# Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2004


data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Dr M. Angeles Ubeda'
_publ_contact_author_address     
;
Departamento de Quimica Inorganica
Universidad de Valencia
Facultat Quimica
Burjassot-Valencia
SPAIN
;

_publ_contact_author_email       ANGELES.UBEDA@UV.ES

_publ_section_title              
;
Enantio and diastereocontrol in intermolecular
cyclopropanation reaction of styrene catalyzed by dirhodium(II)
complexes with bulky ortho-metalated aryl phosphines
;
loop_
_publ_author_name
'Angeles Ubeda'
'Francisco Estevan'
'Pascual Lahuerta'
'Julio Lloret'
'Mercedes Sanau'
'Jaume Vila'

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 242554'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C58 H86 O6 P2 Rh2 Si6 . 2H2O'
_chemical_formula_sum            'C58 H90 O8 P2 Rh2 Si6'
_chemical_formula_weight         1351.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.0100(2)
_cell_length_b                   15.85900(10)
_cell_length_c                   16.2240(2)
_cell_angle_alpha                106.0690(6)
_cell_angle_beta                 92.0150(7)
_cell_angle_gamma                94.9480(6)
_cell_volume                     3690.26(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.216
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1412
_exptl_absorpt_coefficient_mu    5.305
_exptl_absorpt_correction_type   None
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Kappa 2000'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            16847
_diffrn_reflns_av_R_equivalents  0.0592
_diffrn_reflns_av_sigmaI/netI    0.0485
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.84
_diffrn_reflns_theta_max         70.08
_reflns_number_total             13141
_reflns_number_gt                10490
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement.  R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0054(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_number_reflns         13141
_refine_ls_number_parameters     686
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1094
_refine_ls_R_factor_gt           0.0951
_refine_ls_wR_factor_ref         0.2746
_refine_ls_wR_factor_gt          0.2540
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_restrained_S_all      1.140
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.28275(3) 0.38069(3) 0.43345(3) 0.0445(2) Uani 1 1 d . . .
P1 P 0.26162(11) 0.25636(10) 0.46878(10) 0.0471(4) Uani 1 1 d . . .
O1 O 0.2919(3) 0.5030(3) 0.3993(3) 0.0590(12) Uani 1 1 d . . .
Si1 Si -0.15263(14) 0.09168(14) 0.40827(17) 0.0688(6) Uani 1 1 d . . .
Rh2 Rh 0.11586(3) 0.38511(3) 0.42610(3) 0.0437(2) Uani 1 1 d . . .
P2 P 0.11806(11) 0.33870(10) 0.28480(11) 0.0471(4) Uani 1 1 d . . .
O2 O 0.1506(3) 0.5244(3) 0.4327(3) 0.0580(12) Uani 1 1 d . . .
C2 C 0.2402(7) 0.6421(5) 0.4061(7) 0.091(3) Uani 1 1 d . . .
H2A H 0.1862 0.6702 0.4188 0.136 Uiso 1 1 calc R . .
H2B H 0.2549 0.6400 0.3485 0.136 Uiso 1 1 calc R . .
H2C H 0.2883 0.6750 0.4457 0.136 Uiso 1 1 calc R . .
Si2 Si 0.3552(3) 0.3671(2) 0.88261(17) 0.1056(11) Uani 1 1 d . . .
Si3 Si 0.45754(19) -0.09508(16) 0.28535(19) 0.0865(8) Uani 1 1 d . . .
O3 O 0.2762(3) 0.4637(3) 0.5653(3) 0.0543(10) Uani 1 1 d . . .
O4 O 0.1273(3) 0.4372(3) 0.5660(3) 0.0528(10) Uani 1 1 d . . .
Si4 Si 0.50229(16) 0.21076(18) 0.16344(15) 0.0755(6) Uani 1 1 d . . .
O5 O 0.4366(3) 0.4012(3) 0.4664(3) 0.0652(13) Uani 1 1 d . . .
Si5 Si -0.16663(18) 0.01402(17) 0.05793(18) 0.0833(7) Uani 1 1 d . . .
Si6 Si 0.0824(3) 0.6735(2) 0.1275(3) 0.1283(14) Uani 1 1 d . . .
O6 O -0.0334(3) 0.4139(3) 0.4338(3) 0.0559(11) Uani 1 1 d . . .
O7 O 0.4455(4) 0.5330(5) 0.6309(4) 0.0949(19) Uani 1 1 d . . .
O8 O 0.4135(5) 0.4999(7) 0.2699(6) 0.140(3) Uani 1 1 d . . .
C10 C 0.2267(6) 0.5503(4) 0.4145(5) 0.0623(18) Uani 1 1 d . . .
C11 C 0.1478(5) 0.2099(4) 0.4503(4) 0.0513(15) Uani 1 1 d . . .
C12 C 0.0827(4) 0.2616(4) 0.4309(4) 0.0481(14) Uani 1 1 d . . .
C13 C -0.0067(4) 0.2239(4) 0.4183(4) 0.0525(14) Uani 1 1 d . . .
H13A H -0.0506 0.2569 0.4051 0.063 Uiso 1 1 calc R . .
C14 C -0.0328(5) 0.1400(4) 0.4245(5) 0.0581(16) Uani 1 1 d . . .
C15 C 0.0331(5) 0.0891(5) 0.4412(5) 0.065(2) Uani 1 1 d . . .
H15A H 0.0175 0.0317 0.4432 0.078 Uiso 1 1 calc R . .
C16 C 0.1217(5) 0.1239(5) 0.4547(5) 0.0652(19) Uani 1 1 d . . .
H16A H 0.1649 0.0898 0.4670 0.078 Uiso 1 1 calc R . .
C21 C 0.2881(5) 0.2762(4) 0.5836(4) 0.0535(15) Uani 1 1 d . . .
C22 C 0.3724(5) 0.3136(5) 0.6191(5) 0.0642(18) Uani 1 1 d . . .
H22A H 0.4167 0.3219 0.5827 0.077 Uiso 1 1 calc R . .
C23 C 0.3931(6) 0.3392(6) 0.7067(5) 0.074(2) Uani 1 1 d . . .
H23A H 0.4505 0.3645 0.7278 0.089 Uiso 1 1 calc R . .
