# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2006


data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Xiao-Ming Chen'
_publ_contact_author_address     
;
Sun Yat-Sen University
Guangzhou
510275
CHINA
;

_publ_contact_author_email       CXM@MAIL.SYSU.EDU.CN

_publ_section_title              
;
The slow magnetic relaxation observed in a mixed
carboxylate/hydroxide-bridged compound
[Co2Na(4-cpa)2(mu3-OH)(H2O)] featuring spin
frustrated magnetic delta-chains
;

loop_
_publ_author_name
_publ_author_address
'Xiao-Ning Cheng'
; School of Chemistry and Chemical Engineering
Sun Yat-Sen University
Guangzhou 510275
P. R. China
;
'Wei-Xiong Zhang'
; School of Chemistry and Chemical Engineering
Sun Yat-Sen University
Guangzhou 510275
P. R. China
;
'Yan-Zhen Zheng'
; School of Chemistry and Chemical Engineering
Sun Yat-Sen University
Guangzhou 510275
P. R. China
;
'Xiao-Ming Chen'
; School of Chemistry and Chemical Engineering
Sun Yat-Sen University
Guangzhou 510275
P. R. China
;

#============================================================

data_complex_1
_database_code_depnum_ccdc_archive 'CCDC 601874'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C18 H15 Co2 Na O12'
_chemical_formula_weight         564.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.5377(6)
_cell_length_b                   10.0981(7)
_cell_length_c                   22.0819(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.6730(10)
_cell_angle_gamma                90.00
_cell_volume                     1876.7(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            pink
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.997
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1136
_exptl_absorpt_coefficient_mu    1.863
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7303
_exptl_absorpt_correction_T_max  0.8806
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       '/w scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14736
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_sigmaI/netI    0.0234
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.22
_diffrn_reflns_theta_max         27.00
_reflns_number_total             4015
_reflns_number_gt                3635
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       SMART
_computing_cell_refinement       SAINT
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0434P)^2^+1.2448P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4015
_refine_ls_number_parameters     309
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0355
_refine_ls_R_factor_gt           0.0317
_refine_ls_wR_factor_ref         0.0810
_refine_ls_wR_factor_gt          0.0785
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_restrained_S_all      1.054
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.24851(3) 0.78023(3) 0.007893(12) 0.01620(9) Uani 1 1 d . . .
Co2 Co 0.5000 1.0000 0.0000 0.01650(11) Uani 1 2 d S . .
Co3 Co 0.0000 1.0000 0.0000 0.01742(11) Uani 1 2 d S . .
O1 O 1.00447(17) 1.30029(14) 0.46516(7) 0.0207(3) Uani 1 1 d . . .
O1W O 0.2622(2) 0.56975(16) 0.02043(8) 0.0245(3) Uani 1 1 d . . .
O2 O 0.94295(18) 1.10534(16) 0.42027(8) 0.0277(4) Uani 1 1 d . . .
O3 O 0.65322(17) 1.18149(15) 0.36859(7) 0.0220(3) Uani 1 1 d . . .
O4 O 0.54744(17) 1.06810(15) 0.08682(6) 0.0230(3) Uani 1 1 d . . .
O5 O 0.71491(18) 1.23867(15) 0.08530(7) 0.0231(3) Uani 1 1 d . . .
O6 O 0.00474(17) 0.78856(15) -0.02394(7) 0.0211(3) Uani 1 1 d . . .
O7 O -0.02651(18) 0.59462(17) -0.07292(8) 0.0325(4) Uani 1 1 d . . .
O8 O -0.33297(17) 0.64431(16) -0.12097(7) 0.0231(3) Uani 1 1 d . . .
O9 O -0.45419(17) 0.53830(16) -0.40687(7) 0.0228(3) Uani 1 1 d . . .
O10 O -0.27692(19) 0.70350(16) -0.40176(7) 0.0276(4) Uani 1 1 d . . .
O13 O 0.24842(15) 0.98649(16) 0.00053(7) 0.0243(4) Uani 1 1 d . . .
H13 H 0.2679 0.9940 0.0454 0.029 Uiso 1 1 calc R . .
C1 C 0.9116(2) 1.2212(2) 0.43171(9) 0.0183(4) Uani 1 1 d . . .
C2 C 0.7480(2) 1.2757(2) 0.40651(9) 0.0217(4) Uani 1 1 d . . .
H2A H 0.6948 1.3001 0.4404 0.026 Uiso 1 1 calc R . .
H2B H 0.7590 1.3549 0.3828 0.026 Uiso 1 1 calc R . .
