# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2009

data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182
_journal_volume                  ?
_journal_page_first              ?
_journal_year                    ?

_publ_contact_author_name        'Vivian Yam'
_publ_contact_author_email       WWYAM@HKU.HK

_publ_section_title              
;
Selective ion probe for Mg2+
based on Au(I)-Au(I) interactions in tripodal alkynylgold(I) complex
with oligoether pendants
;
loop_
_publ_author_name
'Vivian Yam'
'Eddie Chung-Chin Cheng.'
'Xiaoming He.'
'Nian-Yong Zhu.'

# Attachment 'wt1665.cif'

data_wt1665
_database_code_depnum_ccdc_archive 'CCDC 719572'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C65 H55 Au3 O0.50 P3'
_chemical_formula_sum            'C65 H55 Au3 O0.50 P3'
_chemical_formula_weight         1527.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   29.200(6)
_cell_length_b                   13.992(2)
_cell_length_c                   28.986(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.25(2)
_cell_angle_gamma                90.00
_cell_volume                     11772(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    301(2)
_cell_measurement_reflns_used    0
_cell_measurement_theta_min      0
_cell_measurement_theta_max      0

_exptl_crystal_description       block
_exptl_crystal_colour            light-yellow
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5848
_exptl_absorpt_coefficient_mu    7.579
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.250168
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      301(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            67724
_diffrn_reflns_av_R_equivalents  0.0452
_diffrn_reflns_av_sigmaI/netI    0.0533
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         1.65
_diffrn_reflns_theta_max         25.68
_reflns_number_total             22320
_reflns_number_gt                15563
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0609P)^2^+46.0137P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         22320
_refine_ls_number_parameters     1073
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0830
_refine_ls_R_factor_gt           0.0498
_refine_ls_wR_factor_ref         0.1343
_refine_ls_wR_factor_gt          0.1189
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9714(3) 0.4264(7) 0.6423(3) 0.045(2) Uani 1 1 d D . .
C2 C 0.9600(3) 0.4834(7) 0.6131(3) 0.050(2) Uani 1 1 d D . .
C3 C 0.9451(2) 0.5504(4) 0.57592(19) 0.047(2) Uani 1 1 d G . .
C4 C 0.9008(2) 0.5878(5) 0.5735(2) 0.064(3) Uani 1 1 d G . .
H4 H 0.8819 0.5728 0.5963 0.077 Uiso 1 1 calc R . .
C5 C 0.8848(2) 0.6478(6) 0.5371(3) 0.086(4) Uani 1 1 d G . .
H5 H 0.8552 0.6729 0.5354 0.104 Uiso 1 1 calc R . .
C6 C 0.9131(3) 0.6704(5) 0.5030(2) 0.086(4) Uani 1 1 d G . .
H6 H 0.9024 0.7105 0.4786 0.103 Uiso 1 1 calc R . .
C7 C 0.9574(3) 0.6329(6) 0.5054(2) 0.081(4) Uani 1 1 d G . .
H7 H 0.9763 0.6480 0.4827 0.097 Uiso 1 1 calc R . .
C8 C 0.9734(2) 0.5729(5) 0.5419(2) 0.062(3) Uani 1 1 d G . .
H8 H 1.0030 0.5479 0.5435 0.074 Uiso 1 1 calc R . .
C9 C 1.0092(3) 0.1316(7) 0.5957(3) 0.051(2) Uani 1 1 d D . .
C10 C 1.0394(4) 0.1058(7) 0.5760(3) 0.054(3) Uani 1 1 d D . .
C11 C 1.0743(3) 0.0673(6) 0.5503(3) 0.055(3) Uani 1 1 d G . .
C12 C 1.0640(3) 0.0507(8) 0.5030(3) 0.121(6) Uani 1 1 d G . .
H12 H 1.0350 0.0663 0.4884 0.145 Uiso 1 1 calc R . .
C13 C 1.0969(4) 0.0106(10) 0.4776(3) 0.156(9) Uani 1 1 d G . .
H13 H 1.0899 -0.0005 0.4460 0.187 Uiso 1 1 calc R . .
C14 C 1.1401(4) -0.0127(9) 0.4995(4) 0.135(7) Uani 1 1 d G . .
H14 H 1.1622 -0.0395 0.4825 0.162 Uiso 1 1 calc R . .
C15 C 1.1505(3) 0.0039(9) 0.5468(5) 0.160(9) Uani 1 1 d G . .
H15 H 1.1795 -0.0117 0.5614 0.192 Uiso 1 1 calc R . .
C16 C 1.1176(3) 0.0440(8) 0.5721(3) 0.109(6) Uani 1 1 d G . .
H16 H 1.1246 0.0551 0.6038 0.131 Uiso 1 1 calc R . .
C17 C 0.7613(3) 0.2431(7) 0.7711(3) 0.043(2) Uani 1 1 d D . .
C18 C 0.7373(4) 0.2801(9) 0.7447(4) 0.076(4) Uani 1 1 d D . .
C19 C 0.7037(3) 0.3322(7) 0.7115(4) 0.080(4) Uani 1 1 d G . .
C20 C 0.7142(3) 0.3502(9) 0.6667(4) 0.140(8) Uani 1 1 d G . .
H20 H 0.7414 0.3268 0.6570 0.168 Uiso 1 1 calc R . .
C21 C 0.6841(5) 0.4033(10) 0.6363(4) 0.240(18) Uani 1 1 d G . .
H21 H 0.6912 0.4154 0.6063 0.288 Uiso 1 1 calc R . .
C22 C 0.6435(5) 0.4385(8) 0.6507(5) 0.166(11) Uani 1 1 d G . .
H22 H 0.6233 0.4740 0.6304 0.199 Uiso 1 1 calc R . .
C23 C 0.6330(3) 0.4205(8) 0.6955(5) 0.164(11) Uani 1 1 d G . .
H23 H 0.6058 0.4439 0.7052 0.197 Uiso 1 1 calc R . .
C24 C 0.6631(3) 0.3673(8) 0.7259(4) 0.111(5) Uani 1 1 d G . .
H24 H 0.6561 0.3553 0.7559 0.133 Uiso 1 1 calc R . .
C25 C 0.9185(3) 0.0055(6) 0.7520(3) 0.042(2) Uani 1 1 d . . .
H25A H 0.9226 -0.0074 0.7201 0.063 Uiso 1 1 calc R . .
H25B H 0.8865 -0.0008 0.7563 0.063 Uiso 1 1 calc R . .
H25C H 0.9363 -0.0391 0.7717 0.063 Uiso 1 1 calc R . .
C26 C 0.9346(3) 0.1076(6) 0.7644(3) 0.0336(19) Uani 1 1 d . . .
C27 C 0.9855(3) 0.1128(6) 0.7544(3) 0.0341(19) Uani 1 1 d . . .
H27A H 0.9876 0.0791 0.7255 0.041 Uiso 1 1 calc R . .
H27B H 1.0033 0.0761 0.7785 0.041 Uiso 1 1 calc R . .
C28 C 0.9042(3) 0.1835(6) 0.7368(3) 0.0365(19) Uani 1 1 d . . .
H28A H 0.9180 0.2455 0.7441 0.044 Uiso 1 1 calc R . .
H28B H 0.8744 0.1833 0.7487 0.044 Uiso 1 1 calc R . .
C29 C 0.9337(3) 0.1250(6) 0.8181(3) 0.0353(19) Uani 1 1 d . . .
H29A H 0.9429 0.1907 0.8245 0.042 Uiso 1 1 calc R . .
H29B H 0.9573 0.0848 0.8343 0.042 Uiso 1 1 calc R . .
C30 C 1.07579(17) 0.1925(5) 0.7495(2) 0.043(2) Uani 1 1 d G . .
C31 C 1.0866(2) 0.1108(5) 0.7256(3) 0.073(3) Uani 1 1 d G . .
H31 H 1.0632 0.0733 0.7107 0.088 Uiso 1 1 calc R . .
C32 C 1.1324(3) 0.0853(5) 0.7240(3) 0.089(4) Uani 1 1 d G . .
H32 H 1.1397 0.0307 0.7081 0.106 Uiso 1 1 calc R . .
C33 C 1.16740(18) 0.1414(7) 0.7463(3) 0.093(4) Uani 1 1 d G . .
H33 H 1.1980 0.1243 0.7453 0.111 Uiso 1 1 calc R . .
C34 C 1.1566(2) 0.2230(6) 0.7702(3) 0.095(5) Uani 1 1 d G . .
H34 H 1.1800 0.2605 0.7851 0.115 Uiso 1 1 calc R . .
C35 C 1.1108(2) 0.2486(5) 0.7718(3) 0.070(3) Uani 1 1 d G . .
H35 H 1.1035 0.3032 0.7878 0.084 Uiso 1 1 calc R . .
C36 C 1.0135(2) 0.2882(4) 0.80513(15) 0.038(2) Uani 1 1 d G . .
C37 C 1.0364(2) 0.2518(4) 0.8459(2) 0.052(2) Uani 1 1 d G . .
H37 H 1.0540 0.1966 0.8452 0.062 Uiso 1 1 calc R . .