C24 C 0.3296(7) 0.3276(5) 0.7635(5) 0.075(2) Uani 1 1 d . . .
C25 C 0.2450(7) 0.2894(6) 0.7276(6) 0.086(3) Uani 1 1 d . . .
H25A H 0.2008 0.2804 0.7640 0.103 Uiso 1 1 calc R . .
C26 C 0.2243(6) 0.2645(5) 0.6409(5) 0.0692(19) Uani 1 1 d . . .
H26A H 0.1668 0.2394 0.6198 0.083 Uiso 1 1 calc R . .
C30 C 0.2036(4) 0.4701(4) 0.6018(4) 0.0523(15) Uani 1 1 d . . .
C31 C 0.3236(5) 0.1620(4) 0.4179(4) 0.0540(15) Uani 1 1 d . . .
C32 C 0.2957(5) 0.1113(5) 0.3353(5) 0.070(2) Uani 1 1 d . . .
H32A H 0.2488 0.1277 0.3060 0.084 Uiso 1 1 calc R . .
C34 C 0.4071(6) 0.0094(5) 0.3351(6) 0.073(2) Uani 1 1 d . . .
C35 C 0.4350(6) 0.0624(6) 0.4164(6) 0.087(3) Uani 1 1 d . . .
H35A H 0.4831 0.0472 0.4452 0.104 Uiso 1 1 calc R . .
C36 C 0.3950(6) 0.1368(5) 0.4570(5) 0.075(2) Uani 1 1 d . . .
H36A H 0.4169 0.1703 0.5116 0.091 Uiso 1 1 calc R . .
C40 C 0.2072(6) 0.5220(7) 0.6946(5) 0.086(3) Uani 1 1 d . . .
H40A H 0.2682 0.5434 0.7143 0.129 Uiso 1 1 calc R . .
H40B H 0.1835 0.4849 0.7280 0.129 Uiso 1 1 calc R . .
H40C H 0.1721 0.5710 0.7009 0.129 Uiso 1 1 calc R . .
C41 C 0.2223(4) 0.2965(4) 0.2497(4) 0.0478(13) Uani 1 1 d . . .
C42 C 0.2935(5) 0.3121(4) 0.3109(4) 0.0500(14) Uani 1 1 d . . .
C43 C 0.3752(4) 0.2837(4) 0.2816(4) 0.0532(15) Uani 1 1 d . . .
H43A H 0.4235 0.2940 0.3218 0.064 Uiso 1 1 calc R . .
C44 C 0.3891(5) 0.2416(5) 0.1973(4) 0.0557(15) Uani 1 1 d . . .
C45 C 0.3147(5) 0.2246(5) 0.1384(5) 0.0623(17) Uani 1 1 d . . .
H45A H 0.3208 0.1951 0.0811 0.075 Uiso 1 1 calc R . .
C46 C 0.2330(5) 0.2510(5) 0.1641(5) 0.0635(18) Uani 1 1 d . . .
H46A H 0.1842 0.2385 0.1242 0.076 Uiso 1 1 calc R . .
C51 C 0.0339(4) 0.2522(4) 0.2230(4) 0.0544(15) Uani 1 1 d . . .
C52 C -0.0386(5) 0.2656(5) 0.1754(6) 0.072(2) Uani 1 1 d . . .
H52A H -0.0481 0.3228 0.1754 0.087 Uiso 1 1 calc R . .
C53 C -0.0982(6) 0.1955(6) 0.1270(6) 0.083(3) Uani 1 1 d . . .
H53A H -0.1460 0.2071 0.0950 0.099 Uiso 1 1 calc R . .
C54 C -0.0879(5) 0.1090(5) 0.1256(5) 0.0680(18) Uani 1 1 d . . .
C55 C -0.0168(5) 0.0968(5) 0.1764(5) 0.0687(19) Uani 1 1 d . . .
H55A H -0.0087 0.0398 0.1781 0.082 Uiso 1 1 calc R . .
C56 C 0.0420(5) 0.1645(5) 0.2239(5) 0.0638(18) Uani 1 1 d . . .
H56A H 0.0882 0.1528 0.2575 0.077 Uiso 1 1 calc R . .
C61 C 0.1079(5) 0.4294(4) 0.2364(4) 0.0562(16) Uani 1 1 d . . .
C62 C 0.0407(6) 0.4843(6) 0.2602(6) 0.080(2) Uani 1 1 d . . .
H62A H -0.0003 0.4723 0.2981 0.096 Uiso 1 1 calc R . .
C63 C 0.0326(7) 0.5568(6) 0.2292(7) 0.087(3) Uani 1 1 d . . .
H63A H -0.0133 0.5923 0.2466 0.105 Uiso 1 1 calc R . .
C64 C 0.0933(7) 0.5768(6) 0.1716(7) 0.084(3) Uani 1 1 d . . .
C65 C 0.1597(8) 0.5213(6) 0.1499(7) 0.097(3) Uani 1 1 d . . .
H65A H 0.2014 0.5331 0.1125 0.117 Uiso 1 1 calc R . .
C66 C 0.1679(6) 0.4497(6) 0.1800(6) 0.077(2) Uani 1 1 d . . .
H66A H 0.2140 0.4144 0.1626 0.093 Uiso 1 1 calc R . .
C101 C -0.1967(7) 0.0965(7) 0.5151(8) 0.101(3) Uani 1 1 d . . .
H10D H -0.1944 0.1569 0.5490 0.151 Uiso 1 1 calc R . .
H10E H -0.1609 0.0647 0.5440 0.151 Uiso 1 1 calc R . .
H10F H -0.2576 0.0704 0.5075 0.151 Uiso 1 1 calc R . .
C102 C -0.1567(7) -0.0256(6) 0.3422(8) 0.101(3) Uani 1 1 d . . .
H10A H -0.1339 -0.0278 0.2872 0.151 Uiso 1 1 calc R . .
H10B H -0.2175 -0.0520 0.3345 0.151 Uiso 1 1 calc R . .
H10C H -0.1207 -0.0573 0.3710 0.151 Uiso 1 1 calc R . .
C103 C -0.2190(7) 0.1554(7) 0.3528(8) 0.108(4) Uani 1 1 d . . .
