# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2008

data_global
_journal_name_full               Chem.Commun.
_journal_coden_Cambridge         0182
_audit_creation_method           SHELXL-97
_publ_section_title              
;
Unprecedented twofold intramolecular hydroamination in diam(m)ine-
dicarboxylatodichloridoplatinum(IV) complexes - ethane-1,2-diamine
versus ammine ligands
;
loop_
_publ_author_name
_publ_author_address
'Michael R. Reithofer'
; Institute of Inorganic Chemistry,
University of Vienna
Waehringer Str. 42,
A-1090 Vienna
Austria
;
'Mathea S. Galanski'
; Institute of Inorganic Chemistry,
University of Vienna
Waehringer Str. 42,
A-1090 Vienna
Austria
;
'Vladimir B. Arion'
; Institute of Inorganic Chemistry,
University of Vienna
Waehringer Str. 42,
A-1090 Vienna
Austria
;
'Bernhard K. Keppler'
; Institute of Inorganic Chemistry,
University of Vienna
Waehringer Str. 42
A-1090 Vienna
Austria
;
_publ_contact_author_name        'Mathea S. Galanski'
_publ_contact_author_address     
;
Institute of Inorganic Chemistry
University of Vienna
Waehringerstr. 42
Vienna
1090
AUSTRIA
;

_publ_contact_author_email       MATHEA.GALANSKI@UNIVIE.AC.AT

# Attachment 'MIRE1042.CIF'

data_MIRE104
_database_code_depnum_ccdc_archive 'CCDC 663532'
_audit_creation_method           SHELXL-97

_chemical_name_systematic        
;
(OC-6-54)-Amminedichlorido(2R,2S-imino-kappaN-nis[(4-propylamino)-
4-oxobutanoato-2-yl]-kappa^2^O,O')platinum(IV)
;
_chemical_name_common            
;
(OC-6-54)-Amminedichlorido(2R,2S-imino-kappaN-nis((4-
propylamino)-4-oxobutanoato-2-yl)-kappa$2!O,O')platinum(IV)
;
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C14 H26.25 Cl2 N4 O6.13 Pt'
_chemical_formula_weight         614.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Iba2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'x+1, -y+1, z+1/2'
'-x+1, y+1, z+1/2'

_cell_length_a                   22.1412(9)
_cell_length_b                   22.6423(8)
_cell_length_c                   8.5427(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     4282.7(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    2282
_cell_measurement_theta_min      2.90
_cell_measurement_theta_max      30.01

_exptl_crystal_description       plate
_exptl_crystal_colour            light-yellow
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.906
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2394
_exptl_absorpt_coefficient_mu    6.839
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1921
_exptl_absorpt_correction_T_max  0.8753
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            61325
_diffrn_reflns_av_R_equivalents  0.0826
_diffrn_reflns_av_sigmaI/netI    0.0460
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         2.90
_diffrn_reflns_theta_max         28.39
_reflns_number_total             5339
_reflns_number_gt                4259
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0450P)^2^+26.6516P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.006(11)
_refine_ls_number_reflns         5339
_refine_ls_number_parameters     249
_refine_ls_number_restraints     213
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0369
_refine_ls_wR_factor_ref         0.0926
_refine_ls_wR_factor_gt          0.0841
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_restrained_S_all      1.058
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.845150(10) 0.677872(10) 0.30872(5) 0.01788(8) Uani 1 1 d U . .
Cl1 Cl 0.92836(9) 0.62160(10) 0.2391(3) 0.0293(4) Uani 1 1 d U . .
Cl2 Cl 0.82290(11) 0.69388(11) 0.0495(2) 0.0317(5) Uani 1 1 d U . .
O1 O 0.8974(2) 0.7491(2) 0.3272(11) 0.0271(14) Uani 1 1 d U . .
O2 O 0.9674(3) 0.7853(3) 0.4886(8) 0.0438(18) Uani 1 1 d U . .