C3 C 0.6646(2) 1.1769(2) 0.30735(9) 0.0197(4) Uani 1 1 d . . .
C4 C 0.7754(2) 1.2466(2) 0.28024(10) 0.0234(5) Uani 1 1 d . . .
H4A H 0.8533 1.2973 0.3042 0.028 Uiso 1 1 calc R . .
C5 C 0.7681(2) 1.2396(2) 0.21730(10) 0.0228(5) Uani 1 1 d . . .
H5A H 0.8407 1.2872 0.1990 0.027 Uiso 1 1 calc R . .
C6 C 0.6543(2) 1.1625(2) 0.18090(9) 0.0191(4) Uani 1 1 d . . .
C7 C 0.5498(2) 1.0880(2) 0.20989(10) 0.0228(4) Uani 1 1 d . . .
H7A H 0.4764 1.0325 0.1865 0.027 Uiso 1 1 calc R . .
C8 C 0.5540(2) 1.0953(2) 0.27210(10) 0.0225(4) Uani 1 1 d . . .
H8A H 0.4831 1.0459 0.2906 0.027 Uiso 1 1 calc R . .
C9 C 0.6384(2) 1.1571(2) 0.11267(9) 0.0183(4) Uani 1 1 d . . .
C10 C -0.0756(2) 0.7038(2) -0.05951(9) 0.0193(4) Uani 1 1 d . . .
C11 C -0.2456(2) 0.7443(2) -0.08470(10) 0.0224(5) Uani 1 1 d . . .
H11A H -0.2995 0.7659 -0.0506 0.027 Uiso 1 1 calc R . .
H11B H -0.2440 0.8235 -0.1094 0.027 Uiso 1 1 calc R . .
C12 C -0.3229(2) 0.6367(2) -0.18192(9) 0.0192(4) Uani 1 1 d . . .
C13 C -0.2189(2) 0.7108(2) -0.21075(10) 0.0238(5) Uani 1 1 d . . .
H13A H -0.1428 0.7648 -0.1878 0.029 Uiso 1 1 calc R . .
C14 C -0.2300(2) 0.7031(2) -0.27398(10) 0.0233(5) Uani 1 1 d . . .
H14A H -0.1618 0.7536 -0.2933 0.028 Uiso 1 1 calc R . .
C15 C -0.3411(2) 0.6216(2) -0.30914(9) 0.0197(4) Uani 1 1 d . . .
C16 C -0.4392(2) 0.5439(2) -0.27901(10) 0.0220(4) Uani 1 1 d . . .
H16A H -0.5117 0.4864 -0.3016 0.026 Uiso 1 1 calc R . .
C17 C -0.4304(2) 0.5511(2) -0.21630(10) 0.0231(4) Uani 1 1 d . . .
H17A H -0.4964 0.4985 -0.1969 0.028 Uiso 1 1 calc R . .
C18 C -0.3592(2) 0.6215(2) -0.37773(9) 0.0201(4) Uani 1 1 d . . .
Na1 Na 0.72522(11) 0.96226(9) 0.41283(4) 0.0295(2) Uani 1 1 d . . .
H1W H 0.195(4) 0.535(4) 0.0398(16) 0.070(12) Uiso 1 1 d . . .
H2W H 0.343(4) 0.565(3) 0.0442(15) 0.047(9) Uiso 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Co1 0.01572(15) 0.01601(16) 0.01664(15) -0.00030(10) 0.00202(10) 0.00061(10)
Co2 0.01630(19) 0.0168(2) 0.0156(2) -0.00066(15) 0.00040(15) -0.00125(14)
Co3 0.01500(19) 0.0185(2) 0.0180(2) 0.00128(15) 0.00040(15) 0.00176(14)
O1 0.0169(7) 0.0199(7) 0.0241(8) -0.0043(6) 0.0000(6) -0.0006(6)
O1W 0.0213(8) 0.0222(8) 0.0285(9) 0.0039(7) 0.0002(7) 0.0001(6)
O2 0.0214(8) 0.0217(8) 0.0379(9) -0.0061(7) -0.0012(7) 0.0010(6)
O3 0.0207(7) 0.0283(8) 0.0162(7) -0.0020(6) 0.0005(6) -0.0027(6)
O4 0.0252(8) 0.0276(8) 0.0165(7) -0.0050(6) 0.0039(6) -0.0050(6)
O5 0.0269(8) 0.0239(8) 0.0193(8) -0.0012(6) 0.0062(6) -0.0037(6)