H10G H -0.1959 0.1523 0.2977 0.162 Uiso 1 1 calc R . .
H10H H -0.2148 0.2159 0.3868 0.162 Uiso 1 1 calc R . .
H10I H -0.2805 0.1311 0.3452 0.162 Uiso 1 1 calc R . .
C201 C 0.3031(12) 0.4720(10) 0.9264(9) 0.160(6) Uani 1 1 d . . .
H20G H 0.2394 0.4614 0.9144 0.240 Uiso 1 1 calc R . .
H20H H 0.3269 0.5155 0.9000 0.240 Uiso 1 1 calc R . .
H20I H 0.3161 0.4929 0.9875 0.240 Uiso 1 1 calc R . .
C202 C 0.3100(15) 0.2824(12) 0.9313(10) 0.215(11) Uani 1 1 d . . .
H20D H 0.2463 0.2720 0.9195 0.322 Uiso 1 1 calc R . .
H20E H 0.3234 0.3020 0.9923 0.322 Uiso 1 1 calc R . .
H20F H 0.3367 0.2287 0.9075 0.322 Uiso 1 1 calc R . .
C203 C 0.4821(11) 0.3896(11) 0.9058(8) 0.164(7) Uani 1 1 d . . .
H20A H 0.5093 0.3357 0.8847 0.246 Uiso 1 1 calc R . .
H20B H 0.4954 0.4123 0.9667 0.246 Uiso 1 1 calc R . .
H20C H 0.5053 0.4320 0.8777 0.246 Uiso 1 1 calc R . .
C301 C 0.4080(9) -0.1810(7) 0.3344(10) 0.130(5) Uani 1 1 d . . .
H30A H 0.4330 -0.2355 0.3102 0.195 Uiso 1 1 calc R . .
H30B H 0.3443 -0.1893 0.3227 0.195 Uiso 1 1 calc R . .
H30C H 0.4215 -0.1621 0.3954 0.195 Uiso 1 1 calc R . .
C302 C 0.5794(8) -0.0794(7) 0.3103(10) 0.128(5) Uani 1 1 d . . .
H30D H 0.6060 -0.0364 0.2847 0.193 Uiso 1 1 calc R . .
H30E H 0.6042 -0.1344 0.2879 0.193 Uiso 1 1 calc R . .
H30F H 0.5915 -0.0593 0.3715 0.193 Uiso 1 1 calc R . .
C303 C 0.4333(13) -0.1269(10) 0.1665(9) 0.170(7) Uani 1 1 d . . .
H30G H 0.4598 -0.0814 0.1438 0.254 Uiso 1 1 calc R . .
H30H H 0.3696 -0.1343 0.1539 0.254 Uiso 1 1 calc R . .
H30I H 0.4579 -0.1812 0.1407 0.254 Uiso 1 1 calc R . .
C330 C 0.3362(6) 0.0373(5) 0.2959(6) 0.079(2) Uani 1 1 d . . .
H33A H 0.3152 0.0047 0.2407 0.095 Uiso 1 1 calc R . .
C401 C 0.5688(8) 0.1987(10) 0.2560(8) 0.149(6) Uani 1 1 d . . .
H40G H 0.5397 0.1527 0.2764 0.223 Uiso 1 1 calc R . .
H40H H 0.5742 0.2532 0.3010 0.223 Uiso 1 1 calc R . .
H40I H 0.6274 0.1838 0.2389 0.223 Uiso 1 1 calc R . .
C402 C 0.4884(9) 0.1094(10) 0.0728(11) 0.179(8) Uani 1 1 d . . .
H40J H 0.4605 0.0618 0.0916 0.268 Uiso 1 1 calc R . .
H40K H 0.5461 0.0950 0.0524 0.268 Uiso 1 1 calc R . .
H40L H 0.4515 0.1187 0.0271 0.268 Uiso 1 1 calc R . .
C403 C 0.5578(10) 0.3013(13) 0.1240(12) 0.182(8) Uani 1 1 d . . .
H40D H 0.6162 0.2870 0.1062 0.273 Uiso 1 1 calc R . .
H40E H 0.5632 0.3555 0.1695 0.273 Uiso 1 1 calc R . .
H40F H 0.5223 0.3079 0.0762 0.273 Uiso 1 1 calc R . .
C501 C -0.1139(8) -0.0886(6) 0.0482(8) 0.116(4) Uani 1 1 d . . .
H50A H -0.0593 -0.0866 0.0193 0.173 Uiso 1 1 calc R . .
H50B H -0.1540 -0.1380 0.0158 0.173 Uiso 1 1 calc R . .
H50C H -0.1008 -0.0949 0.1044 0.173 Uiso 1 1 calc R . .
C502 C -0.2727(8) 0.0069(9) 0.1114(9) 0.135(5) Uani 1 1 d . . .
H50G H -0.3122 -0.0419 0.0769 0.203 Uiso 1 1 calc R . .
H50H H -0.3004 0.0605 0.1181 0.203 Uiso 1 1 calc R . .
H50I H -0.2604 -0.0017 0.1668 0.203 Uiso 1 1 calc R . .
C503 C -0.1844(11) 0.0301(9) -0.0497(8) 0.154(6) Uani 1 1 d . . .
H50D H -0.1279 0.0334 -0.0751 0.231 Uiso 1 1 calc R . .
H50E H -0.2115 0.0839 -0.0446 0.231 Uiso 1 1 calc R . .
H50F H -0.2232 -0.0186 -0.0854 0.231 Uiso 1 1 calc R . .
C601 C 0.071(3) 0.7696(13) 0.2187(17) 0.38(2) Uani 1 1 d . . .
H60D H 0.0653 0.8203 0.1983 0.563 Uiso 1 1 calc R . .
H60E H 0.1231 0.7803 0.2576 0.563 Uiso 1 1 calc R . .
H60F H 0.0187 0.7586 0.2480 0.563 Uiso 1 1 calc R . .
C602 C 0.1775(19) 0.697(2) 0.079(3) 0.43(3) Uani 1 1 d . . .
H60A H 0.1703 0.7463 0.0566 0.648 Uiso 1 1 calc R . .
H60B H 0.1876 0.6466 0.0325 0.648 Uiso 1 1 calc R . .
