# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2006

data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Chad Mirkin'
_publ_contact_author_address     
;
Department of Chemistry and the International Institute for
Nanotechnology
Northwestern University
2145 Sheridan Rd.
Evanston
IL
60208
UNITED STATES OF AMERICA
;

_publ_contact_author_email       CAM-SEC@CHEM.NORTHWESTERN.EDU

_publ_section_title              
;
Tetrametallic Rectangular Box Complexes Assembled from
Heteroligated Macrocycles
;
loop_
_publ_author_name
'Chad Mirkin'
'Aaron M. Brown'
'Maxim V. Ovchinnikov'
'Charlotte L. Stern'

# Attachment 's95n1m.cif'

data_s95n1m
_database_code_depnum_ccdc_archive 'CCDC 615031'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C162.50 H142 B4 Cl6 F16 N4 O4 P8 Rh4 S4'
_chemical_formula_weight         3562.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   17.6443(14)
_cell_length_b                   21.5365(17)
_cell_length_c                   24.3009(19)
_cell_angle_alpha                73.6160(10)
_cell_angle_beta                 75.7640(10)
_cell_angle_gamma                88.2150(10)
_cell_volume                     8580.0(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.572
_exptl_crystal_size_mid          0.552
_exptl_crystal_size_min          0.202
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3614
_exptl_absorpt_coefficient_mu    0.663
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.6992
_exptl_absorpt_correction_T_max  0.8831
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            79001
_diffrn_reflns_av_R_equivalents  0.0446
_diffrn_reflns_av_sigmaI/netI    0.0601
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         0.99
_diffrn_reflns_theta_max         28.82
_reflns_number_total             39961
_reflns_number_gt                25179
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         39961
_refine_ls_number_parameters     1861
_refine_ls_number_restraints     16
_refine_ls_R_factor_all          0.1391
_refine_ls_R_factor_gt           0.0987
_refine_ls_wR_factor_ref         0.3260
_refine_ls_wR_factor_gt          0.2883
_refine_ls_goodness_of_fit_ref   1.192
_refine_ls_restrained_S_all      1.192
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.00037(3) 0.22312(2) 0.534087(19) 0.02782(13) Uani 1 1 d . . .
Rh2 Rh -0.10286(4) 0.32435(3) 0.88509(2) 0.04308(16) Uani 1 1 d . . .
Rh3 Rh 0.41574(3) 0.45572(2) 0.75321(2) 0.03435(14) Uani 1 1 d . . .
Rh4 Rh 0.47823(4) 0.07403(4) 0.69015(3) 0.0648(2) Uani 1 1 d . . .
S1 S 0.00205(9) 0.11881(7) 0.59936(6) 0.0305(3) Uani 1 1 d . . .
S2 S -0.05815(12) 0.42686(8) 0.81903(8) 0.0476(4) Uani 1 1 d . . .
S3 S 0.36668(10) 0.38161(8) 0.84702(8) 0.0406(4) Uani 1 1 d . . .
S4 S 0.47448(12) 0.14037(12) 0.59534(9) 0.0626(6) Uani 1 1 d . . .
P1 P -0.08882(9) 0.18123(7) 0.50173(6) 0.0277(3) Uani 1 1 d . . .
P2 P 0.01000(9) 0.32604(7) 0.47332(6) 0.0283(3) Uani 1 1 d . . .
P3 P -0.21449(12) 0.37080(8) 0.91134(8) 0.0448(4) Uani 1 1 d . . .
P4 P -0.14169(13) 0.22330(8) 0.94732(8) 0.0442(4) Uani 1 1 d . . .
P5 P 0.49814(10) 0.49235(8) 0.79386(8) 0.0375(4) Uani 1 1 d . . .
P6 P 0.45341(10) 0.52866(8) 0.66212(7) 0.0345(3) Uani 1 1 d . . .
P7 P 0.59190(13) 0.04344(11) 0.64415(9) 0.0580(6) Uani 1 1 d . . .
P8 P 0.47791(18) 0.00667(11) 0.78137(10) 0.0803(10) Uani 1 1 d . . .
O3 O 0.5046(3) 0.4171(3) 0.5875(2) 0.0540(13) Uani 1 1 d . . .
O4 O 0.4750(3) 0.1186(2) 0.8493(2) 0.0502(13) Uani 1 1 d . . .
O5 O -0.1203(4) 0.1456(2) 0.8411(2) 0.0528(13) Uani 1 1 d . . .
O6 O -0.0387(3) 0.4137(2) 0.57544(19) 0.0383(10) Uani 1 1 d . . .
N1 N 0.0699(3) 0.2525(2) 0.5802(2) 0.0340(11) Uani 1 1 d . . .
N2 N 0.3429(3) 0.4072(3) 0.7230(3) 0.0417(13) Uani 1 1 d . . .
N3 N 0.0006(4) 0.2878(3) 0.8498(3) 0.0536(16) Uani 1 1 d . . .
N4 N 0.3804(4) 0.1173(4) 0.7256(3) 0.069(2) Uani 1 1 d . . .
C1 C -0.0719(4) 0.0705(3) 0.5878(3) 0.0380(14) Uani 1 1 d . . .
H1A H -0.0469 0.0473 0.5585 0.046 Uiso 1 1 calc R . .
H1B H -0.0958 0.0376 0.6255 0.046 Uiso 1 1 calc R . .
C2 C -0.1354(3) 0.1118(3) 0.5658(3) 0.0345(13) Uani 1 1 d . . .
H2A H -0.1678 0.1280 0.5979 0.041 Uiso 1 1 calc R . .
H2B H -0.1697 0.0856 0.5535 0.041 Uiso 1 1 calc R . .
C3 C -0.0578(3) 0.1454(3) 0.4404(3) 0.0331(12) Uani 1 1 d . . .
C4 C -0.0911(4) 0.0890(3) 0.4385(3) 0.0380(14) Uani 1 1 d . . .
H4 H -0.1319 0.0666 0.4710 0.046 Uiso 1 1 calc R . .
C5 C -0.0667(4) 0.0648(4) 0.3911(3) 0.0468(16) Uani 1 1 d . . .
H5 H -0.0898 0.0255 0.3911 0.056 Uiso 1 1 calc R . .
C6 C -0.0086(5) 0.0974(4) 0.3434(4) 0.056(2) Uani 1 1 d . . .
H6 H 0.0077 0.0810 0.3101 0.068 Uiso 1 1 calc R . .
C7 C 0.0264(5) 0.1540(4) 0.3435(3) 0.056(2) Uani 1 1 d . . .
H7 H 0.0666 0.1761 0.3104 0.067 Uiso 1 1 calc R . .
C8 C 0.0028(4) 0.1784(4) 0.3917(3) 0.0449(16) Uani 1 1 d . . .
H8 H 0.0272 0.2170 0.3921 0.054 Uiso 1 1 calc R . .
C9 C -0.1756(3) 0.2261(3) 0.4882(3) 0.0319(12) Uani 1 1 d . . .
C10 C -0.1999(4) 0.2345(3) 0.4361(3) 0.0431(15) Uani 1 1 d . . .
H10 H -0.1711 0.2169 0.4059 0.052 Uiso 1 1 calc R . .
C11 C -0.2661(4) 0.2686(4) 0.4290(4) 0.0527(19) Uani 1 1 d . . .
H11 H -0.2830 0.2743 0.3937 0.063 Uiso 1 1 calc R . .
C12 C -0.3076(5) 0.2940(4) 0.4723(4) 0.0525(18) Uani 1 1 d . . .
H12 H -0.3531 0.3173 0.4668 0.063 Uiso 1 1 calc R . .
C13 C -0.2839(4) 0.2860(4) 0.5248(4) 0.0509(19) Uani 1 1 d . . .
H13 H -0.3130 0.3037 0.5549 0.061 Uiso 1 1 calc R . .
C14 C -0.2180(4) 0.2525(3) 0.5322(3) 0.0388(14) Uani 1 1 d . . .
H14 H -0.2012 0.2473 0.5674 0.047 Uiso 1 1 calc R . .
C15 C 0.0102(4) 0.3432(3) 0.3954(3) 0.0343(13) Uani 1 1 d . . .
C16 C -0.0578(4) 0.3564(3) 0.3750(3) 0.0434(15) Uani 1 1 d . . .
H16 H -0.1058 0.3585 0.4025 0.052 Uiso 1 1 calc R . .
C17 C -0.0575(5) 0.3667(4) 0.3160(4) 0.0562(19) Uani 1 1 d . . .
H17 H -0.1046 0.3753 0.3032 0.067 Uiso 1 1 calc R . .
C18 C 0.0121(6) 0.3639(4) 0.2762(3) 0.065(2) Uani 1 1 d . . .
H18 H 0.0130 0.3711 0.2357 0.078 Uiso 1 1 calc R . .
C19 C 0.0817(5) 0.3509(4) 0.2943(3) 0.057(2) Uani 1 1 d . . .
H19 H 0.1293 0.3484 0.2665 0.068 Uiso 1 1 calc R . .
C20 C 0.0806(4) 0.3415(4) 0.3534(3) 0.0449(16) Uani 1 1 d . . .
H20 H 0.1280 0.3339 0.3657 0.054 Uiso 1 1 calc R . .
C21 C 0.1013(4) 0.3679(3) 0.4686(3) 0.0329(12) Uani 1 1 d . . .
C22 C 0.1068(4) 0.4327(3) 0.4663(3) 0.0365(13) Uani 1 1 d . . .
H22 H 0.0615 0.4578 0.4671 0.044 Uiso 1 1 calc R . .
C23 C 0.1782(5) 0.4611(3) 0.4628(3) 0.0493(18) Uani 1 1 d . . .
H23 H 0.1815 0.5058 0.4603 0.059 Uiso 1 1 calc R . .
C24 C 0.2438(4) 0.4252(4) 0.4629(3) 0.0478(17) Uani 1 1 d . . .
H24 H 0.2919 0.4444 0.4622 0.057 Uiso 1 1 calc R . .
C25 C 0.2394(4) 0.3624(4) 0.4640(3) 0.0501(17) Uani 1 1 d . . .
H25 H 0.2851 0.3377 0.4628 0.060 Uiso 1 1 calc R . .
C26 C 0.1688(4) 0.3334(3) 0.4670(3) 0.0364(13) Uani 1 1 d . . .
H26 H 0.1668 0.2890 0.4680 0.044 Uiso 1 1 calc R . .
C27 C -0.0698(4) 0.3750(3) 0.5001(3) 0.0363(13) Uani 1 1 d . . .
H27A H -0.0561 0.4211 0.4780 0.044 Uiso 1 1 calc R . .
H27B H -0.1175 0.3629 0.4903 0.044 Uiso 1 1 calc R . .
C28 C -0.0892(4) 0.3691(3) 0.5658(3) 0.0351(13) Uani 1 1 d . . .
H28A H -0.1446 0.3792 0.5795 0.042 Uiso 1 1 calc R . .
H28B H -0.0814 0.3243 0.5883 0.042 Uiso 1 1 calc R . .
C29 C -0.0473(4) 0.4139(3) 0.6326(3) 0.0345(13) Uani 1 1 d . . .
C30 C -0.0985(4) 0.3717(3) 0.6811(3) 0.0361(13) Uani 1 1 d . . .
H30 H -0.1317 0.3415 0.6754 0.043 Uiso 1 1 calc R . .
C31 C -0.1000(4) 0.3747(3) 0.7378(3) 0.0364(13) Uani 1 1 d . . .
H31 H -0.1323 0.3443 0.7709 0.044 Uiso 1 1 calc R . .
C32 C -0.0557(4) 0.4208(3) 0.7469(3) 0.0352(13) Uani 1 1 d . . .
C33 C -0.0068(4) 0.4641(3) 0.6982(3) 0.0390(14) Uani 1 1 d . . .
H33 H 0.0234 0.4965 0.7038 0.047 Uiso 1 1 calc R . .
C34 C -0.0023(4) 0.4601(3) 0.6422(3) 0.0397(14) Uani 1 1 d . . .
H34 H 0.0321 0.4893 0.6094 0.048 Uiso 1 1 calc R . .
C35 C -0.1407(6) 0.4784(3) 0.8294(4) 0.058(2) Uani 1 1 d . . .
H35A H -0.1371 0.4998 0.8598 0.070 Uiso 1 1 calc R . .
H35B H -0.1383 0.5126 0.7919 0.070 Uiso 1 1 calc R . .
C36 C -0.2182(5) 0.4408(4) 0.8484(3) 0.057(2) Uani 1 1 d . . .
H36A H -0.2273 0.4262 0.8153 0.068 Uiso 1 1 calc R . .
H36B H -0.2614 0.4686 0.8601 0.068 Uiso 1 1 calc R . .
C37 C -0.3074(5) 0.3275(4) 0.9256(3) 0.0522(18) Uani 1 1 d . . .
C38 C -0.3264(5) 0.3092(4) 0.8796(4) 0.058(2) Uani 1 1 d . . .
H38 H -0.2940 0.3238 0.8405 0.069 Uiso 1 1 calc R . .
C39 C -0.3911(6) 0.2705(5) 0.8908(5) 0.071(3) Uani 1 1 d . . .
H39 H -0.4014 0.2564 0.8596 0.085 Uiso 1 1 calc R . .
C40 C -0.4397(7) 0.2521(5) 0.9433(6) 0.085(3) Uani 1 1 d . . .
H40 H -0.4859 0.2272 0.9489 0.102 Uiso 1 1 calc R . .
C41 C -0.4243(8) 0.2687(7) 0.9904(5) 0.114(5) Uani 1 1 d . . .
H41 H -0.4586 0.2545 1.0287 0.137 Uiso 1 1 calc R . .
C42 C -0.3577(7) 0.3067(6) 0.9806(5) 0.097(4) Uani 1 1 d . . .
H42 H -0.3467 0.3186 1.0127 0.116 Uiso 1 1 calc R . .
C43 C -0.2244(6) 0.4098(3) 0.9709(3) 0.059(2) Uani 1 1 d . . .
C44 C -0.2908(8) 0.4419(7) 0.9869(5) 0.110(5) Uani 1 1 d . . .
H44 H -0.3333 0.4439 0.9690 0.132 Uiso 1 1 calc R . .
C45 C -0.2915(10) 0.4725(8) 1.0330(7) 0.135(7) Uani 1 1 d . . .
H45 H -0.3382 0.4925 1.0470 0.162 Uiso 1 1 calc R . .
C46 C -0.2344(11) 0.4748(6) 1.0563(5) 0.107(5) Uani 1 1 d . . .
H46 H -0.2375 0.4963 1.0859 0.128 Uiso 1 1 calc R . .
C47 C -0.1735(15) 0.4467(8) 1.0374(7) 0.159(9) Uani 1 1 d . . .
H47 H -0.1308 0.4483 1.0544 0.191 Uiso 1 1 calc R . .
C48 C -0.1620(11) 0.4128(8) 0.9934(6) 0.137(7) Uani 1 1 d . . .
H48 H -0.1140 0.3937 0.9808 0.164 Uiso 1 1 calc R . .
C49 C -0.1974(6) 0.2144(3) 1.0240(3) 0.054(2) Uani 1 1 d . . .
C50 C -0.2670(8) 0.1811(5) 1.0491(4) 0.096(4) Uani 1 1 d . . .
H50 H -0.2888 0.1600 1.0267 0.115 Uiso 1 1 calc R . .
C51 C -0.3076(10) 0.1770(5) 1.1077(4) 0.122(6) Uani 1 1 d . . .
H51 H -0.3568 0.1541 1.1246 0.147 Uiso 1 1 calc R . .
C52 C -0.2750(9) 0.2066(5) 1.1401(4) 0.092(4) Uani 1 1 d . . .
H52 H -0.2985 0.2002 1.1810 0.111 Uiso 1 1 calc R . .
C53 C -0.2070(9) 0.2461(9) 1.1128(6) 0.123(6) Uani 1 1 d . . .
H53 H -0.1878 0.2710 1.1335 0.148 Uiso 1 1 calc R . .
C54 C -0.1680(7) 0.2485(7) 1.0555(5) 0.096(4) Uani 1 1 d . . .
H54 H -0.1205 0.2738 1.0374 0.115 Uiso 1 1 calc R . .
C55 C -0.0572(6) 0.1722(4) 0.9585(3) 0.061(2) Uani 1 1 d . . .
C56 C -0.0500(7) 0.1129(4) 0.9479(4) 0.075(3) Uani 1 1 d . . .
H56 H -0.0919 0.0947 0.9386 0.090 Uiso 1 1 calc R . .
C57 C 0.0191(9) 0.0784(6) 0.9506(5) 0.101(4) Uani 1 1 d . . .
H57 H 0.0251 0.0376 0.9425 0.121 Uiso 1 1 calc R . .
C58 C 0.0798(9) 0.1080(7) 0.9660(6) 0.104(4) Uani 1 1 d . . .
H58 H 0.1283 0.0877 0.9668 0.124 Uiso 1 1 calc R . .
C59 C 0.0680(8) 0.1630(6) 0.9790(5) 0.089(3) Uani 1 1 d . . .
H59 H 0.1069 0.1796 0.9926 0.107 Uiso 1 1 calc R . .
C60 C 0.0020(5) 0.1982(5) 0.9741(4) 0.063(2) Uani 1 1 d . . .
