H 0.8518 0.8829 0.3458 0.109 Uiso 1 1 calc R . . C112 C 0.7322(5) 0.8090(4) 0.2481(4) 0.066(2) Uani 1 1 d . . . H11D H 0.7922 0.7880 0.2576 0.100 Uiso 1 1 calc R . . H11E H 0.7360 0.8397 0.2139 0.100 Uiso 1 1 calc R . . H11F H 0.6875 0.7717 0.2393 0.100 Uiso 1 1 calc R . . C113 C 0.6754(7) 0.7952(4) 0.3717(4) 0.074(3) Uani 1 1 d . . . H11G H 0.6184 0.7699 0.3622 0.111 Uiso 1 1 calc R . . H11H H 0.6712 0.8191 0.4094 0.111 Uiso 1 1 calc R . . H11I H 0.7264 0.7618 0.3742 0.111 Uiso 1 1 calc R . . Si3 Si 0.52776(13) 0.94100(10) 0.36224(8) 0.0398(4) Uani 1 1 d . . . C121 C 0.4564(6) 0.8673(4) 0.3910(3) 0.067(2) Uani 1 1 d . . . H12A H 0.4107 0.8527 0.3606 0.100 Uiso 1 1 calc R . . H12B H 0.4255 0.8835 0.4256 0.100 Uiso 1 1 calc R . . H12C H 0.4959 0.8273 0.4018 0.100 Uiso 1 1 calc R . . C122 C 0.6085(6) 0.9677(5) 0.4259(3) 0.067(2) Uani 1 1 d . . . H12D H 0.5737 0.9750 0.4609 0.101 Uiso 1 1 calc R . . H12E H 0.6397 1.0115 0.4162 0.101 Uiso 1 1 calc R . . H12F H 0.6538 0.9305 0.4335 0.101 Uiso 1 1 calc R . . C123 C 0.4459(5) 1.0181(4) 0.3526(4) 0.060(2) Uani 1 1 d . . . H12G H 0.4034 1.0094 0.3190 0.090 Uiso 1 1 calc R . . H12H H 0.4806 1.0611 0.3460 0.090 Uiso 1 1 calc R . . H12I H 0.4115 1.0235 0.3880 0.090 Uiso 1 1 calc R . . Si2 Si 0.61888(13) 1.00043(9) 0.25104(8) 0.0380(4) Uani 1 1 d . . . C131 C 0.6696(5) 1.0712(4) 0.3017(3) 0.0539(19) Uani 1 1 d . . . H13A H 0.7246 1.0530 0.3227 0.081 Uiso 1 1 calc R . . H13B H 0.6248 1.0848 0.3300 0.081 Uiso 1 1 calc R . . H13C H 0.6856 1.1124 0.2786 0.081 Uiso 1 1 calc R . . C132 C 0.5168(5) 1.0440(3) 0.2119(3) 0.056(2) Uani 1 1 d . . . H13D H 0.5110 1.0923 0.2261 0.084 Uiso 1 1 calc R . . H13E H 0.4613 1.0177 0.2197 0.084 Uiso 1 1 calc R . . H13F H 0.5254 1.0446 0.1697 0.084 Uiso 1 1 calc R . . C133 C 0.7103(6) 0.9882(4) 0.1962(4) 0.067(2) Uani 1 1 d . . . H13G H 0.6928 0.9498 0.1693 0.100 Uiso 1 1 calc R . . H13H H 0.7685 0.9768 0.2170 0.100 Uiso 1 1 calc R . . H13I H 0.7169 1.0318 0.1738 0.100 Uiso 1 1 calc R . . In2 In 0.50637(3) 0.758356(19) 0.099505(16) 0.02415(10) Uani 1 1 d . . . C12 C 0.5775(4) 0.7462(3) 0.0145(2) 0.0277(12) Uani 1 1 d . . . Si6 Si 0.55621(18) 0.65175(10) -0.01022(9) 0.0573(6) Uani 1 1 d . . . C211 C 0.5773(7) 0.6322(4) -0.0900(3) 0.076(3) Uani 1 1 d . . . H21A H 0.5438 0.6661 -0.1152 0.114 Uiso 1 1 calc R . . H21B H 0.5563 0.5845 -0.0997 0.114 Uiso 1 1 calc R . . H21C H 0.6428 0.6359 -0.0962 0.114 Uiso 1 1 calc R . . C212 C 0.6364(7) 0.5865(4) 0.0314(4) 0.083(3) Uani 1 1 d . . . H21D H 0.6954 0.5853 0.0131 0.125 Uiso 1 1 calc R . . H21E H 0.6091 0.5395 0.0300 0.125 Uiso 1 1 calc R . . H21F H 0.6455 0.6015 0.0723 0.125 Uiso 1 1 calc R . . C213 C 0.4321(6) 0.6265(4) 0.0003(4) 0.078(3) Uani 1 1 d . . . H21G H 0.4173 0.6355 0.0409 0.117 Uiso 1 1 calc R . . H21H H 0.4234 0.5765 -0.0086 0.117 Uiso 1 1 calc R . . H21I H 0.3919 0.6545 -0.0261 0.117 Uiso 1 1 calc R . . Si5 Si 0.53307(12) 0.81021(9) -0.04607(7) 0.0367(4) Uani 1 1 d . . . C221 C 0.4196(5) 0.7815(5) -0.0821(3) 0.062(2) Uani 1 1 d . . . H22A H 0.3748 0.7755 -0.0521 0.093 Uiso 1 1 calc R . . H22B H 0.4276 0.7369 -0.1026 0.093 Uiso 1 1 calc R . . H22C H 0.3978 0.8174 -0.1102 0.093 Uiso 1 1 calc R . . C222 C 0.6162(5) 0.8163(4) -0.1072(3) 0.0512(18) Uani 1 1 d . . . H22D H 0.5909 0.8474 -0.1381 0.077 Uiso 1 1 calc R . . H22E H 0.6258 0.7694 -0.1235 0.077 Uiso 1 1 calc R . . H22F H 0.6746 0.8352 -0.0915 0.077 Uiso 1 1 calc R . . C223 C 0.5151(5) 0.9036(3) -0.0219(3) 0.0440(16) Uani 1 1 d . . . H22G H 0.5717 0.9216 -0.0027 0.066 Uiso 1 1 calc R . . H22H H 0.4661 0.9051 0.0056 0.066 Uiso 1 1 calc R . . H22I H 0.4983 0.9328 -0.0561 0.066 Uiso 1 1 calc R . . Si4 Si 0.70358(13) 0.76294(10) 0.03425(8) 0.0407(4) Uani 1 1 d . . . C231 C 0.7837(5) 0.7205(5) -0.0180(4) 0.067(2) Uani 1 1 d . . . H23A H 0.7799 0.6693 -0.0146 0.100 Uiso 1 1 calc R . . H23B H 0.8465 0.7358 -0.0081 0.100 Uiso 1 1 calc R . . H23C H 0.7662 0.7347 -0.0582 0.100 Uiso 1 1 calc R . . C232 C 0.7356(5) 0.7232(5) 0.1089(3) 0.063(2) Uani 1 1 d . . . H23D H 0.6882 0.7344 0.1362 0.095 Uiso 1 1 calc R . . H23E H 0.7941 0.7427 0.1238 0.095 Uiso 1 1 calc R . . H23F H 0.7410 0.6721 0.1052 0.095 Uiso 1 1 calc R . . C233 C 0.7350(5) 0.8593(4) 0.0379(3) 0.0517(18) Uani 1 1 d . . . H23G H 0.7206 0.8813 -0.0002 0.078 Uiso 1 1 calc R . . H23H H 0.8005 0.8641 0.0479 0.078 Uiso 1 1 calc R . . H23I H 0.7002 0.8825 0.0679 0.078 Uiso 1 1 calc R . . In3 In 0.29677(3) 0.811471(19) 0.163171(18) 0.02568(11) Uani 1 1 d . . . C13 C 0.1677(4) 0.8532(3) 0.1195(3) 0.0263(12) Uani 1 1 d . . . Si9 Si 0.08760(14) 0.88503(11) 0.17621(9) 0.0504(5) Uani 1 1 d . . . C311 C -0.0354(5) 0.8918(5) 0.1472(4) 0.066(2) Uani 1 1 d . . . H31A H -0.0397 0.9255 0.1147 0.100 Uiso 1 1 calc R . . H31B H -0.0736 0.9078 0.1785 0.100 Uiso 1 1 calc R . . H31C H -0.0566 0.8456 0.1333 0.100 Uiso 1 1 calc R . . C312 C 0.1149(7) 0.9781(5) 0.2048(4) 0.092(4) Uani 1 1 d . . . H31D H 0.1802 0.9816 0.2158 0.138 Uiso 1 1 calc R . . H31E H 0.0794 0.9876 0.2392 0.138 Uiso 1 1 calc R . . H31F H 0.0990 1.0125 0.1741 0.138 Uiso 1 1 calc R . . C313 C 0.0913(6) 0.8260(5) 0.2424(4) 0.074(2) Uani 1 1 d . . . H31G H 0.0881 0.7768 0.2298 0.110 Uiso 1 1 calc R . . H31H H 0.0393 0.8366 0.2663 0.110 Uiso 1 1 calc R . . H31I H 0.1484 0.8339 0.2656 0.110 Uiso 1 1 calc R . . Si7 Si 0.11606(14) 0.77957(10) 0.07245(9) 0.0465(5) Uani 1 1 d . . . C321 C 0.0453(7) 0.7157(4) 0.1170(5) 0.083(3) Uani 1 1 d . . . H32A H 0.0847 0.6940 0.1478 0.124 Uiso 1 1 calc R . . H32B H 0.0191 0.6791 0.0911 0.124 Uiso 1 1 calc R . . H32C H -0.0041 0.7416 0.1348 0.124 Uiso 1 1 calc R . . C322 C 0.2052(6) 0.7217(4) 0.0405(4) 0.074(3) Uani 1 1 d . . . H32D H 0.2416 0.7495 0.0142 0.111 Uiso 1 1 calc R . . H32E H 0.1752 0.6831 0.0187 0.111 Uiso 1 1 calc R . . H32F H 0.2452 0.7024 0.0722 0.111 Uiso 1 1 calc R . . C323 C 0.0369(5) 0.8096(4) 0.0102(3) 0.060(2) Uani 1 1 d . . . H32G H -0.0180 0.8304 0.0259 0.090 Uiso 1 1 calc R . . H32H H 0.0196 0.7694 -0.0146 0.090 Uiso 1 1 calc R . . H32I H 0.0678 0.8448 -0.0130 0.090 Uiso 1 1 calc R . . Si8 Si 0.20468(14) 0.92974(11) 0.07017(11) 0.0562(6) Uani 1 1 d . . . C331 C 0.2591(7) 0.8978(6) 0.0015(4) 0.097(3) Uani 1 1 d . . . H33A H 0.2722 0.9381 -0.0234 0.145 Uiso 1 1 calc R . . H33B H 0.2170 0.8658 -0.0200 0.145 Uiso 1 1 calc R . . H33C H 0.3160 0.8730 0.0123 0.145 Uiso 1 1 calc R . . C332 C 0.2930(6) 0.9877(5) 0.1059(5) 0.085(3) Uani 1 1 d . . . H33D H 0.3473 0.9598 0.1172 0.128 Uiso 1 1 calc R . . H33E H 0.2688 1.0093 0.1408 0.128 Uiso 1 1 calc R . . H33F H 0.3096 1.0246 0.0784 0.128 Uiso 1 1 calc R . . C333 C 0.1061(6) 0.9880(4) 0.0449(4) 0.080(3) Uani 1 1 d . . . H33G H 0.0796 1.0098 0.0790 0.120 Uiso 1 1 calc R . . H33H H 0.0595 0.9597 0.0236 0.120 Uiso 1 1 calc R . . H33I H 0.1281 1.0247 0.0191 0.120 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Cl1 0.0384(9) 0.0522(10) 0.0719(12) -0.0299(9) -0.0187(9) 0.0154(8) Cl2 0.0876(13) 0.0287(8) 0.0297(8) 0.0015(6) 0.0083(8) -0.0200(8) Rh1 0.0174(2) 0.0185(2) 0.0228(2) 0.00375(16) 0.00334(16) 0.00022(16) C4 0.046(4) 0.023(3) 0.037(3) 0.006(2) 0.004(3) -0.008(3) C9 0.094(7) 0.050(5) 0.066(5) 0.004(4) 0.002(5) -0.039(5) C3 0.026(3) 0.027(3) 0.048(4) 0.015(3) 0.010(3) 0.002(2) C8 0.041(4) 0.063(5) 0.120(8) 0.036(5) 0.034(5) 0.005(4) C2 0.080(5) 0.027(3) 0.030(3) 0.012(3) 0.004(3) -0.015(3) C7 0.158(10) 0.062(5) 0.043(5) 0.003(4) 0.034(6) -0.024(6) C1 0.026(3) 0.041(4) 0.070(5) 0.033(3) -0.011(3) -0.006(3) C6 0.061(6) 0.070(6) 0.134(9) 0.059(6) -0.045(6) -0.010(5) C5 0.039(4) 0.024(3) 0.060(4) 0.010(3) 0.020(3) 0.005(3) C10 0.084(6) 0.040(4) 0.126(8) 0.015(5) 0.052(6) 0.018(4) In1 0.0211(2) 0.0229(2) 0.0253(2) 0.00091(15) -0.00207(16) -0.00199(15) C11 0.023(3) 0.030(3) 0.030(3) -0.004(2) -0.001(2) -0.003(2) Si1 0.0275(9) 0.0434(10) 0.0571(12) -0.0081(9) -0.0147(9) 0.0052(8) C111 0.037(4) 0.065(5) 0.112(7) -0.014(5) -0.031(5) -0.001(4) C112 0.039(4) 0.058(5) 0.102(7) -0.020(5) -0.002(4) 0.012(4) C113 0.095(7) 0.058(5) 0.067(5) 0.015(4) -0.027(5) 0.019(5) Si3 0.0416(10) 0.0437(10) 0.0346(9) -0.0079(8) 0.0054(8) -0.0040(8) C121 0.080(6) 0.072(5) 0.051(5) -0.007(4) 0.027(4) -0.026(5) C122 0.076(6) 0.082(6) 0.043(4) -0.024(4) -0.003(4) -0.006(5) C123 0.046(4) 0.055(4) 0.079(6) -0.029(4) 0.002(4) 0.012(4) Si2 0.0418(10) 0.0315(9) 0.0403(10) 0.0003(7) -0.0031(8) -0.0129(8) C131 0.051(4) 0.044(4) 0.065(5) -0.006(3) -0.008(4) -0.018(3) C132 0.073(5) 0.028(3) 0.065(5) 0.008(3) -0.019(4) -0.002(3) C133 0.062(5) 0.073(5) 0.066(5) -0.007(4) 0.025(4) -0.035(4) In2 0.0264(2) 0.0231(2) 0.0236(2) 0.00236(15) 0.00692(16) -0.00145(16) C12 0.038(3) 0.026(3) 0.020(3) 0.000(2) 0.009(2) 0.000(2) Si6 0.0915(17) 0.0357(10) 0.0466(12) -0.0105(9) 0.0219(12) -0.0122(11) C211 0.117(8) 0.065(5) 0.049(5) -0.032(4) 