H60C H 0.2279 0.7111 0.1200 0.648 Uiso 1 1 calc R . .
C603 C -0.0198(18) 0.6568(17) 0.064(2) 0.34(2) Uani 1 1 d . . .
H60G H -0.0250 0.7060 0.0412 0.503 Uiso 1 1 calc R . .
H60H H -0.0691 0.6516 0.0990 0.503 Uiso 1 1 calc R . .
H60I H -0.0206 0.6037 0.0177 0.503 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Rh1 0.0446(3) 0.0457(3) 0.0410(3) 0.0096(2) 0.0017(2) 0.00119(19)
P1 0.0478(8) 0.0478(8) 0.0452(9) 0.0130(6) -0.0030(7) 0.0050(6)
O1 0.063(3) 0.049(2) 0.065(3) 0.019(2) 0.009(2) -0.002(2)
Si1 0.0511(10) 0.0606(11) 0.0963(17) 0.0285(11) 0.0007(10) -0.0055(9)
Rh2 0.0453(3) 0.0411(3) 0.0447(3) 0.0126(2) 0.0023(2) 0.00417(19)
P2 0.0489(8) 0.0489(8) 0.0451(9) 0.0158(7) -0.0003(7) 0.0064(6)
O2 0.061(3) 0.043(2) 0.074(3) 0.020(2) 0.012(2) 0.009(2)
C2 0.089(6) 0.060(5) 0.127(9) 0.037(5) 0.016(6) -0.007(4)
Si2 0.162(3) 0.1034(19) 0.0467(13) 0.0182(13) -0.0112(16) 0.0040(19)
Si3 0.0926(18) 0.0680(13) 0.0998(19) 0.0168(13) 0.0208(15) 0.0295(13)
O3 0.052(2) 0.058(2) 0.047(2) 0.005(2) 0.005(2) 0.005(2)
O4 0.053(2) 0.062(3) 0.043(2) 0.013(2) 0.005(2) 0.009(2)
Si4 0.0605(12) 0.1036(17) 0.0568(12) 0.0090(11) 0.0082(10) 0.0210(11)
O5 0.044(2) 0.085(3) 0.058(3) 0.011(2) -0.006(2) -0.008(2)
Si5 0.0756(15) 0.0843(15) 0.0757(16) 0.0074(12) -0.0152(12) -0.0119(12)
Si6 0.149(3) 0.105(2) 0.163(4) 0.093(2) -0.006(3) 0.012(2)
O6 0.045(2) 0.058(2) 0.064(3) 0.014(2) 0.004(2) 0.0128(19)
O7 0.075(4) 0.123(5) 0.074(4) 0.020(4) -0.006(3) -0.025(4)
O8 0.087(5) 0.203(9) 0.165(9) 0.109(7) 0.020(5) 0.006(5)
C10 0.082(5) 0.046(3) 0.057(4) 0.013(3) 0.001(4) 0.001(3)
C11 0.056(4) 0.045(3) 0.056(4) 0.022(3) -0.002(3) 0.001(3)
C12 0.048(3) 0.048(3) 0.047(3) 0.011(3) 0.000(3) 0.008(3)
C13 0.045(3) 0.056(3) 0.057(4) 0.018(3) -0.001(3) 0.002(3)
C14 0.059(4) 0.053(3) 0.064(4) 0.022(3) 0.003(3) -0.002(3)
C15 0.059(4) 0.051(4) 0.093(6) 0.038(4) -0.008(4) -0.011(3)
C16 0.063(4) 0.053(4) 0.086(5) 0.032(4) -0.009(4) 0.004(3)
C21 0.061(4) 0.053(3) 0.049(4) 0.020(3) -0.004(3) 0.005(3)
C22 0.062(4) 0.071(4) 0.057(4) 0.013(3) 0.001(3) 0.008(3)
C23 0.086(6) 0.083(5) 0.051(4) 0.015(4) -0.016(4) 0.010(4)
C24 0.105(7) 0.075(5) 0.046(4) 0.018(4) -0.008(4) 0.012(4)
C25 0.094(6) 0.099(6) 0.063(5) 0.024(5) 0.011(5) -0.006(5)
C26 0.069(5) 0.081(5) 0.058(4) 0.026(4) -0.001(4) -0.005(4)
C30 0.053(4) 0.055(3) 0.042(3) 0.006(3) -0.007(3) 0.001(3)
C31 0.058(4) 0.058(4) 0.050(4) 0.020(3) 0.001(3) 0.010(3)
C32 0.073(5) 0.065(4) 0.064(5) 0.007(3) -0.016(4) 0.014(4)
C34 0.081(5) 0.057(4) 0.077(5) 0.010(4) 0.007(4) 0.022(4)
C35 0.087(6) 0.082(5) 0.086(6) 0.009(5) -0.018(5) 0.039(5)
C36 0.075(5) 0.079(5) 0.064(5) 0.004(4) -0.013(4) 0.024(4)
C40 0.059(4) 0.129(8) 0.058(5) 0.006(5) 0.002(4) 0.009(5)
C41 0.053(3) 0.049(3) 0.038(3) 0.008(2) 0.005(3) 0.004(3)
C42 0.056(4) 0.050(3) 0.041(3) 0.009(3) 0.007(3) 0.007(3)
C43 0.047(3) 0.066(4) 0.038(3) 0.004(3) -0.001(3) -0.002(3)
C44 0.053(4) 0.065(4) 0.048(4) 0.015(3) 0.002(3) 0.003(3)
C45 0.068(4) 0.073(4) 0.042(4) 0.008(3) 0.005(3) 0.017(4)
C46 0.057(4) 0.083(5) 0.052(4) 0.019(3) -0.003(3) 0.015(4)
C51 0.052(3) 0.059(4) 0.051(4) 0.014(3) -0.003(3) 0.005(3)
C52 0.072(5) 0.066(4) 0.082(6) 0.030(4) -0.018(4) 0.002(4)
C53 0.071(5) 0.083(5) 0.093(6) 0.031(5) -0.033(5) -0.004(4)
C54 0.063(4) 0.076(5) 0.059(4) 0.012(4) -0.006(4) -0.001(4)
C55 0.078(5) 0.057(4) 0.066(5) 0.009(3) -0.004(4) 0.007(4)
C56 0.070(4) 0.062(4) 0.058(4) 0.017(3) -0.015(4) 0.002(3)