C38 C 1.0329(2) 0.2979(5) 0.88788(16) 0.065(3) Uani 1 1 d G . .
H38 H 1.0482 0.2736 0.9152 0.077 Uiso 1 1 calc R . .
C39 C 1.0065(3) 0.3805(5) 0.88901(17) 0.075(4) Uani 1 1 d G . .
H39 H 1.0042 0.4113 0.9171 0.090 Uiso 1 1 calc R . .
C40 C 0.9837(2) 0.4169(4) 0.8482(2) 0.066(3) Uani 1 1 d G . .
H40 H 0.9661 0.4721 0.8490 0.079 Uiso 1 1 calc R . .
C41 C 0.9872(2) 0.3707(4) 0.80626(17) 0.047(2) Uani 1 1 d G . .
H41 H 0.9719 0.3951 0.7790 0.056 Uiso 1 1 calc R . .
C42 C 0.8506(2) 0.0796(4) 0.6607(2) 0.049(2) Uani 1 1 d G . .
C43 C 0.8628(2) -0.0047(5) 0.6399(2) 0.069(3) Uani 1 1 d G . .
H43 H 0.8925 -0.0122 0.6315 0.083 Uiso 1 1 calc R . .
C44 C 0.8308(3) -0.0778(4) 0.6315(3) 0.087(4) Uani 1 1 d G . .
H44 H 0.8390 -0.1343 0.6176 0.104 Uiso 1 1 calc R . .
C45 C 0.7865(3) -0.0666(6) 0.6440(3) 0.099(5) Uani 1 1 d G . .
H45 H 0.7650 -0.1156 0.6384 0.118 Uiso 1 1 calc R . .
C46 C 0.7742(2) 0.0177(7) 0.6648(3) 0.094(5) Uani 1 1 d G . .
H46 H 0.7446 0.0252 0.6732 0.112 Uiso 1 1 calc R . .
C47 C 0.8063(2) 0.0908(5) 0.6732(3) 0.070(3) Uani 1 1 d G . .
H47 H 0.7981 0.1472 0.6871 0.083 Uiso 1 1 calc R . .
C48 C 0.8631(2) 0.2839(4) 0.6563(2) 0.049(2) Uani 1 1 d G . .
C49 C 0.8547(3) 0.3012(6) 0.6089(2) 0.079(4) Uani 1 1 d G . .
H49 H 0.8654 0.2587 0.5879 0.095 Uiso 1 1 calc R . .
C50 C 0.8303(3) 0.3822(7) 0.5929(2) 0.092(5) Uani 1 1 d G . .
H50 H 0.8247 0.3937 0.5612 0.111 Uiso 1 1 calc R . .
C51 C 0.8143(3) 0.4458(5) 0.6243(3) 0.091(4) Uani 1 1 d G . .
H51 H 0.7980 0.4999 0.6136 0.109 Uiso 1 1 calc R . .
C52 C 0.8227(3) 0.4285(5) 0.6717(3) 0.098(5) Uani 1 1 d G . .
H52 H 0.8120 0.4711 0.6927 0.118 Uiso 1 1 calc R . .
C53 C 0.8471(3) 0.3476(6) 0.68769(19) 0.084(4) Uani 1 1 d G . .
H53 H 0.8527 0.3360 0.7194 0.100 Uiso 1 1 calc R . .
C54 C 0.8727(2) -0.0233(4) 0.8505(2) 0.047(2) Uani 1 1 d G . .
C55 C 0.90922(19) -0.0826(5) 0.8665(2) 0.060(3) Uani 1 1 d G . .
H55 H 0.9382 -0.0568 0.8751 0.073 Uiso 1 1 calc R . .
C56 C 0.9023(3) -0.1806(5) 0.8697(3) 0.078(4) Uani 1 1 d G . .
H56 H 0.9267 -0.2203 0.8804 0.094 Uiso 1 1 calc R . .
C57 C 0.8590(4) -0.2192(4) 0.8569(3) 0.089(4) Uani 1 1 d G . .
H57 H 0.8544 -0.2848 0.8590 0.106 Uiso 1 1 calc R . .
C58 C 0.8225(3) -0.1599(6) 0.8408(3) 0.097(5) Uani 1 1 d G . .
H58 H 0.7935 -0.1857 0.8322 0.116 Uiso 1 1 calc R . .
C59 C 0.8294(2) -0.0619(5) 0.8376(3) 0.066(3) Uani 1 1 d G . .
H59 H 0.8049 -0.0222 0.8269 0.079 Uiso 1 1 calc R . .
C60 C 0.8961(2) 0.1502(5) 0.90334(17) 0.046(2) Uani 1 1 d G . .
C61 C 0.8956(3) 0.0921(4) 0.9422(2) 0.076(4) Uani 1 1 d G . .
H61 H 0.8872 0.0282 0.9386 0.092 Uiso 1 1 calc R . .
C62 C 0.9075(3) 0.1295(6) 0.98625(18) 0.092(5) Uani 1 1 d G . .
H62 H 0.9071 0.0906 1.0122 0.110 Uiso 1 1 calc R . .
C63 C 0.9200(3) 0.2251(7) 0.99152(19) 0.087(4) Uani 1 1 d G . .
H63 H 0.9280 0.2501 1.0210 0.105 Uiso 1 1 calc R . .
C64 C 0.9206(3) 0.2832(5) 0.9527(3) 0.085(4) Uani 1 1 d G . .
H64 H 0.9290 0.3471 0.9562 0.102 Uiso 1 1 calc R . .
C65 C 0.9087(3) 0.2458(5) 0.9086(2) 0.067(3) Uani 1 1 d G . .
H65 H 0.9091 0.2847 0.8826 0.080 Uiso 1 1 calc R . .
C66 C 0.4572(4) 0.4044(8) 0.6434(4) 0.058(3) Uani 1 1 d D . .
C67 C 0.4436(4) 0.3490(8) 0.6159(4) 0.069(3) Uani 1 1 d D . .
C68 C 0.4222(3) 0.2845(6) 0.5793(3) 0.072(3) Uani 1 1 d G . .
C69 C 0.4500(3) 0.2243(7) 0.5563(3) 0.094(4) Uani 1 1 d G . .
H69 H 0.4818 0.2253 0.5637 0.113 Uiso 1 1 calc R . .
C70 C 0.4302(5) 0.1625(7) 0.5222(3) 0.138(8) Uani 1 1 d G . .
H70 H 0.4488 0.1222 0.5068 0.166 Uiso 1 1 calc R . .
C71 C 0.3827(5) 0.1610(7) 0.5111(3) 0.154(10) Uani 1 1 d G . .
H71 H 0.3695 0.1197 0.4883 0.185 Uiso 1 1 calc R . .
C72 C 0.3549(3) 0.2213(9) 0.5341(4) 0.128(7) Uani 1 1 d G . .
H72 H 0.3231 0.2203 0.5267 0.153 Uiso 1 1 calc R . .
C73 C 0.3747(3) 0.2831(7) 0.5682(3) 0.092(4) Uani 1 1 d G . .
H73 H 0.3561 0.3234 0.5836 0.110 Uiso 1 1 calc R . .
C74 C 0.3919(3) 0.6711(8) 0.6155(4) 0.064(3) Uani 1 1 d D . .
C75 C 0.3539(4) 0.6805(8) 0.6018(5) 0.074(3) Uani 1 1 d D . .
C76 C 0.3056(2) 0.6904(8) 0.5829(4) 0.082(4) Uani 1 1 d G . .
C77 C 0.2919(4) 0.6565(10) 0.5384(4) 0.197(12) Uani 1 1 d G . .
H77 H 0.3128 0.6239 0.5221 0.236 Uiso 1 1 calc R . .
C78 C 0.2471(4) 0.6713(12) 0.5184(4) 0.29(2) Uani 1 1 d G . .
H78 H 0.2379 0.6486 0.4886 0.351 Uiso 1 1 calc R . .
C79 C 0.2159(3) 0.7200(11) 0.5428(5) 0.194(13) Uani 1 1 d G . .
H79 H 0.1859 0.7299 0.5293 0.233 Uiso 1 1 calc R . .
C80 C 0.2296(3) 0.7539(8) 0.5872(5) 0.129(7) Uani 1 1 d G . .
H80 H 0.2087 0.7865 0.6035 0.155 Uiso 1 1 calc R . .
C81 C 0.2745(4) 0.7391(7) 0.6073(3) 0.094(4) Uani 1 1 d G . .
H81 H 0.2836 0.7618 0.6370 0.113 Uiso 1 1 calc R . .
C82 C 0.7235(4) 0.6889(8) 0.6234(4) 0.067(3) Uani 1 1 d D . .
C83 C 0.7341(4) 0.6866(9) 0.5861(4) 0.068(3) Uani 1 1 d D . .
C84 C 0.7478(3) 0.6836(9) 0.5425(3) 0.081(4) Uani 1 1 d G . .
C85 C 0.7672(4) 0.7626(8) 0.5231(4) 0.119(6) Uani 1 1 d G . .
H85 H 0.7715 0.8190 0.5400 0.143 Uiso 1 1 calc R . .
C86 C 0.7803(4) 0.7573(11) 0.4785(5) 0.183(13) Uani 1 1 d G . .