0.032(5) -0.017(5) C212 0.139(9) 0.032(4) 0.082(6) 0.012(4) 0.048(6) 0.015(5) C213 0.108(8) 0.068(5) 0.059(5) -0.017(4) 0.018(5) -0.050(5) Si5 0.0359(9) 0.0448(10) 0.0298(9) 0.0047(7) 0.0038(8) -0.0012(8) C221 0.052(5) 0.090(6) 0.044(4) -0.003(4) -0.004(4) -0.009(4) C222 0.064(5) 0.052(4) 0.038(4) 0.012(3) 0.014(4) 0.000(4) C223 0.051(4) 0.043(4) 0.039(4) 0.008(3) 0.007(3) 0.013(3) Si4 0.0339(10) 0.0518(11) 0.0369(10) 0.0026(8) 0.0063(8) 0.0074(8) C231 0.049(5) 0.094(6) 0.059(5) -0.005(5) 0.020(4) 0.016(4) C232 0.051(5) 0.092(6) 0.045(4) 0.012(4) -0.004(4) 0.020(4) C233 0.030(4) 0.064(5) 0.061(5) -0.002(4) -0.003(3) -0.015(3) In3 0.0195(2) 0.0236(2) 0.0336(2) 0.00334(16) -0.00184(17) 0.00176(16) C13 0.018(3) 0.022(3) 0.038(3) -0.003(2) -0.008(2) 0.004(2) Si9 0.0377(11) 0.0599(12) 0.0533(12) -0.0158(10) 0.0006(9) 0.0122(9) C311 0.032(4) 0.082(6) 0.085(6) -0.014(5) 0.008(4) 0.012(4) C312 0.087(7) 0.083(6) 0.102(7) -0.059(6) -0.037(6) 0.049(5) C313 0.061(5) 0.105(7) 0.055(5) 0.000(5) 0.013(4) 0.013(5) Si7 0.0439(11) 0.0452(11) 0.0487(11) -0.0148(9) -0.0154(9) 0.0019(9) C321 0.079(6) 0.049(5) 0.118(8) 0.009(5) -0.028(6) -0.029(5) C322 0.083(6) 0.067(5) 0.069(6) -0.041(4) -0.024(5) 0.027(5) C323 0.055(5) 0.066(5) 0.056(5) -0.012(4) -0.026(4) 0.002(4) Si8 0.0368(11) 0.0513(12) 0.0786(15) 0.0266(11) -0.0151(11) -0.0038(9) C331 0.069(6) 0.145(10) 0.079(7) 0.035(7) 0.024(5) 0.000(6) C332 0.054(5) 0.072(6) 0.127(8) 0.043(6) -0.030(6) -0.026(4) C333 0.065(6) 0.057(5) 0.113(8) 0.029(5) -0.039(6) 0.007(4) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic= ) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Cl1 In3 2.6302(16) . ? Cl1 In1 2.7182(17) . ? Cl2 In2 2.6215(15) . ? Cl2 In1 2.7006(16) . ? Rh1 C2 2.217(6) . ? Rh1 C1 2.221(6) . ? Rh1 C3 2.238(6) . ? Rh1 C5 2.244(6) . ? Rh1 C4 2.254(6) . ? Rh1 In2 2.5617(7) . ? Rh1 In3 2.5618(6) . ? Rh1 In1 2.6244(6) . ? C4 C5 1.392(9) . ? C4 C3 1.405(9) . ? C4 C9 1.525(9) . ? C9 H41A 0.9700 . ? C9 H41B 0.9700 . ? C9 H41C 0.9700 . ? C3 C2 1.432(9) . ? C3 C8 1.509(9) . ? C8 H42A 0.9700 . ? C8 H42B 0.9700 . ? C8 H42C 0.9700 . ? C2 C1 1.430(10) . ? C2 C7 1.488(10) . ? C7 H43A 0.9700 . ? C7 H43B 0.9700 . ? C7 H43C 0.9700 . ? C1 C5 1.406(10) . ? C1 C6 1.501(9) . ? C6 H44A 0.9700 . ? C6 H44B 0.9700 . ? C6 H44C 0.9700 . ? C5 C10 1.513(10) . ? C10 H45A 0.9700 . ? C10 H45B 0.9700 . ? C10 H45C 0.9700 . ? In1 C11 2.257(5) . ? In1 In3 3.3560(7) . ? C11 Si1 1.887(6) . ? C11 Si3 1.898(6) . ? C11 Si2 1.903(6) . ? Si1 C113 1.872(8) . ? Si1 C112 1.873(8) . ? Si1 C111 1.880(7) . ? C111 H11A 0.9700 . ? C111 H11B 0.9700 . ? C111 H11C 0.9700 . ? C112 H11D 0.9700 . ? C112 H11E 0.9700 . ? C112 H11F 0.9700 . ? C113 H11G 0.9700 . ? C113 H11H 0.9700 . ? C113 H11I 0.9700 . ? Si3 C121 1.869(8) . ? Si3 C122 1.879(7) . ? Si3 C123 1.881(7) . ? C121 H12A 0.9700 . ? C121 H12B 0.9700 . ? C121 H12C 0.9700 . ? C122 H12D 0.9700 . ? C122 H12E 0.9700 . ? C122 H12F 0.9700 . ? C123 H12G 0.9700 . ? C123 H12H 0.9700 . ? C123 H12I 0.9700 . ? Si2 C132 1.876(7) . ? Si2 C133 1.876(8) . ? Si2 C131 1.885(6) . ? C131 H13A 0.9700 . ? C131 H13B 0.9700 . ? C131 H13C 0.9700 . ? C132 H13D 0.9700 . ? C132 H13E 0.9700 . ? C132 H13F 0.9700 . ? C133 H13G 0.9700 . ? C133 H13H 0.9700 . ? C133 H13I 0.9700 . ? In2 C12 2.241(5) . ? C12 Si6 1.885(6) . ? C12 Si4 1.887(6) . ? C12 Si5 1.912(6) . ? Si6 C211 1.883(7) . ? Si6 C213 1.889(9) . ? Si6 C212 1.908(9) . ? C211 H21A 0.9700 . ? C211 H21B 0.9700 . ? C211 H21C 0.9700 . ? C212 H21D 0.9700 . ? C212 H21E 0.9700 . ? C212 H21F 0.9700 . ? C213 H21G 0.9700 . ? C213 H21H 0.9700 . ? C213 H21I 0.9700 . ? Si5 C223 1.864(6) . ? Si5 C221 1.879(7) . ? Si5 C222 1.884(7) . ? C221 H22A 0.9700 . ? C221 H22B 0.9700 . ? C221 H22C 0.9700 . ? C222 H22D 0.9700 . ? C222 H22E 0.9700 . ? C222 H22F 0.9700 . ? C223 H22G 0.9700 . ? C223 H22H 0.9700 . ? C223 H22I 0.9700 . ? Si4 C233 1.872(7) . ? Si4 C231 1.878(8) . ? Si4 C232 1.885(7) . ? C231 H23A 0.9700 . ? C231 H23B 0.9700 . ? C231 H23C 0.9700 . ? C232 H23D 0.9700 . ? C232 H23E 0.9700 . ? C232 H23F 0.9700 . ? C233 H23G 0.9700 . ? C233 H23H 0.9700 . ? C233 H23I 0.9700 . ? In3 C13 2.218(5) . ? C13 Si9 1.873(6) . ? C13 Si7 1.880(5) . ? C13 Si8 1.916(6) . ? Si9 C313 1.865(9) . ? Si9 C311 1.875(7) . ? Si9 C312 1.903(8) . ? C311 H31A 0.9700 . ? C311 H31B 0.9700 . ? C311 H31C 0.9700 . ? C312 H31D 0.9700 . ? C312 H31E 0.9700 . ? C312 H31F 0.9700 . ? C313 H31G 0.9700 . ? C313 H31H 0.9700 . ? C313 H31I 0.9700 . ? Si7 C323 1.861(7) . ? Si7 C322 1.864(8) . ? Si7 C321 1.903(9) . ? C321 H32A 0.9700 . ? C321 H32B 0.9700 . ? C321 H32C 0.9700 . ? C322 H32D 0.9700 . ? C322 H32E 0.9700 . ? C322 H32F 0.9700 . ? C323 H32G 0.9700 . ? C323 H32H 0.9700 . ? C323 H32I 0.9700 . ? Si8 C332 1.839(8) . ? Si8 C333 1.869(7) . ? Si8 C331 1.878(10) . ? C331 H33A 0.9700 . ? C331 H33B 0.9700 . ? C331 H33C 0.9700 . ? C332 H33D 0.9700 . ? C332 H33E 0.9700 . ? C332 H33F 0.9700 . ? C333 H33G 0.9700 . ? C333 H33H 0.9700 . ? C333 H33I 0.9700 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag In3 Cl1 In1 77.71(5) . . ? In2 Cl2 In1 81.62(4) . . ? C2 Rh1 C1 37.6(3) . . ? C2 Rh1 C3 37.5(2) . . ? C1 Rh1 C3 62.0(2) . . ? C2 Rh1 C5 61.8(2) . . ? C1 Rh1 C5 36.7(3) . . ? C3 Rh1 C5 60.9(2) . . ? C2 Rh1 C4 61.8(2) . . ? C1 Rh1 C4 61.2(2) . . ? C3 Rh1 C4 36.4(2) . . ? C5 Rh1 C4 36.1(2) . . ? C2 Rh1 In2 157.0(2) . . ? C1 Rh1 In2 119.5(2) . . ? C3 Rh1 In2 146.47(17) . . ? C5 Rh1 In2 99.38(17) . . ? C4 Rh1 In2 111.65(16) . . ? C2 Rh1 In3 114.5(2) . . ? C1 Rh1 In3 151.95(19) . . ? C3 Rh1 In3 93.49(14) . . ? C5 Rh1 In3 143.25(18) . . ? C4 Rh1 In3 107.82(16) . . ? In2 Rh1 In3 88.43(2) . . ? C2 Rh1 In1 100.04(16) . . ? C1 Rh1 In1 103.70(18) . . ? C3 Rh1 In1 129.12(17) . . ? C5 Rh1 In1 135.63(18) . . ? C4 Rh1 In1 161.72(15) . . ? In2 Rh1 In1 84.244(19) . . ? In3 Rh1 In1 80.64(2) . . ? C5 C4 C3 108.5(6) . . ? C5 C4 C9 126.5(7) . . ? C3 C4 C9 123.6(6) . . ? C5 C4 Rh1 71.6(3) . . ? C3 C4 Rh1 71.2(3) . . ? C9 C4 Rh1 133.4(4) . . ? C4 C9 H41A 109.5 . . ? C4 C9 H41B 109.5 . . ? H41A C9 H41B 109.5 . . ? C4 C9 H41C 109.5 . . ? H41A C9 H41C 109.5 . . ? H41B C9 H41C 109.5 . . ? C4 C3 C2 108.1(6) . . ? C4 C3 C8 125.8(7) . . ? C2 C3 C8 124.8(7) . . ? C4 C3 Rh1 72.4(3) . . ? C2 C3 Rh1 70.5(3) . . ? C8 C3 Rh1 133.3(4) . . ? C3 C8 H42A 109.5 . . ? C3 C8 H42B 109.5 . . ? H42A C8 H42B 109.5 . . ? C3 C8 H42C 109.5 . . ? H42A C8 H42C 109.5 . . ? H42B C8 H42C 109.5 . . ? C1 C2 C3 106.6(6) . . ? C1 C2 C7 126.2(8) . . ? C3 C2 C7 125.8(8) . . ? C1 C2 Rh1 71.4(4) . . ? C3 C2 Rh1 72.0(3) . . ? C7 C2 Rh1 132.1(5) . . ? C2 C7 H43A 109.5 . . ? C2 C7 H43B 109.5 . . ? H43A C7 H43B 109.5 . . ? C2 C7 H43C 109.5 . . ? H43A C7 H43C 109.5 . . ? H43B C7 H43C 109.5 . . ? C5 C1 C2 107.8(5) . . ? C5 C1 C6 124.1(8) . . ? C2 C1 C6 126.9(8) . . ? C5 C1 Rh1 72.5(3) . . ? C2 C1 Rh1 71.1(3) . . ? C6 C1 Rh1 131.8(5) . . ? C1 C6 H44A 109.5 . . ? C1 C6 H44B 109.5 . . ? H44A C6 H44B 109.5 . . ? C1 C6 H44C 109.5 . . ? H44A C6 H44C 109.5 . . ? H44B C6 H44C 109.5 . . ? C4 C5 C1 108.9(6) . . ? C4 C5 C10 123.1(7) . . ? C1 C5 C10 126.8(7) . . ? C4 C5 Rh1 72.4(3) . . ? C1 C5 Rh1 70.8(3) . . ? C10 C5 Rh1 132.5(5) . . ? C5 C10 H45A 109.5 . . ? C5 C10 H45B 109.5 . . ? H45A C10 H45B 109.5 . . ? C5 C10 H45C 109.5 . . ? H45A C10 H45C 109.5 . . ? H45B C10 H45C 109.5 . . ? C11 In1 Rh1 159.91(14) . . ? C11 In1 Cl2 100.94(15) . . ? Rh1 In1 Cl2 92.72(4) . . ? C11 In1 Cl1 99.37(15) . . ? Rh1 In1 Cl1 93.71(4) . . ? Cl2 In1 Cl1 96.01(6) . . ? C11 In1 In3 148.44(14) . . ? Rh1 In1 In3 48.867(13) . . ? Cl2 In1 In3 78.42(4) . . ? Cl1 In1 In3 49.98(3) . . ? Si1 C11 Si3 110.3(3) . . ? Si1 C11 Si2 111.3(3) . . ? Si3 C11 Si2 109.8(3) . . ? Si1 C11 In1 103.9(2) . . ? Si3 C11 In1 110.1(3) . . ? Si2 C11 In1 111.4(2) . . ? C113 Si1 C112 104.9(4) . . ? C113 Si1 C111 106.3(4) . . ? C112 Si1 C111 105.8(4) . . ? C113 Si1 C11 112.4(4) . . ? C112 Si1 C11 111.5(3) . . ? C111 Si1 C11 115.3(3) . . ? Si1 C111 H11A 109.5 . . ? Si1 C111 H11B 109.5 . . ? H11A C111 H11B 109.5 . . ? Si1 C111 H11C 109.5 . . ? H11A C111 H11C 109.5 . . ? H11B C111 H11C 109.5 . . ? Si1 C112 H11D 109.5 . . ? Si1 C112 H11E 109.5 . . ? H11D C112 H11E 109.5 . . ? Si1 C112 H11F 109.5 . . ? H11D C112 H11F 109.5 . . ? H11E C112 H11F 109.5 . . ? Si1 C113 H11G 109.5 . . ? Si1 C113 H11H 109.5 . . ? H11G C113 H11H 109.5 . . ? Si1 C113 H11I 109.5 . . ? H11G C113 H11I 109.5 . . ? H11H C113 H11I 109.5 . . ? C121 Si3 C122 105.5(4) . . ? C121 Si3 C123 104.8(4) . . ? C122 Si3 C123 104.3(4) . . ? C121 Si3 C11 113.5(3) . . ? C122 Si3 C11 113.5(3) . . ? C123 Si3 C11 114.2(3) . . ? Si3 C121 H12A 109.5 . . ? Si3 C121 H12B 109.5 . . ? H12A C121 H12B 109.5 . . ? Si3 C121 H12C 109.5 . . ? H12A C121 H12C 109.5 . . ? H12B C121 H12C 109.5 . . ? Si3 C122 H12D 109.5 . . ? Si3 C122 H12E 109.5 . . ? H12D