C61 0.066(4) 0.058(4) 0.049(4) 0.022(3) -0.006(3) 0.004(3)
C62 0.078(5) 0.085(5) 0.100(7) 0.056(5) 0.023(5) 0.023(4)
C63 0.089(6) 0.082(5) 0.106(7) 0.045(5) -0.003(5) 0.023(5)
C64 0.091(6) 0.083(5) 0.091(6) 0.048(5) -0.005(5) 0.004(5)
C65 0.117(8) 0.092(6) 0.104(8) 0.058(6) 0.034(6) 0.021(6)
C66 0.089(6) 0.085(5) 0.074(5) 0.042(4) 0.021(5) 0.028(5)
C101 0.098(7) 0.090(6) 0.127(9) 0.046(6) 0.036(7) 0.013(5)
C102 0.080(6) 0.076(5) 0.128(9) 0.010(5) -0.019(6) -0.015(5)
C103 0.073(6) 0.111(7) 0.147(11) 0.057(7) -0.030(6) -0.006(5)
C201 0.202(18) 0.154(12) 0.098(10) -0.015(8) 0.020(10) 0.030(11)
C202 0.36(3) 0.193(16) 0.095(10) 0.083(11) -0.035(14) -0.086(17)
C203 0.192(17) 0.203(16) 0.073(8) 0.012(9) -0.055(9) 0.005(13)
C301 0.120(10) 0.074(6) 0.201(15) 0.040(7) 0.049(9) 0.022(6)
C302 0.090(8) 0.099(7) 0.207(15) 0.051(9) 0.041(9) 0.033(6)
C303 0.26(2) 0.143(11) 0.103(10) 0.009(8) 0.032(11) 0.103(13)
C330 0.085(6) 0.063(4) 0.081(6) 0.004(4) -0.018(5) 0.019(4)
C401 0.110(9) 0.229(16) 0.102(9) 0.014(9) -0.010(7) 0.100(10)
C402 0.108(10) 0.169(13) 0.190(16) -0.079(11) 0.009(10) 0.058(9)
C403 0.100(10) 0.27(2) 0.220(19) 0.147(17) 0.053(11) 0.011(12)
C501 0.127(10) 0.086(6) 0.109(9) -0.004(6) -0.029(7) -0.009(6)
C502 0.080(7) 0.136(10) 0.151(12) -0.014(9) -0.006(8) -0.015(7)
C503 0.192(15) 0.145(11) 0.100(9) 0.017(8) -0.079(10) -0.030(10)
C601 0.80(8) 0.116(15) 0.23(3) 0.075(16) 0.01(4) 0.09(3)
C602 0.33(4) 0.45(4) 0.79(8) 0.56(6) 0.30(5) 0.19(3)
C603 0.30(3) 0.30(3) 0.50(5) 0.31(3) -0.19(3) -0.04(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C42 2.004(6) . ?
Rh1 O1 2.155(4) . ?
Rh1 O3 2.191(4) . ?
Rh1 P1 2.2018(16) . ?
Rh1 O5 2.327(5) . ?
Rh1 Rh2 2.5116(6) . ?
P1 C11 1.782(7) . ?
P1 C21 1.824(7) . ?
P1 C31 1.843(7) . ?
O1 C10 1.274(9) . ?
Si1 C103 1.854(9) . ?
Si1 C101 1.861(11) . ?
Si1 C102 1.866(9) . ?
Si1 C14 1.873(7) . ?
Rh2 C12 2.003(6) . ?
Rh2 O4 2.184(4) . ?
Rh2 O2 2.198(4) . ?
Rh2 P2 2.2076(17) . ?
Rh2 O6 2.326(4) . ?
P2 C41 1.803(6) . ?
P2 C51 1.826(7) . ?
P2 C61 1.834(6) . ?
O2 C10 1.253(9) . ?
C2 C10 1.496(10) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
Si2 C202 1.832(14) . ?
Si2 C201 1.869(14) . ?
Si2 C24 1.874(8) . ?
Si2 C203 1.912(17) . ?
Si3 C302 1.840(12) . ?
Si3 C303 1.867(14) . ?
Si3 C34 1.868(7) . ?
Si3 C301 1.873(12) . ?
O3 C30 1.256(8) . ?
O4 C30 1.266(8) . ?
Si4 C401 1.837(11) . ?
Si4 C402 1.845(12) . ?
Si4 C44 1.868(7) . ?
Si4 C403 1.872(14) . ?
Si5 C501 1.842(11) . ?
Si5 C503 1.847(13) . ?
Si5 C502 1.849(13) . ?
Si5 C54 1.886(8) . ?
Si6 C602 1.72(2) . ?
Si6 C603 1.77(2) . ?
Si6 C601 1.83(2) . ?
Si6 C64 1.879(8) . ?
C11 C16 1.408(9) . ?
C11 C12 1.409(8) . ?
C12 C13 1.406(9) . ?
C13 C14 1.386(9) . ?
C13 H13A 0.9300 . ?
C14 C15 1.394(10) . ?
C15 C16 1.380(10) . ?
C15 H15A 0.9300 . ?
C16 H16A 0.9300 . ?
C21 C22 1.383(10) . ?
C21 C26 1.394(10) . ?
C22 C23 1.381(11) . ?
C22 H22A 0.9300 . ?
C23 C24 1.385(12) . ?
C23 H23A 0.9300 . ?
C24 C25 1.392(13) . ?
C25 C26 1.369(12) . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9300 . ?
C30 C40 1.500(10) . ?
C31 C36 1.370(9) . ?
C31 C32 1.387(10) . ?
C32 C330 1.375(10) . ?
C32 H32A 0.9300 . ?
C34 C35 1.381(12) . ?
C34 C330 1.386(11) . ?
C35 C36 1.381(10) . ?
C35 H35A 0.9300 . ?
C36 H36A 0.9300 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 C42 1.390(9) . ?
C41 C46 1.399(9) . ?
C42 C43 1.396(9) . ?
C43 C44 1.378(9) . ?
C43 H43A 0.9300 . ?
C44 C45 1.401(10) . ?
C45 C46 1.371(10) . ?
C45 H45A 0.9300 . ?