H60 H -0.0025 0.2394 0.9813 0.076 Uiso 1 1 calc R . .
C61 C -0.2061(5) 0.1798(3) 0.9199(3) 0.0488(18) Uani 1 1 d . . .
H61A H -0.2066 0.1330 0.9406 0.059 Uiso 1 1 calc R . .
H61B H -0.2600 0.1944 0.9310 0.059 Uiso 1 1 calc R . .
C62 C -0.1842(5) 0.1882(4) 0.8540(3) 0.0473(17) Uani 1 1 d . . .
H62A H -0.2299 0.1770 0.8413 0.057 Uiso 1 1 calc R . .
H62B H -0.1674 0.2339 0.8323 0.057 Uiso 1 1 calc R . .
C63 C -0.0972(4) 0.1420(3) 0.7845(3) 0.0422(15) Uani 1 1 d . . .
C64 C -0.1198(4) 0.1840(3) 0.7369(3) 0.0363(13) Uani 1 1 d . . .
H64 H -0.1548 0.2173 0.7427 0.044 Uiso 1 1 calc R . .
C65 C -0.0903(4) 0.1766(3) 0.6805(3) 0.0371(13) Uani 1 1 d . . .
H65 H -0.1040 0.2061 0.6476 0.044 Uiso 1 1 calc R . .
C66 C -0.0414(3) 0.1270(3) 0.6719(3) 0.0302(12) Uani 1 1 d . . .
C67 C -0.0186(4) 0.0859(3) 0.7191(3) 0.0401(14) Uani 1 1 d . . .
H67 H 0.0168 0.0530 0.7128 0.048 Uiso 1 1 calc R . .
C68 C -0.0465(5) 0.0917(3) 0.7758(3) 0.0484(17) Uani 1 1 d . . .
H68 H -0.0318 0.0624 0.8084 0.058 Uiso 1 1 calc R . .
C69 C 0.0573(6) 0.2626(4) 0.8332(4) 0.059(2) Uani 1 1 d . . .
C70 C 0.1261(5) 0.2308(4) 0.8147(4) 0.0555(19) Uani 1 1 d . . .
C71 C 0.1971(5) 0.2478(5) 0.8221(4) 0.064(2) Uani 1 1 d . . .
H71 H 0.2004 0.2794 0.8419 0.076 Uiso 1 1 calc R . .
C72 C 0.2645(5) 0.2171(5) 0.7994(4) 0.061(2) Uani 1 1 d . . .
H72 H 0.3141 0.2279 0.8036 0.073 Uiso 1 1 calc R . .
C73 C 0.2571(5) 0.1707(4) 0.7707(3) 0.0502(18) Uani 1 1 d . . .
C74 C 0.1859(5) 0.1541(4) 0.7636(4) 0.057(2) Uani 1 1 d . . .
H74 H 0.1817 0.1222 0.7442 0.068 Uiso 1 1 calc R . .
C75 C 0.1207(6) 0.1856(4) 0.7858(4) 0.066(2) Uani 1 1 d . . .
H75 H 0.0711 0.1755 0.7809 0.080 Uiso 1 1 calc R . .
C76 C 0.3266(5) 0.1427(4) 0.7461(4) 0.059(2) Uani 1 1 d . . .
C77 C 0.6696(5) 0.0203(5) 0.6800(3) 0.065(3) Uani 1 1 d . . .
C78 C 0.7063(6) 0.0657(5) 0.6967(4) 0.083(4) Uani 1 1 d . . .
H78 H 0.6924 0.1098 0.6873 0.100 Uiso 1 1 calc R . .
C79 C 0.7664(7) 0.0446(8) 0.7288(4) 0.100(5) Uani 1 1 d . . .
H79 H 0.7917 0.0750 0.7407 0.120 Uiso 1 1 calc R . .
C80 C 0.7869(9) -0.0186(7) 0.7420(5) 0.108(5) Uani 1 1 d . . .
H80 H 0.8254 -0.0311 0.7638 0.130 Uiso 1 1 calc R . .
C81 C 0.7546(9) -0.0635(7) 0.7252(5) 0.106(4) Uani 1 1 d . . .
H81 H 0.7729 -0.1063 0.7324 0.127 Uiso 1 1 calc R . .
C82 C 0.6930(8) -0.0463(6) 0.6966(5) 0.094(4) Uani 1 1 d . . .
H82 H 0.6665 -0.0788 0.6881 0.113 Uiso 1 1 calc R . .
C83 C 0.5889(5) -0.0140(4) 0.6017(3) 0.0500(18) Uani 1 1 d . . .
C84 C 0.6578(6) -0.0281(4) 0.5661(4) 0.064(2) Uani 1 1 d . . .
H84 H 0.7071 -0.0124 0.5670 0.077 Uiso 1 1 calc R . .
C85 C 0.6526(7) -0.0665(5) 0.5286(4) 0.070(3) Uani 1 1 d . . .
H85 H 0.6990 -0.0766 0.5037 0.084 Uiso 1 1 calc R . .
C86 C 0.5821(6) -0.0891(4) 0.5277(4) 0.064(2) Uani 1 1 d . . .
H86 H 0.5796 -0.1153 0.5026 0.077 Uiso 1 1 calc R . .
C87 C 0.5155(7) -0.0745(5) 0.5623(4) 0.073(3) Uani 1 1 d . . .
H87 H 0.4659 -0.0900 0.5617 0.088 Uiso 1 1 calc R . .
C88 C 0.5210(6) -0.0367(4) 0.5984(4) 0.067(3) Uani 1 1 d . . .
H88 H 0.4740 -0.0262 0.6224 0.081 Uiso 1 1 calc R . .
C89 C 0.5066(9) -0.0778(5) 0.7872(5) 0.111(6) Uani 1 1 d . . .
C90 C 0.5453(14) -0.1118(6) 0.8227(8) 0.200(13) Uani 1 1 d . . .
H90 H 0.5555 -0.0917 0.8504 0.240 Uiso 1 1 calc R . .
C91 C 0.5754(17) -0.1744(7) 0.8274(11) 0.230(17) Uani 1 1 d . . .
H91 H 0.6099 -0.1929 0.8515 0.275 Uiso 1 1 calc R . .
C92 C 0.550(3) -0.2030(14) 0.7951(14) 0.30(3) Uani 1 1 d . . .
H92 H 0.5615 -0.2475 0.8008 0.355 Uiso 1 1 calc R . .
C93 C 0.513(3) -0.1789(12) 0.7573(10) 0.33(3) Uani 1 1 d . . .
H93 H 0.5052 -0.2032 0.7320 0.402 Uiso 1 1 calc R . .
C94 C 0.4786(13) -0.1062(6) 0.7500(6) 0.184(11) Uani 1 1 d . . .
H94 H 0.4455 -0.0867 0.7250 0.220 Uiso 1 1 calc R . .
C95 C 0.3799(8) -0.0023(5) 0.8344(5) 0.096(4) Uani 1 1 d . . .
C96 C 0.3698(8) -0.0032(5) 0.8921(4) 0.104(5) Uani 1 1 d . . .
H96 H 0.4148 0.0034 0.9048 0.124 Uiso 1 1 calc R . .
C97 C 0.2981(9) -0.0133(6) 0.9334(6) 0.118(6) Uani 1 1 d . . .
H97 H 0.2938 -0.0165 0.9738 0.141 Uiso 1 1 calc R . .
C98 C 0.2352(11) -0.0182(7) 0.9129(8) 0.172(10) Uani 1 1 d . . .
H98 H 0.1843 -0.0220 0.9386 0.206 Uiso 1 1 calc R . .
C99 C 0.2440(8) -0.0177(6) 0.8539(6) 0.121(5) Uani 1 1 d . . .
H99 H 0.1991 -0.0224 0.8402 0.145 Uiso 1 1 calc R . .
C100 C 0.3178(9) -0.0105(6) 0.8153(6) 0.117(6) Uani 1 1 d . . .
H100 H 0.3238 -0.0115 0.7756 0.141 Uiso 1 1 calc R . .
C101 C 0.5458(6) 0.0349(4) 0.8149(4) 0.070(3) Uani 1 1 d . . .
H10A H 0.5335 0.0112 0.8576 0.084 Uiso 1 1 calc R . .
H10B H 0.5994 0.0243 0.7968 0.084 Uiso 1 1 calc R . .
C102 C 0.5442(4) 0.1075(3) 0.8084(3) 0.0455(16) Uani 1 1 d . . .
H10C H 0.5913 0.1221 0.8173 0.055 Uiso 1 1 calc R . .
H10D H 0.5433 0.1319 0.7674 0.055 Uiso 1 1 calc R . .
C103 C 0.4557(4) 0.1801(3) 0.8458(3) 0.0434(16) Uani 1 1 d . . .
C104 C 0.4885(4) 0.2339(3) 0.7989(3) 0.0379(14) Uani 1 1 d . . .
H104 H 0.5285 0.2285 0.7666 0.046 Uiso 1 1 calc R . .
C105 C 0.4628(4) 0.2956(3) 0.7996(3) 0.0367(13) Uani 1 1 d . . .
H105 H 0.4865 0.3324 0.7684 0.044 Uiso 1 1 calc R . .
C106 C 0.4029(4) 0.3034(3) 0.8454(3) 0.0352(13) Uani 1 1 d . . .
C107 C 0.3706(4) 0.2487(4) 0.8929(3) 0.0502(18) Uani 1 1 d . . .
H107 H 0.3313 0.2541 0.9256 0.060 Uiso 1 1 calc R . .
C108 C 0.3946(4) 0.1900(3) 0.8923(3) 0.0474(17) Uani 1 1 d . . .
H108 H 0.3703 0.1536 0.9237 0.057 Uiso 1 1 calc R . .
C109 C 0.4223(5) 0.4016(3) 0.8951(3) 0.0461(17) Uani 1 1 d . . .
H10E H 0.3949 0.4349 0.9128 0.055 Uiso 1 1 calc R . .
H10F H 0.4249 0.3625 0.9277 0.055 Uiso 1 1 calc R . .
C110 C 0.5034(5) 0.4265(4) 0.8611(3) 0.0498(17) Uani 1 1 d . . .
H11A H 0.5343 0.3909 0.8496 0.060 Uiso 1 1 calc R . .
H11B H 0.5296 0.4432 0.8860 0.060 Uiso 1 1 calc R . .
C111 C 0.6008(4) 0.5083(4) 0.7550(3) 0.0457(16) Uani 1 1 d . . .
C112 C 0.6409(5) 0.5663(5) 0.7425(5) 0.071(3) Uani 1 1 d . . .
H112 H 0.6149 0.6002 0.7565 0.086 Uiso 1 1 calc R . .
C113 C 0.7177(6) 0.5768(6) 0.7104(5) 0.089(4) Uani 1 1 d . . .
H113 H 0.7436 0.6178 0.7011 0.107 Uiso 1 1 calc R . .
C114 C 0.7563(5) 0.5270(6) 0.6919(4) 0.071(3) Uani 1 1 d . . .
H114 H 0.8092 0.5340 0.6695 0.085 Uiso 1 1 calc R . .
C115 C 0.7199(5) 0.4681(5) 0.7053(4) 0.060(2) Uani 1 1 d . . .
H115 H 0.7478 0.4337 0.6933 0.072 Uiso 1 1 calc R . .
C116 C 0.6419(4) 0.4581(4) 0.7366(4) 0.0512(18) Uani 1 1 d . . .
H116 H 0.6164 0.4170 0.7455 0.061 Uiso 1 1 calc R . .
C117 C 0.4689(5) 0.5608(3) 0.8228(3) 0.0453(16) Uani 1 1 d . . .
C118 C 0.5092(5) 0.5809(4) 0.8586(4) 0.060(2) Uani 1 1 d . . .
H118 H 0.5546 0.5594 0.8670 0.072 Uiso 1 1 calc R . .
C119 C 0.4830(7) 0.6315(5) 0.8813(4) 0.078(3) Uani 1 1 d . . .
H119 H 0.5087 0.6436 0.9070 0.093 Uiso 1 1 calc R . .
C120 C 0.4186(7) 0.6650(4) 0.8665(4) 0.069(3) Uani 1 1 d . . .
H120 H 0.4025 0.7017 0.8801 0.082 Uiso 1 1 calc R . .
C121 C 0.3794(6) 0.6454(4) 0.8333(4) 0.070(3) Uani 1 1 d . . .
H121 H 0.3351 0.6681 0.8241 0.083 Uiso 1 1 calc R . .
C122 C 0.4024(5) 0.5924(4) 0.8120(4) 0.0550(19) Uani 1 1 d . . .
H122 H 0.3724 0.5781 0.7900 0.066 Uiso 1 1 calc R . .
C123 C 0.4749(4) 0.6147(3) 0.6509(3) 0.0428(15) Uani 1 1 d . . .
C124 C 0.5503(6) 0.6407(5) 0.6332(5) 0.083(3) Uani 1 1 d . . .
H124 H 0.5926 0.6136 0.6253 0.099 Uiso 1 1 calc R . .
C125 C 0.5655(9) 0.7034(6) 0.6270(6) 0.114(5) Uani 1 1 d . . .
H125 H 0.6183 0.7189 0.6171 0.137 Uiso 1 1 calc R . .
C126 C 0.5083(8) 0.7444(5) 0.6341(4) 0.081(3) Uani 1 1 d . . .
H126 H 0.5206 0.7892 0.6263 0.097 Uiso 1 1 calc R . .
C127 C 0.4286(8) 0.7212(4) 0.6536(6) 0.096(4) Uani 1 1 d . . .
H127 H 0.3875 0.7499 0.6597 0.115 Uiso 1 1 calc R . .
C128 C 0.4114(6) 0.6530(4) 0.6639(5) 0.076(3) Uani 1 1 d . . .
H128 H 0.3594 0.6351 0.6789 0.092 Uiso 1 1 calc R . .
C129 C 0.3773(4) 0.5339(3) 0.6208(3) 0.0385(14) Uani 1 1 d . . .
C130 C 0.3007(4) 0.5360(3) 0.6510(3) 0.0429(15) Uani 1 1 d . . .
H130 H 0.2892 0.5358 0.6913 0.052 Uiso 1 1 calc R . .
C131 C 0.2393(5) 0.5384(4) 0.6231(4) 0.0515(18) Uani 1 1 d . . .
H131 H 0.1866 0.5403 0.6442 0.062 Uiso 1 1 calc R . .
C132 C 0.2566(5) 0.5379(4) 0.5650(4) 0.055(2) Uani 1 1 d . . .
H132 H 0.2153 0.5372 0.5463 0.067 Uiso 1 1 calc R . .
C133 C 0.3340(5) 0.5384(4) 0.5330(4) 0.0511(18) Uani 1 1 d . . .
H133 H 0.3456 0.5409 0.4921 0.061 Uiso 1 1 calc R . .
C134 C 0.3938(5) 0.5352(3) 0.5613(3) 0.0445(16) Uani 1 1 d . . .
H134 H 0.4465 0.5338 0.5401 0.053 Uiso 1 1 calc R . .
C135 C 0.5437(4) 0.5052(4) 0.6177(3) 0.0457(16) Uani 1 1 d . . .
H13A H 0.5483 0.5279 0.5754 0.055 Uiso 1 1 calc R . .
H13B H 0.5890 0.5196 0.6289 0.055 Uiso 1 1 calc R . .
C136 C 0.5470(5) 0.4326(4) 0.6254(3) 0.0490(17) Uani 1 1 d . . .
H13C H 0.6021 0.4203 0.6147 0.059 Uiso 1 1 calc R . .
H13D H 0.5235 0.4085 0.6671 0.059 Uiso 1 1 calc R . .
C137 C 0.4988(4) 0.3511(4) 0.5915(3) 0.053(2) Uani 1 1 d . . .
C138 C 0.4662(5) 0.3338(5) 0.5509(4) 0.066(2) Uani 1 1 d . . .
H138 H 0.4496 0.3668 0.5217 0.079 Uiso 1 1 calc R . .
C139 C 0.4575(5) 0.2711(5) 0.5521(4) 0.058(2) Uani 1 1 d . . .
H139 H 0.4353 0.2603 0.5239 0.070 Uiso 1 1 calc R . .
C140 C 0.4813(4) 0.2231(4) 0.5949(3) 0.054(2) Uani 1 1 d . . .
C141 C 0.5143(4) 0.2399(4) 0.6346(3) 0.0456(16) Uani 1 1 d . . .
H141 H 0.5316 0.2070 0.6635 0.055 Uiso 1 1 calc R . .
C142 C 0.5229(4) 0.3042(4) 0.6331(3) 0.0445(16) Uani 1 1 d . . .
H142 H 0.5454 0.3153 0.6609 0.053 Uiso 1 1 calc R . .
C143 C 0.3022(4) 0.3821(3) 0.7055(3) 0.0418(15) Uani 1 1 d . . .
C144 C 0.2531(4) 0.3518(3) 0.6811(3) 0.0427(15) Uani 1 1 d . . .
C145 C 0.2821(4) 0.3096(3) 0.6490(3) 0.0443(16) Uani 1 1 d . . .
H145 H 0.3358 0.2997 0.6433 0.053 Uiso 1 1 calc R . .
