# Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2008

data_global
_journal_coden_Cambridge         182
_publ_contact_author_name        'Robin B Bedford'
_publ_contact_author_address     
;
School of Chemistry
University of Bristol
Bristol
BS8 1TS
UK
;
_publ_contact_author_email       r.bedford@bristol.ac.uk
_publ_contact_author_phone       '+44 117 331 7538'
_publ_contact_author_fax         '+44 117 929 0509'

loop_
_publ_author_name
_publ_author_address
'Bedford, Robin B'
;
School of Chemistry
University of Bristol
Bristol
BS8 1TS
UK
;
'Betham, Michael'
;
School of Chemistry
University of Bristol
Bristol
BS8 1TS
UK
;
'Caffyn, Andrew JM'
;
Department of Chemistry
The University of the West Indies
St Augustine
Trinidad and Tobago
;
'Charmant, Jonathan PH'
;
School of Chemistry
University of Bristol
Bristol
BS8 1TS
UK
;
'Lewis-Alleyne, Lesley C'
;
Department of Chemistry
The University of the West Indies
St Augustine
Trinidad and Tobago
;
'Long, Philip D'
;
School of Chemistry
University of Bristol
Bristol
BS8 1TS
UK
;
'Dorian, Polo-Ceron'
;
Departamento de Quimica Inorganica y Analitica
Universidad Rey Juan Carlos
Tulipan; s/n, 28993
Mostoles
Madrid
Spain.
;
'Prashar, Sanjiv'
;
Departamento de Quimica Inorganica y Analitica
Universidad Rey Juan Carlos
Tulipan; s/n, 28993
Mostoles
Madrid
Spain
;

_publ_requested_journal          'Chemical Communications'

data_2
_database_code_depnum_ccdc_archive 'CCDC 669413'
_audit_creation_method           SHELXL-97

_chemical_formula_moiety         'C14 H26 Cl2 P Rh'
_chemical_formula_sum            'C14 H26 Cl2 P Rh'
_chemical_formula_weight         399.13

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   7.4343(4)
_cell_length_b                   20.7246(14)
_cell_length_c                   10.6522(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.041(2)
_cell_angle_gamma                90.00
_cell_volume                     1640.17(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    43729
_cell_measurement_theta_min      2.91
_cell_measurement_theta_max      27.48

_exptl_crystal_description       plate
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.060
_exptl_crystal_size_mid          0.030
_exptl_crystal_size_min          0.005
_exptl_crystal_density_diffrn    1.616
_exptl_crystal_density_method    none
_exptl_crystal_F_000             816
_exptl_absorpt_coefficient_mu    1.447
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.79
_exptl_absorpt_correction_T_max  0.99
_exptl_absorpt_process_details   'SADABS 2007/2 (Sheldrick, G.M., 2007)'

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
'Bruker-Nonius APEX II CCD camera on \k-goniostat'
_diffrn_measurement_method       '\f & \w scans'
_diffrn_detector_area_resol_mean '4096x4096pixels / 62x62mm'
_diffrn_standards_decay_%        0
_diffrn_reflns_number            16093
_diffrn_reflns_av_R_equivalents  0.0486
_diffrn_reflns_av_sigmaI/netI    0.0413
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.91
_diffrn_reflns_theta_max         27.61
_reflns_number_total             3776
_reflns_number_gt                3175
_reflns_threshold_expression     >2\s(I)