O6 0.0177(7) 0.0204(7) 0.0237(8) -0.0025(6) -0.0003(6) 0.0005(6)
O7 0.0234(8) 0.0255(9) 0.0464(10) -0.0105(8) -0.0008(7) 0.0043(7)
O8 0.0220(7) 0.0313(9) 0.0154(7) -0.0023(6) 0.0011(6) -0.0046(6)
O9 0.0238(8) 0.0274(8) 0.0168(7) -0.0040(6) 0.0025(6) -0.0049(6)
O10 0.0342(9) 0.0307(9) 0.0187(8) -0.0024(7) 0.0068(6) -0.0081(7)
O13 0.0205(8) 0.0189(8) 0.0358(10) 0.0019(6) 0.0116(7) 0.0017(6)
C1 0.0178(9) 0.0209(10) 0.0166(10) 0.0007(8) 0.0041(8) -0.0009(8)
C2 0.0209(10) 0.0266(11) 0.0159(10) -0.0043(8) -0.0015(8) 0.0020(8)
C3 0.0196(10) 0.0218(11) 0.0170(10) 0.0007(8) 0.0009(8) 0.0036(8)
C4 0.0197(10) 0.0266(11) 0.0226(11) -0.0042(9) 0.0001(8) -0.0063(9)
C5 0.0201(10) 0.0269(11) 0.0221(11) 0.0005(9) 0.0052(8) -0.0047(9)
C6 0.0195(10) 0.0200(10) 0.0175(10) -0.0028(8) 0.0021(8) 0.0013(8)
C7 0.0217(10) 0.0238(11) 0.0218(11) -0.0035(9) 0.0004(8) -0.0055(9)
C8 0.0220(10) 0.0244(11) 0.0213(11) 0.0000(9) 0.0040(8) -0.0048(9)
C9 0.0159(9) 0.0187(10) 0.0200(10) -0.0016(8) 0.0021(8) 0.0037(8)
C10 0.0174(10) 0.0225(11) 0.0178(10) -0.0003(8) 0.0021(8) 0.0000(8)
C11 0.0198(10) 0.0294(12) 0.0173(10) -0.0050(9) 0.0012(8) 0.0020(9)
C12 0.0173(9) 0.0236(11) 0.0162(10) 0.0009(8) 0.0012(7) 0.0029(8)
C13 0.0187(10) 0.0291(12) 0.0230(11) -0.0042(9) 0.0016(8) -0.0060(9)
C14 0.0208(10) 0.0285(12) 0.0212(11) -0.0006(9) 0.0048(8) -0.0037(9)
C15 0.0203(10) 0.0201(10) 0.0193(10) -0.0022(8) 0.0049(8) 0.0012(8)
C16 0.0226(10) 0.0217(11) 0.0205(11) -0.0041(8) 0.0006(8) -0.0058(9)
C17 0.0221(10) 0.0253(11) 0.0222(11) 0.0011(9) 0.0047(8) -0.0058(9)
C18 0.0183(10) 0.0219(11) 0.0200(10) -0.0009(8) 0.0031(8) 0.0046(8)
Na1 0.0301(5) 0.0233(5) 0.0344(5) 0.0048(4) 0.0029(4) -0.0048(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 O10 2.0494(15) 4_676 ?
Co1 O6 2.0835(15) . ?
Co1 O13 2.0891(16) . ?
Co1 O1 2.1027(14) 2_645 ?
Co1 O5 2.1413(15) 3_675 ?
Co1 O1W 2.1441(16) . ?
Co1 Na1 3.2098(9) 4_575 ?
Co2 O4 2.0127(14) . ?
Co2 O4 2.0127(14) 3_675 ?
Co2 O13 2.1542(13) . ?
Co2 O13 2.1542(13) 3_675 ?
Co2 O1 2.1611(14) 2_645 ?
Co2 O1 2.1611(14) 4_585 ?
Co3 O9 2.0642(15) 4_676 ?
Co3 O9 2.0642(15) 2_454 ?
Co3 O13 2.1234(13) 3_575 ?
Co3 O13 2.1234(13) . ?
Co3 O6 2.2016(15) 3_575 ?
Co3 O6 2.2016(15) . ?
O1 C1 1.271(2) . ?
O1 Co1 2.1027(14) 2_655 ?
O1 Co2 2.1611(14) 2_655 ?
O1W Na1 2.366(2) 4_575 ?
O2 C1 1.236(3) . ?
O2 Na1 2.3382(18) . ?
O3 C3 1.373(3) . ?
O3 C2 1.426(2) . ?
O3 Na1 2.4558(18) . ?
O4 C9 1.260(2) . ?
O5 C9 1.266(3) . ?
O5 Co1 2.1413(15) 3_675 ?
O5 Na1 2.3139(18) 2_655 ?