O3 O 0.8410(2) 0.7707(3) 0.7076(7) 0.0242(12) Uani 1 1 d U . .
O4 O 0.7955(2) 0.6046(2) 0.3249(11) 0.0323(13) Uani 1 1 d U . .
O5 O 0.7882(5) 0.5249(3) 0.4724(9) 0.066(3) Uani 1 1 d U . .
O6 O 0.7552(3) 0.6613(2) 0.7021(7) 0.0228(12) Uani 1 1 d U . .
N1 N 0.7721(3) 0.7274(3) 0.3643(7) 0.0233(14) Uani 1 1 d U . .
H1A H 0.7707 0.7328 0.4698 0.035 Uiso 1 1 calc R . .
H1B H 0.7380 0.7085 0.3322 0.035 Uiso 1 1 calc R . .
H1C H 0.7747 0.7631 0.3158 0.035 Uiso 1 1 calc R . .
N2 N 0.8627(3) 0.6654(3) 0.5398(8) 0.0178(12) Uani 1 1 d U . .
H2 H 0.8341 0.6863 0.5971 0.021 Uiso 1 1 calc R . .
N3 N 0.9107(3) 0.8019(4) 0.8847(9) 0.0331(17) Uani 1 1 d U . .
H3 H 0.9483 0.7985 0.9161 0.040 Uiso 1 1 calc R . .
N4 N 0.7348(4) 0.5867(4) 0.8678(9) 0.042(2) Uani 1 1 d U . .
H4 H 0.7437 0.5501 0.8939 0.050 Uiso 1 1 calc R . .
C1 C 0.9309(4) 0.7468(4) 0.4539(10) 0.0282(17) Uani 1 1 d U . .
C2 C 0.9229(3) 0.6932(4) 0.5680(10) 0.0263(16) Uani 1 1 d U . .
H2A H 0.9549 0.6634 0.5435 0.032 Uiso 1 1 calc R . .
C3 C 0.9331(4) 0.7153(4) 0.7323(11) 0.0312(19) Uani 1 1 d U . .
H3A H 0.9754 0.7287 0.7425 0.037 Uiso 1 1 calc R . .
H3B H 0.9270 0.6822 0.8065 0.037 Uiso 1 1 calc R . .
C4 C 0.8916(3) 0.7654(4) 0.7767(10) 0.030(2) Uani 1 1 d U . .
C5 C 0.8742(4) 0.8475(5) 0.9559(12) 0.038(2) Uani 1 1 d U . .
H5A H 0.8421 0.8292 1.0204 0.045 Uiso 1 1 calc R . .
H5B H 0.8546 0.8715 0.8734 0.045 Uiso 1 1 calc R . .
C6 C 0.9132(6) 0.8866(6) 1.0572(18) 0.069(4) Uani 1 1 d U . .
H6A H 0.8869 0.9146 1.1142 0.083 Uiso 1 1 calc R . .
H6B H 0.9339 0.8617 1.1361 0.083 Uiso 1 1 calc R . .
C7 C 0.9590(6) 0.9204(6) 0.971(2) 0.089(5) Uani 1 1 d U . .
H7A H 0.9829 0.9440 1.0447 0.133 Uiso 1 1 calc R . .
H7B H 0.9391 0.9467 0.8960 0.133 Uiso 1 1 calc R . .
H7C H 0.9857 0.8932 0.9146 0.133 Uiso 1 1 calc R . .
C8 C 0.8105(5) 0.5744(4) 0.4494(12) 0.039(2) Uani 1 1 d U . .
C9 C 0.8527(4) 0.5997(4) 0.5688(11) 0.0312(18) Uani 1 1 d U . .
H9 H 0.8925 0.5793 0.5568 0.037 Uiso 1 1 calc R . .
C10 C 0.8305(4) 0.5889(4) 0.7365(11) 0.0324(18) Uani 1 1 d U . .
H10A H 0.8293 0.5459 0.7566 0.039 Uiso 1 1 calc R . .