C146 C 0.2336(5) 0.2810(4) 0.6243(3) 0.0480(17) Uani 1 1 d . . .
H146 H 0.2537 0.2515 0.6021 0.058 Uiso 1 1 calc R . .
C147 C 0.1563(4) 0.2967(3) 0.6331(3) 0.0401(15) Uani 1 1 d . . .
C148 C 0.1245(5) 0.3382(4) 0.6668(4) 0.0499(18) Uani 1 1 d . . .
H148 H 0.0706 0.3474 0.6724 0.060 Uiso 1 1 calc R . .
C149 C 0.1717(5) 0.3661(3) 0.6921(4) 0.0501(18) Uani 1 1 d . . .
H149 H 0.1508 0.3938 0.7159 0.060 Uiso 1 1 calc R . .
C150 C 0.1054(4) 0.2694(3) 0.6057(3) 0.0406(15) Uani 1 1 d . . .
C151 C 0.5713(5) 0.1343(4) 0.5475(4) 0.059(2) Uani 1 1 d . . .
H15A H 0.5681 0.1016 0.5264 0.070 Uiso 1 1 calc R . .
H15B H 0.5875 0.1765 0.5175 0.070 Uiso 1 1 calc R . .
C152 C 0.6324(5) 0.1151(4) 0.5833(3) 0.055(2) Uani 1 1 d . . .
H15C H 0.6432 0.1508 0.5989 0.066 Uiso 1 1 calc R . .
H15D H 0.6819 0.1051 0.5583 0.066 Uiso 1 1 calc R . .
Cl1 Cl 0.22236(15) 0.18927(12) 0.38972(13) 0.0823(8) Uani 1 1 d . . .
Cl2 Cl 0.13124(14) 0.07033(11) 0.45932(12) 0.0702(6) Uani 1 1 d . . .
Cl3 Cl 0.70345(18) 0.1032(2) 0.42060(17) 0.1092(11) Uani 1 1 d . . .
Cl4 Cl 0.6837(4) 0.1009(4) 0.3064(2) 0.219(4) Uani 1 1 d . . .
Cl5 Cl 0.1261(3) 0.9663(2) 0.75228(16) 0.1239(13) Uani 1 1 d . . .
Cl6 Cl 0.0423(3) 0.9225(4) 0.8755(2) 0.199(3) Uani 1 1 d . . .
C153 C 0.7197(11) 0.0640(8) 0.3667(7) 0.142(7) Uani 1 1 d . . .
H15E H 0.6957 0.0197 0.3845 0.170 Uiso 1 1 calc R . .
H15F H 0.7768 0.0599 0.3529 0.170 Uiso 1 1 calc R . .
C154 C 0.1607(5) 0.1474(4) 0.4579(4) 0.064(2) Uani 1 1 d . . .
H15G H 0.1884 0.1434 0.4895 0.076 Uiso 1 1 calc R . .
H15H H 0.1138 0.1728 0.4665 0.076 Uiso 1 1 calc R . .
C155 C 0.0950(16) 0.8972(9) 0.8092(9) 0.188(10) Uani 1 1 d . . .
H15I H 0.1404 0.8714 0.8176 0.226 Uiso 1 1 calc R . .
H15J H 0.0596 0.8704 0.7984 0.226 Uiso 1 1 calc R . .
B1 B 0.1631(7) 0.4655(8) 0.8099(7) 0.084(4) Uani 1 1 d . . .
F1 F 0.1095(4) 0.4806(5) 0.8567(3) 0.121(3) Uani 1 1 d . . .
F2 F 0.2342(3) 0.4928(4) 0.8083(3) 0.099(2) Uani 1 1 d . . .
F3 F 0.1640(4) 0.4013(4) 0.8175(3) 0.105(2) Uani 1 1 d . . .
F4 F 0.1406(3) 0.4959(3) 0.7583(3) 0.0840(17) Uani 1 1 d . . .
B2 B 0.2226(7) 0.1124(6) 0.6117(5) 0.071(3) Uani 1 1 d . . .
F5 F 0.2788(4) 0.0906(5) 0.6413(4) 0.123(3) Uani 1 1 d . . .
F6 F 0.1969(3) 0.0638(2) 0.5920(2) 0.0696(13) Uani 1 1 d . . .
F7 F 0.1614(3) 0.1355(3) 0.6462(3) 0.0801(16) Uani 1 1 d . . .
F8 F 0.2554(4) 0.1648(3) 0.5603(3) 0.095(2) Uani 1 1 d . . .
B3 B 0.7015(5) 0.2788(5) 0.7038(4) 0.052(2) Uani 1 1 d D . .
F9 F 0.6502(4) 0.3267(3) 0.6997(4) 0.109(3) Uani 1 1 d D . .
F10 F 0.6624(3) 0.2234(3) 0.7062(3) 0.095(2) Uani 1 1 d D . .
F11 F 0.7297(4) 0.2751(4) 0.7517(3) 0.105(2) Uani 1 1 d D . .
F12 F 0.7671(3) 0.2865(4) 0.6569(2) 0.099(2) Uani 1 1 d D . .
B4 B 0.1162(11) 0.3574(10) 0.9699(8) 0.231(3) Uani 1 1 d D . .
F13 F 0.0921(6) 0.3395(6) 0.9281(4) 0.231(3) Uani 1 1 d D . .
F14 F 0.1745(6) 0.3190(6) 0.9853(5) 0.231(3) Uani 1 1 d D . .
F15 F 0.0556(6) 0.3489(6) 1.0187(4) 0.231(3) Uani 1 1 d D . .
F16 F 0.1417(7) 0.4191(4) 0.9503(5) 0.231(3) Uani 1 1 d D . .
C156 C 0.3055(9) 0.9524(9) 0.1109(7) 0.0581(16) Uani 0.50 1 d P . .
C157 C 0.3727(9) 0.9194(9) 0.0580(7) 0.0581(16) Uani 0.50 1 d P . .
C158 C 0.4571(9) 0.9205(9) 0.0179(7) 0.0581(16) Uani 0.50 1 d P . .
C159 C 0.5100(5) 0.9839(4) -0.0088(4) 0.0581(16) Uani 1 1 d . . .
C160 C 0.7830(8) 0.3112(8) 0.2519(6) 0.097(2) Uani 1 1 d . . .
C161 C 0.8264(7) 0.3411(8) 0.2220(6) 0.097(2) Uani 1 1 d . . .
C162 C 0.9222(7) 0.3502(7) 0.1590(6) 0.097(2) Uani 1 1 d . . .
C163 C 1.0145(7) 0.3572(7) 0.1141(5) 0.097(2) Uani 1 1 d . . .
C164 C 1.0814(7) 0.4060(7) 0.1087(5) 0.097(2) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Rh1 0.0298(2) 0.0266(2) 0.0274(2) -0.01027(17) -0.00416(17) -0.00323(17)
Rh2 0.0597(4) 0.0347(3) 0.0346(3) -0.0077(2) -0.0130(2) -0.0021(2)
Rh3 0.0331(3) 0.0366(3) 0.0402(3) -0.0207(2) -0.0106(2) 0.00334(19)
Rh4 0.0652(4) 0.0738(4) 0.0531(4) -0.0454(3) 0.0260(3) -0.0362(3)
S1 0.0346(7) 0.0268(7) 0.0307(7) -0.0109(6) -0.0061(6) 0.0014(5)
S2 0.0692(12) 0.0353(9) 0.0381(9) -0.0092(7) -0.0126(8) -0.0093(8)
S3 0.0373(8) 0.0448(9) 0.0431(9) -0.0219(7) -0.0055(7) 0.0047(7)
S4 0.0528(11) 0.0886(15) 0.0519(11) -0.0471(11) 0.0118(9) -0.0229(10)
P1 0.0279(7) 0.0270(7) 0.0282(7) -0.0108(6) -0.0030(6) -0.0018(5)
P2 0.0326(7) 0.0254(7) 0.0244(7) -0.0081(5) -0.0007(5) -0.0036(6)
P3 0.0679(12) 0.0333(9) 0.0317(8) -0.0130(7) -0.0048(8) -0.0037(8)
P4 0.0681(12) 0.0333(9) 0.0304(8) -0.0103(7) -0.0091(8) 0.0014(8)
P5 0.0381(9) 0.0413(9) 0.0420(9) -0.0241(7) -0.0119(7) 0.0035(7)
P6 0.0357(8) 0.0391(8) 0.0358(8) -0.0208(7) -0.0104(6) 0.0056(6)
P7 0.0625(12) 0.0606(12) 0.0478(11) -0.0347(10) 0.0185(9) -0.0296(10)
P8 0.114(2) 0.0505(12) 0.0542(13) -0.0334(10) 0.0456(13) -0.0405(13)
O3 0.057(3) 0.071(4) 0.050(3) -0.032(3) -0.027(3) 0.027(3)
O4 0.064(3) 0.036(2) 0.037(3) -0.012(2) 0.013(2) -0.006(2)
O5 0.085(4) 0.045(3) 0.032(2) -0.017(2) -0.016(2) 0.013(3)
O6 0.043(2) 0.034(2) 0.031(2) -0.0082(18) 0.0034(18) -0.0095(18)
N1 0.036(3) 0.033(3) 0.036(3) -0.012(2) -0.010(2) 0.000(2)
N2 0.048(3) 0.038(3) 0.046(3) -0.022(3) -0.010(3) -0.003(2)
N3 0.059(4) 0.045(3) 0.054(4) -0.011(3) -0.012(3) -0.004(3)
N4 0.057(4) 0.096(6) 0.057(4) -0.049(4) 0.015(3) -0.026(4)
C1 0.046(4) 0.028(3) 0.037(3) -0.007(3) -0.005(3) -0.007(3)
C2 0.029(3) 0.029(3) 0.040(3) -0.011(2) 0.003(2) -0.007(2)
C3 0.032(3) 0.033(3) 0.036(3) -0.013(2) -0.008(2) 0.002(2)
C4 0.037(3) 0.032(3) 0.046(4) -0.016(3) -0.006(3) -0.003(2)
C5 0.050(4) 0.043(4) 0.056(4) -0.028(3) -0.013(3) 0.002(3)
C6 0.076(6) 0.055(5) 0.046(4) -0.030(4) -0.012(4) 0.012(4)
C7 0.067(5) 0.058(5) 0.038(4) -0.021(3) 0.005(3) -0.010(4)
C8 0.047(4) 0.049(4) 0.037(3) -0.016(3) -0.003(3) -0.003(3)
C9 0.028(3) 0.027(3) 0.039(3) -0.007(2) -0.007(2) -0.004(2)
C10 0.040(4) 0.044(4) 0.048(4) -0.014(3) -0.012(3) -0.001(3)
C11 0.046(4) 0.047(4) 0.068(5) -0.008(4) -0.028(4) 0.002(3)
C12 0.045(4) 0.049(4) 0.065(5) -0.013(4) -0.019(4) 0.010(3)
C13 0.035(4) 0.044(4) 0.070(5) -0.026(4) 0.005(3) 0.006(3)
C14 0.037(3) 0.036(3) 0.038(3) -0.009(3) -0.001(3) -0.002(3)
C15 0.050(4) 0.028(3) 0.022(3) -0.006(2) -0.007(2) 0.000(3)
C16 0.045(4) 0.042(4) 0.046(4) -0.017(3) -0.011(3) -0.001(3)
C17 0.069(5) 0.057(5) 0.050(4) -0.017(4) -0.026(4) -0.004(4)
C18 0.094(7) 0.069(5) 0.032(4) -0.007(4) -0.023(4) -0.027(5)
C19 0.055(5) 0.071(5) 0.036(4) -0.013(4) 0.002(3) -0.021(4)
C20 0.039(3) 0.063(4) 0.032(3) -0.020(3) 0.000(3) -0.009(3)
C21 0.035(3) 0.038(3) 0.024(3) -0.011(2) -0.001(2) -0.006(2)
C22 0.037(3) 0.033(3) 0.040(3) -0.011(3) -0.008(3) -0.002(2)
C23 0.062(5) 0.035(3) 0.051(4) -0.014(3) -0.011(3) -0.019(3)
C24 0.042(4) 0.053(4) 0.049(4) -0.020(3) -0.004(3) -0.014(3)
C25 0.044(4) 0.059(5) 0.047(4) -0.016(3) -0.009(3) -0.005(3)
C26 0.036(3) 0.038(3) 0.033(3) -0.012(3) 0.000(2) -0.006(3)
C27 0.039(3) 0.031(3) 0.037(3) -0.009(3) -0.008(3) 0.003(2)
C28 0.033(3) 0.031(3) 0.037(3) -0.012(2) 0.002(2) -0.003(2)
C29 0.038(3) 0.027(3) 0.033(3) -0.011(2) 0.003(2) 0.001(2)
C30 0.032(3) 0.031(3) 0.041(3) -0.013(3) 0.003(3) -0.004(2)
C31 0.032(3) 0.031(3) 0.039(3) -0.006(3) -0.002(3) -0.003(2)
C32 0.040(3) 0.033(3) 0.030(3) -0.009(2) -0.005(2) -0.002(2)
C33 0.043(4) 0.032(3) 0.039(3) -0.011(3) -0.002(3) -0.007(3)
C34 0.043(4) 0.033(3) 0.034(3) -0.003(3) 0.000(3) -0.011(3)
C35 0.093(6) 0.030(3) 0.043(4) -0.009(3) -0.003(4) 0.005(4)
C36 0.082(6) 0.039(4) 0.041(4) -0.013(3) -0.001(4) 0.013(4)
C37 0.062(5) 0.049(4) 0.049(4) -0.024(3) -0.007(4) -0.009(3)
C38 0.063(5) 0.069(5) 0.057(5) -0.032(4) -0.029(4) 0.019(4)
C39 0.076(6) 0.077(6) 0.076(7) -0.036(5) -0.034(5) 0.017(5)
C40 0.079(7) 0.084(7) 0.099(9) -0.026(6) -0.033(6) -0.021(6)
C41 0.132(11) 0.128(10) 0.070(7) -0.035(7) 0.016(7) -0.093(9)
C42 0.121(9) 0.106(8) 0.061(6) -0.040(6) 0.011(6) -0.070(7)
C43 0.107(7) 0.034(4) 0.030(3) -0.013(3) 0.000(4) -0.014(4)
C44 0.103(8) 0.140(11) 0.098(8) -0.098(8) 0.038(7) -0.035(8)
C45 0.130(12) 0.147(13) 0.129(11) -0.113(11) 0.057(10) -0.056(10)
C46 0.169(14) 0.080(8) 0.075(7) -0.048(6) -0.002(8) -0.035(8)
C47 0.31(3) 0.123(12) 0.121(12) -0.092(11) -0.126(15) 0.075(15)
C48 0.227(17) 0.155(13) 0.107(10) -0.099(10) -0.127(12) 0.111(13)
C49 0.096(6) 0.034(4) 0.027(3) -0.006(3) -0.008(4) 0.002(4)
C50 0.161(11) 0.064(6) 0.046(5) -0.028(4) 0.026(6) -0.049(7)
C51 0.213(15) 0.065(6) 0.050(6) -0.022(5) 0.052(7) -0.061(8)
C52 0.160(12) 0.070(6) 0.034(4) -0.017(4) 0.000(6) 0.021(7)
C53 0.109(10) 0.207(17) 0.095(9) -0.110(11) -0.028(8) 0.028(11)
C54 0.080(7) 0.167(12) 0.062(6) -0.073(7) -0.012(5) 0.006(7)
C55 0.100(7) 0.039(4) 0.038(4) -0.006(3) -0.016(4) 0.027(4)
C56 0.127(9) 0.052(5) 0.046(5) -0.007(4) -0.029(5) 0.025(5)
C57 0.138(11) 0.069(7) 0.078(7) 0.002(6) -0.025(8) 0.047(8)
C58 0.119(11) 0.100(9) 0.097(9) -0.022(7) -0.050(8) 0.058(8)
C59 0.101(9) 0.084(8) 0.083(8) -0.015(6) -0.034(7) 0.017(7)
C60 0.065(5) 0.060(5) 0.066(5) -0.011(4) -0.027(4) 0.006(4)
C61 0.074(5) 0.035(3) 0.034(3) -0.014(3) 0.000(3) -0.009(3)
C62 0.062(5) 0.043(4) 0.037(4) -0.017(3) -0.005(3) 0.000(3)
C63 0.051(4) 0.037(3) 0.037(3) -0.013(3) -0.004(3) -0.005(3)
C64 0.038(3) 0.033(3) 0.038(3) -0.012(3) -0.006(3) -0.004(2)
C65 0.046(4) 0.031(3) 0.033(3) -0.008(2) -0.009(3) -0.003(3)
C66 0.029(3) 0.032(3) 0.030(3) -0.012(2) -0.004(2) -0.001(2)
C67 0.056(4) 0.031(3) 0.032(3) -0.008(3) -0.011(3) 0.008(3)
C68 0.062(5) 0.037(4) 0.047(4) -0.008(3) -0.020(3) 0.007(3)
C69 0.066(5) 0.058(5) 0.041(4) 0.001(4) -0.006(4) -0.007(4)
C70 0.054(5) 0.052(4) 0.048(4) -0.002(3) -0.004(3) 0.001(4)
C71 0.069(6) 0.083(6) 0.048(4) -0.030(4) -0.015(4) -0.004(5)
C72 0.053(5) 0.083(6) 0.050(4) -0.030(4) -0.005(4) -0.010(4)
C73 0.057(4) 0.059(5) 0.033(3) -0.018(3) -0.002(3) -0.004(4)