O6 C10 1.280(3) . ?
O7 C10 1.233(3) . ?
O7 Na1 2.2968(18) 4_575 ?
O8 C12 1.365(2) . ?
O8 C11 1.420(3) . ?
O9 C18 1.266(3) . ?
O9 Co3 2.0642(15) 2_444 ?
O10 C18 1.259(3) . ?
O10 Co1 2.0494(15) 4_575 ?
C1 C2 1.517(3) . ?
C1 Na1 3.053(2) . ?
C3 C8 1.389(3) . ?
C3 C4 1.392(3) . ?
C4 C5 1.383(3) . ?
C5 C6 1.390(3) . ?
C6 C7 1.401(3) . ?
C6 C9 1.491(3) . ?
C7 C8 1.370(3) . ?
C10 C11 1.521(3) . ?
C12 C17 1.390(3) . ?
C12 C13 1.395(3) . ?
C13 C14 1.386(3) . ?
C14 C15 1.390(3) . ?
C15 C16 1.396(3) . ?
C15 C18 1.497(3) . ?
C16 C17 1.376(3) . ?
Na1 O7 2.2968(18) 4_676 ?
Na1 O5 2.3139(18) 2_645 ?
Na1 O1W 2.366(2) 4_676 ?
Na1 Co1 3.2098(9) 4_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10 Co1 O6 93.55(6) 4_676 . ?
O10 Co1 O13 89.84(6) 4_676 . ?
O6 Co1 O13 86.92(5) . . ?
O10 Co1 O1 88.98(6) 4_676 2_645 ?
O6 Co1 O1 171.55(6) . 2_645 ?
O13 Co1 O1 85.02(5) . 2_645 ?
O10 Co1 O5 177.66(6) 4_676 3_675 ?
O6 Co1 O5 88.75(6) . 3_675 ?
O13 Co1 O5 90.70(6) . 3_675 ?
O1 Co1 O5 88.81(6) 2_645 3_675 ?
O10 Co1 O1W 88.06(7) 4_676 . ?
O6 Co1 O1W 96.50(6) . . ?
O13 Co1 O1W 176.09(6) . . ?
O1 Co1 O1W 91.65(6) 2_645 . ?
O5 Co1 O1W 91.27(6) 3_675 . ?
O10 Co1 Na1 133.85(5) 4_676 4_575 ?
O6 Co1 Na1 82.04(4) . 4_575 ?
O13 Co1 Na1 135.27(5) . 4_575 ?
O1 Co1 Na1 101.97(4) 2_645 4_575 ?
O5 Co1 Na1 46.09(4) 3_675 4_575 ?
O1W Co1 Na1 47.48(5) . 4_575 ?
O4 Co2 O4 180.0 . 3_675 ?
O4 Co2 O13 93.31(6) . . ?
O4 Co2 O13 86.69(6) 3_675 . ?
O4 Co2 O13 86.69(6) . 3_675 ?
O4 Co2 O13 93.31(6) 3_675 3_675 ?
O13 Co2 O13 180.00(8) . 3_675 ?
O4 Co2 O1 89.57(6) . 2_645 ?
O4 Co2 O1 90.43(6) 3_675 2_645 ?
O13 Co2 O1 82.05(6) . 2_645 ?
O13 Co2 O1 97.95(6) 3_675 2_645 ?
O4 Co2 O1 90.43(6) . 4_585 ?
O4 Co2 O1 89.57(6) 3_675 4_585 ?
O13 Co2 O1 97.95(6) . 4_585 ?
O13 Co2 O1 82.05(6) 3_675 4_585 ?
O1 Co2 O1 180.0 2_645 4_585 ?
O9 Co3 O9 180.00(9) 4_676 2_454 ?
O9 Co3 O13 92.26(6) 4_676 3_575 ?
O9 Co3 O13 87.74(6) 2_454 3_575 ?
O9 Co3 O13 87.74(6) 4_676 . ?
O9 Co3 O13 92.26(6) 2_454 . ?
O13 Co3 O13 180.0 3_575 . ?
O9 Co3 O6 87.17(6) 4_676 3_575 ?
O9 Co3 O6 92.83(6) 2_454 3_575 ?
O13 Co3 O6 83.13(6) 3_575 3_575 ?
O13 Co3 O6 96.87(6) . 3_575 ?
O9 Co3 O6 92.83(6) 4_676 . ?
O9 Co3 O6 87.17(6) 2_454 . ?
O13 Co3 O6 96.87(6) 3_575 . ?
O13 Co3 O6 83.13(6) . . ?
O6 Co3 O6 180.0 3_575 . ?