_computing_data_collection       'COLLECT (Hooft, R.W.W., 1998)'
_computing_cell_refinement       
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
#Although determined using DirAx, the cell is refined in the HKL
#package during data reduction
_computing_data_reduction        
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0096P)^2^+7.6154P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_number_reflns         3776
_refine_ls_number_parameters     167
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0584
_refine_ls_R_factor_gt           0.0444
_refine_ls_wR_factor_ref         0.0962
_refine_ls_wR_factor_gt          0.0904
_refine_ls_goodness_of_fit_ref   1.185
_refine_ls_restrained_S_all      1.185
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2753(6) 0.2453(2) 0.6398(4) 0.0227(9) Uani 1 1 d . . .
H1 H 0.3391 0.2121 0.5990 0.027 Uiso 1 1 calc R . .
C2 C 0.1194(6) 0.2674(2) 0.5796(4) 0.0212(9) Uani 1 1 d . . .
H2 H 0.0811 0.2467 0.5037 0.025 Uiso 1 1 calc R . .
C3 C 0.0050(6) 0.3225(2) 0.6267(5) 0.0267(10) Uani 1 1 d . . .
H3A H -0.0460 0.3469 0.5539 0.032 Uiso 1 1 calc R . .
H3B H 0.0823 0.3523 0.6773 0.032 Uiso 1 1 calc R . .
C4 C -0.1494(6) 0.2988(2) 0.7071(4) 0.0237(9) Uani 1 1 d . . .
H4A H -0.1854 0.3342 0.7632 0.028 Uiso 1 1 calc R . .
H4B H -0.2544 0.2883 0.6509 0.028 Uiso 1 1 calc R . .
C5 C -0.1030(6) 0.2404(2) 0.7857(4) 0.0211(9) Uani 1 1 d . . .
H5 H -0.1915 0.2074 0.7896 0.025 Uiso 1 1 calc R . .
C6 C 0.0601(6) 0.2303(2) 0.8538(4) 0.0208(9) Uani 1 1 d . . .
H6 H 0.0765 0.1904 0.8963 0.025 Uiso 1 1 calc R . .
C7 C 0.2120(6) 0.2795(2) 0.8638(4) 0.0250(10) Uani 1 1 d . . .
H7A H 0.2709 0.2766 0.9485 0.030 Uiso 1 1 calc R . .
H7B H 0.1609 0.3234 0.8541 0.030 Uiso 1 1 calc R . .
C8 C 0.3540(6) 0.2691(3) 0.7643(5) 0.0285(11) Uani 1 1 d . . .
H8A H 0.4177 0.3103 0.7506 0.034 Uiso 1 1 calc R . .
H8B H 0.4438 0.2374 0.7967 0.034 Uiso 1 1 calc R . .
C9 C -0.2293(5) 0.0414(2) 0.6664(4) 0.0195(9) Uani 1 1 d . . .
H9 H -0.1654 0.0258 0.5912 0.023 Uiso 1 1 calc R . .
C10 C -0.3765(6) 0.0885(3) 0.6180(5) 0.0309(11) Uani 1 1 d . . .
H10A H -0.4561 0.0665 0.5565 0.046 Uiso 1 1 calc R . .
H10B H -0.3202 0.1256 0.5782 0.046 Uiso 1 1 calc R . .
H10C H -0.4467 0.1033 0.6886 0.046 Uiso 1 1 calc R . .
C11 C -0.3079(6) -0.0182(2) 0.7291(5) 0.0242(10) Uani 1 1 d . . .
H11A H -0.3803 -0.0047 0.7996 0.036 Uiso 1 1 calc R . .
H11B H -0.2098 -0.0462 0.7601 0.036 Uiso 1 1 calc R . .
H11C H -0.3840 -0.0418 0.6679 0.036 Uiso 1 1 calc R . .
C12 C 0.0983(6) 0.0249(2) 0.8267(4) 0.0220(9) Uani 1 1 d . . .