C74 0.066(5) 0.054(5) 0.050(4) -0.012(4) -0.016(4) -0.011(4)
C75 0.076(6) 0.057(5) 0.072(6) -0.014(4) -0.030(5) -0.018(4)
C76 0.053(4) 0.076(5) 0.048(4) -0.034(4) 0.012(4) -0.029(4)
C77 0.071(5) 0.080(6) 0.042(4) -0.032(4) 0.015(4) -0.042(5)
C78 0.094(7) 0.095(7) 0.048(5) -0.035(5) 0.030(5) -0.062(6)
C79 0.099(8) 0.161(12) 0.043(5) -0.045(6) 0.008(5) -0.086(9)
C80 0.148(12) 0.117(10) 0.054(6) 0.004(6) -0.042(7) -0.063(9)
C81 0.137(12) 0.104(9) 0.073(7) 0.003(7) -0.049(8) -0.024(8)
C82 0.137(11) 0.092(8) 0.059(6) -0.020(5) -0.029(6) -0.051(7)
C83 0.062(5) 0.046(4) 0.044(4) -0.030(3) 0.004(3) -0.007(3)
C84 0.070(6) 0.068(5) 0.063(5) -0.037(4) -0.011(4) 0.004(4)
C85 0.100(7) 0.071(6) 0.056(5) -0.044(5) -0.024(5) 0.035(5)
C86 0.094(7) 0.049(5) 0.065(5) -0.035(4) -0.030(5) 0.010(4)
C87 0.093(7) 0.066(6) 0.068(6) -0.038(5) -0.009(5) -0.012(5)
C88 0.069(5) 0.066(5) 0.066(5) -0.037(4) 0.010(4) -0.027(4)
C89 0.177(13) 0.039(5) 0.072(7) -0.025(5) 0.067(8) -0.034(7)
C90 0.33(3) 0.036(6) 0.134(14) -0.009(8) 0.112(17) 0.000(11)
C91 0.33(3) 0.061(9) 0.17(2) -0.014(10) 0.14(2) 0.026(13)
C92 0.43(5) 0.117(19) 0.19(3) -0.06(2) 0.22(4) -0.06(3)
C93 0.63(7) 0.14(2) 0.134(18) -0.118(18) 0.21(3) -0.20(3)
C94 0.33(2) 0.065(7) 0.097(9) -0.056(7) 0.113(13) -0.095(11)
C95 0.116(9) 0.069(6) 0.082(7) -0.048(5) 0.052(6) -0.057(6)
C96 0.150(11) 0.067(6) 0.066(6) -0.042(5) 0.058(6) -0.061(7)
C97 0.139(12) 0.078(7) 0.100(9) -0.051(7) 0.074(9) -0.060(8)
C98 0.172(16) 0.125(12) 0.168(15) -0.103(11) 0.132(14) -0.095(12)
C99 0.121(10) 0.111(10) 0.097(9) -0.040(7) 0.054(8) -0.069(8)
C100 0.134(11) 0.094(8) 0.104(9) -0.059(7) 0.051(8) -0.061(8)
C101 0.101(7) 0.037(4) 0.047(4) -0.008(3) 0.026(4) 0.005(4)
C102 0.055(4) 0.036(3) 0.037(3) -0.012(3) 0.006(3) -0.002(3)
C103 0.050(4) 0.040(4) 0.041(4) -0.018(3) -0.002(3) -0.012(3)
C104 0.038(3) 0.041(3) 0.037(3) -0.017(3) -0.007(3) -0.002(3)
C105 0.036(3) 0.039(3) 0.033(3) -0.010(3) -0.003(2) -0.009(3)
C106 0.034(3) 0.034(3) 0.039(3) -0.016(3) -0.004(3) -0.004(2)
C107 0.049(4) 0.057(4) 0.042(4) -0.024(3) 0.007(3) -0.012(3)
C108 0.058(4) 0.036(3) 0.038(4) -0.010(3) 0.009(3) -0.018(3)
C109 0.065(5) 0.040(4) 0.044(4) -0.024(3) -0.021(3) 0.013(3)
C110 0.064(5) 0.046(4) 0.050(4) -0.021(3) -0.026(4) 0.003(3)
C111 0.039(4) 0.058(4) 0.052(4) -0.034(4) -0.012(3) 0.003(3)
C112 0.050(5) 0.080(6) 0.091(7) -0.056(6) 0.009(4) -0.008(4)
C113 0.060(6) 0.113(9) 0.097(8) -0.061(7) 0.016(5) -0.033(6)
C114 0.035(4) 0.124(9) 0.063(5) -0.050(6) 0.001(4) -0.011(5)
C115 0.045(4) 0.091(6) 0.060(5) -0.041(5) -0.017(4) 0.020(4)
C116 0.034(4) 0.067(5) 0.061(5) -0.027(4) -0.018(3) 0.009(3)
C117 0.060(4) 0.039(4) 0.036(3) -0.019(3) 0.001(3) -0.008(3)
C118 0.066(5) 0.060(5) 0.063(5) -0.035(4) -0.012(4) -0.008(4)
C119 0.112(8) 0.060(5) 0.065(6) -0.038(5) -0.001(5) -0.032(6)
C120 0.105(8) 0.040(4) 0.054(5) -0.025(4) 0.006(5) 0.006(5)
C121 0.082(6) 0.049(5) 0.070(6) -0.019(4) -0.003(5) 0.015(4)
C122 0.072(5) 0.043(4) 0.052(4) -0.019(3) -0.012(4) 0.010(4)
C123 0.055(4) 0.042(4) 0.035(3) -0.011(3) -0.015(3) -0.005(3)
C124 0.066(6) 0.078(6) 0.110(8) -0.063(6) 0.014(5) -0.021(5)
C125 0.126(11) 0.090(9) 0.116(10) -0.060(8) 0.031(8) -0.049(8)
C126 0.131(10) 0.045(5) 0.066(6) -0.007(4) -0.030(6) -0.028(6)
C127 0.138(10) 0.043(5) 0.152(11) -0.044(6) -0.107(10) 0.034(6)
C128 0.082(6) 0.038(4) 0.138(9) -0.036(5) -0.071(7) 0.017(4)
C129 0.040(3) 0.042(3) 0.043(3) -0.022(3) -0.017(3) 0.011(3)
C130 0.045(4) 0.044(4) 0.047(4) -0.020(3) -0.015(3) 0.010(3)
C131 0.043(4) 0.044(4) 0.068(5) -0.015(4) -0.018(4) 0.008(3)
C132 0.062(5) 0.050(4) 0.075(6) -0.029(4) -0.043(4) 0.014(4)
C133 0.064(5) 0.051(4) 0.048(4) -0.022(3) -0.023(4) 0.009(4)
C134 0.054(4) 0.041(4) 0.044(4) -0.019(3) -0.014(3) 0.006(3)
C135 0.043(4) 0.061(4) 0.037(4) -0.021(3) -0.009(3) 0.011(3)
C136 0.052(4) 0.060(4) 0.042(4) -0.024(3) -0.017(3) 0.020(3)
C137 0.034(4) 0.087(6) 0.051(4) -0.039(4) -0.011(3) 0.026(4)
C138 0.049(5) 0.107(8) 0.053(5) -0.035(5) -0.020(4) 0.015(5)
C139 0.053(4) 0.089(6) 0.055(5) -0.049(5) -0.021(4) 0.018(4)
C140 0.041(4) 0.085(6) 0.049(4) -0.044(4) -0.006(3) -0.004(4)
C141 0.042(4) 0.064(5) 0.038(4) -0.028(3) -0.009(3) 0.006(3)
C142 0.039(3) 0.062(4) 0.042(4) -0.030(3) -0.011(3) 0.010(3)
C143 0.042(4) 0.039(3) 0.052(4) -0.020(3) -0.016(3) 0.002(3)
C144 0.048(4) 0.041(4) 0.048(4) -0.014(3) -0.028(3) 0.005(3)
C145 0.045(4) 0.049(4) 0.047(4) -0.020(3) -0.018(3) -0.001(3)
C146 0.055(4) 0.048(4) 0.049(4) -0.023(3) -0.016(3) -0.002(3)
C147 0.055(4) 0.029(3) 0.039(3) -0.008(3) -0.017(3) -0.007(3)
C148 0.050(4) 0.042(4) 0.065(5) -0.014(3) -0.029(4) 0.005(3)
C149 0.062(5) 0.036(4) 0.060(5) -0.017(3) -0.025(4) 0.006(3)
C150 0.056(4) 0.035(3) 0.031(3) -0.004(3) -0.016(3) -0.012(3)
C151 0.058(5) 0.063(5) 0.050(4) -0.033(4) 0.015(4) -0.015(4)
C152 0.058(5) 0.049(4) 0.050(4) -0.025(3) 0.016(4) -0.019(3)
Cl1 0.0675(14) 0.0645(14) 0.0945(18) -0.0146(13) 0.0092(13) -0.0033(11)
Cl2 0.0663(13) 0.0502(11) 0.0926(17) -0.0189(11) -0.0184(12) 0.0002(10)
Cl3 0.0770(18) 0.150(3) 0.118(3) -0.086(2) 0.0004(17) -0.0026(19)
Cl4 0.226(6) 0.326(9) 0.096(3) -0.054(4) -0.044(4) 0.149(6)
Cl5 0.132(3) 0.145(3) 0.089(2) -0.024(2) -0.033(2) 0.053(3)
Cl6 0.138(4) 0.339(9) 0.101(3) -0.047(4) 0.000(3) -0.080(5)
C153 0.206(17) 0.153(13) 0.124(11) -0.096(11) -0.096(12) 0.126(13)
C154 0.066(5) 0.061(5) 0.065(5) -0.029(4) -0.004(4) -0.009(4)
C155 0.26(3) 0.105(13) 0.18(2) -0.016(13) -0.035(19) -0.055(15)
B1 0.062(7) 0.119(11) 0.104(10) -0.070(9) -0.037(7) 0.017(7)
F1 0.099(5) 0.186(8) 0.113(6) -0.107(6) -0.015(4) 0.006(5)
F2 0.061(3) 0.142(6) 0.127(5) -0.086(5) -0.033(4) 0.014(4)
F3 0.118(6) 0.110(5) 0.111(5) -0.065(4) -0.035(4) 0.021(4)
F4 0.066(3) 0.113(5) 0.081(4) -0.041(3) -0.016(3) -0.009(3)
B2 0.067(6) 0.089(8) 0.068(7) -0.047(6) -0.009(5) -0.004(6)
F5 0.083(5) 0.180(8) 0.136(7) -0.061(6) -0.066(5) 0.028(5)
F6 0.074(3) 0.061(3) 0.084(4) -0.037(3) -0.020(3) 0.000(2)
F7 0.080(4) 0.091(4) 0.074(4) -0.048(3) -0.001(3) 0.003(3)
F8 0.115(5) 0.091(4) 0.085(4) -0.055(4) 0.002(4) -0.023(4)
B3 0.041(4) 0.066(6) 0.048(5) -0.017(4) -0.008(4) -0.001(4)
F9 0.121(5) 0.068(4) 0.196(8) -0.069(4) -0.114(6) 0.042(4)
F10 0.063(3) 0.065(3) 0.137(6) -0.034(4) 0.020(3) -0.024(3)
F11 0.108(5) 0.169(7) 0.073(4) -0.074(4) -0.048(4) 0.073(5)
F12 0.078(4) 0.157(6) 0.059(3) -0.053(4) 0.023(3) -0.072(4)
B4 0.221(7) 0.297(9) 0.180(6) -0.105(6) -0.008(5) -0.059(6)
F13 0.221(7) 0.297(9) 0.180(6) -0.105(6) -0.008(5) -0.059(6)
F14 0.221(7) 0.297(9) 0.180(6) -0.105(6) -0.008(5) -0.059(6)
F15 0.221(7) 0.297(9) 0.180(6) -0.105(6) -0.008(5) -0.059(6)
F16 0.221(7) 0.297(9) 0.180(6) -0.105(6) -0.008(5) -0.059(6)
C156 0.049(3) 0.076(5) 0.054(4) -0.023(3) -0.012(3) -0.022(3)
C157 0.049(3) 0.076(5) 0.054(4) -0.023(3) -0.012(3) -0.022(3)
C158 0.049(3) 0.076(5) 0.054(4) -0.023(3) -0.012(3) -0.022(3)
C159 0.049(3) 0.076(5) 0.054(4) -0.023(3) -0.012(3) -0.022(3)
C160 0.081(4) 0.155(6) 0.097(4) -0.085(4) -0.047(3) 0.034(4)
C161 0.081(4) 0.155(6) 0.097(4) -0.085(4) -0.047(3) 0.034(4)
C162 0.081(4) 0.155(6) 0.097(4) -0.085(4) -0.047(3) 0.034(4)
C163 0.081(4) 0.155(6) 0.097(4) -0.085(4) -0.047(3) 0.034(4)
C164 0.081(4) 0.155(6) 0.097(4) -0.085(4) -0.047(3) 0.034(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N1 2.070(5) . ?
Rh1 P1 2.2373(15) . ?
Rh1 P2 2.2750(15) . ?
Rh1 S1 2.3605(15) . ?
Rh2 N3 2.051(7) . ?
Rh2 P3 2.215(2) . ?
Rh2 P4 2.2845(18) . ?
Rh2 S2 2.3578(18) . ?
Rh3 N2 2.065(5) . ?
Rh3 P5 2.2204(17) . ?
Rh3 P6 2.2779(18) . ?
Rh3 S3 2.3572(18) . ?
Rh4 N4 2.053(8) . ?
Rh4 P7 2.222(2) . ?
Rh4 P8 2.280(3) . ?
Rh4 S4 2.359(3) . ?
S1 C66 1.796(6) . ?
S1 C1 1.816(6) . ?
S2 C32 1.785(6) . ?
S2 C35 1.815(9) . ?
S3 C106 1.790(6) . ?
S3 C109 1.841(7) . ?
S4 C140 1.787(9) . ?
S4 C151 1.839(8) . ?
P1 C3 1.826(6) . ?
P1 C9 1.835(6) . ?
P1 C2 1.863(6) . ?
P2 C15 1.822(6) . ?
P2 C21 1.832(6) . ?
P2 C27 1.834(6) . ?
P3 C37 1.820(8) . ?
P3 C36 1.833(8) . ?
P3 C43 1.839(7) . ?
P4 C49 1.839(7) . ?
P4 C61 1.845(8) . ?
P4 C55 1.853(9) . ?
P5 C117 1.816(7) . ?
P5 C111 1.817(7) . ?
P5 C110 1.857(8) . ?
P6 C123 1.833(7) . ?
P6 C135 1.836(7) . ?
P6 C129 1.848(7) . ?
P7 C77 1.786(11) . ?
P7 C152 1.827(8) . ?
P7 C83 1.829(7) . ?
P8 C101 1.810(12) . ?
P8 C89 1.849(12) . ?
P8 C95 1.864(10) . ?
O3 C137 1.403(10) . ?
O3 C136 1.430(9) . ?
O4 C103 1.342(8) . ?
O4 C102 1.434(8) . ?
O5 C63 1.359(8) . ?
O5 C62 1.462(9) . ?
O6 C29 1.362(7) . ?
O6 C28 1.434(7) . ?
N1 C150 1.114(8) . ?
N2 C143 1.135(8) . ?
N3 C69 1.162(11) . ?
N4 C76 1.155(11) . ?
C1 C2 1.515(9) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.382(8) . ?
C3 C8 1.414(9) . ?
C4 C5 1.367(9) . ?
C4 H4 0.9500 . ?
C5 C6 1.375(11) . ?
C5 H5 0.9500 . ?
C6 C7 1.383(11) . ?
C6 H6 0.9500 . ?
C7 C8 1.385(10) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 C10 1.396(9) . ?
C9 C14 1.397(9) . ?
C10 C11 1.383(10) . ?
C10 H10 0.9500 . ?
C11 C12 1.365(12) . ?
C11 H11 0.9500 . ?
C12 C13 1.405(12) . ?
C12 H12 0.9500 . ?
C13 C14 1.371(10) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 C16 1.399(10) . ?
C15 C20 1.408(9) . ?
C16 C17 1.388(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.375(13) . ?
C17 H17 0.9500 . ?
C18 C19 1.399(12) . ?
C18 H18 0.9500 . ?
C19 C20 1.389(10) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C26 1.382(9) . ?
C21 C22 1.387(9) . ?
C22 C23 1.390(9) . ?
C22 H22 0.9500 . ?
C23 C24 1.373(11) . ?
C23 H23 0.9500 . ?
C24 C25 1.351(11) . ?
C24 H24 0.9500 . ?
C25 C26 1.388(9) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 C28 1.517(9) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C34 1.395(9) . ?
C29 C30 1.397(8) . ?
C30 C31 1.390(9) . ?
C30 H30 0.9500 . ?
C31 C32 1.379(9) . ?
C31 H31 0.9500 . ?
C32 C33 1.393(9) . ?