H86 H 0.7933 0.8101 0.4655 0.219 Uiso 1 1 calc R . .
C87 C 0.7739(5) 0.6729(14) 0.4533(3) 0.197(14) Uani 1 1 d G . .
H87 H 0.7826 0.6693 0.4234 0.236 Uiso 1 1 calc R . .
C88 C 0.7544(5) 0.5939(11) 0.4727(4) 0.196(12) Uani 1 1 d G . .
H88 H 0.7501 0.5374 0.4558 0.236 Uiso 1 1 calc R . .
C89 C 0.7414(4) 0.5992(8) 0.5173(4) 0.129(6) Uani 1 1 d G . .
H89 H 0.7283 0.5464 0.5303 0.155 Uiso 1 1 calc R . .
C90 C 0.5782(3) 0.8295(7) 0.7174(4) 0.053(2) Uani 1 1 d . . .
H90A H 0.6063 0.8435 0.7044 0.079 Uiso 1 1 calc R . .
H90B H 0.5787 0.8599 0.7471 0.079 Uiso 1 1 calc R . .
H90C H 0.5525 0.8529 0.6971 0.079 Uiso 1 1 calc R . .
C91 C 0.5737(3) 0.7217(7) 0.7232(3) 0.044(2) Uani 1 1 d . . .
C92 C 0.5262(3) 0.7107(7) 0.7430(3) 0.045(2) Uani 1 1 d . . .
H92A H 0.5037 0.7434 0.7215 0.054 Uiso 1 1 calc R . .
H92B H 0.5285 0.7468 0.7718 0.054 Uiso 1 1 calc R . .
C93 C 0.5768(3) 0.6638(7) 0.6792(3) 0.047(2) Uani 1 1 d . . .
H93A H 0.5720 0.5973 0.6868 0.057 Uiso 1 1 calc R . .
H93B H 0.6082 0.6691 0.6715 0.057 Uiso 1 1 calc R . .
C94 C 0.6112(3) 0.6847(7) 0.7607(3) 0.045(2) Uani 1 1 d . . .
H94A H 0.6093 0.6155 0.7607 0.054 Uiso 1 1 calc R . .
H94B H 0.6032 0.7064 0.7905 0.054 Uiso 1 1 calc R . .
C95 C 0.5400(2) 0.5303(5) 0.7976(2) 0.057(3) Uani 1 1 d G . .
C96 C 0.5530(3) 0.4387(5) 0.7858(2) 0.071(3) Uani 1 1 d G . .
H96 H 0.5406 0.4115 0.7579 0.085 Uiso 1 1 calc R . .
C97 C 0.5847(3) 0.3880(5) 0.8156(3) 0.089(4) Uani 1 1 d G . .
H97 H 0.5935 0.3267 0.8076 0.107 Uiso 1 1 calc R . .
C98 C 0.6034(3) 0.4288(7) 0.8571(3) 0.096(5) Uani 1 1 d G . .
H98 H 0.6246 0.3948 0.8771 0.115 Uiso 1 1 calc R . .
C99 C 0.5903(3) 0.5203(7) 0.8690(2) 0.092(4) Uani 1 1 d G . .
H99 H 0.6027 0.5476 0.8968 0.110 Uiso 1 1 calc R . .
C100 C 0.5586(3) 0.5711(5) 0.8392(2) 0.073(3) Uani 1 1 d G . .
H100 H 0.5498 0.6323 0.8471 0.088 Uiso 1 1 calc R . .
C101 C 0.4534(2) 0.6323(6) 0.7861(2) 0.057(3) Uani 1 1 d G . .
C102 C 0.4589(3) 0.6978(6) 0.8224(3) 0.078(4) Uani 1 1 d G . .
H102 H 0.4875 0.7262 0.8305 0.093 Uiso 1 1 calc R . .
C103 C 0.4218(4) 0.7208(6) 0.8465(3) 0.099(5) Uani 1 1 d G . .
H103 H 0.4255 0.7646 0.8707 0.119 Uiso 1 1 calc R . .
C104 C 0.3791(3) 0.6784(8) 0.8343(3) 0.109(5) Uani 1 1 d G . .
H104 H 0.3543 0.6938 0.8504 0.131 Uiso 1 1 calc R . .
C105 C 0.3736(2) 0.6129(7) 0.7980(4) 0.110(5) Uani 1 1 d G . .
H105 H 0.3451 0.5845 0.7899 0.131 Uiso 1 1 calc R . .
C106 C 0.4108(3) 0.5899(6) 0.7740(3) 0.075(3) Uani 1 1 d G . .
H106 H 0.4071 0.5461 0.7497 0.090 Uiso 1 1 calc R . .
C107 C 0.5547(3) 0.8106(5) 0.6082(3) 0.076(4) Uani 1 1 d G . .
C108 C 0.5196(3) 0.8758(7) 0.5958(3) 0.102(5) Uani 1 1 d G . .
H108 H 0.4889 0.8569 0.5949 0.122 Uiso 1 1 calc R . .
C109 C 0.5302(5) 0.9694(6) 0.5849(4) 0.164(11) Uani 1 1 d G . .
H109 H 0.5067 1.0130 0.5766 0.197 Uiso 1 1 calc R . .
C110 C 0.5759(6) 0.9977(5) 0.5863(4) 0.172(13) Uani 1 1 d G . .
H110 H 0.5831 1.0603 0.5789 0.206 Uiso 1 1 calc R . .
C111 C 0.6111(4) 0.9325(9) 0.5986(3) 0.130(8) Uani 1 1 d G . .
H111 H 0.6417 0.9515 0.5995 0.156 Uiso 1 1 calc R . .
C112 C 0.6004(3) 0.8390(8) 0.6096(3) 0.095(5) Uani 1 1 d G . .
H112 H 0.6239 0.7953 0.6178 0.114 Uiso 1 1 calc R . .
C113 C 0.5584(3) 0.6077(6) 0.5833(3) 0.057(3) Uani 1 1 d G . .
C114 C 0.5971(3) 0.6252(6) 0.5606(4) 0.107(5) Uani 1 1 d G . .
H114 H 0.6146 0.6800 0.5675 0.128 Uiso 1 1 calc R . .
C115 C 0.6097(3) 0.5609(8) 0.5277(4) 0.115(6) Uani 1 1 d G . .
H115 H 0.6356 0.5726 0.5125 0.139 Uiso 1 1 calc R . .
C116 C 0.5836(4) 0.4791(8) 0.5175(3) 0.113(6) Uani 1 1 d G . .
H116 H 0.5920 0.4361 0.4954 0.136 Uiso 1 1 calc R . .
C117 C 0.5449(4) 0.4616(7) 0.5402(4) 0.161(9) Uani 1 1 d G . .
H117 H 0.5274 0.4068 0.5333 0.193 Uiso 1 1 calc R . .
C118 C 0.5323(3) 0.5259(7) 0.5731(4) 0.115(6) Uani 1 1 d G . .
H118 H 0.5064 0.5142 0.5883 0.138 Uiso 1 1 calc R . .
C119 C 0.6812(2) 0.8383(4) 0.7794(2) 0.055(3) Uani 1 1 d G . .
C120 C 0.7135(2) 0.8952(5) 0.7607(2) 0.061(3) Uani 1 1 d G . .
H120 H 0.7303 0.8708 0.7379 0.073 Uiso 1 1 calc R . .
C121 C 0.7208(2) 0.9885(5) 0.7762(3) 0.077(4) Uani 1 1 d G . .
H121 H 0.7425 1.0266 0.7637 0.092 Uiso 1 1 calc R . .
C122 C 0.6958(3) 1.0250(4) 0.8103(3) 0.084(4) Uani 1 1 d G . .
H122 H 0.7007 1.0874 0.8206 0.101 Uiso 1 1 calc R . .
C123 C 0.6634(3) 0.9681(5) 0.8290(2) 0.074(3) Uani 1 1 d G . .
H123 H 0.6466 0.9924 0.8518 0.088 Uiso 1 1 calc R . .
C124 C 0.6561(2) 0.8747(5) 0.8135(2) 0.059(3) Uani 1 1 d G . .
H124 H 0.6344 0.8366 0.8260 0.071 Uiso 1 1 calc R . .
C125 C 0.7011(3) 0.6397(5) 0.8011(2) 0.058(3) Uani 1 1 d G . .
C126 C 0.7174(3) 0.5524(6) 0.7869(3) 0.083(4) Uani 1 1 d G . .
H126 H 0.7160 0.5381 0.7555 0.100 Uiso 1 1 calc R . .
C127 C 0.7358(3) 0.4864(5) 0.8197(4) 0.110(5) Uani 1 1 d G . .
H127 H 0.7466 0.4280 0.8102 0.131 Uiso 1 1 calc R . .
C128 C 0.7378(4) 0.5078(7) 0.8667(3) 0.128(7) Uani 1 1 d G . .
H128 H 0.7501 0.4636 0.8886 0.153 Uiso 1 1 calc R . .
C129 C 0.7216(4) 0.5951(8) 0.8809(2) 0.136(8) Uani 1 1 d G . .