H12 H 0.0314 -0.0057 0.8806 0.026 Uiso 1 1 calc R . .
C13 C 0.1827(6) -0.0144(2) 0.7219(5) 0.0246(10) Uani 1 1 d . . .
H13A H 0.2492 0.0145 0.6675 0.037 Uiso 1 1 calc R . .
H13B H 0.0875 -0.0363 0.6722 0.037 Uiso 1 1 calc R . .
H13C H 0.2653 -0.0465 0.7591 0.037 Uiso 1 1 calc R . .
C14 C 0.2435(6) 0.0580(2) 0.9098(4) 0.0258(10) Uani 1 1 d . . .
H14A H 0.3276 0.0255 0.9440 0.039 Uiso 1 1 calc R . .
H14B H 0.1867 0.0805 0.9790 0.039 Uiso 1 1 calc R . .
H14C H 0.3091 0.0892 0.8596 0.039 Uiso 1 1 calc R . .
Cl1 Cl 0.12677(15) 0.11449(5) 0.50425(10) 0.0244(2) Uani 1 1 d . . .
Cl2 Cl -0.20696(16) 0.10007(5) 0.92667(10) 0.0256(2) Uani 1 1 d . . .
P1 P -0.06313(15) 0.08534(5) 0.76465(10) 0.0172(2) Uani 1 1 d . . .
Rh1 Rh 0.05671(4) 0.175790(16) 0.68282(3) 0.01623(10) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.020(2) 0.022(2) 0.026(2) -0.0010(18) 0.0048(18) -0.0065(17)
C2 0.023(2) 0.021(2) 0.020(2) 0.0029(18) 0.0035(17) -0.0027(17)
C3 0.030(2) 0.021(2) 0.029(3) 0.008(2) 0.005(2) 0.0012(19)
C4 0.024(2) 0.022(2) 0.025(2) 0.0032(19) 0.0055(19) 0.0048(18)
C5 0.025(2) 0.019(2) 0.020(2) -0.0040(17) 0.0086(17) 0.0015(17)
C6 0.029(2) 0.020(2) 0.014(2) -0.0055(17) 0.0019(17) 0.0018(18)
C7 0.029(2) 0.029(3) 0.017(2) -0.0049(18) -0.0025(19) -0.0045(19)
C8 0.022(2) 0.035(3) 0.029(3) -0.004(2) 0.0028(19) -0.005(2)
C9 0.0160(19) 0.028(2) 0.014(2) -0.0017(17) -0.0036(16) -0.0037(17)
C10 0.024(2) 0.036(3) 0.033(3) 0.009(2) -0.005(2) -0.002(2)
C11 0.020(2) 0.025(2) 0.027(2) 0.0000(19) 0.0012(18) -0.0073(18)
C12 0.023(2) 0.020(2) 0.023(2) 0.0018(18) 0.0037(18) -0.0028(17)
C13 0.019(2) 0.023(2) 0.032(3) -0.0014(19) -0.0025(19) 0.0035(18)
C14 0.025(2) 0.031(3) 0.021(2) 0.0049(19) -0.0064(18) -0.0066(19)
Cl1 0.0289(6) 0.0260(6) 0.0186(5) -0.0053(4) 0.0071(4) -0.0014(4)
Cl2 0.0334(6) 0.0232(5) 0.0210(5) -0.0010(4) 0.0123(5) -0.0012(4)
P1 0.0192(5) 0.0172(5) 0.0155(5) -0.0004(4) 0.0036(4) -0.0003(4)
Rh1 0.01788(16) 0.01701(16) 0.01399(16) 0.00000(13) 0.00313(11) -0.00010(13)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.382(6) . ?
C1 C8 1.513(7) . ?
C1 Rh1 2.232(4) . ?
C1 H1 0.9500 . ?
C2 C3 1.520(6) . ?
C2 Rh1 2.251(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.537(6) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 C5 1.505(6) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.406(6) . ?
C5 Rh1 2.120(4) . ?
C5 H5 0.9500 . ?
C6 C7 1.522(6) . ?
C6 Rh1 2.143(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.538(7) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C11 1.529(6) . ?
C9 C10 1.542(6) . ?
C9 P1 1.833(4) . ?