C122 H12E 109.5 . . ? Si3 C122 H12F 109.5 . . ? H12D C122 H12F 109.5 . . ? H12E C122 H12F 109.5 . . ? Si3 C123 H12G 109.5 . . ? Si3 C123 H12H 109.5 . . ? H12G C123 H12H 109.5 . . ? Si3 C123 H12I 109.5 . . ? H12G C123 H12I 109.5 . . ? H12H C123 H12I 109.5 . . ? C132 Si2 C133 108.0(4) . . ? C132 Si2 C131 104.7(3) . . ? C133 Si2 C131 102.8(3) . . ? C132 Si2 C11 113.8(3) . . ? C133 Si2 C11 114.5(3) . . ? C131 Si2 C11 112.1(3) . . ? Si2 C131 H13A 109.5 . . ? Si2 C131 H13B 109.5 . . ? H13A C131 H13B 109.5 . . ? Si2 C131 H13C 109.5 . . ? H13A C131 H13C 109.5 . . ? H13B C131 H13C 109.5 . . ? Si2 C132 H13D 109.5 . . ? Si2 C132 H13E 109.5 . . ? H13D C132 H13E 109.5 . . ? Si2 C132 H13F 109.5 . . ? H13D C132 H13F 109.5 . . ? H13E C132 H13F 109.5 . . ? Si2 C133 H13G 109.5 . . ? Si2 C133 H13H 109.5 . . ? H13G C133 H13H 109.5 . . ? Si2 C133 H13I 109.5 . . ? H13G C133 H13I 109.5 . . ? H13H C133 H13I 109.5 . . ? C12 In2 Rh1 159.81(14) . . ? C12 In2 Cl2 103.64(14) . . ? Rh1 In2 Cl2 96.06(4) . . ? Si6 C12 Si4 111.7(3) . . ? Si6 C12 Si5 109.7(3) . . ? Si4 C12 Si5 110.7(3) . . ? Si6 C12 In2 106.0(3) . . ? Si4 C12 In2 105.2(2) . . ? Si5 C12 In2 113.4(3) . . ? C211 Si6 C12 115.9(3) . . ? C211 Si6 C213 105.9(4) . . ? C12 Si6 C213 110.1(3) . . ? C211 Si6 C212 102.9(4) . . ? C12 Si6 C212 112.0(3) . . ? C213 Si6 C212 109.7(4) . . ? Si6 C211 H21A 109.5 . . ? Si6 C211 H21B 109.5 . . ? H21A C211 H21B 109.5 . . ? Si6 C211 H21C 109.5 . . ? H21A C211 H21C 109.5 . . ? H21B C211 H21C 109.5 . . ? Si6 C212 H21D 109.5 . . ? Si6 C212 H21E 109.5 . . ? H21D C212 H21E 109.5 . . ? Si6 C212 H21F 109.5 . . ? H21D C212 H21F 109.5 . . ? H21E C212 H21F 109.5 . . ? Si6 C213 H21G 109.5 . . ? Si6 C213 H21H 109.5 . . ? H21G C213 H21H 109.5 . . ? Si6 C213 H21I 109.5 . . ? H21G C213 H21I 109.5 . . ? H21H C213 H21I 109.5 . . ? C223 Si5 C221 105.4(4) . . ? C223 Si5 C222 105.2(3) . . ? C221 Si5 C222 106.2(3) . . ? C223 Si5 C12 115.6(3) . . ? C221 Si5 C12 112.7(3) . . ? C222 Si5 C12 111.1(3) . . ? Si5 C221 H22A 109.5 . . ? Si5 C221 H22B 109.5 . . ? H22A C221 H22B 109.5 . . ? Si5 C221 H22C 109.5 . . ? H22A C221 H22C 109.5 . . ? H22B C221 H22C 109.5 . . ? Si5 C222 H22D 109.5 . . ? Si5 C222 H22E 109.5 . . ? H22D C222 H22E 109.5 . . ? Si5 C222 H22F 109.5 . . ? H22D C222 H22F 109.5 . . ? H22E C222 H22F 109.5 . . ? Si5 C223 H22G 109.5 . . ? Si5 C223 H22H 109.5 . . ? H22G C223 H22H 109.5 . . ? Si5 C223 H22I 109.5 . . ? H22G C223 H22I 109.5 . . ? H22H C223 H22I 109.5 . . ? C233 Si4 C231 106.4(4) . . ? C233 Si4 C232 107.3(4) . . ? C231 Si4 C232 105.3(4) . . ? C233 Si4 C12 113.8(3) . . ? C231 Si4 C12 113.8(3) . . ? C232 Si4 C12 109.8(3) . . ? Si4 C231 H23A 109.5 . . ? Si4 C231 H23B 109.5 . . ? H23A C231 H23B 109.5 . . ? Si4 C231 H23C 109.5 . . ? H23A C231 H23C 109.5 . . ? H23B C231 H23C 109.5 . . ? Si4 C232 H23D 109.5 . . ? Si4 C232 H23E 109.5 . . ? H23D C232 H23E 109.5 . . ? Si4 C232 H23F 109.5 . . ? H23D C232 H23F 109.5 . . ? H23E C232 H23F 109.5 . . ? Si4 C233 H23G 109.5 . . ? Si4 C233 H23H 109.5 . . ? H23G C233 H23H 109.5 . . ? Si4 C233 H23I 109.5 . . ? H23G C233 H23I 109.5 . . ? H23H C233 H23I 109.5 . . ? C13 In3 Rh1 159.96(13) . . ? C13 In3 Cl1 102.01(14) . . ? Rh1 In3 Cl1 97.33(4) . . ? C13 In3 In1 149.09(13) . . ? Rh1 In3 In1 50.496(16) . . ? Cl1 In3 In1 52.31(4) . . ? Si9 C13 Si7 112.4(3) . . ? Si9 C13 Si8 111.1(3) . . ? Si7 C13 Si8 109.9(3) . . ? Si9 C13 In3 110.3(3) . . ? Si7 C13 In3 107.1(2) . . ? Si8 C13 In3 105.7(2) . . ? C313 Si9 C13 111.5(3) . . ? C313 Si9 C311 108.1(4) . . ? C13 Si9 C311 113.2(3) . . ? C313 Si9 C312 106.2(4) . . ? C13 Si9 C312 113.7(4) . . ? C311 Si9 C312 103.6(4) . . ? Si9 C311 H31A 109.5 . . ? Si9 C311 H31B 109.5 . . ? H31A C311 H31B 109.5 . . ? Si9 C311 H31C 109.5 . . ? H31A C311 H31C 109.5 . . ? H31B C311 H31C 109.5 . . ? Si9 C312 H31D 109.5 . . ? Si9 C312 H31E 109.5 . . ? H31D C312 H31E 109.5 . . ? Si9 C312 H31F 109.5 . . ? H31D C312 H31F 109.5 . . ? H31E C312 H31F 109.5 . . ? Si9 C313 H31G 109.5 . . ? Si9 C313 H31H 109.5 . . ? H31G C313 H31H 109.5 . . ? Si9 C313 H31I 109.5 . . ? H31G C313 H31I 109.5 . . ? H31H C313 H31I 109.5 . . ? C323 Si7 C322 107.4(4) . . ? C323 Si7 C13 114.7(3) . . ? C322 Si7 C13 112.7(3) . . ? C323 Si7 C321 105.3(4) . . ? C322 Si7 C321 103.9(5) . . ? C13 Si7 C321 112.1(4) . . ? Si7 C321 H32A 109.5 . . ? Si7 C321 H32B 109.5 . . ? H32A C321 H32B 109.5 . . ? Si7 C321 H32C 109.5 . . ? H32A C321 H32C 109.5 . . ? H32B C321 H32C 109.5 . . ? Si7 C322 H32D 109.5 . . ? Si7 C322 H32E 109.5 . . ? H32D C322 H32E 109.5 . . ? Si7 C322 H32F 109.5 . . ? H32D C322 H32F 109.5 . . ? H32E C322 H32F 109.5 . . ? Si7 C323 H32G 109.5 . . ? Si7 C323 H32H 109.5 . . ? H32G C323 H32H 109.5 . . ? Si7 C323 H32I 109.5 . . ? H32G C323 H32I 109.5 . . ? H32H C323 H32I 109.5 . . ? C332 Si8 C333 107.0(4) . . ? C332 Si8 C331 104.0(5) . . ? C333 Si8 C331 106.4(5) . . ? C332 Si8 C13 113.6(3) . . ? C333 Si8 C13 112.8(3) . . ? C331 Si8 C13 112.5(4) . . ? Si8 C331 H33A 109.5 . . ? Si8 C331 H33B 109.5 . . ? H33A C331 H33B 109.5 . . ? Si8 C331 H33C 109.5 . . ? H33A C331 H33C 109.5 . . ? H33B C331 H33C 109.5 . . ? Si8 C332 H33D 109.5 . . ? Si8 C332 H33E 109.5 . . ? H33D C332 H33E 109.5 . . ? Si8 C332 H33F 109.5 . . ? H33D C332 H33F 109.5 . . ? H33E C332 H33F 109.5 . . ? Si8 C333 H33G 109.5 . . ? Si8 C333 H33H 109.5 . . ? H33G C333 H33H 109.5 . . ? Si8 C333 H33I 109.5 . . ? H33G C333 H33I 109.5 . . ? H33H C333 H33I 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C2 Rh1 C4 C5 -80.0(4) . . . . ? C1 Rh1 C4 C5 -37.0(4) . . . . ? C3 Rh1 C4 C5 -117.9(5) . . . . ? In2 Rh1 C4 C5 75.7(4) . . . . ? In3 Rh1 C4 C5 171.2(4) . . . . ? In1 Rh1 C4 C5 -73.4(7) . . . . ? C2 Rh1 C4 C3 37.9(4) . . . . ? C1 Rh1 C4 C3 80.9(4) . . . . ? C5 Rh1 C4 C3 117.9(5) . . . . ? In2 Rh1 C4 C3 -166.4(3) . . . . ? In3 Rh1 C4 C3 -70.9(3) . . . . ? In1 Rh1 C4 C3 44.5(7) . . . . ? C2 Rh1 C4 C9 156.7(8) . . . . ? C1 Rh1 C4 C9 -160.2(8) . . . . ? C3 Rh1 C4 C9 118.9(9) . . . . ? C5 Rh1 C4 C9 -123.2(9) . . . . ? In2 Rh1 C4 C9 -47.6(7) . . . . ? In3 Rh1 C4 C9 48.0(7) . . . . ? In1 Rh1 C4 C9 163.4(5) . . . . ? C5 C4 C3 C2 0.4(6) . . . . ? C9 C4 C3 C2 168.1(6) . . . . ? Rh1 C4 C3 C2 -61.8(4) . . . . ? C5 C4 C3 C8 -166.7(6) . . . . ? C9 C4 C3 C8 1.0(10) . . . . ? Rh1 C4 C3 C8 131.1(6) . . . . ? C5 C4 C3 Rh1 62.2(4) . . . . ? C9 C4 C3 Rh1 -130.1(6) . . . . ? C2 Rh1 C3 C4 -117.2(5) . . . . ? C1 Rh1 C3 C4 -78.5(4) . . . . ? C5 Rh1 C3 C4 -36.6(4) . . . . ? In2 Rh1 C3 C4 23.3(5) . . . . ? In3 Rh1 C3 C4 115.7(3) . . . . ? In1 Rh1 C3 C4 -163.5(3) . . . . ? C1 Rh1 C3 C2 38.7(4) . . . . ? C5 Rh1 C3 C2 80.7(4) . . . . ? C4 Rh1 C3 C2 117.2(5) . . . . ? In2 Rh1 C3 C2 140.5(4) . . . . ? In3 Rh1 C3 C2 -127.1(4) . . . . ? In1 Rh1 C3 C2 -46.3(4) . . . . ? C2 Rh1 C3 C8 119.8(9) . . . . ? C1 Rh1 C3 C8 158.5(9) . . . . ? C5 Rh1 C3 C8 -159.5(9) . . . . ? C4 Rh1 C3 C8 -123.0(9) . . . . ? In2 Rh1 C3 C8 -99.7(8) . . . . ? In3 Rh1 C3 C8 -7.3(8) . . . . ? In1 Rh1 C3 C8 73.5(8) . . . . ? C4 C3 C2 C1 -0.4(6) . . . . ? C8 C3 C2 C1 166.9(6) . . . . ? Rh1 C3 C2 C1 -63.4(4) . . . . ? C4 C3 C2 C7 -167.5(6) . . . . ? C8 C3 C2 C7 -0.2(10) . . . . ? Rh1 C3 C2 C7 129.5(7) . . . . ? C4 C3 C2 Rh1 63.0(4) . . . . ? C8 C3 C2 Rh1 -129.7(6) . . . . ? C3 Rh1 C2 C1 115.3(5) . . . . ? C5 Rh1 C2 C1 37.3(4) . . . . ? C4 Rh1 C2 C1 78.4(4) . . . . ? In2 Rh1 C2 C1 -0.4(7) . . . . ? In3 Rh1 C2 C1 176.3(3) . . . . ? In1 Rh1 C2 C1 -99.5(4) . . . . ? C1 Rh1 C2 C3 -115.3(5) . . . . ? C5 Rh1 C2 C3 -78.0(4) . . . . ? C4 Rh1 C2 C3 -36.8(3) . . . . ? In2 Rh1 C2 C3 -115.7(5) . . . . ? In3 Rh1 C2 C3 61.1(4) . . . . ? In1 Rh1 C2 C3 145.3(3) . . . . ? C1 Rh1 C2 C7 122.4(10) . . . . ? C3 Rh1 C2 C7 -122.4(11) . . . . ? C5 Rh1 C2 C7 159.7(10) . . . . ? C4 Rh1 C2 C7 -159.2(10) . . . . ? In2 Rh1 C2 C7 121.9(8) . . . . ? In3 Rh1 C2 C7 -61.3(9) . . . . ? In1 Rh1 C2 C7 22.9(9) . . . . ? C3 C2 C1 C5 0.2(6) . . . . ? C7 C2 C1 C5 167.3(6) . . . . ? Rh1 C2 C1 C5 -63.6(4) . . . . ? C3 C2 C1 C6 -167.6(6) . . . . ? C7 C2 C1 C6 -0.6(11) . . . . ? Rh1 C2 C1 C6 128.5(7) . . . . ? C3 C2 C1 Rh1 63.9(4) . . . . ? C7 C2 C1 Rh1 -129.1(7) . . . . ? C2 Rh1 C1 C5 116.6(5) . . . . ? C3 Rh1 C1 C5 78.0(4) . . . . ? C4 Rh1 C1 C5 36.3(4) . . . . ? In2 Rh1 C1 C5 -63.6(4) . . . . ? In3 Rh1 C1 C5 109.5(5) . . . . ? In1 Rh1 C1 C5 -154.7(3) . . . . ? C3 Rh1 C1 C2 -38.6(4) . . . . ? C5 Rh1 C1 C2 -116.6(5) . . . . ? C4 Rh1 C1 C2 -80.2(4) . . . . ? In2 Rh1 C1 C2 179.8(3) . . . . ? In3 Rh1 C1 C2 -7.1(7) . . . . ? In1 Rh1 C1 C2 88.7(4) . . . . ? C2 Rh1 C1 C6 -123.0(11) . . . . ? C3 Rh1 C1 C6 -161.6(10) . . . . ? C5 Rh1 C1 C6 120.4(11) . . . . ? C4 Rh1 C1 C6 156.8(10) . . . . ? In2 Rh1 C1 C6 56.8(9) . . . . ? In3 Rh1 C1 C6 -130.1(8) . . . . ? In1 Rh1 C1 C6 -34.3(9) . . . . ? C3 C4 C5 C1 -0.2(7) . . . . ? C9 C4 C5 C1 -167.5(6) . . . . ? Rh1 