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["Rh-Sweetener Anions: Relative Affinities for trans-Rh(PPh3)2(CO)+ using 4-picoline in DCM"]
[{"$nulls":9},"Caption:"]
["Freq.","Rh-ace:p","Rh-ace:4","Rh-no3:p","rh-no3:4","rh-sach:p","rh-sach:4","rh-tfa:p","rh-tfa:4","Fig. 2. IR spectra of CH2Cl2 solutions initially 1.60 mM in {Rh}X and 3.20 mM in 4-picoline "]
[1951.6208,0.0475,0.0478,0.0454,0.0243,0.0331,0.0338,0.0361,0.0383,"showing relative anion affinity of X- for {Rh}+ via partitioning into {Rh}X and [{Rh}4pic+]X-. "]
[1953.5493,0.0573,0.0576,0.0533,0.0291,0.0365,0.0373,0.0439,0.0453]
[1955.4778,0.0708,0.071,0.0642,0.0353,0.0415,0.0426,0.0544,0.0551]
[1957.4063,0.089,0.0892,0.0787,0.0431,0.0487,0.0501,0.0686,0.068]
[1959.3347,0.1141,0.1142,0.098,0.0532,0.0589,0.0605,0.0877,0.0856]
[1961.2632,0.1477,0.1476,0.1233,0.0653,0.0726,0.0744,0.1131,0.1087]
[1963.1917,0.1913,0.1905,0.1558,0.0791,0.0901,0.0922,0.1455,0.1382]
[1965.1202,0.2471,0.245,0.1981,0.0951,0.1133,0.1155,0.1879,0.1763]
[1967.0486,0.3189,0.3148,0.2546,0.1155,0.1459,0.1478,0.2455,0.2276]
[1968.9771,0.4087,0.4024,0.3298,0.1425,0.1923,0.1931,0.3233,0.2965]
[1970.9056,0.5129,0.5039,0.4248,0.1761,0.255,0.254,0.4212,0.3825]
[1972.8341,0.6217,0.6097,0.5353,0.2147,0.335,0.3314,0.5326,0.4796]
[1974.7626,0.7227,0.7083,0.6539,0.2559,0.432,0.4253,0.6467,0.5791]
[1976.691,0.8035,0.7886,0.7708,0.2974,0.5441,0.5341,0.7506,0.67]
[1978.6195,0.8538,0.84,0.8725,0.3355,0.666,0.6527,0.8302,0.7401]
[1980.548,0.8687,0.8559,0.9465,0.3656,0.7884,0.7713,0.8738,0.7786]
[1982.4765,0.8466,0.8349,0.9853,0.3838,0.8967,0.8765,0.8759,0.7794]
[1984.405,0.7889,0.7801,0.9849,0.3886,0.9742,0.9532,0.8355,0.7416]
[1986.3334,0.7033,0.7001,0.9435,0.3811,1.0085,0.9898,0.7578,0.6715]
[1988.2619,0.6015,0.6054,0.8638,0.3647,0.9949,0.9803,0.6539,0.5807]
[1990.1904,0.4946,0.5063,0.7545,0.3454,0.9336,0.9252,0.5389,0.4823]
[1992.1189,0.3929,0.4133,0.6311,0.3309,0.8326,0.8331,0.4279,0.3891]
[1994.0474,0.3041,0.3347,0.5095,0.3286,0.7076,0.719,0.3309,0.3104]
[1995.9758,0.231,0.274,0.3995,0.3433,0.5749,0.5981,0.2511,0.2494]
[1997.9043,0.1728,0.231,0.3051,0.3774,0.448,0.4838,0.1873,0.205]
[1999.8328,0.128,0.204,0.2285,0.4304,0.3375,0.3858,0.1384,0.1754]
[2001.7613,0.0952,0.1906,0.1699,0.4975,0.2488,0.3078,0.1028,0.1587]
[2003.6897,0.0717,0.1865,0.1272,0.5694,0.1816,0.2479,0.0775,0.1516]
[2005.6182,0.0547,0.1866,0.0964,0.6329,0.1321,0.202,0.0592,0.149]
[2007.5467,0.0425,0.186,0.0743,0.6733,0.0966,0.1664,0.0458,0.1468]
[2009.4752,0.0339,0.1805,0.0585,0.6772,0.0715,0.138,0.0364,0.1416]
[2011.4037,0.0276,0.1677,0.0468,0.6399,0.0536,0.1141,0.0294,0.1313]
[2013.3321,0.0224,0.1478,0.0377,0.5672,0.0405,0.0929,0.0234,0.1155]
[2015.2606,0.0179,0.1236,0.0306,0.4732,0.0308,0.0741,0.0182,0.096]
[2017.1891,0.0147,0.0989,0.0253,0.3746,0.024,0.0583,0.0145,0.0765]
[2019.1176,0.0128,0.0769,0.0215,0.2854,0.0192,0.0456,0.0125,0.0598]
[2021.0461,0.0116,0.0589,0.0186,0.2118,0.0156,0.0356,0.0113,0.0464]
[2022.9745,0.0103,0.0447,0.016,0.1543,0.0127,0.0276,0.01,0.0356]
[2024.903,0.009,0.0338,0.0136,0.1114,0.0102,0.0216,0.0087,0.0272]
[2026.8315,0.008,0.026,0.0117,0.0809,0.0083,0.0172,0.0077,0.0211]
[2028.76,0.0073,0.0205,0.0102,0.0597,0.0069,0.014,0.0071,0.0168]
[2030.6885,0.0067,0.0166,0.009,0.0449,0.0057,0.0116,0.0067,0.0139]

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["For Supporting Info:  For Individual Anions, IR Overlays of Pure 1.60 mM {Rh}X and "]
["Mixtures Initially 1.60 mM in {Rh}X and 3.20 mM in 4-picoline "]