C9 H9 1.0000 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C13 1.534(6) . ?
C12 C14 1.534(6) . ?
C12 P1 1.841(5) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
Cl1 Rh1 2.3609(11) . ?
Cl2 P1 2.0849(15) . ?
P1 Rh1 2.2634(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C8 126.2(4) . . ?
C2 C1 Rh1 72.8(2) . . ?
C8 C1 Rh1 107.0(3) . . ?
C2 C1 H1 116.9 . . ?
C8 C1 H1 116.9 . . ?
Rh1 C1 H1 90.3 . . ?
C1 C2 C3 124.4(4) . . ?
C1 C2 Rh1 71.3(3) . . ?
C3 C2 Rh1 110.2(3) . . ?
C1 C2 H2 117.8 . . ?
C3 C2 H2 117.8 . . ?
Rh1 C2 H2 88.5 . . ?
C2 C3 C4 112.4(4) . . ?
C2 C3 H3A 109.1 . . ?
C4 C3 H3A 109.1 . . ?
C2 C3 H3B 109.1 . . ?
C4 C3 H3B 109.1 . . ?
H3A C3 H3B 107.9 . . ?
C5 C4 C3 114.0(4) . . ?
C5 C4 H4A 108.8 . . ?
C3 C4 H4A 108.8 . . ?
C5 C4 H4B 108.8 . . ?
C3 C4 H4B 108.8 . . ?
H4A C4 H4B 107.7 . . ?
C6 C5 C4 125.6(4) . . ?
C6 C5 Rh1 71.6(2) . . ?
C4 C5 Rh1 110.0(3) . . ?
C6 C5 H5 117.2 . . ?
C4 C5 H5 117.2 . . ?
Rh1 C5 H5 88.3 . . ?
C5 C6 C7 124.1(4) . . ?
C5 C6 Rh1 69.9(2) . . ?
C7 C6 Rh1 113.5(3) . . ?
C5 C6 H6 117.9 . . ?
C7 C6 H6 117.9 . . ?
Rh1 C6 H6 86.7 . . ?
C6 C7 C8 112.6(4) . . ?
C6 C7 H7A 109.1 . . ?
C8 C7 H7A 109.1 . . ?
C6 C7 H7B 109.1 . . ?
C8 C7 H7B 109.1 . . ?
H7A C7 H7B 107.8 . . ?
C1 C8 C7 113.4(4) . . ?
C1 C8 H8A 108.9 . . ?
C7 C8 H8A 108.9 . . ?
C1 C8 H8B 108.9 . . ?
C7 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C11 C9 C10 112.3(4) . . ?
C11 C9 P1 114.3(3) . . ?
C10 C9 P1 109.4(3) . . ?
C11 C9 H9 106.8 . . ?
C10 C9 H9 106.8 . . ?
P1 C9 H9 106.8 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C13 C12 C14 111.1(4) . . ?
C13 C12 P1 112.2(3) . . ?
C14 C12 P1 109.8(3) . . ?
C13 C12 H12 107.8 . . ?
C14 C12 H12 107.8 . . ?
P1 C12 H12 107.8 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C9 P1 C12 106.5(2) . . ?
C9 P1 Cl2 100.97(15) . . ?
C12 P1 Cl2 98.60(15) . . ?
C9 P1 Rh1 117.28(15) . . ?
C12 P1 Rh1 116.17(15) . . ?
Cl2 P1 Rh1 114.71(6) . . ?
C5 Rh1 C6 38.51(17) . . ?
C5 Rh1 C1 97.11(18) . . ?
C6 Rh1 C1 81.22(17) . . ?
C5 Rh1 C2 81.33(17) . . ?
C6 Rh1 C2 88.49(17) . . ?
C1 Rh1 C2 35.92(16) . . ?
C5 Rh1 P1 95.07(13) . . ?
C6 Rh1 P1 95.88(13) . . ?
C1 Rh1 P1 155.98(13) . . ?
C2 Rh1 P1 167.91(12) . . ?
C5 Rh1 Cl1 154.13(13) . . ?
C6 Rh1 Cl1 166.50(13) . . ?
C1 Rh1 Cl1 89.93(13) . . ?
C2 Rh1 Cl1 90.29(12) . . ?
P1 Rh1 Cl1 88.04(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C1 C2 C3 3.4(7) . . . . ?
Rh1 C1 C2 C3 102.1(4) . . . . ?
C8 C1 C2 Rh1 -98.7(5) . . . . ?
C1 C2 C3 C4 -93.9(5) . . . . ?
Rh1 C2 C3 C4 -13.2(5) . . . . ?
C2 C3 C4 C5 34.6(6) . . . . ?
C3 C4 C5 C6 42.3(6) . . . . ?