C4 C5 C1 61.7(4) . . . . ? C3 C4 C5 C10 168.4(6) . . . . ? C9 C4 C5 C10 1.2(10) . . . . ? Rh1 C4 C5 C10 -129.7(7) . . . . ? C3 C4 C5 Rh1 -61.9(4) . . . . ? C9 C4 C5 Rh1 130.8(6) . . . . ? C2 C1 C5 C4 0.0(7) . . . . ? C6 C1 C5 C4 168.3(6) . . . . ? Rh1 C1 C5 C4 -62.7(4) . . . . ? C2 C1 C5 C10 -168.1(6) . . . . ? C6 C1 C5 C10 0.2(10) . . . . ? Rh1 C1 C5 C10 129.2(7) . . . . ? C2 C1 C5 Rh1 62.7(4) . . . . ? C6 C1 C5 Rh1 -129.0(6) . . . . ? C2 Rh1 C5 C4 79.9(4) . . . . ? C1 Rh1 C5 C4 118.1(6) . . . . ? C3 Rh1 C5 C4 36.9(4) . . . . ? In2 Rh1 C5 C4 -114.1(4) . . . . ? In3 Rh1 C5 C4 -14.0(6) . . . . ? In1 Rh1 C5 C4 154.5(3) . . . . ? C2 Rh1 C5 C1 -38.2(4) . . . . ? C3 Rh1 C5 C1 -81.2(4) . . . . ? C4 Rh1 C5 C1 -118.1(6) . . . . ? In2 Rh1 C5 C1 127.8(4) . . . . ? In3 Rh1 C5 C1 -132.2(4) . . . . ? In1 Rh1 C5 C1 36.4(5) . . . . ? C2 Rh1 C5 C10 -161.1(9) . . . . ? C1 Rh1 C5 C10 -122.8(9) . . . . ? C3 Rh1 C5 C10 156.0(9) . . . . ? C4 Rh1 C5 C10 119.1(9) . . . . ? In2 Rh1 C5 C10 4.9(8) . . . . ? In3 Rh1 C5 C10 105.0(7) . . . . ? In1 Rh1 C5 C10 -86.4(8) . . . . ? C2 Rh1 In1 C11 41.5(5) . . . . ? C1 Rh1 In1 C11 3.2(5) . . . . ? C3 Rh1 In1 C11 68.0(5) . . . . ? C5 Rh1 In1 C11 -18.2(5) . . . . ? C4 Rh1 In1 C11 35.6(7) . . . . ? In2 Rh1 In1 C11 -115.7(4) . . . . ? In3 Rh1 In1 C11 154.9(4) . . . . ? C2 Rh1 In1 Cl2 174.5(2) . . . . ? C1 Rh1 In1 Cl2 136.3(2) . . . . ? C3 Rh1 In1 Cl2 -158.91(19) . . . . ? C5 Rh1 In1 Cl2 114.8(2) . . . . ? C4 Rh1 In1 Cl2 168.6(5) . . . . ? In2 Rh1 In1 Cl2 17.31(5) . . . . ? In3 Rh1 In1 Cl2 -72.04(5) . . . . ? C2 Rh1 In1 Cl1 -89.2(2) . . . . ? C1 Rh1 In1 Cl1 -127.5(2) . . . . ? C3 Rh1 In1 Cl1 -62.70(19) . . . . ? C5 Rh1 In1 Cl1 -148.9(2) . . . . ? C4 Rh1 In1 Cl1 -95.2(5) . . . . ? In2 Rh1 In1 Cl1 113.52(5) . . . . ? In3 Rh1 In1 Cl1 24.17(5) . . . . ? C2 Rh1 In1 In3 -113.4(2) . . . . ? C1 Rh1 In1 In3 -151.7(2) . . . . ? C3 Rh1 In1 In3 -86.87(18) . . . . ? C5 Rh1 In1 In3 -173.1(2) . . . . ? C4 Rh1 In1 In3 -119.3(5) . . . . ? In2 Rh1 In1 In3 89.354(19) . . . . ? In2 Cl2 In1 C11 148.19(15) . . . . ? In2 Cl2 In1 Rh1 -17.01(4) . . . . ? In2 Cl2 In1 Cl1 -111.03(5) . . . . ? In2 Cl2 In1 In3 -64.01(4) . . . . ? In3 Cl1 In1 C11 171.55(15) . . . . ? In3 Cl1 In1 Rh1 -23.75(4) . . . . ? In3 Cl1 In1 Cl2 69.38(5) . . . . ? Rh1 In1 C11 Si1 30.9(6) . . . . ? Cl2 In1 C11 Si1 -101.0(2) . . . . ? Cl1 In1 C11 Si1 160.9(2) . . . . ? In3 In1 C11 Si1 173.32(8) . . . . ? Rh1 In1 C11 Si3 -87.2(5) . . . . ? Cl2 In1 C11 Si3 140.9(2) . . . . ? Cl1 In1 C11 Si3 42.8(3) . . . . ? In3 In1 C11 Si3 55.2(4) . . . . ? Rh1 In1 C11 Si2 150.8(2) . . . . ? Cl2 In1 C11 Si2 18.9(3) . . . . ? Cl1 In1 C11 Si2 -79.2(3) . . . . ? In3 In1 C11 Si2 -66.8(4) . . . . ? Si3 C11 Si1 C113 41.1(4) . . . . ? Si2 C11 Si1 C113 163.1(3) . . . . ? In1 C11 Si1 C113 -76.9(4) . . . . ? Si3 C11 Si1 C112 158.5(3) . . . . ? Si2 C11 Si1 C112 -79.5(4) . . . . ? In1 C11 Si1 C112 40.5(4) . . . . ? Si3 C11 Si1 C111 -80.9(5) . . . . ? Si2 C11 Si1 C111 41.2(5) . . . . ? In1 C11 Si1 C111 161.1(4) . . . . ? Si1 C11 Si3 C121 -79.2(4) . . . . ? Si2 C11 Si3 C121 157.9(4) . . . . ? In1 C11 Si3 C121 34.9(4) . . . . ? Si1 C11 Si3 C122 41.3(4) . . . . ? Si2 C11 Si3 C122 -81.7(4) . . . . ? In1 C11 Si3 C122 155.4(3) . . . . ? Si1 C11 Si3 C123 160.7(3) . . . . ? Si2 C11 Si3 C123 37.8(4) . . . . ? In1 C11 Si3 C123 -85.2(3) . . . . ? Si1 C11 Si2 C132 164.1(3) . . . . ? Si3 C11 Si2 C132 -73.6(4) . . . . ? In1 C11 Si2 C132 48.6(4) . . . . ? Si1 C11 Si2 C133 39.2(4) . . . . ? Si3 C11 Si2 C133 161.6(3) . . . . ? In1 C11 Si2 C133 -76.3(4) . . . . ? Si1 C11 Si2 C131 -77.4(4) . . . . ? Si3 C11 Si2 C131 44.9(4) . . . . ? In1 C11 Si2 C131 167.1(3) . . . . ? C2 Rh1 In2 C12 47.1(6) . . . . ? C1 Rh1 In2 C12 46.8(5) . . . . ? C3 Rh1 In2 C12 -36.0(5) . . . . ? C5 Rh1 In2 C12 14.0(5) . . . . ? C4 Rh1 In2 C12 -21.3(5) . . . . ? In3 Rh1 In2 C12 -129.9(4) . . . . ? In1 Rh1 In2 C12 149.3(4) . . . . ? C2 Rh1 In2 Cl2 -120.1(4) . . . . ? C1 Rh1 In2 Cl2 -120.4(2) . . . . ? C3 Rh1 In2 Cl2 156.8(3) . . . . ? C5 Rh1 In2 Cl2 -153.30(19) . . . . ? C4 Rh1 In2 Cl2 171.38(18) . . . . ? In3 Rh1 In2 Cl2 62.81(5) . . . . ? In1 Rh1 In2 Cl2 -17.94(5) . . . . ? In1 Cl2 In2 C12 -158.00(15) . . . . ? In1 Cl2 In2 Rh1 17.52(4) . . . . ? Rh1 In2 C12 Si6 16.1(6) . . . . ? Cl2 In2 C12 Si6 -176.9(2) . . . . ? Rh1 In2 C12 Si4 -102.4(4) . . . . ? Cl2 In2 C12 Si4 64.6(2) . . . . ? Rh1 In2 C12 Si5 136.6(3) . . . . ? Cl2 In2 C12 Si5 -56.5(3) . . . . ? Si4 C12 Si6 C211 -82.8(5) . . . . ? Si5 C12 Si6 C211 40.3(5) . . . . ? In2 C12 Si6 C211 163.1(4) . . . . ? Si4 C12 Si6 C213 157.1(4) . . . . ? Si5 C12 Si6 C213 -79.8(4) . . . . ? In2 C12 Si6 C213 43.0(4) . . . . ? Si4 C12 Si6 C212 34.7(4) . . . . ? Si5 C12 Si6 C212 157.9(4) . . . . ? In2 C12 Si6 C212 -79.3(4) . . . . ? Si6 C12 Si5 C223 162.1(3) . . . . ? Si4 C12 Si5 C223 -74.1(4) . . . . ? In2 C12 Si5 C223 43.9(4) . . . . ? Si6 C12 Si5 C221 40.8(4) . . . . ? Si4 C12 Si5 C221 164.6(3) . . . . ? In2 C12 Si5 C221 -77.5(4) . . . . ? Si6 C12 Si5 C222 -78.2(4) . . . . ? Si4 C12 Si5 C222 45.6(4) . . . . ? In2 C12 Si5 C222 163.5(3) . . . . ? Si6 C12 Si4 C233 163.4(3) . . . . ? Si5 C12 Si4 C233 40.7(4) . . . . ? In2 C12 Si4 C233 -82.1(3) . . . . ? Si6 C12 Si4 C231 41.2(4) . . . . ? Si5 C12 Si4 C231 -81.4(4) . . . . ? In2 C12 Si4 C231 155.7(3) . . . . ? Si6 C12 Si4 C232 -76.5(4) . . . . ? Si5 C12 Si4 C232 160.9(3) . . . . ? In2 C12 Si4 C232 38.1(4) . . . . ? C2 Rh1 In3 C13 -93.1(5) . . . . ? C1 Rh1 In3 C13 -88.4(6) . . . . ? C3 Rh1 In3 C13 -60.9(5) . . . . ? C5 Rh1 In3 C13 -18.0(5) . . . . ? C4 Rh1 In3 C13 -26.7(5) . . . . ? In2 Rh1 In3 C13 85.6(5) . . . . ? In1 Rh1 In3 C13 170.0(5) . . . . ? C2 Rh1 In3 Cl1 71.64(19) . . . . ? C1 Rh1 In3 Cl1 76.4(4) . . . . ? C3 Rh1 In3 Cl1 103.89(18) . . . . ? C5 Rh1 In3 Cl1 146.7(3) . . . . ? C4 Rh1 In3 Cl1 138.11(17) . . . . ? In2 Rh1 In3 Cl1 -109.62(5) . . . . ? In1 Rh1 In3 Cl1 -25.20(5) . . . . ? C2 Rh1 In3 In1 96.84(18) . . . . ? C1 Rh1 In3 In1 101.6(4) . . . . ? C3 Rh1 In3 In1 129.09(17) . . . . ? C5 Rh1 In3 In1 171.9(3) . . . . ? C4 Rh1 In3 In1 163.31(17) . . . . ? In2 Rh1 In3 In1 -84.424(19) . . . . ? In1 Cl1 In3 C13 -160.75(16) . . . . ? In1 Cl1 In3 Rh1 24.52(5) . . . . ? C11 In1 In3 C13 22.8(4) . . . . ? Rh1 In1 In3 C13 -173.4(3) . . . . ? Cl2 In1 In3 C13 -69.3(3) . . . . ? Cl1 In1 In3 C13 38.9(3) . . . . ? C11 In1 In3 Rh1 -163.8(3) . . . . ? Cl2 In1 In3 Rh1 104.08(4) . . . . ? Cl1 In1 In3 Rh1 -147.75(6) . . . . ? C11 In1 In3 Cl1 -16.1(3) . . . . ? Rh1 In1 In3 Cl1 147.75(6) . . . . ? Cl2 In1 In3 Cl1 -108.17(7) . . . . ? Rh1 In3 C13 Si9 120.8(4) . . . . ? Cl1 In3 C13 Si9 -43.8(3) . . . . ? In1 In3 C13 Si9 -74.3(4) . . . . ? Rh1 In3 C13 Si7 -1.8(7) . . . . ? Cl1 In3 C13 Si7 -166.4(2) . . . . ? In1 In3 C13 Si7 163.09(10) . . . . ? Rh1 In3 C13 Si8 -119.0(4) . . . . ? Cl1 In3 C13 Si8 76.4(2) . . . . ? In1 In3 C13 Si8 45.9(4) . . . . ? Si7 C13 Si9 C313 81.3(4) . . . . ? Si8 C13 Si9 C313 -155.1(4) . . . . ? In3 C13 Si9 C313 -38.2(4) . . . . ? Si7 C13 Si9 C311 -40.8(4) . . . . ? Si8 C13 Si9 C311 82.8(4) . . . . ? In3 C13 Si9 C311 -160.3(3) . . . . ? Si7 C13 Si9 C312 -158.7(3) . . . . ? Si8 C13 Si9 C312 -35.1(4) . . . . ? In3 C13 Si9 C312 81.9(4) . . . . ? Si9 C13 Si7 C323 81.9(4) . . . . ? Si8 C13 Si7 C323 -42.4(4) . . . . ? In3 C13 Si7 C323 -156.8(4) . . . . ? Si9 C13 Si7 C322 -154.8(4) . . . . ? Si8 C13 Si7 C322 80.9(4) . . . . ? In3 C13 Si7 C322 -33.5(4) . . . . ? Si9 C13 Si7 C321 -38.1(4) . . . . ? Si8 C13 Si7 C321 -162.4(4) . . . . ? In3 C13 Si7 C321 83.2(4) . . . . ? Si9 C13 Si8 C332 77.0(5) . . . . ? Si7 C13 Si8 C332 -158.0(4) . . . . ? In3 C13 Si8 C332 -42.7(5) . . . . ? Si9 C13 Si8 C333 -44.9(4) . . . . ? Si7 C13 Si8 C333 80.1(4) . . . . ? In3 C13 Si8 C333 -164.6(4) . . . . ? Si9 C13 Si8 C331 -165.2(4) . . . . ? Si7 C13 Si8 C331 -40.2(5) . . . . ? In3 C13 Si8 C331 75.1(4) . . . . ? _diffrn_measured_fraction_theta_max 0.976 _diffrn_reflns_theta_full 25.05 _diffrn_measured_fraction_theta_full 0.976 _refine_diff_density_max 1.942 _refine_diff_density_min -0.783 _refine_diff_density_rms 0.118 data_2 _database_code_CSD 204638 _publ_section_title ; Insertion of organoindium carbenoids into Rhodium halide bonds: Revisiting a classic type of transitionmetal-Group 13 metal bond formation.