C46 H46A 0.9300 . ?
C51 C52 1.378(9) . ?
C51 C56 1.410(9) . ?
C52 C53 1.395(11) . ?
C52 H52A 0.9300 . ?
C53 C54 1.389(11) . ?
C53 H53A 0.9300 . ?
C54 C55 1.385(10) . ?
C55 C56 1.362(10) . ?
C55 H55A 0.9300 . ?
C56 H56A 0.9300 . ?
C61 C62 1.385(11) . ?
C61 C66 1.387(11) . ?
C62 C63 1.388(10) . ?
C62 H62A 0.9300 . ?
C63 C64 1.407(13) . ?
C63 H63A 0.9300 . ?
C64 C65 1.377(14) . ?
C65 C66 1.367(11) . ?
C65 H65A 0.9300 . ?
C66 H66A 0.9300 . ?
C101 H10D 0.9600 . ?
C101 H10E 0.9600 . ?
C101 H10F 0.9600 . ?
C102 H10A 0.9600 . ?
C102 H10B 0.9600 . ?
C102 H10C 0.9600 . ?
C103 H10G 0.9600 . ?
C103 H10H 0.9600 . ?
C103 H10I 0.9600 . ?
C201 H20G 0.9600 . ?
C201 H20H 0.9600 . ?
C201 H20I 0.9600 . ?
C202 H20D 0.9600 . ?
C202 H20E 0.9600 . ?
C202 H20F 0.9600 . ?
C203 H20A 0.9600 . ?
C203 H20B 0.9600 . ?
C203 H20C 0.9600 . ?
C301 H30A 0.9600 . ?
C301 H30B 0.9600 . ?
C301 H30C 0.9600 . ?
C302 H30D 0.9600 . ?
C302 H30E 0.9600 . ?
C302 H30F 0.9600 . ?
C303 H30G 0.9600 . ?
C303 H30H 0.9600 . ?
C303 H30I 0.9600 . ?
C330 H33A 0.9300 . ?
C401 H40G 0.9600 . ?
C401 H40H 0.9600 . ?
C401 H40I 0.9600 . ?
C402 H40J 0.9600 . ?
C402 H40K 0.9600 . ?
C402 H40L 0.9600 . ?
C403 H40D 0.9600 . ?
C403 H40E 0.9600 . ?
C403 H40F 0.9600 . ?
C501 H50A 0.9600 . ?
C501 H50B 0.9600 . ?
C501 H50C 0.9600 . ?
C502 H50G 0.9600 . ?
C502 H50H 0.9600 . ?
C502 H50I 0.9600 . ?
C503 H50D 0.9600 . ?
C503 H50E 0.9600 . ?
C503 H50F 0.9600 . ?
C601 H60D 0.9600 . ?
C601 H60E 0.9600 . ?
C601 H60F 0.9600 . ?
C602 H60A 0.9600 . ?
C602 H60B 0.9600 . ?
C602 H60C 0.9600 . ?
C603 H60G 0.9600 . ?
C603 H60H 0.9600 . ?
C603 H60I 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C42 Rh1 O1 91.1(2) . . ?
C42 Rh1 O3 175.9(2) . . ?
O1 Rh1 O3 85.17(18) . . ?
C42 Rh1 P1 89.84(18) . . ?
O1 Rh1 P1 175.36(14) . . ?
O3 Rh1 P1 93.98(13) . . ?
C42 Rh1 O5 94.1(2) . . ?
O1 Rh1 O5 89.21(18) . . ?
O3 Rh1 O5 84.07(18) . . ?
P1 Rh1 O5 95.24(14) . . ?
C42 Rh1 Rh2 97.42(19) . . ?
O1 Rh1 Rh2 86.80(13) . . ?
O3 Rh1 Rh2 84.18(12) . . ?
P1 Rh1 Rh2 88.59(5) . . ?
O5 Rh1 Rh2 167.87(13) . . ?
C11 P1 C21 105.7(3) . . ?
C11 P1 C31 102.9(3) . . ?
C21 P1 C31 104.1(3) . . ?
C11 P1 Rh1 112.4(2) . . ?
C21 P1 Rh1 110.0(2) . . ?
C31 P1 Rh1 120.5(2) . . ?
C10 O1 Rh1 118.3(5) . . ?
C103 Si1 C101 110.1(5) . . ?
C103 Si1 C102 110.5(5) . . ?
C101 Si1 C102 109.7(5) . . ?
C103 Si1 C14 109.5(4) . . ?
C101 Si1 C14 108.7(5) . . ?
C102 Si1 C14 108.2(4) . . ?
C12 Rh2 O4 92.7(2) . . ?
C12 Rh2 O2 175.1(2) . . ?
O4 Rh2 O2 82.44(17) . . ?
C12 Rh2 P2 90.61(19) . . ?
O4 Rh2 P2 174.27(13) . . ?
O2 Rh2 P2 94.28(14) . . ?
C12 Rh2 O6 90.8(2) . . ?
O4 Rh2 O6 86.71(16) . . ?
O2 Rh2 O6 88.01(16) . . ?
P2 Rh2 O6 97.91(13) . . ?
C12 Rh2 Rh1 97.06(18) . . ?
O4 Rh2 Rh1 87.05(12) . . ?
O2 Rh2 Rh1 83.70(12) . . ?
P2 Rh2 Rh1 87.92(5) . . ?
O6 Rh2 Rh1 170.21(12) . . ?
C41 P2 C51 103.1(3) . . ?
C41 P2 C61 104.7(3) . . ?
C51 P2 C61 103.7(3) . . ?
C41 P2 Rh2 112.7(2) . . ?
C51 P2 Rh2 120.0(2) . . ?
C61 P2 Rh2 111.2(2) . . ?
C10 O2 Rh2 120.6(4) . . ?
C10 C2 H2A 109.5 . . ?
C10 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C10 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C202 Si2 C201 110.4(10) . . ?
C202 Si2 C24 109.1(6) . . ?
C201 Si2 C24 108.9(5) . . ?
C202 Si2 C203 110.3(8) . . ?
C201 Si2 C203 108.9(8) . . ?
C24 Si2 C203 109.2(6) . . ?
C302 Si3 C303 109.9(8) . . ?