C33 C34 1.370(9) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C35 C36 1.511(13) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 C42 1.372(12) . ?
C37 C38 1.397(11) . ?
C38 C39 1.361(13) . ?
C38 H38 0.9500 . ?
C39 C40 1.310(15) . ?
C39 H39 0.9500 . ?
C40 C41 1.380(15) . ?
C40 H40 0.9500 . ?
C41 C42 1.384(14) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C48 1.356(17) . ?
C43 C44 1.370(16) . ?
C44 C45 1.448(15) . ?
C44 H44 0.9500 . ?
C45 C46 1.28(2) . ?
C45 H45 0.9500 . ?
C46 C47 1.27(2) . ?
C46 H46 0.9500 . ?
C47 C48 1.430(16) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C50 1.354(14) . ?
C49 C54 1.390(13) . ?
C50 C51 1.408(12) . ?
C50 H50 0.9500 . ?
C51 C52 1.374(18) . ?
C51 H51 0.9500 . ?
C52 C53 1.40(2) . ?
C52 H52 0.9500 . ?
C53 C54 1.380(15) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C56 1.368(12) . ?
C55 C60 1.378(13) . ?
C56 C57 1.413(16) . ?
C56 H56 0.9500 . ?
C57 C58 1.44(2) . ?
C57 H57 0.9500 . ?
C58 C59 1.306(17) . ?
C58 H58 0.9500 . ?
C59 C60 1.381(14) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C61 C62 1.511(9) . ?
C61 H61A 0.9900 . ?
C61 H61B 0.9900 . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C63 C64 1.389(9) . ?
C63 C68 1.411(10) . ?
C64 C65 1.394(9) . ?
C64 H64 0.9500 . ?
C65 C66 1.382(9) . ?
C65 H65 0.9500 . ?
C66 C67 1.377(9) . ?
C67 C68 1.384(10) . ?
C67 H67 0.9500 . ?
C68 H68 0.9500 . ?
C69 C70 1.414(13) . ?
C70 C75 1.369(12) . ?
C70 C71 1.382(12) . ?
C71 C72 1.410(13) . ?
C71 H71 0.9500 . ?
C72 C73 1.397(11) . ?
C72 H72 0.9500 . ?
C73 C74 1.380(11) . ?
C73 C76 1.421(12) . ?
C74 C75 1.389(13) . ?
C74 H74 0.9500 . ?
C75 H75 0.9500 . ?
C77 C78 1.391(11) . ?
C77 C82 1.451(16) . ?
C78 C79 1.456(18) . ?
C78 H78 0.9500 . ?
C79 C80 1.36(2) . ?
C79 H79 0.9500 . ?
C80 C81 1.341(17) . ?
C80 H80 0.9500 . ?
C81 C82 1.415(17) . ?
C81 H81 0.9500 . ?
C82 H82 0.9500 . ?
C83 C88 1.336(12) . ?
C83 C84 1.388(11) . ?
C84 C85 1.412(11) . ?
C84 H84 0.9500 . ?
C85 C86 1.357(14) . ?
C85 H85 0.9500 . ?
C86 C87 1.352(13) . ?
C86 H86 0.9500 . ?
C87 C88 1.377(11) . ?
C87 H87 0.9500 . ?
C88 H88 0.9500 . ?
C89 C90 1.28(3) . ?
C89 C94 1.41(2) . ?
C90 C91 1.42(2) . ?
C90 H90 0.9500 . ?
C91 C92 1.28(5) . ?
C91 H91 0.9500 . ?
C92 C93 1.24(8) . ?
C92 H92 0.9500 . ?
C93 C94 1.64(4) . ?
C93 H93 0.9500 . ?
C94 H94 0.9500 . ?
C95 C100 1.33(2) . ?
C95 C96 1.362(15) . ?
C96 C97 1.387(15) . ?
C96 H96 0.9500 . ?
C97 C98 1.34(3) . ?
C97 H97 0.9500 . ?
C98 C99 1.40(2) . ?
C98 H98 0.9500 . ?
C99 C100 1.390(16) . ?
C99 H99 0.9500 . ?
C100 H100 0.9500 . ?
C101 C102 1.526(10) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C102 H10C 0.9900 . ?
C102 H10D 0.9900 . ?
C103 C104 1.395(9) . ?
C103 C108 1.417(9) . ?
C104 C105 1.395(9) . ?
C104 H104 0.9500 . ?
C105 C106 1.377(9) . ?
C105 H105 0.9500 . ?
C106 C107 1.414(10) . ?
C107 C108 1.325(10) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C109 C110 1.495(11) . ?
C109 H10E 0.9900 . ?
C109 H10F 0.9900 . ?
C110 H11A 0.9900 . ?
C110 H11B 0.9900 . ?
C111 C112 1.375(11) . ?
C111 C116 1.401(10) . ?
C112 C113 1.377(12) . ?
C112 H112 0.9500 . ?
C113 C114 1.375(15) . ?
C113 H113 0.9500 . ?
C114 C115 1.358(14) . ?
C114 H114 0.9500 . ?
C115 C116 1.389(11) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C117 C122 1.383(11) . ?
C117 C118 1.407(11) . ?
C118 C119 1.376(12) . ?
C118 H118 0.9500 . ?
C119 C120 1.393(15) . ?
C119 H119 0.9500 . ?
C120 C121 1.340(14) . ?
C120 H120 0.9500 . ?
C121 C122 1.391(11) . ?
C121 H121 0.9500 . ?
C122 H122 0.9500 . ?
C123 C124 1.377(12) . ?
C123 C128 1.397(12) . ?
C124 C125 1.344(14) . ?
C124 H124 0.9500 . ?
C125 C126 1.332(18) . ?
C125 H125 0.9500 . ?
C126 C127 1.427(17) . ?
C126 H126 0.9500 . ?
C127 C128 1.446(12) . ?
C127 H127 0.9500 . ?
C128 H128 0.9500 . ?
C129 C130 1.376(10) . ?
C129 C134 1.395(9) . ?
C130 C131 1.404(10) . ?
C130 H130 0.9500 . ?
C131 C132 1.374(12) . ?
C131 H131 0.9500 . ?
C132 C133 1.394(12) . ?
C132 H132 0.9500 . ?
C133 C134 1.385(10) . ?
C133 H133 0.9500 . ?
C134 H134 0.9500 . ?
C135 C136 1.522(11) . ?
C135 H13A 0.9900 . ?
C135 H13B 0.9900 . ?
C136 H13C 0.9900 . ?
C136 H13D 0.9900 . ?
C137 C142 1.352(11) . ?
C137 C138 1.393(11) . ?
C138 C139 1.355(13) . ?
C138 H138 0.9500 . ?
C139 C140 1.382(12) . ?
C139 H139 0.9500 . ?
C140 C141 1.373(10) . ?
C141 C142 1.387(10) . ?
C141 H141 0.9500 . ?
C142 H142 0.9500 . ?
C143 C144 1.426(9) . ?
C144 C145 1.369(10) . ?
C144 C149 1.434(11) . ?
C145 C146 1.402(10) . ?
C145 H145 0.9500 . ?
C146 C147 1.375(11) . ?
C146 H146 0.9500 . ?
C147 C148 1.393(10) . ?
C147 C150 1.464(9) . ?
C148 C149 1.387(10) . ?
C148 H148 0.9500 . ?
C149 H149 0.9500 . ?
C151 C152 1.524(13) . ?
C151 H15A 0.9900 . ?
C151 H15B 0.9900 . ?
C152 H15C 0.9900 . ?
C152 H15D 0.9900 . ?
Cl1 C154 1.753(9) . ?
Cl2 C154 1.744(9) . ?
Cl3 C153 1.713(12) . ?
Cl4 C153 1.718(13) . ?
Cl5 C155 1.715(18) . ?
Cl6 C155 1.87(2) . ?
C153 H15E 0.9900 . ?
C153 H15F 0.9900 . ?
C154 H15G 0.9900 . ?
C154 H15H 0.9900 . ?
C155 H15I 0.9900 . ?
C155 H15J 0.9900 . ?
B1 F3 1.342(16) . ?
B1 F4 1.387(15) . ?
B1 F2 1.389(14) . ?
B1 F1 1.398(14) . ?
B2 F5 1.361(14) . ?
B2 F7 1.367(12) . ?
B2 F6 1.397(11) . ?
B2 F8 1.435(14) . ?
B3 F9 1.348(10) . ?
B3 F11 1.357(10) . ?
B3 F10 1.377(10) . ?
B3 F12 1.386(10) . ?
B4 F16 1.330(18) . ?
B4 F13 1.344(18) . ?
B4 F14 1.357(19) . ?
B4 F15 1.359(18) . ?
C156 C157 1.81(2) . ?
C157 C158 1.56(2) . ?
C158 C159 1.562(18) . ?
C159 C159 0.931(16) 2_675 ?
C160 C161 1.012(19) . ?
C161 C162 1.953(19) . ?
C162 C163 1.707(17) . ?
C163 C164 1.561(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Rh1 P1 168.85(15) . . ?
N1 Rh1 P2 89.00(15) . . ?
P1 Rh1 P2 99.01(6) . . ?
N1 Rh1 S1 85.69(15) . . ?
P1 Rh1 S1 86.56(5) . . ?
P2 Rh1 S1 174.25(6) . . ?
N3 Rh2 P3 172.65(19) . . ?
N3 Rh2 P4 89.13(19) . . ?
P3 Rh2 P4 96.30(7) . . ?
N3 Rh2 S2 88.56(19) . . ?
P3 Rh2 S2 85.99(7) . . ?
P4 Rh2 S2 177.68(8) . . ?
N2 Rh3 P5 170.91(17) . . ?
N2 Rh3 P6 90.57(17) . . ?
P5 Rh3 P6 96.57(7) . . ?
N2 Rh3 S3 86.57(17) . . ?
P5 Rh3 S3 86.62(7) . . ?
P6 Rh3 S3 175.58(6) . . ?
N4 Rh4 P7 170.7(2) . . ?
N4 Rh4 P8 90.8(2) . . ?
P7 Rh4 P8 95.48(10) . . ?
N4 Rh4 S4 89.0(2) . . ?
P7 Rh4 S4 85.06(9) . . ?
P8 Rh4 S4 177.38(8) . . ?
C66 S1 C1 102.5(3) . . ?
C66 S1 Rh1 105.1(2) . . ?
C1 S1 Rh1 105.5(2) . . ?
C32 S2 C35 100.1(4) . . ?
C32 S2 Rh2 106.1(2) . . ?
C35 S2 Rh2 104.9(3) . . ?
C106 S3 C109 100.0(3) . . ?
C106 S3 Rh3 108.8(2) . . ?
C109 S3 Rh3 104.9(3) . . ?
C140 S4 C151 99.5(4) . . ?
C140 S4 Rh4 108.4(3) . . ?
C151 S4 Rh4 105.0(3) . . ?
C3 P1 C9 104.8(3) . . ?
C3 P1 C2 104.0(3) . . ?
C9 P1 C2 100.3(3) . . ?
C3 P1 Rh1 120.1(2) . . ?
C9 P1 Rh1 120.54(19) . . ?
C2 P1 Rh1 104.0(2) . . ?
C15 P2 C21 101.5(3) . . ?
C15 P2 C27 102.1(3) . . ?
C21 P2 C27 106.4(3) . . ?
C15 P2 Rh1 122.1(2) . . ?
C21 P2 Rh1 111.4(2) . . ?
C27 P2 Rh1 111.9(2) . . ?
C37 P3 C36 102.9(4) . . ?
C37 P3 C43 106.2(4) . . ?
C36 P3 C43 101.1(4) . . ?
C37 P3 Rh2 120.2(3) . . ?
C36 P3 Rh2 106.3(3) . . ?
C43 P3 Rh2 117.5(3) . . ?
C49 P4 C61 102.3(4) . . ?
C49 P4 C55 101.9(4) . . ?
C61 P4 C55 107.6(4) . . ?
C49 P4 Rh2 119.6(2) . . ?
C61 P4 Rh2 112.4(2) . . ?
C55 P4 Rh2 111.9(3) . . ?
C117 P5 C111 105.9(3) . . ?
C117 P5 C110 103.0(3) . . ?
C111 P5 C110 102.0(4) . . ?
C117 P5 Rh3 117.4(3) . . ?
C111 P5 Rh3 120.0(2) . . ?
C110 P5 Rh3 106.1(2) . . ?
C123 P6 C135 101.7(4) . . ?
C123 P6 C129 100.9(3) . . ?
C135 P6 C129 107.4(3) . . ?
C123 P6 Rh3 123.3(2) . . ?
C135 P6 Rh3 111.2(2) . . ?
C129 P6 Rh3 110.8(2) . . ?
C77 P7 C152 103.9(4) . . ?
C77 P7 C83 106.4(4) . . ?
C152 P7 C83 99.4(3) . . ?
C77 P7 Rh4 121.9(3) . . ?
C152 P7 Rh4 104.5(3) . . ?
C83 P7 Rh4 117.4(3) . . ?
C101 P8 C89 102.0(6) . . ?
C101 P8 C95 106.7(5) . . ?
C89 P8 C95 103.7(5) . . ?
C101 P8 Rh4 112.3(3) . . ?
C89 P8 Rh4 118.5(4) . . ?
C95 P8 Rh4 112.6(5) . . ?
C137 O3 C136 115.4(6) . . ?
C103 O4 C102 117.9(5) . . ?
C63 O5 C62 116.9(5) . . ?
C29 O6 C28 116.2(5) . . ?
C150 N1 Rh1 177.7(6) . . ?
C143 N2 Rh3 178.2(6) . . ?
C69 N3 Rh2 174.6(7) . . ?
C76 N4 Rh4 178.2(7) . . ?
C2 C1 S1 111.8(4) . . ?
C2 C1 H1A 109.3 . . ?
S1 C1 H1A 109.3 . . ?
C2 C1 H1B 109.3 . . ?
S1 C1 H1B 109.3 . . ?
H1A C1 H1B 107.9 . . ?
C1 C2 P1 109.0(4) . . ?
C1 C2 H2A 109.9 . . ?
P1 C2 H2A 109.9 . . ?
C1 C2 H2B 109.9 . . ?
P1 C2 H2B 109.9 . . ?
H2A C2 H2B 108.3 . . ?
C4 C3 C8 118.6(6) . . ?
C4 C3 P1 123.8(5) . . ?
C8 C3 P1 117.5(5) . . ?
C5 C4 C3 121.6(6) . . ?
C5 C4 H4 119.2 . . ?
C3 C4 H4 119.2 . . ?
C4 C5 C6 119.7(7) . . ?
C4 C5 H5 120.1 . . ?
C6 C5 H5 120.1 . . ?
C5 C6 C7 120.5(7) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
C6 C7 C8 120.2(7) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 H7 119.9 . . ?
C7 C8 C3 119.3(7) . . ?
C7 C8 H8 120.3 . . ?
C3 C8 H8 120.3 . . ?
C10 C9 C14 119.9(6) . . ?
C10 C9 P1 122.4(5) . . ?
C14 C9 P1 117.7(5) . . ?
C11 C10 C9 119.3(7) . . ?
C11 C10 H10 120.3 . . ?
C9 C10 H10 120.3 . . ?
C12 C11 C10 120.6(8) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
C11 C12 C13 120.7(7) . . ?
C11 C12 H12 119.6 . . ?
C13 C12 H12 119.6 . . ?
C14 C13 C12 119.2(7) . . ?
C14 C13 H13 120.4 . . ?
C12 C13 H13 120.4 . . ?
C13 C14 C9 120.3(7) . . ?
C13 C14 H14 119.8 . . ?
C9 C14 H14 119.8 . . ?
C16 C15 C20 117.5(6) . . ?
C16 C15 P2 122.8(5) . . ?
C20 C15 P2 119.7(5) . . ?
C17 C16 C15 122.3(7) . . ?
C17 C16 H16 118.8 . . ?
C15 C16 H16 118.8 . . ?
C18 C17 C16 118.7(8) . . ?
C18 C17 H17 120.7 . . ?
C16 C17 H17 120.7 . . ?
C17 C18 C19 121.3(7) . . ?
C17 C18 H18 119.3 . . ?
C19 C18 H18 119.3 . . ?
C20 C19 C18 119.2(7) . . ?
C20 C19 H19 120.4 . . ?
C18 C19 H19 120.4 . . ?
C19 C20 C15 120.9(7) . . ?
C19 C20 H20 119.5 . . ?
C15 C20 H20 119.5 . . ?
C26 C21 C22 117.7(6) . . ?
C26 C21 P2 118.7(5) . . ?
C22 C21 P2 123.7(5) . . ?
C21 C22 C23 120.4(6) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C24 C23 C22 120.6(6) . . ?
C24 C23 H23 119.7 . . ?
C22 C23 H23 119.7 . . ?
C25 C24 C23 119.4(7) . . ?
C25 C24 H24 120.3 . . ?
C23 C24 H24 120.3 . . ?
C24 C25 C26 120.7(7) . . ?
C24 C25 H25 119.7 . . ?
C26 C25 H25 119.7 . . ?
C21 C26 C25 121.1(6) . . ?
C21 C26 H26 119.4 . . ?
C25 C26 H26 119.4 . . ?
C28 C27 P2 116.1(5) . . ?
C28 C27 H27A 108.3 . . ?