= ; _publ_section_abstract ; The insertion of InCp* and InC(SiMe3)3 into the Rh-Cl bonds of (RhCp*Cl2)2 is presented. The crystal structures of the two insertion products are given. ; _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C40 H60 Cl2 In3 Rh' _chemical_formula_weight 1059.15 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting orthorhombic _symmetry_space_group_name_H-M Pbca loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x-1/2, y-1/2, z' _cell_length_a 10.732(19) _cell_length_b 21.72(4) _cell_length_c 35.49(5) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 8272(24) _cell_formula_units_Z 8 _cell_measurement_temperature 213(2) _cell_measurement_reflns_used 60 _cell_measurement_theta_min 10 _cell_measurement_theta_max 15 _exptl_crystal_description prism _exptl_crystal_colour red _exptl_crystal_size_max 0.3 _exptl_crystal_size_mid 0.2 _exptl_crystal_size_min 0.2 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.701 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 4208 _exptl_absorpt_coefficient_mu 2.199 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 213(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'BRUKER SMART CCD1000' _diffrn_measurement_method '\w scan' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 21255 _diffrn_reflns_av_R_equivalents 0.0764 _diffrn_reflns_av_sigmaI/netI 0.0849 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -26 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_l_min -38 _diffrn_reflns_limit_l_max 39 _diffrn_reflns_theta_min 2.19 _diffrn_reflns_theta_max 25.49 _reflns_number_total 7199 _reflns_number_gt 4899 _reflns_threshold_expression >2sigma(I) _computing_data_collection SMART _computing_cell_refinement SMART _computing_data_reduction SAINT _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker axs SHELXTL-PLUS' _computing_publication_material SHELXL-97 _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w==1/[\s^2^(Fo^2^)+(0.0628P)^2^+7.2109P] where P==(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 7199 _refine_ls_number_parameters 415 _refine_ls_number_restraints 6 _refine_ls_R_factor_all 0.0906 _refine_ls_R_factor_gt 0.0558 _refine_ls_wR_factor_ref 0.1392 _refine_ls_wR_factor_gt 0.1241 _refine_ls_goodness_of_fit_ref 1.037 _refine_ls_restrained_S_all 1.037 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.39694(5) 0.32663(3) 0.156380(17) 0.01391(16) Uani 1 1 d . . . C15 C 0.3762(7) 0.3613(4) 0.2143(2) 0.0158(17) Uani 1 1 d . . . In3 In 0.60335(5) 0.38512(3) 0.147648(17) 0.01999(17) Uani 1 1 d . . . C34 C 0.5145(8) 0.5367(4) 0.1326(3) 0.026(2) Uani 1 1 d . . . In1 In 0.35517(6) 0.35692(4) 0.088938(18) 0.0331(2) Uani 1 1 d . . . In2 In 0.54444(6) 0.24446(3) 0.13208(2) 0.0344(2) Uani 1 1 d . . . C12 C 0.2036(7) 0.3296(4) 0.1797(2) 0.0215(19) Uani 1 1 d . . . C20 C 0.4613(8) 0.3993(4) 0.2377(2) 0.025(2) Uani 1 1 d . . . H4A H 0.4238 0.4064 0.2622 0.037 Uiso 1 1 calc R . . H4B H 0.4760 0.4384 0.2253 0.037 Uiso 1 1 calc R . . H4C H 0.5399 0.3778 0.2409 0.037 Uiso 1 1 calc R . . Cl2 Cl 0.75274(19) 0.33189(11) 0.19077(7) 0.0311(5) Uani 1 1 d . . . C24 C 0.5418(7) 0.1223(4) 0.1553(3) 0.021(2) Uani 1 1 d . . . Cl1 Cl 0.6848(2) 0.33057(11) 0.08510(7) 0.0356(6) Uani 1 1 d . . . C11 C 0.2755(7) 0.3823(4) 0.1918(2) 0.0184(18) Uani 1 1 d . . . C35 C 0.6003(8) 0.5028(4) 0.1131(2) 0.024(2) Uani 1 1 d . . . C32 C 0.6480(8) 0.5038(4) 0.1774(3) 0.026(2) Uani 1 1 d . . . C8 C 0.4714(9) 0.3772(5) 0.0005(3) 0.039(3) Uani 1 1 d . . . H9A H 0.4545 0.3759 -0.0263 0.058 Uiso 1 1 calc R . . H9B H 0.5375 0.3484 0.0065 0.058 Uiso 1 1 calc R . . H9C H 0.4968 0.4185 0.0075 0.058 Uiso 1 1 calc R . . C33 C 0.5447(8) 0.5386(4) 0.1718(3) 0.026(2) Uani 1 1 d . . . C23 C 0.6508(8) 0.1526(4) 0.1661(3) 0.025(2) Uani 1 1 d . . . C13 C 0.2640(7) 0.2768(4) 0.1937(2) 0.0204(19) Uani 1 1 d . . . C14 C 0.3717(7) 0.2974(4) 0.2144(2) 0.0154(17) Uani 1 1 d U . . C19 C 0.4532(8) 0.2573(4) 0.2381(3) 0.030(2) Uani 1 1 d . . . H18A H 0.4166 0.2528 0.2630 0.045 Uiso 1 1 calc R . . H18B H 0.5350 0.2760 0.2404 0.045 Uiso 1 1 calc R . . H18C H 0.4610 0.2171 0.2264 0.045 Uiso 1 1 calc R . . C36 C 0.8245(8) 0.4709(4) 0.1321(3) 0.042(3) Uani 1 1 d . . . H20A H 0.8616 0.5114 0.1297 0.063 Uiso 1 1 calc R . . H20B H 0.8336 0.4487 0.1086 0.063 Uiso 1 1 calc R . . H20C H 0.8661 0.4484 0.1521 0.063 Uiso 1 1 calc R . . C31 C 0.6879(7) 0.4773(4) 0.1415(3) 0.022(2) Uani 1 1 d . . . C29 C 0.4534(9) 0.0878(4) 0.1809(3) 0.037(2) Uani 1 1 d . . . H22A H 0.3849 0.0715 0.1661 0.055 Uiso 1 1 calc R . . H22B H 0.4212 0.1157 0.1999 0.055 Uiso 1 1 calc R . . H22C H 0.4974 0.0542 0.1930 0.055 Uiso 1 1 calc R . . C18 C 0.2172(9) 0.2137(4) 0.1907(3) 0.034(2) Uani 1 1 d . . . H23A H 0.1606 0.2055 0.2114 0.051 Uiso 1 1 calc R . . H23B H 0.2865 0.1852 0.1917 0.051 Uiso 1 1 calc R . . H23C H 0.1733 0.2088 0.1670 0.051 Uiso 1 1 calc R . . C2 C 0.3169(10) 0.2989(5) 0.0293(3) 0.034(2) Uani 1 1 d . . . C25 C 0.5313(8) 0.1253(4) 0.1151(3) 0.028(2) Uani 1 1 d . . . C39 C 0.4039(10) 0.5680(5) 0.1154(3) 0.052(3) Uani 1 1 d . . . H29A H 0.4022 0.5599 0.0886 0.078 Uiso 1 1 calc R . . H29B H 0.4096 0.6120 0.1197 0.078 Uiso 1 1 calc R . . H29C H 0.3283 0.5523 0.1269 0.078 Uiso 1 1 calc R . . C3 C 0.3558(9) 0.3600(5) 0.0219(2) 0.031(2) Uani 1 1 d . . . C27 C 0.8398(8) 0.1991(5) 0.1307(3) 0.043(3) Uani 1 1 d . . . H34A H 0.8986 0.1652 0.1315 0.064 Uiso 1 1 calc R . . H34B H 0.8550 0.2266 0.1517 0.064 Uiso 1 1 calc R . . H34C H 0.8500 0.2216 0.1072 0.064 Uiso 1 1 calc R . . C6 C 0.1262(12) 0.2473(6) 0.0587(3) 0.070(4) Uani 1 1 d . . . H39A H 0.0713 0.2329 0.0388 0.105 Uiso 1 1 calc R . . H39B H 0.0773 0.2580 0.0807 0.105 Uiso 1 1 calc R . . H39C H 0.1849 0.2150 0.0652 0.105 Uiso 1 1 calc R . . C21 C 0.6355(8) 0.1573(4) 0.1007(3) 0.027(2) Uani 1 1 d . . . C16 C 0.2378(9) 0.4475(4) 0.1848(3) 0.029(2) Uani 1 1 d . . . H42A H 0.1827 0.4611 0.2048 0.044 Uiso 1 1 calc R . . H42B H 0.1948 0.4503 0.1608 0.044 Uiso 1 1 calc R . . H42C H 0.3113 0.4734 0.1843 0.044 Uiso 1 1 calc R . . C4 C 0.2559(10) 0.3998(5) 0.0326(2) 0.032(2) Uani 1 1 d . . . C30 C 0.4316(10) 0.0952(5) 0.0916(3) 0.043(3) Uani 1 1 d . . . H47A H 0.4482 0.0514 0.0897 0.065 Uiso 1 1 calc R . . H47B H 0.4314 0.1132 0.0666 0.065 Uiso 1 1 calc R . . H47C H 0.3509 0.1016 0.1033 0.065 Uiso 1 1 calc R . . C5 C 0.1592(9) 0.3631(6) 0.0473(3) 0.041(3) Uani 1 1 d . . . C37 C 0.7204(8) 0.4971(4) 0.2137(3) 0.032(2) Uani 1 1 d . . . H51A H 0.6766 0.5182 0.2339 0.048 Uiso 1 1 calc R . . H51B H 0.8026 0.5150 0.2107 0.048 Uiso 1 1 calc R . . H51C H 0.7284 0.4538 0.2200 0.048 Uiso 1 1 calc R . . C38 C 0.4747(9) 0.5730(5) 0.2016(3) 0.035(2) Uani 1 1 d . . . H53A H 0.5147 0.5667 0.2258 0.053 Uiso 1 1 calc R . . H53B H 0.3897 0.5579 0.2028 0.053 Uiso 1 1 calc R . . H53C H 0.4742 0.6165 0.1956 0.053 Uiso 1 1 calc R . . C26 C 0.6743(10) 0.1618(5) 0.0603(3) 0.044(3) Uani 1 1 d . . . H56A H 0.7093 0.1228 0.0522 0.065 Uiso 1 1 calc R . . H56B H 0.7365 0.1939 0.0576 0.065 Uiso 1 1 calc R . . H56C H 0.6024 0.1716 0.0449 0.065 Uiso 1 1 calc R . . C22 C 0.7089(8) 0.1743(4) 0.1330(3) 0.027(2) Uani 1 1 d . . . C17 C 0.0825(8) 0.3320(5) 0.1594(3) 0.033(2) Uani 1 1 d . . . H10G H 0.0149 0.3332 0.1775 0.049 Uiso 1 1 calc R . . H10H H 0.0740 0.2957 0.1437 0.049 Uiso 1 1 calc R . . H10I H 0.0796 0.3686 0.1437 0.049 Uiso 1 1 calc R . . C9 C 0.2490(12) 0.4669(5) 0.0253(3) 0.054(3) Uani 1 1 d . . . H10J H 0.2075 0.4740 0.0014 0.081 Uiso 1 1 calc R . . H10K H 0.3325 0.4838 0.0244 0.081 Uiso 1 1 calc R . . H10L H 0.2023 0.4866 0.0453 0.081 Uiso 1 1 calc R . . C7 C 0.3878(13) 0.2433(6) 0.0205(3) 0.064(4) Uani 1 1 d . . . H10M H 0.3610 0.2272 -0.0037 0.096 Uiso 1 1 calc R . . H10N H 0.3736 0.2126 0.0399 0.096 Uiso 1 1 calc R . . H10O H 0.4759 0.2532 0.0194 0.096 Uiso 1 1 calc R . . C10 C 0.0344(10) 0.3875(7) 0.0587(4) 0.073(4) Uani 1 1 d . . . H10P H -0.0225 0.3846 0.0376 0.110 Uiso 1 1 calc R . . H10Q H 0.0425 0.4302 0.0663 0.110 Uiso 1 1 calc R . . H10R H 0.0024 0.3634 0.0796 0.110 Uiso 1 1 calc R . . C28 C 0.6995(10) 0.1569(4) 0.2057(3) 0.035(2) Uani 1 1 d . . . H10A H 0.7359 0.1178 0.2130 0.052 Uiso 1 1 calc R . . H10B H 0.6316 0.1668 0.2227 0.052 Uiso 1 1 calc R . . H10C H 0.7625 0.1889 0.2071 0.052 Uiso 1 1 calc R . . C40 C 0.6126(12) 0.4934(5) 0.0718(3) 0.051(3) Uani 1 1 d . . . H10D H 0.5443 0.5138 0.0589 0.077 Uiso 1 1 calc R . . H10E H 0.6103 0.4497 0.0662 0.077 Uiso 1 1 calc R . . H10F H 0.6911 0.5105 0.0632 0.077 Uiso 1 1 calc R . . C1 C 0.1960(10) 0.3029(5) 0.0453(3) 0.040(3) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0102(3) 0.0225(3) 0.0090(3) -0.0006(3) 0.0015(3) -0.0004(3) C15 0.015(4) 0.024(4) 0.009(4) 0.003(4) 0.003(3) 0.001(3) In3 0.0133(3) 0.0290(3) 0.0177(3) 0.0013(3) 0.0013(3) -0.0049(2) C34 0.024(5) 0.029(5) 0.026(6) 0.000(4) -0.003(4) 0.003(4) In1 0.0302(4) 0.0585(5) 0.0107(4) 0.0042(3) -0.0043(3) -0.0039(3) In2 0.0314(4) 0.0352(4) 0.0367(4) -0.0003(3) 0.0149(3) 0.0130(3) C12 0.018(4) 0.033(5) 0.014(5) 0.000(4) 0.008(4) -0.001(4) C20 0.022(5) 0.040(6) 0.012(5) 0.000(4) 0.006(4) -0.002(4) Cl2 0.0170(10) 0.0351(13) 0.0411(15) 0.0042(11) -0.0095(10) 0.0021(9) C24 0.015(4) 0.016(4) 0.032(6) -0.003(4) 0.009(4) 0.003(3) Cl1 0.0402(13) 0.0358(13) 0.0307(14) -0.0022(11) 0.0202(11) -0.0029(11) C11 0.018(4) 