C302 Si3 C34 110.0(5) . . ?
C303 Si3 C34 109.1(5) . . ?
C302 Si3 C301 108.4(6) . . ?
C303 Si3 C301 112.0(7) . . ?
C34 Si3 C301 107.5(5) . . ?
C30 O3 Rh1 121.5(4) . . ?
C30 O4 Rh2 118.1(4) . . ?
C401 Si4 C402 112.9(8) . . ?
C401 Si4 C44 109.4(5) . . ?
C402 Si4 C44 108.8(5) . . ?
C401 Si4 C403 109.8(8) . . ?
C402 Si4 C403 107.9(9) . . ?
C44 Si4 C403 107.9(6) . . ?
C501 Si5 C503 109.5(6) . . ?
C501 Si5 C502 108.4(7) . . ?
C503 Si5 C502 112.2(7) . . ?
C501 Si5 C54 108.3(4) . . ?
C503 Si5 C54 108.6(5) . . ?
C502 Si5 C54 109.8(5) . . ?
C602 Si6 C603 116.0(17) . . ?
C602 Si6 C601 107.1(18) . . ?
C603 Si6 C601 105.2(17) . . ?
C602 Si6 C64 111.0(7) . . ?
C603 Si6 C64 109.6(7) . . ?
C601 Si6 C64 107.4(8) . . ?
O2 C10 O1 124.7(6) . . ?
O2 C10 C2 117.3(7) . . ?
O1 C10 C2 117.9(7) . . ?
C16 C11 C12 119.6(6) . . ?
C16 C11 P1 122.0(5) . . ?
C12 C11 P1 118.4(5) . . ?
C13 C12 C11 117.2(6) . . ?
C13 C12 Rh2 121.5(4) . . ?
C11 C12 Rh2 121.3(5) . . ?
C14 C13 C12 123.3(6) . . ?
C14 C13 H13A 118.4 . . ?
C12 C13 H13A 118.4 . . ?
C13 C14 C15 118.5(6) . . ?
C13 C14 Si1 122.4(5) . . ?
C15 C14 Si1 119.1(5) . . ?
C16 C15 C14 120.0(6) . . ?
C16 C15 H15A 120.0 . . ?
C14 C15 H15A 120.0 . . ?
C15 C16 C11 121.4(6) . . ?
C15 C16 H16A 119.3 . . ?
C11 C16 H16A 119.3 . . ?
C22 C21 C26 116.5(7) . . ?
C22 C21 P1 120.0(6) . . ?
C26 C21 P1 123.1(5) . . ?
C23 C22 C21 122.5(8) . . ?
C23 C22 H22A 118.8 . . ?
C21 C22 H22A 118.8 . . ?
C22 C23 C24 120.9(8) . . ?
C22 C23 H23A 119.6 . . ?
C24 C23 H23A 119.6 . . ?
C23 C24 C25 116.6(7) . . ?
C23 C24 Si2 121.3(7) . . ?
C25 C24 Si2 122.0(7) . . ?
C26 C25 C24 122.4(9) . . ?
C26 C25 H25A 118.8 . . ?
C24 C25 H25A 118.8 . . ?
C25 C26 C21 121.1(8) . . ?
C25 C26 H26A 119.5 . . ?
C21 C26 H26A 119.5 . . ?
O3 C30 O4 125.2(6) . . ?
O3 C30 C40 117.6(6) . . ?
O4 C30 C40 117.3(6) . . ?
C36 C31 C32 117.1(6) . . ?
C36 C31 P1 124.3(6) . . ?
C32 C31 P1 118.6(5) . . ?
C330 C32 C31 121.1(7) . . ?
C330 C32 H32A 119.4 . . ?
C31 C32 H32A 119.4 . . ?
C35 C34 C330 114.9(7) . . ?
C35 C34 Si3 121.9(6) . . ?
C330 C34 Si3 123.1(6) . . ?
C36 C35 C34 123.1(7) . . ?
C36 C35 H35A 118.4 . . ?
C34 C35 H35A 118.4 . . ?
C31 C36 C35 121.0(7) . . ?
C31 C36 H36A 119.5 . . ?
C35 C36 H36A 119.5 . . ?
C30 C40 H40A 109.5 . . ?
C30 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C30 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 C46 120.4(6) . . ?
C42 C41 P2 117.5(5) . . ?
C46 C41 P2 122.1(5) . . ?
C41 C42 C43 116.8(6) . . ?
C41 C42 Rh1 121.8(5) . . ?
C43 C42 Rh1 121.2(5) . . ?
C44 C43 C42 124.5(6) . . ?
C44 C43 H43A 117.8 . . ?
C42 C43 H43A 117.8 . . ?
C43 C44 C45 116.7(6) . . ?
C43 C44 Si4 121.4(5) . . ?
C45 C44 Si4 121.9(6) . . ?
C46 C45 C44 121.0(7) . . ?
C46 C45 H45A 119.5 . . ?
C44 C45 H45A 119.5 . . ?
C45 C46 C41 120.6(7) . . ?
C45 C46 H46A 119.7 . . ?
C41 C46 H46A 119.7 . . ?
C52 C51 C56 116.5(6) . . ?
C52 C51 P2 125.1(5) . . ?
C56 C51 P2 118.4(5) . . ?
C51 C52 C53 121.7(7) . . ?
C51 C52 H52A 119.1 . . ?
C53 C52 H52A 119.1 . . ?
C54 C53 C52 121.4(7) . . ?
C54 C53 H53A 119.3 . . ?
C52 C53 H53A 119.3 . . ?
C55 C54 C53 116.2(7) . . ?
C55 C54 Si5 122.4(6) . . ?
C53 C54 Si5 121.5(6) . . ?
C56 C55 C54 123.0(7) . . ?
C56 C55 H55A 118.5 . . ?
C54 C55 H55A 118.5 . . ?
C55 C56 C51 121.1(6) . . ?
C55 C56 H56A 119.5 . . ?
C51 C56 H56A 119.5 . . ?
C62 C61 C66 117.2(6) . . ?
C62 C61 P2 119.5(6) . . ?
C66 C61 P2 123.2(6) . . ?
C61 C62 C63 122.1(8) . . ?
C61 C62 H62A 119.0 . . ?