H10B H 0.8597 0.6067 0.8108 0.039 Uiso 1 1 calc R . .
C11 C 0.7697(4) 0.6142(4) 0.7662(8) 0.0255(17) Uani 1 1 d U . .
C12 C 0.6817(5) 0.6146(5) 0.9391(13) 0.049(3) Uani 1 1 d U . .
H12A H 0.6606 0.6377 0.8574 0.058 Uiso 1 1 calc R . .
H12B H 0.6959 0.6429 1.0196 0.058 Uiso 1 1 calc R . .
C13 C 0.6367(7) 0.5736(6) 1.0142(15) 0.064(3) Uani 1 1 d U . .
H13A H 0.6038 0.5973 1.0616 0.077 Uiso 1 1 calc R . .
H13B H 0.6186 0.5482 0.9324 0.077 Uiso 1 1 calc R . .
C14 C 0.6633(7) 0.5367(7) 1.1331(16) 0.081(5) Uani 1 1 d U . .
H14A H 0.6322 0.5109 1.1777 0.121 Uiso 1 1 calc R . .
H14B H 0.6804 0.5616 1.2159 0.121 Uiso 1 1 calc R . .
H14C H 0.6953 0.5126 1.0865 0.121 Uiso 1 1 calc R . .
O7 O 1.0000(7) 0.5000(7) 0.5557(16) 0.042(8) Uani 0.25 2 d SPR . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.01540(11) 0.02068(12) 0.01756(11) -0.0055(2) -0.0023(2) 0.00392(10)
Cl1 0.0247(10) 0.0336(11) 0.0296(10) -0.0103(9) 0.0003(8) 0.0122(9)
Cl2 0.0337(11) 0.0448(13) 0.0166(9) -0.0052(9) -0.0032(8) 0.0131(10)
O1 0.021(2) 0.030(2) 0.030(4) -0.004(3) 0.010(3) -0.0020(19)
O2 0.031(3) 0.044(4) 0.057(4) -0.034(3) 0.013(3) -0.014(3)
O3 0.021(3) 0.025(3) 0.026(3) -0.003(2) -0.003(2) 0.006(2)
O4 0.032(3) 0.036(3) 0.029(3) -0.018(3) 0.006(3) -0.015(2)
O5 0.116(8) 0.031(4) 0.051(5) -0.014(3) 0.024(5) -0.025(4)
O6 0.026(3) 0.013(3) 0.030(3) 0.009(2) 0.004(2) 0.004(2)
N1 0.015(3) 0.035(4) 0.020(3) -0.005(3) -0.003(2) 0.007(3)
N2 0.012(3) 0.021(3) 0.021(3) -0.004(2) 0.002(2) 0.004(2)
N3 0.020(4) 0.039(4) 0.041(4) -0.018(3) 0.000(3) 0.001(3)
N4 0.068(5) 0.025(4) 0.032(4) 0.010(3) 0.009(4) 0.001(4)
C1 0.014(4) 0.039(5) 0.031(4) -0.023(3) 0.010(3) -0.007(3)
C2 0.011(3) 0.042(4) 0.026(4) -0.010(3) -0.004(3) 0.008(3)
C3 0.018(4) 0.043(5) 0.032(4) -0.011(4) -0.005(3) 0.008(3)
C4 0.016(3) 0.038(4) 0.035(7) -0.014(4) -0.003(3) 0.001(3)
C5 0.030(5) 0.037(5) 0.046(6) -0.017(4) 0.003(4) 0.003(4)
C6 0.068(8) 0.058(8) 0.081(9) -0.043(7) -0.010(7) 0.006(6)
C7 0.059(8) 0.053(8) 0.155(16) -0.016(9) -0.025(8) -0.006(6)
C8 0.058(6) 0.024(4) 0.035(4) -0.012(3) 0.020(4) -0.012(4)
C9 0.051(5) 0.015(3) 0.028(4) 0.004(3) 0.007(3) 0.016(3)
C10 0.033(2) 0.032(2) 0.033(2) 0.0017(10) 0.0000(10) 0.0015(10)
C11 0.039(4) 0.024(4) 0.014(4) 0.000(3) -0.002(3) 0.006(3)
C12 0.038(5) 0.054(7) 0.054(7) 0.034(5) 0.008(4) 0.001(5)
C13 0.086(8) 0.061(8) 0.047(7) 0.000(5) 0.012(6) -0.036(7)
C14 0.114(13) 0.070(10) 0.058(8) 0.027(7) 0.030(8) -0.006(9)
O7 0.019(13) 0.011(13) 0.10(3) 0.000 0.000 0.01(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 O1 1.991(5) . ?