0.024(5) 0.013(5) 0.001(4) 0.009(3) 0.000(3) C35 0.032(5) 0.025(5) 0.014(5) 0.007(4) -0.004(4) -0.006(4) C32 0.032(5) 0.022(5) 0.025(6) -0.001(4) -0.004(4) -0.011(4) C8 0.046(6) 0.053(7) 0.017(6) 0.004(5) 0.016(5) 0.010(5) C33 0.017(4) 0.019(5) 0.041(6) -0.003(4) -0.002(4) 0.006(4) C23 0.025(5) 0.023(5) 0.027(5) 0.001(4) 0.005(4) 0.007(4) C13 0.008(4) 0.028(5) 0.024(5) 0.003(4) 0.009(4) -0.009(3) C14 0.0152(19) 0.0159(19) 0.0150(19) 0.0002(10) 0.0008(10) 0.0001(10) C19 0.028(5) 0.040(6) 0.022(6) 0.005(4) 0.000(4) 0.004(4) C36 0.027(5) 0.023(5) 0.075(8) 0.006(5) 0.013(5) -0.003(4) C31 0.018(4) 0.017(4) 0.030(6) -0.005(4) 0.006(4) -0.004(3) C29 0.038(6) 0.027(5) 0.044(7) 0.012(5) 0.001(5) 0.001(4) C18 0.029(5) 0.040(6) 0.033(6) -0.014(5) 0.007(4) -0.015(4) C2 0.049(6) 0.041(6) 0.013(5) 0.002(4) -0.010(5) 0.005(5) C25 0.031(5) 0.021(5) 0.033(6) -0.010(4) 0.000(5) 0.004(4) C39 0.038(6) 0.049(7) 0.069(9) 0.018(6) -0.019(6) 0.011(5) C3 0.037(5) 0.048(6) 0.009(5) 0.002(4) -0.004(4) 0.010(5) C27 0.016(5) 0.036(6) 0.077(9) 0.003(6) 0.007(5) 0.007(4) C6 0.078(9) 0.085(10) 0.047(8) -0.003(7) -0.014(7) -0.052(8) C21 0.035(5) 0.020(5) 0.024(6) -0.005(4) 0.010(4) 0.005(4) C16 0.030(5) 0.030(5) 0.027(6) -0.005(4) -0.003(4) 0.010(4) C4 0.041(6) 0.047(6) 0.010(5) 0.002(4) -0.007(4) 0.010(5) C30 0.044(6) 0.040(6) 0.046(7) -0.010(5) -0.011(5) -0.009(5) C5 0.033(6) 0.074(8) 0.017(6) -0.010(5) -0.012(5) 0.006(6) C37 0.029(5) 0.029(5) 0.037(6) 0.005(4) -0.014(5) -0.006(4) C38 0.038(6) 0.037(6) 0.031(6) -0.009(5) 0.001(5) 0.008(5) C26 0.060(7) 0.038(6) 0.033(6) -0.001(5) 0.016(5) 0.011(5) C22 0.018(4) 0.029(5) 0.034(6) 0.004(4) 0.010(4) 0.007(4) C17 0.015(4) 0.057(7) 0.026(6) -0.001(5) 0.000(4) -0.003(4) C9 0.069(8) 0.060(8) 0.034(7) 0.003(6) -0.004(6) 0.027(7) C7 0.097(11) 0.055(8) 0.040(8) 0.000(6) 0.014(7) 0.015(7) C10 0.025(6) 0.139(14) 0.055(9) 0.009(9) -0.008(6) 0.017(7) C28 0.051(6) 0.025(5) 0.028(6) 0.006(4) -0.009(5) 0.000(4) C40 0.093(9) 0.039(6) 0.021(6) 0.014(5) 0.003(6) -0.005(6) C1 0.047(6) 0.057(7) 0.015(6) 0.003(5) -0.012(5) -0.017(5) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic= ) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C14 2.173(9) . ? Rh1 C11 2.177(8) . ? Rh1 C15 2.202(8) . ? Rh1 C13 2.227(8) . ? Rh1 C12 2.235(9) . ? Rh1 In1 2.522(3) . ? Rh1 In2 2.537(3) . ? Rh1 In3 2.572(4) . ? C15 C14 1.389(11) . ? C15 C11 1.420(11) . ? C15 C20 1.485(11) . ? In3 C31 2.209(9) . ? In3 Cl2 2.500(3) . ? In3 Cl1 2.664(4) . ? In3 In2 3.168(6) . ? C34 C35 1.367(12) . ? C34 C33 1.430(13) . ? C34 C39 1.496(13) . ? In1 C3 2.382(9) . ? In1 C4 2.449(9) . ? In1 C2 2.496(10) . ? In1 C5 2.573(10) . ? In1 C1 2.587(10) . ? In2 C22 2.332(9) . ? In2 C21 2.404(9) . ? In2 C23 2.596(9) . ? In2 C25 2.660(10) . ? In2 Cl1 2.923(4) . ? C12 C13 1.408(12) . ? C12 C11 1.444(12) . ? C12 C17 1.486(12) . ? C24 C23 1.395(12) . ? C24 C25 1.432(13) . ? C24 C29 1.511(12) . ? C11 C16 1.494(12) . ? C35 C31 1.483(12) . ? C35 C40 1.488(13) . ? C32 C33 1.356(12) . ? C32 C31 1.463(12) . ? C32 C37 1.513(12) . ? C8 C3 1.501(13) . ? C33 C38 1.496(12) . ? C23 C22 1.409(12) . ? C23 C28 1.505(13) . ? C13 C14 1.442(11) . ? C13 C18 1.463(12) . ? C14 C19 1.493(11) . ? C36 C31 1.510(12) . ? C2 C3 1.417(14) . ? C2 C1 1.419(14) . ? C2 C7 1.462(15) . ? C25 C21 1.412(13) . ? C25 C30 1.508(13) . ? C3 C4 1.428(13) . ? C27 C22 1.507(12) . ? C6 C1 1.498(15) . ? C21 C22 1.440(13) . ? C21 C26 1.496(13) . ? C4 C5 1.409(15) . ? C4 C9 1.481(15) . ? C5 C1 1.368(16) . ? C5 C10 1.496(15) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C14 Rh1 C11 62.6(3) . . ? C14 Rh1 C15 37.0(3) . . ? C11 Rh1 C15 37.8(3) . . ? C14 Rh1 C13 38.2(3) . . ? C11 Rh1 C13 62.8(3) . . ? C15 Rh1 C13 63.0(3) . . ? C14 Rh1 C12 62.7(3) . . ? C11 Rh1 C12 38.2(3) . . ? C15 Rh1 C12 63.3(3) . . ? C13 Rh1 C12 36.8(3) . . ? C14 Rh1 In1 162.5(2) . . ? C11 Rh1 In1 107.3(2) . . ? C15 Rh1 In1 141.2(2) . . ? C13 Rh1 In1 125.2(2) . . ? C12 Rh1 In1 100.3(2) . . ? C14 Rh1 In2 101.2(2) . . ? C11 Rh1 In2 163.8(2) . . ? C15 Rh1 In2 128.4(2) . . ? C13 Rh1 In2 105.1(3) . . ? C12 Rh1 In2 136.5(2) . . ? In1 Rh1 In2 88.38(8) . . ? C14 Rh1 In3 111.5(2) . . ? C11 Rh1 In3 108.1(2) . . ? C15 Rh1 In3 91.8(2) . . ? C13 Rh1 In3 149.7(2) . . ? C12 Rh1 In3 146.1(2) . . ? In1 Rh1 In3 84.83(5) . . ? In2 Rh1 In3 76.64(13) . . ? C14 C15 C11 107.2(7) . . ? C14 C15 C20 125.1(7) . . ? C11 C15 C20 127.2(8) . . ? C14 C15 Rh1 70.4(5) . . ? C11 C15 Rh1 70.1(5) . . ? C20 C15 Rh1 130.5(5) . . ? C31 In3 Cl2 102.5(3) . . ? C31 In3 Rh1 144.4(2) . . ? Cl2 In3 Rh1 104.49(12) . . ? C31 In3 Cl1 100.7(2) . . ? Cl2 In3 Cl1 95.39(13) . . ? Rh1 In3 Cl1 99.41(9) . . ? C31 In3 In2 159.8(2) . . ? Cl2 In3 In2 77.81(10) . . ? Rh1 In3 In2 51.17(4) . . ? Cl1 In3 In2 59.42(7) . . ? C35 C34 C33 110.8(8) . . ? C35 C34 C39 125.0(9) . . ? C33 C34 C39 124.2(9) . . ? C3 In1 C4 34.4(3) . . ? C3 In1 C2 33.7(3) . . ? C4 In1 C2 55.2(3) . . ? C3 In1 Rh1 162.8(2) . . ? C4 In1 Rh1 162.0(2) . . ? C2 In1 Rh1 134.6(2) . . ? C3 In1 C5 55.0(3) . . ? C4 In1 C5 32.5(3) . . ? C2 In1 C5 53.5(3) . . ? Rh1 In1 C5 134.7(2) . . ? C3 In1 C1 54.3(3) . . ? C4 In1 C1 52.9(4) . . ? C2 In1 C1 32.3(3) . . ? Rh1 In1 C1 124.5(2) . . ? C5 In1 C1 30.7(4) . . ? C22 In2 C21 35.4(3) . . ? C22 In2 Rh1 158.0(2) . . ? C21 In2 Rh1 164.8(2) . . ? C22 In2 C23 32.7(3) . . ? C21 In2 C23 55.3(3) . . ? Rh1 In2 C23 131.1(2) . . ? C22 In2 C25 53.7(3) . . ? C21 In2 C25 31.9(3) . . ? Rh1 In2 C25 136.7(2) . . ? C23 In2 C25 51.7(3) . . ? C22 In2 Cl1 92.1(3) . . ? C21 In2 Cl1 91.7(2) . . ? Rh1 In2 Cl1 93.76(13) . . ? C23 In2 Cl1 122.0(2) . . ? C25 In2 Cl1 121.4(2) . . ? C22 In2 In3 118.5(2) . . ? C21 In2 In3 139.4(2) . . ? Rh1 In2 In3 52.18(9) . . ? C23 In2 In3 124.9(2) . . ? C25 In2 In3 171.1(2) . . ? Cl1 In2 In3 51.67(9) . . ? C13 C12 C11 107.1(7) . . ? C13 C12 C17 126.9(8) . . ? C11 C12 C17 125.8(8) . . ? C13 C12 Rh1 71.3(4) . . ? C11 C12 Rh1 68.7(4) . . ? C17 C12 Rh1 129.3(6) . . ? C23 C24 C25 108.5(8) . . ? C23 C24 C29 126.5(9) . . ? C25 C24 C29 124.8(8) . . ? In3 Cl1 In2 68.90(12) . . ? C15 C11 C12 108.7(7) . . ? C15 C11 C16 127.2(8) . . ? C12 C11 C16 123.8(8) . . ? C15 C11 Rh1 72.0(5) . . ? C12 C11 Rh1 73.1(5) . . ? C16 C11 Rh1 126.3(6) . . ? C34 C35 C31 106.6(7) . . ? C34 C35 C40 129.2(9) . . ? C31 C35 C40 124.1(9) . . ? C33 C32 C31 109.3(8) . . ? C33 C32 C37 126.7(9) . . ? C31 C32 C37 123.7(8) . . ? C32 C33 C34 108.1(8) . . ? C32 C33 C38 125.8(9) . . ? C34 C33 C38 126.0(8) . . ? C24 C23 C22 107.5(8) . . ? C24 C23 C28 125.2(8) . . ? C22 C23 C28 127.1(8) . . ? C24 C23 In2 82.4(5) . . ? C22 C23 In2 63.3(5) . . ? C28 C23 In2 122.7(6) . . ? C12 C13 C14 107.3(7) . . ? C12 C13 C18 125.4(8) . . ? C14 C13 C18 127.0(8) . . ? C12 C13 Rh1 71.9(5) . . ? C14 C13 Rh1 68.9(4) . . ? C18 C13 Rh1 129.2(6) . . ? C15 C14 C13 109.6(7) . . ? C15 C14 C19 124.3(8) . . ? C13 C14 C19 125.3(8) . . ? C15 C14 Rh1 72.6(5) . . ? C13 C14 Rh1 72.9(5) . . ? C19 C14 Rh1 129.2(6) . . ? C32 C31 C35 105.0(7) . . ? C32 C31 C36 120.8(8) . . ? C35 C31 C36 120.1(8) . . ? C32 C31 In3 98.6(5) . . ? C35 C31 In3 98.4(5) . . ? C36 C31 In3 109.7(6) . . ? C3 C2 C1 106.7(9) . . ? C3 C2 C7 125.5(10) . . ? C1 C2 C7 127.8(11) . . ? C3 C2 In1 68.7(5) . . ? C1 C2 In1 77.4(6) . . ? C7 C2 In1 120.9(7) . . ? C21 C25 C24 108.7(8) . . ? C21 C25 C30 125.1(9) . . ? C24 C25 C30 126.0(9) . . ? C21 C25 In2 64.0(5) . . ? C24 C25 In2 79.4(5) . . ? C30 C25 In2 125.8(6) . . ? C2 C3 C4 107.2(9) . . ? C2 C3 C8 124.9(9) . . ? C4 C3 C8 127.2(9) . . ? C2 C3 In1 77.6(5) . . ? C4 C3 In1 75.4(5) . . ? C8 C3 In1 120.9(6) . . ? C25 C21 C22 105.7(8) . . ? C25 C21 C26 126.9(9) . . ? C22 C21 C26 126.4(8) . . ? C25 C21 In2 84.1(5) . . ? C22 C21 In2 69.6(5) . . ? C26 C21 In2 120.3(6) . . ? C5 C4 C3 108.0(9) . . ? C5 C4 C9 125.7(10) . . ? C3 C4 C9 125.8(10) . . ? C5 C4 In1 78.6(6) . . ? C3 C4 In1 70.2(5) . . ? C9 C4 In1 122.6(7) . . ? C1 C5 C4 108.0(9) . . ? C1 C5 C10 127.6(11) . . ? C4 C5 C10 124.0(12) . . ? C1 C5 In1 75.2(6) . . ? C4 C5 In1 68.9(5) . . ? C10 C5 In1 126.5(7) . . ? C23 C22 C21 109.5(8) . . ? C23 C22 C27 125.4(9) . . ? C21 C22 C27 123.9(9) . . ? C23 C22 In2 84.0(5) . . ? C21 C22 In2 75.1(5) . . ? C27 C22 In2 118.1(6) . . ? C5 C1 C2 110.1(9) . . ? C5 C1 C6 127.6(11) . . ? C2 C1 C6 122.3(11) . . ? C5 C1 In1 74.0(6) . . ? C2 C1 In1 70.3(6) . . ? C6 C1 In1 120.4(7) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C11 Rh1 C15 C14 117.6(7) . . . . ? C13 Rh1 C15 C14 38.0(5) . . . . ? C12 Rh1 C15 C14 79.4(5) . . . . ? In1 Rh1 C15 C14 151.5(4) . . . . ? In2 Rh1 C15 C14 -50.2(5) . . . . ? In3 Rh1 C15 C14 -124.5(4) . . . . ? C14 Rh1 C15 C11 -117.6(7) . . . . ? C13 Rh1 C15 C11 -79.6(5) . . . . ? C12 Rh1 C15 C11 -38.2(5) . . . . ? In1 Rh1 C15 C11 33.9(6) . . . . ? In2 Rh1 C15 C11 -167.8(4) . . . . ? In3 Rh1 C15 C11 