C63 C62 H62A 119.0 . . ?
C62 C63 C64 120.5(8) . . ?
C62 C63 H63A 119.8 . . ?
C64 C63 H63A 119.8 . . ?
C65 C64 C63 115.8(8) . . ?
C65 C64 Si6 123.0(8) . . ?
C63 C64 Si6 121.1(7) . . ?
C66 C65 C64 124.0(9) . . ?
C66 C65 H65A 118.0 . . ?
C64 C65 H65A 118.0 . . ?
C65 C66 C61 120.4(8) . . ?
C65 C66 H66A 119.8 . . ?
C61 C66 H66A 119.8 . . ?
Si1 C101 H10D 109.5 . . ?
Si1 C101 H10E 109.5 . . ?
H10D C101 H10E 109.5 . . ?
Si1 C101 H10F 109.5 . . ?
H10D C101 H10F 109.5 . . ?
H10E C101 H10F 109.5 . . ?
Si1 C102 H10A 109.5 . . ?
Si1 C102 H10B 109.5 . . ?
H10A C102 H10B 109.5 . . ?
Si1 C102 H10C 109.5 . . ?
H10A C102 H10C 109.5 . . ?
H10B C102 H10C 109.5 . . ?
Si1 C103 H10G 109.5 . . ?
Si1 C103 H10H 109.5 . . ?
H10G C103 H10H 109.5 . . ?
Si1 C103 H10I 109.5 . . ?
H10G C103 H10I 109.5 . . ?
H10H C103 H10I 109.5 . . ?
Si2 C201 H20G 109.5 . . ?
Si2 C201 H20H 109.5 . . ?
H20G C201 H20H 109.5 . . ?
Si2 C201 H20I 109.5 . . ?
H20G C201 H20I 109.5 . . ?
H20H C201 H20I 109.5 . . ?
Si2 C202 H20D 109.5 . . ?
Si2 C202 H20E 109.5 . . ?
H20D C202 H20E 109.5 . . ?
Si2 C202 H20F 109.5 . . ?
H20D C202 H20F 109.5 . . ?
H20E C202 H20F 109.5 . . ?
Si2 C203 H20A 109.5 . . ?
Si2 C203 H20B 109.5 . . ?
H20A C203 H20B 109.5 . . ?
Si2 C203 H20C 109.5 . . ?
H20A C203 H20C 109.5 . . ?
H20B C203 H20C 109.5 . . ?
Si3 C301 H30A 109.5 . . ?
Si3 C301 H30B 109.5 . . ?
H30A C301 H30B 109.5 . . ?
Si3 C301 H30C 109.5 . . ?
H30A C301 H30C 109.5 . . ?
H30B C301 H30C 109.5 . . ?
Si3 C302 H30D 109.5 . . ?
Si3 C302 H30E 109.5 . . ?
H30D C302 H30E 109.5 . . ?
Si3 C302 H30F 109.5 . . ?
H30D C302 H30F 109.5 . . ?
H30E C302 H30F 109.5 . . ?
Si3 C303 H30G 109.5 . . ?
Si3 C303 H30H 109.5 . . ?
H30G C303 H30H 109.5 . . ?
Si3 C303 H30I 109.5 . . ?
H30G C303 H30I 109.5 . . ?
H30H C303 H30I 109.5 . . ?
C32 C330 C34 122.7(8) . . ?
C32 C330 H33A 118.7 . . ?
C34 C330 H33A 118.7 . . ?
Si4 C401 H40G 109.5 . . ?
Si4 C401 H40H 109.5 . . ?
H40G C401 H40H 109.5 . . ?
Si4 C401 H40I 109.5 . . ?
H40G C401 H40I 109.5 . . ?
H40H C401 H40I 109.5 . . ?
Si4 C402 H40J 109.5 . . ?
Si4 C402 H40K 109.5 . . ?
H40J C402 H40K 109.5 . . ?
Si4 C402 H40L 109.5 . . ?
H40J C402 H40L 109.5 . . ?
H40K C402 H40L 109.5 . . ?
Si4 C403 H40D 109.5 . . ?
Si4 C403 H40E 109.5 . . ?
H40D C403 H40E 109.5 . . ?
Si4 C403 H40F 109.5 . . ?
H40D C403 H40F 109.5 . . ?
H40E C403 H40F 109.5 . . ?
Si5 C501 H50A 109.5 . . ?
Si5 C501 H50B 109.5 . . ?
H50A C501 H50B 109.5 . . ?
Si5 C501 H50C 109.5 . . ?
H50A C501 H50C 109.5 . . ?
H50B C501 H50C 109.5 . . ?
Si5 C502 H50G 109.5 . . ?
Si5 C502 H50H 109.5 . . ?
H50G C502 H50H 109.5 . . ?
Si5 C502 H50I 109.5 . . ?
H50G C502 H50I 109.5 . . ?
H50H C502 H50I 109.5 . . ?
Si5 C503 H50D 109.5 . . ?
Si5 C503 H50E 109.5 . . ?
H50D C503 H50E 109.5 . . ?
Si5 C503 H50F 109.5 . . ?
H50D C503 H50F 109.5 . . ?
H50E C503 H50F 109.5 . . ?
Si6 C601 H60D 109.5 . . ?
Si6 C601 H60E 109.5 . . ?
H60D C601 H60E 109.5 . . ?
Si6 C601 H60F 109.5 . . ?
H60D C601 H60F 109.5 . . ?
H60E C601 H60F 109.5 . . ?
Si6 C602 H60A 109.5 . . ?
Si6 C602 H60B 109.5 . . ?
H60A C602 H60B 109.5 . . ?
Si6 C602 H60C 109.5 . . ?
H60A C602 H60C 109.5 . . ?
H60B C602 H60C 109.5 . . ?
Si6 C603 H60G 109.5 . . ?
Si6 C603 H60H 109.5 . . ?
H60G C603 H60H 109.5 . . ?
Si6 C603 H60I 109.5 . . ?
H60G C603 H60I 109.5 . . ?
H60H C603 H60I 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.936
_diffrn_reflns_theta_full        70.08
_diffrn_measured_fraction_theta_full 0.936
_refine_diff_density_max         2.927
_refine_diff_density_min         -1.629
_refine_diff_density_rms         0.219