Pt1 O4 1.995(5) . ?
Pt1 N1 2.025(6) . ?
Pt1 N2 2.032(7) . ?
Pt1 Cl2 2.298(2) . ?
Pt1 Cl1 2.3177(19) . ?
O1 C1 1.313(12) . ?
O2 C1 1.225(10) . ?
O3 C4 1.273(9) . ?
O4 C8 1.308(13) . ?
O5 C8 1.239(11) . ?
O6 C11 1.240(9) . ?
N2 C2 1.494(10) . ?
N2 C9 1.526(10) . ?
N3 C4 1.309(10) . ?
N3 C5 1.445(11) . ?
N4 C11 1.319(10) . ?
N4 C12 1.467(13) . ?
C1 C2 1.567(13) . ?
C2 C3 1.507(12) . ?
C3 C4 1.507(12) . ?
C5 C6 1.511(15) . ?
C6 C7 1.47(2) . ?
C8 C9 1.497(14) . ?
C9 C10 1.534(13) . ?
C10 C11 1.485(12) . ?
C12 C13 1.506(15) . ?
C13 C14 1.441(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Pt1 O4 171.2(4) . . ?
O1 Pt1 N1 89.8(3) . . ?
O4 Pt1 N1 90.2(3) . . ?
O1 Pt1 N2 85.7(3) . . ?
O4 Pt1 N2 85.6(3) . . ?
N1 Pt1 N2 90.1(3) . . ?
O1 Pt1 Cl2 94.2(3) . . ?
O4 Pt1 Cl2 94.6(3) . . ?
N1 Pt1 Cl2 88.13(19) . . ?
N2 Pt1 Cl2 178.25(19) . . ?
O1 Pt1 Cl1 90.23(15) . . ?
O4 Pt1 Cl1 89.93(17) . . ?
N1 Pt1 Cl1 178.69(19) . . ?
N2 Pt1 Cl1 91.18(18) . . ?
Cl2 Pt1 Cl1 90.57(8) . . ?
C1 O1 Pt1 111.2(6) . . ?
C8 O4 Pt1 110.6(6) . . ?
C2 N2 C9 121.0(7) . . ?
C2 N2 Pt1 105.6(5) . . ?
C9 N2 Pt1 105.4(5) . . ?
C4 N3 C5 124.6(8) . . ?
C11 N4 C12 122.7(8) . . ?
O2 C1 O1 123.0(9) . . ?
O2 C1 C2 118.3(8) . . ?
O1 C1 C2 118.7(7) . . ?
N2 C2 C3 115.0(7) . . ?
N2 C2 C1 109.0(6) . . ?
C3 C2 C1 107.8(7) . . ?
C2 C3 C4 113.2(7) . . ?
O3 C4 N3 123.5(8) . . ?
O3 C4 C3 119.4(7) . . ?
N3 C4 C3 117.2(7) . . ?
N3 C5 C6 109.9(8) . . ?
C7 C6 C5 114.4(13) . . ?
O5 C8 O4 120.1(10) . . ?
O5 C8 C9 119.1(10) . . ?
O4 C8 C9 120.8(8) . . ?
C8 C9 N2 110.7(7) . . ?