H129 H 0.7230 0.6094 0.9124 0.164 Uiso 1 1 calc R . .
C130 C 0.7032(4) 0.6611(6) 0.8482(3) 0.120(6) Uani 1 1 d G . .
H130 H 0.6923 0.7195 0.8577 0.144 Uiso 1 1 calc R . .
P1 P 1.01579(8) 0.22782(16) 0.75008(8) 0.0365(5) Uani 1 1 d . . .
P2 P 0.89384(8) 0.17404(17) 0.67319(8) 0.0403(5) Uani 1 1 d . . .
P3 P 0.88032(8) 0.10449(17) 0.84479(8) 0.0388(5) Uani 1 1 d . . .
P4 P 0.50093(9) 0.59447(19) 0.75549(9) 0.0483(6) Uani 1 1 d . . .
P5 P 0.53828(9) 0.6903(2) 0.62547(9) 0.0522(7) Uani 1 1 d . . .
P6 P 0.67263(9) 0.7173(2) 0.75717(9) 0.0512(6) Uani 1 1 d . . .
Au1 Au 0.990806(12) 0.32771(3) 0.690164(12) 0.04099(10) Uani 1 1 d . . .
Au2 Au 0.956310(13) 0.15596(3) 0.633306(12) 0.04669(11) Uani 1 1 d . . .
Au3 Au 0.817327(12) 0.17793(3) 0.807580(13) 0.04589(10) Uani 1 1 d . . .
Au4 Au 0.478084(14) 0.49920(3) 0.693408(14) 0.05432(12) Uani 1 1 d . . .
Au5 Au 0.461072(14) 0.67409(3) 0.626337(15) 0.06080(13) Uani 1 1 d . . .
Au6 Au 0.699532(15) 0.69937(3) 0.686833(16) 0.06114(13) Uani 1 1 d . . .
O1 O 0.7206(11) 0.029(2) 0.5175(11) 0.174(11) Uiso 0.50 1 d P . .
O2 O 0.3491(12) 0.885(3) 0.4995(12) 0.211(14) Uiso 0.50 1 d P . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.046(5) 0.044(6) 0.043(5) 0.019(5) -0.002(4) 0.000(4)
C2 0.053(6) 0.051(6) 0.045(5) 0.001(5) 0.001(4) -0.012(5)
C3 0.060(6) 0.035(5) 0.044(5) 0.001(4) -0.010(5) -0.013(5)
C4 0.062(7) 0.059(7) 0.068(7) 0.016(6) -0.003(6) -0.006(6)
C5 0.083(9) 0.081(9) 0.088(10) 0.018(8) -0.025(8) 0.010(7)
C6 0.120(12) 0.067(9) 0.065(8) 0.027(7) -0.012(8) -0.007(8)
C7 0.126(12) 0.065(8) 0.049(7) 0.014(6) -0.002(7) -0.024(8)
C8 0.070(7) 0.068(8) 0.046(6) 0.007(5) 0.003(5) 0.001(6)
C9 0.055(6) 0.050(6) 0.048(6) -0.007(5) 0.010(5) -0.005(5)
C10 0.074(7) 0.042(6) 0.046(6) -0.001(5) 0.006(5) -0.008(5)
C11 0.073(7) 0.049(6) 0.045(6) 0.001(5) 0.018(5) -0.001(5)
C12 0.106(12) 0.199(19) 0.063(9) 0.008(10) 0.033(8) 0.050(12)
C13 0.19(2) 0.23(2) 0.060(9) 0.013(12) 0.050(12) 0.079(18)
C14 0.067(10) 0.162(18) 0.18(2) -0.027(16) 0.047(12) 0.005(11)
C15 0.088(13) 0.19(2) 0.19(2) -0.080(18) -0.045(14) 0.029(13)
C16 0.073(9) 0.138(14) 0.116(12) -0.062(11) 0.008(9) 0.003(9)
C17 0.054(6) 0.042(6) 0.032(5) 0.013(4) -0.007(4) 0.015(4)
C18 0.068(8) 0.067(8) 0.093(10) -0.009(7) 0.020(7) -0.018(7)
C19 0.065(8) 0.065(8) 0.104(10) 0.008(7) -0.023(7) 0.013(6)
C20 0.100(13) 0.162(18) 0.149(17) 0.071(14) -0.030(12) -0.033(12)
C21 0.144(19) 0.20(3) 0.35(4) 0.19(3) -0.11(2) -0.031(18)
C22 0.19(2) 0.081(13) 0.20(2) 0.026(15) -0.09(2) 0.016(14)
C23 0.160(18) 0.135(17) 0.17(2) -0.043(15) -0.090(16) 0.105(15)
C24 0.089(11) 0.093(11) 0.144(15) -0.010(10) -0.011(10) 0.031(9)
C25 0.061(6) 0.032(5) 0.034(5) 0.006(4) 0.001(4) -0.002(4)
C26 0.044(5) 0.029(5) 0.027(4) 0.001(3) 0.003(4) -0.001(4)
C27 0.047(5) 0.030(5) 0.027(4) -0.003(4) 0.010(4) 0.006(4)
C28 0.041(5) 0.038(5) 0.030(4) -0.001(4) 0.000(4) 0.001(4)
C29 0.038(5) 0.037(5) 0.031(4) 0.002(4) 0.000(4) -0.001(4)
C30 0.044(5) 0.044(6) 0.042(5) 0.008(4) 0.000(4) 0.000(4)
C31 0.045(6) 0.075(9) 0.102(10) -0.011(7) 0.019(6) 0.001(6)
C32 0.080(9) 0.087(10) 0.104(11) -0.009(8) 0.031(8) 0.012(8)
C33 0.045(7) 0.121(13) 0.115(12) 0.007(10) 0.022(7) 0.013(8)
C34 0.045(7) 0.127(13) 0.113(12) -0.002(10) 0.007(7) -0.010(8)
C35 0.057(7) 0.066(8) 0.086(9) -0.006(6) 0.000(6) -0.001(6)
C36 0.051(5) 0.033(5) 0.030(4) -0.005(4) 0.003(4) -0.005(4)
C37 0.063(6) 0.055(6) 0.037(5) -0.002(5) -0.002(5) 0.001(5)
C38 0.091(9) 0.056(7) 0.044(6) 0.001(5) -0.004(6) -0.009(6)
C39 0.127(11) 0.052(7) 0.046(6) -0.009(5) 0.007(7) -0.004(7)
C40 0.097(9) 0.041(6) 0.061(7) 0.000(5) 0.016(6) 0.019(6)
C41 0.060(6) 0.041(6) 0.039(5) -0.004(4) 0.002(4) 0.006(5)
C42 0.054(6) 0.056(7) 0.037(5) 0.002(5) 0.001(4) -0.021(5)
C43 0.091(9) 0.068(8) 0.046(6) -0.009(6) -0.002(6) -0.022(7)
C44 0.134(13) 0.067(9) 0.057(7) -0.012(6) -0.005(8) -0.038(9)
C45 0.121(13) 0.083(11) 0.086(10) -0.003(8) -0.012(9) -0.062(10)
C46 0.066(8) 0.116(13) 0.097(10) 0.009(9) 0.003(7) -0.041(8)
C47 0.071(8) 0.071(8) 0.066(7) 0.002(6) 0.007(6) -0.026(6)
C48 0.039(5) 0.052(6) 0.052(6) 0.008(5) -0.003(4) -0.008(4)
C49 0.098(10) 0.095(10) 0.043(6) 0.020(6) -0.006(6) 0.007(8)
C50 0.089(10) 0.113(12) 0.071(9) 0.053(9) -0.009(7) 0.010(9)
C51 0.080(9) 0.084(10) 0.103(11) 0.049(9) -0.014(8) 0.013(8)
C52 0.128(12) 0.065(9) 0.098(11) 0.012(8) -0.001(9) 0.041(8)
C53 0.103(10) 0.073(9) 0.073(8) 0.005(7) -0.002(7) 0.028(8)
C54 0.061(6) 0.038(5) 0.042(5) 0.013(4) 0.015(5) 0.001(5)
C55 0.066(7) 0.060(7) 0.058(7) 0.014(5) 0.018(5) 0.023(6)
C56 0.110(11) 0.060(8) 0.071(8) 0.030(6) 0.038(8) 0.034(7)
C57 0.142(14) 0.050(8) 0.078(9) 0.011(7) 0.037(9) -0.011(9)
C58 0.101(11) 0.069(10) 0.123(13) 0.025(9) 0.025(9) -0.017(8)
C59 0.059(7) 0.055(7) 0.084(8) 0.017(6) 0.008(6) -0.004(5)
C60 0.045(5) 0.063(7) 0.032(5) 0.004(5) 0.017(4) 0.018(5)
C61 0.096(9) 0.084(9) 0.050(7) 0.013(6) 0.013(6) 0.044(7)
C62 0.110(11) 0.130(13) 0.037(6) 0.006(7) 0.019(6) 0.058(10)
C63 0.084(9) 0.118(12) 0.058(8) -0.032(8) -0.001(7) 0.013(9)
C64 0.100(10) 0.101(11) 0.057(8) -0.012(7) 0.022(7) -0.013(8)
C65 0.089(8) 0.070(8) 0.044(6) -0.007(6) 0.015(6) -0.009(7)