C3 C4 C5 Rh1 -39.0(5) . . . . ?
C4 C5 C6 C7 3.5(7) . . . . ?
Rh1 C5 C6 C7 105.3(4) . . . . ?
C4 C5 C6 Rh1 -101.8(4) . . . . ?
C5 C6 C7 C8 -93.8(5) . . . . ?
Rh1 C6 C7 C8 -12.9(5) . . . . ?
C2 C1 C8 C7 42.5(7) . . . . ?
Rh1 C1 C8 C7 -38.3(5) . . . . ?
C6 C7 C8 C1 35.0(6) . . . . ?
C11 C9 P1 C12 49.4(4) . . . . ?
C10 C9 P1 C12 176.3(3) . . . . ?
C11 C9 P1 Cl2 -53.1(3) . . . . ?
C10 C9 P1 Cl2 73.8(3) . . . . ?
C11 C9 P1 Rh1 -178.5(3) . . . . ?
C10 C9 P1 Rh1 -51.5(3) . . . . ?
C13 C12 P1 C9 55.5(4) . . . . ?
C14 C12 P1 C9 179.7(3) . . . . ?
C13 C12 P1 Cl2 159.7(3) . . . . ?
C14 C12 P1 Cl2 -76.1(3) . . . . ?
C13 C12 P1 Rh1 -77.2(3) . . . . ?
C14 C12 P1 Rh1 46.9(4) . . . . ?
C4 C5 Rh1 C6 122.2(4) . . . . ?
C6 C5 Rh1 C1 -66.2(3) . . . . ?
C4 C5 Rh1 C1 56.0(3) . . . . ?
C6 C5 Rh1 C2 -98.6(3) . . . . ?
C4 C5 Rh1 C2 23.6(3) . . . . ?
C6 C5 Rh1 P1 93.1(3) . . . . ?
C4 C5 Rh1 P1 -144.7(3) . . . . ?
C6 C5 Rh1 Cl1 -170.9(2) . . . . ?
C4 C5 Rh1 Cl1 -48.8(5) . . . . ?
C7 C6 Rh1 C5 -119.5(4) . . . . ?
C5 C6 Rh1 C1 113.3(3) . . . . ?
C7 C6 Rh1 C1 -6.2(3) . . . . ?
C5 C6 Rh1 C2 77.9(3) . . . . ?
C7 C6 Rh1 C2 -41.6(3) . . . . ?
C5 C6 Rh1 P1 -90.8(3) . . . . ?
C7 C6 Rh1 P1 149.7(3) . . . . ?
C5 C6 Rh1 Cl1 162.9(4) . . . . ?
C7 C6 Rh1 Cl1 43.4(7) . . . . ?
C2 C1 Rh1 C5 -64.5(3) . . . . ?
C8 C1 Rh1 C5 59.0(3) . . . . ?
C2 C1 Rh1 C6 -99.7(3) . . . . ?
C8 C1 Rh1 C6 23.8(3) . . . . ?
C8 C1 Rh1 C2 123.5(4) . . . . ?
C2 C1 Rh1 P1 175.6(2) . . . . ?
C8 C1 Rh1 P1 -60.9(5) . . . . ?
C2 C1 Rh1 Cl1 90.6(3) . . . . ?
C8 C1 Rh1 Cl1 -145.9(3) . . . . ?
C1 C2 Rh1 C5 115.1(3) . . . . ?
C3 C2 Rh1 C5 -5.7(3) . . . . ?
C1 C2 Rh1 C6 77.1(3) . . . . ?
C3 C2 Rh1 C6 -43.7(3) . . . . ?
C3 C2 Rh1 C1 -120.8(4) . . . . ?
C1 C2 Rh1 P1 -171.5(5) . . . . ?
C3 C2 Rh1 P1 67.8(7) . . . . ?
C1 C2 Rh1 Cl1 -89.5(3) . . . . ?
C3 C2 Rh1 Cl1 149.7(3) . . . . ?
C9 P1 Rh1 C5 102.4(2) . . . . ?
C12 P1 Rh1 C5 -130.0(2) . . . . ?
Cl2 P1 Rh1 C5 -15.85(14) . . . . ?
C9 P1 Rh1 C6 141.1(2) . . . . ?
C12 P1 Rh1 C6 -91.3(2) . . . . ?
Cl2 P1 Rh1 C6 22.84(14) . . . . ?
C9 P1 Rh1 C1 -137.3(3) . . . . ?
C12 P1 Rh1 C1 -9.7(4) . . . . ?
Cl2 P1 Rh1 C1 104.5(3) . . . . ?
C9 P1 Rh1 C2 30.3(6) . . . . ?
C12 P1 Rh1 C2 157.9(6) . . . . ?
Cl2 P1 Rh1 C2 -87.9(6) . . . . ?
C9 P1 Rh1 Cl1 -51.89(17) . . . . ?
C12 P1 Rh1 Cl1 75.70(17) . . . . ?
Cl2 P1 Rh1 Cl1 -170.12(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.990
_diffrn_reflns_theta_full        27.61
_diffrn_measured_fraction_theta_full 0.990
_refine_diff_density_max         0.849
_refine_diff_density_min         -0.673
_refine_diff_density_rms         0.136