C8 C9 C10 112.1(8) . . ?
N2 C9 C10 110.6(7) . . ?
C11 C10 C9 112.9(7) . . ?
O6 C11 N4 123.0(8) . . ?
O6 C11 C10 119.4(8) . . ?
N4 C11 C10 117.5(8) . . ?
N4 C12 C13 116.2(10) . . ?
C14 C13 C12 112.8(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 O1 C1 107.5(5) . . . . ?
N2 Pt1 O1 C1 17.4(5) . . . . ?
Cl2 Pt1 O1 C1 -164.3(5) . . . . ?
Cl1 Pt1 O1 C1 -73.8(5) . . . . ?
N1 Pt1 O4 C8 -108.8(6) . . . . ?
N2 Pt1 O4 C8 -18.6(6) . . . . ?
Cl2 Pt1 O4 C8 163.1(6) . . . . ?
Cl1 Pt1 O4 C8 72.5(6) . . . . ?
O1 Pt1 N2 C2 -27.5(5) . . . . ?
O4 Pt1 N2 C2 152.5(5) . . . . ?
N1 Pt1 N2 C2 -117.3(5) . . . . ?
Cl1 Pt1 N2 C2 62.7(4) . . . . ?
O1 Pt1 N2 C9 -156.7(5) . . . . ?
O4 Pt1 N2 C9 23.3(5) . . . . ?
N1 Pt1 N2 C9 113.5(5) . . . . ?
Cl1 Pt1 N2 C9 -66.5(5) . . . . ?
Pt1 O1 C1 O2 178.7(6) . . . . ?
Pt1 O1 C1 C2 -2.6(8) . . . . ?
C9 N2 C2 C3 -88.3(9) . . . . ?
Pt1 N2 C2 C3 152.4(6) . . . . ?
C9 N2 C2 C1 150.6(7) . . . . ?
Pt1 N2 C2 C1 31.3(7) . . . . ?
O2 C1 C2 N2 158.3(7) . . . . ?
O1 C1 C2 N2 -20.5(10) . . . . ?
O2 C1 C2 C3 32.8(10) . . . . ?
O1 C1 C2 C3 -145.9(7) . . . . ?
N2 C2 C3 C4 -64.9(10) . . . . ?
C1 C2 C3 C4 56.9(9) . . . . ?
C5 N3 C4 O3 9.4(15) . . . . ?
C5 N3 C4 C3 -171.6(9) . . . . ?
C2 C3 C4 O3 25.2(12) . . . . ?
C2 C3 C4 N3 -153.9(8) . . . . ?
C4 N3 C5 C6 -171.7(11) . . . . ?
N3 C5 C6 C7 64.7(14) . . . . ?
Pt1 O4 C8 O5 -173.9(8) . . . . ?
Pt1 O4 C8 C9 8.5(11) . . . . ?
O5 C8 C9 N2 -166.1(9) . . . . ?
O4 C8 C9 N2 11.5(12) . . . . ?
O5 C8 C9 C10 -42.0(12) . . . . ?
O4 C8 C9 C10 135.6(9) . . . . ?
C2 N2 C9 C8 -143.7(8) . . . . ?
Pt1 N2 C9 C8 -24.2(8) . . . . ?
C2 N2 C9 C10 91.4(9) . . . . ?
Pt1 N2 C9 C10 -149.2(6) . . . . ?
C8 C9 C10 C11 -58.3(10) . . . . ?
N2 C9 C10 C11 65.8(10) . . . . ?
C12 N4 C11 O6 -13.1(13) . . . . ?
C12 N4 C11 C10 163.0(9) . . . . ?
C9 C10 C11 O6 -35.2(12) . . . . ?
C9 C10 C11 N4 148.6(8) . . . . ?
C11 N4 C12 C13 162.8(10) . . . . ?
N4 C12 C13 C14 56.6(15) . . . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        28.39
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         1.077
_refine_diff_density_min         -1.770
_refine_diff_density_rms         0.181