C66 0.064(7) 0.056(7) 0.054(6) -0.009(6) 0.009(5) -0.003(5)
C67 0.093(9) 0.047(7) 0.069(8) 0.007(6) 0.022(7) -0.010(6)
C68 0.095(10) 0.078(9) 0.042(6) 0.002(6) -0.001(6) -0.005(7)
C69 0.123(12) 0.106(11) 0.056(8) -0.022(8) 0.022(8) -0.016(9)
C70 0.26(3) 0.099(13) 0.054(9) -0.003(9) 0.029(12) -0.044(15)
C71 0.24(3) 0.17(2) 0.046(9) -0.016(10) -0.013(13) -0.088(19)
C72 0.155(17) 0.158(18) 0.064(10) 0.003(11) -0.017(10) -0.068(14)
C73 0.076(9) 0.133(13) 0.062(8) 0.012(8) -0.012(7) -0.020(8)
C74 0.043(6) 0.063(8) 0.081(8) 0.004(6) -0.015(5) 0.002(5)
C75 0.066(8) 0.060(8) 0.099(10) 0.000(7) 0.022(7) -0.009(6)
C76 0.047(7) 0.089(10) 0.109(11) 0.004(8) 0.006(7) -0.005(6)
C77 0.081(13) 0.27(3) 0.22(3) -0.11(2) -0.059(14) 0.018(15)
C78 0.101(18) 0.39(5) 0.36(5) -0.19(4) -0.09(2) 0.01(2)
C79 0.029(8) 0.19(2) 0.35(4) -0.04(2) -0.013(15) -0.022(11)
C80 0.054(9) 0.137(16) 0.20(2) 0.075(15) 0.020(11) 0.007(9)
C81 0.082(10) 0.088(10) 0.114(12) 0.026(9) 0.021(9) 0.000(8)
C82 0.053(6) 0.068(8) 0.080(9) -0.007(6) 0.008(6) -0.005(6)
C83 0.070(8) 0.082(9) 0.054(7) 0.001(6) 0.020(6) 0.007(6)
C84 0.069(8) 0.100(11) 0.074(9) 0.014(8) 0.009(7) 0.007(7)
C85 0.093(11) 0.178(18) 0.083(11) 0.052(12) -0.007(9) 0.001(11)
C86 0.098(13) 0.31(4) 0.142(19) 0.15(2) 0.002(14) 0.020(18)
C87 0.23(3) 0.29(4) 0.075(14) 0.006(19) 0.035(16) 0.03(3)
C88 0.28(3) 0.22(3) 0.088(15) -0.006(17) 0.043(18) 0.00(3)
C89 0.164(17) 0.148(17) 0.078(11) -0.018(11) 0.031(11) 0.011(14)
C90 0.054(6) 0.042(6) 0.061(6) -0.003(5) 0.004(5) -0.007(5)
C91 0.037(5) 0.045(6) 0.049(5) 0.005(4) -0.002(4) -0.004(4)
C92 0.043(5) 0.045(6) 0.046(5) 0.001(4) 0.002(4) -0.001(4)
C93 0.047(5) 0.045(6) 0.050(6) 0.007(5) 0.002(4) -0.005(4)
C94 0.043(5) 0.044(6) 0.047(5) -0.007(4) 0.001(4) -0.009(4)
C95 0.058(6) 0.048(6) 0.066(7) 0.009(5) 0.016(5) -0.007(5)
C96 0.066(7) 0.056(8) 0.088(9) 0.010(7) 0.001(6) 0.002(6)
C97 0.096(10) 0.072(9) 0.096(11) 0.002(8) -0.001(8) 0.004(8)
C98 0.083(10) 0.090(11) 0.114(13) 0.046(10) 0.007(9) 0.014(8)
C99 0.079(9) 0.121(13) 0.072(9) 0.024(9) -0.010(7) -0.008(9)
C100 0.097(9) 0.081(9) 0.040(6) 0.008(6) 0.006(6) 0.003(7)
C101 0.060(7) 0.061(7) 0.049(6) 0.001(5) 0.004(5) -0.004(5)
C102 0.083(9) 0.080(9) 0.074(8) -0.017(7) 0.025(7) -0.020(7)
C103 0.096(11) 0.122(13) 0.085(10) -0.024(9) 0.033(9) 0.013(10)
C104 0.103(12) 0.107(13) 0.126(14) 0.002(10) 0.059(11) 0.016(10)
C105 0.059(8) 0.124(14) 0.149(15) -0.020(12) 0.027(9) -0.007(8)
C106 0.043(6) 0.080(9) 0.101(10) -0.013(7) 0.005(6) -0.002(6)
C107 0.115(11) 0.063(8) 0.052(7) 0.012(6) 0.011(7) -0.010(8)
C108 0.151(14) 0.067(9) 0.098(11) 0.020(8) 0.059(10) 0.028(9)
C109 0.31(3) 0.051(10) 0.157(18) 0.029(11) 0.12(2) 0.025(14)
C110 0.36(4) 0.060(11) 0.117(15) 0.004(10) 0.11(2) -0.045(17)
C111 0.23(2) 0.097(13) 0.073(10) -0.006(9) 0.036(12) -0.089(14)
C112 0.116(12) 0.098(11) 0.073(9) 0.001(8) 0.017(8) -0.041(9)
C113 0.062(7) 0.062(7) 0.045(6) 0.008(5) -0.007(5) 0.003(5)
C114 0.111(12) 0.079(10) 0.140(14) 0.013(10) 0.061(11) -0.001(9)
C115 0.152(16) 0.081(11) 0.127(14) -0.002(10) 0.079(12) 0.011(11)
C116 0.115(13) 0.149(17) 0.079(10) -0.038(10) 0.025(9) 0.015(12)
C117 0.130(15) 0.20(2) 0.160(18) -0.131(17) 0.028(13) -0.014(14)
C118 0.090(10) 0.130(14) 0.133(14) -0.059(11) 0.045(10) -0.031(10)
C119 0.049(6) 0.055(7) 0.062(6) -0.013(5) 0.006(5) -0.004(5)
C120 0.046(6) 0.055(7) 0.079(8) -0.010(6) -0.005(5) -0.014(5)
C121 0.064(8) 0.063(8) 0.102(10) 0.000(7) 0.002(7) -0.018(6)
C122 0.087(9) 0.054(8) 0.109(11) -0.020(7) -0.004(8) 0.000(7)
C123 0.073(8) 0.073(9) 0.076(8) -0.028(7) 0.009(6) 0.002(7)
C124 0.047(6) 0.062(7) 0.067(7) -0.014(6) -0.005(5) -0.004(5)
C125 0.042(5) 0.061(7) 0.071(7) -0.016(6) 0.000(5) -0.003(5)
C126 0.069(8) 0.073(9) 0.105(10) -0.006(8) -0.002(7) 0.011(7)
C127 0.117(13) 0.078(11) 0.125(14) -0.028(10) -0.025(11) 0.024(9)
C128 0.154(16) 0.072(11) 0.140(16) 0.001(10) -0.064(13) 0.028(10)
C129 0.205(19) 0.109(13) 0.076(10) -0.024(9) -0.071(11) 0.053(13)
C130 0.191(18) 0.087(11) 0.071(9) -0.022(8) -0.038(10) 0.040(11)
P1 0.0414(12) 0.0324(13) 0.0357(12) 0.0011(10) 0.0047(10) -0.0017(10)
P2 0.0483(13) 0.0431(14) 0.0291(11) 0.0008(10) 0.0022(10) -0.0070(11)
P3 0.0397(12) 0.0413(14) 0.0363(12) 0.0082(10) 0.0080(10) 0.0068(10)
P4 0.0470(14) 0.0498(16) 0.0487(15) -0.0022(12) 0.0076(11) -0.0064(12)
P5 0.0537(15) 0.0548(17) 0.0470(15) 0.0067(12) 0.0006(12) -0.0025(13)
P6 0.0417(14) 0.0565(17) 0.0554(16) -0.0140(13) 0.0052(12) -0.0052(12)
Au1 0.0482(2) 0.0360(2) 0.03790(19) 0.00633(15) 0.00065(15) -0.00472(15)
Au2 0.0591(2) 0.0470(2) 0.03500(19) -0.00333(16) 0.00970(16) -0.00664(18)
Au3 0.0435(2) 0.0472(2) 0.0468(2) 0.00560(17) 0.00420(16) 0.01081(17)
Au4 0.0606(2) 0.0515(3) 0.0507(2) -0.00404(19) 0.00553(18) -0.00823(19)
Au5 0.0514(2) 0.0677(3) 0.0612(3) 0.0068(2) -0.00356(19) 0.0045(2)
Au6 0.0525(2) 0.0678(3) 0.0653(3) -0.0171(2) 0.0160(2) -0.0067(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.183(9) . ?
C1 Au1 1.996(8) . ?
C2 C3 1.459(10) . ?
C3 C4 1.3900 . ?
C3 C8 1.3900 . ?
C4 C5 1.3900 . ?
C4 H4 0.9300 . ?
C5 C6 1.3900 . ?
C5 H5 0.9300 . ?