P2 C27 H27A 108.3 . . ?
C28 C27 H27B 108.3 . . ?
P2 C27 H27B 108.3 . . ?
H27A C27 H27B 107.4 . . ?
O6 C28 C27 108.4(5) . . ?
O6 C28 H28A 110.0 . . ?
C27 C28 H28A 110.0 . . ?
O6 C28 H28B 110.0 . . ?
C27 C28 H28B 110.0 . . ?
H28A C28 H28B 108.4 . . ?
O6 C29 C34 116.8(5) . . ?
O6 C29 C30 124.1(6) . . ?
C34 C29 C30 119.1(6) . . ?
C31 C30 C29 119.0(6) . . ?
C31 C30 H30 120.5 . . ?
C29 C30 H30 120.5 . . ?
C32 C31 C30 121.4(6) . . ?
C32 C31 H31 119.3 . . ?
C30 C31 H31 119.3 . . ?
C31 C32 C33 119.1(6) . . ?
C31 C32 S2 122.4(5) . . ?
C33 C32 S2 118.5(5) . . ?
C34 C33 C32 120.1(6) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C33 C34 C29 121.1(6) . . ?
C33 C34 H34 119.4 . . ?
C29 C34 H34 119.4 . . ?
C36 C35 S2 112.2(5) . . ?
C36 C35 H35A 109.2 . . ?
S2 C35 H35A 109.2 . . ?
C36 C35 H35B 109.2 . . ?
S2 C35 H35B 109.2 . . ?
H35A C35 H35B 107.9 . . ?
C35 C36 P3 107.8(6) . . ?
C35 C36 H36A 110.1 . . ?
P3 C36 H36A 110.1 . . ?
C35 C36 H36B 110.1 . . ?
P3 C36 H36B 110.1 . . ?
H36A C36 H36B 108.5 . . ?
C42 C37 C38 117.3(8) . . ?
C42 C37 P3 123.4(7) . . ?
C38 C37 P3 119.1(6) . . ?
C39 C38 C37 120.0(9) . . ?
C39 C38 H38 120.0 . . ?
C37 C38 H38 120.0 . . ?
C40 C39 C38 122.1(9) . . ?
C40 C39 H39 119.0 . . ?
C38 C39 H39 119.0 . . ?
C39 C40 C41 120.5(10) . . ?
C39 C40 H40 119.8 . . ?
C41 C40 H40 119.8 . . ?
C40 C41 C42 118.6(10) . . ?
C40 C41 H41 120.7 . . ?
C42 C41 H41 120.7 . . ?
C37 C42 C41 121.3(9) . . ?
C37 C42 H42 119.3 . . ?
C41 C42 H42 119.3 . . ?
C48 C43 C44 120.7(9) . . ?
C48 C43 P3 118.9(8) . . ?
C44 C43 P3 119.9(8) . . ?
C43 C44 C45 115.4(14) . . ?
C43 C44 H44 122.3 . . ?
C45 C44 H44 122.3 . . ?
C46 C45 C44 125.2(15) . . ?
C46 C45 H45 117.4 . . ?
C44 C45 H45 117.4 . . ?
C47 C46 C45 116.0(12) . . ?
C47 C46 H46 122.0 . . ?
C45 C46 H46 122.0 . . ?
C46 C47 C48 127.1(18) . . ?
C46 C47 H47 116.5 . . ?
C48 C47 H47 116.5 . . ?
C43 C48 C47 115.3(15) . . ?
C43 C48 H48 122.3 . . ?
C47 C48 H48 122.3 . . ?
C50 C49 C54 119.2(8) . . ?
C50 C49 P4 123.9(7) . . ?
C54 C49 P4 116.7(7) . . ?
C49 C50 C51 121.3(10) . . ?
C49 C50 H50 119.3 . . ?
C51 C50 H50 119.3 . . ?
C52 C51 C50 118.9(12) . . ?
C52 C51 H51 120.5 . . ?
C50 C51 H51 120.5 . . ?
C51 C52 C53 119.9(9) . . ?
C51 C52 H52 120.1 . . ?
C53 C52 H52 120.1 . . ?
C54 C53 C52 119.4(12) . . ?
C54 C53 H53 120.3 . . ?
C52 C53 H53 120.3 . . ?
C53 C54 C49 120.7(12) . . ?
C53 C54 H54 119.7 . . ?
C49 C54 H54 119.7 . . ?
C56 C55 C60 120.2(9) . . ?
C56 C55 P4 122.4(8) . . ?
C60 C55 P4 117.2(6) . . ?
C55 C56 C57 120.9(12) . . ?
C55 C56 H56 119.6 . . ?
C57 C56 H56 119.6 . . ?
C56 C57 C58 116.9(11) . . ?
C56 C57 H57 121.6 . . ?
C58 C57 H57 121.6 . . ?
C59 C58 C57 119.6(12) . . ?
C59 C58 H58 120.2 . . ?
C57 C58 H58 120.2 . . ?
C58 C59 C60 123.6(13) . . ?
C58 C59 H59 118.2 . . ?
C60 C59 H59 118.2 . . ?
C55 C60 C59 118.6(10) . . ?
C55 C60 H60 120.7 . . ?
C59 C60 H60 120.7 . . ?
C62 C61 P4 115.8(5) . . ?
C62 C61 H61A 108.3 . . ?
P4 C61 H61A 108.3 . . ?
C62 C61 H61B 108.3 . . ?
P4 C61 H61B 108.3 . . ?
H61A C61 H61B 107.4 . . ?
O5 C62 C61 108.2(6) . . ?
O5 C62 H62A 110.1 . . ?
C61 C62 H62A 110.1 . . ?
O5 C62 H62B 110.1 . . ?
C61 C62 H62B 110.1 . . ?
H62A C62 H62B 108.4 . . ?
O5 C63 C64 124.2(6) . . ?
O5 C63 C68 115.4(6) . . ?
C64 C63 C68 120.3(6) . . ?
C63 C64 C65 118.9(6) . . ?
C63 C64 H64 120.6 . . ?
C65 C64 H64 120.6 . . ?
C66 C65 C64 121.0(6) . . ?
C66 C65 H65 119.5 . . ?
C64 C65 H65 119.5 . . ?
C67 C66 C65 119.7(6) . . ?
C67 C66 S1 117.9(5) . . ?
C65 C66 S1 122.1(5) . . ?
C66 C67 C68 121.0(6) . . ?
C66 C67 H67 119.5 . . ?
C68 C67 H67 119.5 . . ?
C67 C68 C63 119.0(6) . . ?
C67 C68 H68 120.5 . . ?
C63 C68 H68 120.5 . . ?
N3 C69 C70 178.4(9) . . ?
C75 C70 C71 121.4(8) . . ?
C75 C70 C69 117.4(8) . . ?
C71 C70 C69 121.1(8) . . ?
C70 C71 C72 118.4(8) . . ?
C70 C71 H71 120.8 . . ?
C72 C71 H71 120.8 . . ?
C73 C72 C71 119.1(8) . . ?
C73 C72 H72 120.5 . . ?
C71 C72 H72 120.5 . . ?
C74 C73 C72 122.0(8) . . ?
C74 C73 C76 120.3(7) . . ?
C72 C73 C76 117.6(7) . . ?
C73 C74 C75 117.7(8) . . ?
C73 C74 H74 121.1 . . ?
C75 C74 H74 121.1 . . ?
C70 C75 C74 121.5(8) . . ?
C70 C75 H75 119.3 . . ?
C74 C75 H75 119.3 . . ?
N4 C76 C73 176.1(8) . . ?
C78 C77 C82 117.7(10) . . ?
C78 C77 P7 120.0(9) . . ?
C82 C77 P7 122.2(7) . . ?
C77 C78 C79 118.7(11) . . ?
C77 C78 H78 120.7 . . ?
C79 C78 H78 120.7 . . ?
C80 C79 C78 120.7(9) . . ?
C80 C79 H79 119.6 . . ?
C78 C79 H79 119.6 . . ?
C81 C80 C79 122.4(13) . . ?
C81 C80 H80 118.8 . . ?
C79 C80 H80 118.8 . . ?
C80 C81 C82 119.1(14) . . ?
C80 C81 H81 120.4 . . ?
C82 C81 H81 120.4 . . ?
C81 C82 C77 121.1(10) . . ?
C81 C82 H82 119.4 . . ?
C77 C82 H82 119.4 . . ?
C88 C83 C84 118.6(7) . . ?
C88 C83 P7 121.4(6) . . ?
C84 C83 P7 119.5(6) . . ?
C83 C84 C85 118.2(9) . . ?
C83 C84 H84 120.9 . . ?
C85 C84 H84 120.9 . . ?
C86 C85 C84 120.7(9) . . ?
C86 C85 H85 119.6 . . ?
C84 C85 H85 119.6 . . ?
C87 C86 C85 120.4(8) . . ?
C87 C86 H86 119.8 . . ?
C85 C86 H86 119.8 . . ?
C86 C87 C88 118.4(10) . . ?
C86 C87 H87 120.8 . . ?
C88 C87 H87 120.8 . . ?
C83 C88 C87 123.6(9) . . ?
C83 C88 H88 118.2 . . ?
C87 C88 H88 118.2 . . ?
C90 C89 C94 119.5(14) . . ?
C90 C89 P8 126.4(12) . . ?
C94 C89 P8 114.1(14) . . ?
C89 C90 C91 131(2) . . ?
C89 C90 H90 114.6 . . ?
C91 C90 H90 114.6 . . ?
C92 C91 C90 112(4) . . ?
C92 C91 H91 124.0 . . ?
C90 C91 H91 124.0 . . ?
C93 C92 C91 127(3) . . ?
C93 C92 H92 116.4 . . ?
C91 C92 H92 116.4 . . ?
C92 C93 C94 122(2) . . ?
C92 C93 H93 119.2 . . ?
C94 C93 H93 119.2 . . ?
C89 C94 C93 108(2) . . ?
C89 C94 H94 126.0 . . ?
C93 C94 H94 126.0 . . ?
C100 C95 C96 119.0(11) . . ?
C100 C95 P8 117.9(9) . . ?
C96 C95 P8 123.0(12) . . ?
C95 C96 C97 124.4(15) . . ?
C95 C96 H96 117.8 . . ?
C97 C96 H96 117.8 . . ?
C98 C97 C96 116.2(14) . . ?
C98 C97 H97 121.9 . . ?
C96 C97 H97 121.9 . . ?
C97 C98 C99 120.5(12) . . ?
C97 C98 H98 119.8 . . ?
C99 C98 H98 119.8 . . ?
C100 C99 C98 120.6(16) . . ?
C100 C99 H99 119.7 . . ?
C98 C99 H99 119.7 . . ?
C95 C100 C99 119.2(13) . . ?
C95 C100 H100 120.4 . . ?
C99 C100 H100 120.4 . . ?
C102 C101 P8 114.1(7) . . ?
C102 C101 H10A 108.7 . . ?
P8 C101 H10A 108.7 . . ?
C102 C101 H10B 108.7 . . ?
P8 C101 H10B 108.7 . . ?
H10A C101 H10B 107.6 . . ?
O4 C102 C101 107.5(6) . . ?
O4 C102 H10C 110.2 . . ?
C101 C102 H10C 110.2 . . ?
O4 C102 H10D 110.2 . . ?
C101 C102 H10D 110.2 . . ?
H10C C102 H10D 108.5 . . ?
O4 C103 C104 125.2(6) . . ?
O4 C103 C108 116.5(6) . . ?
C104 C103 C108 118.2(6) . . ?
C105 C104 C103 120.0(6) . . ?
C105 C104 H104 120.0 . . ?
C103 C104 H104 120.0 . . ?
C106 C105 C104 120.1(6) . . ?
C106 C105 H105 119.9 . . ?
C104 C105 H105 119.9 . . ?
C105 C106 C107 119.4(6) . . ?
C105 C106 S3 121.5(5) . . ?
C107 C106 S3 119.1(5) . . ?
C108 C107 C106 120.6(6) . . ?
C108 C107 H107 119.7 . . ?
C106 C107 H107 119.7 . . ?
C107 C108 C103 121.5(6) . . ?
C107 C108 H108 119.2 . . ?
C103 C108 H108 119.2 . . ?
C110 C109 S3 111.1(5) . . ?
C110 C109 H10E 109.4 . . ?
S3 C109 H10E 109.4 . . ?
C110 C109 H10F 109.4 . . ?
S3 C109 H10F 109.4 . . ?
H10E C109 H10F 108.0 . . ?
C109 C110 P5 109.0(5) . . ?
C109 C110 H11A 109.9 . . ?
P5 C110 H11A 109.9 . . ?
C109 C110 H11B 109.9 . . ?
P5 C110 H11B 109.9 . . ?
H11A C110 H11B 108.3 . . ?
C112 C111 C116 117.6(7) . . ?
C112 C111 P5 124.5(6) . . ?
C116 C111 P5 117.9(6) . . ?
C111 C112 C113 122.1(9) . . ?
C111 C112 H112 119.0 . . ?
C113 C112 H112 119.0 . . ?
C114 C113 C112 119.0(10) . . ?
C114 C113 H113 120.5 . . ?
C112 C113 H113 120.5 . . ?
C115 C114 C113 120.9(8) . . ?
C115 C114 H114 119.6 . . ?
C113 C114 H114 119.6 . . ?
C114 C115 C116 119.9(8) . . ?
C114 C115 H115 120.0 . . ?
C116 C115 H115 120.0 . . ?
C115 C116 C111 120.4(8) . . ?
C115 C116 H116 119.8 . . ?
C111 C116 H116 119.8 . . ?
C122 C117 C118 118.6(7) . . ?
C122 C117 P5 119.0(6) . . ?
C118 C117 P5 122.3(6) . . ?
C119 C118 C117 120.2(9) . . ?
C119 C118 H118 119.9 . . ?
C117 C118 H118 119.9 . . ?
C118 C119 C120 119.8(9) . . ?
C118 C119 H119 120.1 . . ?
C120 C119 H119 120.1 . . ?
C121 C120 C119 120.1(8) . . ?
C121 C120 H120 119.9 . . ?
C119 C120 H120 119.9 . . ?
C120 C121 C122 121.3(9) . . ?
C120 C121 H121 119.3 . . ?
C122 C121 H121 119.3 . . ?
C117 C122 C121 119.8(8) . . ?
C117 C122 H122 120.1 . . ?
C121 C122 H122 120.1 . . ?
C124 C123 C128 120.6(8) . . ?
C124 C123 P6 122.2(7) . . ?
C128 C123 P6 117.1(6) . . ?
C125 C124 C123 121.7(11) . . ?
C125 C124 H124 119.2 . . ?
C123 C124 H124 119.2 . . ?
C126 C125 C124 121.7(12) . . ?
C126 C125 H125 119.2 . . ?
C124 C125 H125 119.2 . . ?
C125 C126 C127 120.0(9) . . ?
C125 C126 H126 120.0 . . ?
C127 C126 H126 120.0 . . ?
C126 C127 C128 118.8(10) . . ?
C126 C127 H127 120.6 . . ?
C128 C127 H127 120.6 . . ?
C123 C128 C127 116.9(10) . . ?
C123 C128 H128 121.5 . . ?
C127 C128 H128 121.5 . . ?
C130 C129 C134 119.0(6) . . ?
C130 C129 P6 117.7(5) . . ?
C134 C129 P6 123.3(5) . . ?
C129 C130 C131 121.1(7) . . ?
C129 C130 H130 119.4 . . ?
C131 C130 H130 119.4 . . ?
C132 C131 C130 118.9(7) . . ?
C132 C131 H131 120.5 . . ?
C130 C131 H131 120.5 . . ?
C131 C132 C133 120.7(7) . . ?
C131 C132 H132 119.6 . . ?
C133 C132 H132 119.6 . . ?
C134 C133 C132 119.5(7) . . ?
C134 C133 H133 120.2 . . ?
C132 C133 H133 120.2 . . ?
C133 C134 C129 120.5(7) . . ?
C133 C134 H134 119.7 . . ?
C129 C134 H134 119.7 . . ?
C136 C135 P6 113.4(5) . . ?
C136 C135 H13A 108.9 . . ?
P6 C135 H13A 108.9 . . ?
C136 C135 H13B 108.9 . . ?
P6 C135 H13B 108.9 . . ?
H13A C135 H13B 107.7 . . ?
O3 C136 C135 108.3(6) . . ?
O3 C136 H13C 110.0 . . ?
C135 C136 H13C 110.0 . . ?
O3 C136 H13D 110.0 . . ?
C135 C136 H13D 110.0 . . ?
H13C C136 H13D 108.4 . . ?
C142 C137 C138 119.3(9) . . ?
C142 C137 O3 122.7(7) . . ?
C138 C137 O3 118.0(8) . . ?
C139 C138 C137 121.8(9) . . ?
C139 C138 H138 119.1 . . ?
C137 C138 H138 119.1 . . ?
C138 C139 C140 118.9(7) . . ?
C138 C139 H139 120.5 . . ?
C140 C139 H139 120.5 . . ?
C141 C140 C139 119.5(8) . . ?
C141 C140 S4 120.6(7) . . ?
C139 C140 S4 119.8(6) . . ?
C140 C141 C142 121.1(8) . . ?
C140 C141 H141 119.5 . . ?