117.9(5) . . . . ? C14 Rh1 C15 C20 119.9(9) . . . . ? C11 Rh1 C15 C20 -122.5(10) . . . . ? C13 Rh1 C15 C20 157.9(9) . . . . ? C12 Rh1 C15 C20 -160.7(9) . . . . ? In1 Rh1 C15 C20 -88.6(8) . . . . ? In2 Rh1 C15 C20 69.7(8) . . . . ? In3 Rh1 C15 C20 -4.6(8) . . . . ? C14 Rh1 In3 C31 -102.1(5) . . . . ? C11 Rh1 In3 C31 -35.1(5) . . . . ? C15 Rh1 In3 C31 -69.8(5) . . . . ? C13 Rh1 In3 C31 -101.9(6) . . . . ? C12 Rh1 In3 C31 -29.3(6) . . . . ? In1 Rh1 In3 C31 71.4(4) . . . . ? In2 Rh1 In3 C31 161.0(4) . . . . ? C14 Rh1 In3 Cl2 36.2(2) . . . . ? C11 Rh1 In3 Cl2 103.2(3) . . . . ? C15 Rh1 In3 Cl2 68.4(2) . . . . ? C13 Rh1 In3 Cl2 36.3(5) . . . . ? C12 Rh1 In3 Cl2 108.9(4) . . . . ? In1 Rh1 In3 Cl2 -150.36(7) . . . . ? In2 Rh1 In3 Cl2 -60.80(11) . . . . ? C14 Rh1 In3 Cl1 134.3(2) . . . . ? C11 Rh1 In3 Cl1 -158.7(2) . . . . ? C15 Rh1 In3 Cl1 166.5(2) . . . . ? C13 Rh1 In3 Cl1 134.4(5) . . . . ? C12 Rh1 In3 Cl1 -153.0(4) . . . . ? In1 Rh1 In3 Cl1 -52.24(11) . . . . ? In2 Rh1 In3 Cl1 37.32(7) . . . . ? C14 Rh1 In3 In2 97.0(2) . . . . ? C11 Rh1 In3 In2 164.0(2) . . . . ? C15 Rh1 In3 In2 129.2(2) . . . . ? C13 Rh1 In3 In2 97.1(4) . . . . ? C12 Rh1 In3 In2 169.7(4) . . . . ? In1 Rh1 In3 In2 -89.56(7) . . . . ? C14 Rh1 In1 C3 -120.5(11) . . . . ? C11 Rh1 In1 C3 -172.5(9) . . . . ? C15 Rh1 In1 C3 166.5(9) . . . . ? C13 Rh1 In1 C3 -104.0(9) . . . . ? C12 Rh1 In1 C3 -133.8(9) . . . . ? In2 Rh1 In1 C3 3.4(9) . . . . ? In3 Rh1 In1 C3 80.1(9) . . . . ? C14 Rh1 In1 C4 35.0(11) . . . . ? C11 Rh1 In1 C4 -17.0(9) . . . . ? C15 Rh1 In1 C4 -38.1(9) . . . . ? C13 Rh1 In1 C4 51.4(9) . . . . ? C12 Rh1 In1 C4 21.7(8) . . . . ? In2 Rh1 In1 C4 158.8(8) . . . . ? In3 Rh1 In1 C4 -124.5(8) . . . . ? C14 Rh1 In1 C2 -80.8(8) . . . . ? C11 Rh1 In1 C2 -132.8(4) . . . . ? C15 Rh1 In1 C2 -153.8(5) . . . . ? C13 Rh1 In1 C2 -64.4(4) . . . . ? C12 Rh1 In1 C2 -94.1(4) . . . . ? In2 Rh1 In1 C2 43.0(3) . . . . ? In3 Rh1 In1 C2 119.8(3) . . . . ? C14 Rh1 In1 C5 -2.3(8) . . . . ? C11 Rh1 In1 C5 -54.3(5) . . . . ? C15 Rh1 In1 C5 -75.3(5) . . . . ? C13 Rh1 In1 C5 14.1(5) . . . . ? C12 Rh1 In1 C5 -15.6(4) . . . . ? In2 Rh1 In1 C5 121.5(4) . . . . ? In3 Rh1 In1 C5 -161.7(4) . . . . ? C14 Rh1 In1 C1 -40.5(8) . . . . ? C11 Rh1 In1 C1 -92.5(4) . . . . ? C15 Rh1 In1 C1 -113.5(5) . . . . ? C13 Rh1 In1 C1 -24.0(4) . . . . ? C12 Rh1 In1 C1 -53.7(4) . . . . ? In2 Rh1 In1 C1 83.4(4) . . . . ? In3 Rh1 In1 C1 160.1(3) . . . . ? C14 Rh1 In2 C22 -37.7(6) . . . . ? C11 Rh1 In2 C22 -37.3(10) . . . . ? C15 Rh1 In2 C22 -9.6(6) . . . . ? C13 Rh1 In2 C22 -76.8(6) . . . . ? C12 Rh1 In2 C22 -99.7(7) . . . . ? In1 Rh1 In2 C22 157.0(6) . . . . ? In3 Rh1 In2 C22 71.9(6) . . . . ? C14 Rh1 In2 C21 106.2(9) . . . . ? C11 Rh1 In2 C21 106.6(12) . . . . ? C15 Rh1 In2 C21 134.3(9) . . . . ? C13 Rh1 In2 C21 67.1(9) . . . . ? C12 Rh1 In2 C21 44.2(9) . . . . ? In1 Rh1 In2 C21 -59.1(8) . . . . ? In3 Rh1 In2 C21 -144.2(8) . . . . ? C14 Rh1 In2 C23 -3.1(3) . . . . ? C11 Rh1 In2 C23 -2.7(8) . . . . ? C15 Rh1 In2 C23 25.0(4) . . . . ? C13 Rh1 In2 C23 -42.2(4) . . . . ? C12 Rh1 In2 C23 -65.1(4) . . . . ? In1 Rh1 In2 C23 -168.4(3) . . . . ? In3 Rh1 In2 C23 106.5(3) . . . . ? C14 Rh1 In2 C25 71.1(4) . . . . ? C11 Rh1 In2 C25 71.5(8) . . . . ? C15 Rh1 In2 C25 99.2(4) . . . . ? C13 Rh1 In2 C25 32.0(4) . . . . ? C12 Rh1 In2 C25 9.1(4) . . . . ? In1 Rh1 In2 C25 -94.2(3) . . . . ? In3 Rh1 In2 C25 -179.3(3) . . . . ? C14 Rh1 In2 Cl1 -142.8(2) . . . . ? C11 Rh1 In2 Cl1 -142.4(8) . . . . ? C15 Rh1 In2 Cl1 -114.6(3) . . . . ? C13 Rh1 In2 Cl1 178.1(2) . . . . ? C12 Rh1 In2 Cl1 155.3(3) . . . . ? In1 Rh1 In2 Cl1 51.97(8) . . . . ? In3 Rh1 In2 Cl1 -33.10(7) . . . . ? C14 Rh1 In2 In3 -109.7(2) . . . . ? C11 Rh1 In2 In3 -109.3(8) . . . . ? C15 Rh1 In2 In3 -81.5(3) . . . . ? C13 Rh1 In2 In3 -148.8(2) . . . . ? C12 Rh1 In2 In3 -171.6(3) . . . . ? In1 Rh1 In2 In3 85.07(6) . . . . ? C31 In3 In2 C22 57.2(7) . . . . ? Cl2 In3 In2 C22 -35.9(3) . . . . ? Rh1 In3 In2 C22 -156.1(3) . . . . ? Cl1 In3 In2 C22 67.9(3) . . . . ? C31 In3 In2 C21 19.7(8) . . . . ? Cl2 In3 In2 C21 -73.5(4) . . . . ? Rh1 In3 In2 C21 166.4(4) . . . . ? Cl1 In3 In2 C21 30.4(4) . . . . ? C31 In3 In2 Rh1 -146.7(7) . . . . ? Cl2 In3 In2 Rh1 120.16(11) . . . . ? Cl1 In3 In2 Rh1 -136.00(7) . . . . ? C31 In3 In2 C23 95.1(7) . . . . ? Cl2 In3 In2 C23 2.0(2) . . . . ? Rh1 In3 In2 C23 -118.2(3) . . . . ? Cl1 In3 In2 C23 105.8(3) . . . . ? C31 In3 In2 C25 30.1(15) . . . . ? Cl2 In3 In2 C25 -63.1(14) . . . . ? Rh1 In3 In2 C25 176.8(14) . . . . ? Cl1 In3 In2 C25 40.8(14) . . . . ? C31 In3 In2 Cl1 -10.7(7) . . . . ? Cl2 In3 In2 Cl1 -103.84(15) . . . . ? Rh1 In3 In2 Cl1 136.00(8) . . . . ? C14 Rh1 C12 C13 -38.1(5) . . . . ? C11 Rh1 C12 C13 -117.7(7) . . . . ? C15 Rh1 C12 C13 -79.9(5) . . . . ? In1 Rh1 C12 C13 137.4(5) . . . . ? In2 Rh1 C12 C13 38.8(6) . . . . ? In3 Rh1 C12 C13 -126.5(5) . . . . ? C14 Rh1 C12 C11 79.6(5) . . . . ? C15 Rh1 C12 C11 37.8(5) . . . . ? C13 Rh1 C12 C11 117.7(7) . . . . ? In1 Rh1 C12 C11 -104.9(5) . . . . ? In2 Rh1 C12 C11 156.5(4) . . . . ? In3 Rh1 C12 C11 -8.8(7) . . . . ? C14 Rh1 C12 C17 -161.0(9) . . . . ? C11 Rh1 C12 C17 119.4(10) . . . . ? C15 Rh1 C12 C17 157.3(9) . . . . ? C13 Rh1 C12 C17 -122.9(11) . . . . ? In1 Rh1 C12 C17 14.6(9) . . . . ? In2 Rh1 C12 C17 -84.1(9) . . . . ? In3 Rh1 C12 C17 110.6(8) . . . . ? C31 In3 Cl1 In2 176.3(2) . . . . ? Cl2 In3 Cl1 In2 72.42(12) . . . . ? Rh1 In3 Cl1 In2 -33.27(5) . . . . ? C22 In2 Cl1 In3 -125.4(3) . . . . ? C21 In2 Cl1 In3 -160.8(2) . . . . ? Rh1 In2 Cl1 In3 33.36(7) . . . . ? C23 In2 Cl1 In3 -111.5(3) . . . . ? C25 In2 Cl1 In3 -173.2(2) . . . . ? C14 C15 C11 C12 3.5(9) . . . . ? C20 C15 C11 C12 -169.3(7) . . . . ? Rh1 C15 C11 C12 64.4(6) . . . . ? C14 C15 C11 C16 176.7(8) . . . . ? C20 C15 C11 C16 3.9(13) . . . . ? Rh1 C15 C11 C16 -122.4(9) . . . . ? C14 C15 C11 Rh1 -60.9(6) . . . . ? C20 C15 C11 Rh1 126.4(8) . . . . ? C13 C12 C11 C15 -2.4(9) . . . . ? C17 C12 C11 C15 172.4(8) . . . . ? Rh1 C12 C11 C15 -63.7(6) . . . . ? C13 C12 C11 C16 -175.9(8) . . . . ? C17 C12 C11 C16 -1.0(13) . . . . ? Rh1 C12 C11 C16 122.8(8) . . . . ? C13 C12 C11 Rh1 61.3(6) . . . . ? C17 C12 C11 Rh1 -123.9(8) . . . . ? C14 Rh1 C11 C15 36.9(5) . . . . ? C13 Rh1 C11 C15 80.2(5) . . . . ? C12 Rh1 C11 C15 116.8(7) . . . . ? In1 Rh1 C11 C15 -158.5(4) . . . . ? In2 Rh1 C11 C15 36.5(10) . . . . ? In3 Rh1 C11 C15 -68.4(5) . . . . ? C14 Rh1 C11 C12 -79.9(5) . . . . ? C15 Rh1 C11 C12 -116.8(7) . . . . ? C13 Rh1 C11 C12 -36.6(5) . . . . ? In1 Rh1 C11 C12 84.7(5) . . . . ? In2 Rh1 C11 C12 -80.3(9) . . . . ? In3 Rh1 C11 C12 174.8(4) . . . . ? C14 Rh1 C11 C16 160.3(8) . . . . ? C15 Rh1 C11 C16 123.4(9) . . . . ? C13 Rh1 C11 C16 -156.5(8) . . . . ? C12 Rh1 C11 C16 -119.9(10) . . . . ? In1 Rh1 C11 C16 -35.2(8) . . . . ? In2 Rh1 C11 C16 159.8(5) . . . . ? In3 Rh1 C11 C16 55.0(8) . . . . ? C33 C34 C35 C31 3.8(10) . . . . ? C39 C34 C35 C31 -176.3(9) . . . . ? C33 C34 C35 C40 -173.8(9) . . . . ? C39 C34 C35 C40 6.0(16) . . . . ? C31 C32 C33 C34 -0.6(10) . . . . ? C37 C32 C33 C34 174.0(8) . . . . ? C31 C32 C33 C38 179.4(8) . . . . ? C37 C32 C33 C38 -6.0(15) . . . . ? C35 C34 C33 C32 -2.1(11) . . . . ? C39 C34 C33 C32 178.1(9) . . . . ? C35 C34 C33 C38 177.9(9) . . . . ? C39 C34 C33 C38 -2.0(15) . . . . ? C25 C24 C23 C22 -0.3(9) . . . . ? C29 C24 C23 C22 175.6(8) . . . . ? C25 C24 C23 C28 -176.6(8) . . . . ? C29 C24 C23 C28 -0.6(14) . . . . ? C25 C24 C23 In2 58.5(6) . . . . ? C29 C24 C23 In2 -125.5(8) . . . . ? C22 In2 C23 C24 -114.1(8) . . . . ? C21 In2 C23 C24 -73.4(6) . . . . ? Rh1 In2 C23 C24 89.2(5) . . . . ? C25 In2 C23 C24 -33.7(5) . . . . ? Cl1 In2 C23 C24 -140.5(4) . . . . ? In3 In2 C23 C24 156.6(4) . . . . ? C21 In2 C23 C22 40.7(5) . . . . ? Rh1 In2 C23 C22 -156.8(5) . . . . ? C25 In2 C23 C22 80.4(6) . . . . ? Cl1 In2 C23 C22 -26.4(6) . . . . ? In3 In2 C23 C22 -89.3(6) . . . . ? C22 In2 C23 C28 118.7(10) . . . . ? C21 In2 C23 C28 159.4(9) . . . . ? Rh1 In2 C23 C28 -38.1(8) . . . . ? C25 In2 C23 C28 -160.9(9) . . . . ? Cl1 In2 C23 C28 92.3(7) . . . . ? In3 In2 C23 C28 29.4(8) . . . . ? C11 C12 C13 C14 0.4(9) . . . . ? C17 C12 C13 C14 -174.3(8) . . . . ? Rh1 C12 C13 C14 60.1(5) . . . . ? C11 C12 C13 C18 174.6(8) . . . . ? C17 C12 C13 C18 -0.1(14) . . . . ? Rh1 C12 C13 C18 -125.7(9) . . . . ? C11 C12 C13 Rh1 -59.7(5) . . . . ? C17 C12 C13 Rh1 125.6(9) . . . . ? C14 Rh1 C13 C12 117.5(7) . . . . ? C11 Rh1 C13 C12 38.0(5) . . . . ? C15 Rh1 C13 C12 80.7(5) . . . . ? In1 Rh1 C13 C12 -54.6(6) . . . . ? In2 Rh1 C13 C12 -153.5(5) . . . . ? In3 Rh1 C13 C12 117.2(5) . . . . ? C11 Rh1 C13 C14 -79.5(5) . . . . ? C15 Rh1 C13 C14 -36.8(4) . . . . ? C12 Rh1 C13 C14 -117.5(7) . . . . ? In1 Rh1 C13 C14 -172.1(4) . . . . ? In2 Rh1 C13 C14 89.0(4) . . . . ? In3 Rh1 C13 C14 -0.2(7) . . . . ? C14 