C6 C7 1.3900 . ?
C6 H6 0.9300 . ?
C7 C8 1.3900 . ?
C7 H7 0.9300 . ?
C8 H8 0.9300 . ?
C9 C10 1.160(9) . ?
C9 Au2 2.014(10) . ?
C10 C11 1.432(12) . ?
C11 C12 1.3900 . ?
C11 C16 1.3900 . ?
C12 C13 1.3900 . ?
C12 H12 0.9300 . ?
C13 C14 1.3900 . ?
C13 H13 0.9300 . ?
C14 C15 1.3900 . ?
C14 H14 0.9300 . ?
C15 C16 1.3900 . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 C18 1.110(10) . ?
C17 Au3 2.060(9) . ?
C18 C19 1.487(13) . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 H22 0.9300 . ?
C23 C24 1.3900 . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.534(11) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 C27 1.547(11) . ?
C26 C28 1.550(11) . ?
C26 C29 1.581(11) . ?
C27 P1 1.846(8) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 P2 1.841(8) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 P3 1.837(8) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 C31 1.3900 . ?
C30 C35 1.3900 . ?
C30 P1 1.822(5) . ?
C31 C32 1.3900 . ?
C31 H31 0.9300 . ?
C32 C33 1.3900 . ?
C32 H32 0.9300 . ?
C33 C34 1.3900 . ?
C33 H33 0.9300 . ?
C34 C35 1.3900 . ?
C34 H34 0.9300 . ?
C35 H35 0.9300 . ?
C36 C37 1.3900 . ?
C36 C41 1.3900 . ?
C36 P1 1.813(5) . ?
C37 C38 1.3900 . ?
C37 H37 0.9300 . ?
C38 C39 1.3900 . ?
C38 H38 0.9300 . ?
C39 C40 1.3900 . ?
C39 H39 0.9300 . ?
C40 C41 1.3900 . ?
C40 H40 0.9300 . ?
C41 H41 0.9300 . ?
C42 C43 1.3900 . ?
C42 C47 1.3900 . ?
C42 P2 1.837(5) . ?
C43 C44 1.3900 . ?
C43 H43 0.9300 . ?
C44 C45 1.3900 . ?
C44 H44 0.9300 . ?
C45 C46 1.3900 . ?
C45 H45 0.9300 . ?
C46 C47 1.3900 . ?
C46 H46 0.9300 . ?
C47 H47 0.9300 . ?
C48 C49 1.3900 . ?
C48 C53 1.3900 . ?
C48 P2 1.821(6) . ?
C49 C50 1.3900 . ?
C49 H49 0.9300 . ?
C50 C51 1.3900 . ?
C50 H50 0.9300 . ?
C51 C52 1.3900 . ?
C51 H51 0.9300 . ?
C52 C53 1.3900 . ?
C52 H52 0.9300 . ?
C53 H53 0.9300 . ?
C54 C55 1.3900 . ?
C54 C59 1.3900 . ?
C54 P3 1.811(6) . ?
C55 C56 1.3900 . ?
C55 H55 0.9300 . ?
C56 C57 1.3900 . ?
C56 H56 0.9300 . ?
C57 C58 1.3900 . ?
C57 H57 0.9300 . ?
C58 C59 1.3900 . ?
C58 H58 0.9300 . ?
C59 H59 0.9300 . ?
C60 C61 1.3900 . ?
C60 C65 1.3900 . ?
C60 P3 1.825(5) . ?
C61 C62 1.3900 . ?
C61 H61 0.9300 . ?
C62 C63 1.3900 . ?
C62 H62 0.9300 . ?
C63 C64 1.3900 . ?
C63 H63 0.9300 . ?
C64 C65 1.3900 . ?
C64 H64 0.9300 . ?
C65 H65 0.9300 . ?
C66 C67 1.152(10) . ?
C66 Au4 2.010(10) . ?
C67 C68 1.477(13) . ?
C68 C69 1.3900 . ?
C68 C73 1.3900 . ?
C69 C70 1.3900 . ?
C69 H69 0.9300 . ?
C70 C71 1.3900 . ?
C70 H70 0.9300 . ?
C71 C72 1.3900 . ?
C71 H71 0.9300 . ?
C72 C73 1.3900 . ?
C72 H72 0.9300 . ?
C73 H73 0.9300 . ?
C74 C75 1.146(10) . ?
C74 Au5 2.009(10) . ?
C75 C76 1.462(13) . ?
C76 C77 1.3900 . ?
C76 C81 1.3900 . ?
C77 C78 1.3900 . ?
C77 H77 0.9300 . ?
C78 C79 1.3900 . ?
C78 H78 0.9300 . ?
C79 C80 1.3900 . ?
C79 H79 0.9300 . ?
C80 C81 1.3900 . ?
C80 H80 0.9300 . ?
C81 H81 0.9300 . ?
C82 C83 1.160(10) . ?
C82 Au6 2.041(11) . ?
C83 C84 1.365(13) . ?
C84 C85 1.3900 . ?
C84 C89 1.3900 . ?
C85 C86 1.3900 . ?
C85 H85 0.9300 . ?
C86 C87 1.3900 . ?
C86 H86 0.9300 . ?
C87 C88 1.3900 . ?
C87 H87 0.9300 . ?
C88 C89 1.3900 . ?
C88 H88 0.9300 . ?
C89 H89 0.9300 . ?
C90 C91 1.525(13) . ?
C90 H90A 0.9600 . ?
C90 H90B 0.9600 . ?
C90 H90C 0.9600 . ?
C91 C93 1.522(13) . ?
C91 C94 1.546(12) . ?
C91 C92 1.564(12) . ?
C92 P4 1.839(9) . ?
C92 H92A 0.9700 . ?
C92 H92B 0.9700 . ?
C93 P5 1.856(9) . ?
C93 H93A 0.9700 . ?
C93 H93B 0.9700 . ?
C94 P6 1.864(9) . ?
C94 H94A 0.9700 . ?
C94 H94B 0.9700 . ?
C95 C96 1.3900 . ?
C95 C100 1.3900 . ?
C95 P4 1.814(6) . ?
C96 C97 1.3900 . ?
C96 H96 0.9300 . ?
C97 C98 1.3900 . ?
C97 H97 0.9300 . ?
C98 C99 1.3900 . ?
C98 H98 0.9300 . ?
C99 C100 1.3900 . ?
C99 H99 0.9300 . ?
C100 H100 0.9300 . ?
C101 C102 1.3900 . ?
C101 C106 1.3900 . ?
C101 P4 1.806(6) . ?
C102 C103 1.3900 . ?
C102 H102 0.9300 . ?
C103 C104 1.3900 . ?
C103 H103 0.9300 . ?
C104 C105 1.3900 . ?
C104 H104 0.9300 . ?
C105 C106 1.3900 . ?
C105 H105 0.9300 . ?
C106 H106 0.9300 . ?
C107 C108 1.3900 . ?
C107 C112 1.3900 . ?
C107 P5 1.835(7) . ?
C108 C109 1.3900 . ?
C108 H108 0.9300 . ?
C109 C110 1.3900 . ?
C109 H109 0.9300 . ?
C110 C111 1.3900 . ?
C110 H110 0.9300 . ?
C111 C112 1.3900 . ?
C111 H111 0.9300 . ?
C112 H112 0.9300 . ?
C113 C114 1.3900 . ?
C113 C118 1.3900 . ?
C113 P5 1.825(7) . ?
C114 C115 1.3900 . ?
C114 H114 0.9300 . ?
C115 C116 1.3900 . ?
C115 H115 0.9300 . ?
C116 C117 1.3900 . ?
C116 H116 0.9300 . ?
C117 C118 1.3900 . ?
C117 H117 0.9300 . ?
C118 H118 0.9300 . ?
C119 C120 1.3900 . ?
C119 C124 1.3900 . ?
C119 P6 1.818(6) . ?
C120 C121 1.3900 . ?
C120 H120 0.9300 . ?
C121 C122 1.3900 . ?
C121 H121 0.9300 . ?
C122 C123 1.3900 . ?
C122 H122 0.9300 . ?
C123 C124 1.3900 . ?
C123 H123 0.9300 . ?
C124 H124 0.9300 . ?
C125 C126 1.3900 . ?
C125 C130 1.3900 . ?
C125 P6 1.806(7) . ?
C126 C127 1.3900 . ?
C126 H126 0.9300 . ?
C127 C128 1.3900 . ?
C127 H127 0.9300 . ?
C128 C129 1.3900 . ?
C128 H128 0.9300 . ?
C129 C130 1.3900 . ?
C129 H129 0.9300 . ?
C130 H130 0.9300 . ?
P1 Au1 2.286(2) . ?
P2 Au2 2.278(2) . ?
P3 Au3 2.274(2) . ?
P4 Au4 2.280(3) . ?
P5 Au5 2.269(3) . ?
P6 Au6 2.277(3) . ?
Au1 Au2 3.0240(6) . ?
Au4 Au5 3.1312(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 Au1 178.5(9) . . ?
C1 C2 C3 177.5(10) . . ?
C4 C3 C8 120.0 . . ?
C4 C3 C2 118.7(6) . . ?