C1 O1 Co1 127.03(13) . 2_655 ?
C1 O1 Co2 138.29(13) . 2_655 ?
Co1 O1 Co2 93.78(6) 2_655 2_655 ?
Co1 O1W Na1 90.61(7) . 4_575 ?
C1 O2 Na1 113.73(13) . . ?
C3 O3 C2 118.30(16) . . ?
C3 O3 Na1 107.88(12) . . ?
C2 O3 Na1 106.76(12) . . ?
C9 O4 Co2 133.26(14) . . ?
C9 O5 Co1 124.82(13) . 3_675 ?
C9 O5 Na1 139.15(14) . 2_655 ?
Co1 O5 Na1 92.10(6) 3_675 2_655 ?
C10 O6 Co1 125.57(13) . . ?
C10 O6 Co3 140.01(13) . . ?
Co1 O6 Co3 90.90(6) . . ?
C10 O7 Na1 128.32(15) . 4_575 ?
C12 O8 C11 118.83(16) . . ?
C18 O9 Co3 128.95(14) . 2_444 ?
C18 O10 Co1 128.36(14) . 4_575 ?
Co1 O13 Co3 92.97(6) . . ?
Co1 O13 Co2 94.37(6) . . ?
Co3 O13 Co2 172.66(9) . . ?
O2 C1 O1 125.32(19) . . ?
O2 C1 C2 119.06(19) . . ?
O1 C1 C2 115.58(18) . . ?
O2 C1 Na1 44.51(10) . . ?
O1 C1 Na1 151.33(14) . . ?
C2 C1 Na1 80.42(12) . . ?
O3 C2 C1 111.73(17) . . ?
O3 C3 C8 114.70(18) . . ?
O3 C3 C4 124.90(19) . . ?
C8 C3 C4 120.4(2) . . ?
C5 C4 C3 119.1(2) . . ?
C4 C5 C6 121.3(2) . . ?
C5 C6 C7 118.24(19) . . ?
C5 C6 C9 122.74(19) . . ?
C7 C6 C9 119.02(18) . . ?
C8 C7 C6 121.20(19) . . ?
C7 C8 C3 119.6(2) . . ?
O4 C9 O5 125.16(19) . . ?
O4 C9 C6 115.38(18) . . ?
O5 C9 C6 119.47(18) . . ?
O7 C10 O6 125.21(19) . . ?
O7 C10 C11 119.65(19) . . ?
O6 C10 C11 115.13(18) . . ?
O8 C11 C10 113.19(17) . . ?
O8 C12 C17 115.38(18) . . ?
O8 C12 C13 124.76(19) . . ?
C17 C12 C13 119.82(19) . . ?
C14 C13 C12 119.2(2) . . ?
C13 C14 C15 121.4(2) . . ?
C14 C15 C16 118.35(19) . . ?
C14 C15 C18 120.68(19) . . ?
C16 C15 C18 120.93(19) . . ?
C17 C16 C15 120.9(2) . . ?
C16 C17 C12 120.1(2) . . ?
O10 C18 O9 125.27(19) . . ?
O10 C18 C15 117.13(19) . . ?
O9 C18 C15 117.59(18) . . ?
O7 Na1 O5 87.85(6) 4_676 2_645 ?
O7 Na1 O2 153.65(7) 4_676 . ?
O5 Na1 O2 115.54(7) 2_645 . ?
O7 Na1 O1W 78.35(7) 4_676 4_676 ?
O5 Na1 O1W 81.78(6) 2_645 4_676 ?
O2 Na1 O1W 92.50(6) . 4_676 ?
O7 Na1 O3 95.88(6) 4_676 . ?
O5 Na1 O3 157.90(7) 2_645 . ?
O2 Na1 O3 67.29(6) . . ?
O1W Na1 O3 120.32(7) 4_676 . ?
O7 Na1 C1 132.35(7) 4_676 . ?
O5 Na1 C1 136.46(7) 2_645 . ?
O2 Na1 C1 21.76(5) . . ?
O1W Na1 C1 90.08(6) 4_676 . ?
O3 Na1 C1 51.10(5) . . ?
O7 Na1 Co1 71.10(5) 4_676 4_676 ?
O5 Na1 Co1 41.81(4) 2_645 4_676 ?
O2 Na1 Co1 117.67(5) . 4_676 ?
O1W Na1 Co1 41.91(4) 4_676 4_676 ?
O3 Na1 Co1 158.70(5) . 4_676 ?
C1 Na1 Co1 126.20(5) . 4_676 ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        27.00
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         0.717
_refine_diff_density_min         -0.386
_refine_diff_density_rms         0.092