Rh1 C13 C18 -121.1(10) . . . . ? C11 Rh1 C13 C18 159.4(9) . . . . ? C15 Rh1 C13 C18 -157.9(9) . . . . ? C12 Rh1 C13 C18 121.4(10) . . . . ? In1 Rh1 C13 C18 66.8(9) . . . . ? In2 Rh1 C13 C18 -32.1(8) . . . . ? In3 Rh1 C13 C18 -121.4(7) . . . . ? C11 C15 C14 C13 -3.2(9) . . . . ? C20 C15 C14 C13 169.7(7) . . . . ? Rh1 C15 C14 C13 -64.0(6) . . . . ? C11 C15 C14 C19 -173.2(7) . . . . ? C20 C15 C14 C19 -0.3(13) . . . . ? Rh1 C15 C14 C19 126.0(8) . . . . ? C11 C15 C14 Rh1 60.8(5) . . . . ? C20 C15 C14 Rh1 -126.3(8) . . . . ? C12 C13 C14 C15 1.8(9) . . . . ? C18 C13 C14 C15 -172.3(8) . . . . ? Rh1 C13 C14 C15 63.8(6) . . . . ? C12 C13 C14 C19 171.7(8) . . . . ? C18 C13 C14 C19 -2.4(13) . . . . ? Rh1 C13 C14 C19 -126.3(8) . . . . ? C12 C13 C14 Rh1 -62.0(6) . . . . ? C18 C13 C14 Rh1 123.9(9) . . . . ? C11 Rh1 C14 C15 -37.7(5) . . . . ? C13 Rh1 C14 C15 -117.6(7) . . . . ? C12 Rh1 C14 C15 -80.9(5) . . . . ? In1 Rh1 C14 C15 -95.7(8) . . . . ? In2 Rh1 C14 C15 142.1(4) . . . . ? In3 Rh1 C14 C15 62.2(4) . . . . ? C11 Rh1 C14 C13 79.9(5) . . . . ? C15 Rh1 C14 C13 117.6(7) . . . . ? C12 Rh1 C14 C13 36.7(5) . . . . ? In1 Rh1 C14 C13 22.0(10) . . . . ? In2 Rh1 C14 C13 -100.2(5) . . . . ? In3 Rh1 C14 C13 179.9(4) . . . . ? C11 Rh1 C14 C19 -158.2(9) . . . . ? C15 Rh1 C14 C19 -120.4(9) . . . . ? C13 Rh1 C14 C19 121.9(10) . . . . ? C12 Rh1 C14 C19 158.6(9) . . . . ? In1 Rh1 C14 C19 143.9(6) . . . . ? In2 Rh1 C14 C19 21.7(8) . . . . ? In3 Rh1 C14 C19 -58.2(8) . . . . ? C33 C32 C31 C35 2.9(9) . . . . ? C37 C32 C31 C35 -172.0(8) . . . . ? C33 C32 C31 C36 142.6(8) . . . . ? C37 C32 C31 C36 -32.2(12) . . . . ? C33 C32 C31 In3 -98.3(7) . . . . ? C37 C32 C31 In3 86.9(8) . . . . ? C34 C35 C31 C32 -4.0(9) . . . . ? C40 C35 C31 C32 173.7(8) . . . . ? C34 C35 C31 C36 -144.2(8) . . . . ? C40 C35 C31 C36 33.6(13) . . . . ? C34 C35 C31 In3 97.3(7) . . . . ? C40 C35 C31 In3 -85.0(9) . . . . ? Cl2 In3 C31 C32 -78.2(5) . . . . ? Rh1 In3 C31 C32 60.4(7) . . . . ? Cl1 In3 C31 C32 -176.3(5) . . . . ? In2 In3 C31 C32 -166.9(5) . . . . ? Cl2 In3 C31 C35 175.1(5) . . . . ? Rh1 In3 C31 C35 -46.3(7) . . . . ? Cl1 In3 C31 C35 77.1(5) . . . . ? In2 In3 C31 C35 86.4(8) . . . . ? Cl2 In3 C31 C36 48.9(7) . . . . ? Rh1 In3 C31 C36 -172.5(5) . . . . ? Cl1 In3 C31 C36 -49.1(7) . . . . ? In2 In3 C31 C36 -39.8(12) . . . . ? C4 In1 C2 C3 39.7(6) . . . . ? Rh1 In1 C2 C3 -160.1(4) . . . . ? C5 In1 C2 C3 79.9(6) . . . . ? C1 In1 C2 C3 113.8(9) . . . . ? C3 In1 C2 C1 -113.8(9) . . . . ? C4 In1 C2 C1 -74.0(6) . . . . ? Rh1 In1 C2 C1 86.1(6) . . . . ? C5 In1 C2 C1 -33.9(6) . . . . ? C3 In1 C2 C7 119.5(12) . . . . ? C4 In1 C2 C7 159.3(11) . . . . ? Rh1 In1 C2 C7 -40.6(10) . . . . ? C5 In1 C2 C7 -160.6(11) . . . . ? C1 In1 C2 C7 -126.7(12) . . . . ? C23 C24 C25 C21 0.7(10) . . . . ? C29 C24 C25 C21 -175.4(8) . . . . ? C23 C24 C25 C30 176.1(9) . . . . ? C29 C24 C25 C30 0.0(14) . . . . ? C23 C24 C25 In2 -57.1(6) . . . . ? C29 C24 C25 In2 126.9(8) . . . . ? C22 In2 C25 C21 -42.7(6) . . . . ? Rh1 In2 C25 C21 163.4(5) . . . . ? C23 In2 C25 C21 -84.0(6) . . . . ? Cl1 In2 C25 C21 24.0(6) . . . . ? In3 In2 C25 C21 -12.8(17) . . . . ? C22 In2 C25 C24 74.3(5) . . . . ? C21 In2 C25 C24 117.0(8) . . . . ? Rh1 In2 C25 C24 -79.5(5) . . . . ? C23 In2 C25 C24 33.0(5) . . . . ? Cl1 In2 C25 C24 141.1(4) . . . . ? In3 In2 C25 C24 104.2(14) . . . . ? C22 In2 C25 C30 -158.6(10) . . . . ? C21 In2 C25 C30 -115.9(11) . . . . ? Rh1 In2 C25 C30 47.5(9) . . . . ? C23 In2 C25 C30 160.1(10) . . . . ? Cl1 In2 C25 C30 -91.9(8) . . . . ? In3 In2 C25 C30 -128.7(12) . . . . ? C1 C2 C3 C4 -1.4(10) . . . . ? C7 C2 C3 C4 176.2(10) . . . . ? In1 C2 C3 C4 -70.2(6) . . . . ? C1 C2 C3 C8 -172.0(9) . . . . ? C7 C2 C3 C8 5.6(15) . . . . ? In1 C2 C3 C8 119.2(9) . . . . ? C1 C2 C3 In1 68.8(7) . . . . ? C7 C2 C3 In1 -113.6(10) . . . . ? C4 In1 C3 C2 -111.7(9) . . . . ? Rh1 In1 C3 C2 55.1(11) . . . . ? C5 In1 C3 C2 -75.0(6) . . . . ? C1 In1 C3 C2 -37.1(6) . . . . ? C2 In1 C3 C4 111.7(9) . . . . ? Rh1 In1 C3 C4 166.8(6) . . . . ? C5 In1 C3 C4 36.7(6) . . . . ? C1 In1 C3 C4 74.6(7) . . . . ? C4 In1 C3 C8 124.9(11) . . . . ? C2 In1 C3 C8 -123.4(10) . . . . ? Rh1 In1 C3 C8 -68.3(13) . . . . ? C5 In1 C3 C8 161.6(10) . . . . ? C1 In1 C3 C8 -160.5(9) . . . . ? C24 C25 C21 C22 -0.7(9) . . . . ? C30 C25 C21 C22 -176.2(9) . . . . ? In2 C25 C21 C22 66.8(5) . . . . ? C24 C25 C21 C26 168.6(8) . . . . ? C30 C25 C21 C26 -6.8(15) . . . . ? In2 C25 C21 C26 -123.8(10) . . . . ? C24 C25 C21 In2 -67.6(6) . . . . ? C30 C25 C21 In2 117.0(9) . . . . ? C22 In2 C21 C25 109.2(8) . . . . ? Rh1 In2 C21 C25 -48.3(12) . . . . ? C23 In2 C21 C25 71.8(6) . . . . ? Cl1 In2 C21 C25 -159.6(5) . . . . ? In3 In2 C21 C25 177.0(4) . . . . ? Rh1 In2 C21 C22 -157.6(7) . . . . ? C23 In2 C21 C22 -37.5(5) . . . . ? C25 In2 C21 C22 -109.2(8) . . . . ? Cl1 In2 C21 C22 91.1(5) . . . . ? In3 In2 C21 C22 67.7(6) . . . . ? C22 In2 C21 C26 -121.1(10) . . . . ? Rh1 In2 C21 C26 81.3(11) . . . . ? C23 In2 C21 C26 -158.6(9) . . . . ? C25 In2 C21 C26 129.7(11) . . . . ? Cl1 In2 C21 C26 -30.0(8) . . . . ? In3 In2 C21 C26 -53.4(9) . . . . ? C2 C3 C4 C5 1.5(10) . . . . ? C8 C3 C4 C5 171.8(9) . . . . ? In1 C3 C4 C5 -70.3(7) . . . . ? C2 C3 C4 C9 -171.7(9) . . . . ? C8 C3 C4 C9 -1.4(16) . . . . ? In1 C3 C4 C9 116.5(10) . . . . ? C2 C3 C4 In1 71.8(6) . . . . ? C8 C3 C4 In1 -117.9(10) . . . . ? C3 In1 C4 C5 114.1(9) . . . . ? C2 In1 C4 C5 75.2(7) . . . . ? Rh1 In1 C4 C5 -53.4(12) . . . . ? C1 In1 C4 C5 35.0(6) . . . . ? C2 In1 C4 C3 -38.9(6) . . . . ? Rh1 In1 C4 C3 -167.4(6) . . . . ? C5 In1 C4 C3 -114.1(9) . . . . ? C1 In1 C4 C3 -79.0(7) . . . . ? C3 In1 C4 C9 -120.6(12) . . . . ? C2 In1 C4 C9 -159.4(10) . . . . ? Rh1 In1 C4 C9 72.0(13) . . . . ? C5 In1 C4 C9 125.3(12) . . . . ? C1 In1 C4 C9 160.4(11) . . . . ? C3 C4 C5 C1 -1.0(11) . . . . ? C9 C4 C5 C1 172.3(9) . . . . ? In1 C4 C5 C1 -65.6(7) . . . . ? C3 C4 C5 C10 -174.7(9) . . . . ? C9 C4 C5 C10 -1.5(16) . . . . ? In1 C4 C5 C10 120.6(10) . . . . ? C3 C4 C5 In1 64.7(6) . . . . ? C9 C4 C5 In1 -122.1(10) . . . . ? C3 In1 C5 C1 77.4(7) . . . . ? C4 In1 C5 C1 116.4(9) . . . . ? C2 In1 C5 C1 35.7(6) . . . . ? Rh1 In1 C5 C1 -84.1(7) . . . . ? C3 In1 C5 C4 -39.0(6) . . . . ? C2 In1 C5 C4 -80.7(7) . . . . ? Rh1 In1 C5 C4 159.6(5) . . . . ? C1 In1 C5 C4 -116.4(9) . . . . ? C3 In1 C5 C10 -156.4(13) . . . . ? C4 In1 C5 C10 -117.4(14) . . . . ? C2 In1 C5 C10 161.9(13) . . . . ? Rh1 In1 C5 C10 42.1(13) . . . . ? C1 In1 C5 C10 126.2(14) . . . . ? C24 C23 C22 C21 -0.1(10) . . . . ? C28 C23 C22 C21 176.0(8) . . . . ? In2 C23 C22 C21 -71.8(6) . . . . ? C24 C23 C22 C27 -167.9(8) . . . . ? C28 C23 C22 C27 8.2(14) . . . . ? In2 C23 C22 C27 120.4(9) . . . . ? C24 C23 C22 In2 71.7(6) . . . . ? C28 C23 C22 In2 -112.2(9) . . . . ? C25 C21 C22 C23 0.5(10) . . . . ? C26 C21 C22 C23 -168.9(8) . . . . ? In2 C21 C22 C23 77.9(6) . . . . ? C25 C21 C22 C27 168.6(8) . . . . ? C26 C21 C22 C27 -0.8(14) . . . . ? In2 C21 C22 C27 -114.1(9) . . . . ? C25 C21 C22 In2 -77.4(6) . . . . ? C26 C21 C22 In2 113.2(9) . . . . ? C21 In2 C22 C23 -112.1(8) . . . . ? Rh1 In2 C22 C23 52.5(9) . . . . ? C25 In2 C22 C23 -73.9(6) . . . . ? Cl1 In2 C22 C23 157.8(5) . . . . ? In3 In2 C22 C23 111.2(5) . . . . ? Rh1 In2 C22 C21 164.6(5) . . . . ? C23 In2 C22 C21 112.1(8) . . . . ? C25 In2 C22 C21 38.2(5) . . . . ? Cl1 In2 C22 C21 -90.1(5) . . . . ? In3 In2 C22 C21 -136.8(4) . . . . ? C21 In2 C22 C27 120.7(10) . . . . ? Rh1 In2 C22 C27 -74.7(10) . . . . ? C23 In2 C22 C27 -127.2(11) . . . . ? C25 In2 C22 C27 158.9(9) . . . . ? Cl1 In2 C22 C27 30.7(8) . . . . ? In3 In2 C22 C27 -16.0(9) . . . . ? C4 C5 C1 C2 0.1(11) . . . . ? C10 C5 C1 C2 173.5(10) . . . . ? In1 C5 C1 C2 -61.5(7) . . . . ? C4 C5 C1 C6 177.9(10) . . . . ? C10 C5 C1 C6 -8.7(18) . . . . ? In1 C5 C1 C6 116.3(11) . . . . ? C4 C5 C1 In1 61.5(7) . . . . ? C10 C5 C1 In1 -125.0(11) . . . . ? C3 C2 C1 C5 0.9(11) . . . . ? C7 C2 C1 C5 -176.7(10) . . . . ? In1 C2 C1 C5 63.8(7) . . . . ? C3 C2 C1 C6 -177.1(9) . . . . ? C7 C2 C1 C6 5.4(16) . . . . ? In1 C2 C1 C6 -114.1(9) . . . . ? C3 C2 C1 In1 -62.9(6) . . . . ? C7 C2 C1 In1 119.5(11) . . . . ? C3 In1 C1 C5 -80.1(7) . . . . ? C4 In1 C1 C5 -37.1(6) . . . . ? C2 In1 C1 C5 -118.8(9) . . . . ? Rh1 In1 C1 C5 120.9(6) . . . . ? C3 In1 C1 C2 38.7(6) . . . . ? C4 In1 C1 C2 81.7(6) . . . . ? Rh1 In1 C1 C2 -120.3(5) . . . . ? C5 In1 C1 C2 118.8(9) . . . . ? C3 In1 C1 C6 155.3(12) . . . . ? C4 In1 C1 C6 -161.7(12) . . . . ? C2 In1 C1 C6 116.6(13) . . . . ? Rh1 In1 C1 C6 -3.7(11) . . . . ? C5 In1 C1 C6 -124.6(13) . . . . ? _diffrn_measured_fraction_theta_max 0.938 _diffrn_reflns_theta_full 25.49 _diffrn_measured_fraction_theta_full 0.938 _refine_diff_density_max 1.881 _refine_diff_density_min -1.768 _refine_diff_density_rms 0.181