C8 C3 C2 121.2(6) . . ?
C5 C4 C3 120.0 . . ?
C5 C4 H4 120.0 . . ?
C3 C4 H4 120.0 . . ?
C4 C5 C6 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C8 C7 C6 120.0 . . ?
C8 C7 H7 120.0 . . ?
C6 C7 H7 120.0 . . ?
C7 C8 C3 120.0 . . ?
C7 C8 H8 120.0 . . ?
C3 C8 H8 120.0 . . ?
C10 C9 Au2 171.4(10) . . ?
C9 C10 C11 175.1(11) . . ?
C12 C11 C16 120.0 . . ?
C12 C11 C10 119.0(7) . . ?
C16 C11 C10 121.0(7) . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C15 C14 C13 120.0 . . ?
C15 C14 H14 120.0 . . ?
C13 C14 H14 120.0 . . ?
C16 C15 C14 120.0 . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C15 C16 C11 120.0 . . ?
C15 C16 H16 120.0 . . ?
C11 C16 H16 120.0 . . ?
C18 C17 Au3 165.4(10) . . ?
C17 C18 C19 176.7(14) . . ?
C20 C19 C24 120.0 . . ?
C20 C19 C18 119.8(9) . . ?
C24 C19 C18 120.1(9) . . ?
C19 C20 C21 120.0 . . ?
C19 C20 H20 120.0 . . ?
C21 C20 H20 120.0 . . ?
C22 C21 C20 120.0 . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C24 C23 C22 120.0 . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
C23 C24 C19 120.0 . . ?
C23 C24 H24 120.0 . . ?
C19 C24 H24 120.0 . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C25 C26 C27 106.1(7) . . ?
C25 C26 C28 111.9(7) . . ?
C27 C26 C28 112.4(7) . . ?
C25 C26 C29 109.7(7) . . ?
C27 C26 C29 107.2(6) . . ?
C28 C26 C29 109.4(7) . . ?
C26 C27 P1 122.1(6) . . ?
C26 C27 H27A 106.8 . . ?
P1 C27 H27A 106.8 . . ?
C26 C27 H27B 106.8 . . ?
P1 C27 H27B 106.8 . . ?
H27A C27 H27B 106.7 . . ?
C26 C28 P2 119.3(6) . . ?
C26 C28 H28A 107.5 . . ?
P2 C28 H28A 107.5 . . ?
C26 C28 H28B 107.5 . . ?
P2 C28 H28B 107.5 . . ?
H28A C28 H28B 107.0 . . ?
C26 C29 P3 119.8(6) . . ?
C26 C29 H29A 107.4 . . ?
P3 C29 H29A 107.4 . . ?
C26 C29 H29B 107.4 . . ?
P3 C29 H29B 107.4 . . ?
H29A C29 H29B 106.9 . . ?
C31 C30 C35 120.0 . . ?
C31 C30 P1 119.9(4) . . ?
C35 C30 P1 120.1(4) . . ?
C30 C31 C32 120.0 . . ?
C30 C31 H31 120.0 . . ?
C32 C31 H31 120.0 . . ?
C33 C32 C31 120.0 . . ?
C33 C32 H32 120.0 . . ?
C31 C32 H32 120.0 . . ?
C34 C33 C32 120.0 . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C35 C34 C33 120.0 . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C30 120.0 . . ?
C34 C35 H35 120.0 . . ?
C30 C35 H35 120.0 . . ?
C37 C36 C41 120.0 . . ?
C37 C36 P1 121.2(3) . . ?
C41 C36 P1 118.8(3) . . ?
C38 C37 C36 120.0 . . ?
C38 C37 H37 120.0 . . ?
C36 C37 H37 120.0 . . ?
C37 C38 C39 120.0 . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 120.0 . . ?
C40 C39 H39 120.0 . . ?
C38 C39 H39 120.0 . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C40 C41 C36 120.0 . . ?
C40 C41 H41 120.0 . . ?
C36 C41 H41 120.0 . . ?
C43 C42 C47 120.0 . . ?
C43 C42 P2 119.5(4) . . ?
C47 C42 P2 120.5(4) . . ?
C42 C43 C44 120.0 . . ?
C42 C43 H43 120.0 . . ?
C44 C43 H43 120.0 . . ?
C43 C44 C45 120.0 . . ?
C43 C44 H44 120.0 . . ?
C45 C44 H44 120.0 . . ?
C46 C45 C44 120.0 . . ?
C46 C45 H45 120.0 . . ?
C44 C45 H45 120.0 . . ?
C45 C46 C47 120.0 . . ?
C45 C46 H46 120.0 . . ?
C47 C46 H46 120.0 . . ?
C46 C47 C42 120.0 . . ?
C46 C47 H47 120.0 . . ?
C42 C47 H47 120.0 . . ?
C49 C48 C53 120.0 . . ?
C49 C48 P2 116.2(4) . . ?
C53 C48 P2 123.8(4) . . ?
C50 C49 C48 120.0 . . ?
C50 C49 H49 120.0 . . ?
C48 C49 H49 120.0 . . ?
C51 C50 C49 120.0 . . ?
C51 C50 H50 120.0 . . ?
C49 C50 H50 120.0 . . ?
C50 C51 C52 120.0 . . ?
C50 C51 H51 120.0 . . ?
C52 C51 H51 120.0 . . ?
C53 C52 C51 120.0 . . ?
C53 C52 H52 120.0 . . ?
C51 C52 H52 120.0 . . ?
C52 C53 C48 120.0 . . ?
C52 C53 H53 120.0 . . ?
C48 C53 H53 120.0 . . ?
C55 C54 C59 120.0 . . ?
C55 C54 P3 121.5(4) . . ?
C59 C54 P3 118.5(4) . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C57 C56 C55 120.0 . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C56 C57 C58 120.0 . . ?
C56 C57 H57 120.0 . . ?
C58 C57 H57 120.0 . . ?
C59 C58 C57 120.0 . . ?
C59 C58 H58 120.0 . . ?
C57 C58 H58 120.0 . . ?
C58 C59 C54 120.0 . . ?
C58 C59 H59 120.0 . . ?
C54 C59 H59 120.0 . . ?
C61 C60 C65 120.0 . . ?
C61 C60 P3 121.6(4) . . ?
C65 C60 P3 118.4(4) . . ?
C62 C61 C60 120.0 . . ?
C62 C61 H61 120.0 . . ?
C60 C61 H61 120.0 . . ?
C61 C62 C63 120.0 . . ?
C61 C62 H62 120.0 . . ?
C63 C62 H62 120.0 . . ?
C64 C63 C62 120.0 . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C65 C64 C63 120.0 . . ?
C65 C64 H64 120.0 . . ?
C63 C64 H64 120.0 . . ?
C64 C65 C60 120.0 . . ?
C64 C65 H65 120.0 . . ?
C60 C65 H65 120.0 . . ?
C67 C66 Au4 176.8(11) . . ?
C66 C67 C68 174.2(14) . . ?
C69 C68 C73 120.0 . . ?
C69 C68 C67 119.4(8) . . ?
C73 C68 C67 120.6(8) . . ?
C70 C69 C68 120.0 . . ?
C70 C69 H69 120.0 . . ?
C68 C69 H69 120.0 . . ?
C71 C70 C69 120.0 . . ?
C71 C70 H70 120.0 . . ?
C69 C70 H70 120.0 . . ?
C70 C71 C72 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C73 C72 C71 120.0 . . ?
C73 C72 H72 120.0 . . ?
C71 C72 H72 120.0 . . ?
C72 C73 C68 120.0 . . ?
C72 C73 H73 120.0 . . ?
C68 C73 H73 120.0 . . ?
C75 C74 Au5 166.4(12) . . ?
C74 C75 C76 177.7(15) . . ?
C77 C76 C81 120.0 . . ?
C77 C76 C75 119.0(9) . . ?
C81 C76 C75 120.8(9) . . ?
C78 C77 C76 120.0 . . ?
C78 C77 H77 120.0 . . ?
C76 C77 H77 120.0 . . ?
C79 C78 C77 120.0 . . ?
C79 C78 H78 120.0 . . ?
C77 C78 H78 120.0 . . ?
C78 C79 C80 120.0 . . ?
C78 C79 H79 120.0 . . ?
C80 C79 H79 120.0 . . ?
C81 C80 C79 120.0 . . ?
C81 C80 H80 120.0 . . ?
C79 C80 H80 120.0 . . ?
C80 C81 C76 120.0 . . ?
C80 C81 H81 120.0 . . ?
C76 C81 H81 120.0 . . ?
C83 C82 Au6 174.8(11) . . ?
C82 C83 C84 178.6(13) . . ?
C83 C84 C85 121.6(10) . . ?
C83 C84 C89 118.4(10) . . ?
C85 C84 C89 120.0 . . ?
C86 C85 C84 120.0 . . ?
C86 C85 H85 120.0 . . ?
C84 C85 H85 120.0 . . ?
C87 C86 C85 120.0 . . ?
C87 C86 H86 120.0 . . ?
C85 C86 H86 120.0 . . ?
C86 C87 C88 120.0 . . ?
C86 C87 H87 120.0 . . ?