C142 C141 H141 119.5 . . ?
C137 C142 C141 119.3(7) . . ?
C137 C142 H142 120.3 . . ?
C141 C142 H142 120.3 . . ?
N2 C143 C144 177.6(8) . . ?
C145 C144 C143 121.3(7) . . ?
C145 C144 C149 120.7(6) . . ?
C143 C144 C149 118.0(6) . . ?
C144 C145 C146 120.9(7) . . ?
C144 C145 H145 119.5 . . ?
C146 C145 H145 119.5 . . ?
C147 C146 C145 118.1(7) . . ?
C147 C146 H146 121.0 . . ?
C145 C146 H146 121.0 . . ?
C146 C147 C148 122.4(6) . . ?
C146 C147 C150 119.0(6) . . ?
C148 C147 C150 118.5(7) . . ?
C149 C148 C147 119.9(7) . . ?
C149 C148 H148 120.1 . . ?
C147 C148 H148 120.0 . . ?
C148 C149 C144 117.9(7) . . ?
C148 C149 H149 121.1 . . ?
C144 C149 H149 121.1 . . ?
N1 C150 C147 173.7(7) . . ?
C152 C151 S4 111.3(5) . . ?
C152 C151 H15A 109.4 . . ?
S4 C151 H15A 109.4 . . ?
C152 C151 H15B 109.4 . . ?
S4 C151 H15B 109.4 . . ?
H15A C151 H15B 108.0 . . ?
C151 C152 P7 106.7(5) . . ?
C151 C152 H15C 110.4 . . ?
P7 C152 H15C 110.4 . . ?
C151 C152 H15D 110.4 . . ?
P7 C152 H15D 110.4 . . ?
H15C C152 H15D 108.6 . . ?
Cl3 C153 Cl4 115.0(7) . . ?
Cl3 C153 H15E 108.5 . . ?
Cl4 C153 H15E 108.5 . . ?
Cl3 C153 H15F 108.5 . . ?
Cl4 C153 H15F 108.5 . . ?
H15E C153 H15F 107.5 . . ?
Cl2 C154 Cl1 112.8(5) . . ?
Cl2 C154 H15G 109.0 . . ?
Cl1 C154 H15G 109.0 . . ?
Cl2 C154 H15H 109.0 . . ?
Cl1 C154 H15H 109.0 . . ?
H15G C154 H15H 107.8 . . ?
Cl5 C155 Cl6 107.5(11) . . ?
Cl5 C155 H15I 110.2 . . ?
Cl6 C155 H15I 110.2 . . ?
Cl5 C155 H15J 110.2 . . ?
Cl6 C155 H15J 110.2 . . ?
H15I C155 H15J 108.5 . . ?
F3 B1 F4 109.6(9) . . ?
F3 B1 F2 113.8(10) . . ?
F4 B1 F2 109.5(12) . . ?
F3 B1 F1 111.3(13) . . ?
F4 B1 F1 107.5(10) . . ?
F2 B1 F1 105.0(9) . . ?
F5 B2 F7 111.1(9) . . ?
F5 B2 F6 110.7(10) . . ?
F7 B2 F6 111.0(9) . . ?
F5 B2 F8 109.0(9) . . ?
F7 B2 F8 107.7(10) . . ?
F6 B2 F8 107.2(8) . . ?
F9 B3 F11 107.8(8) . . ?
F9 B3 F10 107.2(7) . . ?
F11 B3 F10 114.7(8) . . ?
F9 B3 F12 116.8(8) . . ?
F11 B3 F12 105.1(7) . . ?
F10 B3 F12 105.6(7) . . ?
F16 B4 F13 110.7(13) . . ?
F16 B4 F14 109.9(13) . . ?
F13 B4 F14 109.1(13) . . ?
F16 B4 F15 109.8(13) . . ?
F13 B4 F15 109.0(13) . . ?
F14 B4 F15 108.3(13) . . ?
C158 C157 C156 148.1(12) . . ?
C159 C158 C157 121.5(14) . . ?
C159 C159 C158 111.6(14) 2_675 . ?
C160 C161 C162 147.3(15) . . ?
C163 C162 C161 169.4(8) . . ?
C164 C163 C162 126.5(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Rh1 S1 C66 60.6(2) . . . . ?
P1 Rh1 S1 C66 -111.4(2) . . . . ?
P2 Rh1 S1 C66 83.1(6) . . . . ?
N1 Rh1 S1 C1 168.5(3) . . . . ?
P1 Rh1 S1 C1 -3.4(2) . . . . ?
P2 Rh1 S1 C1 -169.0(5) . . . . ?
N3 Rh2 S2 C32 68.8(3) . . . . ?
P3 Rh2 S2 C32 -106.3(2) . . . . ?
P4 Rh2 S2 C32 64.9(18) . . . . ?
N3 Rh2 S2 C35 174.3(4) . . . . ?
P3 Rh2 S2 C35 -0.8(3) . . . . ?
P4 Rh2 S2 C35 170.3(18) . . . . ?
N2 Rh3 S3 C106 69.9(3) . . . . ?
P5 Rh3 S3 C106 -104.0(2) . . . . ?
P6 Rh3 S3 C106 119.6(8) . . . . ?
N2 Rh3 S3 C109 176.3(3) . . . . ?
P5 Rh3 S3 C109 2.3(2) . . . . ?
P6 Rh3 S3 C109 -134.1(8) . . . . ?
N4 Rh4 S4 C140 59.0(3) . . . . ?
P7 Rh4 S4 C140 -113.8(3) . . . . ?
P8 Rh4 S4 C140 144(2) . . . . ?
N4 Rh4 S4 C151 164.6(3) . . . . ?
P7 Rh4 S4 C151 -8.2(3) . . . . ?
P8 Rh4 S4 C151 -110(2) . . . . ?
N1 Rh1 P1 C3 -135.7(8) . . . . ?
P2 Rh1 P1 C3 88.8(2) . . . . ?
S1 Rh1 P1 C3 -89.7(2) . . . . ?
N1 Rh1 P1 C9 91.0(8) . . . . ?
P2 Rh1 P1 C9 -44.5(2) . . . . ?
S1 Rh1 P1 C9 137.0(2) . . . . ?
N1 Rh1 P1 C2 -20.1(8) . . . . ?
P2 Rh1 P1 C2 -155.6(2) . . . . ?
S1 Rh1 P1 C2 25.9(2) . . . . ?
N1 Rh1 P2 C15 147.5(3) . . . . ?
P1 Rh1 P2 C15 -40.3(3) . . . . ?
S1 Rh1 P2 C15 125.0(6) . . . . ?
N1 Rh1 P2 C21 27.6(3) . . . . ?
P1 Rh1 P2 C21 -160.2(2) . . . . ?
S1 Rh1 P2 C21 5.1(6) . . . . ?
N1 Rh1 P2 C27 -91.4(3) . . . . ?
P1 Rh1 P2 C27 80.8(2) . . . . ?
S1 Rh1 P2 C27 -113.8(6) . . . . ?
N3 Rh2 P3 C37 98.0(15) . . . . ?
P4 Rh2 P3 C37 -39.4(3) . . . . ?
S2 Rh2 P3 C37 140.2(3) . . . . ?
N3 Rh2 P3 C36 -18.0(15) . . . . ?
P4 Rh2 P3 C36 -155.4(3) . . . . ?
S2 Rh2 P3 C36 24.2(3) . . . . ?
N3 Rh2 P3 C43 -130.2(15) . . . . ?
P4 Rh2 P3 C43 92.4(3) . . . . ?
S2 Rh2 P3 C43 -88.0(3) . . . . ?
N3 Rh2 P4 C49 141.8(4) . . . . ?
P3 Rh2 P4 C49 -43.1(4) . . . . ?
S2 Rh2 P4 C49 145.7(18) . . . . ?
N3 Rh2 P4 C61 -98.2(3) . . . . ?
P3 Rh2 P4 C61 76.8(3) . . . . ?
S2 Rh2 P4 C61 -94.3(18) . . . . ?
N3 Rh2 P4 C55 22.9(4) . . . . ?
P3 Rh2 P4 C55 -162.0(3) . . . . ?
S2 Rh2 P4 C55 26.8(18) . . . . ?
N2 Rh3 P5 C117 -135.2(11) . . . . ?
P6 Rh3 P5 C117 83.3(3) . . . . ?
S3 Rh3 P5 C117 -93.6(3) . . . . ?
N2 Rh3 P5 C111 93.8(11) . . . . ?
P6 Rh3 P5 C111 -47.8(3) . . . . ?
S3 Rh3 P5 C111 135.3(3) . . . . ?
N2 Rh3 P5 C110 -20.8(11) . . . . ?
P6 Rh3 P5 C110 -162.3(3) . . . . ?
S3 Rh3 P5 C110 20.7(3) . . . . ?
N2 Rh3 P6 C123 144.5(3) . . . . ?
P5 Rh3 P6 C123 -41.1(3) . . . . ?
S3 Rh3 P6 C123 95.0(8) . . . . ?
N2 Rh3 P6 C135 -94.4(3) . . . . ?
P5 Rh3 P6 C135 80.0(3) . . . . ?
S3 Rh3 P6 C135 -143.9(8) . . . . ?
N2 Rh3 P6 C129 25.1(3) . . . . ?
P5 Rh3 P6 C129 -160.6(2) . . . . ?
S3 Rh3 P6 C129 -24.5(8) . . . . ?
N4 Rh4 P7 C77 98.7(14) . . . . ?
P8 Rh4 P7 C77 -33.5(3) . . . . ?
S4 Rh4 P7 C77 149.0(3) . . . . ?
N4 Rh4 P7 C152 -18.2(14) . . . . ?
P8 Rh4 P7 C152 -150.4(3) . . . . ?
S4 Rh4 P7 C152 32.2(3) . . . . ?
N4 Rh4 P7 C83 -127.1(14) . . . . ?
P8 Rh4 P7 C83 100.7(3) . . . . ?
S4 Rh4 P7 C83 -76.7(3) . . . . ?
N4 Rh4 P8 C101 -98.4(4) . . . . ?
P7 Rh4 P8 C101 74.7(3) . . . . ?
S4 Rh4 P8 C101 176(52) . . . . ?
N4 Rh4 P8 C89 143.1(6) . . . . ?
P7 Rh4 P8 C89 -43.8(6) . . . . ?
S4 Rh4 P8 C89 58(2) . . . . ?
N4 Rh4 P8 C95 21.9(4) . . . . ?
P7 Rh4 P8 C95 -164.9(3) . . . . ?
S4 Rh4 P8 C95 -63(2) . . . . ?
P1 Rh1 N1 C150 -66(15) . . . . ?
P2 Rh1 N1 C150 70(14) . . . . ?
S1 Rh1 N1 C150 -112(14) . . . . ?
P5 Rh3 N2 C143 178(100) . . . . ?
P6 Rh3 N2 C143 -40(20) . . . . ?
S3 Rh3 N2 C143 136(20) . . . . ?
P3 Rh2 N3 C69 -143(7) . . . . ?
P4 Rh2 N3 C69 -5(8) . . . . ?
S2 Rh2 N3 C69 175(8) . . . . ?
P7 Rh4 N4 C76 -52(30) . . . . ?
P8 Rh4 N4 C76 80(29) . . . . ?
S4 Rh4 N4 C76 -102(29) . . . . ?
C66 S1 C1 C2 83.1(5) . . . . ?
Rh1 S1 C1 C2 -26.7(5) . . . . ?
S1 C1 C2 P1 50.1(5) . . . . ?
C3 P1 C2 C1 76.4(5) . . . . ?
C9 P1 C2 C1 -175.4(4) . . . . ?
Rh1 P1 C2 C1 -50.1(4) . . . . ?
C9 P1 C3 C4 -81.4(6) . . . . ?
C2 P1 C3 C4 23.5(6) . . . . ?
Rh1 P1 C3 C4 139.1(5) . . . . ?
C9 P1 C3 C8 97.4(5) . . . . ?
C2 P1 C3 C8 -157.8(5) . . . . ?
Rh1 P1 C3 C8 -42.2(6) . . . . ?
C8 C3 C4 C5 0.1(10) . . . . ?
P1 C3 C4 C5 178.8(5) . . . . ?
C3 C4 C5 C6 -1.1(11) . . . . ?
C4 C5 C6 C7 1.2(13) . . . . ?
C5 C6 C7 C8 -0.3(14) . . . . ?
C6 C7 C8 C3 -0.8(13) . . . . ?
C4 C3 C8 C7 0.9(11) . . . . ?
P1 C3 C8 C7 -178.0(6) . . . . ?
C3 P1 C9 C10 -7.6(6) . . . . ?
C2 P1 C9 C10 -115.1(5) . . . . ?
Rh1 P1 C9 C10 131.8(5) . . . . ?
C3 P1 C9 C14 172.5(5) . . . . ?
C2 P1 C9 C14 64.9(5) . . . . ?
Rh1 P1 C9 C14 -48.2(5) . . . . ?
C14 C9 C10 C11 -0.4(10) . . . . ?
P1 C9 C10 C11 179.6(5) . . . . ?
C9 C10 C11 C12 0.1(11) . . . . ?
C10 C11 C12 C13 0.0(12) . . . . ?
C11 C12 C13 C14 0.3(11) . . . . ?
C12 C13 C14 C9 -0.6(10) . . . . ?
C10 C9 C14 C13 0.7(9) . . . . ?
P1 C9 C14 C13 -179.4(5) . . . . ?
C21 P2 C15 C16 -141.7(6) . . . . ?
C27 P2 C15 C16 -31.9(6) . . . . ?
Rh1 P2 C15 C16 93.8(5) . . . . ?
C21 P2 C15 C20 40.2(6) . . . . ?
C27 P2 C15 C20 150.0(5) . . . . ?
Rh1 P2 C15 C20 -84.3(6) . . . . ?
C20 C15 C16 C17 1.0(10) . . . . ?
P2 C15 C16 C17 -177.1(6) . . . . ?
C15 C16 C17 C18 -0.3(12) . . . . ?
C16 C17 C18 C19 0.4(13) . . . . ?
C17 C18 C19 C20 -1.1(13) . . . . ?
C18 C19 C20 C15 1.9(12) . . . . ?
C16 C15 C20 C19 -1.8(10) . . . . ?
P2 C15 C20 C19 176.4(6) . . . . ?
C15 P2 C21 C26 -92.8(5) . . . . ?
C27 P2 C21 C26 160.8(5) . . . . ?
Rh1 P2 C21 C26 38.6(5) . . . . ?
C15 P2 C21 C22 87.0(6) . . . . ?
C27 P2 C21 C22 -19.4(6) . . . . ?
Rh1 P2 C21 C22 -141.6(5) . . . . ?
C26 C21 C22 C23 -0.3(9) . . . . ?
P2 C21 C22 C23 179.9(5) . . . . ?
C21 C22 C23 C24 -1.5(11) . . . . ?
C22 C23 C24 C25 2.7(12) . . . . ?
C23 C24 C25 C26 -2.1(11) . . . . ?
C22 C21 C26 C25 0.9(9) . . . . ?
P2 C21 C26 C25 -179.3(5) . . . . ?
C24 C25 C26 C21 0.3(11) . . . . ?
C15 P2 C27 C28 176.8(5) . . . . ?
C21 P2 C27 C28 -77.2(5) . . . . ?
Rh1 P2 C27 C28 44.6(5) . . . . ?
C29 O6 C28 C27 -178.8(5) . . . . ?
P2 C27 C28 O6 85.9(6) . . . . ?
C28 O6 C29 C34 -175.7(6) . . . . ?
C28 O6 C29 C30 3.4(9) . . . . ?
O6 C29 C30 C31 177.5(6) . . . . ?
C34 C29 C30 C31 -3.4(9) . . . . ?
C29 C30 C31 C32 3.9(10) . . . . ?
C30 C31 C32 C33 -1.8(10) . . . . ?
C30 C31 C32 S2 178.6(5) . . . . ?
C35 S2 C32 C31 -86.5(6) . . . . ?
Rh2 S2 C32 C31 22.4(6) . . . . ?
C35 S2 C32 C33 93.9(6) . . . . ?
Rh2 S2 C32 C33 -157.2(5) . . . . ?
C31 C32 C33 C34 -0.9(10) . . . . ?
S2 C32 C33 C34 178.7(5) . . . . ?
C32 C33 C34 C29 1.3(11) . . . . ?
O6 C29 C34 C33 -180.0(6) . . . . ?
C30 C29 C34 C33 0.9(10) . . . . ?
C32 S2 C35 C36 80.6(6) . . . . ?
Rh2 S2 C35 C36 -29.2(6) . . . . ?
S2 C35 C36 P3 50.4(7) . . . . ?
C37 P3 C36 C35 -175.9(5) . . . . ?
C43 P3 C36 C35 74.5(6) . . . . ?
Rh2 P3 C36 C35 -48.7(5) . . . . ?
C36 P3 C37 C42 -130.2(10) . . . . ?
C43 P3 C37 C42 -24.5(10) . . . . ?
Rh2 P3 C37 C42 112.0(9) . . . . ?
C36 P3 C37 C38 55.5(7) . . . . ?
C43 P3 C37 C38 161.2(7) . . . . ?
Rh2 P3 C37 C38 -62.3(8) . . . . ?