C88 C87 H87 120.0 . . ?
C87 C88 C89 120.0 . . ?
C87 C88 H88 120.0 . . ?
C89 C88 H88 120.0 . . ?
C88 C89 C84 120.0 . . ?
C88 C89 H89 120.0 . . ?
C84 C89 H89 120.0 . . ?
C91 C90 H90A 109.5 . . ?
C91 C90 H90B 109.5 . . ?
H90A C90 H90B 109.5 . . ?
C91 C90 H90C 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C93 C91 C90 114.8(8) . . ?
C93 C91 C94 107.9(8) . . ?
C90 C91 C94 110.2(8) . . ?
C93 C91 C92 113.1(7) . . ?
C90 C91 C92 103.2(8) . . ?
C94 C91 C92 107.3(7) . . ?
C91 C92 P4 123.4(7) . . ?
C91 C92 H92A 106.5 . . ?
P4 C92 H92A 106.5 . . ?
C91 C92 H92B 106.5 . . ?
P4 C92 H92B 106.5 . . ?
H92A C92 H92B 106.5 . . ?
C91 C93 P5 120.7(7) . . ?
C91 C93 H93A 107.1 . . ?
P5 C93 H93A 107.1 . . ?
C91 C93 H93B 107.1 . . ?
P5 C93 H93B 107.1 . . ?
H93A C93 H93B 106.8 . . ?
C91 C94 P6 119.5(7) . . ?
C91 C94 H94A 107.4 . . ?
P6 C94 H94A 107.4 . . ?
C91 C94 H94B 107.4 . . ?
P6 C94 H94B 107.4 . . ?
H94A C94 H94B 107.0 . . ?
C96 C95 C100 120.0 . . ?
C96 C95 P4 117.4(4) . . ?
C100 C95 P4 122.5(4) . . ?
C95 C96 C97 120.0 . . ?
C95 C96 H96 120.0 . . ?
C97 C96 H96 120.0 . . ?
C98 C97 C96 120.0 . . ?
C98 C97 H97 120.0 . . ?
C96 C97 H97 120.0 . . ?
C99 C98 C97 120.0 . . ?
C99 C98 H98 120.0 . . ?
C97 C98 H98 120.0 . . ?
C98 C99 C100 120.0 . . ?
C98 C99 H99 120.0 . . ?
C100 C99 H99 120.0 . . ?
C99 C100 C95 120.0 . . ?
C99 C100 H100 120.0 . . ?
C95 C100 H100 120.0 . . ?
C102 C101 C106 120.0 . . ?
C102 C101 P4 122.2(4) . . ?
C106 C101 P4 117.7(4) . . ?
C103 C102 C101 120.0 . . ?
C103 C102 H102 120.0 . . ?
C101 C102 H102 120.0 . . ?
C102 C103 C104 120.0 . . ?
C102 C103 H103 120.0 . . ?
C104 C103 H103 120.0 . . ?
C105 C104 C103 120.0 . . ?
C105 C104 H104 120.0 . . ?
C103 C104 H104 120.0 . . ?
C104 C105 C106 120.0 . . ?
C104 C105 H105 120.0 . . ?
C106 C105 H105 120.0 . . ?
C105 C106 C101 120.0 . . ?
C105 C106 H106 120.0 . . ?
C101 C106 H106 120.0 . . ?
C108 C107 C112 120.0 . . ?
C108 C107 P5 117.7(6) . . ?
C112 C107 P5 122.2(6) . . ?
C109 C108 C107 120.0 . . ?
C109 C108 H108 120.0 . . ?
C107 C108 H108 120.0 . . ?
C110 C109 C108 120.0 . . ?
C110 C109 H109 120.0 . . ?
C108 C109 H109 120.0 . . ?
C109 C110 C111 120.0 . . ?
C109 C110 H110 120.0 . . ?
C111 C110 H110 120.0 . . ?
C112 C111 C110 120.0 . . ?
C112 C111 H111 120.0 . . ?
C110 C111 H111 120.0 . . ?
C111 C112 C107 120.0 . . ?
C111 C112 H112 120.0 . . ?
C107 C112 H112 120.0 . . ?
C114 C113 C118 120.0 . . ?
C114 C113 P5 122.9(5) . . ?
C118 C113 P5 117.1(5) . . ?
C113 C114 C115 120.0 . . ?
C113 C114 H114 120.0 . . ?
C115 C114 H114 120.0 . . ?
C116 C115 C114 120.0 . . ?
C116 C115 H115 120.0 . . ?
C114 C115 H115 120.0 . . ?
C115 C116 C117 120.0 . . ?
C115 C116 H116 120.0 . . ?
C117 C116 H116 120.0 . . ?
C118 C117 C116 120.0 . . ?
C118 C117 H117 120.0 . . ?
C116 C117 H117 120.0 . . ?
C117 C118 C113 120.0 . . ?
C117 C118 H118 120.0 . . ?
C113 C118 H118 120.0 . . ?
C120 C119 C124 120.0 . . ?
C120 C119 P6 117.9(4) . . ?
C124 C119 P6 122.1(4) . . ?
C121 C120 C119 120.0 . . ?
C121 C120 H120 120.0 . . ?
C119 C120 H120 120.0 . . ?
C120 C121 C122 120.0 . . ?
C120 C121 H121 120.0 . . ?
C122 C121 H121 120.0 . . ?
C123 C122 C121 120.0 . . ?
C123 C122 H122 120.0 . . ?
C121 C122 H122 120.0 . . ?
C122 C123 C124 120.0 . . ?
C122 C123 H123 120.0 . . ?
C124 C123 H123 120.0 . . ?
C123 C124 C119 120.0 . . ?
C123 C124 H124 120.0 . . ?
C119 C124 H124 120.0 . . ?
C126 C125 C130 120.0 . . ?
C126 C125 P6 117.7(5) . . ?
C130 C125 P6 122.0(5) . . ?
C127 C126 C125 120.0 . . ?
C127 C126 H126 120.0 . . ?
C125 C126 H126 120.0 . . ?
C128 C127 C126 120.0 . . ?
C128 C127 H127 120.0 . . ?
C126 C127 H127 120.0 . . ?
C129 C128 C127 120.0 . . ?
C129 C128 H128 120.0 . . ?
C127 C128 H128 120.0 . . ?
C128 C129 C130 120.0 . . ?
C128 C129 H129 120.0 . . ?
C130 C129 H129 120.0 . . ?
C129 C130 C125 120.0 . . ?
C129 C130 H130 120.0 . . ?
C125 C130 H130 120.0 . . ?
C36 P1 C30 105.1(3) . . ?
C36 P1 C27 106.4(3) . . ?
C30 P1 C27 103.4(4) . . ?
C36 P1 Au1 110.2(2) . . ?
C30 P1 Au1 112.8(2) . . ?
C27 P1 Au1 118.0(3) . . ?
C48 P2 C42 104.2(3) . . ?
C48 P2 C28 103.4(4) . . ?
C42 P2 C28 106.5(4) . . ?
C48 P2 Au2 110.9(2) . . ?
C42 P2 Au2 113.1(2) . . ?
C28 P2 Au2 117.6(3) . . ?
C54 P3 C60 106.4(3) . . ?
C54 P3 C29 108.1(4) . . ?
C60 P3 C29 101.3(3) . . ?
C54 P3 Au3 112.9(2) . . ?
C60 P3 Au3 113.1(2) . . ?
C29 P3 Au3 114.2(3) . . ?
C101 P4 C95 105.9(4) . . ?
C101 P4 C92 100.6(4) . . ?
C95 P4 C92 109.5(4) . . ?
C101 P4 Au4 112.7(3) . . ?
C95 P4 Au4 110.5(3) . . ?
C92 P4 Au4 116.8(3) . . ?
C113 P5 C107 106.6(4) . . ?
C113 P5 C93 103.0(4) . . ?
C107 P5 C93 105.1(4) . . ?
C113 P5 Au5 109.7(3) . . ?
C107 P5 Au5 112.6(3) . . ?
C93 P5 Au5 118.8(3) . . ?
C125 P6 C119 106.0(4) . . ?
C125 P6 C94 100.7(4) . . ?
C119 P6 C94 107.7(4) . . ?
C125 P6 Au6 112.8(3) . . ?
C119 P6 Au6 111.8(3) . . ?
C94 P6 Au6 116.7(3) . . ?
C1 Au1 P1 173.9(3) . . ?
C1 Au1 Au2 96.8(3) . . ?
P1 Au1 Au2 89.31(6) . . ?
C9 Au2 P2 175.8(3) . . ?
C9 Au2 Au1 101.5(3) . . ?
P2 Au2 Au1 82.69(6) . . ?
C17 Au3 P3 177.5(3) . . ?
C66 Au4 P4 174.1(3) . . ?
C66 Au4 Au5 93.0(3) . . ?
P4 Au4 Au5 92.64(7) . . ?
C74 Au5 P5 169.4(4) . . ?
C74 Au5 Au4 99.8(3) . . ?
P5 Au5 Au4 89.68(7) . . ?
C82 Au6 P6 177.8(3) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.68
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.420
_refine_diff_density_min         -0.970
_refine_diff_density_rms         0.159