C42 C37 C38 C39 -2.1(14) . . . . ?
P3 C37 C38 C39 172.5(7) . . . . ?
C37 C38 C39 C40 3.8(15) . . . . ?
C38 C39 C40 C41 -3.6(19) . . . . ?
C39 C40 C41 C42 2(2) . . . . ?
C38 C37 C42 C41 0.4(19) . . . . ?
P3 C37 C42 C41 -174.0(11) . . . . ?
C40 C41 C42 C37 0(2) . . . . ?
C37 P3 C43 C48 142.5(10) . . . . ?
C36 P3 C43 C48 -110.5(10) . . . . ?
Rh2 P3 C43 C48 4.6(11) . . . . ?
C37 P3 C43 C44 -45.2(9) . . . . ?
C36 P3 C43 C44 61.9(9) . . . . ?
Rh2 P3 C43 C44 176.9(7) . . . . ?
C48 C43 C44 C45 -6.0(18) . . . . ?
P3 C43 C44 C45 -178.2(9) . . . . ?
C43 C44 C45 C46 4(2) . . . . ?
C44 C45 C46 C47 -1(3) . . . . ?
C45 C46 C47 C48 0(3) . . . . ?
C44 C43 C48 C47 5(2) . . . . ?
P3 C43 C48 C47 177.1(12) . . . . ?
C46 C47 C48 C43 -2(3) . . . . ?
C61 P4 C49 C50 1.7(10) . . . . ?
C55 P4 C49 C50 -109.5(9) . . . . ?
Rh2 P4 C49 C50 126.7(8) . . . . ?
C61 P4 C49 C54 -173.2(8) . . . . ?
C55 P4 C49 C54 75.6(9) . . . . ?
Rh2 P4 C49 C54 -48.3(9) . . . . ?
C54 C49 C50 C51 -4.0(18) . . . . ?
P4 C49 C50 C51 -178.8(10) . . . . ?
C49 C50 C51 C52 -1(2) . . . . ?
C50 C51 C52 C53 7(2) . . . . ?
C51 C52 C53 C54 -8(2) . . . . ?
C52 C53 C54 C49 3(2) . . . . ?
C50 C49 C54 C53 3.2(19) . . . . ?
P4 C49 C54 C53 178.3(11) . . . . ?
C49 P4 C55 C56 106.2(8) . . . . ?
C61 P4 C55 C56 -0.9(8) . . . . ?
Rh2 P4 C55 C56 -124.9(7) . . . . ?
C49 P4 C55 C60 -78.3(7) . . . . ?
C61 P4 C55 C60 174.5(7) . . . . ?
Rh2 P4 C55 C60 50.6(7) . . . . ?
C60 C55 C56 C57 -2.4(14) . . . . ?
P4 C55 C56 C57 173.0(8) . . . . ?
C55 C56 C57 C58 1.2(16) . . . . ?
C56 C57 C58 C59 2.7(18) . . . . ?
C57 C58 C59 C60 -6(2) . . . . ?
C56 C55 C60 C59 -0.3(14) . . . . ?
P4 C55 C60 C59 -175.9(8) . . . . ?
C58 C59 C60 C55 4.5(18) . . . . ?
C49 P4 C61 C62 169.2(6) . . . . ?
C55 P4 C61 C62 -84.0(6) . . . . ?
Rh2 P4 C61 C62 39.7(6) . . . . ?
C63 O5 C62 C61 174.1(6) . . . . ?
P4 C61 C62 O5 79.5(7) . . . . ?
C62 O5 C63 C64 12.3(10) . . . . ?
C62 O5 C63 C68 -168.3(6) . . . . ?
O5 C63 C64 C65 178.0(6) . . . . ?
C68 C63 C64 C65 -1.3(10) . . . . ?
C63 C64 C65 C66 2.2(9) . . . . ?
C64 C65 C66 C67 -2.8(9) . . . . ?
C64 C65 C66 S1 -176.4(5) . . . . ?
C1 S1 C66 C67 98.3(5) . . . . ?
Rh1 S1 C66 C67 -151.6(5) . . . . ?
C1 S1 C66 C65 -88.0(6) . . . . ?
Rh1 S1 C66 C65 22.1(5) . . . . ?
C65 C66 C67 C68 2.7(10) . . . . ?
S1 C66 C67 C68 176.5(6) . . . . ?
C66 C67 C68 C63 -1.9(11) . . . . ?
O5 C63 C68 C67 -178.2(7) . . . . ?
C64 C63 C68 C67 1.2(11) . . . . ?
Rh2 N3 C69 C70 -37(43) . . . . ?
N3 C69 C70 C75 110(37) . . . . ?
N3 C69 C70 C71 -74(37) . . . . ?
C75 C70 C71 C72 -0.3(13) . . . . ?
C69 C70 C71 C72 -176.2(8) . . . . ?
C70 C71 C72 C73 -0.3(13) . . . . ?
C71 C72 C73 C74 0.2(13) . . . . ?
C71 C72 C73 C76 177.3(8) . . . . ?
C72 C73 C74 C75 0.4(12) . . . . ?
C76 C73 C74 C75 -176.6(8) . . . . ?
C71 C70 C75 C74 1.0(13) . . . . ?
C69 C70 C75 C74 177.0(8) . . . . ?
C73 C74 C75 C70 -1.1(13) . . . . ?
Rh4 N4 C76 C73 -170(19) . . . . ?
C74 C73 C76 N4 -14(16) . . . . ?
C72 C73 C76 N4 169(15) . . . . ?
C152 P7 C77 C78 51.3(7) . . . . ?
C83 P7 C77 C78 155.7(6) . . . . ?
Rh4 P7 C77 C78 -65.8(7) . . . . ?
C152 P7 C77 C82 -133.2(7) . . . . ?
C83 P7 C77 C82 -28.9(8) . . . . ?
Rh4 P7 C77 C82 109.6(7) . . . . ?
C82 C77 C78 C79 0.9(12) . . . . ?
P7 C77 C78 C79 176.6(6) . . . . ?
C77 C78 C79 C80 0.4(14) . . . . ?
C78 C79 C80 C81 1.5(19) . . . . ?
C79 C80 C81 C82 -5(2) . . . . ?
C80 C81 C82 C77 6.2(19) . . . . ?
C78 C77 C82 C81 -4.2(15) . . . . ?
P7 C77 C82 C81 -179.8(9) . . . . ?
C77 P7 C83 C88 140.6(8) . . . . ?
C152 P7 C83 C88 -111.8(8) . . . . ?
Rh4 P7 C83 C88 0.0(9) . . . . ?
C77 P7 C83 C84 -47.6(8) . . . . ?
C152 P7 C83 C84 60.0(8) . . . . ?
Rh4 P7 C83 C84 171.8(6) . . . . ?
C88 C83 C84 C85 -0.6(14) . . . . ?
P7 C83 C84 C85 -172.6(7) . . . . ?
C83 C84 C85 C86 -0.3(14) . . . . ?
C84 C85 C86 C87 0.8(15) . . . . ?
C85 C86 C87 C88 -0.4(15) . . . . ?
C84 C83 C88 C87 1.1(15) . . . . ?
P7 C83 C88 C87 173.0(8) . . . . ?
C86 C87 C88 C83 -0.6(16) . . . . ?
C101 P8 C89 C90 20.0(14) . . . . ?
C95 P8 C89 C90 -90.7(14) . . . . ?
Rh4 P8 C89 C90 143.7(12) . . . . ?
C101 P8 C89 C94 -162.9(9) . . . . ?
C95 P8 C89 C94 86.4(10) . . . . ?
Rh4 P8 C89 C94 -39.2(10) . . . . ?
C94 C89 C90 C91 9(3) . . . . ?
P8 C89 C90 C91 -174.2(15) . . . . ?
C89 C90 C91 C92 -9(3) . . . . ?
C90 C91 C92 C93 10(5) . . . . ?
C91 C92 C93 C94 -10(6) . . . . ?
C90 C89 C94 C93 -6.2(19) . . . . ?
P8 C89 C94 C93 176.5(12) . . . . ?
C92 C93 C94 C89 7(4) . . . . ?
C101 P8 C95 C100 167.4(10) . . . . ?
C89 P8 C95 C100 -85.4(12) . . . . ?
Rh4 P8 C95 C100 43.9(10) . . . . ?
C101 P8 C95 C96 -15.3(11) . . . . ?
C89 P8 C95 C96 91.9(11) . . . . ?
Rh4 P8 C95 C96 -138.8(9) . . . . ?
C100 C95 C96 C97 0.9(19) . . . . ?
P8 C95 C96 C97 -176.3(10) . . . . ?
C95 C96 C97 C98 -4(2) . . . . ?
C96 C97 C98 C99 4(2) . . . . ?
C97 C98 C99 C100 -2(2) . . . . ?
C96 C95 C100 C99 2.2(19) . . . . ?
P8 C95 C100 C99 179.6(10) . . . . ?
C98 C99 C100 C95 -2(2) . . . . ?
C89 P8 C101 C102 171.5(5) . . . . ?
C95 P8 C101 C102 -80.1(7) . . . . ?
Rh4 P8 C101 C102 43.6(6) . . . . ?
C103 O4 C102 C101 -171.1(7) . . . . ?
P8 C101 C102 O4 75.5(7) . . . . ?
C102 O4 C103 C104 12.8(11) . . . . ?
C102 O4 C103 C108 -170.3(7) . . . . ?
O4 C103 C104 C105 178.8(7) . . . . ?
C108 C103 C104 C105 1.9(10) . . . . ?
C103 C104 C105 C106 -2.4(10) . . . . ?
C104 C105 C106 C107 3.0(10) . . . . ?
C104 C105 C106 S3 -178.6(5) . . . . ?
C109 S3 C106 C105 -96.8(6) . . . . ?
Rh3 S3 C106 C105 12.9(6) . . . . ?
C109 S3 C106 C107 81.6(6) . . . . ?
Rh3 S3 C106 C107 -168.7(5) . . . . ?
C105 C106 C107 C108 -3.4(11) . . . . ?
S3 C106 C107 C108 178.1(6) . . . . ?
C106 C107 C108 C103 3.1(12) . . . . ?
O4 C103 C108 C107 -179.5(7) . . . . ?
C104 C103 C108 C107 -2.4(11) . . . . ?
C106 S3 C109 C110 80.8(5) . . . . ?
Rh3 S3 C109 C110 -31.9(5) . . . . ?
S3 C109 C110 P5 50.9(6) . . . . ?
C117 P5 C110 C109 77.1(5) . . . . ?
C111 P5 C110 C109 -173.2(5) . . . . ?
Rh3 P5 C110 C109 -46.8(5) . . . . ?
C117 P5 C111 C112 -10.3(9) . . . . ?
C110 P5 C111 C112 -117.7(8) . . . . ?
Rh3 P5 C111 C112 125.6(7) . . . . ?
C117 P5 C111 C116 169.6(6) . . . . ?
C110 P5 C111 C116 62.2(7) . . . . ?
Rh3 P5 C111 C116 -54.5(7) . . . . ?
C116 C111 C112 C113 3.4(15) . . . . ?
P5 C111 C112 C113 -176.7(9) . . . . ?
C111 C112 C113 C114 -2.3(18) . . . . ?
C112 C113 C114 C115 -0.4(17) . . . . ?
C113 C114 C115 C116 1.9(15) . . . . ?
C114 C115 C116 C111 -0.7(13) . . . . ?
C112 C111 C116 C115 -1.9(12) . . . . ?
P5 C111 C116 C115 178.3(6) . . . . ?
C111 P5 C117 C122 129.1(6) . . . . ?
C110 P5 C117 C122 -124.2(6) . . . . ?
Rh3 P5 C117 C122 -8.2(7) . . . . ?
C111 P5 C117 C118 -54.2(7) . . . . ?
C110 P5 C117 C118 52.5(7) . . . . ?
Rh3 P5 C117 C118 168.5(6) . . . . ?
C122 C117 C118 C119 -0.8(12) . . . . ?
P5 C117 C118 C119 -177.5(7) . . . . ?
C117 C118 C119 C120 -3.1(14) . . . . ?
C118 C119 C120 C121 4.2(14) . . . . ?
C119 C120 C121 C122 -1.1(14) . . . . ?
C118 C117 C122 C121 3.8(12) . . . . ?
P5 C117 C122 C121 -179.4(7) . . . . ?
C120 C121 C122 C117 -2.9(14) . . . . ?
C135 P6 C123 C124 -21.4(8) . . . . ?
C129 P6 C123 C124 -131.9(8) . . . . ?
Rh3 P6 C123 C124 104.0(8) . . . . ?
C135 P6 C123 C128 161.8(7) . . . . ?
C129 P6 C123 C128 51.2(7) . . . . ?
Rh3 P6 C123 C128 -72.8(7) . . . . ?
C128 C123 C124 C125 -1.1(17) . . . . ?
P6 C123 C124 C125 -177.9(10) . . . . ?
C123 C124 C125 C126 -4(2) . . . . ?
C124 C125 C126 C127 5(2) . . . . ?
C125 C126 C127 C128 -1.3(18) . . . . ?
C124 C123 C128 C127 4.6(14) . . . . ?
P6 C123 C128 C127 -178.5(7) . . . . ?
C126 C127 C128 C123 -3.4(15) . . . . ?
C123 P6 C129 C130 -88.7(6) . . . . ?
C135 P6 C129 C130 165.2(6) . . . . ?
Rh3 P6 C129 C130 43.5(6) . . . . ?
C123 P6 C129 C134 92.1(6) . . . . ?
C135 P6 C129 C134 -14.0(7) . . . . ?
Rh3 P6 C129 C134 -135.7(5) . . . . ?
C134 C129 C130 C131 0.9(11) . . . . ?
P6 C129 C130 C131 -178.4(6) . . . . ?
C129 C130 C131 C132 0.7(11) . . . . ?
C130 C131 C132 C133 -3.3(12) . . . . ?
C131 C132 C133 C134 4.1(12) . . . . ?
C132 C133 C134 C129 -2.4(11) . . . . ?
C130 C129 C134 C133 -0.1(10) . . . . ?
P6 C129 C134 C133 179.2(6) . . . . ?
C123 P6 C135 C136 172.2(5) . . . . ?
C129 P6 C135 C136 -82.3(6) . . . . ?
Rh3 P6 C135 C136 39.1(6) . . . . ?
C137 O3 C136 C135 -177.1(6) . . . . ?
P6 C135 C136 O3 82.6(6) . . . . ?
C136 O3 C137 C142 7.9(10) . . . . ?
C136 O3 C137 C138 -172.6(7) . . . . ?
C142 C137 C138 C139 0.3(12) . . . . ?
O3 C137 C138 C139 -179.1(7) . . . . ?
C137 C138 C139 C140 0.3(13) . . . . ?
C138 C139 C140 C141 -1.0(12) . . . . ?
C138 C139 C140 S4 -177.3(6) . . . . ?
C151 S4 C140 C141 -86.2(7) . . . . ?
Rh4 S4 C140 C141 23.2(7) . . . . ?
C151 S4 C140 C139 89.9(7) . . . . ?
Rh4 S4 C140 C139 -160.7(6) . . . . ?
C139 C140 C141 C142 1.2(11) . . . . ?
S4 C140 C141 C142 177.3(5) . . . . ?
C138 C137 C142 C141 -0.2(11) . . . . ?
O3 C137 C142 C141 179.2(6) . . . . ?
C140 C141 C142 C137 -0.5(11) . . . . ?
Rh3 N2 C143 C144 60(31) . . . . ?
N2 C143 C144 C145 62(18) . . . . ?
N2 C143 C144 C149 -119(18) . . . . ?
C143 C144 C145 C146 -178.9(7) . . . . ?
C149 C144 C145 C146 2.1(11) . . . . ?
C144 C145 C146 C147 0.3(11) . . . . ?
C145 C146 C147 C148 -1.8(11) . . . . ?
C145 C146 C147 C150 177.5(6) . . . . ?
C146 C147 C148 C149 1.0(11) . . . . ?
C150 C147 C148 C149 -178.4(7) . . . . ?
C147 C148 C149 C144 1.4(11) . . . . ?
C145 C144 C149 C148 -2.9(11) . . . . ?
C143 C144 C149 C148 178.0(7) . . . . ?
Rh1 N1 C150 C147 -103(15) . . . . ?
C146 C147 C150 N1 -74(7) . . . . ?
C148 C147 C150 N1 105(7) . . . . ?
C140 S4 C151 C152 88.5(6) . . . . ?
Rh4 S4 C151 C152 -23.7(6) . . . . ?
S4 C151 C152 P7 50.9(6) . . . . ?
C77 P7 C152 C151 175.4(5) . . . . ?
C83 P7 C152 C151 65.7(6) . . . . ?
Rh4 P7 C152 C151 -55.9(5) . . . . ?
C156 C157 C158 C159 -30(3) . . . . ?
C157 C158 C159 C159 13(2) . . . 2_675 ?
C160 C161 C162 C163 -96(6) . . . . ?
C161 C162 C163 C164 -52(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.891
_diffrn_reflns_theta_full        28.82
_diffrn_measured_fraction_theta_full 0.891
_refine_diff_density_max         5.494
_refine_diff_density_min         -2.695
_refine_diff_density_rms         0.199